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Применить Всего найдено 20792. Отображено 100.
16-08-1998 дата публикации

УСТАНОВКА ХИМИЧЕСКОГО КОНДИЦИОНИРОВАНИЯ ДЫМОВЫХ ГАЗОВ

Номер: RU0000007349U1

Установка химического кондиционирования дымовых газов, содержащая источник смеси диоксида серы с воздухом, калорифер и по крайней мере двухступенчатый, каталитический конвектор, выход которого подключен к устройству ввода триоксида серы в дымовые газы, отличающаяся тем, что выход источника смеси диоксида серы с воздухом подведен через калорифер к входу первой ступени каталитического конвектора и соединен с входом его второй ступени. (19) RU (11) (13) 7 349 U1 (51) МПК B03C 3/01 (1995.01) C01B 17/00 (1995.01) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К СВИДЕТЕЛЬСТВУ (21), (22) Заявка: 97115356/20, 15.09.1997 (46) Опубликовано: 16.08.1998 (71) Заявитель(и): Электроэнергетическая ассоциация "Корпорация единый электроэнергетический комплекс", Московский энергетический институт U 1 7 3 4 9 R U (57) Формула полезной модели Установка химического кондиционирования дымовых газов, содержащая источник смеси диоксида серы с воздухом, калорифер и по крайней мере двухступенчатый, каталитический конвектор, выход которого подключен к устройству ввода триоксида серы в дымовые газы, отличающаяся тем, что выход источника смеси диоксида серы с воздухом подведен через калорифер к входу первой ступени каталитического конвектора и соединен с входом его второй ступени. Ñòðàíèöà: 1 U 1 (54) УСТАНОВКА ХИМИЧЕСКОГО КОНДИЦИОНИРОВАНИЯ ДЫМОВЫХ ГАЗОВ 7 3 4 9 (73) Патентообладатель(и): Электроэнергетическая ассоциация "Корпорация единый электроэнергетический комплекс", Московский энергетический институт R U (72) Автор(ы): Чернов С.Л., Микушевич Э.Э., Липочкин С.В., Водолазов А.В., Шанин М.П. U 1 U 1 7 3 4 9 7 3 4 9 R U R U Ñòðàíèöà: 2 RU 7 349 U1 RU 7 349 U1 RU 7 349 U1 RU 7 349 U1 RU 7 349 U1 RU 7 349 U1

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10-03-2001 дата публикации

УСТРОЙСТВО ДЛЯ ПОЛУЧЕНИЯ ЭЛЕМЕНТАРНОЙ СЕРЫ

Номер: RU0000017040U1

Устройство для получения элементарной серы, содержащее нагреватели газов, реактор с охлаждающими змеевиками и газораспределительной решеткой с насыпанным на нее слоем катализатора, серосборник с установленным в нем барботером, соединенным с реактором и с патрубками отвода жидкой серы с верхнего уровня барботажного слоя и очищенных от нее продуктов реакции, каплеуловителем и регулятором верхнего уровня барботажного слоя, узел ввода охлаждающей воды, размещенный на выходе из реактора, взаимодействующий с исполнительным механизмом, установленным на линии подвода охлаждающей воды, отличающееся тем, что на патрубке отвода жидкой серы с верхнего уровня барботажного слоя установлен датчик вязкости, выход которого соединен через регулятор вязкости с входом исполнительного механизма узла ввода охлаждающей воды. (19) RU (11) 17 040 (13) U1 (51) МПК C01B 17/04 (2000.01) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К СВИДЕТЕЛЬСТВУ (21), (22) Заявка: 2000126248/20, 19.10.2000 (24) Дата начала отсчета срока действия патента: 19.10.2000 (46) Опубликовано: 10.03.2001 (73) Патентообладатель(и): Акционерное общество "ТАТНЕФТЬ" 1 7 0 4 0 R U (57) Формула полезной модели Устройство для получения элементарной серы, содержащее нагреватели газов, реактор с охлаждающими змеевиками и газораспределительной решеткой с насыпанным на нее слоем катализатора, серосборник с установленным в нем барботером, соединенным с реактором и с патрубками отвода жидкой серы с верхнего уровня барботажного слоя и очищенных от нее продуктов реакции, каплеуловителем и регулятором верхнего уровня барботажного слоя, узел ввода охлаждающей воды, размещенный на выходе из реактора, взаимодействующий с исполнительным механизмом, установленным на линии подвода охлаждающей воды, отличающееся тем, что на патрубке отвода жидкой серы с верхнего уровня барботажного слоя установлен датчик вязкости, выход которого соединен через регулятор вязкости с входом исполнительного механизма узла ...

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20-04-2002 дата публикации

УСТАНОВКА ОЧИСТКИ СЕРЫ ОТ МЕХАНИЧЕСКИХ ПРИМЕСЕЙ

Номер: RU0000022661U1

Установка очистки серы от механических примесей, включающая устройство плавления комовой серы в виде обогреваемой емкости, устройство гравитационного отстоя расплава серы в виде обогреваемого отстойника непрерывного действия с переливом серы и сборник очищенного расплава серы, отличающаяся тем, что обогреваемая емкость снабжена вертикальными трубами для вывода расплава серы на установленную под ними наклонную обогреваемую направляющую пластину, под которой размещено устройство гравитационного отстоя расплава серы, состоящее по меньшей мере из трех горизонтальных отстойников, снабженных перфорированными отбойными пластинами, установленными перед переливами серы, и расположенных один под другим с взаимным смещением в горизонтальной плоскости. (19) RU (11) 22 661 (13) U1 (51) МПК C01B 17/02 (2000.01) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К СВИДЕТЕЛЬСТВУ Адрес для переписки: 460000, г.Оренбург, ул. Пушкинская, 20, ВолгоУралНИПИгаз, зав.пат.отделом, пат.пов. Б.А.Дронову (72) Автор(ы): Вязиков В.М., Калименева О.А., Переселкин Н.В. (24) Дата начала отсчета срока действия патента: 22.11.2001 2 2 6 6 1 R U (57) Формула полезной модели Установка очистки серы от механических примесей, включающая устройство плавления комовой серы в виде обогреваемой емкости, устройство гравитационного отстоя расплава серы в виде обогреваемого отстойника непрерывного действия с переливом серы и сборник очищенного расплава серы, отличающаяся тем, что обогреваемая емкость снабжена вертикальными трубами для вывода расплава серы на установленную под ними наклонную обогреваемую направляющую пластину, под которой размещено устройство гравитационного отстоя расплава серы, состоящее по меньшей мере из трех горизонтальных отстойников, снабженных перфорированными отбойными пластинами, установленными перед переливами серы, и расположенных один под другим с взаимным смещением в горизонтальной плоскости. Ñòðàíèöà: 1 U 1 U 1 (54) УСТАНОВКА ОЧИСТКИ СЕРЫ ОТ ...

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27-04-2003 дата публикации

Установка по переработке серы для использования ее в качестве вулканизирующего агента в шинной промышленности

Номер: RU0000029052U1
Автор: Хажиев Р.С.

Установка по переработке серы для использования ее в качестве вулканизирующего агента в шинной промышленности, отличающаяся тем, что она содержит узел чешуирования жидкой серы, который включает вальцовый кристаллизатор и систему охлаждения воды, узел размола, устройство для подачи дозированной антистатической присадки и узел затаривания. (19) RU (11) 29 052 (13) U1 (51) МПК C01B 17/00 (2000.01) B01D 9/02 (2000.01) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К СВИДЕТЕЛЬСТВУ (21), (22) Заявка: 2002130627/20 , 18.11.2002 (24) Дата начала отсчета срока действия патента: 18.11.2002 (46) Опубликовано: 27.04.2003 (72) Автор(ы): Хажиев Р.С. (73) Патентообладатель(и): Хажиев Ринат Сулейманович U 1 2 9 0 5 2 R U Ñòðàíèöà: 1 U 1 (57) Формула полезной модели Установка по переработке серы для использования ее в качестве вулканизирующего агента в шинной промышленности, отличающаяся тем, что она содержит узел чешуирования жидкой серы, который включает вальцовый кристаллизатор и систему охлаждения воды, узел размола, устройство для подачи дозированной антистатической присадки и узел затаривания. 2 9 0 5 2 (54) Установка по переработке серы для использования ее в качестве вулканизирующего агента в шинной промышленности R U Адрес для переписки: 450000, г.Уфа-центр, ул. К. Маркса, 12, УГАТУ, ОИС, В.П. Ефремовой (71) Заявитель(и): Хажиев Ринат Сулейманович U 1 U 1 2 9 0 5 2 2 9 0 5 2 R U R U Ñòðàíèöà: 2 RU 29 052 U1 RU 29 052 U1 RU 29 052 U1 RU 29 052 U1

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27-11-2003 дата публикации

Установка для получения элементарной серы

Номер: RU0000034156U1

Установка для получения элементарной серы, включающая входной сепаратор, печь-реактор термической ступени, конденсаторы-коагуляторы серы, два из которых соединены через печи подогрева с каталитическими конверторами первой и второй ступеней, отличающаяся тем, что она дополнительно содержит фильтр-сепаратор, включенный последовательно с входным сепаратором. (19) RU (11) 34 156 (13) U1 (51) МПК C01B 17/04 (2000.01) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21), (22) Заявка: 2003117189/20 , 11.06.2003 (24) Дата начала отсчета срока действия патента: 11.06.2003 (46) Опубликовано: 27.11.2003 R U 3 4 1 5 6 Формула полезной модели Установка для получения элементарной серы, включающая входной сепаратор, печь-реактор термической ступени, конденсаторы-коагуляторы серы, два из которых соединены через печи подогрева с каталитическими конверторами первой и второй ступеней, отличающаяся тем, что она дополнительно содержит фильтр-сепаратор, включенный последовательно с входным сепаратором. Ñòðàíèöà: 1 U 1 U 1 (54) Установка для получения элементарной серы 3 4 1 5 6 (73) Патентообладатель(и): Общество с ограниченной ответственностью "Оренбурггазпром" R U Адрес для переписки: 460000, г.Оренбург, ул. Пушкинская, 20, ООО "ВолгоУралНИПИгаз", зав. пат. отд., Б.А. Дронову (72) Автор(ы): Гафаров Н.А., Молчанова З.В., Трынов А.М., Чехонин М.Ф., Морозов М.М., Савин Ю.М., Молчанов С.А., Золотовский Б.П., Гульбин А.В. U 1 U 1 3 4 1 5 6 3 4 1 5 6 R U R U Ñòðàíèöà: 2 RU 34 156 U1 RU 34 156 U1 RU 34 156 U1 RU 34 156 U1

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27-11-2004 дата публикации

УСТАНОВКА СЕРООЧИСТКИ ПРИРОДНОГО ГАЗА

Номер: RU0000042228U1

1. Установка сероочистки природного газа, включающая блок окисления, блок насыщения воды кислородом, инжектор, на выходе которого установлен фильтр с фильтрующей поверхностью, блок флотации, на выходе которого установлен блок уплотнения элементарной серы, соединенный с блоком плавления, накопитель жидкости, отличающаяся тем, что в него введен подогреватель газа регенерации со змеевиками высокого и низкого давлений, фильтрующая поверхность фильтра имеет слой активированного угля и выполнена с возможностью вращения и регенерации, а накопитель жидкости выполнен с возможностью трехфазного разделения на воду, газовый конденсат и дегазированный из жидкости газ, при этом вход змеевика высокого давления соединен через компрессор с выходом фильтра очищенного газа, а его выход – со входом фильтра для газа обратной продувки, вход змеевика низкого давления через регулятор давления также соединен с выходом фильтра очищенного газа, а его выход – со входом флотатора для подачи флотирующего агента, при этом вход жидкости во флотатор соединен с выходом фильтра для суспензии. 2. Установка по п.1, отличающаяся тем, что в него введены отводчики жидкости, установленные на выходе блоков насыщения воды кислородом, флотации, а также фильтра и накопителя жидкости. 3. Установка по п.1, отличающаяся тем, что в него введен охладитель газа с эжекторным скруббером и охладитель воды, включенный между блоком насыщения воды кислородом и блоком трехфазного разделения, причем вход скруббера соединен с выходом дымовых газов подогревателя. 4. Установка по п.1, отличающаяся тем, что в нем блок уплотнения элементарной серы выполнен в виде шнекового транспортера. 5. Установка по п.1, отличающаяся тем, что блок плавления выполнен в виде жаротрубного газового подогревателя. 6. Установка по п.1, отличающаяся тем, что газовый выход флотатора соединен с горелками подогревателя газа и блока плавления элементарной серы. 7. Установка по п.5, отличающаяся тем, что газовый выход накопителя жидкости соединен с ...

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10-11-2005 дата публикации

ХЕМОСОРБЦИОННО-КАТАЛИТИЧЕСКАЯ СИСТЕМА ДЛЯ ОЧИСТКИ БИОГАЗА

Номер: RU0000048810U1
Автор: Ланген С.В.

1. Хемосорбционно-каталитическая система для очистки биогаза, включающая по меньшей мере два параллельных хемосорбера с неподвижными слоями твердого гранулированного хемосорбента, способного хемосорбировать сероводород, отличающаяся тем, что она дополнительно включает узел предварительной сероочистки биогаза, состоящий из устройства смешения исходного биогаза с воздухом и частью очищенного от серы биогаза, нагревателя полученной газовой смеси, реактора окисления сероводорода, содержащего неподвижный слой твердого гранулированного катализатора, способного окислять сероводород кислородом до элементарной серы, теплообменник для охлаждения газовой смеси и конденсации паров образовавшейся элементарной серы, а также трубопровод для рециркуляции части очищенного от серы биогаза, причем устройство смешения исходного биогаза с воздухом и частью очищенного от серы биогаза содержит систему управления расходами воздуха и части очищенного от серы биогаза, выполненную с возможностью поддержания концентрации сероводорода в получаемой газовой смеси не выше 1,2 об.% и концентрации кислорода в диапазоне 60-100% от указанной концентрации сероводорода. 2. Система по п.1, отличающаяся тем, что она дополнительно включает в себя блок выделения диоксида углерода из очищенного биогаза. 3. Система по п.2, отличающаяся тем, что она дополнительно включает в себя блок осушки выделенного диоксида углерода. 4. Система по п.3, отличающаяся тем, что она дополнительно включает в себя блок производства жидкой двуокиси углерода и/или сухого льда из осушенного диоксида углерода. 5. Система по пп.1-4, отличающаяся тем, что она дополнительно включает в себя блок для производства тепловой и/или электрической энергии из очищенного биогаза. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 48 810 (13) U1 (51) МПК B01D 53/52 (2000.01) C01B 17/04 (2000.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21), (22) Заявка: 2005119142/22 , 02.06.2005 (24) ...

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10-12-2006 дата публикации

УСТРОЙСТВО ДЕГАЗАЦИИ ЖИДКОЙ СЕРЫ

Номер: RU0000059042U1

1. Устройство дегазации жидкой серы, выполненное в виде емкости, разделенной стенкой с отверстиями для перелива серы, по меньшей мере, на две камеры, одна из которых оснащена средствами выгрузки дегазированной серы, а другая - по меньшей мере, двумя барботажными колонками с расположенными под ними средствами для подачи тонко распыленного воздуха, каждая из барботажных колонок установлена на -образной опорной конструкции, вертикальные элементы которой одним краем жестко заделаны в стенках емкости, а их свободные края служат направляющими для барботажной колонки, на корпусе которой жестко закреплены ребра, снабженные пазами, при этом барботажная колонка установлена с зазором к горизонтальному элементу опорной конструкции, на котором с возможностью перемещения прикреплена пластина, регулирующая величину зазора между колонкой и горизонтальным элементом, а средства для подачи тонко распыленного воздуха оснащены индивидуальным механизмом регулирования расхода газа для каждой колонки в зависимости от количества поступающей серы. 2. Устройство по п.1, отличающееся тем, что вертикальные и горизонтальные элементы опорной конструкции жестко соединены между собой. 3. Устройство по п.1, отличающееся тем, что расстояние, на которое перемещается регулирующая пластина каждого горизонтального элемента опорной конструкции, установлено из расчета уменьшения зазора на 0÷25% для каждой последующей барботажной колонки. 4. Устройство по п.1, отличающееся тем, что верхний край регулирующей пластины снабжен переливными прорезями. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 59 042 (13) U1 (51) МПК C01B 17/02 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21), (22) Заявка: 2006124830/22 , 12.07.2006 (24) Дата начала отсчета срока действия патента: 12.07.2006 (45) Опубликовано: 10.12.2006 (73) Патентообладатель(и): Открытое акционерное общество "Гипрогазоочистка" (RU) U 1 5 9 0 4 2 R U жестко заделаны в стенках емкости, ...

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27-01-2007 дата публикации

УСТАНОВКА ДЛЯ РЕГЕНЕРАЦИИ ОТРАБОТАННОЙ СЕРНОЙ КИСЛОТЫ

Номер: RU0000060510U1

1. Установка для регенерации отработанной серной кислоты из раствора, содержащего примеси сульфатов металлов, включающая устройства для концентрирования указанного раствора и удаления из него кристаллов солей металлов, отличающаяся тем, что она дополнительно содержит устройство охлаждения исходного раствора отработанной серной кислоты и кристаллизации из него преимущественно товарных солей металлов, установленное перед устройством для концентрирования, при этом указанное устройство охлаждения и кристаллизации оснащено узлом разделения суспензии на осветленный раствор и продукционные кристаллы. 2. Установка по п.1, отличающаяся тем, что она снабжена узлом подготовки исходной отработанной серной кислоты, соединенным со входом устройства охлаждения и кристаллизации. 3. Установка по п.2, отличающаяся тем, что вход узла подготовки исходной отработанной серной кислоты соединен по кристаллам солей и/или по концентрированному раствору с выходами устройства для удаления кристаллов солей металлов из концентрированного раствора. 4. Установка по п.1, отличающаяся тем, что устройство для концентрирования раствора соединено по осветленному раствору с выходом по концентрированному раствору устройства для удаления кристаллов солей металлов из концентрированного раствора. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 60 510 (13) U1 (51) МПК C01B 17/88 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21), (22) Заявка: 2006132447/22 , 08.09.2006 (24) Дата начала отсчета срока действия патента: 08.09.2006 (45) Опубликовано: 27.01.2007 6 0 5 1 0 R U Формула полезной модели 1. Установка для регенерации отработанной серной кислоты из раствора, содержащего примеси сульфатов металлов, включающая устройства для концентрирования указанного раствора и удаления из него кристаллов солей металлов, отличающаяся тем, что она дополнительно содержит устройство охлаждения исходного раствора отработанной серной кислоты и ...

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Номер: RU0000071329U1

Печь для непрерывной переработки отходов, в частности жидких, содержащая корпус с загрузочным устройством, камеру дожигания с каталитической решеткой, систему турбонаддува, газоход и горелку, отличающаяся тем, что корпус печи выполнен в виде двух конусообразных частей, футерованных огнеупорным материалом и соединенных герметично по горизонтали фланцами, горелка снабжена водоохлаждаемым кожухом, загрузочное устройство выполнено в виде гибкого обогреваемого шланга, а в нижней части печи выполнен цилиндрический люк, к которому шарнирно прикреплен шток пневмоцилиндра. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 71 329 (13) U1 (51) МПК C01B 17/80 (2006.01) F23G 5/32 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21), (22) Заявка: 2007130822/22 , 14.08.2007 (24) Дата начала отсчета срока действия патента: 14.08.2007 (45) Опубликовано: 10.03.2008 (73) Патентообладатель(и): Лашкевич Евгений Захарович (RU), Арсеньев Владимир Георгиевич (RU), Самойленко Сергей Александрович (RU) U 1 7 1 3 2 9 R U Ñòðàíèöà: 1 U 1 Формула полезной модели Печь для непрерывной переработки отходов, в частности жидких, содержащая корпус с загрузочным устройством, камеру дожигания с каталитической решеткой, систему турбонаддува, газоход и горелку, отличающаяся тем, что корпус печи выполнен в виде двух конусообразных частей, футерованных огнеупорным материалом и соединенных герметично по горизонтали фланцами, горелка снабжена водоохлаждаемым кожухом, загрузочное устройство выполнено в виде гибкого обогреваемого шланга, а в нижней части печи выполнен цилиндрический люк, к которому шарнирно прикреплен шток пневмоцилиндра. 7 1 3 2 9 (54) ПЕЧЬ ДЛЯ НЕПРЕРЫВНОЙ ПЕРЕРАБОТКИ ОТХОДОВ, В ЧАСТНОСТИ ЖИДКИХ R U Адрес для переписки: 603083, г.Нижний Новгород, ул. Старых производственников, 13, кв.44, В.Г. Арсеньеву (72) Автор(ы): Лашкевич Евгений Захарович (RU), Арсеньев Владимир Георгиевич (RU), Самойленко Сергей Александрович (RU) U 1 U 1 ...

