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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 1144. Отображено 100.
02-02-2012 дата публикации

PESTICIDE COMPOSITION COMPRISING A TETRAZOLYLOXIME DERIVATIVE AND A FUNGICIDE OR AN INSECTICIDE ACTIVE SUBSTANCE

Номер: US20120027741A1
Автор: Coqueron Pierre-Yves, Portz Daniela, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to a pesticide composition intended for protecting plants, crops or seeds against fungal diseases or insect damages, and the corresponding methods of protection by application of the said composition. More precisely, the subject of the present invention is a pesticide composition based on a tetrazolyloxime derivative and a fungicide or an insecticide active substance or compound. 6. A composition according to or wherein the substitution position of Rin the tetrazolyloxime derivative of formula (I) is not specifically limited and Rrepresents a hydrogen atom , a halogen atom , a substituted or non-substituted C-C-alkyl , a substituted or non-substituted C-C-alkoxy.7. A composition according to or wherein the substitution position of Rin the tetrazolyloxime derivative of formula (I) is not specifically limited and Rrepresents a hydrogen atom , a halogen atom , a methyl group , a tert-butyl group , a methoxy group or an ethoxy group.8. A composition according to wherein Rrepresents a hydrogen atom or a halogen atom.9. A composition according to or wherein Y represents a methyl group.10. A composition according to or wherein Rand Rindependently represent a hydrogen atom or a halogen atom.11. A composition according to or wherein the tetrazolyloxime derivative of formula (1) is but-3-yn-1-yl {6-[({[(Z)-(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate.12. A composition according to wherein fungicide compounds B and C are independently selected in the list consisting of:(1.1) aldimorph (1704-28-5), (1.2) azaconazole (60207-31-0), (1.3) bitertanol (55179-31-2), (1.4) bromuconazole (116255-48-2), (1.5) cyproconazole (113096-99-4), (1.6) diclobutrazole (75736-33-3), (1.7) difenoconazole (119446-68-3), (1.8) diniconazole (83657-24-3), (1.9) diniconazole-M (83657-18-5), (1.10) dodemorph (1593-77-7), (1.11) dodemorph acetate (31717-87-0), (1.12) epoxiconazole (106325-08-0), (1.13) etaconazole (60207-93-4), (1.14) ...

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Номер записи: 1
22-03-2012 дата публикации

2-PYRIDINYLETHYLCARBOXAMIDE DERIVATIVES AND THEIR USE AS FUNGICIDES

Номер: US20120071517A1
Автор: Coqueron Pierre-Yves, Desbordes Philippe, Genix Pierre, Grosjean-Cournoyer Marie-Claire, MANSFIELD Darren James, Rieck Heiko, VILLIER Alain
Принадлежит: BAYER SAS

The invention discloses a compound of general formula (I) 119-. (canceled)21. The compound of wherein n is 1 or 2.22. The compound of wherein X is a halogen atom.23. The compound of wherein X is chlorine.24. The compound of wherein W is —CF.25. The compound of wherein the 2-pyridyl is substituted in the 3- and/or in the 5-position.26. The compound of wherein the 2-pyridyl is substituted in the 3-position by X and in the 5-position by R.27. The compound of wherein the 2-pyridyl is substituted in the 3-position by —Cl and in the 5-position by —CF.28. The compound of wherein Rand Rare independently selected from the group consisting of a hydrogen atom claim 20 , a halogen atom claim 20 , a cyano group claim 20 , a hydroxy group claim 20 , a C-C-alkyl claim 20 , a C-C-halogenoalkyl having 1 to 5 halogen atoms claim 20 , a C-C-alkenyl claim 20 , a C-C-alkoxy claim 20 , a C-C-alkylsulfanyl claim 20 , a C-C-alkylsulfenyl claim 20 , a C-C-alkylsulfinyl claim 20 , a C-C-alkoxycarbonyl claim 20 , a C-C-alkylcarbonylamino claim 20 , a C-C-alkoxycarbonyloxy claim 20 , a C-C-alkoxycarbonylamino claim 20 , and a phenyl group.29. The compound of wherein Rand Rare independently selected from the group consisting of a halogen atom claim 28 , a C-C-alkyl claim 28 , a C-C-halogenoalkyl having 1 to 5 halogen atoms claim 28 , and a C-C-alkylcarbonylamino.30. The compound of wherein Rand Rare independently selected from the group consisting of a hydrogen atom claim 20 , a halogen atom claim 20 , a cyano group claim 20 , a C-C-alkyl claim 20 , a C-C-halogenoalkyl having 1 to 5 halogen atoms claim 20 , a C-C-alkylcarbonylamino claim 20 , and a phenyl group.31. The compound of wherein Rand Rare independently selected from the group consisting of a halogen atom claim 30 , a C-C-alkyl claim 30 , a C-C-halogenoalkyl having 1 to 5 halogen atoms claim 30 , and a phenyl group.32. The compound of wherein Ris selected from the group consisting of a hydrogen atom claim 20 , and a C-C-cycloalkyl.33. ...

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Номер записи: 2
10-01-2013 дата публикации

FUNGICIDE HYDROXIMOYL-TETRAZOLE DERIVATIVES

Номер: US20130012546A1
Автор: Beier Christian, Benting Jurgen, Bernier David, Coqueron Pierre-Yves, Desbordes Philippe, Dubost Christophe, Gary Stephanie, Genix Pierre, Portz Daniela, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to hydroximoyl-tetrazole derivatives of formula (I), their process of preparation, their use as fungicide active agents, particularly in the form of fungicide compositions and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions. 2. A compound according to claim 1 , wherein X represents a hydrogen atom claim 1 , a halogen atom claim 1 , substituted or non-substituted C-C-alkyl claim 1 , a substituted or non-substituted C-C-alkoxy claim 1 , a cyano group claim 1 , a methanesulfonyl group claim 1 , a nitro group claim 1 , a trifluoromethyl group or an aryl group.3. A compound according to claim 1 , wherein X represents a hydrogen atom.4. A compound according to anyone of claim 1 , wherein Y represents a substituted or non-substituted C-C-alkyl group.5. A compound according to anyone of claim 1 , wherein Y represents a substituted or non-substituted alkyl group having 1 to 3 carbon atoms.6. A compound according to anyone of claim 1 , wherein Y represents a methyl group or an ethyl group.7. A compound according to anyone of claim 1 , wherein R in the pyridyl group of formula (Het) represents a hydrogen atom or a halogen atom.8. A compound according to anyone of claim 1 , wherein R in the pyridyl group of formula (Het) represents a hydrogen atom or a chlorine atom.9. A compound according to anyone of claim 1 , wherein Q represents substituted or non-substituted C-C-alkyl-(C-C-alkoxyimino)- claim 1 , substituted or non-substituted C-C-alkyl-(C-C-alkenyloxyimino)- claim 1 , substituted or non-substituted C-C-alkyl-(C-C-alkynyloxyimino)- claim 1 , substituted or non-substituted C-C-alkyl-(benzyloxyimino)- claim 1 , substituted or non-substituted aryl-(C-C-alkoxyimino)- claim 1 , substituted or non-substituted aryl-(C-C-alkenyloxyimino)- claim 1 , substituted or non-substituted aryl-(C-C-alkynyloxyimino)- claim 1 , substituted or non-substituted aryl-(benzyloxyimino)- claim 1 , a substituted ...

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Номер записи: 3
21-02-2013 дата публикации

FUNGICIDE HYDROXIMOYL-HETEROCYCLES DERIVATIVES

Номер: US20130045995A1
Автор: Beier Christian, Benting Jurgen, Bernier David, Coqueron Pierre-Yves, Desbordes Philippe, Dubost Christophe, Portz Daniela, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to hydroximoyl-heterocycle derivatives of formula (I) 2. A compound according to wherein X represents a halogen atom claim 1 , a substituted or non-substituted C-C-alkyl group claim 1 , a substituted or non-substituted C-C-alkoxy group claim 1 , or a hydrogen atom.3. A compound according to wherein X represents a hydrogen atom.4. A compound according to wherein T represents T claim 1 , Tor T.5. A compound according to wherein Xrepresents a hydrogen atom claim 4 , a halogen atom claim 4 , methyl claim 4 , isopropyl claim 4 , isobutyl claim 4 , tertbutyl claim 4 , trifluoromethyl claim 4 , difluoromethyl claim 4 , allyl claim 4 , ethynyl claim 4 , propargyl claim 4 , cyclopropyl claim 4 , benzyl claim 4 , phenethyl claim 4 , methoxy claim 4 , trifluoromethoxy claim 4 , acetyl claim 4 , trifluoroacetyl or cyano.6. A compound according to wherein Xrepresents methyl.7. A compound according to wherein Wrepresents a hydrogen atom claim 1 , a halogen atom claim 1 , a cyano group claim 1 , substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl claim 1 , substituted or non-substituted C-C-halogenoalkyl having 1 to 5 halogen atoms claim 1 , a C-C-alkenyl claim 1 , substituted or non-substituted C-C-alkynyl claim 1 , substituted or non-substituted C-C-alkoxy claim 1 , substituted or non-substituted C-C-halogenoalkoxy having 1 to 5 halogen atoms claim 1 , substituted or non-substituted phenoxy claim 1 , substituted or non-substituted aryl claim 1 , or a substituted or non-substituted aryl-[C-C]-alkyl.8. A compound according to wherein R represents a hydrogen atom or a halogen atom.9. A compound according to wherein Rin the group of formula Q represents a hydrogen atom claim 1 , a fluorine atom or a methyl group.10. A compound according to wherein n in the group of formula Q represents 1.11. A compound according to wherein Rand Rin the group of formula Q independently represent a hydrogen atom claim 1 , a ...

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Номер записи: 4
28-03-2013 дата публикации

N-[(HET)ARYLALKYL)] PYRAZOLE(THIO)CARBOXAMIDES AND THEIR HETEROSUBSTITUTED ANALOGUES

Номер: US20130079302A1
Автор: Benting Jurgen, Coqueron Pierre-Yves, Cristau Pierre, Dahmen Peter, Desbordes Philippe, Gary Stephanie, Greul Jorg, Hadano Hiroyuki, Meissner Ruth, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to fungicidal N-[(het)arylalkyl)]pyrazolecarboxamide or thiocarboxamide and their heterosubstituted analogues, their process of preparation and intermediate compounds for their preparation, their use as fungicides, particularly in the form of fungicidal compositions and methods for the control of phytopathogenic fungi of plants using these compounds or their compositions. 2. A compound according to wherein Xand Xindependently represent a chlorine or a fluorine atom.3. A compound according to wherein Y represents methyl.4. A compound according to wherein T represents O.5. A compound according wherein B represents a substituted or non-substituted phenyl ring; a substituted or non-substituted naphthyl ring; a substituted or non-substituted pyridyl ring; a substituted or non-substituted thienyl ring; or a substituted or non-substituted benzothienyl ring; preferably a substituted or non-substituted phenyl ring or a substituted or non-substituted 2-pyridyl ring.6. A compound according to wherein X independently represents a halogen atom; substituted or non-substituted C-C-alkyl; C-C-halogenoalkyl comprising up to 9 halogen atoms that can be the same or different; substituted or non-substituted tri(C-C-alkyl)silyl; substituted or non-substituted C-C-alkoxy or C-C-halogenoalkoxy comprising up to 9 halogen atoms that can be the same or different; substituted or non-substituted C-C-alkylsulfanyl or C-C-halogenoalkylsulfanyl comprising up to 9 halogen atoms that can be the same or different; or wherein two consecutive substituents X together with the phenyl ring form a substituted or non-substituted cyclopentyl or cyclohexyl ring.7. A compound according to wherein X independently represents fluorine claim 1 , chlorine claim 1 , bromine claim 1 , iodine claim 1 , methyl claim 1 , ethyl claim 1 , propyl claim 1 , isopropyl claim 1 , butyl claim 1 , isobutyl claim 1 , secbutyl claim 1 , terbutyl claim 1 , cyclopropyl claim 1 , cyclopentyl claim 1 , ...

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Номер записи: 5
18-04-2013 дата публикации

PROCESS FOR THE PREPARATION OF 5-SUBSTITUTED 1-ALKYLTETRAZOLYL OXIME DERIVATIVES

Номер: US20130096311A1
Автор: Beier Christian, Bernier David, Coqueron Pierre-Yves, Desbordes Philippe, Dubost Christophe, LUI Norbert, PAZENOK Sergii
Принадлежит:

The present invention relates to a process for the preparation of 5-substituted 1-alkyltetrazolyl oxime derivatives. 3. Process according to claim 1 , characterized in that step (1) is carried out in the presence of a base.4. Process according to claim 3 , characterized in that the molar ratio of base to the oxime of the formula (II) used is 0.8-10.5. Process according to claim 1 , characterized in that step (1) is carried out in a solvent.6. Process according to claim 1 , characterized in that step (2) and (3) are carried out in the presence of a base.7. Process according to claim 6 , characterized in that the molar ratio of base to the compound of the formula (IV) used is 0.8-10.8. Process according to claim 1 , characterized in that the compound of the formula (V) obtained in step (2) is not isolated claim 1 , but is further reacted in situ. The present invention relates to a process for the preparation of 5-substituted 1-alkyltetrazolyl oxime derivatives.5-Substituted 1-alkyltetrazolyl oxime derivatives are important intermediate compounds in active ingredient manufacture or are already fungicidally effective compounds (see e.g. WO 2010/000841). It is already known that 5-substituted 1-alkyltetrazoles can be prepared by lithiation of 1-methyltetrazole at −70° C. (cf. 1971, 49, 2139-2142). However, the yield using the example of 5-benzoyl-1-methyltetrazole is only 41%. The 1-methyltetrazole used likewise has to be prepared in a multistage synthesis sequence. For an industrial reaction, the low temperatures and the expensive use of butyllithium are disadvantageous. Another process for the preparation of 5-benzoyl-1-methyltetrazole is known from 1963, 85, 2967-2976. Benzyl cyanide is reacted with ammonium azide to give 5-benzyltetrazole and then oxidized with chromium trioxide to give 5-benzoyltetrazole. The methylation to 5-benzoyl-1-methyltetrazole takes place with diazomethane. This synthesis route is likewise disadvantageous as regards safety and economical ...

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Номер записи: 6
25-04-2013 дата публикации

PROCESS FOR THE PREPARATION OF 5-SUBSTITUTED 1-ALKYLTETRAZOLYL OXIME DERIVATIVES

Номер: US20130102786A1
Автор: Beier Christian, Bernier David, Coqueron Pierre-Yves, Desbordes Phillipe, Dubost Christophe, LUI Norbert, PAZENOK Sergii
Принадлежит:

The present invention relates to a process for the preparation of 5-substituted 1-alkyltetrazolyl oxime derivatives. 3. Process according to one of claim 1 , characterized in that step (1) is carried out in the presence of a base.4. Process according to claim 3 , characterized in the molar ratio of base to the oxime of the formula (II) used is 0.8-10.5. Process according to claim 1 , characterized in that step (1) is carried out in a solvent.6. Process according to claim 1 , characterized in that step (2) is carried out in the presence of a base.7. Process according to claim 6 , characterized in that the molar ratio of base to the compound of the formula (IV) used is 0.8-10. The present invention relates to a process for the preparation of 5-substituted 1-alkyltetrazolyl oxime derivatives.5-Substituted 1-alkyltetrazolyl oxime derivatives are important intermediate compounds in active ingredient manufacture or are already fungicidally effective compounds (see e.g. WO 2010/000841). It is already known that 5-substituted 1-alkyltetrazoles can be prepared by lithiation of 1-methyltetrazole at −70° C. (cf. 1971, 49, 2139-2142). However, the yield using the example of 5-benzoyl-1-methyltetrazole is only 41%. The 1-methyltetrazole used likewise has to be prepared in a multistage synthesis sequence. For an industrial reaction, the low temperatures and the expensive use of butyllithium are disadvantageous. Another process for the preparation of 5-benzoyl-1-methyltetrazole is known from 1963, 85, 2967-2976. Benzyl cyanide is reacted with ammonium azide to give 5-benzyltetrazole and then oxidized with chromium trioxide to give 5-benzoyltetrazole. The methylation to 5-benzoyl-1-methyltetrazole takes place with diazomethane. This synthesis route is likewise disadvantageous as regards safety and economical aspects. The preparation of 1-cyclohexyl-5-acetyltetrazole by reacting acetyl chloride over cyclohexyl isocyanide with subsequent reaction with hydrazoic acid is also known (cf ...

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Номер записи: 7
09-05-2013 дата публикации

FUNGICIDE HYDROXIMOYL-HETEROCYCLES DERIVATIVES

Номер: US20130116287A1
Автор: Beier Christian, Benting Jurgen, Bernier David, Coqueron Pierre-Yves, Desbordes Philippe, Dubost Christophe, Portz Daniela, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to hydroximoyl-heterocycle derivatives of formula (I) 2. A compound according to wherein X represents a chlorine atom claim 1 , a fluorine atom claim 1 , an alkyl group having 1 to 4 carbon atoms claim 1 , a methyl group claim 1 , a tert-butyl group claim 1 , a methoxy group claim 1 , an ethoxy group claim 1 , or a hydrogen atom.3. A compound according to wherein X represents a hydrogen atom.4. A compound according to wherein T represents T.5. A compound according to wherein Xrepresents a hydrogen atom claim 1 , a halogen atom claim 1 , a cyano group claim 1 , an amino group claim 1 , a sulphenyl group claim 1 , a pentafluoro-□-sulphenyl group claim 1 , substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted tri(C-C-alkyl)silyl-C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl claim 1 , substituted or non-substituted tri(C-C-alkyl)silyl-C-C-cycloalkyl claim 1 , substituted or non-substituted C-C-halogenoalkyl having 1 to 5 halogen atoms claim 1 , substituted or non-substituted C-C-halogenocycloalkyl having 1 to 5 halogen atoms claim 1 , a C-C-alkenyl claim 1 , substituted or non-substituted C-C-alkynyl claim 1 , substituted or non-substituted C-C-alkoxy claim 1 , substituted or non-substituted C-C-halogenoalkoxy having 1 to 5 halogen atoms claim 1 , substituted or non-substituted C-C-alkylsulphenyl claim 1 , substituted or non-substituted C-C-halogenoalkylsulphenyl having 1 to 5 halogen atoms claim 1 , substituted or non-substituted C-C-alkenyloxy claim 1 , substituted or non-substituted C-C-halogenoalkenyloxy having 1 to 5 halogen atoms claim 1 , substituted or non-substituted C-C-alkynyloxy claim 1 , substituted or non-substituted C-C-halogenoalkynyloxy having 1 to 5 halogen atoms claim 1 , substituted or non-substituted C-C-alkylcarbonyl claim 1 , substituted or non-substituted N—(C-C-alkoxy)-C-C-alkanimidoyl claim 1 , substituted or non-substituted N—(C-C-alkoxy)-C-C-halogenoalkanimidoyl ...

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Номер записи: 8
16-05-2013 дата публикации

FUNGICIDE HYDROXIMOYL-TETRAZOLE DERIVATIVES

Номер: US20130123305A1
Автор: Beier Christian, Benting Jurgen, Bernier David, Coqueron Pierre-Yves, Desbordes Philippe, Dubost Christophe, Gary Stephanie, Genix Pierre, Portz Daniela, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to hydroximoyl-tetrazole derivatives of formula (I), their process of preparation, their use as fungicide active agents, particularly in the form of fungicide compositions and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions. 2. A compound according to claim 1 , wherein X represents a hydrogen atom claim 1 , a halogen atom claim 1 , substituted or non-substituted C-C-alkyl claim 1 , a substituted or non-substituted C-Calkoxy claim 1 , a cyano group claim 1 , a methanesulfonyl group claim 1 , a nitro group claim 1 , a trifluoromethyl group or an aryl group.3. A compound according to claim 1 , wherein X represents a hydrogen atom.4. A compound according to claim 1 , wherein Y represents a substituted or non-substituted C-Calkyl group.5. A compound according to claim 1 , wherein Y represents an alkyl group having 1 to 3 carbon atoms.6. A compound according to claim 1 , wherein R in the pyridyl group of formula (Het) represents a hydrogen atom or a halogen atom.7. A compound according to claim 1 , wherein R in the pyridyl group of formula (Het) represents a hydrogen atom or a chlorine atom8. A compound according to claim 1 , wherein Rrepresents a hydrogen atom claim 1 , a fluorine atom or a methyl group.9. A compound according to claim 1 , wherein n represents 1.10. A compound according to claim 1 , wherein Rand Rindependently represent a hydrogen atom claim 1 , a halogen atom claim 1 , or substituted or non-substituted C-C-alkyl.11. A compound according to claim 1 , wherein Rand Rindependently represent a hydrogen atom claim 1 , a fluorine atom claim 1 , or a methyl group.12. A compound according to claim 1 , wherein Lrepresents an oxygen atom or a divalent group of formula —CH.13. A compound according to claim 1 , wherein Lrepresents an oxygen atom.14. A compound according to claim 1 , wherein K claim 1 , K claim 1 , Kand Kindependently represent a hydrogen atom claim 1 , a halogen ...

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Номер записи: 9
23-05-2013 дата публикации

N-[(HET)ARYLETHYL)] PYRAZOLE(THIO)CARBOXAMIDES AND THEIR HETEROSUBSTITUTED ANALOGUES

Номер: US20130131119A1
Автор: Benting Jurgen, BRAUN Christoph, Coqueron Pierre-Yves, Cristau Pierre, Dahmen Peter, Desbordes Philippe, Gary Stephanie, Greul Jorg, Hadano Hiroyuki, KNOBLOCH Thomas, Meissner Ruth, Wachendorf-Neumann Ulrike, Willms Lothar
Принадлежит:

The present invention relates to fungicidal N-[(het)arylethyl)] pyrazolecarboxamide or thiocarboxamide and their heterosubstituted analogues, their process of preparation and intermediate compounds for their preparation, their use as fungicides, particularly in the form of fungicidal compositions and methods for the control of phytopathogenic fungi of plants using these compounds or their compositions. 2. A compound according to wherein Xand Xindependently represent a chlorine or a fluorine atom.3. A compound according to wherein Y represents methyl.4. A compound according to wherein T represents O.5. A compound according to wherein B represents a substituted or non-substituted phenyl ring; a substituted or non-substituted naphthyl ring; a substituted or non-substituted pyridyl ring; a substituted or non-substituted thienyl ring; or a substituted or non-substituted benzothienyl ring; preferably a substituted or non-substituted phenyl ring or a substituted or non-substituted 2-pyridyl ring.6. A compound according to wherein X independently represents a halogen atom; substituted or non-substituted C-C-alkyl; C-C-halogenoalkyl comprising up to 9 halogen atoms that can be the same or different; substituted or non-substituted tri(C-C-alkyl)silyl; substituted or non-substituted C-C-alkoxy or C-C-halogenoalkoxy comprising up to 9 halogen atoms that can be the same or different; substituted or non-substituted C-C-alkylsulfanyl or C-C-halogenoalkylsulfanyl comprising up to 9 halogen atoms that can be the same or different; or wherein two consecutive substituents X together with the phenyl ring form a substituted or non-substituted cyclopentyl or cyclohexyl ring.7. A compound according to wherein X independently represents fluorine claim 1 , chlorine claim 1 , bromine claim 1 , iodine claim 1 , methyl claim 1 , ethyl claim 1 , propyl claim 1 , isopropyl claim 1 , butyl claim 1 , isobutyl claim 1 , secbutyl claim 1 , terbutyl claim 1 , cyclopropyl claim 1 , cyclopentyl claim 1 ...

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Номер записи: 10
13-06-2013 дата публикации

PROCESS FOR ADJUSTING THE RELATIVE POSITION OF A FIRST AND A SECOND PIECE OF A MECHANICAL ASSEMBLY

Номер: US20130145811A1
Автор: Bourban Stewes, DUBACH Alban, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A process for adjusting a device including a first piece and at least one second piece, wherein the at least one second piece is fixed to the first piece by a joint made from a first material arranged between the first and second piece. The first material is an at least partially amorphous metal alloy. The process further includes: heating at least the joint to a heating temperature in a range of between a glass transition temperature and a crystallisation temperature of the first material; modifying a position of the at least one second piece until a desired determined position is obtained; cooling at least the joint so that it retains its at least partially amorphous state. 19-. (canceled)10. A process for adjusting a device comprising a first piece and at least one second piece , comprising:fixing said at least one second piece to the first piece by a joint made from a first material arranged between said first and second pieces, wherein said first material is an at least partially amorphous metal alloy;heating at least said joint to a heating temperature in a range of between a glass transition temperature and a crystallisation temperature of the first material;modifying a position of said at least one second piece until a desired determined position is obtained;cooling at least said joint so that it retains its at least partially amorphous state.11. The process according to claim 10 , wherein said first material is completely amorphous.12. The process according to claim 10 , wherein said metal alloy comprises at least one precious metal element selected from the group consisting of gold claim 10 , platinum claim 10 , palladium claim 10 , rhenium claim 10 , ruthenium claim 10 , rhodium claim 10 , silver claim 10 , iridium or osmium.13. The process according to claim 11 , wherein said metal alloy comprises at least one precious metal element selected from the group consisting of gold claim 11 , platinum claim 11 , palladium claim 11 , rhenium claim 11 , ruthenium ...

