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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 6607. Отображено 101.
08-02-2018 дата публикации

SEMI-CRYSTALLINE THERMOPLASTIC POLYESTER FOR PRODUCING BIORIENTED FILMS

Номер: WO2018024993A1
Принадлежит:

Use of a semi-crystalline thermoplastic polyester for producing bioriented films, said polyester having at least one 1,4:3,6-dianhydrohexitol unit (A), at least one alicyclic diol unit (B) other than the 1,4:3,6-dianhydrohexitol units (A), and at least one terephthalic acid unit (C), wherein the molar ratio (A)/[(A)+(B)] is at least 0.05 and at most 0.30, said polyester being free of non-cyclic aliphatic diol units or comprising a molar amount of non-cyclic aliphatic diol units, relative to the totality of monomeric units in the polyester, of less than 5%, and with a reduced viscosity in solution (25°C; phenol (50 wt.%): ortho-dichlorobenzene (50 wt.%); 5 g/L of polyester) greater than 50 mL/g.

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27-09-2012 дата публикации

Polyol Acrylates for Use in Energy Curable Inks

Номер: US20120245246A1
Принадлежит: Stepan Co

Polyol acrylates are disclosed that are the reaction products of a modified polyol and a (meth)acrylic acid or derivative thereof. The modified polyols used in preparing the polyol acrylates are the reaction product of a natural oil or fatty carboxylic acid or derivative thereof with a polyol selected from the group consisting of polyester polyols, polyether polyols, polyester ether polyols and polyalcohols such that the natural oil or fatty carboxylic acid or derivative thereof is incorporated into the backbone of the polyol. The polyol acrylates are used to prepare pigment dispersions that are useful in formulating energy curable ink compositions.

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08-11-2012 дата публикации

Polyester process

Номер: US20120283392A1
Автор: Guerino G. Sacripante
Принадлежит: Xerox Corp

The present disclosure provides processes for the preparation of unsaturated polyesters. In embodiments, a process of the present disclosure includes reacting an organic diol with a cyclic alkylene carbonate in the presence of a first catalyst to thereby form a polyalkoxy diol, optionally adding thereto a further amount of cyclic alkylene carbonate in the presence of a second catalyst, and subsequently polycondensing the resulting mixture with a dicarboxylic acid in combination with an anhydride.

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15-11-2012 дата публикации

Polyester resin and optical lens

Номер: US20120289676A1
Принадлежит: Mitsubishi Gas Chemical Co Inc

A polyester resin having a diol unit containing a unit derived from ethylene glycol and a unit derived from a diol represented by the following formula (I), and a dicarboxylic acid unit containing a unit derived from an aromatic dicarboxylic acid in an amount of 50 mol % or more; wherein the entire diol unit contains the unit derived from ethylene glycol in an amount of 40 to 99 mol %, and the unit derived from a diol represented by formula (I) in an amount of 1 to 60 mol %: wherein A represents an aromatic ring selected from the group consisting of benzene, naphthalene, anthracene, phenanthrene and pyrene; R 1 represents a C1 to C12 alkyl group, a substituted or unsubstituted C6 to C12 aryl group or a halogen atom; n represents an integer of 0 to 4; and when plural R 1 s are present, R 1 s may be the same as or different from each other.

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04-04-2013 дата публикации

Electrostatic image developing toner and manufacturing method of the same, electrostatic image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method

Номер: US20130084520A1
Принадлежит: Fuji Xerox Co Ltd

An electrostatic image developing toner of the exemplary embodiment of the invention contains an amorphous first polyester resin of a polycondensation product of at least a carboxylic acid component and an alcohol component containing rosin, and a second polyester resin having the difference (absolute value) in parameter of solubility relative to the first polyester resin of from about 0.3 (cal/cm 3 ) 1/2 to about 3 (cal/cm 3 ) 1/2 .

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18-04-2013 дата публикации

Polyester compositions containing furandicarboxylic acid or an ester thereof and ethylene glycol

Номер: US20130095269A1
Принадлежит: Eastman Chemical Co

Described are polyesters comprising (a) a dicarboxylic acid component comprising 2,5-furandicarboxylic acid residues; optionally, aromatic dicarboxylic acid residues and/or modifying aliphatic dicarboxylic acid residues and ethylene glycol residues. The polyesters may be manufactured into articles such as fibers, films, bottles, coatings, or sheets.

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18-04-2013 дата публикации

Polyester compositions containing furandicarboxylic acid or an ester thereof, cyclobutanediol and ethylene glycol

Номер: US20130095272A1
Принадлежит: Eastman Chemical Co

Described are polyesters comprising (a) a dicarboxylic acid component comprising 2,5-furandicarboxylic acid residues; optionally, aromatic dicarboxylic acid residues and/or modifying aliphatic dicarboxylic acid residues, 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and ethylene glycol. The polyesters may be manufactured into articles such as fibers, films, bottles, coatings, or sheets.

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23-05-2013 дата публикации

POLYMERIZATION WITH ENHANCED GLYCOL ETHER FORMATION

Номер: US20130129951A1
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

The processes disclosed herein provide methods for dehydrating diols such that dimers of the diols are formed and incorporated into polyesters during polycondensation. Control over this phenomenon provides unique polymer compositions with a range of thermo-mechanical properties, crystallinity, bio-content and biodegradability. Generation of a wide range of properties allows development of polymers that can be used for a wide range of applications. 2. The blend of wherein the other polymer is a natural polymer.3. The blend of wherein the natural polymer is a starch.4. A shaped article formed from the blend of .5. A shaped article of selected from the group consisting of films claim 4 , sheets claim 4 , fibers claim 4 , melt blown containers claim 4 , molded parts claim 4 , and foamed parts.6. A process for making an aliphatic-aromatic copolyetherester claim 4 , comprising:a. combining one or more dicarboxylic acid monomers or diester derivatives thereof with a diol in the presence of an ester interchange catalyst to form a first reaction mixture of an ester interchange reaction;b. heating the first reaction mixture with mixing to a temperature between about 200 degrees C. and about 260 degrees C., whereby volatile products of the ester interchange reaction are distilled off, to form a second reaction mixture; andc. polycondensing the second reaction mixture with stirring at a temperature between about 240 degrees C. and 260 degrees C. under vacuum to form the aliphatic-aromatic copolyetherester.7. The process of claim 6 , wherein the diol consists essentially of 100 mole percent of a single glycol component based on 100 mole percent total glycol component.8. The process of or claim 6 , wherein the diol is added in an excess of between about 10% and 100% relative to that needed to provide equimolar proportions of hydroxyl moieties and carboxylic acid moieties or ester-forming derivatives thereof to the reaction vessel.9. The process of or claim 6 , wherein the ester ...

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30-05-2013 дата публикации

RESIN COMPOSITION COMPRISING ISOSORBIDE CONTAINING SATURATED POLYMER

Номер: US20130137823A1
Принадлежит:

The present invention relates to a resin composition comprising (a) an unsaturated polyester resin and/or a vinyl ester resin, (b) a reactive diluent and (c) a saturated polymer soluble in the reactive diluent, wherein the saturated polymer comprises isosorbide building blocks and has a molecular weight Mof at least 1500 Dalton. 1. A resin composition comprising (a) an unsaturated polyester resin and/or a vinyl ester resin , (b) a reactive diluent and (c) a saturated polymer soluble in the reactive diluent , characterized in that the saturated polymer comprises isosorbide building blocks and has a number-average molecular weight Mof at least 1500 Dalton.2. A resin composition according to claim 1 , characterized in that the saturated polymer soluble in the reactive diluent is a saturated polyester.3. A resin composition according to claim 2 , characterized in that the saturated polyester comprises claim 2 , next to the isosorbide building blocks claim 2 , saturated aliphatic dicarboxylic acid building blocks.4. A resin composition according to claim 3 , characterized in that the saturated aliphatic dicarboxylic acid has the following formula HOOC—(CH)—COOH claim 3 , in which x is an integer from 1 up to 20.5. A resin composition according to claim 4 , characterized in that x is 4.6. A resin composition according to claim 1 , characterized in that the resin composition comprises an unsaturated polyester resin.7. A resin composition according to claim 1 , characterized in that the saturated polymer has a bimodal molecular weight distribution obtained by chain extension.9. A resin composition according to claim 1 , characterized in that the composition comprises from 10 up to 70 wt. % of component (a) claim 1 , from 5 up to 50 wt. % of component (b) and from 2 up to 70 wt. % of component (c) (whereby the total amount of (a) claim 1 , (b) and (c) is considered 100 wt. %).11. An isosorbide containing polymer according to claim 10 , characterized in that P has a molecular ...

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13-06-2013 дата публикации

BIODEGRADABLE SHAPE MEMORY POLYMER

Номер: US20130150533A1
Принадлежит:

A shape-memory polymers comprising at least one monomer subunit represented by the following structural formula (1). 2. The compound of claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , Rand Rfor each occurrence is independently selected from a hydrogen claim 1 , a C1-C12 alkyl claim 1 , a C3-C12 cycloalkyl claim 1 , a C2-C12 alkenyl claim 1 , a C3-C12 cycloalkenyl claim 1 , a C3-C12 cycloalkynyl claim 1 , a C2-C12 alkynyl claim 1 , a (C6-C18)aryl(C6-C12)alkyl claim 1 , or a (C6-C18)heteroaryl(C6-C12)alkyl.3. The compound of claim 2 , wherein L is selected from —X— claim 2 , —C(X)— claim 2 , —N(R)— claim 2 , —C(X)X— claim 2 , —XC(X)— claim 2 , —C(X)NR— claim 2 , —NRC(X)—.4. The compound of claim 3 , wherein R claim 3 , R claim 3 , Rand Reach is hydrogen.5. The compound of claim 4 , wherein k and n are each independently is from 0 to 3.6. The compound of claim 5 , wherein X is O.7. The compound of claim 6 , wherein Ar is a C6-C18 aryl.8. The compound of claim 7 , wherein:R for each occurrence is independently selected from a hydrogen, a C1-C12 alkyl, a C3-C12 cycloalkyl, a C2-C12 alkenyl, a (C6-C18)aryl(C6-C12)alkyl, or a (C6-C18)heteroaryl(C6-C12)alkyl; andL is selected from —C(X)—, —C(O)O—, or —OC(O)—.9. The compound of claim 8 , wherein k and n are each independently from 0 to 2.14. The polymer of claim 13 , wherein the polymer comprises from 1 to 99% by weight of the repeat units of structural formula (III).15. The polymer of claim 14 , wherein the polymer comprises from 20 to 50% by weight of the repeat units of structural formula (III).16. The polymer of claim 12 , further comprising at least one initiator.17. The polymer of claim 15 , wherein the initiator is of 2 claim 15 ,2′-(ethane-1 claim 15 ,2-diylbis(oxy))diethanol.18. The polymer of claim 13 , wherein R claim 13 , R claim 13 , R claim 13 , Rand Rfor each occurrence is independently selected from a hydrogen claim 13 , a C1-C12 alkyl claim 13 , a C3-C12 cycloalkyl claim 13 , a C2-C12 alkenyl claim 13 ...

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20-06-2013 дата публикации

ALIPHATIC-AROMATIC COPOLYETHERESTERS

Номер: US20130158168A1
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

Provided are aliphatic-aromatic copolyetheresters that can exhibit biodegradation with improved physical properties. The copolyetheresters can be blended with other polymeric materials, and are useful for making a variety of shaped articles. The aliphatic-aromatic copolyetheresters can include combinations of terephthalic acid or ester with linear aliphatic, or a non-linear dicarboxylic acid or ester, that is condensed with a linear glycol and a polyalkylene ether glycol. 1. An aliphatic-aromatic copolyetherester consisting essentially of:a) a dicarboxylic acid component consisting essentially of terephthalic acid; andb) a glycol component consisting essentially of, based on 100 mol-% total glycol component:i. 99.5 to 30 mol-% of a linear glycol; andii. 0.5 to 70 mol-% of a polyalkylene ether glycol having a molecular weight within the range of 200 to 4,000 Da.2. An aliphatic-aromatic copolyetherester consisting essentially of:a) a dicarboxylic acid component consisting essentially of: less than 100 to 40 mol-% terephthalic acid, and up to 60 mol-% of a linear aliphatic dicarboxylic acid or derivative thereof; andb) a glycol component consisting essentially of, based on 100 mol-% total glycol component:i. 99.5 to 30 mol-% of a linear glycol; andii. 0.5 to 70 mol-% of a polyalkylene ether glycol having a molecular weight within the range of 200 to 4,000 Da.3. An aliphatic-aromatic copolyetherester consisting essentially of:a) a dicarboxylic acid component consisting essentially of: 98 to 40 mol-% of terephthalic acid, and 2 to 60 mol-% of a non-linear dicarboxylic acid component, which is not terephthalic acid, or a derivative thereof; andb) a glycol component consisting essentially of, based on 100 mol-% total glycol component:i. 99.5 to 30 mol-% of a linear glycol; andii. 0.5 to 70 mol-% of a polyalkylene ether glycol having a molecular weight within the range of 200 to 4,000 Da.4. An aliphatic-aromatic copolyetherester consisting essentially of:a) a dicarboxylic ...

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11-07-2013 дата публикации

ADVANCED POLY EPOXY ESTER RESIN COMPOSITIONS

Номер: US20130178591A1
Принадлежит: Dow Global Technologies LLC

A poly epoxy ester resin composition of the following chemical structure: where n is a number from 2 to about 3000; each m independently has a value of 0 or 1; each Ris independently —H or —CH; each Ris independently —H or a Cto Calkylene radical (saturated divalent aliphatic hydrocarbon radical), Ar is a divalent aryl group or heteroarylene group;_and X is cycloalkylene group, including substituted cycloalkylene group, where the substitute group include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substitute group, for example, a halogen, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between. 2. The composition of claim 1 , wherein the advanced poly epoxy ester resin polymeric composition comprises a reaction product of (a) at least one cycloaliphatic diglycidyl ether compound claim 1 , and (b) at least one aromatic dicarboxylic acid compound.3. The composition of claim 2 , wherein the at least one cycloaliphatic diglycidyl ether compound comprises a diglycidyl ether of cyclohexanedimethanol.4. The composition of claim 2 , wherein the at least one cycloaliphatic diglycidyl ether compound comprises a diglycidyl ether of cis-1 claim 2 ,3-cyclohexanedimethanol and/or a diglycidyl ether of trans-1 claim 2 ,3-cyclohexanedimethanol.5. The composition of claim 2 , wherein at least one cycloaliphatic diglycidyl ether compound comprises a diglycidyl ether of cis-1 claim 2 ,4-cyclohexanedimethanol and/or a diglycidyl ether of trans-1 claim 2 ,4-cyclohexanedimethanol.6. The composition of claim 2 , wherein the at least one cycloaliphatic diglycidyl ether compound comprises a diglycidyl ether of cis-1 claim 2 ,3-cyclohexanedimethanol claim 2 , a diglycidyl ether of trans-1 claim 2 ,3-cyclohexanedimethanol claim 2 , a diglycidyl ether of cis-1 claim 2 ,4-cycloexanedimethanol claim 2 , and/or a diglycidyl ether of trans-1 ...

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08-08-2013 дата публикации

Polyester Concentrates Having High Stability In Solution And Having A Greying-Inhibiting Effect

Номер: US20130200290A1
Принадлежит: Clariant Finance BVI Ltd

The invention relates to an aqueous polyester concentrate having a proportion by weight of polyesters of 12 to 60%, wherein the polyesters are obtainable by means of polymerisation of the components selected from a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R 1 O(CHR 2 CHR 3 O) n H ( 1 ), where R 1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R 2 and R 3 , independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and n is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH 2 CH 2 ) m —SO 3 X (2), where m is an integer of from 1 to 10 and X is hydrogen or an alkali metal ion, and g) optionally one or more cross-linking polyfunctional compounds, provided that at least one of the components b) or f) is present, and provided further that the molar ratio of the components c) 1,2-propylene glycol to d) ethylene glycol is greater than or equal to 1.60.

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08-08-2013 дата публикации

METHOD FOR PRODUCING AQUEOUS DISPERSION OF RESIN FINE PARTICLES AND METHOD FOR PRODUCING TONER

Номер: US20130202998A1
Принадлежит: CANON KABUSHIKI KAISHA

The present invention provides a method for producing an aqueous dispersion of resin fine particles wherein the particle size of the obtained resin particles is small and the aqueous dispersion is excellent in productivity, the production method including: mixing a resin having an acid group, a betaine surfactant and a solvent capable of dissolving the resin having an acid group to obtain a mixture; and emulsifying the mixture by placing the mixture in an aqueous medium and by applying shear force to the mixture under a condition of pH=7.0 or more to obtain an emulsion. 1. A method for producing an aqueous dispersion of resin fine particles , comprising the steps of:(A-1) preparing a mixture A by mixing a resin having an acid group, a betaine surfactant and a solvent capable of dissolving the resin; and(A-2) preparing an emulsion A by adding the mixture A into an aqueous medium, and applying shear force to the mixture A in the aqueous medium under a condition of pH=7.0 or more.2. The method for producing an aqueous dispersion of resin fine particles according to claim 1 , wherein the betaine surfactant comprises a carboxylate group.3. The method for producing an aqueous dispersion of resin fine particles according to claim 1 , wherein the betaine surfactant is an amide betaine.4. A method for producing an aqueous dispersion of resin fine particles claim 1 , comprising:(B-1) preparing a mixture B by mixing a resin having an acid group, a betaine surfactant and an aqueous medium; and(B-2) preparing an emulsion B by applying shear force to the resin in the mixture B under a condition of pH=7.0 or more and at a temperature equal to or higher than the glass transition temperature (Tg) of the resin.5. The method for producing an aqueous dispersion of resin fine particles according to claim 4 , wherein the betaine surfactant comprises a carboxylate group.6. The method for producing an aqueous dispersion of resin fine particles according to claim 4 , wherein the betaine ...

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22-08-2013 дата публикации

Terminal Silicone Capped Regiospecific Glycerin Polyesters

Номер: US20130217837A1
Автор: OLenick Thomas G.
Принадлежит:

The present invention is directed to a series of glycerin based polymers that have been designed to have very specific substitution patterns, herein referred to as regiospecific substitution (RSS). The attachment of terminal mono-functional silicone polymers engineered polyesters of glycerin results in heretofore unrecognized products. The unique properties include lower surface tension, better spreadability and a dry skin feel, all of which cannot be attained without the use of a terminal silicone. Incorporation of silicone into the terminal position requires a very specific synthesis regime to establish the sought after regiospecificity. 2. A polyester of wherein a is 1.3. A polyester of wherein a is 5.4. A polyester of wherein a is 20.5. A polyester of wherein Ris derived from dimer acid.6. A polyester of wherein Ris an alkyl having 18 carbons.7. A polyester of wherein Ris an alkyl having 7 carbons.9. A polyester of wherein a is 1.10. A polyester of wherein a is 5.11. A polyester of wherein a is 20.12. A polyester of wherein Ris dimer acid.13. A polyester of wherein Ris an alkyl having 18 carbons.14. A polyester of wherein Ris an alkyl having 7 carbons.15. A polyester of wherein Ris an alkyl having 18 carbons.17. A process of wherein said effective conditioning concentration ranges from 0.1% to 45% by weight.18. A process of wherein said effective conditioning concentration ranges from 1% to 20% by weight.20. A process of wherein said effective conditioning concentration ranges from 0.1% to 45% by weight. This application is a continuation in part of co-pending U.S. serial number 13/373,974, filed Dec. 8, 2011.The present invention is directed to a series of glycerin-based polymers that have been designed to have very specific substitution patterns, herein referred to as regio-specific substitution (RSS). The attachment of terminal mono-functional silicone polymers engineered polyesters of glycerin results in heretofore unrecognized products. The unique ...

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29-08-2013 дата публикации

POLYESTER RESIN, METHOD OF PRODUCING THE SAME, COMPOSITION FOR MOLDED ARTICLE AND MOLDED ARTICLE

Номер: US20130225784A1
Автор: Eritate Shinji
Принадлежит: CANON KABUSHIKI KAISHA

A polyester resin that can be used for producing a molded article having excellent impact resistance, and a method of producing the polyester resin. The polyester resin has structural units represented by general formulae (1) and (2), and contains the structural unit represented by the general formula (2) at a content of 50.1 mol % or more to 99.9 mol % or less with respect to the total of the structural units represented by the general formulae (1) and (2). The method of producing a polyester resin includes copolymerizing a furandicarboxylic acid or an ester thereof with ethylene glycol and diethylene glycol. In the formula, Rrepresents an aromatic hydrocarbon group which may be substituted, or an aliphatic hydrocarbon group which may be substituted. 2. The polyester resin according to claim 1 , wherein Rrepresents an ethylene group claim 1 , and Rrepresents an ethylene group.3. A composition for a molded article comprising the polyester resin according to .4. A molded article obtained by molding the composition according to .5. A method of producing a polyester resin claim 3 , consisting essentially of copolymerizing one of a furandicarboxylic acid and an ester thereof with ethylene glycol and polyethylene glycol.6. A method of producing a polyester resin claim 3 , consisting essentially of copolymerizing one of a furandicarboxylic acid and an ester thereof with ethylene glycol and polyalkylene glycol. This application is a divisional of application Ser. No. 12/441,797, which was the National Stage of International Application No. PCT/JP2009/053123, filed Feb. 17, 2009, which claims the benefit of Japanese Patent Application No. 2008-039360, filed Feb. 20, 2008. All prior applications are hereby incorporated by reference herein in their entirety.The present invention relates to a polyester resin useful for various resin materials, a method of producing the polyester resin, a composition for a molded article, and a molded article.Polymer materials typified by, for ...

