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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 12059. Отображено 100.
01-03-2012 дата публикации

Functionalizable Synthetic Hydrocarbon Fluids and Integrated Method for Production Thereof

Номер: US20120053309A1
Автор: John R. Hagadorn, Matthew S. Bedoya, Matthew W. Holtcamp
Принадлежит: ExxonMobil Chemical Patents Inc

This invention relates to a process to produce a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) comprising: contacting at least one renewable feedstream with at least one lower olefin in the presence of a metathesis catalyst, wherein a mixture of at least one C 4 to C 40 linear alpha-olefin and at least one alpha, internally unsaturated, nonconjugated olefin is produced; and contacting the mixture with a metallocene catalyst system, wherein a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) is produced.

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Номер записи: 1
22-03-2012 дата публикации

Crosslinkable dielectrics and methods of preparation and use thereof

Номер: US20120068314A1
Автор: Marcel Kastler, Silke Annika Koehler
Принадлежит: BASF SE, Polyera Corp

The present invention relates to an electronic device comprising at least one dielectric layer, said dielectric layer comprising a crosslinked organic compound based on at least one compound which is radically crosslinkable and a method of making the electronic device.

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Номер записи: 2
19-04-2012 дата публикации

Film for film capacitor

Номер: US20120094070A1
Автор: Junya Ishida, Kazuhiro Suzuki, Kenro Takizawa, Masaru Yoneyama
Принадлежит: Shin Etsu Polymer Co Ltd

A film for film capacitors having a thickness of 10 microns or less, wherein the film has surface properties of (Ra) of 0.2 microns or less, (Rz/Ra) of 10 or less and a dynamic friction coefficient of 1.5 or less, where (Ra) is an arithmetic average roughness and (Rz) is a maximum height defined both by the method specified in JIS B 0601 2001. The film can be manufactured by the successive steps of: mixing and preparing a forming material composed of a thermoplastic resin composition; melting and extruding the forming material to a film through a T-die; pinching and cooling the film between a pressure roll and a cooling roll having a rough surface for forming a rough surface to the film; and rolling up the cooled film onto a winding tube in a winding unit.

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Номер записи: 3
03-05-2012 дата публикации

Method for manufacturing carboxyl group-containing water-soluble polymer

Номер: US20120108776A1
Автор: Masatoyo Yoshinaka, Masayuki Toda, Shinji Kobayashi, Taro Ashida, Yuichiro Morimitsu
Принадлежит: Sumitomo Seika Chemicals Co Ltd

In manufacturing of a carboxyl group-containing water-soluble polymer by a precipitation polymerization method, a method which can improve production efficiency with increasing practicality continuously adds a monomer solution wherein a monomer component containing an α,β-unsaturated carboxylic acid is dissolved in an inert solvent in a concentration of 20 to 50% by volume to an inert solvent charged in a reaction vessel. In this case, the amount of the inert solvent charged in the reaction vessel is set so that the concentration of the monomer component in the total amount summed up with the monomer solution is 10 to 24% by volume, and the time period until completion of continuous addition of the total amount of the monomer solution is set so that the conversion of the monomer component at the time of completion of addition of the total amount of the monomer solution is 60% or more. The monomer component may contain a polymerizable compound having two or more ethylenically unsaturated groups.

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Номер записи: 4
19-07-2012 дата публикации

Fluorinated compound, fluorinated polymer and fluorinated copolymer

Номер: US20120184695A1
Автор: Taiki Hoshino
Принадлежит: Asahi Glass Co Ltd

To provide a fluorinated compound having an R F group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer and a fluorinated copolymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH 2 ═C(M)COO(CH 2 ) n PhCOO(CH 2 ) m CF 2r+1   (I) (in the formula (I), M is a hydrogen atom, a methyl group or a halogen atom, n is an integer of from 0 to 2, Ph is a phenylene group, m is an integer of from 1 to 4, and r is an integer of from 1 to 6).

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Номер записи: 5
19-07-2012 дата публикации

Process for preparing a polymer polyol

Номер: US20120184707A1
Автор: Andre Buijs, Nico Maria Venne, Paulus Jacobus Fennis, Willem Karzijn
Принадлежит: Shell Internationale Research Maatschappij BV

The invention relates to a process for preparing a polymer polyol, comprising mixing in a reactor vessel, a base polyol, one or more ethylenically unsaturated monomers, a polymerization initiator, optionally a macromer, and optionally a chain transfer agent, and polymerizing the mixture thus obtained at a temperature of 50 to 200° C., wherein after discharging the reactor vessel content, the interior surface of the reactor vessel walls and/or any internals present in the reactor vessel are blasted with round media.

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Номер записи: 6
16-08-2012 дата публикации

(meth)acrylic resin composition

Номер: US20120205043A1
Автор: Hiroyuki Kurimura, Isamu Ichikawa, Jun Watanabe, Takako Hoshino, Takayuki Nagumo
Принадлежит: Denki Kagaku Kogyo KK

Provided is an adhesive (meth)acrylic resin composition being high in adhesiveness and capable of affording an adhered body which can be used at high temperatures of 250° C. or higher, and possessing low outgassing property and heat resistance. A (meth)acrylic resin composition including (A) a polyfunctional (meth)acrylate, and (B) a photopolymerization initiator that exhibits a mass loss on heating of 15% by mass or less when increasing temperature from 30° C. to 250° C. at a temperature increase rate of 10° C./min. under nitrogen flow, wherein the glass transition temperature of a cured body obtained from the composition is 250° C. or higher.

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Номер записи: 7
29-11-2012 дата публикации

Process for Continuously Producing Water-Absorbing Polymer Particles

Номер: US20120302711A1
Автор: Karl J. Possemiers, Rüdiger Funk, Thomas Pfeiffer
Принадлежит: BASF SE

A process for continuously producing water-absorbing polymer particles, in a continuous polymerization reactor, wherein the amount of initiator used and/or the intensity of the UV radiation optionally used to initiate the polymerization is reduced after the startup of the polymerization reactor.

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Номер записи: 8
03-01-2013 дата публикации

Fluorinated compound and fluorinated polymer

Номер: US20130005924A1
Автор: Taiki Hoshino
Принадлежит: Asahi Glass Co Ltd

To provide a fluorinated compound having an R F group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH 2 ═C(M)COOXPhCOO(CH 2 ) m C r F 2r+1   (I) (in the formula (I), M is a hydrogen atom, a methyl group or a halogen atom, X is CHR 1 CH 2 O or CH 2 CHR 1 O, R 1 is a C 1-4 linear or branched alkyl group or CH 2 OR 2 , R 2 is a C 1-4 linear or branched alkyl group, Ph is a phenylene group, m is an integer of from 1 to 4, and r is an integer of from 1 to 6).

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Номер записи: 9
07-03-2013 дата публикации

Joinable sheet metal profile for roof gable end

Номер: US20130055652A1
Автор: Johan Larsson
Принадлежит: Individual

The invention relates to a sheet metal profile ( 9 a,b, 19 a,b, 22 a,b, 23 a,b, 24 a,b, 25 ) primarily intended for installation against parts of a building, for example for the protection of bargeboards ( 2 ) or other wooden component parts of the building, comprising a bent metal sheet having a central section and at least one lateral part ( 3 a,b ) with inward-folded edge sections ( 15 a,b ) at the bottom. The invention is achieved by the sheet metal profile ( 9 a,b, 19 a,b, 22 a,b, 23 a,b, 24 a,b, 25 ) being of mirror symmetrical configuration at both end sections ( 11 a,b, 17, 21 a,b ), and by the end sections ( 11 a,b, 17, 22 a,b ) being provided with an inward-facing edge ( 13 a,b, 21 a,b ) cut at an angle, that is to say one or both lateral parts ( 10 a,b, 20 a,b ) of the sheet metal profile ( 9 a,b, 19 a,b, 22 a,b, 23 a,b, 24 a,b, 25 ) are executed with angled end edges ( 13 a,b, 21 a,b ), where the angle (v) between the upper plane surface ( 12 ) of the sheet metal profile ( 9 ) and the end edges ( 13 a,b, 21 a,b ) of the lateral parts form an acute angle (v).

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Номер записи: 10
21-03-2013 дата публикации

NOVEL CATALYST COMPOSITION AND PROCESS FOR PREPARING OLEFIN POLYMER USING THE SAME

Номер: US20130072646A1
Автор: CHAE Hoon, Ha Jong-Joo, JEON Sang-Jin, Kim Won-Hee, Lee Choong-Hoon, Lee Eun-Jung, Noh Kyung-Seop, PARK Cheon-Il
Принадлежит: LG CHEM, LTD.

The present invention relates to a catalyst composition and a process for preparing an olefin polymer using the same. More specifically, the present invention relates to a novel catalyst composition comprising at least two types of catalysts and a process for preparing an olefin polymer having excellent heat resistance using the same. The present invention can provide an olefin polymer having excellent activity and high heat resistance, and also can control the values of density, heat resistance and melt index (MI) of the olefin polymer. 2. The catalyst composition for olefin polymerization according to claim 1 , wherein the catalyst composition further comprises one or more promoter compounds selected from the group consisting of the compounds of the following formulas (3) to (5):{'br': None, 'sup': '4', 'sub': '3', 'J(R)\u2003\u2003[Formula 3]'}in the formula (3),J represents aluminum or boron;{'sup': '4', 'claim-text': {'br': None, 'sup': +', '−', '+', '−, 'sub': 4', '4, '[L-H][ZA] or [L][ZA]\u2003\u2003[Formula 4]'}, 'Rindependently of one another represents halogen, or a hydrocarbyl radical which is unsubstituted or substituted by halogen and has 1 to 20 carbon atoms;'}in the formula (4),L represents a neutral or cationic Lewis acid;H represents hydrogen;Z represents a group XIII atom; {'br': None, 'sup': '5', 'sub': 'a', '—[Al(R)—O]—\u2003\u2003[Formula 5]'}, 'A independently of one another represents alkyl having 1 to 20 carbon atoms or aryl having 6 to 20 carbon atoms wherein one or more hydrogen atoms are replaced by halogen, hydrocarbyl having 1 to 20 carbon atoms, alkoxy having 1 to 20 carbon atoms or phenoxy;'}in the formula (5),{'sup': '5', 'Rrepresents halogen, or hydrocarbyl which is unsubstituted or substituted by halogen and has 1 to 20 carbon atoms; and'}a denotes an integer of 2 or more.3. The catalyst composition for olefin polymerization according to claim 2 , wherein the promoter compound is contained with respect to the compound having a ...

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Номер записи: 11
04-04-2013 дата публикации

DISPERSING AGENT FOR ADDITIVE FOR POLYOLEFIN-BASED RESIN, POLYOLEFIN-BASED RESIN COMPOSITION, AND MOLDED ARTICLE

Номер: US20130085196A1
Автор: Hirai Shinya, Kasai Toshihiro, KIURA Masaaki, Matsui Yuuki, Murakami Shouko
Принадлежит: MITSUBISHI RAYON CO., LTD.

Disclosed is a versatile dispersant for an additive for olefin resins. The dispersant (A) for an additive (B) for polyolefins contains an alkyl methacrylate polymer which comprises an alkyl methacrylate (a1) unit having an alkyl group with a carbon number of at least 2 as the main component, and which has a mass average molecular weight of 15,000-145,000. 1. A dispersing agent (A) comprising an alkyl methacrylate-based polymer comprising mainly an alkyl methacrylate (a1) unit comprising a C2 or greater alkyl group , and having a weight-average molecular weight of between 15 ,000 and 145 ,000.2. The dispersing agent according to claim 1 , wherein the C2 or greater alkyl group is a C4 alkyl group.3. The dispersing agent according to claim 1 , wherein the (a1) unit is an i-butyl methacrylate unit.4. The dispersing agent according to claim 1 , which is suitable for an additive for a polyolefin (B) claim 1 , said additive being at least one selected from the group consisting of a flame retardant claim 1 , a crystal nucleating agent claim 1 , a foaming agent and a pigment.5. A polyolefin-based resin composition claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the dispersing agent (A) according to ;'}an additive for a polyolefin (B), anda polyolefin-based resin (C),wherein the dispersing agent (A) is suitable for the additive for the polyolefin (B).6. The polyolefin-based resin composition according to claim 5 , wherein the additive for a polyolefin (B) is at least one type selected from the group consisting of a flame retardant claim 5 , a crystal nucleating agent claim 5 , a foaming agent and a pigment.7. A molded article obtained by molding the polyolefin-based resin composition according to .8. A method for producing the polyolefin-based resin composition according to claim 5 , the method comprising combining a master batch comprising a total amount of the dispersing agent (A) claim 5 , a total amount of the additive for the polyolefin (B) claim ...

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Номер записи: 12
11-04-2013 дата публикации

Aqueous poly(meth)acrylic acid-based polymer solution

Номер: US20130090425A1
Автор: Akihiko Kanzaki, Junichi Chosa, Norihiro Wakao
Принадлежит: NIPPON SHOKUBAI CO LTD

An aqueous solution containing a poly(meth)acrylic acid-based polymer which shows excellent dispersibility for inorganic substances, satisfactory long-term dispersibility, and a favorable color is provided. The aqueous solution of the present invention is an aqueous solution comprising a poly(meth)acrylic acid-based polymer, the poly(meth)acrylic acid-based polymer including carboxyl groups, wherein in 100 mol % of the carboxyl groups, 30 to 85 mol % of the carboxyl groups are in an alkali metal salt form of the carboxyl groups, and 15 to 70 mol % of the carboxyl groups are in an acid form of the carboxyl groups, the poly(meth)acrylic acid-based polymer containing a phosphorus-containing group, the poly(meth)acrylic acid-based polymer having a weight average molecular weight of 2000 to 9000, the aqueous poly(meth)acrylic acid-based polymer solution having a concentration of inorganic anions, each including a sulfur or phosphorus atom, of 1000 to 10000 ppm relative to the aqueous poly(meth)acrylic acid-based polymer solution.

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Номер записи: 13
18-04-2013 дата публикации

POLYLACTIC ACID DECOMPOSITION METHOD

Номер: US20130095545A1
Автор: Tsubota Jun
Принадлежит: OSAKA GAS CO., LTD.

A primary object of the present invention is to provide a polylactic acid decomposition method that efficiently decomposes polylactic acid so that the polylactic acid can readily undergo degradation by a biological treatment such as methane fermentation. Specifically, the present invention provides a polylactic acid decomposition method involving a step of impregnating a polylactic acid-containing organic material with a treatment solution containing an organic acid salt and/or inorganic acid salt of an amine compound. 2. The method according to claim 1 , wherein the organic acid salt and/or inorganic acid salt of an amine compound represented by Formula (I) has buffering capacity.3. The method according to claim 1 , wherein the organic acid salt and/or inorganic acid salt of an amine compound represented by Formula (I) is at least one salt selected from the group consisting of ammonium carbonate claim 1 , ammonium hydrogen carbonate claim 1 , diammonium hydrogenphosphate claim 1 , triammonium phosphate claim 1 , ammonium borate claim 1 , and triammonium citrate.4. The method according to claim 1 , wherein the treatment is performed at a molecular ammonia concentration of 500 mg/L or more.5. The method according to claim 1 , wherein the treatment is performed at a temperature of greater than 40° C.6. The method according to claim 1 , wherein the treatment is performed at a pH of 8 to 9.7. The method according to claim 1 , wherein the polylactic acid-containing organic material is a mixture of polylactic acid and garbage.9. The method according to claim 8 , comprising heating the polylactic acid-containing organic material to a temperature of greater than 40° C. in the presence of molecular ammonia.10. The method according to claim 9 , wherein the molecular ammonia has a concentration of 500 mg/L or more.11. The method according to claim 9 , wherein the heating is performed at a pH of 8 to 9. The present invention relates to a polylactic acid decomposition method ...

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Номер записи: 14
18-04-2013 дата публикации

PROCESS FOR PREPARING A (METH)ACRYLATE COPOLYMER CONTAINING TERTIARY AMINO GROUPS BY FREE-RADICAL POLYMERIZATION IN SOLUTION

Номер: US20130096272A1
Автор: Boehmann Pamela, Denger Marcus, Hoffmann Norbert, Klosendorf Andreas, Kueksal Alpertunga, Meier Christian, Papadopoulos Nikolaos, Vorholz Johannes, Weber Andreas
Принадлежит: Evonik Roehm GmbH

The invention relates to a process for preparing a (meth)acrylate copolymer containing quaternary ammonium groups from a monomer mixture selected from: (a) 80 to 99% by weight of a C1-C4-alkyl ester of acrylic acid or methacrylic acid; and (b) 20 to 1% by weight of an alkyl ester of acrylic acid or methacrylic acid with a quaternary ammonium group in the alkyl radical; and (c) 0 to 10% of further copolymerizable vinyl monomers whereby one or more polymerization initiators, optionally one or more molecular weight regulators and one or more solvents or of a solvent mixture are added to the monomer mixture to give a polymerization mixture, which is polymerized at temperatures from 30 to 120 C over a period of 2 to 24 hours, where the polymerization mixture is polymerized to a polymerization syrup with a conversion of the monomers to the copolymer of at least 99% by weight, where the polymerization syrup is subsequently degassed by distillation or by extrusion and the degassed polymerization syrup is further comminuted to a copolymer preparation in the form of a granulate or powder and where the copolymer preparation is characterized by a molecular weight (Mw) of 25.000 to 50.000, a polydispersity index of 2.0 to 3.0 and a residual solvent concentration of less than 10.000 ppm by weight. 1. A process for preparing a (meth)acrylate copolymer , the process comprising:adding a polymerization initiator and a solvent or a solvent mixture to a monomer mixture, thereby obtaining a polymerization mixture,dissolving monomers of the monomer mixture and the polymerization initiator,polymerizing the polymerization mixture at the temperature from 30 to 120° C. over a period of from 2 to 24 hours, thereby obtaining a polymerization syrup with a conversion of the monomers to the copolymer of at least 99% by weight,subsequently degassing the polymerization syrup by distillation or by extrusion, thereby obtaining a degassed polymerization syrup, and comminuting the degassed ...

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Номер записи: 15
25-04-2013 дата публикации

POLYAMINE-CONTAINING POLYMERS AND METHODS OF SYNTHESIS AND USE

Номер: US20130102079A1
Автор: Boluk Mehmet Yaman, Jost Robert W., Uludag Hasan
Принадлежит: ALBERTA INNOVATES - TECHNOLOGY FUTURES

The present invention relates to polyamine-containing polymers and methods of their synthesis and use. The polymer may be hydroxyethylcellulose, dextran, poly(vinyl alcohol) or poly(methyl acrylate). 1. A method of transfecting a cell with a nucleic acid , comprising contacting the cell with a composition comprising (1) a compound comprising a carbon polymer and one or more polyamine groups , wherein the carbon polymer is selected from the group consisting of hydroxyethylcellulose , dextran , poly(vinyl alcohol) and poly(methyl acrylate); and (2) a nucleic acid.2. A method of introducing an exogenous nucleic acid into a cell , comprising contacting the cell with a composition comprising (1) a compound comprising a carbon polymer and one or more polyamine groups , wherein the carbon polymer is selected from the group consisting of hydroxyethylcellulose , dextran , poly(vinyl alcohol) and poly(methyl acrylate); and (2) a nucleic acid.3. The method of wherein the method is in vitro claim 2 , ex vivo or in vivo. This application is a divisional application of U.S. application Ser. No. 13/078,347 filed Apr. 1, 2011, which claims priority upon U.S. provisional application Ser. No. 61/320,355, filed Apr. 2, 2010. These applications are hereby incorporated by reference in their entireties.The present invention relates to compounds comprising carbon polymers and one or more polyamine groups.Nucleic acids encoding biologically active polypeptides or nucleic acids may be transferred to a cell by any of several methods, including viral vectors and chemical transfection. The choice of technique is a balance between the need to incorporate the nucleic acid efficiently, minimizing impact on the short term, and preferably the long term, survival of the cell, and without compromising the genetic makeup of the cell.Aminated, cationic polymers that interact with the nucleic acid and are then taken up by the cell may be advantageous, at least, by avoiding some of the immunological and ...

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Номер записи: 16
02-05-2013 дата публикации

POLYCARBONATE DIOL AND PRODUCING METHOD THEREOF, AND POLYURETHANE AND ACTIVE ENERGY RAY-CURABLE POLYMER COMPOSITION BOTH FORMED USING SAME

Номер: US20130109804A1
Автор: IIDUKA Haruo, ITO Hiroto, KOMAYA Takashi, KUSAKA Haruhiko, KUSANO Kazunao, OHARA Teruhiko, UCHINO Kentaro, WAKABAYASHI Kazuki, YAMAMOTO Masanori
Принадлежит: MITSUBISHI CHEMICAL CORPORATION

A novel polycarbonate diol is useful as a raw material for producing a polycarbonate diol-based polyurethane with a high degree of hardness, superior abrasion resistance, and superior hydrophilicity. The polyurethane is useful in paints, coating agents, synthetic leathers, artificial leathers, and highly-functional elastomers, or the like. The polycarbonate diol is also useful for producing an active-energy radiation curable polymer composition giving a cured film having superior contamination resistance and high degree of hardness. The curable polymer composition contains a urethane(meth)acrylate oligomer obtained from the polycarbonate diol. The polycarbonate diol is obtained, for example, by reacting two specific types of diols with diester carbonate in the presence of a transesterification catalyst. The catalyst has a metal of Group 1 or 2 on the periodic table. A metal content of the transesterification catalyst is 100 weight ppm or less. 1. A polycarbonate diol , obtained by reacting (i) at least one of diols selected from isosorbide , isomannide and isoidide , (ii) a diol having 1 to 15 carbons which may contain hetero atom , and (iii) a diester carbonate , by use of a transesterification catalyst , wherein ,the transesterification catalyst is either a compound using a metal of Group 1 or a compound using a metal of Group 2 on the periodic table; andthe amount of the transesterification catalyst contained in the polycarbonate diol is 100 ppm or less as the weight ratio of the metal.2. The polycarbonate diol according to claim 1 , wherein the amount of the transesterification catalyst contained in the polycarbonate diol is 0.1 ppm or more as the weight ratio of the metal.3. The polycarbonate diol according to claim 1 , wherein the transesterification catalyst is a compound using a metal of Group 2 on the periodic table.5. The polycarbonate diol according to claim 1 , wherein the highest temperature of the reaction is lower than 180° C.7. The polycarbonate diol ...

