СПОСОБ ЭКСТРУЗИИ ЖИДКОКРИСТАЛЛИЧЕСКОГО РАСТВОРА НА ОСНОВЕ ЦЕЛЛЮЛОЗНЫХ МАТЕРИАЛОВ И ТЯНУТОЕ ИЗДЕЛИЕ

Изобретение относится к целлюлозным материалам, т.е. целлюлозе и производным целлюлозы, к жидкокристаллическим растворам на основе целлюлозных материалов, конкретнее к растворам, пригодным для экструзии и способным давать после коагуляции тянутые изделия, такие как волокна и пленки, а также к самим тянутым изделиям, жидкокристаллический раствор на основе целлюлозных материалов содержит по меньшей мере одну водорастворимую добавку, выбранную из группы веществ, включающих аммиак, амины и соли этих соединений, причем эта добавка должна обеспечивать значение рН коагулирующего агента выше 6. Предпочтительной добавкой является соль, выбранная из группы солей, включающей формиаты, ацетаты и фосфаты аммония, смешанные соли этих соединений или смеси названных компонентов, и, более конкретно, ортофосфат аммония формулы (NH4)2 HPO4. Тянутое изделие в виде целлюлозного волокна имеет эластичность выше 40 сН/текс, исходный модуль растяжения выше 1200 сН/текс и повышенную устойчивость к усталости. Падение ...

БИОЛОГИЧЕСКИ РАЗРУШАЕМАЯ ТЕРМОПЛАСТИЧНАЯ КОМПОЗИЦИЯ НА ОСНОВЕ ДИАЦЕТАТА ЦЕЛЛЮЛОЗЫ

Изобретение относится к биологически разрушаемой термопластической композиции, применяемой в производстве пленок и различных термоформованных изделий в виде потребительской тары. Композиция содержит диацетат целлюлозы, наполнитель, в качестве которого используют костную ткань, в качестве технологических добавок неионогенное поверхностно-активное вещество - синтанол и катионное поверхностно-активное вещество - четвертичные аммониевые соединения. Полученная композиция обладает хорошими реологическими характеристиками и биологически разрушается под действием света, влаги, микрофлоры почвы. 1 з.п.ф-лы, 2 табл.

СМЕШАННЫЙ ЭФИР ЦЕЛЛЮЛОЗЫ, СОДЕРЖАЩИЙ ОДНОВРЕМЕННО СУЛЬФАТНЫЕ И ФОСФАТНЫЕ ГРУППЫ, И СПОСОБ ЕГО ПОЛУЧЕНИЯ

... 1. Способ получения СФЦ, включающий дополнительно предварительное выдерживание целлюлозного материала, полученного из хлопковой, древесной или льняной целлюлозы для набухания в N,N-диметилформамиде, этерификацию целлюлозного материала раствором оксида фосфора, воды, и хлорсульфоновой кислоты в N,N-диметилформамиде, выделение и очистку продукта. ! 2. Способ по п.1, отличающийся тем, что этерификацию проводят при температуре 50-70°С и продолжительности процесса 1-3 ч. ! 3. Способ по п.1, отличающийся тем, что содержанием воды в N,N-диметилформамиде составляет до 3 мас.%. ! 4. Смешанный эфир целлюлозы, содержащий одновременно сульфатные, фосфатные и гидроксильные группы следующей структурной формулы, ! ! где заместитель Х - Н, -SO3 -, -РO(O-)2.

БИОРАЗЛАГАЕМАЯ ЦЕЛЛЮЛОЗОАЦЕТАТНАЯ СТРУКТУРА И ТАБАЧНЫЙ ФИЛЬТР

... 1. Целлюлозоацетатная структура, по меньшей мере, поверхностная область которой содержит биодеградируемую ацетилцеллюлозную композицию, содержащую агент, содействующий биодеградации, включенный в ацетилцеллюлозу и представляющий собой, по меньшей мере, одно соединение, выбранное из группы, состоящей из соли кислородной кислоты фосфора, сложного эфира кислородной кислоты фосфора или его соли, угольной кислоты и ее соли. 2. Структура по п.1, в которой указанная ацетилцеллюлоза имеет значение DS (степени замещения), находящееся в пределах между 2,0 и 2,6. 3. Структура по п.1, в которой указанный агент, содействующий биодеградации, имеет водорастворимость при комнатной температуре 2 г/дм3 или менее. 4. Структура по п.3, в которой указанный агент, содействующий биодеградации, выбран из группы, состоящей из фосфата целлюлозы, фосфата крахмала, вторичного фосфата кальция, третичного фосфата кальция и гидроокиси фосфата кальция. 5. Структура по п.1, в которой указанный агент, содействующий биодеградации ...

Способ стабилизации эфиров целлюлозы

Biologisch abbaubarer Werkstoff und Verfahren zu seiner Herstellung

Aliphatisch-aromatische Copolyester

Fibre-reinforced plastics moulding used in commercial, passenger and rail vehicles and aircraft

The invention relates to a method for producing a source material with a view to manufacturing a fibre-reinforced plastic casting using said source material according to a known forming process. To produce the source material, fibres and solid-state synthetic plastic are separated and placed in a mixing chamber of a die press, the fibres being first cut to the right length (less than 30 mm), preferably less than 20 mm and ideally less than 10 mm, and the plastic is introduced in a granular form into the mixing chamber, where both the plastic and the fibres are duly mixed to a solid plastic mixture and carried to the opening-fitted die of the die press. In the area upstream of or inside said openings, the solid plastic mixture is warmed up. During or after the warm-up process, the fibres are embedded, at least partly, in the plastic material, and/or sunk therein, at least partly. Finally, the material carried across the die is crushed and used as a granular source material in the subsequent ...

UV absorbierender Film und Verwendung als Schutzfolie

Modifizierte Cellulosefasern, Verfahren zu deren Herstellung, deren Verwendung, Filterhilfsmittel oder Filterplatten und Verfahren zur künstlichen Klärung von trüben Flüssigkeiten

Verfahren zur Herstellung von modifizierten Cellulosefasern für die künstliche Klärung von trübungsaktiven Substanzen aus Flüssigkeiten mit folgenden Schritten: • Einwiegen einer Fasermischung bestehend aus 80–99,9 Gew.% Cellulosefasern, 0,1–10 Gew.% Croscarmellose-Natrium und 0–10 Gew.% eines oder mehrerer Additive; • Quellen und Aufbereiten der Fasermischung im neutral bis alkalischen Milieu; • Kochen der Fasermischung; • Waschen; • Isolieren der modifizierten Fasern.

Blends enthaltende Cellulosederivate und ausgewählte Polymere

The invention relates to blends containing cellulose esters and/or cellulose ethers and selected polymers which are also biologically degradable and, optionally, plasticizers.

THERMOPLASTIC RESIN COMPOSITIONS

... 1,217,057. Thermoplastic polymer compositions. MONSANTO CO. 12 Dec., 1968 [13 Dec., 1967], No. 59214/68. Headings C3F, C3G, C3P and C3R. Thermoplastic polymers contain as a processing aid an alkenyl succinic mono- or di-ester in which the alkenyl radical has a molecular weight of 400-3000 and is derived from a polymer of a C 3 -C 30 olefin. In examples, such aids are added to PVC, graft copolymer of vinyl chloride on chlorinated polyethylene, vinyl chloride/vinyl acetate copolymer, polymethyl methacrylate, polystyrene, ABS terpolymer, polyethylene, butadiene/styrene copolymer, polyvinyl acetate, polypropylene, ethylene/vinyl chloride copolymer, styrene/methyl methacrylate copolymer, styrene/acrylonitrile copolymer, methyl methacrylate copolymer with methacrylic acid or glycidyl methacrylate, methyl methacrylate/ acrylonitrile/acrylic acid copolymer, styrene/ acrylonitrile/acrylic acid copolymer, vinyl chloride/acrylonitrile/acrylic acid copolymer, poly - ( - methylstyrene), poly - 4 - methylpentene ...

Process for working up molten cellulose derivatives into threads and other shaped articles

A cellulose derivative having a content of water between that which it would normally have after being exposed to the open air and that of the saturation point observed on melting is brought into the molten state and worked up into threads or other shaped structures. On exposure to the open air, cellulose triacetate takes up 0.1-0.3 per cent of water; a partially hydrolysed cellulose acetate may take up about 1.5 per cent. The saturation point observed on melting is that content of water above which evaporation of the water with foaming occurs when the cellulose derivative is melted. The presence of water in the cellulose derivative considerably reduces the melting-point and thus the temperature of the working-up process. The upper limit of the moisture content is usually not more than 10 per cent. For cellulose triacetate it is about 6 per cent and for a hydrolysed cellulose acetate it may be 8-9 per cent. The cellulose derivative may be dried to the desired moisture content during the ...

Modified polymeric films

Stabilisation of plastic compositions based on cellulose esters

Plastic compositions comprising a major proportion of cellulose organic acid esters are stabilized against the effects of heat, light, or weather, and rendered odourless by the addition of one or more carbodiimides. In general, aliphatic, cycloaliphatic or aromatic monocarbodiimides may be used, those of the formula: being preferred, where R represents like or different alkyl, alkoxy, or aryl radicals, especially phenyl and aralkyl and particularly phenalkyl radicals, R1 represents R or alternatively halogen or nitro-radicals, X is any desired inert radical and n is an integer from 0 to 3. Alkyl-substituted derivatives of diphenylcarbodiimide are preferred. Monocarbodiimides specified include N, N1-diisopropylcarbodiimide, N,N1-dibutylcarbodiimide, N, N1-diallylcarbodiimide, N, N1-dioctylcarbodiimide, N, N1-dicyclopentylcarbodiimide, N, N1-dicyclohexylcarbodiimide, N, N1-dicycloheptylcarbodiimide, N, N1-dicyclooctylcarbodiimide, N, N1-dibornylcarbodiimide, diphenylcarbodiimide ...

Adhesive composition

A composition which forms an adhesive on mixing with water comprises a polyvinyl ester, a cellulose derivative, a cement and marble powder. The preferred composition comprises 0.1-2% methyl hydroxyethylcellulose, 2-20% polyvinyl acetate, 15-50% white Portland cement and 30-80% marble powder, by weight. 3 parts by weight of the above composition in powder form may be mixed with 1 to 1 1/4 parts of water to form an adhesive for ceramic or glass surfaces.

Polymer compositions comprising polymerized episulphides and a process for the preparation of reaction products of polymerized episulphides

... 1,148,652. Laminates. DUNLOP CO. Ltd. 27 June, 1966 [20 July, 1965], No. 30729/65. Heading B5N. [Also in Divisions B2 and C3] A polymer composition comprising a mixture of (a) a polymer of one or more episulphides having at least two reactive terminal groups and (b) a potentially thermosetting organic aminoplast may be used as an adhesive whereby the composition is applied between the surfaces to be adhered together, e.g. both of the surfaces may be coated and the coated surfaces pressed into contact. The composition is then dried and preferably heated to 160‹ C. Materials which may be adhered together include metal, wood, textiles and paper.

Coating Processes

... 1,178,621. Laminates. EASTMAN KODAK CO. 9 March, 1967 [14 March, 1966], No. 11062/67. Heading B5N. A substrate having movement relative to an extrusion orifice is coated with a thermoplastic composition comprising 70-90% by wt. cellulose acetate butyrate and 10-30% by wt. of one or more of the plasticizers triethyl citrate, diisodecyl adipate and di-(2-ethylhexyl) adipate or phthalate by heating the composition to at least 250‹ C. at a pressure of at least 50 p.s.i., and extruding it as a falling curtain on to the substrate from a long narrow orifice, the coated substrate being cooled and recovered. The substrate may be air permeable, e.g. paperboard, and may support an article of manufacture, which becomes bound to the substrate as a package by the falling curtain. The viscosity of the melt may be 20,000-175,000 cPs.

Stabilised cellulose ester compositions

... 1,063,637. Cellulose ester spinning solutions. EASTMAN KODAK CO. March 25, 1964 [March 29, 1963], No. 12569/64. Heading B5B. A composition comprises a cellulose ester and a metal salt of a mono- or di-alkyl ester of phosphoric acid (excluding zinc monoethyl phosphate) or phosphorous acid, a metal salt of a mono-aryl ester of phosphoric acid or phosphorous acid, a metal salt of an alkyl or aryl phosphorous acid (= an alkyl or aryl phosphonate), a metal salt of an alkyl ester of an alkyl phosphorous acid or an aryl phosphorous acid, a metal salt of an aryl ester of an alkyl phosphorous acid or an aryl phosphorous acid, or a metal dialkyl phosphite, the proportion of metal salt in the composition being 0À1% to 5% by weight and such that the composition is more resistant to ultra-violet radiation than the cellulose ester. The composition is used to form spinning solutions for the manufacture of yarns, filaments, fabrics and films. The cellulose ester may be e.g. cellulose acetate, propionate ...

Improvements in or relating to flameproofing compositions

A flameproofing composition comprises a chlorinated organic material containing at least 50 per cent by weight of chlorine and an antimony, arsenic or bismuth derivative of an organic material, the metal or metalloid being bound through an oxygen linkage to the organic component of the derivative. The composition may be incorporated into synthetic rubber or synthetic resins, e.g. unsaturated polyester resins, polyvinyl chloride polystyrene, cellulose acetate butyrate or propionate, cellulose acetate, cellulose ether resins, ethyl cellulose, polymethyl, ethyl, isopropyl and butyl methacrylates, polyethylene and cellulosic and synthetic fibre fabrics. The chlorinated organic material preferably comprises more than eight carbon atoms, e.g. derivatives of paraffin and other oils and waxes, fats, higher fatty acids, and higher fatty esters. The antimony, arsenic or bismuth derivative may be that of a carboxylic acid such as glycollic, lactic, salicylic, citric, malic, tartronic, mucic, tartaric ...

PROCEDURE FOR THE PRODUCTION POLYMERS OF A MIXTURE

POLYMILCHSÄURE HARZZUSAMMENSETZUNG, MANUFACTURING PROCESSES FOR IT, BIAXIAL OF EXTENSIONS POLYMILCHSÄUREFILM AND FROM IT FORMED ARTICLES

CELLULOSEACYLAT AND SOLUTION OF IT

THERMOPLASTIC MOLDING MATERIALS FROM CELLULOSE ESTERS AND ATHYLEN VINYLESTER COPOLYMERS

MIXTURES OF ALIPHATIC-AROMATIC COPOLYESTERN WITH CELLULOSE ESTER POLYMERS

PROCEDURE FOR THE PRODUCTION OF AN WATER-INSOLUBLE POLYMER POWDER, IN OF A LIQUID PHASE REDISPERGIERT CAN AND PROCEDURES FOR THE PRODUCTION OF A DISPERSION OF THE POLYMER POWDER.

BIOLOGICALLY DEGRADABLE ONE PLASTIC MATERIALS.

PLASTIFIZIERTES CELLULOSEACETAT, PROCEDURE FOR ITS PRODUCTION AND ITS USE FOR THE PRODUCTION OF FILAMENTS

PLASTIC MATERIAL FROM ONE POLYMER-DAZZLE

CELLULOSE ESTER COMPOSITIONS

BIODEGRADABLE COMPOSITIONS OF STRENGTH AND POLYSACCHARIDE ESTERS

Biopolymer compositions and products thereof

Methods and systems employing an inclined digestion unit for hydrothermal digestion of cellulosic biomass solids

Maintaining long residence times during hydrothermal digestion of cellulosic biomass solids may be complicated by a number of factors, including biomass compaction. Advantages in this regard may be realized by digesting cellulosic biomass solids in an inclined digestion unit. Such methods can comprise: introducing cellulosic biomass solids to a hydrothermal digestion unit comprising one or more inclined surfaces therein; introducing a fluid phase digestion medium containing a slurry catalyst to the hydrothermal digestion unit, the slurry catalyst being capable of activating molecular hydrogen; supplying an upwardly directed flow of molecular hydrogen from a source disposed along each inclined surface as the cellulosic biomass solids descend along each inclined surface; and heating the cellulosic biomass solids as they descend along each inclined surface in the presence of the slurry catalyst and the molecular hydrogen, thereby forming an alcoholic component derived from the cellulosic biomass ...

pH-modified polymer compositions with enhanced biodegradability

Sealing material which swells when treated with water

PROCESS FOR PREPARING A POWDER OF WATER-INSOLUBLE POLYMER WHICH CAN BE REDISPERSED IN A LIQUID PHASE, THE RESULTING POWDER AND UTILIZATION THEREOF

Coagulating agent for liquid crystal solutions with base of cellulose substances

HYDROPHILIC SUBSTRATE FOR SORBING HEAVY METALS

HYDROPHILIC SUBSTRATE FOR SORBING HEAVY METALS Method for making a water insoluble hydrophilic polymeric substrate having incorporated therein a dispersion of a finely precipitated metal sulfide for sorbing by ion exchange heavy metals from aqueous solutions such as photographic solutions, seawater, mine tailings, electroplating baths and the like, the substrate being formed from such polymers as cellulose esters, cellulose ethers, starches cross-linked to render them water insoluble, natural polymers, or regenerated cellulose; and the product of the method.

THERMOSETTING RESIN COMPOSITIONS WITH LOW SHRINKAGE ON THE BASE OFTURATED POLYESTER RESINS SUITABLE FOR THE PRODUCTION OF MOULDING OSITIONS CAPABLE OF FREELY FLOWING

THERMOPLASTIC MOULDING COMPOSITIONS CONSISTING OF ORGANIC CELLULOSE RS AND COPOLYMERS OF OLEFINICALLY UNSATURATED NITRILES AND UGATED DIOLEFINS

COATING OF HYDROXYLATED SURFACES BY GAS PHASE GRAFTING

A method of coating hydroxylated surfaces by gas phase grafting is described. Especially acyl groups, silyl groups and/or alkyl groups are located on the surface of materials by gas phase grafting. The grafting method is a dry process. The materi-al to coat can be organic or inorganic materials. The produced surface coated material are strong and durable and material normal-ly not water-proof can be water-proof due to the surface treating. Examples of items produced from surface treated material may be water-proof cardboard boxes, other containers, furniture, interior for cars and boats. Items produced from organic materials such as from plant parts are biodegradable.

CELLULOSE ESTERS IN PNEUMATIC TIRES

A tire component is provided comprising an elastomeric composition containing at least one non-fibril cellulose ester, at least one non-nitrile primary elastomer, optionally a starch, and at least 70 parts per hundred rubber (phr) of one or more fillers, wherein the weight ratio of the cellulose ester to the starch is at least 3:1, and wherein the cellulose ester is in the form of particles having an average diameter of not more than 10 µm.

CELLULOSE ESTER SHAPED ARTICLES FROM SOLUTIONS CAPABLE OF INCREASED PRODUCTION SPEED

... 2125992 9313250 PCTABS00024 An improved extrudable solution such as a cellulose acetate/acetone spinning solution is provided containing cellulose ester, solvent, metal oxide precursor, acid, and water. The solution is extruded such as by spinning and produces a shaped article such as a cellulose acetate fiber containing metal oxide interpenetrating networks.

CELLULOSE ESTER RESIN STABILIZER AND CELLULOSE ESTER RESIN COMPOSITIONS STABILIZED THEREWITH

CELLULOSE ESTER RESIN STABILIZER AND CELLULOSE ESTER RESIN COMPOSITIONS STABILIZED THEREWITH Surinder Ahluwalia Michael Fisch Davie Peveler Nonylphenyl neopentylene phosphite or stated in terms of systematic nomenclature 5,5-dimethyl-2-nonylphenoxy-1,3,2-dioxaphosphorinane, compositions effective to stabilize cellulose ester resins against the degradative effects of heat and processing are disclosed. In accordance with the present invention, preferred stabilizing compositions for cellulose ester resins include nonylphenyl neopentylene phosphite in combination with epoxidized linseed oil. These stabilizing compositions demonstrate their stabilizing effectiveness by maintaining the melt viscosity of he polymer during hot working and minimizing discoloration of the polymer when heated.

Verfahren zum Gelatinieren von Zelluloseestern.

Verfahren zum Gelatinieren von Zelluloseestern.

Verfahren zur Herstellung von Formlingen aus Cellulosederivaten.

Verfahren zur Herstellung wasserdichter Erzeugnisse, insbesondere Folien und Hohlkörper, aus Celluloseestern und -äthern.

Kunststoff aus Zellulose-Fettsäure-Triestern.

Verfahren zur Verarbeitung von Zellulosederivaten aus dem Schmelzfluss.

Verfahren zur Herstellung mattierter Formgebilde aus Celluloseestern.

Emballage alimentaire et procédé de fabrication de cet emballage

Formbare thermoplastische Mischung

Verwendung von Carbodiimiden als Stabilisierungsmittel für Kunststoffe auf Basis von Celluloseestern

Verfahren zur Herstellung von geschäumten thermoplastischen Materialien

Composition de revêtement

Casting a cellulose acetate membrane for reverse

Semipermeable membranes are produced by (a) casting a soln. consisting of (I) a cellulose ester, (II) ZnCl2, (III) an org. solvent for the cellulose ester, and (Iv) a solvent for the ZnCl2, which is miscible with (III), the soln. have such as degree of acidity that hydrolysis of the ZnCl2 and saponification of the ester are prevented, (b) evaporating at least a part of the org. solvent to form a membrane, (c) immersing the membrane in (V) a solvent for ZnCl2, which is miscible with solvent III, and (d) heating the membrane in a (VI) a liquid in which (I) is insoluble. The semipermeable membrane is employed for reverse osmosis processes. Typical uses include the desalting of drinking water, purification of sewage.

Dyeing cellulose esters - in bulk, using dyes derived from 2,6-dihydr cyano-4-methyl pyridine

Cellulose esters are bulk dyed by dyes of formula: (where D is the residue of a diazo component contg. a sulphonamide gp) without the addition of a dispersant to the compsn. The cellulose ester is esp. the 2 1/2- or triacetate. Strong, clear colours, fast to light, washing and dry cleaning, are obtd. The colours do not migrate to the surface.

Verfahren zur Herstellung von photopolymerisierbaren Massen

Resin composition based on unsaturated polyester resins which can be cured with low shrinkage

Thermoplastic moulding materials based on cellulose esters and ethylene-vinyl ester copolymers

PROCEDURE FOR THE PRODUCTION OF AN UP TO HIGH TEMPERATURES STABLE ONES AND HOMOGENEOUS ONE POLYMER ALLOY AS WELL AS USE THE SAME.

ПОЛИМЕРНЫЙ МАТЕРИАЛ НА ОСНОВЕ ЦЕЛЛЮЛОЗЫ

Изобретение относится к полимерному материалу с некоторыми полезными свойствами. Полимерный материал имеет низкую степень набухания в воде, является биоразлагаемым, имеет исключительно низкую проницаемость для газов, таких как CO2, и имеет высокую прочность. Полимерный материал может быть использован для ряда целей, таких как получение емкостей для пищевых продуктов или напитков. Полимерный материал получают из предполимеризационной смеси, содержащей привитой материал, полученный из растения, и мономеры и/или сшивающие агенты.

ПОЛИМЕРНЫЙ МАТЕРИАЛ НА ОСНОВЕ ЦЕЛЛЮЛОЗЫ

Изобретение относится к полимерному материалу с некоторыми полезными свойствами. Полимерный материал имеет низкую степень набухания в воде, является биоразлагаемым, имеет исключительно низкую проницаемость для газов, таких как CO2, и имеет высокую прочность. Полимерный материал может быть использован для ряда целей, таких как получение емкостей для пищевых продуктов или напитков. Полимерный материал получают из предполимеризационной смеси, содержащей привитой материал, полученный из растения, и мономеры и/или сшивающие агенты.

БИОПОЛИМЕРНЫЕ КОМПОЗИЦИИ И ПРОДУКТЫ НА ИХ ОСНОВЕ

Изобретение относится к композициям на основе биополимеров и содержащим биополимер сформованным телом, таким как пленки, капсулы, пластинки, оболочки или покровные пленки или изготовленные из них спреи. В соответствии с другим вариантом осуществления, изобретение относится к способу получения исходного материала на основе биополимеров и сформованных тел, содержащих биополимер, как например, упомянутые выше, для производства фармацевтических, ветеринарных, пищевых и косметических продуктов.