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05-09-2013 дата публикации

Methods and Compounds For Detection of Molecular Targets

Номер: US20130230853A1
Автор: Jesper Lohse
Принадлежит: Dako Denmark ApS

The present invention relates to methods and compounds for detection of molecular targets, such as biological or chemical molecules, or molecular structures, in samples using a host of experimental schemes for detecting and visualizing such targets, e.g. immunohistochemistry (IHC), in situ hybridization (ISH), ELISA, Southern, Northern, and Western blotting, etc.

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19-09-2013 дата публикации

Polyester resin for toner, electrostatic charge image developing toner, electrostatic charge image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method

Номер: US20130244171A1
Принадлежит: Fuji Xerox Co Ltd

A polyester resin for a toner is a polycondensate of a dicarboxylic acid component and an alcohol component including rosin diol that is represented by the following formula (1), and has a weight average molecular weight (Mw) of from 40000 to 150000, and a molecular weight distribution (Mw/Mn) of from 12 to 25: wherein, R 1 and R 2 each independently represents hydrogen or a methyl group; L 1 , L 2 , and L 3 each independently represents a divalent linking group selected from a group consisting of a carbonyl group, a carboxyl group, an ether group, a sulfonyl group, a chain-like alkylene group which may have a substituent, a cyclic alkylene group which may have a substituent, an arylene group which may have a substituent, and combinations thereof, and L 1 and L 2 or L 1 and L 3 may form a ring; and A 1 and A 2 represent a rosin ester group.

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03-10-2013 дата публикации

UNSATURATED POLYESTER RESIN COMPOSITION FOR USE IN LED REFLECTOR, AND LED REFLECTOR AND LED LUMINAIRE USING SAID COMPOSITION

Номер: US20130261243A1
Автор: Kubo Toshio, Nagaoka Sunao
Принадлежит: Panasonic Corporation

Provided are a resin composition for general-purpose LED reflectors, which discolors little through thermal deterioration and is excellent in heat discoloration resistance, which can provide an LED lamp using it and having a long life, which is relatively inexpensive and has good storage stability, and which is excellent in handleability and workability, and an LED reflector and an LED luminaire using the resin composition. 112-. (canceled)13. A dry-type unsaturated polyester resin composition containing at least an unsaturated polyester resin , a polymerization initiator , an inorganic filler , a white pigment , a release agent and a reinforcing material , wherein the unsaturated polyester resin is within a range of from 14 to 40% by mass relative to the entire amount of the composition , the total amount of the inorganic filler and the white pigment is within a range of from 44 to 74% by mass relative to the entire amount of the composition , the proportion of the white pigment to the total amount of inorganic filler and the white pigment is at least 30% by mass , and the unsaturated polyester resin is an unsaturated alkyd resin mixed with a crosslinking agent.14. The unsaturated polyester resin composition for LED reflectors according to claim 13 , wherein the inorganic filler is at least one selected from a group consisting of silica claim 13 , aluminium hydroxide claim 13 , aluminium oxide claim 13 , magnesium oxide claim 13 , barium sulfate claim 13 , magnesium carbonate and barium carbonate.15. The unsaturated polyester resin composition for LED reflectors according to claim 13 , wherein the white pigment is at least one selected from a group consisting of titanium oxide claim 13 , barium titanate claim 13 , strontium titanate claim 13 , aluminium oxide claim 13 , magnesium oxide claim 13 , zinc oxide claim 13 , barium sulfate claim 13 , magnesium carbonate and barium carbonate.16. The unsaturated polyester resin composition for LED reflectors according to ...

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09-01-2014 дата публикации

Bio-based polyester latex

Номер: US20140011931A1
Принадлежит: Oce Technologies BV

The present invention relates to a copolyester from between 30 and 50 mol % of a first monomer being an isohexide; between 40 and 60 mol % of a second monomer being an aromatic dicarboxylic acid or a cycloaliphatic dicarboxylic acid; and between 1 and 20 mol % of a third monomer being an aliphatic diol, the copolyester having an acid number of between 10 and 50. The invention also relates to a process for preparing such copolyesters, a latex composition comprising such a copolyester, a method for preparing such a latex composition and the use of a particular latex as an (ink-jet) ink.

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16-01-2014 дата публикации

REACTANT COMPOSITION AND POLYESTER MADE THEREFROM

Номер: US20140018512A1
Принадлежит: FAR EASTERN NEW CENTURY CORPORATION

A reactant composition includes: a diol component; a diacid-derived component; and a modifier represented by the following formula (I): 2. The reactant composition as claimed in claim 1 , wherein said modifier is 1 claim 1 ,2 claim 1 ,2-trimethyl-1 claim 1 ,3-bis(hydroxymethyl)cyclopentane.3. The reactant composition as claimed in claim 1 , wherein said modifier is prepared from 1 claim 1 ,7 claim 1 ,7-trimethylbicyclo[2.2.1]heptan-2-one.4. The reactant composition as claimed in claim 1 , wherein said modifier is present in an amount ranging from 1 to 30 mol % based on total moles of said diol component and said modifier.5. The reactant composition as claimed in claim 1 , wherein said modifier is present in an amount ranging from 3 to 25 mol % based on the total moles of said diol component and said modifier.6. The reactant composition as claimed in claim 1 , wherein said diacid-derived component is selected from the group consisting of aromatic diacid claim 1 , alkyl ester of aromatic diacid claim 1 , aliphatic diacid claim 1 , alkyl ester of aliphatic diacid claim 1 , and combinations thereof.7. The reactant composition as claimed in claim 1 , wherein said diacid-derived component is terephthalic acid or dimethyl terephthalate.8. The reactant composition as claimed in claim 1 , said diol component is a C-Caliphatic diol.10. The polyester as claimed in claim 9 , wherein at least one of X claim 9 , X claim 9 , and Xis an arylene group.11. The polyester as claimed in claim 9 , wherein R claim 9 , R claim 9 , and Rindependently represent a methyl group. This application claims priority of Taiwanese Patent Application No. 101125314, filed on Jul. 13, 2012.1. Field of the InventionThe present invention relates to a reactant composition and a polyester made from the reactant composition and having a relatively high glass transition temperature.2. Description of the Related ArtPolyesters are formed by virtue of condensation polymerization of diol (or polyol) components ...

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13-02-2014 дата публикации

Oil in water emulsion

Номер: US20140045974A1
Принадлежит: DSM IP ASSETS BV

The present invention relates to an oil-in-water emulsion, wherein the oil comprises an acid functional unsaturated polyester which acid functional unsaturated polyester comprises unsaturated dicarboxylic acid units, diol units, units of an emulsifier with HLB value of from 9 to 20 and further comprising chain extender units. The present invention further relates to a fibre mat comprising fibres and a binder comprising such acid functional unsaturated polyester.

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27-02-2014 дата публикации

THERMOPLASTIC POLYESTER ELASTOMER RESIN COMPOSITION AND MOLDING ARTICLE COMPRISING THE SAME

Номер: US20140058019A1
Принадлежит: LG CHEM, LTD.

Disclosed are a thermoplastic polyester elastomer resin composition and a molded article comprising the same. More specifically, disclosed is a thermoplastic polyester elastomer resin composition which comprises a glycidyl group-modified ethylene-octene based copolymer resin, as a chain extension/hydrolysis resistance agent for blow and extrusion molding to improve melt viscosity, and increases a molecular weight through reaction extrusion and thus exhibits superior heat resistance, weather resistance, heat aging resistance, hydrolysis resistance, fatigue resistance properties, melt viscosity and parison stability, and in particular, exhibits superior blow molding, contains no gel, reduces production of odor-causing substances such as volatile organic compounds (TVOC) during blow molding, and maintains a balance between physical properties, moldability and operation environments 1. A thermoplastic polyester elastomer resin composition comprising:a copolyetherester elastomer resin;a polyalkylene dicarboxylate-based resin; anda glycidyl group-modified ethylene-octene based copolymer (EOR-GMA),wherein the glycidyl group-modified ethylene-octene based copolymer (EOR-GMA) is present in an amount exceeding 1% by weight in the composition.2. The thermoplastic polyester elastomer resin composition according to claim 1 , wherein the copolyetherester elastomer resin is a resin obtained by melt polymerizing aromatic decarboxylic acid or an ester-forming derivative thereof claim 1 , a lower aliphatic diol and polyalkylene oxide claim 1 , and then solid state polymerizing the product.3. The thermoplastic polyester elastomer resin composition according to claim 1 , wherein the copolyetherester elastomer resin is present in an amount of 60 to 88% by weight in the composition.4. The thermoplastic polyester elastomer resin composition according to claim 1 , wherein the copolyetherester elastomer resin has a melt flow index (MFI) of 1 to 10 g/10 min (230° C. claim 1 , 2.16 kg).5. The ...

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06-03-2014 дата публикации

Polymer in multicoat color and/or effect paint systems

Номер: US20140065428A1
Принадлежит: BASF COATINGS GMBH

Disclosed is a polymer which is prepared by reacting (a) dimer fatty acids with (b) at least one polyether of general structural formula (I) where R is a C 3 to C 6 alkylene radical and n is selected accordingly such that said polyether has a number-average molecular weight of 450 to 2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting polymer has a number-average molecular weight of 1500 to 5000 g/mol and an acid number <10 mg KOH/g. Also disclosed is a pigmented aqueous basecoat material which comprises this polymer, and the use of said polymer in pigmented aqueous basecoat materials. It further relates to a method for producing multicoat paint systems, and also to the multicoat paint systems producible by means of said method. Moreover, the present invention relates to the refinish of defect areas on multicoat paint systems.

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04-01-2018 дата публикации

CROSSLINKABLE COATING COMPOSITIONS FORMULATED WITH DORMANT CARBAMATE INITIATOR

Номер: US20180000720A1
Принадлежит: ELEMENTIS SPECIALTIES, INC.

A crosslinkable coating composition comprising: ingredient A that has at least two protons that can be activated to form a Michael carbanion donor; ingredient B that functions as a Michael acceptor having at least two ethylenically unsaturated functionalities each activated by an electron-withdrawing group; and a dormant carbamate initiator of Formula (1) 2. The crosslinkable coating composition according to claim 1 , wherein the ingredient A is independently selected from a malonate group containing compound claim 1 , a malonate group containing oligomer claim 1 , a malonate group containing polymer claim 1 , an acetoacetate group containing compound claim 1 , an acetoacetate group containing oligomer claim 1 , an acetoacetate group containing polymer or combinations thereof.3. The crosslinkable coating composition according to claim 2 , wherein the malonate group containing compound claim 2 , malonate group containing oligomer claim 2 , malonate group containing polymer claim 2 , an acetoacetate group containing compound claim 2 , acetoacetate group containing oligomer claim 2 , or acetoacetate group containing polymer are each selected from the group consisting of: polyurethanes claim 2 , polyesters claim 2 , polyacrylates claim 2 , epoxy polymers claim 2 , polyamides claim 2 , polyesteramides or polyvinyl polymers claim 2 , wherein such compounds claim 2 , oligomers or polymers have (i) a malonate group claim 2 , (ii) an acetoacetate group or (iii) combinations thereof located in a main chain of such compound or oligomer or polymer or a side chain of such compound or oligomer or polymer.4. The crosslinkable coating composition according to claim 3 , wherein ingredient B is selected from the group consisting of acrylates claim 3 , fumarates claim 3 , maleates and combinations thereof.5. The crosslinkable coating composition according to claim 4 , wherein the acrylate is independently selected from the group consisting of hexanediol diacrylate claim 4 , ...

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05-01-2017 дата публикации

A POLYOL BASED ON DIMER FATTY ACID RESIDUES AND THE CORRESPONDING POLYURETHANES

Номер: US20170002134A1
Принадлежит: Croda International PLC

The present invention relates to a polyol comprising a) at least one dimer fatty residue selected from a dimer fatty diacid residue and a dimer fatty diol residue; and b) at least one residue of a linear or branched C17 to C32 dicarboxylic acid or diol; wherein the polyol comprises at least two hydroxyl end groups. The invention also relates to a a polyurethane comprising the polyol, the use of the polyol and a method of making the polyurethane. 1. A polyol comprising:a) at least one dimer fatty residue selected from a dimer fatty diacid residue and a dimer fatty diol residue; andb) at least one residue of a linear or branched C17 to C32 dicarboxylic acid or diol;wherein the polyol comprises at least two hydroxyl end groups.2. A polyol as claimed in wherein the C17 to C32 dicarboxylic acid or diol is a linear dicarboxylic acid or diol.3. A polyol as claimed in wherein the weight ratio of a) to b) in the polyol is in the range 90:10 to 30:70.4. A polyol as claimed in wherein the weight % of a) in the polyol is at least the weight % of b) in the polyol.5. A polyol as claimed in wherein the C17 to C32 dicarboxylic acid or diol is a C18 to C26 dicarboxylic acid or diol.6. A polyol as claimed in wherein the C17 to C32 dicarboxylic acid or diol is derived from a C17 to C32 diacid or dialkyl ester which is obtained by a metathesis reaction.7. A polyol as claimed in which further comprises:c) at least one residue of a C2 to C16 acid or alcohol which has at least 2 functional groups selected from a carboxylic acid group, a hydroxyl group and mixtures thereof.8. A polyol as claimed in wherein c) is at least one residue of a diol comprising from 2 to 10 carbon atoms.9. A polyol as claimed in wherein the weight % of a) in the polyol is greater than the weight % of c) in the polyol.10. A polyol as claimed in wherein the weight % of b) in the polyol is greater than the weight % of c) in the polyol.11. A polyurethane comprising a polyol as claimed in .12. A polyurethane as claimed ...

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05-01-2017 дата публикации

Liquid Crystalline Polymer for Use in Melt-Extuded Articles

Номер: US20170002137A1
Автор: Nair Kamlesh P.
Принадлежит:

A melt-polymerized liquid crystalline polymer is provided that comprises repeating units (1) to (5): 2. The liquid crystalline polymer of claim 1 , wherein the repeating units (2) claim 1 , (3) claim 1 , (4) claim 1 , and (5) each constitutes from about 1 mole % to about 30 mole % of the polymer.3. The liquid crystalline polymer of claim 1 , wherein the repeating units (3) are used in a molar amount greater than the repeating units (2).4. The liquid crystalline polymer of claim 1 , wherein the repeating units (5) are used in a molar amount greater than the repeating units (4).5. The liquid crystalline polymer of claim 1 , wherein l claim 1 , m claim 1 , n claim 1 , o claim 1 , p claim 1 , and/or q are 0.6. The liquid crystalline polymer of wherein the repeating units (1) are derived from HBA claim 1 , the repeating units (2) are derived from BP claim 1 , the repeating units (3) are derived from HQ claim 1 , the repeating units (4) are derived from TA claim 1 , and the repeating units (5) are derived from IA.7. The liquid crystalline polymer of claim 1 , wherein the polymer is wholly aromatic.8. The liquid crystalline polymer of claim 1 , wherein the polymer contains less than about 5 mol. % of repeating units derived from NDA claim 1 , HNA claim 1 , or a combination thereof.9. The liquid crystalline polymer of claim 1 , wherein the polymer contains less than about 5 mol. % of repeating units derived from NDA claim 1 , HNA claim 1 , or a combination thereof.10. The liquid crystalline polymer of claim 1 , wherein the total molar percentage of the repeating units (1)-(5) equals 100%.11. The liquid crystalline polymer of claim 1 , wherein the polymer has a melting temperature of from about 100° C. to about 280° C.12. The liquid crystalline polymer of claim 1 , wherein the polymer has a melt viscosity of from about 25 to about 150 Pa-s claim 1 , as determined in accordance with ISO Test No. 11443:2005 at a shear rate of 1000 secondsand temperature of about 15° C. higher ...

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05-01-2017 дата публикации

HIGH RECYCLE CONTENT POLYOLS FROM THERMOPLASTIC POLYESTERS AND LIGNIN OR TANNIN

Номер: US20170002138A1
Принадлежит:

Polyester polyols, processes for making them, and applications for the polyols are disclosed. In some aspects, the polyols comprise recurring units from a thermoplastic polyester or an aromatic polyacid source, a glycol, and a lignin, tannin, or mixture thereof. Optionally, the polyols incorporate recurring units of a hydrophobe. The polyols are made in one or multiple steps; in some aspects, the thermoplastic polyester or aromatic polyacid source and the glycol are reacted first, followed by reaction with the lignin, tannin, or mixture thereof. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including two-component polyurethane coatings, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols. 1. A polyester polyol comprising recurring units from:(a) a digested thermoplastic polyester;(b) a glycol; and(c) a lignin, a tannin, or a mixture thereof;wherein the molar ratio of glycol to thermoplastic polyester recurring units is at least 0.8, the amount of lignin, tannin, or mixture thereof incorporated into the polyol is within the range of 0.1 to 35 wt. %, and the polyol has a hydroxyl number within the range of 25 to 800 mg KOH/g.2. The polyol of wherein the thermoplastic polyester is selected from the group consisting of polyethylene terephthalate; polybutylene terephthalate; polytrimethylene terephthalate; glycol-modified polyethylene terephthalate; copolymers of terephthalic acid and 1 claim 1 ,4-cyclohexanedimethanol; isophthalic acid-modified copolymers of terephthalic acid and 1 claim 1 ,4-cyclohexanedimethanol; copolymers of 2 claim 1 ,2 claim 1 ,4 claim 1 ,4-tetramethyl-1 claim 1 ,3-cyclobutanediol with isophthalic acid claim 1 , terephthalic acid or orthophthalic derivatives; polyhydroxyalkanoates; polyethylene furanoate; dihydroferulic acid polymers; and mixtures thereof.3. The polyol of wherein the thermoplastic polyester is selected from the group ...

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02-01-2020 дата публикации

Production of purified dialkyl-furan-2,5-dicarboxylate (dafd) in a retrofitted dmt plant

Номер: US20200002301A1
Принадлежит: Eastman Chemical Co

Disclosed is a process to produce a purified vapor comprising dialkyl-furan-2,5-dicarboxylate (DAFD). Furan-2,5-dicarboxylic acid (FDCA) and an alcohol in an esterification zone to generate a crude diester stream containing dialkyl furan dicarboxylate (DAFD), unreacted alcohol, 5-(alkoxycarbonyl)furan-2-carboxylic acid (ACFC), and alkyl furan-2-carboxylate (AFC). The esterification zone comprises at least one reactor that has been previously used in an DMT process.

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02-01-2020 дата публикации

PROCESS FOR PREPARING POLY(ALKYLENE FURANDICARBOXYLATE)

Номер: US20200002471A1
Принадлежит:

A process to prepare poly(alkylene furandicarboxylate) polymer is disclosed herein. In one embodiment, the process comprises a) contacting a mixture comprising furandicarboxylic acid dialkyl ester, a diol comprising ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,4-cyclohexanedimethanol, or mixtures thereof, and a metal catalyst at a temperature in the range of from about 140° C. to about 220° C. to form prepolymer, 2. The process of claim 1 , wherein the furandicarboxylic acid dialkyl ester is 2 claim 1 ,5-furandicarboxylate dimethyl ester.3. The process of claim 1 , wherein the diol is 1 claim 1 ,3-propanediol and the poly(alkylene furandicarboxylate) polymer is poly(trimethylene furandicarboxylate).4. The process of claim 1 , wherein the diol is ethylene glycol and the poly(alkylene furandicarboxylate) polymer is poly(ethylene furandicarboxylate).5. The process of claim 1 , wherein the diol is 1 claim 1 ,4-butanediol and the poly(alkylene furandicarboxylate) polymer is poly(butylene furandicarboxylate).6. The process of claim 1 , wherein the metal catalyst comprises at least one titanium claim 1 , bismuth claim 1 , zirconium claim 1 , tin claim 1 , antimony claim 1 , germanium claim 1 , aluminum claim 1 , cobalt claim 1 , magnesium claim 1 , or manganese compound.7. The process of claim 1 , wherein the metal catalyst is present in the mixture in a concentration in the range of from about 20 ppm to about 300 ppm claim 1 , based on the total weight of the polymer.8. The process of claim 1 , wherein the anthraquinone compound is present in the mixture in a concentration in the range of from about 1 ppm to about 20 ppm claim 1 , based on the total weight of the polymer.9. The process of claim 1 , wherein the anthraquinone compound is present in the prepolymer in a concentration in the range of from about 1 ppm to about 20 ppm claim 1 , based on the total weight of the polymer.10. The process of claim 1 , wherein the anthraquinone compound is 1 claim 1 ,4-bis[(2 ...