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Номер записи: 17
09-05-2013 дата публикации

Polymer for use in liquid crystal alignment layer

Номер: US20130116396A1
Автор: Haruyoshi Takatsu, Hoi Sing Kwok, Isa Nishiyama, Martin Schadt, Sayaka Nose, Vladimir Chigrinov, Yutaka Nagashima
Принадлежит: DIC Corp

The present invention relates to materials used for aligning liquid crystals of liquid crystal display elements and to a polymer for use in liquid crystal vertical alignment layer used in producing a liquid crystal vertical alignment layer. The polymer for use in a liquid crystal vertical alignment layer includes (a) a moiety that is photochemically isomerizable but not photochemically crosslinked, (b) a moiety that is photochemically crosslinkable, and (c) a moiety that stabilizes a vertical alignment. The polymer can be used to produce a vertical alignment layer that has a liquid crystal alignment property enabling control of alignment at a low UV dose and that offers a large pretilt angle and superior optical stability.

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Номер записи: 18
16-05-2013 дата публикации

IODINE ADSORBENT AND COLUMN FOR WATER TREATMENT USING IODINE ADSORBENT

Номер: US20130118968A1
Автор: Sekiguchi Yumiko, Tsuji Hideyuki, YAMADA Arisa
Принадлежит:

An iodine adsorbent of an embodiment includes: a carrier modified with a functional group represented by a formula (1); and a silver ion supported on the carrier, 3. The iodine adsorbent according to claim 1 ,wherein, the carrier is silica.4. The iodine adsorbent according to claim 1 ,wherein the carrier is at least one selected from the group consisting of titania, alumina, and zirconia.5. The iodine adsorbent according to claim 1 ,wherein the carrier is an acrylic resin.6. The iodine adsorbent according to claim 1 ,wherein the carrier has an average particle size being not less than 100 μm and not more than 5 mm.7. A column for water treatment claim 1 , comprising the iodine adsorbent according to filled therein. This application is based upon and claims the benefit of priority from Japanese Patent Application No. 2011-250858 filed on Nov. 16, 2011; the entire contents of which are incorporated herein by reference.Embodiments described herein relate generally to an iodine adsorbent, and a column for water treatment using an iodine adsorbent.Due to the development of industry and increase in population, effective utilization of water resources has been required. Thus, reuse of waste water is very important. In order to achieve the effective utilization and reuse, it is necessary to purify the water, namely, to separate other substances from the water. As a method of separating other substances from liquid, various methods have been known, and there can be cited, for example, membrane separation, centrifugal separation, active carbon adsorption, ozonation, and aggregation, with which the removal of suspended solids or the like is conducted. Such methods make it possible to remove chemical substances such as iodine and nitrogen contained in water, which greatly affect on the environment, and to remove oil, clay and so on dispersed in water.Meanwhile, in recent years, technologies of recovery and removal of iodine have been drawing an attention. A usage range of ...

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Номер записи: 19
16-05-2013 дата публикации

Method for producing a water-absorbent resin

Номер: US20130119309A1
Автор: Atsushi Heguri, Hideki Yokoyama, Nobuhiro Maeda, Sachi Kikuno
Принадлежит: Sumitomo Seika Chemicals Co Ltd

A method for producing a water-absorbent resin comprising at least two stages of reversed-phase suspension polymerization, wherein the first stage of the at least two stages of reversed-phase suspension polymerization comprises the following steps of: (A) performing a primary dispersion by stirring to mix in the absence of surfactants an aqueous solution of a water-soluble ethylenically unsaturated monomer containing a hydrophilic polymeric dispersion agent with a petroleum hydrocarbon dispersion medium in which a hydrophobic polymeric dispersion agent dissolves or disperses; (B) further performing a secondary dispersion by adding a surfactant to the resultant dispersion liquid; and (C) performing a polymerization by using a water-soluble radical polymerization initiator to obtain a water-absorbent resin as particles in a hydrous gel state which disperse in the petroleum hydrocarbon dispersion medium, and a water-absorbent resin obtained by the method.

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Номер записи: 20
16-05-2013 дата публикации

Method for producing a water-absorbent resin

Номер: US20130123445A1
Автор: Atsushi Heguri, Hideki Yokoyama, Nobuhiro Maeda, Sachi Kikuno
Принадлежит: Sumitomo Seika Chemicals Co Ltd

A method for producing a water-absorbent resin by performing a reversed-phase suspension polymerization of a water-soluble ethylenically unsaturated monomer in a petroleum hydrocarbon dispersion medium, comprising the following steps of: (A) performing a primary dispersion in the absence of surfactants by adding an aqueous solution of a water-soluble ethylenically unsaturated monomer containing a hydrophilic polymeric dispersion agent to a petroleum hydrocarbon dispersion medium in which a hydrophobic polymeric dispersion agent was heat-dispersed or heat-dissolved, under stirring; (B) further performing a secondary dispersion by adding a surfactant to a dispersion liquid obtained after the primary dispersion; and (C) performing the reversed-phase suspension polymerization by using a radical polymerization initiator; and the water-absorbent resin obtained by the method.

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Номер записи: 21
16-05-2013 дата публикации

Fluorinated compound, fluorinated polymer and fluorinated copolymer

Номер: US20130123447A1
Автор: Taiki Hoshino
Принадлежит: Asahi Glass Co Ltd

To provide a fluorinated compound having an R F group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer and a fluorinated copolymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH 2 ═C(M)COO(CH 2 ) n PhCOO(CH 2 ) m C r F 2r+1   (I) (in the formula (I), M is a hydrogen atom, a methyl group or a halogen atom, n is an integer of from 0 to 2, Ph is a phenylene group, m is an integer of from 1 to 4, and r is an integer of from 1 to 6).

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Номер записи: 22
16-05-2013 дата публикации

Method for producing a water-absorbent resin

Номер: US20130123455A1
Автор: Atsushi Heguri, Hideki Yokoyama, Nobuhiro Maeda, Sachi Kikuno
Принадлежит: Sumitomo Seika Chemicals Co Ltd

A method for producing a water-absorbent resin having a further reduced odor as compared with a water-absorbent resin obtained by a conventional method as well as a water-absorbent resin produced by the same method, by maintaining the addition rate V from the pouring nozzle for the aqueous solution of the water-soluble ethylenically unsaturated monomer in a polymerization reaction tank not more than 0.30 [min −1 ], in the first stage polymerization step which is within the step of the conventional method upon performing multi-stages such as two or more stages of reversed-phase suspension polymerizations in a method for producing a water-absorbent resin, and thereby by being able to reduce the amount of the petroleum hydrocarbon dispersion medium remaining in the above water-absorbent resin.

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Номер записи: 23
23-05-2013 дата публикации

STYRYLPYRIDINE DERIVATIVES AND THEIR USE FOR BINDING AND IMAGING AMYLOID PLAQUES

Номер: US20130129624A1
Автор: Kung Hank F., Kung Mei-Ping
Принадлежит: THE TRUSTEES OF THE UNIVERSITY OF PENNSYLVANIA

This invention relates to a method of imaging amyloid deposits and to styrylpyridine compounds, and methods of making radiolabeled styrylpyridine compounds useful in imaging amyloid deposits. This invention also relates to compounds, and methods of making compounds for inhibiting the aggregation of amyloid proteins to form amyloid deposits, and a method of delivering a therapeutic agent to amyloid deposits. 3. The compound of claim 1 , wherein n is one.4. The compound of claim 1 , wherein at least one halogen is a radiohalogen.5. The compound of claim 1 , wherein at least one halogen is I claim 1 , I claim 1 , I claim 1 , I claim 1 , Br claim 1 , Br claim 1 , Br claim 1 , F or F.6. The compound of claim 5 , wherein Ris —(CH)NRR claim 5 , wherein Rand Rare independently hydrogen or Calkyl and p is 0.8. The compound of claim 7 , wherein q is an integer from 1 to 5.9. The compound of claim 8 , wherein R claim 8 , R claim 8 , Rand Rare each hydrogen.14. The compound of claim 13 , wherein q is an integer from 1 to 5.15. The compound of claim 14 , wherein R claim 14 , R claim 14 , Rand Rare each hydrogen claim 14 , and q is 1 claim 14 , 2 or 3.17. The compound of claim 16 , wherein R claim 16 , R claim 16 , Rand R claim 16 , R claim 16 , Rand Rare each hydrogen.20. A composition comprising a compound according to wherein said compound contains a C isotope claim 1 , said isotope present in an amount above natural abundance claim 1 , and said compound containing said C isotope having a specific activity above background level.22. The compound of claim 21 , wherein one of R′ and R″ is hydrogen claim 21 , the other is Calkyl.23. A pharmaceutical composition comprising a compound of any one of or and a pharmaceutically acceptable carrier or diluent.24. A diagnostic composition for imaging amyloid deposits claim 21 , comprising a radiolabeled compound of any one of or and a pharmaceutically acceptable carrier or diluent.25. A method of imaging amyloid deposits in a mammal claim ...

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Номер записи: 24
23-05-2013 дата публикации

CATALYST SLURRY PREPARATION SYSTEM AND USE THEREOF

Номер: US20130130890A1
Автор: Brusselle Alain, Fouarge Louis
Принадлежит: TOTAL RESEARCH & TECHNOLOGY FELUY

The present invention relates to the use of a catalyst preparation system for the preparation of a diluted catalyst slurry. In particular, the invention relates to a catalyst preparation system comprising a mixing vessel for mixing a particulate catalyst and a liquid hydrocarbon diluent. According to the invention, diluted catalyst slurry is prepared in a mixing vessel comprising a rotatable axial impeller system comprising at least two double-bladed hubs. The invention also relates to a process for preparing diluted catalyst slurry for use in the preparation of a particulate polyethylene product in a loop reactor with the catalyst preparation system as described herein. 13311811925251173125225117. Use of a catalyst slurry preparation system for the preparation of a diluted catalyst slurry comprising a solid particulate catalyst and a liquid hydrocarbon diluent , wherein said catalyst slurry preparation system comprises a cylindrical mixing vessel () wherein said mixing vessel () comprises a top part () , a bottom part () and a rotatable impeller system () which is actuated by a motor , said impeller system () comprising a magnetic actuated agitator shaft () which is positioned along a longitudinal axis of said mixing vessel () and extends through said top part of said mixing vessel and comprises at least two double-bladed hubs ( , ) , which are fixed to said agitator shaft ().21242243. Use according to claim 1 , wherein said mixing vessel further comprises one or more baffles ( claim 1 , ) claim 1 , wherein said one or more baffle are fixed longitudinally along the inner wall of said mixing vessel () claim 1 , whereby said one or more baffles extend radially inward.3126226125225. Use according to claim 1 , wherein the blades ( claim 1 , ) of each double-bladed hub ( claim 1 , ) are symmetrically positioned about said hub and have a pitch angle (α) comprised between 65° and 75.4126226127227128228129229130230. Use according to claim 1 , wherein each blade ( claim 1 , ...

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Номер записи: 25
23-05-2013 дата публикации

Process for Preparing Vinyl Acetate-Ethylene Copolymers by Means of Emulsion Polymerization

Номер: US20130131261A1
Автор: KOGLER Gerhard, Zecha Helmut
Принадлежит: Wacker Chemie AG

The invention provides processes for preparing vinyl acetate-ethylene copolymers by means of free-radical initiated emulsion polymerization of vinyl acetate, ethylene and optionally one or more further comonomers in the presence of at least one protective colloid and optionally at least one emulsifier, characterized in that the vinyl acetate-ethylene copolymers contain 18 to 45% by weight of ethylene units, based on the total weight of the vinyl acetate-ethylene copolymers, and at least 70% by weight of ethylene units, based on the total weight of the ethylene units and of the further comonomer units of the vinyl acetate-ethylene copolymers, and the free-radical initiated emulsion polymerization is performed in the presence of A) 0.5 to 20% by weight, based on the total weight of the monomers used overall, of one or more solvents, or B) 0.1 to 20% by weight, based on the total weight of monomers used overall, of one or more solvents, and 0.5 to 4% by weight, based on the total weight of monomers used overall, of one or more anionic sulphosuccinic esters of the general formula RO—CO—CH—CH (SOM)—CO—O—R(I) in which M is a cation, Ris a linear or branched alkyl radical having 4 to 17 carbon atoms, an alkylene oxide group —(R—O)-X or a cation M, where Ris a linear or branched alkylene unit having 2 to 5 carbon atoms, n is an integer from 2 to 20 and X is a linear or branched alkyl radical having 4 to 17 carbon atoms, where at most one Rradical in the general formula (I) is a cation M. 1. A process for preparing vinyl acetate-ethylene copolymers by means of radically initiated emulsion polymerization of vinyl acetate , ethylene , and optionally one or more further comonomers in the presence of at least one protective colloid and optionally at least one emulsifier , whereinthe vinyl acetate-ethylene copolymers contain 18% to 45% by weight of ethylene units, based on the total weight of the vinyl acetate-ethylene copolymers, andat least 70% by weight of ethylene units, ...

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Номер записи: 26
06-06-2013 дата публикации

Binder Resin for Electrode of Nonaqueous Electrolyte Secondary Battery, Slurry Composition, Electrode for Nonaqueous Electrolyte Secondary Battery, and Nonaqueous Electrolyte Secondary Battery

Номер: US20130143116A1
Автор: Fujikawa Daisuke, Ito Masakazu, Momose Fumino, Nodono Mitsufumi
Принадлежит: MITSUBISHI RAYON CO., LTD.

A binder resin for an electrode of a nonaqueous electrolyte secondary battery is provided, which is used as the binder resin in a slurry composition for an electrode of a nonaqueous electrolyte secondary battery, containing a binder resin, an active material and an organic solvent. 3. The binder resin for an electrode of a nonaqueous electrolyte secondary battery according to claim 1 , wherein said binder resin contains a polymer having a vinyl cyanide monomer unit.4. A slurry composition for an electrode of a nonaqueous electrolyte secondary battery claim 1 , containing the halogen element-free binder resin according to claim 1 , an active material and an organic solvent.5. An electrode for a nonaqueous electrolyte secondary battery claim 1 , comprising a current collector and an electrode mixture layer provided on said current collector claim 1 , wherein{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'said electrode mixture layer contains the binder resin for an electrode of a nonaqueous electrolyte secondary battery according to and an active material.'}6. An electrode for a nonaqueous electrolyte secondary battery claim 1 , comprising a current collector and an electrode mixture layer provided on said current collector claim 1 , wherein{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, 'said electrode mixture layer is obtained by coating the slurry composition for an electrode of a nonaqueous electrolyte secondary battery according to on the current collector and drying the coating.'}7. A nonaqueous electrolyte secondary battery claim 5 , comprising the electrode for a nonaqueous electrolyte secondary battery according to .8. A binder resin composition for an electrode of a nonaqueous electrolyte battery claim 5 , comprising a polymer (A) having a vinyl cyanide monomer (a1) unit as the main component and a polymer (B) containing a phosphoric acid-containing monomer (b1) unit.9. The binder resin composition for an electrode of a nonaqueous electrolyte battery ...

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Номер записи: 27
20-06-2013 дата публикации

METHOD FOR PREPARING CARBENE IN SOLUTION, NOVEL STABLE FORM OF CARBENE OBTAINED IN PARTICULAR BY MEANS OF SAID METHOD, AND USES THEREOF IN CATALYSIS

Номер: US20130158274A1
Автор: Baceiredo Antoine J., Gojon Sophie, Kato Tsuyoshi, Maliverney Christian, Saint-Jalmes Laurent
Принадлежит: BLUESTAR SILICONES FRANCE SAS

The invention relates to a method for preparing carbene by means of deprotonation of a precursor salt using a strong base. A purpose of the invention is to enhance the synthesis of carbenes, i.e. to simplify same, to make said synthesis more economical and to obtain a liquid or solid, stable and pure form consitituting a catalytic system that is easy to store and use and that has a higher efficiency, higher yield and higher selectivity than carbene catalysts of the prior art. In order to do so, the method comprises deprotonation in a solvent including an alcohol. The invention also relates to an alcohol-containing solution and carbene, and to a solid that can be obtained from the solution, e.g. by means of sublimation. 3. The process as claimed in claim 1 , characterized in that the wherein said alcohol corresponds to formula (I°) R° OH claim 1 , in which R° corresponds to an alkyl claim 1 , cycloalkyl claim 1 , aryl claim 1 , alkenyl claim 1 , alkynyl claim 1 , arylalkyl claim 1 , silyl or siloxane group claim 1 , R° optionally being selected from the group consisting of: methyl claim 1 , ethyl claim 1 , propyl and butyl.4. The process as claimed in claim 1 , wherein said strong base is selected from the group consisting of alkali metal and alkaline earth metal hydroxides claim 1 , alkoxides claim 1 , hydrides and amides claim 1 , optionally from the subgroup consisting of: CHONa claim 1 , potassium tert-butoxide claim 1 , KOH claim 1 , NaOH claim 1 , CHCHOMgOCHCHand mixtures thereof.5. The process as claimed in claim 1 , wherein said deprotonation produces a salt which precipitates and which is separated from said solution A.6. The process as claimed in claim 1 , in which said solvent is sublimed so as to collect said carbene C in solid form.9. The solution A as claimed in claim 7 , capable of being used as a catalyst and/or in preparing a metal catalyst which is either in zero state and/or in ionized state and which comprises at least one carbene as ligand and/or ...

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Номер записи: 28
27-06-2013 дата публикации

CATALYST CARRIER BASED ON SILICA GEL

Номер: US20130165608A1
Автор: Braedikow Andreas, Eckardt Tobias, Puvogel Thorsten, Siegel Angela
Принадлежит: BASF SE

The present invention relates to spherical beads comprising at least one metal and/or semimetal oxide, having a mean diameter in the range from 10 to 120 μm, a BET surface area in the range from 400 to 800 m/g and a pore volume in the range from 0.3 to 3.0 cm/g, wherein the diameter of a given bead at any one point of said bead deviates by less than 10% from the average diameter of said bead and the surface of said bead is substantially smooth, and also to a process for producing these spherical beads, to a particulate catalyst comprising the spherical beads and to the use of the spherical beads as catalysts or catalyst carriers. 110-. (canceled)11. Spherical beads comprising at least one metal and/or semimetal oxide , having a mean diameter in the range from 10 to 120 μm , a BET surface area in the range from 400 to 800 m/g and a pore volume in the range from 0.3 to 3.0 cm/g , wherein the diameter of a given bead at any one point of said bead deviates by less than 10% from the average diameter of said bead and the surface of said bead is substantially smooth.12. The beads of wherein the at least one metal and/or semimetal oxide is selected from the group consisting of SiO claim 11 , AlO claim 11 , TiO claim 11 , MgO and mixtures thereof.13. The beads of claim 11 , consisting of SiOto an extent of at least 96% by weight.14. The beads of wherein the at least one metal and/or semimetal oxide is substantially amorphous.15. The beads of wherein the BET surface area is in the range from 500 to 600 m/g.16. The beads of wherein the pore volume is in the range from 1.5 to 2.5 cm/g.17. A process for producing spherical beads comprising at least one metal and/or semimetal oxide claim 11 , having a mean diameter in the range from 10 to 120 μm claim 11 , a BET surface area in the range from 400 to 800 m/g and a pore volume in the range from 0.3 to 3.0 cm/g claim 11 , wherein the diameter of a given bead at any one point of said bead deviates by less than 10% from the average ...

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Номер записи: 29
27-06-2013 дата публикации

PROPYLENE-BASED TERPOLYMERS FOR FILM

Номер: US20130165613A1
Автор: Galvan Monica, Marzolla Roberta
Принадлежит:

A propylene/ethylene/1-hexene terpolymer containing from 1.0 wt % to 2.5 wt %, of ethylene derived units and from 2.0 wt % to 3.5 wt % of 1-hexene derived units, the sum of the amounts of propylene, ethylene and 1-.hexene derived units being 100, having the following features: a)the amount (Wt %) of 1-hexene (C6) and the amount (Wt %) of ethylene (C2) fulfil the following relation (i): 0.5 Подробнее

Номер записи: 30
27-06-2013 дата публикации

Method for Preparing Polycondensation Resin

Номер: US20130165621A1
Автор: JANG Bok Nam, JANG Seung Hyun, Kanda Tomomich, Tomoaki Shimoda
Принадлежит: CHEIL INDUSTRIES INC.

Disclosed herein is a method for preparing a polycondensation resin. The method includes preparing a low degree condensate; and solid phase polymerizing the low degree condensate, wherein a granular molded article is introduced into the solid phase polymerization. The method enables efficient manufacture of high quality resins without problems such as agglomeration or scaling of a low degree condensate in pipes. 1. A method for preparing a polycondensation resin , comprising:preparing a low degree condensate; andsolid phase polymerizing the low degree condensate,wherein a granular molded article is provided upon solid phase polymerization.2. The method according to claim 1 , wherein the granular molded article is a granular compression-molded article of the low degree condensate.3. The method according to claim 2 , wherein the granular molded article of the low degree condensate is prepared by compression molding of the low degree condensate at about 10 MPa to about 800 MPa.4. The method according to claim 2 , wherein the solid phase polymerization is performed in a longitudinal tower type apparatus or a longitudinal tower type machine.5. The method according to claim 1 , wherein the granular molded article is a granular molded article of a thermoplastic resin.6. The method according to claim 5 , wherein the low degree condensate is prepared in the form of crystalline powder claim 5 , and the crystalline powder of the low degree condensate and the granular molded article of the thermoplastic resin are mixed to carry out solid phase polymerization.7. The method according to claim 5 , wherein the thermoplastic resin is end-capped with an end capping agent.8. The method according to claim 6 , wherein the granular molded article of the thermoplastic resin is mixed in an amount of about 0.1 wt % to 10 wt % with respect to the crystalline powder of the low degree condensate.9. The method according to claim 5 , wherein the granular molded article of the thermoplastic resin ...