НАНЕСЕНИЕ ПОКРЫТИЙ НА ГИДРОКСИЛИРОВАННЫЕ ПОВЕРХНОСТИ ГАЗОФАЗНОЙ ПРИВИВКОЙ

Рассмотрен способ нанесения покрытий на гидроксилированные поверхности газофазной прививкой. В частности, ацильные группы, силильные группы и/или алкильные группы возникают на поверхности материала в результате газофазной прививки. Метод прививки является сухим процессом. Подлежащий покрытию материал может быть органическим или неорганическим. Образующийся материал с поверхностным покрытием является прочным и долговечным, и материал, обычно не водоотталкивающий, может стать водоотталкивающим вследствие поверхностной обработки. Примерами изделий, полученных из материала с обработанной поверхностью, могут быть водоотталкивающие картонные ящики, другие контейнеры, мебель, детали интерьера автомобилей и яхт. Изделия, полученные из органических материалов, таких как растительные части, являются биоразрушаемыми.

МАТЕРИАЛ ДЕКОРАТИВНОГО ОБЛИЦОВОЧНОГО ПОКРЫТИЯ

Материал декоративного облицовочного покрытия содержит карбоксиметилцеллюлозу, целлюлозу, полиэфирную предориентированную нить, латекс.

МАТЕРИАЛ ДЕКОРАТИВНОГО ОБЛИЦОВОЧНОГО ПОКРЫТИЯ

Материал декоративного облицовочного покрытия содержит карбоксиметилцеллюлозу, полиэфирные полностью ориентированные гладковытянутые нити, латекс.

Method for producing cellulose ester film, cellulose ester film, polarizing plate and liquid crystal display

Disclosed is a method for producing a cellulose ester film wherein a film-forming material containing the following components A-C is heated and melted, and a cellulose ester film is formed therefrom by melt-casting. A: a cellulose resin B: an ester compound obtained by condensing an organic acid represented by the general formula (1) below and a polyhydric alcohol C: an aliphatic polyester or an aliphatic-aromatic copolyester General formula (1).

Cellulose ester membrane

Manufacturing method of cellulose acylate film

Manufactoring process of products moulded by means of derived from cellulose of higher fatty-acids

Fireproof composition

TRANSPARENT PLASTIC SHEET FOR MAKING WELDERS' PROTECTIVE SCREENS OR GOGGLES

New compositions stabilized containing cellulose esters

Films, films, sheets and similar products improved and proceeded to manufacture them

A method for treating cellulose derivatives

Composition, capable for extruded materials, based on cellulose formate

Composition, susceptible de donner des fibres ou des films, à base de formiate de cellulose, comportant comme solvant un ou plusieurs composés choisis dans le groupe constitué par les alkylsulfoxydes, les lactames N-substitués, les amides acycliques, les dérivés cycliques de l'urée. Procédés pour obtenir ces fibres et ces films. Fibre en cellulose régénérée dont le degré de substitution en groupes formiate est inférieur à 2 %, cette fibre étant pratiquement dépourvue de fibrillation. Cette fibre peut être utilisée pour renforcer des enveloppes de pneumatiques.

PROCESS FOR PREPARING CELLULOSE ESTER REVERSE OSMOSIS MEMBRANES ON FLEXIBLE WEBS HAVING ENHANCED RELEASABILITY

Semipermeable membranes made by dissolving amine salt

COMPOSE FOR THERMOPLASTIC MOULDING CONTAINING VINYL COPOLYMER ETHYLENE/ESTER AND CELLULOSE ESTERS

PHASE DIFFERENCE FILM, METHOD FOR PRODUCING SAME, POLARIZING PLATE, AND LIQUID CRYSTAL DISPLAY DEVICE

셀룰로오스에스테르와 그의 성형체

... 일반식 (I)의 구조식 중, X가 아실기일 때의 치환도가 2.91 내지 3.0이고, 아실기가, 치환기를 갖고 있어도 되는 벤조일기 (A)와, 상기 벤조일기 (A)와는 상이한 치환기를 갖고 있어도 되는 벤조일기 (B)를 포함하는 것이고, 치환도가 3.0일 때, 상기 벤조일기 (A)의 치환도가 1.5 내지 2.9, 상기 벤조일기 (B)의 치환도가 0.1 내지 1.5인 셀룰로오스에스테르. (일반식 (I) 중, X의 전부 또는 일부가 아실기, X의 일부가 아실기일 때, 잔부가 수소 원자, 알킬기에서 선택되는 기를 나타내고, n은 20 내지 20,000의 정수를 나타낸다.) ...

OPTICAL FILM FOR LIQUID CRYSTAL PHASE DIFFERENCE FILM

The present invention relates to an optical film for a liquid crystal phase difference film. More specifically, the present invention relates to an optical film for a liquid crystal phase difference film with excellent optical reliability by comprising a resin and an additive which can improve reliability under high temperature and humidity conditions. COPYRIGHT KIPO 2017 (AA) nz (Thickness direction) (BB) ny (MD direction) (CC) nx (TD direction) (DD) d (Film thickness) ...

셀룰로오스에스테르 필름 및 셀룰로오스에스테르 필름의 제조 방법

... 본 발명의 과제는, 환경의 습도 변동에 대하여 위상차 변동이 일어나기 어려운 내습성이 우수한 셀룰로오스에스테르 필름을 제공하는 것이다. 또한, 그 제조 방법을 제공하는 것이다. 본 발명의 셀룰로오스에스테르 필름은, 연신된 셀룰로오스에스테르 필름이며, 연신 후의 헤이즈값이, 연신 전으로부터 0.1 내지 0.9배의 범위 내로 조정된 것을 특징으로 한다.

OPTICAL FILM

CELLULOSE ESTER FILM, AND LIQUID CRYSTAL DISPLAY COMPRISING SAME

The present invention relates to a cellulose ester film and a liquid crystal display comprising the same and, more specifically, to a cellulose ester film comprising a compound represented by chemical formula 1. The cellulose ester film of the present invention has improved durability, moisture permeability, and optical reliability. In the chemical formula 1, the E is an aryl monocarboxylic acid residue having 12 to 18 carbon numbers or a hydroxyl group, the D is an alkylene glycol residue having 2 to 12 carbon numbers, the A is an aryl dicarboxylic acid residue having 6 to 12 carbon numbers, and the n is an integer of one or more. COPYRIGHT KIPO 2016 ...

COMPOSITION FOR A RETARDATION FILM, CAPABLE OF PROVIDING HIGH RETARDATION VALUE, EXCELLENT MECHANICAL PROPERTIES, AND HIGH TRANSMITTANCY, THE RETARDATION FILM, AND A MANUFACTURING METHOD THEREOF

PURPOSE: A composition for a retardation film is provided to have high retardation value to a plane direction, and to improve aligning property due to elongation property of an ester-based film. CONSTITUTION: A composition for a retardation film comprises a cellulose ester compound and a cholesteric polymer liquid crystal compound. The included amount of the cholesteric polymer liquid crystal compound is 5-25 parts by weight based on 100.0 parts by weight of cellulose ester compound. A manufacturing method of the retardation film comprises: a step of mixing the cellulose ester compound and cholesteric polymer liquid crystal compound to manufacture the composition for a retardation film; a step of molding the composition by a solution softening method; and a step of elongating the film. COPYRIGHT KIPO 2013 [Reference numerals] (AA) Step of manufacturing a composition for a retardation film; (BB) Step of shaping a film; (CC) Step of elongating; ...

CELLULOSE ACYLATE COMPOSITION, CELLULOSE ACYLATE FILM CONTAINING THE COMPOSITION, POLARIZER HAVING THE FILM, AND IMAGE DISPLAY DEVICE HAVING THE POLARIZER

PURPOSE: Provided are a cellulose acylate composition which is reduced in the retardation in thickness direction and its chromatic dispersion and the pollution during manufacturing process, a cellulose acylate film containing the composition, a polarizer having the film, and an image display device having the polarizer. CONSTITUTION: The cellulose acylate composition comprises cellulose acylate whose degree of substitution into an acyl group satisfies the three relations represented by 2.3<=SA+SB<=3.0, 1.5<=SA<=3.0 and 0<=SB<=0.8 (wherein SA and SB represents the degree of substitution of the acyl group of cellulose substituted with a hydroxyl group, SA represents the degree of substitution of an acetyl group, and SB represents the degree of substitution of an acyl group of C3-C22); and a compound represented by the formula I (wherein Q1 and Q2 are independently an aromatic ring; and X is NR (wherein R is H or a substituent), O or S). © KIPO 2006 ...

SPIRO ([...]) PHOTOCHROMIC BENZOXAZINE AND ARTICLES CONTAINING THE SAME

Agente coagulante aquoso para solu-Æo de cristal l¡quido - base de materiais celulÄsicos processo de fia-Æo artigo fiado fibra celulÄsica e artigo de borrach(s) ou de material(ais) pl stico(s)

Cellulose acylate film and method for manufacturing the same

According to the present invention, a film is formed from a powdered cellulose acylate resin using a twin-screw extruder which has complete-mating-type screws and whose L/D is set in the range of 20 to 55, while setting the temperature of the resin in the extruder in the range of Tm + 10 DEG C to Tm + 70 DEG C, keeping the average residence time of the cellulose acylate resin within 5 minutes, and drawing a vacuum so that the degree of vacuum in extruder after the powdered cellulose acylate resin has been melted is kept at 100 Torr or lower, whereby the color change or deterioration in mechanical strength of the resin can be decreased, and thus, a high-quality and high-functionality film which is good for the optical application can be provided.

Water cleanable thick film paste composition

A thick film paste composition comprizing: finely divided inorganic particles dispersed in an organic vehicle comprizing: (a) organic solvent; and (b) solid organic polymer; with the proviso that: (I) the polymer is dissolved in the organic vehicle and is 1-5% wt. Of the total paste composition; and (ii) the organic solvent having an evaporation rate at least 2 times slower than water at 30oC and 1 atm; and (iii) the total paste composition is water cleanable.

PHOSPHORUS-CONTAINING CELLULOSE ESTERS, METHODS FOR THEIR PREPARATION, THEIR USE, AND FLAME RETARDANTS

The invention relates to cellulose esters, the ester groups of which are at least partially containing phosphorus and are based on unsaturated carboxylic acids and reactive phosphorus components, wherein the latter are preferably phosphorus derivatives of sugar alcohols or of tartaric acid derivatives. The invention also relates to methods for preparing novel phosphorus-containing cellulose esters and to their use as flame retardants for plastics.

PROCESS FOR PRODUCING CELLULOSE ACYLATE FILM, CELLULOSE ACYLATE FILM, POLARIZER, AND LIQUID-CRYSTAL DISPLAY

A process for cellulose acylate film production which is sufficiently effective in reducing viscosity and in reducing moisture permeability. The cellulose acylate film does not suffer bleeding, i.e., the phenomenon in which a component separates out or volatilizes from the cellulose acylate film, has high flatness, is inhibited from having streak unevenness, and has high evenness. Even through long-term storage, the film does not suffer film deformation failures such as ridge failures or protrusion failures. This process for cellulose acylate film production comprises forming a cellulose acylate film by the melt casting method, and is characterized in that the cellulose acylate film contains at least one compound represented by the following general formula (1) and that the cellulose acylate film extruded from a casting die in the film formation by melt casting is pressed between a touch roll having an elastically deformable surface and a cooling roll to produce the target film.

PHASE DIFFERENCE FILM, POLARIZING PLATE USING SAME, AND LIQUID CRYSTAL DISPLAY DEVICE

... [Problem] An object of the present invention is to provide a phase difference film that uses a low-substituted cellulose ester and that has improved moist heat stability of post-saponification retardation and internal haze; a polarizing plate that uses the same; and a liquid crystal display device. [Solution] An optical film containing a cellulose ester and the compound represented by general formula (1) is characterized in that the average degree of substitution of the compound is within a range of 3.0 to 6.0, and in comprising 30 to 80 mass% of a component having a degree of substitution of 4 or less. (In the formula, R1 to R8 are substituted or unsubstituted alkylcarbonyl groups or substituted or unsubstituted arylcarbonyl groups; R1 to R8 may be the same or different.) ...

Light scattering sheet and method for producing the same

A light scattering sheet includes: a transparent support; and a light scattering layer on the transparent support, the light scattering layer having a phase-separated convexo-concave structure formed by spinodal decomposition of a solution containing two or more resin materials capable of phase-separation from each other are dissolved in a solvent. In the light scattering layer, the phase-separated convexo-concave structure is formed into a sea-island structure of two or more resin materials including a styrene-acrylonitrile copolymer, and a plurality of domains constituting the islands have random shapes mainly having a string shape, and a transmitted image definition measured according to JTS K 7374 using an optical comb having a width of 2.0 mm is 10% or more and less than 25%.

Optical film, retardation film, polarizing plate, and liquid crystal display device

An optical film contains a cellulose ester and more than 30% by mass, relative to the cellulose ester, of a condensation product of at least one polyhydric alcohol having an average of 2.01 or more carbon atoms and at least one polybasic acid having an average of 4.10 or more carbon atoms, and at least one of the at least one polyhydric alcohol contains at least three carbon atoms bonded together without being interrupted by any other atom.

Filled Fluororesin Sheet, Process for Producing the Same, and Gasket

Provided is a filled fluororesin sheet excellent in stress relaxation properties, in particular stress relaxation properties at a high temperature. The filled fluororesin sheet includes a fluororesin and an inorganic filler having a revised Mohs hardness of not less than 8, in a fluororesin:inorganic filler volume ratio of 30-55:70-45 (wherein the total of the two is 100).

Polymer composition, method for producing non-stretched film, non-stretched film, heat seal material, and packing material

Provided is a polymer composition that contains an ionomer which includes an ethylene-α,β-unsaturated carboxylic acid copolymer and a ternary polymer of ethylene-α,β-unsaturated carboxylic acid-α,β-unsaturated carboxylic acid ester, and a propylene-based polymer, wherein a melt flow rate (MFR) value (under a load of 2160 g) of the ionomer at a process temperature in forming a film by T-die melting casting method is from 50% to 250% based on an MFR value of the propylene-based polymer under the same condition.

Filled polyimide polymers

The present disclosure relates generally to filled polyimides that can be used in films and articles comprising the films. The films are useful in coverlay applications and have advantageous optical properties. The present disclosure also relates to blends of polyimide precursor, polyacrylonitrile, and cellulosic polymer which can be used to obtain the filled polyimides.

Methods of Improving the Physical Properties of Polyolefin Films

Methods of improving the physical properties of a polyolefin film that include providing interpolymer resin particles, forming a blend composition by blending from about 0.1 to about 25% by weight based on the weight of the blend composition of interpolymer resin particles into a second polyolefin; and forming a film from the blend composition. The interpolymer resin particles are made up a styrenic polymer intercalated within a first polyolefin. The first polyolefin is present at from about 20% to about 80% by weight based on the weight of the particles and the styrenic polymer is present at from about 20% to about 80% by weight based on the weight of the particles.

Liquid crystal film

A liquid crystal film (LCF) is provided. The exemplified LCF can be used as a reflective polarization plate, which can improve luminance and light utilization efficiency of a display device, such as an LCD, and the like.

Films of polymer-oil compositions

Films formed from compositions comprising thermoplastic polymers and oils are disclosed, where the oil is dispersed throughout the thermoplastic polymer. Also disclosed are articles formed from films of these compositions.

Film, resin composition and polymer

Provided is a film comprising a polymer that comprises a structural unit represented by the following formula (1), wherein at least part of the terminal structure of the polymer is at least one structure selected from the group consisting of structural units represented by the following formula (2) and structural units represented by the following formula (3).

Polymer porous film and method of producing the same

Provided is a porous material excellent in heat insulating property, mechanical property, and surface properties (such as adhesiveness and abrasion property). The porous material is a polymer porous film of a single layer, including a first porosity size changing portion ( 613 ) formed of independent porosities each showing a gradual increase in porosity size across a region accounting for 10% or more of a film thickness from a first surface side ( 611 ) toward a second surface side ( 612 ).

POLYPROPYLENE WITH SPECIFIC CALCIUM STEARATE CONTENT FOR SPECIAL CAPACITORS

Capacitor film comprising a biaxially oriented polypropylene (BOPP) and more than 100 to below or equal 400 ppm of an alkali earth fatty acid salt. 116-. (canceled)17. Capacitor film comprising:(a) at least 90 wt. % of a biaxially oriented polypropylene (BOPP), and(b) more than 100 to below or equal 400 ppm of an alkali earth fatty acid salt.18. Capacitor film according to claim 17 , wherein the biaxially oriented polypropylene (BOPP) has a draw ratio in machine direction of at least 4.0 and a draw ratio in transverse direction of at least 4.0.19. Capacitor film according to claim 17 , wherein the biaxially oriented polypropylene (BOPP) is the only polymer component within the capacitor film.20. Capacitor film according to claim 17 , wherein the biaxially oriented polypropylene (BOPP) is a propylene homopolymer.21. Capacitor film according to claim 17 , wherein the capacitor film and/or the biaxially oriented polypropylene (BOPP) has/have an ash content below 100 ppm.22. Capacitor film according to claim 17 , wherein the biaxially oriented polypropylene (BOPP) has:{'sup': '13', '(a) <2,1>erythro regiodefects of not more than 0.4 mol. % determined by C-spectroscopy,'}and/or(b) a branching g′ valve of at least 0.9.23. Capacitor film according to claim 17 , wherein the biaxially oriented polypropylene (BOPP) has:(a) a molecular weight distribution (MWD) measured according to ISO 16014 of at least 2.8,and/or{'sub': '2', '(b) a melt flow rate MFR(230° C.) measured according to ISO 1133 in the range of 1.0 to 6.0 g/10 min.'}24. Capacitor film according to claim 17 , wherein the capacitor film and/or the biaxially oriented polypropylene (BOPP) has/have:{'sub': 'm', '(a) a melting temperature (T) measured according to ISO 11357-3 of at least 145.0° C.,'}and/or{'sub': 'c', '(b) crystallization temperature (T) measured according to ISO 11357-3 of at least 113° C.'}25. Capacitor film according to claim 17 , wherein the capacitor film and/or the biaxially oriented polypropylene ...

CELLULOSE ACYLATE FILM, PROTECTIVE FILM FOR POLARIZING PLATE, POLARIZING PLATE, AND LIQUID CRYSTAL DISPLAY DEVICE

There is provided a cellulose acylate film, containing a hindered amin-based compound, wherein the hindered amine-based compound is contained in an amount of 0.001% by mass to 5% by mass based on cellulose acylate, a minimum value of Knoop hardness is 170 N/mmto 220 N/mm, and the Knoop hardness is measured several times by a Knoop indenter, the Knoop indenter is rotated by a given angle in each measurement, and a rotation axis of the Knoop indenter is orthogonal to an upper surface of the cellulose acylate film. 1. A cellulose acylate film , comprising a hindered amin-based compound ,wherein the hindered amine-based compound is contained in an amount of 0.001% by mass to 5% by mass based on cellulose acylate,{'sup': 2', '2, 'a minimum value of Knoop hardness is 170 N/mmto 220 N/mm, and'}the Knoop hardness is measured several times by a Knoop indenter under press load of 50 mN in accordance with a method of JIS Z 2215, the Knoop indenter is rotated by a given angle in each measurement, the each measurement is carried out at a same press position and a rotation axis of the Knoop indenter is orthogonal to an upper surface of the cellulose acylate film.2. The cellulose acylate film according to claim 1 , further comprising a compound represented by the following Formula (1) in an amount of 2% by mass to 20% by mass based on cellulose acylate.{'br': None, 'B-(G-A)n-G-B\u2003\u2003Formula (1)'}wherein, each of B independently represents a benzenemonocarboxylic acid residue,each of G independently represents an alkylene glycol residue having 2 to 12 carbon atoms, an aryl glycol residue having 6 to 12 carbon atoms or an oxyalkylene glycol residue having 4 to 12 carbon atoms,A represents an alkylenedicarboxylic acid residue having 4 to 12 carbon atoms or an arylenedicarboxylic acid residue having 6 to 12 carbon atoms, andn represents an integer of 1 or more.3. The cellulose acylate film according to claim 2 , comprising two or more kinds of the compound represented by ...

CELLULOSE ESTER/ELASTOMER COMPOSITIONS

A cellulose ester composition is provided comprising at least one cellulose ester and at least one additive selected from the group consisting of a compatibilizer, and a plasticizer. Processes for producing the cellulose ester composition are also provided. In another embodiment, a cellulose ester/elastomer composition is provided comprising at least one elastomer, at least one cellulose ester; and at least one additive; wherein the additive is at least one selected from the group consisting of a compatibilizer and a plasticizer. Processes for producing the cellulose ester/elastomer composition is also provided as well as articles comprising the cellulose ester/elastomer composition. 1. A tire comprising a cellulose ester/elastomer composition wherein said cellulose ester/elastomer comprising at least one cellulose ester , at least one elastomer , and at least one additive selected from the group consisting of at least one compatibilizer and at least one plasticizer.2. The tire according to wherein said cellulose ester has an inherent viscosity (IV) of about 0.2 to about 3.0 deciliters/gram.3. The tire according to wherein said cellulose ester has a total degree of substitution per anhydroglucose unit (DS/AGU) from about 0.5 to about 2.8.4. The tire according to wherein the cellulose ester is a low molecular weight cellulose mixed ester selected from the group consisting of:a) a low molecular weight mixed cellulose ester having the following properties:a total degree of substitution per anhydroglucose unit of from about 3.08 to about 3.50, having the following substitutions:a degree of substitution per anhydroglucose unit of hydroxyl of no more than about 0.70,{'sub': 3', '4, 'a degree of substitution per anhydroglucose unit of C-Cesters from about 0.80 to about 1.40, and'}a degree of substitution per anhydroglucose unit of acetyl of from about 1.20 to about 2.34;an inherent viscosity of from about 0.05 to about 0.15 dL/g, as measured in a 60/40 (wt./wt.) solution ...

CELLULOSE ESTERS IN HIGHLY-FILLED ELASTOMERIC SYSTEMS

An elastomeric composition is provided comprising at least one non-fibril cellulose ester, at least one non-nitrile primary elastomer, optionally a starch, and at least 70 parts per hundred rubber (phr) of one or more fillers, wherein the weight ratio of the cellulose ester to the starch is at least 3:1, wherein the cellulose ester is in the form of particles having an average diameter of not more than 10 μm. 1. An elastomeric composition comprising at least one non-fibril cellulose ester , at least one non-nitrile primary elastomer , optionally a starch , and at least 70 parts per hundred rubber (phr) of one or more fillers , wherein the weight ratio of said cellulose ester to said starch is at least 3:1 , wherein said cellulose ester is in the form of particles having an average diameter of not more than 10 μm.2. The elastomeric composition according to wherein said elastomeric composition comprises at least 1 and/or not more than 75 phr of said cellulose ester.3. The elastomeric composition according to wherein said elastomeric composition comprises at least 75 phr and/or not more than 150 phr of said one more fillers.4. The elastomeric composition according to wherein said elastomeric composition comprises at least 85 phr and/or not more than 130 phr of said one more fillers.5. The elastomeric composition according to wherein said fillers comprise silica claim 1 , carbon black claim 1 , clay claim 1 , alumina claim 1 , talc claim 1 , mica claim 1 , discontinuous fibers including cellulose fibers and glass fibers claim 1 , aluminum silicate claim 1 , aluminum trihydrate claim 1 , barites claim 1 , feldspar claim 1 , nepheline claim 1 , antimony oxide claim 1 , calcium carbonate claim 1 , kaolin claim 1 , and combinations thereof.6. The elastomeric composition according to wherein at least 75 percent of said particles have an aspect ratio of not more than 2:1.7. The elastomeric composition according to wherein at least 75 percent of said particles have a particle ...

Process for dispersing cellulose esters into elastomeric compositions

A cellulose ester concentrate is provided comprising at least one non-nitrile carrier elastomer and at least one non-fibril cellulose ester, wherein said cellulose ester concentrate comprises at least 15 weight percent of said cellulose ester.