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Номер записи: 11
13-06-2013 дата публикации

ESCAPEMENT SYSTEM FOR A TIMEPIECE

Номер: US20130148480A1
Автор: CHARBON Christian, Verardo Marco, Winkler Yves
Принадлежит: THE SWATCH GROUP RESEARCH AND DEVELOPMENT LTD.

An escapement system that includes an anchor fitted with a fork configured to cooperate with a pin mounted on a disc and a shaft including arms configured to receive pallets to cooperate with at least one escape wheel. A part of the escapement system is made from an at least partially amorphous metal alloy. 113-. (canceled)14. An escapement system comprising:an anchor fitted with a fork configured to cooperate with a pin mounted on a disc; anda shaft comprising arms configured to receive pallets to cooperate with at least one escape wheel;wherein at least one part of the escapement system is made from an at least partially amorphous metal alloy.15. The escapement system according to claim 14 , wherein the anchor is made from an at least partially amorphous metal alloy.16. The escapement system according to claim 14 , wherein the pallets of the anchor are made from an at least partially amorphous metal alloy.17. The escapement system according to claim 15 , wherein the pallets of the anchor are made from an at least partially amorphous metal alloy.18. The escapement system according to claim 14 , wherein the pallets of the anchor and the anchor form one and a same piece.19. The escapement system according to claim 15 , wherein the pallets of the anchor and the anchor form one and a same piece.20. The escapement system according to claim 16 , wherein the pallets of the anchor and the anchor form one and a same piece.21. The escapement system according to claim 17 , wherein the pallets of the anchor and the anchor form one and a same piece.22. The escapement system according to claim 14 , wherein the escape wheel is made from an at least partially amorphous metal alloy.23. The escapement system according to claim 14 , wherein the disc is made from an at least partially amorphous metal alloy.24. The escapement system according to claim 14 , wherein at least one part of the escapement system comprises recesses to reduce moment of inertia of the at least one part.25. The ...

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Номер записи: 12
13-06-2013 дата публикации

DIAL FOOT OF A TIMEPIECE

Номер: US20130148484A1
Автор: Jeanrenaud Frederic, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A dial of a timepiece. The dial includes at least one foot. The foot is fixed on the dial and is used to fix the dial on the timepiece. The foot is produced in a metallic alloy which is at least partially amorphous. 117-. (canceled)18. A timepiece dial comprising:at least one foot, said at least one foot being fixed on said dial and used to fix said dial on said timepiece,wherein said at least one foot and the dial are produced in a metallic alloy which is at least partially amorphous.19. A timepiece dial comprising:at least one foot, said dial is fixed on a support on which said at least one foot is fixed to fix said dial on said timepiece,wherein said at least one foot and the support are produced in a metallic alloy which is at least partially amorphous.20. The timepiece dial according to claim 18 , wherein said at least one foot and the dial are one and a same part.21. The timepiece dial according to claim 19 , wherein said at least one foot and the support are one and a same part.22. The timepiece dial according to claim 18 , wherein said at least one foot is mounted on the dial.23. The timepiece dial according to claim 19 , wherein said at least one foot is mounted on the support.24. The dial according to claim 18 , wherein said material is totally amorphous.25. The dial according to claim 19 , wherein said material is totally amorphous.26. The dial according to claim 18 , wherein the dial comprises at least one recess in which said at least one foot is fixed.27. The dial according to claim 19 , wherein the support on which the dial is fixed comprises at least one recess in which said at least one foot is fixed.28. The dial according to claim 26 , wherein sides of said at least one recess comprise reliefs to improve fixing of said at least foot in said at least one recess.29. The dial according to claim 27 , wherein sides of said at least one recess comprise reliefs to improve fixing of said at least foot in said at least one recess.30. The dial according to ...

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Номер записи: 13
04-07-2013 дата публикации

METHOD OF MAKING A COATED AMORPHOUS METAL PART

Номер: US20130167606A1
Автор: Bourban Stewes, Dionne Jean-François, DUBACH Alban, FALLET Yann, Winkler Yves
Принадлежит: THE SWATCH GROUP RESEARCH AND DEVELOPMENT LTD.

A method of producing a first part having at least one surface, formed of a first material. The first part includes at least one coating on the at least one surface. The production method includes: a) taking a second part including a cavity forming the negative of the first part; b) depositing the coating, including at least a first layer, onto the second part; c) taking a first metallic material, chosen for its ability to become at least partially amorphous; d) shaping the first material in the cavity of the second part so as to secure the coating to the at least one surface of the first part, the first material having been subject to a treatment allowing it to become at least partially amorphous, at the latest at the time of the shaping operation; e) separating the first part from the second part so as to obtain the first part coated with the coating. 119-. (canceled)20. A method of making a first part having at least one surface formed of a first material and coated with at least one coating on said at least one surface , said first material including at least one metallic element and being chosen for the ability thereof to become at least partially amorphous when subject to an increase in temperature above the melting temperature thereof which allows said material to lose any crystalline structure locally , followed by cooling to a temperature lower than the vitreous transition temperature thereof allowing said material to become at least partially amorphous , wherein said method comprises:a) taking a second part comprising a cavity forming the negative of the first part;b) depositing said coating, comprising at least a first layer, onto said second part;c) taking the first material;d) shaping the first material by filling said cavity of the second part with said first material so as to secure said coating to said at least one surface of said first part, said first material having been subject to a treatment allowing said material to become at least partially ...

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Номер записи: 14
04-07-2013 дата публикации

METHOD OF MANUFACTURING A DEVICE COMPRISING AT LEAST TWO PARTS

Номер: US20130167981A1
Автор: Bourban Stewes, DUBACH Alban, Winkler Yves
Принадлежит: THE SWATCH GROUP RESEARCH AND DEVELOPMENT LTD.

A method of assembling a device including first and second parts, the method including: taking the first and second parts; assembling the first and second parts provided by their arrangement so a gap is present between the first and second parts; taking a metal alloy, chosen for its ability to become at least partially amorphous; shaping the metal alloy to fill the gap between the first and second parts to join them and thereby form the device, the metal alloy having been subject to a treatment allowing the alloy to become at least partially amorphous, at a latest at a time of the shaping. The metal alloy is subject to a temperature increase above the melting temperature thereof causing the alloy to lose any local crystalline structure, the increase followed by cooling to a lower temperature than vitreous transition temperature thereof allowing the material to become at least partially amorphous. 116-. (canceled)17. A method of assembling a device comprising a first part and at least one second part , said first part and said at least one second part being arranged to allow assembly to each other , wherein said method comprises:taking the first part and the at least one second part;assembling said at least one second part and said first part as provided by the arrangement thereof so that a gap is present between said at least one second part and said first part;taking a metal alloy, chosen for its ability to become at least partially amorphous;shaping said metal alloy so that it fills the gap between said at least one second part and said first part so as to join them and thereby form said device, said metal alloy having been subject to a treatment allowing said alloy to become at least partially amorphous, at the latest at the time of said shaping operation.18. The method according to claim 17 , wherein said metal alloy is subject to a temperature increase above the melting temperature thereof causing said alloy to lose any local crystalline structure claim 17 , ...

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Номер записи: 15
25-07-2013 дата публикации

TIMEPIECE ANTI-SHOCK SYSTEM

Номер: US20130188462A1
Автор: HELFER Jean-Luc, WILLEMIN Michel, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A shock absorber bearing for an arbour of a timepiece wheel set. The arbour includes a pivot-shank extended by a pivot. The bearing includes a support including a recess for receiving a pivot system into which the pivot-shank is inserted. The pivot system is arranged to absorb, at least in part, shocks experienced by the timepiece wheel set and is formed of a single piece made of an at least partially amorphous metal alloy. 16-. (canceled)7. A shock absorber bearing for an arbour of a timepiece wheel set ,said arbour comprising a pivot-shank extended by a pivot;said bearing comprising a support including a recess for receiving a suspended pivot system into which the pivot-shank is inserted;wherein said pivot system is arranged to absorb, at least in part, shocks experienced by the timepiece wheel set, and the pivot system is formed of a single piece made of totally amorphous metal alloy.8. The shock absorber bearing according to claim 7 , wherein said metal alloy includes at least one precious metal element or an alloy thereof.9. The shock absorber bearing according to claim 8 , wherein said precious metal alloy includes gold claim 8 , platinum claim 8 , palladium claim 8 , rhenium claim 8 , ruthenium claim 8 , rhodium claim 8 , silver claim 8 , iridium or osmium.10. The shock absorber bearing according to claim 7 , wherein said pivot system is a disc including an annular portion claim 7 , a central portion claim 7 , and elastic arms connecting the central portion to the annular portion claim 7 , the central portion comprising a recess so that the pivot which is engaged therein can pivot freely therein.11. The shock absorber bearing according to claim 10 , wherein the recess includes a cylindrical portion including a rounded convex portion at an end thereof. The present invention concerns a shock absorber bearing for an arbour of a timepiece wheel set. The arbour includes a pivot-shank extended by a pivot and the bearing includes a support, said support being ...

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Номер записи: 16
25-07-2013 дата публикации

FUNGICIDE COMPOSITION COMPRISING A TETRAZOLYLOXIME DERIVATIVE AND A THIAZOLYLPIPERIDINE DERIVATIVE

Номер: US20130190353A1
Автор: Coqueron Pierre-Yves, Cristau Pierre, TSUCHIYA Tomoki, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to a pesticide composition intended for protecting plants, crops or seeds against fungal diseases or insect damages, and the corresponding methods of protection by application of the said composition. More precisely, the subject of the present invention is a pesticide composition based on a tetrazolyloxime derivative and a thiazolylpiperidine derivative, which may further comprise another fungicide and/or an insecticide active substance or compound. 2. A composition according to wherein Rindependently represents a hydrogen atom claim 1 , a halogen atom claim 1 , a substituted or non-substituted C-C-alkyl claim 1 , a substituted or non-substituted C-C-alkoxy.3. A composition according to wherein Rindependently represents a hydrogen atom or a halogen atom.4. A composition according to wherein Y represents a methyl group.5. A composition according to wherein Rand Rindependently represent a hydrogen atom or a halogen atom.6. A composition according to wherein Rindependently represents a hydrogen atom or a halogen atom.7. A composition according to wherein Rrepresents a hydrogen atom or a fluorine.8. A composition according to wherein the tetrazolyloxime derivative of formula (I) is but-3-yn-1-yl {6-[({[(Z)-(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl }carbamate or tert-butyl{6-[{]([(Z)-(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate.9. A composition according to wherein the thiazolylpiperidine derivative of formula (II) is 2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]-1-{4-[4-(5-phenyl-4 claim 1 ,5-dihydro-1 claim 1 ,2-oxazol-3 -yl)-1 claim 1 ,3-thiazol-2]piperidin-1-1-yl}ethanone or1-(4-{4-[5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone.10. A composition according to further comprisingC) a third fungicide compound,in an A/B/C weight ratio ranging from 1,000/1,000/1 to 1/1,000/1 ...

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Номер записи: 17
22-08-2013 дата публикации

METHOD OF ASSEMBLING A PART

Номер: US20130212856A1
Автор: Bourban Stewes, DUBACH Alban, Winkler Yves
Принадлежит: THE SWATCH GROUP RESEARCH AND DEVELOPMENT LTD.

A method of permanent assembly between at least a first part formed of a first material on the one hand, and at least a second part formed of a second material on the other hand which is configured to confine the first part in the permanent assembly. 113-. (canceled)14. A method of permanent assembly between at least a first part , formed of a first material , and at least a second part , which is formed of a second material , and which is configured to confine said first part in said permanent assembly , the method comprising:selecting as the first material a metal alloy capable of becoming at least partially amorphous, the second material not being a metal alloy capable of becoming at least partially amorphous;taking the part formed of said second material;shaping the first part and simultaneously assembling said first part to the second part, with said first material having undergone, at a latest at a moment of said shaping, a treatment allowing said material to become at least partially amorphous, the first part and the second part undergoing a thermal cycle consisting in an increase in temperature gradient to ensure at least expansion of the second part followed by a cooling gradient for shrinking the second part around the first part so as to confine said first part;sizing said at least one second part and said at least one first part, and choosing the thermal expansion coefficient of said second material compared to the thermal expansion coefficient of said first material, in order, as appropriate;obtaining a permanent assembly with said second part clamped over said first part if the product of said thermal expansion coefficient of said second material and said cooling gradient is higher than the product of said thermal expansion coefficient of said first material and said cooling gradient;obtaining a permanent assembly with at least a degree of freedom between said second part and said first part if the product of said thermal expansion coefficient of said ...

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Номер записи: 18
03-10-2013 дата публикации

Food products comprising hydrolyzed whole grain

Номер: US20130259978A1
Автор: Anne-Sophie Wavreille, Christelle Schaffer-Lequart, Olivier Yves Roger, Yves Bouvet
Принадлежит: Nestec SA

The present invention relates to food products comprising a raising agent, a moisture content below 10% by weight of the food product, a hydrolyzed whole grain composition, and an alpha-amylase or fragment thereof, which alpha-amylase or fragment thereof shows no hydrolytic activity towards dietary fibres when in the active state.

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Номер записи: 19
31-10-2013 дата публикации

FUNGICIDE HYDROXIMOYL-TETRAZOLE DERIVATIVES

Номер: US20130289077A1
Автор: BENTING Juergen, Coqueron Pierre-Yves, Desbordes Philippe, Dubost Christophe, Portz Daniela, Rebstock Anne-Sophie, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to hydroximoyl-heterocycle derivatives of formula (I) 2. A compound according to wherein X represents a hydrogen atom claim 1 , a halogen atom claim 1 , substituted or non-substituted C-C-alkyl claim 1 , a substituted or non-substituted C-C-alkoxy claim 1 , a cyano group claim 1 , a methanesulfonyl group claim 1 , a nitro group claim 1 , a trifluoromethyl group or an aryl group.3. A compound according to wherein X represents a hydrogen atom claim 1 , a chlorine atom claim 1 , a fluorine atom claim 1 , a methyl group claim 1 , a tert-butyl group claim 1 , a methoxy group claim 1 , an ethoxy group claim 1 , a cyano group claim 1 , a methanesulfonyl group claim 1 , a nitro group claim 1 , a trifluoromethyl group or an aryl group.4. A compound according to wherein X represents a hydrogen atom.5. A compound according to wherein q represents 1.6. A compound according to wherein Y represents a substituted or non-substituted C-C-alkyl group.7. A compound according to wherein Y represents a methyl group or an ethyl group.8. A compound according to wherein R represents a hydrogen atom or a halogen atom.9. A compound according to wherein R represents a hydrogen atom or a chlorine atom10. A compound according to wherein Qrepresents a hydrogen atom claim 1 , substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl claim 1 , substituted or non-substituted C-C-alkenyl claim 1 , substituted or non-substituted C-C-alkynyl claim 1 , substituted or non-substituted aryl claim 1 , substituted or non-substituted claim 1 , saturated or unsaturated 4- claim 1 , 5- claim 1 , 6- claim 1 , 7- claim 1 , 8- claim 1 , 9- claim 1 , 10- claim 1 , or 11-membered heterocyclyl comprising up to 4 heteroatoms selected in the list consisting of N claim 1 , O claim 1 , S.11. A compound according to wherein Qrepresents a hydrogen atom claim 1 , or a substituted or non-substituted C-C-alkyl.12. A compound according to wherein Qrepresents ...

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Номер записи: 20
07-11-2013 дата публикации

5-Halogenopyrazolecarboxamides

Номер: US20130296269A1
Автор: Benting Jurgen, Coqueron Pierre-Yves, Cristau Pierre, Dahmen Peter, Desbordes Philippe, Dubost Christophe, Gary Stephanie, Greul Jorg, Hadano Hiroyuki, Vors Jean-Pierre, Wachendorff-Neumann Ulrike
Принадлежит: Bayer Intellectual Property GmbH

The present invention relates to novel 5-halogenopyrazole(thio)carboxamides, their process of preparation, their use as fungicide active agents, particularly in the form of fungicide compositions, and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions. 2. A compound according to claim 1 , wherein T represents an oxygen atom.3. A compound according to claim 1 , wherein R represents hydrogen claim 1 , methylsulfonyl claim 1 , ethylsulfonyl claim 1 , n- or isopropylsulfonyl claim 1 , n- claim 1 , iso- claim 1 , sec- or tert-butylsulfonyl claim 1 , methoxymethyl claim 1 , methoxyethyl claim 1 , ethoxymethyl claim 1 , ethoxyethyl claim 1 , trifluoromethyl-sulfonyl claim 1 , trifluoromethoxymethyl or formyl.4. A compound according to claim 1 , wherein R represents hydrogen claim 1 , methoxymethyl claim 1 , or formyl.6. A compound according to claim 1 ,{'sup': '1', 'wherein Rrepresents hydrogen, fluorine, chlorine, methyl or trifluoromethyl.'}7. A compound according to claim 1 ,{'sup': 1', '1, 'wherein Q and Rtogether with the carbon atoms to which said Q and Rare attached represent a 5- or 6-membered carbocyclic ring which is optionally mono-, di- or trisubstituted by methyl or a 5- or 6-membered saturated heterocyclic ring containing one oxygen atom and which is optionally mono-, di- or trisubstituted by methyl.'}14. A compound according to claim 1 , wherein X represents a single bond.15. A compound according to claim 1 , wherein Y represents oxygen claim 1 , sulfur claim 1 , N(R) claim 1 , CH claim 1 , CHCH claim 1 , CHCHCH claim 1 , C(CH) claim 1 , CH(CH) claim 1 , CH(CH) claim 1 , C(CH)(CH) claim 1 , CH(OCH) or C(OCH).16. A compound according to claim 1 , wherein n represents 0.17. A compound according to claim 1 , wherein m represents 0.19. A fungicide composition comprising claim 1 , as an active ingredient claim 1 , an effective amount of a compound of formula (I) according to claim 1 , and an agriculturally ...

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Номер записи: 21
12-12-2013 дата публикации

PYRAZOLE CARBOXYLIC ACID AMIDES USEFUL FOR THE REDUCTION OF MYCOTOXIN CONTAMINATION IN PLANTS

Номер: US20130331261A1
Автор: Coqueron Pierre-Yves, Desbordes Philippe, Hoffmann Sebastian, Meissner Ruth
Принадлежит: Bayer Intellectual Property GmbH

The present invention relates to the novel use of pyrazole carboxylic acid amides, compositions comprising these compounds and their use in methods for the reduction of mycotoxin contamination in plants. 2. The method according to claim 1 , wherein Ris hydrogen.3. The method according to claim 1 , wherein Ris CF claim 1 , CFH or CFH claim 1 , optionally CFH or CF; Ris C-C-alkyl claim 1 , optionally methyl; and Ris hydrogen or halogen claim 1 , optionally hydrogen or chlorine or fluorine and/or optionally Ris CFH; Ris methyl and Ris hydrogen.4. The method according to claim 1 , wherein Ris hydrogen or C-C-alkyl claim 1 , which is unsubstituted or substituted by at least one substituent R.8. The method according to claim 1 , wherein said mycotoxins trichothecene mycotoxin.9. The method according to claim 1 , wherein said mycotoxin is deoxynivalenol.10. A compound as defined as being used in said method of according to claim 1 , wherein said compound is capable of reducing mycotoxin contamination in a plant and/or any plant material and/or plant propagation material.11. A plant and/or plant material and/or plant propagation material treated by the method according to . The present invention relates to the novel use of pyrazole carboxylic acid amides, compositions comprising these compounds and their use in methods for the reduction of mycotoxin contamination in plants.Numerous fungi are serious pests of economically important agricultural crops. Further, crop contamination by fungal toxins is a major problem for agriculture throughout the world.Mycotoxins, such as aflatoxins, ochratoxins, patulin, fumonisins, zearalenones, and trichothecenes, are toxic fungal metabolites, often found in agricultural products that are characterized by their ability to cause health problems for humans and vertebrates. They are produced for example by different and and species.Aflatoxins are toxins produced by species that grow on several crops, in particular on maize or corn before and ...

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Номер записи: 22
20-02-2014 дата публикации

FUNGICIDE HYDROXIMOYL-TETRAZOLE DERIVATIVES

Номер: US20140051575A1
Автор: BENTING Juergen, Coqueron Pierre-Yves, Desbordes Philippe, Dubost Christophe, Portz Daniela, Rebstock Anne-Sophie, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to hydroximoyl-tetrazole derivatives of formula (I), their process of preparation, their use as fungicide active agents, particularly in the form of fungicide compositions and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions. 2. A compound according to wherein X represents a hydrogen atom claim 1 , a chlorine atom claim 1 , fluorine atom claim 1 , a methyl group claim 1 , a tert-butyl group claim 1 , a methoxy group claim 1 , an ethoxy group claim 1 , a cyano group claim 1 , a methanesulfonyl group claim 1 , a nitro group claim 1 , a trifluoromethyl group or an aryl group.3. A compound according to wherein X represents a hydrogen atom.4. A compound according to wherein Y represents a methyl group or an ethyl group.5. A compound according to wherein R represents a hydrogen atom or a chlorine atom.6. A compound according to wherein Q represents a substituted or non-substituted (C-C-cycloalkyl)-(C-C-alkoxy)-C-C-alkyl group claim 1 , a substituted or non-substituted (C-C-cycloalkyl)-(C-C-alkoxy)-C-C-alkoxy group claim 1 , a substituted or non-substituted (C-C-cycloalkoxy)-C-C-alkoxy group claim 1 , a substituted or non-substituted heterocyclyl-(C-C-alkoxy)-C-C-alkyl group.7. A compound according to wherein Q represents a substituted or non-substituted (C-C-cycloalkyl)-methyloxymethyl group claim 1 , a substituted or non-substituted (C-C-cycloalkyl)-methyloxy-ethyloxy group claim 1 , a substituted or non-substituted (C-C-cycloalkoxy)-C-C-alkoxy group claim 1 , a substituted or non-substituted heterocyclyl-methyloxy-methyl group.8. A Composition for controlling phytopathogenic harmful fungi claim 1 , characterized by a content of at least one compound of the formula (I) according to claim 1 , in addition to at least one extender and/or one surfactant.9. A fungicide composition according to comprising at least one further active ingredient selected from the group of the insecticides ...

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Номер записи: 23
07-01-2016 дата публикации

FUNGICIDAL 3--OXADIAZOLONE DERIVATIVES

Номер: US20160000078A1
Автор: Coqueron Pierre-Yves, Dubost Christophe, LACHAISE Helene, Maechling Simon, Rebstock Anne-Sophie, Rinolfi Philippe, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention provides 4-substituted-3-{phenyl[(heterocyclylmethoxy)imino]methyl}-1,2,4-oxadiazol-5(4H)-one derivatives of formula (I) 2. A compound according to wherein Xrepresents a hydrogen atom claim 1 , substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl or a substituted or non-substituted C-C-alkenyl.3. A compound according to wherein Xrepresents a hydrogen atom claim 2 , a methyl group claim 2 , an ethyl group claim 2 , a n-propyl group claim 2 , an isopropyl group or a cyclopropyl group.4. A compound according to wherein Zrepresents a substituted or non-substituted carbaldehyde O—(C-C-alkyl)oxime claim 1 , a substituted or non-substituted (hydroxyimino)-C-C-alkyl group claim 1 , substituted or non-substituted C-C-alkenyl claim 1 , substituted or non-substituted C-C-alkynyl claim 1 , substituted or non-substituted (C-C-alkoxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (C-C-alkenyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (C-C-alkynyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (benzyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (N-hydroxy-C-C-alkanimidoyl)amino claim 1 , or substituted or non-substituted (N—C-C-alkoxy-C-C-alkanimidoyl)amino.5. A compound according to wherein Zrepresents substituted or non-substituted C-C-alkenyl claim 4 , substituted or non-substituted C-C-alkynyl claim 4 , substituted or non-substituted (C-C-alkoxyimino)-C-C-alkyl claim 4 , substituted or non-substituted (C-C-alkenyloxyimino)-C-C-alkyl claim 4 , substituted or non-substituted (C-C-alkynyloxyimino)-C-C-alkyl claim 4 , substituted or non-substituted (benzyloxyimino)-C-C-alkyl claim 4 , or substituted or non-substituted (N—C-C-alkoxy-C-C-alkanimidoyl)amino.6. A compound according to wherein Zrepresents substituted or non-substituted C-C-alkynyl claim 5 , or substituted or non-substituted (N—C-C-alkoxy-C-C-alkanimidoyl)amino.7. A compound according to wherein Z ...