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Номер записи: 31
04-07-2013 дата публикации

Golf ball resin composition and golf ball

Номер: US20130172109A1
Автор: Kazuyoshi Shiga, Ryo Murakami, Takahiro Shigemitsu
Принадлежит: Dunlop Sports Co Ltd

An object of the present invention is to provide a golf ball resin composition excellent in shot feeling and resilience. The golf ball resin composition includes (A) at least one resin component selected from the group consisting of (a-1) a binary copolymer composed of an olefin and an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms, (a-2) an ionomer resin consisting of a metal ion-neutralized product of the binary copolymer components, (a-3) a ternary copolymer composed of the binary copolymer components and an α,β-unsaturated carboxylic acid ester, and (a-4) an ionomer resin consisting of a metal ion-neutralized product of the ternary copolymer components; and (B) a basic metal salt of a fatty acid, and having a storage modulus E′ (Pa) and a loss modulus E″ (Pa) satisfying a following expression; log( E′/E″ 2 )≧−5.84 when measured in a tensile mode using a dynamic viscoelasticity measuring apparatus.

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Номер записи: 32
11-07-2013 дата публикации

Composite polymerization initiator and polymer brush composite obtained therefrom

Номер: US20130178588A1
Автор: Avataneo Marco, Denisov Evgeny, Kent Bradley Lane, Lin Shiow-Ching, Marchionni Giuseppe, Spada Fabrizio
Принадлежит: SOLVAY SPECIALTY POLYMERS ITALY, S.P.A.

Composite polymerization initators are disclosed suitable to prepare polymer brush composites. 1. A composite polymerization initiator comprising groups of formula (1) covalently anchored to the surface of a solid substrate:{'br': None, 'sub': n', '2', 'B1', '2, '-(L)-CR—B(R)\u2003\u2003(1)'}{'sub': 1', '15', 'B1', '1', '20', '5', '10', 'B1', 'B1', '2, 'wherein L is a linker group, n is equal to 0 or 1; each R is independently selected from the group consisting of hydrogen, C-Clinear or branched alkyl group, optionally comprising heteroatoms; and wherein each Ris independently selected from the group consisting of hydrogen, C-Clinear, branched or cyclic alkyl group, C-Caromatic group, optionally fluorinated; each group Rmay be comprised in an, optionally substituted, aliphatic or aromatic cyclic structure; and wherein said —B(R)may be an aliphatic bicyclic borane radical wherein both boron-carbon bonds are part of a cyclic structure.'}2. A method for the preparation of the composite initiator of comprising the steps of: (a) providing a solid substrate comprising surface reactive groups GSR; said{'sub': 2', 'B1', '2', '2', 'B1', '2', 'B1', '2', 'B2', 'B1', 'B2', '1', '5, 'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(b) reacting the solid substrate with a compound comprising one functional group X capable of forming a covalent bond with the substrate surface by reaction with the surface reactive groups GSR, and at least one functional group either comprising a moiety of formula —CR—B(R)or capable of forming a moiety —CR—B(R)by reaction with an organoborane of formula B(R)R, wherein R and Rare as defined in and Ris selected from the group consisting of hydrogen, halogen, said C-Clinear or branched alkyl.'}3. The method according to comprising the step of reacting the solid substrate with a linker compound of formula X-(L′)-Ycomprising one functional group [X] capable of forming a covalent bond with the substrate surface by reaction with the surface reactive groups ...

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Номер записи: 33
11-07-2013 дата публикации

PROCESS FOR PREPARING (METH)ACRYLIC ESTERS

Номер: US20130178592A1
Автор: BERGMANN Hermann, Bette Virginie, Dust Matthias, Meisenburg Uwe, Misske Andrea, Petzoldt Jochen
Принадлежит: BASF SE

The invention relates to a process for preparing (meth)acrylic esters by esterifying (meth)acrylic acid or transesterifying at least one (meth)acrylic ester with at least one compound comprising at least one OH group in the presence of a heterogeneous catalyst comprising at least one inorganic salt, wherein the esterification or transesterification is performed in the presence of 300 to 3000 ppm of water based on the total weight of the reaction mixture. 1. A process for preparing (meth)acrylic esters by esterifying (meth)acrylic acid or transesterifying at least one (meth)acrylic ester with at least one compound comprising at least one OH group in the presence of a heterogeneous catalyst comprising at least one inorganic salt , which comprises performing the esterification or transesterification in the presence of 300 to 3000 ppm of water based on the total weight of the reaction mixture.2. The process according to claim 1 , wherein the esterification or transesterification is performed in the presence of 400 to 2000 ppm of water based on the total weight of the reaction mixture.3. The process according to claim 1 , wherein the esterification or transesterification is performed in the presence of 500 to 1200 ppm of water based on the total weight of the reaction mixture.4. The process according to claim 1 , wherein the water comprises essentially HO.5. The process according to claim 1 , wherein the water claim 1 , in the case that a reaction mixture is made up in one process step claim 1 , is added completely or in portions in several process steps.6. The process according to claim 1 , wherein the water is supplied completely in one process step or in portions in several process steps when the reaction mixture is made up claim 1 , before or after addition of the heterogeneous catalyst.7. The process according to claim 1 , wherein the water is supplied completely in one process step before the addition of the heterogeneous catalyst claim 1 , preferably before the ...

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Номер записи: 34
18-07-2013 дата публикации

METHOD FOR CONTROLLING SIZE DISTRIBUTION OF POLYMER PARTICLES DURING PREPARATION OF AQUEOUS POLYMER DISPERSION AND AQUEOUS POLYMER DISPERSION

Номер: US20130184407A1
Автор: Bruun Nina, Heiska Perttu, Huhtala Kimmo, Peuranen Helena
Принадлежит: KEMIRA OYJ

The present disclosure relates to a method for controlling size distribution of formed polymer particles during preparation of aqueous polymer dispersion. The method comprises obtaining an aqueous polysaccharide solution, which comprises about 10 to 40 weight-% polysaccharide containing a free hydroxyl group, such as starch, and polymerising in the polysaccharide solution in the presence of a graft-linking, water-soluble redox system about 30 to 60 weight-% of at least one optionally substituted styrene, about 60 to 30 weight-% of at least one C1-C4-alkyl (meth)acrylate, and 0 to about 10 weight-% of other ethylenically unsaturated copolymerizable monomers. The size distribution of the formed polymer particles is controlled by adjusting viscosity of the polysaccharide solution before the polymerisation to a level less than about 20 mPas. The present disclosure relates also to an aqueous polymer dispersion having the D(99) value less than about 160 nm for polymer particles in the polymer dispersion and its use. 1. A method for controlling size distribution of formed polymer particles during preparation of an aqueous polymer dispersion , comprising: '(a) about 10 to 40 weight-% of polysaccharide containing a free hydroxyl group, such as starch,', 'obtaining an aqueous polysaccharide solution, which comprises'} (b) about 30 to 60 weight-% of at least one optionally substituted styrene,', '(c) about 60 to 30 weight-% of at least one C1-C4-alkyl (meth)acrylate,', '(d) 0 to about 10 weight-% of other ethylenically unsaturated copolymerizable monomers,, 'polymerising in the polysaccharide solution in the presence of a graft-linking, water-soluble redox system'}wherein the sum of (a)+(b)+(c)+(d) is 100%,wherein the size distribution of the formed polymer particles is controlled by adjusting viscosity of the polysaccharide solution before the polymerisation to a level less than about 20 mPas, measured at about 23° C. with Brookfield LVDV viscometer with spindle 18, 60 rpm.2. ...

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Номер записи: 35
25-07-2013 дата публикации

Crosslinker-Accelerator System for Polyacrylates

Номер: US20130190457A1
Автор: Bamberg Sarah, Beschmann Jennifer, Papenbroock Marten, Prenzel Alexander
Принадлежит: TESA SE

Controlled thermal crosslinking in a polyacrylate-based composition is accomplished by a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprising at least 1. A crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups , comprisinga crosslinker comprising at least one substance comprising at least one epoxide group; and {'br': None, 'sup': 1', '2', '3', '4', '5', '6', '7', '8', '9', '10, 'sub': 'n', 'RRN—CRR—CRR—(CRR)—NRR\u2003\u2003(I)'}, 'an accelerator comprising at least one substance conforming to the general formula (I)'}{'sup': 1', '2', '9', '10', '1', '2', '9', '10, 'wherein the radicals R, R, Rand Rindependently of one another are a hydrogen atom or a substituted or unsubstituted alkyl or cycloalkyl radical having 1 to 8 carbon atoms or an alkylene group bonded to the main chain and having 1 to 8 carbon atoms, where at least one of the radicals R, R, Rand Ris not a hydrogen atom;'}{'sup': 3', '4', '5', '6', '7', '8, 'the radicals R, R, R, R, Rand Rindependently of one another are a hydrogen atom or an alkyl group having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; and'}n is an integer from 0 to 4.2. The crosslinker-accelerator system according to claim 1 , wherein at least one of the radicals R claim 1 , R claim 1 , Rand Ris a methyl group.3. The crosslinker-accelerator system according to wherein Rand Rand/or Rand Rare each a methyl group.4. The crosslinker-accelerator system according to wherein n is 0 (zero).5. The crosslinker-accelerator system according to wherein n is 0 (zero) and Rand Rand/or Rand Rare each a methyl group.6. The crosslinker-accelerator system according to wherein the ratio of the number of all the substituted and unsubstituted amino and phosphine groups in the accelerator to the number of ...

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Номер записи: 36
25-07-2013 дата публикации

CROSSLINKER-ACCELERATOR SYSTEM FOR POLYACRYLATES

Номер: US20130190459A1
Автор: Bamberg Sarah, Beschmann Jennifer, Papenbroock Marten, Prenzel Alexander
Принадлежит: TESA SE

Crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups capable of entering into linking reactions with epoxide groups, comprising at least one substance having at least one epoxide group as crosslinker and at least one substance of the formula 1. Crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups capable of entering into linking reactions with epoxide groups , comprisingat least one substance comprising at least one epoxide group as crosslinker and {'br': None, 'sup': 1', '2', '3', '4', '5', '6', '7, 'sub': 2', 'n, 'RN—CRR—CRR—(CRR)—X \u2003\u2003(I)'}, 'at least one substance of the formula (I)'}in which{'sup': '1', 'the radicals Rindependently of one another are a hydrogen atom or a substituted or unsubstituted alkyl or cycloalkyl radical having 1 to 8 carbon atoms or together'}with the nitrogen atom form a 5-7-membered ring which comprises at least 4 carbon atoms and not more than one further heteroatom as ring atoms;{'sup': 2', '3', '4', '5', '6', '7, 'the radicals R, R, R, R, Rand Rindependently of one another are a hydrogen atom or an alkyl radical having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group;'}n is an integer from 0 to 4; and{'sub': 2', '1', '18', '2', '18', '2', '18, 'X is a group selected from the group consisting of —OH, —OR, —SH, —SR and —PR, in which the radicals R independently of one another are a C-Calkyl radical, C-Calkenyl radical or C-Calkynyl radical which is in each case linear or branched and unsubstituted or substituted, or an unsubstituted or substituted aryl group or an aliphatic or aromatic heterocycle, as accelerator.'}2. Crosslinker-accelerator system according to claim 1 , wherein X is a group selected from the group consisting of —OH claim 1 , —OR and —PR.3. Crosslinker-accelerator system according to claim 2 , wherein X is —OH or —OR.4. Crosslinker-accelerator system according to claim 3 , wherein R is an optionally ...

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Номер записи: 37
25-07-2013 дата публикации

Crosslinker-Accelerator System for Polyacrylates

Номер: US20130190460A1
Автор: Bamberg Sarah, Beschmann Jennifer, Papenbroock Marten, Prenzel Alexander
Принадлежит: TESA SE

In the context of a polyacrylate-based composition, the intention is to allow controlled thermal crosslinking. This is accomplished by provision of a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprising 1. A crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups , comprising at least one substance comprising at least one epoxide group (crosslinker) and at least one substance conforming to the general formula (I){'br': None, 'sub': '3', 'NR\u2003\u2003(I),'}in which the radicals R independently of one another are a hydrogen atom or an organic radical with 1 to 20 carbon atoms,with at least one of the radicals R being an organic radical with 1 to 20 carbon atoms and comprising at least one alcoholic OH group.2. The crosslinker-accelerator system according to claim 1 , wherein at least two radicals R independently of one another are an organic radical with 1 to 20 carbon atoms claim 1 , with at least one of these radicals R comprising at least one alcoholic OH group.3. The crosslinker-accelerator system according to wherein the radicals R independently of one another are an organic radical with 1 to 20 carbon atoms claim 1 , with at least one of these radicals R comprising at least one alcoholic OH group.4. The crosslinker-accelerator system according to wherein at least one of the radicals R is a hydroxyalkyl group with 1 to 8 carbon atoms.5. The crosslinker-accelerator system according to wherein the radicals R are substituted or unsubstituted alkyl groups with 1 to 8 carbon atoms.6. The crosslinker-accelerator system according to wherein at least one of the radicals R is a hydroxyalkyl group with 1 to 8 carbon atoms claim 1 , and at least one further radical R is an aminoalkyl group with 1 to 8 carbon atoms.7. The crosslinker- ...

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Номер записи: 38
01-08-2013 дата публикации

MANUFACTURING METHOD OF (METH) ACRYLIC POLYMER

Номер: US20130197175A1
Автор: Kato Yasunaka, Yoshihashi Kenichi
Принадлежит: KANEKA CORPORATION

In a method for polymerizing a (meth)acrylic monomer by living radical polymerization in the presence of a transition metal complex catalyst, the combined use of a multidentate amine (A), a base (B) and a reducing agent (C) makes it possible to achieve a rapid polymerization reaction and high monomer conversion rate and obtain a polymer having a narrow molecular weight distribution when 5-30 ppm by weight of copper atoms and a mole amount of 7 mmol % or less of multidentate amine (A) are used, each based on the total amount of (meth)acrylic monomer introduced. 1. A method for producing a (meth)acrylic polymer , comprising living radical polymerization of a (meth)acrylic monomer in the presence of a copper complex catalyst , wherein , based on the total amount of (meth)acrylic monomer introduced , 5 to 30 ppm by weight of copper atoms and a mole amount of 7 mmol % or less of a multidentate amine (A) are contained , the multidentate amine (A) being in an amount of 150 mol % or less based on the total amount of copper atoms ,wherein a base (B) other than the multidentate amine (A), and a reducing agent (C) are contained in a reaction system, andwherein the resulting (meth)acrylic polymer has a molecular weight distribution of 1.1 to 1.8, andwherein the base (B) is at least one of a monoamine compound and an inorganic compound.47-. (canceled)8. The method for producing a (meth)acrylic polymer according to claim 1 , wherein the reducing agent (C) is at least one selected from the group consisting of a metal claim 1 , an organic tin compound claim 1 , ascorbic acid claim 1 , an ester of ascorbic acid claim 1 , an ascorbic acid salt claim 1 , hydrazine or a borohydride.9. The method for producing a (meth)acrylic polymer according to claim 1 , wherein the reducing agent (C) is a hydride reducing agent.10. The method for producing a (meth)acrylic polymer according to claim 1 , wherein the reducing agent (C) is at least one selected from the group consisting of hydrazine ...

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Номер записи: 39
08-08-2013 дата публикации

HYBRID SILICONE COMPOSITION FOR LIGHT EMITTING DEVICE

Номер: US20130200426A1
Автор: Borque Leticia, Dunekake Ralf, Gillissen Stijn, Leyssens Karen, Plantenberg Thomas, Zhou Jing
Принадлежит:

A silicon-based curable composition providing improved transparency, mechanical strength and resistance against heat and photo-degradation comprises at least one organopolysiloxane represented by the composition formula (1): 1. A curable composition comprising {'br': None, 'sup': 1', '1', '1', '2', '1', '2', '1', '2, 'sub': 3', '1/2', 'a', '2', '2/2', 'b', '2/2', 'c', '3/2', 'd', '3/2', 'e', '2', '1/2', 'f, '(RSiO)(RSiO)(RRSiO)(RSiO)(RSiO)(RRSiO)\u2003\u2003(1),'}, '(A) at least one organopolysiloxane represented by the composition formula (1){'sup': 1', '2', '1', '2, 'wherein each Rindependently represents a monovalent organic group having 1 to 20 carbon atoms or an OH group with the proviso that at each silicon-atom bearing no Rat least one Rrepresents a monovalent organic group having 1 to 20 carbon atoms, each Rindependently represents a methacryloxyalkyl group having 5 to 20 carbon atoms and a, b, c, d, e, f each represent the fraction of the number of the respective units based on the number of all units of the organopolysiloxane and satisfy a≧0, b≧0, c≧0, d≧0, e≧0, f≧0 and also satisfy c+e>0 and a+b+c+d+e+f=1; and'}(B) at least one curing catalyst.3. The curable composition according to claim 2 , wherein the composition further comprises at least one organopolysiloxane which is of branched structure represented by the composition formula (4):{'br': None, 'sup': 1′', '1′', '1′', '2', '1′', '2, 'sub': 3', '1/2', 'a', '2', '2/2', 'b', '2/2', 'c', '3/2', 'd', '3/2', 'e, '(RSiO)(RSiO)(RRSiO)(RSiO)(RSiO)\u2003\u2003(4),'}{'sup': 1′', '2, 'wherein each R independently represents an unsubstituted or substituted monovalent hydrocarbon group having 1 to 20 carbon atoms, each Rindependently represents a methacryloxyalkyl group having 5 to 20 carbon atoms and a, b, c, d, e each represent the fraction of the number of the respective units based on the number of all units of the organopolysiloxane and satisfy a>0, b≧0, c≧0, d≧0, e>0 and a+b+c+d+e=1.'}4. The curable ...

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Номер записи: 40
15-08-2013 дата публикации

ADDUCTS, ADDUCTS AND OLIGOMERS, OR ADDUCTS, OLIGOMERS AND LOW MOLECULAR WEIGHT POLYMERS, AND THEIR PREPARATION

Номер: US20130210995A1
Автор: JR. William J., Kolich Charles H., Layman, Mack Arthur G.
Принадлежит: Albemarle Corporation

This invention provides adducts, mixtures of adducts and oligomers, and/or mixtures of adducts, oligomers, and low molecular weight polymers formed from monovinylaromatic hydrocarbons. 1. A composition which comprises {'br': None, 'sub': 2', '2', 'n', '2, 'Ar—CH[—CHCR(Ar′)]—CHCHR—Ar′'}, 'a mixture comprising two or more adducts and one or more oligomers, which individual adducts and oligomer(s) of these mixtures can be represented by the formulawherein Ar and each Ar′ are, independently, aromatic hydrocarbon moieties, each R is a hydrogen atom, n is a whole number in the range of 0 to 24 and wherein said composition has a polydispersity in the range of 1.32 to 1.64, a standard deviation in the range of 174 to 471 Daltons, and an asymmetry in the range of 1.763 to 4.13.2. A composition as in wherein Ar contains in the range of 1 to 4 aromatic rings and has in the range of 1 to 6 alkyl ring substituents.3. A composition as in claim 1 , wherein Ar′ contains in the range of 1 to 4 aromatic rings.4. A composition as in wherein each of Ar and Ar′ is a phenyl group.5. A composition as in claim 1 , wherein an adduct of said composition is 1-phenyl-3-(o-tolyl)propane claim 1 , 1-phenyl-3-(m-tolyl)propane claim 1 , 1-phenyl-3-(p-tolyl)propane claim 1 , 1-phenyl-3-(p-tert-butylphenyl)propane claim 1 , 1-phenyl-3-(p-ethylphenyl)propane claim 1 , 1-(o-isopropylphenyl)-3-(p-tolyl)propane claim 1 , 1-phenyl-3-(2 claim 1 ,4 claim 1 ,6-trimethylphenyl)propane claim 1 , 1-phenyl-3-(1-naphthyl)propane claim 1 , or 1-phenyl-3-(2-naphthyl)propane.6. A composition as in wherein said composition is a mixture of adducts in which the values of n in the individual adduct formulas are consecutive numbers.7. A composition as in wherein said composition is a mixture comprising two or more adducts and one or more oligomers.8. A composition as in wherein n is in the range of about 1 to about 20.9. A composition as in wherein n is in the range of about 1 to about 9.10. A composition as in wherein ...

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Номер записи: 41
15-08-2013 дата публикации

Process for the Preparation of 1-Hydroxy-6-Substituted Pyridones

Номер: US20130211093A1
Автор: Hani Rahim, Jardas John Joseph, Steele David A.
Принадлежит: ARCH CHEMICALS, INC.

Disclosed herein is a cost effective and environmentally friendly process to prepare 1-hydroxy-6-substituted pyridones from 2,6-dichloropyridine. The process includes the steps of (a) reacting 2,6-dichloropyridine with hydrogen peroxide in the presence of trifluoroacetic acid at a first temperature to produce a first intermediate containing (1) trifluoroacetic acid and (2) 2,6-dichloropyridine N-oxide and/or salts thereof; (b) adding sulfuric acid to the first intermediate to provide a second intermediate; (c) removing trifluoroacetic acid from the second intermediate to provide a composition containing 2,6-dichloropyridine N-oxide and/or salts thereof which is essentially free of trifluoroacetic acid; (d) reacting 2,6-dichloropyridine N-oxide and/or salts thereof from step (c) with RXH and a base wherein each R is independently a substituted or unsubstituted hydrocarbyl group having between 1 and 20 carbon atoms, X is oxygen or sulfur, to produce a corresponding 2,6-disubstituted-pyridine N-oxide; and (e) heating the disubstituted compound thereby producing the 1-hydroxy-6-substituted pyridone. 1. A process for separating (1) an acid catalyst and (2) 2 ,6-dichloropyridine-N-oxide and/or salts thereof from a composition containing (1) the acid catalyst and (2) 2 ,6-dichloropyridine-N-oxide and/or salts thereof , the process comprisingadding an acid having a pKa number lower than the pKa number of the acid catalyst to the a composition containing (1) an acid catalyst and (2) 2,6-dichloropyridine-N oxide and/or salts thereof; andremoving the acid catalyst.3. A process as defined in claim 2 , wherein the acid catalyst comprises trifluoroacetic acid.4. A process as defined in claim 2 , wherein the acid comprises sulfuric acid.5. A process for separating (1) trifluoroacetic acid and (2) 2 claim 2 ,6-dichloropyridine-N-oxide and/or salts thereof from a composition containing (1) trifluoroacetic acid and (2) 2 claim 2 ,6-dichloropyridine-N-oxide and/or salts thereof claim ...