CELLULOSE ESTERS IN PNEUMATIC TIRES

A tire component is provided comprising an elastomeric composition containing at least one non-fibril cellulose ester, at least one non-nitrile primary elastomer, optionally a starch, and at least 70 parts per hundred rubber (phr) of one or more fillers, wherein the weight ratio of the cellulose ester to the starch is at least 3:1, and wherein the cellulose ester is in the form of particles having an average diameter of not more than 10 μm. 1. A tire component comprising an elastomeric composition containing at least one non-fibril cellulose ester , at least one non-nitrile primary elastomer , optionally a starch , and at least 70 parts per hundred rubber (phr) of one or more fillers , wherein the weight ratio of said cellulose ester to said starch is at least 3:1 , wherein said cellulose ester is in the form of particles having an average diameter of not more than 10 μm.2. The tire component according to wherein said tire component comprises a tire tread claim 1 , tire subtread claim 1 , tire undertread claim 1 , body plies claim 1 , belts claim 1 , overlay cap plies claim 1 , belt wedges claim 1 , shoulder inserts claim 1 , tire apex claim 1 , tire sidewalls claim 1 , and/or bead fillers.3. The tire component according to wherein said tire component comprises a tire tread claim 1 , tire subtread claim 1 , tire undertread claim 1 , and/or tire sidewall.4. The tire component according to wherein said elastomeric composition comprises at least 1 and/or not more than 75 phr of said cellulose ester.5. The tire component according to wherein said elastomeric composition comprises at least 75 phr and/or not more than 150 phr of said one or more fillers.6. The tire component according to wherein said elastomeric composition comprises at least 85 phr and/or not more than 130 phr of said one or more fillers.7. The tire component according to wherein said fillers comprise silica claim 1 , carbon black claim 1 , clay claim 1 , alumina claim 1 , talc claim 1 , mica claim 1 , ...

Process for dispersing cellulose esters into elastomeric compositions

A process to produce a cellulose ester concentrate is provided. The process comprising mixing at least one cellulose ester with one or more carrier elastomers to produce the cellulose ester concentrate, wherein at least a portion of the mixing occurs at a temperature that exceeds the Tg of the cellulose ester, wherein at least a portion of the mixing operates at a shear rate of at least 50 s −1 .

CELLULOSE ESTERS IN PNEUMATIC TIRES

A process for producing a tire component is provided. The process comprises: (a) blending at least one cellulose ester, at least one non-nitrile primary elastomer, and at least 70 phr of one or more fillers to produce an elastomeric composition, wherein at least a portion of the blending occurs at a temperature exceeding the Tg of the cellulose ester, wherein the elastomeric composition exhibits a Mooney viscosity at 100° C. as measured according to ASTM D1646 of not more than 110 AU; and (b) forming the tire component with the elastomeric composition. 1. A process for producing a tire component , said process comprising:(a) blending at least one cellulose ester, at least one non-nitrile primary elastomer, and at least 70 phr of one or more fillers to produce an elastomeric composition, wherein at least a portion of said blending occurs at a temperature exceeding the Tg of said cellulose ester, wherein said elastomeric composition exhibits a Mooney viscosity at 100° C. as measured according to ASTM D1646 of not more than 110 AU; and(b) forming said tire component with said elastomeric composition.2. The process according to wherein said tire component comprises a tire tread claim 1 , tire subtread claim 1 , tire undertread claim 1 , body plies claim 1 , belts claim 1 , overlay cap plies claim 1 , belt wedges claim 1 , shoulder inserts claim 1 , tire apex claim 1 , tire sidewalls claim 1 , and/or bead fillers.3. The process according to wherein said tire component comprises a tire tread claim 1 , tire subtread claim 1 , tire undertread claim 1 , and/or tire sidewall.4. The process according to wherein at least a portion of said blending occurs at temperatures that exceed the Tg of said cellulose ester by at least 10° C.5. The process according to wherein at least a portion of said blending occurs at temperatures of at least 130° C. and/or not more than 220° C.6. The process according to wherein at least a portion of said blending operates at a shear rate of at least ...

Cellulose esters in highly-filled elastomeric systems

A process to produce an elastomeric composition is provided. The process comprises blending at least one cellulose ester, at least one non-nitrile primary elastomer, and at least 70 phr of one or more fillers to produce the elastomeric composition, wherein at least a portion of the blending occurs at a temperature exceeding the Tg of said cellulose ester, and wherein the elastomeric composition exhibits a Mooney viscosity at 100° C. as measured according to ASTM D1646 of not more than 110 AU.

CELLULOSE ESTERS IN PNEUMATIC TIRES

A process for producing a tire component is provided. The process comprises blending an elastomeric composition containing at least one non-fibril cellulose ester, at least one primary elastomer, and one or more fillers, wherein the elastomeric composition exhibits a dynamic mechanical analysis (DMA) strain sweep modulus as measured at 5% strain and 30° C. of at least 1,450,000 Pa and a molded groove tear as measured according to ASTM D624 of at least 120 lbf/in. 1. A process for producing a tire component , said process comprising blending an elastomeric composition containing at least one non-fibril cellulose ester , at least one primary elastomer , and one or more fillers , wherein said elastomeric composition exhibits a dynamic mechanical analysis (DMA) strain sweep modulus as measured at 5% strain and 30° C. of at least 1 ,450 ,000 Pa and a molded groove tear as measured according to ASTM D624 of at least 120 lbf/in.2. The process according to wherein said tire component comprises a tire tread claim 1 , tire subtread claim 1 , tire undertread claim 1 , body plies claim 1 , belts claim 1 , overlay cap plies claim 1 , belt wedges claim 1 , shoulder inserts claim 1 , tire apex claim 1 , tire sidewalls claim 1 , and/or bead fillers.3. The process according to wherein said tire component comprises a tire tread claim 1 , tire subtread claim 1 , tire undertread claim 1 , and/or tire sidewall.4. The process according to wherein at least a portion of said blending occurs at temperatures that exceed the Tg of said cellulose ester by at least 10° C.5. The process according to wherein at least a portion of said blending occurs at temperatures of at least 130° C. and/or not more than 220° C.6. The process according to wherein at least a portion of said blending operates at a shear rate of at least 50 sand/or not more than 1 claim 1 ,000 s.7. The process according to wherein said elastomeric composition exhibits a Mooney viscosity at 100° C. as measured according to ASTM D ...

CELLULOSE ESTERS IN HIGHLY-FILLED ELASTOMERIC SYSTEMS

A process to produce an elastomeric composition is provided. The process comprises blending at least one cellulose ester, at least one primary elastomer, and one or more fillers to produce an uncured elastomeric composition, wherein the blending occurs at a temperature exceeding the Tg of the cellulose ester and curing the uncured elastomeric composition to produce a cured elastomeric composition, wherein the cured elastomeric composition exhibits a dynamic mechanical analysis (DMA) strain sweep modulus of at least 1,450,000 Pa and a molded groove tear as measured according to ASTM D624 of at least 120 lbf/in. 1. A process to produce an elastomeric composition , said process comprising:blending at least one cellulose ester, at least one primary elastomer, and one or more fillers to produce an uncured elastomeric composition, wherein said blending occurs at a temperature exceeding the Tg of said cellulose ester, wherein said uncured elastomeric composition exhibits a Mooney viscosity at 100° C. as measured according to ASTM D1646 of not more than 110 AU; andcuring said uncured elastomeric composition to produce a cured elastomeric composition, wherein said cured elastomeric composition exhibits a dynamic mechanical analysis (DMA) strain sweep modulus as measured at 5% strain and 30° C. of at least 1,450,000 Pa and a molded groove tear as measured according to ASTM D624 of at least 120 lbf/in.2. The process according to wherein said uncured elastomeric composition exhibits a Mooney viscosity at 100° C. as measured according to ASTM D 1646 of not more than 105 AU.3. The process according to wherein said cured elastomeric composition exhibits a DMA strain sweep modulus as measured at 5% strain and 30° C. of at least 1 claim 1 ,600 claim 1 ,000 Pa.4. The process according to wherein said cured elastomeric composition exhibits a molded groove tear as measured according to ASTM D624 of at least 130 lbf/in.5. The process according to wherein at least a portion of said ...

POLYAMIDE RESIN FILMS AND PROCESSES FOR MANUFACTURING THEM

Provided is a windable thin single layer film comprising a xylylenediamine-based polyamide resin. 1. A polyamide resin film comprising:a polyamide resin which is a polycondensate of a diamine and a dicarboxylic acid,wherein the diamine comprises 70 mol % or more of xylylenediamine, and the polyamide resin film has a thickness of 10 to 50 μm and a surface having a texture.2. The polyamide resin film according to claim 1 ,wherein the polyamide resin film has the texture formed by texturing a surface of a film comprising the polyamide resin with a plurality of texturing rolls comprising a first roll and a second roll positioned opposite to the first roll, and the first roll is positioned such that the film contacts with the first roll after the film is extruded from an extrusion die.3. The polyamide resin film according to claim 1 , wherein the polyamide resin film has a surface roughness of 0.01 to 1 μm.4. The polyamide resin film according to claim 1 , wherein the xylylenediamine is m-xylylenediamine claim 1 , p-xylylenediamine or a mixture of m-xylylenediamine and p-xylylenediamine.5. The polyamide resin film according to claim 1 , wherein the dicarboxylic acid is a dicarboxylic acid comprising 50 mol % or more of a straight chain aliphatic α claim 1 ,ω-dicarboxylic acid having 4 to 20 carbon atoms.6. The polyamide resin film according to claim 1 , wherein the dicarboxylic acid is a dicarboxylic acid comprising 70 mol % or more of a straight chain aliphatic α claim 1 ,ω-dicarboxylic acid having 4 to 20 carbon atoms and 1 mol % or more and less than 30 mol % of isophthalic acid.7. The polyamide resin film according to claim 1 , wherein the dicarboxylic acid is adipic acid claim 1 , sebacic acid or a combination thereof.8. The polyamide resin film according to claim 1 , wherein the polyamide resin is a poly(m-xylylene sebacamide) resin claim 1 , a poly(p-xylylene sebacamide) resin or a poly(m-xylylene/p-xylylene sebacamide) copolymer resin.9. The polyamide resin film ...

WEATHER-RESISTANT CROSSLINKED POLYOLEFIN COMPOSITION, POLYOLEFIN SHEET MADE FROM THE SAME AND METHOD FOR MAKING THE SHEET

A weather-resistant crosslinked polyolefin composition is a novel formula containing a comprehensive mixture constituted by crosslinking agent, antistatic agent, TiOsized in nanometer and TiOsized in micrometer and essential components including polyolefin composition resin, lubricant auxiliary crosslinking agent, antioxidant, UV absorber and filler etc; this novel formula is particularly suited to produce a weather-resistant crosslinked polyolefin sheet with a calender machine instead of an extruder conventionally used, and the polyolefin sheets produced thereof are excellent in both heat-resistant and weather-resistant as well as in a high-quality sheet surface and capably made at a high yield rate through the calender machine. 1. A weather-resistant crosslinked polyolefin composition , suitably processed by a calender machine to produce a weather-resistant crosslinked polyolefin sheet , comprising: 20-50 PHR of polyethylene (PE),', '30-60 PHR of polypropylene (PP), and', '0.1-30 PHR of an ethylene-vinyl acetate (EVA) copolymer having a vinyl acetate (VA) content of 8-33%;, '100 PHR (parts per hundred resin) of a polyolefin composition resin comprising{'sub': 2', '2, '0.1-35 PHR of a comprehensive mixture comprising, based on a total comprehensive mixture weight thereof, 0.1-3 wt % of a main crosslinking agent, 0.1-1.5 wt % of an antistatic agent, 0.1-1.5 wt % of TiOnanoparticles and 94-99.7 wt % of TiOmicroparticles;'}0.01-2 PHR of an auxiliary crosslinking agent;0.1-15 PHR of a lubricant;0.1-5 PHR of an antioxidant;0.1-3 PHR of a UV absorber;0.1-30 PHR of a filler; and0-35 PHR of a colorant, if any.2. A method for producing a weather-resistant crosslinked polyolefin sheet produced through a calender machine , comprising the steps of:{'sub': 2', '2, '1) adding 0.1-3 wt % of a main crosslinking agent, 0.1-1.5 wt % of an antistatic agent, 0.1-1.5 wt % of TiOnanoparticles and 94-99.7 wt % of TiOmicroparticles, and mixing aforesaid ingredients evenly in a kneader at ...

Mechanical adhesion of copper metallization to dielectric with partially cured epoxy fillers

In some embodiments, an improved mechanical adhesion of copper metallization to dielectric with partially cured epoxy fillers is presented. In this regard, a substrate build-up film is introduced having epoxy material and a plurality of epoxy microspheres, wherein an interior of the microspheres is not fully cured. Other embodiments are also disclosed and claimed.

Cellulose Acylate Film

Provided is a cellulose acylate film. More particularly, the present invention relates to a cellulose acylate film having a low light scattering efficiency (haze).

Multi-Layer Films And Methods Of Forming Same

A multi-layer film having a first film layer being at least partially formed from a polymer (A) and a polymer (B) and a second film layer being at least partially formed from the polymer (A), the polymer (B), a polymer (C), and optionally an opacifying agent, wherein at least one of the polymer (A), the polymer (B) and the polymer (C) is synthetic and is at least partially derived from a renewable resource such that the multi-layer film has a bio-based content of about 10% to about 100% using ASTM D6866-10, method B. Methods of forming multi-layer films are also provided. 1. A method , of forming a multi-layer film , comprising:a. providing a renewable resource that is a natural resource that can be replenished within a 100 year time frame;b. deriving a monomer from the renewable resource and polymerizing the monomer to form a synthetic polymer;c. forming at least one of polymer (A), polymer (B) and polymer (C) from the synthetic polymer;d. processing a first film layer having an upper surface and a lower surface, the first film layer being at least partially formed from a polymer (A) and a polymer (B), wherein the first film layer comprises from about 75% to about 99% by weight of the polymer (A) and from about 1% to about 25% by weight of the polymer (B), wherein the polymer (A) comprises at least one of a low density polyethylene (LDPE) and a linear low density polyethylene (LLDPE) and the polymer (B) comprises a copolymer;e. processing a second film layer that is at least partially formed from polymer (A), polymer (B), from about 1% to about 35% by weight of a polymer (C), and optionally an opacifying agent, wherein polymer (C) comprises a homo polypropylene (homo-PP), and wherein at least one of polymer (A), polymer (B) and polymer (C) comprises the synthetic polymer to provide the multi-layer film having a bio-based content of about 10% to about 100% using ASTM D6866-10, method B; andf. at least partially overlying the second film layer onto one of the upper ...

Antireflection film, method for producing antireflection film, polarizer and image display device

The claimed invention provides an antireflection film including a light-transmitting substrate, a hard coat layer, and a low-refractive-index layer, the hard coat layer and the low-refractive-index layer being formed on the light-transmitting substrate, the low-refractive-index layer including a (meth)acrylic resin, hollow silica particles, reactive silica particles, and two kinds of antifouling agents, the hollow silica particles having an average particle size of 40 to 80 nm and a blending ratio to the (meth)acrylic resin, represented by a ratio: Amount of hollow silica particles/Amount of (meth)acrylic resin, of 0.9 to 1.4, the amount of the reactive silica particles being 5 to 60 parts by mass based on 100 parts by mass of the (meth) acrylic resin, the antifouling agents including an antifouling agent that contains a fluorine compound and an antifouling agent that contains a fluoro-silicone compound.

Retardation film, polarizing plate, liquid crystal display device, and compound

The purpose of the present invention is to provide a retardation film which has high retardation developability, good mechanical strength and good durability. This retardation film contains a cellulose derivative and at least one compound represented by general formula (1), wherein each of R 1 and R 2 independently represents an alkyl group, a cycloalkyl group, an aryl group or a heterocyclic group; X1 represents a single bond, —NR 4 —, —O— or —S—; X 2 represents a single bond, —NR 5 —, —NR 5 —(C═O)—, —O— or —S—; each of R 4 and R 5 independently represents a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group or a heterocyclic group; R 3 represents a substituent; n represents an integer of 0-4; and when n is 2 or more, a plurality of R 3 s may be the same or different and adjacent R 3 s may be joined together to form a ring).

TRANSPARENT RESIN COMPOSITION

The present invention relates to a transparent resin composition which comprises (a) a (meth)acrylate based resin comprising one or more (meth)acrylate based derivatives; and (b) an aromatic based resin having a chain having the hydroxy group containing portion and an aromatic moiety. 115-. (canceled)16. A method for manufacturing an optical film , the method comprising the steps of:preparing the a resin composition comprising(a) a copolymer comprising 50 to 99% by weight of a (meth)acrylate based unit and 1 to 50% by weight of a cyclic based unit having a cyclic portion derived from N-cyclohexylmaleimide and(b) an aromatic based resin having a chain having the hydroxy group containing portion and an aromatic moiety; andshaping the film by using the resin composition,wherein a haze value of the optical film is 2.5% or less.17. The method for manufacturing an optical film as set forth in claim 16 , further comprising:uniaxially or biaxially stretching the film.19. The method for manufacturing an optical film as set forth in claim 18 , further comprising:uniaxially or biaxially stretching the film.20. The method for manufacturing an optical film as set forth in claim 16 , wherein the (meth)acrylate based unit is selected from the group consisting of methyl methacrylate claim 16 , methyl acrylate claim 16 , ethyl acrylate claim 16 , butyl acrylate claim 16 , 2-ethylhexyl methacrylate claim 16 , lauryl methacrylate and benzyl methacrylate.21. The method for manufacturing an optical film as set forth in claim 16 , wherein the aromatic based resin includes a phenoxy based resin.22. The method for manufacturing an optical film as set forth in claim 21 , wherein the aromatic based resin has a number average molecular weight in the range of 1 claim 21 ,500 to 2 claim 21 ,000 claim 21 ,000 g/mol.26. The method for manufacturing an optical film as set forth in claim 16 , wherein the resin composition has a single glass transition temperature.27. The method for manufacturing an ...

Highly insulating film

An object of this invention is to provide a highly insulating film, which is excellent in the heat resistance and has increased breakdown voltage. This invention is a highly insulating film, which is characterized by comprising a biaxially stretched film containing a styrene polymer having a syndiotactic structure as a main component, containing a thermoplastic amorphous resin Y having a glass transition temperature Tg by DSC of 130° C. or higher in an amount of 5% by mass or more and 48% by mass or less, and having a plane orientation coefficient (ΔP) represented by the following equation (1) of −0.027 or less. ΔP=(Nx+Ny)/2−Nz (1) (Here, in the equation (1), Nx represents the minimum value of the refractive index in the plane direction of the film, Ny represents the refractive index in the direction perpendicular to Nx in the plane direction of the film, and Nz represents the refractive index in the thickness direction of the film.)

Composites Comprising a Polymer and a Layered Compound and Methods of Preparing and Using Same

A method comprising extrusion compounding a styrenic polymer and a layered compound to produce a composite, and orienting the composite to produce an oriented composite wherein the layered compound comprises natural clay, synthetic clay, natural colloid, synthetic colloid, natural sol, synthetic sol, natural gel, synthetic gel, natural fumes, synthetic fumes, or combinations thereof. A method of preparing an oriented film comprising extrusion compounding a styrenic polymer and a clay to produce a nanocomposite, casting the nanocomposite into a film, and orienting the film in at least one direction. 119-. (canceled)20. A method of preparing an oriented film comprising:extrusion compounding a styrenic polymer and a clay to produce a nanocomposite;casting the nanocomposite into a film; andorienting the film in at least one direction.21. The method of claim 20 , wherein the styrenic polymer is present in an amount of from 50% to 99.9% by weight of the nanocomposite claim 20 , and wherein the clay is present in an amount of from 0.1% to 50% by weight of the nanocomposite.22. The method of claim 20 , wherein the styrenic polymer comprises substituted styrenes claim 20 , alpha-methyl styrene claim 20 , ring-substituted styrenes claim 20 , p-methylstyrene claim 20 , disubstituted styrenes claim 20 , p-t-butyl styrene claim 20 , unsubstituted styrenes claim 20 , halogenated styrenes claim 20 , alkylated styrenes claim 20 , acrylonitrile claim 20 , esters of methacrylic acid with alcohols having from 1 to 8 carbons claim 20 , N-vinyl compounds claim 20 , vinylcarbazole claim 20 , maleic anhydride claim 20 , compounds which contain two polymerizable double bonds claim 20 , divinylbenzene claim 20 , butanediol diacrylate claim 20 , or combinations thereof; and the clay comprises natural clay claim 20 , synthetic clay claim 20 , natural colloid claim 20 , synthetic colloid claim 20 , natural sol claim 20 , synthetic sol claim 20 , natural gel claim 20 , synthetic gel claim 20 , ...

FILMS AND MEMBRANES OF POLY (ARYL KETONES) AND METHODS OF CASTING THE SAME FROM SOLUTION

A method of manufacturing a film or membrane includes: (a) dissolving at least one polymer comprising a poly(aryl ketone) in at least one solvent to form a dope; (b) depositing the dope on a substrate to form a coated substrate at appropriate conditions; and (c) drying the coated substrate to form the film or membrane. The dope may also include additional polymers or fillers, such as carbon nanotubes. 1. A method of manufacturing a film or membrane comprising;dissolving at least one polymer comprising a poly(aryl ketone) in at least one solvent to form a dope; depositing the dope on a substrate to form a coated substrate; and drying the coated substrate to form the film or membrane.2. A method of manufacturing a film or membrane according to claim 1 , wherein the at least one polymer comprises one or more poly(aryl ketones) selected from polyetherketoneketones (PEKK) claim 1 , polyetheretherketones (PEEK) claim 1 , polyetherketones (PEK) claim 1 , polyetherketoneetherketoneketones (PEKEKK) claim 1 , or mixtures thereof.3. A method of manufacturing a film or membrane according to claim 2 , wherein the poly(aryl ketone) comprises PEKK.4. A method of manufacturing a film or membrane according to claim 1 , wherein the at least one solvent comprises a halogenated organic compound.5. A method of manufacturing a film or membrane according to claim 1 , wherein the at least one solvent comprises a halogenated organic acid.6. A method of manufacturing a film or membrane according to claim 1 , wherein the at least one solvent comprises a chlorinated organic acid.7. A method of manufacturing a film or membrane according to claim 1 , wherein the at least one solvent comprises an aromatic solvent.8. A method of manufacturing a film or membrane according to claim 1 , wherein the at least one solvent has a boiling point at atmospheric pressure of not greater than 250° C.9. A method of manufacturing a film or membrane according to claim 1 , wherein the at least one solvent comprises ...

METHODS FOR MAKING LIGNOCELLULOSE CONTAINING COMPOSITE PRODUCTS

Methods for making composite products are provided. In at least one specific embodiment, the method can include combining a plurality of lignocellulose substrates and one or more free radical precursors to produce a mixture of the lignocellulose substrates and the one or more free radical precursors. The method can also include maintaining the mixture at a temperature less than 60° C. for at least 10 minutes while retaining at least 11 wt % of the one or more free radical precursors charged to the mixture. The method can then include heating the mixture comprising at least 11 wt % of the one or more free radical precursors charged to the mixture to a temperature of at least 60° C. to about 300° C. to produce a composite product. The composite product can have a density less than 1 g/cmand an internal bond strength of at least 0.35 MPa. 1. A method for making a composite product , comprising:combining a plurality of lignocellulose substrates and one or more free radical precursors to produce a mixture of the lignocellulose substrates and the one or more free radical precursors;maintaining the mixture at a temperature less than 60° C. for at least 10 minutes while retaining at least 11 wt % of the one or more free radical precursors charged to the mixture; and then{'sup': '3', 'heating the mixture comprising at least 11 wt % of the one or more free radical precursors charged to the mixture to a temperature of at least 60° C. to about 300° C. to produce a composite product having a density less than 1 g/cmand an internal bond strength of at least 0.35 MPa.'}2. The method of claim 1 , wherein the mixture is maintained at the temperature less than 60° C. for at least 20 minutes while retaining at least 25 wt % of the one or more free radical precursors charged to the mixture claim 1 , and wherein the mixture comprising at least 25 wt % of the one or more free radical precursors charged to the mixture is heated to the temperature of at least 60° C. to about 300° C. to ...