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10-02-2009 дата публикации

УСТАНОВКА ПОЛУЧЕНИЯ ЭЛЕМЕНТАРНОЙ СЕРЫ

Номер: RU0000080451U1

Установка получения элементарной серы, включающая входной сепаратор, печь-реактор термической ступени, каталитические реакторы первой и второй ступеней, конденсаторы-коагуляторы серы, экономайзер, отличающаяся тем, что выход печи-реактора термической ступени соединен с входом каталитического реактора первой ступени, выходы каталитических реакторов первой и второй ступеней соединены соответственно с входами конденсаторов-коагуляторов серы, а выход конденсатора-коагулятора второй ступени соединен с входом экономайзера. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 80 451 U1 (51) МПК C01B 17/04 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21), (22) Заявка: 2008122224/22, 02.06.2008 (24) Дата начала отсчета срока действия патента: 02.06.2008 (45) Опубликовано: 10.02.2009 U 1 8 0 4 5 1 R U Формула полезной модели Установка получения элементарной серы, включающая входной сепаратор, печьреактор термической ступени, каталитические реакторы первой и второй ступеней, конденсаторы-коагуляторы серы, экономайзер, отличающаяся тем, что выход печиреактора термической ступени соединен с входом каталитического реактора первой ступени, выходы каталитических реакторов первой и второй ступеней соединены соответственно с входами конденсаторов-коагуляторов серы, а выход конденсаторакоагулятора второй ступени соединен с входом экономайзера. Ñòðàíèöà: 1 ru CL U 1 (54) УСТАНОВКА ПОЛУЧЕНИЯ ЭЛЕМЕНТАРНОЙ СЕРЫ 8 0 4 5 1 (73) Патентообладатель(и): Общество с ограниченной ответственностью "Газпром добыча Оренбург" (ООО "Газпром добыча Оренбург") (RU) R U Адрес для переписки: 460000, г.Оренбург, ул. Пушкинская, 20, ООО "ВолгоУралНИПИгаз", зав. патентным отделом, пат.пов. РФ Б.А. Дронову, рег. №384 (72) Автор(ы): Иванов Сергей Иванович (RU), Селезнев Кирилл Геннадьевич (RU), Столыпин Василий Иванович (RU), Пантелеев Дмитрий Вячеславович (RU), Трынов Анатолий Михайлович (RU), Чехонин Михаил Федорович (RU), Никитин ...

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Номер: RU0000081293U1

1. Печь дожига отходящих газов, содержащая узел подачи отходящего газа и воздуха на горение и цилиндрическую футерованную реакционную камеру, включающую камеру сгорания, по меньшей мере, одну тангенциально установленную горелку и стабилизирующую решетку, отличающаяся тем, что в футеровке торца реакционной камеры проложены каналы, сообщающиеся с камерой сгорания и узлом подачи отходящего газа и воздуха, геометрические оси которых направлены перпендикулярно оси тора, образуемого вращением факела горелки. 2. Печь дожига отходящих газов, отличающаяся тем, что отношение суммы площадей проходного сечения каналов к площади выходного отверстия амбразуры горелки составляет 0,035÷0,1. 3. Печь дожига отходящих газов, отличающаяся тем, что узел подачи отходящего газа и воздуха выполнен в виде двух концентрических патрубков. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 81 293 U1 (51) МПК F23G 7/06 (2006.01) C01B 17/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21), (22) Заявка: 2008141883/22, 22.10.2008 (24) Дата начала отсчета срока действия патента: 22.10.2008 (45) Опубликовано: 10.03.2009 (73) Патентообладатель(и): Открытое акционерное общество "Гипрогазоочистка" (RU) U 1 8 1 2 9 3 R U Ñòðàíèöà: 1 ru CL U 1 Формула полезной модели 1. Печь дожига отходящих газов, содержащая узел подачи отходящего газа и воздуха на горение и цилиндрическую футерованную реакционную камеру, включающую камеру сгорания, по меньшей мере, одну тангенциально установленную горелку и стабилизирующую решетку, отличающаяся тем, что в футеровке торца реакционной камеры проложены каналы, сообщающиеся с камерой сгорания и узлом подачи отходящего газа и воздуха, геометрические оси которых направлены перпендикулярно оси тора, образуемого вращением факела горелки. 2. Печь дожига отходящих газов, отличающаяся тем, что отношение суммы площадей проходного сечения каналов к площади выходного отверстия амбразуры горелки составляет 0, ...

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20-03-2009 дата публикации

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Номер: RU0000081489U1

1. Конусно-регулируемая горелка, содержащая рассекатель для предварительного смешения воздуха, отличающаяся тем, что горелка содержит рассекатель кислого газа, выполненный в виде конуса, отражатель воздуха, выполненный в виде конуса, штурвал для регулировки скорости и угла атаки воздуха, штурвал для регулировки скорости и угла атаки кислого газа. 2. Конусно-регулируемая горелка по п.1, отличающаяся тем, что рассекатель кислого газа, выполненный в виде конуса, является подвижным. 3. Конусно-регулируемая горелка по п.1, отличающаяся тем, что отражатель воздуха, выполненный в виде конуса, является подвижным. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 81 489 U1 (51) МПК C01B 17/00 C01B 17/04 (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21), (22) Заявка: 2008133861/22, 18.08.2008 (24) Дата начала отсчета срока действия патента: 18.08.2008 (45) Опубликовано: 20.03.2009 (72) Автор(ы): Капустин Сергей Иванович (RU), Солодкий Анатолий Михайлович (RU), Шумеев Алексей Михайлович (RU), Пшегорский Антон Александрович (RU) U 1 8 1 4 8 9 R U Ñòðàíèöà: 1 ru CL U 1 Формула полезной модели 1. Конусно-регулируемая горелка, содержащая рассекатель для предварительного смешения воздуха, отличающаяся тем, что горелка содержит рассекатель кислого газа, выполненный в виде конуса, отражатель воздуха, выполненный в виде конуса, штурвал для регулировки скорости и угла атаки воздуха, штурвал для регулировки скорости и угла атаки кислого газа. 2. Конусно-регулируемая горелка по п.1, отличающаяся тем, что рассекатель кислого газа, выполненный в виде конуса, является подвижным. 3. Конусно-регулируемая горелка по п.1, отличающаяся тем, что отражатель воздуха, выполненный в виде конуса, является подвижным. 8 1 4 8 9 (54) КОНУСНО-РЕГУЛИРУЕМАЯ ГОРЕЛКА R U (73) Патентообладатель(и): Капустин Сергей Иванович (RU), Солодкий Анатолий Михайлович (RU), Шумеев Алексей Михайлович (RU), Пшегорский Антон Александрович ( ...

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27-04-2011 дата публикации

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Номер: RU0000103799U1

Реэкстрактор для выделения элементной серы, включающий обогреваемый вакуумный нутч-фильтр, расположенный на водоохлаждаемом сборнике со сферическим днищем для сбора суспензии, и запорное устройство для разгрузки охлажденной суспензии. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 103 799 (13) U1 (51) МПК C01B 17/033 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21)(22) Заявка: 2010119838/05, 17.05.2010 (24) Дата начала отсчета срока действия патента: 17.05.2010 (45) Опубликовано: 27.04.2011 R U 1 0 3 7 9 9 Формула полезной модели Реэкстрактор для выделения элементной серы, включающий обогреваемый вакуумный нутч-фильтр, расположенный на водоохлаждаемом сборнике со сферическим днищем для сбора суспензии, и запорное устройство для разгрузки охлажденной суспензии. Ñòðàíèöà: 1 ru CL U 1 U 1 (54) РЕЭКСТРАКТОР ДЛЯ ИЗВЛЕЧЕНИЯ ЭЛЕМЕНТНОЙ СЕРЫ 1 0 3 7 9 9 Адрес для переписки: 620002, г.Екатеринбург, ул. Мира, 19, УГТУУПИ, центр интеллектуальной собственности, Т.В. Маркс (73) Патентообладатель(и): Государственное образовательное учреждение высшего профессионального образования "Уральский государственный университет - УПИ имени первого Президента России Б.Н. Ельцина" (RU) R U Приоритет(ы): (22) Дата подачи заявки: 17.05.2010 (72) Автор(ы): Нечвоглот Ольга Владимировна (RU), Кляйн Станислав Эдуардович (RU), Трефилов Денис Александрович (RU) U 1 U 1 1 0 3 7 9 9 1 0 3 7 9 9 R U R U Ñòðàíèöà: 2 RU 5 10 15 20 25 30 35 40 45 50 103 799 U1 Полезная модель относится к гидрометаллургическим агрегатам для выделения элементной серы из органических экстрагентов. Известен шнековый экстрактор для извлечения серы, содержащий систему подачи руды, шнек для передвижения руды, фильтр и дистилляционный аппарат, обогреваемый змеевиком [Менковский М.А. и др. Природная сера, Издательство «Химия», М., 1972 г. 240 с.]. Известен экстрактор (патент на полезную модель №40633), принятый в качестве прототипа, представляющий собой ...

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Номер: RU0000149826U1

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Номер: RU0000150513U1

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Номер: RU0000159656U1

Контактный аппарат для окисления диоксида серы в трехокись серы, включающий корпус с крышкой и днищем, центральную колонну, подводящие исходный газ и отводящие прореагировавший газ газоходы с клапанами на них, соединенные между собой переточными газоходами с клапанами на них, кольцевой объем, образованный коаксиально расположенным цилиндром и корпусом аппарата, заполненный катализатором, разделенным на несколько секторов попарно установленными радиальными перегородками, одни из которых имеют перфорацию, а другие - сплошные, параллельно которым размещены дополнительные перфорированные перегородки, вертикальные ребра, установленные между крышкой распределителя газа и листом, перекрывающим сечение аппарата на уровне верха кольцевого объема, заполненного катализатором, отличающийся тем, что распределитель исходного сернистого газа и сборник прореагировавшего газа объединены в один общий узел - распределитель газа, состоящий из пластин, полностью перекрывающих сечение аппарата, между которыми размещаются концентрически расположенные перегородки, образующие кольцевые каналы, против каналов в днище и крышке распределителя газа имеются отверстия для входа исходного сернистого газа в слой катализатора и выхода прореагировавшего газа из слоя катализатора, при этом между крышкой распределителя газа и днищем кольцевого объема, заполненного катализатором, установлена вертикальная кольцевая сплошная перегородка, отделяющая вход исходного сернистого газа в слой катализатора от выхода прореагировавшего газа из слоя катализатора, причем в днище кольцевого объема, заполненного катализатором, имеются отверстия для входа исходного газа в слой катализатора и выхода прореагировавшего газа из слоя катализатора. И 1 159656 ко РОССИЙСКАЯ ФЕДЕРАЦИЯ ВУ” 159 656” 44 ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ИЗВЕЩЕНИЯ К ПАТЕНТУ НА ПОЛЕЗНУЮ МОДЕЛЬ ММ9К Досрочное прекращение действия патента из-за неуплаты в установленный срок пошлины за поддержание патента в силе Дата прекращения ...

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КОНТАКТНЫЙ АППАРАТ ДЛЯ ОКИСЛЕНИЯ ДИОКСИДА СЕРЫ В ТРЕХОКИСЬ СЕРЫ ПРИ ПЕРЕРАБОТКЕ НИЗКОКОНЦЕНТРИРОВАННЫХ СЕРНИСТЫХ ГАЗОВ

Номер: RU0000171032U1

Контактный аппарат для окисления SO в SО при переработке низкоконцентрированных сернистых газов в нестационарных условиях с неизменным направлением движения нескольких тепловых фронтов - зон реакции в секциях с катализатором. Использование данного типа контактного аппарата на 2-ой стадии окисления SO в SO в контактном узле, работающем по схеме ДК/ДА, позволит обеспечить существенное сокращение капитальных и эксплуатационных затрат. И 1 171032 ко РОССИЙСКАЯ ФЕДЕРАЦИЯ ‘7 ВУ’ 171 032°° 44 ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ИЗВЕЩЕНИЯ К ПАТЕНТУ НА ПОЛЕЗНУЮ МОДЕЛЬ ММ9К Досрочное прекращение действия патента из-за неуплаты в установленный срок пошлины за поддержание патента в силе Дата прекращения действия патента: 01.11.2020 Дата внесения записи в Государственный реестр: 24.09.2021 Дата публикации и номер бюллетеня: 24.09.2021 Бюл. №27 Стр.: 1 па ссор ЕП

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15-05-2018 дата публикации

БРЫЗГОУЛОВИТЕЛЬ

Номер: RU0000179468U1

Используемые в промышленной практике сернокислотного производства волокнистые фильтры, работающие при скорости фильтрации 0,2-0,75 м/с, имеют значительную поверхность элементов, количество которых достигает более десятка штук с высотой каждого элемента 2,5-3 м, что определяет данный тип брызгоуловителя как крупногабаритный, дорогостоящий аппарат, имеющий недостаточную эффективность, поскольку в основу действия приняты броуновское движение и вероятность столкновения капель жидкости с волокном диаметром 20 микрон. Наряду с этим волокнистые фильтры в процессе эксплуатации достигают гидравлического сопротивления 250-300 мм вод. ст. и имеют отрицательное свойство вторичного брызгоуноса. Предлагаемый тип брызгоуловителя состоит из вертикальных труб и стержней, закрепленных в трубных решетках и установленных в коаксиальных рядах в шахматном порядке, работает при скорости газа 5-6 м/с, что определяет его незначительные габариты, при этом эффективность нового типа брызгоуловителя основана на действии реально возникающих в процессе очистки газа от капель жидкости инерционных сил, а также сопутствующих факторов (образование пленки жидкости на трубах, резкое изменение направления движения газа при переходе с одного ряда труб на последующий и др.), которые позволяют обеспечить степень очистки газа на трубах в диапазоне 98,8-99,2%. Наряду с этим предусмотрено вторая ступень брызгоуловителя, состоящая из стержней и работающая в поле статического электричества, позволяющего выделит из газа частицы жидкости размером в микрон и менее и достигать очистки газа в пределах 99,8-99,9% при гидравлическом сопротивлении брызгоуловителя не более 100 мм вод. ст. И 1 179468 ко РОССИЙСКАЯ ФЕДЕРАЦИЯ ВУ” 179 468`” 44 ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ИЗВЕЩЕНИЯ К ПАТЕНТУ НА ПОЛЕЗНУЮ МОДЕЛЬ ММ9К Досрочное прекращение действия патента из-за неуплаты в установленный срок пошлины за поддержание патента в силе Дата прекращения действия патента: 21.03.2020 Дата внесения записи в ...

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06-09-2019 дата публикации

Устройство для подачи катализатора в реактор установки для получения элементарной серы

Номер: RU0000192222U1

Предложение относится к установкам для процессов переработки сероводородсодержащих газов с получением элементарной серы. Устройство для подачи катализатора в реактор установки для получения элементарной серы, содержащее емкость для катализатора с герметичной крышкой, сообщенную снизу через запорный механизм с реактором установки, а сверху - через задвижку с линией подачи инертного газа, причем оно снабжено устройствами для контроля давления с двух сторон от запорного механизма. Предлагаемое устройство для подачи катализатора в реактор установки для получения элементарной серы позволяет добавлять катализатор во время работы реактора и экономит технологическое время, исключая непроизводственные остановки, и кислый газ (газ, содержащий окислители, например, кислород), а также и защищать окружающую среду от загрязнений несгоревшими при низкой температуре продуктами реакции. 1 ил. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 192 222 U1 (51) МПК C01B 17/04 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (52) СПК C01B 17/00 (2019.05); C01B 17/04 (2019.05) (21)(22) Заявка: 2019120359, 30.06.2019 (24) Дата начала отсчета срока действия патента: (73) Патентообладатель(и): Публичное акционерное общество «Татнефть» имени В.Д. Шашина (RU) Дата регистрации: 06.09.2019 (56) Список документов, цитированных в отчете о поиске: RU 2461418 C2, 20.09.2012. RU 149826 U1, 20.01.2015. RU 53664 U1, 27.05.2006. RU 17040 U1, 10.03.2001. (45) Опубликовано: 06.09.2019 Бюл. № 25 1 9 2 2 2 2 R U (54) Устройство для подачи катализатора в реактор установки для получения элементарной серы (57) Реферат: Предложение относится к установкам для сторон от запорного механизма. процессов переработки сероводородсодержащих Предлагаемое устройство для подачи газов с получением элементарной серы. катализатора в реактор установки для получения Устройство для подачи катализатора в элементарной серы позволяет добавлять реактор установки для получения элементарной ...

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21-12-2020 дата публикации

СУШИЛЬНАЯ БАШНЯ ДЛЯ ОСУШКИ СЕРНИСТОГО АНГИДРИДА

Номер: RU0000201545U1

Полезная модель предназначена для осушки сернистого ангидрида в производстве серной кислоты контактным методом. Полезная модель направлена на повышение эксплуатационной надежности сушильной башни для осушки сернистого ангидрида за счет использования тепломассообменной насадки из полипропилена. Указанный результат достигается за счет того, что у предложенной конструкции сушильной башни для осушки сернистого ангидрида, в отличие от известной конструкции, включающей стальную обечайку, футеровку, штуцер входа сернистого ангидрида, штуцер выхода сернистого ангидрида, штуцер входа серной кислоты, штуцер выхода серной кислоты, тепломассообменную насадку, опорную решетку для тепломассообменной насадки, крышу, распределительное устройство, лаз для загрузки и выгрузки тепломассообменной насадки, днище, тепломассообменная насадка выполнена из полипропилена, причем соотношение толщины стенок к наружному диаметру элементов тепло-массообменной насадки из полипропилена менее 0,03. Совокупность низкой стоимости полипропилена, меньшей плотности, высоких показателей допускаемых напряжений при сжатии, модуля упругости при изгибе, максимальной допускаемой температуры эксплуатации и коррозионной стойкости в серной кислоте, в сравнении с кислотоупорной керамикой, используемой в известной сушильной башне для осушки сернистого ангидрида, а также такими полимерными материалами, как полиэтилен низкого давления и поливинилхлорид, позволяет добиться максимальных значений допускаемых поперечных усилий для элементов тепломассообменных насадок, при минимальных толщинах их стенок. Снабжение известной сушильной башни для осушки сернистого ангидрида тепломассообменной насадкой из полипропилена позволит повысить ее эксплуатационную надежность. Уменьшение толщины стенки насадки из полипропилена, по сравнению с керамическими насадками, позволяет снизить ее гидравлическое сопротивление, повысить эффективность проведения процесса тепломассообмена. При соотношении толщины стенок к наружному диаметру ...