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Номер записи: 24
07-01-2016 дата публикации

FUNGICIDAL 3--OXADIAZOLONE DERIVATIVES

Номер: US20160002217A1
Автор: Coqueron Pierre-Yves, Dubost Christophe, LACHAISE Helene, Maechling Simon, Rebstock Anne-Sophie, Rinolfi Philippe, Wachendorff-Neumann Ulrike
Принадлежит: Bayer CropScience AG

The present invention provides 3-{heterocyclyl[(heterocyclylmethoxy)imino]methyl}-oxadiazolinone derivatives of formula (I) 2. A compound according to wherein Xrepresents a hydrogen atom claim 1 , substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl or a substituted or non-substituted C-C-alkenyl.3. A compound according to wherein Xrepresents a hydrogen atom claim 2 , a methyl group claim 2 , an ethyl group claim 2 , a n-propyl group claim 2 , an isopropyl group or a cyclopropyl group.4. A compound according to wherein A is selected from the group consisting of Ato A.5. A compound according to wherein A is selected from the group consisting of A claim 1 , A claim 1 , A claim 1 , A claim 1 , Aand A.6. A compound according to wherein Zrepresents a hydrogen atom claim 1 , a halogen atom claim 1 , a nitro group claim 1 , an amino group claim 1 , an hydroxyamino group claim 1 , a substituted or non-substituted carbaldehyde O—(C-C-alkyl)oxime claim 1 , substituted or non-substituted C-C-alkoxyamino group claim 1 , a substituted or non-substituted (hydroxyimino)-C-C-alkyl group claim 1 , substituted or non-substituted C-C-alkenyl claim 1 , substituted or non-substituted C-C-alkynyl claim 1 , substituted or non-substituted (C-C-alkoxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (C-C-alkenyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (C-C-alkynyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (benzyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (N-hydroxy-C-C-alkanimidoyl)amino claim 1 , substituted or non-substituted (N—C-C-alkoxy-C-C-alkanimidoyl)amino claim 1 , substituted or non-substituted C-C-alkylamino claim 1 , substituted or non-substituted C-C-cycloalkylamino claim 1 , substituted or non-substituted C-C-cycloalkenylamino claim 1 , substituted or non-substituted C-C-fused bicycloalkylamino claim 1 , substituted or non-substituted C-C-fused bicycloalkenylamino claim ...

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Номер записи: 25
14-01-2016 дата публикации

FUNGICIDAL 3--OXADIAZOLONE DERIVATIVES

Номер: US20160007607A1
Автор: BRAUN Christoph Andreas, Coqueron Pierre-Yves, Dubost Christophe, LACHAISE Helene, Maechling Simon, Rebstock Anne-Sophie, Rinolfi Philippe, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention provides 4-substituted-3-{phenyl[(heterocyclylmethoxy)imino]methyl}-1,2,4-oxadiazol-5(4H)-one derivatives of formula (I) 2. A compound according to wherein Xrepresents a hydrogen atom claim 1 , substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl or a substituted or non-substituted C-C-alkenyl.3. A compound according to wherein Xrepresents a hydrogen atom claim 2 , a methyl group claim 2 , an ethyl group claim 2 , a n-propyl group claim 2 , an isopropyl group or a cyclopropyl group.4. A compound according to wherein A is selected from the group consisting of Ato A.5. A compound according to wherein A is selected from the group consisting of A claim 4 , A claim 4 , Aand A.6. A compound according to wherein A is selected from the group consisting of Aand A.7. A compound according to wherein Zrepresents a hydrogen atom claim 1 , a halogen atom claim 1 , a nitro group claim 1 , an amino group claim 1 , a carboxylic acid claim 1 , an hydroxyamino group claim 1 , a substituted or non-substituted carbaldehyde O—(C-C-alkyl)oxime claim 1 , substituted or non-substituted C-C-alkoxyamino group claim 1 , substituted or non-substituted C-C-alkoxycarbonyl group claim 1 , a substituted or non-substituted (hydroxyimino)-C-C-alkyl group claim 1 , substituted or non-substituted C-C-alkenyl claim 1 , substituted or non-substituted C-C-alkynyl claim 1 , substituted or non-substituted aryl-C-C-alkynyl claim 1 , substituted or non-substituted (C-C-alkoxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (C-C-alkenyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (C-C-alkynyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (benzyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (N-hydroxy-C-C-alkanimidoyl)amino claim 1 , substituted or non-substituted (N—C-C-alkoxy-C-C-alkanimidoyl)amino claim 1 , substituted or non-substituted C-C-alkylamino claim 1 , substituted or non- ...

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Номер записи: 26
14-01-2016 дата публикации

ZIRCONIUM-BASED AND BERYLLIUM FREE SOLID AMORPHOUS ALLOY

Номер: US20160010194A1
Автор: CAROZZANI Tommy, DUBACH Alban, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

The invention concerns a zirconium and/or hafnium based, beryllium free, solid, amorphous alloy, with the addition of silver and/or gold and/or platinum to increase its critical diameter. 1. A solid amorphous alloy , wherein the alloy contains no beryllium and consists of , in atomic percentage:a base composed of zirconium and/or hafnium, with the total zirconium and hafnium having a minimum value of 57% and a maximum value of 63%;at least one first additional metal, wherein the total value of said at least one first additional metal ranges from a minimum value of 0% to a maximum value of 0.5%, said at least a first additional metal being selected from a first group consisting of niobium and tantalum, the niobium value being less than or equal to 0.5%;at least one second additional metal, wherein the total value of said at least one second additional metal ranges from a minimum value of 1.2% to a maximum value of 4.5%, said at least one second additional metal being selected from a second group consisting of silver, gold and platinum;at least one third additional metal, wherein the total value of said at least one third additional metal ranges from a minimum value of 8.5% to a maximum value of 17.5%, said at least one third additional metal being selected from a third group consisting of nickel, cobalt, manganese and iron;aluminium ranging from a minimum value 9% to a maximum value 13%;copper and inevitable impurities constituting the complement to 100%, but less than or equal to 18% in atomic percentage of the alloy.2. Alley The alloy according to claim 1 , wherein said base composed of zirconium and/or hafnium claim 1 , has a total zirconium and hafnium content with a minimum value of 57% and a maximum value of 63%.3. The alloy according to claim 1 , wherein the total value of said at least one second additional metal in atomic percentage ranges from a minimum value of 1.2% to a maximum value of 4.0%.4. The alloy according to claim 3 , wherein the total value of ...

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Номер записи: 27
21-01-2016 дата публикации

FUNGICIDAL 3--HETEROCYCLE DERIVATIVES

Номер: US20160016944A1
Автор: Coqueron Pierre-Yves, Dubost Christophe, LACHAISE Helene, Maechling Simon, Rebstock Anne-Sophie, RINOLFI Philipe, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention provides 3-{phenyl[(heterocyclylmethoxy)imino]methyl}-heterocyclyl derivatives of formula (I) 2. A compound according to wherein Xrepresents a hydrogen atom claim 1 , substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl or a substituted or non-substituted C-C-alkenyl.3. A compound according to wherein Xrepresents a hydrogen atom claim 2 , a methyl group claim 2 , an ethyl group claim 2 , a n-propyl group claim 2 , an isopropyl group or a cyclopropyl group.4. A compound according to wherein Xand Xindependently represent O claim 1 , S claim 1 , C═O claim 1 , C═S claim 1 , or C═NR.5. A compound according to wherein Xand Xindependently represent an O or C═S.6. A compound according to wherein Xrepresents C═S when Xrepresents O or Xrepresents C═S when Xrepresents O.7. A compound according to wherein Xor/and Xrepresents independently C═NR or S(═O)(═NR) and R represents a cyano group or substituted or unsubstituted C-C-alkyl.8. A compound according to wherein A is selected in the list consisting of Ato A.9. A compound according to wherein A is selected in the list consisting of A claim 8 , A claim 8 , A claim 8 , A claim 8 , Aand A.10. A compound according to wherein Zrepresents a hydrogen atom claim 1 , a halogen atom claim 1 , a nitro group claim 1 , an amino group claim 1 , an hydroxyamino group claim 1 , a substituted or non-substituted carbaldehyde O—(C-C-alkyl)oxime claim 1 , substituted or non-substituted C-C-alkoxyamino group claim 1 , a substituted or non-substituted (hydroxyimino)-C-C-alkyl group claim 1 , substituted or non-substituted C-C-alkenyl claim 1 , substituted or non-substituted C-C-alkynyl claim 1 , substituted or non-substituted (C-C-alkoxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (C-C-alkenyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (C-C-alkynyloxyimino)-C-C-alkyl claim 1 , substituted or non-substituted (benzyloxyimino)-C-C-alkyl claim 1 , substituted ...

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Номер записи: 28
16-01-2020 дата публикации

NOVEL TRIAZOLE DERIVATIVES

Номер: US20200017467A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Genix Pierre, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, SUDAU Alexander
Принадлежит:

The present invention relates to novel triazole derivatives of formula (I), 2. Triazole derivative of formula (I) according to claim 1 , wherein{'sup': '1', 'sub': 3', '2', '3', '2, 'Rrepresents hydrogen, methyl, ethyl, propyl, isopropyl, butyl, cyclopropyl, CF, benzyl, allyl, CHC≡C—CHor CHC≡CH,'}and/or{'sup': '2', 'Rrepresents hydrogen'}and/or a salt or N-oxide thereof.5. Triazole derivative of formula (I) according to claim 1 , wherein{'sup': 4', '6', '4a', '4b, 'sub': 2', '3', '3', '3', '3, 'claim-text': {'sup': 4a', '4b, 'sub': 1', '4, 'wherein Rand Rrepresent independently from each other hydrogen or C-C-alkyl, optionally hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl or tert.-butyl, optionally hydrogen or methyl,'}, 'each Rrepresents independently from each other Br, Cl, F, CN, nitro, methyl, ethyl, n-propyl, isopropyl, CHF, CF, cyclopropyl, 1-fluorocyclopropyl, 1-chlorocyclopropyl, 1-methylcyclopropyl, methoxy, OCF, vinyl, allyl, propargyl, SCH, SCF, formyl, pentafluoro-λ-sulfanyl or —C(R)═N—OR,'}and/or a salt or N-oxide thereof.7. Triazole derivative of formula (I) according to claim 1 , wherein{'sub': '3', 'R represents CFor Cl,'}and/orn is 0and/or a salt or N-oxide thereof.1420-. (canceled) The present invention relates to novel triazole derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators.It is already known that particular phenoxy-phenyl-substituted triazole derivatives show fungicidal efficacy (e.g. EP-A 0 275 955; J. Agric. Food Chem. 2009, 57, 4854-4860; CN-A 101225074, DE-A 40 03 180; EP-A 0 113 640; EP-A 0 470 466; U.S. Pat. No. 4,949,720; EP-A 0 126 430, DE-A 38 01 233; WO-A 2013/007767; WO-A 2013/010862; WO-A 2013/010885; WO-A 2013/010894; WO-A 2013/024075; WO-A 2013/024076; WO-A 2013/024077; WO- ...

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Номер записи: 29
29-01-2015 дата публикации

FUNGICIDAL 3-[(1,3-THIAZOL-4-YLMETHOXYIMINO)(PHENYL)METHYL]-2-SUBSTITUTED-1,2,4-OXADIAZOL-5(2H)-ONE DERIVATIVES

Номер: US20150031730A1
Автор: BRAUN Christoph, Coqueron Pierre-Yves, Dubost Christophe, LACHAISE Helene, Maechling Simon, Rebstock Anne-Sophie, Rinolfi Philippe, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to 3-[(1,3-thiazol-4-ylmethoxyimino)(phenyl)methyl]-2-substituted-1,2,4-oxadiazol-5(2H)-one derivatives of formula (I), their process of preparation, their use as fungicide active agents, particularly in the form of fungicide compositions, and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions. 2. A compound according to wherein Xrepresents substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl or a substituted or non-substituted C-C-alkenyl.3. A compound according to wherein Xrepresents a methyl group claim 1 , an ethyl group claim 1 , a n-propyl group claim 1 , an isopropyl group or a cyclopropyl group.4. A compound according to wherein Zrepresents a hydrogen atom claim 1 , a halogen atom claim 1 , a nitro group claim 1 , an amino group claim 1 , an hydroxyamino group claim 1 , substituted or non-substituted C-C-alkoxyamino group claim 1 , substituted or non-substituted C-C-alkylamino claim 1 , substituted or non-substituted C-C-cycloalkylamino claim 1 , substituted or non-substituted C-C-cycloalkenylamino claim 1 , substituted or non-substituted C-C-fused bicycloalkylamino claim 1 , substituted or non-substituted C-C-fused bicycloalkenylamino claim 1 , substituted or non-substituted di-C-C-alkylamino claim 1 , substituted or non-substituted phenylamino claim 1 , substituted or non-substituted heterocyclylamino claim 1 , or a group of formula QC(═U)NR—.5. A compound according to wherein Zrepresents a hydrogen atom claim 1 , a halogen atom claim 1 , a nitro group claim 1 , an amino group claim 1 , substituted or non-substituted C-C-alkylamino claim 1 , substituted or non-substituted C-C-cycloalkylamino claim 1 , or a group of formula QC(═U)NR—.6. A compound according to wherein U represents an oxygen atom.7. A compound according to wherein Rrepresents a hydrogen atom claim 1 , a hydroxy group claim 1 , substituted or non-substituted C-C- ...

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Номер записи: 30
04-02-2016 дата публикации

NOVEL TRIAZOLINTHIONE DERIVATIVES

Номер: US20160031851A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Dahmen Peter, GEIST Julie, Genix Pierre, Hoffmann Sebastian, KENNEL Philippe, LACHAISE Helene, MILLER Ricarda, SUDAU Alexander, VIDAL Jacky, Vors Jean-Pierre, Wachendorff-Neumann Ulrike
Принадлежит: Bayer CropScience Aktiengesellschaft

The present invention relates to novel triazolinthione derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 2. Triazole derivative of formula (I) and/or a salt and/or N-oxide thereof according to claim 1 , wherein{'sup': '1', 'sub': 1', '8', '2', '8', '2', '8', '3', '7', '4', '8', '3', '7', '1', '8, 'Rrepresents substituted or non-substituted C-C-alkyl; substituted or non-substituted C-C-alkenyl; substituted or non-substituted C-C-alkynyl; substituted or non-substituted C-C-cycloalkyl; substituted or non-substituted C-C-cycloalkylalkyl; substituted or non-substituted C-C-cycloalkenyl; substituted or non-substituted arylalkyl; substituted or non-substituted arylalkenyl; substituted or non-substituted arylalkynyl, substituted or non-substituted phenoxyalkyl; substituted or non-substituted phenylcycloalkyl; substituted or non-substituted hetaryl; substituted hetarylalkyl; substituted or non-substituted heterocycloalkyl; substituted or non-substituted heterocycloalkyl-C-C-alkyl;'}{'sup': 2', '3a', '3b', '3c, 'sub': 1', '8', '2', '2', '2', '1', '8', '3', '7', '1', '8', '1', '8', '1', '8, 'Rrepresents H, C-C-alkyl, —Si(R)(R)(R), —P(O)(OH), —CH—O—P(O)(OH), substituted or non-substituted —C(O)—C-C-alkyl or substituted, non-substituted —C(O)—C-C-cycloalkyl, substituted or non-substituted —C(O)NH—C-C-alkyl; substituted or non-substituted —C(O)N-di-C-C-alkyl; substituted or non-substituted —C(O)O—C-C-alkyl;'}{'sup': 3a', '3b', '3c, 'sub': 1', '8, 'R, R, Rindependent from each other represent a substituted or non-substituted C-C-alkyl;'}andX represents a substituted or non-substituted unsaturated 5- or 6 membered heterocycle containing 1 or 2 nitrogen atom(s) as heteroatom(s) or a benzannulated derivative thereof, with the provisio that X ...

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Номер записи: 31
30-01-2020 дата публикации

NOVEL 5-SUBSTITUTED IMIDAZOLYLMETHYLDIOXOLANE DERIVATIVES

Номер: US20200029563A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Genix Pierre, GOERTZ Andreas, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, Wachendorff-Neumann Ulrike, WITTROCK Sven
Принадлежит:

The present invention relates to novel 5-substituted imidazolylmethyldioxolane derivatives, to processes for preparing these compounds, to compositions and mixtures comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 2. Imidazole derivative of formula (I) and/or a salt and/or N-oxide thereof according to claim 1 , wherein{'sub': 2', '3', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '3', '2', '3', '1', '4', '1', '4', '3', '2', '3, 'sup': 1', '1', '1', '1', '1', '1', '1, 'A represents a linear C- or C-alkylene bridge which may be substituted by 1, 2 or up to the maximum possible number of identical or different groups R, wherein each Ris independently selected from C-C-alkyl, C-C-haloalkyl, C-C-alkoxy, C-C-alkoxy-C-C-alkoxy and C-C-haloalkoxy, and optionally from methyl, ethyl, n-propyl, CF, methoxy, ethoxy and methoxymethoxy, or two substituents Rbound on adjacent carbon atoms, together with the carbon atoms to which they are bound, form a cyclopentyl or cyclohexyl ring; optionally represents a linear C- or C-alkylene bridge which may be substituted by 1 or 2 group(s) R, wherein each Ris independently from each other selected from C-C-alkyl and C-C-haloalkyl, optionally from methyl, ethyl, n-propyl and CF; optionally represents a linear C-alkylene bridge which may be substituted by 1 or 2 group(s) R, wherein each Ris independently from each other selected from methyl, ethyl, n-propyl and CF; optionally represents ethylene, 1,2-propylene, 1,2-butylene, 2,3-butylene or 1,2-pentylene.'}5. Imidazole derivative of formula (I) and/or a salt and/or N-oxide thereof according to claim 1 , wherein{'sup': '3', 'sub': 2', '4', '1', '4', '1', '4', '1', '4', '1', '4', '3', '7', '3', '7', '2', '5', '2', '5', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '8', '1', '8', '1', '8', '1', ...

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Номер записи: 32
30-01-2020 дата публикации

NOVEL 5-SUBSTITUTED IMIDAZOLYLMETHYLOXIRANE DERIVATIVES

Номер: US20200029564A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Genix Pierre, GOERTZ Andreas, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, Wachendorff-Neumann Ulrike, WITTROCK Sven
Принадлежит:

Novel 5-substituted imidazolylmethyloxirane derivatives The present invention relates to novel 5-substituted imidazolylmethyloxirane derivatives, to processes for preparing these compounds, to compositions and mixtures comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 4. Imidazole derivative of formula (I) according to claim 1 , wherein{'sup': '1a', 'sub': 1', '8', '1', '8', '1', '4', '1', '4', '3', '7, 'Rrepresents hydrogen, C-C-alkyl, C-C-haloalkyl, optionally halogen-, C-C-alkyl-, or C-C-haloalkyl-substituted C-C-cycloalkyl, optionally hydrogen,'}And/or a salt and/or N-oxide thereof.7. Imidazole derivative of formula (I) according to claim 1 , wherein{'sup': '3', 'sub': 2', '4', '1', '4', '1', '4', '1', '4', '1', '4', '3', '7', '3', '7', '2', '5', '2', '5', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '8', '1', '8', '1', '8', '1', '8, 'Rrepresents halogen, cyano, carboxaldehyde, hydroxycarbonyl, C-C-alkyl, C-C-haloalkyl, C-C-cyanoalkyl, C-C-alkyloxy, C-C-haloalkyloxy, C-C-cycloalkyl, C-C-halocycloalkyl, C-C-alkenyl, C-C-alkynyl, C-C-alkylsulfanyl, C-C-haloalkylsulfanyl, C-C-alkylcarbonyl, C-C-haloalkylcarbonyl, aminothiocarbonyl, C-C-alkoxycarbonyl, C-C-haloalkoxycarbonyl, benzyl, phenyl, furyl, pyrrolyl, thienyl, pyridyl, benzyloxy, or phenyloxy, wherein the benzyl, phenyl, 5-membered heteroaryl, δ-membered heteroaryl, benzyloxy or phenyloxy may be optionally substituted by one or more group(s) selected from halogen, C-C-alkyl, C-C-haloalkyl, C-C-alkyloxy, C-C-haloalkyloxy; optionally represents fluorine, chlorine, bromine, iodine, cyano, hydroxycarbonyl, carboxaldehyde, trifluoromethyl, cyanomethyl, methoxy, methylsulfanyl, cyclopropyl, ethinyl, methylcarbonyl (acetyl), carboxyl, aminothiocarbonyl, methoxycarbonyl, ethoxycarbonyl, phenyl, or 2-thienyl, more preferred ...

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Номер записи: 33
04-02-2021 дата публикации

USE OF PYDIFLUMETOFEN FOR THE REDUCTION OF MYCOTOXIN CONTAMINATION IN PLANTS

Номер: US20210030002A1
Автор: Coqueron Pierre-Yves, Dahmen Peter, Wetcholowsky Ingo
Принадлежит:

The present invention relates to the novel use of the pyrazole carboxylic acid amide derivative Pydiflumetofen, compositions comprising this compound and its use in methods for the reduction of mycotoxin contamination in plants. Pydiflumetofen is also useful in increasing yield, in particular in cereals eg. wheat. 2. The method according to wherein the compound of Formula I and prothioconazole are applied in a liquid composition.4. The method according to wherein the compound of formula (I) and the prothioconazole are applied in a liquid composition.5. A plant which has been treated by the method according to .6. The method according to claim 1 , wherein the plant is wheat.7. The method according to claim 1 , wherein the plant has at least 80% less deoxynivalenol contamination than a plant which has not been treated.8. The method of claim 1 , wherein the compound of formula (I) and the prothioconazole are applied during flowering. This application is a Continuation of U.S. patent application Ser. No. 15/766,726, filed 6 Apr. 2018, which is a National Stage entry of International Application No. PCT/EP2016/074109, filed 7 Oct. 2016, which claims priority to European Patent Application No 15189239.5, filed 9 Oct. 2015. Each of these applications is incorporated by reference in its entiretyThe present invention relates to the novel use of the pyrazole carboxylic acid amide derivative Pydiflumetofen, compositions comprising this compound and its use in methods for the reduction of mycotoxin contamination in plants. Pydiflumetofen is also useful in increasing yield, in particular in cereals eg. wheat.Numerous fungi are serious pests of economically important agricultural crops. Further, crop contamination by fungal toxins is a major problem for agriculture throughout the world.Mycotoxins, such as aflatoxins, ochratoxins, patulin, fumonisins, zearalenones, and trichothecenes, are toxic fungal metabolites, often found in agricultural products that are characterized by ...

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Номер записи: 34
30-01-2020 дата публикации

NOVEL 5-SUBSTITUTED IMIDAZOLYLMETHYL DERIVATIVES

Номер: US20200031778A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Dahmen Peter, Genix Pierre, GOERTZ Andreas, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, NICOLAS Lionel, Wachendorff-Neumann Ulrike, WITTROCK Sven
Принадлежит:

The present invention relates to novel 5-substituted imidazolylmethyl derivatives, to processes for preparing these compounds, to compositions and mixtures comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 4. Imidazole derivative of formula (I) according to claim 1 , wherein{'sup': 2', '2a', '2a, 'sub': 1', '3', '1', '3', '1', '3', '1', '3', '3', '8', '3', '8', '1', '8', '1', '8', '1', '8, 'Rrepresents —OR, wherein Rrepresents H, C-C-alkyl, C-C-cyanoalkyl, C-C-alkoxy-C-C-alkyl, C-C-alkenyl, C-C-alkynyl, —C(O)N-di-C-C-alkyl, or halogen- or C-C-alkoxy-substituted or non-substituted —C(O)—C-C-alkyl;'}And/or a salt and/or N-oxide thereof,5. Imidazole derivative of formula (I) according to claim 1 , wherein{'sup': '3', 'sub': 2', '4', '1', '4', '1', '4', '1-4', '1', '4', '3', '7', '3', '7', '2', '2', '1-4', '1-4', '1', '4', '1-4', '1-4', '1-4', '1', '8', '1', '8', '1', '8', '1', '8, 'Rrepresents halogen, cyano, carboxaldehyde, hydroxycarbonyl, C-C-alkyl, C-C-haloalkyl, C-C-cyanoalkyl, C-alkyloxy, C-C-haloalkyloxy, C-C-cycloalkyl, C-C-halocycloalkyl, C-05-alkenyl, C-05-alkynyl, C-alkylsulfanyl, C-haloalkylsulfanyl, C-C-alkylcarbonyl, C-haloalkylcarbonyl, carbamoyl, aminothiocarbonyl, C-alkoxycarbonyl, C-haloalkoxycarbonyl, benzyl, phenyl, furyl, pyrrolyl, thienyl, pyridyl, benzyloxy, or phenyloxy, wherein the benzyl, phenyl, 5-membered heteroaryl, 6-membered heteroaryl, benzyloxy or phenyloxy may be optionally substituted by one or more group(s) selected from halogen, C-C-alkyl, C-C-haloalkyl, C-C-alkyloxy, C-C-haloalkyloxy; optionally represents fluorine, chlorine, bromine, iodine, cyano, hydroxycarbonyl, carboxaldehyde, trifluoromethyl, cyanomethyl, methoxy, methylsulfanyl, cyclopropyl, ethinyl, methylcarbonyl (acetyl), carboxyl, aminothiocarbonyl, methoxycarbonyl, ethoxycarbonyl, phenyl, or 2-thienyl, ...