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07-01-2021 дата публикации

POLYESTER RESIN OR POLYESTER CARBONATE RESIN, AND OPTICAL MEMBER USING SAID RESIN

Номер: US20210002420A1
Принадлежит: TEIJIN LIMITED

The purpose of the present invention is to provide a polyester resin or polyester carbonate resin, which has high refractive index, while achieving an excellent balance between heat resistance and low birefringence. A polyester resin or a polyester carbonate resin, which contains repeating units represented by the following formulae (1) and (2), and wherein the ratio of the repeating unit represented by formula (1) to the repeating unit represented by formula (2) is 15:85 to 85:15. (In formula (1), each of rings Zand Zrepresents a polycyclic aromatic hydrocarbon group having 9-20 carbon atoms; each of R, R, Rand Rindependently represents a hydrocarbon group which may contain an aromatic group having 1-12 carbon atoms; each of R-Rand R-Rrepresents a hydrogen atom or an aliphatic or aromatic substituents; each of j, k, r and s independently represent an integer of 0 or more; and each of m, n, p and q independently represents 1 or 2) (In formula (2), each of R, R, Rand Rindependently represent a hydrocarbon group which may contain an aromatic group having 1-12 carbon atoms; each of R-Rand R-Rrepresents a hydrogen atoms or an aliphatic or aromatic substituents; and each of r, s, t and u independently represents an integer of 0 or more.) 2. The polyester resin or polyester carbonate resin according to claim 1 , wherein Z and Zin formula (1) represent naphthalene-diyl groups.4. The polyester resin or polyester carbonate resin according to claim 3 , wherein R-Rand R-Rin formula (3) represent hydrogen atoms claim 3 , and j claim 3 , k claim 3 , r claim 3 , s claim 3 , m claim 3 , n claim 3 , p and q represent 1.5. The polyester resin or polyester carbonate resin according to claim 3 , wherein Rand Rin formula (3) represent ethylene groups and Rand Rrepresent methylene groups.6. The polyester resin or polyester carbonate resin according to claim 1 , wherein the repeating unit represented by formula (1) constitutes 20 mol % or more of all repeating units.7. The polyester ...

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14-01-2021 дата публикации

CROSSLINKABLE COATING COMPOSITIONS FORMULATED WITH DORMANT CARBAMATE INITIATOR

Номер: US20210007963A1
Принадлежит: ELEMENTIS SPECIALTIES, INC.

A crosslinkable coating composition comprising: ingredient A that has at least two protons that can be activated to form a Michael carbanion donor; ingredient B that functions as a Michael acceptor having at least two ethylenically unsaturated functionalities each activated by an electron-withdrawing group; and a dormant carbamate initiator of Formula (1) 134-. (canceled)36. The crosslinkable coating composition according to claim 35 , wherein the ingredient A is independently selected from a malonate group containing compound claim 35 , a malonate group containing oligomer claim 35 , a malonate group containing polymer claim 35 , an acetoacetate group containing compound claim 35 , an acetoacetate group containing oligomer claim 35 , an acetoacetate group containing polymer or combinations thereof.37. The crosslinkable coating composition according to claim 36 , wherein the malonate group containing compound claim 36 , malonate group containing oligomer claim 36 , malonate group containing polymer claim 36 , an acetoacetate group containing compound claim 36 , acetoacetate group containing oligomer claim 36 , or acetoacetate group containing polymer are each selected from the group consisting of: polyurethanes claim 36 , polyesters claim 36 , polyacrylates claim 36 , epoxy polymers claim 36 , polyamides claim 36 , polyesteramides or polyvinyl polymers claim 36 , wherein such compounds claim 36 , oligomers or polymers have (i) a malonate group claim 36 , (ii) an acetoacetate group or (iii) combinations thereof located in a main chain of such compound or oligomer or polymer or a side chain of such compound or oligomer or polymer.38. The crosslinkable coating composition according to claim 37 , wherein ingredient B is selected from the group consisting of acrylates claim 37 , fumarates claim 37 , maleates and combinations thereof.39. The crosslinkable coating composition according to claim 38 , wherein the acrylate is independently selected from the group consisting ...

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11-01-2018 дата публикации

SORBITAN POLYESTER CONJUGATES FOR STABILIZING WATER-IN-OIL EMULSIONS AND DELIVERING CONTROLLED RELEASE OF BIOACTIVE AGENTS

Номер: US20180008713A1
Принадлежит:

A composition in a water-in-oil-in-water (W/O/W) emulsion is disclosed. The composition comprises: (a) a continuous aqueous phase, comprising HO; (b) an oil phase or an oil shell, dispersed in the continuous aqueous phase; and (c) a hydrophilic polymer, stabilizing an interface between the continuous aqueous phase and the oil phase or the oil shell to form the water-in-oil-in-water (W/O/W) emulsion. The oil phase or the oil shell comprises: (i) oil; (ii) an internal aqueous phase, dispersed within the oil or the oil shell; and (iii) a lipophilic sorbitan-polyester conjugate, stabilizing an interface between the oil and the inner aqueous phase to form a water-in-oil (W/O) emulsion. The lipophilic sorbitan-polyester conjugate comprises: (1) sorbitan; and (2) poly(lactide-co-ε-caprolactone) or polylactic acid (polylactide), conjugated to the sorbitan. 1. A composition in a water-in-oil-in-water (W/O/W) emulsion , comprising:{'sub': '2', '(a) a continuous aqueous phase, comprising HO; and'} (i) oil;', '(ii) an internal aqueous phase, dispersed within the oil or the oil shell; and', (1) sorbitan; and', '(2) poly(lactide-co-ε-caprolactone) or polylactic acid (polylactide), conjugated to the sorbitan; and, '(iii) a lipophilic sorbitan-polyester conjugate, stabilizing an interface between the oil and the inner aqueous phase to form a water-in-oil (W/O) emulsion, the lipophilic sorbitan-polyester conjugate comprising], '(b) an oil phase or an oil shell, dispersed in the continuous aqueous phase, the oil phase or the oil shell comprising(c) a hydrophilic polymer, stabilizing an interface between the continuous aqueous phase and the oil phase or the oil shell to form an oil-in-water (O/W) emulsion.2. The composition of claim 1 , wherein the weight ratio of sorbitan:lactide:caprolactone in the sorbitan-poly(lactide-co-ε-caprolactone) conjugate is greater than 1:2:2 but less than 1:12:12.3. The composition of claim 2 , wherein the weight ratio of sorbitan:lactide:caprolactone in ...

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27-01-2022 дата публикации

HEAT SHRINKABLE FILM AND METHOD FOR REPRODUCING POLYESTER CONTAINER USING SAME

Номер: US20220025112A1
Принадлежит:

The embodiments relate to a heat shrinkable film and a process for regenerating a polyester container using the same. The heat shrinkable film comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component and has a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds, a melting point of 190° C. or higher as measured by differential scanning calorimetry, and a peak temperature (Tp) of 95° C. to 115° C. as measured in the endothermic and exothermic curve (heat flow) by differential scanning calorimetry. It not only solves the environmental problem by improving the recyclability of the polyester container, but also is capable of enhancing the yield and productivity. 1. A heat shrinkable film , which comprises a copolymerized polyester resin. comprising a diol component and a dicarboxylic acid component , andwhich has a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds,a melting point of 190° C. or higher as measured by differential scanning calorimetry, anda peak temperature (Tp) of 95° C. to 115° C. as measured in the endothermic and exothermic curve (heat flow) by differential scanning calorimetry.2. The heat shrinkable film of claim 1 , which has a clumping fraction of 8% or less.3. The heat shrinkable film of claim 1 , which has a crystallization temperature that is not measured or is 70° C. to 95° C. by differential scanning calorimetry.4. The polyester film of claim 1 , which has a heat of crystallization at the crystallization temperature that is not measured or is 0.01 to 50 J/g.5. The heat shrinkable film of claim 1 , wherein the diol component is at least one selected from the group consisting of ethylene glycol claim 1 , diethylene glycol claim 1 , neopentyl glycol claim 1 , and cyclohexanedimethanol.6. The heat shrinkable film of claim 1 , wherein the ...

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14-01-2016 дата публикации

POLYESTER RESIN FOR TONER, ELECTROSTATIC CHARGE IMAGE DEVELOPING TONER, ELECTROSTATIC CHARGE IMAGE DEVELOPER, TONER CARTRIDGE, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS

Номер: US20160011531A1
Принадлежит: FUJI XEROX CO., LTD.

A polyester resin for toner includes a repeating unit that is derived from a diol represented by the following formula (1), and a repeating unit that is derived from a dicarboxylic acid not having a double carbon-carbon bond: 2. The polyester resin for toner according to claim 1 ,wherein the diol represented by the formula (1) has an SP value of from 8.7 to 9.4.3. The polyester resin for toner according to claim 1 ,wherein an amount of a residual dicarboxylic acid is 2.0% by weight or less.4. The polyester resin for toner according to claim 1 ,wherein an amount of a residual dicarboxylic acid is 1.5% by weight or less.5. The polyester resin for toner according to claim 1 ,wherein the polyester resin contains a plurality of repeating unit that is derived from alcohols and a ratio of the repeating unit that is derived from the diol represented by the formula (1) with respect to all the alcohol components is from 50% by weight to 80% by weight.6. An electrostatic charge image developing toner comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a binder resin that contains the polyester resin for toner according to .'}7. The electrostatic charge image developing toner according to claim 6 ,wherein the diol represented by the formula (1) has an SP value of from 8.7 to 9.4.8. An electrostatic charge image developer comprising:{'claim-ref': {'@idref': 'CLM-00006', 'claim 6'}, 'the electrostatic charge image developing toner according to ; and'}an electrostatic charge image developing carrier.9. A toner cartridge comprising:{'claim-ref': {'@idref': 'CLM-00006', 'claim 6'}, 'a container that accommodates the electrostatic charge image developing toner according to , and is detachable from an image forming apparatus.'}10. A process cartridge comprising:{'claim-ref': {'@idref': 'CLM-00008', 'claim 8'}, 'a developing unit that accommodates the electrostatic charge image developer according to and develops an electrostatic charge image, which is formed on a surface of ...

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16-01-2020 дата публикации

PROCESS FOR PREPARING POLY(TRIMETHYLENE FURANDICARBOXYLATE) USING ZINC CATALYST

Номер: US20200017634A1
Принадлежит:

A process is disclosed herein comprising the steps: a) contacting a mixture comprising furandicarboxylic acid dialkyl ester, 1,3-propanediol, a zinc compound, and optionally a poly(alkylene ether) diol, at a temperature in the range of from about 120° C. to about 220° C. to form prepolymer, wherein the mole ratio of the furandicarboxylic acid dialkyl ester to the 1,3-propanediol is in the range of from 1:1.3 to 1:2.2; and b) heating the prepolymer under reduced pressure to a temperature in the range of from about 220° C. to about 260° C. to form polymer. The mixture of step a) can further comprise an anthraquinone compound. 1. A process comprising the steps:a) contacting a mixture comprising furandicarboxylic acid dialkyl ester, 1,3-propanediol, a zinc compound, and optionally a poly(alkylene ether) diol, at a temperature in the range of from about 120° C. to about 220° C. to form prepolymer,wherein the mole ratio of the furandicarboxylic acid dialkyl ester to the 1,3-propanediol is in the range of from 1:1.3 to 1:2.2; andb) heating the prepolymer under reduced pressure to a temperature in the range of from about 220° C. to about 260° C. to form a polymer.2. The process of claim 1 , wherein the furandicarboxylic acid dialkyl ester is 2 claim 1 ,5-furandicarboxylate dimethyl ester and the polymer is poly(trimethylene furandicarboxylate).3. The process of claim 1 , wherein the zinc compound comprises zinc acetate claim 1 , zinc acetylacetonate claim 1 , zinc glycolate claim 1 , zinc p-toluenesulfonate claim 1 , zinc carbonate claim 1 , zinc trifluoroacetate claim 1 , zinc oxide claim 1 , or zinc nitrate.4. The process of claim 1 , wherein the concentration of the zinc compound is in the range of from about 20 ppm to about 300 ppm claim 1 , based on the total weight of the polymer.5. The process of claim 1 , wherein step a) is performed in the absence of a titanium compound.6. The process of claim 1 , wherein step b) is performed in the absence of a titanium compound.7 ...

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21-01-2021 дата публикации

POLYESTER RESIN

Номер: US20210017331A1
Принадлежит:

The present invention relates to a polyester resin. The polyester resin is useful for bottles, sheets, multilayer sheets, stretched films and fiber applications due to excellent heat resistance and transparency, and in particular, the polyester resin has little deterioration of physical properties such as yellowing, etc., during processing 1. A manufacturing method for a polyester resin , comprising:(a) performing an esterification reaction or a transesterification reaction on (i) a dicarboxylic acid or a derivative thereof that includes a terephthalic acid or a derivative thereof and (ii) a diol including 0.5 to 25 mol % of isosorbide with respect to a total diol; and(b) performing a polycondensation reaction on a product obtained by the esterification reaction or the transesterification reaction.2. The manufacturing method of claim 1 , wherein:a polycondensation catalyst, a stabilizer, a coloring agent, a crystallizer, an antioxidant or a branching agent is added to a slurry before (a) the esterification reaction or the transesterification reaction starts or to the product after (a) the esterification reaction or the transesterification reaction is completed.3. The manufacturing method of claim 1 , wherein:the dicarboxylic acid or the derivative thereof is a dicarboxylic acid, and an initial mixing molar ratio of the dicarboxylic acid or the derivative thereof and the diol is 1:1.01 to 1.04.4. The manufacturing method of claim 1 , wherein:the dicarboxylic acid or the derivative thereof is a dicarboxylic acid alkyl ester or a dicarboxylic acid anhydride, and an initial mixing molar ratio of the dicarboxylic acid or the derivative thereof and the diol is 1:2.0 to 1:2.1.5. The manufacturing method of claim 1 , further comprising:before (b) the polycondensation reaction, allowing the reaction product obtained by the esterification reaction or the transesterification reaction to stand under a reduced pressure of 400 to 1 mmHg for 0.2 to 3 hours.6. The manufacturing ...

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16-01-2020 дата публикации

Oxygen Scavenging Plastic Material

Номер: US20200017679A1
Принадлежит: CLARIANT PLASTICS & COATINGS LTD

The invention relates to a polyether-polyester copolymer comprising: (i) polyether segments wherein at least one polyether segment contains at least one polytetramethylene oxide segment, (ii) polyester segments, (iii) bridging elements of the structure —CO—R2-CO—, wherein R2 represents an optionally substituted bivalent hydrocarbon residue consisting of 1 to 100 carbon atoms; (iv) one or two end-caps R1 —O—(C-C—O—)—*, wherein R1 is an optionally substituted hydrocarbon residue and e is an integer of from 0 to 1000. 1. A polyether-polyester copolymer comprising(i) polyether segments wherein at least one polyether segment contains at least one polytetramethylene oxide segment;(ii) polyester segments;(iii) bridging elements of the structure —CO—R2-CO—, wherein R2 is an optionally substituted bivalent hydrocarbon residue consisting of 1 to 100 carbon atoms; and{'sub': 2', '4', 'e, '(iv) one or two end-caps R1-O—(C-C—O—)—*, wherein R1 is an optionally substituted hydrocarbon residue and e is an integer of from 0 to 1000.'}2. The polyether-polyester copolymer as claimed in claim 1 , wherein the polyether segments (i) contain ethylene oxide segments claim 1 , propylene oxide segments or a combination thereof.5. The polyether-polyester copolymer as claimed in claim 1 , wherein end-caps are described by the following general formula{'br': None, 'sub': 2', '4', 'e, 'R1-O—(C-C—O—)—*,'}wherein R1 is an aliphatic hydrocarbon residue of 1 to 24 carbon atoms, an olefinic hydrocarbon residue of 2 to 24 carbon atoms, or an aromatic hydrocarbon residue of 6 to 14 carbon atoms,{'sub': 1', '5, 'wherein said hydrocarbon residues are optionally substituted with C-C-alkoxy, nitro, cyano, sulfo, or a combination thereof, and'}wherein e is an integer of between 0 and 500.7. The polyether-polyester copolymer as claimed in claim 1 , wherein R1 is methyl claim 1 , ethyl claim 1 , n-propyl claim 1 , iso-propyl claim 1 , n-butyl claim 1 , iso-butyl claim 1 , sec-butyl claim 1 , tert-butyl claim ...

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24-01-2019 дата публикации

Production of purified dialkyl-furan-2,5-dicarboxylate (dafd) in a retrofitted dmt plant

Номер: US20190023677A1
Принадлежит: Eastman Chemical Co

Disclosed is a process to produce a purified vapor comprising dialkyl-furan-2,5-dicarboxylate (DAFD). Furan-2,5-dicarboxylic acid (FDCA) and an alcohol in an esterification zone to generate a crude diester stream containing dialkyl furan dicarboxylate (DAFD), unreacted alcohol, 5-(alkoxycarbonyl)furan-2-carboxylic acid (ACFC), and alkyl furan-2-carboxylate (AFC). The esterification zone comprises at least one reactor that has been previously used in an DMT process.

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24-01-2019 дата публикации

PRODUCTION OF POLYETHYLENE FURANOATE IN A RETROFITTED POLYESTER PLANT

Номер: US20190023837A1
Принадлежит: EASTMAN CHEMICAL COMPANY

Disclosed is a process for the manufacture of a composition comprising PEF; wherein said process polymerizes FDCA and a diol in a polymerization reactor; wherein the polymerization reaction occurs in at least one reactor previously used in a polyester plant to produce said composition comprising PEF. 1. A process for the manufacture of a composition comprising PEF; wherein said process polymerizes FDCA and a diol in a polymerization reactor; wherein the polymerization reaction occurs in at least one reactor previously used in a polyester plant to produce said composition comprising PEF.2. The process according to wherein said diol has 6 to 20 carbon atoms or aliphatic diols preferably having 2 to 20 carbon atoms.3. The process according to wherein said diol comprises ethylene glycol.4. A process for the manufacture a composition comprising PEF; wherein said process polymerizes DAFD and a diol in a polymerization reactor; wherein the polymerization reaction occurs in at least one reactor previously used in a polyester plant to produce said composition comprising PEF.5. The process according to wherein said diol has 6 to 20 carbon atoms or aliphatic diols preferably having 2 to 20 carbon atoms6. The process according to wherein said diol comprises ethylene glycol.7. A process for the manufacture a composition comprising PEF; wherein said process polymerizes DMFD and a diol in a polymerization reactor; wherein the polymerization reaction occurs in at least one reactor previously used in a polyester plant to produce said composition comprising PEF.8. The process according to wherein said diol comprises ethylene glycol.9. The process according to wherein said diol has 6 to 20 carbon atoms or aliphatic diols preferably having 2 to 20 carbon atoms10. A process for the manufacture a composition comprising PEF; wherein said process polymerizes DAFD and diol in a polymerization reactor; wherein the polymerization reaction occurs in at least two reactors previously used in a ...

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24-01-2019 дата публикации

PRODUCTION OF POLYETHYLENE FURANOATE IN A RETROFITTED PET PLANT

Номер: US20190023838A1
Принадлежит: EASTMAN CHEMICAL COMPANY

Disclosed is a process for the manufacture of a composition comprising PEF; wherein said process polymerizes FDCA and a diol in a polymerization reactor; wherein the polymerization reaction occurs in at least one reactor previously used in a polyester plant to produce said composition comprising PEF. 1. A process for the manufacture of a composition comprising PEF; wherein said process polymerizes FDCA and a dial in a polymerization reactor; wherein the polymerization reaction occurs in at least one reactor previously used in a PET plant to produce said composition comprising PEF.2. The process according to wherein said diol has 6 to 20 carbon atoms or aliphatic diols preferably having 2 to 20 carbon atoms.3. The process according to where said diol is at least one selected from the group consisting of comprise ethylene glycol (EG) claim 1 , diethylene glycol claim 1 , triethylene glycol claim 1 , 1 claim 1 ,4-cyclohexane-dimethanol claim 1 , propane-1 claim 1 ,3-diol claim 1 , butane-1 claim 1 ,4-diol claim 1 , pentane-1 claim 1 ,5-diol claim 1 , hexane-1 claim 1 ,6-diol claim 1 , neopentylglycol claim 1 , 3-methylpentanediol-(2 claim 1 ,4) claim 1 , 2-methylpentanediol-(1 claim 1 ,4) claim 1 , 2 claim 1 ,2 claim 1 ,4-trimethylpentane-diol-(1 claim 1 ,3) claim 1 , 2-ethylhexanediol-(1 claim 1 ,3) claim 1 , 2 claim 1 ,2-diethylpropane-diol-(1 claim 1 ,3) claim 1 , hexanediol-(1 claim 1 ,3) claim 1 , 1 claim 1 ,4-di-(hydroxyethoxy)-benzene claim 1 , 2 claim 1 ,2-bis-(4-hydroxycyclohexyl)-propane claim 1 , 2 claim 1 ,4-dihydroxy-1 claim 1 ,1 claim 1 ,3 claim 1 ,3-tetramethyl-cyclobutane claim 1 , 2 claim 1 ,2 claim 1 ,4 claim 1 ,4 tetramethylcyclobutanediol claim 1 , 2 claim 1 ,2-bis-(3-hydroxyethoxyphenyl)-propane claim 1 , 2 claim 1 ,2-bis-(4-hydroxypropoxyphenyl)-propane claim 1 , isosorbide claim 1 , hydroquinone claim 1 , and BDS-(2 claim 1 ,2-(sulfonylbis)4 claim 1 ,1-phenyleneoxy))bis(ethanol).4. The process according to wherein said diol comprises ethylene ...

