DEFOLIANT COMPOSITION AND METHOD

An aqueous suspension or slurry (suspension concentrate) contains a synergistic amount of thidiazuron, diuron and surfactants. The aqueous suspension contains surfactants in amounts to obtain a stable suspension or slurry without the use of organic solvents. 1. A composition for controlling vegetation comprising an aqueous suspension or slurry of thidiazuron , diuron , and at least one surfactant in an amount sufficient to maintain thidiazuron and diuron in suspension in an aqueous matrix.2. The composition of claim 1 , wherein said thidiazuron and diuron are present in a ratio of about 5:1 by weight.3. The composition of claim 1 , wherein said diuron is present in a synergistic amount to enhance the efficacy of the thidiazuron.4. The composition of claim 1 , wherein the composition further includes at least one component selected from the group consisting of emulsifiers claim 1 , wetting agents claim 1 , thickening agents claim 1 , dispersing agents claim 1 , and mixtures thereof.5. (canceled)6. The composition of claim 1 , wherein the composition is a suspension concentrate.7. The composition of claim 6 , wherein the concentrate includes about 10 wt % to about 40 wt % thidiazuron and about 5 wt % to about 20 wt % diuron based on the total weight of the concentrate.8. The composition of claim 6 , wherein the concentrate includes about 35 wt % to about 40 wt % thidiazuron and about 15 wt % to about 20 wt % diuron based on the total weight of the concentrate.9. The composition of claim 6 , further comprising a dispersing agent.10. The composition of claim 9 , wherein the thidiazuron and diuron have a median particle diameter of not greater than about 5 μm.11. The composition of claim 9 , wherein the concentrate comprises about 10 wt % to about 40 wt % thidiazuron claim 9 , about 5 wt % to about 20 wt % diuron claim 9 , a surfactant claim 9 , a dispersing agent and the balance water claim 9 , where the percentages are based on the total weight of the concentrate.12. ...

HERBICIDAL COMPOSITION

Many herbicidal compositions have been developed and are presently used. However, weeds to be controlled are various in types and their emergence extends over a long period. Accordingly, it is desired to develop a herbicidal composition which has a broad herbicidal spectrum, a high activity and a long lasting effect. The present invention provides a herbicidal composition comprising, as active ingredients, (a) flazasulfuron or its salt, and (b) amicarbazone or its salt. 1. A herbicidal composition comprising , as active ingredients , (a) flazasulfuron or its salt , and (b) amicarbazone or its salt.2. A method for controlling noxious plants , which comprises applying a herbicidally effective amount of a herbicidal composition comprising , as active ingredients , (a) flazasulfuron or its salt , and (b) amicarbazone or its salt , to the noxious plants or to a place where they grow3. A method for controlling noxious plants , which comprises applying a herbicidally effective amount of (a) flazasulfuron or its salt , and a herbicidally effective amount of (b) amicarbazone or its salt , to the noxious plants or to a place where they grow.4. The composition according to claim 1 , wherein the mixing ratio of (a) to (b) is from 1:2 claim 1 ,000 to 5:1 claim 1 , by the weight ratio.5. The method according to claim 2 , wherein (a) is applied in an amount of from 2 to 250 g/ha claim 2 , and (b) is applied in an amount of from 50 to 4 claim 2 ,000 g/ha.6. The method according to claim 2 , wherein the noxious plants are weeds having sensitivity to a sulfonylurea type compound lowered.7. The method according to claim 2 , wherein the noxious plants are convolvulaceae claim 2 , cyperaceae or gramineae.8. The method according to claim 3 , wherein (a) is applied in an amount of from 2 to 250 g/ha claim 3 , and (b) is applied in an amount of from 50 to 4 claim 3 ,000 g/ha.9. The method according to claim 3 , wherein the noxious plants are weeds having sensitivity to a sulfonylurea type ...

METHODS AND COMPOSITIONS FOR TREATING ANXIETY

Methods of treating a TRPC5 mediated disorder in a subject by administering an effective amount of a TRPC5 antagonist, such as a compound disclosed herein, are described. 1. A method of treating a TRPC5 mediated disorder in a subject , the method comprising administering an effective amount of a TRPC5 antagonist.2. The method of claim 1 , wherein the TRPC5 mediated disorder is pain.3. The method of claim 1 , wherein the TRPC5 mediated disorder is anxiety.4. The method of claim 1 , wherein the TRPC5 mediated disorder is epilepsy. This applications claims priority from U.S. Ser. No. 61/086,784; U.S. Ser. No. 61/086,785; and U.S. Ser. No. 61/086,787, all of which were filed Aug. 6, 2008, and are hereby incorporated by reference in their entireties.A variety of ion channel proteins exist to mediate ion flux across cellular membranes. The proper expression and function of ion channel proteins is essential for the maintenance of cell function, intracellular communication, and the like. Numerous diseases are the result of misregulation of membrane potential or aberrant calcium handling. Given the central importance of ion channels in modulating membrane potential and ion flux in cells, identification of agents that can promote or inhibit particular ion channels are of great interest as potential therapeutic agents.The present invention provides methods and compositions for treating conditions such as pain and/or anxiety by modulating the activity of the transient receptor potential cation channel subfamily C, member 5 (TRPC5), which can exist in homomultimeric form as well as heteromultimeric form with other ion channels such as TRPC1 or TRPC3 (i.e., TRPC5-TRPC1 and TRPC1-TRPC3-TRPC5). The compounds described herein modulate the function of TRPC5 by inhibiting a TRPC5-mediated ion flux or by inhibiting the inward current, the outward current, or both currents mediated by TRPC5. The inhibition of a particular current is the ability to inhibit or reduce such current (e.g., ...

SYNERGISTIC HERBICIDAL COMPOSITION AND THE METHOD OF CONTROLLING THE GROWTH OF UNDESIRED PLANTS

A synergistic herbicidal composition comprising Pyroxasulfone and Thifensulfuron methyl as the active components, as well as the use of the synergistic herbicidal composition for controlling the growth of undesirable plants is provided. A method of controlling the growth of undesirable plants, which comprises applying the active components Pyroxasulfone and Thifensulfuron methyl of the synergistic herbicidal composition to the undesirable plants or their growing locus jointly or separately is also provided. A method of reducing or preventing harm caused by Pyroxasulfone when applied to plants, seeds or other reproductive parts of useful crops is also provided. 1. A synergistic herbicidal composition comprising Pyroxasulfone and Thifensulfuron methyl as the active components , wherein the weight ratio of Pyroxasulfone and Thifensulfuron methyl ranges from 50:1 to 1:50.2. The synergistic herbicidal composition of claim 1 , wherein the weight ratio of said Pyroxasulfone and Thifensulfuron methyl ranges from 25:1 to 1:25.3. The synergistic herbicidal composition of claim 1 , wherein the weight ratio of said Pyroxasulfone and Thifensulfuron methyl ranges from 10:1 to 1:10.4. The synergistic herbicidal composition of claim 1 , wherein the weight ratio of said Pyroxasulfone and Thifensulfuron methyl ranges from 5:1 to 1:5.5. The synergistic herbicidal composition of claim 1 , further comprising a surfactant and/or filler.6. The synergistic herbicidal composition of claim 5 , wherein said active components of Pyroxasulfone and Thifensulfuron methyl is present in the synergistic herbicidal composition in an amount of 5% to 90% by weight.7. The synergistic herbicidal composition of claim 5 , wherein said active components of Pyroxasulfone and Thifensulfuron methyl is present in the synergistic herbicidal composition in an amount of 10% to 80% by weight.8. The synergistic herbicidal composition of claim 5 , wherein said active components of Pyroxasulfone and Thifensulfuron ...

HERBICIDAL COMPOSITION

To provide a high active herbicidal composition having a broad herbicidal spectrum. 1. A herbicidal composition comprising synergistically effective amounts of (A) pyridate or its salt and (B) at least one sulfonylurea compound selected from the group consisting of flazasulfuron , nicosulfuron , trifloxysulfuron , chlorimuron and its alkyl ester , halosulfuron and its alkyl ester , and their salts.2. The herbicidal composition according to claim 1 , wherein the mixing ratio of (A) to (B) is from 500:1 to 1:2.5 by the weight ratio.3. A method for controlling undesired plants or inhibiting their growth claim 1 , which comprises applying the herbicidal composition as defined in in synergistically effective amounts to the undesired plants or to a place where they grow.4. The method according to claim 3 , wherein (A) is applied in an amount of from 200 to 5 claim 3 ,000 g/ha and (B) is applied in an amount of from 10 to 500 g/ha.5kyllinga.. The method according to claim 3 , wherein the undesired plant is green6kyllinga. The method according to claim 3 , wherein the undesired plant is green having lowered sensitivity to herbicides.7kyllingakyllinga. A method for controlling green or inhibiting its growth claim 3 , which comprises applying a herbicidally effective amount of (A) pyridate or its salt to the green or to a place where it grows.8kyllingakyllinga. The method according to claim 7 , wherein the green is green having lowered sensitivity to herbicides.9. The method according to claim 7 , wherein (A) pyridate or its salt is applied in an amount of from 200 to 5 claim 7 ,000 g/ha. The present invention relates to a herbicidal composition and a method for controlling undesired plants.Patent Document 1 discloses a herbicidal composition comprising nicosulfuron and a specific known herbicide, and discloses pyridate as an example of the known herbicide.However, it has not been known that a herbicidal composition comprising synergistically effective amounts of (A) pyridate ...

HERBICIDAL COMPOSITION

At present, many herbicidal compositions have been developed and used, but there are a variety of types of weeds to be controlled, and their development lasts for a long period of time. Thus, a high active and long-residual herbicidal composition having a broad herbicidal spectrum has been desired. 1. A method for controlling undesired plants or inhibiting their growth , which comprises applying a synergistic herbicidally effective amount of (A) flazasulfuron or its salt and (B) duiron or its salt , to the undesired plants or to a place where they grow.2. The method according to claim 1 , wherein (A) is applied in an amount of from 10 to 150 g/ha claim 1 , and (B) is applied in an amount of from 150 to 5 claim 1 ,000 g/ha.3. The method according to claim 1 , wherein (A) is applied in an amount of from 30 to 50 g/ha claim 1 , and (B) is applied in an amount of from 1 claim 1 ,100 to 2 claim 1 ,000 g/ha. The present application is a continuation of U.S. application Ser. No. 13/700,769, which is a National Stage of International Patent Application No. PCT/JP2011/063625 filed Jun. 8, 2011, which claims priority to Japanese Application No. 2010-135400, filed Jun. 14, 2010 and Japanese Application No. 2010-229645 filed Oct. 12, 2010. The disclosures of U.S. application Ser. No. 13/700,769 and International Patent Application No. PCT/JP2011/063625 are incorporated by reference herein in their entireties.The present invention relates to a synergistic herbicidal composition comprising (A) flazasulfuron or its salt (hereinafter referred to as compound A) and (B) at least one urea compound selected from the group consisting of tebuthiuron, diuron and metobromuron or its salt (hereinafter referred to as compound B).Various heribicidal compositions have been studied to control undesired plants (hereinafter simply referred to as weeds) in agricultural fields and non-crop land. For example, Patent Document 1 discloses a mixture comprising a sulfonylurea herbicide, diuron and ...

APPLICATION FOR HERBICIDE-TOLERANT PROTEIN

The present invention relates to the use of a herbicide-tolerant protein, wherein the method for controlling weeds comprises applying a herbicide containing an effective dose of halosulfuron-methyl to a plant growth environment where at least one transgenic plant is present, wherein the transgenic plant comprises a nucleotide sequence encoding a thifensulfuron hydrolase in its genome, and compared to other plants without the nucleotide sequence encoding the hydrolase, the transgenic plant has reduced plant damage and/or an increased plant yield. The present invention discloses for the first time that a thifensulfuron hydrolase can show a high tolerance to a halosulfuron-methyl herbicide, plants containing a nucleotide sequence encoding the thifensulfuron hydrolase are strongly tolerant to the halosulfuron-methyl herbicide and can at least tolerate 1-fold field concentration, and thus the hydrolase has broad application prospects in plants. 1. A method for controlling weeds , characterized in that the method comprises applying a herbicide containing an effective dose of halosulfuron-methyl to a plant growth environment where at least one transgenic plant is present , wherein the transgenic plant comprises a nucleotide sequence encoding a thifensulfuron hydrolase in its genome , and compared to other plants without the nucleotide sequence encoding the thifensulfuron hydrolase , the transgenic plant has reduced plant damage and/or an increased plant yield.2. (canceled)3. (canceled)4Arabidopsis thaliana. The method for controlling weeds according to claim 31 , characterized in that the transgenic plant is maize claim 31 , soybean claim 31 , claim 31 , cotton claim 31 , rape claim 31 , rice claim 31 , sorghum claim 31 , wheat claim 31 , barley claim 31 , millet claim 31 , sugar cane or oat.5. The method for controlling weeds according to claim 1 , characterized in that the amino acid sequence of the thifensulfuron hydrolase comprises an amino acid sequence as shown in ...

HERBICIDAL COMPOSITION COMPRISING FLAZASULFURON AND AN INHIBITOR OF PROTOPORPHYRINOGEN OXIDASE

Many herbicidal compositions have been developed and are presently used. However, weeds to be controlled are various in types and their emergence extends over a long period. Accordingly, it is desired to develop a herbicidal composition which has a broad herbicidal spectrum, a high activity and a long-lasting effect. 1. A herbicidal composition comprising (A) flazasulfuron or its salt and (B) at least one protoporphyrinogen oxidase inhibitor selected from the group consisting of a phenylpyrazole compound , a triazolinone compound , a N-phenylphthalimide compound , a pyrimidindione compound , an oxadiazole compound , an oxazolidinedione compound , a thiadiazole compound , pyraclonil , profluazol , flufenpyr-ethyl and their salts.2. The herbicidal composition according to claim 1 , wherein the mixing ratio of (A) to (B) is from 100:1 to 1:100 by the weight ratio.3. The herbicidal composition according to claim 1 , wherein (B) is at least one member selected from the group consisting of pyraflufen-ethyl claim 1 , carfentrazone-ethyl claim 1 , sulfentrazone claim 1 , flumioxazin claim 1 , saflufenacil claim 1 , ethyl [3-(2-chloro-4-fluoro-5-(3-methyl-2 claim 1 ,6-dioxo-4-trifluoromethyl-3 claim 1 ,6-dihydro-2H-pyrimidin-1-yl)phenoxy)pyridin-2-yloxy]acetate claim 1 , oxadiargyl claim 1 , fluthiacet-methyl claim 1 , flufenpyr-ethyl claim 1 , flumiclorac-pentyl claim 1 , azafenidin claim 1 , butafenacil claim 1 , pentoxazone claim 1 , pyraclonil and their salts.4. The herbicidal composition according to claim 1 , wherein (B) is at least one member selected from the group consisting of pyraflufen-ethyl claim 1 , carfentrazone-ethyl claim 1 , sulfentrazone claim 1 , flumioxazin claim 1 , saflufenacil claim 1 , oxadiargyl claim 1 , fluthiacet-methyl claim 1 , flufenpyr-ethyl claim 1 , butafenacil claim 1 , pentoxazone claim 1 , pyraclonil and their salts.5. A method for controlling undesired plants or inhibiting their growth claim 1 , which comprises applying a herbicidally ...

METHODS FOR TREATING IMMUNE-MEDIATED DISEASES OF THE NERVOUS SYSTEM ADMINISTERING A COMPOUND COMPRISING AGENTS THAT INHIBIT PROKINETICIN RECEPTORS ACTIVITY

The invention relates to a compound comprising non-peptide prokineticin receptors antagonists and agents that modulate or inhibit the activity of prokineticin receptors for use in the treatment of immune-mediated diseases of the central nervous system, peripheral nervous system and neuromuscular junctions. 1. A compound comprising non-peptide prokineticin receptors antagonists for use in the treatment of immune-mediated diseases of the central nervous system , peripheral nervous system and neuromuscular junction.3. The compound according to for modulating claim 1 , directly and indirectly claim 1 , the specific autoimmune response against myelin by shifting it from a T-helper 1-type phenotype to a T-helper 2-type phenotype so as to reduce the production of T-helper 1 inflammatory cytokines and increase the production of T-helper 2-type inflammatory cytokines.4. The compound comprising non-peptide prokineticin receptors antagonists according to claim 1 , for use in the treatment of human multiple sclerosis and/or experimental autoimmune encephalomyelitis (EAE).5. The compound according to for use in the treatment of relapsing-remitting experimental autoimmune encephalomyelitis (EAE).6. The compound according to for use in the treatment of chronic experimental autoimmune encephalomyelitis (EAE).7. An SJL mouse model exhibiting induced relapsing-remitting experimental autoimmune encephalomyelitis (EAE) and treated with a compound comprising non-peptide prokineticin receptors antagonists according to .8. A C57B1/6 mouse model exhibiting induced chronic experimental autoimmune encephalomyelitis (EAE) and treated with a compound comprising non-peptide prokineticin receptors antagonists according to .9. An agent that inhibits and/or modulates the activity or the signalling of prokineticin receptors for use in the prevention and/or treatment of immune-mediated diseases of the central nervous system claim 1 , peripheral nervous system and neuromuscular junctions.10. The ...

Method for spray tank cleanout

A method for spray tank cleanout. In particular, the invention further relates to a method for reducing residual sulfonylurea pesticide contamination of a spray tank from which the sulfonylurea is applied, and a composition for achieving this method.

