04-01-2018 дата публикации
Номер: US20180002357A1
The present invention provides a process for the preparation of mono- and bisacylphosphanes based on formula (I): 2. The process as recited in claim 1 , wherein{'sup': 8', '8', '8', '6', '7', '8', '4, 'claim-text': either not, once, twice or more than twice interrupted by non-successive functional groups selected from the group consisting of:', {'sub': 2', '2', '2', '2', '2', '2', '2, 'sup': 4', '4', '4', '4', '4', '4', '4', '4', '4', '5', '5', '5', '5, '—O—, —S—, —SO—, —SO—, —SONR—, NRSO—, —NR—, —CO—, —O(CO)—, (CO)O—, —O(CO)O—, —NR(CO)NR—, NR(CO)—, —(CO)NR—, —NR(CO)O—, —O(CO)NR—, —Si(R)—, —OSi(R)—, —OSi(R)O—, —Si(R)O—,'}, 'and,', 'either not, additionally or alternatively either once, twice or more than twice interrupted by bivalent residues selected from the group consisting of heterocyclo-diyl, and aryldiyl,', 'and,', 'either not, additionally or alternatively either once, twice or more than twice substituted by substituents selected from the group consisting of:', {'sub': 6', '14', '1', '8', '1', '8', '3', '3', '2', '2', '2', '2', '2', '2', '2', '2', '2', '2', 'y', '3-y', 'y', '3-y, 'sup': 5', '5', '4', '4', '5', '4', '4', '4', '5', '4', '4', '4', '5', '5', '5, 'oxo, hydroxy, halogen, cyano, azido, C-C-aryl, C-C-alkoxy, C-C-alkylthio, —SOM, —COOM, POM, —PO(N(R)), PO(OR), —SON(R), —N(R), —CON(R), —COR, —OCOR, —NR(CO)R, —(CO)OR, —NR(CO)N(R), —Si(OR)(R), —OSi(OR)(R), with y=1, 2 or 3.'}], 'wherein the alkyl, alkenyl, aryl, alkanediyl and alkenediyl substituents are'}, 'Rindependently of further substituents Rwhich may be present in the substituent of formulae (IIa) to (IId) is alkyl, alkenyl or aryl or two substituents Rirrespective of whether they are both part of a substituent Z or belong to different substituents selected from Z, Rand Rtogether are alkanediyl or alkenediyl or alternatively, where two substituents —(CO)Rare present within the substituent of formulae (IIa), are together —O— or —NR—,'}3. The process as recited in claim 1 , wherein if Mis 1/q ...
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