26-05-2023 дата публикации
Номер: CN116162028A
Принадлежит:
The invention provides a method for preparing aniline by liquid-phase low-temperature catalytic hydrogenation of nitrobenzene, which comprises the following steps: adding nitrobenzene, aniline and a noble metal catalyst into a reaction kettle according to a mass ratio, introducing nitrogen for replacement for three times, and introducing hydrogen at the pressure of 0.3-1.5 MPa; stirring at a certain rotating speed, heating to 60-110 DEG C, starting hydrogenation reaction, supplementing hydrogen to set partial pressure according to the pressure drop of the reaction kettle in the reaction process, starting heat exchange according to the temperature change to maintain the temperature stable, and finishing hydrogenation, cooling and filtering the catalyst by supplementing hydrogen for multiple times until no pressure drop exists in the reaction kettle to obtain the product aniline. On the basis of a noble metal hydrogenation catalyst, the invention provides the method for preparing aniline ...
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