Increased walnut yields with brassinosteroid application

Methods and materials for producing walnuts with improved characteristics including: increased whole nut size, kernel size, shell size and hull size, and increased fruit set are disclosed. 1. A solution for increasing the mass of edible seeds from a walnut tree comprising a plant growth regulator selected from the group consisting of 28-Homobrassinolide , Brassinolide , 24-epibrassinolide , Gibberellic acid , Castasterone , and 28-Homocastasterone.2. The solution of further comprising forchlorfenuron.3. The solution of in which the concentration the plant growth regulator is between approximately 0.4 ppm and 20 ppm.4. The solution of further comprising approximately 10 ppm forchlorfenuron.5. A method for increasing the mass of edible seeds harvested from a walnut tree comprising the steps of applying a aqueous solution of a plant growth regulator selected from the group consisting of Homobrassinolide claim 1 , Brassinolide claim 1 , Epibrassinolide claim 1 , Gibberellic acid claim 1 , Castasterone claim 1 , and Homocastasterone to the flowers of a walnut tree at a determined time during flowering.6. The method of in which the aqueous solution is comprised of between 0.4 ppm and 20 ppm Homobrassinolide.7. The method of further comprising the steps of preparing said plant growth regulator solution by diluting a concentrated plant growth regulator solution to the desired final concentration claim 5 , allowing the edible seeds to grow to maturity following application of the aqueous plant growth regulator solution claim 5 , and harvesting the mature nuts.8. The method of in which the determined time during flowering is the pre-bloom growth stage.9. The method of in which the determined time during flowering is the full-bloom growth stage.10. The method of in which the determined time during flowering is the post-bloom growth stage.11. The method of in which the aqueous solution further comprises 10 ppm forchlorfenuron. The subject matter of this application pertains to ...

USE OF FORCHLORFENURON FOR PROMOTING PLANT GROWTH

A method is disclosed herein for promoting the root growth of a plant. The method includes contacting the plant, or a seed of the plant, with a composition containing forchlorfenuron (CPPU) before the reproductive growth stage of the plant, such that either the root length of the plant is at least about 5% greater than for an untreated plant, or the ratio of root length to stem length is increased by at least 5% compared to the untreated plant. 1. A method of promoting root growth of a plant , the method comprising contacting the plant , or a seed of the plant , with a composition comprising forchlorfenuron (CPPU) before the reproductive growth stage of the plant , such that either the root length of the plant is at least about 5% greater than for an untreated plant , or the ratio of root length to stem length is increased by at least 5% compared to the untreated plant.2BrassicaGossypium.. The method of claim 1 , wherein the plant is a member of the genus selected from the group consisting of and3Brassica.. The method of claim 2 , wherein the plant is a member of the genus4Brassica oleracea.. The method of claim 3 , wherein the plant is a member of the species5. The method of claim 4 , wherein the plant is broccoli.6Gossypium.. The method of claim 2 , wherein the plant is a member of the genus7Gossypium hirsutum, Gossypium barbadense, Gossypium arboreumGossypium herbaceum.. The method of claim 6 , wherein the plant is a member of a species selected from the group consisting of claim 6 , and8. The method of claim 6 , wherein following the contacting step claim 6 , the plant exhibits at least one characteristic selected from the group consisting of reduced apical dominance claim 6 , increased rate of development of fruiting branches claim 6 , decreased time to first bloom claim 6 , increased number of cotton squares formed claim 6 , thickening of the hypocotyl claim 6 , reduced rate of leaf wilting claim 6 , reduced water usage claim 6 , and increased root development ...

HERBICIDE COMBINATION CONTAINING PELARGONIC ACID AND DEFINED ALS INHIBITORS

The present invention relates to a herbicide combination comprising at least pelargonic acid and at least one ALS inhibitor selected from the group consisting of iodosulfuron-methyl, foramsulfuron, mesosulfuron-methyl, flazasulfuron, amidosulfuron, ethoxysulfuron and thiencarbazone-methyl. 1. A herbicide composition comprisingas component (A) an herbicidally active amount of pelargonic acidandas component (B) at least one ALS inhibitor selected from the group consisting of mesosulfuron-methyl, flazasulfuron, amidosulfuron, ethoxysulfuron and thiencarbazone-methyl,wherein a weight ratio of components (A) and (B) is in a range of 30,000:1 to 12.5:1, and wherein the composition is synergistically effective.2. The herbicide composition as claimed in where the component (B) used is mesosulfuron-methyl and the weight ratio of components (A) and (B) is in a range of from 4000:1 to 333:1 orthe component (B) used is thiencarbazone-methyl and the weight ratio of components (A) and (B) is in a range of from 3000:1 to 333:1 orthe component (B) used is flazasulfuron and the weight ratio of components (A) and (B) is in a range of from 3000:1 to 200:1 orthe component (B) used is amidosulfuron and the weight ratio of components (A) and (B) is in a range of from 1000:1 to 167:1 orthe component (B) used is ethoxysulfuron and the weight ratio of components (A) and (B) is in a range of from 500:1 to 50:1.3. The herbicide composition as claimed in where claim 1 , in addition to component (A) claim 1 , at least two different ALS inhibitors are used as component (B).4. The herbicide composition as claimed in claim 1 , comprising an effective amount of components (A) and (B) and additionally one or more further components selected from the group consisting of agrochemically active compounds of a different type claim 1 , formulation auxiliaries and additives customary in crop protection.5. A method for controlling weeds claim 1 , comprising applying a herbicide composition as claimed in to ...

HERBICIDE COMBINATION CONTAINING PELARGONIC ACID AND DEFINED ALS INHIBITORS

The present invention relates to a herbicide combination comprising at least pelargonic acid and at least one ALS inhibitor selected from the group consisting of iodosulfuron-methyl, foramsulfuron, mesosulfuron-methyl, flazasulfuron, amidosulfuron, ethoxysulfuron and thiencarbazone-methyl. 1. A herbicide combination comprisingas component (A) pelargonic acidandas component (B) at least one ALS inhibitor selected from the group consisting of iodosulfuron-methyl, foramsulfuron, mesosulfuron-methyl, flazasulfuron, amidosulfuron, ethoxysulfuron and thiencarbazone-methyl.2. The herbicide combination as claimed in where the weight ratio of components (A) and (B) is in the range from 30000:1 to 12.5:1.3. The herbicide combination as claimed in where the component (B) used is foramsulfuron and the weight ratio of components (A) and (B) is in a range of from 2000:1 to 167:1 orthe component (B) used is iodosulfuron and the weight ratio of components (A) and (B) is in a range of from 30000:1 to 1000:1 orthe component (B) used is mesosulfuron and the weight ratio of components (A) and (B) is in a range of from 4000:1 to 333:1 orthe component (B) used is thiencarbazone and the weight ratio of components (A) and (B) is in a range of from 3000:1 to 333:1 orthe component (B) used is flazasulfuron and the weight ratio of components (A) and (B) is in a range of from 3000:1 to 200:1 orthe component (B) used is amidosulfuron and the weight ratio of components (A) and (B) is in a range of from 1000:1 to 167:1 orthe component (B) used is ethoxysulfuron and the weight ratio of components (A) and (B) is in a range of from 500:1 to 50:1.4. The herbicide combination as claimed in where claim 1 , in addition to component (A) claim 1 , at least two different ALS inhibitors are used as component (B).5. The herbicide combination as claimed in where the ALS inhibitors are selected from the group consisting of iodosulfuron-methyl and foramsulfuron.6. The herbicide combination as claimed in where ...

SYNERGISTIC HERBICIDAL COMPOSITION AND USE THEREOF

A herbicidal composition is provided, the composition comprising: (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of methyl 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoate (metsulfuron-methyl). A method of controlling plant growth at a locus comprises applying to the locus herbicidally effective amounts of both (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of methyl 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoate (metsulfuron-methyl). 1. A composition comprising a herbicidally effective amount of(A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and 6.28±0.2', '12.61±0.2', '13.50±0.2', '16.59±0.2', '17.66±0.2', '19.70±0.2', '21.63±0.2', '21.84±0.2', '23.22±0.2', '24.21±0.2', '27.25±0.2', '27.98±0.2', '29.25±0.2., '(B) the crystalline modification I of methyl 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoate (metsulfuron-methyl), wherein the crystalline modification I of metsulfuron-methyl exhibits each of the following reflexes as 20 values in an X-ray powder diffractogram2. The composition according to claim 1 , wherein the weight ratio of (A) to (B) is in the range of from about 200:1 to about 1:200.3. The composition according to claim 2 , wherein the weight ratio of (A) to (B) is in the range of from 150:1 to about 1:1.4. The composition according to claim 3 , wherein the weight ratio of (A) to (B) is 20:1.5. The composition according to claim 1 , wherein the total amount of (A) and (B) is from 5% to 99% by weight of the composition.6. The composition according to claim 5 , wherein the composition comprises claim 5 , by weight claim 5 , from about 1% to about 90% of (A) and from about 1% to about 90% of (B).7. The composition ...

SYNERGISTIC HERBICIDAL COMPOSITION AND USE THEREOF

A herbicidal composition is provided, the composition comprising: (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of sodium salt of methyl 4-iodo-2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino] carbonyl]amino]sulfonyl]benzoate (iodosulfuron-methyl-sodium). A method of controlling plant growth at a locus comprises applying to the locus herbicidally effective amounts of both (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of sodium salt of methyl 4-iodo-2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino] carbonyl]amino]sulfonyl]benzoate (iodosulfuron-methyl-sodium). 1. A composition comprising a herbicidally effective amount of(A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and(B) the crystalline modification I of sodium salt of methyl 4-iodo-2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino] carbonyl]amino]sulfonyl]benzoate (iodosulfuron-methyl-sodium), 11.558±0.2', '14.569±0.2', '18.045±0.2', '19.442±0.2', '20.633±0.2', '23.226±0.2', '26.145±0.2', '27.199±0.2', '27.877±0.2', '29.090±0.2., 'wherein the crystalline modification I of iodosulfuron-methyl-sodium exhibits each of the following reflexes as 2θ values in an X-ray powder diffractogram2. The composition according to claim 1 , wherein the weight ratio of (A) to (B) is in the range of from about 150:1 to about 1:50.3. The composition according to claim 2 , wherein the weight ratio of (A) to (B) is in the range of from 50:1 to about 1:10.4. The composition according to claim 3 , wherein the weight ratio of (A) to (B) is 10:1.5. The composition according to claim 1 , wherein the total amount of (A) and (B) is from 5% to 99% by weight of the composition.6. The composition according to claim 5 , wherein the composition comprises claim 5 , by weight claim 5 , from about 1% to about ...

PROCESS FOR PREPARING A NOVEL CRYSTALLINE FORM OF METSULFURON-METHYL AND USE OF THE SAME

A crystalline form of metsulfuron-methyl of formula (I), the crystal preparation process, the analyses of the crystal through various analytical methods and using the crystal to prepare stable agrochemical formulation. The invention also describes the use of various solvents towards the crystalline form preparation conditions. 1. A crystalline modification I of metsulfuron-methyl (methyl 2-[[[[(4-methoxy-6-methyl-1 ,3 ,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoate) exhibiting each of the following reflexes as 2θ values in X-ray powder diffractogram recorded using Cu-Kα radiation at 25° C.:{'br': None, '2θ=6.28±0.2\u2003\u2003(1)'}{'br': None, '2θ=12.61±0.2\u2003\u2003(2)'}{'br': None, '2θ=13.50±0.2\u2003\u2003(3)'}{'br': None, '2θ=16.59±0.2\u2003\u2003(4)'}{'br': None, '2θ=17.66±0.2\u2003\u2003(5)'}{'br': None, '2θ=19.70±0.2\u2003\u2003(6)'}{'br': None, '2θ=21.63±0.2\u2003\u2003(7)'}{'br': None, '2θ=21.84±0.2\u2003\u2003(8)'}{'br': None, '2θ=23.22±0.2\u2003\u2003(9)'}{'br': None, '2θ=24.21±0.2\u2003\u2003(10)'}{'br': None, '2θ=27.25±0.2\u2003\u2003(11)'}{'br': None, '2θ=27.98±0.2\u2003\u2003(12), and'}{'br': None, '2θ=29.25±0.2\u2003\u2003(13).'}2. (canceled)3. The crystalline modification I of Metsulfuron-methyl according to claim 1 , exhibiting an IR spectrum with the following bands at 3076.92 claim 1 , 2952.03 claim 1 , 2160.21 claim 1 , 2022.83 claim 1 , 1726.29 and 1702.52 cm.4. The crystalline modification I of metsulfuron-methyl according to exhibiting a Differential Scanning calorimeter (DSC) thermogram having an endothermic melting peak with onset at 170.5° C. and peak maximum at 173.6° C.5. A process of preparing crystalline modification I of metsulfuron-methyl according to claim 1 , comprising:i) dissolving metsulfuron-methyl in an amorphous state into a solvent;ii) precipitating the dissolved compound into the crystalline modification I of metsulfuron-methyl; andiii) isolating the precipitated crystalline modification I.6. The process according ...

PROCESS FOR PREPARING A NOVEL CRYSTALLINE FORM OF IODOSULFURON-METHYL-SODIUM AND USE OF THE SAME

A crystalline form of iodosulfuron-methyl-sodium of formula (I), the crystal preparation process, the analyses of the crystal through various analytical methods and using the crystal to prepare stable agrochemical formulation. The invention also describes the use of various solvents towards the crystalline form preparation conditions. 1. A crystalline modification I of iodosulfuron-methyl-sodium , exhibiting each of the following reflexes in an X-ray powder diffractogram recorded using Cu-Kα radiation at 25° C.:{'br': None, '2θ=11.558±0.2\u2003\u2003(1)'}{'br': None, '2θ=14.569±0.2\u2003\u2003(2)'}{'br': None, '2θ=18.045±0.2\u2003\u2003(3)'}{'br': None, '2θ=19.442±0.2\u2003\u2003(4)'}{'br': None, '2θ=20.633±0.2\u2003\u2003(5)'}{'br': None, '2θ=23.226±0.2\u2003\u2003(6)'}{'br': None, '2θ=26.145±0.2\u2003\u2003(7)'}{'br': None, '2θ=27.199±0.2\u2003\u2003(8)'}{'br': None, '2θ=27.877±0.2\u2003\u2003(9)'}{'br': None, '2θ=29.090±0.2\u2003\u2003(10).'}2. (canceled)3. (canceled)4. (canceled)5. The crystalline modification I of iodosulfuron-methyl-sodium according to claim 1 , exhibiting IR spectrum with the characteristic bands at 3516.78 claim 1 , 3330.55 claim 1 , 2946.18 and 2160.93 cm.6. A process for the preparation of a crystalline modification I of iodosulfuron-methyl-sodium according to claim 1 , comprising:i) preparing a solution of an amorphous iodosulfuron-methyl-sodium in a solvent;ii) effecting crystallization of iodosulfuron-methyl-sodium from the solution to obtain a solid precipitate; andiii) isolating the solid precipitate.7. The process according to claim 6 , wherein the solvent comprises an alcohol.8. The process according to claim 6 , wherein the solvent is methanol claim 6 , ethanol claim 6 , or a mixture thereof.9. A composition comprising the crystalline modification I of iodosulfuron-methyl-sodium according to and at least one herbicidally acceptable auxiliary.10. The composition according to claim 9 , wherein the composition is in the form of a ...

PESTICIDAL PYRIMIDINE COMPOUNDS

Pyrimidine compounds and their use in controlling pests such as insects and other invertebrates are provided. Further embodiments, forms, objects, features, advantages, aspects and benefits shall become apparent from the description. 112-. (canceled)14. A compound according to claim 13 , wherein Rrepresents halogen.15. A compound according to claim 14 , wherein Rrepresents F.16. A compound according to claim 13 , wherein Rrepresents substituted or unsubstituted C-Chaloalkyl17. A compound according to claim 16 , wherein Rrepresents CF.201. A compound according to claim claim 16 , wherein Rrepresents CF claim 16 , each of R claim 16 , R claim 16 , and Rrepresents H claim 16 , and Rrepresents F.21. A compound according to claim 20 , wherein Rrepresents H or methyl.22. A composition for controlling insects which comprises a compound according to in combination with a phytologically-acceptable carrier.23. A method of controlling insects which comprises applying to a locus where control is desired an insect-inactivating amount of a compound according to .24. A composition which comprises a compound according to and at least one compound selected from the group consisting of fungicides claim 13 , insecticides claim 13 , nematocides claim 13 , miticides claim 13 , arthropodicides claim 13 , and bactericides.25. A composition which comprises a compound according to and one or more compounds selected from: (3-ethoxypropyl)mercury bromide claim 13 , 1 claim 13 ,2-dichloropropane claim 13 , 1 claim 13 ,3-dichloropropene claim 13 , 1-methylcyclopropene claim 13 , 1-naphthol claim 13 , 2-(octylthio)ethanol claim 13 , 2 claim 13 ,3 claim 13 ,5-tri-iodobenzoic acid claim 13 , 2 claim 13 ,3 claim 13 ,6-TBA claim 13 , 2 claim 13 ,3 claim 13 ,6-TBA-dimethylammonium claim 13 , 2 claim 13 ,3 claim 13 ,6-TBA-lithium claim 13 , 2 claim 13 ,3 claim 13 ,6-TBA-potassium claim 13 , 2 claim 13 ,3 claim 13 ,6-TBA-sodium claim 13 , 2 claim 13 ,4 claim 13 ,5-T claim 13 , 2 claim 13 ,4 claim 13 ,5 ...

1 4,2-diazaphospholidine derivatives

The present invention relates to novel 1,4,2-diazaphospholidine derivatives, to a process for preparation thereof and to use as catalysts.

Herbicidal composition

At present, a large number of herbicidal compositions have been developed and used. However, weeds to be controlled include a lot of kinds, and the emergence thereof extends over a long period of time. Therefore, the appearance of a herbicidal composition having a broad weed spectrum and having a high activity and a long residual effect is desired. The present invention relates to a synergistic herbicidal composition comprising (A) at least one member selected from the group consisting of flazasulfuron, nicosulfuron, and their salts and (B) pyroxasulfone or its salt. According to the synergistic herbicidal composition of the present invention, a herbicidal composition having a broad weed spectrum and having a high activity and a long residual effect can be provided.

