04-10-2018 дата публикации
Номер: US20180282896A1
Принадлежит:
There is provided a manufacturing method of a ferroelectric crystal film in which an orientation of a seed crystal film is transferred preferably and a film deposition rate is suitable for volume production. 1. A manufacturing apparatus for a ferroelectric crystal film , comprising:a first apparatus forming a ferroelectric seed crystal film having an orientation in a predetermined face over a substrate in epitaxial growth by a sputtering method;a second apparatus performing coating to form an amorphous film including ferroelectric material over said ferroelectric seed crystal film by a spin-coat coating method; anda third apparatus heating said ferroelectric seed crystal film and said amorphous film in an oxygen atmosphere to oxidize and crystallize said amorphous film, and thereby forming a ferroelectric coated-and-sintered crystal film.2. The manufacturing apparatus for a ferroelectric crystal film according to claim 1 , whereinsaid ferroelectric coated-and-sintered crystal film has an orientation in the same face as said predetermined face.3. The manufacturing apparatus for a ferroelectric crystal film according to claim 1 , wherein{'sub': 3', '3, 'each of said ferroelectric seed crystal film and said ferroelectric coated-and-sintered crystal film is a Pb(Zr, Ti)Ofilm or a (Pb, A) (Zr, Ti)Ofilm and A is configured with at least one kind selected from the group consisting of Li, Na, K, Rb, Ca, Sr, Ba, Bi, and La.'}4. The manufacturing apparatus for a ferroelectric crystal film according to claim 3 , wherein{'sub': 3', '3, 'claim-text': {'br': None, '60/40≤Zr/Ti≤40/60\u2003\u2003(1)'}, 'a Zr/Ti ratio in the number of elements for said Pb(Zr, Ti)Ofilm or (Pb, A) (Zr, Ti)Ofilm satisfies the following formula (1).'}5. The manufacturing apparatus for a ferroelectric crystal film according to claim 3 , wherein{'sub': 3', '3, 'claim-text': [{'br': None, 'Pb/(Zr+Ti)<1.06\u2003\u2003(2)'}, {'br': None, '(Pb+A)/(Zr+Ti)≤1.35\u2003\u2003(3)'}], 'each ratio in the number of ...
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