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Номер записи: 42
22-08-2013 дата публикации

PROCESS FOR THE PRODUCTION OF RUBBER IONOMERS AND POLYMER NANOCOMPOSITES

Номер: US20130217833A1
Автор: Adkinson Dana, Feller Rolf, Kirchhoff Jörg, Lovegrove John, Magill Phil, Paul Hanns-Ingolf, Wagner Paul
Принадлежит: LANXESS INTERNATIONAL SA

The invention relates to an energy efficient, environmentally favourable process for preparing water and solvent-free rubber ionomers and/or polymer nanocomposites comprising said rubber ionomers. 1. A process for the preparation of rubber ionomers comprising at least the steps of: a concentrated fluid (L) containing at least one brominated rubber and at least one volatile compound', 'and at least one nitrogen and/or phosphorous containing nucleophile., 'a) feeding at least'} an extruder degassing section comprising at least a conveying section and at least one vent port with one or more vapor lines,', 'an accumulating section and', 'an outlet section,, 'into an extruder unit comprising at least'}andb) at least partially reacting the brominated rubber or the brominated rubbers with the nitrogen and/or phosphorous containing nucleophile or the nitrogen and/or phosphorous containing nucleophiles within the extruder unit whereby rubber ionomers (ION) are formed and volatile compounds are at least partially removed through the vent ports and vapor lines.2. A process for the preparation of polymer nanocomposites comprising at least the steps of: a concentrated fluid (L) containing at least one brominated rubber and at least one volatile compound', 'and at least one nitrogen and/or phosphorous containing nucleophile', 'and at least one filler, 'a*) feeding at least'} an extruder degassing section comprising at least a conveying section and at least one vent port with one or more vapor lines,', 'an accumulating section and', 'an outlet section,, 'into an extruder unit comprising at least'}and [ the brominated rubber or the brominated rubbers and the nitrogen and/or phosphorous containing nucleophile or the nitrogen and/or phosphorous containing nucleophiles and/or', 'the rubber ionomers (ION), 'formation of polymer nanocomposites by reaction of'}, 'with at least one filler, 'b*) reacting the brominated rubber or the brominated rubbers with the nitrogen and/or phosphorous ...

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Номер записи: 43
29-08-2013 дата публикации

ADDUCT

Номер: US20130225728A1
Автор: Potisek Stephanie L., Wilson Mark B.
Принадлежит:

An adduct of (a) at least one divinylarene dioxide, and (b) at least one end-functionalized polymer. For example, the adduct may be beneficially used as a toughening agent for toughening thermoset resins such as epoxy resins. 1. An adduct comprising a reaction product of (a) at least one divinylarene dioxide , and (b) at least one end-functionalized polymer.2. The adduct of claim 1 , wherein the at least one divinylarene dioxide comprises divinylbenzene dioxide.3. The adduct of claim 2 , wherein the divinylarene dioxide comprises a composition having a purity of greater than 5 weight percent.4. The adduct of claim 1 , wherein the at least one end-functionalized polymer comprises at least one functionally terminated poly(butadiene-acrylonitrile)copolymer.5. The adduct of claim 1 , wherein the at least one end-functionalized polymer comprises an end-functionalized acrylonitrile butadiene copolymer.6. The adduct of claim 1 , wherein the at least one end-functionalized polymer comprises a carboxylic acid-terminated acrylonitrile butadiene copolymer.7. The adduct of claim 1 , wherein the at least one end-functionalized polymer comprises a carboxy-terminated polybutadiene.8. The adduct of claim 1 , wherein the at least one end-functionalized polymer comprises an end-functionalized polysiloxane.9. The adduct of claim 1 , wherein the at least one end-functionalized polymer is selected from the group consisting of a carboxy-terminated butadiene acrylonitrile copolymer claim 1 , an amine-terminated butadiene acrylonitrile copolymer; and mixtures thereof.10. The adduct of claim 1 , wherein the at least one end-functionalized polymer has a glass transition temperature (T) of below about 0° C.11. The adduct of claim 1 , wherein the molar ratio of the at least one end-functionalized polymer to the at least one divinylarene dioxide is from about 0.01:1 to about 10 claim 1 ,000:1.12. The adduct of claim 11 , wherein the molar ratio of the at least one end-functionalized polymer to ...

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Номер записи: 44
05-09-2013 дата публикации

POLYMER-DENDRIMER HYBRIDS

Номер: US20130231450A1
Автор: Bonzi Gwenaelle, Cooper Andrew, Rannard Steven, Weaver Jonathan
Принадлежит: THE UNIVERSITY OF LIVERPOOL

The present invention relates to a branched vinyl polymer carrying dendrons made from monofunctional vinyl monomers and branched by virtue of difunctional vinyl monomers so that there is on average one branch or fewer per polymer chain to avoid gelation. The polymer may be made by chain-growth polymerization of predominantly monofunctional vinyl monomers in the presence of difunctional vinyl monomers and dendron units. 1. A branched vinyl polymer carrying dendrons , wherein the branched vinyl polymer is made from a monofunctional vinyl monomer and is branched by virtue of a difunctional vinyl monomer so that there is on average one branch or fewer per vinyl polymer chain.2. A polymer as claimed in claim 1 , wherein the dendrons are present predominantly at the ends of the vinyl polymer chains.3. A polymer as claimed in claim 1 , wherein the dendrons are present predominantly as pendant groups on the vinyl polymer chains.4. A polymer as claimed in claim 1 , wherein the dendrons are present at the ends of the vinyl polymer chains and as pendant groups on the vinyl polymer chains.5. A non-gelled branched vinyl polymer carrying dendrons claim 1 , wherein the non-gelled branched vinyl polymer is a chain-growth polymer and comprises a predominant amount of monofunctional vinyl monomer units in the presence of difunctional vinyl monomer units and dendron units.6. A vinyl polymer-dendrimer hybrid product comprising:vinyl polymer chains and dendrons attached to the vinyl polymer chains, wherein adjacent vinyl polymer chains are attached to one another by a branch and the vinyl polymer-dendrimer hybrid product comprises one branch or fewer per vinyl polymer chain.7. The vinyl polymer-dendrimer hybrid product of claim 6 , wherein the vinyl polymer chains comprise a reaction product of monofunctional vinyl monomers.8. The vinyl polymer-dendrimer hybrid product of claim 7 , wherein the monofunctional vinyl monomer comprises 2-hydroxypropyl methacrylate claim 7 , 2- ...

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Номер записи: 45
12-09-2013 дата публикации

(meth)acrylate composition

Номер: US20130237660A1
Автор: Daichi Ogawa, Takeshi Iwasaki, Tomoaki Takebe, Yutaka Obata
Принадлежит: Idemitsu Kosan Co Ltd

Provided is a (meth)acrylate composition containing: (A) at least one (meth)acrylate compound selected from the group consisting of a (meth)acrylate-modified silicone oil, a (meth)acrylate having a long-chain aliphatic hydrocarbon group, and a polyalkylene glycol (meth)acrylate having number-average molecular weight of not less than 400; (B) a (meth)acrylate compound to which an alicyclic hydrocarbon group having 6 or more carbon atoms is ester-linked; (C) (meth)acrylic acid or a (meth)acrylate compound having a polar group; (D) a radical polymerization initiator; and (E) a white pigment.

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Номер записи: 46
19-09-2013 дата публикации

PARTICLES FOR ELECTROPHORETIC DISPLAYS

Номер: US20130244035A1
Автор: Barthen Peter, Bartlett Paul, Beylage Ludger, Frank Walter, Garcia Rodrigo Sanchez, Goulding Mark John, Greinert Nils, Ignatyev Nikolai (Mykola), Kemp Roger, Smith Ashley Nathan, Uerdingen Marc, Wilson Jonathan Henry
Принадлежит:

This invention relates to polymer particles with surface functionality for charge retention, a process for their preparation, the use of these particles for the preparation of an electrophoretic device, electrophoretic displays comprising such particle, and new polymerisable dyes. 117-. (canceled)18. Polymer particles for use in electrophoretic devices comprising monomer units of [{'br': None, 'sup': +', '−, 'X—R—CA,'}, 'wherein', 'X is a polymerizable group,', 'R is a spacer group,', {'sup': '+', 'C is a cation, and'}, {'sup': '−', 'A is an anion;'}], 'a) at least one polymerizable ionic liquid'}b) at least one monomer,c) optionally at least one polymerizable dye, andd) optionally at least one crosslinking co-monomer.19. The polymer particles according to claim 18 , wherein X is a methacrylate claim 18 , acrylate claim 18 , methacrylamide claim 18 , acrylonitrile claim 18 , α-substituted acrylate claim 18 , styrene claim 18 , vinyl or substituted vinyl group.20. The polymer particles according to claim 18 , wherein X is a methacrylate or acrylate group.21. The polymer particles according to claim 18 , wherein R is an alkyl claim 18 , polyether or polydimethylsiloxane group.22. The polymer particles according to claim 18 , wherein C is a phosphonium claim 18 , sulfonium claim 18 , oxonium claim 18 , ammonium claim 18 , uronium claim 18 , thiouronium claim 18 , imidazolium claim 18 , pyridinium claim 18 , pyrrolidinium claim 18 , triazolium claim 18 , morpholinium or piperidinium cation.23. The polymer particles according to claim 18 , wherein C is an alkyl substituted ammonium claim 18 , imidazolium claim 18 , pyridinium or pyrrolidinium group.24. The polymer particles according to claim 20 , whereinR is an alkyl, polyether or polydimethylsiloxane group,{'sup': '+', 'C is an alkyl substituted ammonium, imidazolium, pyridinium or pyrrolidinium group and'}A- is tetrakis[3,5-bis(trifluoromethyl)phenyl]borate or (bis(2-2-ethyl hexyl) sulfosuccinate.25. The polymer ...

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Номер записи: 47
19-09-2013 дата публикации

SET-LRP POLYMERIZATION OF ACRYLATES IN THE PRESENCE OF ACIDS

Номер: US20130245216A1
Автор: Fitzwater Susan J., Fleischmann Sven, Percec Virgil, Van Dyk Antony K.
Принадлежит:

SET-LRP polymerization of acrylic monomers under acidic conditions is described. The source of the acidity may be the solvent (e.g., an acetic acid-containing solvent) or in the monomer content (e.g., acrylic acid or methacrylic acid, optionally in combination with other monomers such as methyl methacrylate). 2. A polymeric composition according to claim 1 , wherein the metal single-electron transfer catalyst contains copper claim 1 , and the component or combination of component and monomer is capable of disproportionating the metal catalyst Cu(I)X into Cu(0) and Cu(II)Xwhere X is Cl claim 1 , Br claim 1 , or I.3. A polymeric composition according to claim 2 , wherein the ligand comprises N-ligand groups.4. A polymeric composition according to claim 1 , wherein the ligand comprises N-ligand groups.6. A method according to claim 5 , wherein the metal single-electron transfer catalyst contains copper claim 5 , and the component or combination of component and monomer is capable of disproportionating the metal catalyst Cu(I)X into Cu(0) and Cu(II)Xwhere X is Cl claim 5 , Br claim 5 , or I.7. A method according to claim 6 , wherein the ligand comprises N-ligand groups.8. A method according to claim 5 , wherein the ligand comprises N-ligand groups. Living radical polymerization (“LRP”), also commonly referred to as controlled radical polymerization (“CRP”), has been reported in one form or another for some time. Unlike LRP, conventional free radical polymerization often proceeded at a relatively uncontrolled rate until the occurrence of a chain-terminating reaction or exhaustion of monomer reactant. Average molecular weight could be generally controlled by controlling a quantity of chain-terminating reactants; however, due to the difficulty of controlling precisely when the chain-terminating reaction might occur on any individual macroradical chain, conventional free radical polymerization could result in a wide range of polymer chain lengths in the population of ...

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Номер записи: 48
26-09-2013 дата публикации

CAPACITOR AND METHOD FOR MANUFACTURING THE SAME

Номер: US20130250475A1
Автор: Furusawa Akihiro, Kubouchi Tatsuo, Mori Masayuki
Принадлежит: NIPPON CHEMI-CON CORPORATION

A capacitor includes a capacitor element that is a wound element or an element other than the wound element, and that includes electrode bodies each of which is in an anode side and a cathode side, and separators that intervenes between the electrode bodies; a sealing member that seals an opening of a case member accommodating the capacitor element; at least one electrode protrusion that protrudes from one of the electrode bodies on an element end-face of the capacitor element, at least one of current collector plate that is connected to the electric protrusion; and at least one terminal member that is disposed in the sealing member, and is superposed on the current collector plate, a side face part of the terminal member being welded to a side face part of the current collector plate. 1. A capacitor comprising:a capacitor element that is a wound element or an element other than the wound element, and that includes electrode bodies each, of which is in an anode side and a cathode side, and separators that intervenes between the electrode bodies;a sealing member that seals an opening of a case member accommodating the capacitor element;at least one electrode protrusion that protrudes from one of the electrode bodies on an element end-face of the capacitor element,at least one of current collector plate that is connected to the electric protrusion; andat least one terminal member that is disposed in the sealing member, and is superposed on the current collector plate, a side face part of the terminal member being welded to a side face part of the current collector plate.2. The capacitor of claim 1 , whereinthe electrode protrusion is an aggregate that is formed by part of one electrode body, which is in the electrode bodies, and is bent toward an element center of the capacitor element to be molded on the element end-face, and is joined to the current collector plate.3. The capacitor of claim 1 , whereinthe electrode protrusion is an anode protrusion that protrudes ...

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Номер записи: 49
10-10-2013 дата публикации

Processes for Producing Acrylic Acids and Acrylates with Controlled Oxygen Concentration Across Reactor

Номер: US20130267737A1
Автор: Chapman Josefina T., Mueller Sean, Nagaki Dick, Peterson Craig J., Scates Mark O.
Принадлежит: Celanese International Corporation

In one embodiment, the invention is to a process for producing an acrylate product. The process comprises the step of producing a crude product stream by reacting reactants comprising an alkanoic acid, an alkylenating agent and oxygen in the presence of a catalyst, wherein the oxygen concentration across the reactor is from 0.5 to 10 wt %. The oxygen may be fed to the reactor through a plurality of feeds. The invention is also directed to methods of monitoring the oxygen concentration for the reaction and adjusting the oxygen concentration and/or placement of oxygen feed(s). The process further comprises the step of separating at least a portion of the crude product stream to form an alkylenating agent stream and an intermediate product stream. 1. A process for producing an acrylate product , the process comprising the steps of:(a) contacting in a reactor reactants comprising an alkanoic acid, an alkylenating agent and a plurality of oxygen feed streams over a catalyst under conditions effective to form a crude product stream comprising acrylate product and alkylenating agent; and(b) separating at least a portion of the crude product stream to form at least one alkylenating agent stream and at least one purified acrylate product stream comprising acrylate product;wherein oxygen concentration across the reactor ranges from 0.5 wt % to 10 wt %.2. The process of claim 1 , wherein the plurality of oxygen feeds is configured across a length of the reactor.3. The process of claim 1 , wherein the plurality of oxygen feeds comprises at least three oxygen feeds.4. The process of claim 1 , wherein the plurality of oxygen feeds is fed to the reactor separately from the alkanoic acid and alkylenating agent feed.5. The process of claim 1 , wherein the reactor has an inlet oxygen concentration and an outlet oxygen concentration and the outlet concentration is substantially similar to or greater than the inlet concentration.6. The process of claim 5 , wherein variance between the ...

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Номер записи: 50
17-10-2013 дата публикации

Poly(Acrylic Acid) From Bio-Based Acrylic Acid And Its Derivatives

Номер: US20130273384A1
Автор: Collias Dimitris Ioannis, Dziezok Peter, Godlewski Jane Ellen, Meyer Axel, Velasquez Juan Estaban, Villalobos Janette
Принадлежит: The Procter & Gamble Company

Bio-based glacial acrylic acid, produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof and having impurities of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof, is polymerized to poly(acrylic acid) or superabsorbent polymer using the same processes as petroleum-derived glacial acrylic acid. 1. A superabsorbent polymer composition produced from an acrylic composition , wherein said acrylic composition comprises an acrylic acid composition , wherein said acrylic acid composition consists of acrylic acid , acrylic acid derivatives , or mixtures thereof , wherein said acrylic acid composition comprises at least about 98 wt % acrylic acid , acrylic acid derivatives , or mixtures thereof , and wherein a portion of the remaining impurities in said acrylic acid composition is hydroxypropionic acid , hydroxypropionic acid derivatives , or mixtures thereof.2. The composition of claim 1 , wherein said hydroxypropionic acid claim 1 , hydroxypropionic acid derivatives claim 1 , or mixtures thereof is lactic acid claim 1 , lactic acid derivatives claim 1 , or mixtures thereof.3. The superabsorbent polymer composition of produced by the steps comprising: (i) said acrylic composition, and', '(ii) a solvent;', 'and wherein the pH of said pre-polymerization solution is less than about 6;, 'a. Preparing a pre-polymerization solution comprisingb. Combining an initiator with said pre-polymerization solution to produce a polymerization mixture;c. Polymerizing said polymerization mixture to produce a gel; andd. Drying said gel to produce the superabsorbent polymer composition.4. The composition of claim 3 , wherein the amount of said acrylic acid composition in said pre-polymerization solution is from about 5 wt % to about 95 wt %.5. The composition of claim 3 , wherein the amount of said initiator is from about 0.01% wt % to about 10 wt % claim 3 , based on the total amount of said acrylic acid composition in said pre- ...

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Номер записи: 51
24-10-2013 дата публикации

PROTEIN-BASED CONJUGATES AND SELF-ASSEMBLED NANOSTRUCTURES

Номер: US20130280782A1
Автор: Olsen Bradley D., Thomas Carla S.
Принадлежит: Massachusetts Institute of Technology

The present disclosure provides protein-containing compositions, methods and uses thereof. A conjugate comprises a globular protein conjugated with a polymer that preserves the folded and functional structure of a protein. In some embodiments, a fusion protein comprises a globular protein conjugated with an elastin-mimic polymer (EMP). Also disclosed is an assembled solid-state or gel-state nanostructure comprising a plurality of conjugates, wherein each comprises a globular protein conjugated with a polymer that preserving the folded and functional structure of a protein. In certain embodiments, provided compositions and methods further comprise an additive. 1. A conjugate comprising a globular protein conjugated with a polymer that preserves the folded and functional structure of a protein.2. The conjugate of claim 1 , wherein the globular protein is covalently attached to the polymer.3. The conjugate of claim 1 , wherein the globular protein is non-covalently attached to the polymer.4. (canceled)5. (canceled)6. The conjugate of claim 1 , wherein the globular protein is selected from the group consisting of mCherry claim 1 , a green fluorescent protein claim 1 , lysozyme claim 1 , albumin claim 1 , and carbonic anhydrase.7. The conjugate of claim 1 , wherein the weight percentage of the globular protein is greater than 20%.8. The conjugate claim 1 , wherein the weight percentage of the globular protein is in a range of 20% to 85%.9. The conjugate of wherein the molecular weight of the globular protein is greater than 10 kDa.10. (canceled)11. The conjugate of claim 1 , wherein the polymer has a transition temperature greater than 0° C.12. The conjugate of claim 1 , wherein the polymer has a transition temperature less than 80° C.13. The conjugate of claim 1 , wherein the polymer has a transition temperature in a range of 25° C. to 70° C.14. The conjugate of claim 1 , wherein the polymer has a molecular weight greater than 5 kDa.15. The conjugate of claim 1 , ...

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Номер записи: 52
24-10-2013 дата публикации

Fully Backbone Degradable and Functionalizable Polymers Derived from the Ring-Opening Metathesis Polymerization (ROMP)

Номер: US20130281644A1
Автор: Fishman Joshua, KIESSLING Laura L., Prost Lynne
Принадлежит: WISCONSIN ALUMNI RESEARCH FOUNDATION

Functionalized degradable ROMP (ring-opening metathesis) polymers and methods, starting monomers and synthetic monomeric and polymeric intermediates for preparation of such functionalized polymers. More specifically, monomers having a bicyclic oxazinone structure, a bicyclic urea, or a heteronorbornene core structure, among others, have been found to be substrates for ROMP polymerization. ROMP polymers prepared from these monomers have been found to be both acid and base labile. Additionally, the monomers can be chemically modified at a site distal to the polymerizable moieties and bridgehead carbons. The properties of the resulting polymers and copolymers can be tailored without destabiling the monomer. Polymers and copolymers of the invention are degradable but have a glass temperature of 100° C. or more. 2. The method of wherein FG is selected from a halogen claim 1 , a silyl group claim 1 , a silyl ether claim 1 , a sulfonate claim 1 , an amine claim 1 , —N claim 1 , an azide claim 1 , a tosyl group claim 1 , an aryl claim 1 , an alkynyl claim 1 , an alkenyl claim 1 , an arylalkyl claim 1 , an alkylaryl claim 1 , a triazolyl claim 1 , an epoxide group claim 1 , —OH claim 1 , —COOH claim 1 , an activated ester group claim 1 , a thioester group claim 1 , a phosphinothioester group claim 1 , an acid halide group claim 1 , a malemide group claim 1 , HS— claim 1 , an acyl azide group claim 1 , a hydroxylamine group claim 1 , an aldehyde or ketone group claim 1 , a urea group claim 1 , a disulfide claim 1 , a diol group claim 1 , a dithiol claim 1 , —CO—CH═CH claim 1 , —NH—CO—CH═CH claim 1 , a hydrazine claim 1 , a hydrazone claim 1 , an acyl sulfonamide claim 1 , a boronic acid claim 1 , cyano claim 1 , isocyanide claim 1 , isocyanate claim 1 , isothiocyanate claim 1 , phosphoric acid esters (mono- claim 1 , di- claim 1 , and tri-esters) claim 1 , a phosphite claim 1 , a phosphine claim 1 , a claim 1 , phosphoranes claim 1 , an iminophosphorane claim 1 , a ...