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12-03-2021 дата публикации

Устройство для очистки атмосферного воздуха "Искусственное дерево"

Номер: RU0000202892U1

Полезная модель относится к области очистки газов, в частности к устройствам очистки воздуха. Устройство содержит корпус с закрепленными на нем сменными панелями, содержащими фильтрующий субстрат, систему полива, систему вентиляции. Корпус выполнен с верхней крышкой, оборудованной системой сбора дождевой воды, соединенной с системой полива, к корпусу по всему периметру снаружи закреплено защитное ограждение, выполненное из ударопрочного светопрозрачного материала со светодиодными лампами, на верхней части корпуса установлены элементы солнечных батарей, соединенные с накопителем энергии и системой полива, системой вентиляции, светодиодными лампами и датчиками контроля состояния окружающей среды, которые размещены равномерно по верхнему краю корпуса. В качестве фильтрующего субстрата используют в теплое время года мохPolýtrichum сommune, а в холодное время года сорбент SAAFBlend WS. Технический результат: способность устройства функционировать вне зависимости от температурных режимов. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 202 892 U1 (51) МПК B01D 53/04 (2006.01) B01D 53/84 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (52) СПК B01D 53/04 (2021.01); B01D 53/84 (2021.01) (21)(22) Заявка: 2020126983, 12.08.2020 (24) Дата начала отсчета срока действия патента: Дата регистрации: 12.03.2021 (45) Опубликовано: 12.03.2021 Бюл. № 8 2 0 2 8 9 2 R U (56) Список документов, цитированных в отчете о поиске: RU 82420 U1, 27.04.2009. RU 68310 U1, 27.11.2007. WO 2018202571 A1, 08.11.2018. DE 202015000866 U1, 09.04.2015. US 20150237811 A1, 27.08.2015. GB 2297087 B, 06.01.1999. (54) Устройство для очистки атмосферного воздуха "Искусственное дерево" (57) Реферат: Полезная модель относится к области очистки корпуса установлены элементы солнечных газов, в частности к устройствам очистки воздуха. батарей, соединенные с накопителем энергии и Устройство содержит корпус с закрепленными системой полива, системой вентиляции, на нем ...

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23-11-2021 дата публикации

МОНОГИДРАТНЫЙ АБСОРБЕР ДЛЯ ПРОИЗВОДСТВА СЕРНОЙ КИСЛОТЫ

Номер: RU0000207897U1

Полезная модель предназначена для производства серной кислоты контактным методом. Полезная модель направлена на повышение эксплуатационной надежности моногидратного абсорбера для производства серной кислоты за счет использования тепло-массообменной насадки из полипропилена. Указанный результат достигается за счет того, что у предложенной конструкции моногидратного абсорбера для производства серной кислоты, в отличие от известной конструкции, включающей стальную обечайку, футеровку, штуцер входа серного ангидрида, штуцер выхода серного ангидрида, штуцер входа серной кислоты, штуцер выхода серной кислоты, тепло-массообменную насадку, опорную решетку для тепло-массообменной насадки, крышу, распределительное устройство, лаз для загрузки и выгрузки тепло-массообменной насадки, днище, тепло-массообменная насадка выполнена из полипропилена, причем соотношение толщины стенок к наружному диаметру элементов тепло-массообменной насадки из полипропилена не менее 0,03. Снабжение известного моногидратного абсорбера для производства серной кислоты тепло-массообменной насадкой из полипропилена с толщиной стенки не менее 0,03 позволит исключить растрескивание тепло-массообменной насадки и, тем самым повысить его эксплуатационную надежность. Кроме того, совокупность низкой стоимости, меньшей плотности и высоких показателей допускаемых напряжений при сжатии и модуля упругости при изгибе дает тепло-массообменной насадке из полипропилена преимущества в сравнении с тепло-массообменной насадкой из кислотоупорной керамики, используемой в известном моногидратном абсорбере для производства серной кислоты. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 207 897 U1 (51) МПК C01B 17/88 (2006.01) B01J 19/30 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (52) СПК C01B 17/88 (2021.08); B01J 19/30 (2021.08) (21)(22) Заявка: 2021116010, 24.05.2021 (24) Дата начала отсчета срока действия патента: (73) Патентообладатель(и): Голованов Иван Юрьевич (RU), ...

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16-03-2022 дата публикации

Узел перегрева олеума блока выпаривания серного ангидрида из олеума установки для выпаривания серного ангидрида из олеума

Номер: RU0000209511U1

Полезная модель относится к устройствам для получения серной кислоты и может быть использована в химической отрасли промышленности. Сущность полезной модели заключается в узле перегрева олеума блока выпаривания серного ангидрида из олеума установки для выпаривания серного ангидрида из олеума, который характеризуется тем, что представлен в виде кожухотрубного теплообменного аппарата, теплообменные трубки которого подключены к его входу и выходу олеума, при этом к выходу олеума подключен трубопровод для соединения с узлом расширения перегретого олеума, при этом трубопровод содержит дросселирующее устройство, а на выходе теплоносителя межтрубного пространства кожухотрубного теплообменного аппарата установлен регулирующий клапан. Технический результат, на достижение которого направлена полезная модель, заключается в снижении риска выхода из строя компонентов блока выпаривания серного ангидрида из олеума установки для выпаривания серного ангидрида из олеума. 1 з.п. ф-лы, 1 ил. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 209 511 U1 (51) МПК C01B 17/74 (2006.01) C01B 17/88 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (52) СПК C01B 17/74 (2021.08); C01B 17/88 (2021.08) (21)(22) Заявка: 2021124322, 17.08.2021 (24) Дата начала отсчета срока действия патента: Дата регистрации: (73) Патентообладатель(и): Общество с ограниченной ответственностью "Реиннольц ЛАБ" (RU) 16.03.2022 (45) Опубликовано: 16.03.2022 Бюл. № 8 2 0 9 5 1 1 R U (54) Узел перегрева олеума блока выпаривания серного ангидрида из олеума установки для выпаривания серного ангидрида из олеума (57) Реферат: Полезная модель относится к устройствам для расширения перегретого олеума, при этом получения серной кислоты и может быть трубопровод содержит дросселирующее использована в химической отрасли устройство, а на выходе теплоносителя промышленности. Сущность полезной модели межтрубного пространства кожухотрубного заключается в узле перегрева олеума блока ...

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09-02-2012 дата публикации

Treatment method and treatment facilities of exhaust gas

Номер: US20120034145A1
Принадлежит: Hitachi Plant Technologies Ltd

An object of the present invention is to provide a treatment method and a plant of an exhaust gas in which corrosion resistance of the exhaust gas treatment plant to a sulfuric acid mist after wet type desulfurization is increased. The treatment method of an exhaust gas in the present invention, wherein sulfur oxide is removed by wet type desulfurization of the exhaust gas and a sulfuric acid mist is removed by feeding ammonia into the exhaust gas, is characterized in that an ammonia gas is mixed into the exhaust gas by feeding inorganic ammonium salt to an alkali desulfurizing agent when the desulfurizing agent is sprayed into the exhaust gas to absorb and remove the sulfur oxide in the exhaust gas.

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29-03-2012 дата публикации

Hydrogen sulfide conversion to hydrogen

Номер: US20120076721A1
Автор: James A. Wasas
Принадлежит: SWAPSOL Corp

A process and system for substantially eliminating contaminants from a gas and a gas produced therefrom.

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16-08-2012 дата публикации

Method and System For the Selective Oxidative Decarboxylation of Fatty Acids

Номер: US20120209049A1

Selective, radically initiated oxidative decarboxylation may produce low viscosity renewable fuels from biologically derived fats and oils. Fatty acids and triglycerides may be decarboxylated using oxidants at a water/oil interface. The oxidants may be produced using photo-Fenton reagents. The reaction advantageously can be carried out at room temperature and pressure and has fewer unwanted byproducts than traditional decarboxylation techniques.

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06-12-2012 дата публикации

Process for The Production of Sulfur from Sulfur Dioxide with Tail Gas Recycle

Номер: US20120308474A1

The reduction of the gas stream containing sulfur dioxide to elemental sulfur is carried out by reacting a reducing gas, such as natural gas, methanol or a mixture of hydrogen and carbon monoxide, with recycled sulfur and recycled tail gas to produce a stream containing hydrogen sulfide that may be reacted with the gas stream that contains sulfur dioxide. Gas streams with a molar concentration of sulfur dioxide from 1 to 100% may be processed to achieve nearly 100% sulfur recovery efficiency.

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21-03-2013 дата публикации

Process for removing hydrogen sulfide from very sour hydrocarbon gas streams using metal sulfide

Номер: US20130071310A1
Автор: Puneet Gupta
Принадлежит: Shell Oil Co

A process for sweetening a gas stream containing hydrogen sulfide wherein said process comprises contacting said gas stream within a contacting zone a contacting composition comprising metal sulfide in a lower sulfided state and yielding from said contacting zone a product gas stream having a reduced hydrogen sulfide concentration and a recovered contacting composition comprising metal sulfide in a higher sulfided state.

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21-03-2013 дата публикации

Configurations and methods of treatment of sulfur-containing vent gases

Номер: US20130071315A1
Принадлежит: Fluor Technologies Corp

Sulfur emissions from liquid sulfur are reduced, or even entirely avoided by degassing the liquid sulfur at pressure in an out-of-pit vessel and by sweeping the rundown pit (or vessel) with a sweep gas that is non-poisonous for a hydrogenation catalyst. Acid gases from degassing are fed at pressure to the Claus unit, while sweep gases are fed to the tail gas treatment unit to substantially recycle the acid gases to extinction. In preferred plants and methods, motive fluids and booster eductors or compressors are not needed, and incineration of the acid gases can be avoided.

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28-03-2013 дата публикации

DECOMPOSITION/ELIMINATION METHOD USING A PHOTOCATALYTIC MATERIAL

Номер: US20130078174A1
Принадлежит: SHOWA CO., LTD.

The present invention provides a new method for decomposing and/or removing hazardous substances using a photocatalytic material. The method of the present invention is sufficiently useful in fields requiring quick decomposition and/or removal of hazardous substances in gas and/or liquid phases. The decomposition method of the present invention using a photocatalytic material enables significantly efficient and rapid decomposition of hazardous substances in gas and/or liquid phases by causing a photocatalytic material to coexist with a dilute hydrogen peroxide solution. 1. A decomposition method using a photocatalytic material , the method comprising performing decomposition in the presence of a photocatalytic material and a dilute hydrogen peroxide solution.2. The decomposition method using a photocatalytic material according to claim 1 ,wherein the photocatalytic material is a photocatalytic material having a crystalline titanium oxide film, obtained by forming a titanium nitride on a surface of a titanium metal or a titanium alloy, and anodizing the titanium metal or titanium alloy with a surface on which a titanium nitride is formed.3. The decomposition method using a photocatalytic material according to claim 2 , wherein the crystalline titanium oxide is an anatase-type titanium oxide.4. The decomposition method using a photocatalytic material according to claim 1 , wherein the dilute hydrogen peroxide solution has a hydrogen peroxide concentration of 1 weight % or less.5. A method of removing a gaseous hazardous substance containing a highly concentrated nitrogen oxides and sulfur oxides in an environment containing the hazardous substance claim 1 , the method comprising: (1) removing nitrogen oxides by using an amine compound aqueous solution as a chemical for removing nitrogen oxides in a primary device and (2) removing sulfur oxides by using the decomposition method of in which the photocatalytic material and the dilute hydrogen peroxide solution are ...

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18-04-2013 дата публикации

METHOD FOR THE TREATMENT OF PROCESS GAS FOR BIOLOGICAL H2S REMOVAL

Номер: US20130095017A1
Автор: Grill Jeffrey J.
Принадлежит:

The present invention provides a biological HS removal system for the treatment of process gas, comprising: a housing that receives a process gas stream through a gas inlet, the housing comprising a plurality of layers through which the process gas stream flows while it is treated for HS removal, and a gas outlet through which a treated gas stream exits; wherein air is added to the process gas stream prior to the process gas stream entering the housing. 1. A method for the treatment of process gas for biological HS removal , comprising:receiving a process gas stream from an anaerobic digestion system or from a landfill gas system;adding air to the process gas stream;passing the process gas stream through a gas inlet of a housing;{'sub': '2', 'treating the process gas stream for HS removal; and'}passing a treated gas stream through a gas outlet in the housing.2. The method of claim 1 , further comprising using a pressure swing adsorption system to separate the HS into the process gas stream prior to adding air to the process gas stream.3. The method of claim 1 , further comprising using a water scrubbing system to separate the HS into the process gas stream prior to adding air to the process gas stream.4. The method of claim 1 , wherein adding air to the process gas stream comprises metering the air into the process gas stream to achieve a predetermined oxygen concentration for biological use before release into the atmosphere or destruction.5. The method of claim 1 , further comprising feeding the treated gas stream into an anaerobic digester cleanup system.6. The method of claim 1 , further comprising feeding the treated gas stream into a landfill gas cleanup system.7. The method of claim 1 , wherein treating the process gas stream for HS removal comprises spraying the process gas stream with a neutralizing agent for HS removal.8. The method of claim 7 , wherein the neutralizing agent comprises a water solution.9. The method of claim 7 , wherein the neutralizing ...

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25-04-2013 дата публикации

Semiconductor nanocrystal-polymer composite, method of preparing the same, and composite film and optoelectronic device including the same

Номер: US20130099213A1
Принадлежит: SAMSUNG ELECTRONICS CO LTD

A semiconductor nanocrystal-polymer composite including a semiconductor nanocrystal, a polymer comprising a plurality of carboxylate anion groups (—COO − ) bindable to a surface of the semiconductor nanocrystal, and a metal cation bindable to a carboxylate anion group of the plurality of carboxylate anion groups.

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25-04-2013 дата публикации

METHOD FOR REMOVAL OF HYDROGEN SULFIDE FROM GEOTHERMAL STEAM AND CONDENSATE

Номер: US20130101473A1
Принадлежит: MULTI-CHEM GROUP, LLC

A method for scavenging hydrogen sulfide from geothermal steam in a condenser under vacuum. A fine curtain of atomized acrolein-water droplets may be sprayed into geothermal steam condensers in an amount of approximately 2:1 molar ratio of acrolein to HS based on hydrogen sulfide in the incoming steam from the turbine. The range being approximately 0.1 ppm to 500 ppm of sulfide. The acrolein is allowed to react with the gas phase HS to form non-volatile aldehyde byproducts which partition into the water phase, are returned to the cooling tower and ultimately removed by normal cooling-tower blow down. 15-. (canceled)6. A system comprising:a cooling tower comprising cooling water;an acrolein feed line in fluid communication with the cooling tower;a condenser, where the condenser is in fluid communication with the cooling tower through a flow line;a geothermal steam line in fluid communication with the condenser; anda plurality of spray nozzles, the spray nozzles in fluid communication with the flow line and adapted to spray acrolein-water droplets inside the condenser.7. The system of claim 6 , further comprising:an acrolein reservoir in fluid communication with the acrolein feed line; anda bisulfate scrubber in fluid communication with the acrolein reservoir.8. The system of further comprising:a cooling water return line in fluid communication with the cooling tower and the condenser.9. The system of claim 6 , further comprising:a cooling tower sump outlet line in fluid communication with the cooling tower and the flow line; andan acrolein injector in fluid communication with the acrolein feed line and the cooling tower sump outlet line.10. The system of further comprising a hydrogen sulfide sensor adapted to measure hydrogen sulfide in a non-condensible gas layer in the condenser.11. The system of claim 6 , wherein the acrolein-water droplets comprise acrolein the aqueous phase.12. The system of wherein the condenser is under vacuum.13. The system of claim 6 , ...

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02-05-2013 дата публикации

PROCESS FOR DIRECTLY PRODUCING SULFUR TRIOXIDE AND SULFURIC ACID USING GYPSUM AS RAW MATERIAL

Номер: US20130108541A1
Автор: Yin Xiaolin
Принадлежит:

Provided is a process for directly producing sulfur trioxide and sulfuric acid from gypsum. Sulfur trioxide is directly substituted with silicon dioxide by thermal or light-quantum activation, which is assisted with catalytic activation, while restraining reducing atmosphere and removing the resultant sulfur trioxide in time. The resultant sulfur trioxide is then used as raw material to produce sulfuric acid by a well-known method in prior art. The process has the advantages of simplified operational steps, little investment, low energy consumption and manufacturing cost, and low environmental pollution. 1. A process for directly producing sulfur trioxide and sulfuric acid using gypsum as raw material , wherein sulfur trioxide in gypsum is directly replaced with silica dioxide through thermal activation or light quantum activation under the assistance of catalytic activation , while restraining reducing atmosphere and removing the resultant sulfur trioxide in time , [{'br': None, 'sub': 4', '2', '3', '3, 'img': [{'@id': 'CUSTOM-CHARACTER-00004', '@he': '2.79mm', '@wi': '12.36mm', '@file': 'US20130108541A1-20130502-P00001.TIF', '@alt': 'custom-character', '@img-content': 'character', '@img-format': 'tif'}, {'@id': 'CUSTOM-CHARACTER-00005', '@he': '4.91mm', '@wi': '6.35mm', '@file': 'US20130108541A1-20130502-P00002.TIF', '@alt': 'custom-character', '@img-content': 'character', '@img-format': 'tif'}], 'CaSO+M+SiOM+CaSiO/M. CaSiO+'}, {'br': None, 'sub': 4', '2', '2', '2', '3', '2', '3', '2', '3', '2', '4, 'i': +a', '.b', '.b, 'img': {'@id': 'CUSTOM-CHARACTER-00006', '@he': '2.79mm', '@wi': '12.36mm', '@file': 'US20130108541A1-20130502-P00001.TIF', '@alt': 'custom-character', '@img-content': 'character', '@img-format': 'tif'}, 'CaSO.2HO+M+SiOHOM+CaSiOHO/M.CaSiOHO+SO/HSO'}], 'the basic reaction equations are as follows,'}{'sub': '2', 'wherein M is the catalytic activator, and a and b prefixed to HO are 1, 2 or 3;'}then the resultant sulfur trioxide is used as raw material ...

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09-05-2013 дата публикации

ENERGY RECOVERY IN MANUFACTURE OF SULFURIC ACID

Номер: US20130115159A1
Принадлежит: MECS Inc.

This invention relates to the recovery of energy in the manufacture of sulfuric acid, and more particularly to enhanced recovery of energy from the absorption of wet SOin sulfuric acid. The invention is further directed to control of mist formation during SOabsorption, and of the sulfuric acid mist content of the gas stream leaving the SOabsorption step in a process wherein SOabsorption energy is recovered from absorption acid in useful form. 1148-. (canceled)149. A process for the preparation of sulfuric acid in a contact sulfuric acid manufacturing facility comprising an interpass absorber wherein said facility is retrofitted to be operated in accordance with a process that recovers the heat of absorption of SOin useful form at a temperature of at least about 150° C. , the process comprising:burning a source of sulfur in a gas comprising excess oxygen to produce a sulfur oxide-bearing gas stream comprising a combustion gas comprising sulfur dioxide and oxygen;{'sub': '3', 'contacting the sulfur oxide-bearing gas stream comprising said combustion gas with a catalyst for conversion of sulfur dioxide to sulfur trioxide, thereby converting the sulfur oxide-bearing gas stream to a conversion gas containing SO;'}contacting the conversion gas in a primary absorption zone with a primary absorption liquid comprising sulfuric acid, thereby absorbing sulfur trioxide and/or transferring sulfuric acid from the conversion gas to the primary absorption liquid;circulating said absorption liquid between said primary absorption zone and an indirect heat exchanger in which heat generated by reaction of sulfur trioxide and water, condensation of sulfuric acid, and/or absorption of sulfur trioxide into the primary absorption liquid is transferred to a heat transfer fluid, thereby heating the heat transfer fluid to at least 150° C.; and{'sub': '3', 'contacting the gas stream exiting the primary absorption zone with a secondary absorption liquid comprising sulfuric acid in a secondary ...

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16-05-2013 дата публикации

AIR POLLUTION CONTROL SYSTEM AND METHOD

Номер: US20130118351A1
Принадлежит: MITSUBISHI HEAVY INDUSTRIES, LTD.

SOremoval equipment for reducing sulfur oxides from flue gas from a boiler, a cooler provided on a downstream side of the SOremoval equipment, for reducing the sulfur oxides that remain in the flue gas and decrease a gas temperature, COrecovery equipment including an absorber for bringing COin the flue gas into contact with a COabsorption liquid to be reduced, and a regenerator for causing the COabsorption liquid to emit COto recover COand regenerate the COabsorption liquid, a heat exchanger which is provided on an inlet passage side of the electric dust collector, for decreasing a temperature of the flue gas are included, and a mist generation material in the flue gas is converted from a gas state to a mist state to cause particulates in the flue gas to arrest and reduce the mist generation material in the mist state. 1. An air pollution control system comprising:an electric dust collector for reducing particulates from flue gas from a boiler;{'sub': 'x', 'SOremoval equipment for reducing sulfur oxides from the flue gas after the dust reduction;'}{'sub': 'x', 'a cooler which is provided on a downstream side of the SOremoval equipment, for reducing the sulfur oxides that remain in the flue gas and for decreasing a gas temperature;'}{'sub': '2', 'claim-text': [{'sub': 2', '2, 'an absorber for bringing COin the flue gas into contact with a COabsorption liquid so as to be reduced, and'}, {'sub': 2', '2', '2', '2, 'a regenerator for causing the COabsorption liquid to emit COso as to recover COand regenerate the COabsorption liquid; and'}], 'COrecovery equipment includinga heat exchanger which is provided on an inlet passage side of the electric dust collector, for decreasing a temperature of the flue gas,wherein a mist generation material in the flue gas is converted from a gas state to a mist state to cause particulates in the flue gas to arrest and reduce the mist generation material in the mist state.2. The air pollution control system according to claim 1 , further ...