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Номер записи: 35
11-02-2016 дата публикации

PYRAZOLE INDANYL CARBOXAMIDES

Номер: US20160039768A1
Автор: Bernier David, BRUNET Stephane, Carles Lionel, Coqueron Pierre-Yves, Dahmen Peter, Dubost Christophe, ES-SAYED Mazen, LACHAISE Helene, Maechling Simon, Vors Jean-Pierre, Wachendorff-Neumann Ulrike, WASNAIRE Pierre
Принадлежит:

The present invention relates to novel 1-methyl-pyrazole(thio)indanyl carboxamides, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials. 5. A method for controlling phytopathogenic harmful fungi claim 1 , comprising applying a compound of the formula (I) according to to the phytopathogenic harmful fungi and/or a habitat thereof.6. A composition for controlling phytopathogenic harmful fungi claim 1 , comprising a content of at least one compound of formula (I) according to claim 1 , in addition to one or more extenders and/or surfactants.7. A compound of formula (I) according to capable of being used for control of phytopathogenic harmful fungi.8. A process for producing compositions for controlling phytopathogenic harmful fungi claim 1 , comprising mixing a compound of formula (I) according to with one or more extenders and/or surfactants.9. A method according to claim 5 , comprising treatment of one or more transgenic plants.10. A method according to claim 5 , comprising treatment of seed or of seed of one or more transgenic plants.11. Seed treated with a compound of formula (I) according to .12. A compound according to claim 1 , wherein T is oxygen.13. A compound according to claim 1 , wherein n is zero.14. A compound according to claim 1 , wherein X2 is hydrogen.15. A compound according to claim 1 , wherein X2 is not hydrogen.16. A compound according to claim 1 , wherein T is sulfur.17. A compound according to claim 1 , wherein Q is hydrogen.18. A compound according to claim 1 , wherein Rand Rform together with the carbon to which they are attached a C-cycloalkyl which is optionally substituted. This application is a divisional application of U.S. application Ser. No. 14/399,541, filed Nov. 7, 2014, which is a §371 National Stage Application of PCT/EP2013/059415, filed ...

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Номер записи: 36
09-02-2017 дата публикации

NICKEL-FREE ZIRCONIUM AND/OR HAFNIUM-BASED BULK AMORPHOUS ALLOY

Номер: US20170038733A1
Автор: CAROZZANI Tommy, DUBACH Alban, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

Nickel-free bulk amorphous alloy, formed, in atomic percent, of: 1. A bulk amorphous alloy , wherein the alloy that contains no nickel and consists of , in atomic percent values:a base formed of zirconium and/or hafnium, the content of which forms the balance, with a total zirconium and hafnium value greater than or equal to 52.0, and less than or equal to 62.0;copper: greater than or equal to 16.0, and less than or equal to 28.0;iron: greater than or equal to 0.5, and less than or equal to 10.0;aluminium: greater than or equal to 7.0, and less than or equal to 13.0;at least a first additional metal and a second additional metal called X taken from the group consisting of Ti, V, Nb, Y, Cr, Mo, Co, Sn, Zn, P, Pd, Ag, Au, Pt, Ta, Ru, Rh, Ir, Os, and Hf when said base contains none, and Zr when said base contains none, with the cumulative atomic percentage of said at least two additional metals being greater than 6.0 and less than or equal to 10.0.2. The bulk amorphous alloy according to claim 1 , wherein said first additional metal and said second additional metal are selected from the group consisting of Ti claim 1 , Nb claim 1 , Pd claim 1 , Ag claim 1 , Au claim 1 , Pt claim 1 , Ta claim 1 , Ru claim 1 , Rh claim 1 , Ir claim 1 , Os claim 1 , Hf when said base contains none claim 1 , and Zr when said base contains none claim 1 , with the cumulative atomic percentage of said at least two additional metals being greater than 6.0 and less than or equal to 10.0.3. The bulk amorphous alloy according to claim 2 , wherein said first additional metal and said second additional metal are taken from the group consisting of Ti claim 2 , Nb claim 2 , Pd claim 2 , Ag claim 2 , Au claim 2 , Pt claim 2 , Ta claim 2 , Ru claim 2 , Rh claim 2 , Ir claim 2 , and Os claim 2 , with the cumulative atomic percentage of said at least two additional metals being greater than 6.0 and less than or equal to 10.0.4. The bulk amorphous alloy according to claim 1 , wherein said alloy further ...

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Номер записи: 37
06-02-2020 дата публикации

NOVEL 5-SUBSTITUTED IMIDAZOLYLMETHYL DERIVATIVES

Номер: US20200039973A1
Автор: BERNIE David, BRUNET Stephane, Coqueron Pierre-Yves, Genix Pierre, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, Wachendorff-Neumann Ulrike, WITTROCK Sven
Принадлежит:

The present invention relates to novel 5-substituted imidazolylmethyl derivatives, to processes for preparing these compounds, to compositions and mixtures comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 11. Composition according to comprising at least one further active ingredient selected from the group of insecticides claim 10 , attractants claim 10 , sterilants claim 10 , bactericides claim 10 , acaricides claim 10 , nematicides claim 10 , fungicides claim 10 , growth regulators claim 10 , herbicides claim 10 , fertilizers claim 10 , safeners and semiochemicals. The present invention relates to novel 5-substituted imidazolylmethyl derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators.It is already known that imidazole derivatives, which may be substituted at the imidazole ring, and salts thereof can be used in crop protection as fungicides, safeners and/or plant growth regulators (cf. e.g. WO-A 2013/076228, U.S. Pat. No. 4,085,209, WO-A 2014/118170, EP-A 2 746 259, U.S. Pat. No. 4,118,461, U.S. Pat. No. 4,115,578, DE-A 2604047, DE-A 2750031, Manabe, Akio; Kirino, Osamu; Funaki, Yuji; Hisada, Yoshio; Takano, Hirotaka; Tanaka, Shizuya, Agricultural and Biological Chemistry (1986), 50(12), 3215-17, JP-A 60069067, EP-A 0 130 366, NL-A 8201572, DE-A 1940388, DE-A 2935452, and DE-A 2732750).Since the ecological and economic demands made on modern active ingredients, for example fungicides, are increasing constantly, for example with respect to activity spectrum, toxicity, selectivity, application rate, formation of residues and favourable manufacture, and there can ...

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Номер записи: 38
25-02-2016 дата публикации

NOVEL TRIAZOLE DERIVATIVES

Номер: US20160050928A1
Автор: Bernier David, BRUNET Stephanie, Coqueron Pierre-Yves, Dahmen Peter, GEIST Julie, Genix Pierre, Hoffmann Sebastian, KENNEL Philippe, LACHAISE Helene, MILLER Ricarda, SUDAU Alexander, VIDAL Jacky, Vors Jean-Pierre, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to novel triazole derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 2. Triazole derivative of formula (I) and/or salt and/or N-oxide according to claim 1 , wherein{'sup': '1', 'sub': 1', '8', '4', '8', '2', '8', '2', '8, 'Rrepresents substituted or non-substituted C-C-alkyl; substituted or non-substituted C-C-cycloalkylalkyl; substituted or non-substituted C-C-alkenyl; substituted or non-substituted C-C-alkynyl;'}{'sup': 2', '3a', '3b', '3c, 'sub': 1', '8', '2', '2', '2', '1', '8', '3', '7', '1', '8', '1', '8', '1', '8, 'Rrepresents H, C-C-alkyl, —Si(R)(R)(R)), —P(O)(OH), —CH—O—P(O)(OH), substituted or non-substituted —C(O)—C-C-alkyl; substituted or non-substituted —C(O)—C-C-cycloalkyl, substituted or non-substituted —C(O)NH—C-C-alkyl; substituted or non-substituted —C(O)N-di-C-C-alkyl; substituted or non-substituted —C(O)O—C-C-alkyl;'}{'sup': 3a', '3b', '3c, 'sub': 1', '8, 'R, R, Rindependent from each other represent a substituted or non-substituted C-C-alkyl;'}andX represents a substituted or non-substituted unsaturated 6 membered heterocycle containing 1 or 2 nitrogen atom(s) as heteroatom(s) or a benzannulated derivative thereof, with the provisio that X does not represent 2-pyridinyl.3. Triazole derivative of formula (I) and/or salt and/or N-oxide according to claim 1 , wherein{'sup': '1', 'sub': 1', '8, 'Rrepresents substituted or non-substituted C-C-alkyl;'}{'sup': '2', 'sub': 1', '8', '1', '8, 'Rrepresents H, C-C-alkyl, substituted or non-substituted —C(O)—C-C-alkyl;'}andX represents a substituted or non-substituted 3-pyridinyl, 4-pyridinyl, 4-pyrimidinyl, 5-pyrimidinyl, pyrazin-2-yl, pyridazin-3-yl, pyridazin-4-yl, quinoline-2-yl or quinoline-3-yl.4. Method for controlling one or more ...

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Номер записи: 39
13-02-2020 дата публикации

NOVEL TRIAZOLE DERIVATIVES

Номер: US20200045967A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Genix Pierre, KENNEL Philippe, MILLER Ricarda, NAUD Sebastien
Принадлежит:

The present invention relates to novel triazole derivatives of formula 2. The triazole derivative of formula (I) according to claim 1 , wherein{'sup': '1', 'sub': 3', '2', '3', '2, 'Rrepresents hydrogen, methyl, ethyl, propyl, isopropyl, butyl, cyclopropyl, CF, benzyl, allyl, CHC≡C—CHor CHC≡CH,'}and/or{'sup': '2', 'Rrepresents hydrogen'}and/or a salt or N-oxide thereof.3. The triazole derivative of formula (I) according to claim 1 , wherein{'sup': 4', '4a', '4b, 'sub': 3', '2', '3', '2', '2', '3', '2', '2, 'claim-text': {'sup': 4a', '4b, 'sub': 1', '4, 'wherein Rand Rrepresent independently from each other hydrogen or C-C-alkyl, optionally hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl or tert.-butyl, optionally hydrogen or methyl,'}, 'each Rrepresents independently from each other cyclopropyl, 1-fluorocyclopropyl, 1-chlorocyclopropyl, 1-methylcyclopropyl, vinyl, allyl, ethynyl, prop-2-ynyl, SCH, SCHCH, SCHF, SCHF, SCF, methylsulfonyl, phenylsulfonyl, methyl-SONH—, phenyl-SONH—, formyl, dioxolanyl, dioxanyl, or —C(R)═N—OR,'}and/orm is 1and/or a salt or N-oxide thereof.5. The triazole derivative of formula (I) according to claim 1 , wherein{'sub': '3', 'R represents CFor Cl,'}and/orn is 0and/or a salt or N-oxide thereof.7. The triazole derivative of formula (I) according to claim 1 , wherein Ris located in the 4-position of the phenyl moiety of formula (I) claim 1 , and/or a salt or N-oxide thereof.12. A product comprising at least one compound according to and/or a composition thereof for control of one or more harmful microorganisms claim 1 , optionally phytopathogenic harmful fungi claim 1 , in crop protection and/or in protection of one or more materials.13. (canceled)14. (canceled)15. (canceled)16. (canceled)17. (canceled)18. (canceled)19. (canceled)20. (canceled) The present invention relates to novel triazole derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as ...

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Номер записи: 40
13-02-2020 дата публикации

NOVEL 5-SUBSTITUTED IMIDAZOLYLMETHYL DERIVATIVES

Номер: US20200045972A1
Автор: Bernier David, Coqueron Pierre-Yves, Genix Pierre, MILLER Ricarda, NAUD Sebastien, WITTROCK Sven
Принадлежит:

The present invention relates to novel 5-substituted imidazolylmethyl derivatives, to processes for preparing these compounds, to compositions and mixtures comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 4. Imidazole derivative of formula (I) according to claim 1 , wherein{'sup': 2', '2a', '2a, 'sub': 1', '3', '1', '3', '1', '3', '1', '3', '3', '8', '3', '8', '1', '8', '1', '8', '1', '8, 'Rrepresents —OR, wherein Rrepresents H, C-C-alkyl, C-C-cyanoalkyl, C-C-alkoxy-C-C-alkyl, C-C-alkenyl, C-C-alkynyl, —C(O)N-di-C-C-alkyl, or halogen- or C-C-alkoxy-substituted or non-substituted C(O)—C-C-alkyl;'}and/or a salt and/or N-oxide thereof.5. Imidazole derivative of formula (I) according to claim 1 , wherein{'sup': '3', 'sub': 2', '4', '1', '4', '1', '4', '1', '4', '1', '4', '3', '7', '3', '7', '2', '5', '2', '5', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '8', '1', '8', '1', '8', '1', '8, 'Rrepresents halogen, cyano, carboxaldehyde, hydroxycarbonyl, C-C-alkyl, C-C-haloalkyl, C-C-cyanoalkyl, C-C-alkyloxy, C-C-haloalkyloxy, C-C-cycloalkyl, C-C-halocycloalkyl, C-C-alkenyl, C-C-alkynyl, C-C-alkylsulfanyl, C-C-haloalkylsulfanyl, C-C-alkylcarbonyl, C-C-haloalkylcarbonyl, carbamoyl, aminothiocarbonyl, C-C-alkoxycarbonyl, C-C-haloalkoxycarbonyl, phenyl, furyl, pyrrolyl, thienyl, pyridyl, benzyloxy, or phenyloxy, wherein the phenyl, 5-membered heteroaryl, 6-membered heteroaryl, benzyloxy or phenyloxy may be optionally substituted by one or more group(s) selected from halogen, C-C-alkyl, C-C-haloalkyl, C-C-alkyloxy, C-C-haloalkyloxy; optionally represents fluorine, chlorine, bromine, iodine, cyano, hydroxycarbonyl, carboxaldehyde, trifluoromethyl, cyanomethyl, methoxy, methylsulfanyl, cyclopropyl, ethynyl, methylcarbonyl (acetyl), carboxyl, aminothiocarbonyl, methoxycarbonyl, ethoxycarbonyl, ...

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Номер записи: 41
13-02-2020 дата публикации

Subperiosteal jaw implant

Номер: US20200046470A1
Автор: Maurice Yves Mommaerts
Принадлежит: CADSKILLS BVBA

Disclosed is an assembly of: a jaw implant for oral subperiosteal placement over the alveolar ridge of a patient's maxilla or mandible; dentures; and supports for the dentures on the jaw implant, spaced apart therefrom. The dentures selections from right premolars and right molars and other from incisors, canine, premolars and molars left of the median line, and/or selections from left premolars and left molars and selections from incisors, canine, premolars and molars right of the median line. The implast is divided into segments or bodies configured for respective placement in different areas of the alveolar ridge, spaced apart from one another in arc direction of the alveolar ridge. The dentures include a bridge part that is bending-rigid under the intended loads that occur and has an arc length that suffices to connect the segments to each other via the supports.

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Номер записи: 42
01-03-2018 дата публикации

NOVEL TRIAZOLE DERIVATIVES

Номер: US20180057467A1
Автор: BENTING, Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Dahmen Peter, Genix Pierre, II JUERGEN, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, PERIS Gorka, VORS JEAN-PIERE, Wachendorff-Neumann Ulrike, WITTROCK Sven
Принадлежит:

The present invention relates to novel triazole derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 2. Triazole derivative of the formula (I) according to claim 1 , whereinX represents fluorine or chlorine;{'sup': '1', 'sub': 1', '8', '1', '8', '1', '8, 'Rrepresents H, C-C-alkyl, halogen- or C-C-alkoxy-substituted or non-substituted —C(O)—C-C-alkyl;'}{'sup': '1', 'sub': 1', '8', '1', '8', '1', '8', '3', '7', '2', '8', '2', '8', '2', '8', '3', '8', '3', '8', '1', '8', '1', '8', '2', '8', '2', '8', '3', '7', '1', '8', '1', '8', '1', '8', '3', '7', '2', '8', '2', '8', '2', '8', '3', '8', '3', '8', '1', '8', '1', '8, 'Xrepresents halogen; C-C-alkyl; C-C-haloalkyl; C-C-halogenalkoxy; C-C-cycloalkyl; C-C-alkenyl; C-C-alkynyl; C-C-alkenyloxy; C-C-alkynyloxy; C-C-halogenoalkynyloxy; C-C-alkoxy; C-C-haloalkylsulfanyl; phenyl; 5-membered heteroaryl; 6-membered heteroaryl; benzyloxy; phenyloxy; benzylsulfanyl; benzylamino; phenylsulfanyl; or phenylamino; wherein the C-C-alkenyl, C-C-alkynyl, C-C-cycloalkyl, benzyl, phenyl, 5-membered heteroaryl, 6-membered heteroaryl, benzyloxy or phenyloxy may be optionally substituted by one or more group(s) selected from halogen; C-C-alkyl; C-C-haloalkyl; C-C-halogenalkoxy; C-C-cycloalkyl; C-C-alkenyl; C-C-alkynyl; C-C-alkenyloxy; C-C-alkynyloxy; C-C-halogenoalkynyloxy; C-C-alkoxy; C-C-haloalkylsulfanyl;'}{'sup': '2', 'sub': 1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '2', '4, 'Xrepresents fluorine, chlorine, bromine, iodine, C-C-alkyl, C-C-haloalkyl, C-C-alkoxy, C-C-haloalkoxy, C-C-haloalkylthio or C-C-alkynyl;'}{'sup': '3', 'sub': 1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '2', '4, 'Xrepresents fluorine, chlorine, bromine, iodine, C-C-alkyl, C-C-haloalkyl, C-C-alkoxy, C-C-haloalkoxy, C-C- ...

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Номер записи: 43
02-03-2017 дата публикации

NITROGEN-CONTAINING HETEROCYCLIC COMPOUNDS FOR PLANT DISEASE CONTROL

Номер: US20170057951A1
Автор: BRUNET Stephane, Coqueron Pierre-Yves, DITTGEN JAN, ES-SAYED Mazen, Feucht Dieter, FRENZEL Thomas, GATZWEILER ELMAR, Grosjean-Cournoyer Marie-Claire, HAAF Klaus Bernhard, HÄEUSER-HAHN ISOLDE, Heinemann Ines, HILLS Martin, KEHNE Heinz, LACHAISE Helene, Rinolfi Philippe, ROSINGER CHRISTOPHER HUGH, SCHMIDT Jan Peter, SCHMITT Monika H., TUCH Arounarith, VIDAL Jacky, Willms Lothar
Принадлежит:

The present invention relates to novel isoxazoline carboxamide derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials. This application is a divisional application of 14/430,919 (filed Mar. 25, 2015), which is a §371 National Stage Application of PCT/EP2013/069893 (filed Sep. 25, 2013), which claims priority to EP 12186485.4 (filed Sep. 28, 2012), the contents of each of which are incorporated herein by reference in their entirety.Field of the InventionThe present invention relates to novel isoxazoline carboxamide derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials.Description of Related ArtIt is already known that certain phenyl-substituted isoxazolecarboxamides have fungicidal properties (M. Gucma, W. M. Golebiewski, Monatsh. Chemie, 2010, 141, 461-469; M. Gucma, W. M. Golebiewski, A. Michalczyk, Pestycydy, 2011, 1-4, 21).Since the ecological and economic demands made on modern active ingredients, for example fungicides, are increasing constantly, for example with respect to activity spectrum, toxicity, selectivity, application rate, formation of residues and favourable manufacture, and there can also be problems, for example, with resistances, there is a constant need to develop novel fungicidal compositions which have advantages over the known compositions at least in some areas.The present invention now provides novel quinoline-isoxazoline derivatives of formula (I)in whichThe salts or N-oxides of the quinoline-isoxazoline derivatives of formula (I) also have fungicidal properties.The formula (I) provides a general definition of the quinoline-isoxazoline ...

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Номер записи: 44
10-03-2016 дата публикации

NOVEL TRIAZOLE DERIVATIVES

Номер: US20160068516A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Dahmen Peter, GEIST Julie, Genix Pierre, Hoffmann Sebastian, KENNEL Philippe, LACHAISE Helene, MILLER Ricarda, SUDAU Alexander, VIDAL Jacky, Vors Jean-Pierre, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to novel triazole derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 2. Triazole derivative of formula (I) and/or salt and/or N-oxide according to claim 1 , wherein{'sup': '1', 'sub': 1', '8', '2', '8', '2', '8', '3', '7', '1', '4', '3', '7', '1', '4', '3', '7', '1', '4', '3', '7', '3', '7', '1', '8, 'Rrepresents C-C-haloalkyl; C-C-halooalkenyl; C-C-haloalkynyl; C-C-halocycloalkyl-C-C-alkyl; C-C-halocycloalkyl-C-C-haloalkyl; C-C-cycloalkyl-C-C-haloalkyl; substituted or non-substituted C-C-cycloalkyl; substituted or non-substituted C-C-cycloalkenyl; substituted or non-substituted arylalkyl; substituted or non-substituted arylalkenyl; substituted or non-substituted arylalkynyl; substituted or non-substituted phenoxyalkyl; substituted or non-substituted phenylcycloalkyl; substituted or non-substituted hetaryl; substituted hetarylalkyl; substituted or non-substituted heterocycloalkyl; substituted or non-substituted heterocycloalkyl-C-C-alkyl;'}{'sup': 2', '3a', '3b', '3c, 'sub': 1', '8', '2', '2', '2', '1', '8', '3', '7', '1', '8', '1', '8', '1', '8, 'Rrepresents H, C-C-alkyl, —Si(R)(R)(R), —P(O)(OH), —CH—O—P(O)(OH), substituted or non-substituted —C(O)—C-C-alkyl or substituted, non-substituted —C(O)—C-C-cycloalkyl, substituted or non-substituted —C(O)NH—C-C-alkyl; substituted or non-substituted —C(O)N-di-C-C-alkyl; substituted or non-substituted —C(O)O—C-C-alkyl;'}{'sup': 3a', '3b', '3c, 'sub': 1', '8, 'R, R, Rindependent from each other represent a substituted or non-substituted C-C-alkyl;'}andX represents a substituted or non-substituted unsaturated 6 membered heterocycle containing 1 or 2 nitrogen atom(s) as heteroatom(s) or a benzannulated derivative thereof, with the provisio that X does not ...

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Номер записи: 45
29-05-2014 дата публикации

Baby food products comprising hydrolysed whole grain

Номер: US20140147551A1
Автор: Anne-Sophie Wavreille, Christelle Schaffer-Lequart, Olivier Yves Roger
Принадлежит: Nestec SA

The present invention relates to a baby food product comprising at least one food ingredient selected from the group consisting of vegetables, fruits, meat, fish, egg, legumes, aromatic herbs, nuts and any combination thereof, a hydrolyzed whole grain composition, an alpha-amylase or fragment thereof, which alpha-amylase or fragment thereof shows no hydrolytic activity towards dietary fibers when in the active state, and wherein the baby food product has a viscosity in the range 301-1000 mPa·s.

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Номер записи: 46
17-03-2022 дата публикации

Reconfigurable optical networks

Номер: US20220086540A1
Автор: David James Mather, Erik J. Gronvall, John Charles Chamberlain, Joseph Christopher Coffey, Olivier Hubert Daniel Yves ROUSSEAUX, Peter MERLO
Принадлежит: CommScope Technologies LLC

Switching technology may be incorporated into various systems, components, and/or architectures in a fiber optic network to promote network reconfigurability and design flexibility. A signal access unit comprises an input, an output, an access port, a switch arrangement including a switch, and a controller. The switch optically couples the input to the output and not to the access port when in a first configuration, and optically couples the access port to at least one of the input and the output without optically coupling the input and the output together when in a second configuration. The controller is configured to receive an indication of a selected wavelength and to operate the switch arrangement to change the switch between the first and second configurations based on the indication of the selected wavelength.