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28-01-2021 дата публикации

COPOLYESTERS DERIVED FROM ALIPHATIC GLYCOLS, AROMATIC DICARBOXYLIC ACIDS AND POLY(ALKYLENE-OXIDES) AND FILMS MADE THEREFROM

Номер: US20210024688A1

An optionally oriented copolyester film comprising a copolyester which comprises repeating units derived from an aliphatic diol, an aromatic dicarboxylic acid and a poly(alkylene oxide), wherein the copolyester film further comprises lithium ions, and wherein the film has a thickness of no more than about 25 μm. The copolyester film is suitable for use a separator in a lithium-ion rechargeable battery. 1. A copolyester film comprising a copolyester which comprises repeating units derived from an aliphatic diol , an aromatic dicarboxylic acid and a poly(alkylene oxide) , wherein the copolyester film further comprises lithium ions , and wherein the film has a thickness of no more than 25 μm.2. A film according to claim 1 , wherein the copolyester is block-like and/or random claim 1 , the repeating units of the copolyester having a degree of randomness denoted by a value of B of from about 0.1 to 1.0 claim 1 , preferably from about 0.2 to about 0.95.3. A film according to claim 2 , wherein the value of B is from about 0.3 to about 0.9 claim 2 , preferably from about 0.4 to about 0.8 claim 2 , preferably from about 0.5 to about 0.7.4. A film according to any preceding claim claim 2 , wherein the film has a thickness of no more than about 20 μm claim 2 , preferably no more than about 18 μm.5. A film according to any preceding claim claim 2 , wherein the film has a thickness of no more than 15 μm.6. A film according any preceding claim claim 2 , wherein the film has a thickness of no more than about 12 μm claim 2 , preferably no more than about 5 μm claim 2 , preferably from about 0.9 μm to about 5 μm.7. A film according to any preceding claim claim 2 , where the film comprises no plasticiser or comprises less than 15% of any plasticiser by weight of the film.8. A film according to claim 7 , where the film has no plasticiser.9. A film according to any preceding claim claim 7 , wherein said copolyester comprises semi-crystalline segments derived from an aromatic ...

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01-02-2018 дата публикации

Liquid detergent or cleaning agent with suspended particles

Номер: US20180030377A1
Принадлежит: Henkel AG and Co KGaA

Particulate solids with an average particle diameter X 50,3 of 0.01 mm to 3 mm, containing a total quantity of 30 to 100 wt. %, based on the total weight, of at least one polyester, containing at least one structural unit of the formula (I) and at least one structural unit of the formula (II), in which a and c each represents a number from 1 to 200 independently of each other. R 2 , R 5 , and R 6 each represents hydrogen or a C 1 -C 18 n-alkyl group or a C 3 -C 18 isoalkyl group independently of one another. R 7 represents a linear or branched C 1 -C 30 alkyl group or a linear or branched C 2 -C 30 alkenyl group, a cycloalkyl group with 5 to 9 carbon atoms, a C 6 -C 30 aryl group, or a C 6 -C 30 arylalkyl group. The particulate solids can be suspended in liquid, water-containing surfactant compositions in a stable manner. The invention also relates to liquid detergent or cleaning agents containing (i) a liquid phase, which contains at least one surfactant and water, and (ii) solid particles, which are suspended in the liquid phase, and to the use of the particulate solids and a liquid phase, which contains water and surfactant, for producing a liquid detergent or cleaning agent.

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31-01-2019 дата публикации

DIMER FATTY ACID-CONTAINING REACTION PRODUCT AND COATING COMPOSITION COMPRISING THE REACTION PRODUCT

Номер: US20190031825A1
Принадлежит: BASF COATINGS GMBH

The present invention relates to a reaction product preparable by reacting 1. (canceled)2. The pigmented aqueous basecoat material as claimed in claim 7 , wherein the dimer fatty acid(s) used consist of at least 90 wt % of dimeric molecules claim 7 , less than 5 wt % of trimeric molecules claim 7 , and less than 5 wt % of monomeric molecules and other byproducts.3. The pigmented aqueous basecoat material as claimed in claim 7 , wherein the compound (b) possesses a number-average molecular weight of 140 to 425 g/mol.4. The pigmented aqueous basecoat material as claimed in claim 7 , wherein the group R as per the general structural formula (I) comprises isopropylene radicals or tetramethylene radicals and the compound (b) possesses a number-average molecular weight of 170 to 350 g/mol.5. The pigmented aqueous basecoat material as claimed in claim 7 , wherein components (a) and (b) are used in a molar ratio of 0.9/2.1 to 1.5/1.8.6. The pigmented aqueous basecoat material as claimed in claim 7 , which possesses a number-average molecular weight of 800 to 3500 g/mol.8. The pigmented aqueous basecoat material as claimed in claim 7 , wherein the sum total of weight-percentage fractions of the reaction products claim 7 , based on the total weight of the pigmented aqueous basecoat material(s) is 0.1 to 30 wt %.9. The pigmented aqueous basecoat material as claimed in claim 7 , which comprises as further binder at least one polyurethane resin.10. The pigmented aqueous basecoat material as claimed in claim 7 , which comprises a polyurethane resin that is grafted by means of olefinically unsaturated monomers and that also comprises hydroxyl groups claim 7 , and a melamine resin.12. A method for producing a multiple-coat paint system claim 7 , where{'claim-ref': {'@idref': 'CLM-00007', 'claim 7'}, '(1) applying a pigmented aqueous basecoat material according to to a substrate,'}(2) forming a polymer film from the coating material applied in stage (1) thus forming a basecoat film ...

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31-01-2019 дата публикации

PROCESS FOR ENHANCING THE MOLECULAR WEIGHT OF A POLYESTER BY SOLID STATE POLYMERIZATION

Номер: US20190031826A1
Принадлежит:

The molecular weight of a semi-crystalline polyester including ethylene 2,5-furandicarboxylate units is increased in a process, including heating the semi-crystalline polyester during a solid state polymerization period. The temperature is at least 180° C. and is kept below the melting point of the semi-crystalline polyester whilst the semi-crystalline polyester is either under a flow of inert gas or under vacuum to obtain a solid state polymerized polyester. The temperature is continuously or periodically increased during the solid state polymerization period. 1. A process for enhancing the molecular weight of a semi-crystalline polyester comprising ethylene 2 ,5-furandicarboxylate units , which process comprises:heating the semi-crystalline polyester during a solid state polymerization period wherein the temperature is at least 180° C. and is kept below the melting point of the semi-crystalline polyester whilst the semi-crystalline polyester is either under a flow of inert gas or under vacuum to obtain a solid state polymerized polyester, andwherein the temperature is continuously or periodically increased during the solid state polymerization period.2. The process according to claim 1 , wherein the semi-crystalline polyester has a melting point of at least 200° C. claim 1 , as measured by Differential Scanning calorimetry (DSC).3. The process according to claim 1 , wherein the semi-crystalline polyester has an intrinsic viscosity of at least 0.45 dL/g.4. The process according to claim 3 , wherein the semi-crystalline polyester has an intrinsic viscosity in the range of 0.45 to 0.75 dL/g.5. The process according to claim 1 , wherein the semi-crystalline polyester has an amount of carboxylic acid end groups of 2 to 122 meq/kg.6. The process according to claim 1 , wherein the semi-crystalline polyester has been obtained by crystallizing substantially amorphous polyester by keeping the substantially amorphous polyester at a temperature in the range of 90 to 180° C.7. ...

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31-01-2019 дата публикации

Injection-molded foam of resin composition with satisfactory surface property and capable of weight reduction and rib design

Номер: US20190031851A1
Автор: Soichi Uchida
Принадлежит: Kaneka Corp

A foam injection molded article includes a resin composition, wherein the resin composition includes: (A) a polycarbonate resin, (B) a thermoplastic polyester resin, (C) a polyester-polyether copolymer, and (D) a foaming agent. The article has an arithmetic average roughness (Ra) that is greater than 0.1 μm and less than 9 μm, a maximum height (Ry) that is greater than 1 μm and less than 90 μm; and a 10-point average roughness (Rz) that is greater than 1 μm and less than 70 μm.

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09-02-2017 дата публикации

POLYESTER RESIN, METHOD FOR MANUFACTURING POLYESTER RESIN, AND COATING COMPOSITION CONTAINING POLYESTER RESIN

Номер: US20170037182A1
Принадлежит: MITSUBISHI RAYON CO., LTD.

The present invention relates to a polyester resin with excellent solubility in generic solvents, especially with excellent solubility at a temperature of 0° C. or lower. According to the present invention, by using the polyester resin with excellent solubility in generic solvents, solubility at a lower temperature, especially the solubility at a temperature of 0° C. or lower, is enhanced, making it easier to prepare paints, coatings and the like. The polyester resin related to the present invention contains 0.05 to 0.5 mol of an isosorbide-derived structural unit and 0.015 to 0.4 mol of a trihydric or higher alcohol-derived structural unit relative to 1 mol of a polycarboxylic acid-derived structural unit. 1. A polyester resin , comprising:a polycarboxylic acid-derived structural unit;a trihydric or higher alcohol-derived structural unit; andan isosorbide-derived structural unit,wherein the polyester resin comprises 0.05 to 0.5 mol of the isosorbide-derived structural unit and 0.015 to 0.4 mol of the trihydric or higher alcohol-derived structural unit relative to 1 mol of the polycarboxylic acid-derived structural unit.2. The polyester resin according to claim 1 , wherein the polyester resin comprises 0.015 to 0.2 mol of the trihydric or higher alcohol-derived structural unit relative to 1 mol of the polycarboxylic acid-derived structural unit.3. The polyester resin according to claim 1 , wherein the polyester resin comprises 0.05 to 0.4 mol of the isosorbide-derived structural unit relative to 1 mol of the polycarboxylic acid-derived structural unit.4. The polyester resin according to claim 1 , further comprising a structural unit derived from a dihydric alcohol having an alicyclic skeleton claim 1 , which is not isosorbide.5. The polyester resin according to claim 4 , wherein the dihydric alcohol having an alicyclic skeleton is 1 claim 4 ,4-cyclohexanedimethanol.6. The polyester resin according to claim 4 , wherein the polyester resin comprises 0.001 to 0.15 mol ...

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06-02-2020 дата публикации

PROCESS FOR THE PRODUCTION OF A SOLID-STATE POLYMERIZED POLY (TETRAMETHYLENE-2, 5-FURAN DICARBOXYLATE) POLYMER AND POLYMER THUS PRODUCED

Номер: US20200040134A1
Автор: Sipos Laszlo
Принадлежит:

A solid-state polymerized poly(tetramethylene-2,5-furandicarboxylate) polymer is produced in a process including: providing a poly (tetramethylene-2,5-furandicarboxylate) polycondensate having a number average molecular weight (Mn) of at least 10,000, as determined by Gel Permeation Chromatography (GPC) using polystyrene as standard, and having a content of carboxylic acid end groups of at most 50 meq/kg; and keeping the poly(tetramethylene-2,5-furandicarboxylate) polycondensate at a temperature in the range of 80 to 140° C. to obtain a semi-crystalline polycondensate; and subjecting the semi-crystalline polycondensate to solid-state polymerization by keeping the semi-crystalline polycondensate at a temperature of at least 140° C. and below its melting point, whilst the semi-crystalline polycondensate is either under a flow of inert gas or under vacuum to obtain the solid-state polymerized poly(tetramethylene-2,5-furandicarboxylate) polymer. 1. A process for the production of a solid-state polymerized poly(tetramethylene-2 ,5-furandicarboxylate) polymer comprising:providing a poly (tetramethylene-2,5-furandicarboxylate) polycondensate having a number average molecular weight (Mn) of at least 10,000, as determined by Gel Permeation Chromatography (GPC) using polystyrene as standard, and having a content of carboxylic acid end groups of at most 50 meq/kg; andkeeping the poly(tetramethylene-2,5-furandicarboxylate) polycondensate at a temperature in the range of 80 to 140° C. to obtain a semi-crystalline polycondensate; andsubjecting the semi-crystalline polycondensate to solid-state polymerization by keeping the semi-crystalline polycondensate at a temperature of at least 140° C. and below its melting point, whilst the semi-crystalline polycondensate is either under a flow of inert gas or under vacuum to obtain the solid-state polymerized poly(tetramethylene-2,5-furandicarboxylate) polymer.2. The process according to claim 1 , wherein the poly(tetramethylene-2 claim 1 ...

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16-02-2017 дата публикации

RESIN PRODUCED BY POLYCONDENSATION, AND RESIN COMPOSITION

Номер: US20170044312A1
Принадлежит: MITSUBISHI GAS CHEMICAL COMPANY, INC.

According to one embodiment, a polyester resin is provided, which includes a structural unit derived from a compound represented by general formula (1), a structural unit derived from a compound represented by general formula (2), and a structural unit derived from a dicarboxylic acid or a derivative thereof. 3. The polyester resin according to claim 1 , wherein the dicarboxylic acid or a derivative thereof is naphthalene dicarboxylic acid claim 1 , terephthalic acid claim 1 , isophthalic acid claim 1 , dicarboxylic acid having a fluorene group or an ester thereof.4. The polyester resin according to claim 1 , wherein in structural units derived from a dihydroxy compound in the polyester resin claim 1 , the ratio of the structural unit derived from the compound represented by general formula (1) is 5 to 95 mol % and the ratio of the structural unit derived from the compound represented by general formula (2) is 2.5 to 47.5 mol %.5. The polyester resin according to claim 1 , further comprising a structural unit derived from glycol claim 1 , wherein in the structural units derived from the dihydroxy compound in the polyester resin claim 1 , the ratio of the structural unit derived from glycol is 5 to 70 mol %.6. An optical member comprising the polyester resin according to .7. The optical member according to claim 6 , which is an optical lens of a single-lens reflex camera claim 6 , a digital still camera claim 6 , a video camera claim 6 , a cellular phone with a camera claim 6 , a disposable camera claim 6 , a telescope claim 6 , binoculars claim 6 , a microscope or a projector.10. The polyester carbonate resin according to claim 8 , wherein the dicarboxylic acid or a derivative thereof is naphthalene dicarboxylic acid claim 8 , terephthalic acid claim 8 , isophthalic acid claim 8 , dicarboxylic acid having a fluorene group or an ester thereof.11. The polyester carbonate resin according to claim 8 , wherein in structural units derived from a dihydroxy compound in the ...

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03-03-2022 дата публикации

Modified thermoplastic polyester elastomer and breathable and waterproof membrane

Номер: US20220064435A1
Принадлежит: Nan Ya Plastics Corp

A modified thermoplastic polyester elastomer and a breathable and waterproof membrane are provided. The modified thermoplastic polyester elastomer is formed from a thermoplastic polyester elastomer, a regenerated polyethylene terephthalate, and a compatibilizer. Based on a total weight of the modified thermoplastic polyester elastomer being 100 phr, a content of the regenerated polyethylene terephthalate is greater than 0 phr and up to 50 phr. Based on a total weight of the thermoplastic polyester elastomer being 100 wt %, the thermoplastic polyester elastomer includes 25 wt % to 75 wt % of hard segments and 25 wt % to 75 wt % of soft segments.

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14-02-2019 дата публикации

MODIFIER FOR RESIN, RESIN COMPOSITION, AND FILM IN WHICH SAME IS USED

Номер: US20190048135A1
Принадлежит: ADEKA CORPORATION

Provided are: a resin modifier with which flexibility, transparency and bleed resistance can be balanced at a high level; a resin composition; and a film using the same. The resin modifier includes a random copolymer composed of a structural unit derived from an aliphatic dibasic acid, a structural unit derived from an alkylenediol, and a structural unit derived from a polyalkylene ether glycol, which random copolymer has a hydroxyl group or a carboxyl group at a terminal. The polyalkylene ether glycol is preferably a polyethylene ether glycol, and the alkylenediol is preferably at least one selected from the group consisting of ethylene glycol, 1,2-propylene glycol, 1,3-propanediol, 2-methyl-1,3-propanediol, 1,3-butanediol, 1,4-butanediol, neopentyl glycol, 3-methyl-1,5-pentanediol, and hexanediol. 1. A resin modifier comprising a random copolymer composed of a structural unit derived from an aliphatic dibasic acid , a structural unit derived from an alkylenediol , and a structural unit derived from a polyalkylene ether glycol , which random copolymer has a hydroxyl group or a carboxyl group at a terminal.2. The resin modifier according to claim 1 , wherein said polyalkylene ether glycol is a polyethylene ether glycol.3. The resin modifier according to claim 1 , wherein said alkylenediol is at least one selected from the group consisting of ethylene glycol claim 1 , 1 claim 1 ,2-propylene glycol claim 1 , 1 claim 1 ,3-propanediol claim 1 , 2-methyl-1 claim 1 ,3-propanediol claim 1 , 1 claim 1 ,3-butanediol claim 1 , 1 claim 1 ,4-butanediol claim 1 , neopentyl glycol claim 1 , 3-methyl-1 claim 1 ,5-pentanediol claim 1 , and hexanediol.4. The resin modifier according to claim 1 , wherein the ratios of said structural unit derived from an aliphatic dibasic acid claim 1 , said structural unit derived from an alkylenediol and said structural unit derived from a polyalkylene ether glycol are 10 to 80% by mass claim 1 , 5 to 80% by mass and 1 to 50% by mass claim 1 , ...

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14-02-2019 дата публикации

POLYESTER RESINS

Номер: US20190048136A1
Принадлежит: MITSUBISHI GAS CHEMICAL COMPANY, INC.

Provided is a polyester resin including a diol structural unit and a dicarboxylic acid structural unit, wherein the diol structural unit includes a structural unit derived from a diol having a cyclic acetal skeleton, a content of the structural unit derived from the diol having the cyclic acetal skeleton is 1 to 80 mol % based on the total amount of the diol structural unit, and a amount of crosslinking points in the resin chain is 1.0 wt % or less. 2. The polyester resin according to claim 1 , wherein the diol having the cyclic acetal skeleton is 3 claim 1 ,9-bis(1 claim 1 ,1-dimethyl-2-hydroxyethyl)-2 claim 1 ,4 claim 1 ,8 claim 1 ,10-tetraoxaspiro[5.5]undecane or 5-methylol-5-ethyl-2-(1 claim 1 ,1-dimethyl-2-hydroxyethyl)-1 claim 1 ,3-dioxane. The present invention relates to polyester resins.Aromatic saturated polyester resins, especially polyethylene terephthalate (hereinafter, also referred to as “PET”), are well balanced in properties, such as mechanical performance, solvent resistance, aroma retaining property, weather resistance and recyclability, and have been used mainly for the application to produce products, such as bottles and films, in a large scale. However, PET has disadvantages with respect to crystallinity and heat resistance. That is, PET is high in crystallinity, and hence when an attempt to produce a thick molded article or sheet is made, whitening occurs due to crystallization, which impairs transparency. In addition, as for the heat resistance, the glass transition temperature of PET is approximately 80° C., and hence it has been impossible to utilize PET for applications requiring high heat resistance and transparency, such as products used in vehicles, packaging materials for import and export, packaging materials onto which retorting or heating with microwave oven is performed, and feeding bottles or tableware onto which heat sterilization is performed.From the viewpoint of solving such problems, polyester resins obtained by ...

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10-03-2022 дата публикации

FOAM

Номер: US20220073728A1
Принадлежит:

The invention relates to a foam comprising thermoplastic copolyester elastomer in an amount of at least 60 wt % with respect to the total weight of the foam, wherein the thermoplastic copolyester elastomer has a number average molecular weight (Mn) of at least 34000 g/mol and a shore D hardness measured at 3 s of between 28 to 50. The invention further relates to a process for preparing the foam and articles comprising the foam. 1. Foam comprising thermoplastic copolyester elastomer in an amount of at least 60 wt % with respect to the total weight of the foam , wherein the thermoplastic copolyester elastomer has a number average molecular weight (Mn) of at least 34000 g/mol and a shore D hardness measured at 3 s of between 28 to 50.2. Foam according to claim 1 , wherein the thermoplastic copolyester elastomer has a Mw/Mn of less than 2.7.3. Foam according to claim 1 , wherein the shore D hardness is between 30 and 45.4. Foam according to claim 1 , wherein the thermoplastic copolyester elastomer comprises hard segments chosen from ethylene terephthalate (PET) claim 1 , propylene terephthalate (PPT) claim 1 , butylene terephthalate (PBT) claim 1 , polybutylene isophthalate (PBI) claim 1 , polyethylene isophthalate (PEI) claim 1 , polyethelyene naphthalate (PEN) claim 1 , polybutylene naphthalate (PBN) claim 1 , and polypropylene naphthalate (PPN) and combinations thereof.5. Foam according to claim 4 , wherein the thermoplastic copolyester elastomer comprises hard segments being PBT optionally in combination with PBI.6. Foam according to claim 1 , wherein the thermoplastic copolyester elastomer comprises soft segments being polytetramethylene oxide (PTMO) claim 1 , polyethylene oxide (PEO) claim 1 , polypropylene oxide (PPO) claim 1 , block copolymers of poly(ethylene oxide) and poly(propylene oxide) claim 1 , linear aliphatic polycarbonates claim 1 , polybutylene adipate (PB A) and derivates of dimer fatty acids or dimer fatty acid diols claim 1 , linear aliphatic ...