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16-05-2013 дата публикации

Method of producing sulfur dioxide

Номер: US20130123556A1
Принадлежит: Shell Oil Co

A method of producing sulfur dioxide is provided. A feed gas stream comprising at least 5% by volume hydrogen sulfide is provided. The feed gas stream is separated into a hydrogen sulfide stream and a hydrocarbon gas stream. An oxidant stream is provided and is combusted with the hydrogen sulfide stream to produce thermal power and a combustion stream containing sulfur dioxide and steam. Sulfur dioxide is separated from the combustion stream.

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06-06-2013 дата публикации

METHOD AND A DEVICE FOR CLEANING A CARBON DIOXIDE RICH FLUE GAS

Номер: US20130139738A1
Принадлежит:

A gas cleaning system () for cleaning a carbon dioxide rich flue gas containing sulphur dioxide generated in a boiler () comprises a first gas cleaning device () being operative for removing at least 80% of the sulphur dioxide content of the flue gas generated in the boiler (), thereby generating a partly cleaned carbon dioxide rich flue gas, and a second gas cleaning device (), being separate from the first gas cleaning device () and being operative for receiving at least a portion of the partly cleaned carbon dioxide rich flue gas that passed through the first gas cleaning device (). The second gas cleaning device () is operative for removing at least a portion of the water content of the partly cleaned carbon dioxide rich flue gas by means of cooling the partly cleaned carbon dioxide rich flue gas to condense water there from. 1. A method of cleaning a carbon dioxide rich flue gas containing sulphur dioxide generated in a boiler combusting a fuel in the presence of a gas containing oxygen gas , the method comprising:removing at least 80% of the sulphur dioxide content of the flue gas generated in the boiler n a first gas cleaning device to generate a partly cleaned carbon dioxide rich flue gas,forwarding at least a portion of the partly cleaned carbon dioxide rich flue gas to a second gas cleaning device being separate from the first gas cleaning device,cooling, in said second gas cleaning device, the partly cleaned carbon dioxide rich flue gas to condense water there from, thereby generating a cleaned carbon dioxide rich flue gas having a lower concentration of water vapour than the partly cleaned carbon dioxide rich flue gas.2. A method according to claim 1 , wherein said step of cooling claim 1 , in the second gas cleaning device claim 1 , the partly cleaned carbon dioxide rich flue gas to condense water there from claim 1 , comprises bringing the partly cleaned carbon dioxide rich flue gas into direct contact with a cooling liquid.3. A method according to ...

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06-06-2013 дата публикации

Reactors and Processes for the Oxidative Coupling of Hydrocarbons

Номер: US20130142707A1
Принадлежит: FINA TECHNOLOGY, INC.

A method for the oxidative coupling of hydrocarbons includes providing an oxidative catalyst inside a reactor and carrying out the oxidative coupling reaction under a set of reaction conditions. The reactor surfaces that contact the reactants and products do not provide a significant detrimental catalyzing effect. In an embodiment the reactor contains an inert lining or a portion of the reactor inner surface is treated to reduce the detrimental catalytic effects. In an embodiment the reactor contains a lining that includes an oxidative catalyst. 115-. (canceled)16. A reactor for the oxidative coupling of hydrocarbons comprising:a reactor vessel having a reaction contact surface;an inlet for feeding at least one hydrocarbon feedstream;an inlet for providing an oxygen source; andan outlet for recovering a product from the reactor; andwherein the reaction contact surface of the reactor vessel does not provide a significant detrimental catalyzing effect under conditions for the oxidative coupling of hydrocarbons.17. The reactor of claim 16 , wherein the reactor comprises a lining covering a majority of wetted parts of the reactor.18. The reactor of claim 17 , wherein the lining covers at least 99% of the reaction contact surface of the reactor.19. The reactor of claim 17 , wherein the lining is selected from the group consisting of an inert high temperature sealant claim 17 , glass claim 17 , quartz claim 17 , a ceramic material claim 17 , and combinations thereof.20. The reactor of claim 17 , wherein the lining comprises an oxidative catalyst.21. The reactor of claim 16 , wherein the reactor comprises a reaction zone capable of reaction conditions for the oxidative coupling of hydrocarbons.22. The reactor of claim 16 , wherein the reactor is treated to reduce detrimental catalytic effects of the reaction contact surface.23. The reactor of claim 22 , wherein the reactor is treated to passivate portions of the reactor that contact the hydrocarbon feedstock or product.24. ...

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06-06-2013 дата публикации

EXHAUST GAS PURIFICATION CATALYST AND PRODUCTION METHOD THEREFOR, AND METHOD FOR PURIFYING NITROGEN OXIDE IN EXHAUST GAS

Номер: US20130142719A1
Принадлежит: BABCOCK-HITACHI KABUSHIKI KAISHA

An exhaust gas purification catalyst is made as a composition comprising titanium oxide (TiO), aluminum sulfate (Al(SO)), an oxide of vanadium (V), and an oxide of molybdenum (Mo) and/or tungsten (W), wherein on titanium oxide having sulfate ions and aluminum ions adsorbed thereon obtained by making contact with aluminum sulfate at more than 1 wt % and not more than 6 wt % relative to titanium oxide in the presence of water, an oxo acid salt of vanadium or a vanadyl salt and an oxo acid or an oxo acid salt of molybdenum and/or tungsten are supported in a proportion of more than 0 atom % and not more than 3 atom %, respectively. By this, the degradation of catalyst performance can be suppressed even with exhaust gas containing potassium compounds at a high concentration in combustion ash. 1. An exhaust gas purification catalyst having a composition comprising:{'sub': '2', 'titanium oxide (TiO);'}{'sub': 2', '4', '3, 'aluminum sulfate (Al(SO));'}an oxide of vanadium (V); andan oxide of molybdenum (Mo) and/or tungsten (W), whereinon titanium oxide having sulfate ions and aluminum ions adsorbed thereon obtained by making contact with aluminum sulfate at more than 1 wt % and not more than 6 wt % relative to titanium oxide in the presence of water, an oxo acid salt of vanadium or a vanadyl salt and an oxo acid or an oxo acid salt of molybdenum and/or tungsten are supported in a proportion of more than 0 atom % and not more than 3 atom %, respectively.2. A production method for an exhaust gas purification catalyst comprising titanium oxide (TiO) , aluminum sulfate (Al(SO)) , an oxide of vanadium (V) , and an oxide of molybdenum (Mo) and/or tungsten (W) , comprisingsupporting an oxo acid salt of vanadium or a vanadyl salt and an oxo acid or an oxo acid salt of molybdenum and/or tungsten in a proportion of more than 0 atom % and not more than 3 atom %, respectively, onto titanium oxide having sulfate ions and aluminum ions adsorbed thereon obtained by making contact with ...

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27-06-2013 дата публикации

SUSPENDED SOLIDS SEPARATION SYSTEMS AND METHODS

Номер: US20130165678A1
Принадлежит:

A method that includes clarifying a thin stillage product in a mechanical processor to produce a fine suspended solids stream and a clarified thin stillage is provided. The method further includes providing the thin stillage product and the clarified thin stillage, separately or in a combined stream, to one or more evaporators to produce one or more reduced suspended solids streams, each stream having a reduced amount of suspended solids and a lower viscosity as compared to process streams having a comparable total solids content but containing a higher amount of suspended solids. The method can further included further processing of one or more of the reduced suspended solids streams to produce a bio-oil product. 1. A method comprising:clarifying a thin stillage product in a mechanical processor to produce a fine suspended solids stream and clarified thin stillage; andproviding the thin stillage product and the clarified thin stillage, separately or in a combined stream, to one or more evaporators to produce one or more reduced suspended solids streams, each stream having a reduced amount of suspended solids and a lower viscosity as compared to process streams having a comparable total solids content and which contains a higher amount of suspended solids.2. The method of claim 1 , wherein the suspended solids comprise less than about 10% by weight of the total solids content and the total solids content is between about 68% and about 72% by weight.3. The method of claim 1 , wherein at least one of the one or more reduced suspended solids stream has a total solids content comprising suspended solids and dissolved solids in an amount between about 30% and about 90% by weight claim 1 , wherein the suspended solids comprise less than 25% by weight of the total solids content.4. The method of claim 1 , wherein at least one of the one or more reduced suspended solids stream is clarified concentrated thin stillage claim 1 , which contains an amount of bio-oil which is ...

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11-07-2013 дата публикации

REACTOR FOR SYNTHESIZING HYDROGEN SULFIDE, APPARATUS FOR PRODUCING HYDROGEN SULFIDE, APPARATUS FOR PRODUCING SODIUM HYDROGEN SULFIDE, METHOD FOR PRODUCING HYDROGEN SULFIDE, AND METHOD FOR PRODUCING SODIUM HYDROGEN SULFIDE

Номер: US20130177496A1
Принадлежит: JGC CORPORATION

A reactor for synthesizing hydrogen sulfide in which sulfur and hydrogen are subjected to gas-phase reaction in the absence of a catalyst to synthesize hydrogen sulfide, the reactor including: a reactor body that retains liquid sulfur in a bottom portion thereof; a heating unit that gasifies part of the liquid sulfur; a hydrogen gas supply unit that supplies hydrogen gas into the liquid sulfur; and a heat-exchanging portion provided in a gas-phase reaction region located above the liquid surface of the liquid sulfur in the reactor body, wherein heat-exchanging portion is configured such that the reaction temperature in the gas-phase reaction region is controlled to be within a predetermined temperature range by changing the heat exchange amount per unit volume in a gas-phase reaction region located farther from the liquid surface from the heat exchange amount per unit volume in a gas-phase reaction region located closer to the liquid surface. 1. A reactor for synthesizing hydrogen sulfide in which sulfur and hydrogen are subjected to gas-phase reaction in the absence of a catalyst to synthesize hydrogen sulfide , the reactor comprising:a reactor body that retains liquid sulfur in a bottom portion thereof;a heating unit that gasifies part of the liquid sulfur;a hydrogen gas supply unit that supplies hydrogen gas into the liquid sulfur; anda heat-exchanging portion provided in a gas-phase reaction region located above the liquid surface of the liquid sulfur in the reactor body,wherein the heat-exchanging portion is configured such that the reaction temperature in the gas-phase reaction region is controlled to be within a predetermined temperature range by changing the heat exchange amount per unit volume in a gas-phase reaction region located farther from the liquid surface from the heat exchange amount per unit volume in a gas-phase reaction region located closer to the liquid surface.2. The reactor for synthesizing hydrogen sulfide according to claim 1 , wherein the ...

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25-07-2013 дата публикации

CHEMICALLY MODIFIED CARBONIC ANHYDRASES USEFUL IN CARBON CAPTURE SYSTEMS

Номер: US20130189756A1
Принадлежит: CODEXIS, INC.

The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering. 193-. (canceled)94. A method for removing carbon dioxide from a gas stream comprising the step of contacting the gas stream with a homogenous liquid solution under suitable conditions , wherein the solution comprises:(i) an α-class carbonic anhydrase polypeptide chemically modified by treatment with a cross-linking agent; and{'sub': '2', '(ii) a COabsorption mediating compound;'}whereby the solution absorbs carbon dioxide from the gas stream.95. The method of claim 94 , wherein the chemically modified carbonic anhydrase has increased carbonic anhydrase activity in the presence of the COabsorption mediating compound relative to the activity of the same carbonic anhydrase polypeptide that is not chemically modified.96. The method of claim 94 , wherein the chemically modified carbonic anhydrase has increased carbonic anhydrase activity in 4.2 M N-methyldiethanolamine (MDEA) at 50° C. compared to the activity under the same conditions of the same carbonic anhydrase polypeptide that is unmodified.97. The method of claim 94 , wherein the cross-linking agent is selected from the group consisting of a dialdehyde claim 94 , a bis-imidate ester claim 94 , a bis(N-hydroxysuccinimide) ester ...

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08-08-2013 дата публикации

Hybrid particles and associated methods

Номер: US20130200313A1
Принадлежит: Battelle Energy Alliance Llc

Hybrid particles that comprise a coating surrounding a chalcopyrite material, the coating comprising a metal, a semiconductive material, or a polymer; a core comprising a chalcopyrite material and a shell comprising a functionalized chalcopyrite material, the shell enveloping the core; or a reaction product of a chalcopyrite material and at least one of a reagent, heat, and radiation. Methods of forming the hybrid particles are also disclosed.

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08-08-2013 дата публикации

ENZYME ENHANCED CO2 CAPTURE AND DESORPTION PROCESSES

Номер: US20130203155A1
Принадлежит: CO2 SOLUTIONS INC.

An enzyme-catalyzed desorption process for releasing COgas from an ion-rich solution containing bicarbonate ions includes providing carbonic anhydrase in the ion-rich solution such that in a desorption unit the carbonic anhydrase is allowed to flow with the ion-rich solution while promoting conversion of the bicarbonate ions into COgas and generating an ion-depleted solution and releasing the COgas and the ion-depleted solution from the desorption unit. A COcapture process includes contacting a CO-containing gas with a solution in an absorption unit, to convert COinto ions; feeding an ion-rich solution to a desorption unit wherein carbonic anhydrase is present within the ion-rich solution to generate an ion-depleted solution and, preferably, recycling the ion-depleted solution. Methods of decreasing the COdesorption temperature in a desorption unit, decreasing the COdesorption reactor size, and decreasing the COdesorption energy input in a desorption unit, are also described. 1. An enzyme catalyzed desorption process for releasing CO2 gas from an ion-rich solution containing bicarbonate ions , the process comprising:providing carbonic anhydrase or variants or analogues thereof in the ion-rich solution such that in a desorption unit the carbonic anhydrase or variants or analogues thereof is allowed to flow with the ion-rich solution while promoting conversion of the bicarbonate ions into CO2 gas and generating an ion-depleted solution; andreleasing the CO2 gas and the ion-depleted solution from the desorption unit.2. The process of claim 1 , wherein the desorption unit comprises a liquid inlet for receiving the ion-rich solution comprising the carbonic anhydrase claim 1 , a gas outlet for releasing the CO2 gas and a liquid outlet for releasing the ion-depleted solution comprising the carbonic anhydrase.3. The process of claim 2 , comprising regulating a concentration of carbonic anhydrase in the ion-rich solution by adding an amount of the carbonic anhydrase prior to ...

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08-08-2013 дата публикации

Sulfur Modified Polyvinyl Acetate (PVAc)

Номер: US20130203902A1
Принадлежит:

Provided are a sulfur modified polymer composition, free from asphalt, bitumen or like compounds, and method of making same. The inclusion of 50% by weight sulfur, or greater, into the polymer composition results in a composition that is softer and having an increased melting point, relative to the unmodified polymer composition. 1. A sulfur modified polyvinyl acetate polymer composition , the polymer composition comprising:a polyvinyl acetate polymer having a melting point; andsulfur, wherein the sulfur is present in an amount up to 50% by weight, such that the sulfur modified polymer has an increased melting point as compared to the melting point of the polyvinyl acetate polymer.2. The polymer composition of claim 1 , wherein the composition does not contain asphalt claim 1 , bitumen claim 1 , and combinations thereof.3. The polymer composition of wherein the sulfur is present in an amount between about 10 and 20% by weight.4. The polymer composition of wherein the sulfur is present in an amount between about 20 and 30% by weight.5. The polymer composition of wherein the sulfur is present in an amount between about 30 and 40% by weight.6. The polymer composition of wherein the sulfur is present in an amount between about 40 and 50% by weight.7. The polymer composition of wherein at least a portion of the sulfur is present in elemental form.8. The polymer composition of wherein sulfur modified polyvinyl acetate polymer composition has a melting point that is up to 50° C. greater than the melting point of the unmodified polyvinyl acetate polymer.9. The polymer composition of wherein sulfur modified polyvinyl acetate polymer composition has a melting point that is between 10° C. and 50° C. greater than the melting point of the unmodified polyvinyl acetate polymer.10. The polymer composition of wherein sulfur modified polyvinyl acetate polymer composition has a melting point that is between 10° C. and 30° C. greater than the melting point of the unmodified polyvinyl ...

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29-08-2013 дата публикации

Process for co2 absorption with carbonic anhydrase entrapped in porous supports

Номер: US20130224842A1
Принадлежит: Co2 Solutions Inc

A carbonic anhydrase bioreactor for treating a CO 2 -containing gas includes a reaction chamber for receiving a liquid; porous particles with carbonic anhydrase entrapped therein provided in the reaction chamber for catalyzing a reaction of CO 2 into bicarbonate and hydrogen ions to obtain a treated gas and an ion-rich solution; a retention device for retaining the porous particles within the reaction chamber; a liquid inlet for providing the liquid; a gas inlet for providing the CO 2 -containing gas; a liquid outlet for releasing the ion-rich solution; and a gas outlet to release the treated gas. Processes are also described for treating a CO 2 -containing gas, where particles comprising porous material with entrapped carbonic anhydrase catalyze the reaction and the particles are retained in the reaction chamber.

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05-09-2013 дата публикации

Method of Generating Micronized Sulphur

Номер: US20130230448A1
Принадлежит:

A method of producing micronized sulphur wherein elemental sulphur is dissolved in a solvent for sulphur to produce a sulphur-solvent solution and precipitation of the dissolved sulphur is effected or controlled by manipulation of at least one of pressure, temperature or water content in the solvent to produce the micronized sulphur. 1. A method of producing micronized sulphur comprising:dissolving elemental sulphur in a solvent for sulphur to produce a sulphur-solvent solution;controlling precipitation of said dissolved sulphur in said sulphur-solvent solution by manipulation of at least one of pressure, temperature or water content to produce micronized sulphur.2. The method of claim 1 , wherein said control of precipitation comprises adjusting the temperature of said sulphur-solvent solution.3. The method of claim 1 , wherein said solvent comprises anhydrous ammonia containing less than 0.3 wt. % water.4. The method of claim 1 , wherein said solvent comprises hydrous ammonia containing from 0.3 to 70 wt. % water.5. The method of claim 4 , wherein said solvent comprises hydrous ammonia containing from 0.3 to 10 wt. % water.6. The method of claim 1 , wherein said solvent is one wherein the solubility of said elemental sulphur is directly proportional to temperature.7. The method of claim 1 , wherein said solvent is one wherein the solubility of said elemental sulphur is inversely proportional to temperature.8. The method of claim 1 , wherein said solvent is selected from the group consisting of anhydrous ammonia claim 1 , hydrous ammonia claim 1 , liquid sulphur dioxide claim 1 , liquid carbon dioxide claim 1 , supercritical carbon dioxide claim 1 , carbon disulphide claim 1 , dimethydisulphide and mixtures thereof.9. The method of claim 1 , wherein said micronized sulphur has an average particle size of less than 1000 μm claim 1 , preferably less than 10 μm.10. The method of claim 1 , wherein said sulphur is present in said solvent in an amount up to saturation ...

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12-09-2013 дата публикации

METHOD FOR INCREASING THE SULFURIC ACID CONCENTRATION OF A SULFURIC ACID SOLUTION

Номер: US20130236389A1
Принадлежит: TEIJIN ARAMID B.V.