SYNERGISTIC HERBICIDAL COMPOSITION AND USE THEREOF

A herbicidal composition is provided, the composition comprising: (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of methyl 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)methylamino]carbonyl]amino]sulfonyl]benzoate (tribenuron-methyl). A method of controlling plant growth at a locus comprises applying to the locus herbicidally effective amounts of both (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of 2-[[[[(4-methoxy-6-methyl-1,3,5 -triazin-2-yl)methylamino]carbonyl]amino]sulfonyl]benzoate (tribenuron-methyl). 1. A composition comprising a herbicidally effective synergistic amount of(A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and [{'br': None, '2θ=6.47±0.2 \u2003\u2003(1)'}, {'br': None, '2θ=10.46±0.2 \u2003\u2003(2)'}, {'br': None, '2θ=11.02±0.2 \u2003\u2003(3)'}, {'br': None, '2θ=14.01±0.2 \u2003\u2003(4)'}, {'br': None, '2θ=15.73±0.2 \u2003\u2003(5)'}, {'br': None, '2θ=16.71±0.2 \u2003\u2003(6)'}, {'br': None, '2θ=16.98±0.2 \u2003\u2003(7)'}, {'br': None, '2θ=21.04±0.2 \u2003\u2003(8)'}, {'br': None, '2θ=22.23±0.2 \u2003\u2003(9)'}, {'br': None, '2θ=23.26±0.2 \u2003\u2003(10)'}, {'br': None, '2θ=25.01±0.2 \u2003\u2003(11)'}, {'br': None, '2θ=26.14±0.2 \u2003\u2003(12).'}], '(B) the crystalline modification I of methyl 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)methylamino]carbonyl]amino]sulfonyl]benzoate (tribenuron-methyl), wherein the crystalline modification I of tribenuron-methyl is crystallized using methanol and/or ethanol, and the crystalline modification I of tribenuron-methyl exhibits each of the following reflexes as 2θ values in X-ray powder diffractogram recorded using Cu-Kα radiation at 25° C.2. The composition according to claim 1 , wherein the weight ratio of (A) to (B) is in the range of from about 99:1 to ...

Novel form of tribenuron-methyl, a process for its preparation and use of the same

A crystalline form of tribenuron-methyl of formula (I), the crystal preparation process, the analyses of the crystal through various analytical methods and using the crystal to prepare stable agrochemical formulation. The invention also describes the use of various solvents towards the crystalline form preparation conditions.

PROCESS FOR PREPARING A NOVEL CRYSTALLINE FORM OF MESOSULFURON-METHYL AND USE OF THE SAME

A crystalline form of mesosulfuron-methyl of formula (I), the crystal preparation process, the analyses of the crystal through various analytical methods and using the crystal to prepare stable agrochemical formulation. The invention also describes the use of various solvents towards the crystalline form preparation conditions. 1. A crystalline modification I of mesosulfuron-methyl , exhibiting each of the following reflexes as 2θ values in an X-ray powder diffractogram recorded using Cu-Kα radiation at 25° C.:{'br': None, '2θ=5.41±0.2\u2003\u2003(1)'}{'br': None, '2θ=10.26±0.2\u2003\u2003(2)'}{'br': None, '2θ=10.88±0.2\u2003\u2003(3)'}{'br': None, '2θ=12.14±0.2\u2003\u2003(4)'}{'br': None, '2θ=16.38±0.2\u2003\u2003(5)'}{'br': None, '2θ=18.87±0.2\u2003\u2003(6)'}{'br': None, '2θ=19.47±0.2\u2003\u2003(7)'}{'br': None, '2θ=20.82±0.2\u2003\u2003(8)'}{'br': None, '2θ=21.88±0.2\u2003\u2003(9)'}{'br': None, '2θ=22.55±0.2\u2003\u2003(10)'}{'br': None, '2θ=22.96±0.2\u2003\u2003(11)'}{'br': None, '2θ=23.22±0.2\u2003\u2003(12)'}{'br': None, '2θ=24.10±0.2\u2003\u2003(13)'}{'br': None, '2θ=24.50±0.2\u2003\u2003(14)'}{'br': None, '2θ=26.35±0.2\u2003\u2003(15).'}2. (canceled)3. (canceled)4. The crystalline modification I of mesosulfuron-methyl according to claim 1 , exhibiting a Differential Scanning calorimeter (DSC) thermogram having endothermic melting peak with onset at 188.8° C. and peak maximum at about 192.9° C.5. The crystalline modification I of mesosulfuron-methyl according to claim 1 , exhibiting IR spectrum with the characteristic bands at 3246.88 claim 1 , 2958.83 claim 1 , 1741.75 and 1712.06 cm.6. A process for the preparation of a crystalline modification I of mesosulfuron-methyl according to claim 1 , comprising:i) preparing a solution of an amorphous mesosulfuron-methyl in a solvent, wherein the solvent is 1,1-dichloroethane, ethanol, or a mixture thereof;ii) effecting crystallization of mesosulfuron-methyl from the solution to obtain a precipitate; andiii) ...

SYNERGISTIC HERBICIDAL COMPOSITION AND USE THEREOF

A herbicidal composition is provided, the composition comprising: (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of methyl 2-[(4,6-dimethoxypyrimidin-2-ylcarbamoyl)sulfamoyl]-α-(methanesulfonamido)-p-toluate (mesosulfuron-methyl). A method of controlling undesirable plant growth at a locus comprises applying to the locus herbicidally effective amounts of both (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of methyl 2-[(4,6-dimethoxypyrimidin-2-ylcarbamoyl)sulfamoyl]-α-(methanesulfonamido)-p-toluate (mesosulfuron-methyl). 1. A composition comprising a herbicidally effective amount of(A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and [{'br': None, '2θ=5.41±0.2\u2003\u2003(1)'}, {'br': None, '2θ=10.26±0.2\u2003\u2003(2)'}, {'br': None, '2θ=10.88±0.2\u2003\u2003(3)'}, {'br': None, '2θ=12.14±0.2\u2003\u2003(4)'}, {'br': None, '2θ=16.38±0.2\u2003\u2003(5)'}, {'br': None, '2θ=18.87±0.2\u2003\u2003(6)'}, {'br': None, '2θ=19.47±0.2\u2003\u2003(7)'}, {'br': None, '2θ=20.82±0.2\u2003\u2003(8)'}, {'br': None, '2θ=21.88±0.2\u2003\u2003(9)'}, {'br': None, '2θ=22.55±0.2\u2003\u2003(10)'}, {'br': None, '2θ=22.96±0.2\u2003\u2003(11)'}, {'br': None, '2θ=23.22±0.2\u2003\u2003(12)'}, {'br': None, '2θ=24.10±0.2\u2003\u2003(13)'}, {'br': None, '2θ=24.50±0.2\u2003\u2003(14)'}, {'br': None, '2θ=26.35±0.2\u2003\u2003(15).'}], '(B) the crystalline modification I of methyl 2-[(4,6-dimethoxypyrimidin-2-ylcarbamoyl)sulfamoyl]-α-(methanesulfonamido)-p-toluate (mesosulfuron-methyl), wherein the crystalline modification I of mesosulfuron-methyl is crystallized using 1,1-dichloroethane and/or ethanol, and the crystalline modification I of mesosulfuron-methyl exhibits each of the following reflexes as 20 values in an X-ray powder diffractogram recorded using Cu-Kα ...

SYNERGISTIC HERBICIDAL COMPOSITION AND USE THEREOF

A herbicidal composition is provided, the composition comprising: (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of methyl 3-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl)thiophene-2-carboxylate (thifensulfuron-methyl). A method of controlling undesirable plant growth at a locus comprises applying to the locus herbicidally effective amounts of both (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of methyl 3-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl)thiophene-2-carboxylate (thifensulfuron-methyl). 1. A composition comprising a herbicidally effective amount of(A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and [{'br': None, '2θ=6.62±0.2\u2003\u2003(1)'}, {'br': None, '2θ=11.11±0.2\u2003\u2003(2)'}, {'br': None, '2θ=12.84±0.2\u2003\u2003(3)'}, {'br': None, '2θ=13.30±0.2\u2003\u2003(4)'}, {'br': None, '2θ=15.48±0.2\u2003\u2003(5)'}, {'br': None, '2θ=20.04±0.2\u2003\u2003(6)'}, {'br': None, '2θ=22.34±0.2\u2003\u2003(7)'}, {'br': None, '2θ=24.62±0.2\u2003\u2003(8)'}, {'br': None, '2θ=24.92±0.2\u2003\u2003(9)'}, {'br': None, '2θ=27.83±0.2\u2003\u2003(10).'}], '(B) the crystalline modification I of methyl 3-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl)thiophene-2-carboxylate (thifensulfuron-methyl), wherein the crystalline modification I of thifensulfuron-methyl is crystallized using isopropanol and/or n-butanol, and the crystalline modification I of thifensulfuron-methyl exhibits each of the following reflexes as 2θ values in an X-ray powder diffractogram recorded using Cu-Kα radiation at 25° C.2. The composition according to claim 1 , wherein the weight ratio of (A) to (B) is in the range of from about 150:1 to about 1:50.3. The composition according to claim 2 , wherein the weight ratio of (A) to (B) is ...

PROCESS FOR PREPARING A NOVEL CRYSTALLINE FORM OF THIFENSULFURON-METHYL AND USE OF THE SAME

A the crystalline form of thifensulfuron-methyl of formula (I), the crystal preparation process, the analyses of the crystal through various analytical methods and using the crystal to prepare stable agrochemical formulation. The invention also describes the use of various solvents towards the crystalline form preparation conditions. 1. A crystalline modification I of (methyl 3-(4-methoxy-6-methyl-1 ,3 ,5-triazin-2-ylcarbamoylsulfamoyl)thiophene-2-carboxylate) (thifensulfuron-methyl) exhibiting at least three each of the following reflexes , in any combination , as 20 values in X-ray powder diffractogram recorded using Cu-Kα radiation at 25° C.:{'br': None, '2θ=6.62±0.2\u2003\u2003(1)'}{'br': None, '2θ=11.11±0.2\u2003\u2003(2)'}{'br': None, '2θ=12.84±0.2\u2003\u2003(3)'}{'br': None, '2θ=13.30±0.2\u2003\u2003(4)'}{'br': None, '2θ=15.48±0.2\u2003\u2003(5)'}{'br': None, '2θ=20.04±0.2\u2003\u2003(6)'}{'br': None, '2θ=22.34±0.2\u2003\u2003(7)'}{'br': None, '2θ=24.62±0.2\u2003\u2003(8)'}{'br': None, '2θ=24.92±0.2\u2003\u2003(9)'}{'br': None, '2θ=27.83±0.2\u2003\u2003(10).'}2. (canceled)3. The crystalline modification I of thifensulfuron-methyl according to claim 1 , exhibiting an IR spectrum with characteristic bands at one or more of 3293.22 claim 1 , 3075.76 and 1728.23 cm.4. The crystalline modification I of thifensulfuron-methyl according exhibiting a Differential Scanning calorimeter (DSC) thermogram having a single predominant endotherm at about 179° C. to 183° C.5. A process of preparing crystalline modification I of thifensulfuron-methyl according to claim 1 , comprising:i) dissolving an amorphous thifensulfuron-methyl in a solvent;ii) precipitating the dissolved compound into crystalline modification I of thifensulfuron-methyl; andiii) isolating the precipitated crystalline modification I.6. The process according to claim 5 , where the solvent comprises at least one of isopropanol and n-butanol.7. (canceled)8. The process according to claim 6 , wherein step ii) ...

METHOD FOR CONTROLLING GROWTH OF GLYPHOSATE-TOLERANT PLANTS

A method for controlling the growth of unwanted plants in crop plants at a locus using a sulphonylurea herbicide, wherein the sulfonylurea herbicide exhibits phytotoxicity to the crop plants is provided, The method comprises: 1. A method for controlling the growth of unwanted plants in crop plants at a locus using a sulphonylurea herbicide , wherein the sulfonylurea herbicide exhibits phytotoxicity to the crop plants , the method comprising:a). applying a sulphonylurea herbicide to the locus; andb). planting the crop plants at the locus a time N days after the application of the sulphonylurea herbicide in step a).2. The method according to claim 1 , wherein the sulphonylurea herbicide is selected from amidosulfuron claim 1 , azimsulfuron claim 1 , bensulfuron claim 1 , chlorimuron claim 1 , cyclosulfamuron claim 1 , ethoxysulfuron claim 1 , flazasulfuron claim 1 , flucetosulfuron claim 1 , flupyrsulfuron claim 1 , foramsulfuron claim 1 , halosulfuron claim 1 , imazosulfuron claim 1 , mesosulfuron claim 1 , metazosulfuron claim 1 , methiopyrisulfuron claim 1 , monosulfuron claim 1 , nicosulfuron claim 1 , orthosulfamuron claim 1 , oxasulfuron claim 1 , primisulfuron claim 1 , propyrisulfuron claim 1 , pyrazosulfuron claim 1 , rimsulfuron claim 1 , sulfometuron claim 1 , sulfosulfuron claim 1 , trifloxysulfuron claim 1 , zuomihuanglong claim 1 , chlorsulfuron claim 1 , cinosulfuron claim 1 , ethametsulfuron claim 1 , iodosulfuron claim 1 , iofensulfuron claim 1 , metsulfuron claim 1 , prosulfuron claim 1 , thifensulfuron claim 1 , triasulfuron claim 1 , tribenuron claim 1 , triflusulfuron claim 1 , tritosulfuron claim 1 , and mixtures thereof.3. The method according to claim 2 , wherein the sulphonylurea herbicide is nicosulfuron.4. The method according to claim 1 , wherein the crop plants are soybean plants or corn plants.5Amaranthus hybridusAmaranthus palmeriAmaranthus spinosusAmaranthus tuberculatusAmbrosia artemisiifoliaAmbrosia trifidaBidens pilosaBidens ...

HERBICIDAL COMPOSITION COMPRISING NICOSULFURON OR ITS SALT AND S -METOLACHLOR OR ITS SALT

At present, various herbicidal compositions have been developed and use, but there are a variety of types of weeds to be controlled, and their development lasts for a long period of time. Thus, a herbicidal composition having a broad herbicidal spectrum, having high activity and having a long-lasting effect has been desired. 1. A herbicidal composition comprising , as active ingredients , (a) nicosulfuron or its salt , (b) S-metolachlor or its salt , and (c) bicyclopyrone or its salt.2. A method for controlling undesired plants or inhibiting their growth , which comprises applying a herbicidally effective amount of (a) nicosulfuron or its salt , a herbicidally effective amount of (b) S-metolachlor or its salt , and a herbicidally effective amount of (c) bicyclopyrone or its salt to the undesired plants or to a place where they grow.3. The herbicidal composition according to claim 1 , wherein the weight ratio of (a) to (b) is within a range of from 1:1.3 to 1:800 claim 1 , and the weight ratio of (a) to (c) is within a range of from 1:0.006 to 1:400.4. The method according to claim 2 , wherein (a) is applied in an amount of from 5 to 150 g/ha claim 2 , (b) is applied in an amount of from 200 to 4 claim 2 ,000 g/ha claim 2 , and (c) is applied in an amount of from 1 to 2 claim 2 ,000 g/ha.5. The method according to claim 2 , wherein the undesired plants are undesired plants in 7—or later leaf stage.6. The method according to claim 2 , wherein the undesired plants are undesired plants having lowered sensitivity to herbicides.7. The method according to claim 5 , wherein the undesired plants are plants having lowered sensitivity to ALS inhibitors.8. The method according to claim 2 , wherein the undesired plants are controlled or their growth is inhibited over at least 60 days after the application of the herbicidally active ingredients.9. The method according to claim 2 , wherein the undesired plants are noxious weeds in corn fields.10. The method according to claim 4 , ...

PESTICIDE COMPOSITION AND METHOD

The present invention relates to a pesticide composition comprising at least one pesticide compound and at least one adjuvant comprising a microfibrillated cellulose. The invention also relates to a method for preparing a pesticide composition comprising the admixture of a microfibrillated cellulose, and a pesticide compound. 1. Pesticide composition comprising:i) at least one pesticide compound, andii) at least one adjuvant comprising a microfibrillated cellulose.2. Pesticide composition of claim 1 , where the microfibrillated cellulose is free of cationic substituents.3. The Composition of claim 1 , wherein the amount of the microfibrillated cellulose is 0.5% by weight or less.4. The Composition of claim 1 , wherein the amount of the microfibrillated cellulose is from 0.001%-0.4% by weight.5. The Composition of claim 1 , wherein said microfibrillated cellulose (MFC) is an unmodified MFC and/or a chemically modified MFC having neutral or negatively charged substituents and/or a physically modified MFC.6. The Composition of claim 5 , wherein the microfibrillated cellulose (MFC) is an unmodified MFC and/or a chemically modified MFC having neutral or negatively charged substituents.7. The Composition of claim 5 , wherein the microfibrillated cellulose (MFC) is a physically modified MFC.8. The Composition of claim 1 , wherein said pesticide is a herbicide claim 1 , insecticide claim 1 , growth regulator and/or fungicide.9. The Composition of claim 8 , wherein said pesticide is a hydrophilic pesticide.10. The Composition of claim 8 , wherein said pesticide is a herbicide selected from the groups consisting of Acetyl CoA carboxylase inhibitors claim 8 , Acetolacetate synthase and/or Acetohydroxy acid synthase inhibitors claim 8 , Photosystem II inhibitors claim 8 , Photosystem I inhibitors claim 8 , Carotenoid biosynthesis inhibitors claim 8 , Enolpyruvyl shikimate-3-phosphate synthase inhibitors claim 8 , Glutamine synthase inhibitors and/or Synthetic auxins.11. The ...