POLYAMIC ACID COMPOSITION FOR PACKAGING ELECTRONIC COMPONENTS, AND METHOD FOR PACKAGING ELECTRONIC COMPONENTS USING SAME

The present invention relates to a polyamic acid composition for packaging electronic components and a method for packaging electronic components using the same, wherein the polyamic acid composition comprises a dianhydride main component having a benzophenone structure as a dianhydride-based monomer in a high proportion and a diamine component having a benzene ring as a diamine-based monomer, whereby it is possible to improve a coefficient of thermal expansion, a glass transition temperature, an elongation, and the like of a polyimide thin film formed therefrom, and when the polyimide thin film is used as a packaging material for an inorganic material such as a silicon water, it exhibits excellent adhesion to the inorganic material and can be easily removed upon 02 plasma removal, as well as has a remarkably low residual ratio of organic residues on the surface of the inorganic material after the removal, so that it can be easily used as a packaging material for electronic components and the like. 1. A poly amic acid composition ,comprising a polyamic acid prepared by polymerizing a dianhydride-based monomer and a diamine-based monomer, wherein the dianhydride-based monomer comprises 60 mol % or more of a dianhydride main component having a benzophenone structure, anda concentration of organic residues produced by the following test method (a) is 1,000 ppm or less:in a test method (a),{'sub': '2', 'the polyamic acid composition is applied on a silicon-based wafer having a width of 1 cm*a length of 1 cm and heat-treated to form a polyimide thin film having a thickness of 10 p.m to 15 μm, the formed polyimide thin film is treated with Oplasma at 75 Watt and 150 mT for 1 minute, and then the concentration of the organic residues derived from the polyimide thin film present on the silicon-based wafer is measured.'}2. The polyamic acid composition according to claim 1 ,further comprising a dianhydride subcomponent having one benzene ring when the content of the ...

BENDABLE CIRCUIT BOARD, EXPANDABLE CIRCUIT BOARD, AND ELECTRONIC DEVICE MADE THEREFROM

Provided are an expandable or bendable circuit board having good body-contact feel, strong against bending and folding, and an electronic device made therefrom. The bendable circuit board includes: a film comprising a polyurethane synthesized by reacting a long-chain polyol with polyisocyanate and having a storage modulus at ° C. of to MPa, a tensile strength of to MPa, and an elongation at break of to %, and the temperature of which the storage elastic modulus reaches to MPa is at ° C. or higher; and circuit wiring formed in contact with a surface of the film. Alternatively, an expandable circuit board having the ratio ρ/ρof the specific electrical resistance ρ of the circuit wiring when the circuit wiring is expanded to the specific electrical resistance (Ω·cm) ρof the circuit wiring before the circuit wiring is expanded is within a range of to 1. A bendable wiring board , comprising:a film composed of a polyurethane to be synthesized by allowing a long-chain polyol to react with a polyisocyanate, whereina temperature of the polyurethane at which a storage elastic modulus measured by a dynamic viscoelasticity measurement becomes 1 MPa is 155° C. or higher, and the storage elastic modulus of 20 to 200 MPa at 25° C.,', 'a tensile strength of 20 to 80 MPa, and', 'elongation at break of 500 to 900%; and, 'the polyurethane has'}circuit wiring formed so as to be in contact with a surface of the film.2. The bendable wiring board according to claim 1 , wherein the polyisocyanate has a constituent unit derived from 1 claim 1 ,4-bis(isocyanatomethyl)cyclohexane with a trans isomer at a proportion of 70% to 95%.3. The bendable wiring board according to claim 1 , wherein the long-chain polyol has a number average molecular weight of 500 to 3 claim 1 ,500.4. The bendable wiring board according to claim 1 , wherein the polyurethane is a thermoplastic polyurethane claim 1 , and the film is a single-layer film.5. An elastic (stretchable and shrinkable) wiring board claim 1 , ...

RADICALLY POLYMERIZABLE POLYETHER, METHOD FOR PRODUCING SAID RADICALLY POLYMERIZABLE POLYETHER, POLYMERIZABLE COMPOSITION COMPRISING SAID RADICALLY POLYMERIZABLE POLYETHER AND RADICALLY POLYMERIZABLE VINYL MONOMER, AND COPOLYMER, MOLDED ARTICLE AND FILM EACH FORMED BY RADICAL POLYMERIZATION OF SAID POLYMERIZABLE COMPOSITION

Provided is (1) a radically polymerizable polyether which imparts excellent mechanical properties including excellent transparency, a high degree of elongation at break and high bending strength to a copolymer produced by the radical polymerization of a radically polymerizable monomer, and a method for producing the radically polymerizable polyether; (2) a polymerizable composition comprising the radically polymerizable polyether and a radically polymerizable vinyl monomer, which enables the formation of a copolymer having excellent mechanical properties; and (3) a copolymer, a molded article and a film, each of which comprises the copolymer. 1. A radically polymerizable polyether (A) which has a mass average molecular weight of from 20 ,000 to 100 ,000 and comprises a polyalkylene ether backbone having a (meth)acryloyl group as a pendant group and a polytetramethylene ether backbone.3. The radically polymerizable polyether (A) according to claim 2 , wherein m1 claim 2 , m2 claim 2 , and n in Formula (1) are in a relation of 0.0005 m1/(m1 +m2 +n) 0.20.4. The radically polymerizable polyether (A) according to claim 2 , wherein m1 claim 2 , m2 claim 2 , and n in Formula (1) are in a relation of 0.001≦m1/(m1+m2+n)≦0.10.5. A polymerizable composition (C) which comprises the radically polymerizable polyether (A) according to and a radically polymerizable vinyl monomer (B) as main components and is formed by blending the component (B) at from 99 to 1% by mass with respect to from 1 to 99% by mass of the component (A).6. The polymerizable composition (C) according to claim 5 , wherein the radically polymerizable vinyl monomer (B) is a (meth)acrylic monomer.7. A copolymer formed by radical polymerization of the polymerizable composition (C) according to .8. A molded article formed by radical polymerization of the polymerizable composition (C) according to after being shaped into a desired shape.9. A film formed by radical polymerization of the polymerizable composition (C) ...

CROSS-LINKED POLYMER NETWORKS AND METHODS OF MAKING AND USING SAME

Cross-linked polymer networks that are at least partially conjugated (e.g., phenylene vinylene polymer networks). The cross-linked polymer networks may be thin-films disposed on a substrate. The cross-linked polymer network may be covalently bonded to the substrate. The cross-linked polymer networks can be used, for example, in methods of detecting explosives (e.g., RDX (cyclotrimethylenetrinitramine)) and degradation products thereof. 2. The method of claim 1 , wherein the cross-linked polymer network is covalently bonded to the substrate.4. The method of claim 1 , wherein the explosive is selected from nitramines claim 1 , nitroesters claim 1 , degradation products thereof claim 1 , and combinations thereof.5. The method of claim 4 , wherein the nitramine is cyclotrimethylenetrinitramine (RDX) claim 4 , and the nitroester is pentaerythritol tetranitrate (PETN) claim 4 , trinitrotoluene (TNT) claim 4 , dinitrotoluene (DNT) claim 4 , 2 claim 4 ,4 claim 4 ,6-triamino-1 claim 4 ,3 claim 4 ,5-trinitrobenzene (TATB) claim 4 , or 2 claim 4 ,3-dimethyl-2 claim 4 ,3-dinitrobutane (DMNB) claim 4 , octahydro-1 claim 4 ,3 claim 4 ,5 claim 4 ,7-tetranitro-1 claim 4 ,3 claim 4 ,5 claim 4 ,7-tetrazocine (HMX).6. The method of claim 1 , wherein the test sample is a gas-phase sample or a solid sample.7. The method of claim 1 , wherein the sample is not pre-concentrated.8. A thin film of a cross-linked polymer network comprising a plurality of trivinyl benzene moieties disposed on a substrate.9. The thin-film of claim 8 , wherein the substrate is selected from fused silica claim 8 , silicon claim 8 , gold claim 8 , silver claim 8 , platinum claim 8 , copper claim 8 , nickel claim 8 , glass claim 8 , sapphire claim 8 , mica claim 8 , and polymer substrates.10. The thin-film of claim 8 , wherein the cross-linked polymer network is covalently bonded to the substrate.12. The thin film of claim 8 , wherein the film has a thickness of 2 nm to 10 micrometers. This application claims ...

PRINTABLE FILM

This invention concerns a process for producing a food contact approvable, printable film comprising: providing a web of film having a width of at least about 1 cm and/or a length of at least 1 m and/or a weight of at least about 1 g and having a food-contactable surface; at a first location subjecting at least a first surface of the film web to a modified atmosphere dielectric barrier discharge (MADBD) treatment; winding the film web onto a reel; transporting the wound film web to a second location; unwinding the film web from the reel; and subjecting the first surface of the film to corona treatment. The invention also concerns printed films obtainable by the process of the invention, and articles of packaging and/or labelling made from such films. 1. A process for producing a food contact approvable , printable film comprising:a. providing a web of film having a width of at least about 1 cm and/or a length of at least 1 m and/or a weight of at least about 1 g and having a food-contactable surface;b. at a first location subjecting at least a first surface of the film web to a modified atmosphere dielectric barrier discharge (MADBD) treatment;c. winding the film web onto a reel;d. transporting the wound film web to a second location;e. unwinding the film web from the reel; andf. subjecting the first surface of the film to corona treatment.2. The process according to claim 1 , wherein the film web:i. comprises no migratory additives or substances; or{'sup': '2', 'ii. comprises one or more migratory additives or substances in amounts such that not more than 100 mg of any such migratory additive(s) or substance(s) per dmof the food-contactable surface is or are able to migrate to the food-contactable surface of the film,'}with the proviso that when the film comprises no migratory additives or substances then the film is preferably not a 55 μm thick biaxially oriented polymeric film having a core layer of random polypropylene/polyethylene copolymer and coextruded skin ...

Asymmetric Regio-regular Conjugated Polymers for Electronic Applications

A polymer consisting of a regio-regular polymer backbone basing on asymmetric fluorine-substituted 2,1,3-benzothiadiazole units (FBT) having a Formula 1MP0: 4. A film formed from a solvent solution contains the polymer of .5. A device made from a film contains the polymer of . This invention relates to the field of asymmetric regio-regular conjugated polymers and their use in electronic-optical and electronic devices. More particularly, this invention relates to regio-regular conjugated semiconducting polymers containing asymmetric fluorine substituted (2,1,3)-benzothiadiazole in backbone. The invented asymmetric regio-regular conjugated polymers are soluble in common organic solvents for printing thin film devices such as organic photovoltaic devices (OPV), organic photo detectors, organic thin film transistors (OTFT) and organic sensors.Conjugated polymers consist at least of one backbone chain of alternating double and single bonds. The π-electrons in conjugated polymers are delocalized and can be easier moved from one bond to the other, what makes such conjugated polymers to be a kind of organic semiconductors, thus referred as semiconducting polymers as well.Generally, semiconducting polymers are created via cross-coupling condensation reactions with symmetrical monomer units that produce linear polymer backbone configurations. When symmetric monomer units are involved, various regiochemistries between adjacent structural units along the backbone vector can be created. As an example. Scheme-1 demonstrates the possible polymer chain configurations can be generated from monomer 3-hexylthiophene. The electronic properties such as charge mobility in organic thin film transistor (OTFT) and power conversion efficiency (PCE) in organic photovolatic (OPV) devices have been shown to be strongly dependent on the configuration of polymer backbone. Higher performance has been generally observed for these polymers with higher regioregularity. A high regioregularity means a ...

Composition for Low density, Ultrathin, and Inorganic Film and Its Preparation Method

A composition for low density, ultrathin, and inorganic films, comprising a mixture of 70-82% of calcium carbonate by weight, 10-15% of linear polyethylene by weight, 1-5% of stearic acid by weight, 0.40-0.80% of aluminate by weight, 0.20-0.80% of titanic acid ester by weight, 0.4-3.0% of modified polyethoxylated silicone emulsion by weight, 0.05-0.5% of foaming agent by weight, and 0.01-0.1% of foaming agent accelerator by weight. The inorganic of the present invention is reduced in thickness, light in weight, easy to degrade, high tensile and high tear strength, toxicity-free, high temperature resistance, and low prices, so as to fulfill the requirement of producing the mulch, trash bags, shopping bags, and package bags. 1. A composition for low density , ultrathin , and inorganic films , comprising a mixture of 70-82% of calcium carbonate by weight , 10-15% of linear polyethylene by weight , 1-5% of stearic acid by weight , 0.40-0.80% of aluminate by weight , 0.20-0.80% of titanic acid ester by weight , 0.4-3.0% of modified polyethoxylated silicone emulsion by weight , 0.05-0.5% of foaming agent by weight , and 0.01-0.1% of foaming agent accelerator by weight.2. The composition claim 1 , as recited in claim 1 , wherein a granularity of said calcium carbonate is 1-3 micron.3. The composition claim 1 , as recited in claim 1 , wherein said modified polythoxylated silicone emulsion has 70% of modified polythoxylated silicone.4. The composition claim 2 , as recited in claim 2 , wherein said modified polythoxylated silicone emulsion has 70% of modified polythoxylated silicone.5. The composition claim 1 , as recited in claim 1 , further comprising not more than 2% of polyethylene wax by weight and not more than 3% of refined paraffin wax by weight.6. The composition claim 4 , as recited in claim 4 , further comprising not more than 2% of polyethylene wax by weight and not more than 3% of refined paraffin wax by weight.7. The composition claim 1 , as recited in claim 1 , ...

BARRIER FILM FOR FOOD PACKAGING

Barrier films are prepared from a blend of two high density polyethylene blend components and a high performance organic nucleating agent. The two high density polyethylene blend components have substantially different melt indices. Large reductions in the moisture vapor transmission rate of the film are observed in the presence of the nucleating agent when the melt indices of the two blend components have a ratio of greater than 10/1. The resulting barrier films are suitable for the preparation of packaging for dry foods such as crackers and breakfast cereals. 115-. (canceled)16. A method for improving the barrier properties of a polyethylene film , said method comprising the steps of converting into a film a mixture comprising;{'sub': '2', 'I) from about 5 to about 60 weight percent, based on the total weight of said mixture, of a blend component a), comprising a first high density polyethylene having a melt index, I;'}{'sub': '2', 'II) from about 95 to about 40 weight percent, based on the total weight of said mixture, of a blend component b), comprising a second high density polyethylene having a melt index I′, and;'}III) from 100 to 3,000 ppm of a nucleating agent, comprising a calcium salt of 1,2 cyclohexanedicarboxylic acid;{'sub': 2', '2, 'wherein, a melt index ratio, defined by dividing said melt index, I, of said blend component a) by said melt index, I′′, of blend component b), is from about 12 to about 19;'}wherein each of said blend component a) and said blend component b) have a density from about 0.950 to about 0.975 g/cc;wherein said mixture has a melt index from about 0.5 to about 4 grams/10 minutes;wherein the water vapor transmission rate of said polyethylene film is improved, by being from about 19 percent lower to about 25 percent lower relative to a control polyethylene film of the same composition but not containing said nucleating agent, and;wherein melt index is measured according to ASTM D1238 (2.16 kg load and 190° C.), density is measured ...

POLYAMIDE-IMIDE PRECURSOR, POLYAMIDE-IMIDE FILM AND DISPLAY DEVICE COMPRISING SAME

This invention relates to a polyamide-imide precursor, a polyamide-imide obtained by imidizing the same, a polyamide-imide film, and an image display device including the film. The polyamide-imide precursor includes, in a molecular structure thereof, a first block, obtained by copolymerizing monomers including dianhydride and diamine, and a second block, obtained by copolymerizing monomers including an aromatic dicarbonyl compound and aromatic diamine. The dianhydride includes biphenyltetracarboxylic acid dianhydride (BPDA) and 2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA), and the diamine includes bistrifluoromethylbenzidine (TFDB). 1. A polyamide-imide precursor comprising:in a molecular structure thereof,a first block obtained by copolymerizing monomers including dianhydride and diamine; anda second block obtained by copolymerizing monomers including an aromatic dicarbonyl compound and aromatic diamine,wherein the dianhydride includes biphenyltetracarboxylic acid dianhydride (BPDA) and 2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA), and the diamine includes bistrifluoromethylbenzidine (TFDB).2. The polyamide-imide precursor of claim 1 , wherein the aromatic dicarbonyl compound for forming the second block is one or more selected from the group consisting of terephthaloyl chloride (p-terephthaloyl chloride claim 1 , TPC) claim 1 , iso-phthaloyl dichloride claim 1 , and 4 claim 1 ,4′-benzoyl dichloride (4 claim 1 ,4′-benzoyl chloride).3. The polyamide-imide precursor of claim 1 , wherein the aromatic diamine for forming the second block is one or more selected from the group consisting of 2 claim 1 ,2-bis(4-(4-aminophenoxy)phenyl)hexafluoropropane (HFB APP) claim 1 , bis(4-(4-aminophenoxy)phenyl)sulfone (BAPS) claim 1 , bis(4-(3-minophenoxy)phenyl)sulfone (BAPSM) claim 1 , 4 claim 1 ,4′-diaminodiphenylsulfone (4DDS) claim 1 , 3 claim 1 ,3′-diaminodiphenylsulfone (3DDS) claim 1 , 2 claim 1 ,2-bis(4-(4-aminophenoxy)phenylpropane (BAPP ...

POLYAMIDE-IMIDE PRECURSOR, POLYAMIDE-IMIDE FILM, AND DISPLAY DEVICE COMPRISING SAME

The present invention relates to a polyamide-imide precursor, a polyamide-imide obtained by imidizing the same, a polyamide-imide film, and an image display device including the film. The polyamide-imide precursor includes, in a molecular structure thereof, a first block, obtained by copolymerizing monomers including dianhydride and diamine, a second block, obtained by copolymerizing monomers including an aromatic dicarbonyl compound and the diamine, and a third block, obtained by copolymerizing monomers including the aromatic dicarbonyl compound and aromatic diamine. The dianhydride for forming the first block includes 2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA), and the diamine for forming the first block and the second block includes 9,9-bis(3-fluoro-4-aminophenyl)fluorene (FFDA). 1. A polyamide-imide precursor comprising:in a molecular structure thereof, a first block obtained by copolymerizing monomers including dianhydride and diamine;a second block obtained by copolymerizing monomers including an aromatic dicarbonyl compound and the diamine; anda third block obtained by copolymerizing monomers including the aromatic dicarbonyl compound and aromatic diamine,wherein the dianhydride for forming the first block includes 2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA), and the diamine for forming the first block and the second block includes 9,9-bis(3-fluoro-4-aminophenyl)fluorene (FFDA).2. The polyamide-imide precursor of claim 1 , wherein the aromatic dicarbonyl compound for forming the second block and the third block is one or more selected from the group consisting of terephthaloyl chloride (p-terephthaloyl chloride claim 1 , TPC) claim 1 , terephthalic acid claim 1 , iso-phthaloyl dichloride claim 1 , and 4 claim 1 ,4′-benzoyl dichloride (4 claim 1 ,4′-benzoyl chloride).3. The polyamide-imide precursor of claim 1 , wherein the aromatic diamine for forming the third block is one or more selected from the group consisting of 2 ...

POLYIMIDE RESIN COMPOSITION, METHOD FOR PRODUCING SAME, AND POLYIMIDE FILM

Provided is a polyimide resin composition and a production method thereof, wherein the polyimide resin composition contains an alicyclic polyimide resin having a structural unit represented by the following general formula (1) and inorganic particles of at least one selected from the group consisting of titanium dioxide, barium titanate, and zirconium oxide, wherein the alicyclic polyimide resin has a glass transition temperature of 260° C. or higher, 2. The polyimide resin composition according to claim 1 ,wherein a polyimide film with a thickness of 1 μm of the polyimide resin composition has a total light transmittance of 75% or greater.3. The polyimide resin composition according to claim 1 ,wherein a tetracarboxylic acid component of the alicyclic polyimide resin is derived from a tetracarboxylic acid selected from the group consisting of 1,2,3,4-cyclobutanetetracarboxylic acid, 1,2,4,5-cyclopentanetetracarboxylic acid, 1,2,4,5-cyclohexanetetracarboxylic acid, bicyclo[2.2.2]octa-7-en-2,3,5,6-tetracarboxylic acid, dicyclohexyltetracarboxylic acid, and regioisomers thereof.5. The polyimide resin composition according to claim 1 ,wherein a diamine component of the alicyclic polyimide resin is derived from a diamine selected from the group consisting of 1,4-bis(4-amino-α,α-dimethylbenzyl)benzene, 4,4′-bis(4-aminophenoxy)biphenyl, 5-amino-1,3,3-trimethyl-1-(4-aminophenyl)-indane, 6-amino-1,3,3-trimethyl-1-(4-aminophenyl)-indane, 2,2′-dimethylbenzidine, and 2,2′-bis(trifluoromethyl)benzidine.7. The method for producing a polyimide resin composition according to claim 6 ,wherein a solvent of the polyimide resin solution is one or more selected from the group consisting of N-methyl-2-pyrrolidone, N,N-dimethylacetamide, γ-butyrolactone, N,N-dimethylformamide, dimethyl sulfoxide, hexamethylphosphoramide, tetramethylene sulfone, p-chlorophenol, m-cresol, 2-chloro-4-hydroxytoluene, and 1,3-dioxolane.8. The method for producing a polyimide resin composition according to ...

LIQUID CRYSTAL POLYMER RESIN COMPOSITION FOR OUTER PLATE AND OUTER PLATE

A liquid crystal polymer resin composition for an outer plate includes a liquid crystal polymer and a plate-shaped filler, in which the amount of the plate-shaped filler is 20 parts by mass or more and 70 parts by mass or less with respect to 100 parts by mass of the liquid crystal polymer. 1. A liquid crystal polymer resin composition for an outer plate , comprising:a liquid crystal polymer; and a plate-shaped filler,wherein an amount of the plate-shaped filler is 20 parts by mass or more and 70 parts by mass or less with respect to 100 parts by mass of the liquid crystal polymer.2. The liquid crystal polymer resin composition for an outer plate according to claim 1 ,{'sup': '2', 'wherein the composition is used for an outer plate in which a projected area of a maximum surface is 400 cmor more.'}3. The liquid crystal polymer resin composition for an outer plate according to claim 1 ,wherein the composition is used for an outer plate in which an average thickness is 0.03 cm or more and 0.5 cm or less.4. The liquid crystal polymer resin composition for an outer plate according to claim 1 ,{'sup': '2', 'wherein the composition is used for an outer plate in which a ratio of a projected area of a maximum surface (unit: cm) to an average thickness (unit: cm) is 8,000 or more.'}5. An outer plate that is an injection-molded body for which the liquid crystal polymer resin composition for an outer plate according to is used as a forming material.6. An outer plate comprising claim 1 , as forming materials:a liquid crystal polymer; anda plate-shaped filler,wherein an amount of the plate-shaped filler is 20 parts by mass or more and 70 parts by mass or less with respect to 100 parts by mass of the liquid crystal polymer.7. The outer plate according to claim 6 ,{'sup': '2', 'wherein a projected area of a maximum surface is 400 cmor more.'}8. The outer plate according to claim 6 ,wherein an average thickness is 0.03 cm or more and 0.5 cm or less.9. The outer plate according to ...

BIAXIALLY-STRETCHED FILM AND ETHYLENE POLYMER COMPOSITION

Provided is a biaxially-stretched film wherein the biaxial stretching is possible in a broader temperature range and which is excellent in thickness accuracy, and an ethylene polymer composition serving as a raw material of the film. The biaxially-stretched film of the present invention is obtained from an ethylene polymer composition (E) including a specific ethylene polymer component (A) containing 20 to 100 wt % of an ethylene polymer (a) being a copolymer of ethylene and a C4-10 α-olefin and having specific melt flow rate and density, and an ethylene polymer component (B) being another copolymer of ethylene and a C4-10 α-olefin, wherein a weight fraction [W] of the ethylene polymer component (A) is 0.50 or more and 0.92 or less, and a weight fraction [W] of the ethylene polymer component (B) is 0.08 or more and 0.50 or less provided that Wand Wtotal 1.0. 16-. (canceled)7. A biaxially-stretched film obtained from an ethylene polymer composition (E) comprising an ethylene polymer component (A) fulfilling requirements described below and an ethylene polymer component (B) fulfilling requirements described below ,{'sub': A', 'B', 'A', 'B, 'wherein a weight fraction [W] of the ethylene polymer component (A) is 0.50 or more and 0.87 or less, and a weight fraction [W] of the ethylene polymer component (B) is 0.13 or more and 0.50 or less provided that Wand Wtotal 1.0,'}wherein the ethylene polymer component (A) comprises an ethylene polymer (a) described below at 20% by weight or more and 100% by weight or less and fulfills requirements (A-1) to (A-3) described below:{'sub': 'A', '(A-1) Melt flow rate (MFR) at 190° C. under a load of 2.16 kg is not less than 0.1 g/10 min and not more than 3 g/10 min;'}{'sub': 'A', 'sup': 3', '3, '(A-2) Density (D) is 907 kg/mor more and 940 kg/mor less; and'}{'sup': 0.776', '0.776', '−4', '−4, '(A-3) Ratio [η]/Mwof intrinsic viscosity measured in decalin at 135° C. [[η] (dl/g)] to weight average molecular weight measured by GPC- ...