Described is a method of increasing the sulfuric acid concentration of a first aqueous sulfuric acid solution with a sulfuric acid concentration of 82-89% to a concentrated sulfuric acid solution with a sulfuric acid concentration of at least 90%, including evaporating water from the first aqueous sulfuric acid solution in an evaporator vessel to the concentrated sulfuric acid solution, pumping around a mixture of the first aqueous sulfuric acid solution, part of the concentrated sulfuric acid solution, a second aqueous sulfuric acid solution, and hydrogen peroxide through an enameled piping system comprising the evaporator vessel and one or more heaters and pumps, wherein the piping system is operating at a temperature of at least 180° C., and the sulfuric acid concentration of the second aqueous sulfuric acid solution is at least 90%. 1. A method of increasing the sulfuric acid concentration of a first aqueous sulfuric acid solution with a sulfuric acid concentration of 82-89% to a concentrated sulfuric acid solution with a sulfuric acid concentration of at least 90% , the method comprising:evaporating water from the first aqueous sulfuric acid solution in an evaporator vessel to the concentrated sulfuric acid solution; and the piping system is operating at a temperature of at least 180° C., and', 'the sulfuric acid concentration of the second aqueous sulfuric acid solution is at least 90%., 'pumping around a mixture of the first aqueous sulfuric acid solution, part of the concentrated sulfuric acid solution, a second aqueous sulfuric acid solution, and hydrogen peroxide through an enameled piping system comprising the evaporator vessel and one or more heaters and pumps, wherein'}2. The method according to claim 1 , wherein the concentrated sulfuric acid solution has a sulfuric acid concentration of 90 to 105%.3. The method according to claim 1 , wherein the second sulfuric acid solution is a fraction of the concentrated sulfuric acid solution.4. The method ...

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19-09-2013 дата публикации

AMINE TREATING PROCESS FOR SELECTIVE ACID GAS SEPARATION

Номер: US20130243677A1

A process for the selective separation of hydrogen sulfide from gas mixtures containing carbon dioxide as well as other acidic gases uses severely sterically hindered amino alcohol absorbents based on amino alcohols and ethers containing secondary nitrogen atoms hindered by an alpha tertiary carbon atom. Preferred absorbents include 2-(N-methylamino)-2-methylpropan-1-ol, (2-(N-ethylamino))-2-methylpropan-1-ol, (2-(N-isopropylamino)-2-methylpropan-1-ol, SBAE (2-(N-sec-butylamino)-2-methylpropan-1-ol) and (2-(N-t-butylamino)-2-methylpropan-1-ol. 2. A process according to in which Ris CH.3. A process according to in which Rand Rare each CHor CH4. A process according to in which at least one of R claim 1 , Rand Ris a tertiary alkyl group.5. A process according to in which Ris a tertiary alkyl group.6. A process according to in which Ris tertiary butyl.7. A process according to in which Ris OH8. A process according to in which n is an integer from 1 to 4 claim 1 , preferably 1-3.9. A process according to in which Ris CH claim 1 , Rand Rare CHor CH claim 1 , Ris OH and n is 1.10. A process according to in which the compound is 2-(N-methylamino)-2-methyl propan-1-ol.11. A process according to in which the acid gas mixture is contacted with an aqueous solution of the compound.12. A process according to in which the acid gas mixture is contacted with anon-aqueous solution of the compound.13. A process according to in which the acid gas mixture is contacted with a solid grafted or impregnated with the compound.14. A process according to in which the acid gas mixture is contacted with the compound for a contact time less than 10 minutes15. A process according to in which the acid gas mixture is contacted with the compound for a contact time less than 1 minute16. A process according to in which the acid gas mixture is contacted with the compound for a contact time less than 10 seconds.17. A process according to in which the acid gas mixture is contacted with the compound for a ...

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19-09-2013 дата публикации

COMPOSITE CATALYTIC MEMBRANE APPLIED TO CATALYTIC ESTERIFICATION AND PREPARATION METHOD THEREOF

Номер: US20130244861A1
Принадлежит: TIANJIN POLYTECHNIC UNIVERSITY

A composite catalytic membrane applied to catalytic esterification and preparation method thereof are provided. The composite catalytic membrane is porous, and includes nonwoven fabric as base membrane and catalytic coating which is formed on the surface of nonwoven fabric and in the pores and gaps between the nonwoven fabric fibers. The catalytic coating uses solid acid as catalyst and polymer or modified sulfonated polymer as membrane-forming material. The membrane is formed by coating or immersion method, and the composite catalytic membrane is obtained by cross-linking after forming. The greenization and high efficiency of catalytic esterification and preparation of biodiesel can be achieved owing to the microporous structure and huge specific surface area of the composite catalytic membrane. The composite catalytic membrane has high mechanical strength, good reproducibility and stability and easily enables continuous repetitive production of catalytic esterification. The process is simple and easy to control and scale-up. 1. A composite catalytic film for catalyzing esterification , wherein the film comprises a porous structure with nonwoven fabric as a base membrane and with a catalytic coating on a surface of the fabric as well as in gaps between the fibers , and wherein said coating uses a solid acid as a catalyst and a modified sulfonated polymer as a film-forming material.2. The composite catalytic film for catalyzing esterification according to claim 1 , wherein said modified sulfonated polymer is derived from a precursor which is modified by sulfonation wherein a degree of substitution of the sulfonated group is greater than 0 and less than or equal to 50% claim 1 , and wherein said polymer is at least one of polyvinyl alcohol claim 1 , polyethylene-vinyl alcohol claim 1 , polyvinylidene fluoride claim 1 , polyacrylonitrile claim 1 , cellulose acetate claim 1 , polysulfone and polyether sulfone.3. The composite catalytic film for catalyzing ...

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19-09-2013 дата публикации

Supported Catalyst of Digestion Residues of Titanyl Sulphate-Containing Black Solution

Номер: US20130244869A1
Автор: Auer Gerhard, Hipler Frank
Принадлежит: SACHTLEBEN PIGMENT GMBH

A composition includes titanium dioxide-containing digestion residue from titanium dioxide production, and at least one further component which is catalytically active. Dimensionally stable, catalytically active solids which are obtained from this composition can be used as catalyst, for example for minimizing nitrogen oxides. 1. A composition , comprising:an insoluble digestion residue occurring in the production of titanium dioxide using the sulphate process upon digestion of the titanium-bearing starting material with sulphuric acid, andat least one further component which is catalytically active comprising one or more tungsten- or vanadium-compounds,{'sub': 3', '2', '3, 'wherein the composition comprises at least 1.0% by weight tungsten, calculated as WO, and/or at least 0.05% by weight vanadium, calculated as VO, with respect to the solids content of the composition.'}2. A composition according to claim 1 , whereinthe digestion residue has been partially neutralised,optionally the impurities of the digestion residue, in particular the neutral salts, have been partially washed out, andoptionally the composition has been calcined.3. A composition according to claim 1 , wherein the sulphate content of the digestion residue is 1.0 to 6.0% by weight claim 1 , with respect to the solids content of the digestion residue.4. A composition according to claim 1 , wherein a pH value of the composition is adjusted to 1 to 5.5. A composition according to claim 1 , wherein it is present in the form of a filter cake or a suspension with a solids content of less than 90% by weight.6. A composition according to claim 1 , having has a Ti-content of 6 to 54% by weight.7. A composition according to claim 1 , wherein after calcination has a BET surface area of 3 to 70 m/g.8. A composition according to claim 1 , wherein it has a sulphate content of 0.1 to 10% by weight claim 1 , with respect to the solids proportion of the composition.9. A composition according to claim 1 , wherein ...

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03-10-2013 дата публикации

REMOVING SULPHUR OXIDES FROM A FLUID STREAM

Номер: US20130259789A1
Принадлежит:

A process for removing sulphur oxides from a fluid stream, such as flue gas, that comprises a) providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the non-aqueous absorption liquid being incompletely miscible with water: b) treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex: c) causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; d) separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas. 123.-. (canceled)24. A process for removing sulphur oxides from a fluid stream comprisinga) providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the non-aqueous absorption liquid being incompletely miscible with water;b) treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex;c) causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid;d) separating the aqueous liquid from the non-aqueous absorption liquid.25. The process of claim 24 , wherein the non-aqueous absorption liquid is caused to be in ...

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10-10-2013 дата публикации

POLYSILICATE-POLYSILICONE ENZYME IMMOBILIZATION MATERIALS

Номер: US20130267004A1
Принадлежит: AKERMIN, INC.

The present invention generally relates to improvements in enzyme immobilization, particularly for use in the field of carbon dioxide capture and sequestering. It has been discovered that the utilization of sol-gel processes to immobilize enzymes in polysilicate-polysilicone copolymer coatings and particles, and the deposition of these coatings on solid state supports or use of suspensions of these particles, provides significant benefits for use in industrial applications involving enzymatic catalysts. 13-. (canceled)4. A coated support comprising a polysilicate-polysilicone copolymer immobilizing a biocatalyst; the polysilicate-polysilicone copolymer adhered to a solid support by an adhesive coating and wherein the biocatalyst comprises a carbonic anhydrase.56-. (canceled)7. A coated support comprisinga solid support;a coating composition forming a layer on the surface of the solid support, the coating composition comprising a polysilicate-polysilicone copolymer and a hydrophilic additive; anda biocatalyst that catalyzes hydration of carbon dioxide being entrapped in the coating composition;wherein the biocatalyst comprises a carbonic anhydrase.8. (canceled)9. The coated support of wherein the adhesive coating comprises a polymer adhesive.10. The coated support of wherein the polymer adhesive comprises a urethane polymer claim 9 , an epoxy polymer claim 9 , a resin claim 9 , a cyanoacrylate polymer claim 9 , a methacrylate polymer claim 9 , or a combination thereof.1112-. (canceled)13. The coated support of wherein the polymer adhesive comprises a two-part epoxy polymer.14. (canceled)15. The coated support of wherein the coating composition is derived from reaction of a sol claim 7 , the sol comprising (i) an alkoxy silane or an organotrialkoxy silane or metasilicate claim 7 , (ii) a poly(silicone) claim 7 , (iii) a hydrophilic additive claim 7 , and (iv) the carbonic anhydrase.16. The coated support of wherein the coating composition is derived from reaction of ...

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24-10-2013 дата публикации

Sterically Hindered Amines and Associated Methods

Номер: US20130280155A1
Принадлежит: Huntsman Petrochemical LLC

Amine compositions comprising sterically hindered amines and associated methods are provided. In some embodiments, amine compositions of the present disclosure may be useful for selective removal of HS from an acidic gas stream. 2. The amine composition of wherein x is an integer from 7 to 14.3. The amine composition of wherein y is an integer from 7 to 14.4. The amine composition of wherein x is an integer from 7 to 14 and y is an integer from 7 to 14.5. The amine composition of wherein the weight ratio of the first amine to the second amine is about 4:1.7. The method of wherein x is an integer from 7 to 14.8. The method of wherein y is an integer from 7 to 14.9. The method of wherein x is an integer from 7 to 14 and y is an integer from 7 to 14.10. The method of wherein the weight ratio of the first amine to the second amine is about 4:1.11. The method of wherein the polyethylene glycol has a molecular weight of from about 180 to 1000 g/mol.12. The method of wherein the polyethylene glycol has a molecular weight of from about 180 to 400 g/mol.13. The method of further comprising contacting a gaseous stream comprising sulfur-containing compounds with the amine composition.14. The method of wherein the polyethylene glycol and the tertiarybutylamine are reacted in a fixed-bed reactor claim 6 , a fluid-bed reactor claim 6 , a continuous stirred reactor or a batch reactor.15. The method of wherein the polyethylene glycol and the tertiarybutylamine are reacted at a temperature of from about 160° C. to about 240° C.17. The method of further comprising contacting the gaseous stream with a strong acid.18. The method of wherein the strong acid is phosphoric acid or sulfuric acid.19. The method of wherein x is an integer from 7 to 14 and y is an integer from 7 to 14.20. The method of wherein the weight ratio of the first amine to the second amine is about 4:1. This application claims the benefit of U.S. Provisional Patent Application Ser. No. 61/418,425 filed Dec. 1, 2010, ...

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31-10-2013 дата публикации

SODIUM THIOSULFATE-CONTAINING PHARMACEUTICAL COMPOSITIONS

Номер: US20130287676A1
Принадлежит:

Provided herein are pharmaceutically acceptable sodium thiosulfate and pharmaceutical compositions thereof. Also provided herein are methods for determining the total non-purgeable organic carbon in a sodium thiosulfate-containing sample. Further provided herein are methods for producing pharmaceutically acceptable sodium thiosulfate. Still further provided herein are methods of treatment comprising the administration of pharmaceutically acceptable sodium thiosulfate. 120-. (canceled)21. A method for preparing pharmaceutical grade sodium thiosulfate pentahydrate comprising:a) contacting sodium sulfite with sulfur in a solvent at a temperature of between about 90° C. and about 110° C., wherein the pH after about 4 hours of the resulting mixture is from about 7 to about 9;b) cooling the mixture to between about 15° C. and about 25° C.;c) adding a base to the mixture until the pH of the mixture is basic;d) filtering the mixture to yield a solution;e) distilling the solution at between about 50° C. and about 100° C. to a gravity of between about 1.20 to about 1.70;f) contacting the solution with activated carbon at between about 45° C. and about 55° C.;g) filtering the solution to remove the activated carbon;h) cooling the solution to between about 15° C. and about 25° C. and adding a seed crystal of sodium thiosulfate pentahydrate;i) cooling the solution to between about 0° C. and about 10° C. and filtering the solution; andj) drying the sodium thiosulfate pentahydrate at about 35° C. until the water content of the sodium thiosulfate pentahydrate is between about 34% weight and about 36.8% weight.22. The method of claim 21 , wherein the contacting of the sodium sulfite and the sulfur is conducted under an inert atmosphere.23. The method of claim 21 , wherein the sodium sulfite and the sulfur are contacted in water.24. The method of claim 21 , wherein the sodium sulfite and the sulfur are contacted in water for about 4 hours.25. The method of claim 21 , wherein the base ...

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07-11-2013 дата публикации

PROCESS FOR PRODUCING SULFUR DIOXIDE AND SULFUR TRIOXIDE

Номер: US20130295001A1
Принадлежит: Albemarle Corporation

SOis formed from a replenished circulating inventory of fresh and recycled SO. Also, a feed stream of replenished SOis heated by indirect heat exchange with a hot stream of SOand SOwhereby the hot stream is cooled for separating the two gases. The heated feed stream of replenished SOserves as a hot gaseous feed to a sulfur burner. This SOfeed is divided into two feed streams, one being oxygenated with pure oxygen and the other remains as an SOfeed. These feeds plus a feed of molten sulfur are concurrently and separately introduced into the sulfur burner where additional SOis formed via continuous exothermic reaction. Although heated, the oxygenated feed(s) of SObring in the needed oxygen for the reaction and the feeds of the oxygenated and non-oxygenated SOserve as a heat sink in the sulfur burner to reduce the temperature therein. 1. A process for producing sulfur trioxide from a replenished circulating inventory of sulfur dioxide , which process comprises:{'sub': 2', '2', '2', '2', '2', '2', '2', '2, 'A) dividing a stream of gaseous SOinto a first gaseous SOstream and a second gaseous SOstream, adding a controlled amount of pure oxygen into the first gaseous SOstream and concurrently and separately feeding (i) the resultant oxygenated first gaseous SOstream into an upstream stage of a sulfur burner having an upstream stage and a downstream stage, and (iii) the second gaseous SOstream into the downstream stage of said sulfur burner while concurrently feeding molten sulfur into said upstream stage of the sulfur burner so that additional SOis formed in the sulfur burner via a continuous exothermic reaction taking place in said sulfur burner, said first and second feeds reducing the temperature of the exothermic reaction in the sulfur burner, and the proportions of pure oxygen and sulfur being fed to the sulfur burner providing a gaseous exit stream of gaseous SOand free oxygen;'}{'sub': 3', '2', '3', '2', '3, 'B) feeding said gaseous exit stream into a catalytic ...

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28-11-2013 дата публикации

REGENERATIVE RECOVERY OF CONTAMINANTS FROM EFFLUENT GASES

Номер: US20130315807A1
Принадлежит: MECS, Inc.

This invention relates to processes for the selective removal of contaminants from effluent gases. More particularly, various embodiments of the present invention relate to selective removal and recovery of sulfur dioxide from effluent gases in a regenerative sulfur dioxide absorption/desorption process that achieves favorable energy efficiency. Energy is recovered from a wet stripper overhead gas stream produced in the desorption cycle by indirect transfer of heat from the stripper gas to a cooling medium and used to generate steam for use in stripping contaminants from the absorption liquor. The absorption zone may optionally be cooled to enhance the capacity of the absorption medium for absorption of a contaminant gas, thereby lowering the volume of absorption medium and contaminant-enriched absorption liquor that must be pumped, handled, heated and cooled in the absorption/desorption cycle. 1. A process for selectively removing and recovering a contaminant gas from a contaminant-containing source gas , the process comprising:contacting a feed gas stream comprising the source gas in a contaminant gas absorber with an aqueous absorption medium comprising a sorbent for the contaminant gas, thereby absorbing contaminant gas from the feed gas stream into the absorption medium and producing an exhaust gas from which contaminant gas has been removed and a contaminant-enriched absorption liquor;contacting the contaminant-enriched absorption liquor with stripping steam in an absorption liquor stripper to desorb the contaminant from the contaminant-enriched absorption liquor and thereby produce a regenerated contaminant absorption medium and a primary stripper gas effluent comprising water vapor and contaminant gas;withdrawing regenerated absorption medium from a liquid outlet of the absorption liquor stripper and primary stripper gas effluent from a vapor outlet of the absorption liquor stripper;compressing the primary stripper gas effluent;condensing water from the ...

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12-12-2013 дата публикации

RECOVERY OF SULFUR FROM SULFUR-CONTAINING WASTE

Номер: US20130330266A1
Принадлежит:

The invention provides an environmentally friendly industrial process for treating sulfur-containing waste, resulting in recovered pure sulfur and a sulfur-free ash for landfilling. 1. A process for disposing of sulfur-containing waste , comprising the steps ofi) heating a sulfur-containing waste in a receptacle at a temperature of between 120 and 160°, thereby obtaining a mixture comprising raw molten sulfur;ii) optionally separating solids, by rough screening, from said mixture obtained in step i);iii) transferring said mixture obtained in step i) optionally screened as in said step ii) from said receptacle to a separating reactor heated at a temperature of between 450 and 500° C., whereby creating sulfur vapor and sulfur-free solid phase;iv) transferring said sulfur vapor formed in step iii) from said reactor to a condenser cooled to a temperature of between 120 and 140° C., whereby obtaining molten sulfur;v) transferring said solid phase formed in step iii) from said reactor to a cooling conveyor, and collecting said phase as an ash for landfilling; andvi) removing gases from said condenser by means of an off-gas cleaner, and collecting from said condenser essentially pure sulfur.2. A process according to claim 1 , further comprising a step of recovering heat from said sulfur condenser by transferring said heat to water vapor.3. A process according to claim 1 , further comprising a step of recovering heat from said cooling conveyor.4. A process according to claim 1 , wherein said step ii) of separating comprises screening.5. A process according to claim 1 , comprising converting harmful waste to essentially pure sulfur product and to an essentially sulfur-free solid waste for landfilling.6. A process according to claim 5 , wherein said sulfur product contains at least 99.0 wt % sulfur.7. A process according to claim 5 , wherein said solid for landfilling contains less than 1 wt % sulfur.8. A process according to claim 5 , wherein said sulfur product contains at ...