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Номер записи: 47
17-03-2016 дата публикации

N-(2-FLUORO-2-PHENETHYL)CARBOXAMIDES AS NEMATICIDES AND ENDOPARASITICIDES

Номер: US20160075637A1
Автор: Coqueron Pierre-Yves, Decor Anne, Goergens Ulrich, Greul Joerg, Heilmann Eike Kevin, ILG Kerstin, LOESEL PETER, Luemmen Peter, MALSAM Olga, Portz Daniela, Schwarz Hans-Georg, WELZ Claudia
Принадлежит:

The present invention relates to N-(2-halogen-2-phenethyl)carboxamides, a process for producing such compounds, their use for the control of nematodes in agricultures and their use as anthelmintics against endoparasites in animals or humans, compositions containing such compounds and methods for the control of nematodes and helminths. 4. Compound of as defined in for use as a medicament with the proviso that the following compounds are disclaimed:3-chloro-N-[2-(4-chlorophenyl)-2,2-difluoroethyl]thiophene-2-carboxamide, 3-bromo-N-[2-(4-chlorophenyl)-2,2-difluoroethyl]thiophene-2-carboxamide, N-[2-(4-chlorophenyl)-2,2-difluoroethyl]-2-(trifluoromethyl)nicotin-amide, N-[2-(2,4-dichlorophenyl)-2,2-difluoroethyl]-2-(trifluoromethyl)nicotin-amide, 2-chloro-N-[2-(4-chlorophenyl)-2,2-difluoroethyl]-4-(trifluoromethyl)nicotinamide, 2-chloro-N-[2-(2,4-dichlorophenyl)-2,2-difluoroethyl]-4-(trifluoromethyl)nicotinamide, 6-chloro-N-[2-(4-chloro-phenyl)-2,2-difluoroethyl]-4-(trifluoromethyl)nicotinamide and 6-chloro-N-[2-(2,4-dichloro phenyl)-2,2-difluoroethyl]-4-(trifluoromethyl)nicotinamide.5. Compound of according to capable for use as a medicament with the proviso that the following compounds are disclaimed:3-chloro-N-[2-(4-chlorophenyl)-2,2-difluoroethyl]thiophene-2-carboxamide, 3-bromo-N-[2-(4-chlorophenyl)-2,2-difluoroethyl]thiophene-2-carboxamide, N-[2-(4-chlorophenyl)-2,2-difluoroethyl]-2-(trifluoromethyl)nicotin-amide, N-[2-(2,4-dichlorophenyl)-2,2-difluoroethyl]-2-(trifluoromethyl)nicotin-amide, 2-chloro-N-[2-(4-chlorophenyl)-2,2-difluoroethyl]-4-(trifluoromethyl)nicotinamide, 2-chloro-N-[2-(2,4-dichlorophenyl)-2,2-difluoroethyl]-4-(trifluoromethyl)nicotinamide, 6-chloro-N-[2-(4-chloro-phenyl)-2,2-difluoroethyl]-4-(trifluoromethyl)nicotinamide and 6-chloro-N-[2-(2,4-dichloro phenyl)-2,2-difluoroethyl]-4-(trifluoromethyl)nicotinamide.6. Compound of as defined in capable for use in treatment of helminths in animals and humans.7. Compound of as defined in capable for use ...

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Номер записи: 48
17-03-2016 дата публикации

NEMATICIDAL N-(PHENYLCYCLOALKYL)CARBOXAMIDES AND N-(PHENYLCYCLOALKYL)THIOCARBOXAMIDES

Номер: US20160075653A1
Автор: CHRISTIAN Isabelle, Coqueron Pierre-Yves, Decor Anne, Desbordes Philippe, ELBE Hans-Ludwig, Frackenpohl Jens, Gary Stephanie, GESING Ernst Rudolf, Goergens Ulrich, Greul Joerg, Heilmann Eike Kevin, ILG Kerstin, LOESEL PETER, Luemmen Peter, MALSAM Olga, MARTELLETTI Arianna, Portz Daniela, Schwarz Hans-Georg, WELZ Claudia, WIESE Welf Burkhard
Принадлежит:

The present invention relates to the use of N-(Phenylcycloalkyl)carboxamides and N-(Phenylcycloalkyl)thiocarboxamides for the control of nematodes in agriculture and as anthelmintic agents against endoparasites in animals and humans, compositions containing such compounds and methods for the control of nematodes and helminths and furthermore to novel N-(Phenylcycloalkyl)carboxamides and N-(Phenylcycloalkyl)thiocarboxamides, processes and intermediate compounds for their preparation, their use as nematicides, compositions containing such compounds and methods for the control of nematodes. 3. A compound according to claim 1 , in which T represents sulphur claim 1 , capable of being used for controlling nematodes.6. Composition claim 1 , comprising an effective amount of at least one compound of formula (I-1) or (I-2) and at least one surfactant claim 1 , solid or liquid diluent.7. A compound according to capable of being used as an endoparasiticide.8. A compounds according to capable of being used as an anthelmintic.9. A compound according to capable of being used for preparation of an endoparasitic agent for combating one or more endoparasites. The present invention relates to the use of N-(Phenylcycloalkyl)carboxamides and N-(Phenylcycloalkyl)thiocarboxamides for the control of nematodes in agriculture and as anthelmintic agents against endoparasites in animals and humans, compositions containing such compounds and methods for the control of nematodes and helminths.The present invention further relates to novel N-(Phenylcycloalkyl)carboxamides and N-(Phenylcycloalkyl)thiocarboxamides, processes and intermediate compounds for their preparation, their use as nematicides, compositions containing such compounds and methods for the control of nematodes.Nematodes cause a substantial loss in agricultural product including food and industrial crops and are controlled with chemical compounds having nematicidal activity. To be useful in agriculture these compounds should have ...

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Номер записи: 49
29-03-2018 дата публикации

Novel 5-substituted imidazole derivatives

Номер: US20180084780A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Dahmen Peter, Genix Pierre, HELMKE Hendrik, Hoffmann Sebastian, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, Vors Jean-Pierre, Wachendorff-Neumann Ulrike, WITTROCK Sven
Принадлежит:

The present invention relates to novel 5-substituted imidazolylmethyl derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 5. Method for controlling harmful microorganisms in crop protection and in the protection of one or more materials claim 1 , comprising applying a compound of the formula (I) and/or a salt and/or N-oxide thereof according to to the harmful microorganisms and/or a habitat thereof.6. Method for controlling phytopathogenic harmful fungi in crop protection and in the protection of one or more materials claim 1 , comprising applying a compound of the formula (I) and/or a salt and/or N-oxide thereof according to to the phytopathogenic harmful fungi and/or a habitat thereof.7. Composition for controlling harmful microorganisms claim 1 , optionally for controlling phytopathogenic harmful fungi claim 1 , comprising a content of at least one compound of the formula (I) and/or a salt and/or N-oxide thereof according to claim 1 , in addition to one or more extenders and/or surfactants.8. Composition according to comprising at least one further active ingredient selected from the group consisting of insecticides claim 7 , attractants claim 7 , sterilants claim 7 , bactericides claim 7 , acaricides claim 7 , nematicides claim 7 , fungicides claim 7 , growth regulators claim 7 , herbicides claim 7 , fertilizers claim 7 , safeners and semiochemicals.9. A product comprising a compound of the formula (I) and/or a salt and/or N-oxide thereof according to for control of harmful microorganisms claim 1 , optionally phytopathogenic harmful fungi claim 1 , in crop protection and/or for protection of one or more materials.10. Process for producing a composition for controlling harmful microorganisms claim 1 , optionally for ...

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Номер записи: 50
21-03-2019 дата публикации

NOVEL 5-SUBSTITUTED IMIDAZOLE DERIVATIVES

Номер: US20190082691A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Dahmen Peter, Genix Pierre, HELMKE Hendrik, Hoffmann Sebastian, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, Vors Jean-Pierre, Wachendorff-Neumann Ulrike, WITTROCK Sven
Принадлежит:

The present invention relates to novel 5-substituted imidazolylmethyl derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 2. A compound of formula (XVII) and/or a salt and/or N-oxide thereof according to claim 1 , wherein{'sup': '1', 'sub': 1', '8', '1', '8', '2', '7', '2', '7', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '3', '7, 'Rrepresents in each case optionally branched C-C-alkyl, C-C-haloalkyl, C-C-alkenyl, C-C-haloalkenyl, or optionally halogen-, cyano-, C-C-alkyl-, C-C-haloalkyl-, C-C-alkoxy-, C-C-haloalkoxy-, C-C-alkylthio- or C-C-haloalkylthio-substituted C-C-cycloalkyl.'}3. A compound of formula (XVII) and/or a salt and/or N-oxide thereof according to claim 1 , wherein{'sup': '1', 'sub': 1', '4', '1', '4', '2', '5', '2', '5', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '3', '6, 'Rrepresents in each case optionally branched C-C-alkyl, C-C-haloalkyl, C-C-alkenyl, C-C-haloalkenyl, or optionally halogen-, cyano-, C-C-alkyl-, C-C-haloalkyl-, C-C-haloalkoxy-, C-C-alkoxy-, C-C-alkylthio- or C-C-haloalkylthio-substituted C-C-cycloalkyl.'}4. A compound of formula (XVII) and/or a salt and/or N-oxide thereof according to claim 1 , wherein{'sup': '1', 'sub': 1', '4', '1', '4', '1', '4, 'Rrepresents tert-butyl, isopropyl, 1-halocyclopropyl, 1-(C-C-alkyl)cyclopropyl, 1-(C-C-alkoxy)cyclopropyl or 1-(C-C-alkylthio)cyclopropyl.'}5. A compound of formula (XVII) and/or a salt and/or N-oxide thereof according to claim 1 , wherein{'sup': '1', 'Rrepresents tert-butyl, isopropyl, 1-chlorocyclopropyl, 1-fluorocyclopropyl or 1-methylcyclopropyl.'}6. A compound of formula (XVII) and/or a salt and/or N-oxide thereof according to claim 1 , wherein{'sup': '1', 'Rrepresents 1-chlorocyclopropyl or 1-fluorocyclopropyl ...

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Номер записи: 51
25-03-2021 дата публикации

Antibody glycoconjugates and methods of production and use

Номер: US20210087298A1
Автор: Maria L. Jaramillo, Maurizio ACCHIONE, Michel Gilbert, Traian Sulea, Yves Durocher
Принадлежит: NATIONAL RESEARCH COUNCIL OF CANADA

The present invention relates to compounds, compositions, and methods are provided for covalently linking a cargo molecule, such as a therapeutic or a diagnostic agent, to a glycan in the Fab region of an antibody. Also provided are methods of modeling and producing antibodies having de novo Fab glycosylation sites. Also provided are antibody carrier conjugates, methods of using the conjugates.

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Номер записи: 52
26-06-2014 дата публикации

DECORATIVE PIECE WITH INVISIBLE SETTING

Номер: US20140174125A1
Автор: BLASER Lionel, Bourban Stewes, DUBACH Alban, KISSLING Gregory, LAUPER Stephane, Winkler Yves
Принадлежит: Omega S.A.

The invention relates to a decorative piece comprising a plurality of stones and a device for fixing the stones relative to each other, the fixing device comprises a single base made of a first material which makes it possible to attach all the stones relative to each other by one of their faces, the kites of stones are mounted edge to edge relative to each other so that said single base is masked, characterised in that the first material is an at least partially amorphous alloy. 1. Decorative piece comprising a plurality of stones and a device for fixing the stones relative to each other , the fixing device comprises a single base made of a first material which makes it possible to attach all the stones relative to each other by one of their faces , the kites of stones are mounted edge to edge relative to each other so that said single base is masked , wherein the first material is an at least partially amorphous alloy.2. Piece according to the preceding claim , wherein the single base making it possible to attach all the stones relative to each other by their culet.3. Piece according to claim 1 , wherein the single base making it possible to attach all the stones relative to each other by their crown.4. Piece according to claim 1 , wherein the single base makes it possible to attach a plurality of stones so that certain stones are fixed by their culet and certain stones are fixed by their crown.5. Piece according to claim 2 , wherein the single base covers the totality of the culets of said stones.6. Piece according to claim 2 , wherein the single base leaves a part of the culets of said stones uncovered.7. Piece according to claim 3 , wherein the single base covers the totality of the crowns of said stones.8. Piece according to claim 3 , wherein the single base leaves a part of the crowns of said stones uncovered.9. Piece according to claim 2 , wherein the fixing device comprises at least one undercut produced in at least one of the stones at the level of their ...

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Номер записи: 53
12-05-2022 дата публикации

1,3,4-OXADIAZOLES AND THEIR DERIVATIVES AS NEW ANTIFUNGAL AGENTS

Номер: US20220144815A1
Автор: BRUNET Stephane, Coqueron Pierre-Yves, Desbordes Philippe, DUCERF Sophie, DUFOUR Jérémy, GOERTZ Andreas, HILT Emmanuelle, MALLINGER Aurelie, NAUD Sebastien, Rebstock Anne-Sophie, Thomas Vincent
Принадлежит:

The present disclosure relates to the use of 1,3,4-oxadiazoles and derivatives thereof as fungicide. It also relates to new 1,3,4-oxadiazoles derivatives, their use as fungicide and compositions comprising thereof. 2. A product comprising the compound of formula (I) according to or a salt claim 1 , N-oxide or solvate thereof claim 1 ,wherein{'sub': 2', '2', '3, 'U is selected from CHF, CClFand CF;'}{'sup': '1', 'Qis O or S;'}{'sup': 1', '2, 'Wand Ware independently N or CH;'}{'sup': 4', '4', '5', '4', '5', '4', '5', '4', '4', '5, 'A is a direct bond, O, S, NR, —N(R)—(C═O), —(C═O)—O—, —(C═O)—N(R)—, —(C═O)—N(R)—N(R), —N(R)—N(R)—, —N(R)—(C═O)—O— or —N(R)—(C═O)—N(R)—;'}{'sup': 1', '2, 'm is 0, 1 or 2; wherein, if m is 2, the two [CRR] groups may be the same or different;'}p is 0 or 1;X is fluorine;{'sup': 1', '2, 'sub': 1', '8', '1', '8', '2', '8', '3', '7', '1', '8', '1', '8, 'each Rand each Rare independently selected from the group consisting of hydrogen, halogen, cyano, C-C-alkyl, C-C-halogenoalkyl, C-C-alkynyl, C-C-cycloalkyl and aryl, wherein said C-C-alkyl may be substituted with one or more substituents selected from hydroxy and C-C-alkoxy, or'}{'sup': 1', '2, 'sub': 3', '7, 'Rand Rmay form, together with the carbon atom to which they are linked, a C-C-cycloalkyl or oxetanyl ring, or'}{'sup': '1', 'sub': 3', '7, 'two consecutive R, when m is 2, may form, together with the carbon atoms to which they are linked, a C-C-cycloalkyl ring;'}{'sup': '3', 'sub': 1', '8', '1', '8', '3', '7', '3', '8, 'claim-text': [{'sub': 1', '3, 'wherein said 1,3,2-dioxaborolan-2-yl may be substituted with one to four C-C-alkyl substituents,'}, {'sub': 1', '8', '1', '8', '1', '8, 'wherein said C-C-alkyl may be substituted with one C-C-alkoxy or C-C-haloalkoxy substituent, and'}, {'sub': 3', '7', '3', '8', '1', '8', '3', '7', '1', '8', '1', '8', '1', '8', '1', '8, 'sup': '3b', 'wherein said C-C-cycloalkyl, C-C-cycloalkenyl, aryl, heterocyclyl, heteroaryl, biphenyl, phenoxyphenyl and ...

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Номер записи: 54
14-04-2016 дата публикации

NEMATICIDAL N-(2-SUBSTITUTED 2-PHENYLETHYL)CARBOXAMIDES AND N-(2-SUBSTITUTED 2-PHENYLETHYL)-THIOCARBOXAMIDES

Номер: US20160100579A1
Автор: Coqueron Pierre-Yves, Decor Anne, Desbordes Philippe, FUESSLEIN Martin, Goergens Ulrich, GREUL Joerg Nico, Heilmann Eike Kevin, Hoffmann Sebastian, ILG Kerstin, LOESEL PETER, Luemmen Peter, MALSAM Olga, Portz Daniela, Sasaki Norio, Schwarz Hans-Georg, SUDAU Alexander, TSUCHIYA Tomoki, Willms Lothar
Принадлежит:

The present invention relates to the use of known and novel N-(2-substituted 2-phenylethyl)carboxamides and N-(2-substituted 2-phenylethyl)thiocarboxamides, for the control of plant damaging nematodes in agriculture and further relates to novel N-(2-substituted 2-phenylethyl)carboxamides and N-(2-substituted 2-phenylethyl)thiocarboxamides, processes and intermediate compounds for their preparation, their use as nematicides and their use as anthelmintics against endoparasites in animals and humans, compositions containing such compounds and methods for the control of nematodes and helminths. 4. Composition claim 2 , comprising an effective amount of at least one compound according to and at least one surfactant claim 2 , solid or liquid diluent.5. A compounds as described in capable of being used for preparation of a medicament for control of one or more animal parasites.6. A compounds as described in capable of being used for preparation of a medicament for control of helminths.7. A compound according to capable of being used for preparation of a medicament for control of one or more animal parasites.8. A compound as described in capable of being used for preparation of a medicament for control of helminths.9. A compound according to capable of being used for preparation of a medicament for control of one or more animal parasites.10. A compounds as described in capable of being used for preparation of a medicament for control of helminths.11. Composition claim 3 , comprising an effective amount of at least one compound according to and at least one surfactant claim 3 , solid or liquid diluent The present invention relates to the use of known and novel N-(2-substituted 2-phenylethyl)carboxamides and N-(2-substituted 2-phenylethyl)thiocarboxamides, for the control of plant damaging nematodes predominantly in agriculture.The present invention further relates to novel N-(2-substituted 2-phenylethyl)carboxamides and N-(2-substituted 2-phenylethyl)thiocarboxamides, ...

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Номер записи: 55
26-06-2014 дата публикации

DECORATIVE PIECE PRODUCED BY SETTING ON AMORPHOUS METAL

Номер: US20140178625A1
Автор: BLASER Lionel, Bourban Stewes, DUBACH Alban, KISSLING Gregory, LAUPER Stephane, NETUSCHILL Alexandre, Winkler Yves
Принадлежит: Omega S.A.

The present invention relates to a decorative piece comprising a support produced in a material which does not include plastic deformation and in which at least one hollow is provided, characterised in that said hollow being filled with a first material being an at least partially amorphous alloy forming a substrate in which at least one housing is provided, said at least one housing being designed so that at least one aesthetic element can be housed therein. 1. Decorative piece comprising a support produced in a material which does not include plastic deformation and in which at least one hollow is provided , wherein said hollow being filled with a first material being an at least partially amorphous alloy forming a substrate in which at least one housing is provided , said at least one housing being designed so that at least one aesthetic element can be housed therein , said substrate comprising in addition catching means which deform in order to retain said at least one aesthetic element in said at least one housing.2. Decorative piece according to claim 1 , wherein the catching means comprise at least one setting element.3. Decorative piece according to claim 1 , wherein said at least one hollow comprises vertical flanks in order to improve retention of each aesthetic element in the support.4. Decorative piece according to claim 3 , wherein said at least one hollow comprises flanks designed so that the surface of the hollow increases with the depth of the hollow.5. Decorative piece according to claim 3 , wherein said at least one hollow comprises flanks designed so that the surface of the hollow decreases with the depth of the hollow.6. Decorative piece according to claim 1 , wherein said at least one hollow comprises retaining means which extend from one of the walls of the hollow in order to retain the first material in said hollow.7. Decorative piece according to claim 6 , wherein the retaining means have the shape of at least one recess.8. Decorative piece ...

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Номер записи: 56
26-03-2020 дата публикации

NOVEL TRIAZOLETHIONE DERIVATIVES

Номер: US20200095223A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Genix Pierre, GOERTZ Andreas, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien
Принадлежит:

The present invention relates to novel triazole derivatives of formula (I-S) 2. Triazole derivative of formula (I-S) according to claim 1 , wherein{'sup': '1', 'sub': 3', '2', '3', '2, 'Rrepresents hydrogen, methyl, ethyl, propyl, isopropyl, butyl, cyclopropyl, CF, benzyl, allyl, CHC≡C—CHor CHC≡CH,'}and/or{'sup': '2', 'Rrepresents hydrogen'}and/or a salt or N-oxide thereof.3. Triazole derivative of formula (I-S) according to claim 1 , wherein{'sup': 4', '6', '4a', '4b, 'sub': 2', '3', '3', '3', '3, 'claim-text': {'sup': 4a', '4b, 'wherein Rrepresents hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl or tert.-butyl, optionally hydrogen or methyl, Rrepresents hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl or tert.-butyl, optionally hydrogen or methyl,'}, 'each Rrepresents independently from each other Br, CI, F, CN, nitro, methyl, ethyl, n-propyl, isopropyl, CHF, CF, methoxy, OCF, SCH, SCF, pentafluoro-λ-sulfanyl or —C(R)═N—OR,'}and/orm is 1and/or a salt or N-oxide thereof.6. Triazole derivative of formula (I-S) according to claim 1 , wherein{'sub': '3', 'R represents CFor Cl,'}and/orn is 0and/or a salt or N-oxide thereof.10. Composition for controlling one or more harmful microorganisms claim 1 , optionally for controlling phytopathogenic harmful fungi claim 1 , comprising at least one compound according to claim 1 , and at least one extender and/or surfactant.11. Composition according to comprising at least one further active ingredient selected from the group of insecticides claim 10 , attractants claim 10 , sterilants claim 10 , bactericides claim 10 , acaricides claim 10 , nematicides claim 10 , fungicides claim 10 , growth regulators claim 10 , herbicides claim 10 , fertilizers claim 10 , safeners and semiochemicals.12. Method for controlling one or more harmful microorganisms in crop protection and in protection of one or more materials claim 1 , comprising applying at least one compound according to claim 1 , and/or a composition ...

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Номер записи: 57
26-03-2020 дата публикации

PROCESS FOR THE PRODUCTION OF A TIMEPIECE PROVIDED WITH A HOLLOW OR RAISED EXTERNAL ELEMENT

Номер: US20200096946A1
Автор: Bourban Stewes, Grossenbacher Pascal, Vuille Pierry, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A process for producing a part provided with an external element includes: providing an electrically conductive substrate having an upper surface and a raised pattern with a crest on the upper surface; depositing an electrically insulating layer onto the upper surface around the pattern to a thickness less than or equal to the distance between the crest and the upper surface; depositing a metal layer onto the crest by galvanic growth so that the metal layer partly rests on the insulating layer; dissolving the insulating layer; covering an assembly including the substrate and the metal layer with a mass of a base material of the part to form an imprint; separating the mass and the metal layer from the substrate, the mass then exhibiting an external element formed by a recess, the shape of which corresponds to the imprint and the base of which interfaces with the metal layer. 1. A process for producing a part provided with an external element , the process comprising:providing an electrically conductive substrate having an upper surface;depositing an electrically insulating layer onto the upper surface of the substrate;machining the insulating layer and the substrate so that a hollow pattern is formed that passes through the insulating layer and extends over a portion of the substrate;depositing a metal layer into the pattern by galvanic growth so that, at the end of the depositing the metal layer, the metal layer partly rests on the insulating layer;dissolve the insulating layer;covering an assembly comprising the substrate and the metal layer with a mass of a base material of the part, wherein the mass forms an imprint of the assembly;separating the mass and the metal layer from the substrate, wherein the metal layer then forms an outgrowth forming an external element on the mass, the shape of the outgrowth corresponding to the imprint of the pattern.2. The production process according to claim 1 , further comprising:dissolving the metal layer, wherein the mass then ...

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Номер записи: 58
21-04-2016 дата публикации

KNOWN AND NEW HETEROCYCLIC COMPOUNDS AS PEST CONTROL AGENTS

Номер: US20160106102A1
Автор: Andree Roland, BOLLENBACH-WAHL Birgit, Coqueron Pierre-Yves, FISCHER Reiner, FRANKEN Eva-Maria, HEIL Markus, ILG Kerstin, Jansen Johannes-Rudolf, KUEBBELER Susanne, VOERSTE Arnd
Принадлежит:

The present application relates to the use of known and novel heterocyclic compounds for controlling animal pests, to novel heterocyclic compounds, to processes for preparation thereof and to the use thereof for controlling animal pests. 3. Composition claim 1 , comprising a content of at least one compound of formula (I) according to and one or more customary extenders and/or surfactants.4. Composition claim 2 , comprising a content of at least one compound of formula (I) according to and one or more customary extenders and/or surfactants.5. Method for controlling one or more pests claim 1 , comprising allowing a compound of formula (I) according to to act on the pests and/or a habitat thereof.6. A compound of formula (I) according to capable of being used for controlling one or more pests. The present application relates to the use of known and novel heterocyclic compounds for controlling animal pests, to novel heterocyclic compounds, to processes for preparation thereof and to the use thereof for controlling animal pests.WO 2011/049987 A2, WO 2011/106114 A1, WO 2009/025793 A2, US 2008/0103182 A1, WO 2007/055941 A2, WO 2006/114313 A1, US 2009/0163545 A1 and FR 2836915 A1 disclose heterocyclic compounds for which pharmaceutical uses are described. U.S. Pat. No. 2,511,231 and JP 63218665 A disclose heterocyclic compounds for use in photography. The literature describes particular substituted pyridines as insecticides; see, for example WO 2003/097604 A1. WO 2005/074686 A1 and WO 2008/014905 A2 disclose carboxamides for control of unwanted microorganisms.The heterocyclic compounds of the formulae (G1), (G2) and (G4) are known. No use for these compounds has been described.In the case of compounds G1-1, G1-5, G1-6, G1-17, G1-71, G1-79 to G1-82 and G1-96 to G1-98 and G1-103, the Yand Ycolumns also show the carbon atoms bonded to Yand Yand the nitrogen atom bonded to Z. The same applies to all the tables in this patent application in which Yand Yoccur together.Modern ...

