28-04-2023 дата публикации
Номер: CN116023674A
Принадлежит:
The invention discloses an iron-based metal organic framework material as well as a preparation method and application thereof. The method comprises the following steps: (1) adding FeCl3 and 5-(3, 5-dicarboxybenzyloxy) isophthalic acid into DMF (Dimethyl Formamide) for dissolving, adding glacial acetic acid, and stirring; filling the obtained mixed solution into a glass scintillation bottle, and carrying out program temperature control solvothermal synthesis reaction to obtain the iron-based metal organic framework material; (2) washing the target crystal product, carrying out solvent exchange, activating and degassing to obtain an activated iron-based metal organic framework material; the iron-based metal organic framework material disclosed by the invention has high CO2 adsorption capacity, and the CO2 adsorption capacity is as high as 6.4 mmol/g under 298K and 100kPa. And the material has the performance of enhancing CO2 adsorption by water vapor, and the working capacity of the material ...
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