20-06-2013 дата публикации
Номер: US20130152788A1
A process for removing mercury from a gas or liquid phase, wherein the gas or liquid phase containing mercury is placed in contact with a composition comprising a precipitated metal sulfide. The precipitated metal sulfide may be made by the process of combining a metal source, sulfide source, and modifier to form the precipitated metal sulfide. The metal source may comprise iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, silver, or gold salts. The metal salt may be selected from metal nitrate, metal sulfate, metal phosphate, metal acetate, metal carbonate, metal hydroxide, metal ammonium carbonate, and metal hydroxycarbonate. The sulfide source is selected from hydrogen sulfide (HS), carbonyl sulfide (COS), salts of sulfide (S), salts of hydrosulfide (HS), and salts of polysulfide (S). The modifier may be selected from alumina, silica, aluminosilicate, clay, zeolites, carbon, cement, titania, zirconia. 1. A process for removing mercury from a gas phase , wherein a powdered composition comprising a precipitated metal sulfide is placed in contact with a gas phase.2. The process of claim 1 , wherein the precipitated metal sulfide comprises a metal selected from iron claim 1 , cobalt claim 1 , nickel claim 1 , copper claim 1 , zinc claim 1 , zirconium claim 1 , molybdenum claim 1 , silver claim 1 , and gold.3. The process of claim 1 , wherein the precipitated metal sulfide comprises copper sulfide.4. The process of claim 3 , wherein the precipitated copper sulfide is formed from a metal salt selected from copper nitrate claim 3 , copper sulfate claim 3 , copper phosphate claim 3 , copper acetate claim 3 , copper carbonate claim 3 , copper hydroxide claim 3 , copper ammonium carbonate claim 3 , and copper hydroxycarbonate.5. The process of claim 3 , wherein the composition is formed in the presence of a modifier claim 3 , wherein the modifier is selected from alumina claim 3 , silica claim 3 , aluminosilicate claim 3 , clay claim 3 , zeolites claim 3 , carbon ...
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