TRANSPARENT POLYESTER FILM WITH LOW VISIBLE LIGHT TRANSMITTANCE AND HIGH INFRARED-BLOCKING RATE AND METHOD FOR MAKING THE SAME

A transparent polyester film has low visible light transmittance of 5-50% by JIS K7705 testing standard and a high infrared-blocking rate of at least 90% by JIS R3106 testing standard, which is extruded from a kind of polyester resins obtained from 5-40 wt % of nanoparticle-based thermal insulation slurry and/or 0.005-0.1 wt % of nanoparticle-based black pigment slurry by weight of and to react with the polymerization materials to completely perform an esterification and a polycondensation, wherein the thermal insulation nanoparticle has a chemical formula of CsNWOClwith an average particle size of 10-90 nm and the nanoparticle-based black contains carbon black particles having a particle size of 20-80 nm. 1. A method for making a transparent polyester film with low visible light transmittance and a high infrared-blocking rate as well as has a common film thickness ranged from 12 to 75 μm , comprising the steps of: [{'sub': X', 'Y', '3-Z', 'C, 'a1) 10-50 wt % of thermal insulation particles, based on the total weight of the thermal insulation slurry; and the thermal insulation particles having a chemical formula of CsNWOClwith an average particle size of 10-90 nm,'}, {'br': None, 'X≦1.0; Y≦1.0; Y/X≦1.0; Z≦0.6, and C≦0.1;'}, 'wherein Cs is cesium; N is tin (Sn), antimony (Sb), or bismuth (Bi); W is tungsten; O is oxygen; and X, Y, Z, and C are positive numbers satisfying the following conditions], 'a) preparing a nanoparticle-based thermal insulation slurry with a viscosity of 50-200 cps, wherein the thermal insulation slurry comprises the following ingredients a1)-a3) to add up to 100% 'a3) 5-40 wt % of a dispersing aid, based on the total weight of the thermal insulation slurry; wherein the dispersing aid is one or more selected from the group consisting of an anionic dispersant, a non-ionic dispersant and a polymeric dispersant;', 'a2) 30-70 wt % of ethylene glycol, based on the total weight of the thermal insulation slurry; and'} b1) 5-25 wt % of carbon black ...

Bioplastic Composition Comprising Wheat Bran and Bioplastic Film Using the Same

The present invention relates to a bioplastic composition comprising wheat bran that is a food byproduct and a bioplastic pellet/film using the same. More particularly, the present invention relates to a bioplastic composition comprising wheat bran and a bioplastic film using the same in which the properties of the composition are enhanced to secure the improved properties of the bioplastic film prepared from it, thereby showing a carbon reduction effect and providing a substitute for the conventional petroleum-derived bioplastic products. 1. A bioplastic composition comprising a polyolefin resin , wheat bran , a wax , an inorganic filler , and a surfactant.2. The bioplastic composition as claimed in claim 1 , wherein the polyolefin resin is at least one selected from the group consisting of polyethylene (PE) claim 1 , polypropylene (PP) claim 1 , polybutylene claim 1 , and polymethylpentene.3. The bioplastic composition as claimed in claim 1 , wherein the polyolefin resin is contained in an amount of 40 to 70 wt. % in the composition.4. The bioplastic composition as claimed in claim 1 , wherein the wheat bran has a size of 5 to 30 μm.5. The bioplastic composition as claimed in claim 1 , wherein the wheat bran has a polydispersity index (PDI) of 2 or less.6. The bioplastic composition as claimed in claim 1 , wherein the wheat bran has a water content of 1 to 10%.7. The bioplastic composition as claimed in claim 1 , wherein the wheat bran is contained in an amount of 10 to 30 wt. % in the composition.8. The bioplastic composition as claimed in claim 1 , wherein the wax is at least one selected from the group consisting of paraffin wax claim 1 , liquid paraffin wax claim 1 , beeswax claim 1 , montan wax claim 1 , candelilla wax claim 1 , polyethylene wax claim 1 , and polypropylene wax claim 1 ,wherein the wax is contained in an amount of 10 to 20 wt. % in the composition.9. The bioplastic composition as claimed in claim 1 , wherein the inorganic filler is at least ...

THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE

The present invention relates to a thermoplastic resin composition and a molded article manufactured thereofrom. In accordance with the present invention, a thermoplastic resin composition providing higher chemical resistance with respect to a blowing agent while providing the same impact strength, gloss, and vacuum moldability as existing resin compositions when used to produce an inner case of a refrigerator, and a molded article manufactured from the same are provided. 1. A thermoplastic resin composition , comprising:100 parts by weight of a base resin that comprises greater than 0% by weight to 35% by weight of a diene-based graft copolymer, greater than 0% by weight to 30% by weight of an acrylic graft copolymer, and 35 to 85% by weight of a copolymer of a vinyl cyanide compound and an aromatic vinyl compound; andgreater than 1 part by weight of a polyester-based elastomer having a melt index of 0.1 to 10 g/10 min (230° C., 2.16 kg).2. The thermoplastic resin composition according to claim 1 , wherein the diene-based graft copolymer is a copolymer prepared by graft polymerizing 30 to 70% by weight of a diene-based rubbery polymer; and 30 to 70% by weight of a sum of an aromatic vinyl compound and a vinyl cyanide compound claim 1 ,wherein the vinyl cyanide compound is comprised in an amount of 20 to 40% by weight based on 100% by weight of a total of the compounds.3. The thermoplastic resin composition according to claim 2 , wherein the diene-based rubbery polymer has an average particle diameter of 0.2 to 0.4 μm.4. The thermoplastic resin composition according to claim 1 , wherein the acrylic graft copolymer is a copolymer prepared by graft polymerizing 30 to 70% by weight of an acrylic rubbery polymer; and 30 to 70% by weight of a sum of the aromatic vinyl compound and the vinyl cyanide compound claim 1 ,wherein the vinyl cyanide compound is comprised in an amount of 20 to 40% by weight based on 100% by weight of a total of the compounds.5. The thermoplastic ...

POLYIMIDE DRY FILM AND APPLICATION THEREOF

A polyimide dry film including a carrier and a polyimide layer and a method of using the same are provided. The polyimide layer contains (a) a polyimide precursor or soluble polyimide and (b) a solvent. The solvent includes a hydrophilic solvent and a hydrophobic solvent and a weight ratio of the hydrophilic solvent to the hydrophobic solvent is in the range of about 0.05 to about 2. The polyimide dry film of the present invention has water absorbability, is relatively stable even in the presence of water, and has a non-sticky surface. The resulting polyimide has excellent physical properties and can be used in a process in which water or an aqueous solution is involved to form a coverlay with excellent physical properties. 2. The dry film according to claim 1 , wherein the weight ratio of the hydrophilic solvent to the hydrophobic solvent is in the range of about 0.1 to about 1.3. The dry film according to claim 1 , wherein the weight ratio of the hydrophilic solvent to the hydrophobic solvent is in the range of about 0.25 to about 0.8.4. The dry film according to claim 1 , wherein the content of the solvent is in the range of about 30 wt % to about 70 wt % claim 1 , based on the total weight of the polyimide layer.5. The dry film according to claim 1 , wherein the hydrophilic solvent comprises dimethyl sulfoxide claim 1 , diethyl sulfoxide claim 1 , N claim 1 ,N-dimethyl-formamide claim 1 , N claim 1 ,N-diethyl-formamide claim 1 , N claim 1 ,N-dimethylacetamide claim 1 , N claim 1 ,N-diethylacetamide claim 1 , N-methyl-2-pyrrolidone claim 1 , N-ethyl-2-pyrrolidone claim 1 , N-propyl-pyrrolidone claim 1 , N-propyl-2-pyrrolidone claim 1 , phenol claim 1 , o-cresol claim 1 , m-cresol claim 1 , p-cresol claim 1 , xylenol claim 1 , halogenated phenol claim 1 , pyrocatechol claim 1 , tetrahydrofuran claim 1 , dioxane claim 1 , dioxolane claim 1 , propylene glycol monomethyl ether claim 1 , tetraethylene glycol dimethyl ether claim 1 , 2-butoxyethanol claim 1 , γ- ...

Optical Film

Provided are an optical film using a cellulose derivative, useful in an image display device, such as a liquid crystal display or the like, a retardation film and a polarization film using the optical film, and a liquid crystal display having excellent view angle characteristics by using these films, while the optical film uses a cellulose derivative resin in which some hydrogen atoms of hydroxy groups of cellulose are substituted with three or more kinds of substituents.

Polymeric Sheet Useful for Application to Concave Surface Topographies of Articles and Related Methods

Polymeric sheets of the invention comprise sequential layers as follows: a topcoat layer, a polyurethane-based carrier layer, and an adhesive layer. The polyurethane-based carrier layer is formed using essentially no chain extender having a molecular weight of 350 grams/mole or less, resulting in a relatively low storage modulus polymeric sheet. Such polymeric sheets are particularly useful for application to surfaces having a concave topography. 1. A polymeric sheet comprising sequential layers as follows:a topcoat layer;a polyurethane-based carrier layer, wherein essentially no chain extender having a molecular weight of 350 grams/mole or less is used in formation of the polyurethane-based carrier layer; andan adhesive layer.2. The polymeric sheet of claim 1 , wherein the adhesive layer comprises a pressure-sensitive adhesive.3. The polymeric sheet of claim 1 , further comprising a release film on an exterior surface of the adhesive layer.4. The polymeric sheet of claim 1 , further comprising a carrier film on an exterior surface of the topcoat layer.5. The polymeric sheet of claim 1 , wherein the carrier layer is in-situ polymerized.6. The polymeric sheet of claim 1 , wherein essentially no butane diol is used in formation of the polyurethane-based carrier layer.7. The polymeric sheet of claim 1 , wherein essentially no polyols having a molecular weight of 1 claim 1 ,000 grams/mole or greater are used in formation of the polyurethane-based carrier layer.8. The polymeric sheet of claim 1 , wherein each polyol used in formation of the polyurethane-based carrier layer has a molecular weight between about 350 grams/mole and about 1 claim 1 ,000 grams/mole.9. The polymeric sheet of claim 1 , wherein each polyol used in formation of the polyurethane-based carrier layer has a molecular weight between about 350 grams/mole and about 450 grams/mole.10. The polymeric sheet of claim 1 , wherein the only polyol used in formation of the polyurethane-based carrier layer is a ...

FILM OR SHEET, AND SCREEN

To provide a film or sheet and a screen excellent in visibility of a projected image, in see-through properties when an image is not projected and in bending resistance. A single-layer film or sheet comprising a fluororesin, a light-scattering agent and a light absorbing agent, characterized in that the light-scattering agent is at least one light-scattering agent selected from the group consisting of a titanium oxide-containing pigment, a zinc oxide-containing pigment and a cerium oxide-containing pigment, and the content thereof is from 0.01 to 0.175 g/m, and the light absorbing agent is at least one light absorbing agent selected from the group consisting of carbon black, a black interference aluminum pigment, black iron oxide and titanium black, and the content thereof is from 0.0005 to 0.035 g/m. 1. A film or sheet which is a single layer film or sheet comprising a fluororesin , a light scattering agent and a light absorbing agent , and which is characterized in that{'sup': '2', 'the light-scattering agent is at least one light-scattering agent selected from the group consisting of a titanium oxide-containing pigment, a zinc oxide-containing pigment and a cerium oxide-containing pigment, and the content thereof is from 0.01 to 0.175 g/m, and'}{'sup': '2', 'the light absorbing agent is at least one light absorbing agent selected from the group consisting of carbon black, a black interference aluminum pigment, black iron oxide and titanium black, and the content thereof is from 0.0005 to 0.035 g/m.'}2. The film or sheet according to claim 1 , wherein the titanium oxide-containing pigment is a composite having part or all of the surface of titanium oxide particles coated with at least one of coating materials selected from the group consisting of silicon oxide claim 1 , aluminum oxide claim 1 , talc claim 1 , zirconium oxide claim 1 , calcium carbonate claim 1 , barium sulfate claim 1 , aluminum hydroxide claim 1 , magnesium hydroxide claim 1 , boehmite claim 1 , ...

CONDUCTIVE FILM, METHOD FOR PRODUCING SAME, CONDUCTOR, RESIST PATTERN FORMATION METHOD, AND LAMINATE

The conductive film of the present invention includes a conductive polymer (A) and has a film thickness of 35 nm or less, wherein: a surface resistance of the conductive film is 1×10Ω/sq. or less, and a standard deviation of current that flows through the conductive film upon application of voltage to the conductive film is 5 or less. The conductor of the present invention has a substrate, and the conductive film provided on at least a part of the surface of the substrate. The resist pattern forming method of the present invention includes a lamination step of forming the conductive film on a surface of a resist layer including a chemically amplified resist, said resist layer formed on one surface of a substrate, and an exposure step of irradiating the substrate with an electron beam according to a pattern on its side on which the conductive film is formed. The laminate of the present invention has a resist layer and an antistatic film formed on the surface of the resist layer, wherein the antistatic film is the above-mentioned conductive film. 1. A conductive film comprising a conductive polymer (A) and having a film thickness of 35 nm or less , wherein:{'sup': '11', 'a surface resistivity of the conductive film is 1×10Ω/sq. or less, and'}a standard deviation of current that flows through the conductive film upon application of voltage to the conductive film is 5 or less.2. The conductive film according to claim 1 , which further comprises a basic compound (B).3. The conductive film according to claim 1 , which further comprises a surfactant.4. The conductive film according to claim 2 , which further comprises a surfactant.5. The conductive film according to claim 1 , wherein the conductive polymer (A) has an acidic group.6. The conductive film according to claim 2 , wherein the conductive polymer (A) has an acidic group.7. The conductive film according to claim 3 , wherein the conductive polymer (A) has an acidic group.11. The conductive film according to claim 1 ...

METHOD FOR MANUFACTURING ELECTRONIC COMPONENT, RESIN COMPOSITION FOR TEMPORARY PROTECTION, AND RESIN FILM FOR TEMPORARY PROTECTION

The present invention relates to a method for manufacturing an electronic component having an electromagnetic shield, comprising: a bonding step of bonding a temporary protective material on a workpiece with unevenness on the surface thereof; a photocuring step of curing the temporary protective material by light irradiation; a icing step of singulating the workpiece and the temporary protective material; a shielding step of forming a metal film on the portion of the singulated workpiece, the portion having no temporary protective material bonded thereon; and a peeling step of peeling the temporary protective material from the workpiece having the metal film formed, wherein the temporary protective material is formed from a resin composition for temporary protection with an elastic modulus at 25° C. of 3 MPa or less and an elastic modulus at 25° C. of 40 MPa or more after light irradiation with an exposure dose of 500 mJ/cmor more. 1. A method for manufacturing an electronic component having an electromagnetic shield , the method comprising:a bonding step of bonding a temporary protective material on a workpiece with unevenness on the surface thereof;a photocuring step of curing the temporary protective material by light irradiation;a dicing step of singulating the workpiece and the temporary protective material;a shielding step of forming a metal film on a portion of the singulated workpiece, the portion having no temporary protective material bonded thereon; anda peeling step of peeling the temporary protective material from the workpiece having the metal film formed,{'sup': '2', 'wherein the temporary protective material is formed from a resin composition for temporary protection with an elastic modulus at 25° C. of 3 MPa or less and an elastic modulus at 25° C. of 40 MPa or more after light irradiation with an exposure dose of 500 mJ/cmor more.'}2. The method according to claim 1 , wherein the resin composition has a tack force of 1 to 5 N as measured at 25° C. ...

Polyethylene and Method for Preparing the Same

In the present disclosure, there are provided a polyethylene having improved low-temperature sealing properties with an increase in the content and molecular weight of a low crystalline polymer, and a method for preparing the same. 1. A polyethylene comprising an ethylene repeating unit and an α-olefin-based repeating unit ,{'sup': '3', 'wherein the polyethylene has a density of 0.916 g/cmor more, measured according to ASTM D1505, and has three elution temperatures of Te1, Te2, and Te3 corresponding to elution temperatures of first to third semicrystalline polymer fractions contained in the polyethylene, respectively, in a temperature range of 20 to 120° C. when analyzed by temperature rising elution fractionation (TREF),'}wherein Te2 is lower than Te3 and higher than Te1,Te1 is 25 to 30° C., andthe first semicrystalline polymer fraction has a weight average molecular weight of 200,000 g/mol or more, and is contained in an amount of 5 wt % or more based on a total weight of the polyethylene.2. The polyethylene of claim 1 , wherein the first semicrystalline polymer fraction has a weight average molecular weight of 200 claim 1 ,000 to 500 claim 1 ,000 g/mol claim 1 , and is contained in an amount of 10 to 20 wt % based on a total weight of the polyethylene.3. The polyethylene of claim 1 , wherein Te2 is 40 to 65° C. claim 1 , and Te3 is 80 to 100° C.4. The polyethylene of claim 1 , wherein the polyethylene has an average number of short chain branches per 1000 carbons of 35 or more in the polymer in a high-molecular weight region having log Mw of 5.5 or more claim 1 , when analyzed by gel permeation chromatography combined with Fourier transform infrared spectroscopy.5. The polyethylene of claim 1 , wherein an average number of short chain branches per 1000 carbons in the polyethylene is 18 to 22.6. The polyethylene of claim 1 , wherein the polyethylene has a molecular weight distribution of 3 or less.7. The polyethylene of claim 1 , wherein the polyethylene has a ...

POLYIMIDE FILM COMPRISING AT LEAST TWO FILLERS HAVING DIFFERENT DIAMETERS, AND ELECTRONIC DEVICE COMPRISING SAME

The present invention provides a polyimide film comprising an inorganic filler, which comprises a first filler group having a diameter (D50) of 2-2.7 μm and a second filler group having an average diameter (D50) of 1-1.7 μm, wherein the polyimide film satisfies relation 1: 0.7≤(D90−D10)/(D50)≤1.2, which is about the respective diameters of the first filler group and the second filler group. 1. A polyimide film , comprising a base film made of polyimide , and inorganic fillers dispersed in the base film ,wherein the polyimide film has a modulus of 3.5 GPa or less,the inorganic fillers include a first filler group having an average particle diameter (D50) falling within the range of 2 μm to 2.7 μm and a second filler group having an average particle diameter (D50) falling within the range of 1 μm to 1.7 μm, and {'br': None, 'i': D', 'D', 'D, '0.7≤(90−10)/50≤1.2\u2003\u2003(1).'}, 'each of the first filler group and the second filler group satisfies the following relational expression 1 for particle diameters2. The polyimide film of claim 1 , wherein the first filler group is included in an amount of 60% to 80% by weight and the second filler group is included in an amount of 20% to 40% by weight claim 1 , based on the total weight of the inorganic fillers.3. The polyimide film of claim 1 , wherein the inorganic fillers further include a third filler group having an average particle diameter (D50) falling within the range of 0.3 μm to 0.6 μm and satisfying the relational expression 1.4. The polyimide film of claim 3 , wherein the third filler group is included in an amount of 5% by weight or more to less than 20% by weight claim 3 , based on the total weight of the inorganic fillers.5. The polyimide film of claim 1 , wherein the inorganic filler is one or more selected from the group consisting of silica claim 1 , calcium phosphate claim 1 , calcium carbonate claim 1 , and barium sulfate.6. The polyimide film of claim 5 , wherein the inorganic filler is spherical ...

Shape-Memory-Self-Healing Polymers (SMSHPS)

A shape-memory self-healing polymeric network (SMSHP) is useful as a molded part, a coating, or as a matrix for a composite that can be repaired by heating to a controlled temperature. The SMSHP has thermally reversible repeating units where a thermally reversible adduct is situated between two common linking units formed during a polymerization process between thermally reversible monomers and cross-linking monomers. Optionally, other repeating units can be present from other monomers. Shape-memory results when the SMSHP is warmed to a temperature in excess of its glass transition temperature and self-healing then proceeds when a higher temperature is achieved where thermally reversible adducts dissociates to complementary groups that subsequently reform the adduct without distortion of the memorized shape. The thermally reversible adducts can be Diels-Alder (DA) adducts in a polyurethane, poly urea, or amine epoxy SMSHP network. 1. A shape-memory self-healing polymeric network (SMSHP) , comprising:thermally reversible repeating units comprising a Diels-Alder (DA) adduct between two linking units to other repeating units of the SMSHP, wherein the linking units are urethane units and/or urea units;optionally, one or more other repeating units lacking the DA adduct between two of the linking units; and{'sub': g', 'g, 'cross-linking repeating units lacking a thermally reversible unit; wherein the cross-linking units connect three or more chains by the linking units, wherein the majority of the chains comprise at least one of the thermally reversible units, wherein a glass transition temperature (T) of the SMSHP is below an onset temperature where the thermally reversible adduct cleaves to two complementary functionalities, and wherein at temperatures between the Tand the onset temperature form the thermally reversible adduct.'}2. The SMSHP of claim 1 , wherein the thermally reversible repeating unit is derived from the DA adduct of maleimide and furan.3. The SMSHP of ...

ANTIFOULING FILM EQUIPPED WITH PROTECTIVE FILM AND METHOD FOR MANUFACTURING SAME

[PROBLEM] To provide an antifouling film equipped with protective film having an antifouling layer with excellent antifouling characteristics even after aging, and to a method for manufacturing same. [SOLUTION MEANS] An antifouling film equipped with protective film in which protective film is laminated on an antifouling layer of an antifouling film having an antifouling layer on a substrate film X, the antifouling film equipped with protective film being such that, when the protective film is detached from the antifouling film, a contact angle of water with respect to a surface of the protective film that had been in contact with the antifouling layer of the antifouling film is 90° to 115°. And also a method for manufacturing the aforementioned antifouling film equipped with protective film in which aging is carried out under certain temperature conditions while the protective film is laminated to a surface of the antifouling layer. 1. An antifouling film equipped with protective film in which protective film is laminated on an antifouling layer of an antifouling film having the antifouling layer on a substrate film X , the antifouling film equipped with protective film being such that , when the protective film is detached from the antifouling film , a contact angle of water with respect to a surface of the protective film that had been in contact with the antifouling layer of the antifouling film is 90° to 115°.2. The antifouling film equipped with protective film according to wherein the antifouling layer of the antifouling film comprises silicone-type resin and/or fluorine-type resin as primary constituent.3. The antifouling film equipped with protective film according to wherein a surface of the protective film that comes in contact with the antifouling layer of the antifouling film satisfies FORMULA 1;{'br': None, 'i': a', 'b|≤, 'wherein FORMULA 1 is |-10(°);'}wherein a is a contact angle (°) of water with respect to a surface of the protective film that will ...