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Номер записи: 53
31-10-2013 дата публикации

POLYPROPYLENE FILM FOR CAPACITOR

Номер: US20130288000A1
Автор: Ishiwata Tadakazu, Matsuo Yoshinori, Shishido Yuichi
Принадлежит: OJI HOLDINGS CORPORATION

A biaxially-oriented polypropylene film for an ultra-thin capacitor that has superior heat resistance, withstand voltage performance and long-term durability. The film has a stereoregularity in which mesopentad fraction (mmmm) as determined by measurement of high temperature nuclear magnetic resonance (high temperature NMR) is between 94% and 98%, a weight average molecular weight (Mw) of 250,000 to 450,000, a molecular weight distribution (Mw/Mn) of 4 to 7, and on a molecular weight distribution curve, a difference determined by subtracting the differential distribution value when the logarithm of molecular weight Log(M)=6 from the differential distribution value when Log(M)=4.5 that is 9% to 15%. The film is fabricated using a polypropylene raw material resin in which the composition of the aforementioned molecular weight distribution has been adjusted by peroxidative decomposition treatment of a polypropylene resin. 1. A biaxially-oriented polypropylene film for a capacitor , wherein , together with having stereoregularity in which mesopentad fraction (mmmm) as determined by measurement of high temperature nuclear magnetic resonance (high temperature NMR) is 94% or more to less than 98% , weight average molecular weight (Mw) as measured by gel permeation chromatography (GPC) is 250 ,000 to 450 ,000 , molecular weight distribution (Mw/Mn) is 4 to 7 , and on a molecular weight distribution curve , the difference determined by subtracting the differential distribution value when the logarithm of molecular weight Log(M)=6 from the differential distribution value when the logarithm of molecular weight Log(M)=4.5 is 9% to 15%; and , uses a polypropylene raw material resin in which the composition of the molecular weight distribution has been adjusted by peroxidative decomposition treatment of a polypropylene resin.2. The biaxially-oriented polypropylene film for a capacitor according to claim 1 , wherein the biaxially-oriented polypropylene film contains at least one ...

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Номер записи: 54
07-11-2013 дата публикации

REACTOR OPERABILITY IN A GAS PHASE POLYMERIZATION PROCESS

Номер: US20130296507A1
Автор: Hoang Peter Phung Minh, Mak Andy, Shaw Benjamin Milton
Принадлежит: NOVA CHEMICALS (INTERNATIONAL) S.A.,

Olefin polymerization is carried out with a single site polymerization catalyst in the presence of a continuity additive. The continuity additive is a cocktail containing one or more dialkanolamide derived from a fatty acid, an oil soluble sulfonic acid and a dialkanolamine. 1. A process for polymerizing ethylene and optionally an alpha olefin in a reactor with at least one single site polymerization catalyst in the presence of a continuity additive , said continuity additive comprising:i) a fatty acid dialkanolamide,ii) an oil soluble sulfonic acid, andiii) a dialkanolamine.2. The process of wherein the continuity additive comprises:{'sup': 1', '1, 'sub': 2', '2', '2, 'i) at least one fatty acid diethanolamide having the formula RC(═O)N(CHCHOH)where Ris a hydrocarbyl group having from 5 to 30 carbon atoms,'}{'sup': 3', '3, 'sub': 6', '4', '3, 'ii) a benzene sulfonic acid having the formula RCHSOH, where Ris a hydrocarbyl group having from 6 to 30 carbon atoms, and'}{'sub': 2', 'x', '2, 'iii) a dialkanolamine having the formula HN((CH)OH)where x is independently an integer from 1 to 8.'}3. The process of wherein the continuity additive comprises:{'sup': 1', '1, 'sub': 2', '2', '2, 'i) a mixture of two or more different fatty acid diethanolamides having the formula RC(═O)N(CHCHOH), where Ris a hydrocarbyl group having anywhere from 5 to 30 carbon atoms,'}{'sup': 3', '3, 'sub': 6', '4', '3, 'ii) a benzene sulfonic acid having the formula RCHSOH, where Ris a hydrocarbyl group having 6 to 22 carbon atoms, and'}{'sub': 2', 'x', '2, 'iii) a dialkanolamine having the formula HN((CH)OH), where x is 2 or 3.'}4. The process of wherein the mixture of two or more different fatty acid diethanolamides comprises compounds having the formula R(C═O)N(CHCHOH)where Ris a hydrocarbyl group with 5 claim 3 , 7 claim 3 , 9 claim 3 , 11 claim 3 , 13 claim 3 , 15 claim 3 , or 17 carbon atoms and wherein diethanolamide compounds having hydrocarbyl groups with 5 claim 3 , 7 claim 3 , 9 claim ...

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Номер записи: 55
14-11-2013 дата публикации

BOPP FILM WITH HIGH AC BREAKDOWN STRENGTH

Номер: US20130303684A1
Автор: Fiebig Joachim, Gloger Dietrich, Grein Christelle, Klimke Katja, Persson Robert
Принадлежит: Borealis AG

Polypropylene composition comprising a polypropylene and an α-nucleating agent, wherein the polypropylene composition has •a comonomer content of equal or below 1.0 wt.-%, •<2,1> erythro regiodefects of more than 0.1 mol.-%, and •at least 9.0 wt-% of a crystalline fraction crystallizing in the temperature range of above 160 to 170° C., wherein said fraction is determined by the stepwise isothermal segregation technique (SIST). 1. Polypropylene composition (PP-C) comprising:(i) at least 70 wt. % of a polypropylene (PP) and(ii) 0.005 to 1.5 wt. % of an α-nucleating agent (N) based on the polypropylene composition (PP-C), wherein the polypropylene composition (PP-C) and/or the polypropylene (PP) has/have{'sub': 4', '20, '(a) a comonomer content of equal or below 1.0 wt. %, the comonomers are ethylene and/or at least one Cto Cα-olefin, and'}{'sup': '13', '(b) <2,1> erythro regiodefects of more than 0.1 mol.% determined by C-spectroscopy,'}and wherein further(c) the polypropylene composition (PP-C) and/or the polypropylene (PP) has/have a pentad isotacticity of at least 98 mol.%, and/or(d) the polypropylene composition (PP-C) comprises at least 9.0 wt % of a crystalline fraction crystallizing in the temperature range of above 160 to 170° C., wherein said fraction is determined by the stepwise isothermal segregation technique (SIST).2. Polypropylene composition (PP-C) according to claim 1 , wherein the polypropylene (PP) is the only polymer within the polypropylene composition (PP-C).3. Polypropylene composition (PP-C) according to claim 1 , wherein:(a) the polypropylene composition (PP-C) comprises crystalline fractions crystallizing in the temperature range of:(i) above 140 to 150° C.(ii) above 150 to 160° C.(iii) above 160 to 170° C.wherein the amount of the three crystalline fractions [wt. %] differ from each other of not more than 5.0 wt. %,and/or(b) the amount of the crystalline fraction of the polypropylene composition (PP-C) crystallizing in the temperature ...

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Номер записи: 56
14-11-2013 дата публикации

PROCESS FOR THE PRODUCTION OF METHACRYLIC ACID AND ITS DERIVATIVES AND POLYMERS PRODUCED THEREFROM

Номер: US20130303713A1
Автор: Eastham Graham Ronald, Huddle Thomas Andrew, Johnson David William, Poliakoff Martyn
Принадлежит: LUCITE INTERNATIONAL UK LIMITED

A process for the production of methacrylic acid is described. The process comprises the base catalysed decarboxylation of at least one or a mixture of dicarboxylic acids selected from itaconic, citraconic or mesaconic acid. The decarboxylation is carried out in the range greater than 240 and up to 275° C. to provide high selectivity. The methacrylic acid product may be esterified to produce an ester. A method of preparing polymers or copolymers of methacrylic acid or methacrylic acid esters using the process is also described. Optionally, the process may be preceded with a decarboxylation and, if necessary, a dehydration step on a source of pre-acid such as citric acid or isocitric acid. 1. A process for the production of methacrylic acid by the base catalysed decarboxylation of at least one dicarboxylic acid selected from itaconic , citraconic or mesaconic acid or mixtures thereof , wherein the decarboxylation is carried out at greater than 240 and up to 275° C.2. A process according to claim 1 , wherein the decarboxylation is in the temperature range between 245 and up to 275° C.3. A process according to claim 1 , wherein the dicarboxylic acid reactants and preferably the base catalyst are in aqueous solution.4. A process according to claim 1 , wherein the decarboxylation reaction is carried out at suitable pressures in excess of atmospheric pressure.5. A process according to claim 1 , wherein the base catalyst comprises a metal oxide claim 1 , hydroxide claim 1 , carbonate claim 1 , acetate (ethanoate) claim 1 , alkoxide claim 1 , hydrogencarbonate or salt of a decomposable di- or tri-carboxylic acid claim 1 , or a quaternary ammonium compound of one of the above claim 1 , or one or more amines.6. A process according to claim 1 , wherein the base catalyst is selected from one or more of the following: LiOH claim 1 , NaOH claim 1 , KOH claim 1 , Mg(OH) claim 1 , Ca(OH) claim 1 , Ba(OH) claim 1 , CsOH claim 1 , Sr(OH) claim 1 , RbOH claim 1 , NHOH claim 1 , LiCO ...

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Номер записи: 57
21-11-2013 дата публикации

RESIST COMPOSITION, PATTERNING PROCESS, MONOMER, AND COPOLYMER

Номер: US20130309606A1
Автор: Hatakeyama Jun, Sagehashi Masayoshi
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

A polymer is obtained from copolymerization of a recurring unit having a carboxyl and/or phenolic hydroxyl group substituted with an acid labile group and a recurring unit having formula (1) wherein Ris methyl, ethyl, propyl, methoxy, ethoxy or propoxy, Ris H or CH, and m is 1 to 4. The polymer is used as a base resin to formulate a resist composition, which is improved in contrast of alkali dissolution rate before and after exposure, acid diffusion control, resolution, and profile and edge roughness of a pattern after exposure. 3. The resist composition of wherein in addition to the recurring units (a) and acid labile group-substituted recurring units (b1) and/or (b2) claim 2 , as represented by the general formula (2) claim 2 , the polymer further comprises recurring units (c) having an adhesive group selected from the class consisting of hydroxyl (exclusive of hydroxyl in formula (1)) claim 2 , carboxyl claim 2 , lactone ring claim 2 , carbonate claim 2 , thiocarbonate claim 2 , carbonyl claim 2 , cyclic acetal claim 2 , ether claim 2 , ester claim 2 , sulfonic acid ester claim 2 , cyano claim 2 , amide claim 2 , and —O—C(═O)-G- wherein G is sulfur or NH and c is a number in the range: 0 Подробнее

Номер записи: 58
12-12-2013 дата публикации

MOLECULARLY IMPRINTED POLYMERS HAVING AFFINITY FOR NATRIURETIC PEPTIDES

Номер: US20130330384A1
Автор: Mohapatra Subhra, Wang Chunyan
Принадлежит: UNIVERSITY OF SOUTH FLORIDA

The present invention concerns molecularly imprinted polymers (MIPs) having an affinity for natriuretic peptides, such as atrial natriuretic peptide (ANP). In some embodiments, the MIP is a nanoparticle (a molecularly imprinted polymeric nanoparticle (MIPNP)). Other aspects of the invention include methods of preparing an MIP having affinity for a natriuretic peptide, methods for binding a natriuretic peptide in vitro or in vivo using an MIP of the invention, methods for interfering with the binding of a natriuretic peptide with its receptor in vivo, methods for reducing inflammation, cell growth, cell differentiation, or a cell proliferation disorder, methods for detecting natriuretic peptides, and devices and kits for sequestering and/or detecting natriuretic peptides. 1. A composition of matter , comprising:(a) a molecularly imprinted polymer (MIP) having affinity for a natriuretic peptide or a fragment thereof; or(b) a pharmaceutical composition comprising an MIP of (a), and a pharmaceutically acceptable carrier; or(c) a device for sequestering or detecting natriuretic peptides, comprising a substrate with an MIP of (a) attached thereto; or(d) a kit for sequestration and/or detection of one or more natriuretic peptides, comprising, in one or more separate containers, one or more MIPs of (a).2. The composition of claim 1 , wherein the composition is (a) claim 1 , and wherein the MIP is a nanoparticle.3. The composition of claim 1 , wherein the composition is (a) claim 1 , and wherein the natriuretic peptide is atrial natriuretic peptide (ANP (SEQ ID NO:3)).4. The composition of claim 1 , wherein the composition is (a) claim 1 , and wherein the natriuretic peptide is selected from among atrial natriuretic peptide (ANP (SEQ ID NO:3); amino acids 99-126 of pro-ANP) claim 1 , long-acting natriuretic peptide (LANP (SEQ ID NO:7); amino acids 1-30 of pro-ANP) claim 1 , vessel dilator (VD (SEQ ID NO:8); amino acids 31-67 of pro-ANP) claim 1 , kaliuretic peptide (KP (SEQ ...

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Номер записи: 59
19-12-2013 дата публикации

FLAME-RETARDANT RESIN COMPOSITION

Номер: US20130334477A1
Автор: Taketani Shuji, Yamamoto Tetsuro
Принадлежит: KANEKA CORPORATION

Contained in a thermoplastic resin (A) are a flame retardant (B) including a reaction product of a specific nitrogen-containing compound (such as triallyl isocyanurate) and a specific phosphorus-containing compound (such as 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide), is insoluble in toluene and contains the phosphorus atoms in 5.0 to 10.0% by weight; and at least one kind of a component (C) selected from the group consisting of a flame-retardant promoter (Cx), an impact modifier (Cy), and a layered compound (Cz). 2. The flame-retardant resin composition according to claim 1 , wherein the flame retardant (B) has a weight average molecular weight (M) of 2 claim 1 ,000 to 10 claim 1 ,000.4. The flame-retardant resin composition according to claim 1 , wherein the flame retardant (B) includes a cross-linked component claim 1 , the cross-linked component being contained in a proportion of 1% by weight or more of the total amount of the flame retardant (B).5. The flame-retardant resin composition according to claim 4 , wherein the cross-linked component is a component which is insoluble in chloroform.7. The flame-retardant resin composition according to claim 1 , wherein the thermoplastic resin (A) is at least one resin selected from the group consisting of a polyester resin claim 1 , a polyamide resin claim 1 , a polycarbonate resin claim 1 , and a modified polyphenylene oxide resin claim 1 , and the component (C) is the flame retardant promoter (CO.8. The flame-retardant resin composition according claim 1 , wherein the flame retardant promoter (C) is at least one compound selected from the group consisting of a nitrogen-containing compound claim 1 , a metal hydroxide claim 1 , a metal oxide claim 1 , a boron compound claim 1 , a tin compound claim 1 , and a zinc compound.9. The flame-retardant resin composition according to claim 1 , wherein the thermoplastic resin (A) is a thermoplastic polyamide resin having a melting point of 240° C. or higher claim 1 , and ...

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Номер записи: 60
19-12-2013 дата публикации

Control of Resin Molecular Weight Distribution Using Mixed Catalyst Systems

Номер: US20130338320A1
Автор: Jorgensen Robert J.
Принадлежит: Union Carbide Chemicals & Plastics Technology LLC

A polymerization process including the use of a first Ziegler-Natta type procatalyst having no internal electron donor and a second Ziegler-Natta type procatalyst including an internal electron donor is provided. 2. (canceled)3. The process according to claim 1 , wherein the first and second Ziegler-Natta type procatalysts are mixed to form a mixed procatalyst feed prior to being fed into the reactor.4. The process according to claim 1 , wherein the first and second Ziegler-Natta type procatalysts are separately fed into the reactor.5. The process according to claim 1 , wherein a feed of the first Ziegler-Natta type procatalyst is decreased as a feed of the second Ziegler-Natta type procatalyst is increased.6. The process of wherein the mixed procatalyst feed comprises between 0.8 and 2.1 wt % of the second Ziegler-Natta type procatalyst and between 99.2 and 97.9 wt % of the first Ziegler-Natta type procatalyst based on the total weight of the first and second Zielger-Natta procatalysts.7. The process according to claim 1 , wherein no electron donor is added to the reactor.8. The process according to claim 1 , further comprising adding a continuity additive to the reactor.9. The process of wherein the relative weight percentages of the first and second Ziegler-Natta type procatalysts produce a variation in the molecular weight of the polyolefin polymer.10. The process of wherein the relative weight percentages of the first and second Ziegler-Natta type procatalysts produce a variation in the molecular weight distribution of the polyolefin polymer.11. The process of wherein the one or more olefins comprises ethylene and further wherein a partial pressure of the ethylene is varied to maintain a constant rate of production of polyolefin.12. The process according to claim 1 , the second Ziegler-Natta type procatalyst has a second order productivity response to ethylene concentration.13. The process according to claim 1 , wherein the polymerization is a slurry reactor or ...

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Номер записи: 61
19-12-2013 дата публикации

PROCESS FOR POLYMERIZATION OF A DIENE

Номер: US20130338324A1
Автор: Beierlein Christine, Berlineanu Andreas, Denkinger Peter, Gruenfelder Thomas, Haberkorn Niko, Haneke Martin, Hellwig Juergen, Korell Michael, Oldenkott Michael, Pospiech Juergen, RICHTER NORBERT
Принадлежит: Evonik Industries AG

A process for polymerization of a diene is provided. The process comprises: a) reacting the diene with hydrogen peroxide in a hydrophilic organic solvent in the presence of water to obtain a polymerization reaction mixture; b) contacting the polymerization reaction mixture with water having a temperature of from 20 to 80° C. to form a mixture having an organic phase and an aqueous phase; c) removing unreacted gaseous diene from the water mixture obtained in b); d) separating the aqueous phase comprising the hydrophilic solvent from the organic phase of the water mixture; and e) distilling volatile materials from the separated organic phase from d) to obtain the polymerization product; wherein a temperature of the reaction a) is from 50-150° C., a pressure of the reaction a) is from 0 to 50 bar, the unreacted gaseous diene removed in c) is condensed, distilled and the distillate obtained reacted according to a), and the hydrophilic solvent is recovered from the separated aqueous phase and reused according to a). Also provided is an apparatus for conducting the process of the invention. 1. A process for polymerization of a diene , the process comprising:a) reacting the diene with hydrogen peroxide in a hydrophilic organic solvent in the presence of water to obtain a polymerization reaction mixture;b) contacting the polymerization reaction mixture with water having a temperature of from 20 to 80° C. to form a mixture having an organic phase and an aqueous phase;c) removing unreacted gaseous diene from the water mixture obtained in b);d) separating the aqueous phase comprising the hydrophilic solvent from the organic phase of the water mixture; ande) distilling volatile materials from the separated organic phase from d) to obtain the polymerization product;whereina temperature of the reaction a) is from 50-150° C.,a pressure of the reaction a) is from 0 to 50 bar,the unreacted gaseous diene removed in c) is condensed, distilled and the distillate obtained reacted ...

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Номер записи: 62
26-12-2013 дата публикации

Process for Recycling Solvent Used in an Ethylene-Based Polymerization Reaction and System Therefor

Номер: US20130341567A1
Автор: Castelluccio Anthony J., Gemoets Frederik E., Hyde Stacey
Принадлежит: Dow Global Technologies LLC

A process for recycling solvent used in an ethylene-based polymerization comprising: passing a solvent stream which has been used in a first ethylene-based solvent polymerization reactor through an online purification bed to produce a recycle solvent stream, wherein the solvent stream prior to being passed through the online purification bed comprises solvent, ethylene, hydrogen, polymerization by-products and optionally comonomer; and passing the recycle solvent stream from the online purification bed to a second ethylene-based solvent polymerization reactor; wherein the second ethylene-based solvent polymerization reactor exhibits a catalyst efficiency dip of less than or equal to 20% for no longer than a forty-eight hour period following a swap of the online purification bed to a regenerated purification bed which contains an adsorbent having low reactivity to alkenes is provided. 1. A process for recycling solvent used in an ethylene-based polymerization comprising: 'wherein the solvent stream prior to being passed through the online purification bed comprises solvent, ethylene, hydrogen, polymerization by-products and optionally comonomer; and', 'passing a solvent stream which has been used in a first ethylene-based solvent polymerization reactor through an online purification bed to produce a recycle solvent stream,'} 'wherein the second ethylene-based solvent polymerization reactor exhibits a catalyst efficiency dip of less than or equal to 20% for no longer than a forty-eight hour period following a swap of the online purification bed to a regenerated purification bed which contains an adsorbent which, upon exposure to a chlorooctane and ethylene produces less than or equal to 650 mg ethylene dimer/(kg adsorbent*h).', 'passing the recycle solvent stream from the online purification bed to a second ethylene-based solvent polymerization reactor;'}2. The process according to claim 1 , wherein the first and second ethylene-based solvent polymerization reactors ...

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Номер записи: 63
26-12-2013 дата публикации

HIGH-CONCENTRATION POLYMER POLYOL AND METHOD FOR ITS PRODUCTION

Номер: US20130345331A1
Автор: Harada Kensuke, Hayashi Tomohiro, Horie Akio, ITO Takashi, Sasaki Takayuki, Suzuki Chitoshi
Принадлежит: Asahi Glass Company, Limited

If it is attempted to produce a polymer polyol at a high concentration, there will be a problem such that during polymerization of a monomer to form fine polymer particles, particles are likely to aggregate one another to form aggregates, and storage stability of the polymer polyol tends to deteriorate. A method for producing a polymer polyol is presented which comprises polymerizing at least one type of ethylenically unsaturated monomer together with a seed particle dispersion, in a polyol, wherein the seed particle dispersion is one obtained by polymerizing an ethylenically unsaturated monomer in the presence of an ethylenically unsaturated macromonomer, a solvent and a chain transfer agent, and the ethylenically unsaturated macromonomer is a reaction product of a specific polyol, an isocyanate compound and an ethylenically unsaturated monomer having a hydroxy group. 1. A method for producing a polymer polyol , which comprises polymerizing at least one type of ethylenically unsaturated monomer (M1) together with a seed particle dispersion (E) , in a polyol (A) , wherein the seed particle dispersion (E) is a dispersion obtained by polymerizing an ethylenically unsaturated monomer (M2) in the presence of an ethylenically unsaturated macromonomer (B) , a solvent (C) and a chain transfer agent (D) , and the ethylenically unsaturated macromonomer (B) is a reaction product of a polyol (b1) having a hydroxy value of from 20 to 50 mgKOH/g and an oxyethylene group-content of at least 10 mass % and less than 30 mass % , an isocyanate compound (b2) and an ethylenically unsaturated monomer (b3) having a hydroxy group.2. The method for producing a polymer polyol according to claim 1 , wherein the polyol (b1) a bifunctional polyoxyalkylenediol.3. The method for producing a polymer polyol according to claim 1 , wherein the average number of hydroxy groups per one molecule of the ethylenically unsaturated macromonomer (B) is 1.4. The method for producing a polymer polyol ...