PROCESS FOR PREPARING A NOVEL FORMULATION OF RIMSULFURON AND USE OF THE SAME

A herbicidal composition including rimsulfuron with anti-hydrolysis agent, wherein the anti-hydrolysis agent is 2-isoxazoline-3-carboxylic acid derivatives having formula (I): 2. (canceled)3. The herbicidal composition according to claim 1 , wherein the anti-hydrolysis agent is isoxadifen-ethyl.4. The herbicidal composition according to claim 1 , wherein the amount of antihydrolysis agent to the amount of rimsulfuron is in a range of about 1:10 to about 5:1.5. (canceled)6. The herbicidal composition according to claim 1 , wherein the amount of rimsulfuron is less than about 30% by weight of the composition.7. The herbicidal composition according to claim 1 , wherein the amount of rimsulfuron is about 25% by weight of the composition.8. The herbicidal composition according to claim 1 , wherein the composition is formulated as a suspension concentrate (SC) claim 1 , an oil-based suspension concentrate (OD) claim 1 , a soluble granule (SG) claim 1 , a dispersible concentrate (DC) claim 1 , an emulsifiable concentrate (EC) claim 1 , an emulsion for seed treatment (ES) claim 1 , a flowable concentrate for seed treatment (FS) claim 1 , a granule claim 1 , a microgranule (MG) claim 1 , a suspo-emulsion (SE) claim 1 , or a water dispersible granule (WG).9. The herbicidal composition according to claim 8 , further comprising one or more auxiliaries selected from the group consisting of a liquid diluent claim 8 , a solid diluent claim 8 , a wetting agent claim 8 , a dispersant claim 8 , a thickening agent claim 8 , and combinations thereof.10. A method for controlling weeds claim 1 , comprising applying to a plant or plant part claim 1 , or the surroundings thereof claim 1 , an effective amount of the herbicidal composition according to .12. (canceled)13. The method according to claim 11 , wherein the hydrolysis resistance providing effective amount is from about 8 wt % to about 40 wt % claim 11 , based upon the weight of the herbicidal composition.14. The method according to ...

NITROGEN-CONTAINING MACROCYCLIC CONJUGATES AS RADIOPHARMACEUTICALS

The present invention relates to compounds that are useful as metal ligands and which either contain a molecular recognition moiety or can be bound to a molecular recognition moiety and methods of making these compounds. Once the compounds that contain a molecular recognition moiety are coordinated with a suitable metallic radionuclide, the coordinated compounds are useful as radiopharmaceuticals in the areas of radiotherapy and diagnostic imaging. The invention therefore also relates to methods of diagnosis and therapy utilising the radiolabelled compounds of the invention. 2. The method according to claim 1 , wherein the cancer is breast cancer claim 1 , colon cancer claim 1 , lung cancer claim 1 , ovarian cancer claim 1 , prostate cancer claim 1 , head and/or neck cancer claim 1 , renal cancer claim 1 , gastric cancer claim 1 , pancreatic cancer or brain cancer.3. The method according to claim 2 , wherein the cancer is prostate cancer.4. A method of treating or detecting a hyperproliferative disease claim 1 , the method including the step of administering to a subject in need thereof claim 1 , a therapeutically effective amount of the compound of Formula (I) as defined in .5. The method according to claim 4 , wherein the hyperproliferative disease is a leukemia claim 4 , psoriasis or restenosis.6. A method of treating or detecting a pre-cancer condition claim 1 , the method including the step of administering to a subject in need thereof claim 1 , a therapeutically effective amount of the compound of Formula (I) as defined in .7. The method according to claim 6 , wherein the pre-cancer condition is familial adenomatous polyposis claim 6 , colonic adenomatous polyps claim 6 , myeloid dysplasia claim 6 , endometrial dysplasia claim 6 , endometrial hyperplasia with atypia claim 6 , cervical dysplasia claim 6 , vaginal intraepithelial neoplasia claim 6 , benign prostatic hyperplasia claim 6 , papillomas of the larynx claim 6 , actinic and solar keratosis claim 6 , ...

USE OF SOPHOROLIPIDS AND DERIVATIVES THEREOF IN COMBINATION WITH PESTICIDES AS ADJUVANT/ADDITIVE FOR PLANT PROTECTION AND THE INDUSTRIAL NON-CROP FIELD

Use of sophorolipids as adjuvants in combination with pesticides as tank mix additive and/or as formulation additive for crop protection and for the industrial non-crop sector. 110.-. (canceled)11. A composition comprisinga) at least one of a sophorolipid, a sophorolipid preparation, and derivatives thereof obtainable by fermentative preparation, and at least oneb) active pesticidal ingredientwith the proviso that component (a) has no inherent pesticidal activity.12. The composition as claimed in wherein a pesticidal efficacy and activity of the composition is greater than the sum of the efficacies of the individual components.13. The composition as claimed in claim 11 , wherein component a) is present in an adjuvant claim 11 , based on the solids claim 11 , with a fraction of >30% by weight in the adjuvant.14. A composition as claimed in claim 11 , wherein fermentative preparation includes a hydrophobic substance selected from the group consisting of hydrocarbons claim 11 , fatty acids claim 11 , fatty acid esters claim 11 , fatty alcohols and mixtures thereof.15. A composition as claimed in claim 11 , wherein component a) is in purified or unpurified form claim 11 , andi) is present as a mixture of lactone and acid form, with an acid fraction of 10% to less than 60% by weight, orii) consists to a fraction of >90% by weight of the lactone form, which can be solubilized by adjustment of pH to a level of between 6 and 8, oriii) is present as methyl or ethyl ester, with a fraction of 1% to 100% by weight of the respective ester.1719.-. (canceled) The present application is a continuation application of U.S. Ser. No. 13/497,588 filed Mar. 22, 2012, which is a U.S. National Phase of PCT/EP2010/062600 filed Aug. 30, 2010, the entire contents of which are incorporated herein by reference.The invention relates to the use of sophorolipids and/or derivatives thereof and compositions as a formulating additive and/or tank mix additive (also called adjuvant) for pesticides or ...

BLEED-OUT PREVENTING AGENT, COMPOSITION FOR PREVENTING BLEED-OUT INCLUDING THE SAME, AND METHOD OF PREVENTING BLEED-OUT

Provided are a bleed-out preventing agent and a composition for preventing bleed-out including the same. 1. A bleed-out preventing agent represented by Formula 1:{'br': None, 'sub': 1', 'a1', '2', 'a2, '(R)—X—(R)\u2003\u2003'}In Formula 1,{'sub': 6', '60', '1', '60, 'X is selected from the group consisting of a C-Carylene group and a C-Cheteroarylene group;'}{'sub': 1', '1', '60', '1', '60', '6', '60', '6', '60', '1', '1', '2', '1', '2', '1', '60', '1', '60', '6', '60', '6', '60, 'Ris selected from the group consisting of a C-Calkyl group, a fluorine-substituted C-Calkyl group, a C-Caryl group, a fluorine-substituted C-Caryl group, —NH(Q), and —N(Q)(Q); and Qand Qare each independently selected from the group consisting of a C-Calkyl group, a fluorine-substituted C-Calkyl group, a C-Caryl group, and a fluorine-substituted C-Caryl group;'}a1 is selected from 1, 2, and 3;{'sub': '2', 'Ris selected from functional groups including one or more heterogeneous elements that are selected from the group consisting of oxygen (O), sulfur (S), boron (B), nitrogen (N), phosphorous (P), and silicon (Si); and'}a2 is selected from 1, 2, and 3.2. The bleed-out preventing agent of claim 1 , wherein X is selected from the group consisting of a phenylene group claim 1 , a naphthylenylene group claim 1 , a phenanthrenylene group claim 1 , an anthracenylene group claim 1 , a triphenylenylene group claim 1 , a pyrenylene group claim 1 , a chrysenylene group claim 1 , a pyrrolylene group claim 1 , an imidazolylene group claim 1 , a pyrazolylene group claim 1 , a pyridinylene group claim 1 , a pyrazinylene group claim 1 , a pyrimidinylene group claim 1 , an indolylene group claim 1 , a quinolinylene group claim 1 , an isoquinolinylene group claim 1 , a phenanthridinylene group claim 1 , a phenanthrolinylene group claim 1 , a triazolylene group claim 1 , a tetrazolylene group claim 1 , and a triazinylene group.3. The bleed-out preventing agent of claim 1 , wherein X is selected ...

A Method for Topically Treating Actinic Keratosis on the Scalp with Ingenol 3-(3,5-diethylisoxazole-4-carboxylate)

The invention relates to the treatment of actinic keratosis on the scalp with ingenol 3-(3,5-diethylisoxazole-4-carboxylate). 1. A method of treating a subject diagnosed with actinic keratosis on the scalp , said method comprising applying an effective amount of ingenol 3-(3 ,5-diethylisoxazole-4-carboxylate) to a treatment area on the scalp for three days.2. The method of claim 1 , wherein the method provides a reduction in the number of actinic keratosis lesions in the treatment area.3. The method of claim 1 , wherein the three day treatment is three consecutive days.4. The method of claim 1 , wherein the treatment area is up to about 250 cm.5. The method of claim 1 , wherein the effective amount of the ingenol 3-(3 claim 1 ,5-diethylisoxazole-4-carboxylate) is applied from a dosage strength formulation of ingenol 3-(3 claim 1 ,5-diethylisoxazole-4-carboxylate) of about 0.037%.6. The method of claim 1 , wherein the amount of the ingenol 3-(3 claim 1 ,5-diethylisoxazole-4-carboxylate) applied is about 0.9 mg ingenol 3-(3 claim 1 ,5-diethylisoxazole-4-carboxylate)/per day/250 cmtreatment area.7. The method of claim 1 , wherein the ingenol 3-(3 claim 1 ,5-diethylisoxazole-4-carboxylate) is formulated in a gel.8. The method of claim 1 , wherein the ingenol 3-(3 claim 1 ,5-diethylisoxazole-4-carboxylate) is topically applied in a concentration of about 0.037%.9. A method of treating a subject diagnosed with actinic keratosis on the scalp claim 1 , said method comprising topically applying an effective amount of ingenol 3-(3 claim 1 ,5-diethylisoxazole-4-carboxylate) to a treatment area on the the scalp for three consecutive days claim 1 , wherein said method provides a reduction in the number of actinic keratosis lesions in the treated area on the scalp claim 1 , wherein the treatment area is of a size up to about 250 cm claim 1 , and wherein the dosage strength of the ingenol 3-(3 claim 1 ,5-diethylisoxazole-4-carboxylate) is about 0.037%. The invention relates to the ...

HERBICIDAL COMPOSITION

At present, many herbicidal compositions have been developed and used, but they are not necessarily sufficient to control undesired plants such as weeds to be controlled in some cases, and a herbicidal composition having high activity has been desired. 1. A method for controlling undesired plants or inhibiting their growth , which comprises applying a herbicidal composition comprising (A) flazasulfuron or its salt and (B) mesotrione or its salt.2. The method composition according to claim 1 , wherein the mixing ratio of (A) to (B) is from 1:1 to 1:20 by the weight ratio.3. The method according to claim 1 , wherein the undesired plants are gramineae claim 1 , compositae claim 1 , leguminosae claim 1 , caryophyllaceae claim 1 , geraniaceae claim 1 , labiatae claim 1 , convolvulaceae claim 1 , portulacaeae or polygonaeae.4Avena fatuaPoa annuaPanicum maximumConyza bonariensiscanadensisTaraxacum officinaleAmbrosia artemisiifoliasesbaniaSesbania rostrataTrifolium repensCerastium glomeratumGeranium carolinianumLamium amplexicauleConvolvulus arvensisPortulaca oleraceaPolygonum lapathifoliumPolygonum scabrum. The method according to claim 3 , wherein the undesired plants are wild oat (L.) claim 3 , annual bluegrass (L.) claim 3 , guinea grass (Jacq.) claim 3 , hairy fleabane ((L.) Cronq.) claim 3 , horseweed (Erigeron L.) claim 3 , dandelion (Weber) claim 3 , common ragweed (L.) claim 3 , rostrate (Bremek. & Oberm.) claim 3 , white clover (L.) claim 3 , sticky chickweed (Thuill.) claim 3 , carolina geranium (L.) claim 3 , henbit (L.) claim 3 , field bindweed (L.) claim 3 , common purslane (L.) claim 3 , spotted knotweed (L.) or green smartweed (MOENCH).5Poa annuaConyza bonariensisErigeron canadensisLamium amplexicauleConvolvulus arvensisPortulaca oleraceaPolygonum lapathifoliumPolygonum scabrum. The method according to claim 4 , wherein the undesired plants are annual bluegrass (L.) claim 4 , hairy fleabane ((L.) Cronq.) claim 4 , horseweed (L.) claim 4 , henbit (L.) claim 4 ...

METHOD FOR THE INDUSTRIAL PRODUCTION OF 2-HALO-4,6-DIALKOXY-1,3,5-TRIAZINES AND THEIR USE IN THE PRESENCE OF AMINES

A method for stabilization of collagen matrices and of condensation of natural and synthetic polymers that uses 2-halo-4,6-dialkoxy-1,3,5-triazines in the presence of one or more amines as activating agents for reactions of crosslinking, condensation, grafting, and curing of collagen matrices, cellu lose, modified celluloses, polysaccharides, acid unsaturated polymers, and chiral and non-chiral amines, etc. Forming an integral part of the present invention is also the method for production on an industrial scale of 2-halo-4,6-dialkoxy-1,3,5-triazines. 137-. (canceled)39. The method according to claim 38 , wherein the first reagent comprises one or more 2-halo-4 claim 38 ,6-dialkoxy-1 claim 38 ,3 claim 38 ,5-triazines of formula III as active principle claim 38 , in a concentration ranging between 0.1 and 1.0 M.40. The method according to claim 38 , wherein Reagent 1 comprises a buffer selected from the group consisting of MES claim 38 , ACES claim 38 , BES claim 38 , BIS-Tris claim 38 , MOPS claim 38 , TEA claim 38 , TAPSO claim 38 , POPSO claim 38 , TAPS claim 38 , formiate claim 38 , phosphate claim 38 , and succinate; and a base or a salt of formula XY claim 38 , where X is selected from the group consisting of Na claim 38 , K claim 38 , and Ag claim 38 , and Y is selected from the group consisting of ClO claim 38 , BF claim 38 , PF claim 38 , CO claim 38 , Cl claim 38 , and HCO.41. The method according to claim 38 , wherein the solvent of Reagent 1 is selected from the group consisting of aliphatic ether claim 38 , halogenate claim 38 , alcohol claim 38 , ketone claim 38 , ester claim 38 , aromatic hydrocarbon claim 38 , aliphatic hydrocarbon claim 38 , amide claim 38 , carbonate claim 38 , DMSO claim 38 , and water.42. The method according to claim 38 , wherein Reagent 2 comprises one or more linear claim 38 , branched claim 38 , cyclic claim 38 , aromatic claim 38 , heterocyclic tertiary amines claim 38 , and/or a quaternary salt thereof as active principle ...

NITROGEN-CONTAINING MACROCYCLIC CONJUGATES AS RADIOPHARMACEUTICALS

The present invention relates to compounds that are useful as metal ligands and which either contain a molecular recognition moiety or can be bound to a molecular recognition moiety and methods of making these compounds. Once the compounds that contain a molecular recognition moiety are coordinated with a suitable metallic radionuclide, the coordinated compounds are useful as radiopharmaceuticals in the areas of radiotherapy and diagnostic imaging. The invention therefore also relates to methods of diagnosis and therapy utilising the radiolabelled compounds of the invention. 2. The compound according to wherein X is a linking moiety having from 1 to 20 atoms in the normal chain.3. The compound according to wherein X is a group of the formula:{'br': None, 'sub': 2', 'q', 'r', '2', 's, '—(CH)CO(AA)NH(CH)—'}wherein each AA is independently an amino acid group;q is an integer selected from the group consisting of 1, 2, 3, 4, 5, 6, 7, and 8;r is an integer selected from the group consisting of 0, 1, 2, 3, 4, 5, 6, 7, and 8; ands is an integer selected from the group consisting of 0, 1, 2, 3, 4, 5, 6, 7, and 8.4. The compound according to wherein q is 3 claim 3 , r is 0 and s is 5.5. The compound according to wherein X is a group of the formula{'br': None, 'sub': 2', 'n, '—(CH)—,'}{'sub': 2', '1', '12', '3', '12', '6', '18', '1', '18, 'sup': 3', '3, 'wherein optionally one or more of the CHgroups may be independently replaced by a heteroatomic group selected from S, O, P and NRwhere Ris selected from the group consisting of H, optionally substituted C-Calkyl, optionally substituted C-Ccycloalkyl, optionally substituted C-Caryl, and optionally substituted C-Cheteroaryl; and'}n is an integer selected from the group consisting of 1, 2, 3, 4, 5, 6, 7, 8, 9 and 10.6. The compound according to wherein n is an integer selected from the group consisting of 1 claim 5 , 2 claim 5 , 3 claim 5 , 4 claim 5 , and 5.7. The compound according to wherein X is selected from the group ...

SYNERGISTIC HERBICIDAL COMPOSITION AND USE THEREOF

A herbicidal composition is provided, the composition comprising: (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of 1-(4,6-dimethoxypyrimidin-2-yl)-3-(3-ethylsulfonyl-2-pyridylsulfonyl)urea (rimsulfuron). A method of controlling plant growth at a locus comprises applying to the locus herbicidally effective amounts of both (A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and (B) the crystalline modification I of 1-(4,6-dimethoxypyrimidin-2-yl)-3-(3-ethylsulfonyl-2-pyridylsulfonyl)urea (rimsulfuron). 1. A composition comprising a herbicidally effective amount of(A) the crystalline modification I of 2-(4-mesyl-2-nitrobenzoyl)cyclohexane-1,3-dione (mesotrione); and(B) the crystalline modification I of 1-(4,6-dimethoxypyrimidin-2-yl)-3-(3-ethylsulfonyl-2-pyridylsulfonyl)urea (rimsulfuron).2. The composition according to claim 1 , wherein the weight ratio of (A) to (B) is in the range of from about 150:1 to about 1:50.3. The composition according to claim 2 , wherein the weight ratio of (A) to (B) is in the range of from about 40:1 to about 1:3.4. The composition according to claim 3 , wherein the weight ratio of (A) to (B) is about 10:1.5. The composition according to claim 1 , wherein the total amount of (A) and (B) is from 5% to 99% by weight of the composition.6. The composition according to claim 5 , wherein the composition comprises claim 5 , by weight claim 5 , from about 1% to about 90% of (A) and from about 0.1% to about 90% of (B).7. The composition according to claim 5 , wherein the composition comprises claim 5 , by weight claim 5 , from about 1% to about 70% of (A) and from about 1% to about 60% of (B).8. The composition according to claim 1 , further comprising one or more auxiliaries selected from the group consisting of extenders claim 1 , carriers claim 1 , solvents claim 1 , surfactants claim 1 , stabilizers claim ...

