13-04-2017 дата публикации
Номер: US20170101376A1
The present invention relates to a process for the synthesis of molecules that have a pyrrole ring bonded to a diol. In particular, the invention relates to the synthesis of molecules that have the pyrrole ring and a diol derived from serinol by means of a process that does not demand the use of solvents or chemical catalysts. 2. Process according to claim 1 , characterized in that said step a) of reaction of the compound of formula (II) with the compound of formula (III) is conducted without acids.3. Process according to claim 1 , characterized in that said R claim 1 , R claim 1 , R claim 1 , and Rare preferably independently selected from the group consisting of: hydrogen claim 1 , C-Calkyl claim 1 , C-Calkenyl claim 1 , C-Calkynyl claim 1 , C-Clinear or branched alkyl claim 1 , aryl claim 1 , alkyl-aryl claim 1 , C-Clinear or branched alkenyl-aryl claim 1 , C-C-alkynyl aryl claim 1 , heterocycle claim 1 , and said R claim 1 , Rare preferably independently selected from the group consisting of: hydrogen claim 1 , C-Calkyl claim 1 , C-Calkenyl claim 1 , C-Calkynyl claim 1 , C-Clinear or branched alkyl claim 1 , aryl claim 1 , alkyl-aryl claim 1 , C-Clinear or branched alkenyl-aryl claim 1 , C-Calkynyl aryl claim 1 , heterocycle.4. Process according to claim 1 , characterized in that said R claim 1 , R claim 1 , R claim 1 , and Rare more preferably independently selected from the group consisting of: H claim 1 , CH claim 1 , CHCH claim 1 , phenyl claim 1 , and said R claim 1 , Rare more preferably independently selected from the group consisting of: H claim 1 , CH claim 1 , CHCH.5. Process according to claim 1 , characterized in that said carbon allotrope or its derivative are selected from the group consisting of: carbon black claim 1 , fullerene claim 1 , single-wall or multiwall carbon nanotube claim 1 , graphene claim 1 , graphite with a number of graphene layers from 2 to 10000.6. Process according to claim 1 , characterized in that said carbon allotrope ...
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