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Номер записи: 59
11-04-2019 дата публикации

PESTICIDE COMPOSITION COMPRISING A TETRAZOLYLOXIME DERIVATIVE AND A FUNGICIDE OR AN INSECTICIDE ACTIVE SUBSTANCE

Номер: US20190104736A1
Автор: Coqueron Pierre-Yves, Grosjean-Cournoyer Marie-Claire, Hutin Pierre, Spica Gilbert, VOERSTE Arnd, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to a pesticide composition intended for protecting plants, crops or seeds against fungal diseases or insect damages, and the corresponding methods of protection by application of the said composition. More precisely, the subject of the present invention is a pesticide composition based on a tetrazolyloxime derivative and a fungicide or an insecticide active substance or compound. 2. A composition according to claim 1 , further comprising.C) a second further fungicide compound in an A/B/C weight ratio ranging from 1/0.01/0.01 to 1/100/100.3. A composition according to claim 1 , further comprising:D) an insecticide compound in an A/B/D weight ratio ranging from 1/0.01/0.01 to 1/100/100.4. A composition according to claim 1 , further comprising:C) a second further fungicide compound andD) an insecticide compound in an A/B/C/D weight ratio ranging from 1/0.01/0.01/1 to 1/100/100/100.5. A composition according to wherein X represents a hydrogen atom claim 1 , a halogen atom claim 1 , an alkyl group claim 1 , an alkoxy group claim 1 , a cyano group claim 1 , a rnethanesulfonyl group claim 1 , a nitro group claim 1 , a trifluoromethyl group or an aryl group.6. A composition according to wherein X independently represents a chlorine atom claim 1 , a bromine atom claim 1 , an iodine atom claim 1 , a fluorine atom claim 1 , a methyl group claim 1 , an ethyl group claim 1 , an n-propyl group claim 1 , an isopropyl group claim 1 , an n-butyl group claim 1 , an isobutyl group claim 1 , a sec-butyl group claim 1 , a tert-butyl group claim 1 , a methoxy group claim 1 , an ethoxy group claim 1 , a propoxy group and an isopropoxy group claim 1 , a phenyl group claim 1 , a 4-methylphenyl group claim 1 , or a 4-chlorophenyl group.7. A composition according to wherein X represents a hydrogen atom.8. A composition according to wherein Y represents a methyl group claim 1 , an ethyl group claim 1 , an n-propyl group or an isopropyl group.9. A composition ...

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Номер записи: 60
30-04-2015 дата публикации

5-HALOGENOPYRAZOLE INDANYL CARBOXAMIDES

Номер: US20150119241A1
Автор: Bernier David, BRUNET Stephane, Carles Lionel, Coqueron Pierre-Yves, Dubost Christophe, ES-SAYED Mazen, Genix Pierre, LACHAISE Helene, Maechling Simon, Vors Jean-Pierre, Wachendorff-Neumann Ulrike, WASNAIRE Pierre
Принадлежит:

The present invention relates to novel 1-methyl-3-dihalogenomethyl-5-halogenopyrazole(thio)indanyl carbox-amides, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials. 2. 1-Methyl-3-dihalogenomethyl-5-halogenopyrazole(thio)indanyl carboxamide of formula (I) according to claim 1 , wherein{'sup': '1', 'Halrepresents chlorine or fluorine;'}{'sup': '2', 'Halrepresents chlorine, bromine, or fluorine;'}T represents an oxygen or sulfur atom;{'sub': 1', '4', '1', '3', '1', '3', '1', '4', '1', '3', '1', '3, 'Q represents hydrogen, C-C-alkylsulfonyl, C-C-alkoxy-C-C-alkyl, C-C-haloalkylsulfonyl, halo-C-C-alkoxy-C-C-alkyl having in each case 1 to 9 fluorine, chlorine and/or bromine atoms;'}X represents fluorine, chlorine, iodine, methyl, cyclopropyl, or trifluoromethyl;m represents 0, 1 or 2;{'sup': 1', '2', '3', '4', '5', '6', 'b', 'b', 'b', 'b', 'b', 'b', 'b, 'sub': 1', '16', '1', '6', '3', '8', '3', '8', '1', '8', '3', '8', '3', '8', '2', '8', '2', '8', '2', '8', '1', '16', '2', '8', '1', '16', '1', '16', '3', '8', '3', '8', '1', '8', '1', '8', '3', '8', '3', '8', '1', '8', '2', '8', '3', '8', '1', '8', '1', '8', '3', '8', '2', '8', '3', '8', '2', '8', '1', '8', '8', '1', '8', '1', '8', '2', '8', '2', '8, 'R, R, R, R, Rand Rindependently of one another represent hydrogen, halogen; cyano; C-C-alkyl; C-C-haloalkyl having 1 to 9 identical or different halogen atoms; C-C-cycloalkyl; (C-C-cycloalkyl)-C-C-alkyl; (C-C-cycloalkyl)-C-C-cycloalkyl; C-C-alkenyl; C-C-alkynyl; C-C-alkenyl-C-C-alkyl; C-C-alkynyl-C-C-alkyl; C-C-alkoxy; C-C-cycloalkyloxy; (C-C-cycloalkyl)-C-C-alkyloxy; C-C-alkylsulfanyl; C-C-cycloalkylsulfanyl; (C-C-cycloalkyl)-C-C-alkylsulfanyl; C-C-alkenyloxy; C-C-alkynyloxy; aryl-C-C-alkyloxy which is optionally substituted by up to 6 identical or different groups R; aryl-C-C- ...

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Номер записи: 61
03-05-2018 дата публикации

NOVEL TRIAZOLE DERIVATIVES

Номер: US20180116220A1
Автор: BENTING, Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Dahmen Peter, Genix Pierre, II JUERGEN, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, PERIS Gorka, VORS JEAN-PIERE, Wachendorff-Neumann Ulrike, WITTROCK Sven
Принадлежит:

The present invention relates to novel triazole derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 5. Method for controlling harmful microorganisms in crop protection and in the protection of one or more materials claim 1 , a compound of the formula (I) and/or a salt and/or N-oxide thereof according to to the harmful microorganisms and/or a habitat thereof.6. Method for controlling phytopathogenic harmful fungi claim 1 , comprising applying a compound of the formula (I) and/or a salt and/or N-oxide thereof according to the phytopathogenic harmful fungi and/or a habitat thereof.7. Composition for controlling harmful microorganisms in crop protection and in the protection of one or more materials claim 1 , optionally for controlling phytopathogenic harmful fungi claim 1 , comprising a content of at least one compound of the formula (I) and/or a salt and/or N-oxide thereof according to claim 1 , in addition to one or more extenders and/or surfactants.8. Composition according to comprising at least one further active ingredient selected from the group consisting of insecticides claim 7 , attractants claim 7 , sterilants claim 7 , bactericides claim 7 , acaricides claim 7 , nematicides claim 7 , fungicides claim 7 , growth regulators claim 7 , herbicides claim 7 , fertilizers claim 7 , safeners and semiochemicals.9. A product comprising a compound of the formula (I) and/or a salt and/or N-oxide thereof according to for control of harmful microorganisms claim 1 , optionally phytopathogenic harmful fungi claim 1 , for crop protection and/or for protection of one or more materials.10. Process for producing compositions for controlling harmful microorganisms claim 1 , optionally for controlling phytopathogenic harmful fungi claim 1 , ...

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Номер записи: 62
24-07-2014 дата публикации

FUNGICIDE HYDROXIMOYL-TETRAZOLE DERIVATIVES

Номер: US20140206726A1
Автор: BENTING Juergen, Coqueron Pierre-Yves, Desbordes Philippe, Dubost Christophe, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to hydroximoyl-tetrazole derivatives of formula (I), their process of preparation, their use as fungicide active agents, particularly in the form of fungicide compositions and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions. 2. A compound according to claim 1 , wherein X represents a hydrogen atom claim 1 , a chlorine atom claim 1 , a fluorine atom claim 1 , a methyl group claim 1 , an ethyl group claim 1 , an n-propyl group claim 1 , an isopropyl group claim 1 , an n-butyl group claim 1 , an isobutyl group claim 1 , a sec-butyl group claim 1 , and a tert-butyl group claim 1 , a methoxy group claim 1 , an ethoxy group claim 1 , a propoxy group claim 1 , and an isopropoxy group claim 1 , a cyano group claim 1 , a methanesulfonyl group claim 1 , a nitro group claim 1 , a trifluoromethyl group or an aryl group.3. A compound according to claim 1 , wherein X represents a hydrogen atom.4. A compound according to claim 1 , wherein Y represents a methyl group claim 1 , an ethyl group claim 1 , an n-propyl group or an isopropyl group.5. A compound according to claim 1 , wherein R represents a fluorine atom in the pyridyl group of formula (Het).6. A compound according to claim 1 , wherein Rrepresents a methyl in the group of formula (Z).7. A compound according to claim 1 , wherein Rand Rindependently represent a hydrogen atom claim 1 , a methyl group claim 1 , an ethyl group or a cyclopropyl group in the group of formula (Z).8. A compound according to claim 1 , wherein Rand Rform together a substituted or non-substituted claim 1 , saturated or partially saturated claim 1 , 4- claim 1 , 5- claim 1 , 6-membered cycle claim 1 , which is a carbocycle or a heterocycle comprising up to 2 heteroatoms selected in the list consisting of N claim 1 , O claim 1 , S.9. A compound according to claim 1 , wherein Rrepresents a substituted or non-substituted C-C-cycloalkyl in the group of formula (Z).10. ...

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Номер записи: 63
25-04-2019 дата публикации

HAND COMPRISING AN END PIECE AND ASSEMBLY METHOD

Номер: US20190121294A1
Автор: CAROZZANI Tommy, Winkler Yves
Принадлежит: THE SWATCH GROUP RESEARCH AND DEVELOPMENT LTD.

A device including a first part and at least a second part to be assembled to the first part, the first part including a body from which an attachment extends, the attachment defining a housing for the second part, for example as a timepiece hand. 118-. (canceled)19: A method for assembling a device including a timepiece hand and at least one end piece to be assembled to one end of the hand , the hand being made of an at least partially amorphous metal material , the method comprising:taking the hand and the end piece, the hand including a body and attachment means defining a housing, the attachment means including two elastic arms made of at least partially amorphous metal material;deforming the attachment means by exerting a force to temporarily enlarge the housing;placing the end piece inside the housing;releasing the force exerted on the attachment means to allow the housing to return to its initial dimensions and hold the end piece.20: An assembly method according to claim 19 , wherein the force is exerted by a tool.21: An assembly method according to claim 19 , wherein the deforming claim 19 , placing claim 19 , and releasing the force are grouped into a single operation of press fitting the second part.22: An assembly method according to claim 19 , wherein the end piece is a decorative element.23: An assembly method according to claim 19 , wherein the end piece is a functional element taken from the following group: pipe claim 19 , arbor claim 19 , counterweight claim 19 , indicator claim 19 , vernier claim 19 , magnifying glass claim 19 , disc of fluorescent or phosphorescent material claim 19 , LED.24: An assembly method according to claim 19 , wherein the metal material is completely amorphous.25: An assembly method according to claim 19 , wherein the metal material is at least 50% amorphous.26: A method for assembling a device including a timepiece hand and at least one end piece to be assembled to one end of the hand claim 19 , the end piece being made ...

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Номер записи: 64
18-05-2017 дата публикации

Fabric softening composition comprising a heur thickener

Номер: US20170137751A1
Автор: Jean-Marc Suau, Yves Kensicher, Yves MATTER
Принадлежит: Coatex SAS

The present invention relates to a fabric softening composition, comprising a cationic fabric softening agent and a thickening polyurethane resulting from the condensation: a) of at least one compound of formula (I): R-[(EO) m —(PO) n —(BO) p ]—OH  (I) in which: R is a linear or branched carbon chain, including at least one unsaturation and having between 17 and 24 carbon atoms, [(EO) m —(PO) n —(BO) p ] represents an alkoxylated chain constituted of alternating or statistical alkoxylated units, distributed in blocks, chosen from ethoxylated units EO, propoxylated units PO and butoxylated units BO and m, n and p represent, independently of each other, 0 or an integer ranging between 1 and 10, the sum of m, n and p being between 0 and 10, b) of at least one polyol, for example of at least one poly(alkylene glycol) and c) of at least one polyisocyanate.

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Номер записи: 65
25-05-2017 дата публикации

SUBSTITUTED PYRAZOLYL-NICOTIN(THIO)AMIDE DERIVATIVES AND THEIR USE AS FUNGICIDES

Номер: US20170142969A1
Автор: BRUNET Stephane, Coqueron Pierre-Yves, Dubost Christophe, Greul Joerg, Montagne Cyril, Vors Jean-Pierre, Wachendorff-Neumann Ulrike, WINTER PHILIPP
Принадлежит:

The present invention relates to novel substituted pyrazolyl-nicotin(thio)amide derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms, in crop protection and in the protection of materials. 5. A method for controlling phytopathogenic harmful fungi claim 1 , comprising applying a compound according to to the phytopathogenic harmful fungi and/or a habitat thereof.6. A composition for controlling phytopathogenic harmful fungi claim 1 , comprising a content of at least one compound according to claim 1 , in addition to one or more extenders and/or surfactants.7. At least one compound according to for controlling phytopathogenic harmful fungi.8. A process for producing a composition for controlling phytopathogenic harmful fungi according to claim 1 , comprising mixing a compound of with one or more extenders and/or surfactants.9. A compound according to for treatment of seed.10. A compound according to for treatment of one or more transgenic plants. The present invention relates to novel substituted pyrazolyl-nicotin(thio)amide derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials.Since the ecological and economical demands made on modern crop protection agents are increasing constantly, for example with respect to activity spectrum, toxicity, selectivity, application rate, formation of residues and favourable manufacture, and there can furthermore be problems, for example, with resistances, there is a constant need to develop novel crop protection compositions, in particular fungicides, which, at least in some areas, have advantages over the known ones.JP2012056944, JP2010202649 JP201205694 and EP1329160 disclose ...

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Номер записи: 66
11-06-2015 дата публикации

ZIRCONIUM-BASED AND BERYLLIUM FREE BULK AMORPHOUS ALLOY

Номер: US20150159249A1
Автор: CAROZZANI Tommy, DUBACH Alban, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

The invention concerns a zirconium and/or hafnium based, beryllium free, bulk, amorphous alloy, with the addition of silver and/or gold and/or platinum to increase its critical diameter. 1. A bulk amorphous alloy , wherein the alloy comprises no beryllium and consists , in atomic percent values , of:a base comprising 50%-63% of zirconium and/or hafnium;1.5%-4.5% of at least one first additional metal, said at least one first additional metal being selected from the group consisting of titanium, niobium and tantalum, the niobium being less than or equal to 2.5%;0.5%-4.5% of at least one second additional metal, said at least one second additional metal being selected from the group consisting of silver, gold and platinum;8.5%-17.5% of at least one third additional metal, said at least one third additional metal being selected from the group consisting of nickel, cobalt, manganese and iron;9%-13% of aluminum; andcopper and inevitable impurities in a positive amount less than or equal to 18%.2. The alloy according to claim 1 , wherein the alloy comprises 2.5%-4.5% of said at least one first additional metal.3. The alloy according to claim 1 , wherein the alloy comprises 1.0%-4.0% of said at least one second additional metal.4. The alloy according to claim 3 , wherein the alloy comprises 1.5%-3.8% of said at least one second additional metal.5. The alloy according to claim 1 , wherein the alloy comprises 1.5%-2.5% of gold in atomic percentage.6. The alloy according to claim 1 , wherein the alloy comprises 1.5%-2.5% of platinum in atomic percentage.7. The alloy according to claim 1 , wherein the alloy comprises 1.0%-3.8% of silver in atomic percentage.8. The alloy according to claim 1 , wherein the alloy comprises less than or equal to 60% of zirconium and/or hafnium in the base.9. The alloy according to claim 1 , wherein the alloy comprises more than 10.0% of aluminum.10. The alloy according to claim 1 , wherein the alloy comprises a ratio of zirconium to copper claim 1 ...

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Номер записи: 67
30-05-2019 дата публикации

ACTIVE COMPOUND COMBINATIONS COMPRISING A (THIO)CARBOXAMIDE DERIVATIVE AND A FUNGICIDAL COMPOUND

Номер: US20190159452A1
Автор: Coqueron Pierre-Yves, Cristau Pierre, Desbordes Philippe, DRÖGE Thomas, Meissner Ruth
Принадлежит: Bayer CropScience Aktiengesellschaft

The present invention relates to active compound combinations, in particular within a fungicide composition, which comprises (A) a N-cyclopropyl-N-[substituted-benzyl]-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide or thiocarboxamide derivative and at least a further fungicidally active compound (B) consisting of 5-fluoro-4-imino-3-methyl-1-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(1H)-one, 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-3-methyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide or (2E,3Z)-5-{[1-(4-chloro-2-fluorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide 2: The active compound combination according to claim 1 , wherein the compound (A) of formula (I) is selected from the group consisting of:N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide (compound A1),N-cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide (compound A2),N-(2-tert-butylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide (compound A3),N-(5-chloro-2-ethylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide (compound A4),N-(5-chloro-2-isopropylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide (compound A5),N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-fluorobenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide (compound A6),N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(5-fluoro-2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide (compound A7),N-cyclopropyl-N-(2-cyclopropyl-5-fluorobenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide (compound A8),N-(2-cyclopentyl-5-fluorobenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide (compound A9),N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-fluoro-6-isopropylbenzyl)- ...

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Номер записи: 68
04-09-2014 дата публикации

Compounds with Nematicidal Activity

Номер: US20140249149A1
Автор: Carles Lionel, Coqueron Pierre-Yves, Desbordes Philippe, FÜßLEIN Martin, GÖRGENS Ulrich, Greul Jörg Nico, ILG Kerstin, Kather Kristian, Lösel Peter, MALSAM Olga, Mansfield Darren, Meresse Philippe, Rieck Heiko, RIEDRICH Matthias, Rodefeld Lars, Schwarz Hans-Georg, VOERSTE Arnd
Принадлежит: Bayer Intellectual Property GmbH

The present invention relates to the use of known pyridyl carboxamide derivatives and novel pyridyl carboxamide derivatives as nematicides, compositions containing such compounds and methods for the control of nematodes. 4. A compound according to claim 3 , in which R claim 3 , R claim 3 , Rrepresent hydrogen claim 3 , n represents 2 and X represent 3-Cl and 6-CF.6. A Compound according to claim 5 , in which R claim 5 , R claim 5 , Rrepresent hydrogen claim 5 , n represents 2 and X represent 3-Cl and 6-CF.7. A compound according to claim 5 , in which R claim 5 , R claim 5 , Rrepresent hydrogen claim 5 , n represents 2 and X represent 3-Cl and 6-Cl.10. A compound according to claim 9 , in which R claim 9 , R claim 9 , Rrepresent hydrogen claim 9 , n represents 1 and X represents 6-Cl.27. A composition claim 1 , comprising an effective amount of at least one compound of formula (I) according to claim 1 , and at least one surfactant claim 1 , solid or liquid diluent. The present invention relates to the use of predominantly known pyridyl carboxamide derivatives as nematicides, compositions containing such compounds and methods for the control of nematodes.Nematodes cause a substantial loss in agricultural product including food and industrial crops and are combated with chemical compounds having nematicidal activity. To be useful in agriculture these compounds should have a high activity, a broad spectrum activity against different strains of nematodes and should not be toxic to non-target organisms.The use of certain N-2-(pyridyl)ethyl-carboxamide derivatives for controlling nematodes is described in EP 2 132 987 A1.Most of the compounds of formula (I) described below are known from WO 2001/011965 A1 (later, e.g. in the Tables, referred to as P1), WO 2005/058828 A1 (P2), WO2005/014545 A2 (P3), WO 2005/103004 A1 (P4), WO 2006/122952 A1 (P5), EP 2 289 880 A1 (P6), WO 2006/008191 A1 (P7) and WO 2006/008192 A1 (P8). There it is stated that they can be used as fungicides. ...

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Номер записи: 69
24-06-2021 дата публикации

Method for converting an image and corresponding device

Номер: US20210195139A1
Автор: Cambodge Bist, Foteini Tania POULI, Jean-Yves Aubie
Принадлежит: FONDATION B COM

A method is described for converting an input image into an output image, the output image including an output luminance component made of elements. The method includes: obtaining an input luminance component from the input image; determining the output luminance component, the respective ranges of the output luminance component element values and input luminance component element values being of different range extension, the determining step including: —determining a first intermediate luminance component from the input luminance component and an exponent, —obtaining a mapping profile allowing for mapping a luminance component based on the input luminance component into the output luminance component, —determining a second intermediate luminance component from the input luminance component and the obtained mapping profile, —determining the output luminance component from the first and second intermediate luminance components; and converting the input image into the output image.

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Номер записи: 70
11-09-2014 дата публикации

COMPOUNDS WITH NEMATICIDAL ACTIVITY

Номер: US20140256728A1
Автор: Bernier David, Coqueron Pierre-Yves, Cristau Pierre, Desbordes Philippe, Dunkel Ralf, Gary Stephanie, GÖRGENS Ulrich, Greul Jörg Nico, ILG Kerstin, Lösel Peter, MALSAM Olga, MARTELLETTI Arianna, Maue Michael, Meresse Philippe, Paulitz Christian, Rieck Heiko, RIEDRICH Matthias, Schwarz Hans-Georg, SUDAU Alexander, VOERSTE Arnd
Принадлежит: Bayer Intellectual Property GmbH

The present invention relates to the use of predominantly known pyridyl carboxamide derivatives as nematicides, compositions containing such compounds and methods for the control of nematodes.

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Номер записи: 71
23-06-2016 дата публикации

METHOD OF PRODUCING A DECORATED ELEMENT FOR A TIMEPIECE OR PIECE OF JEWELLERY, AND ELEMENT MADE BY THE METHOD

Номер: US20160176228A1
Автор: Bourban Stewes, DUBACH Alban, Martin Jean-Claude, Vuille Pierry, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

The method makes it possible to produce a decorated element for a timepiece or piece of jewellery. This decorated element may be, for example, a watch dial. The method includes the steps of taking a base substrate, and micromachining on said base substrate a mould or decorative partitions in a programmed pattern, and filling the mould or the decorative partitions with at least one filler material to obtain the decorated element. The filler material may be an epoxy resin and the mould or the partitions are obtained by melting and solidifying a solder paste or powder. 1. A method for producing a decorated element for a timepiece or piece of jewellery , wherein the method includes the steps of:taking a base substrate,depositing a layer of positive or negative photosensitive resin on the base substrate,placing a contour mask of the pattern to be created on the photosensitive resin,illuminating the resin through the mask,removing the illuminated portions of the resin, if the photosensitive resin is of the positive type, or removing the non-illuminated portions of the resin, if the photosensitive resin is of the negative type,filling the removed portions of the resin with at least one solder paste or powder to produce partitions or a mould,heating the assembly formed of the base substrate, the resin and the solder paste or powder to melt the solder paste or powder prior to solidification of the solder,removing all the resin, andfilling the mould or decorative partitions with at least one filler material to obtain the decorated element.2. A method for producing a decorated element for a timepiece or piece of jewellery , wherein the method includes the steps of:taking a base substrate,depositing a layer of positive or negative photosensitive resin on the base substrate,placing a contour mask of the pattern to be created on the photosensitive resin,illuminating the resin through the mask,removing the illuminated portions of the resin, if the photosensitive resin is of the ...

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Номер записи: 72
22-06-2017 дата публикации

COMPOSITE COMPONENT WITH STRESSED RESILIENT MEANS

Номер: US20170176935A1
Автор: DUBOIS PHILIPPE, Winkler Yves
Принадлежит: NIVAROX-FAR S.A.