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Номер записи: 64
16-01-2014 дата публикации

Nucleation in Aqueous Polymerization of Fluoromonomer

Номер: US20140018499A1
Автор: BROTHERS PAUL DOUGLAS, Gangal Subhash Vishnu, Khasnis Dipti Dilip
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

A process is provided for polymerizing fluoromonomer in an aqueous medium, wherein a dispersion of essentially surfactant-free hydrocarbon-containing oleophilic nucleation sites is first formed in the aqueous medium, and then polymerization is commenced to form a dispersion of fluoropolymer particles at the oleophilic nucleation sites, wherein the nucleation sites can be derived from hydrocarbon-containing compound. The surfactant used to stabilize the fluoropolymer dispersion can also be hydrocarbon-containing. 1. Process for polymerizing fluoromonomer in an aqueous medium in a polymerization reactor , comprising forming a dispersion of hydrocarbon-containing oleophilic nucleation sites in said medium , said dispersion being essentially free of surfactant and thereafter kicking off said polymerizing of said fluoromonomer to form a dispersion of fluoropolymer particles at said oleophilic nucleation sites.2. Process of wherein said nucleation sites are the product of degrading a water-soluble hydrocarbon-containing compound that contains hydrophobic moiety claim 1 , whereby said nucleation sites are hydrocarbon containing.3. The process of wherein said hydrocarbon-containing compound is a surfactant which contains hydrophilic moiety and said hydrophobic moiety claim 2 , said degrading being effective to enable said compound to enable said hydrophobic moiety to provide said oleophilic nucleation sites.4. The process of wherein said hydrocarbon-containing compound is present in said aqueous medium in an amount no greater than 50 ppm.5. The process of wherein at the time of said degrading claim 2 , water-soluble inorganic salt is also present in said aqueous medium to aid in the formation of said dispersion of hydrocarbon-containing oleophilic nucleation sites.6. The process of wherein that amount of said salt in said aqueous medium is no greater than 125 ppm and the amount of hydrocarbon-containing compound in said aqueous medium is no greater than 50 ppm.7. The ...

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Номер записи: 65
30-01-2014 дата публикации

ETHYLENE-BASED POLYMER, MANUFACTURING METHOD OF ETHYLENE-BASED POLYMER AND MANUFACTURING METHOD OF CATALYST FOR POLYMERIZATION, AND MOLDED ARTICLE OF HOLLOW PLASTICS CONTAINING ETHYLENE-BASED POLYMER AND USE THEREOF

Номер: US20140030460A1
Автор: Kanazawa Satoshi, Kuzuba Yuuichi, Monoi Takashi, Ogawa Kouichi
Принадлежит: JAPAN POLYETHYLENE CORPORATION

An object of the invention is to provide an ethylene-based polymer excellent in moldability and durability, and also excellent in the balance of stiffness and durability, and to provide a molded product of hollow plastic using the ethylene-based polymer. The ethylene-based polymer according to the invention is an ethylene-based polymer having specific characteristics and manufactured by a homopolymerization of ethylene or a copolymerization of ethylene and α-olefin using a chromium catalyst. 1. An ethylene-based polymer which is manufactured by a homopolymerization of ethylene or a copolymerization of ethylene and α-olefin by using a chromium catalyst , and has the following characteristics of (1) to (8):(1) the high load melt flow rate (HLMFR) is 1 to 10 g/10 min,{'sup': '3', '(2) the density is 0.940 to 0.960 g/cm,'}(3) the molecular weight distribution (Mw/Mn) is 25 or more,(4) the strain hardening parameter of elongation viscosity (λmax) is 1.05 to 1.50,{'sup': '2', '(5) the Charpy impact strength is 7 kJ/mor more,'}{'sup': '2', '(6) the tensile impact strength is 130 kJ/mor more,'}(7) the swell ratio (SR) is 50 to 65%, and(8) the rupture time in the full notch creep test is 40 hours or more.2. The ethylene-based polymer as claimed in claim 1 , wherein the chromium catalyst is a catalyst obtained by having a chromium compound (b) supported on an inorganic oxide support (a) having a specific surface area of 625 to 1 claim 1 ,000 m/g and a pore volume of 1.0 to 5.0 cm/g claim 1 , and drying and calcining the obtained inorganic oxide support (a) in a non-reducing atmosphere.3. The ethylene-based polymer as claimed in claim 1 , which is a copolymer of ethylene and α-olefin having 3 to 8 carbon atoms.4. A method for manufacturing an ethylene-based polymer comprising homopolymerizing ethylene or copolymerizing ethylene and α-olefin using a catalyst claim 1 , in which the catalyst is obtained by activating a catalyst precursor (d) at 250° C. to 550° C. in a non- ...

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Номер записи: 66
30-01-2014 дата публикации

METHOD FOR PRODUCING POLYACRYLIC ACID (SALT)-BASED WATER ABSORBENT RESIN POWDER

Номер: US20140031473A1
Автор: HONDA Koji, Ishizaki Kunihiko, Kimura Kazuki, Machida Sayaka, Matsumoto Satoshi, Nakamura Masatoshi, Nakatsuru Reiko, Nogi Kozo, Shibata Hirofumi, Watanabe Yusuke
Принадлежит: NIPPON SHOKUBAI CO., LTD.

From a viewpoint of reduction in an out of spec product after surface crosslinking, particularly, when an alkylene carbonate compound is used as a surface crosslinking agent, influence by an air temperature is great, and it is necessary to reduce ethylene glycol which is produced as a byproduct, and there is provided a process for producing a polyacrylic acid (salt)-based water absorbent resin powder, comprising 138-. (canceled)39. A method for producing a polyacrylic acid (salt)-based water absorbent resin powder , comprisinga step of polymerizing an aqueous acrylic acid (salt)-based monomer solution,a step of drying the resulting polymer,an optional pulverization and•classification step, anda surface crosslinking step,wherein in the surface crosslinking step,(1) a surface crosslinking agent comprising an alkylene carbonate compound and a polyhydric alcohol compound is mixed into a water absorbent resin powder, the mixture is heat-reacted and, further, simultaneously with, or separately from the mixing, an ion reactive surface crosslinking agent is mixed, and/or(2) mixing treatment of mixing a surface crosslinking agent solution into a water absorbent resin powder containing at least one or more kinds of ion reactive surface crosslinking agents is performed two or more times.40. The method according to claim 39 , wherein an internal gas bubble ratio of a water absorbent resin powder before a surface crosslinking step is 0.5% or more.41. The method according to claim 39 , wherein an aqueous surface crosslinking agent solution comprising at least an alkylene carbonate compound claim 39 , a polyhydric alcohol compound and water is prepared by heating the alkylene carbonate compound or the polyhydric alcohol compound in advance and claim 39 , thereafter claim 39 , mixing the alkylene carbonate compound or the polyhydric alcohol compound with water claim 39 , and the aqueous surface crosslinking agent solution is mixed into the water absorbent resin powder.42. The ...

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Номер записи: 67
13-02-2014 дата публикации

Reactive resins for cable sealing compounds

Номер: US20140045993A1
Автор: Gerold Schmitt, Joachim Knebel, Mario Gomez Andreu, Martina Ebert, Sabine Koemmelt, Thorben Schuetz, Volker Herzog
Принадлежит: Evonik Roehm GmbH

The invention describes a composition, especially in the form of a 2-component system comprising (meth)acrylated polyether polyols and/or polyester polyols and/or (meth)acrylated hydroxy-functionalized triglycerides with an adjustable pot life, especially for cable potting compounds.

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Номер записи: 68
13-02-2014 дата публикации

RESIN COMPOSITION FOR OPTICAL FILM AND OPTICAL FILM USING THE SAME

Номер: US20140046016A1
Автор: CHOI Eun-Jung, Han Chang-Hun, Kang Byoung-II, KIM Beom-Seok, KIM Joon-Sik, Kim Su-Kyung, Lee Dae-Woo, Lee Nam-Jeong, Seo Jae-Bum, Sung Da-Eun
Принадлежит: LG CHEM, LTD.

The present invention relates to a resin composition for an optical film comprising a copolymer which includes an alkyl (meth)acrylate unit, a (meth)acrylate unit having a benzene ring, and a (meth)acrylic acid unit, wherein a content of a residual monomer is less than 2000 ppm in the resin composition and an optical film using the same. 1. A resin composition for an optical film comprising a copolymer ,the copolymer including:an alkyl (meth)acrylate unit;a (meth)acrylate unit having a benzene ring; anda (meth)acrylic acid unit,wherein a content of a residual monomer in the resin composition is 2000 ppm or less.3. The resin composition of claim 1 , wherein a content ratio among the alkyl (meth)acrylate unit claim 1 , the (meth)acrylate unit having the benzene ring claim 1 , and the (meth)acrylic acid in the copolymer is 70 to 95:2 to 10:3 to 20 by weight ratio.4. The resin composition of claim 2 , wherein a content ratio among the alky (meth)acrylate unit claim 2 , the (meth)acrylate unit having the benzene ring claim 2 , the (meth)acrylic acid claim 2 , and the unit represented by Chemical Formula 1 in the copolymer is 60 to 90:2 to 10:3 to 10:5 to 20 by weight ratio.5. The resin composition of claim 1 , wherein an alkyl group of the alkyl (meth)acrylate has 1 to 10 carbon atoms.6. The resin composition of claim 5 , wherein the alkyl (meth)acrylate unit is methyl methacrylate.7. The resin composition of claim 1 , wherein the alkyl (meth)acrylate unit is one or more species selected from the group consisting of benzyl methacrylate claim 1 , benzyl acrylate claim 1 , 1-phenylethyl methacrylate claim 1 , 2-phenoxyethyl methacrylate claim 1 , 2-phenylethyl methacrylate claim 1 , 3-phenylpropyl methacrylate claim 1 , 3-phenylpropyl acrylate claim 1 , and 2-phenoxyethyl acrylate.8. The resin composition of claim 1 , wherein the (meth)acrylic acid is selected from the group consisting of acrylic acid claim 1 , methacrylic acid claim 1 , methylacrylic acid claim 1 , ...

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Номер записи: 69
20-02-2014 дата публикации

RESIN MATERIAL

Номер: US20140051811A1
Автор: ANAZAWA Kazunori, MIYAHARA Tomoko, SAEGUSA Hiroshi, TORIKOSHI Kaoru, YOSHIZAWA Hisae
Принадлежит: FUJI XEROX CO., LTD.

A resin material contains a polymer of a composition containing an isocyanate and an acrylic resin having OH-group-containing side chains in which a proportion of OH-group-containing side chains each having 6 or more carbon atoms relative to all of the OH-group-containing side chains is about 76 mol % or more and about 100 mol % or less. 1. A resin material comprising a polymer of a composition containing an isocyanate and an acrylic resin having OH-group-containing side chains in which a proportion of OH-group-containing side chains each having 6 or more carbon atoms relative to all of the OH-group-containing side chains is about 76 mol % or more and about 100 mol % or less.2. The resin material according to claim 1 , wherein the polymer contains one or both of a fluorine atom and a silicon atom.3. The resin material according to claim 1 , wherein the polymer includes a siloxane bond.4. The resin material according to claim 2 , wherein a proportion of side chains containing a fluorine atom relative to all side chains in the acrylic resin is about 5 mol % or more and about 25 mol % or less.5. The resin material according to claim 1 , wherein the acrylic resin has a hydroxyl value of about 30 mgKOH/g or more and about 250 mgKOH/g or less.6. The resin material according to claim 1 , wherein the composition contains a long chain polyol. This application is based on and claims priority under 35 USC 119 from Japanese Patent Application No. 2012-181837 filed Aug. 20, 2012.(i) Technical FieldThe present invention relates to a resin material.(ii) Related ArtIn various fields, resin materials have been used to form protective films on surfaces in order to suppress generation of scratches. For example, such resin materials are applied as protective films for protecting portable devices having displays such as cellular phones and portable game machines; windowpanes; lenses of eyeglasses; windowpanes and bodies of automobiles; recording surfaces of optical discs such as CDs, ...

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Номер записи: 70
27-02-2014 дата публикации

PROCESS FOR PRODUCING WATER-ABSORBING POLYMER PARTICLES

Номер: US20140053478A1
Автор: Peterson Monte
Принадлежит: BASF SE

The invention relates to a process for producing water-absorbing polymer particles, comprising handling water-absorbing polymer particles in intermediate silos, storage silos and/or big bag filing stations that are connected with vent lines having a mitered joint. 1. A process for producing water-absorbing polymer particles , comprising polymerization of a monomer solution or suspension , comprisinga) at least one ethylenically unsaturated monomer which bears an acid group and may be at least partly neutralized,b) at least one crosslinker,c) at least one initiator,d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a) ande) optionally one or more water-soluble polymer,drying, grinding, and classifying the resulting polymer gel, optionally thermally postcrosslinking, handling water-absorbing polymer particles in intermediate silos, storage silos, and/or big bag filing stations, wherein at least one vent line of at least one intermediate silo, storage silo, and/or big bag filing station has at least one bend for changing the direction of the vent line from upward to downward, the bend has a mitered joint and a slope upward and downward each of not less than 30° based on the horizontal.2. The process according to claim 1 , wherein the slope upward and downward of the bend is not less than 60° based on the horizontal.3. The process according to claim 1 , wherein the bend has a shape of a turned up V.4. The process according to claim 1 , wherein the vent line is thermally insulated.5. The process according to claim 1 , wherein the vent line is external heated.6. The process according to claim 1 , wherein the water-absorbing polymer particles in the intermediate silos claim 1 , storage silos claim 1 , and/or big bag filing stations are covered with dry air.7. The process according to claim 1 , wherein the proportion of acrylic acid in the total amount of ethylenically unsaturated monomer a) is at least 95 mol %.8. ...

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Номер записи: 71
27-02-2014 дата публикации

SCRATCH-RESISTANT FILM

Номер: US20140057117A1
Автор: Suzuki Yasuhiro
Принадлежит: RIKEN TECHNOS CORPORATION

The present invention provides a paint film which is superior in scratch resistance, weather resistance, stain resistance, chemical resistance, bending durability and impact resistance and is useful as a scratch resistant film or a decorative film. 2. A film according to claim 1 , wherein Y in monomer unit (D) has one or more groups selected from the group consisting of the ring-opened lactone group claim 1 , the carbonate group claim 1 , the ester group claim 1 , the ether group and the urethane group.3. A film having the film according to claim 1 , laminated on at least one side of a thermoplastic resin film.4. A scratch-resistant film made of the film according to .5. An article having the scratch-resistant film according to .6. A film having the film according to claim 2 , laminated on at least one side of a thermoplastic resin film.7. A scratch-resistant film made of the film according to .8. A scratch-resistant film made of the laminated film according to .9. A scratch-resistant film made of the laminated film according to .10. An article having the scratch-resistant film according to .11. An article having the scratch-resistant film according to .12. An article having the scratch-resistant film according to . This application claims the benefits of Japanese Patent application No. 2011-62883 filed on Mar. 22, 2011, the contents of which are hereby incorporated by reference.The present invention relates to a film which is used for protecting or decorating surface of articles, or instead of directly coating articles with paint. More particularly, the present invention relates to a film for protecting or decorating surface of automobile exterior parts, wall materials, floor materials, or household appliances such as refrigerators.Conventionally, automobile exterior parts, such as door sash, were directly coated with hardening resin paint such as a melamine resin, an isocyanate resin and a urethane resin, depending on materials of the parts, in order to provide ...

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Номер записи: 72
06-03-2014 дата публикации

HIGH ACTIVITY, LOW MOLECULAR WEIGHT OLEFIN POLYMERIZATION PROCESS

Номер: US20140066585A1
Автор: Boone Harold W., Frazier Kevin A., Vanderlende Daniel D., Vosejpka Paul C.
Принадлежит: Dow Global Technologies LLC

Group 4 metal complexes comprising a polyvalent, heteroaryl donor ligand and their use as components of olefin polymerization catalysts, especially suited for preparing propylene copolymer products having high isotacticity and low molecular weight, are disclosed. 1copolymerizing propylene and 1-octene at a temperature from 100 to 130° C., a pressure from 100 kPa to 10 MPa, and a hydrogen partial pressure from 25 to 500 kPa in the presence of a metal complex corresponding to the formula:. A propylene/octene copolymer wherein the copolymer is made by the process comprising:wherein, X is an anionic ligand group; andcovalent bonds are represented by lines and coordination interactions are represented by arrows. This invention relates to a Group 4 metal complex, to a catalyst composition and to a process for polymerizing addition polymerizable unsaturated monomers, especially olefins. In particular, the invention is directed to certain Group 4 metal complexes, to catalyst compositions comprising the same, and to addition polymerization processes using the same.Advances in polymerization and catalysis have resulted in the capability to produce many new polymers having improved physical and chemical properties useful in a wide variety of superior products and applications. With the development of new catalysts the choice of polymerization-type (solution, slurry, high pressure or gas phase) for producing a particular polymer has been greatly expanded. Also, advances in polymerization technology have provided more efficient, highly productive and economically enhanced processes. Recently, several new disclosures related to metal complexes based on polyvalent metal-centered, heteroaryl donor ligands have published. Among these are U.S. Pat. No. 6,103,657, U.S. Pat. No. 6,906,160, U.S. Pat. No. 6,919,407, U.S. Pat. No. 6,927,256, US-A-2002/0142912, US-A-2004/0220050, US-A-2004/0005984, WO 2000/020377, and WO 2002/038628.Regardless of the technological advances in the ...

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Номер записи: 73
20-03-2014 дата публикации

PROPYLENE-HEXENE RANDOM COPOLYMER PRODUCED IN THE PRESENCE OF A ZIEGLER NATTA CATALYST

Номер: US20140079899A1
Автор: Bernreitner Klaus, Hafner Norbert, Jaaskelainen Pirjo, Stadlbauer Manfred, Töltsch Wilfried
Принадлежит: Borealis AG

Propylene copolymer a. comprising at least 1-hexene as a comonomer, b. having a comonomer content in the range of 1.0 to 3.0 wt.-%, c. having a xylene soluble fraction equal or below 2.5 wt.-%, and d. being partially crystallized in the β-modification. 1. Propylene copolymer (A)(a) comprising at least 1-hexene as a comonomer,(b) having a comonomer content in the range of 1.0 to 3.0 wt.-%,(c) having a xylene soluble fraction equal or below 2.5 wt.-%, and(d) being partially crystallized in the β-modification.2. Propylene copolymer according to claim 1 , wherein the copolymer (A) comprises a β-nucleating agent (B).3. Propylene copolymer (A)(a) comprising at least 1-hexene as a comonomer,(b) having a comonomer content in the range of 1.0 to 3.0 wt.-%,(c) having a xylene soluble fraction equal or below 2.5 wt.-%, and(d) comprising a β-nucleating agent (B).4. Propylene copolymer according to claim 3 , wherein the copolymer (A) is partially crystallized in the β-modification.5. Propylene copolymer (A) according to claim 1 , wherein propylene copolymer (A) has a MFR(230° C.) of not more than 0.8 g/10 min measured according to ISO 1133.6. Propylene copolymer (A) according to claim 1 , wherein the 1-hexene content of the propylene copolymer (A) is in the range of 1.0 to 2.0 wt.-%.7. Propylene copolymer (A) according to claim 1 , wherein the propylene copolymer (A) is only constituted by propylene and 1-hexene units.8. Propylene copolymer (A) according to claim 1 , wherein the comonomer content of the propylene copolymer (A) is in the range of 1.0 to 2.0 wt.-%.9. Propylene copolymer (A) according to claim 1 , wherein the propylene copolymer (A) has a polydispersity index (PI) of 3.0 to 8.0 Pa.10. Propylene copolymer (A) according to claim 1 , wherein the amount of the β-modification of the propylene copolymer (A) is at least 50%.11. Propylene copolymer (A) according to claim 1 , wherein the propylene copolymer (A) has a flexural modulus measured according to ISO 178 of at ...

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Номер записи: 74
20-03-2014 дата публикации

HYDROPHILIZED ANTIMICROBIAL POLYMERS

Номер: US20140080977A1
Автор: Sellenet Philippe H., Stratton Thomas R., Youngblood Jeffrey P.
Принадлежит: PURDUE RESEARCH FOUNDATION

A bactericidal or antimicrobial polymeric composition includes a hydrophilic first comonomer copolymerized to a second comonomer to produce a polymeric composition that is more hydrophilic or more bactericidal or antimicrobial in an aqueous solution than either of the comonomers alone. Methods for identifying bactericidal or antimicrobial polymers, methods for rendering materials bactericidal or antimicrobial, and methods for using bactericidal or antimicrobial compositions to kill or reduce bacterial or microbial growth are also described. Applications for the inventive compositions include their use in catheters, stents, medical devices, contact lenses; root canal fillers; fibers; paper; and/or wound dressing. 1. A composition comprising a copolymer formed from a hydrophilic first comonomer having an acrylate moiety and a second pyridinium-type comonomer containing a nitrogen atom and a vinyl moiety , wherein the first comonomer and the second comonomer are chemically bonded within the copolymer through the acrylate moiety of the first comonomer and the vinyl moiety of the second comonomer , wherein said nitrogen atom is quaternized with an alkyl moiety such that said copolymer is polycationic , and wherein the amounts of the first comonomer and the second comonomer provide said copolymer witha. improved bactericidal activity as compared to the first comonomer; andb. improved bactericidal activity as compared to the second comonomer.2. The composition of claim 1 , wherein the hydrophilic first comonomer comprises hydroxyethylmethacrylate.3. The composition of claim 1 , wherein the hydrophilic first comonomer comprises poly(ethylene glycol) methacrylate.4. The composition of claim 1 , wherein the second comonomer comprises 4-vinylpyridine.5. The composition of wherein said nitrogen is quaternized with an alkyl moiety.6. The composition of further comprising a halide anion associated with a cation of the quaternized nitrogen of the polycationic copolymer.7. The ...

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Номер записи: 75
10-04-2014 дата публикации

MOLDING MATERIAL AND MOLDING

Номер: US20140100345A1
Автор: ASAI Takafumi, Nakaya Fuminori, Noda Tetsuya, Nogami Hiroyuki, Sakashita Keiichi
Принадлежит: MITSUBISHI RAYON CO., LTD.