SULFONYLUREA HERBICIDE-CONTAINING SUBSTRATES AND METHODS OF MAKING THE SAME

Compositions comprising a substrate coated with a sulfonylurea herbicide, and methods for making and using such compositions, are generally described herein. 1. A composition comprising a substrate , a sulfonylurea herbicide and a carrier.2. The composition of claim 1 , wherein the carrier comprises polybutene claim 1 , white mineral oil claim 1 , mineral seal oil claim 1 , hexylene glycol claim 1 , or combinations thereof.3. The composition of or claim 1 , wherein the carrier comprises 0.01-10.00% by weight of the composition.4. The composition of any of - claim 1 , wherein the substrate comprises a stabilizing compound.5. The composition of claim 4 , wherein the stabilizing compound comprises cellulose fiber.6. The composition of claim 5 , wherein the cellulose fiber comprises BIODAC®.7. The composition of any of the above claims claim 5 , wherein the substrate comprises a fertilizer.8. The composition of claim 7 , wherein the fertilizer is methylene urea claim 7 , coated urea claim 7 , uncoated urea claim 7 , or combinations thereof.9. The composition of any of - claim 7 , wherein the sulfonylurea herbicide comprises metsulfuron-methyl.10. The composition of any of - claim 7 , wherein the composition has less than 10% degradation of metsulfuron-methyl over a period of 9 months.11. The composition of any of - claim 7 , wherein the composition has less than 10% degradation when stored at a temperature of 50° C. or less for one month.12. The composition of any of - claim 7 , wherein the composition has less than 10% degradation when stored at a temperature of 40° C. or less for two months.13. The composition of any of - claim 7 , wherein the composition has less than 10% degradation when stored at a temperature of 35° C. or less for three months.14. The composition of any of - claim 7 , wherein the composition has less than 10% degradation when stored at room temperature or less for 24 months.15. The composition of any of - claim 7 , wherein the composition has a pH ...

COMPOSITION COMPRISING ALLANTOIN AND METHOD OF APPLYING ALLANTOIN TO A PLANT

A method for cultivating a plant includes: applying allantoin to a grapevine; and growing the grapevine in a cultivation medium. Applying the allantoin may be performed at a veraison stage of the grapevine. Allantoin may be applied to a part of the grapevine that is above the cultivation medium at a dose of about 0.05 to 5 g per grapevine, and may be applied by spraying the allantoin on leaves or fruits of the grapevine at a dose of about 0.05 to 5 g per grapevine. The grapevine may be grown at a density of about 1,500 to 10,000 per hectare, and about 0.1 to 13 g/mof the allantoin may be applied. 1. A method for cultivating a plant , comprising:applying allantoin to a grapevine; andgrowing the grapevine in a cultivation medium.2. The method according to claim 1 , wherein applying the allantoin is performed at a veraison stage of the grapevine.3. The method according to claim 1 , wherein the allantoin is applied to a part of the grapevine that is above the cultivation medium at a dose of about 0.05 to 5 g per grapevine.4. The method according to claim 1 , wherein the allantoin is applied by spraying the allantoin on leaves or fruits of the grapevine at a dose of about 0.05 to 5 g per grapevine.5. The method according to claim 1 , wherein the grapevine is grown at a density of about 1 claim 1 ,500 to 10 claim 1 ,000 per hectare claim 1 , and wherein about 0.1 to 13 g/mof the allantoin is applied.6. The method according to claim 1 , wherein an anthocyanin content in grapes of the grapevine is increased by about 10 to 350% at least 10 days after applying the allantoin claim 1 , as compared to an anthocyanin content in grapes of a grapevine that is not applied with allantoin.7. The method according to claim 1 , wherein an anthocyanin content in grapes of the grapevine is increased by about 150% or more 10 days after applying the allantoin claim 1 , as compared to an anthocyanin content in grapes of a grapevine that is not applied with allantoin.8. The method according to ...

PLANT GROWTH REGULATOR COMPOSTION HAVING SYNERGISTIC EFFECT

A plant growth regulator composition having synergistic effect. The effective ingredients of the composition include active components A and B, wherein the active component A is thidiazuron, and the active component B is brassinolide or a derivative thereof. Also, a preparation method and use of the composition. Experimental results indicate that the composition is effective in regulating the growth, increasing the disease and stress resistance, promoting the health and increasing the yield of crops. 1. A plant growth regulator composition having synergistic effect , comprising active components A and B , wherein the active component A is thidiazuron , and the active component B is bras sinolide or a derivative thereof , and the weight ratio of the active component A to the active component B is 1:0.001-0.19.2. The composition according to claim 1 , wherein the weight ratio of the active component A to the active component B is 0.001-0.17.3. The composition according to claim 2 , wherein the weight ratio of the active component A to the active component B is 0.0012-0.16.4. The composition according to claim 2 , wherein the weight ratio of the active component A to the active component B is 0.0011-0.143.5. The composition according to claim 1 , wherein the brassinolide derivative is selected from propionyl bras sinolide.6. The composition according to claim 1 , which is in a pesticidally acceptable formulation prepared with the active ingredients and an adjuvant.7. The composition according to claim 6 , wherein the formulation is an aqueous solution claim 6 , a suspension claim 6 , a soluble concentrate or microcapsules.8. A method promoting or regulating the growth of plants in the agricultural area with the pesticide composition according to .9. A method according to claim 8 , wherein the plants are selected from sorghum claim 8 , wheat or corn. The present invention relates to the field of protection of agricultural plants, in particular to a plant growth ...

ORGANIC SEMICONDUCTOR SOLUTION BLENDS FOR SWITCHING AMBIPOLAR TRANSPORT TO N-TYPE TRANSPORT

The present disclosure describes additives that attenuate a specific transport channel in ambipolar semiconductors to achieve unipolar characteristics. Carrier selective traps are included in the ambipolar semiconductors and are chosen on the basis of energetic preferences for holes or electrons and the relative positions of the molecular orbital energies of host polymer and the dopants. In one embodiment, a composition of matter useful as a current transport region in an organic semiconductor device comprises a semiconducting polymer; and means for accepting holes (e.g., a hole trapping compound) injected into the current transport region so as to impede conduction of the holes in the semiconducting polymer. This simple solution-processable method can improve the on and off current ratios (I/I) of OFETs by up to three orders of magnitude. Moreover, the treatment yields tailored blends that can be used to fabricate complementary inverters with excellent gain and low-power characteristics. 1. A composition of matter , comprising:donor-acceptor copolymers each comprising a main chain section, the main chain section having a repeat unit that comprises a donor and an acceptor; andhole trapping compounds combined with the donor-acceptor copolymers so as to reduce hole current in the donor-acceptor copolymers.2. The composition of matter of claim 1 , further comprising a solution comprising the hole trapping compounds and the donor-acceptor copolymers claim 1 , wherein a total weight percentage (wt. %) of the hole trapping compounds in the solution is in a range of 0.005-50 wt. % based on a total weight of the solution.3. The composition of matter of claim 2 , wherein the wt. % is in a range of 0.005-10 wt. %.4. The composition of matter of claim 1 , further comprising a film cast from a solution claim 1 , wherein:{'sub': CP', 'HT', 'CP', 'CP', 'HT, 'a total weight (W) of the donor-acceptor copolymers added in the solution and a total weight Wof the hole trapping ...

Increased Almond Yields with Brassinosteroid Application

Methods for increasing the yield of almond trees by the application of certain plant growth regulators are disclosed. 1. A method for increasing the number of edible seeds produced by an Almond tree comprising the steps of applying at least one plant growth regulator to flowers of said almond tree at a determined time during flowering; allowing the edible seeds to develop to maturity , and collecting the edible seeds from the tree.2. The method of in which the plant growth regulator solution comprises a brassinosteroid.3. The method of in which the plant growth regulator solution comprises at least one member of the group consisting of 28-Homobrassinolide (HBR) claim 1 , Brassinolide (BL) claim 1 , 24-epibrassinolide (epi-BL) claim 1 , Castasterone (CS) claim 1 , 28-Homocastasterone (HCS) claim 1 , Forchlorfenuron (CPPU) claim 1 , and Gibberellic acid (GA3).4. The method of in which the determined time during flowering is approximately during the full bloom stage.5. The method of in which the determined time during flowering is approximately two weeks after full bloom.6. The method of in which the determined time during flowering is during the petal fall stage.7. The method of in which the plant growth regulator solution is comprised of 28-homobrassinolide at a concentration of about 1 to 10 parts per million concentration.8. The method of in which the plant growth regulator solution is comprised of a brassinosteroid and forchlorfenuron.9. The method of in which the plant growth regulator solution is comprised of a brassinosteroid and forchlorfenuron claim 1 , said forchlorfenuron present in a concentration between 1 part per million and 10 parts per million.10. A plant growth regulating solution comprising a brassinosteroid and forchlorfenuron.11. The plant growth regulating solution of in which the brassinosteroid is 28-homobrassinolide.12. The plant growth regulating solution of in which the brassinosteroid is present at a concentration of between 1 and 10 parts ...

NEAR-INFRARED ABSORPTION COMPOSITION, CURED FILM, NEAR-INFRARED CUT FILTER, SOLID-STATE IMAGING DEVICE, INFRARED SENSOR, AND COMPOUND

To provide a near-infrared absorption composition which contains a squarylium compound having excellent solvent solubility, a cured film which uses the near-infrared absorption composition, a near-infrared cut filter, a solid-state imaging device, an infrared sensor, and a compound. A near-infrared absorption composition includes a compound represented by the following Formula (1) and a resin. Rand Reach independently represent “—S-L-T” or the like, Rand Reach independently represent a hydrogen atom or an alkyl group, Xand Xeach independently represent an oxygen atom or —N(R)—, Rrepresents a hydrogen atom or the like, Yto Yeach independently represent a substituent, p and s each independently represent an integer of 0 to 3, and q and r each independently represent an integer of 0 to 2; and Srepresents an arylene group or the like, Lrepresents an alkylene group or the like, and Trepresents an alkyl group or the like. 2. The near-infrared absorption composition according to claim 1 ,{'sup': '1', 'wherein in Formula (W), Sis an arylene group or a heteroarylene group.'}3. The near-infrared absorption composition according to claim 1 ,{'sup': 1', 'L2', 'L2, 'wherein in Formula (W), Lis an alkylene group, an alkenylene group, —O—, —OR—, or a group obtained by combining two or more thereof, and Ris an alkylene group.'}4. The near-infrared absorption composition according to claim 1 ,{'sup': 1', '1, 'wherein in Formula (W), a -L-Tportion includes a branched alkyl structure.'}5. The near-infrared absorption composition according to claim 1 ,{'sup': 1', '1, 'wherein in Formula (W), a -L-Tportion includes asymmetric carbon.'}6. The near-infrared absorption composition according to claim 1 ,wherein the compound represented by Formula (1) includes two or more types of optical isomers.7. The near-infrared absorption composition according to claim 1 ,{'sup': 3', '4, 'wherein in Formula (1), Rand Reach independently represent a hydrogen atom or a methyl group.'}8. The near-infrared ...

NOVEL CRYSTAL FORMS OF THE MONOSODIUM SALT OF FORAMSULFURON

The present invention relates to a novel crystal form of the monosodium salt of foramsulfuron, a method for preparing this crystal form, use thereof in agrochemical formulations and also particular compositions, mixtures or agrochemical formulations comprising this crystal form, and also a novel monomethanol solvate of the monosodium salt of foramsulfuron. 2. Mixture comprising(i) monosodium salt of foramsulfuron and/or a solvate thereof, and(ii) a diluent or diluent mixture selected from the group consisting of alcohols having 3 to 6 carbon atoms, in this case optionally primary alcohols having 3 to 6 carbon atoms, and ketones having 3 to 6 carbon atoms, and mixtures thereof, or comprises at least 20% by weight thereof. This application is a Divisional Application of U.S. application Ser. No. 15/535,310, filed on 21 Sep. 2017, which is a National Stage entry of International Application No. PCT/EP2015/079283, filed 10 Dec. 2015, which claims priority to European Patent Application No. 14198010.2, filed 15 Dec. 2014. The disclosure of the priority applications are incorporated in their entirety herein by reference.The present invention relates to a novel crystal form of the monosodium salt of foramsulfuron, a method for preparing this crystal form, use thereof in agrochemical formulations and also particular compositions, mixtures or agrochemical formulations comprising this crystal form, and also a novel monomethanol solvate of the monosodium salt of foramsulfuron.Foramsulfuron of formula (I) below and the monosodium salt thereof are known from EP 0 757 679 A1.Foramsulfuron of formula (I) and certain salts of this compound are known herbicidal active ingredients, see “The Pesticide Manual”, 16th edition, The British Crop Protection Council and the Royal Society of Chemistry, 2012.It is also known that foramsulfuron of formula (I) and salts thereof may be used in combination with other herbicidal active ingredients and/or with safeners, described in EP 0 790 771 A1 ...

Synergistic agent and method for selective weed control

Herbicidal pyridinesulfonylureas

A herbicidal mixture of compounds consisting essentially of an effective amount of (N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-3-­(ethylsulfonyl)-2-pyridinesulfonamide I and at least one compound selected from (2-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]-­carbonyl]amino]sulfonyl]-N,N-dimethyl-3-pyridine­carboxamide II and (methyl 3-[[[[(4-methoxy-6-methyl-1,3,5-­triazin-2-yl)-amino]carbonyl]amino]sulfonyl]-2-­thiophenecarboxylate III and their agriculturally suitable salts.

Oil suspension concentrate

The present invention relates to an oil suspension concentrate comprising a) one or more herbicidally active compounds from the group of the pyridylsulfonylureas in suspended form, and b) one or more organic solvents. The oil suspension concentrate is suitable for use in crop protection.

Herbicidal composition comprising a pyrandione herbicide and a sulfonyl urea herbicide

The invention relates to a herbicidal composition comprising: (a) a compound of formula (I) or an agriculturally acceptable salt thereof: wherein R 1 is ethyl or cyclopropyl, and R 2 is chlorine or fluorine; and (b) metazosulfuron or an agriculturally acceptable salt thereof. Preferably, R 1 is ethyl and R 2 is chlorine; or R 1 is cyclopropyl and R 2 is fluorine. The invention also relates to a herbicidal composition comprising: the compound of formula (I) or a salt thereof, and halosulfuron-methyl or a salt thereof, wherein the weight ratio of the compound of formula (I) to the halosulfuron-methyl is from 30:60 to 250:3. The herbicidal compositions are preferably for controlling weeds in crops of useful plants (e.g. rice), especially for controlling Echinochloa, Brachiaria and/or other weeds. The invention also relates to a method of controlling Brachiaria weeds in crops of useful plants, which comprises applying the compound of formula (I) or an agriculturally acceptable salt thereof to the Brachiaria weeds or to the locus thereof.

Oil suspensions of sulphonylureas and agrochemical combinations

An agrochemical formulation in the form of an oil suspension characterised in that it contains as essential elements of the formulation (percentages by weight related to the total weight of the formulation) at least; a herbicide of the sulphonylurea type at a concentration of 0.5-50%, preferably 2-30%, a paraffin mineral oil at a concentration of 10-75%, preferably without the existence of any other type of mineral or vegetable oil in the formulation and the concentration of mineral oil being 40-60%, an organomodified silane compound at a concentration of 5-40%, preferably 10-25%, with the existence of other coformulants until reaching 100% by weight of the formulation.

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Process for preparing n-aryl-sulfonyl-n'-triazolulureas

N-arylsulfonyl-N'-triazolylurea of formula (I) and their salts are prepared. In (I), R1 is a gp. of formula (II) or (III); R2 and R3 each= H or C1-6 alkyl; R4= H, halogen, C1-6 alkyl, C1-6 halo alkyl, cyclopropyl; Z=O or S; R5 and R9= H, halogen, cyano, nitro, C1-6 alkyl, C1-6 haloalkyl, C2-6 alkenyl substd. by 1-3 of halogen atom(s) , etc.; R6= H, halogen, nitro or C1-6 alkoxy; R7 and R8= H, halogen, nitro, C1-6 haloalkyl, -NH2, C1-6 alkyl, C1-6 alkoxy, C1-6 alkoxy, C1-6 alkylthio, C1-6 alkylsulfinyl or C1-6 alkylsulfonyl. (I) have plant growth regulating and bactericidal properties.