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21-02-2019 дата публикации

POLYESTER RESIN

Номер: US20190055349A1
Принадлежит:

The present invention relates to a polyester resin. The polyester resin is useful for bottles, sheets, multilayer sheets, stretched films and fiber applications due to excellent heat resistance and transparency, and in particular, the polyester resin has little deterioration of physical properties such as yellowing, etc., during processing 1. A polyester resin having a structure in which a dicarboxylic acid or a derivative thereof that includes a terephthalic acid or a derivative thereof , and a diol that includes isosorbide are polymerized so that an acid moiety derived from the dicarboxylic acid or the derivative thereof and a diol moiety derived from the diol are repeated ,wherein the diol moiety derived from the isosorbide has a content of 0.5 to 20 mol % with respect to a total diol moiety derived from the diol, andwhen a standard solution in which isosorbide is dissolved in chloroform at a concentration of 150 μg/mL, and a resin solution obtained by dissolving a component extracted from 0.5 g of the polyester resin in 5 mL of chloroform using a solvent in which cyclohexane and isopropyl alcohol are mixed at a volume ratio of 2.5:97.5, are analyzed by gas chromatography, respectively, a peak area ratio of a peak of the resin solution confirmed at the same retention time to a peak confirmed in the analysis of the standard solution (peak area of the resin solution/peak area of the standard solution) is 1.0 or less.2. The polyester resin of claim 1 , wherein:the dicarboxylic acid or the derivative thereof includes 0 to 50 mol % of at least one selected from the group consisting of a C8-C14 aromatic dicarboxylic acid or a derivative thereof and a C4-C12 aliphatic dicarboxylic acid or a derivative thereof, as a dicarboxylic acid or a derivative thereof other than the terephthalic acid or the derivative thereof, with respect to a total dicarboxylic acid or a derivative thereof.3. The polyester resin of claim 1 , wherein:the diol moiety derived from isosorbide has a ...

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20-02-2020 дата публикации

Process for Producing a Polyester Polyol, the Polyester Polyol Produced Thereby, and Use of the Polyester Polyol

Номер: US20200055982A1
Принадлежит:

A process for producing a polyester polyol includes the steps of: (a) preparing a diol composition which includes a C-Cshort-chain diol component and a diol monomeric component of Formula (I) defined herein in a weight ratio of the C-Cshort-chain diol component to the diol monomeric component of Formula (I) of larger than 0 and less than 1.6, (b) preparing a dicarbonyl composition which includes one selected from the group consisting of a dicarboxylic acid component, a dicarboxylic anhydride component, and a combination thereof, and (c) subjecting the diol composition and the dicarbonyl composition to a polycondensation reaction. 3. The process according to claim 1 , wherein in step (a) claim 1 , the C-Cshort-chain diol component is selected from the group consisting of ethylene glycol claim 1 , diethylene glycol claim 1 , propylene glycol claim 1 , butanediol claim 1 , and combinations thereof.4. The process according to claim 3 , wherein in step (a) claim 3 , the C-Cshort-chain diol component is diethylene glycol.5. The process according to claim 2 , wherein the diol monomeric component of Formula (I) includes a combination of the first diol monomer of Formula (I-1) and the second diol monomer of Formula (I-2).6. The process according to claim 5 , wherein in step (a) claim 5 , the first diol monomer of Formula (I-1) and the second diol monomer of Formula (I-2) are mixed with each other at a mixing temperature which is lower than a prepolymerization temperature at which the first diol monomer of Formula (I-1) and the second diol monomer of Formula (I-2) are subjected to a prepolymerization reaction.7. The process according to claim 6 , wherein the mixing temperature is in a range from 120° C. to 180° C.8. The process according to claim 1 , wherein in step (c) claim 1 , the polycondensation reaction is implemented at a temperature ranging from 180° C. to 300° C.9. A polyester polyol produced by the process according to .10. A polyurethane foam produced by subjecting ...

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17-03-2022 дата публикации

THERMOPLASTIC RESIN, OPTICAL FILM MADE THEREFROM, DIOL COMPOUND, DIESTER COMPOUND

Номер: US20220081510A1
Принадлежит: MITSUBISHI CHEMICAL CORPORATION

A thermoplastic resin may have a structural unit of formula (1): 2. The thermoplastic resin of claim 1 , comprising the structural unit of formula (1) in an amount in a range of from 1 to 70 wt %.3. The thermoplastic resin of claim 1 , having an absolute value of a photoelastic coefficient of 20×10Paor less.4. The thermoplastic resin of claim 1 , having a glass transition temperature in a range of from 110 to 160° C.5. The thermoplastic resin of claim 1 , comprising at least one selected from the group consisting of a polycarbonate claim 1 , a polyester claim 1 , and a polyester carbonate.8. A transparent film claim 1 , comprising the resin of .9. A retardation film claim 8 , comprising the transparent film of claim 8 , stretched in at least one direction.10. The retardation film of claim 9 , wherein an R450/R550 ratio of a retardation at a wavelength of 450 nm (R450) and a retardation at a wavelength of 550 nm (R550) satisfies formula (I):{'br': None, 'i': R', 'R, '0.50≤450/550≤1.02\u2003\u2003(I).'}11. A circularly polarizing plate claim 9 , comprising the retardation film of . This application is a Continuation of International Application No. PCT/JP2020/024490 filed on Jun. 23, 2020, which claims priority to Japanese Patent Application No. 2019-116226 filed on Jun. 24, 2019. The entire contents of which are incorporated herein by reference.The present disclosure relates to a resin excellent in various properties such as optical property, heat resistance, and moldability; an optical film obtained by using the same; and a diol compound and a diester compound used for producing a resin.Recently, demands for optical transparent resins for use in optical systems such as optical lenses, optical films, and optical recording media have increased. Among them, various optical films have been developed and used for the purpose of improving contrast or tinting or enhancing display quality such as increase in viewing angle and prevention of external light reflection because ...

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10-03-2016 дата публикации

POLYESTER BASED COPOLYMER RESIN AND MOLDED PRODUCT COMPRISING THE SAME

Номер: US20160068629A1
Автор: KIM Sung-gi, LIM Seol-Hee
Принадлежит:

There are provided a polyester based copolymer resin capable of having an excellent shrinkage rate and being heat-shrunk at a low temperature, and a molded product comprising the same. The polyester based copolymer resin includes a dicarboxylic acid-derived residue including a residue derived from an aromatic dicarboxylic acid; and a diol-derived residue including a predetermined residue derived from 4-(hydroxymethyl)cyclohexylmethyl 4′-(hydroxymethyl)cyclohexane carboxylate and a predetermined residue derived from 4,4-(oxybis(methylene)bis)cyclohexane methanol. 2. The polyester based copolymer resin of claim 1 , wherein the diol-derived residue further includes residues derived from 1 claim 1 ,4-cyclohexanedimethanol claim 1 , diethylene glycol claim 1 , and ethylene glycol.3. The polyester based copolymer resin of claim 1 , wherein the aromatic dicarboxylic acid is one or more selected from the group consisting of terephthalic acid claim 1 , dimethyl terephthalate claim 1 , cycloaliphatic dicarboxylic acid claim 1 , isophthalic acid claim 1 , adipic acid claim 1 , azelaic acid claim 1 , naphthalenedicarboxylic acid claim 1 , and succinic acid.5. The method of claim 4 , wherein the diol further includes 1 claim 4 ,4-cyclohexanedimethanol claim 4 , diethylene glycol claim 4 , and ethylene glycol.6. The method of claim 5 , wherein the diol includes 0.1 to 5 mol % of 4-(hydroxymethyl)cyclohexylmethyl 4′-(hydroxymethyl)cyclohexane carboxylate claim 5 , 0.1 to 12 mol % of 4 claim 5 ,4-(oxybis(methylene)bis)cyclohexane methanol claim 5 , 0.1 to 15 mol % of 1 claim 5 ,4-cyclohexanedimethanol claim 5 , 2 to 15 mol % of diethylene glycol claim 5 , and 53 to 97.7 mol % of ethylene glycol based on 100 mol % of the dicarboxylic acid.7. The method of claim 4 , wherein the esterification reaction is performed at a reaction temperature of 230 to 265° C. and a pressure of 1.0 to 3.0 kg/cmfor 100 to 300 minutes after injecting the diol at a molar ratio of 1.2 to 3.0 with respect to ...

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10-03-2016 дата публикации

POLYHYDROXY KETAL ESTER ADDUCTS, METHODS OF MANUFACTURE AND USES THEREOF

Номер: US20160068660A1
Принадлежит:

Disclosed herein is a polyhydroxy ketal adduct obtained by the esterification of a hydrocarbon polyol by at least 1.5 equivalents of a ketocarboxy to produce an intermediate ketocarboxylic ester. The intermediate polyketocarboxylic ester is then ketalized to produce the polyhydroxyketal adduct, which can be used to provide a polymeric composition. 1. (canceled)2. (canceled)3. (canceled)4. (canceled)5. (canceled)6. (canceled)7. (canceled)8. (canceled)9. (canceled)10. (canceled)11. (canceled)12. (canceled)13. (canceled)15. The composition of claim 14 , wherein{'sup': 12', '12', '11, 'sub': 'u', 'G is C2-32 alkylene, C2-32 alkenylene, C4-8 cycloalkylene, C5-8 cycloalkenylene, C6-12 arylene, or C2-32 —(RO )R— wherein each Ris methylene, ethylene, 1,3-propylene, or 1,2-propylene and u=1-31,'}{'sup': '2', 'each Ris independently C1-3 alkyl,'}{'sup': 3', '4', '6, 'each R, R, and Ris each independently hydrogen or C1-3 alkyl,'}{'sup': '7', 'each Ris independently C1-6 alkylene,'}each a is independently=0-3,each b is independently=0-1,each m is independently=1-40,p=0-11,q-n=0-10, andn=1-12, provided that p+n≧2, q≧n, and p+(q-n)+n=t.16. The composition of claim 15 , wherein{'sup': 12', '12', '12, 'sub': 'u', 'G is C2-8 alkylene, C2-8 alkenylene, C6-12 arylene, or C4-16 —(RO)R— wherein each Ris independently ethylene, 1,3-propylene, or 1,2-propylene, and u=1-7,'}{'sup': '2', 'each Ris independently C1-3 alkyl,'}{'sup': 3', '4', '6, 'each R, R, and Ris independently hydrogen or C1-3 alkyl,'}{'sup': '7', 'each Ris independently C1-6 alkylene,'}each a is independently=0-3,each b is independently=0-1,each m is independently 1-30,p=0-11,q-n=0-10, andn=1-12, provided that p+n≧2, q≧n, and p+(q-n)+n=t.17. The composition of claim 16 , whereinp=0-9,q-n=1-8, andn=1-10, provided that p+n≧2, q≧n, and p+(q-n)+n=t.18. The composition of claim 17 , whereinp=0-7,q-n=1-6, andn=1-8, provided that p+n≧2, q≧n, and p+(q-n)+n=t.19. The composition of claim 18 , wherein{'sub': 2', '2', '2', '2, 'G ...

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27-02-2020 дата публикации

AROMATIC POLYESTERS FROM BIOSUCCINIC ACID

Номер: US20200062895A1
Принадлежит:

Biosuccinic acid, obtained via sugar fermentation, is cyclodimerized and oxidized to yield building blocks for aromatic polyesters with high glass transition temperatures. 2. The polymer according to claim 1 , wherein the polymer is a copolymer claim 1 , possessing additional repeat units.4. The polymer according to claim 3 , wherein the polymer has a number average molecular weight in a range of from about 5 claim 3 ,000 to about 500 claim 3 ,000.5. The polymer according to claim 3 , wherein the polymer has a weight average molecular weight in a range of from about 10 claim 3 ,000 to about 1 claim 3 ,000 claim 3 ,000.6. The polymer according to claim 3 , wherein the polymer has a dispersity in a range of from about 1.1 to about 10.7. The polymer according to claim 3 , wherein the polymer has a glass transition temperature in a range of from about 30 to about 180° C.9. The polymer according to claim 8 , wherein the polymer has a number average molecular weight in a range of from about 5 claim 8 ,000 to about 500 claim 8 ,000.10. The polymer according to claim 8 , wherein the polymer has a weight average molecular weight in a range of from about 10 claim 8 ,000 to about 1 claim 8 ,000 claim 8 ,000.11. The polymer according to claim 8 , wherein the polymer has a dispersity in a range of from about 1.1 to about 10.12. The polymer according to claim 8 , wherein the polymer has a glass transition temperature in a range of from about 5 to about 80° C.13. A method for producing a polymer claim 8 , comprising:esterifying succinic acid to form dimethyl succinate;dimerizing the dimethyl succinate to obtain dimethyl succinyl succinate;aromatizing the dimethyl succinyl succinate via at least one selected from N-chlorosuccinimide oxidation, sulfuric acid oxidation, dimethylsulfoxide oxidation, hydrogen peroxide oxidation, and transfer dehydrogenation to produce dimethyl 2,5-dihydroxyterephthalate;hydrolysing and optionally methylating the dimethyl 2,5-dihydroxyterephthalate to ...

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09-03-2017 дата публикации

POLYESTER-CONTAINING OBJECT MADE FROM MELT-PROCESSING POLY(ETHYLENE- 2,5-FURANDICARBOXYLATE)

Номер: US20170066875A1
Принадлежит: FURANIX TECHNOLOGIES B.V.

A polyester-containing object, such as an injection stretch blow moulded bottle, a biaxially oriented film or a drawn fibre, is made from melt-processing poly(ethylene-2,5-furandicarboxylate). The poly(ethylene-2,5-furandicarboxylate) has a number average molecular weight of at least 25,000, as determined by GPC based on polystyrene standards, and includes an antimony catalyst. 119-. (canceled)20. A polyester-containing object made from melt-processing poly(ethylene-2 ,5-furandicarboxylate) , wherein the poly(ethylene-2 ,5-furandicarboxylate) has a number average molecular weight of at least 25 ,000 , as determined by GPC based on polystyrene standards , and comprises an antimony catalyst.21. The object according to claim 20 , wherein the poly(ethylene-2 claim 20 ,5-furandicarboxylate) further comprises is a calcium or zinc catalyst22. The object according to that has been subjected to a step comprising strain hardening improve mechanical properties.25. The object according to claim 20 , wherein the poly(ethylene-2 claim 20 ,5-furandicarboxylate) has an absorbance as a 5 mg/mL solution in a dichloromethane:hexafluoroisopropanol 8:2 at 400 nm of below 0.05 claim 20 , without intermediate or subsequent purification and/or washing step.24. The object according to claim 20 , which is an injection stretch blow moulded bottle.25. The object according to claim 20 , which is biaxially oriented film.26. The object according to claim 20 , which is a drawn fibre. This application is a continuation of U.S. application Ser. No. 14/353,138, filed Apr. 21, 2014, which is the National Stage of International Application No. PCT/NL2012/050738 filed Oct. 24, 2012, which claims the benefit of Netherlands Application No. 2007650, filed Oct. 25, 2011 and the benefit of U.S. Provisional Application No. 61/550,707, filed Oct. 24, 2011, the contents of all of which are incorporated by reference herein.This invention relates to a process for preparing polymers having 2,5-furandicarboxylic ...

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11-03-2021 дата публикации

THERMOPLASTIC POLYESTER HAVING IMPROVED RESISTANCE TO THE PHENOMENON OF CRACKING

Номер: US20210070930A1
Принадлежит:

The invention relates to the field of polymers, particularly a thermoplastic polyester having an improved resistance to the cracking phenomenon, to the production method thereof, and to the use of same for producing plastic items. The thermoplastic polyester comprises at least one 1,4:3,6-dianhydrohexitol motif (A), at least one diol motif (B), other than the 1,4:3,6-dianhydrohexitol motif (A), at least one aromatic dicarboxylic acid motif (C) and at least one branching agent, and has a reduced viscosity in solution of a minimum of 0.75 dL/g and a maximum of 1.5 dL/g. Said thermoplastic polyester is advantageous in that it is particularly resistant to the phenomenon of cracking and also has improved esterification and polycondensation times during the production method thereof. 1. A thermoplastic polyester comprising:at least one 1,4:3,6-dianhydrohexitol unit (A),at least one diol unit (B), other than the 1,4:3,6-dianhydrohexitol unit (A),at least one aromatic dicarboxylic acid unit (C),said polyester being characterized in that it comprises a branching agent and in that it has a reduced viscosity in solution of at least 0.90 dl/g and at most 1.3 dl/g measured using an Ubbelohde capillary viscometer at 25° C. in an equi-mass mixture of phenol and ortho-dichlorobenzene after dissolution of the polymer at 135° C. with stirring, the concentration of polyester introduced being 5 g/l.2. The thermoplastic polyester as claimed in claim 1 , characterized in that the 1 claim 1 ,4:3 claim 1 ,6-dianhydrohexitol unit (A) is isosorbide claim 1 , isomannide claim 1 , isoidide claim 1 , or a mixture thereof.3. The thermoplastic polyester as claimed in claim 1 , characterized in that the diol unit (B) is an alicyclic diol unit claim 1 , a non-cyclic aliphatic diol unit or a mixture of an alicyclic diol unit and a non-cyclic aliphatic diol unit.4. The thermoplastic polyester as claimed in claim 3 , characterized in that the alicyclic diol unit is chosen from the group comprising 1 ...

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17-03-2016 дата публикации

Polymeric materials

Номер: US20160075716A1

The present invention relates to a polymer comprising as part of its polymer backbone a moiety of Formula (II): where one of R 6 to R 10 represents A-O— and one of R 6 to R 10 represents —O—B and the remainder of R 6 to R 10 represent H, where A and B represent the remainder of the polymer backbone and may be the same or different.

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19-03-2015 дата публикации

Polymeric nanocarriers with linear dual response mechanism

Номер: US20150079005A1
Принадлежит: UNIVERSITY OF CALIFORNIA

Nanocarriers are synthesized with polymers that respond to lower pH and/or ROS by being degraded. The compositions may be utilized to selectively deliver payloads within patients by responding to lower pH and/or ROS at localities within the patient. The present invention also features methods of synthesizing nanocarriers that are degraded by lower pH and/or ROS.

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16-03-2017 дата публикации

ARTICLES COMPRISING ISOSORBIDE AND PROCESSES FOR THEIR MANUFACTURE

Номер: US20170073461A1
Принадлежит: EASTMAN CHEMICAL COMPANY

The invention is generally directed to sports bottles and other articles produced by blow molding from polymeric materials containing isosorbide having glass transition temperatures ranging from 90° C. to 130° C., as well as to processes for producing them. These articles can be exposed to water at high tempeatures and can be produced by using a suitable combination of a stretch ratio of less than 3× and a preform temperature at least 20° C. greater than the glass transition temperature (Tg) of the polymeric material. 129.-. (canceled)30. A molded article comprising a polymeric material ,wherein the polymeric material comprises at least one polyester, which comprises i) 70 to 100 mole % of terephthalic acid residues;', 'ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and', 'iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and, '(a) a dicarboxylic acid component comprising i) 5 to 35 mole % of isosorbide residues;', 'ii) 40 to 65 mole % of 1,4-cyclohexanedimethanol residues,', 'iii) 20 to 40 mole % of ethylene glycol residues;, '(b) a glycol component comprisingwherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %;wherein the inherent viscosity of the polyester is from 0.45 to 1.0 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; andwherein the polyester has a Tg in the range from 90° C. to 130° C.31. The article according to claim 30 , wherein the glycol component comprises 10 to 35 mole % of isosorbide residues.32. The article according to claim 31 , wherein the glycol component comprises 10 to 30 mole % of isosorbide residues.33. The article according to claim 32 , wherein the glycol component comprises 20 to 30 mole % of isosorbide residues.34. The article according to claim 30 , wherein the glycol component comprises 45 to 65 mole % of 1 claim 30 , ...

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05-03-2020 дата публикации

THERMOPLASTIC POLYETHER ESTER ELASTOMER COMPRISING ANHYDROSUGAR ALCOHOL DERIVATIVE AND METHOD FOR PREPARING SAME

Номер: US20200071518A1
Принадлежит: SAMYANG CORPORATION

The present invention relates to a thermoplastic polyether ester elastomer (TPEE) having a hard segment and a soft segment and a method for preparing the same and, more specifically, to a thermoplastic polyether ester elastomer and a method for preparing the same, wherein a unit derived from an anhydrosugar alcohol derivative with improved reactivity derived from biomass is contained in the soft segment, and thus through the adjustment of the content of the anhydrosugar alcohol derivative, elastic characteristics and physical characteristics (for example, hardness, etc.), which are important characteristics of an elastomer, can be favorably maintained, the melting point variously required in the molding process of a final product can be easily controlled, a problem of depletion of, especially, petroleum resources as finite resources, can be solved, and environmental friendliness can be improved. 1. A thermoplastic polyether ester elastomer consisting of a hard segment and a soft segment ,wherein the hard segment comprises an aromatic dicarboxylic compound and an aliphatic diol component as polymerized units,the soft segment comprises an aromatic dicarboxylic compound and a glycol component as polymerized units, andthe glycol component comprises an anhydrosugar alcohol-alkylene glycol.2. The thermoplastic polyether ester elastomer according to claim 1 , wherein the aromatic dicarboxylic compound is selected from the group consisting of terephthalic acid claim 1 , isophthalic acid claim 1 , 1 claim 1 ,5-dinaphthalene dicarboxylic acid claim 1 , 2 claim 1 ,6-dinaphthalene dicarboxylic acid claim 1 , dimethyl terephthalate claim 1 , dimethyl isophthalate and combinations thereof.3. The thermoplastic polyether ester elastomer according to claim 1 , wherein the aliphatic diol component is a linear aliphatic diol having 2 to 8 carbon atoms or a cyclic aliphatic diol having 3 to 8 carbon atoms.4. The thermoplastic polyether ester elastomer according to claim 1 , wherein the ...