An object of the invention is to provide a molding with suppressed coloring which has good weather resistance and in which the advantageous effect does not decrease with time. The present invention provides a molding material comprising a polymer (A) obtained by polymerizing 0.01 to 35 mol % of monomer (a1) represented by a specified formula (1) and 65 to 99.99 mol % of monomer (a2) whose main component is methylmethacrylate. 2. The molding material according to claim 1 , wherein in the case a molding having a thickness of 2 mm is obtained by molding the molding material claim 1 , a total light transmittance is from 85 to 100% and a haze value is 5% or less.3. The molding material according to claim 1 , wherein a content of a component derived from the monomer (a1) in 100 wt % of the molding material is from 0.01 to 50 wt %.4. The molding material according to claim 1 , wherein a content of the polymer is 50 wt % or more.5. A method of molding the molding material according to claim 1 , comprising molding the molding material at a temperature of 280° C. or lower.6. A molding obtained by the method according to .7. The molding according to claim 6 , wherein a total light transmittance of the molding at a thickness of 2 mm is from 85 to 100% and a haze value of the molding at a thickness of 2 mm is 5% or lower.8. The molding material according to claim 1 , wherein the molding material is obtained by a process comprising:supplying the polymer to a compact injection molding machine;fusing and holding for three minutes; and theninjection molding with a mold having a dimension of 10 mm×20 mm×2 mm at a mold temperature of 60° C., to obtain a molding having a yellow index of 10 or less.9. The molding according to claim 7 , wherein a yellow index of the molding is ten or less. The present invention relates to a molding material obtained by polymerization of monomer components comprising a monomer having a piperidine skeleton, and a molding obtained from the molding material. ...

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Номер записи: 76
06-01-2022 дата публикации

ENCAPSULATING COMPOSITION

Номер: US20220002569A1
Автор: CHOI Kook Hyun, Kim Joon Hyung, KWAK Ji Won, LEE Yung Jong, YU Mi Lim
Принадлежит:

The present disclosure relates to an encapsulating composition and an organic electronic device comprising the same, and provides an encapsulating composition which can effectively block moisture or oxygen introduced into an organic electronic device from the outside to secure the lifetime of the organic electronic device, can implement a top-emitting organic electronic device, can be applied in an inkjet method and can provide a thin display having low dielectric constant characteristics. 2. The encapsulating composition according to claim 1 , wherein X in Formula 1 contains no oxygen atom.3. The encapsulating composition according to claim 1 , wherein X in Formula 1 has an alicyclic structure.4. The encapsulating composition according to claim 1 , wherein X in Formula 1 has a bicyclic or tricyclic structure.6. The encapsulating composition according to claim 5 , wherein X in Formula 2 represents a residue derived from a linear alkyl group having 12 to 30 carbon atoms.7. The encapsulating composition according to claim 5 , wherein X in Formula 2 contains no oxygen atom.8. The encapsulating composition according to claim 5 , wherein the multifunctional monomer of Formula 2 is comprised in a range of 50 to 140 parts by weight relative to 100 parts by weight of the multifunctional monomer of Formula 1.9. The encapsulating composition according to claim 1 , wherein the monofunctional monomer is comprised in a range of 80 to 230 parts by weight relative to 100 parts by weight of the multifunctional monomer of Formula 1.10. The encapsulating composition according to claim 1 , wherein the monofunctional monomer comprises an alkyl (meth)acrylate.11. The encapsulating composition according to claim 1 , wherein the monofunctional monomer comprises an alkyl (meth)acrylate containing a linear claim 1 , branched or cyclic alkyl group having 8 to 30 carbon atoms.12. The encapsulating composition according to claim 1 , further comprising a crosslinking agent.13. The encapsulating ...

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Номер записи: 77
05-01-2017 дата публикации

ELECTRODE COMPOSITION FOR CAPACITIVE DEIONIZATION DEVICE, AND ELECTRODE FOR CAPACITIVE DEIONIZATION DEVICE CONTAINING THE SAME

Номер: US20170001188A1
Автор: Choi Yeong Suk, LIM Ju Wan
Принадлежит: SAMSUNG ELECTRONICS CO., LTD.

Provided are a binder composition for an electrode for a capacitive deionization device including a first polymer including a first structural unit including a zwitterionic functional group and a second structural unit including a cross-linkable functional group, a cross-linking agent, and ionic functional group, an electrode for a capacitive deionization device including the composition, a capacitive deionization device including the electrode, and a method of removing ions from a fluid using the device. 3. The electrode binder composition for a capacitive deionization device of claim 1 , wherein A of Chemical Formula 1 is a hydroxy group claim 1 , a carboxyl group claim 1 , a sulfonic acid group claim 1 , a phosphonic acid group claim 1 , an acrylate group claim 1 , a methacrylate group claim 1 , or a halogenated salt.4. The electrode binder composition for a capacitive deionization device of claim 1 , wherein Rto Rof Chemical Formula 1 are all hydrogen claim 1 , Lis a C1 to C10 alkylene group claim 1 , and A is a sulfonic acid group.5. The electrode binder composition for a capacitive deionization device of claim 1 , wherein Rof Chemical Formula 2 is methyl claim 1 , Rand Rare hydrogen claim 1 , Lis a C1 to C10 alkylene group claim 1 , and Ris a hydroxy group.6. The electrode binder composition for a capacitive deionization device of claim 2 , wherein Rof Chemical Formula 3 is hydrogen or methyl claim 2 , Rand Rare hydrogen claim 2 , Lis a single bond or —(C═O)O— claim 2 , and Ris a methyl claim 2 , phenyl claim 2 , or cyano group.8. The electrode binder composition for a capacitive deionization device of claim 1 , further comprising:at least one second hydrophilic polymer selected from polystyrene, polyacrylic acid-co-maleic acid, polyvinyl alcohol, carboxylmethyl cellulose, hydroxypropyl cellulose, polyvinylchloride, carboxylated polyvinylchloride, polyvinylfluoride, polyvinyl amine, chitosan, polyamide, polyurethane, polyacrylamide, polyacrylamide-co-acrylic ...

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Номер записи: 78
04-01-2018 дата публикации

Container Assembly

Номер: US20180002078A1
Автор: H Stephen Quinn
Принадлежит: Plastek Industries Inc

A container comprises: a tub ( 22 ) having a bottom ( 50 ) and four sides ( 56, 58, 60, 62 ), adjacent said sides joined at junctions; and a closure ( 24 ). The closure comprises: a lid ( 28 ); a living hinge member ( 26 ) unitarily formed with the lid and coupling the lid to the tub so as to allow the lid to shift between a closed condition and an open condition, the living hinge having an insertion portion ( 222 ) received in a pocket ( 82 ) of the tub.

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Номер записи: 79
02-01-2020 дата публикации

WATER-ABSORBENT RESIN, AND SOIL

Номер: US20200002445A1
Автор: CHIBA Mikito, Onoda Yuichi
Принадлежит:

Provided is a water-absorbent resin that quickly absorbs water, even in sandbag in which a large amount of the water-absorbent resin has been used, that does not easily form unswollen lump, and that has a high gel swelling volume when water is used to swell the water-absorbent resin. This water-absorbent resin is configured from a polymer of water-soluble ethylenic unsaturated monomers. The physiological-saline absorption capacity of the water-absorbent resin is 40-60 g/g. When a cross-sectional image of the water-absorbent resin is observed by x-ray computed tomography, the fraction of the area of the cross-sectional image that is hollow portions (the hollow area ratio of the cross-sectional image), as calculated on the basis of formula (I), is no more than 10%. (I) Hollow area ratio [%]={total cross-sectional area (B) of hollow portions of the water-absorbent resin/(total cross-sectional area (A) of resin portions of the water-absorbent resin+total cross-sectional area (B) of hollow portions of the water-absorbent resin)}×100%. 1. A water-absorbent resin comprising a polymer of a water-soluble ethylenically unsaturated monomer , wherein:a physiological-saline absorption capacity is 40 to 60 g/g, and {'br': None, 'cavity area ratio [%]={total cross-sectional area (B) of cavity portions in the water-absorbent resin/(total cross-sectional area (A) of resin portions in the water-absorbent resin+total cross-sectional area (B) of cavity portions in the water-absorbent resin)}×100. \u2003\u2003(I)'}, 'when a cross-sectional image of the water-absorbent resin obtained by X-ray computed tomography is observed, a ratio (cavity area ratio) as calculated by Equation (I) of an area of cavity portions in the cross-sectional image is 10% or more2. The water-absorbent resin according to claim 1 , wherein the water-absorbent resin has a granular shape claim 1 , a substantially spherical shape claim 1 , or a shape in which particles having a substantially spherical shape are ...

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Номер записи: 80
07-01-2021 дата публикации

IN VIVO ENGINEERED CEREBLON PROTEIN

Номер: US20210002337A1
Автор: BALTGALVIS Kristen, CRAVATT Benjamin F., HORNING Benjamin, Kinsella Todd, NORDIN Brian, PATRICELLI Matthew, SIMON Gabe, Stamos Dean, VINOGRADOVA Ekaterina, Weinstein David
Принадлежит:

Disclosed herein are in vivo engineered cereblon protein and methods of making the same. The in vivo engineered cereblon protein can include a site-specific non-naturally occurring modification at cysteine 287 as set forth in SEQ ID NO:1, or cysteine 286 as set forth in SEQ ID NO: 2 or 3, the modification comprising a moiety resulting from an in vivo Michael addition reaction between an exogenous Michael acceptor and the cysteine 287 as set forth in SEQ ID NO:1, or cysteine 286 as set forth in SEQ ID NO: 2 or 3. 1. An in vivo engineered cereblon protein consisting of a site-specific non-naturally occurring modification at cysteine 287 as set forth in SEQ ID NO:1 , or cysteine 286 as set forth in SEQ ID NO: 2 or 3 , the modification comprising a moiety resulting from an in vivo Michael addition reaction between an exogenous Michael acceptor and the cysteine 287 as set forth in SEQ ID NO:1 , or cysteine 286 as set forth in SEQ ID NO: 2 or 3.2. The in vivo engineered cereblon of claim 1 , wherein the IMiD pocket-dependent binding on the engineered cereblon protein is prevented by the modification.3. The in vivo engineered cereblon of claim 1 , wherein the engineered cereblon protein has an inhibited or reduced binding for immunomodulatory drugs as compared to unmodified cereblon claim 1 ,4. The in vivo engineered cerebion of claim 1 , wherein the engineered cereblon has reduced engagement potency at cysteine 318 as set forth in SEQ ID NO:1 or at cysteine 317 as set forth in SEQ ID NO: 2 or 3.5. The in vivo engineered cereblon of claim 1 , wherein the amino acid residue at cysteine 318 as set forth in SEQ ID NO:1 or cysteine 317 as set forth in SEQ ID NO: 2 or 3 is not modified.6. The in vivo engineered cereblon of claim 1 , wherein the amino acid residues at cysteine 234 claim 1 , cysteine 205 claim 1 , cysteine 219 claim 1 , cysteine 366 claim 1 , cysteine 188 claim 1 , and cysteine 343 as set forth in SEQ ID NO:1 are not modified.7. The in vivo engineered cereblon of ...

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Номер записи: 81
03-01-2019 дата публикации

STRUCTURE MATERIAL

Номер: US20190002654A1
Автор: Honma Masato, Shinohara Kotaro, Takebe Yoshiki
Принадлежит: Toray Industries, Inc.

A structure material includes a resin, reinforced fibers, and voids, a volume content of the resin being within a range of 2.5% by volume or more and 85% by volume or less, a volume content of the reinforced fibers being within a range of 0.5% by volume or more and 55% by volume or less, the voids being contained in the structure material in a rate within a range of 10% by volume or more and 97% by volume or less, a thickness St of the structure material satisfying a conditional expression: St≥Lf·(1−cos(θf)) where a length of the reinforced fibers is Lf and an oriented angle of the reinforced fibers in a sectional direction of the structure material is θf, and a compression strength in an in-plane direction at 50% compression of the structure material measured in accordance with JIS K7220 being 3 MPa or more. 1. A structure material comprising a resin , reinforced fibers , and voids ,a volume content of the resin being within a range of 2.5% by volume or more and 85% by volume or less,a volume content of the reinforced fibers being within a range of 0.5% by volume or more and 55% by volume or less,the voids being contained in the structure material in a rate within a range of 10% by volume or more and 97% by volume or less,{'sup': '2', 'a thickness St of the structure material satisfying a conditional expression: St≥Lf·(1−cos(θf)) where a length of the reinforced fibers is Lf and an oriented angle of the reinforced fibers in a sectional direction of the structure material is θf, and'}a compression strength in an in-plane direction at 50% compression of the structure material measured in accordance with JIS K7220 being 3 MPa or more.2. The structure material according to claim 1 , wherein a compression strength in an out-of-plane direction of the structure material is 10 MPa or more.3. The structure material according to claim 1 , wherein a specific bending modulus of the structure material represented as Ec·ρis within a range of 3 or more and 20 or less where a ...

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Номер записи: 82
13-01-2022 дата публикации

Stimuli Responsive Polymers For Lost Circulation Applications

Номер: US20220010194A1
Автор: KADAM Sunita Sameer, Patil Rahul Chandrakant, Shumway William Walter
Принадлежит: Halliburton Energy Services, Inc.

A method is disclosed for mitigating a lost circulation zone. The method may include providing a lost circulation treatment composition that may include an acid responsive polymer that may include at least one monomer, at least one comonomer, and at least one crosslinker; a carbonate-based solvent; and a carrier fluid that may include water. The method may also include introducing the lost circulation treatment composition into a wellbore within a subterranean formation, wherein the subterranean formation may include the lost circulation zone; placing the lost circulation treatment composition into the lost circulation zone, and hydrolyzing the carbonate-based solvent to generate carbon dioxide. 1. A method for mitigating a lost circulation zone comprising:providing a lost circulation treatment composition comprising an acid responsive polymer comprising at least one monomer, at least one comonomer, and at least one crosslinker; a carbonate-based solvent; and a carrier fluid comprising water;introducing the lost circulation treatment composition into a wellbore within a subterranean formation, wherein the subterranean formation comprises the lost circulation zone;placing the lost circulation treatment composition into the lost circulation zone; andhydrolyzing the carbonate-based solvent to generate carbon dioxide.3. The method of claim 2 , wherein each Ris independently a C-Calkyl claim 2 , Ris a substituted or unsubstituted linear claim 2 , branched claim 2 , cyclic claim 2 , heterocyclic claim 2 , or aromatic hydrocarbyl group claim 2 , and m is an integral in a range from 1 to 5.4. The method of claim 1 , wherein the comonomer is an alkene or mono-vinyl having a chemical formula R—CH═CH claim 1 , wherein Ris a substituted or unsubstituted linear claim 1 , branched claim 1 , cyclic claim 1 , heterocyclic claim 1 , or aromatic hydrocarbyl group.5. The method of claim 4 , wherein Ris a phenyl claim 4 , an aryl claim 4 , or a C-Calkyl.7. The method of claim 6 , ...

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Номер записи: 83
05-01-2017 дата публикации

SEMICONDUCTOR ELEMENT AND INSULATING LAYER-FORMING COMPOSITION

Номер: US20170005266A1
Автор: Nagata Yuzo, Takizawa Hiroo, Tsuchimura Tomotaka, TSURUTA Takuya
Принадлежит: FUJIFILM Corporation

Provided is a semiconductor element having a semiconductor layer and an insulating layer adjacent to the semiconductor layer, in which the insulating layer is formed of a crosslinked product of a polymer compound having a repeating unit (IA) represented by the following General Formula (IA) and a repeating unit (IB) represented by the following General Formula (IB). 2. The semiconductor element according to claim 1 , wherein Lis represented by the following Formula (1a) claim 1 ,{'br': None, 'sup': 1a', '3a, '*-Ar-L** \u2003\u2003Formula (1a)'}{'sup': 3a', '1a', '1a', '2a, 'in Formula (1a), Lrepresents a single bond or a linking group, Arrepresents an aromatic ring, * indicates the bonding position of the carbon atom to which Rin the repeating unit (IA) is bonded, and ** indicates the bonding position of Lin the repeating unit (IA).'}3. The semiconductor element according to claim 2 , wherein Aris a benzene ring.6. The semiconductor element according to claim 1 , wherein the crosslinkable group X is an epoxy group claim 1 , an oxetanyl group claim 1 , a hydroxymethyl group claim 1 , an alkoxymethyl group claim 1 , a (meth)acryloyloxy group claim 1 , a styryl group claim 1 , or a vinyl group.7. The semiconductor element according to claim 1 , wherein the crosslinkable group X is a hydroxymethyl group or an alkoxymethyl group.8. The semiconductor element according to claim 1 , wherein the crosslinked product is a crosslinked product by a crosslinking reaction between the crosslinkable group X of the repeating unit (IA) and the repeating unit (IB).9. The semiconductor element according to claim 8 , wherein the crosslinked product has a crosslinked portion where a hydroxymethyl group or an alkoxymethyl group as a crosslinkable group is formed by a reaction.10. The semiconductor element according to claim 1 , wherein the semiconductor layer contains an organic semiconductor. This application is a Continuation of PCT International Application No. PCT/JP2015/058775 filed ...

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Номер записи: 84
02-01-2020 дата публикации

EDDER COMPOUND AND CAPACITOR THEREOF

Номер: US20200006000A1
Автор: EDDER Carine, Lazarev Pavel Ivan
Принадлежит:

A metadielectric composite oligomeric organic material according to the formula: 3. The metadielectric composite oligomeric organic material of wherein all resistive insulating groups are selected independently from the group consisting of non-aromatic carbocycles and non-aromatic heterocycles.4. The metadielectric composite oligomeric organic material of wherein each instance of A is independently selected from —NO claim 1 , —CHO (aldehyde) claim 1 , —CRO (keto group) claim 1 , —SOH (sulfonic acids) claim 1 , —SOR (sulfonates) claim 1 , SONH claim 1 , —SONHR claim 1 , —SONR′R″ (sulfonamides) claim 1 , —COOH (carboxylic acid) claim 1 , —COOR (esters claim 1 , from carboxylic acid side) claim 1 , —CONH claim 1 , CONHR claim 1 , CONR′R″ (amides claim 1 , from carboxylic acid side) claim 1 , —CF claim 1 , —CCl claim 1 , and —CN claim 1 , and{'sub': 2', '2', '6', '5, 'wherein each instance of D is independently selected from —NH, —NHR, —NR, —OH, OR (ethers), —NHCOR (amides, from amine side), —OCOR (esters, from alcohol side), alkyls, —CH, and vinyls, and'}wherein R and R′ and R″ are radicals independently selected from the list comprising hydrogen, alkyl (methyl, ethyl, isopropyl, tert-butyl, neopentyl, cyclohexyl etc.), allyl (˜CH2-CH═CH2), benzyl (—CH2C6H5) groups, phenyl (+substituted phenyl) and other aryl (aromatic) groups.6. The composite oligomeric organic material of wherein the insulating resistive groups are independently selected from the group consisting of saturated hydrocarbon claim 1 , saturated halogenated hydrocarbon claim 1 , partially halogenated hydrocarbon claim 1 , aryl chain claim 1 , and cycloalkyl claim 1 , and X—RR′R″; wherein X is selected from C claim 1 , O claim 1 , N claim 1 , and S claim 1 , and R claim 1 , R′ claim 1 , and R″ claim 1 , wherein R′ and R″ are absent when necessitated by the valence of X claim 1 , are independently selected from H and C claim 1 , wherein one or more of R claim 1 , R′ claim 1 , and R″ is C.7. The composite ...

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Номер записи: 85
11-01-2018 дата публикации

Poly(Acrylic Acid) From Bio-Based Acrylic Acid And Its Derivatives

Номер: US20180009915A1
Автор: Axel Meyer, Dimitris Ioannis Collias, Jane Ellen Godlewski, Janette Villalobos Lingoes, Juan Esteban VELASQUEZ, Peter Dziezok
Принадлежит: Procter and Gamble Co

Bio-based glacial acrylic acid, produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof and having impurities of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof, is polymerized to poly(acrylic acid) or superabsorbent polymer using the same processes as petroleum-derived glacial acrylic acid.

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Номер записи: 86
08-01-2015 дата публикации

Methods of Making Polyethylene Polymer Comprising Polar Comonomer and Polymer Compositions

Номер: US20150011717A1
Автор: Garland, Graham Michael L., Jr. Don A.
Принадлежит:

A continuous process for producing high pressure polyethylene is described. The process includes contacting first amounts of ethylene, an optional polar comonomer, and a first Cto Cmodifier in the presence of a first amount of initiator in a reaction system under polymerization conditions to form a reaction system effluent comprising a first polyethylene resin having a first concentration of unreacted monomer therein; and directing an ethylene stream and the reaction system effluent to a pressure separation unit operated at separation conditions thereby removing at least a portion of the unreacted monomer from the reaction system effluent. 1. A continuous process for producing high pressure polyethylene , comprising:{'sub': 2', '12, 'contacting a first amount of ethylene and a first amount of a Cto Cmodifier in the presence of a first amount of initiator in a reaction system under polymerization conditions to form a reaction system effluent comprising a first polyethylene resin having a first concentration of an unreacted monomer therein; and'}directing an ethylene stream and the reaction system effluent to a pressure separation unit operated at separation conditions thereby removing at least a portion of the unreacted monomer from the reaction system effluent.2. The process of claim 1 , further including providing a first amount of polar monomer claim 1 , and contacting the first amount of ethylene claim 1 , the first amount of a Cto Cmodifier and the first amount of polar monomer claim 1 , wherein the unreacted monomer comprises unreacted polar monomer.3. The process of claim 2 , further including providing a second amount of ethylene claim 2 , a second amount of polar monomer claim 2 , and a second amount of a Cto Cmodifier to the reaction system.4. The process of claim 1 , wherein the first amount of a Cto Cmodifier includes at least one saturated or unsaturated modifier claim 1 , preferably a linear or branched claim 1 , substituted or unsubstituted aldehyde or ...