Гербицидная композиция с повышенным гербицидным действием и способ повышения гербицидного действия

Описывается гербицидная композиция, включающая гербицидное производное сульфонилмочевины или его соль и алкоксилированный глицерид в массовом соотношении от 2:1 до 1:600. Гербицидная композиция может дополнительно содержать вспомогательное вещество, выбранное из группы, состоящей из лимонной кислоты, ЭДТА и азотсодержащего удобрения. Описывается также способ контроля нежелательной растительности или ингибирования ее роста, который включает нанесение гербицидно эффективного количества гербицидной композиции на нежелательную растительность или место, где она произрастает. Описывается способ повышения гербицидного действия гербицидного производного сульфонилмочевины или его соли с помощью алкоксилированного глицерида. Техническим результатом является расширение спектра растений, на которое распространяется гербицидное действие, увеличение длительности действия гербицида. 6 н. и 2 з.п. ф-лы, 22 табл. ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß RU (19) (11) 2 337 549 (13) C2 (51) ÌÏÊ A01N 47/36 A01N 25/30 A01P 13/00 (2006.01) (2006.01) (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÎÏÈÑÀÍÈÅ ÈÇÎÁÐÅÒÅÍÈß Ê ÏÀÒÅÍÒÓ (21), (22) Çà âêà: 2006105643/04, 30.06.2004 (72) Àâòîð(û): ÉÎÑÈÉ Õèðîñè (JP), ÈÑÈÕÀÐÀ Éîñèàêè (JP), ßÌÀÄÀ Ðèó (JP), ÖÓÐÓÒÀ Òàöóõèêî (JP) (24) Äàòà íà÷àëà îòñ÷åòà ñðîêà äåéñòâè ïàòåíòà: 30.06.2004 (73) Ïàòåíòîîáëàäàòåëü(è): ÈÑÈÕÀÐÀ ÑÀÍÃÈÎ ÊÀÉÑß, ËÒÄ. (JP) (43) Äàòà ïóáëèêàöèè çà âêè: 10.08.2006 R U (30) Êîíâåíöèîííûé ïðèîðèòåò: 25.07.2003 JP 2003-280259 (45) Îïóáëèêîâàíî: 10.11.2008 Áþë. ¹ 31 2 3 3 7 5 4 9 (56) Ñïèñîê äîêóìåíòîâ, öèòèðîâàííûõ â îò÷åòå î ïîèñêå: ÅÐ 0598515 À1, 25.05.1994. ÅÐ 0313317 À2, 26.04.1989. RU 2054427 C1, 20.02.1996. RU 2113793 Ñ1, 27.06.1998. GB 2309904 À, 13.08.1997. WO 9816102 À1, 23.04.1998. WO 0025586 À1, 11.05.2000. 2 3 3 7 5 4 9 R U (86) Çà âêà PCT: JP 2004/009598 (30.06.2004) C 2 C 2 (85) Äàòà ïåðåâîäà çà âêè PCT íà íàöèîíàëüíóþ ôàçó: 26.02.2006 (87) Ïóáëèêàöè PCT: WO 2005/009132 (03.02.2005) Àäðåñ äë ...

Non-aqueous or low aqueous concentrates of active substance mixture for plant protection

FIELD: agriculture. SUBSTANCE: claimed concentrate contains a) one or more solid herbicidal active substances selected from sulfonyl carbamides in suspension form; b) one or more herbicidal active substances and protective agents at least partially dissolved in component c); c) organic solvent or mixture thereof; optionally e) one or more emulsifier; optionally f) one or more thickening agents or thixotropy agents and contains no water or contains at most 30 wt.% of water in solution form. Method for weed controlling includes concentrate dilution with water and application thereof on weeds and cultivated area. EFFECT: preparation of increased stability. 11 cl, 2 tbl ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß (19) RU (11) 2 279 221 (13) C9 (51) ÌÏÊ A01N 47/36 A01N 25/04 (2006.01) (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÑÊÎÐÐÅÊÒÈÐÎÂÀÍÍÎÅ ÎÏÈÑÀÍÈÅ ÈÇÎÁÐÅÒÅÍÈß Ê ÏÀÒÅÍÒÓ Ïðèìå÷àíèå: áèáëèîãðàôè îòðàæàåò ñîñòî íèå ïðè ïåðåèçäàíèè (21), (22) Çà âêà: 2002113743/15, 11.10.2000 (72) Àâòîð(û): ÇÈÊÑËÜ Ôðàíê (DE) (24) Äàòà íà÷àëà îòñ÷åòà ñðîêà äåéñòâè ïàòåíòà: 11.10.2000 (73) Ïàòåíòîîáëàäàòåëü(è): ÀÂÅÍÒÈÑ ÊÐÎÏÑÀÉÅÍÑ ÃÌÁÕ (DE) R U (30) Êîíâåíöèîííûé ïðèîðèòåò: 26.10.1999 (ïï.1-11) DE 199 51 427.5 (43) Äàòà ïóáëèêàöèè çà âêè: 27.07.2004 Îïóáëèêîâàíî íà CD-ROM: MIMOSA RBI 2006/19D 2 2 7 9 2 2 1 (45) Îïóáëèêîâàíî: 10.07.2006 RBI200619D (15) Èíôîðìàöè î êîððåêöèè: Âåðñè êîððåêöèè ¹ 1 (W1 C2) (56) Ñïèñîê äîêóìåíòîâ, öèòèðîâàííûõ â îò÷åòå î ïîèñêå: ÅÐ 0554015 À, 04.08.1994. WO 9641537 À, 27.12.1996. RU 2147401 Ñ1, 20.04.2000. C 9 C 9 (48) Êîððåêöè îïóáëèêîâàíà: 10.10.2007 Áþë. ¹ 28/2007 R U 2 2 7 9 2 2 1 (85) Äàòà ïåðåâîäà çà âêè PCT íà íàöèîíàëüíóþ ôàçó: 27.05.2002 (86) Çà âêà PCT: EP 00/09984 (11.10.2000) (87) Ïóáëèêàöè PCT: WO 01/30156 (03.05.2001) Àäðåñ äë ïåðåïèñêè: 103064, Ìîñêâà, óë. Êàçàêîâà,16, ÍÈÈÐ Êàíöåë ðè "Ïàòåíòíûå ïîâåðåííûå Êâàøíèí, Ñàïåëüíèêîâ è ïàðòíåðû", Â.Ï.Êâàøíèíó (54) ÍÅÂÎÄÍÛÅ ÈËÈ ÌÀËÎÂÎÄÍÛÅ ÊÎÍÖÅÍÒÐÀÒÛ ÑÓÑÏÅÍÇÈÈ ÑÌÅÑÅÉ ÀÊÒÈÂÍÛÕ ...

N-arylsulfonyl-n'-pyrimidinylureas and process thereof

내용 없음. No content.

New sulphonyl-urea derivatives

一种高效摘除槭树科植物病叶并调控观赏期的方法

本发明属于植物生长调节剂领域，具体涉及一种高效摘除槭树科植物病叶并调控观赏期的方法，步骤包括：喷施脱叶剂前对于树进行灌溉；配制乙烯利浓度为2000ppm、噻苯隆浓度为1000ppm的脱叶剂；将脱叶剂均匀喷洒在槭树科的植物叶片上，直至叶片滴落小液滴；每3天喷施1次磷酸二氢钾，共喷施3次；待叶片脱落完毕，新叶开始萌发时，每3天喷施1次外源糖，共喷施2次。本发明通过采用乙烯利和噻苯隆复配喷施脱叶剂，使病叶和正常叶迅速脱落，促使新叶生长，脱叶率基本在90%以上，通过合理灌溉、喷施磷酸二氢钾、外源糖，促进花色素苷合成，利于叶色表现，在脱叶剂脱叶的同时，更能利用脱叶效果为槭树科植物的观赏期进行人工调控。

N- (substituted amino) pyrrole derivatives, production method thereof and herbicides

1-{[alpha-cyclopropyl-alpha-(substitutuent-oxy)-o-tolyl]-sulfamoyl}-3- (4,6-dimethoxy-2-pyrimidinyl)ureas and method for suppressing undesired plant species

FIELD: herbicides. SUBSTANCE: new urea derivatives with general formula α wherein R is hydrogen or radical α ( is -CO-R 1 -alkyl) can be used as herbicides. EFFECT: enhanced efficiency of suppressing undesired plant species. 6 cl, 4 tbl, 6 ex УУбругс ПЧ Го РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (19) ВИ” 2141 954‘ 13) СЛ 57 МК С 070 239/52, А 01 М 43/54 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 94045284/04, 21.12.1994 (24) Дата начала действия патента: 27.12.1994 (30) Приоритет: 28.12.1993 Ц$ 08/174506 (46) Дата публикации: 21.11.1999 (56) Ссылки: 4$ 5009699 А, 13.04.91. ЗИ 1169516 АЗ, 23.07.85. 54 1466634 А, 15.03.89. $0 1517750 АЗ, 23.09.89. 4$ 4666508 А, 19.05.87. 4$ 5464808 А, 07.11.95. 4$ 4666508 А, 19.05.87. ЕР 0184122 А1, 11.06.86. УР 58-15962 А, 29.01.83. (98) Адрес для переписки: 129010, Москва, ул.Большая Спасская, 25, стр.3, "Городисский и партнеры" Лебедевой Н.Г. (71) Заявитель: Американ Цианамид Компани (1$) (72) Изобретатель: Майкл Эдвард Кондон (1$), Филип Марк Хэрринггон (1$) (73) Патентообладатель: Американ Цианамид Компани (0$) (54) 1[а-ЦИКЛОПРОПИЛ-о-(ЗАМЕЩЕННЫЕ ОКСИ)-О-ГТОЛИЛ]СУЛЬФАМОИЛ]}-3-(4,6-ДИМЕТОКСИ-2-ПИРИМИДИНИЛ) МОЧЕВИНЫ И СПОСОБ ПОДАВЛЕНИЯ НЕЖЕЛАТЕЛЬНЫХ ВИДОВ РАСТЕНИЙ (57) Реферат: Описываются новые |-{[ «-циклопропил-а-(замещенные окси)-о-толил|сульфамоил} -3-(4,6-диметокси-2-пиримидинил) мочевиновые соединения общей формулы (1), где К представляет водород или группу С(О)К 1, в которой К представляет С 1-Свалкил. Соединения могут быть использованы в качестве гербицидных агентов. Описывается также способ подавления нежелательных видов растений. Технический результат - повышение эффективности подавления нежелательных видов растений. 2 с. и 5 з.п.ф-лы, 7 табл. ОЕ осн з 50 мСсо>м р [27| | Н Н Н осн 3 2141954 С1 КО УУбругс ПЧ Го (19) КУЗЗАМ АСЕМСУ ГОК РАТЕМТ$ АМО ТКАОЕМАКК$ 12) АВЗТКАСТ ОЕ 1МУЕМТОМ ВИ” 2141 954 ^^ Сл (51) п. С1.6 с 07 р 239/52, А Ол М 43/54 (21), (22) АррИсаНоп: 94045284/04, 21.12. ...

Method of fighting undesirable plants

Herbicidal composition in the form of suspending concentrate

A pyrazolesulfonamide derivative represented by Formula (I): wherein Q, m, R, B, D, E, W and G are as defined in the specification. The compound is useful as herbicide having not only an excellent killing effect on weeds but also the selectivity on certain crops. Useful processes for synthesizing the compound are also disclosed.

Substituted phenylsulfonylurea derivative, its intermediate, their preparation, and herbicide

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

A kind of ointment containing acequinocyl and nicosulfuron

本发明涉及一种防治杨树天牛虫害的药膏，具体涉及一种含有灭螨醌与烟嘧磺隆的药膏，属于农药及其制剂领域。一种含有灭螨醌与烟嘧磺隆的药膏，其特征在于：所述药膏由灭螨醌、烟嘧磺隆和助剂混配而成，其中灭螨醌占所述药膏总重量的重量百分比为0.1～50%，烟嘧磺隆占所述药膏总重量的重量百分比为0.1～50%，其余是助剂。优选的，所述灭螨醌、烟嘧磺的重量配比为1:4、1:7、7:1、4:1。本发明含有灭螨醌与烟嘧磺隆的药膏，该药膏用于防治杨树天牛虫害，持效期长，对环境污染小，施药简便。

Method of selective inhibition of undesirable flora

METHODS FOR PRODUCING 2-AMINO-4-CHLORINE-1,3,5-TRIAZINES

А 2001103751 ко РОССИИСКАЯ ФЕДЕРАЦИЯ (19) РЦ (11) 2004 * 5 М’ С 070 2514/16, 251/48, 43/68 ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12 ИЗВЕЩЕНИЯ К ЗАЯВКЕ НА ИЗОБРЕТЕНИЕ 071 м (21), (22) Заявка: 2001103751/04, 02.07.1999 (71) Заявитель(и): АВЕНТИС КРОПСАЙЕНС ГМБХ (ОЕ) (30) Приоритет: 10.07.1998 ОЕ 19830902.3 (72} Автор(ы): (43) Дата публикации заявки: 10.02.2003 ЦИНДЕЛЬ Юрген (ОЕ), ХОЛЛАНДЕР Йенс (ОЕ), МИНН Клеменс (0Е), ВИЛЛЬМС Лотар (0Е) (85) Дата перевода заявки РСТ на национальную фазу: 12.02.2001 (86) Заявка РСТ: ЕР 99/04581 (02.07.1999) (74) Патентный поверенный: Егорова Галина Борисовна (87) Публикация РСТ: М/О 00/02868 (20.01.2000) Адрес для переписки: 129010, Москва, ул. Б.Спасская, 25, стр.3, ООО "Юридическая фирма Городисский и Партнеры", пат.пов. Г.Б. Егоровой (54) СПОСОБЫ ПОЛУЧЕНИЯ 2-АМИНО-4-ХЛОР-1 ,3,5-ГРИАЗИНОВ Заявка, утратившая статус отозванной (51) С070 Дата отзыва заявки: 13.05.2005 Дата утраты заявкой статуса отозванной: 09.08.2005 Извещение опубликовано: 20.10.2005 БИ: 29/2005 Страница: 1 па 150 ЕО 0Сс А"

PROCEDURE FOR PREPARING SULFONIL-UREAS.

COMPUESTOS DE FORMULA I O SUS SALES, DONDE X EQUIVALE A OXIGENO, Y N O CH, R1 EQUIVALE A (C1 (C2 C6)ALQUINILO DADO EL CASO SUSTITUIDO, O EN CASO DE QUE X = OXIGENO, TAMBIEN FENILO (SUSTITUIDO), R2 EQUIVALE A H, (C1 6)ALQUILO, (C2 CLOALQUILO, R3,R4 EQUIVALEN A H, (C1 LQUILAMINO O DI[(C1 EN OBTENERSE DE FORMA QUE LOS COMPUESTOS DE FORMULA II, SE TRANSFORMEN CON LOS COMPUESTOS DE FORMULAS III, IV Y V, DONDE R7 Y R8 SON UN AMONIO CUATERNARIO O UN EQUIVALENTE DE UN CATION METALICO. LA ESTRUCTURA DE LOS COMPUESTOS INTERMEDIOS NO ESTA ACLARADA. FORMULA COMPOUNDS IO ITS SALTS, WHERE X IS EQUIVALENT TO OXYGEN, YNO CH, R1 IS EQUIVALENT TO (C1 (C2 C6) ALKYNIL, GIVEN THE CASE SUBSTITUTED, OR IN CASE X = OXYGEN, ALSO PHENYL (SUBSTITUTED), R2 EQUIVALATES AH, (C1 6) ALKYL, (C2 CLOALQUILO, R3, R4 EQUIVALEN AH, (C1 LQUILAMINO OR DI [(C1 TO BE OBTAINED SO THAT THE COMPOUNDS OF FORMULA II, ARE TRANSFORMED WITH THE COMPOUNDS OF FORMULAS III, IV AND V, WHERE R7 AND R8 ARE A QUATERNARY AMMONIUM OR AN EQUIVALENT OF A METAL CATION THE STRUCTURE OF THE INTERMEDIATE COMPOUNDS IS NOT CLEARED.

Method for producing 2-amino-4-chloro-1,3,5-triazine

(57)【要約】 式（Ｉ） 【化１】 の化合物又はそれらの塩は式（IV） 【化２】 のアミノトリアジンの種類からの活性剤、例えば除草剤の製造に適している。前記式（Ｉ）の化合物は式（II） 【化３】 の化合物を塩素化することにより製造される。前記式のＲ 1 、Ｒ 2 、Ｒ 3 及びＸは請求項１で定義した通りであり、Ａ及びＲは製造される活性剤において必要とされる意味を有する。この化合物は次に式Ａ−ＮＨ−Ｒのアミンにより活性剤に転化することができる。

Herbicide

Method for preparing derivatives of 2-amino-4-chloro-1,3,5-triazines

FIELD: organic chemistry, chemical technology. SUBSTANCE: invention relates to the improved method for preparing compounds of the formula (I) or their salts. Compounds of the formula (I) can be synthesized by the chlorination reaction of compounds of the formula (II) wherein X means hydrogen atom (H), (C 1 -C 6 )-alkyl; R 1 means (C 1 -C 6 )-alkyl substituted with halogen atom(s); R 2 and R 3 mean hydrogen atom (H) in the presence of a water-free protonic organic solvent. Proposed compounds are useful for preparing active substances among class of aminotriazines, for example, herbicide active substances. EFFECT: improved preparing method. 7 cl, 1 tbl, 1 ex ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß RU (19) (11) 2 271 353 (13) C2 (51) ÌÏÊ C07D 251/16 C07D 251/18 (2006.01) (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÎÏÈÑÀÍÈÅ ÈÇÎÁÐÅÒÅÍÈß Ê ÏÀÒÅÍÒÓ (21), (22) Çà âêà: 2001103751/04, 02.07.1999 (24) Äàòà íà÷àëà îòñ÷åòà ñðîêà äåéñòâè ïàòåíòà: 02.07.1999 (30) Ïðèîðèòåò: 10.07.1998 DE 19830902.3 (72) Àâòîð(û): ÖÈÍÄÅËÜ Þðãåí (DE), ÕÎËËÀÍÄÅÐ Éåíñ (DE), ÌÈÍÍ Êëåìåíñ (DE), ÂÈËËÜÌÑ Ëîòàð (DE) (45) Îïóáëèêîâàíî: 10.03.2006 Áþë. ¹ 7 (85) Äàòà ïåðåâîäà çà âêè PCT íà íàöèîíàëüíóþ ôàçó: 20010212 2 2 7 1 3 5 3 R U (87) Ïóáëèêàöè PCT: WO 00/02868 (20.01.2000) C 2 C 2 (86) Çà âêà PCT: EP 99/04581 (02.07.1999) Àäðåñ äë ïåðåïèñêè: 129010, Ìîñêâà, óë. Á.Ñïàññêà , 25, ñòð.3, ÎÎÎ "Þðèäè÷åñêà ôèðìà Ãîðîäèññêèé è Ïàðòíåðû", ïàò.ïîâ. Å.Å.Íàçèíîé (54) ÑÏÎÑÎÁ ÏÎËÓ×ÅÍÈß ÏÐÎÈÇÂÎÄÍÛÕ 2-ÀÌÈÍÎ-4-ÕËÎÐ-1,3,5-ÒÐÈÀÇÈÍΠ(57) Ðåôåðàò: Èçîáðåòåíèå îòíîñèòñ ê óëó÷øåííîìó ñïîñîáó ïîëó÷åíè ñîåäèíåíèé ôîðìóëû (I) èëè èõ ñîëåé, ïðèãîäíûõ äë ïîëó÷åíè àêòèâíûõ âåùåñòâ èç êëàññà àìèíîòðèàçèíîâ, íàïðèìåð ãåðáèöèäíûõ àêòèâíûõ âåùåñòâ. Ñîåäèíåíè ôîðìóëû (I) ìîãóò áûòü ïîëó÷åíû õëîðèðîâàíèåì ñîåäèíåíèé ôîðìóëû (II), ãäå Õ-Í, C1-Ñ6àëêèë, R1 -C1 -Ñ6 àëêèë, çàìåùåííûé àòîìîì(àìè) ãàëîãåíà, R 2,R 3-H, â ïðèñóòñòâèè ñâîáîäíîãî îò âîäû ïðîòîííîãî îðãàíè÷åñêîãî ðàñòâîðèòåë . 6 ç.ï.ô-ëû, 1 òàáë. ...

