SILICIUM-ZINN-VERBINDUNGEN, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ZUM HERSTELLEN VON ORGANOPOLYSILOXANELASTOMEREN

HERSTELLUNG VON KOHLENWASSERSTOFFLÖSLICHEN HYDROCARBYLALUMINOXANEN

Fusible and heat-curable solid materials, useful as the basis of coating powders for plastics, glass, ceramics and especially metals

Fusible and heat-curable solid materials based on condensates with a viscosity minimum of 10 mPa.s to 150 Pa.s in the range 50-200 deg C, derived from hydrolysable silanes (and possibly also hydrolysable metal compounds) containing groups which enable further condensation and also non-hydrolysable organic groups. Fusible and heat-curable solid materials comprise condensates (K) derived from hydrolysable silane(s) and optionally hydrolysable metal compound(s), with central atoms (M) linked to groups (A) which facilitate further condensation of (K) and with non-hydrolysable organic groups (R) on at least 70% of the atoms (M), these groups (R) being partly replaceable by complex-forming species coordinated with (M). The viscosity of (K) passes through a minimum value of 10 mPa.s to 150 Pa.s in the range 50-200 deg C. Independent claims are also included for (a) a process for coating substrates with coating powder based on these materials; (b) a process for the production of these materials ...

Gehaertete und/oder verschaeumte Copolymere auf Polyphosphasenbasis

Improved compositions comprising stabilised polymers of vinyl chloride

Polymers of vinyl chloride are stabilized by the incorporation therein of 0,05 to 5 weight per cent of a stannonoic and/or thiostannonoic acid condensation product having the general formula (RSnO1,5)n or (RSnS1,5)n or (RSnO1,5)m. (RSnS1,5)n wherein R is a C1-20 alkyl, cycloalkyl or aryl group, and n or m+n is an integer from 2 to about 1,000, or of a mixture of such products. Their preparation is described in Specification 890,283. The polymers may be vinyl chloride homopolymers, copolymers of at least 50% vinyl chloride, and mixtures containing at least 50% of such polymers. Comonomers specified are vinylidene chloride, vinyl acetate and stearate, acrylates (e.g. butyl acrylate), maleates (e.g. dicetyl maleate), and mixtures thereof. Other polymers which may be mixed with the vinyl chloride polymers are synthetic rubbers, e.g. copolymers of butadiene with acrylonitrile and/or styrene, and chlorinated or sulphochlorinated polyolefines or mixtures thereof. The stabilizers may be mixed with ...

SILICON-TIN COMPOUNDS

POLYPHOSPHAZENE BLENDS

AMINOPHOSPHINATPOLYMERE

FLAMMHEMMENDE ZUSAMMENSETZUNG

POLYMER COMPOSITION WITH METAL ALKOXIDE CONDENSATION PRODUCT, ORGANIC SILANE CONNECTION AND BORON CONNECTION

PROCEDURE FOR THE PRODUCTION OF NEW CONDENSED POLYMERS PHOSPHAZENEN

ION-LEADING POLYMERE MATERIAL AND PROCEDURE FOR ITS PRODUCTION.

PROCEDURE FOR THE MIXTURE OF POLYPHOSPHAZENEN.

ARYLOXYALKOXY SUBSTITUTING POLYPHOSPHAZENE.

ARYLOXY ALKOXY ALKENYLPHENOXY SUBSTITUTING POLYPHOSPHAZENE.

FIRM ONE, MELT OPEN-CASH AND THERMAL HARDENABLE ONES MASS, THEIR PRODUCTION AND THEIR USE

WET-DEVELOPABLE ANTI-REFLECTIVE COMPOSITIONS

CHEMICAL MODIFICATION OF POLY BIS-ARYLOXYPHOSPHAZENE WITH AMINES

OLIGOMERS TERMINATED BY PERFLUOROALKYL CONTAINING MERCAPTO GROUPS, PROCESS FOR THEIR MANUFACTURE AND THEIR USE AS SURFACE TENSION DEPRESSANTS AND ADDITIVES IN FIRE FIGHTING COMPOSITIONS

POLY(DIALKYLAMINOARYLOXYPHOSPHAZENE) POLYMERS AND FOAMS

YOU CONDUCTING MACROMOLECULAR MATERIAL, AND ITS MANUFACTURE

Matériau macromoléculaire à conduction ionique constitué par un sel en solution dans un matériau macromoléculaire, lui-même constitué par un polymère organométallique. Application à la réalisation de générateurs électrochimiques.