FLAME RETARDANT COMPOUND, METHOD OF MAKING THE SAME, RESIN COMPOSITION AND ARTICLE MADE THEREFROM

A compound has a structure of Formula (I) below, wherein E represents a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide functional group or a diphenylphosphine oxide functional group. Moreover, a method of making the compound of Formula (I), a resin composition including the compound of Formula (I) and a resin additive and an article made from the resin composition are described. The article includes a prepreg, a resin film, a laminate or a printed circuit board, wherein one or more properties including copper foil peeling strength, Z-axis ratio of thermal expansion, glass transition temperature, flame retardancy, thermal resistance after moisture absorption, dielectric constant, and dissipation factor may be improved. 3. A method of making the compound of claim 1 , comprising: reacting a diphenyldivinylsilane with a 9 claim 1 ,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide or a diphenylphosphine oxide compound.4. The method of claim 3 , wherein a molar ratio of a reactive functional group of the diphenyldivinylsilane to a reactive functional group of the 9 claim 3 ,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide or a reactive functional group of the diphenylphosphine oxide compound is between 1:1 and 1:6.5. A resin composition comprising the compound of Formula (I) as claimed in and a resin additive.6. The resin composition of claim 5 , wherein the resin additive comprises a vinyl-containing resin claim 5 , a styrene maleic anhydride resin claim 5 , an epoxy resin claim 5 , a phenolic resin claim 5 , a benzoxazine resin claim 5 , a cyanate ester resin claim 5 , a polyester resin claim 5 , a polyamide resin claim 5 , a polyimide resin or a combination thereof.7. The resin composition of claim 6 , wherein the vinyl-containing resin comprises a vinyl-containing polyphenylene ether resin claim 6 , a maleimide resin claim 6 , a maleimide triazine resin claim 6 , a polyolefin resin claim 6 , styrene claim 6 , divinylbenzene claim 6 , bis(vinylbenzyl) ether claim 6 ...

POLYAMIDE RESIN, AND POLYMER FILM, RESIN LAMINATE USING THE SAME

The present invention relates to a polyamide resin in which an average particle size of individual crystals measured by a small-angle X-ray scattering apparatus is 8.0 nm or less, and a polymer film and resin laminate using the same. 1. A polyamide resin having an average particle size of individual crystals measured by a small-angle X-ray scattering apparatus is 8.0 nm or less.2. The polyamide resin according to claim 1 , whereinthe average particle size of the individual crystals is measured through an analytical equipment by fitting a scattering pattern obtained by irradiating X-rays with energies of 10 KeV to 20 KeV in the small-angle X-ray scattering apparatus to a solid sphere model.3. The polyamide resin according to claim 1 , whereinamorphous polymer chains are present between the individual crystals having the average particle size of 8.0 nm or less.4. The polyamide resin according to claim 3 , whereina distance between the individual crystals having the average particle size of 8.0 nm or less is 0.1 nm to 100 nm.5. The polyamide resin according to claim 1 , whereinthe individual crystals having the average particle size of 8.0 nm or less comprises a first aromatic polyamide repeating unit derived from a combination of a 1,4-aromatic diacyl compound and an aromatic diamine compound.6. (canceled)7. The polyamide resin according to claim 3 , whereinthe amorphous polymer chain comprises a second aromatic amide repeating unit derived from a combination of a 1,2-aromatic diacyl compound and an aromatic diamine compound, or a third aromatic amide repeating unit derived from a combination of a 1,3-aromatic diacyl compound and an aromatic diamine compound.8. (canceled)10. The polyamide resin according to claim 9 , whereinthe first polyamide segment has a number average molecular weight of 100 g/mol to 5000 g/mol.11. The polyamide resin according to claim 7 , whereinthe polyamide resin includes 40 mol % to 95 mol % of the first polyamide segment based on the total ...

CELLULOSE ESTER AND IMPACT MODIFIER COMPOSITIONS AND ARTICLES MADE USING THESE COMPOSITIONS

A cellulose ester composition is provided comprising at least one cellulose ester and at least one impact modifier and optionally at least one plasticizer. Processes for producing the cellulose ester compositions as well as articles made using these compositions, such as eyeglass frames, automotive parts, and toys are also provided. 120-. (canceled)21. A cellulose ester composition comprising 55 to 99 wt % of at least one cellulose ester , 1 to 30 wt % of at least one impact modifier , and 1 to 15 wt % of at least one plasticizer , based on the total weight of the composition , wherein the at least one cellulose ester is a cellulose acetate , wherein the composition has an HDT value greater than 95° C. , and a notched Izod impact strength value greater than 80 J/m measured according to ASTM D256 on 3.2 mm thick bars at 23° C. , after conditioning the bars at 230° C. and 50% RH for 48 hours.22. The cellulose ester composition of claim 21 , wherein the cellulose acetate has an absolute weight average molecular weight of 5000-40000.23. The cellulose ester composition of claim 21 , wherein the cellulose acetate has an absolute weight average molecular weight of 70000-120000.24. The cellulose ester composition according to claim 21 , wherein said composition comprises plasticizer selected from the group consisting of triacetin claim 21 , trimethyl phosphate claim 21 , triethyl phosphate claim 21 , tributyl phosphate claim 21 , triphenyl phosphate claim 21 , triethyl citrate claim 21 , acetyl trimethyl citrate claim 21 , acetyl triethyl citrate claim 21 , acetyl tributyl citrate claim 21 , tributyl-o-acetyl citrate claim 21 , dibutyl phthalate claim 21 , diaryl phthalate claim 21 , diethyl phthalate claim 21 , dimethyl phthalate claim 21 , di-2-methoxyethyl phthalate claim 21 , di-octyl phthalate claim 21 , di-octyl adipate claim 21 , dibutyl tartrate claim 21 , ethyl o-benzoylbenzoate claim 21 , ethyl phthalyl ethyl glycolate claim 21 , methyl phthalyl ethyl glycolate ...

Ethylene-Based Interpolymers and Processes to Make the Same

Ethylene-based interpolymers, e.g., ethylene-acrylic acid copolymers, are made by a process comprising the steps of: 115-. (canceled)16. An ethylene-based interpolymer comprising at least one comonomer that comprises at least one ethylenic unsaturation and at least one carbonyl group , and wherein the interpolymer comprises at least one the following properties:{'sup': '2', 'A. An average small gel count per 50,000 square inches (in) of less than or equal to 600; and'}{'sup': '2', 'B. An average micro gel count per 50,000 inof less than or equal to 3,500.'}17. The ethylene-based interpolymer of having a percent by weight of acid comonomer units in the polymer chain from 2 to 30.18. The ethylene-based interpolymer of having a molecular weight distribution (MWD claim 16 , Mw/Mn) from 3 to 20.19. The ethylene-based interpolymer of having a molecular weight distribution (MWD claim 17 , Mw/Mn) from 3 to 20.20. The ethylene-based interpolymer of wherein the ethylenic unsaturation of the comonomer is conjugated with the carbonyl group.21. The ethylene-based interpolymer of wherein the comonomer is at least one of an ethylenically unsaturated carboxylic acid claim 16 , anhydride claim 16 , or ester or its salt.22. The ethylene-based interpolymer of wherein the comonomer is acrylic acid or methacrylic acid.23. The ethylene-based interpolymer of wherein the average small gel count per 50 claim 16 ,000 square inches (in) of less than or equal to 300.24. The ethylene-based interpolymer of wherein the average micro gel count per 50 claim 16 ,000 inof less than or equal to 1 claim 16 ,500.25. The ethylene-based interpolymer of wherein the percent by weight of acid comonomer units in the interpolymer chain is from 4 to 15.26. The ethylene-based interpolymer of wherein the molecular weight distribution (MWD claim 16 , Mw/Mn) from 5 to 12.27. The ethylene-based interpolymer of comprising greater than claim 16 , or equal to claim 16 , 1 weight percent of the comonomer based on the ...

FILM

A film obtained by molding a methacrylic resin composition, the methacrylic resin composition comprises: a methacrylic resin having a triad syndiotacticity (rr) of not less than 50% and a weight average molecular weight of 80000 to 200000 and comprising not less than 92% by mass of a structural unit derived from methyl methacrylate, and a polycarbonate resin having an MVR of 130 to 250 cm/20 min at 300° C. and 1.2 Kg, in which a mass ratio of the methacrylic resin to the polycarbonate resin is 91/9 to 99/1, and the total content of the methacrylic resin and the polycarbonate resin is 80 to 100% by mass. The film is layered to at least one surface of a polarizer to give a polarizing plate. 1. A film comprising a methacrylic resin composition , the methacrylic resin composition comprising:a methacrylic resin having a triad syndiotacticity (rr) of not less than 50% and a weight average molecular weight of 80000 to 200000 and comprising not less than 92% by mass of a structural unit derived from methyl methacrylate, and{'sup': '3', 'a polycarbonate resin having an MVR of 130 to 250 cm/10 min at 300° C. and 1.2 Kg;'}in which a mass ratio of the methacrylic resin to the polycarbonate resin is from 91/9 to 99/1, and the total content of the methacrylic resin and the polycarbonate resin is 80 to 100% by mass.2. The film according to claim 1 , having a thickness of 10 to 50 μm.3. The film according to claim 1 , wherein the methacrylic resin has the syndiotacticity (rr) of not less than 58% and not more than 85%.4. The film according to claim 1 , wherein the methacrylic resin comprises not less than 99% by mass of the structural unit derived from methyl methacrylate.5. The film according to claim 1 , the film being a biaxially stretched film having an area based draw ratio of 1.5 to 8.6. A polarizer protective film claim 1 , comprising the film according to .7. A polarizing plate claim 6 , comprising a polarizer and at least one of the polarizer protective film according to ...

POLY(VINYL ALCOHOL) FILM AND PRODUCTION METHOD FOR POLARIZING FILM

A polyvinyl alcohol film comprises a vinyl alcohol-based polymer, wherein, when the polyvinyl alcohol film being measured by a solid echo method using pulse NMR at 60° C. for waveform separation of a free induction decay curve of 1H spin-spin relaxation into three curves derived from three components a component A, a component B, and a component C in order of short relaxation time, the component A has a resulting relaxation time of 0.0070 milliseconds or more and 0.0092 milliseconds or less, and a resulting component ratio of 20% or more and 50% or less. 1. A polyvinyl alcohol film comprising a vinyl alcohol-based polymer ,wherein, when the polyvinyl alcohol film is measured by a solid echo method using pulse NMR at 60° C. for waveform separation of a free induction decay curve of 1H spin-spin relaxation into three curves derived from three components a component A, a component B, and a component C in order of short relaxation time, the component A has a resulting relaxation time of 0.0070 milliseconds or more and 0.0092 milliseconds or less, and a resulting component ratio of 20% or more and 50% or less.2. The polyvinyl alcohol film according to claim 1 , wherein the vinyl alcohol-based polymer has a degree of saponification of 99 mol % or more.3. The polyvinyl alcohol film according to claim 1 , wherein the vinyl alcohol-based polymer has a degree of polymerization of 2000 or more and 4000 or less.4. The polyvinyl alcohol film according to claim 1 , comprising a plasticizer.5. The polyvinyl alcohol film according to claim 1 , for use in a polarizing film.6. A method for manufacturing a polarizing film comprising using the polyvinyl alcohol film according to .7. The method for manufacturing a polarizing film according to claim 6 , comprising steps of dyeing the polyvinyl alcohol film claim 6 , stretching the polyvinyl alcohol film claim 6 , and performing a fixation treatment to the dyed polyvinyl alcohol film.8. The method for manufacturing a polarizing film ...

WATER-SOLUBLE FILM, PRODUCTION METHOD THEREOF, AND CHEMICAL AGENT PACKAGE

A water-soluble film is provided, which is less susceptible to curling even after long-term storage. The water-soluble film includes a polyvinyl alcohol resin (A) , and has a first surface, which has a crystal Unity index Xa, and a second surface, which is opposite to the first surface and has a crystallinity index Xb, where: Xa≥Xb; Xa−Xb is from 0.015 to 0.10; and the crystallinity indexes Xa and Xb are measured through an infrared spectroscopic analysis by an attenuated total reflection method and represented by: ABS/ABS, wherein ABSand ABSare absorbances at wavenumbers of 1141 cmand 1093 cm, respectively. 1. A water-soluble film , comprising a polyvinyl alcohol resin (A) , and having a first surface , which has a crystallinity index Xa , and a second surface , which is opposite to the first surface and has a crystallinity index Xb , Xa≥Xb;', 'a difference Xa−Xb is from 0.015 to 0.10; and', {'br': None, 'sub': 1141', '1093, 'ABS/ABS,'}, 'the crystallinity indexes Xa and Xb are each measured through an infrared spectroscopic analysis by an attenuated total reflection method and represented by, 'wherein:', {'sub': '1141', 'sup': '−1', 'ABSis an absorbance at a wavenumber of 1141 cm; and'}, {'sub': '1093', 'sup': '−1', 'ABSis an absorbance at a wavenumber of 1093 cm.'}], 'wherein2. The water-soluble film according to claim 1 , further comprising a plasticizer (B).3. The water-soluble film according to claim 2 , wherein the plasticizer (B) is present in a proportion of 5 parts by weight or more based on 100 parts by weight of the polyvinyl alcohol resin (A).4. The water-soluble film according to claim 1 , further comprising a filler (C).5. The water-soluble film according to claim 4 , wherein the filler (C) is present in a proportion of 1 to 30 parts by weight based on 100 parts by weight of the polyvinyl alcohol resin (A).61. The water-soluble film according to claim wherein the polyvinyl alcohol resin (A) comprises an anion group-modified polyvinyl alcohol resin (a ...

METHODS FOR ENHANCING THE BONDING STRENGTH OF THERMOSET ADHESIVES AND SEALANTS VIA DISULFIDE DYNAMIC CHEMISTRY

Curable compositions for dynamic epoxy-based thermoset adhesives and/or sealants are provided. Methods of applying the compositions to form strong, low-stress, cured adhesive polymer films are also provided. The cured polymer films use crosslinkers that include disulfide and carbon-nitrogen bonds, wherein the disulfide bonds impart dynamic chemistry to the polymer network structure in order to the achieve adaptable thermoset adhesives and sealants. 2. The composition of claim 1 , wherein the polymer is poly[(phenyl glycidyl ether)-co-formaldehyde].3. The composition of claim 1 , wherein the poly[(phenyl glycidyl ether)-co-formaldehyde] has a number average molecular weight of at least 320.4. The composition of claim 2 , wherein the poly[(phenyl glycidyl ether)-co-formaldehyde] has a number average molecular weight in the range from 320 to 6000.5. The composition of claim 1 , wherein the crosslinker has the structure HN—X—S—S—X—NH claim 1 , wherein X represents an aliphatic or aromatic hydrocarbon group having from one to ten carbon atoms.6. The composition of claim 5 , wherein the crosslinker is cystamine.7. The composition of claim 1 , wherein the at least two reactive amine groups are hydrazine groups.8. The composition of claim 1 , wherein the crosslinker is cystamine.9. The composition of claim 1 , wherein the mole ratio of amine groups on the crosslinker to epoxy groups on the polymer is at least 1:2.11. The polymer film of claim 10 , wherein the polymer is poly[(phenyl glycidyl ether)-co-formaldehyde].12. The polymer film of claim 11 , wherein the poly[(phenyl glycidyl ether)-co-formaldehyde] has a number average molecular weight in the range from 320 to 6000.13. The polymer film of claim 10 , wherein the crosslinker has the structure HN—X—S—S—X—NH claim 10 , wherein X represents an aliphatic or aromatic hydrocarbon group having from one to ten carbon atoms.14. The polymer film of claim 10 , wherein the crosslinker is cystamine.15. The composition of claim 12 ...

PROCESS FOR PREPARING PROPYLENE COPOLYMER COMPOSITIONS

The present invention relates to an olefin polymerization process for producing propylene copolymer composition (P), wherein propylene, Cto Cα-olefin and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst in a multistage polymerization process comprising at least two polymerization reactors, wherein the copolymer composition is bimodal with respect to the content of Cto Cα-olefin and, if present, to ethylene. Further, the invention is directed to the propylene copolymer composition being bimodal with respect to the content of Cto Cα-olefin and optionally to ethylene, and use of said propylene copolymer compositions for producing articles. 1. An olefin polymerization process for producing a propylene copolymer composition (P) , wherein propylene , Cto Cα-olefin and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst in a multistage polymerization process comprising at least two slurry polymerization reactors , wherein the copolymer composition is bimodal with respect to the content of Cto Cα-olefin and , if present , to ethylene , and wherein the process comprises{'b': '1', 'feeding a fresh propylene monomer (C3) via a first line () into a monomer feed tank (A),'}{'b': '3', 'feeding circulated unreacted monomers from a product receiver (D) into the monomer feed tank (A) via a third line (),'}{'b': 4', '4', '4, 'dividing a monomer mixture from the monomer feed tank (A) in a fourth feed line () into a first divided fourth feed line (-C), which feeds the monomer mixture to a second reactor (C), and to a second divided fourth feed line (-B) which feeds to a first reactor (B),'}{'b': 4', '5', '6, 'feeding a fresh C4 to C10 α-olefin monomer and optionally ethylene into the second divided fourth feed line (-B) via a fifth line () forming a second combined monomer mixture feed in a sixth line (),'}{'b': '6', 'feeding the second combined monomer mixture via the sixth line () to the first reactor (B),'}{'b': '1', 'polymerizing ...

POLYCARBONATE RESIN, AND PRODUCTION METHOD AND FILM THEREOF

To provide a polycarbonate resin having an excellent hue and high heat stability, and a production method and a film thereof. 2. The polycarbonate resin according to claim 1 , wherein the content of the carbonate constituent unit represented by the formula (A) is 50 to 94 mol % based on the total of all carbonate constituent units.4. The polycarbonate resin according to claim 1 , wherein the formula (A) represents a carbonate constituent unit derived from isosorbide.5. The polycarbonate resin according to claim 1 , wherein the content of the terminal group represented by the formula (1) or (2) is 10 to 90 mol % based on the total of all terminal groups.6. The polycarbonate resin according to claim 1 , wherein the specific viscosity of a 20° C. methylene chloride solution of the polycarbonate resin is 0.18 to 0.5.8. The production method according to claim 7 , wherein the alcohol compound represented by the formula (a) or (b) is reacted in an amount of 0.1 to 5 mol % based on the total of all dihydroxy compounds.9. The production method according to claim 7 , wherein the alcohol compound represented by the formula (a) or (b) has a boiling point at normal pressure of 180 to 300° C.10. A film made of the polycarbonate resin of .11. The film made of the polycarbonate resin of claim 1 , wherein Ris an alkyl group having 6 to 15 carbon atoms which may be substituted or alkoxy group having 6 to 15 carbon atoms which may be substituted in the formula (1) claim 1 , and Rand Rare each independently an alkylene group having 1 to 12 carbon atoms which may be substituted claim 1 , Ris a hydrogen atom or alkyl group having 1 to 12 carbon atoms which may be substituted claim 1 , and n is an integer of 1 to 20 in the formula (2).12. The film according to which has a transmittance at 260 nm of not less than 30% and a transmittance at 280 nm of not less than 20%.13. The film according to which is a film for agricultural houses claim 11 , dust-proof film or food packaging film. The ...

POLYIMIDE-BASED BLOCK COPOLYMER AND POLYIMIDE-BASED FILM COMPRISING THE SAME

The present disclosure relates to a polyimide-based block copolymer and a polyimide-based film including the same. The polyimide-based block copolymer according to the present disclosure makes it possible to provide a polyimide-based film exhibiting excellent mechanical properties while being colorless and transparent. The polyimide-based film may be used as a cover film of various flexible or foldable devices. 3. The polyimide-based block copolymer of claim 2 , wherein Rand Rare the same as or different from each other in each repeating unit claim 2 , and each is independently a single bond or —C(CF)—; and{'sup': '10', 'Zis a trivalent linking group derived from at least one compound selected from the group consisting of 1,3,5-benzenetricarbonyl trichloride, 1,2,4-benzenetricarbonyl trichloride, 1,3,5-benzenetricarboxylic acid, 1,2,4-benzenetricarboxylic acid, trimethyl 1,3,5-benzenetricarboxylate, and trimethyl 1,2,4-benzenetricarboxylate.'}11. The polyimide-based block copolymer of claim 1 , wherein the copolymer exhibits a H NMR (300 MHz claim 1 , DMSO-d6 claim 1 , TMS as standard material) spectrum having at least one peak within a δ range of 10.80 ppm to 11.00 ppm claim 1 , and at least one peak within a δ range of 10.60 ppm to less than 10.80 ppm.12. The polyimide-based block copolymer of claim 1 , wherein a molar ratio of the first repeating unit: the second repeating unit is 1:0.1 to 1:10 claim 1 , and a molar ratio of the second repeating unit: the third repeating unit is 1:0.5 to 1:2.13. The polyimide-based block copolymer of claim 1 , wherein a weight average molecular weight is 100 claim 1 ,000 to 5 claim 1 ,000 claim 1 ,000 g/mol.14. A polyimide-based film comprising the polyimide-based block copolymer according to .15. The polyimide-based film of claim 14 , wherein pencil hardness is at least an HB grade claim 14 , as measured in accordance with ASTM D3363. This application claims the benefit of Korean Patent Applications No. 10-2016-0082990 filed on ...

HIGH-STRENGTH TRANSPARENT POLYAMIDE-IMIDE AND METHOD FOR MANUFACTURING SAME

Provided in the present invention is a polyamide-imide film having significantly enhanced mechanical physical properties and heat resistance while maintaining transparency. The polyamide-imide has excellent transparency, heat resistance, mechanical strength and flexibility, and thus can be used in a variety of fields including a device substrate, a cover substrate for a display, an optical film, an integrated circuit (IC) package, an adhesive film, a multilayer flexible printed circuit (FPC), a tape, a touch panel, and a protection film for an optical disk. 4. The polyamide-imide according to claim 1 , wherein the repeating structures of Chemical Formulas 1a and 1b and the repeating structure of Chemical Formula 1c are contained at a molar ratio of 1:5 to 1:2.5. The polyamide-imide according to claim 1 , wherein the repeating structure of Chemical Formulas 1a claim 1 , the repeating structure of Chemical Formula 1b and the repeating structure of Chemical Formula 1c are polymerized in the form of a random copolymer8. The method for manufacturing the polyamide-imide according to claim 7 , wherein the compounds of Chemical Formula 2 claim 7 , Chemical Formula 3 and Chemical Formula 4 claim 7 , and the diamine of Chemical Formula 5 are reacted at a molar ratio of 1:1.1 to 1.1:1.10. A polyamide-imide film comprising the polyamide-imide according to .11. The polyamide-imide film according to claim 10 , which has Haze of 2 or lower.12. The polyamide-imide film according to claim 10 , which has yellowness index (YI) of 10 or lower.13. The polyamide-imide film according to claim 10 , which has a coefficient of thermal expansion (CTE) of 15 ppm/° C. or lower at 50° C. to 300° C. claim 10 , and a solvent resistance index defined as the following Formula 1 of 2% or lower:{'br': None, 'i': T', '−T', 'T, 'sub': 0', '10', '0, 'Solvent resistance index (%)=()/×100\u2003\u2003[Formula 1]'}{'sub': 10', '0, 'wherein, Tis a film thickness after immersing the film in a polar solvent for ...

POROUS FILM SEALING METHOD AND POROUS FILM SEALING MATERIAL

A porous film sealing method and porous film sealing material are provided to seal an object to be sealed that has a porous film. 1. A method to seal a hole within a porous film comprising the step ofsupplying a first material to a treatment vessel, the treatment vessel containing an object having the porous film, whereinthe first material comprises a non-aromatic fluorocarbon having 6 or more carbon atoms.2. The porous film sealing method as claimed in wherein claim 1 ,in the first step,the first material is introduced into the treatment vessel in a gas state, and whereinthe first material seals the holes within the porous film.3. The porous film sealing method as claimed in wherein claim 1 ,in the first step,the first material is introduced into the treatment vessel in a liquid state, and whereinthe first material seals the holes within the porous film.4. The porous film sealing method as claimed in further comprising a second step of forming a plasma from the first material.5. The porous film sealing method as claimed inwhereinthe plasma of the first material acts as an etching gas in the second step.6. The porous film sealing method as claimed in further comprising a third step of removing the first material from the holes in the porous film by increasing a temperature within the treatment vessel and/or decreasing a pressure within the treatment vessel.7. The porous film sealing method as claimed in claim 1 , wherein the first material has a ring structure claim 1 , and a vapor pressure of the first material at a temperature of 25° C. is from 0.05 Torr to 25 Torr.8. The porous film sealing method as claimed in claim 1 , wherein the first material has a straight chain or a branched structure claim 1 , and a vapor pressure of the first material at a temperature of 25° C. is from 0.05 Torr to 40 Torr.9. The porous film sealing method as claimed in claim 1 , wherein a vapor pressure range of the first material in a temperature range from −50° C. to −20° C. is from 0 ...

