28-05-2020 дата публикации
Номер: US20200165375A1
Принадлежит:
The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same. 2: The polyurethane according to claim 1 , wherein the polyisocyanate is selected from the group consisting of diisocyanates claim 1 , triisocyanates claim 1 , dimers claim 1 , trimers and mixtures thereof.3: The polyurethane according to claim 2 , wherein the polyisocyanate is selected from the group consisting of ethylene diisocyanate claim 2 , trimethylene diisocyanate claim 2 , 1 claim 2 ,6-hexamethylene diisocyanate claim 2 , tetramethylene diisocyanate claim 2 , hexamethylene diisocyanate claim 2 , octamethylene diisocyanate claim 2 , nonamethylene diisocyanate claim 2 , decamethylene diisocyanate claim 2 , 1 claim 2 ,6 claim 2 ,11-undecane-triisocyanate claim 2 , 1 claim 2 ,3 claim 2 ,6-hexamethylene triisocyanate claim 2 , bis(isocyanatoethyl)-carbonate claim 2 , bis(isocyanatoethyl)ether claim 2 , trimethylhexane diisocyanate claim 2 , trimethylhexamethylene diisocyanate claim 2 , 2 claim 2 ,2′-dimethylpentane diisocyanate claim 2 , 2 claim 2 ,2 claim 2 ,4-trimethylhexane diisocyanate claim 2 , 2 claim 2 ,4 claim 2 ,4-trimethylhexamethylene diisocyanate claim 2 , 1 claim 2 ,8-diisocyanato-4-(isocyanatomethyl) octane claim 2 , 2 claim 2 ,5 claim 2 ,7-trimethyl-1 claim 2 ,8 ...
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