PROCESS FOR THE PREPARATION OF POLYADDITION PRODUCTS CONTAINING PHOSPHORUS

... of the disclosure Compounds of the formula wherein Z is alkyl with 2 to 6 carbon atoms, x is oxygen, NH or sulfur, n and m are integers from 2 to 6, r is zero or 1, R4, R5 R6 and R7 are hydrogen or methyl and R3 is methyl, ethyl or phenyl. They are obtained by reacting 1 mole of a compound of formula Z-(X-H)n with n?m moles of an alkyleneoxide or alkylenecarbonate of the formulas and and n(m+r) moles of a phospholane of formula These compounds are used as flameproofing agents especially for pile carpets.

NAPHTHALENIC DERIVATIZED PLASTICIZERS FOR POLYPHOSPHAZENE POLYMERS

Plasticized polyphosphazene compositions exhibiting excellent flame resistance and low smoke output are disclosed. The plasticizers are resinous alkylated naphthalenes condensed with formaldehyde which are characterized by methylene bridges between naphthalenic rings with softening points ranging from 28.degree.F. to 158.degree.F. These plasticized resins are useful in the production of foams, insulation, cushioning formulations, wire coating formulations and other low smoke, low flammability formulations.

PREPARATION OF ELECTRICALLY CONDUCTIVE HETERO- POLYPHENYLENES

A process for the preparation of electrically conductive hetero-poly-phenylenes, having conductivities greater than 10-2S/cm, wherein from 0.5 to 35 per cent by weight of a strong Lewis acid having a pka of from -10 to +4, preferably AsF5, SbF5, UF6, HCLO4, NO+SbF6-, NO2+SbF6-, NO+AsF6-, NO+PF6-, NO2+PF6-, NO+BF4-, NO2+BF4-, NO+CLO4-, (CF3)2SO4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenyl-sulfonic acid or 2,4,6-trinitrobenzoic acid, is added to a hetero-polyphenylene the absence of moisture and of oxygen.

CURABLE BINDING SYSTEMS

A curable binder for use in forming a castable propellant of the hydroxy terminated polybutadiene type uses two bonding agents, an aziridine polyester and an amine polyester. The amount of aziridine polyester is reduced by a factor of 3 to 4 compared to known systems. Improved propellant properties, including elongation at maximum load, and at rupture while maintaining comparable tensile strength and initial moduli, are obtained. A diisocyanate curing agent, an antioxidant such as phenyl-beta-naphthyl amine and isodecyl pelargonate as a plasticizer may be included.

METAL 8-HYDROXYQUINOLATE COMPLEXES AS STABILIZERS FOR POLY(PHOSPHAZENES) TO INHIBIT MAL DEGRADATION AT ELEVATED TEMPERATURES

Stabilization of polyphosphazenes against thermal degradation is achieved by the incorporation in the polyphosphazenes of 0.05 to 5.0% by weight of composition of metal complexes of 8-hydroxy-quinolates wherein the metal is of the group of alkali metals, alkaline earth metals including Mg, and Al, Zn and Cr.

PROCESS FOR THE PREPARATION OF POLY (HALOARYLOXYPHOSPHAZENE) HOMOPOLYMERS

Poly(haloaryloxyphosphazenes) which consist of recurring units represented by the following general formula in which n is between 20 and 50,000 and R1, R2 and R3 are monovalent radicals selected from the group consisting of H, Cl, Br, and alkyl (one to five carbon atoms) and at least one R group is halogen, the improvement which comprises the formation of the polymer by reaction of poly(dichlorophosphazene) with a stoichiometric excess of alkali metal salt of a phenol substituted in at least one of the meta or para positions at a temperature and length of time between about 115.degree.C for 100 hours and about 160.degree.C for about 5 hours, whereby a poly(haloaryloxyphosphazene) product free from P-Cl sites and soluble in tetrahydrofuran is obtained. The polymers of this invention are film formers, which often can be rendered into fibers. Many of these poly(aryloxyphosphazenes) are particularly useful in flame-retardant applications in the form of wire insulation, structural composites ...

TITANIC ACID ESTER-CONTAINING BINDER FOR COATING MATERIALS AND REFRACTORY SHAPED BODIES AS WELL AS PROCESS FOR THE PRODUCTION OF THESE BINDERS

POLYMERIC HINDERED PHOSPHONATE STABILIZERS

Verfahren zum Stabilisieren von vinylchloridhaltigen Polymerisaten

Verfahren zur Herstellung von linearen polymeren Zinnalkylenchloriden

АЛКОКСИПРОИЗВОДНЫЕ ТИТАНА КАК ГИДРОФОБИЗАТОРЫ ЦЕЛЛЮЛОЗОСОДЕРЖАЩИХ МАТЕРИАЛОВ И ИЗДЕЛИЙ ИЗ НИХ И СОСТАВ КОМПОЗИЦИИ ДЛЯ ПРОПИТКИ

