07-04-2016 дата публикации
Номер: US20160097108A1
Принадлежит:
The present invention provides processes for catalytic deconstruction of biomass using a solvent produced in a bioreforming reaction. 1. A method of making a biomass hydrolysate , the method comprising:{'sub': 2+', '1+', '2', '2+', '1-3, 'A. catalytically reacting water and a water-soluble CO oxygenated hydrocarbon in a liquid or vapor phase with Hin the presence of a deoxygenation catalyst at a deoxygenation temperature and deoxygenation pressure to produce a biomass processing solvent comprising a COhydrocarbon in a reaction stream; and'}B. reacting the biomass processing solvent with a biomass component, hydrogen and a deconstruction catalyst at a deconstruction temperature and a deconstruction pressure to produce a biomass hydrolysate comprising at least one member selected from the group consisting of a water-soluble lignocellulose derivative, a water-soluble cellulose derivative, a water-soluble hemicellulose derivative, a carbohydrate, a starch, a monosaccharide, a disaccharide, a polysaccharide, a sugar, a sugar alcohol, an alditol and a polyol.2. The method of claim 1 , wherein the biomass processing solvent comprises a member selected from the group consisting of an alcohol claim 1 , ketone claim 1 , aldehyde claim 1 , cyclic ether claim 1 , ester claim 1 , diol claim 1 , triol claim 1 , hydroxy carboxylic acid claim 1 , carboxylic acid claim 1 , and a mixture thereof.3. The method of claim 1 , wherein the deconstruction catalyst comprises an acidic resin or a basic resin.4. The method of claim 3 , wherein the deconstruction catalyst further comprises a member selected from the group consisting of Fe claim 3 , Co claim 3 , Ni claim 3 , Cu claim 3 , Ru claim 3 , Rh claim 3 , Pd claim 3 , Pt claim 3 , Re claim 3 , Mo claim 3 , W claim 3 , an alloy thereof claim 3 , and a combination thereof.5. The method of claim 1 , wherein the deconstruction catalyst comprises a support and a member adhered to the support claim 1 , wherein the member is selected from the ...
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