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18-03-2021 дата публикации

Polyester resin and preparation method of the same

Номер: US20210079157A1

Provided are a polyester resin having a high residual rate of isosorbide, thereby exhibiting excellent heat resistance, excellent mechanical properties such as tensile strength, Young's modulus, etc., and excellent appearance properties and transparency, and a preparation method thereof.

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31-03-2022 дата публикации

POLYCARBONATE POLYESTER

Номер: US20220098365A1
Принадлежит:

A polycarbonate polyester includes residues of following formula (1), formula (2) and formula (3): 2. (canceled)3. (canceled)4. The polycarbonate polyester of claim 3 , wherein the residue of the formula (1) further comprises a C-Caliphatic linear or branched diol residue.8. The polycarbonate polyester of claim 1 , wherein the residue of the formula (3) is present in an amount of no more than 50 mol % of the polycarbonate polyester.9. The polycarbonate polyester of claim 1 , wherein Rof the formula (1) is a polycycloalkyl group.10. The polycarbonate polyester of claim 1 , wherein Rof the formula (1) is a bicycloalkyl group or a tricycloalkyl group.12. The polycarbonate polyester of claim 11 , wherein Ris a C-Caliphatic hydrocarbon group or a C-Caromatic hydrocarbon group.14. The polycarbonate polyester of claim 1 , wherein the residue of the formula (2) is derived from a dialkyl carbonate monomer.15. The polycarbonate polyester of claim 11 , wherein the residue of the formula (4) is present in an amount of less than or equal to 0.4 mol % of the polycarbonate polyester.16. The polycarbonate polyester of claim 11 , wherein the residue of the formula (4) is present in an amount of 0.05 mol % to 0.2 mol % of the polycarbonate polyester. This application claims priority to Taiwan Application Serial Number 109133778, filed Sep. 29, 2020, which is herein incorporated by reference.The present disclosure relates to a polycarbonate polyester, and particularly relates to a polycarbonate polyester including specific residues (i.e., following formulas (1), (2) and (3)).In general, polycarbonate has poor heat resistance, chemical resistance, and impact resistance. If polycarbonate is used in combination with polyester, chemical resistance of the composition can be improved, but heat resistance and impact resistance of the composition will be significantly reduced. Therefore, how to make polycarbonate polyester possess both good heat resistance and good mechanical properties has ...

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12-03-2020 дата публикации

ALIPHATIC-AROMATIC BIODEGRADABLE POLYESTER

Номер: US20200079899A1
Принадлежит:

Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding. 2. The biodegradable polyester according to claim 1 , wherein the at least one aliphatic dicarboxylic acid or ester thereof originating from renewable sources is a C8-C13 dicarboxylic acid or ester thereof.3. The biodegradable polyester according to claim 1 , wherein the at least one aliphatic dicarboxylic acid or ester thereof originating from renewable sources is selected from the group of azelaic acid claim 1 , sebacic acid claim 1 , suberic acid claim 1 , brassylic acid and their esters.4. The biodegradable polyester according to claim 1 , wherein the polydispersity index Mw/Mn of the polyester is between 1.4 and 8.5. The biodegradable polyester according to claim 1 , wherein the molecular weight Mn of the polyester is between 10 claim 1 ,000 and 120 claim 1 ,000.6. The biodegradable polyester according to claim 5 , wherein the molecular weight Mn of the polyester is between 20 claim 5 ,000 and 100 claim 5 ,000.7. A blend of the biodegradable polyester according to claim 1 , obtained also by reactive extrusion claim 1 , both with polyesters of the same type and with at least one other biodegradable polymer of either natural or synthetic origin.8. The blend according to claim 7 , wherein the polymer of synthetic origin is selected from the group of a biodegradable polyester or ...

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25-03-2021 дата публикации

TOUGH SHRINKABLE FILMS

Номер: US20210086468A1
Принадлежит: EASTMAN CHEMICAL COMPANY

The present disclosure relates to a shrink film comprising a polyester composition comprising: 1. A shrink film comprising a polyester composition comprising: [ (i) about 70 to about 100 mole % of terephthalic acid residues;', '(ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and, '(a) a dicarboxylic acid component comprising, (i) about 0.01 to about 26 mole % neopentyl glycol residues;', '(ii) about less than 10 mole % 1,4-cyclohexanedimethanol residues;', '(iii) about 50 to 90 mole % ethylene glycol residues; and', '(iv) about 2 to 15 mole % total diethylene glycol residues in the final polyester composition;, '(b) a diol component comprising], '(1) at least one polyester which compriseswherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.2. The shrink film of claim 1 , wherein the inherent viscosity of the polyester is from 0.50 to 0.80 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C.3. The shrink film of claim 1 , wherein the polyester has a Tg of from 60° C. to 80° C. as determined using a TA DSC 2920 from Thermal Analyst Instrument at a scan rate of 20° C./min.4. The shrink film of claim 1 , wherein the sum of one or more diol monomer components capable of forming an amorphous component in the final polyester composition is from 20 to 45 mole % wherein the total diol component is 100 mole %.5. The shrink film of claim 1 , wherein the sum of the residues of 1 claim 1 ,4-cyclohexanedimethanol and neopentyl glycol in the final polyester composition is from 10 to 40 mole % wherein the total diol component is 100 mole %.6. The shrink film of claim 1 , wherein the ethylene glycol residues are present in an amount of 65 to 75 mole %.7. The shrink film of claim 1 , wherein the diethylene glycol residues are present in an amount of 2 to 12 mole %.8. The shrink ...

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29-03-2018 дата публикации

Method of producing furan carboxylates from aldaric acids by using solid heterogeneous catalyst

Номер: US20180086728A1
Принадлежит:

According to an example aspect of the present invention, there is provided a method of producing furan carboxylates from aldaric acids in the presence of a solid heterogeneous catalyst and a solvent with short reaction time. The feedstock for the production is a stable compound, which allows industrial scaling of the process. Solid acid catalyst and sustainable solvent provide considerable reduction of toxic waste compared to traditional methods, and recyclability. 1. A method of producing furan carboxylates and furan dicarboxylates from aldaric acids , comprising mixing together an aldaric acid , a solid heterogeneous catalyst selected from the group consisting of perfluorosulfonic acid polymer , phenyl sulfonic acid ethyl sulfide silica , sulfonated alumina catalyst and sulfonated zirconia catalyst , and a solvent at temperature between 130 and 250° C. , and by applying a reaction time of 0.25 to 9 hours , to form a solution comprising furan esters.2. The method of claim 1 , further comprising the steps of:charging an aldaric acid, a non-toxic heterogeneous solid acid catalyst and an organic solvent into a pressure reaction vessel to form a reaction mixture,heating the reaction mixture to temperature between 130 and 250° C. in said reaction vessel,maintaining the temperature in the reaction vessel for a pre-determined reaction time, andrecovering the desired furan ester(s) and/or acid(s) from the reaction mixture.3. The method of claim 1 , further comprising applying a reaction time of 0.25 to 4 hours claim 1 , preferably 0.5 to 2 hours claim 1 , and most suitably about 1 hour.4. The method of claim 1 , wherein the aldaric acid is either galactaric acid or glucaric acid in either free acid or ester form.5. The method of claim 1 , wherein the solvent is water or tetrahydrofuran (THF) or mixtures thereof.6. The method of claim 1 , wherein the solvent is an alcohol solvent selected from monovalent or polyvalent C-Calcohols claim 1 , or any combination thereof.7. The ...

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29-03-2018 дата публикации

ANTISTATIC RESIN COMPOSITION AND POLYOLEFIN ANTISTATIC FIBER FOR CONTAINER AND PIPE FOR ORGANIC SOLVENT

Номер: US20180086958A1
Принадлежит: ADEKA CORPORATION

Provided are: an antistatic resin composition for containers and pipes of organic solvents, which has long-lasting and sufficient antistaticity and whose antistatic performance is not impaired even when the composition is in contact with an organic solvent for a long period of time; and a container and a pipe for organic solvents, which include the same. 1. An antistatic resin composition for containers and pipes of organic solvents , said antistatic resin composition comprising 3 to 25 parts by mass of at least one polymer compound (E) with respect to 100 parts by mass of a thermoplastic resin , {'br': None, 'sub': 2', '2, '—CH—CH—O—\u2003\u2003(1)'}, 'wherein said polymer compound (E) has a structure in which a diol, an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, a compound (B) which comprises at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and an epoxy compound (D) having two or more epoxy groups are bound via ester bonds2. The antistatic resin composition for containers and pipes of organic solvents according to claim 1 , wherein said polymer compound (E) has a structure in which a polyester (A) claim 1 , which is constituted by a diol claim 1 , an aliphatic dicarboxylic acid and an aromatic dicarboxylic acid claim 1 , said compound (B) and said epoxy compound (D) are bound via ester bonds.3. The antistatic resin composition for containers and pipes of organic solvents according to claim 2 , wherein said polymer compound (E) has a structure in which a block polymer (C) having carboxyl groups at both ends and said epoxy compound (D) are bound via an ester bond claim 2 , said block polymer (C) comprising a block constituted by said polyester (A) and a block constituted by said compound (B) that are repeatedly and alternately bound via ester bonds.4. The antistatic resin composition for containers and pipes of organic solvents according to claim 2 , wherein said polyester (A) constituting said ...

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02-04-2015 дата публикации

LIQUID, ADHESION-PROMOTING ADDITIVE AND PROCESS FOR ITS PREPARATION

Номер: US20150094419A1
Принадлежит: Evonik Industries AG

A polyester resin, comprising a polyester which comprises as esterified polymer units: at least one of an unsaturated dicarboxylic acid and an unsaturated polycarboxylic acid; and at least one of an alkoxylated diol and an alkoxylated polyol is provided. An adhesion-promoting additive comprising the polyester resin is also provided 1. A polyester resin , comprising a polyester which comprises as esterified polymer units:at least one of an unsaturated dicarboxylic acid and an unsaturated polycarboxylic acid; andat least one of an alkoxylated diol and an alkoxylated polyol.2. The polyester resin according to claim 1 , wherein the polyester resin is free of a polyester comprising any of bisphenol A claim 1 , B claim 1 , C claim 1 , F or derivatives thereof.3. The polyester resin according to claim 1 , wherein the at least one of an unsaturated dicarboxylic acid and an unsaturated polycarboxylic acid is an unsaturated dicarboxylic or polycarboxylic acid selected from the group consisting of citraconic acid claim 1 , fumaric acid claim 1 , itaconic acid claim 1 , maleic acid and mesaconic acid.4. The polyester resin according to claim 1 , wherein the polyester further comprises as an esterified polymer unit claim 1 , an acid selected from the group consisting of an aromatic claim 1 , aliphatic or cycloaliphatic monocarboxylic acid claim 1 , an aromatic claim 1 , aliphatic or cycloaliphatic dicarboxylic acid claim 1 , an aromatic claim 1 , aliphatic or cycloaliphatic polycarboxylic acid and a phosphoric acid.5. The polyester resin according to claim 1 , wherein the alkoxylated diol or polyol is selected from the group consisting of a linear claim 1 , branched claim 1 , aliphatic cycloaliphatic or aromatic diol and a linear claim 1 , branched claim 1 , aliphatic cycloaliphatic or aromatic polyol.6. The polyester resin according to claim 1 , wherein the alkoxylated diol or polyol is a linear claim 1 , branched claim 1 , aliphatic or cycloaliphatic diol or a linear claim 1 , ...

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05-05-2022 дата публикации

A Method for the Combined Production of at Least Two Target Products

Номер: US20220135737A1
Принадлежит:

The present invention relates to a method for the combined production of at least two target products selected from the group consisting of (T), (T) and (T), wherein (T) is a terephthalate polyester, (T) is a copolyester on the basis of terephthalic acid, at least one aliphatic 1,ω-dicarboxylic acid and at least one aliphatic 1,ω-diol, and (T) is a copolyester on the basis of terephthalic acid, polytetramethylene glycoland at least one aliphatic 1,ω-diol.

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19-03-2020 дата публикации

POLYESTER RESIN, METHOD FOR PREPARING SAME, AND RESIN MOLDED PRODUCT FORMED THEREFROM

Номер: US20200087450A1
Принадлежит:

The present invention relates to a polyester resin. The polyester resin contains a particular content of diol moieties, derived from isosorbide and diethylene glycol, and thus can provide a resin molded product exhibiting high transparency in spite of a large wall thickness thereof. 1. A polyester resin polymerized with a dicarboxylic acid including terephthalic acid or a derivative thereof and a diol including isosorbide and ethylene glycol , thereby having an alternating structure of an acid moiety derived from the dicarboxylic acid or a derivative thereof and a diol moiety derived from the diol ,wherein the polyester resin includes 6 to 12 mol % of a diol moiety derived from isosorbide and 2 to 5 mol % of a diol moiety derived from diethylene glycol based on the total diol moieties derived from the diol,wherein a melting point exists during the first scan through a differential scanning calorimetry (DSC), andwherein a haze is less than 3% as measured according to ASTM D1003-97 for a specimen having a thickness of 6 mm obtained from the polyester resin.2. The polyester resin of claim 1 , wherein the haze is 1.5% or less as measured according to ASTM D1003-97 for a specimen having a thickness of 6 mm obtained from the polyester resin.3. The polyester resin of claim 1 , wherein the dicarboxylic acid or a derivative thereof is a dicarboxylic acid or a derivative thereof other than terephthalic acid or a derivative thereof claim 1 , which includes at least one selected from the group consisting of an aromatic dicarboxylic acid having 8 to 14 carbon atoms or a derivative thereof and an aliphatic dicarboxylic acid having 4 to 12 carbon atoms or a derivative thereof in an amount of 0 to 50 mol % based on the total dicarboxylic acids or derivatives thereof.4. The polyester resin of claim 1 , wherein the polyester resin has a number average molecular weight of 15 claim 1 ,000 to 50 claim 1 ,000 g/mol.5. The polyester resin of claim 1 , wherein the polyester resin has a ...

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19-03-2020 дата публикации

METHOD FOR REPRODUCING POLYESTER CONTAINER AND REPRODUCED POLYESTER CHIP PREPARED THEREFROM

Номер: US20200087480A1
Принадлежит:

Embodiments relate to a process for regenerating a polyester container and regenerated polyester chips prepared therefrom. The process comprises preparing a polyester container provided with a heat shrinkable film; crushing the container provided with the heat shrinkable film to obtain flakes; and thermally treating the flakes to produce regenerated polyester chips, wherein when the flakes are thermally treated at a temperature of 200° C. to 220° C. for 60 minutes to 120 minutes, the clumping fraction is 5% or less, and the flakes comprise first flakes obtained by crushing the container and second flakes obtained by crushing the heat shrinkable film. It not only solves the environmental problems by improving the recyclability of the polyester container, but also is capable of enhancing the yield and productivity. 1. A plastic container comprising:a polyester container, anda heat shrinkable film, which is provided at the polyester container;wherein the heat shrinkable film is shrunk by steam or hot air to wrap the outer surface of the polyester container,wherein the heat shrinkable film comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component andhas a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds anda melting point of 190° C. or higher as measured by differential scanning calorimetry,wherein when a plurality of flakes are thermally treated at a temperature of 200° C. to 220° C. for 60 minutes to 120 minutes, the clumping fraction is 5% or less,wherein the flakes comprise first flakes obtained by crushing the container and second flakes obtained by crushing the heat shrinkable film.2. The plastic container of claim 1 , wherein the copolymerized polyester resin comprises ethylene glycol and neopentyl glycol.3. The plastic container of claim 1 , wherein the particle size of the first flakes is 0.1 to 20 mm claim 1 , and the particle size ...

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12-05-2022 дата публикации

THERMOPLASTIC RESIN, METHOD FOR MANUFACTURING SAME, AND OPTICAL LENS

Номер: US20220145004A1
Принадлежит: MITSUBISHI GAS CHEMICAL COMPANY, INC.

Provided is a thermoplastic resin including constituent units represented by general formula (1). (In formula (1), R1 and R2 each independently represent: a hydrogen atom; a fluorine atom; a chlorine atom; a bromine atom; an iodine atom; a C1-6 alkyl group; a monocyclic or polycyclic C6-36 aryl group; a monocyclic or polycyclic heteroaryl group having 5-36 ring atoms, 1, 2, 3, or 4 of the ring atoms being selected from nitrogen, sulfur, and oxygen, and the other ring atoms being carbon in the heteroaryl group; a C2-6 alkenyl group; a C1-6 alkoxy group; or a C7-17 aralkyl group. In formula (1), X, a, and bare each as described in the present specification.) 2. The thermoplastic resin according to claim 1 , which is a polyester resin or a polyester carbonate resin.45.-. (canceled)6. The thermoplastic resin according to claim 1 , which comprises the structural unit represented by general formula (1) in an amount of more than 50 mol %.7. The thermoplastic resin according to claim 1 , wherein at least one of R1 and R2 in general formula (1) is an aryl group having 6 to 20 carbon atoms.8. (canceled)11. The thermoplastic resin according to claim 10 , which comprises a copolymer comprising at least the structural unit represented by general formula (1) and the structural unit represented by general formula (3).12. (canceled)13. The thermoplastic resin according to claim 10 , which comprises a copolymer comprising at least the structural unit represented by general formula (1) and the structural unit represented by general formula (4).1415.-. (canceled)1719.-. (canceled)20. The thermoplastic resin according to claim 1 , wherein the aryl group is selected from among a pyrenyl group claim 1 , a furanyl group claim 1 , a benzodioxanyl group claim 1 , a dihydrobenzofuranyl group claim 1 , a piperonyl group claim 1 , a benzofuranyl group claim 1 , a dibenzofuranyl group claim 1 , a pyrrolidinyl group claim 1 , an isoquinolyl group claim 1 , a pyrimidinyl group and a carbazole ...

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12-05-2022 дата публикации

PROTECTIVE COMPOSITION

Номер: US20220145094A1
Принадлежит:

A protective composition is used to form a protective coating on a metal and contains a water-soluble polyester resin. 1. A protective composition for use to form a protective coating on a metal , the protective composition containing a water-soluble polyester resin (A).2. The protective composition of claim 1 , whereinthe water-soluble polyester resin (A) includes a polyvalent carboxylic acid residue (a),the polyvalent carboxylic acid residue (a) includes a polyvalent carboxylic acid residue (a1) having a metal sulfonate group, anda proportion of the polyvalent carboxylic acid residue (a1) having the metal sulfonate group to the polyvalent carboxylic acid residue (a) falls within a range from 7 mol % to 80 mol %.3. The protective composition of claim 2 , whereinthe proportion of the polyvalent carboxylic acid residue (a1) having the metal sulfonate group to the polyvalent carboxylic acid residue (a) falls within a range from 7 mol % to less than 15 mol %.4. The protective composition of claim 1 , whereinthe water-soluble polyester resin (A) includes a polyvalent carboxylic acid residue (a),the polyvalent carboxylic acid residue (a) includes a naphthalene dicarboxylic acid residue (a2), anda proportion of the naphthalene dicarboxylic acid residue (a2) to the polyvalent carboxylic acid residue (a) falls within a range from 20 mol % to 93 mol %.5. The protective composition of claim 1 , whereinthe water-soluble polyester resin (A) includes a polyvalent alcohol residue (b),the polyvalent alcohol residue (b) includes an ethylene glycol residue (b1), anda proportion of the ethylene glycol residue (b1) to the polyvalent alcohol residue (b) is equal to or greater than 70 mol %.6. The protective composition of claim 1 , whereinthe water-soluble polyester resin (A) has an acid number of 10 mgKOH/g or less.7. The protective composition of claim 1 , whereinthe water-soluble polyester resin (A) has a glass transition temperature of 10° C. to 100° C.8. The protective composition ...

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28-03-2019 дата публикации

Polyester resin for toners, method for producing same, toner and method for producing toner

Номер: US20190094733A1
Принадлежит: Mitsubishi Chemical Corp

Provided is polyester resin for toner including: a constitutional unit derived from at least one compound selected from the group consisting of specific Compounds (A) and (B); and a constitutional unit derived from tri- or higher valent carboxylic acid (excluding Compounds (A) and (B)), in which a content of the constitutional unit derived from tri- or higher valent carboxylic acid with respect to all constitutional units derived from carboxylic acid is greater than or equal to 0.5 mol %, and an acid value after melting and kneading is less than or equal to 55 mgKOH/g.

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13-04-2017 дата публикации

TRANSPARENT BIODEGRADABLE POLYMER

Номер: US20170101504A1
Принадлежит: LOTTE FINE CHEMICAL CO., LTD.