Изобретение касается алкоксипроизводных титана, которые являются частично гидролитически конденсированными, общей формулы: [(R'O)Tio3-x/2(OR)x]n, где: R - алифатический, насыщенный, нормального или изостроения алкильный радикал ряда С1-С4 или частично -R'; R' - алифатический, насыщенный, нормального или изостроения алкильный радикал ряда С6-С23; x = 0,1-3; n = до 30, с содержанием алкоксигрупп OR ряда С1-С4 от 60 до 1,5 % мас., как гидрофобизаторов целлюлозосодержащих материалов и изделий из них. Также изобретение касается состава для пропитки, содержащего указанные соединения и растворитель.

固化促进剂、环氧树脂组合物及半导体装置

... 本发明公开了一种用于各种固化性树脂的固化促进剂和、固化性，保存性，流动性良好的环氧树脂组合物及其耐焊锡裂纹性、耐湿可靠性优良的半导体装置。本发明所述环氧树脂组合物，含有，在一个分子内具有2个以上的环氧基的化合物(A)和在一个分子内具有2个以上的酚性羟基的化合物(B)和作为三取代膦翁苯酚化物或其盐的固化促进剂(C)和无机填充材料(D)。 ...

METAL 8-HYDROXYQUINOLATE COMPLEXES AS STABILIZERS FOR POLY- PHOSPHAZENES- TO INHIBIT THERMAL DEGRADATION AT ELEVATED TEMPERATURES

APPLICATION OF COMPOSE OXYGENS TO FACILITATE THE DISSOLUTION OF POLY (DICHLOROPHOSPHAZENES)

MACROMOLECULAR MATERIAL HAS IONIC CONDUCTION FOR the REALIZATION Of ELECTROLYTES OR ELECTRODES

리소그래피 도포를 위한 소형 분자로부터의 금속-산화물 필름

... 리소그래피 도포를 위한 금속-산화물 필름이 제공된다. 필름은 금속 및 규소 이외의 준금속을 포함하는 금속-산화물 전구체 화합물을 포함하는 조성물로부터 형성된다. 이러한 필름은 쉽게 제조되고, 알콕사이드, 페녹사이드, 카르복실레이트, 베타-디케톤, 및 베타-케토에스테르를 포함하는 다양한 리간드로써 개질될 수 있다.

METHOD FOR PRODUCING METAL OXIDE FIBERS, AND METAL OXIDE FIBERS

RELEASE CONTROLLING COMPOSITION

PURPOSE: A release controlling composition and a silicon release coating composition are provided, which vaporization temperature is elevated and freezing point is lowered. CONSTITUTION: The release controlling composition comprises one or more alkenyl functional siloxanes, and one or more branched olefins represented by the formula 1, wherein the total number of carbons is at least 20, n and m are independently an integer of 0-20, and x, y and z are independently an integer of 1-12. The silicon release coating composition comprises one or more alkenyl functional polyorganosiloxanes containing at least two silicon-binding alkenyl group per molecule; one or more organohydrogensiloxanes containing at least two silicon-binding hydrogen group per molecule; a catalyst containing metals of platinum group; and the release controlling composition. COPYRIGHT 2000 KIPO ...

Ativador catalisador de aluminoxano modificado

SOLID MAO COMPOSITION CONTAINING AL2O3 AND METHOD FOR PRODUCING SAME

Provided is a solid polymethylaluminoxane composition which has higher activity when being used as a co-catalyst in olefin polymerization. The solid polymethylaluminoxane composition contains polymethylaluminoxane, trimethylaluminum, and Al2O3, wherein: (i) the aluminum content is within the range of 36-43 mass%; and (ii) the Al2O3 content is within the range of 0.001-10 mol% represented in terms of aluminum.

Macromonomers having reactive end groups

A soluble rigid-rod macromonomer is provided which has the following formula: см. иллюстрацию в PDF-документе wherein each A1, A2, A3, and A4, on each monomer unit, independently, is C or N, and each G1, G2, G3, and G4, on each monomer unit, independently, is H or a solubilizing side group, provided that at least one monomer unit has at least one solubilizing side group. The solubilizing side groups provide the macromonomers with a solubility of at least 0.5% by weight in the solvent system from which they are formed. E is a reactive end group, and the macromonomer has an average degree of polymerization, DPn, greater than 6. Such macromonomers are chemically incorporated into polymer systems to provide stronger stiffened polymers.

