09-05-2013 дата публикации
Номер: US20130115367A1
A method for forming a ruthenium oxide film includes: providing a substrate in a processing chamber; supplying a ruthenium compound having a structure of the following formula (1) in which two β-diketons and two groups selected among olefin, amine, nitril, and carbonyl are coordinate-bonded to Ru in a vapor state onto the substrate; supplying oxygen gas onto the substrate; and forming a ruthenium oxide film on the substrate by reaction between the ruthenium compound gas and the oxygen gas. 2. The method of claim 1 , wherein the oxygen gas is supplied at a flow rate that allows the ruthenium compound to be reduced to metal ruthenium and the reduced metal ruthenium to be oxidized.3. The method of claim 2 , wherein the oxygen gas is supplied such that an oxygen gas partial pressure in the processing chamber becomes about 5 Torr or above.4. The method of claim 2 , wherein the ruthenium compound and the oxygen gas are supplied such that a partial pressure ratio of the oxygen gas to the Ru compound gas in the processing chamber becomes about 20 or above.5. The method of claim 1 , wherein the β-diketons of the ruthenium compound are any one of 2 claim 1 ,4-hexanedione claim 1 , 5-methyl-2 claim 1 ,4-hexanedione claim 1 , 2 claim 1 ,4-heptanedione claim 1 , 5-methyl-2 claim 1 ,4-heptanedione claim 1 , 6-methyl-2 claim 1 ,4-heptanedione claim 1 , and 2 claim 1 ,4-octanedione.8. The method of claim 1 , wherein the ruthenium compound gas and the oxygen gas are simultaneously supplied into the processing chamber.9. The method of claim 1 , wherein the ruthenium compound gas and the oxygen gas are alternately supplied into the processing chamber with a purge process therebetween.10. A storage medium that stores a program for execution on a computer to control a film forming apparatus claim 1 , wherein the program claim 1 , when executed claim 1 , controls the film forming apparatus such that the method of is performed. The present application claims priority under 35 U.S.C. §119 ...
Подробнее