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19-12-2013 дата публикации

Low Temperature Sulphur Dioxide Oxidation Catalyst for Sulfuric Acid Manufacture

Номер: US20130336876A1
Принадлежит:

Improved catalysts for oxidation of sulfur dioxide which are alkali metal-promoted vanadium catalysts which are further promoted by gold. Improved methods employing such catalyst for oxidation of sulfur dioxide and for manufacture of sulfuric acid. Improved methods for multiple step oxidation of sulfur dioxide in which the last oxidation step is carried out employing improved catalysts of this invention at temperatures lower than 400° C. 1. A method for the oxidation of SOwhich comprises the step of contacting a gas stream comprising SOand Oat temperatures between 275° C. and 450° C. with a catalyst comprising vanadium , one or more alkali metals and gold.2. The method of wherein the catalyst is a supported catalyst comprising 0.005-5 wt % of gold and the atomic ratio of total alkali metal to vanadium ranges from 0.1 to 10.34.-. (canceled)5. The method of wherein the catalyst is a supported catalyst comprising 0.01-1 wt % of gold claim 1 , 5-15 wt % vanadium and 5-30 wt % alkali metal.6. The method of wherein the catalyst further comprises a second promoter metal selected from aluminum claim 1 , magnesium claim 1 , yttrium claim 1 , lanthanum or mixtures thereof.7. The method of wherein the catalyst further comprises a second promoter metal (P2) selected from aluminum claim 1 , magnesium claim 1 , yttrium claim 1 , lanthanum or mixtures thereof and wherein the atomic ratio of P2:V ranges from 0.1:1 to 1:1.8. The method of wherein the catalyst further comprises a second promoter metal (P2) selected from aluminum claim 1 , magnesium claim 1 , yttrium claim 1 , lanthanum or mixtures thereof and wherein the second promoter is present in an amount ranging from 0.5 to 10 wt % in the catalyst.9. The method of wherein the catalyst is supported on silica claim 1 , alumina claim 1 , silica-alumina claim 1 , titania claim 1 , clay claim 1 , zeolite claim 1 , zirconia claim 1 , ceria claim 1 , cordierite claim 1 , mullite claim 1 , mullite-alumina claim 1 , or mixtures thereof. ...

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26-12-2013 дата публикации

DEVICE FOR EVAPORATING A LIQUID AND RELATED METHOD

Номер: US20130341809A1
Автор: Sardo Alberto
Принадлежит: XEDA INTERNATIONAL

Device () for evaporating a liquid, includes: a reservoir () containing the liquid; an organ for absorbing the liquid (); and an organ for producing a gas flow (), which is directed towards the absorption organ (); characterized in that the absorption organ () includes a plurality of absorbent strips () suited to retain the liquid. 110110. Device ( , ) for evaporating a liquid , including:{'b': '14', 'a reservoir () containing the liquid;'}{'b': '16', 'an organ for absorbing the liquid (); and'}{'b': 18', '16, 'an organ for producing a gas flow (), which is directed towards the absorption organ ();'}{'b': 16', '24, 'characterised in that the absorption organ () comprises a plurality of absorbent strips () suited to retain the liquid.'}210110. Device ( claim 1 , ) according to claim 1 , characterised in that the liquid comprises at least one essential oil claim 1 , a volatile synthetic product claim 1 , water claim 1 , pyrethrum claim 1 , synthetic pyrethrins claim 1 , or volatile synthetic molecules with biocidal properties.310110. Device ( claim 2 , ) according to claim 2 , characterised in that the/each essential oil is chosen from mint oil claim 2 , clove oil claim 2 , rose oil claim 2 , thyme oil claim 2 , oregano oil claim 2 , or at least one of their constituents from the group of L-carvone claim 2 , eugenol claim 2 , geraniol claim 2 , thymol claim 2 , or carvacrol.410110. Device ( claim 1 , ) according to claim 1 , characterised in that the gas flow is at a temperature below 50° C.510110201614. Device ( claim 1 , ) according to claim 1 , characterised in that it comprises an organ for injecting () liquid into the absorption organ () from the reservoir ().6101102038. Device ( claim 5 , ) according to claim 5 , characterised in that the injection organ () comprises a dosing pump ().7101102628203626. Device ( claim 5 , ) according to claim 5 , characterised in that each strip has a first end () and a second end () claim 5 , and that the injection organ () has a ...

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26-12-2013 дата публикации

Process and Apparatus for Production of a Granular Urea Product

Номер: US20130344239A1
Автор: Bedetti Gianfranco
Принадлежит: Urea Casale SA

A process for production of a granular urea product in a fluidized-bed where: small droplets () of fresh urea melt are contacted with a cooling medium to form solid particles, said solid particles () are contacted with droplets of urea melt () which are larger than said germ particles, the solid particles and said droplets forming together larger solid particles (), and said solid particles further increasing their size step by step and upon contact with droplets of urea melt, until the solid particles reaches a given size, and said solid particles are then subject to a further growing process by contact with liquid droplets now smaller than the solid particles, until a desired size of the granular product is reached. 1. A process for production of a granular urea product comprising the steps of:a) contacting small droplets of fresh urea melt with a cooling medium to foam solid starting particles,b) contacting said starting particles with droplets of urea melt which are larger than said particles, the solid particles and said droplets forming together larger solid particles, and said solid particles further increasing their size step-by-step upon contact with larger droplets of urea melt, until the solid particles reaches a given size, andc) subjecting said solid particles to a further growing process by contact with liquid droplets now smaller than the solid particles, until a desired size of the granular product is reached.2. The process according to claim 1 , said small droplets which form the starting particles having an average size equal to or less than 200 μm (0.2 mm) and preferably in a range 50-200 μm (0.05-0.2 mm).3. The process according to claim 2 , the solid particles obtained after step b) having an average size of around 0.5 mm and preferably in the range 0.5 to 1 mm.4. The process according to claim 1 , a fluidized-bed state being maintained at least in the stage c) of the process with air which also acts as the cooling medium.5. The process ...

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26-12-2013 дата публикации

SYNTHESIS OF THIOETHER CONTAINING TRIALKOXYSILANES

Номер: US20130345412A1

The invention relates to a radical-initiated thiol-ene or thiol-yne “click” reaction that provides a simple and efficient route to diverse trialkoxysilanes. Trialkoxysilanes made in this way are obtained in quantitative to near-quantitative yields with high purity without any or minimal purification. A wide range of functional groups is tolerated in this approach, and even complex alkenes click with the silane precursors. The modular nature of these radical-based thiol-ene or thiol-yne “click” reactions allows a wide variety of pendant groups to be coupled to silane compounds that can then be coupled to a wide variety surfaces in order to modify their material properties. Consequently, such radical initiated thiol-ene and thiol-yne reactions provide facile and efficient methods for preparing an enormous number of surface-active functional trialkoxysilanes. 1. A method for making a trialkoxysilane compound comprising a thioether , the method comprising the steps of: a trialkoxysilane compound;', 'a compound comprising a sulfhydryl moiety;', 'an alkene compound or an alkyne compound; and', 'a radical initiator agent;, '(a) forming a mixture comprising the radical initiator agent reacts with a hydrogen atom in a first sulfhydryl moiety so as to form a thiyl radical;', 'the thiyl radical reacts with the alkene or the alkyne so as to form a radical intermediate;', 'the radical intermediate reacts with a hydrogen atom in a second thiol moiety so as to form a thioether;, '(b) initiating a chemical reaction in the mixture so thatso that the trialkoxysilane compound comprising the thioether is made; andthe chemical reaction in (b) produces a composition of matter wherein the trialkoxysilane compound comprising the thioether has a purity of at least 90%.2. The method of claim 1 , wherein:the trialkoxysilane compound comprises the sulfhydryl moiety; orthe trialkoxysilane compound is the alkene compound.3. The method of claim 1 , further comprising placing the composition of ...

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02-01-2014 дата публикации

Process for the combustion of a liquid

Номер: US20140004034A1
Принадлежит: OUTOTEC OYJ, SAACKE GmbH

A process for the combustion of a liquid in a combustion chamber includes atomizing liquid sulfur using a rotary atomizer and introducing the liquid sulfur into the combustion chamber. The liquid sulfur is charged onto an inside of a cup. The cup is rotated so as to form a liquid film on the inside of the cup and so that parts of the liquid film arc radially flung off from an edge of the cup edge into the combustion chamber. The rotational speed of the cup is varied so as to control a thickness of the liquid film in the cup to between 200 and 1000 μm. The liquid sulfur is evaporated and subsequently burnt in the combustion chamber.

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09-01-2014 дата публикации

Reactor for Carrying Out an Exothermic Reaction in the Gas Phase

Номер: US20140010751A1
Принадлежит: BASF SE

The invention relates to a reactor for carrying out an exothermic reaction in the gas phase, which comprises a vessel having an outer wall () composed of a metallic material, wherein an inner shell () is accommodated in the interior of the reactor () and the inner shell () has a spacing of at least 50 mm to the inside of the outer wall (). 1131711713. A reactor for carrying out an exothermic reaction in the gas phase , which comprises a vessel having an outer wall () composed of a metallic material , wherein an inner shell () is accommodated in the interior of the reactor () and the inner shell () has a spacing of at least 50 mm to the inside of the outer wall ().21713. The reactor according to claim 1 , wherein the inner shell () is made of the same material as the outer wall ().319171. The reactor according to claim 1 , wherein there is a gap () between the inner shell () and the bottom and/or lid of the reactor ().41. The reactor according to claim 1 , wherein at least one tray is accommodated in the reactor ().571. The reactor according to claim 1 , wherein a catalyst bed () is present in the reactor ().6133379. The reactor according to claim 1 , wherein the reactor () is divided into a plurality of segments () claim 1 , with each segment () having at least one inlet and at least one outlet and each segment () comprising a catalyst bed () and a gas space () above the catalyst bed.77. The reactor according to claim 5 , wherein the catalyst bed () comprises a heterogeneous catalyst.82313. The reactor according to claim 6 , wherein an intermediate tray () is accommodated in the reactor () to separate in each case two segments ().9. The use of the reactor according to for carrying out an exothermic reaction in the gas phase claim 1 , wherein the reaction is carried out at a temperature above 300° C.10. The use of the reactor according to for carrying out a reaction of sulfur dioxide with oxygen to form SO.117. The reactor according to claim 6 , wherein the catalyst ...

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16-01-2014 дата публикации

Hydrogen sulphide sampling method

Номер: US20140017144A1
Принадлежит: TOTAL SE

A method for sampling a sulphur-containing solid product including supplying a gas flow comprising hydrogen sulphide, bringing the gas flow into contact with a solid reagent and reacting the solid reagent with the hydrogen sulphide contained in the gas flow, the reaction fixing the sulphur of the hydrogen sulphide by forming a sulphur-containing solid product which is different in colour from the solid reagent, and recovering the sulphur-containing solid product. The invention also relates to a device suitable for the implementation of this method.

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16-01-2014 дата публикации

N-FUNCTIONALIZED IMIDAZOLE-CONTAINING SYSTEMS AND METHODS OF USE

Номер: US20140017153A1
Автор: Bara Jason E.
Принадлежит:

Systems containing imidazoles or blends of imidazoles and amines are described herein. Methods of their preparation and use are also described herein. The methods of using the systems include the reduction of volatile compounds from gas streams and liquid streams. 141-. (canceled)42. A method for removing a volatile compound from a stream , comprising:contacting the stream with a solvent system comprising an N-functionalized imidazole,wherein the N-functionalized imidazole is non-ionic under neutral conditions and is from about 20% to about 80% by weight of the solvent system, andwherein the volatile compound comprises carbon dioxide, carbon monoxide, sulfur dioxide, hydrogen sulfide, thiols, nitrogen oxide, nitrogen dioxide, carbonyl sulfide, carbon disulfide, or any mixture thereof.43. The method of claim 42 , wherein the N-functionalized imidazole comprises from about 30% to about 70% by weight of the solvent system.46. The method of claim 45 , wherein the amine is monoethanolamine claim 45 , N-methylethanolamine claim 45 , diglycolamine claim 45 , diethanolamine claim 45 , or N-methyldiethanolamine.47. The method of claim 45 , wherein the amine is 2-amino-2-methylpropanol.48. The method of claim 45 , wherein the amine is diisopropanolamine.49. The method of claim 45 , wherein the amine is substituted or unsubstituted piperazine.50. The method of claim 45 , wherein the N-functionalized imidazole and the amine are present in the solvent system in a weight ratio from 9:1 to 1:9.51. The method of claim 42 , wherein the stream is a natural gas stream claim 42 , a synthesis gas claim 42 , a liquid hydrocarbon stream claim 42 , or a flue gas stream.52. The method of claim 42 , further comprising regenerating the solvent system by heating claim 42 , applying vacuum or any combination thereof to regenerate the solvent system.53. The method of claim 42 , wherein the solvent system further comprises water.54. A solvent system for capturing a volatile compound from a stream ...

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16-01-2014 дата публикации

Sulfur recovery unit and sulfur recovery method

Номер: US20140017162A1
Принадлежит: JGC Corp

A sulfur recovery unit comprising: a reaction furnace configured to carry out a high-temperature Claus reaction between hydrogen-sulfide-containing gas and oxygen-containing gas introduced to the reaction furnace; a sulfur condenser configured to cool reaction gas discharged from the reaction furnace and condense sulfur contained in the reaction gas; and a pipe that connects the reaction furnace to the sulfur condenser, wherein the reaction furnace is fixed to the ground; and the sulfur condenser and the pipe are arranged so as to be able to move relative to the reaction furnace.

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16-01-2014 дата публикации

VANADIA-TITANIA CATALYST FOR REMOVING NITROGEN OXIDES AND METHOD FOR MANUFACTURING THE SAME

Номер: US20140018237A1

Provided is a method for preparing a vanadia-titania catalyst, comprising: vaporizing a titanium precursor; conveying the vaporized titanium precursor to a reaction unit together with an oxygen supplying source; reacting the vaporized titanium precursor conveyed to the reaction unit with the oxygen supplying source to produce titania particles; condensing the titania particles, collecting and recovering them; mixing the recovered titania particles with a vanadium precursor solution; drying the mixture of the titania particles with the vanadium precursor solution; and calcining the dried mixture under oxygen atmosphere or air. Provided also is a vanadia-titania catalyst obtained by the method. In the vanadia-titania catalyst, titania particles (carriers) are prepared by chemical vapor condensation, and then vanadia is supported on the titania particles (carriers) through impregnation and calcining. Therefore, the vanadia-titania catalyst has a large specific surface area, uniform and fine nano-scaled size, and high dispersibility, thereby providing excellent nitrogen oxide removal efficiency, particularly in a low temperature range of 200° C.-250° C. 1. A method for preparing a vanadia-titania catalyst , comprising:vaporizing a titanium precursor;conveying the vaporized titanium precursor to a reaction unit together with an oxygen supplying source;reacting the vaporized titanium precursor conveyed to the reaction unit with the oxygen supplying source to produce titania particles;condensing the titania particles, collecting and recovering them;mixing the recovered titania particles with a vanadium precursor solution;drying the mixture of the titania particles with the vanadium precursor solution; andcalcining the dried mixture under oxygen atmosphere or air.2. The method for preparing a vanadia-titania catalyst according to claim 1 , wherein said recovering the titania particles comprises cooling the titania particles to condense them and collecting the condensed ...

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16-01-2014 дата публикации

PERFORMANCE OF A HYDROCARBON CONVERSION OR PROCESSING OF A HYDROCARBON CONVERSION IN APPARATUSES WITH SURFACES MADE FROM NONMETALLIC MATERIALS

Номер: US20140018590A1
Принадлежит:

The present invention relates to a process for performing a hydrocarbon conversion or processing an output from a hydrocarbon conversion in the presence of an acidic ionic liquid. The hydrocarbon conversion, which is preferably an isomerization, is performed in apparatuses whose surfaces which come into contact with the acidic ionic liquid have been manufactured completely or at least partially from at least one nonmetallic material. The nonmetallic material in turn has been applied to at least one further material other than the nonmetallic material. 119.-. (canceled)20. A process for performing a hydrocarbon conversion or processing an output from a hydrocarbon conversion in the presence of an acidic ionic liquid using at least one apparatus (V1) , wherein the surfaces of the apparatus (V1) which come into contact with the acidic ionic liquid have been manufactured completely or at least partially from at least one nonmetallic material (W1) , the nonmetallic material (W1) having been applied to at least one material (W2) other than the nonmetallic material (W1).21. The process according to claim 20 , wherein the nonmetallic material (W1) is an oxidic material or a polymer or the material (W2) is steel.22211. The process according to claim claim 20 , wherein the oxidic material is glass or the polymer is a fluorinated polymer.23. The process according to claim 22 , wherein the fluorinated polymer is polytetrafluoroethylene (PTFE) or a perfluoroalkoxy polymer (PFA).24. The process according to claim 20 , wherein the nonmetallic material (W1) is glass and forms an enamel with material (W2).25. The process according to claim 20 , wherein the nonmetallic material (W1) is a polymer with which apparatus (V1) has been coated or lined.26. The process according to claim 25 , wherein the nonmetallic material (W1) is a polymer with which apparatus (V1) is lined and materials (W1) and (W2) are bonded to one another.27. The process according to claim 26 , wherein materials (W1) ...

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30-01-2014 дата публикации

PROCESS FOR SEPARATION AND PURIFICATION OF SODIUM SULFIDE

Номер: US20140030185A1

The present disclosure provides a method for isolation and purification of sodium sulfide (NaS) formed during desulfurization of petroleum residue. The process involves treating a sludge containing NaS obtained during desulfurization of petroleum residue with a mixture of at least one organic solvent and water. 1. A method for isolation and purification of sodium sulfide (NaS) formed during desulfurization of petroleum residue; said method comprising treating a sludge containing NaS obtained during desulfurization of petroleum residue with a mixture of at least one organic solvent capable of dissolving the petroleum residue and water; allowing the treated sludge to separate into an organic phase containing petroleum oil and an aqueous phase containing NaS; and distilling the aqueous phase to obtain isolated NaS followed by purification.2. A method for recovering NaS and oil from a sludge resulting from desulfurization of petroleum residue; said method comprising the following steps:preparing a mixture of at least one organic solvent and water;adding the mixture to the sludge at a temperature of about 25 to 100° C. for a period of about 20 min to 2 hours under stirring and optionally cooling to obtain a solution;{'sub': '2', 'transferring the solution to a separating funnel and setting it aside to obtain a mixture containing an aqueous phase containing NaS and an organic phase containing petroleum oil; and'}{'sub': '2', 'distilling each of the two phases separately to recover the organic solvent and the oil from the organic phase and water and NaS from the aqueous phase respectively.'}3. The method as claimed in claim 1 , wherein the organic solvent is selected from the group consisting of alkanes claim 1 , aromatic hydrocarbons claim 1 , alkenes claim 1 , cyclic alkenes claim 1 , alkynes and mixtures thereof.4. The method as claimed in claim 1 , wherein the organic solvent is at least one hydrocarbon solvent selected from the group consisting of xylene claim 1 , n- ...

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20-02-2014 дата публикации

PROCESS FOR PRODUCTION OF SULPHURIC ACID

Номер: US20140048228A1
Принадлежит:

The invention relates to a condenser, having a process gas side and a heat transfer medium side said condenser being configured for feeding a hot process gas containing a condensable component to an inlet of the condensing side, and being further configured for withdrawing a cooled process gas from an outlet of the condensing side, and being even further configured for with-drawing a condensate in a position proximate to one end of the condenser, and said condenser having the process gas side divided in a process gas cooling zone configured for having a cool heat transfer medium inlet and a heated heat transfer medium outlet, and a process gas re-heating zone downstream the process gas cooling section, configured for re-heating of the process gas, as well as a processes for condensation and production of sulphuric acid employing such a condenser. 1. A sulphuric acid condenser , having a process gas side and a heat transfer medium sidesaid condenser being configured for feeding a hot process gas containing sulfuric acid to an inlet of the condensing side,and being further configured for withdrawing a cooled process gas from an outlet of the condensing side,and being even further configured for withdrawing a sulfuric acid or oleum condensate in a position proximate to one end of the condenser,and said condenser having the process gas side divided in a process gas cooling zone configured for having a cool heat transfer medium inlet and a heated heat transfer medium outlet,and a process gas re-heating zone downstream the process gas cooling section, configured for re-heating of the process gas.2. A condenser according to claim 1 , in which the condenser is configured for the process gas side of the process gas re-heating zone to receive thermal energy from the heated heat transfer medium.3. A condenser according to claim 2 , configured for the heat transfer medium and the process gas in the reheating zone to flow counter-current.4. A condenser according to claim 2 , ...

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20-02-2014 дата публикации

WET SCRUBBER FOR REMOVING SULFUR DIOXIDE FROM A PROCESS GAS

Номер: US20140050645A1
Автор: Åhman Stefan O.H.
Принадлежит: ALSTOM TECHNOLOGY, LTD.