Pyrimidine or s.triazine derivatives

Undesirable vegetation control method

Изобретение относитс  к области химических способов борьбы с сорной и нежелательной растительностью. Цель изобретени  - уничтожение сорных растений в посевах культурных растений с помощью производного сульфонилмочевины общейформулы (>&QQnQ_1 II >&Uc;3 -OSO^-NHC^H-< QEN^D^4где RI - 2-хлорэтил, аллил, пропаргил, 2-ме- токсиэтил; R2 - водород, фтор, хлор, метил, этил, метокси; Нз - метил, метокси; RA - метил, метокси, хлор; Е - N или СН. Способ согласно изобретению позвол ет избирательно уничтожать сорн ки в посевах культурных растений при дозах активного вещества от 0,01 до 0,6 кг/га. 5 табл.^^ This invention relates to the field of chemical methods for controlling weeds and unwanted vegetation. The purpose of the invention is the destruction of weeds in crops of cultivated plants using a sulfonylurea derivative of the general formula (> & QQnQ_1 II > & allyl, propargyl, 2-methoxyethyl; R2 is hydrogen, fluorine, chlorine, methyl, ethyl, methoxy; Hz is methyl, methoxy; RA is methyl, methoxy, chlorine; E is N or CH. destroy weeds in crops of cultivated plants with doses of the active substance from 0.01 to 0.6 kg / ha.

Replace the sulfonic acid diamine class, their preparation method and as the application of weedicide and plant-growth regulator

本发明所涉及的是结构式(1)的化合物和它们的 盐，

1-[o-]-3-46--2-

본 발명은 농작물-선택적 제초제 1-{[O-시클로프로필카르보닐)페닐]설파모일}-3-(4,6-디메톡시-2-피리미디닐)우레아, 그의 제조 방법 및, 농작물 존재하에 상기 농작물-선택적 설파모일 우레아 유도체로 바람직하지 못한 식물 종을 선택적으로 제어하기 위한 방법에 관한 것이다. The present invention provides a crop-selective herbicide 1-{[O-cyclopropylcarbonyl) phenyl] sulfamoyl} -3- (4,6-dimethoxy-2-pyrimidinyl) urea, a process for preparing the same, and in the presence of a crop A method for selectively controlling undesirable plant species with said crop-selective sulfamoyl urea derivatives.

Pyridinesulfoneamide and its salts, hydrates and complexes with -alcohols useful in agriculture, herbicide compositions, method of struggle against weeds, method of struggle against foxtail (alopecurus), an intermediate compound for its synthesis

FIELD: organic chemistry, agriculture. SUBSTANCE: invention relates to pyridinesulfoneamide of the formula: and its salts, hydrates and lower alcohols that can be used in agriculture. Herbicide composition for struggle against weeds has the claimed compound (I) as an active component taken at effective amount. Invention relates to also the new compound of the formula (II) Эээ гс ПЧ Го РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (19) (51) МПК ВИ "” 2417 666 сл С 070 401/12, 213/80, А ОЛ М 47136 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 93058626/04, 06.09.1993 (30) Приоритет: 07.03.1991 4$ 666,109 (46) Дата публикации: 20.08.1998 (56) Ссылки: МО 88/042, кл. С 070 40172, 1988. (86) Заявка РСТ: 1$ 9201528 (05.03.92) (71) Заявитель: Е.И.Дю Пон де Немурс энд Компани (ЦЗ) (72) Изобретатель: Андреа Тэрик Артур (ЦЗ), Лиэнг Пауль Хсиао-Тсенг (1$) (73) Патентообладатель: Е.И.Дю Пон де Немурс энд Компани (1$) (54) ПИРИДИНСУЛЬФОНАМИД И ЕГО ПРИГОДНЫЕ В СЕЛЬСКОМ ХОЗЯЙСТВЕ СОЛИ, ГИДРАТЫ ИЛИ КОМПЛЕКСЫ СО СПИРТАМИ С; - С., ГЕРЬИЦИДНЫЕ КОМПОЗИЦИИ, СПОСОБ БОРЬБЫ С НЕЖЕЛАТЕЛЬНОЙ РАСТИТЕЛЬНОСТЬЮ, СПОСОБ БОРЬБЫ С ЛИСОХВОСТОМ, ПРОМЕЖУТОЧНЫЙ ПРОДУКТ ДЛЯ ЕГО СИНТЕЗА (57) Реферат: Изобретение относится К пиридинсульфонамиду формулы: со СН 3 СН О: И СЕ $0 _ННСНН ©) 3 2. Т осн и его приемлемым в сельском хозяйстве солям, гидратам и комплексам с низшими спиртами. Гербицидная композиция для борьбы С ростом нежелательной растительности содержит в качестве активного вещества заявляемое соединение (1} в эффективном количестве. Изобретение относится также к новому соединению формулы 11, которое является промежуточным соединением для соединения формулы |: со _сСнН 2 3 <) ТТ СЕ $30 _ МН 3 2 2 Тс и2з.п., 8 табл. 2117666 С1 КО Эээ гс ПЧ Го КОЗЗШАМ АСЕМСУ ГОК РАТЕМТ$ АМО ТКАОЕМАКК$ (19) ВИ "” 2417 666 ' (51) 1пЕ. С1.6 13) СЛ 47136 12) АВЗТКАСТ ОЕ 1МУЕМТОМ (21), (22) АррИсаНоп: (30) Рпошу: 07.03.1991 Ц$ 666,109 (46) Рае о! рибИсаНоп: 20.08.1998 (86) РСТ аррИсанНоп: 1 ...

Heterocyclo substituted phenoxysulfonylurea, process of preparation and use as herbicides and plant grouth regulants thereof

式(I)表示的化合物及其盐类 其中各个基团和符号的意义见说明书，它们具有优良的除草和调节植物生长的性质。

Method for producing sulfonylurea

설포닐우레아의 제조방법 Method for producing sulfonylurea 하기 일반식(Ⅰ)의 화합물 또는 그의 염은 하기 일반식(Ⅱ)의 화합물을 하기 일반식(Ⅲ), (Ⅳ) 및 (Ⅴ)의 화합물과 반응시켜 제조할 수 있다: The compound of formula (I) or a salt thereof can be prepared by reacting a compound of formula (II) with a compound of formulas (III), (IV) and (V): 상기 식들에서, In the above formulas, X 는 산소, -0-NR 2 - 또는 -SO 2 -NR 2 - 이고, X is oxygen, -0-NR 2 -or -SO 2 -NR 2- , Y 는 N 또는 CH 이고, Y is N or CH, R 1 은 각각 비치환되거나 치환된, C 1 내지 C 4 알킬, C 2 내지 C 6 알케닐이거나, 또는 X 가 산소인 경우에는 비치환되거나 치환된 페닐이고, R 1 is each unsubstituted or substituted C 1 to C 4 alkyl, C 2 to C 6 alkenyl, or when X is oxygen, unsubstituted or substituted phenyl, R 2 는 H, C 1 내지 C 6 알킬, C 2 내지 C 6 알케닐, C 2 내지 C 6 알키닐 또는 C 3 내지 C 6 사이클로알킬이고, R 2 is H, C 1 to C 6 alkyl, C 2 to C 6 alkenyl, C 2 to C 6 alkynyl or C 3 to C 6 cycloalkyl, R 3 및 R 4 는 H, 비치환되거나 치환된 C 1 내지 C 6 알킬, 비치환되거나 치환된 C 1 내지 C 4 알콕시, 할로겐, C 1 내지 C 4 알킬티오, C 1 내지 C 4 알킬아미노 또는 디(C 1 내지 C 4 알킬)-아미노이고, R 3 and R 4 are H, unsubstituted or substituted C 1 to C 6 alkyl, unsubstituted or substituted C 1 to C 4 alkoxy, halogen, C 1 to C 4 alkylthio, C 1 to C 4 alkylamino or Di (C 1 to C 4 alkyl) -amino, R 5 는 H 노는 C 1 내지 C 4 알킬이고, R 5 is H 1 -C 1 to C 4 alkyl, R 6 은 H이고, R 6 is H, R 7 및 R 8 은 각각 H, 4 급 암모늄 이온 또는 1 당량의 금속 양이온이다. R 7 and R 8 are each H, a quaternary ammonium ion or one equivalent of metal cation.

Synergetic herbicidal composition for combating weeds in the corn crops

FIELD: agriculture. SUBSTANCE: invention relates to agriculture. A synergetic herbicidal composition for combating weeds in corn crops contains metribuzin, picloram and nicosulfuron with a weight ratio of metribuzin: nicosulfuron: picloram, respectively, weight% (5.6–8):(2.3–3.3):1, and the active substances are taken in synergetically effective amounts. EFFECT: synergetic herbicidal composition for combating weeds in corn crops is proposed. 1 cl, 3 tbl, 1 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (51) МПК A01N 47/36 A01N 43/34 A01N 43/64 A01P 13/00 (11) (13) 2 650 295 C1 (2006.01) (2006.01) (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК A01N 47/36 (2006.01); A01N 43/34 (2006.01); A01N 43/64 (2006.01) (21)(22) Заявка: 2017135976, 11.10.2017 (24) Дата начала отсчета срока действия патента: Дата регистрации: (73) Патентообладатель(и): Акционерное общество "Щелково Агрохим" (RU) 11.04.2018 (56) Список документов, цитированных в отчете о поиске: RU 2472343 C9, 20.04.2013. RU (45) Опубликовано: 11.04.2018 Бюл. № 11 (54) СИНЕРГЕТИЧЕСКАЯ ГЕРБИЦИДНАЯ КОМПОЗИЦИЯ ДЛЯ БОРЬБЫ С СОРНЯКАМИ В ПОСЕВАХ КУКУРУЗЫ (57) Реферат: Изобретение относится к сельскому хозяйству. он:пиклорам соответственно, вес.% (5,6-8):(2,3Синергетическая гербицидная композиция для 3,3):1, причем действующие вещества взяты в борьбы с сорняками в посевах кукурузы содержит синергетически эффективных количествах. 3 табл., метрибузин, пиклорам и никосульфурон при 1 пр. весовом соотношении метрибузин:никосульфур R U 2 6 5 0 2 9 5 2424661 C2, 27.07.2011. WO 2012176938 A1, 27.12.2012. Стр.: 1 C 1 C 1 Адрес для переписки: 141100, г. Щелково, ул. Заводская, д.2, корп.142, комн.204, АО "Щелково Агрохим", патентный отд. 2 6 5 0 2 9 5 Приоритет(ы): (22) Дата подачи заявки: 11.10.2017 R U 11.10.2017 (72) Автор(ы): Спиридонов Юрий Яковлевич (RU), Петровский Александр Степанович (RU), Каракотов Салис Добаевич (RU) RUSSIAN FEDERATION (19) RU (51) Int. Cl. A01N 47/ ...

Method for control of undesirable vegetations

Herbicidal composition

FIELD: agriculture. SUBSTANCE: invention relates to agriculture and can be used to control weed vegetation in crops of cereals. Herbicidal composition contains as an active substance a herbicidally effective amount of tribenuron-methyl, a tertiary alkylamine, in which at least one alkyl radical contains at least eight carbon atoms, surfactant and additionally salts of carbonic acid, which are sodium carbonate, potassium carbonate, sodium bicarbonate, individually or in combination with each other. EFFECT: invention allows to reduce time of working fluid preparation. 1 cl, 2 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 714 736 C1 (51) МПК A01N 47/36 (2006.01) A01N 25/00 (2006.01) A01P 13/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК A01N 47/36 (2019.05); A01N 25/00 (2019.05) (21)(22) Заявка: 2019109777, 02.04.2019 (24) Дата начала отсчета срока действия патента: Дата регистрации: 19.02.2020 (45) Опубликовано: 19.02.2020 Бюл. № 5 2 7 1 4 7 3 6 R U (54) Гербицидная композиция (57) Реферат: Изобретение относится к сельскому хозяйству и может быть использовано для борьбы с сорной растительностью в посевах зерновых культур. Гербицидная композиция содержит в качестве действующего вещества гербицидно эффективное количество трибенурон-метила, третичный алкиламин, в котором по меньшей мере один алкильный радикал содержит не менее восьми Стр.: 1 (56) Список документов, цитированных в отчете о поиске: RU 2648418 C1, 26.03.2018. WO 2016102499 A1, 30.06.2016. CN 101530105 A, 16.09.2009. UA 32879 U, 10.06.2008. RU 2400068 C1, 27.09.2010. RU 2488999 C2, 10.08.2013. C 1 C 1 Адрес для переписки: 450068, Респ. Башкортостан, г. Уфа, а/я 84, Т.И. Радченко (73) Патентообладатель(и): Общество с ограниченной ответственностью "АХК-АГРО" (RU) 2 7 1 4 7 3 6 Приоритет(ы): (22) Дата подачи заявки: 02.04.2019 R U 02.04.2019 (72) Автор(ы): Валитов Раиль Бакирович (RU), Логвин Борис Олегович (RU), Низаева Элина Рамилевна (RU), ...

Method of producing n-(cyclopropyltriazinyl) or n-(cyclopropylpyrimidinyl)-nъ-arylsulfonylureas

Compound weeding composition and granules thereof

本发明公开了一种除草组合物及其颗粒剂。该除草组合物由双环磺草酮、丙草胺与吡嘧磺隆组成，其中，双环磺草酮、丙草胺与吡嘧磺隆的质量比为(0.1～50)：(5～70)：(0.1～10)。所述颗粒剂以上述除草组合物为活性成分，其组成包括下述质量百分含量的组分：双环磺草酮0.1～50％、丙草胺5～70％、吡嘧磺隆0.1～10％、分散剂5～10％、润湿剂0～10％、崩解剂0～10％、粘结剂0～3％、吸附剂0～5％、填料补足至100％。本发明提供的含双环磺草酮、丙草胺与吡嘧磺隆的复配颗粒剂，可一次施药、扩展了杀草谱、提高了施药均匀程度，提高了药效和持效期，降低了用药量及使用成本，同时也降低了施药对环境的污染。

A kind of defoliant composition and its production and use

一种脱叶剂组合物及其制备方法，所述脱叶剂组合物包括1～40重量份噻苯隆、1～20重量份敌草隆和10～70重量份有机硅助剂；所述方法包括按所述重量份将噻苯隆、敌草隆和有机硅助剂混合即得。本申请的脱叶剂组合物对棉花有较好的脱叶效果。

Anti-hydrolysis nicosulfuron water suspension and preparation method therefor

本发明公开了一种抗水解的烟嘧磺隆水悬浮剂，由以下重量百分比的组分组成：烟嘧磺隆1％-35％，稳定剂1％-7％，分散剂1％-8％，润湿剂1％-10％，增稠剂0.1％-2％，防冻剂1％-10％，消泡剂0.1％-1％，防腐剂0.1％-0.5％，pH调节剂调节pH为6-8，余量为水。本发明还公开了上述水悬浮剂的制备方法，将称量好的烟嘧磺隆、稳定剂、润湿剂、分散剂、防冻剂、pH调节剂、防腐剂、消泡剂及水投入搅拌釜中进行剪切混合均匀，然后通入砂磨机进行砂磨至合格粒径后，最后加入增稠剂，再次剪切便形成产品；本发明提供了一种抗水解烟嘧磺隆水悬浮剂，具有闪点高、生产贮存和使用安全、环境污染小、产品成本低、容易包装等优点，可以高效、安全的满足农业生产的要求。

Herbicides with acylated aminophenylsulfonyl urea

상승적 제초 효과를 갖는 Having a synergistic herbicidal effect (A) 화학식 1의 화합물 또는 이들의 염의 군으로부터 선택되는 1 종 이상의 제초제인 성분; 및 (A) a component which is at least one herbicide selected from the group of compounds of Formula 1 or salts thereof; And (B) (B1) 곡류 및 몇몇의 쌍자엽성 작물중에서 단자엽성 및 쌍자엽성 유해 식물에 대해선택적으로 효과적인 잎-작용 및 토양-작용 제초제, (B) (B1) leaf-acting and soil-acting herbicides that are selectively effective against monocotyledonous and dicotyledonous harmful plants in cereals and some dicotyledonous crops, (B2) 곡류 및 몇몇의 쌍자엽성 작물중에서 주로 쌍자엽성 유해 식물에 대해 선택적으로 효과적인 제초제, 및 (B2) herbicides that are selectively effective against mainly dicotyledonous plants, among cereals and some dicotyledonous crops, and (B3) 비선택적으로 이용되거나 특정 내성 작물에 이용되고, 단자엽성 및 쌍자엽성 유해 식물에 대해 효과적인 제초제 (B3) Herbicides that are used nonselectively or in certain resistant crops and are effective against monocotyledonous and dicotyledonous harmful plants 로 구성되는 화합물의 군으로부터 선택되는 1 종 이상의 제초제인 성분 A component which is at least one herbicide selected from the group of compounds consisting of 을 포함하는 제초제 조성물. Herbicide composition comprising a. 화학식 1 Formula 1 상기 식에서, Where R 1 , R 2 , R 3 , X, Y 및 Z는 청구항 1에서 정의한 바와 같다. R 1 , R 2 , R 3 , X, Y and Z are as defined in claim 1.

