18-07-2023 дата публикации
Номер: CN116454297A
Принадлежит:
The invention provides an MOF membrane air positive electrode catalyst and a preparation method and application thereof, and the preparation method comprises the following steps: 1) carrying out hydrothermal reaction on a reaction solution containing Mo < 6 + >, Ni < 2 + >, Mn < 2 + > and an organic ligand, and carrying out solid-liquid separation to obtain a solid MnNiMo-MOF crystal powder; (2) under the protective atmosphere, the MnNiMo-MOF crystal powder is calcined, and a MnNi/MoO2 material is obtained; and 3) dispersing the MnNi/MoO2 material, a carbon nanotube, a surfactant and polyvinylidene fluoride in water, carrying out suction filtration to form a film, and calcining and carbonizing the film in a protective atmosphere to obtain the MOF film air positive electrode catalyst. The preparation process is simple and universal, has no special requirements on equipment, and can be used for large-scale industrial production; the MOF membrane air positive electrode catalyst is uniform ...
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