01-01-2015 дата публикации
Номер: US20150005456A1
Принадлежит:
The present invention pertains to semi-crystalline fluoropolymer [polymer (F)] comprising: —recurring units derived from vinylidene fluoride (VDF); —from 10% to 50% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived from trifluoroethylene (TrFE); and—from 0.01% to 10% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived from at least one monomer comprising an azide group [monomer (Az)], to a process for its manufacture, to a crosslinkable composition comprising the same, to a process for crosslinking the same and to a method for manufacturing one of electrical and electronic devices using the same. 1. A semi-crystalline fluoropolymer (F) comprising:recurring units derived from vinylidene fluoride (VDF);from 10% to 50% by moles with respect to the total moles of recurring units of fluoropolymer (F) of recurring units derived from trifluoroethylene (TrFE); andfrom 0.01% to 10% by moles with respect to the total moles of recurring units of fluoropolymer (F) of recurring units derived from at least one monomer (Az) comprising an azide group.2. The fluoropolymer (F) of claim 1 , wherein monomer (Az) is selected from monomers of formula (I):{'br': None, 'sub': 1', '2', 'p', 'f', '2', 'n', 'q', 's', '3, 'CXX═CX—(O)—R—(CH)[S(O)]N\u2003\u2003(I)'}{'sub': 1', '2', 'f, 'wherein: X, Xand X, equal to or different from each other, are independently H or F, p is 0 or 1, n is 0 to 4, s is 0 or 1, q is 1 or 2, Ris a divalent (hydro)fluorocarbon group, optionally interrupted by one or more ethereal oxygen atoms.'}3. The fluoropolymer (F) of claim 2 , wherein the monomer (Az) is selected from monomers of formula (II):{'br': None, 'sub': 1', '2', 'f', '2', 'n', 'q', 's', '3, 'CXX═CX—O—R—(CH)—[S(O)]N\u2003\u2003formula (II)'}{'sub': i', '2', 'f, 'wherein: X, Xand X, equal to or different from each other, are independently H or F, n is 0 to 4, s is 0 or 1, q is 1 or 2, Ris a divalent ( ...
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