A wet scrubber () for cleaning a process gas containing sulphur dioxide comprises an absorption vessel () operative for bringing the process gas into contact with an absorption liquid to absorb sulphur dioxide from the process gas. The wet scrubber () further comprises an acidification system () operative for mixing absorption liquid that has absorbed sulphur dioxide from the process gas with a carbon dioxide containing gas, an absorbent dissolution tank () operative for adding an absorbent material to at least a portion of the absorption liquid, and a return pipe () operative for returning to the absorption vessel () at least a portion of the absorption liquid that has been mixed with the carbon dioxide containing gas. 1. A method of cleaning a process gas containing sulphur dioxide by a wet scrubber , said method comprisingbringing the process gas into contact with an absorption liquid in an absorption vessel to absorb sulphur dioxide from the process gas,mixing the absorption liquid with a carbon dioxide containing gas comprising at least 20% by volume carbon dioxide,adding an absorbent material to at least a portion of the absorption liquid, andreturning at least a portion of the absorption liquid to the absorption vessel to absorb more sulphur dioxide from the process gas.2. A method according to claim 1 , wherein the mixing the absorption liquid with a carbon dioxide containing gas comprising at least 20% by volume carbon dioxide is carried out simultaneously with the step of adding an absorbent material to at least a portion of the absorption liquid.3. A method according to claim 1 , the method further comprising mixing the absorption liquid with an oxygen containing gas containing at least 3% by volume oxygen claim 1 , O claim 1 , prior to mixing the absorption liquid with the carbon dioxide containing gas comprising at least 20% by volume carbon dioxide.4. A method according to claim 3 , wherein the mixing the absorption liquid with an oxygen containing gas ...

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27-02-2014 дата публикации

WET TYPE EXHAUST GAS DESULFURIZATION APPARATUS

Номер: US20140056775A1
Автор: Inaba Norikazu
Принадлежит: MITSUBISHI HEAVY INDUSTRIES, LTD.

A wet type flue gas desulfurization apparatus desulfurizes flue gas existing inside an absorption tower by causing the flue gas to come into gas-liquid contact with an absorbent, and the absorbent is fed through a header pipe and sprayed through nozzles. In the apparatus, the absorbent accumulated inside the absorption tower is fed to the nozzles to circulate in the absorption tower. The apparatus includes: a bypass pipe feeding the absorbent through the nozzles from a downstream of the nozzles into the absorption tower; a tank arranged at an intermediate location on the bypass pipe; a perforated plate arranged inside the tank; and an access port opening on a side surface of the tank above the perforated plate to communicate between an inside and an outside of the tank. The absorbent that freely falls and passes through the perforated plate while scales or impurities are collected above the perforated plate. 1. A wet type flue gas desulfurization apparatus comprising:an absorption tower configured to desulfurize flue gas by causing the flue gas to come into gas-liquid contact with an absorbent;nozzles configured to spray the absorbent into the absorption tower;a header pipe configured to feed the absorbent to the nozzles;a circulation mechanism configured to feed the absorbent accumulated inside the absorption tower through the nozzles of the header pipe toward an upstream of a flow of the absorbent;a bypass pipe configured to feed the absorbent through the nozzles of the header pipe from a downstream of the nozzles into the absorption tower in a direction of flow of the absorbent;a tank arranged at an intermediate location on the bypass pipe in the direction of flow of the absorbent;a perforated plate being arranged inside the tank and having multiple transmission holes; andan access port that opens on a side surface of the tank to communicate between an inside and an outside of the tank;wherein the access port is arranged above the perforated plate, andwherein the ...

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27-02-2014 дата публикации

Process for producing sulfuric acid with low levels of nitrogen oxides

Номер: US20140056802A1
Принадлежит: EI Du Pont de Nemours and Co

A process for producing sulfuric acid with reduced levels of nitrogen oxides (NO x ) within a typical sulfuric acid production line. A hydrazine source material can be mixed with a sulfuric acid effluent at a temperature of at least about 90° C. for a period of at least 1 minute to reduce the level of NO x is the sulfuric acid effluent.

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06-03-2014 дата публикации

DESULPHURIZATION AND COOLING OF PROCESS GAS

Номер: US20140065046A1
Принадлежит: ALSTOM Technology Ltd

The present invention relates to a method of cleaning a process gas containing sulphur dioxide the method including removing sulphur dioxide from the process gas by contacting the process gas with seawater to generate an at least partly cleaned process gas in a first gas cleaning device. In a second gas cleaning device, being arranged in direct fluid connection with the first gas cleaning device, the at least partly cleaned process gas having passed through the first gas cleaning device is cooled to condense water there from, thereby generating a process gas having a reduced content of water vapour. At least a part of the condensed water generated in the second gas cleaning device is passed to the first gas cleaning device. The present invention moreover relates to a gas cleaning system for cleaning of a process gas containing sulphur dioxide. 1. A method of cleaning a process gas containing sulphur dioxide , comprisingin a first gas cleaning device, removing sulphur dioxide from the process gas by contacting the process gas with seawater to generate an at least partly cleaned process gas;in a second gas cleaning device being arranged in direct fluid connection with the first gas cleaning device, cooling the at least partly cleaned process gas having passed through the first gas cleaning device to condense water there from, thereby generating a process gas having a reduced content of water vapour, andpassing at least a part of the condensed water generated in the second gas cleaning device to the first gas cleaning device.2. The method according to claim 1 , wherein cooling in the second gas cleaning device comprises contacting the at least partly cleaned process gas with a cooling liquid to condense water there from claim 1 , thereby further generating a used cooling liquid.3. The method according to claim 2 , further comprisingpolishing, in the second gas cleaning device, the partly cleaned process gas to further remove sulphur dioxide there from, thereby ...

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06-03-2014 дата публикации

Process and apparatus for extracting sulfur compounds in a hydrocarbon stream

Номер: US20140066682A1
Принадлежит: UOP LLC

One exemplary embodiment can be a process for extracting sulfur compounds in a hydrocarbon stream. The process can include feeding a hydrocarbon stream containing sulfur compounds to a prewash zone containing an alkali, withdrawing a prewashed hydrocarbon stream from the prewash zone, and feeding the prewashed hydrocarbon stream to a mass transfer zone for extracting one or more thiol compounds from the prewashed hydrocarbon stream. Often, the mass transfer zone includes a hollow fiber membrane contactor.

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20-03-2014 дата публикации

Process for Reducing Sulfur Emission of Sulfur Plant

Номер: US20140079614A1
Принадлежит: CHINA PETROLEUM & CHEMICAL CORPORATION

The present invention provides a process for reducing sulfur emission of a sulfur plant, wherein the sulfur plant includes a thermal reaction unit, a catalytic reaction unit and a tail-gas purification unit, the process is characterized in that the waste-gas from the degassing of the liquid sulfur in the liquid sulfur tank is introduced into the catalytic reaction unit, and/or the waste-gas from the degassing of the liquid sulfur in the liquid sulfur tank is introduced into the tail-gas purification unit. In present invention, the H2S in purified tail-gas can be reduced to no more than 10 ppm(v) and the SOemission concentration of the sulfur plant can be reduced to no more than 100 mg/m. 1. A process for reducing sulfur emission of a sulfur plant , wherein the sulfur plant includes a thermal reaction unit , a catalytic reaction unit and a tail-gas purification unit , the process includes:{'sub': 2', '2', '2', '2', '2, 'introducing a HS-containing acid gas into the thermal reaction unit, combusting the HS-containing acid gas to produce SO, and conducting Claus reaction between HS and SOso as to produce element sulfur and a process gas, wherein the element sulfur is introduced into a liquid sulfur tank to obtain liquid sulfur;'}introducing the process gas into the catalytic reaction unit to carry out Claus catalytic conversion so as to obtain element sulfur and Claus tail-gas, wherein the obtained element sulfur is introduced into the liquid sulfur tank; and{'sub': 2', '2, 'introducing the Claus tail-gas into the tail-gas purification unit, wherein the Claus tail-gas firstly undergoes hydrogenation to produce a hydrogenation tail-gas, and then the hydrogenation tail-gas which comprises HS is cooled down and introduced into an absorption column, wherein HS is absorbed in the absorption column to provide a purified tail-gas;'}characterized in that the waste-gas from the degassing of the liquid sulfur in the liquid sulfur tank is introduced into the catalytic reaction ...

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20-03-2014 дата публикации

ENERGY RECOVERY IN MANUFACTURE OF SULFURIC ACID

Номер: US20140079624A1
Принадлежит: MECS INC

This invention relates to the recovery of energy in the manufacture of sulfuric acid, and more particularly to enhanced recovery of energy from the absorption of wet SOin sulfuric acid. The invention is further directed to control of mist formation during SOabsorption, and of the sulfuric acid mist content of the gas stream leaving the SOabsorption step in a process wherein SOabsorption energy is recovered from absorption acid in useful form. 1. A process for the preparation of sulfuric acid comprising:{'sub': '2', 'burning sulfur in a dry gas comprising excess oxygen to produce a sulfur oxide-bearing gas stream comprising a combustion gas comprising sulfur dioxide, oxygen and not more than 0.005 moles water vapor per mole SO;'}{'sub': '3', 'contacting the sulfur oxide-bearing gas stream comprising said combustion gas with a catalyst for conversion of sulfur dioxide to sulfur trioxide, thereby converting the sulfur oxide-bearing gas stream to a conversion gas containing not more than 0.005 moles water vapor per mole SO;'}contacting the conversion gas in a primary heat recovery absorption zone with an absorption liquid comprising sulfuric acid, thereby transferring sulfuric acid from the conversion gas to the absorption liquid;introducing water vapor into the sulfur oxide-bearing gas upstream of the primary absorption zone with respect to the direction of gas flow in a proportion sufficient to increase the equivalent water vapor content of the gas to at least about 0.55 moles per mole total equivalent sulfur oxide gas content prior to entry of the gas stream into the primary absorption zone; andcirculating said absorption liquid between said primary absorption zone and an indirect heat exchanger in which heat generated by reaction of sulfur trioxide and water, condensation of sulfuric acid, and/or absorption of sulfur trioxide into the absorption liquid is transferred to a heat transfer fluid, thereby heating the heat transfer fluid to at least 150° C.2. A process ...

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20-03-2014 дата публикации

EXHAUST GAS TREATMENT CATALYST AND METHOD FOR REGENERATING THE SAME

Номер: US20140080695A1
Принадлежит: MITSUBISHI HEAVY INDUSTRIES, LTD.

Provided are an exhaust gas treatment catalyst for denitrifying an exhaust gas including sulfur oxides and vanadium discharged from a heavy oil combustion boiler, including: a support comprising any one or all of titanium oxide and silica wherein a content of silica is from 10% to 20%, and an active component supported in the support and comprising one selected from the group consisting of vanadium and tungsten. 1. An exhaust gas treatment catalyst for denitrifying an exhaust gas including sulfur oxides and vanadium discharged from a heavy oil combustion boiler , comprising:a support comprising titanium and silica wherein a content of silica is 10% by mass or more, andan active component supported in the support and comprising one selected from the group consisting of vanadium and tungsten.2. The exhaust gas treatment catalyst according to claim 1 , further comprising a coating layer formed of at least one component selected from the group consisting of silicalite and metallosilicate on a surface of the exhaust gas treatment catalyst.3. A method for regenerating an exhaust gas treatment catalyst whose NOremoval performance is reduced by sulfur dioxides and vanadium included in an exhaust gas discharged from a heavy oil combustion boiler claim 1 ,the exhaust gas treatment catalyst comprising:titanium and silica; andan active component comprising one selected from the group consisting of vanadium and tungsten in a support having an Si content of 10% by mass or more, andthe method comprising:immersing the exhaust gas treatment catalyst in an alkali cleaning liquid at a concentration from 0.5 N to 2.0 N so as to remove vanadium oxysulfate on the surface of the exhaust gas treatment catalyst, andsubjecting the catalyst to activation treatment with an acid aqueous solution after cleaning the exhaust gas treatment catalyst with the alkali cleaning liquid.4. The method for regenerating an exhaust gas treatment catalyst according to claim 3 , wherein the exhaust gas ...

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27-03-2014 дата публикации

APPARATUS FOR PROVIDING GASEOUS SAMPLE IONS/MOLECULES AND A CORRESPONDING METHOD

Номер: US20140084154A1
Принадлежит:

An apparatus for providing gaseous sample ions/molecules from liquid droplets containing sample ions/molecules. The apparatus has a chamber having one or more walls which define an interior of the chamber, the chamber being configured to receive liquid droplets containing sample ions/molecules. The apparatus also has a gas flow producing means configured to produce a flow of gas within the chamber for promoting evaporation of liquid droplets in the chamber to provide gaseous sample ions/molecules. The apparatus is configured such that the flow of gas produced within the chamber inhibits liquid droplets in the chamber from coming into contact with the one or more walls of the chamber. 1. An apparatus for providing gaseous sample ions/molecules from liquid droplets containing sample ions/molecules , the apparatus having:a chamber having one or more walls which define an interior of the chamber, the chamber being configured to receive liquid droplets containing sample ions/molecules;a gas flow producing means configured to produce a flow of gas within the chamber for promoting evaporation of liquid droplets in the chamber to provide gaseous sample ions/molecules;wherein the apparatus is configured such that the flow of gas produced within the chamber inhibits liquid droplets in the chamber from coming into contact with the one or more walls of the chamber.2. An apparatus according to claim 1 , wherein the apparatus is configured such that the flow of gas produced within the chamber has a vortex or swirling structure in at least a region of space within the chamber.3. An apparatus according to wherein the flow of gas within the chamber has an inner region and an outer region in which the flow of gas has an axial velocity in a forward direction claim 1 , as well as an intermediate region claim 1 , between the inner region and outer region claim 1 , in which the flow of gas has an axial velocity in a reverse direction that is opposite to the forward direction.4. An ...

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27-03-2014 дата публикации

PROCESS FOR PREPARING LITHIUM SULFIDE

Номер: US20140084224A1
Принадлежит: Chemetall GmbH

The invention relates to a novel process for preparing lithium sulfide and to the use thereof, wherein a reaction of lithium-containing strong bases with hydrogen sulfide is undertaken in an aprotic organic solvent within the temperature range from −20 to 120° C. under inert conditions. The lithium sulfide obtained by the process is used as a positive material in a galvanic element or for the synthesis of Li ion-conductive solids, especially for the synthesis of glasses, glass ceramics or crystalline products. 110.-. (canceled)11. A method for preparing lithium sulfide comprising:reacting a lithium-containing strong base with hydrogen sulfide in an aprotic organic solvent at a temperature of from −20° to 120° C. under inert conditions.12. A method according to claim 11 , wherein the lithium-containing strong base is selected from the group consisting of a lithium alkylene claim 11 , a lithium arylene claim 11 , and a lithium amide.13. A method according to claim 11 , wherein the lithium-containing strong base is selected from the group consisting of butyllithium claim 11 , hexyllithium claim 11 , lithium diisopropylamide and lithium hexamethyldisilazide.14. A method according to claim 11 , wherein the aprotic organic solvent comprises at least one member selected from the group consisting of an aliphatic hydrocarbon claim 11 , an aromatic hydrocarbon and an etheric solvent.15. A method according to claim 11 , wherein the aprotic organic solvent comprises at least one member selected from the group consisting of hexane claim 11 , toluene claim 11 , diethyl ether claim 11 , and tetrahydrofuran16. A method according to claim 11 , wherein the reaction is carried out at a temperature range of 0° to 80° C.17. A positive electrode comprising the lithium sulfide prepared by the process of and a galvanic element.18. A Li ion-conductive solids comprising the lithium sulfide prepared by the method of .19. A glass claim 11 , glass ceramics claim 11 , or crystalline product ...

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27-03-2014 дата публикации

DUAL VESSEL REACTOR

Номер: US20140086809A1
Принадлежит:

A dual vessel reactor and a method of carrying out a reaction using a dual vessel reactor are provided using a non-condensable gas to substantially isolate the inner vessel from the outer vessel during the reaction and limit the heating of the outer vessel when steam from the inner vessel condenses on the interior surface of the outer vessel. By limiting the heating of the outer vessel through the condensation of the steam or other vapour from the inner vessel, the operating temperature of the outer vessel is kept below an upper threshold of the operating temperature of a seal used to seal the door in the outer vessel. 1. A dual vessel chemical reactor comprising:an outer vessel;a reactor lid on the outer vessel, the reactor lid openable for accessing the inner vessel;an inner vessel supported within the outer vessel for containing a liquid, the inner vessel in atmospheric communication with the outer vessel, wherein the support of the inner vessel minimizes metal to metal contact between the inner vessel and the outer vessel;a seal for sealing the reactor lid with the outer vessel when in a closed position;an inner vessel lid for covering the inner vessel;wherein during operation a non-condensable gas is used to substantially insolate the outer vessel from the inner vessel.2. The reactor of claim 1 , wherein the inner vessel is supported within the outer vessel on at least two support points.3. The reactor of claim 2 , wherein each of the at least two support points comprise an upper portion fixed to the inner vessel that rests on a lower portion fixed to the outer vessel.4. The reactor of claim 3 , wherein each lower portion comprises a ‘V’ shape.5. The reactor of claim 4 , wherein each upper portion is welded to the inner vessel and each lower portion is welded to the outer vessel.6. The reactor of claim 1 , further comprising a heat source for heating reactants within the inner vessel during operation.7. The reactor of claim 1 , wherein the reactor further ...

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27-03-2014 дата публикации

Sulfur Recovery Process

Номер: US20140086812A1
Автор: Smith Strom W.
Принадлежит:

A process for removing sulfur compounds, particularly hydrogen sulfide, from a waste gas wherein sulfur dioxide is introduced into the process gas at multiple process locations. Quantities of sulfur dioxide are introduced into the process gas stream at one or more locations preceding catalytic reaction. The process of the present invention may be practiced for Claus processes involving initial thermal reactions, and may be practiced without necessity of preliminary thermal reaction. In an embodiment of the invention, one of the injection locations of sulfur dioxide is the thermal reactor. 1. A process for removing hydrogen sulfide from a waste stream comprising:a first mixing step of mixing a sulfur dioxide stream with said waste stream to create a process stream, said process stream containing sulfur dioxide and hydrogen sulfide;a first reacting step of reacting said hydrogen sulfide with said sulfur dioxide in the presence of a catalyst;a first condensing step of condensing sulfur from said process stream;at least one subsequent mixing step of mixing at least one subsequent sulfur dioxide stream with said process stream;at least one subsequent reacting step of reacting said hydrogen sulfide with said sulfur dioxide in the presence of a catalyst;at least one subsequent condensing step of condensing sulfur from said process stream;an analyzing step of analyzing the amount of hydrogen sulfide and sulfur dioxide in said process stream; anda control step of adjusting flow of sulfur dioxide in at least one of said first mixing step and said at said at least one subsequent mixing step.2. A process according to further comprising:a first heating step prior to said first reacting step of heating said process stream as required to maintain said process stream at a determined temperature in excess of the dew point of sulfur; andat least one subsequent heating step prior to each said at least one reacting step of heating said process stream as required to maintain said ...

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03-04-2014 дата публикации

CORROSION CONTROL IN ACID GAS REMOVAL EQUIPMENT BY THE SITU GENERATION OF POLYSULFIDE IONS

Номер: US20140093440A1

A method for the reduction of corrosion in a treatment unit acid used for separating hydrogen sulfide from and acid gas stream using an alkaline absorption solution. Ions comprising the S and/or HS ions formed by the absorption of the hydrogen sulfide in the absorbent solution are subjected to in situ electrochemical oxidization to form polysulfide ions which form a protective coating on the surfaces of the unit. 1. A method for operating an acid gas treatment unit with reduced corrosion by the in situ generation of polysulfide ions comprising:{'sub': 2', '2, 'sup': −', '2−, '(a) contacting an acid gas stream containing HS with an aqueous alkaline absorbent solution to absorb the HS into the solution to form a providing a process stream including HS and/or S ions; and'}{'sup': −', '2−, '(b) subjecting the stream containing the HS and/or S ions to electrochemical oxidation to oxidize the HS− and/or S2− ions to generate polysulfide ions, and'}(c) regenerating the aqueous alkaline absorbent solution to release acid gas components from the solution.2. The method of in which the acid gas stream fluid stream also comprises at least one of CO claim 1 , SO claim 1 , SO claim 1 , CS claim 1 , HCN claim 1 , COS or a C1-C4 thiol.3. The method of in which the aqueous alkaline absorbent solution includes at an alkanolamine claim 1 , a metal hydroxide claim 1 , a metal carbonate claim 1 , a metal hydrated oxide claim 1 , a metal bicarbonate claim 1 , ammonium or amine cations.4. The method of in which the aqueous alkaline absorbent solution includes a sterically hindered amino ether compound having a degree of steric hindrance such that the cumulative −Es value (Taft's steric hindrance constant) is greater than 1.75.5. The method of in which the aqueous alkaline absorbent solution includes an alkanolamines selected from monoethanolamine (MEA) claim 1 , diethanolamine (DEA) claim 1 , triethanolamine (TEA) claim 1 , dipropanolamine (DPA) claim 1 , diisopropanolamine (DIPA) claim 1 ...