The invention relates to a composite component comprising an element with an opening into which extend stressed resilient means confined within a volume of an at least partially amorphous metal alloy, said composite component comprising a passage that, is centred with respect to said stressed resilient means. 1. A method for fabrication of a composite component comprising the following steps:a) forming an element with an opening into which resilient means extend;b) placing a tool between the resilient means of the element so as to place the resilient means under stress;c) overmoulding the element with an at least partially amorphous metal alloy so as to confine the resilient means under stress;d) removing the tool to form the composite component provided with a passage of corresponding shape to the tool between the resilient means under stress.2. The method according to claim 1 , wherein the resilient means form at least two deformable strips connected in one-piece to the wall of the opening in the element.3. The method according to claim 2 , wherein at least one end of one of the at least two deformable strips is connected in one-piece to at least one end of another of the at least two deformable strips.4. The method according to claim 3 , wherein the at least two interconnected deformable strips form a V-shaped structure.5. The method according to claim 3 , wherein the at least two interconnected deformable strips form a polygon.6. The method according to claim 3 , wherein the at least two interconnected deformable strips form a Y-shaped structure.7. The method according to claim 1 , wherein claim 1 , in step c) claim 1 , an at least partially amorphous metal alloy blank is heated between its glass transition temperature and its crystallization temperature in order to overmould the resilient means.8. The method according to claim 1 , wherein claim 1 , in step c) claim 1 , the at least partially amorphous metal alloy overmould forms a protruding portion of the ...

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Номер записи: 73
06-07-2017 дата публикации

TIMEPIECE ASSORTMENT USING AN AMORPHOUS METAL ALLOY

Номер: US20170192390A1
Автор: CHARBON Christian, DUBOIS PHILIPPE, Mallet Daniel, Winkler Yves
Принадлежит: NIVAROX-FAR S.A.

The invention relates to a timepiece assortment including a timepiece component fixed to an arbor with the aid of a fixing element. According to the invention, the fixing element is made of at least partially amorphous metal alloy, is secured to the timepiece component by partial insertion and includes a hole into which the arbor is driven. 1. A timepiece assortment that is assembled by the following steps:a) separately manufacturing a timepiece component and a fixing element, the fixing element being manufactured from an at least partially amorphous metal alloy;b) partially inserting at least one portion of the timepiece component into the thickness of the fixing element heated to between its vitreous transition temperature and its crystallisation temperature in order to form a timepiece component fixing element assembly;c) driving an arbor into a hole of the fixing element to form the timepiece assortment so as to leave a gap between timepiece component and the arbor,the timepiece assortment comprising:the timepiece component fixed to the arbor with the aid of the fixing element including the hole into which the arbor is driven, wherein the fixing element is made of an at least partially amorphous metal alloy and is secured to the timepiece component by partial insertion of one into the other, and wherein the timepiece component includes an opening which extends around the hole of the fixing element and has a larger cross-section so as to leave a gap between the wall of the opening and the arbor.2. The timepiece assortment according to claim 1 , wherein the timepiece component is mounted against a shoulder of the arbor.3. The timepiece assortment according to claim 1 , wherein the fixing element is mounted against a shoulder of the arbor.4. The timepiece assortment according to claim 1 , wherein at least one fifth of the height of the timepiece component is covered by the fixing element.5. The timepiece assortment according to claim 1 , wherein the timepiece ...

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Номер записи: 74
12-07-2018 дата публикации

PART COATING METHOD

Номер: US20180193919A1
Автор: DUBACH Alban, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A device including a first portion made of a first material and a second portion made of a second material, the second part extends from one of faces of the first portion and is made of an amorphous material. 116-. (canceled)17. A method of manufacturing a part including a first portion made of a first material and a second portion made of a second material , the method comprising:procuring a preform made of the second material, the second material being an at least partially amorphous metal adapted to increase in volume subject to temperature and pressure conditions:procuring the first portion and placing the first portion and the preform between two dies having a negative shape of the part to be manufactured;heating the combination to a temperature between the glass transition temperature and the crystallization temperature inclusive of the preform, at a latest during the heating, to enable the preform to form an at least partially amorphous metal foam and to enable expansion of the preform to fill the negative shape of the device and form the part;cooling the combination to solidify the preform to retain the at least partially amorphous metal foam state and separate the device from the dies.18. The method of manufacture as claimed in wherein the expansion of the preform used to form a coated part.19. The method of manufacture as claimed in claim 17 , wherein the expansion of the preform is used to form a bimaterial part.20. The method of manufacture claim 17 , as claimed in claim 17 , wherein the first portion includes at least one cavity into which the amorphous metal foam forming the second part extends.21. The method of manufacture as claimed in claim 17 , wherein the first portion includes at least one protuberance around which the amorphous metal foam forming the second part extends.22. The method of manufacture as claimed in claim 17 , wherein the first part includes structures enabling better attachment of the second part.23. The method of manufacture as ...

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Номер записи: 75
12-07-2018 дата публикации

ASSEMBLING A PART MADE OF BRITTLE MATERIAL

Номер: US20180193921A1
Автор: DUBACH Alban, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A process for assembling a device including first and second parts made of first and second materials, respectively, and a third part made of a third material that acts as an intermediate part enabling the assembling, the process including: providing a preform made from an at least partially amorphous metal material capable of increasing its volume under temperature and pressure conditions; placing the first and second parts with the preform between two cavity plates having, the negative shape of the device; heating the assembly to a temperature between the glass transition temperature and the crystallization temperature of the preform to enable, at latest during the heating, the preform to be in a form of a foam and enable expansion of the preform to fill the negative shape of the device and form the third part; cooling the assembly to solidify the preform and separate the device from the cavity plates. 117-. (canceled)18. A process for assembling a device including a first part and a second part , the first part being made of a first material and the second part being made of a second material , the device additionally including a third part made of a third material that acts as an intermediate part enabling the assembling , the process comprising:providing a preform made from the third material, the third material being an at least partially amorphous metal material capable of increasing its volume under temperature and/or pressure conditions;providing the first and second parts and placing them with the preform between two cavity plates having a negative shape of a final device;heating the assembly to a temperature between the glass transition temperature and the crystallization temperature of the preform to enable, at latest during the heating, the preform to be in a form of an at least partially amorphous metal foam and to enable an expansion of the preform to fill the negative shape of the device and form the third part;cooling the assembly to solidify the ...

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Номер записи: 76
27-06-2019 дата публикации

PROCESS FOR PRODUCING A BALANCE WHEEL FOR A TIMEPIECE

Номер: US20190196408A1
Автор: CORSON Donald William, DI DOMENICO Gianni, GUEISSAZ Francois, HAEMMERLI Alexandre, HELFER Jean-Luc, HINAUX Baptiste, Martin Jean-Claude, PARATTE Lionel, TOMBEZ Lionel, WILLEMIN Michel, WINKLER Pascal, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A process for producing a metal alloy balance wheel by molding, the process including the following steps: a) making a mold in the negative shape of the balance wheel, b) getting hold of a metal alloy that has a thermal expansion coefficient of less than 25 ppm/° C. and is able to be in an at least partly amorphous state when it is heated to a temperature between its glass transition temperature and its crystallization temperature, c) putting the metal alloy into the mold, the metal alloy being heated to a temperature between its glass transition temperature and its crystallization temperature so as to be hot-molded and to form a balance wheel, d) cooling the metal alloy to obtain a balance wheel made of the metal alloy, e) releasing the balance wheel obtained in step d) from its mold. 1. A process for producing a balance wheel for a timepiece comprising a serge , a hub and at least one arm connecting the hub to said serge , the serge , the hub and the arm being made of a metal alloy , said process comprising the following steps:a) making a mold in the negative shape of the balance wheel;b) getting hold of a metal alloy that has a thermal expansion coefficient of less than 25 ppm/° C. and is able to be in an at least partly amorphous state when it is heated to a temperature between its glass transition temperature and its crystallization temperature;c) putting the metal alloy into the mold, said metal alloy being heated to a temperature between its glass transition temperature and its crystallization temperature so as to be hot molded and to form a balance wheel;d) cooling said metal alloy to obtain a balance wheel made of said metal alloy: ande) releasing the balance wheel obtained in step d) from its mold.2. The process according to claim 1 , comprising a step to over-mold first inertia adjusting components in the serge claim 1 , said first inertia adjusting components being made of a first material having a density that is greater than the density of said metal ...

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Номер записи: 77
02-10-2014 дата публикации

Filling composition comprising hydrolyzed whole grain

Номер: US20140295025A1
Автор: Anne-Sophie Wavreille, Christelle Schaffer-Lequart, Olivier Yves Roger, Yves Bouvet
Принадлежит: Nestec SA

The present invention relates to a filling composition comprising a fat content above 20% by weight of the filling composition, a hydrolyzed whole grain composition; and an alpha-amylase or fragment thereof, which alpha-amylase or fragment thereof shows no hydrolytic activity towards dietary fibres when in the active state.

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Номер записи: 78
06-08-2015 дата публикации

NITROGEN-CONTAINING HETEROCYCLIC COMPOUNDS FOR PLANT DISEASE CONTROL

Номер: US20150216172A1
Автор: BRUNET Stephane, Coqueron Pierre-Yves, DITTGEN JAN, ES-SAYED Mazen, Feucht Dieter, FRENZEL Thomas, GATZWEILER ELMAR, Grosjean-Cournoyer Marie-Claire, HAAF Klaus Bernhard, HÄEUSER-HAHN ISOLDE, Heinemann Ines, HILLS Martin, KEHNE Heinz, LACHAISE Helene, Rinolfi Philippe, ROSINGER CHRISTOPHER HUGH, SCHMIDT Jan Peter, SCHMITT Monika H., TUCH Arounarith, VIDAL Jacky, Willms Lothar
Принадлежит:

The present invention relates to novel isoxazoline carboxamide derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials. 2. Quinoline-isoxazoline derivative of formula (I) according to claim 1 , wherein{'sup': 1', '2', '1', '2, 'sub': 1', '8', '1', '8', '1', '8', '3', '7, 'Rand Rindependently of one another represent hydrogen; halogen; substituted or non-substituted C-C-alkyl; C-C-haloalkyl; substituted or non-substituted C-C-alkoxy; or Rand Rcan form together with the carbon atom to which they are attached a substituted or non-substituted C-C-cycloalkyl;'}{'sup': '3', 'sub': 1', '8', '1', '8', '2', '8', '2', '8', '2', '8', '2', '8', '1', '8', '3', '7', '1', '8', '1', '8', '1', '8', '1', '8, 'Rrepresents hydrogen; substituted or non-substituted C-C-alkyl; C-C-haloalkyl; substituted or non-substituted C-C-alkenyl; C-C-haloalkenyl; substituted or non-substituted C-C-alkynyl; C-C-haloalkynyl; cyano; halogen; substituted or non-substituted C-C-alkoxy; substituted or non-substituted C-C-cycloalkyl; substituted or non-substituted C-C-alkylsulfanyl; substituted or non-substituted tri(C-C)alkylsilyl-C-C-alkyl; substituted or non-substituted C-C-alkoxycarbonyl; substituted or non-substituted aryl; or'}{'sup': 3', '1', '2, 'sub': 3', '7', '3', '7, 'Rtogether with Ror Rtogether with the carbon atoms to which they are attached can form a substituted or non-substituted C-Ccycloalkyl; C-C-halocycloalkyl; or a substituted or non-substituted saturated 5, 6 or 7 membered heterocycle;'}Y represents an oxygen or sulfur atom;{'sup': 1', '2', '3', 'a', 'a, 'sub': 1', '8', '1', '8', '1', '8', '2', '8', '2', '8', '2', '8', '2', '8', '3', '7', '1', '8', '1', '8', '1', '8', '1', '8', '1', '8', '1', '8', '1', '8', '2', '8, 'claim-text': wherein', {'sup': 'a', 'sub': 1', '8', '1', '8', '1', ' ...

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Номер записи: 79
25-06-2020 дата публикации

BEARING, PARTICULARLY A SHOCK ABSORBER, AND ROTARY WHEEL SET OF A TIMEPIECE MOVEMENT

Номер: US20200201259A1
Автор: Born Jean-Jacques, Lechot Dominique, Vincent Christophe, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A bearing for an arbor or staff of a rotary wheel set of a timepiece movement, the bearing including a bearing block provided with a housing and an endstone arranged inside the housing, the endstone having a main body provided with a cavity configured to receive a pivot of the arbor of the rotary wheel set, the pivot having the shape of a first cone having a first solid angle, the apex of the first cone being rounded with a predefined first radius of curvature in a range from 0.2 μm to 50 μm, the cavity having a second cone shape with a second solid angle, greater than the first solid angle, so that the pivot can rotate in the cavity, the apex of the second cone being rounded and having a predefined second radius of curvature. The second radius of curvature is smaller than the first radius of curvature. 1161820131422142217201617302631362928323136173028. A bearing , particularly a shock absorber , for an arbor or staff () of a rotary wheel set of a timepiece movement , for example a balance staff , the bearing ( , ) comprising a bearing block () provided with a housing () and an endstone () arranged inside the housing () , the endstone () comprising a main body provided with a cavity configured to receive a pivot ( , ) of the arbor () of the rotary wheel set , the pivot ( , ) having the shape of a first cone () having a first solid angle ( , ) , the apex () of the first cone being rounded with a predefined first radius of curvature comprised in a range from 0.2 μm to 50 μm , the cavity having the shape of a second cone () having a second solid angle () greater than the first solid angle ( , ) , such that the pivot ( , ) can rotate in the cavity , the apex of the second cone () being rounded and having a predefined second radius of curvature , characterized in that the second radius of curvature is smaller than the first radius of curvature.2. The bearing according to claim 1 , characterized in that the second radius of curvature is less than 40 μm.3. The bearing ...

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Номер записи: 80
11-07-2019 дата публикации

METHOD OF FABRICATING AN EMBOSSED DECORATION PROVIDED WITH AN ATTACHMENT

Номер: US20190210402A1
Автор: Vuille Pierry, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A method of fabricating a decoration formed of an embossed envelope the internal surface of which includes at least one attachment adapted for fixing the decoration. 1. A method of fabricating a decoration provided with at least one attachment comprising the following steps:a) forming an envelope of material the external surface of which forms the visible embossed part of the decoration;b) forming said at least one attachment;c) fastening said at least one attachment directly against the internal surface of the envelope of the decoration formed during step a) before possibly filling the volume of the cavity defined by the envelope.2. The method according to claim 1 , wherein step a) includes the following phases:a1) forming an imprint of said decoration in a substrate;a2) covering said imprint with a layer of material.3. The method according to claim 1 , wherein step a) further includes the following final phase:a3) removing the substrate in order to obtain an envelope of material the external surface of which forms the visible embossed part of said decoration.4. The method according to claim 1 , wherein step a) includes the following phases:a4) obtaining a sheet of material;a5) deforming the sheet of material in order to form an envelope of material.5. The method according to claim 1 , wherein step a) further includes the following final phase:a6) removing said envelope from the rest of the sheet in order to obtain an envelope the external surface of which forms the visible embossed part of said decoration.6. The method according to claim 1 , wherein step a) includes the following phases:a7) forming a mould for said decoration;a8) covering the mould with material in order to form an envelope of material.7. The method according to claim 1 , wherein step a) further includes the following final phase:a9) removing the mould in order to obtain an envelope the external surface of which forms the visible embossed part of said decoration.8. The method according to claim 1 ...

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Номер записи: 81
11-07-2019 дата публикации

NOVEL TRIAZOLE DERIVATIVES

Номер: US20190211002A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Genix Pierre, Hoffmann Sebastian, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, WITTROCK Sven
Принадлежит:

The present invention relates to novel triazole derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 11. Composition according to comprising at least one further active ingredient selected from the group of insecticides claim 10 , attractants claim 10 , sterilants claim 10 , bactericides claim 10 , acaricides claim 10 , nematicides claim 10 , fungicides claim 10 , growth regulators claim 10 , herbicides claim 10 , fertilizers claim 10 , safeners and semiochemicals. The present invention relates to novel triazole derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators.It is already known that particular phenoxy-phenyl-substituted triazole derivatives can be used in crop protection as fungicides (e.g. EP-A 0 065 485; EP-A 0 275 955; J. Agric. Food Chem. 2009, 57, 4854-4860; CN-A 101225074; DE-A 40 03 180; EP-A 0 113 640; EP-A 0 470 466; U.S. Pat. No. 4,949,720; EP-A 0 126 430; DE-A 38 01 233; WO-A 2013/007767; WO-A 2013/010862; WO-A 2013/010885; WO-A 2013/010894; WO-A 2013/024075; WO-A 2013/024076; WO-A 2013/024077; WO-A 2013/024080; WO-A 2013/024081; WO-A 2013/024082; WO-A 2013/024083). It is also known that particular phenoxy-phenyl-substituted triazolinethione derivatives (e.g. WO-A 2010/146114) and particular phenoxy-hetaryl-substituted triazole and triazolinethione derivatives (e.g. WO-A 2010/146116) can be used in crop protection as fungicides. Moreover, EP-A 0 296 518 discloses the use of particular hetaryloxy-phenyl-substituted triazole derivatives as fungicides.Since the ecological and ...

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Номер записи: 82
18-07-2019 дата публикации

NOVEL 5-SUBSTITUTED IMIDAZOLE DERIVATIVES

Номер: US20190218188A1
Автор: Bernier David, Coqueron Pierre-Yves, Genix Pierre, MILLER Ricarda, NAUD Sebastien, WITTROCK Sven
Принадлежит:

The present invention relates to novel 5-substituted imidazolylmethyl derivatives, to processes for preparing these compounds, to compositions and mixtures comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 5. Imidazole derivative of formula (I) and/or a salt and/or N-oxide thereof according to claim 1 , wherein Ris hydrogen.6. Imidazole derivative of formula (I) and/or a salt and/or N-oxide thereof according to claim 1 , wherein Ris cyano.7. Imidazole derivative of formula (I) and/or a salt and/or N-oxide thereof according to claim 1 , wherein Ris fluorine or chlorine.8. Method for controlling one or more harmful microorganisms in crop protection and/or in protection of materials claim 1 , comprising applying a compound of formula (I) and/or a salt and/or N-oxide thereof according to to the harmful microorganisms and/or a habitat thereof.9. Method for controlling one or more phytopathogenic harmful fungi in crop protection and/or in protection of materials claim 1 , comprising applying a compound of formula (I) and/or a salt and/or N-oxide thereof according to to the phytopathogenic harmful fungi and/or a habitat thereof.10. Composition for controlling one or more harmful microorganisms claim 1 , optionally for controlling one or more phytopathogenic harmful fungi claim 1 , comprising a content of at least one compound of formula (I) and/or a salt and/or N-oxide thereof according to claim 1 , in addition to at least one extender and/or surfactant.11. Composition according to claim 10 , comprising at least one further active ingredient selected from the group consisting of insecticides claim 10 , attractants claim 10 , sterilants claim 10 , bactericides claim 10 , acaricides claim 10 , nematicides claim 10 , fungicides claim 10 , growth regulators claim 10 , herbicides claim 10 , fertilizers claim 10 ...

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Номер записи: 83
19-08-2021 дата публикации

Track system

Номер: US20210253185A1
Автор: Andre Todd, Branislav NANAC, Cedric Alliguie, Genevieve Therrien, Jonathan Lapalme, Marc Nadeau, Nicolas Dubuc, Philippe Jaillet-Gosselin, Pierre-Yves PEPIN, Yves SAUVAGEAU
Принадлежит: Soucy International Inc

A track system for use with a vehicle includes an attachment assembly connectable to the chassis of the vehicle having a first pivot extending vertically and defining a yaw pivot axis of the track system, and a second pivot extending laterally and defining a pitch pivot axis of the track system. A frame assembly is disposed laterally outwardly from the attachment assembly and connected thereto. The frame assembly includes at least one wheel-bearing frame member. The track system further includes at least one actuator connected between the attachment assembly and the frame assembly for pivoting the frame assembly about the yaw pivot axis, a leading idler wheel assembly at least indirectly connected to the at least one wheel-bearing frame member, a trailing idler wheel assembly at least indirectly connected to the at least one wheel-bearing frame member, at least one support wheel assembly, and an endless track.

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Номер записи: 84
19-08-2021 дата публикации

Breakable polymers for the assisted recovery of hydrocarbons

Номер: US20210253941A1
Автор: Bruno Delfort, Isabelle Henaut, Veronique Bardin, Yves Benoit
Принадлежит: IFP Energies Nouvelles IFPEN

The invention relates to a process for enhanced hydrocarbon recovery in a subterranean formation, in particular enhanced crude oil recovery, using at least one water-soluble terpolymer in aqueous solution, said water-soluble terpolymer being a partially hydrolysed polyacrylamide of formula (I)wherein X is an alkali metal cation chosen from sodium, lithium or potassium, or an ammonium cation NH4+;the coefficients a, b and c being defined in the following way:aa+b+cis greater than or equal to 0.50, preferably between 0.5 and 0.8, limits included,ba+b+cis less than 0.50, preferably between 0.1 and 0.4, limits included,ca+b+cis between 0.01 and 0.20, preferably between 0.02 and 0.15, limits included, all of the ratios having a sum equal to 1.

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Номер записи: 85
30-10-2014 дата публикации

USE OF ARYL AND HETARYL CARBOXAMIDES AS ENDOPARASITICIDES

Номер: US20140323736A1
Автор: Coqueron Pierre-Yves, GÖRGENS Ulrich, Harder Achim, Hink Maike, LÜMMEN Peter, Schwarz Hans-Georg, Trautwein Axel, WELZ Claudia, Willms Lothar
Принадлежит:

The present application relates to known and novel aryl- and hetarylcarboxamides of the formula (I) 2. A compound as claimed inwhere{'sup': '1', 'X represents mono- or poly-M-substituted phenyl, 2-thienyl, 3-thienyl, 2-furanyl or 3-furanyl;'}{'sup': '1', 'Q represents mono- or poly-M-substituted 2-thienyl, 3-thienyl, 2-furanyl, 5-isothiazolyl, 3-pyridyl or 2-pyridyl;'}{'sup': 2', '2, 'sub': 1', '10', '2', '10', '2', '10', '1', '10', '2', '10', '2', '10', '1', '10', '2', '10', '3', '10', '3', '14', '1', '10, 'Y represents hydrogen or represents optionally mono- or poly-M-substituted (C-C)-alkyl, (C-C)-alkenyl, (C-C)-alkynyl, (C-C)-haloalkyl, (C-C)-haloalkenyl, (C-C)-haloalkynyl, (C-C)-alkoxy, (C-C)-alkenyloxy, (C-C)-alkynyloxy, (C-C)-cycloalkyl-(C-C)-alkyl or represents an optionally mono- or poly-M-substituted 3- to 14-membered cyclic group;'}{'sup': 1', '11', '12', '1, 'Lrepresents —C(R, R)—, oxygen or —N(R)—;'}{'sup': '1', 'sub': 1', '6', '1', '6', '1', '6', '1', '6', '1', '6', '1', '6', '1', '6', '1', '6', '1', '6', '1', '6', '3', '14', '3', '14', '6', '14', '3', '14', '3', '14', '6', '14, 'Mrepresents hydrogen, halogen, cyano, nitro, OH, (C-C)-alkyl, (C-C)-haloalkyl, (C-C)-alkoxy, (C-C)-haloalkoxy, (C-C)-alkylthio, (C-C)-haloalkylthio, (C-C)-alkylsulfonyl, (C-C)-haloalkylsulfonyl, (C-C)-alkylsulfanyl, (C-C)-haloalkylsulfanyl, (C-C)-cycloalkyl-O—, (C-C)-cycloalkenyl-O—, (C-C)-aryl-O—, halogenated (C-C)-cycloalkyl-O—, halogenated (C-C)-cycloalkenyl-O—, halogenated (C-C)-aryl-O—;'}{'sup': 1', '2', '2, 'sub': 1', '4', '2', '4', '2', '4', '1', '4', '2', '4', '2', '4', '3', '4', '1', '10', '3', '8', '3', '8, 'Rrepresents hydrogen or optionally mono- or poly-M-substituted (C-C)-alkyl, (C-C)-alkenyl, (C-C)-alkynyl, (C-C)-haloalkyl, (C-C)-haloalkenyl, (C-C)-haloalkynyl, (C-C)-cycloalkyl-(C-C)-alkyl or represents optionally mono- or poly-M-substituted (C-C)-cycloalkyl or halogenated (C-C)-cycloalkyl;'}{'sup': 11', '12', '2, 'sub': 1', '6', '1', '6', '1', '6', '3', '6', '1 ...