The present invention is characterized by introducing isosorbide to a monomer configuration for securing the transparency of a biodegradable polymer as well as providing material having excellent heat resistance and flexibility, As a monomer, a component derived from isosorbide which has a rigid structure is contained by 10-50 mol % of a total diol component, thereby bringing a heat resistance enhancing effect, and enhancing transparency by interfering with crystal formation, and allowing for providing a polymer having excellent flexibility. Thus, the present invention may enable securing stability in usage especially in the packaging area, and enable the heightening of the range of usage and utilization thereof. 1. A biodegradable polymer , comprising:a component derived from isosorbide at 10 to 50 mol % and a component derived from an aliphatic diol, which has a backbone consisting of 2 to 5 carbon atoms, at 50 to 90 mol % based on total diol components; anda component derived from an aromatic dicarboxylic acid at 50 to 70 mol % and a component derived from an aliphatic dicarboxylic acid with 2 to 6 carbon atoms at 30 to 50 mol % based on total dicarboxylic acid components.2. The biodegradable polymer of claim 1 , wherein the aliphatic diol which has a backbone consisting of 2 to 5 carbon atoms is at least one selected from the group consisting of ethylene glycol claim 1 , 1 claim 1 ,2-propanediol claim 1 , 1 claim 1 ,3-propanediol claim 1 , 1 claim 1 ,4-butanediol claim 1 , 2 claim 1 ,3-butanediol claim 1 , 2-methyl-2 claim 1 ,3-butanediol claim 1 , 2 claim 1 ,3-dimethyl-2 claim 1 ,3-butanediol claim 1 , 1 claim 1 ,5-pentanediol and 4-methyl-2 claim 1 ,3-pentanediol.3. The biodegradable polymer of claim 1 , Wherein the aromatic dicarboxylic acid is at least one selected from the group consisting of dimethyl terephthalate claim 1 , terephthalic acid claim 1 , isophthalic acid claim 1 , naphthoic acid claim 1 , naphthalenedicarboxylic acid and derivatives thereof.4 ...

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13-04-2017 дата публикации

ALKOXYLATED POLYMERS

Номер: US20170101505A1
Принадлежит: SUN CHEMICAL CORPORATION

The present invention provides alkoxylated polymers. The alkoxylated polymers have two or more alkoxylated sites. The alkoxylated polymers can comprise any monomers and/or oligomers that contain one or more functional groups with an active hydrogen. The alkoxylated polymers are useful in any application for which polymers are generally used. For example, the alkoxylated polymers are useful as additives in ink and coating compositions. 1. An alkoxylated polymer comprising:a) a backbone with one or more alkoxylated sites;b) terminal ends each of which is a site that can be alkoxylated; andc) one or more polyfunctional monomers or oligomers having two or more functional polar groups with an active hydrogen, or mixtures thereof.2. The alkoxylated polymer of claim 1 , wherein the functional polar groups are independently selected from the group consisting of hydroxyl claim 1 , carboxyl claim 1 , thiol claim 1 , amino claim 1 , imino claim 1 , amido claim 1 , or ureido.3. The alkoxylated polymer of claim 1 , wherein one or more functional polar groups are hydroxyl.4. The alkoxylated polymer of claim 1 , where the polyfunctional monomers and/or oligomers are functionalized by one or more COOH functional diols.5. The alkoxylated polymer of claim 4 , wherein at least one COOH functional diol is dimethylolpropionic acid.6. The alkoxylated polymer of claim 1 , where the polyfunctional monomers and/or oligomers are functionalized by one or more diacids or anhydrides claim 1 , or mixtures thereof.7. The alkoxylated polymer of claim 6 , wherein at least one anhydride is tetrahydrophthalic anhydride.8. The alkoxylated polymer of claim 1 , where the polyfunctional monomers and/or oligomers are functionalized by one or more diols.9. The alkoxylated polymer of claim 1 , wherein the one or more polyfunctional monomers or oligomers is selected from the group consisting of trimethylol propane claim 1 , ethylene glycol claim 1 , diethylene glycol claim 1 , 1 claim 1 ,4-butandiol claim 1 ...

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23-04-2015 дата публикации

Bio-Based Toner Resin with Increased Fusing Performance

Номер: US20150111141A1
Принадлежит: XEROX CORPORATION

The disclosure describes a sustainable toner with favorable hot offset and gloss mottle comprising a bioresin, where the toner surface has a carbon to oxygen ratio higher than found in existing bio-based toners comprising a bioresin. 1. A toner comprising at least one bioresin , wherein said toner comprises a surface carbon-to-oxygen (C/O) ratio greater than about 3.9.2. The toner of claim 1 , comprising a shell.3. The toner of claim 2 , wherein said shell comprises a bioresin.4. The toner of claim 1 , comprising a wax.5. The toner of claim 1 , comprising at least one amorphous resin and optionally a crystalline resin.6. The toner of claim 1 , wherein said amorphous resin is selected from the group consisting of polyesters claim 1 , polyamides claim 1 , polyimides claim 1 , polyisobutyrates claim 1 , polyolefins and combinations thereof.7. The toner of claim 1 , comprising at least two amorphous resins.8. The toner of claim 1 , comprising at least two amorphous resins and a crystalline resin.9. The toner of claim 1 , comprising a high molecular weight amorphous resin and a low molecular weight amorphous resin.10. The toner of claim 9 , further comprising a crystalline resin.11. The toner of claim 1 , wherein said C/O is from about 3.9 to about 4.2.12. The toner of claim 1 , wherein said bioresin comprises a rosin acid.13. The toner of claim 1 , wherein said bioresin comprises a neopentyl glycol diglycidyl ether.14. The toner of claim 1 , wherein said bioresin comprises a terephthalic acid.15. The toner of claim 1 , wherein said bioresin comprises a succinic acid.16. The toner of claim 1 , wherein said bioresin comprises a propylene glycol.17. The toner of claim 1 , wherein said bioresin comprises a fumaric acid.18. The toner of claim 1 , wherein said bioresin comprises a disproportionated rosin acid.19. A developer comprising the toner of .20. The developer of claim 18 , comprising a carrier. Bio-based resins are optimized for fusing performance.The vast majority of ...

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02-06-2022 дата публикации

TONER

Номер: US20220171301A1
Принадлежит:

The toner contains a toner particle having a core-shell structure including: a core containing a binder resin and a colorant; and a shell, wherein the toner contains a crystalline material, and the shell contains an amorphous thermoplastic resin; and when SP values of the crystalline material and the amorphous thermoplastic resin, which are calculated by the Fedors method, are defined as SPc (J/cm)and SPa (J/cm), respectively, the SPc and the SPa (J/cm) satisfy a particular relationship, and when the toner is observed by SEM after the toner has been subjected to ruthenium staining that treats the toner in an atmosphere of RuOgas having 500 Pa for 15 minutes, a ratio S2 (%) of an area occupied by the crystalline material per area of the toner satisfies a particular relationship. 1. A toner containing a toner particle having a core-shell structure comprising:a core containing a binder resin and a colorant; anda shell, whereinthe toner contains a crystalline material, andthe shell contains an amorphous thermoplastic resin;{'sup': 3', '0.5', '3', '0.5, 'claim-text': {'br': None, 'i': 'SPa−SPc≤', '2.50 ≤4.50\u2003\u2003(1), and'}, 'when an SP value of the crystalline material calculated by the Fedors method is defined as SPc (J/cm), and an SP value of the amorphous thermoplastic resin calculated by the Fedors method is defined as SPa (J/cm), the SPc and the SPa satisfy the following expression (1){'sub': '4', 'claim-text': {'br': None, 'i': 'S≤', '1.0 ≤20.0\u2003\u2003(2).'}, 'when the toner is observed by a scanning electron microscope (SEM) after the toner has been subjected to ruthenium staining that treats the toner in an atmosphere of RuO(ruthenium tetroxide) gas having 500 Pa for 15 minutes, and a ratio of an area occupied by the crystalline material per area of the toner is defined as S2(%), the S2(%) satisfies the following expression (2)2. The toner according to claim 1 , wherein the toner has a viscosity claim 1 , at 100° C. measured by a flow tester ...

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19-04-2018 дата публикации

CRYSTALLINE WHOLLY AROMATIC POLYESTER AND METHOD FOR MANUFACTURE THEREOF

Номер: US20180105641A1
Автор: ANDO Masatoshi
Принадлежит: JXTG NIPPON OIL & ENERGY CORPORATION

[Problem] Provided is a crystalline wholly aromatic polyester which is a polycondensate of an aromatic dicarboxylic acid and an aromatic diol and method for manufacture thereof. 4. The wholly aromatic polyester according to claim 1 , satisfying 80 mol %≤[the structural unit represented by formula (1)+the structual unit represented by formula (4)]≤100 mol %.5. The wholly aromatic polyester according to claim 3 , containing the structural unit represented by formula (1) in a proportion of 50 mol % claim 3 , the structual unit represented by formula (4) in a proportion of 30-45 mol % claim 3 , and the structual unit represented by formula (7) in a proportion of 5-20 mol %.6. The wholly aromatic polyester according to claim 3 , containing the structural unit represented by formula (1) in a proportion of 50 mol % claim 3 , the structual unit represented by formula (4) in a proportion of 30-45 mol % claim 3 , and the structual units represented by formula (8) in a proportion of 5-20 mol %.7. The wholly aromatic polyester according to claim 3 , containing the structural unit represented by formula (1) in a proportion of 50 mol % claim 3 , the structual unit represented by formula (4) in a proportion of 30-47 mol % claim 3 , and one or two kinds of the structual units represented by formulae (5) and (6) in a total proportion of 3-20 mol %.8. The wholly aromatic polyester according to claim 2 , containing the structural unit represented by formula (1) in a proportion of 30-47 mol % claim 2 , the structual unit represented by formula (4) in a proportion of 50 mol % claim 2 , and one or two kinds of the structual units represented by formulae (2) and (3) in a total proportion of 3-20 mol %.9. The wholly aromatic polyester according to claim 1 , having a melting point of 300° C. or higher.13. The method for manufacturing the wholly aromatic polyester according to claim 10 , whereinthe compounds are used in 80 mol %≤[the compound represented by formula (9)+the compound ...

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20-04-2017 дата публикации

POLYESTER COMPOSITION WITH IMPROVED DYEING PROPERTIES

Номер: US20170107662A1
Автор: JR. Robert Alton, Usher
Принадлежит: Parkdale Incorporated

A copolymer composition is disclosed with advantages for textile fibers, yarns, blended yarns, fabrics, and garments. The composition includes polyester copolymer, between about 4.5 and 5.5 percent adipic acid based on the amount of copolymer, between about 630 and 770 parts per million (ppm) of pentaerythritol based on the amount of copolymer, and between about 3.4 and 4.2 percent polyethylene glycol based on the amount of copolymer. 1. A composition with advantages for textile fibers , and comprising a melt of:polyester precursors selected from the group consisting of terephthalic acid, dimethyl terephthalate, and ethylene glycol;adipic acid in an amount sufficient to give filaments and fibers made from said melt a dye receptively similar to cotton at atmospheric pressure;pentaerythritol in an amount sufficient to give pill resistance to yarns blended of cotton with fibers made from said melt;polyethylene glycol in an amount sufficient to give said melt the elasticity necessary to produce extruded filament from the melt;said melt being maintained at a temperature of between about 285° F. and 295° F., and at an intrinsic viscosity of between about 0.58 and 0.82.2. A polymerized melt according to containing less than 2 percent diethylene glycol (DEG).3. A polymerized melt according to at an intrinsic viscosity of 0.75.4. A polyester copolymer filament made from the melt of .5. A dyed yarn formed of a blend of:cotton fibers; and{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, 'staple fibers cut from a textured filament made from the filament of .'}6. A copolymer composition with advantages for textile fibers; said composition comprising:polyester copolymer;between about 4.5 and 5.5 percent adipic acid based on the amount of copolymer;between about 630 and 770 parts per million (ppm) of pentaerythritol based on the amount of copolymer; andbetween about 3.4 and 4.2 percent polyethylene glycol based on the amount of copolymer.7. A composition according to containing ...

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11-04-2019 дата публикации

ARTICLES COMPRISING ISOSORBIDE AND PROCESSES FOR THEIR MANUFACTURE

Номер: US20190106535A1
Принадлежит: EASTMAN CHEMICAL COMPANY

The invention is generally directed to sports bottles and other articles produced by blow molding from polymeric materials containing isosorbide having glass transition temperatures ranging from 90° C. to 130° C., as well as to processes for producing them. These articles can be exposed to water at high temperatures and can be produced by using a suitable combination of a stretch ratio of less than 3× and a preform temperature at least 20° C. greater than the glass transition temperature (Tg) of the polymeric material. 129.-. (canceled)30. A molded article comprising a polymeric material ,wherein the polymeric material comprises at least one polyester, which comprises i) 70 to 100 mole % of terephthalic acid residues;', 'ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and', 'iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and, '(a) a dicarboxylic acid component comprising i) 20 to 30 mole % of isosorbide residues;', 'ii) 50 to 60 mole % of 1,4-cyclohexanedimethanol residues,', 'iii) 20 to 30 mole % of ethylene glycol residues;, '(b) a glycol component comprisingwherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %;wherein the inherent viscosity of the polyester is from 0.5 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; andwherein the polyester has a Tg in the range from 100° C. to 120° C.31. The article according to claim 30 , wherein the glycol component comprises 20 to 25 mole % of isosorbide residues.32. The article according to claim 30 , wherein the glycol component comprises 55 to 60 mole % of 1 claim 30 ,4-cyclohexanedimethanol residues.33. The article according to claim 30 , wherein the inherent viscosity of the polyester is from 0.55 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/ ...

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18-04-2019 дата публикации

Blend and method for manufacturing the same

Номер: US20190112419A1

A blend is provided, which includes 50 to 99 parts by weight of PET and 1 to 50 parts by weight of modified PEF. The modified PEF is polymerized of diacid, ester of diacid, or a combination thereof and polyol. The diacid, ester of diacid, or a combination thereof includes (1) furan dicarboxylic acid, dialkyl furandicarboxylate, or a combination thereof or (2) furan dicarboxylic acid, dialkyl furandicarboxylate, or a combination thereof and spiro-diacid. The polyol includes (3) C2-C14 polyol or (4) C2-C14 polyol and spiro-diol. The diacid, ester of diacid, or a combination thereof includes (1) furan dicarboxylic acid, dialkyl furandicarboxylate, or a combination thereof, the polyol includes 1 to 3 parts by mole of (4) C2-C14 polyol and spiro-diol, wherein the spiro-diol and the furan dicarboxylic acid, dialkyl furandicarboxylate, or a combination thereof have a weight ratio of 500 ppm to 4000 ppm.

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13-05-2021 дата публикации

Polyester Copolymer

Номер: US20210139645A1
Принадлежит:

A polyester copolymer, having a number average molecular weight of equal to or more than 4000 grams/mole and having a glass transition temperature of less than 160° C., containing: 1. A polyester copolymer , having a number average molecular weight of equal to or more than 4000 grams/mole and having a glass transition temperature of less than 160° C. , comprising:(a) in the range from equal to or more than 45 mole % to equal to or less than 50 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of one or more bicyclic diol monomer units, wherein such one or more bicyclic diol monomer units is/are derived from one or more bicyclic diols chosen from the group consisting of isosorbide, isoidide, isomannide, 2,3:4,5-di-O-methylene-galactitol and 2,4:3,5-di-O-methylene-D-mannitol;(b) in the range from equal to or more than 25 mole % to equal to or less than 49.9 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of an oxalate monomer unit;(c) in the range from equal to or more than 0.1 mole % to equal to or less than 25 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of one or more linear C3-C12 dicarboxylate monomer units; and(d) optionally equal to or more than 0 mole % to equal to or less than 5 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of one or more additional monomer units.2. The polyester copolymer according to claim 1 , comprising:in the range from equal to or more than 45.0 mole % to equal to or less than 50.0 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of the one or more bicyclic diol-derived monomer units; and/orin the range from equal to or more than 25.0 mole % to equal to or less than 49.9 mole % of the oxalate monomer unit, based on the total amount of moles of monomer units within the polyester copolymer; and/orin the range from equal ...

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13-05-2021 дата публикации

INKJET INK AND IMAGE FORMING METHOD

Номер: US20210139726A1
Автор: OJIMA Seishi
Принадлежит:

The composite particles contained in an inkjet ink are particles of a composite of a polyester resin having a sulfur atom-containing polar group and a dye. The polyester resin is non-crystalline. The polyester resin has a first repeating unit derived from a polyvalent carboxylic acid having the sulfur atom-containing polar group, a second repeating unit derived from a polyvalent carboxylic acid having no sulfur atom-containing polar group, and a third repeating unit derived from a polyhydric alcohol. The content percentage of the first repeating unit relative to a total amount of the first repeating unit and the second repeating unit is 1 to 10 mol %. The content percentage of the polyester resin relative to the composite particles is 50% by mass or more and less than 100% by mass. 1. An inkjet ink comprising:an aqueous medium and composite particleswherein:the composite particles are particles of a composite of a polyester resin having a sulfur atom-containing polar group and a dye, andthe polyester resin is a non-crystalline, andthe polyester resin has:a first repeating unit derived from a polyvalent carboxylic acid having the sulfur atom-containing polar group:a second repeating unit derived from a polyvalent carboxylic acid having no sulfur atom-containing polar group; anda third repeating unit derived from a polyhydric alcohol,wherein a content percentage of the first repeating unit relative to a total amount of the first repeating unit and the second repeating unit is 1 mol % or more and 10 mol % or less,wherein a content percentage of the polyester resin relative to the composite particles is 50% by mass or more and less than 100% by mass.2. The inkjet ink according to claim 1 , wherein the dye is a disperse dye or an oil-soluble dye.3. The inkjet ink according to claim 1 , wherein the sulfur-atom-containing polar group is a sulfonic acid group or an alkali metal salt of a sulfonic acid group.4. The inkjet ink according to claim 1 , wherein the first ...

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09-04-2020 дата публикации

POLYESTER RESIN COMPOSITION AND PREPARATION METHOD THEREOF

Номер: US20200109240A1
Принадлежит:

The present invention relates to a polyester resin composition capable of having an excellent shrinkage rate, being heat-shrunk at a low temperature, and improving adhesion properties, without impairing insulation properties in a state of heat-shrinkable films, and a method for preparing the same. The present polyester resin composition comprises: a copolymerized polyester resin including a dicarboxylic acid-derived residue including a residue derived from an aromatic dicarboxylic acid; and a diol-derived residue including a residue derived from 4-(hydroxymethyl)cyclohexyl methyl 4′-(hydroxymethyl)cyclohexane carboxylate, and a residue derived from 4,4-(oxybis(methylene)bis) cyclohexane methanol, an alkali metal compound, and an alkaline earth metal compound, wherein the alkali metal compound and the alkaline earth metal compound are contained in an amount that the content ratio of the alkali metal element/the alkaline earth metal element derived therefrom is 0.01 to 1. 1. (canceled)2. (canceled)3. (canceled)4. (canceled)5. (canceled)6. (canceled)7. (canceled)8. (canceled)9. (canceled)10. (canceled)11. (canceled)12. (canceled)13. A method for preparing a polyester resin composition comprising:reacting a dicarboxylic acid including an aromatic dicarboxylic acidwith the diol including 4-(hydroxymethyl)cyclohexylmethyl 4′-(hydroxymethyl)cyclohexane carboxylate and 4,4-(oxybis(methylene)bis)cyclohexane methanol, thus performing esterification and polycondensation reactions,wherein at least one step of the esterification and polycondensation reaction steps is performed in the presence of an alkali metal compound, and an alkaline earth metal compound,wherein the alkali metal compound and the alkaline earth metal compound are used in an amount that the content ratio of the alkali metal element/the alkaline earth metal element derived from therefrom is 0.01 to 1.14. The method for preparing a polyester resin composition according to wherein the esterification reaction is ...

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04-05-2017 дата публикации

Fiber and method of manufacturing the same

Номер: US20170121859A1

A fiber is provided, which includes a polyester copolymerized of a diacid monomer, an esterified diacid monomer or a combination thereof with a polyol monomer. The diacid monomer, the esterified diacid monomer or a combination thereof includes (1) furan dicarboxylic acid, dialkyl furandicarboxylate, or a combination thereof or (2) furan dicarboxylic acid, dialkyl furandicarboxylate, or a combination thereof and spiro-diacid. The polyol monomer includes (3) C 2 -C 14 polyol or (4) C 2 -C 14 polyol and spiro-diol. The diacid monomer, the esterified diacid monomer or a combination thereof and the polyol monomer meet the following conditions: (a) The diacid monomer, the esterified diacid monomer or a combination thereof includes (2) furan dicarboxylic acid, dialkyl furandicarboxylate, or a combination thereof and spiro-diacid, (b) The polyol monomer includes (4) C 2 -C 14 polyol and spiro-diol, or (c) a combination thereof. The polyester has an inherent viscosity at 30° C. of 0.5 dL/g to 1.5 dL/g.