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10-04-2014 дата публикации

CATALYST FOR DECOMPOSING NITROGEN OXIDE AND PREPARATION METHOD THEREOF

Номер: US20140100106A1
Автор: HA Heon Phil, Lee Kyung Ju

Provided is a catalyst including: a support including titanium oxide; an active catalyst component including vanadium oxide; and a co-catalyst including antimony and cerium, in which the catalyst is included in a deNox reduction reaction that decomposes nitrogen oxide. The catalyst may improve sulfur poisoning tolerance characteristics while improving the deNox efficiency at a temperature in a wide range from low temperature to high temperature. 1. A catalyst , comprising:a support comprising titanium oxide;an active catalyst component comprising vanadium oxide; anda co-catalyst comprising antimony and cerium,wherein the catalyst is included in a deNox reduction reaction that decomposes nitrogen oxide.2. The catalyst of claim 1 , wherein:the vanadium oxide is from about 1% by weight to about 3% by weight, the antimony is from about 1% by weight to about 3% by weight, and the cerium is from about 3% by weight to about 17% by weight.3. The catalyst of claim 2 , wherein:the deNox reduction reaction comprises a reducing agent.4. The catalyst of claim 3 , wherein:the reducing agent is ammonia, a hydrocarbon-based compound, or a mixture thereof.5. A method for preparing a catalyst claim 3 , comprising:mixing a support comprising titanium oxide, a vanadium oxide precursor included in an active catalyst component, an antimony precursor included in a co-catalyst, and a cerium precursor or cerium oxide included in a co-catalyst to form a mixture, andsintering the mixture to prepare a catalyst included in a deNox reduction reaction that decomposes nitrogen oxide.6. The method of claim 5 , wherein:the deNox reduction reaction shows a deNox efficiency of about 90% or more at a temperature of about 225° C.7. The method of claim 5 , wherein:the vanadium oxide is from about 1% by weight to about 3% by weight, the antimony is from about 1% by weight to about 3% by weight, and the cerium is from about 3% by weight to about 17% by weight.8. The method of claim 5 , wherein:the deNox ...

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01-01-2015 дата публикации

SYSTEM AND METHOD FOR REDUCING EMISSIONS

Номер: US20150000244A1
Принадлежит:

A system for reducing emissions includes a gas production source that produces nitrogen oxides, sulfur oxides, hydrogen sulfide, sulfuric acid, nitric acid, formaldehyde, benzene, metal oxides, or volatile organic compound emissions. An exhaust plenum is downstream from the gas production source, and structure for dispersing a solvent is in the exhaust plenum. A collection tank is in fluid communication with the exhaust plenum to receive the solvent from the exhaust plenum, and a heat source is in the exhaust plenum downstream from the structure for dispersing the solvent. A method for reducing emissions from a gas production source includes flowing exhaust gases through an exhaust plenum, dispersing a solvent through a nozzle in the exhaust plenum, collecting the dispersed solvent in a collection tank, and heating the exhaust gases flowing through the exhaust plenum downstream from the nozzle. 1. A system for reducing emissions , comprising:a. a gas production source that produces at least one of nitrogen oxides, sulfur oxides, hydrogen sulfide, sulfuric acid, nitric acid, formaldehyde, benzene, metal oxides, or volatile organic compound emissions;b. an exhaust plenum downstream from the gas production source;c. means for dispersing a solvent in the exhaust plenum;d. a collection tank in fluid communication with the exhaust plenum to receive the solvent from the exhaust plenum; ande. a heat source in the exhaust plenum downstream from the means for dispersing the solvent in the exhaust plenum.2. The system as in claim 1 , further comprising a recirculation path between the collection tank and the means for dispersing the solvent in the exhaust plenum.3. The system as in claim 1 , further comprising a sparge pipe in fluid communication with the collection tank.4. The system as in claim 1 , further comprising a catalytic converter in the exhaust plenum and a fluid communication between the collection tank and the exhaust plenum upstream from the catalytic converter.5 ...

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06-01-2022 дата публикации

Process for workup of mixed acid and wastewater from the nitration of aromatics and apparatus for performing the process

Номер: US20220002155A1
Принадлежит:

In a process for workup of mixed acid and wastewater from the nitration of aromatics in which the nitric acid present is converted by reaction with an aromatic under adiabatic conditions, 1. Process for workup of mixed acid and wastewater from the nitration of aromatics , in which the nitric acid present is reacted under adiabatic conditions by reaction with an aromatic , characterised in thata. at least one waste stream component selected from waste acid (mixed acid) generated in the nitration, acidic washing water from the workup of crude nitroaromatics and dilute nitric acid generated in an off-gas treatment in the course of the nitration is provided,b. the at least one waste stream component is mixed with re-concentrated sulfuric acid,c. an aromatic is added to the mixture in stoichiometric excess based on the nitric acid,d. the obtained reaction mixture is reacted in an adiabatically operated reactor,e. the obtained organic phase is separated from the sulfuric-acid-containing phase in a separator,f. the sulfuric-acid-containing phase is concentrated under vacuum andg. at least one substream of the re-concentrated sulfuric acid from step g) is employed in step b).2. Process according to claim 1 , characterised in that at least two claim 1 , preferably all claim 1 , of the aforementioned waste stream components are provided mixed in step a).3. Process according to either or claim 1 , characterised in that the at least one waste stream component is preheated in step b) before the re-concentrated sulfuric acid is added.4. Process according to claim 3 , characterised in that the preheating of the mixture is adjusted in such a way that the temperature after the addition of the re-concentrated sulfuric acid is in a range of 70° C. to 130° C. claim 3 , preferably in a range of 90° C. to 110° C.5. Process according to any of to claim 3 , characterised in that the amount and concentration of the re-concentrated sulfuric acid are selected in a manner resulting in a ...

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01-01-2015 дата публикации

VIBRATION-DAMPING RUBBER COMPOSITION, CROSSLINKED VIBRATION-DAMPING RUBBER COMPOSITION, AND VIBRATION-DAMPING RUBBER

Номер: US20150001434A1
Автор: Nagata Takeshi
Принадлежит: BRIDGESTONE CORPORATION

Provided is a vibration-insulating rubber composition and a crosslinked vibration-insulating rubber composition which successfully maintain basic physical properties and thermal resistance while being excellent in weather resistance and crack growth resistance, and a vibration-insulating rubber using the vibration-insulating rubber composition and the crosslinked vibration-insulating rubber composition. The vibration-insulating rubber composition of the present invention includes: a rubber component having a conjugated diene compound/non-conjugated olefin copolymer; sulfur by 0.6 parts by mass or less per 100 parts by mass of the rubber component; and a bismaleimide compound by 1 to 5 parts by mass per 100 parts by mass of the rubber component.

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07-01-2021 дата публикации

STAINLESS STEEL MEMBER AND PRODUCTION METHOD THEREOF

Номер: US20210001303A1
Принадлежит: TOKUYAMA CORPORATION

The purpose of the present invention is to provide a stainless steel member and a production method thereof, said stainless steel member having a passivation layer formed on a surface of a base material formed from stainless steel, wherein the film thickness of the passivation layer is 2-20 nm, and the concentration of chromium atoms in the outermost surface of the passivation layer is 0.1-2.3 by atomic percentage. Also provided are a device or container, the liquid-contact part of which in contact with a semiconductor treatment liquid is formed from the stainless steel member, a semiconductor treatment liquid production method for producing the semiconductor treatment liquid by using the device, and a semiconductor treatment liquid storage method for storing the semiconductor treatment liquid in the container. 1. An austenite stainless steel member comprising:a base material made of austenite stainless steel; anda passivation layer formed on a surface of the base material made of austenite stainless steel,wherein the passivation layer has a thickness of 2 nm to 20 nm, a concentration of chromium atoms in an outermost surface of the passivation layer is 0.1 atomic % to 1.0 atomic %, and a concentration of silicon atoms in the outermost surface of the passivation layer is 2 atomic % to 10 atomic %.2. The austenite stainless steel member according to which is for use in a part to be in contact with a semiconductor treatment liquid.3. (canceled)4. The austenite stainless steel member according to claim 1 , wherein the passivation layer has a thickness of 3 nm to 20 nm.5. An apparatus having a part to be in contact with a semiconductor treatment liquid claim 1 , wherein the part comprises the austenite stainless steel member according to .6. A method of producing a semiconductor treatment liquid claim 1 , the method comprising:{'claim-ref': {'@idref': 'CLM-00005', 'claim 5'}, 'using the apparatus according to in producing a semiconductor treatment liquid.'}7. A method ...

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07-01-2016 дата публикации

EXHAUST GAS CLEAN-UP SYSTEM FOR FOSSIL FUEL FIRED POWER PLANT

Номер: US20160001225A1
Принадлежит:

A fossil fuel fired power plant exhaust gas clean-up system is provided to remove detrimental compounds/elements from the exhaust gas emitting from the power plant to protect the environment. The removal of detrimental compounds/elements is accomplished by directing the exhaust gas thought several process steps. For example, one step includes a wet scrubber that includes the exhaust gas, water, and a chemically produced compound. The chemical reaction therein is effective to remove sulfur from the exhaust gas and as a side benefit, a useful by-product is produced and stored. Another step directs the remaining exhaust gas through a catalytic converter that is effective to convert nitrogen oxide to nitrogen gas and converts carbon monoxide into carbon dioxide. The final step includes directing the remaining exhaust gas into a reaction chamber with the addition of a reacting compound to remove the carbon dioxide and produce a chemical compound that is used in the first step. The final exhaust gas can now be safely exhausted to the atmosphere and only contains nitrogen gas, oxygen, water and a trace amount of carbon dioxide. 1. A process for gas clean-up of a fossil fuel fired power plant , comprising the steps of:directing the exhaust gas from the fossil fuel fired power plant through a wet scrubber;adding a chemically produced compound from another source to the wet scrubber;adding water from a remote source to the wet scrubber to mix with the exhaust gas and the chemically produced compound;bypassing a chemically produced byproduct from the wet scrubber;directing the chemically modified exhaust gas through a catalytic converter to further chemically modify the exhaust gas from the wet scrubber;directing the further chemically modified exhaust gas to a reactor chamber for additional modification;adding a reacting compound to the reaction chamber to aid in the additional modification of the exhaust gas therein;bypassing the chemically produced product from the reactor ...

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02-01-2020 дата публикации

DESULFURIZATION ABSORPTION TOWER

Номер: US20200001235A1
Принадлежит:

A desulfurization absorption tower, a method for setting up the same and a method for operating the same. The tower may include an internal anti-corrosion layer that may be used for contacting the flue gas and the desulfurization absorption liquid, may define the tower chamber, and may include stainless steel plate whose thickness is 1.0 mm to 6.0 mm. The tower body may include an external supporting layer that may be used for supporting the anti-corrosion layer and may include carbon steel. The supporting layer and the anti-corrosion layer may be designed to jointly bear a load, wherein the supporting layer may be designed to bear a large part of the load, and the anti-corrosion layer may be designed to bear a small part of the load. 128-. (canceled)29. A method for cleaning flue gas , the method comprising:introducing flue gas into an interior region defined by a stainless steel plate interior layer of a desulfurization absorption tower;flowing the flue gas up through the tower;receiving in the interior, through the interior layer, a desulfurization absorption liquid;transferring chloride ion from the flue gas to the desulfurization absorption liquid;contacting the chloride ion with the interior layer; andguiding the chloride ion out of the interior layer, in a desulfurization absorption liquid with a predetermined content of ammonium sulfate, to an ammonium sulfate after-treatment system.30. The method of wherein the contacting comprises:contacting the absorption liquid with the interior layer at a first location, where steel plate includes steel of a first grade; and, then,contacting the absorption liquid with the interior layer at a second location, where the steel plate includes steel of a second grade; the absorption liquid in the first contacting has a first chloride ion concentration;', 'the absorption liquid in the second contacting has a second chloride ion concentration;', 'the first grade is preselected for the first concentration; and', 'the second ...

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03-01-2019 дата публикации

DESULFURIZATION ABSORPTION TOWER

Номер: US20190001267A1
Принадлежит:

A desulfurization absorption tower, a method for setting up the same and a method for operating the same. The tower may include an internal anti-corrosion layer that may be used for contacting the flue gas and the desulfurization absorption liquid, may define the tower chamber, and may include stainless steel plate whose thickness is 1.0 mm to 6.0 mm. The tower body may include an external supporting layer that may be used for supporting the anti-corrosion layer and may include carbon steel. The supporting layer and the anti-corrosion layer may be designed to jointly bear a load, wherein the supporting layer may be designed to bear a large part of the load, and the anti-corrosion layer may be designed to bear a small part of the load. 2. The apparatus of wherein the carbon steel support bears more of the load than does the steel plate.3. The apparatus of wherein the stainless steel plate has a thickness in the range 1.0 mm to 6.0 mm.4. The apparatus of wherein the thickness is about 2.0 mm.5. The apparatus of wherein the thickness is about 3.0 mm.6. The apparatus of wherein the thickness is about 4.0 mm.7. The apparatus of wherein the thickness is about 5.0 mm.8. The apparatus of wherein the steel plate comprises a plurality of steel plates connected together to form an interior layer of a tower.9. The apparatus of wherein the steel plate: a first desulfurization absorption liquid having, after application to the flue gas, a first chloride ion concentration; and', 'a second desulfurization absorption liquid having, after application to the flue gas, a second chloride ion concentration that is different from the first chloride ion concentration;, 'is included in an interior layer of a tower that is configured to apply to the flue gas a first composition; and', 'a second composition; and, 'includes the first liquid with the first composition; and', 'the second liquid with the second composition., 'defines a flue gas guide path that is configured to contact10. The ...

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07-01-2016 дата публикации

PRODUCTION METHOD FOR ALKOXYSILANES

Номер: US20160002271A1

Provided is a method for efficiently producing alkoxysilanes that are useful as various functional chemicals. In order to produce alkoxysilanes efficiently, an ethoxy- or methoxysilane and an alcohol are caused to react using, as a catalyst, for instance an inorganic solid acid having a regular-pore and/or layered structure. Zeolites, montmorillonites or the like can be used as the inorganic solid acid. When a zeolite is used as the catalyst, the silica/alumina ratio of the zeolite ranges preferably from 5 to 1000. The reaction can be promoted through irradiation of microwaves. 1. A method for producing alkoxysilanes , comprising a reaction step of reacting an alkoxysilane having an ethoxy group or a methoxy group , and an alcohol , in the presence of a catalyst , whereinthe alkoxysilane having an ethoxy group or methoxy group is an alkoxysilane represented by Formula (I);the alcohol is an alcohol represented by Formula (II);the catalyst is a solid acid catalyst; and {'br': None, 'sup': 1', '2', '3', '4, 'sub': p', 'q', 'r', '4−(p+q+r), 'RRRSi(OR)\u2003\u2003(I)'}, 'an alkoxysilane obtained in the reaction step is an alkoxysilane represented by Formula (III){'sup': 1', '2', '3', '4', '1', '2', '3, 'claim-text': {'br': None, 'ROH\u2003\u2003(II)'}, '(In Formula (I), p, q, r and p+q+r are integers ranging from 0 to 3; R, Rand Rare each independently a hydrocarbon group having 1 to 23 carbon atoms, or a hydrogen atom; Ris independently an ethyl group or a methyl group; and in a case where R, Rand Rare hydrocarbon groups, some of the hydrogen atoms of the hydrocarbon groups may be substituted by groups that do not participate in the reaction);'} {'br': None, 'sup': 1', '2', '3', '4, 'sub': p', 'q', 'r', '4−(p+q+r)−m', 'm, 'RRRSi(OR)(OR)\u2003\u2003(III)'}, '(In Formula (II), R is a hydrocarbon group having 1 to 23 carbon atoms, and some of the hydrogen atoms in the hydrocarbon group may be substituted by groups that do not participate in the reaction);'}{'sup': 1', '2', ...

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07-01-2016 дата публикации

PROCESS FOR RECAUSTICIZING GREEN LIQUOR

Номер: US20160002852A1
Принадлежит:

A process for recausticizing green liquor in a sulphate or Kraft process for wood pulp production, in which a green liquor consisting of an aqueous solution of sodium carbonate as the major component and sodium sulphide is admixed with calcium oxide in a slaker and undergoes a reaction in a recausticizer to form an aqueous suspension containing sodium hydroxide and calcium carbonate as the major components, which suspension is filtered on a first filter and subsequently, after dilution with water in a dilution vessel, is fed over further filters two or three times and filtered to separate solids suspended therein, characterized in that after a first separation of calcium carbonate as the major component and calcium oxide as the minor component, carbon dioxide is added to the aqueous suspension at least during dilution in a dilution vessel and in particular in the dilution vessel (s) upstream of a second and/or a third filter. 1. A process for recausticizing green liquor in a sulphate or Kraft process for wood pulp production , in which a green liquor consisting of an aqueous solution of sodium carbonate as the major component and sodium sulphide is admixed with calcium oxide in a slaker and undergoes a reaction in a recausticizer to form an aqueous suspension containing sodium hydroxide and calcium carbonate as the major components , which suspension is filtered on a first filter and subsequently , after dilution with water in a dilution vessel , is fed over further filter two or three times and filtered to separate solids suspended therein , wherein after a first separation of calcium carbonate as the major component and calcium oxide as the minor component , carbon dioxide is added to the aqueous suspension at least during dilution in a dilution vessel and in particular in the dilution vessel(s) upstream of a second and/or a third filter.2. The process as claimed in claim 1 , wherein a period for supplying carbon dioxide to the aqueous suspension containing ...

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03-01-2019 дата публикации

PROCESSES FOR FORMING VULCANIZABLE ELASTOMERIC FORMULATIONS AND VULCANIZED ELASTOMERIC ARTICLES

Номер: US20190002665A1
Принадлежит: EASTMAN CHEMICAL COMPANY

Processes for forming a vulcanizable elastomeric formulation are disclosed. The processes include the steps of mixing an elastomer with a vulcanizing agent to form a vulcanizable elastomeric formulation that includes the vulcanizing agent dispersed in the elastomeric compound, wherein the vulcanizing agent includes a cyclododecasulfur compound. A process for forming a vulcanized elastomeric article is also described. 1. A process for forming a vulcanized elastomeric article , said process comprising (a) mixing an elastomer with a vulcanizing agent to form a vulcanizable elastomeric formulation that includes said vulcanizing agent dispersed in said elastomer; (b) forming the vulcanizable elastomeric formulation into a formed shape; and (c) vulcanizing the formed shape to form said vulcanized elastomeric article; wherein at least one of said mixing and forming steps comprises increasing the bulk average processing temperature of said vulcanizable elastomeric formulation to greater than 125° C. for at least a portion of said step.2. The process of claim 1 , wherein at least one of said mixing and forming steps comprises increasing the bulk average processing temperature of said vulcanizable elastomeric formulation to greater than 128° C. for at least a portion of said step.3. The process of claim 1 , wherein at least one of said mixing and forming steps comprises increasing the bulk average processing temperature of said vulcanizable elastomeric formulation to greater than 130° C. for at least a portion of said step.4. The process of claim 14 , wherein at least one of said mixing and forming steps comprises increasing the bulk average processing temperature of said vulcanizable elastomeric formulation to greater than 135° C. for at least a portion of said step.5. The process of claim 1 , wherein the vulcanizing agent comprises a cyclododecasulfur compound characterized by a DSC melt point onset of from about 155° C. to about 167° C. when measured at a DSC heat rate of ...

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