Method for producing 1,2,3-thiadiazol-3-in-5-ilideneurea derivatives or acid-additive salts thereof with hydrochloric acid

Die Erfindung betrifft neue 1,2,3-Thiadiazol-3-in-5-yliden-harnstoffderivate der allgemeinen Formel in der R, Wasserstoff oder einen gegebenenfalls ein- oder mehrfach durch Sauerstoff- oder Schwefelatome unterbrochenen C 1 -C 4 -Alkylrest, R 2 einen gegebenenfalls ein- oder mehrfach durch Sauerstoff- oder Schwefelatome unterbrochenen C 1 -C 4 -Alkylrest, einen gegebenenfalls ein- oder mehrfach durch Alkyl substituierten C 3 -C 8 -Cycloalkylrest, einen gegebenenfalls ein- oder mehrfach durch Alkyl und/oder Halogen und/ oder Alkylthio und/oder Alkoxy und/oder Trifluormethyl und/oder die Nitrogruppe substituierten aromatischen Kohlenwasserstoffrest oder einen gegebenenfalls substituierten heterocyclischen, mindestens ein N-Atom enthaltenen, Kohlenwasserstoffrest oder R, und R 2 gemeinsam mit dem N-Atom die Morpholino-, Piperidino- oder Pyrrolidinogruppe, R 3 einen gegebenenfalls substituierten C 1 -C 10 -Alkylrest, einen C 2 -C 8 -Alkenyl- oder C 3 -C 8 -Alkinylrest oder einen gegebenenfalls substituierten Aryl-C 1 -C 2 -alkylrest und X ein Sauerstoff- oder ein Schwefelatom bedeuten sowie deren Säureadditionssalze mit anorganischen und organischen Säuren, Verfahren zur Herstellung dieser Verbindungen sowie diese enthaltende Mittel mit wuchsregulatorischer und entblätternder Wirkung.

Method of producing n-/4-/2-(5-methylpyrazinyl-2-carboxamido)-ethyl/-benzosulfonyl/-n-cyclohexyl-urea

The present invention relates to a method of preparing N-{4-[2-(5-methyl-pyrazinyl-2-carboxamido)-ethyl]-benzenesulphonyl}-N min -cyclohexylurea or glipizide, which has the chemical structure (I), <CHEM> by letting 4-[2-(5-methylpyrazinyl)-2-carboxamido)-ethyl]-benzenesulphonamide with the chemical structure (II), where R<1> = NH2, react with N-cyclohexyl trichloroacetamide with the chemical structure (III), where R<2> = NHCOCCl3, according to the following reaction scheme: <CHEM> The reaction is carried out in the presence of a polar, aprotic solvent such as N-methylpyrrolidone (NMP), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA) or dimethylsulphoxide (DMSO) under anhydrous conditions in the presence of a base such as an alcoholate, amide or hydride of an alkali metal. The reaction mixture is heated under reflux condensation to 40-100 DEG C and the reaction is going on for 2-5 hours.

Non-aqueous or low aqueous concentrates of active substance mixture for plant protection

FIELD: agriculture. SUBSTANCE: claimed concentrate contains a) one or more solid herbicidal active substances selected from sulfonyl carbamides in suspension form; b) one or more herbicidal active substances and protective agents at least partially dissolved in component c); c) organic solvent or mixture thereof; optionally e) one or more emulsifier; optionally f) one or more thickening agents or thixotropy agents and contains no water or contains at most 30 wt.% of water in solution form. Method for weed controlling includes concentrate dilution with water and application thereof on weeds and cultivated area. EFFECT: preparation of increased stability. 11 cl, 2 tbl ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß (19) RU (11) 2 279 221 (13) C2 (51) ÌÏÊ A01N 47/36 A01N 25/04 (2006.01) (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÎÏÈÑÀÍÈÅ ÈÇÎÁÐÅÒÅÍÈß Ê ÏÀÒÅÍÒÓ (21), (22) Çà âêà: 2002113743/15, 11.10.2000 (72) Àâòîð(û): ÇÈÊÑËÜ Ôðàíê (DE) (24) Äàòà íà÷àëà îòñ÷åòà ñðîêà äåéñòâè ïàòåíòà: 11.10.2000 (73) Ïàòåíòîîáëàäàòåëü(è): ÀÂÅÍÒÈÑ ÊÐÎÏÑÀÉÅÍÑ ÃÌÁÕ (DE) R U (30) Êîíâåíöèîííûé ïðèîðèòåò: 26.10.1999 (ïï.1-11) DE 199 51 427.5 (43) Äàòà ïóáëèêàöèè çà âêè: 27.07.2004 (45) Îïóáëèêîâàíî: 10.07.2006 Áþë. ¹ 19 2 2 7 9 2 2 1 (56) Ñïèñîê äîêóìåíòîâ, öèòèðîâàííûõ â îò÷åòå î ïîèñêå: ÅÐ 0554015 À, 04.08.1994. WO 9641537 À, 27.12.1996. RU 2147401 Ñ1, 20.04.2000. (85) Äàòà ïåðåâîäà çà âêè PCT íà íàöèîíàëüíóþ ôàçó: 27.05.2002 2 2 7 9 2 2 1 R U (87) Ïóáëèêàöè PCT: WO 01/30156 (03.05.2001) C 2 C 2 (86) Çà âêà PCT: EP 00/09984 (11.10.2000) Àäðåñ äë ïåðåïèñêè: 103064, Ìîñêâà, óë. Êàçàêîâà,16, ÍÈÈÐ Êàíöåë ðè "Ïàòåíòíûå ïîâåðåííûå Êâàøíèí, Ñàïåëüíèêîâ è ïàðòíåðû", Â.Ï.Êâàøíèíó (54) ÍÅÂÎÄÍÛÅ ÈËÈ ÌÀËÎÂÎÄÍÛÅ ÊÎÍÖÅÍÒÐÀÒÛ ÑÓÑÏÅÍÇÈÈ ÑÌÅÑÅÉ ÀÊÒÈÂÍÛÕ ÂÅÙÅÑÒ ÄËß ÇÀÙÈÒÛ ÐÀÑÒÅÍÈÉ (57) Ðåôåðàò: Èçîáðåòåíèå îòíîñèòñ ê ñåëüñêîìó õîç éñòâó. Êîíöåíòðàò ñóñïåíçèé ñîäåðæèò: à) îäèí èëè íåñêîëüêî òâåðäûõ ãåðáèöèäíûõ àêòèâíûõ âåùåñòâ èç ð äà ñóëüôîíèëêàðáàìèäîâ â ñóñïåíäèðîâàííîé ôîðìå, b) ...

Compound for optical waveguide, copolymer thereof and optical waveguide using thereof

본 발명은 광도파로용 화합물, 이의 공중합체 및 이를 이용한 광도파로에 관한 것으로, 구체적으로 본 발명의 광도파로용 화합물은 하기 화학식 1 내지 3 중 어느 하나로 표현될 수 있다: <화학식 1> <화학식 2> <화학식 3> 본 발명의 공중합체는 광손실을 최소화할 수 있으며 굴절률을 조절할 수 있을 뿐만 아니라 UV에 의해 중합 반응을 할 수 있어 나노임프린린트 공정에 사용할 수 있으므로 광도파로의 제조에 적용가능하다. The present invention relates to an optical waveguide compound, a copolymer thereof, and an optical waveguide using the same, and specifically, the optical waveguide compound of the present invention may be represented by one of the following Chemical Formulas 1 to 3: &Lt; Formula 1 >< EMI ID = (3) The copolymer of the present invention can minimize the light loss and control the refractive index as well as the polymerization reaction by UV can be used in the nanoimprint process can be applied to the manufacture of the optical waveguide.

Based on the phenoxy group sulfonylurea of 3-substituted salicylic acid alkyl ester, its method for making and as the application of weedicide and growth regulator

本发明提出了除草剂或植物生长调节剂以及提出了阻止非所希望植物生长或调节植物的生长的方法。本发明除草剂或植物生长调节剂含有式(I)化合物或基盐。式中R 1 ，R 2 ，R 3 ，E，R 4 ，R 5 定义详见说明书。

Herbicidal composition

A kind of tribenuron-methyl and azoles humulone built wettable powder and preparation method thereof

一种苯磺隆和唑草酮复配可湿性粉剂及其制备方法，涉及冬小麦田阔叶杂草防治技术领域。至少由14份苯磺隆、22份唑草酮、10份脂肪醇聚氧乙烯醚、10份苯乙基苯酚聚氧乙烯聚氧丙烯醚和补足至100份的轻质碳酸钙制成。将原料混合，依次经过粗粉碎和气流粉碎，再充分混合，取样分析，合格后计量、包装、入库。本发明以7：11配比混用所复配的36％时的苯磺隆和唑草酮复配可湿性粉剂，可起到明显增效作用范围，而其它配比混用的制剂，均无法达到明显增效作用范围。

Herbicidal composition comprising a mixture of sulfonylurea herbicides

1-(2-클로로이미다조[1,2-a] 피리딘-3-일술포닐)-3-(4,6-디메톡시피리미딘-2-일)우레아 (이마조술푸론) 및 하기 화학식 (I) 로 나타낸 화합물 (화합물 [I]): Dimethoxypyrimidin-2-yl) urea (imazosulfuron) and a compound represented by the formula ( I) (Compound [I]): 을 활성 성분으로서 포함하고, 여기서 이마조술푸론 : 화합물 [I] 의 중량비가 1:0.1 - 1:10 인 제초용 조성물은, 작물 밭 또는 논에서 잡초 방제에 대한 제초 활성이 우수하고, 유용한 식물에 식물독소성을 유발하지 않는다. Wherein the herbicidal composition having a weight ratio of imazosulfuron: compound [I] of 1: 0.1 - 1: 10 has excellent herbicidal activity against weed control in crop fields or paddies, It does not cause plant toxicity.

Herbicidal pyridine sulfonamides

A N,N-dimethyl-2-(aminosulfonyl)-3-pyridine-carboxamide of formula (I) and its agriculturally acceptable salt is prepd. In (I), J=a gp. of formula (II) or (III); R=H or Me; R1=H or C1-3 alkyl; R2=C1-3 alkyl or C1-2 alkoxy; R1 and R2 together form -(CH2)n-; n=2, 3 or 4; R3=H, Cl, Br, F or Me; X=Me, Cl, -CH2F or -OCH2CH3. (I) is useful as a herbicide which selectively kills harmful weeds in cornfield.

Blend of Phenylsulfonylurease Herbicide and Toxic Emollient

본 발명은 설포닐우레아 제초제(A) 및 이들의 염과 유형 (B1) 및 (B2)의 독성 완화제의 배합물에 관한 것이다: The present invention relates to a combination of sulfonylurea herbicides (A) and salts thereof and toxic modifiers of types (B1) and (B2): [화학식 A] [Formula A] [화학식 B1] [Formula B1] [화학식 B2] [Formula B2] 상기식에서, R 2 는 H, OH, 지방족 탄화수소 라디칼 또는 탄화수소-옥시 라디칼이고, Wherein R 2 is H, OH, an aliphatic hydrocarbon radical or a hydrocarbon-oxy radical, R 1 은 아실 라디칼이고, 기타 기호들은 청구항 1에서 정의한 바와 같다. R 1 is an acyl radical and other symbols are as defined in claim 1.

Herbicidal and plant growth regulating compositions comprising alkyl- and alkenylsulfonylurea derivatives substituted by heterocyclic group and process for producing the active ingredients

Herbicide combination

Herbicidal combination comprises: (A) one or more herbicides from 2-iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzene sulfonamide or a salt of 2-iodo-N-[(4-methoxy-6-methyl-1,3,5 triazin-2-yl)carbamoyl]benzene sulfonamide (I); and (B) one or more herbicides from a herbicidal active agent, which does not belong to sulfonamide group, e.g. N-acetylthiazolidine-4-carxylic acid, acrolein, aminopyralid, ammonium pelargonate, aviglycine, benazolin, benfluralin, benfuresate, bentazone, benzobicyclon, 6-benzylaminopurine, borax, butralin, carvone, catechin and chloridazon. Herbicidal combination comprises: (A) one or more herbicides from 2-iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzene sulfonamide or a salt of 2-iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzene sulfonamide of formula (I); and (B) one or more herbicides from a herbicidal active agent, which does not belong to sulfonamide group, consisting of N-acetylthiazolidine-4-carxylic acid, acrolein, aminopyralid, ammonium pelargonate, ammonium sulfamate, aviglycine, benazolin, benfluralin, benfuresate, bentazone, benzobicyclon, 6-benzylaminopurine, borax, butralin, carvone, catechin, chlorflurenol-methyl, chloridazon, chlormequat chloride, chloroacetic acid, chlorphthalim, chlorthal-dimethyl, cinidon-ethyl, cinmethylin, clofencet, clomazone, cloxyfonac, cyanamide, cyclanilide, 6-isopentyl aminopurine, kinetin, zeatin, dalapon, daminozide, dazomet, n-decanol, difenzoquat metilsulfate, 2,6-diisopropyl naphthalene, dikegulac, dimethipin, dimethylarsenic acid, dinitramine, dinoterb, diquat dibromide, dithiopyr, dinitro-o-cresol, endothal, ethalfluralin, ethofumesate, ethylchlozate, ferrous sulfate, flamprop-M-methyl, flufenpyrethyl, flumetralin, flumiclorac-pentyl, flumioxazin, flupropanate, flurenol, fluridone, flurochloridone, flurtamone, gibberellic acid, gibberellin A4/gibberellin A7, indanofan, isopropalin, isoprothiolane, maleic hydrazide, mepiquat chloride, metam, ...

Agent for defoliating cotton plants

A composition for growth regulation of plants or for defoliating plants comprises in combination (a) at least one compound of the formula <IMAGE> wherein R1 is hydrogen or alkyl of 1 to 3 carbon atoms and R2 is hydrogen or alkyl of 1 to 4 carbon atoms and R3 has the meaning defined in the specification and X is oxygen or sulfur and (b) at least one other plant growth regulating or defoliating agent which, in combination with the compound at (a) results in a synergistic effect in regard to the growth regulating and defoliant properties. The composition is particularly suited for the defoliation of cotton plants.

Arylsulfonylureas, method for their preparing and their using as herbicides

FIELD: organic chemistry, herbicides. SUBSTANCE: invention relates to novel arylsulfonylureas of the formula (I): wherein Q means oxygen atom (O); Y means -CH or nitrogen atom (N); Z means N; R means hydrogen atom (H), (C 1 -C 12 )-alkyl, (C 2 -C 10 )-alkenyl; R 1 means H, (C 1 -C 3 )-alkyl; R 2 means H, halogen atom, (C 1 -C 3 )-alkyl, (C 1 -C 3 )-alkoxy-group wherein both latter residues are unsubstituted or mono- or multiple-substituted with halogen atom or (C 1 -C 3 )-alkoxy-group; R 3 means H, halogen atom, (C 1 -C 3 )-alkyl, (C 1 -C 3 )-alkoxy-, (C 1 -C 3 )-alkylthio-groups wherein indicated alkyl-containing groups are unsubstituted or mono- or multiple-substituted with halogen atom, or mono- or bisubstituted with (C 1 -C 3 )-alkoxy- or (C 1 -C 3 )-alkylthio-groups, or it means -NR 5 R 6 wherein R 5 and R 6 mean independently H, (C 1 -C 4 )-alkyl. Compounds of the formula (I) elicit herbicide activity and therefore they can be used for the selective control for harmful plants. Also, invention describes intermediate compounds and methods for synthesis of compound of the formula (I). EFFECT: improved method of synthesis, valuable properties of compounds. 14 cl, 22 tbl, 13 ex ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß RU (19) (11) 2 314 291 (13) C2 (51) ÌÏÊ C07C 311/29 (2006.01) C07C 311/65 (2006.01) C07C 303/38 (2006.01) C07D 239/32 (2006.01) C07D 239/42 (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ C07D 251/42 (2006.01) ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ,C07D 251/46 (2006.01) ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ A01N 47/36 (2006.01) (12) ÎÏÈÑÀÍÈÅ ÈÇÎÁÐÅÒÅÍÈß Ê ÏÀÒÅÍÒÓ (21), (22) Çà âêà: 93053940/04, 12.02.1992 (30) Êîíâåíöèîííûé ïðèîðèòåò: 12.02.1991 DE P4104227.1 (73) Ïàòåíòîîáëàäàòåëü(è): ÁÀÉÅÐ ÊÐÎÏÑÀÉÅÍÑ Àà (DE) (43) Äàòà ïóáëèêàöèè çà âêè: 20.06.1996 2 3 1 4 2 9 1 (45) Îïóáëèêîâàíî: 10.01.2008 Áþë. ¹ 1 (56) Ñïèñîê äîêóìåíòîâ, öèòèðîâàííûõ â îò÷åòå î ïîèñêå: ÅÐ 0046626, 03.03.1982. DE 1237094, 23.03.1967. ÅÐ 0007687, 06.02.1980. ÅÐ 0030138, 10.06.1981. SU 1187700, 23.10.1985. (85) Äàòà ïåðåâîäà çà âêè PCT ...

Nerbicide