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Номер записи: 87
27-01-2022 дата публикации

BUSHING FOR A POWER SYSTEM

Номер: US20220028584A1
Автор: Eriksson Goran
Принадлежит:

A bushing for a power system, comprising: a conductor, and a condenser core, wherein the condenser core comprises a dielectric sheet and a plurality of disjoint regions of electrically conducting material provided on the dielectric sheet, wherein the dielectric sheet and the electrically conducting material form a wound structure around the conductor, wherein in at least one region the electrically conducting material is a semiconducting material, wherein the semiconducting material extends more than one turn around the conductor, whereby the at least one region has overlapping edges in the radial direction, and wherein the dielectric sheet extends between the overlapping edges whereby a capacitance is formed between the overlapping edges, which capacitance is partly defined by an overlap length of the overlapping edges and which capacitance forms part of a resonance circuit of the at least one region, wherein the overlap length is such that the resonance circuit has a resonance frequency contained in a very fast transient, VFT, spectrum. 1. A bushing for a power system , comprising:a conductor, anda condenser core,wherein the condenser core comprises a dielectric sheet and a plurality of disjoint regions of electrically conducting material provided on the dielectric sheet, wherein the dielectric sheet and the electrically conducting material form a wound structure around the conductor,wherein in at least one region of electrically conducting material, the electrically conducting material is a semiconducting material, wherein the semiconducting material extends more than one turn around the conductor, whereby the at least one region of electrically conducting material has overlapping edges in a radial direction, andwherein the dielectric sheet-(extends between the overlapping edges whereby a capacitance is formed between the overlapping edges, which capacitance is partly defined by an overlap length of the overlapping edges and which capacitance forms part of a ...

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Номер записи: 88
09-01-2020 дата публикации

PHOTOSENSITIVE RESIN COMPOSITION

Номер: US20200012192A1
Автор: SAKURAI Takaaki
Принадлежит: ZEON CORPORATION

Disclosed are photosensitive resin compositions capable of forming positive resin films with excellent heat shape retention. The photosensitive resin compositions comprises a polymer having a monomer unit represented by the following general formula (I) and a polyamideimide: 2. The photosensitive resin composition according to claim 1 , wherein the polyamideimide is a polyamideimide having a branched structure.3. The photosensitive resin composition according to claim 1 , wherein the polyamideimide has a number-average molecular weight of 1 claim 1 ,000 or more and 30 claim 1 ,000 or less.4. The photosensitive resin composition according to claim 1 , wherein the polymer is a copolymer further having a (meth)acrylate monomer unit.5. The photosensitive resin composition according to claim 1 , wherein a content ratio by mass of the polymer to the polyamideimide (polymer:polyamideimide) is 90:10 to 70:30.6. The photosensitive resin composition according to claim 1 , further comprising a photoactive compound and a cross-linker. The present disclosure relates to photosensitive resin compositions and, in particular, photosensitive resin compositions capable of forming positive resist films with excellent heat shape retention.Organic electroluminescent elements (organic EL electroluminescent elements), an example of electronic components, are provided with a variety of resin films, such as protective films for preventing degradation and damage, planarizing films for planarizing the element surface and interconnections, electric insulating films for ensuring electrical insulation, and pixel separation films for separating light emitter portions.Similarly, micro light-emitting diodes (LEDs) and organic light-emitting diode (OLEDs), other examples of electronic components, are provided with a variety of resin films, such as protective films for preventing degradation and damage, electric insulating films for ensuring electrical insulation, and passivation films for preventing ...

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Номер записи: 89
03-02-2022 дата публикации

FUNCTIONALIZED A- ANGELICA LACTONE MONOMERS AND POLYMERS OBTAINED THEREFROM

Номер: US20220033370A1
Автор: Back Horst, Brandt Adrian, De Vries Johannes Gerardus, ITO Kenji, Savini Arianna, Taden Andreas, Tin Sergey
Принадлежит:

The present invention is directed to a monomer for chain growth polymerization, in particular anionic polymerization, said monomer having the general formula (EFL) 3. The monomer according to claim 1 , wherein Ris a C-Calkyl or C-Calkenyl group.5. The process according to claim 4 , wherein the acid anhydride is one of acetic anhydride claim 4 , propionic anhydride claim 4 , butyric anhydride or succinic anhydride and further wherein said acid anhydride is present in a catalytically sufficient amount based on the total number of moles of reactants (a) claim 4 , b)).6. The process according to claim 4 , wherein said antioxidant comprises or consists of at least one sterically hindered phenol and wherein said antioxidant is present in an amount of up to 10 wt. % based on the total weight of the reactants (a) claim 4 , b)).7. A process for the chain growth polymerization of at least one monomer (EFL) as defined in .8. A process according to for the anionic polymerization of at least one monomer (EFL) claim 7 , wherein said anionic polymerization is conducted in the presence of an initiator selected from the group consisting of: alkali metal organyls; alkali metal alkoxides; alkali metal thiolate; alkali metal amides; and compounds of an element of group 3a of the Periodic Table of the Elements.9. The process according to claim 8 , wherein said initiator is present in an amount of from 0.0001 to 5 wt. % claim 8 , based on the total weight of monomers.10. The process according to claim 8 , wherein said initiator comprises an aliphatic alkoxide of sodium claim 8 , potassium or lithium.11. The process according to claim 8 , wherein said initiator comprises an organolithium compounds selected from the group consisting of: ethyllithium; propyllithium; isopropyllithium; n-butyllithium; sec-butyllithium; tert-butyllithium; phenyllithium; diphenylhexyllithium; hexamethylenedilithium; butadienyllithium; isoprenyllithium; polystyryllithium; 1 claim 8 ,4-dilithiobutane; 1 claim 8 , ...

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Номер записи: 90
03-02-2022 дата публикации

METHOD OF PRODUCING POLYMERIZABLE COMPOSITION AND POLYMERIZABLE COMPOSITION

Номер: US20220033533A1
Автор: FUKUYO Yuri, KASAI Yuki, Kato Hiroki, Takahashi Makoto, UENO Takayuki
Принадлежит:

There is provided a method of producing a polymerizable composition that includes a first polymerizable monomer; and a second polymerizable monomer, a polymer of the second polymerizable monomer, or both, the second polymerizable monomer, the polymer of the second polymerizable monomer, or the both being dispersed in the first polymerizable monomer, the method of producing a polymerizable composition includes dissolving the first polymerizable monomer; the second polymerizable monomer, the polymer of the second polymerizable monomer, or the both in a solvent to obtain a solution in a first step; and evaporating the solvent from the solution in a second step, wherein the first polymerizable monomer is a liquid, and wherein the second polymerizable monomer is a solid. 1. A method of producing a polymerizable composition that includes a first polymerizable monomer; and a second polymerizable monomer , a polymer of the second polymerizable monomer , or both , the second polymerizable monomer , the polymer of the second polymerizable monomer , or the both being dispersed in the first polymerizable monomer , the method of producing a polymerizable composition comprising:dissolving the first polymerizable monomer;the second polymerizable monomer, the polymer of the second polymerizable monomer, or the both in a solvent to obtain a solution in a first step; andevaporating the solvent from the solution in a second step,wherein the first polymerizable monomer is a liquid, andwherein the second polymerizable monomer is a solid.2. The method of producing the polymerizable composition according to claim 1 , wherein one or both of the first polymerizable monomer and the second polymerizable monomer is a (meth)acrylate.3. The method of producing the polymerizable composition according to claim 1 , wherein the second polymerizable monomer includes a functional group that exhibits an antibacterial property.4. The method of producing the polymerizable composition according to claim 1 ...

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Номер записи: 91
03-02-2022 дата публикации

LIMITED CONDUCTION HEAT RETAINING MATERIALS

Номер: US20220034003A1
Автор: Beckham Haskell W., Blackford Michael Woody, Durr Rebecca A., Mergy Jeffrey Thomas
Принадлежит: COLUMBIA SPORTSWEAR NORTH AMERICA, INC.

Embodiments relate to an article of clothing that includes a base material with a moisture vapor transfer rate (MVTR) of at least 2000 g/m/24 h (JIS 1099 A1). The article of clothing may further include a foam-based spacer material coupled to the first side of the base material. The foam-based spacer material may be positioned between the base material and a wearer of the article of clothing when the article of clothing is worn. The foam-based spacer material may be an array of discrete elements coupled with the base material. Other embodiments may be described and/or claimed. 1. An insulating material comprising:{'sup': '2', 'a base material having a moisture vapor transfer rate (MVTR) of at least 2000 g/m/24 h (JIS 1099 A1);'}a plurality of heat-reflecting elements coupled to a first side of the base material, each heat-reflecting element having a heat-reflecting surface and being positioned to reflect heat towards an underlying surface; anda foam-based spacer material coupled to the first side of the base material, wherein at least one of the plurality of heat-reflecting elements is at least partially between the foam-based spacer material and the base material.2. The insulating material of claim 1 , wherein the foam-based spacer material includes polyacrylate claim 1 , polyurethane claim 1 , or polyolefin.3. The insulating material of claim 2 , wherein the foam-based spacer material further includes a crosslinking agent.4. The insulating material of claim 1 , wherein the foam-based spacer material has a thickness between approximately 0.05 millimeters (mm) and approximately 0.15 mm.5. The insulating material of claim 1 , wherein the base material has a rippled profile.6. The insulating material of claim 5 , wherein a peak of the rippled profile of the base material is adjacent to a portion of the base material that is coupled with the foam-based spacer material.7. The insulating material of claim 1 , wherein the foam-based spacer material has a cross-shaped ...

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Номер записи: 92
18-01-2018 дата публикации

METHODS FOR TREATING FIBROUS SUBSTRATES USING FLUORINE-FREE COMPOSITIONS INCLUDING ISOCYANATE-DERIVED (METH)ACRYLATE-CONTAINING POLYMERIC COMPOUNDS

Номер: US20180016739A1
Автор: Coppens Dirk M., Dams Rudolf J., Jariwala Chetan P.
Принадлежит:

A method of treating a fibrous substrate, the method including applying a fluorine-free treating composition in an amount sufficient to make the fibrous substrate water repellent, wherein the treating composition includes one or more polymeric compounds derived from the polymerization of at least one (meth)acrylate monomer comprising at least one isocyanate-derived group and at least one hydrocarbon group having at least 16 carbon atoms. 1. A method of treating a fibrous substrate , the method comprising applying a fluorine-free treating composition in an amount sufficient to make the fibrous substrate water repellent , wherein the treating composition comprises:one or more polymeric compounds derived from the polymerization of at least one (meth)acrylate monomer comprising at least one isocyanate-derived group and at least one hydrocarbon group having at least 16 carbon atoms.2. The method of wherein the one or more polymeric compounds is obtained from polymerization of at least one (meth)acrylate monomer comprising at least one isocyanate-derived group and at least one hydrocarbon group having from 16 to 60 carbon atoms.3. The method of wherein at least 70% by weight of the one or more polymeric compounds is obtained from polymerization of a (meth)acrylate monomer comprising at least one isocyanate-derived group and at least one hydrocarbon group having from 16 to 60 carbon atoms.4. The method of wherein the treating composition comprises one or more polymeric compounds are derived from the polymerization of at least one (meth)acrylate monomer having at least one of the following formulas:{'br': None, 'sup': 1', '1', '2, 'sub': '2', 'R—NH—C(O)O—L—OC(O)C(R)═CH(Formula I);'}{'br': None, 'sup': 3', '1', '2', '4, 'sub': '2', 'R—X—C(O)NH—L—OC(O)C(R)═CH(Formula II); or'}{'br': None, 'sup': 5', '2', '3', '6, 'sub': '2', 'R—X—C(O)NH—Q—NH—C(O)O—L—OC(O)C(R)═CH(Formula III).'} [{'sup': 1', '3', '5, 'R, R, and Rare independently a hydrocarbon group having at least 16 carbon ...

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Номер записи: 93
17-01-2019 дата публикации

PROCESS FOR PREPARING ALKYL SALICYLIC ACID AND PRODUCTS THEREOF

Номер: US20190016660A1
Автор: HAASE Cornelius, KNEZEVIC Milan, Makenzie Todd, Smith Scott, Zampella Joseph
Принадлежит:

This invention relates to a process for preparing an alkylsalicylic acid. The process comprises reacting salicylic acid with an olefin having at least four carbon atoms at a temperature ranging from about 50° C. to about 200° C. in the presence of an arylsulfonic acid-containing catalyst (such as para-toluene sulfonic acid), to produce an alkylsalicylic acid. The resulting alkylsalicylic acid has various applications such as a food preservative, an oil field chemical for oil recovery, and a component in a color toner agent for electrophotography. 1. A process for preparing an alkylsalicylic acid , comprising:reacting salicylic acid with an olefin having at least four carbon atoms at a temperature ranging from about 50° C. to about 200° C. in the presence of an arylsulfonic acid-containing catalyst, to produce an alkylsalicylic acid with a residual olefin of less than about 2 wt %, wherein the molar ratio of the olefin to salicylic acid is about 1:1 to about 1.3:1.2. The process of claim 1 , wherein the catalyst is para-toluene sulfonic acid claim 1 , xylene sulfonic acid claim 1 , naphthalene sulfonic acid claim 1 , phenol sulfonic acid claim 1 , or combinations thereof.3. The process of claim 2 , wherein the catalyst is para-toluene sulfonic acid claim 2 , and wherein the catalyst is at least 95% pure claim 2 , contains 0-5% water claim 2 , and contains 0-5% sulfuric acid.4. The process of claim 1 , wherein the olefin is added to the reaction in two or more portions over a course of about 30 minutes to about 20 hours under the reaction temperature.5. The process of claim 4 , wherein the olefin is added to the reaction in two or more portions over the course of about 2 to about 6 hours claim 4 , under reaction temperature.6. The process of claim 1 , wherein the olefin is an α-olefin containing 4 to 24 carbon atoms claim 1 , or a mixture thereof.7. The process of claim 1 , wherein the molar ratio of the arylsulfonic acid to salicylic acid is about 0.5:1 to about 1.5: ...

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Номер записи: 94
16-01-2020 дата публикации

POLYMERIZATION INHIBITOR AND RETARDER COMPOSITIONS WITH AMINE STABILIZER

Номер: US20200017610A1
Автор: Alnasleh Bassam, Colorado, JR. RAMON, Masere Jonathan, Neilson Andrew R.
Принадлежит:

Described are compositions and methods for inhibiting polymerization of a monomer (e.g., styrene) composition, which use an N—O polymerization inhibitor, a quinone methide polymerization retarder, and an amine stabilizer having a primary and/or secondary amine group. In a mixture, the amine-based stabilizer can prevent antagonistic effects and can provide greater antipolymerant activity. In turn, the mixture inhibits apparatus fouling and improves the purity of monomer streams. 1. A composition for inhibiting monomer polymerization comprising:an inhibitor compound that comprises an N-to-O bond;a retarder compound that is a quinone methide; anda stabilizer compound comprising a primary or secondary amine group.2. The composition of wherein the stabilizer is an alkylamine that comprises a linear claim 1 , branched claim 1 , heterocyclic claim 1 , or cyclic alkyl group.3. The composition of claim 1 , wherein the stabilizer compound has at least 4 carbons claim 1 , has a number of carbons in the range of 6-24 claim 1 , or has a number of carbons in the range of 8-24.4. The composition of wherein the stabilizer compound is of formula RNH claim 3 , wherein Ris a linear claim 3 , branched claim 3 , or cyclic alkyl group of 4-24 claim 3 , 6-24 claim 3 , or 8-24 carbons.5. The composition of wherein the stabilizer compound is selected from the group consisting of hexylamine claim 4 , heptylamine claim 4 , ethylhexylamine claim 4 , octylamine claim 4 , nonylamine claim 4 , decylamine claim 4 , undecylamine claim 4 , and dodecylamine.6. The composition of wherein the stabilizer compound is of formula RNHR claim 1 , wherein Rand Rare independently selected from linear claim 1 , branched claim 1 , or cyclic alkyl groups of 1-23 carbon atoms with the proviso that the total number of carbon atoms in Rand Ris in the range of 4-24 claim 1 , 6-24 claim 1 , or 8-24 carbons.7. The composition of wherein the stabilizer compound is a cyclic secondary amine claim 1 , a heterocyclic ...

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Номер записи: 95
16-01-2020 дата публикации

ACRYLIC POLYMER PARTICLES, PRODUCTION PROCESS THEREFOR, INK COMPOSITION, AND COATING COMPOSITION

Номер: US20200017613A1
Автор: FUKUOKA Hiroyuki, KIURA Masaaki, MORIYA Makoto, MUKUDA Takahiro, Saito Yoshikazu, SERIZAWA Masashi
Принадлежит: MITSUBISHI CHEMICAL CORPORATION

Particles of an acrylic polymer comprising a constituent unit (A) derived from methyl methacrylate and a constituent unit (B) derived from a (meth)acrylic acid alkyl ester in which the alkyl group has 2 to 8 carbon atoms, wherein the particles having electrostatic buildup inhibition rate of 90 to 99.9° as obtained by a specific method. 139-. (canceled)41. The particles of an acrylic polymer according to claim 40 , wherein a sodium element amount in the particles of an acrylic polymer is 3.5 to 50 ppm.42. The particles of an acrylic polymer according to claim 41 , wherein the sodium element amount in the particles of an acrylic polymer is 3.5 to 30 ppm.43. The particles of an acrylic polymer according to claim 40 , wherein the particles have a mass average particle diameter of 100 to 1000 μm.44. The particles of an acrylic polymer according to claim 40 , further comprising a constituent unit (C) derived from α claim 40 ,β-unsaturated carboxylic acid.45. Particles of an acrylic polymer claim 40 , comprising a constituent unit (A) derived from methyl methacrylate and a constituent unit (B) derived from (meth)acrylic acid alkyl ester in which the alkyl group has 2 to 8 carbon atoms claim 40 , the particles having a sodium element amount of 3.5 to 50 ppm.46. The particles of an acrylic polymer according to claim 45 , wherein the sodium element amount in the particles of an acrylic polymer is 3.5 to 30 ppm.47. The particles of an acrylic polymer according to claim 45 , wherein the particles have a mass average particle diameter of 100 to 1000 μm.48. The particles of an acrylic polymer according to claim 45 , further comprising a constituent unit (C) derived from α claim 45 ,β-unsaturated carboxylic acid.49. A process for producing particles of an acrylic polymer according to claim 40 , the process comprising a step of washing the acrylic polymer obtained by suspension polymerization so as to have a sodium element amount of 3.5 to 50 ppm.50. The process for producing ...

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Номер записи: 96
21-01-2021 дата публикации

Zwitterionic polymer, method for producing same and protein stabilizer containing zwitterionic polymer

Номер: US20210017309A1
Автор: Hideharu Mori, Ryutaro Imamura
Принадлежит: NOF Corp, Yamagata University NUC

Provided is a zwitterionic polymer that has a zwitterion that includes an effect of improving the stability of proteins. This zwitterionic polymer is a polymeric protein stabilizer that exhibits a protein stabilizing effect even at a small addition amount of addition, and at the same time has an antioxidant capability. Also provided is a method for producing this zwitterionic polymer. This problem is solved by a zwitterionic polymer containing a repeating unit represented by formula (1) and having a number-average molecular weight of 1,000 to 1,000,000. On formula (1), R 1 and R 2 are each independently selected from a hydrogen atom; linear, branched or cyclic alkyl groups having 1 to 6 carbons; aromatic groups having 6 to 20 carbons; or alkylene groups having 1 to 6 carbons and formed by linking R 1 to R 2 . R 3 represents a hydrogen atom or a methyl group).

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Номер записи: 97
16-01-2020 дата публикации

Surface treatment liquid and hydrophilic treatment method

Номер: US20200017652A1
Автор: Takahiro Senzaki, Takashi KAMIZONO
Принадлежит: Tokyo Ohka Kogyo Co Ltd

An object is to provide a surface treatment liquid which can firmly bond, while coating the surface of a treatment target with an extremely thin film, a coating whose hydrophilicity is unlikely to be lowered even when the coating is brought into contact with fats and the like to the surface of the treatment target and a surface treatment method using the surface treatment liquid described above. In a surface treatment liquid containing a resin (A) and a solvent (S), as the resin (A), a resin is used which includes a constituent unit (a1) that includes an organic group including a quaternary ammonium cation group and having a sulfonic acid anion group at a terminal and that is derived from an N-substituted (meth) acrylamide, and includes a reactive silyl group in at least one of molecular chain terminals, the concentration of the resin (A) in the surface treatment liquid is less than 2 mass % and the pH of the surface treatment liquid is 4 or less.

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Номер записи: 98
22-01-2015 дата публикации

CAPACITOR WITH MULTIPLE ELEMENTS FOR MULTIPLE REPLACEMENT APPLICATIONS

Номер: US20150022991A1
Автор: Sirotiak Shaun Brandon, Stockman Richard W., Stockman Robert M.
Принадлежит:

An apparatus includes a case having an elliptical cross-section capable of receiving a plurality of capacitive elements. One or more of the capacitive elements provide at least one capacitor having a first capacitor terminal and a second capacitor terminal. The apparatus also includes a cover assembly that includes a deformable cover mountable to the case, and, a common cover terminal having a contact extending from the cover. The cover assembly also includes at least three capacitor cover terminals, each of the at least three capacitor cover terminals having at least one contact extending from the deformable cover. The deformable cover is configured to displace at least one of the at least three capacitor cover terminals upon an operative failure of at least one of the plurality of the capacitive elements. The cover assembly also includes at least four insulation structures. One of the four insulation structures is associated with one of the at least three capacitor cover terminals. The apparatus also includes a first conductor capable of electrically connecting the first capacitor terminal of a capacitor provided by one of the plurality of capacitive elements to one of the at least three capacitor cover terminals and a second conductor capable of electrically connecting the second capacitor terminal of the capacitor provided by one of the plurality of capacitive elements to the common cover terminal. 1. An apparatus comprising:a case having an elliptical cross-section capable of receiving a plurality of capacitive elements, one or more of the capacitive elements providing at least one capacitor having a first capacitor terminal and a second capacitor terminal; a deformable cover mountable to the case,', 'a common cover terminal having a contact extending from the cover,', 'at least three capacitor cover terminals, each of the at least three capacitor cover terminals having at least one contact extending from the deformable cover, wherein the deformable cover is ...

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Номер записи: 99
16-01-2020 дата публикации

Organic el image display device

Номер: US20200020888A1
Автор: Daisuke Kashiwagi, Rikio Inoue
Принадлежит: Fujifilm Corp

The present invention provides an organic EL image display device including a reflecting layer, an organic electroluminescent layer group, a polarization separation layer, and a circularly polarizing plate in this order, in which the polarization separation layer includes polarization separation sites arranged in a matrix form corresponding to the organic electroluminescent layer group, the polarization separation site reflects light of one polarization state and transmits light of the other polarization state in light emitted from the corresponding organic electroluminescent layer, the polarization separation layer is divided by a visible light transmission region to form the polarization separation sites, and a wavelength range of the reflection is wider than a wavelength range of the light emission. The organic EL image display device according to the present invention has high brightness at the time of both front observation and oblique observation and little image blurring.

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Номер записи: 100