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Номер записи: 86
23-08-2018 дата публикации

TRIAZOLE DERIVATIVES, INTERMEDIATES THEREOF AND THEIR USE AS FUNGICIDES

Номер: US20180235223A1
Автор: Bernier David, BRUNET Stephane, Coqueron Pierre-Yves, Dahmen Peter, GEIST Julie, Genix Pierre, Hoffmann Sebastian, KENNEL Philippe, Meissner Ruth, MILLER Ricarda, NAUD Sebastien, SUDAU Alexander, Vors Jean-Pierre, Wachendorff-Neumann Ulrike, WITTROCK Sven
Принадлежит:

The present invention relates to novel triazole derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators. 2. Triazole derivative of formula (I) according to claim 1 , wherein{'sup': 4', '6, 'sub': 1', '4', '1', '4', '1', '4', '1', '4, 'Rrepresents halogen, CN, nitro, C-C-alkyl, C-C-halogenalkyl, C-C-alkoxy, C-C-halogenalkoxy or pentafluoro-λ-sulfanyl;'}and/or{'sub': 1', '2, 'R represents hydrogen, C-C-halogenalkyl or halogen.'}5. Triazole derivative of formula (I) according to claim 1 , wherein{'sub': '1', 'R represents hydrogen, C-halogenalkyl, F or Cl;'}n is 0;and/or a salt or N-oxide thereof.7. Method for controlling one or more harmful microorganisms in crop protection and in the protection of materials claim 1 , comprising applying a compound according to to the harmful microorganisms and/or a habitat thereof.8. Method for controlling phytopathogenic harmful fungi in crop protection and in the protection of materials claim 16 , comprising applying a compound according to to the phytopathogenic harmful fungi and/or a habitat thereof.9. Composition for controlling one or more harmful microorganisms claim 1 , optionally for controlling phytopathogenic harmful fungi claim 1 , comprising applying a content of at least one compound of formula (I) according to claim 1 , in addition to one or more extenders and/or surfactants.10. Composition according to comprising at least one further active ingredient selected from the group of the insecticides claim 9 , attractants claim 9 , sterilants claim 9 , bactericides claim 9 , acaricides claim 9 , nematicides claim 9 , fungicides claim 9 , growth regulators claim 9 , herbicides claim 9 , fertilizers claim 9 , safeners and semiochemicals.11. A product comprising one or more compounds according ...

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Номер записи: 87
17-09-2015 дата публикации

PESTICIDE COMPOSITION COMPRISING A TETRAZOLYLOXIME DERIVATIVE AND A FUNGICIDE OR AN INSECTICIDE ACTIVE SUBSTANCE

Номер: US20150257387A1
Автор: Coqueron Pierre-Yves, Grosjean-Cournoyer Marie-Claire, Hutin Pierre, Spica Gilbert, VOERSTE Arnd, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to a pesticide composition intended for protecting plants, crops or seeds against fungal diseases or insect damages, and the corresponding methods of protection by application of the said composition. More precisely, the subject of the present invention is a pesticide composition based on a tetrazolyloxime derivative and a fungicide or an insecticide active substance or compound. 6. A composition according to or wherein the substitution position of X in the tetrazolyloxime derivative of formula (I) is not specifically limited and X represents a hydrogen atom , a halogen atom , an alkyl group , an alkoxy group , a cyano group , a methanesulfonyl group , a nitro group , a trifluoromethyl group or an aryl group.7. A composition according to wherein X independently represents a chlorine atom claim 6 , a bromine atom claim 6 , an iodine atom claim 6 , a fluorine atom claim 6 , a methyl group claim 6 , an ethyl group claim 6 , an n-propyl group claim 6 , an isopropyl group claim 6 , an n-butyl group claim 6 , an isobutyl group claim 6 , a sec-butyl group claim 6 , a tert-butyl group claim 6 , a methoxy group claim 6 , an ethoxy group claim 6 , a propoxy group and an isopropoxy group claim 6 , a phenyl group claim 6 , a 4-methylphenyl group claim 6 , a 4-chlorophenyl group.8. A composition according to or wherein X represents a hydrogen atom.9. A composition according to or wherein (A1) claim 6 , (A2) claim 6 , Y independently represent an alkyl group.10. A composition according to or wherein (A1) claim 6 , (A2) claim 6 , Y independently represent a methyl group claim 6 , an ethyl group claim 6 , an n-propyl group or an isopropyl group is preferable.11. A composition according to or wherein R in the pyridyl group of formula (Het1) represents a hydrogen atom claim 6 , a chlorine atom claim 6 , a bromine atom claim 6 , an iodine atom or a fluorine atom.12. A composition according to or wherein Het represents either a pyridyl group of formula ( ...

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Номер записи: 88
08-08-2019 дата публикации

Humanized antibodies transmigrating the blood-brain barrier and uses thereof

Номер: US20190241653A1
Автор: Danica Stanimirovic, Kristin KEMMERICH, Traian Sulea, Yves Durocher
Принадлежит: NATIONAL RESEARCH COUNCIL OF CANADA

The present invention relates to antibodies and fragments thereof derived by humanization of an existing antibody, and methods of making them. The humanized antibodies of the present invention show enhanced binding to the brain endothelial antigen, improved transmigration across the blood-brain barrier, and increased thermal stability relative to the parent non-humanized antibody.

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Номер записи: 89
20-11-2014 дата публикации

FUNGICIDAL N-BICYCLOALKYL AND N-TRICYCLOALKYL PYRAZOLE-4-(THIO)CARBOXAMIDE DERIVATIVES

Номер: US20140343113A1
Автор: Benting Jurgen, BRUNET Stephane, Coqueron Pierre-Yves, Cristau Pierre, Dahmen Peter, Desbordes Philippe, Gary Stephanie, Greul Jorg, LACHAISE Helene, Rinolfi Philippe, Schmidt Jan-Peter, Vors Jean-Pierre, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to fungicidal N-bicycloalkyl and N-tricycloalkyl pyrazole-4-(thio)carboxamide derivatives of formula (I), wherein T represents 0 or S; n represents 0 or 1; and B represents where the bond marked by * is attached to the (CZ2Z3)n-N amide moiety, their process of preparation and intermediate compounds for their preparation, their use as fungicides, particularly in the form of fungicidal compositions and methods for the control of phytopathogenic fungi of plants using these compounds or their compositions. 2. A compound according to wherein Rrepresents a substituted or non-substituted C-C-alkyl claim 1 , C-C-halogenoalkyl comprising up to 9 halogen atoms that can be the same or different claim 1 , or substituted or non-substituted C-C-alkoxy; Rrepresents a hydrogen atom claim 1 , or a halogen atom; and Rrepresents a substituted or non-substituted C-C-alkyl.3. A compound according to wherein Rrepresents C-C-alkyl or C-C-halogenoalkyl comprising up to 3 halogen atoms that can be the same or different; Rrepresents a hydrogen atom claim 1 , a chlorine atom claim 1 , or a fluorine atom; and Rrepresents a methyl.4. A compound according to wherein T represents O.5. A compound according to wherein B represents B; Qrepresents a direct bond; u is equal to 3 or 4; and m+p is equal to 2 or 3.6. A compound according to wherein B represents a substituted or non-substituted decahydronaphthalenyl group claim 1 , a substituted or non-substituted octahydro-1H-indenyl group claim 1 , or a substituted or non-substituted octahydropentalenyl group.7. A compound according to wherein B represents B; Qrepresents a methylene group claim 1 , or an oxygen atom; t is equal to 1; and u is equal to 1 or 2.8. A compound according to wherein B represents a substituted or non-substituted bicyclo[2.2.1]heptyl group claim 1 , a substituted or non-substituted bicyclo[2.2.1]hept-2-enyl group claim 1 , a substituted or non-substituted 7-oxabicyclo[2.2.1]heptyl group claim 1 , a ...

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Номер записи: 90
15-09-2016 дата публикации

ACTIVE COMPOUND COMBINATIONS COMPRISING A (THIO)CARBOXAMIDE DERIVATIVE AND A FUNGICIDAL COMPOUND

Номер: US20160262393A1
Автор: Coqueron Pierre-Yves, Cristau Pierre, Dahmen Peter, Desbordes Philippe, TSUCHIYA Tomoki, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to active compound combinations, in particular within a fungicide composition, which comprises (A) a N-cyclopropyl-N-[substituted-benzyl]-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide or thiocarboxamide derivative and a further fungicidally active compound (B). Moreover, the invention relates to a method for curatively or preventively or eradicatively controlling the phytopathogenic fungi of plants or crops, to the use of a combination according to the invention for the treatment of seed, to a method for protecting a seed and not at least to the treated seed. 2. An active compound combination according to wherein the compound (A) of formula (I) is selected from the group consisting of:N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide,N-cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide,N-(2-tert-butylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide,N-(5-chloro-2-ethylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide,N-(5-chloro-2-isopropylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide,N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-fluorobenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide,N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(5-fluoro-2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide,N-cyclopropyl-N-(2-cyclopropyl-5-fluorobenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide,N-(2-cyclopentyl-5-fluorobenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide,N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-fluoro-6-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide,N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-methylbenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide,N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropyl-5-methylbenzyl)-1-methyl-1H-pyrazole-4- ...

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Номер записи: 91
24-09-2015 дата публикации

METHOD OF MANUFACTURING A WATCH PLATE

Номер: US20150266089A1
Автор: Bazin Jean-Luc, Bourban Stewes, BREBNER-GRUPP Nathalie, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A method of making a timepiece plate including the steps of: taking (A, A) the material forming the plate including at least one metallic element; forming (B, B) the plate; cooling (C) everything so as to obtain the timepiece plate in an at least partially amorphous state; and retrieving (D) the plate. 1. A method of making a timepiece plate , wherein it includes the following steps:a) taking the material forming a plate including at least one metallic element;b) forming said plate;c) cooling the material so as to obtain said timepiece plate in an at least partially amorphous state; andd) retrieving said plate.e) inserting at least one complementary member in the plate or the bridge by hot setting.2. A method of making a timepiece bridge , wherein it includes the following steps:a) taking the material forming a bridge including at least one metallic element;b) forming said bridge;c) cooling the material so as to obtain said timepiece bridge in an at least partially amorphous state; andd) retrieving said bridge.e) inserting at least one complementary member in the plate or the bridge by hot setting.3. The method according to claim 1 , wherein step b) consists in making said plate by pouring said material into a mould claim 1 , and in that step c) consists in cooling everything so as to give said element an amorphous structure.4. The method according to claim 2 , wherein step b) consists in making said bridge by pouring said material into a mould claim 2 , and in that step c) consists in cooling everything so as to give said element an amorphous structure.5. The method according to claim 3 , wherein the cast moulding is injection moulding.6. The method according to claim 4 , wherein the cast moulding is injection moulding.7. The method according to claim 3 , wherein the mould includes inserts.8. The method according to claim 4 , wherein the mould includes inserts.9. The method according to claim 7 , wherein each insert is intended to make a shape in the plate.10. The ...

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Номер записи: 92
15-09-2016 дата публикации

5-HALOGENOPYRAZOLE INDANYL CARBOXAMIDES

Номер: US20160264528A1
Автор: Bernier David, BRUNET Stephane, Carles Lionel, Coqueron Pierre-Yves, Dubost Christophe, ES-SAYED Mazen, Genix Pierre, LACHAISE Helene, Maechling Simon, Vors Jean-Pierre, Wachendorff-Neumann Ulrike, WASNAIRE Pierre
Принадлежит:

The present invention relates to novel 1-methyl-3-dihalogenomethyl-5-halogenopyrazole(thio)indanyl cathoxamides, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful micmorgarnsms in crop protection and in the protection of materials. This application is a divisional application of U.S. application Ser. No. 14/399,539 (filed Nov. 7, 2014), which is a 371 National Stage of PCT/EP2013/059410 (filed May 6, 2013), which claims priority to EP 12167280.2 (filed May 9, 2012) and to EP 12197381.2 (filed Dec. 16, 2012), the contents of each of which are incorporated herein by reference in their entirety.1. Field of the InventionThe present invention relates to novel 1-methyl-3-dihalogenomethyl-5-halogenopyrazole(thio)indanyl carboxamides, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials.It is already known that certain pyrazole indanyl carboxamides have fungicidal properties (e.g. WO 92/12970, EP-A 0 199 822, EP-A 0 276 177, JP-A 62-096472, JP-A 05-310512, JP-A 01-313402, WO 02/059086, WO 2004/103975 and 1995, 60, 1626-1631).Since the ecological and economic demands made on modern active ingredients, for example fungicides, are increasing constantly, for example with respect to activity spectrum, toxicity, selectivity, application rate, formation of residues and favourable manufacture, and there can also be problems, for example, with resistances, there is a constant need to develop novel fungicidal compositions which have advantages over the known compositions at least in some areas.This invention now provides novel 1-methyl-3-dihalogenomethyl-5-halogenopyrazole(thio)indanyl carboxamides of the formula (I)in whichThis invention now provides novel 1-methyl ...

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Номер записи: 93
27-11-2014 дата публикации

FUNGICIDAL 4-SUBSTITUTED-3--1,2,4-OXADIZOL-5(4H)-ONE DERIVATIVES

Номер: US20140349848A1
Автор: BRAUN Christoph, BRUNET Stephane, Coqueron Pierre-Yves, Dubost Christophe, LACHAISE Helene, Maechling Simon, Rebstock Anne-Sophie, Rinolfi Philippe, Sawada Haruko, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention provides fungicidal 4-substituted-3-{phenyl[(heterocyclylmethoxy)imino]methyl}-1,2,4-oxadiazol-5(4H)-one derivatives of formula (I) 2. A compound according to wherein Xrepresents a hydrogen atom claim 1 , substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl or a substituted or non-substituted C-C-alkenyl.3. A compound according to wherein Xrepresents a hydrogen atom claim 2 , a methyl group claim 2 , an ethyl group claim 2 , a n-propyl group claim 2 , an isopropyl group or a cyclopropyl group.4. A compound according to wherein A represents A.5. A compound according to wherein Zrepresents a hydrogen atom claim 1 , a halogen atom claim 1 , a nitro group claim 1 , an amino group claim 1 , an hydroxyamino group substituted or non-substituted C-C-alkoxyamino group claim 1 , substituted or non-substituted C-C-alkylamino claim 1 , substituted or non-substituted C-C-cycloalkylamino claim 1 , substituted or non-substituted C-C-cycloalkenylamino claim 1 , substituted or non-substituted C-C-fused bicycloalkylamino claim 1 , substituted or non-substituted C-C-fused bicycloalkenylamino claim 1 , substituted or non-substituted di-C-C-alkylamino claim 1 , substituted or non-substituted phenylamino claim 1 , substituted or non-substituted heterocyclylamino claim 1 , or a group of formula QC(═U)NR—6. A compound according to wherein Zrepresents an amino group claim 5 , or a group of formula QC(═U)NR.7. A compound according to wherein U represents an oxygen atom8. A compound according to wherein Rrepresents a hydrogen atom claim 1 , a hydroxy group claim 1 , substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl claim 1 , substituted or non-substituted C-C-alkoxy.9. A compound according to wherein Q represents a substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl claim 1 , substituted or non-substituted C-C-alkynyl claim 1 , ...

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Номер записи: 94
27-11-2014 дата публикации

FUNGICIDAL 3-[(PYRIDIN-2-YLMETHOXYIMINO)(PHENYL)METHYL]-2-SUBSTITUTED-1,2,4-OXADIAZOL-5(2H)-ONE DERIVATIVES

Номер: US20140350058A1
Автор: BRAUN Christoph, Coqueron Pierre-Yves, Dubost Christophe, LACHAISE Helene, Maechling Simon, Rebstock Anne-Sophie, Rinolfi Philippe, Sawada Haruko, Wachendorff-Neumann Ulrike
Принадлежит:

The present invention relates to 3-[(pyridin-2-ylmethoxyimino)(phenyl)methyl]-2-substituted-1,2,4-oxadiazol-5(2H)-one derivatives of formula (I), their process of preparation, their use as fungicide active agents, particularly in the form of fungicide compositions, and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions. 2. A compound according to wherein Xrepresents substituted or non-substituted C-C-alkyl claim 1 , substituted or non-substituted C-C-cycloalkyl or a substituted or non-substituted C-C-alkenyl.3. A compound according to wherein Xrepresents a methyl group claim 1 , an ethyl group claim 1 , a n-propyl group claim 1 , an isopropyl group or a cyclopropyl group.4. A compound according to wherein Zrepresents a hydrogen atom claim 1 , a halogen atom claim 1 , a nitro group claim 1 , an amino group claim 1 , an hydroxyamino group claim 1 , substituted or non-substituted C-C-alkoxyamino group claim 1 , substituted or non-substituted C-C-alkylamino claim 1 , substituted or non-substituted C-C-cycloalkylamino claim 1 , substituted or non-substituted C-C-cycloalkenylamino claim 1 , substituted or non-substituted C-C-fused bicycloalkylamino claim 1 , substituted or non-substituted C-C-fused bicycloalkenylamino claim 1 , substituted or non-substituted di-C-C-alkylamino claim 1 , substituted or non-substituted phenylamino claim 1 , substituted or non-substituted heterocyclylamino claim 1 , or a group of formula QC(═U)NR—.5. A compound according to wherein Zrepresents a hydrogen atom claim 1 , a halogen atom claim 1 , a nitro group claim 1 , an amino group claim 1 , substituted or non-substituted C-C-alkylamino claim 1 , substituted or non-substituted C-C-cycloalkylamino claim 1 , or a group of formula QC(═U)NR.6. A compound according to wherein U represents an oxygen atom.7. A compound according to wherein Rrepresents a hydrogen atom claim 1 , a hydroxy group claim 1 , substituted or non-substituted C-C-alkyl ...

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Номер записи: 95
11-12-2014 дата публикации

AMORPHOUS METAL CURRENT COLLECTOR

Номер: US20140363743A1
Автор: Marlot Doerr Agnes, Stalder Michael, Winkler Yves
Принадлежит: THE SWATCH GROUP RESEARCH AND DEVELOPMENT LTD.

The present invention concerns an electrochemical device comprising a cathode and an anode separated from each other by a separator, the battery further comprising two current collectors so that the anode and cathode are each arranged between the separator and a current collector, characterized in that at least one of the two current collectors is made of an at least partially amorphous material comprising at least one metallic element. 114-. (canceled)15. A cell comprising a cathode and an anode separated from each other by a separator , said electrochemical device further including an electrolyte and two current collectors so that the anode and the cathode are each arranged between the separator and a current collector , wherein the two current collectors is made of an at least partially amorphous material including at least one metallic element.16. The cell according to claim 15 , wherein the two collectors are made of a totally amorphous material.17. The cell according to claim 15 , wherein said material includes at least one of the elements found in the list comprising Ti claim 15 , Zr claim 15 , Ni claim 15 , Cu claim 15 , Fe claim 15 , Cr claim 15 , Mn claim 15 , V claim 15 , W claim 15 , Al.18. The cell according to claim 15 , wherein said material has a maximum resistivity of 10Ohm*m.19. The cell according to claim 15 , wherein said material has a maximum resistivity of 10Ohm*m.20. The cell according to claim 15 , wherein said material includes 47.5% weight percent copper claim 15 , 47.5% weight percent zirconium and 5% weight percent aluminium.21. The cell according to claim 15 , wherein the thickness of the current collectors is comprised between 1 μm and 50 μm.22. The cell according to claim 15 , wherein the thickness of the current collectors is comprised between 5 μm and 25 μm.23. The cell according to claim 15 , wherein the thickness of the current collectors is unequal.24. The cell according to claim 23 , wherein the edges of the current collectors ...

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Номер записи: 96
11-11-2021 дата публикации

Oilfield system

Номер: US20210348490A1
Автор: Alex Bird, Carlos Rocha, Christy Rubenstein, Emmanuel Coste, Jeffery Anderson, John MacDonald, Jonathan Wun Shiung Chong, Matthew Worthington, Nam Tuan Nguyen, Robb Wheatley, YING Wang, Yves-Marie Subervie
Принадлежит: SCHLUMBERGER TECHNOLOGY CORPORATION

A method can include receiving time series data acquired during equipment operations at a plurality of natural resource sites; detecting operational events using the time series data; ranking the operational events; associating each of the operational events with a corresponding operational action; and outputting at least a portion of the ranked operational events, each with its corresponding operational action.

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Номер записи: 97
29-08-2019 дата публикации

METHOD FOR MANUFACTURING AN AMORPHOUS METAL PART

Номер: US20190262896A1
Автор: CAROZZANI Tommy, DUBACH Alban, Winkler Yves
Принадлежит: The Swatch Group Research and Development Ltd

A method for manufacturing a micromechanical component made of a first material, the first material being a material that can become at least partially amorphous, the method including: a) providing a mold made of a second material, the mold including a cavity forming the negative of the micromechanical component; b) providing the first material and forming the first material in the cavity of the mold, the first material having undergone, at a latest at a time of the forming, treatment allowing the first material to become at least partially amorphous; c) separating the micromechanical component thus formed from the mold. 112-. (canceled)13. A method for manufacturing a component made of a first material , the first material being a metallic material that can become at least partially amorphous , the method comprising:a) providing a mold made of a second material, the mold comprising a cavity forming the negative of the component;b) providing the first material and forming the first material in the cavity of the mold, the first material having undergone, at a latest at a time of the forming, treatment allowing the first material to become at least partially amorphous;c) separating the component thus formed from the mold;{'sup': 2', '0.5, 'wherein the second material forming the mold has a thermal effusivity from 250 to 2500 J/K/m/s, and wherein the treatment allowing the first material to become at least partially amorphous comprises cooling, which is only accomplished owing to effusivity of the mold and only at a mold/gas interface.'}14. The method of manufacture as claimed in claim 13 , wherein c) dissolves the mold.15. The method of manufacture as claimed in claim 13 , wherein the first material is submitted to a temperature rise above its melting point claim 13 , allowing the first material to lose any crystalline structure locally claim 13 , the rise being followed by cooling to a temperature below its glass transition temperature allowing the first material to ...

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Номер записи: 98
08-10-2015 дата публикации

TIMEPIECE ASSORTMENT USING AN AMORPHOUS METAL ALLOY

Номер: US20150286188A1
Автор: CHARBON Christian, DUBOIS PHILIPPE, Mallet Daniel, Winkler Yves
Принадлежит: NIVAROX-FAR S.A.

The invention relates to a timepiece assortment including a timepiece component fixed to an arbor with the aid of a fixing element. According to the invention, the fixing element is made of at least partially amorphous metal alloy, is secured to the timepiece component by partial insertion and includes a hole into which the arbor is driven. 1. A method of assembling a timepiece assortment comprising the following steps:a) separately manufacturing a timepiece component and a fixing element, the fixing element being manufactured from an at least partially amorphous metal alloy;b) partially inserting at least one portion of the timepiece component into the thickness of the fixing element heated to between its vitreous transition temperature and its crystallisation temperature in order to form a timepiece component fixing element assembly;c) driving an arbor into a hole of the fixing element to form the timepiece assortment so as to leave a gap between timepiece component and the arbor.2. The method according to claim 1 , wherein the hole is formed in step a) claim 1 , in step b) or in step c).3. The method according to claim 1 , wherein between step b) and step c) claim 1 , the method also includes the following step:d) maintaining the timepiece component fixing element assembly above the vitreous transition temperature of the fixing element to make the fixing element more ductile.4. The method according to claim 1 , wherein step c) also comprises the following phases:c1) heating the arbor to above the vitreous transition temperature of the fixing element.c2) driving the arbor into the hole of the fixing element to raise the temperature of the contact surface of the fixing element above the vitreous transition temperature in order to locally soften the fixing element and decrease the stresses on the material of the timepiece component while maintaining good adherence.5. The method according to claim 1 , wherein the timepiece component is pressed against a shoulder of ...

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Номер записи: 99
29-08-2019 дата публикации

Device for measuring at least one electrical quantity of a current flowing through at least one electrical device

Номер: US20190265279A1
Автор: Albert Chansavang, Jean-Yves Amblard
Принадлежит: Schneider Electric Industries SAS

A system for measuring an electrical quantity of a current circulating in an electrical device mounted on a mounting support, including an electrical power supply device, the device for measuring the current circulating in the device, the device for tapping the voltage at the terminals of the device, and the device for measuring this voltage, device for processing the measurement information, and device for communicating the measurement information to a receiver. This system includes a first main module, including the power supply device, the current and voltage measurement device, the processing device and the communication device, and a second auxiliary module, including the voltage tapping device and electrical connection device connecting with the main module, this connection making it possible to supply voltage to the main module and to measure the voltage recorded by the auxiliary module, the second module including electrical coupling device for connecting to the terminals of the device to be measured, these device being adapted to the configuration of these terminals.

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Номер записи: 100