Thermoplastic Polyurethane Film and Preparation Method Thereof

A thermoplastic polyurethane film including a cured product of a polyurethane resin compositon is provided. The polyurethane resin compostion includes a polyurethane resin, a first isocyanate-based curing agent, and an organic solvent. The thermoplastic polyurethane film has a tensile strength break of 50 MPa to 80 MPa. A method for preparing the thermoplastic polyurethane film is also provided. 1. A thermoplastic polyurethane film comprising:a cured product of a polyurethane resin composition, wherein the polyurethane resin compositon comprisesa polyurethane resin,a first isocyanate-based curing agent, andan organic solvent,wherein the thermoplastic polyurethane film has a tensile strength at break of 50 MPa to 80 MPa.2. The thermoplastic polyurethane film of claim 1 , wherein a content of the first isocyanate-based curing agent is 7.5 parts by weight to 15 parts by weight based on 100 parts by weight of the polyurethane resin.3. The thermoplastic polyurethane film of claim 1 , wherein the first isocyanate-based curing agent comprises two to six isocyanate functional groups.4. The thermoplastic polyurethane film of claim 1 , wherein the polyurethane resin is a copolymer of a mixture comprising:a polyol having a number average molecular weight of 1,800 g/mol to 2,200 g/mol;a chain extender comprising a diol having 4 to 10 carbon atoms; anda second isocyanate-based curing agent.5. The thermoplastic polyurethane film of claim 4 , wherein a content of the polyol is 50 wt % to 75 wt % based on a weight of the mixture.6. The thermoplastic polyurethane film of claim 4 , wherein a content of the chain extender is 5 wt % to 15 wt % based on a weight of the mixture.7. The thermoplastic polyurethane film of claim 4 , wherein a content of the second isocyanate-based curing agent is 20 wt % to 37.5 wt % based on a weight of the mixture.8. The thermoplastic polyurethane film of claim 1 , wherein a content of a solid content of the polyurethane resin composition is 20% to 70%.9. ...

POLARIZER, POLARIZING PLATE, AND METHOD FOR PRODUCING POLARIZER

There is provided a polarizer excellent in durability. A polarizer according to one embodiment of the present invention includes a resin film containing boric acid, wherein the resin film has a low-concentration portion, which contains a lower concentration of the boric acid than that in any other site, formed in an end portion thereof. 1. A polarizer , comprising a resin film containing boric acid , wherein the resin film has a low-concentration portion , which contains a lower concentration of the boric acid than that in any other site , formed in an end portion thereof.2. The polarizer according to claim 1 , wherein the low-concentration portion has such a concentration gradient that the concentration of the boric acid contained therein reduces outward in a plane direction.3. The polarizer according to claim 1 , wherein the low-concentration portion is formed in a region ranging from an end surface of the resin film to a position distant therefrom by 5 μm or more inward in a plane direction.4. The polarizer according to claim 1 , wherein the low-concentration portion is formed in an end portion in an absorption axis direction.5. The polarizer according to claim 1 , wherein the polarizer has formed therein a through-hole and the low-concentration portion is formed in a peripheral edge portion of the through-hole.6. The polarizer according to claim 1 , wherein the low-concentration portion is formed in an outer edge portion.7. The polarizer according to claim 6 , wherein the outer edge portion includes a site that forms a substantially V-shape that is convex inward in a plane direction.8. A polarizing plate claim 6 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the polarizer of ; and'}a protective film arranged on at least one surface of the polarizer.9. A production method for a polarizer claim 6 , comprising a step of bringing a treatment liquid into contact with a resin film containing boric acid claim 6 , to thereby form a low-concentration ...

SILANE-CONTAINING ETHYLENE INTERPOLYMER FORMULATION INCLUDING FILMS AND ELECTRONIC DEVICE MODULE COMPRISING SAME

Disclosed in more detail in this application are ethylene interpolymer films having one or more layers, comprising surface layer comprising: (A) a silane-containing ethylene interpolymer comprising (1) an ethylene interpolymer having a density of less than 0.905 g/cm3, and (2) at least 0.1 percent by weight alkoxysilane; characterized by: (3) having a volume resistivity of greater than 5×1015 ohm-cm as measured at 60 C. In one embodiment, such ethylene interpolymer has a residual boron content of less than 10 ppm and residual aluminum content of less than 100 ppm. Also disclosed are laminated electronic device modules comprising: A. at least one electronic device, and B. one of the ethylene interpolymer films as described above in intimate contact with at least one surface of the electronic device. Such laminated electronic device modules according to the invention have been shown to suffer reduced potential induced degradation (“PID”). 1. An ethylene interpolymer film having one or more layers , comprising surface layer comprising: (1) an ethylene interpolymer having a density of less than 0.905 g/cm3, and', '(2) at least 0.1 percent by weight alkoxysilane;, '(A) a silane-containing ethylene interpolymer comprising'} {'sup': '15', '(3) having a volume resistivity of greater than 5×10ohm-cm as measured at 60° C.'}, 'characterized by2. The ethylene interpolymer film according to wherein ethylene interpolymer has a residual boron content of less than 10 ppm and a residual aluminum content of less than 100 ppm claim 1 , both contents being based on weight of ethylene interpolymer.3. The ethylene interpolymer film according to wherein the ethylene interpolymer is prepared using a catalyst comprising a complex of bis-(biphenylphenol) ligands coordinated through oxygen atoms to a transition metal.4. The ethylene interpolymer film according to wherein the transition metal is selected from the group consisting of Ti claim 3 , Zr and Hf.5. The ethylene interpolymer film ...

EVA SHEET COMPRISING MICROPARTICLES FOR SOLAR CELL AND METHOD FOR MANUFACTURING THE SAME

An EVA sheet for a photovoltaic module comprising microparticles, the main component of which is an ethylene-vinyl acetate resin is provided. 1. An EVA sheet for a photovoltaic module comprising microparticles , the main component of which is an ethylene-vinyl acetate resin.2. An EVA sheet for a photovoltaic module according to claim 1 , wherein the microparticles exist in a fused state with each other.3. An EVA sheet for a photovoltaic module according to claim 1 , wherein the microparticles further comprise 0.1 to 5 parts by weight of a crosslinking agent claim 1 , 0.1 to 3 parts by weight of a co-crosslinking agent claim 1 , and 0.1 to 3 parts by weight of a ultraviolet ray blocking agent to 100 parts by weight based on the ethylene-vinyl acetate resin.4. An EVA sheet for a photovoltaic module according to claim 1 , wherein a mean particle diameter of the microparticles is 200 to 400 μm.5. An EVA sheet for a photovoltaic module according to claim 1 , wherein an angle of repose of the microparticles is 40° or less.6. An EVA sheet for a photovoltaic module according to claim 1 , wherein a thickness of the EVA sheet is 250 to 400 μm.7. A method for manufacturing an EVA sheet for a photovoltaic module comprising the steps of:(a) preparing microparticles, the main component of which is an ethylene-vinyl acetate;(b) dispersing the microparticles; and(c) sintering the dispersed microparticles.8. A method for manufacturing an EVA sheet for a photovoltaic module according to claim 7 , in the step (a) claim 7 , the microparticles are manufactured by freeze pulverizing.9. A method for manufacturing an EVA sheet for a photovoltaic module according to claim 8 , wherein the freeze pulverizing is performed at temperatures of −150 to −100° C.10. A method for manufacturing an EVA sheet for a photovoltaic module according to claim 7 , in the step (b) claim 7 , the microparticles are dispersed in a thickness of 750 to 1 claim 7 ,200 μm. The present invention provides an EVA sheet ...

HEAT-SHRINKABLE POLYESTER FILM AND PACKAGES

Provided is a heat-shrinkable polyester-based film having: a slow shrinkage speed; a shrinkage rate that increases gently with the increase of temperature; a large shrinkage stress; and an excellent shrinkage finish. This heat-shrinkable polyester-based film is characterized in that: the ratio (A1/A2) between the absorbancy (A1) at 1340 cmof the heat-shrinkable polyester-based film measured by the polarized ATR-FTIR method and the absorbancy (A2) at 1410 cmis from 0.65 to 0.9 in the main shrinkage direction of the film and from 0.45 to 0.75 in the direction orthogonal to the main shrinkage direction; and the warm-water heat shrinkage rate for when the film is immersed in 90-degree warm water for 10 seconds is from 40% to 60% in the main shrinkage direction of the film and from 0% to 12% in the direction orthogonal to the main shrinkage direction.

CELLULOSE ACYLATE FILM AND METHOD FOR PRODUCING THE SAME

A cellulose acylate film that contains at least one kind of cellulose acylate that has a substitution degree of an acyl group that contains an aromatic group of from 0.1 to 2.0, or a substitution degree of an acyl group having from 2 to 4 carbon atoms of from 2.0 to 2.6, and has an in-plane retardation at a wavelength of 550 nm Re(550) of from 80 to 350 nm, and the number of bright spots caused from irregular retardation regions having a major axis diameter of from 0.01 to 0.05 mm of 500 or less per 1 cmcauses less light leakage irrespective of Re of 80 nm or more, so as to enhance the display capability of IPS type and FFS type liquid crystal display devices. 1. A cellulose acylate film ,comprising at least one kind of cellulose acylate that has a substitution degree of an acyl group that contains an aromatic group of from 0.1 to 2.0, or a substitution degree of an aliphatic acyl group having from 2 to 4 carbon atoms of from 2.0 to 2.6,having an in-plane retardation at a wavelength of 550 nm Re(550) of from 80 to 350 nm, and{'sup': '2', 'wherein when two polarizing plates are disposed to form crossed nicols and the cellulose acylate film is inserted between the two polarizing plates to observe bright spots caused from irregular retardation regions having a major axis diameter of from 0.01 to 0.05 mm with a polarizing microscope, the number of the observed bright spots is 500 or less per 1 cm.'}2. The cellulose acylate film according to claim 1 , wherein the irregular retardation region has a solid particle present at center thereof claim 1 , and satisfies the relationship claim 1 , L>2D claim 1 , wherein D represents the diameter of the solid particle claim 1 , and L represents the major axis of the irregular retardation region.3. The cellulose acylate film according to claim 1 , having an in-plane retardation at a wavelength of 550 nm Re(550) of from 200 to 350 nm.4. The cellulose acylate film according to claim 1 , having a thickness of from 20 to 60 μm.5. The ...

LIQUID REPELLENT FILM

The present invention is a liquid-repellent film that exhibits an excellent liquid repellency, and a packaging material of which a surface is formed of the same. The liquid-repellent film comprises: 1. A liquid-repellent film formed on a substrate surface comprising:(i) a minute uneven structured part formed of hydrophilic microparticles;(ii) a liquid-repellent moiety that bonds to the surface of the minute uneven structured part; and(iii) a binder resin that is present between the substrate surface and the minute uneven structured part, and is distributed to cover the bonding part of the minute uneven structured part and the liquid-repellent moiety.2. A liquid-repellent film formed on a substrate surface comprising:(A) an undercoat part formed unevenly on the substrate surface by microparticles and a thermoplastic resin; and(B) a topcoat part having: (i) a minute uneven structured part formed of hydrophilic microparticles having a smaller particle size than the microparticles; (ii) a liquid-repellent moiety that bonds to the surface of the minute uneven structured part; and (iii) a binder resin that is present between the surface of the undercoat part and the minute uneven structured part, and is distributed to cover the bonding part of the minute uneven structured part and the liquid-repellent moiety.3. The liquid-repellent film of claim 1 , wherein an aggregated part of the liquid-repellent moieties and an exposed part of a hydrophilic surface of the hydrophilic microparticle are distributed on the surface of the minute uneven structure.4. The liquid-repellent film of claim 1 , wherein an aggregated part of the liquid-repellent moieties and an aggregated part of the hydrophilic moieties comprised to the binder resin are distributed on the surface of the minute uneven structure.5. The liquid-repellent film of that is suitable for preventing adhesion of an O/W emulsion.6. The liquid-repellent film of claim 1 , wherein the hydrophilic microparticles are hydrophilic ...

Polyimide Film and Flexible Display Panel Including the Same

Provided are a polyimide-based film, a window cover film, and a display panel including the same. More particularly, a polyimide-based film having excellent visibility, a window cover film using the same, and a display panel including the same are provided. 1. A polyimide-based film , which has a standard deviation of an in-plane retardation (Ro) per a unit area of less than 5 nm and the number of contour lines of 50 or less , based on a film having a size of 100×100 mm.2. The polyimide-based film of claim 1 , wherein the polyimide-based film has the in-plane retardation of 300 nm or less as measured at a wavelength of 550 nm.3. The polyimide-based film of claim 2 , wherein the polyimide-based film has the in-plane retardation of 0 to 300 nm as measured at a wavelength of 550 nm.4. The polyimide-based film of claim 1 , wherein the polyimide-based film has a modulus in accordance with ASTM D882 of 3 GPa or more claim 1 , an elongation at break of 8% or more claim 1 , a light transmittance of 80% less more as measured at 388 nm in accordance with ASTM D1746 claim 1 , a total light transmittance of 87% or more as measured at 400 to 700 nm claim 1 , a haze of 2.0% or less claim 1 , a yellow index of 5.0 or less claim 1 , and a b* value of 2.0 or less.5. The polyimide-based film of claim 1 , wherein the polyimide-based film is formed of a polyamide-imide-based resin.6. The polyimide-based film of claim 5 , wherein the polyimide-based film comprises a unit derived from a fluorine-based aromatic diamine claim 5 , a unit derived from an aromatic dianhydride claim 5 , and a unit derived from an aromatic diacid dichloride.7. The polyimide-based film of claim 6 , wherein the polyimide-based film further comprises a unit derived from a cycloaliphatic dianhydride.8. The polyimide-based film of claim 1 , wherein the polyimide-based film has a thickness of 30 to 110 μm.9. A window cover film comprising the polyimide-based film of .10. The window cover film of claim 9 , wherein the ...

POLYROTAXANE COMPOSITION AND SENSOR

The present invention provides a sensor that exhibits a small effect on a detection target during detection, a high detection sensitivity, a wide dynamic range for detection, and a small change after repeated detection, as well as a composition suitable for use in the sensor. 1. A polyrotaxane composition comprising two polyrotaxane cyclic molecules crosslinked with a crosslinking agent present between the molecules , wherein the polyrotaxane composition exhibits a hysteresis loss as a mechanical energy loss rate of 10% or less , an elongation at break of 200% or more , an initial Young's modulus of 5 MPa or less , and a relative dielectric constant of 8.0 or more.2. The polyrotaxane composition according to claim 1 , wherein the crosslinking agent is a polymer having no side chain claim 1 , having a number average molecular weight of 500 or more claim 1 , and having functional groups at both ends of the polymer claim 1 , and the functional groups are directly or indirectly bonded to the polyrotaxane cyclic molecules.3. The polyrotaxane composition according to claim 2 , wherein the polymer is polyether or polyester.4. The polyrotaxane composition according to claim 3 , wherein the polymer is polytetramethylene ether glycol.5. A sensor comprising a film formed of the polyrotaxane composition according to claim 1 , and elastomer-made electrode layers disposed on both surfaces of the film.6. The sensor according to claim 5 , wherein a hysteresis loss of a change in capacitance is 0.5% or less during expansion and contraction of the sensor. The present invention relates to a polyrotaxane composition and a sensor formed of the composition.A polyrotaxane is a molecular assembly having a structure wherein a linear molecule slidably penetrates through a cyclic molecule, and the cyclic molecule is prevented from being removed by blocking groups disposed at both ends of the linear molecule (Patent Document 1). A composition containing a polyrotaxane is expected to be used in ...

PROPYLENE TERPOLYMER

A terpolymer compositions made from or containing: 1. A terpolymer composition comprising: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %, based upon the total weight of the first terpolymer;', 'ii) the content of 1-butene derived units ranging from 7.2 wt % to 14.8 wt % based upon the total weight of the first terpolymer;', 'iii) the xylene soluble fraction at 25° C. ranging from 7.2 wt % to 13.4 wt %, based upon the total weight of the first terpolymer;', 'iv) the melting point determined by differential scanning calorimetry (DSC), according to ISO 11357-3, with a heating rate of 20° C./minute ranging from 123° C. to 138° C.;', {'sup': '13', 'v) the CNMR sequences EEE ranging from 0.16 mol % to 0.40 mol %; and'}, 'vi) the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 1.0 g/10 min to 20.0 g/10 min; and, 'A) From 80 wt % to 97 wt %; of a first propylene, ethylene, 1-butene terpolymer having i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %, based upon the total weight of the second terpolymer;', 'ii) the content of 1-butene derived units ranging from 14.4 wt % to 26.5 wt % based upon the total weight of the second terpolymer; and', 'iii) the xylene soluble fraction at 25° C. ranging from 38.2 wt % to 60.2 wt % based upon the total weight of the second terpolymer;, 'B) From 20 wt % to 3 wt %; of a second propylene, ethylene, 1-butene terpolymer havingwherein the content of 1-butene derived units of component A) is lower than the amount of the content of 1-butene derived units of component B); andthe terpolymer composition having -the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 3.0 g/10 min to 20.0 g/10 min;the sum of the amounts of A) and B) being 100 wt %.2. The terpolymer composition according to comprising from 83 wt % to 95 wt % of component A) and from 17 wt % to 5 wt % of component B).3. The ...

PLASTICIZER FOR VINYL CHLORIDE RESIN CONTAINING NON-PHTHALATE ESTER AND VINYL CHLORIDE RESIN COMPOSITION CONTAINING SUCH PLASTICIZER

An object of the present invention is to provide a plasticizer for vinyl chloride-based resin superior in cold resistance and volatility resistance, and desirable in flexibility, fogging resistance, heat discoloration resistance, and weather resistance, and to also provide a vinyl chloride-based resin composition comprising the plasticizer. 1. A plasticizer for vinyl chloride-based resin , comprising a non-phthalate ester (C) obtained by reacting a polycarboxylic acid (A) and an alcohol (B) ,wherein:(i) the polycarboxylic acid (A) is a polycarboxylic acid compound selected from the group consisting of alicyclic dicarboxylic acids, aromatic tricarboxylic acids, and derivatives thereof;{'sub': '9', '(ii) the alcohol (B) is a saturated aliphatic alcohol (B1) comprising a Csaturated aliphatic alcohol as a major component;'}{'sub': 9', '9, '(iii) the saturated aliphatic alcohol (B1) comprises a linear Csaturated aliphatic alcohol (B1-1) of 60 wt % or more, and a branched Csaturated aliphatic alcohol (B1-2) of 40 wt % or less;'}(iv) the linear-chain ratio of the alcohol (B1) is 60% or more; and(v) the non-phthalate ester (C) does not substantially comprise a phthalate ester obtained by reacting a phthalic acid compound or a derivative thereof with an alkyl alcohol having 8 or fewer carbon atoms.2. The plasticizer for vinyl chloride-based resin according to claim 1 , wherein the saturated aliphatic alcohol (B1) comprises the linear Csaturated aliphatic alcohol (B1-1) of 60 to 95 wt % claim 1 , and the branched Csaturated aliphatic alcohol B1-2) of 5 to 40 wt %.3. The plasticizer for vinyl chloride-based resin according to claim 2 , wherein the saturated aliphatic alcohol (B1) comprises the linear Csaturated aliphatic alcohol (B1-1) of 70 to 90 wt % claim 2 , and the branched Csaturated aliphatic alcohol (B1-2) of 10 to 30 wt %.4. The plasticizer for vinyl chloride-based resin according to claim 1 , wherein the polycarboxylic acid (A) is an alicyclic dicarboxylic acid or a ...

SOLVENT-CONTAINING DRY FILM AND METHOD FOR APPLYING THE SAME ON A SUBSTRATE

The present disclosure relates to a solvent-containing dry film and a method for applying a dry film on a substrate. The dry film includes a carrier and a resin layer. The resin layer contains a resin composition and a solvent and the solvent is present in a total amount of at least 5 wt % based on the total weight of the resin layer. The dry film of the present invention can be applied onto a substrate without the use of a prior art vacuum lamination apparatus. The application process is simple and is more cost-efficient than the prior art techniques.

ASSEMBLY, METHOD FOR PRODUCING SAME, AND SHEET COMPRISING MODIFIED BLOCK COPOLYMER HYDRIDE

The present invention provides: an assembly obtained by bonding a sheet made of a modified hydrogenated block copolymer having an alkoxysilyl group introduced therein with a thermoplastic resin sheet, wherein a peel strength of the adherend surface is 4 N/cm or higher; a method for producing an assembly by bonding a sheet made of a modified hydrogenated block copolymer having an alkoxysilyl group introduced therein with a thermoplastic resin sheet, the method comprising steps of: (1) activating an adherend surface of the thermoplastic resin sheet with at least one selected from plasma exposure, excimer UV exposure and corona discharge; and (2) superposing the sheet made of the modified hydrogenated block copolymer having the alkoxysilyl group introduced therein with the adherend surface of the thermoplastic resin sheet to be subjected to thermally press-bonding; and a sheet made of a modified hydrogenated block copolymer, comprising at least one surface activated. 1. An assembly obtained by bonding a sheet made of a modified hydrogenated block copolymer having an alkoxysilyl group introduced therein with a thermoplastic resin sheet , whereina peel strength of the adherend surface is 4 N/cm or higher.2. A method for producing an assembly by bonding a sheet made of a modified hydrogenated block copolymer having an alkoxysilyl group introduced therein with a thermoplastic resin sheet , the method comprising steps of:(1) activating an adherend surface of the thermoplastic resin sheet with at least one selected from plasma exposure, excimer UV exposure and corona discharge; and(2) superposing the sheet made of the modified hydrogenated block copolymer having the alkoxysilyl group introduced therein with the adherend surface of the thermoplastic resin sheet to be subjected to thermally press-bonding.3. The method for producing the assembly according to claim 2 , whereinthe step (1) is a step of activating both surfaces of the adherend surface of the sheet made of the ...

SILICONE MEMBRANES

Silicone membranes and methods of manufacturing membranes are provided. 1. A silicone membrane derived from a silicone composition comprising:(i) 80 to 90 wt % of a silicone binder;(ii) a plasticizer selected from: 5 to 15 wt % of a hydroxyl-terminated polysiloxane plasticizer; 5 to 15 wt % of a vinyl-terminated polysiloxane plasticizer; or a combination thereof;(iii) 0.5 to 1.5 wt % of a reinforcing filler;(iv) 1 to 8 wt % of a curative agent; and(v) 1 to 25 wt % of a pigment;wherein wt % is based on the total weight of the polymer solids.2. The silicone membrane of claim 1 , wherein the silicone binder is a polydimethylsiloxane.5. The silicone membrane of claim 1 , wherein the reinforcing filler is fumed silica.6. The silicone membrane of claim 1 , wherein the reinforcing filler is carbon black.7. The silicone membrane of claim 1 , wherein the curative agent is a peroxide.8. The silicone membrane of claim 7 , wherein the hydroxyl-terminated plasticizer and the vinyl-terminated plasticizer are present in a ratio of about 3 to 1.9. The silicone membrane of claim 1 , wherein the curative agent is a hydrosilation curative agent.11. The silicone membrane of claim 9 , wherein the hydroxyl-terminated plasticizer and the vinyl-terminated plasticizer are present in a ratio of about 1 to 1.12. The silicone membrane of claim 1 , wherein the composition further comprises an additive selected from a polyalkylene oxide compound having terminal functional groups selected from vinyl claim 1 , allyl claim 1 , acryloxy claim 1 , methacryloxy claim 1 , thiol claim 1 , hydroxy claim 1 , alkyl claim 1 , alkoxysilyl claim 1 , and silyl groups.13. The silicone membrane of claim 1 , wherein the pigment is a UV absorbing pigment claim 1 , a UV reflecting pigment claim 1 , an IR absorbing pigment claim 1 , or a IR reflecting pigment.14. The silicone membrane of claim 1 , wherein the pigment is TiO.15. The silicone membrane of any of claim 1 , wherein the composition further comprises a ...