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16-04-2020 дата публикации

TOUGH SHRINKABLE FILMS

Номер: US20200114614A1
Принадлежит: EASTMAN CHEMICAL COMPANY

The present disclosure relates to a shrink film comprising a polyester composition comprising: 1. A shrink film comprising a polyester composition comprising: [ (i) about 70 to about 100 mole % of terephthalic acid residues;', '(ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and, '(a) a dicarboxylic acid component comprising, (i) about 10 to about 25 mole % neopentyl glycol residues;', '(ii) about 0.01 to about 5 mole % 1,4-cyclohexanedimethanol residues;', '(iii) about 65 mole % or greater of ethylene glycol residues; and', '(iv) about 2 to 7 mole %/o total diethylene glycol residues in the final polyester composition;, '(b) a diol component comprising], '(1) at least one polyester which compriseswherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.2. The shrink film of claim 1 , wherein the inherent viscosity of the polyester is from 0.65 to 0.80 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C.3. The shrink film of claim 1 , wherein the polyester has a Tg of from 70° C. to 80° C. as determined using a TA DSC 2920 from Thermal Analyst Instrument at a scan rate of 20° C./min.4. The shrink film of claim 1 , wherein the sum of one or more diol monomer components capable of forming an amorphous component in the final polyester composition is from 20 to 40 mole % wherein the total diol component is 100 mole %.5. The shrink film of claim 1 , wherein the sum of the residues of 1 claim 1 ,4-cyclohexanedimethanol and neopentyl glycol in the final polyester composition is from 12 to 35 mole % wherein the total diol component is 100 mole %.6. The shrink film of claim 1 , wherein the sum of the residues of 1 claim 1 ,4-cyclohexanedimethanol and neopentyl glycol in the final polyester composition is from 15 to 35 mole % wherein the total diol component is 100 mole %.7 ...

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27-05-2021 дата публикации

SKIN CONTACT COPOLYESTERS

Номер: US20210154049A1
Принадлежит: EASTMAN CHEMICAL COMPANY

This invention pertains to polyester compositions. More particularly, this invention pertains to polyester compositions that have particular utility as component of medical adhesive tapes, topical and transdermal drug delivery patches and cosmetic patches. The polyester is comprised of a diacid selected from the group consisting of a cyclohexane dicarboxylic acid, a dimethylcyclohexane dicarboxylic acid, and combinations thereof and polytetramethylene ether glycol and optionally a branching agent. 1. A patch for adhesion to skin comprising: i. 99 to 100 mole percent, based on the total molar acid content of the polyester, of a diacid selected from the group consisting of a cyclohexane dicarboxylic acid, a dimethylcyclohexane dicarboxylic acid, and combinations thereof;', 'ii. 75 to 92 mole percent of 1,4-cyclohexane dimethanol and 8 to 25 mole percent of polytetramethylene ether glycol based on the total glycol content of the polyester; and', 'iii. optionally up to 1 mole percent of a branching agent selected from the group consisting of glycerin, pentaerythritol, phenyl dianhydride, trimellitic anhydride and combinations thereof based on the total molar acid content of the polyester; and, 'a. polyester backing layer comprised ofb. an adhesive layer.2. The polyester backing layer of wherein said layer has an elastic modulus of from 5 to 50 MPa.3. The polyester backing layer of wherein said layer has a yield strain strength of at least 15%.4. The polyester backing of wherein said layer has a yield strain strength of 15 to 20%.5. A patch for the application of a medication to the skin of a patient comprising: i. 99 to 100 mole percent, based on the total molar acid content of the polyester, of a diacid selected from the group consisting of a cyclohexane dicarboxylic acid, a dimethylcyclohexane dicarboxylic acid, and combinations thereof;', 'ii. 75 to 92 mole percent of 1,4-cyclohexane dimethanol and 8 to 25 mole percent of polytetramethylene ether glycol based on the ...

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25-08-2022 дата публикации

METHOD FOR CRYSTALLIZING A POLYESTER COMPRISING AT LEAST ONE 1,4:3,6-DIANHYDROHEXITOL UNIT

Номер: US20220267514A1
Принадлежит:

The invention relates to the field of polymers and concerns a method for the crystallization of polyester. More particularly, it relates to a crystallization method that comprises a step of providing a polyester comprising at least one 1,4:3,6-dianhydrohexitol unit, and a step of crystallizing said semi-crystalline polyester, said method being characterized in that the crystallization step is performed at a pressure of at least 600 mbar absolute. The method according to the invention makes it possible to strongly limit, or even eliminate, the phenomenon of polyester expansion during crystallization. Advantageously, the elimination of the expansion phenomenon through pressure conditions implemented according to the invention thus makes it possible to dispense with obtaining very fragile empty spheres that break when agitated and thus cause the formation of undesirable fine particles. 1. A method for crystallizing a polyester comprising at least one 1 ,4:3 ,6-dianhydrohexitol unit , and comprising the following steps of:providing a semi-crystalline polyester comprising at least one 1,4:3,6-dianhydrohexitol unit,crystallizing said polyester,said method being characterized in that the crystallization step is performed at a pressure of at least 600 mbar absolute.2. The crystallization method according to claim 1 , wherein the crystallization step is performed at a pressure within the range extending from 600 mbar absolute up to atmospheric pressure.3. The method according to claim 1 , wherein the 1 claim 1 ,4:3 claim 1 ,6-dianhydrohexitol unit is isosorbide.4. The method according to claim 1 , the polyester provided is a semi-crystalline thermoplastic polyester comprising:at least one 1,4:3,6-dianhydrohexitol unit (A),at least one diol unit (B), other than the 1,4:3,6-dianhydrohexitol unit (A),at least one aromatic dicarboxylic acid unit (C).5. The method according to claim 4 , wherein the diol unit (B) of said polyester claim 4 , other than the 1 claim 4 ,4:3 claim 4 ,6 ...

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25-08-2022 дата публикации

FOAM COMPOSITIONS AND USES THEREOF

Номер: US20220267551A1
Автор: Baghdadi Hossein A.
Принадлежит:

A variety of foams and foam components are provided, including foam components for articles of footwear and athletic equipment. The articles include a composition having a foam structure, wherein the composition includes a thermoplastic copolyester elastomer comprising: (a) a plurality of first segments, each first segment derived from a dihydroxy-terminated polydiol; (b) a plurality of second segments, each second segment derived from a diol; and (c) a plurality of third segments, each third segment derived from an aromatic dicarboxylic acid. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including at least one of the foam components. In some aspects, the foams and foam components can be made by extrusion or injection molding to foam the polymeric composition, or extrusion or injection molding to foam the polymeric composition followed by compression molding of the foam. 1. A method of making a midsole component , the method comprising:forming a single phase solution (SPS) comprising a molten polymeric material and a supercritical fluid, wherein the molten polymeric material comprises a thermoplastic elastomer;injecting the SPS into a mold cavity;foaming the molten polymeric material of the SPS in the mold cavity by transitioning the supercritical fluid to a gas, thereby forming a foamed polymeric material;solidifying the foamed polymeric material in the mold cavity, thereby forming a midsole component including a single solidified thermoplastic foam portion, wherein the single solidified thermoplastic foam portion has a closed skin over its entire exterior surface, the closed skin surrounds an interior region, and the interior region has a multicellular foam structure, wherein the single solidified thermoplastic foam portion has a specific gravity of from about 0.08 to about 0.31; andremoving the midsole component from the mold cavity.2. The method of claim 1 , wherein the thermoplastic elastomer is a ...

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16-04-2020 дата публикации

HEAT SHRINKABLE FILM AND METHOD FOR REPRODUCING POLYESTER CONTAINER USING SAME

Номер: US20200115520A1
Принадлежит:

Embodiments relate to a heat shrinkable film and a process for regenerating a polyester container using the same. The heat shrinkable film comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component and has a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds and a melting point of 190° C. or higher as measured by differential scanning calorimetry. It not only solves the environmental problems by improving the recyclability of the polyester container, but also is capable of enhancing the yield and productivity. 1. A container comprising:a polyester container, anda heat shrinkable film, which is provided at the polyester container;wherein the heat shrinkable film is shrunk by steam or hot air to wrap the outer surface of the polyester container,wherein the heat shrinkable film comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component andhas a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds anda melting point of 190° C. or higher as measured by differential scanning calorimetry,wherein when a plurality of flakes are thermally treated at a temperature of 200° C. to 220° C. for 60 minutes to 120 minutes, the clumping fraction is 5% or less,wherein the flakes are formed by crushing the polyester container and the heat shrinkable film.2. The container of claim 1 , wherein the crystallization temperature of the resin is not measured or is 70° C. to 95° C. by differential scanning calorimetry.3. The container of claim 1 , wherein the diol component is at least one selected from the group consisting of ethylene glycol claim 1 , diethylene glycol claim 1 , neopentyl glycol claim 1 , and cyclohexanedimethanol.4. The container of claim 1 , wherein the copolymerized polyester resin comprises neopentyl glycol in an amount of 5 to ...

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27-05-2021 дата публикации

ALIPHATIC COPOLYESTERS COMPOSITIONS WITH IMPROVED IMPACT AND WEATHER RESISTANCE

Номер: US20210155795A1
Автор: Young Robert Erik
Принадлежит: EASTMAN CHEMICAL COMPANY

Disclosed are polymeric compositions that exhibit improved weathering and ultraviolet radiation resistance. The compositions comprise a polymer, at least one ultra-violet light (UV) absorber, at least one primary antioxidant, at least one secondary antioxidant, at least one hindered amine light stabilizer and at least one chain extending agent. In some embodiments the invention comprises a polyester; at least one triazine UV absorber; at least one hindered phenol primary antioxidant; at least one phosphite secondary antioxidant; at least one hindered amine light stabilizer and at least one styrene-acrylate copolymer. 1. An ultraviolet light degradation resistant composition comprising:a. a polymer;b. at least one UV absorber;c. at least one primary antioxidant;d. at least one secondary antioxidant;e. at least one hindered amine light stabilizer; andf. at least one chain extending agent.2. The composition of wherein said polymer is selected from the group consisting of polyesters claim 1 , copolyesters claim 1 , liquid crystalline polyesters/amides/imides claim 1 , polyesteramides claim 1 , polyimides claim 1 , polyetherimides claim 1 , polyurethanes claim 1 , polyureas claim 1 , polybenzimidazole claim 1 , polybenzoxazoles claim 1 , polyimines claim 1 , polycarbonate claim 1 , and polyamides3. The composition of wherein said polymer is selected from the group consisting of polycaprolactone claim 1 , polycaprolactam claim 1 , polyphenylene sulfide claim 1 , polyphenylene oxide claim 1 , poly ether ether ketone claim 1 , poly ether ketone claim 1 , poly ether ketone ketone.4. The composition of wherein said UV absorber B is selected from the group consisting of benzotriazoles claim 1 , benzophenones claim 1 , triazines claim 1 , benzoxazinones claim 1 , oxanilides and benzylidene malonates and combinations thereof.5. The composition of wherein said primary antioxidant is selected from the group consisting of hindered phenols and arylamines.6. The composition of ...

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11-05-2017 дата публикации

POLYESTERS COMPRISING 2,5-FURANDICARBOXYLATE AND SATURATED DIOL UNITS HAVING A HIGH GLASS TRANSITION TEMPERATURE

Номер: US20170129994A1
Принадлежит:

A polyester including at least one furandicarboxylate unit, at least one saturated, linear or branched, diol unit including from 2 to 10 carbon atoms, and at least one bicyclic diol unit, the said bicyclic diol being chosen from: isosorbide, isoidide, isomannide, 2,3:4,5-di-O-methylene-galactitol, and 2,4:3,5-di-O-methylene-D-mannitol. The glass transition temperature of the polyester is greater than or equal to 90° C. Processes for preparing this polyester are also described. 3. The polyester according to claim 2 , wherein the dianhydrohexitol unit is an isosorbide unit.4. The polyester according to claim 1 , the polyester comprises claim 1 , with respect to the sum of the saturated claim 1 , linear or branched claim 1 , diol and bicyclic diol units claim 1 , at least 5 mol % of bicyclic diol units.5. The polyester according to claim 4 , the polyester comprises claim 4 , with respect to the sum of the saturated claim 4 , linear or branched claim 4 , diol and bicyclic diol units claim 4 , at least 10 mol % of bicyclic diol units.6. The polyester according to claim 1 , wherein the furandicarboxylate unit is a 2 claim 1 ,5-furandicarboxylate unit.7. The polyester according to claim 1 , wherein the saturated diol unit is an ethylene glycol unit.8. The polyester according to claim 1 , wherein claim 1 , with respect to the total amount of the units claim 1 , the said polyester comprises:from 40% to 60% of furandicarboxylate units;from 5% to 55% of saturated, linear or branched, diol units; andfrom 5% to 55% of bicyclic diol units.9. The polyester according to claim 1 , wherein the polyester exhibits a weight-average molar mass of greater than 7500 g/mol claim 1 , preferably of greater than 10 000 g/mol.10. The polyester according to claim 1 , wherein the glass transition temperature of the said polyester is greater than or equal to 95° C.11. The polyester according to claim 1 , wherein the polyester exhibits claim 1 , according to the Lab method claim 1 , an index b* of ...

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02-05-2019 дата публикации

SOLVENT AND METHOD FOR PURIFYING CRUDE OF 2,5-FURANDICARBOXYLIC ACID BY CRYSTALLIZATION

Номер: US20190127342A1

Method for purifying a crude of 2,5-furandicarboxylic acid (cFDCA) by crystallization is provided. The method includes (a) mixing the cFDCA and a solvent to form a mixture, wherein the solvent has a dipole moment of 3.7D (Debye) to 4.1D; (b) heating the mixture; (c) after step (b), cooling the mixture to precipitate a solid; and (d1) after step (c), filtering the mixture to collect a wet filter cake of the solid, and drying the wet filter cake to obtain purified FDCA. The purified FDCA has a higher FDCA purity than that of the cFDCA. 15.-. (canceled)6. A method for purifying a crude of 2 ,5-furandicarboxylic acid (cFDCA) by crystallization , comprising:(a) mixing the cFDCA and a solvent to form a mixture, wherein the solvent is dimethyl acetamide, acetonitrile, dimethylformamide, 2-nitropropane, N-methyl-2-pyrrolidone, or a combination thereof;(b) heating the mixture;(c) after step (b), cooling the mixture to precipitate a solid; and(d1) after step (c), filtering the mixture to collect a wet filter cake of the solid, and drying the wet filter cake to obtain purified 2,5-furandicarboxylic acid (FDCA),wherein the purified FDCA has a higher FDCA purity than that of the cFDCA.7. The method as claimed in claim 6 , wherein step (a) of mixing the cFDCA and a solvent to form a mixture comprises stirring claim 6 , supersonic vibration claim 6 , or a combination thereof.8. (canceled)9. The method as claimed in claim 6 , wherein the cFDCA comprises 80 wt % to 99 wt % of FDCA and 0.01 wt % to 10 wt % of 2-formyl-5-furancarboxylic acid (FFCA).10. The method as claimed in claim 6 , wherein the cFDCA comprises 90 wt % to 99 wt % of FDCA and 0.01 wt % to 10 wt % of FFCA.11. The method as claimed in claim 6 , wherein the cFDCA comprises 95 wt % to 99 wt % of FDCA and 0.01 wt % to 5 wt % of FFCA.12. The method as claimed in claim 6 , wherein step (b) heating the mixture to a temperature of 40° C. to 120° C.13. The method as claimed in claim 6 , further recycling a filtrate produced ...

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01-09-2022 дата публикации

COMBINATION MOBILE BUILT-IN AIR FLOW MECHANISM AND LED KILL CHAMBER

Номер: US20220275150A1
Принадлежит:

Disclosed embodiments relate to a combination axial fan and LED lighting system configured to fit into the footprint of a standard ceiling tile. Disclosed embodiments further include ceiling tiles with a built-in fan and/or LED lighting. The disclosed systems may include one or more UV-C light sources which irradiate contaminants as air flows through the UV-C unit. The UV-C unit is mounted on either a universal mounting mechanism or a mobile support unit to provide mobility to the UV-C unit. 1. A mobile air purifying device , comprising:a UV-C unit having at least a vent and a fan portion;an enclosure to the UV-C unit wherein the UV-C unit defines at least an airway between the fan portion and the vent;a fan positioned in the fan portion adapted to guide air to the UV-C airway;{'b': 200', '280, 'a UV light source mounted in the UV-C airway, wherein the UV light source is a UV-C light source emitting light having a wavelength between and nanometers directed into the UV-C airway;'}an air diversion mechanism positioned in the UV-C airway, wherein the air diversion mechanism is configured to direct air guided by the fan to a UV-C kill chamber housing the UV light source;a baffle is positioned in the UV-C kill chamber to act as a barrier preventing light emitted from the UV light source from exiting the air purifying device;the enclosure including a mount to affix the UV-C unit to a frame having a rigid support; anda base affixed to the frame.2. The mobile air purifying device of claim 1 , wherein the UV-C kill chamber accommodates a UV reflective material.3. The mobile air purifying device of claim 1 , wherein the enclosure has an interior surface which includes a UV reflective material.4. The UV-C unit of claim 1 , further comprising a universal mounting mechanism affixed to the base.5. The UV-C unit of claim 4 , wherein the universal mounting mechanism is a clamp.6. The UV-C unit of claim 4 , wherein the universal mounting mechanism is a suction mount.7. The UV-C unit ...

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01-09-2022 дата публикации

SYNTHESIS OF FUNCTIONAL POLYURETHANES AND POLYESTERS FROM BIOMASS-DERIVED MONOMERS

Номер: US20220275151A1
Принадлежит:

A method of making polyesters and polyurethanes from biomass-derived polyols. The polyol is biomass-derived and has the structure: 2. The method of claim 1 , wherein the diisocyanate is selected from the group consisting of methyldiphenyldiisocyanate claim 1 , toluene diisocyanate claim 1 , 1 claim 1 ,6-hexamethylene diisocyanate claim 1 , 1-isocyanato-3-isocyanatomethyl-3 claim 1 ,5 claim 1 ,5-trimethyl-cyclohexane claim 1 , and 4 claim 1 ,4′-diisocyanato dicyclohexylmethane; and the dicarboxylic acid is selected from the group consisting of oxalic claim 1 , malonic claim 1 , succinic claim 1 , glutaric claim 1 , adipic claim 1 , picric claim 1 , phthalic claim 1 , isophthalic claim 1 , terephthalic claim 1 , biphenyl-2 claim 1 ,2′-dicarboxylic claim 1 , and 2 claim 1 ,6-naphthalenedicarboxylic acid acids.3. The method of claim 1 , wherein claim 1 , prior to reacting the first polyol with the diisocyanate or dicarboxylic acid claim 1 , the first polyol is blended with a second polyol that is structurally distinct from the first polyol.4. The method of claim 3 , wherein the second polyol is selected from the group consisting of linear or branched alkylene glycols claim 3 , sugar alcohols claim 3 , polyether polyols claim 3 , polyester polyols claim 3 , polycarbonate polyols claim 3 , polycaprolactone polyols claim 3 , polybutadiene polyol claim 3 , and polysulfide polyols.5. The method of claim 3 , wherein the diisocyanate is selected from the group consisting of methyldiphenyldiisocyanate claim 3 , toluene diisocyanate claim 3 , 1 claim 3 ,6-hexamethylene diisocyanate claim 3 , 1-isocyanato-3-isocyanatomethyl-3 claim 3 ,5 claim 3 ,5-trimethyl-cyclohexane claim 3 , and 4 claim 3 ,4′-diisocyanato dicyclohexylmethane; and the dicarboxylic acid is selected from the group consisting of oxalic claim 3 , malonic claim 3 , succinic claim 3 , glutaric claim 3 , adipic claim 3 , picric claim 3 , phthalic claim 3 , isophthalic claim 3 , terephthalic claim 3 , biphenyl-2 claim ...

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02-05-2019 дата публикации

METHOD FOR PREPARING POLYETHERESTER COPOLYMER

Номер: US20190127521A1
Принадлежит:

The present invention relates to a method for preparing a polyetherester copolymer having excellent economical efficiency by recycling unreacted diol and excellent physical properties. Accordingly, the preparation method may prepare a polyetherester copolymer of high purity having excellent economical efficiency by purifying a byproduct to separate a recycle stream including unreacted diol therefrom, and reusing the recycle stream. 1. A method for preparing a polyetherester copolymer , the method comprising:1) preparing an intermediate reaction product by transesterifying a reaction raw material including dicarboxylate, diol, and polyol in the presence of a reaction catalyst; and2) separating and recovering a reaction product and a byproduct by subjecting the intermediate reaction product to a condensation polymerization reaction, wherein the byproduct is purified to separate a recycle stream including unreacted diol therefrom such that the recycle stream is used as a reaction raw material for the step 1), wherein the byproduct includes diol and an oligomer of polyol, and the oligomer of polyol is removed by the purification.2. The method of claim 1 , wherein the oligomer of polyol is a cyclic oligomer having a degree of polymerization of 3 to 9.3. The method of claim 1 , wherein the purification is performed using a plurality of distillation columns in which a first distillation column and a second distillation column are connected in series.4. The method of claim 1 , wherein the purification is performed using a single distillation column claim 1 , and the recycle stream is discharged from a middle portion in the height direction of the single distillation column.5. The method of claim 1 , wherein the byproduct comprises 10 to 30 wt % of oligomer of polyol.6. The method of claim 1 , wherein the byproduct further comprises a low boiling point compound including water claim 1 , tetrahydrofuran claim 1 , and methanol claim 1 , and the low boiling point compound is ...

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