METHOD FOR PREPARING MICROPOROUS POLYOLEFIN FILM BY THERMALLY-INDUCED PHASE SEPARATION METHOD

The present invention discloses a method for preparing a microporous polyolefin film comprising: a step of injecting a composition comprising polyolefin 30 to 60 wt % and a diluent mixture comprising a diluent, which can make liquid-liquid phase separation with the polyolefin thermodynamically 40 to 70 wt %, into an extruding machine, and melting and kneading thereof to prepare a single phase melt; and a step of extruding the melt while conducting liquid-liquid phase separation by passing through a section having the temperature below the liquid-liquid phase separation temperature and forming thereof in the form of a sheet, and a microporous polyolefin film prepared according to the method. 1. A method for preparing a microporous polyolefin film comprising:(a) a step of injecting a composition comprising polyolefin 30 to 60 wt % and a diluent mixture 40 to 70 wt % into an extruding machine, and melting and kneading thereof to prepare a single phase melt, wherein the diluent mixture comprises a diluent, which can make liquid-liquid phase separation with the polyolefin thermodynamically and a supplementary diluent forming a thermodynamic single phase with the polyolefin, and weight ratio of the diluent and the supplementary diluent is 3:7 to 7:3; and{'sup': 3', '1/2, 'claim-text': {'br': None, 'i': Ra', 'D', '−δD', 'P', '−δP', 'H', '−δH, 'sup': 3', '1/2', 'P', 'D', '2', 'P', 'D', '2', 'P', 'D', '2', '1/2, '(J/cm)=[4*(δ)+(δ)+(δ)]'}, '(b) a step of extruding the melt while conducting liquid-liquid phase separation by passing through a section having the temperature below the liquid-liquid phase separation temperature and forming thereof in the form of a sheet, wherein Hansen solubility parameter distance (Ra), expressed by the following formula of the diluent mixture to the polyolefin is 4.0 to 6.5 (J/cm){'sup': P', 'P', 'P, '(wherein δD, δPand δHrepresent polyolefin solubility parameter generated by non-polar dispersion energy, polyolefin solubility parameter generated ...

POLYIMIDE FILM AND FABRICATION METHOD THEREOF

A polyimide film includes a polyimide polymer forming a main molecular structure of the polyimide film, and polyimide particles present in the polyimide film at a weight ratio between about 15 wt % and 30 wt % of a total weight of the polyimide film, the polyimide particles having an average diameter between about 3 μm and 8 μm. The polyimide film can have a 60° gloss value equal to or smaller than 10, a haze equal to or higher than 90%, and a Young's modulus equal to or higher than 280 kgf/mm. In some embodiments, methods of fabricating the polyimide film are also described. 1. A polyimide film comprising:a polyimide polymer forming a main molecular structure of the polyimide film; andpolyimide particles present in the polyimide film at a weight ratio between about 15 wt % and 30 wt % of a total weight of the polyimide film, the polyimide particles having an average diameter between about 3 μm and 8 μm.2. The polyimide film according to claim 1 , having a 60° gloss value equal to or smaller than 10.3. The polyimide film according to claim 1 , having a haze equal to or higher than 90%.4. The polyimide film according to claim 1 , having a Young's modulus equal to or higher than 280 kgf/mm.5. The polyimide film according to claim 1 , having a 60° gloss value equal to or smaller than 10 claim 1 , a haze equal to or higher than 90% claim 1 , and a Young's modulus equal to or higher than 280 kgf/mm.6. The polyimide film according to claim 1 , wherein the polyimide particles are obtained by reacting diamine monomers with dianhydride monomers claim 1 , the diamine monomers being selected from a group consisting of phenylenediamine (PDA) claim 1 , oxydianiline (ODA) and 2-(4-aminophenyl)-5-amino benzimidazole (PBOA) claim 1 , and the dianhydride monomers being selected from a group consisting of 3 claim 1 ,3′ claim 1 ,4 claim 1 ,4′-biphenyltetracarboxylic dianhydride (BPDA) and pyromellitic dianhydride (PMDA).7. The polyimide film according to claim 1 , wherein the ...

HEAT-SHRINKABLE WHITE FILM

A heat-shrinkable white film including an amorphous polyethylene terephthalate; a cyclic olefin resin having a glass transition temperature of 100° C. or higher; and a polyester elastomer having a Vicat softening point of 150° C. or lower. 1an amorphous polyethylene terephthalate;a cyclic olefin resin having a glass transition temperature of 100° C. or higher;a polyester elastomer having a Vicat softening point of 150° C. or lower.. A heat-shrinkable white film comprising: The present invention relates to a heat-shrinkable white film.In general, a label formed of a heat-shrinkable film subjected to printing is mounted on a beverage or seasoning bottle.Most heat-shrinkable films which have been used in the past are transparent. However, white heat-shrinkable films are required from the viewpoint of diversification of designs. As a method of whitening a heat-shrinkable film, a method of containing an inorganic white pigment such as titanium oxide and a coating method using a white ink are proposed (for example, Patent Document 1 and 2).[Patent Document 1] Japanese Unexamined Patent Application, First Publication No. 2004-155482[Patent Document 2] Japanese Unexamined Patent Application, First Publication No. 2005-212226However, it is difficult to uniformly disperse an inorganic white pigment in a resin film. As a result, problems such as classification and an increase in specific gravity of the film occur. In addition, the coating method using a white ink is not easily performed.Moreover, when a label looks unattractive, a product having the label mounted thereon also gives a bad impression. Therefore, heat-shrinkable films are required to have high surface smoothness in order to improve the appearance of the label and to prevent print omission.An object of the invention is to provide a heat-shrinkable white film which has heat shrinkability, high concealability, and high surface smoothness, and is white and simple to obtain.The invention has the following aspect.A ...

POLYAMIDE-IMIDE, METHOD FOR PREPARING SAME, AND POLYAMIDE-IMIDE FILM USING SAME

The present invention provides a polyamide-imide, a method for preparing same, and a polyimide film using same. The polyamide-imide film exhibits excellent transparency, heat resistance, mechanical strength and flexibility, and thus may be used in various fields such as substrates for device, cover substrates for displays, optical films, integrated circuit (IC) packages, adhesive films, multi-layer flexible printed circuits (FPCs), tapes, touch panels and protective films for optical discs. 3. The polyamide-imide according to claim 1 , wherein the repeating structure of the Chemical Formula 1a and the repeating structure of the Chemical Formula 1b are polymerized at molar ratio of 1:5 to 2:1.4. The polyamide-imide according to claim 1 , wherein the repeating structure of the Chemical Formula 1a and the repeating structure of the Chemical Formula 1b are polymerized in the form of a random copolymer.8. The method for manufacturing the polyamide-imide according to claim 7 , wherein the tetracarboxylic dianhydride of the Chemical Formula 2 and the compound of the Chemical Formula 3 are added at molar ratio of 1:5 to 2:1.9. The method for manufacturing the polyamide-imide according to claim 7 , wherein the compounds of the Chemical Formula 2 and the Chemical Formula 3 and the diisocyanate of the Chemical Formula 4 are reacted at molar ratio of 1:1.1 to 1.1:1.10. The method for manufacturing the polyamide-imide according to claim 7 , wherein anhydride is further added in the step b) before reaction.11. A high strength transparent polyamide-imide film comprising the polyamide-imide according to .12. The high strength transparent polyamide-imide film according to claim 11 , which has haziness (Haze) of 2 or lower and yellowness index (YI) of 10 or lower.13. The high strength transparent polyamide-imide film according to claim 11 , which has pencil strength of 2H or higher.14. The polyamide-imide film according to claim 11 , which has coefficient of thermal expansion (CTE) ...

RESIN FILM

A resin film comprising a resin (A) and a multi-layered particle (B), the multi-layered particle comprising a layer (a) made of a polymer comprising 80 to 99.99% by mass of a methyl methacrylate unit, 0.01 to 2% by mass of a crosslinkable monomer unit and 0 to 19.99% by mass of additional copolymerizable monomer units, a layer (b) made of a polymer comprising 70 to 99.8% by mass of an alkyl acrylate unit, 0.2 to 10% by mass of a crosslinkable monomer unit and 0 to 29.8% by mass of additional copolymerizable monomer units, and a layer (c) made of a polymer comprising 80 to 100% by mass of a methyl methacrylate unit and 0 to 20% by mass of additional copolymerizable monomer units, wherein an amount of the layer (a) is 5 to 15 parts by mass, an amount of the layer (b) is 40 to 60 parts by mass and an amount of the layer (c) is 35 to 50 parts by mass, based on 100 parts by mass of the total amount of the layer (a), the layer (b) and the layer (c), and the layer (a), the layer (b) and the layer (c) are arranged in this order from the center of the particle toward the outer surface of the particle, and a volume-based average particle diameter is 90 to 150 nm. 1. A resin film comprisinga multi-layered particle (B) comprising a layer (a) made of a polymer comprising 80 to 99.99% by mass of a methyl methacrylate unit, 0.01 to 2% by mass of a crosslinkable monomer unit and 0 to 19.99% by mass of additional copolymerizable monomer units, a layer (b) made of a polymer comprising 70 to 99.8% by mass of an alkyl acrylate unit, 0.2 to 10% by mass of a crosslinkable monomer unit and 0 to 29.8% by mass of additional copolymerizable monomer units, and a layer (c) made of a polymer comprising 80 to 100% by mass of a methyl methacrylate unit and 0 to 20% by mass of additional copolymerizable monomer units, wherein an amount of the layer (a) is 5 to 15 parts by mass, an amount of the layer (b) is 40 to 60 parts by mass, and an amount of the layer (c) is 35 to 50 parts by mass, based on ...

DISPLAY APPARATUS

A display apparatus includes a display panel, a light guide unit disposed under the display panel that includes a light incident surface, an opposite surface opposite to the light incident surface, side surfaces connecting the light incident surface and the opposite surface, and a light exiting surface facing the display panel, and a foam tape attached on an edge of the light exiting surface and an edge of a lower surface of the display panel to fix the display panel and the light guide unit. The foam tape includes a first adhesive layer, a reflecting layer disposed on the first adhesive layer, a foam layer disposed on the reflecting layer, and a second adhesive layer disposed on the foam layer and attached to the display panel. 1. A display apparatus , comprising:a display panel;a light guide unit disposed under the display panel that includes a light incident surface, an opposite surface opposite to the light incident surface, side surfaces connecting the light incident surface and the opposite surface, and a light exiting surface facing the display panel; anda foam tape attached onto an edge of the light exiting surface and an edge of a lower surface of the display panel to fix the display panel and the light guide unit,wherein the foam tape comprises a first adhesive layer, a reflecting layer disposed on the first adhesive layer, a foam layer disposed on the reflecting layer, and a second adhesive layer disposed on the foam layer and attached to the display panel.2. The display apparatus of claim 1 , wherein the foam tape comprises a first foam tape claim 1 , a second foam tape claim 1 , and a third foam tape claim 1 ,the first foam tape is attached on an edge of the light exiting surface adjacent to the opposite surface,the second foam tape and the third foam tape are attached on edges of the light exiting surface adjacent to the side surfaces of the light guide unit, respectively.3. The display apparatus of claim 2 , wherein one or more of the first foam tape ...

Methods of Making Ion-conductive Polymer Films for Electrochromic Devices

Methods and materials to fabricate electrochromic including electrochemical devices are disclosed. In particular, emphasis is placed on the composition, fabrication and incorporation of electrolytic sheets in these devices. Composition, fabrication and incorporation of redox layers and sealants suitable for these devices are also disclosed. Incorporation of EC devices in insulated glass system (IGU) windows is also disclosed. 1. A method of making an ion-conductive polymer film for an electrochromic device , wherein the method comprises:(a) mixing one or more monomers capable of forming a thermoplastic polymer, a plasticizer, a salt which is soluble in the plasticizer, a UV stabilizer, and a polymer-forming catalyst to form a mixture;(b) polymerizing the mixture to obtain a formulation containing a thermoplastic polymer; and(c) extruding or casting the formulation to form said ion-conductive film.2. The method of claim 1 , wherein at least one of the salt claim 1 , the UV stabilizer and the polymer-forming catalyst is dissolved in at least one of the plasticizer and a monomer prior to its mixing with other ingredients.3. The method of claim 1 , wherein the polymerization reaction is selected from condensation and addition.4. The method of claim 1 , wherein more than one plasticizer claim 1 , polymer-forming catalyst claim 1 , and UV stabilizer is included in the mixture.5. The method of claim 1 , wherein the formulation may further contain at least one thermal stabilizer claim 1 , colorant claim 1 , processing aid claim 1 , adhesion promotion agent claim 1 , non-electronically conductive nanoparticle claim 1 , or combination thereof.6. The method of claim 1 , wherein the polymer is a homopolymer claim 1 , random copolymer claim 1 , block copolymer claim 1 , or a graft polymer.7. The method of claim 1 , wherein more than one monomer is used claim 1 , and all monomers are added prior to the start of the polymerization reaction or some monomers are added at different ...

Polymers For Use In Electronic Devices

Disclosed is a polyimide having a repeat unit structure of Formula III 2. The liquid composition according to claim 1 , wherein at least one of Rand Ris a fluorinated group.3. The liquid composition according to claim 1 , wherein at least one of Rand Ris an unsubstituted or substituted hydrocarbon aryl.4. The liquid composition according to claim 1 , wherein Rand Rare joined together to form an unsubstituted or substituted cyclic group selected from the group consisting of a cycloalkyl group claim 1 , a hydrocarbon aryl group claim 1 , and a heteroaryl group.5. The liquid composition according to claim 1 , wherein 40-60 mol % of Rhas Formula II.7. The polyimide film according to claim 6 , wherein the film has a Tg greater than 350° C. and a CTE less than 20 ppm/° C.8. The polyimide film according to claim 6 , wherein the film has a Tg greater than 350° C. and an optical retardation less than 100.9. The polyimide film according to claim 6 , wherein the film has a Tg greater than 350° C. claim 6 , an optical retardation less than 250 nm claim 6 , and a b* value less than 5.0.10. An electronic device wherein a polyimide film having a repeat unit of Formula III claim 6 , according to claim 6 , is used in device components selected from the group consisting of device substrates claim 6 , substrates for color filter sheets claim 6 , cover films claim 6 , and touch screen panels. The present disclosure relates to novel polymeric compounds. The disclosure further relates to methods for preparing such polymeric compounds and electronic devices having at least one layer comprising these materials.Materials for use in electronics applications often have strict requirements in terms of their structural, optical, thermal, electronic, and other properties. As the number of commercial electronics applications continues to increase, the breadth and specificity of requisite properties demand the innovation of materials with new and/or improved properties. Polyimides represent a ...

POLYETHYLENE COMPOSITION AND FILM HAVING RETAINED DART IMPACT

A polyethylene composition comprises a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M/Mof <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of less than 75,000 and a molecular weight distribution M/Mof <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 100,000 to 300,000 and a molecular weight distribution M/Mof >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a soluble fraction in a CEF analysis of at least 15 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ≥200 MPa (at a film thickness of about 1 mil) and an oxygen transmission rate (OTR) of ≥700 cmper 100 inch(at a film thickness of about 1 mil). Film made from the polyethylene composition retains much of its dart impact performance on downgauging from a thickness of 1 mil to a thickness of 0.75 mil. 1. A polyethylene composition comprising:{'sub': W', 'w', 'n, 'from 15 to 75 wt % of a first polyethylene which is an ethylene copolymer, the first polyethylene having a weight average molecular weight Mof from 70,000 to 250,000, a molecular weight distribution M/Mof <2.3 and from 5 to 100 short chain branches per thousand carbon atoms;'}{'sub': W', 'w', 'n, 'from 5 to 80 wt % of a second polyethylene which is an ethylene copolymer or an ethylene homopolymer, the second polyethylene having a weight average molecular weight Mof less than 75,000, a molecular weight distribution M/Mof <2.3 and from 0 to 20 short chain branches per thousand carbon atoms; and'}{'sub': W', 'w', 'n, 'from 5 to 60 wt % of a third polyethylene which is an ethylene copolymer or an ethylene homopolymer, the third polyethylene having a ...

POLYETHYLENE COMPOSITION AND FILM HAVING A GOOD PERMEABILITY, STIFFNESS AND SEALABILITY

A polyethylene composition includes a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M/Mof <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000 and a molecular weight distribution M/Mof <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M/Mof >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a soluble fraction in a CEF analysis of at least 10 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ≥190 MPa (at a film thickness of about 1 mil), a seal initiation temperature (SIT) of ≤100° C. (at a film thickness of about 2 mil), an area of hot tack window (AHTW) of ≥160 Newtons·C° (at a film thickness of about 2 mil) and an oxygen transmission rate (OTR) of ≥650 cmper 100 inch(at a film thickness of about 1 mil). 1. A polyethylene composition comprising:{'sub': w', 'w', 'n, 'from 5 to 80 wt % of a first polyethylene which is an ethylene copolymer, the first polyethylene having a weight average molecular weight Mof from 70,000 to 250,000, a molecular weight distribution M/Mof <2.3 and from 5 to 100 short chain branches per thousand carbon atoms;'}{'sub': w', 'w', 'n, 'from 5 to 80 wt % of a second polyethylene which is an ethylene copolymer or an ethylene homopolymer, the second polyethylene having a weight average molecular weight Mof from 15,000 to 100,000, a molecular weight distribution M/Mof <2.3 and from 0 to 20 short chain branches per thousand carbon atoms; and'}{'sub': w', 'w', 'n, 'from 5 to 80 wt % of a third polyethylene which is an ethylene copolymer or an ethylene homopolymer, the ...

POLARIZER PROTECTIVE FILM AND MANUFACTURING METHOD THEREOF

Provided are a polarizer protective film comprising a polymeric film and a coating layer formed on at least one surface of the polymeric film, where the coating layer has a plurality of concave embossed patterns and has a surface roughness of 2.0 nm to 20.0 nm, and a manufacturing method thereof. 1. A polarizer protective film comprising a polymeric film and a coating layer formed on at least one surface of the polymeric film , wherein the coating layer comprises a plurality of concave embossed patterns and has a surface roughness (Ra) of 2.0 nm to 20.0 nm.2. The polarizer protective film of claim 1 , wherein a diameter of the embossed patterns is 0.1 μm to 20 μm.3. The polarizer protective film of claim 1 , wherein a depth of the embossed patterns is 1 nm to 1 μm.4. The polarizer protective film of claim 1 , wherein the coating layer comprises a photocurable binder claim 1 , a silicon-based or fluorine-based compound claim 1 , and a polymerization initiator.5. The polarizer protective film of claim 4 , wherein the silicon-based or fluorine-based compound is present in an amount from 0.2 parts by weight to 10 parts by weight with respect to 100 parts by weight of the photocurable binder.6. The polarizer protective film of claim 1 , wherein the polymeric film includes one or more selected from the group consisting of a polyester claim 1 , a polyethylene claim 1 , a cyclic olefin polymer (COP) claim 1 , a cyclic olefin copolymer (COC) claim 1 , a polyacrylate (PAC) claim 1 , a polycarbonate (PC) claim 1 , a polymethylmethacrylate (PMMA) claim 1 , a polyimide (PI) claim 1 , a triacetylcellulose (TAC) claim 1 , and a cellulose.7. A method of manufacturing a polarizer protective film claim 1 , the method comprising the steps of:coating a photocurable coating composition comprising a photocurable binder, a silicon-based or fluorine-based compound, and a polymerization initiator onto at least one surface of a polymeric film;heat-treating the polymeric film onto which the ...

CUSHIONING MATERIAL HAVING SENSOR, AND BED

The cushioning material having a sensor includes a resin sheet composed of photoelastic resin, a cushioning material laminated on the resin sheet , a photosensor including a light generating unit and a light receiving unit that are disposed to face each other so as to sandwich the resin sheet , and a processor that detects a stress applied to the resin sheet based on the light signal detected by the photosensor 1. A cushioning material having a sensor , comprising:a resin sheet composed of photoelastic resin,a cushioning material laminated on the resin sheet,a photosensor including a light generating unit and a light receiving unit that receives light generated from the light generating unit through the resin sheet, anda processor that detects a stress applied to the resin sheet based on a light signal detected by the photosensor.2. The cushioning material having a sensor according to claim 1 , whereinthe light generating unit and the light receiving unit are disposed so as to overlap with the resin sheet on a plane of projection projected in a direction perpendicular to the thickness direction of the resin sheet.3. The cushioning material having a sensor according to claim 1 , whereinthe light generating unit is disposed so as to overlap with the resin sheet on a plane of projection projected in a direction perpendicular to the thickness direction of the resin sheet, andthe light receiving unit is disposed so as to overlap with the resin sheet on a plane of projection projected in the thickness direction of the resin sheet.4. The cushioning material having a sensor according to claim 3 , whereinthe cushioning material has a protruded accommodation unit for accommodating the light receiving unit.5. The cushioning material having a sensor according to claim 1 , wherein{'sup': −12', '−1', '−1, 'the photoelastic resin has a photoelastic constant at 25° C. of 1000×10Paor more and 100000×10−12 Paor less.'}6. The cushioning material having a sensor according to claim 1 , ...

Polymer Films Having Improved Heat Sealing Properties

A polymer composition comprising an ethylene alpha-olefin copolymer, wherein the polymer composition is characterized as having (a) a density in the range of from greater than about 0.910 g/cc to about 0.930 g/cc, as determined according to ASTM D1505; (b) a melt index in the range of from greater than about 0.5 g/10 min to about 3 g/10 min, as determined by ASTM D1238, Condition 190° C./2.16 kg; (c) a molecular weight distribution of from about 3.4 to about 12, as determined by gel permeation chromatography (GPC); (d) a weight average molecular weight of from greater than about 85 kg/mol to about 160 kg/mol, as determined by gel permeation chromatography (GPC); and (e) a z-average molecular weight of from greater than about 210 kg/mol to about 500 kg/mol, as determined by gel permeation chromatography (GPC). 1. An ethylene alpha-olefin copolymer having:(a) a density in the range of less than about 0.945 g/cc, as determined according to ASTM D1505;(b) a melt index in the range of from greater than about 0.5 g/10 min to about 3 g/10 min, as determined according to ASTM D1238, Condition 190° C./2.16 kg;(c) a molecular weight distribution of from about 3.4 to about 12, as determined by gel permeation chromatography;(d) a weight average molecular weight of from greater than about 85 kg/mol to about 160 kg/mol, as determined by gel permeation chromatography;(e) a z-average molecular weight of from greater than about 210 kg/mol to about 500 kg/mol, as determined by gel permeation chromatography;(f) a ratio of high load melt index to melt index of from about 16 to about 30;(g) a number average molecular weight of from about 7 kg/mol to about 50 kg/mol; and(h) at least a first peak and a second peak when subjected to analytical temperature rising elution fractionation.2. The polymer of wherein the at least first peak and at least second peak elute within the temperature range of from about 20° C. to about 110° C.3. The polymer of wherein the at least first peak and at least ...

ANTI-REFLECTIVE FILM FOR PHOTOVOLTAIC ARRAYS

A film containing polymeric particles which have an average particle diameter from 0.75 to 15 μm and a refractive index which changes continuously from the center of the particles to the surface. The particles are embedded in a continuous polymeric phase comprising a polyolefin. The average refractive index difference measured from 400 nm to 800 nm between the polymeric particles and the continuous polymeric phase is no greater than 0.02. 1. A film comprising polymeric particles having: (a) an average particle diameter from 0.75 to 15 μm; and (b) a refractive index which changes continuously from the center of the particles to the surface; and a continuous polymeric phase comprising a polyolefin; wherein an average refractive index difference measured from 400 nm to 800 nm between the polymeric particles and the continuous polymeric phase is no greater than 0.02.2. The film of in which the average particle diameter is from 1.5 to 10 μm.3. The film of in which the polymeric particles have a refractive index from 1.45 to 1.53.4. The film of in which the polyolefin comprises polymers or copolymers of alkenes having from two to eight carbon atoms.5. The film of in which the refractive index refractive index at the center of the polymeric particles is from 1.52 to 1.60 and the refractive index at the surface is from 1.46 to 1.52.6. The film of in which the continuous polymeric phase comprises from 1 to 12 wt % of the polymeric particles.7. The film of in which the average particle diameter is from 2 to 8 μm.8. The film of in which the polymeric particles comprise at least 60% polymerized residues of acrylic and styrenic monomers. This invention relates to an anti-reflective film which is particularly useful for construction of photovoltaic modules.There are a number of approaches to minimizing wasteful reflection of visible light from photovoltaic arrays, including application of a low dielectric constant layer onto the surface of the array. For example, U.S. Pat. No. 7, ...