PRINTING PLATES DOPED WITH RELEASE OIL

An imaging member surface contains a swellable elastomer doped with a release oil. This aids in complete transfer of ink to a receiving substrate when a thin film of release oil forms upon the surface during application of pressure at the nip.

Process for preparing and purifying alkoxyphosphazene polymer

Alkoxyphosphazene polymer is prepared in a homogeneous system by admixing chloropolymer dissolved in cyclohexane or a mix of cyclohexane and C5-C7 alkane with alkali metal alkoxide dissolved in tetrahydrofuran, reacting, desalting the resulting reaction solution and concentrating by a first step involving admixing non-solvent which is cyclohexane (and/or C5-C7 alkane if that is also present in the reaction solution) to cause coagulation thereby forming a higher viscosity rubber phase enriched in polymer and a lower viscosity liquid phase depleted in polymer and separating the rubber and liquid phases and a second step involving evaporating the residual solvent and non-solvent. The first concentrating step is preferably carried out utilizing an extruder.

Aryloxy-alkoxy-alkenylphenoxy-substituted polyphosphazenes

硬化性組成物

METHOD FOR MANUFACTURING OPTICAL MATERIAL RESIN, OPTICAL MATERIAL RESIN AND PLASTIC LENS

PROBLEM TO BE SOLVED: To develop a plastic lens which reduces or eliminates an offensive smell and a nasty smell caused on cutting and polishing the plastic lens, is suitably used as a glasses lens and the like, and is obtained by subjecting a plastic lens monomer having a specific structure to polymerization and curing and its manufacturing method. SOLUTION: An optical material resin which can reduce or eliminate an offensive smell and a nasty smell caused on cutting and polishing the optical material resin is produced by adding one or more compounds selected from citronellal, cineol, methyl anthranilate, ethyl anthranilate, dimethyl anthranilate, limonene, α-terpineol, ethyl enanthate, methyl enanthate, isopropyl enanthate, vinyl enanthate, methyl caprylate, ethyl caprylate, methyl nonanoate, and ethyl nonanoate as a perfume composition into the above optical material resin monomer. COPYRIGHT: (C)2009,JPO&INPIT ...

Harzzusammensetzung mit anisotropischen Schmelzeigenschaften.

POLYPHOSPHAZENE POLYMER/ORGANIC POLYMER BLENDS AND FOAMS THEREFROM

POLYPENTAERYTHRITYLDIPHOSPHONAT AND ITS USE IN SELF-EXTINGUISHING THERMOPLASTIC COMPOSITIONS

FLAME PROTECTION CENTRAL COMBINATION

VERFAHREN ZUR HERSTELLUNG VON NEUEN SILICIUM-ZINN-VERBINDUNGEN

PROCEDURE FOR THE PHOTO-INITIATED CONTROLLING OF THE INORGANIC NETWORK FORMATION WITH SOL GELPROZESS.

FLAME RETARDING COMPOSITION

STABILIZATION OF POOLYPHOSPHAZENES

ORGANOTIN COMPOUNDS AS COLOR AND CORROSION INHIBITORS IN THERMOPLASTIC POLYMER COMPOSITIONS AINING FLAME RETARDANTS

HALOGEN-FREE LOW-FLAMMABILITY FILMS

Mo-2175 LeA 20,151 HALOGEN-FREE LOW-FLAMMABILITY FILMS The invention is directed to compositions comprising halogen-free aromatic polycarbonates and halogen-free aromatic polyphosphonates suitable for producing films of improved flame resistance and to processes for their preparation. LeA 20,151 ...

POLYPHOSPHAZENE PLASTICIZED RESINS

RJH:KSH 1-28-77 5562 POLYPHOSPHAZENE PLASTICIZED RESINS Flame-retardant and low-smoke plasticized polyphosphazenes are disclosed. The plasticizers are substituted cyclotriphosphazenes and cyclotetraphosphazenes.

POLY (ALKOXYARYLOXYPHOSPHAZENE) ELASTOMERS

PHOSPHAZENE RUBBER LATICES

This invention relates to aqueous dispersions or latices of phosphazene rubbers which are useful in the production of coatings and foams particularly where fire resistant materials are required, and to the resulting coatings and foams prepared using such latices.

POLYESTER COMPOSITION CONTAINING A POLYMER OF BENZENE PHOSPHORUS OXYDICHLORIDE, A DIPHENOL AND POCL3

SMOKE-SUPPRESSANT ADDITIVES FOR POLYPHOSPHAZENES

POLYPHOSPHAZENE BLENDS

STABILIZATION OF POLY(PHOSPHAZENES)

PHOSPHAZENE RUBBER LATICES

ADDITION OF SILICONE GUM RUBBER TO PHOSPHONITRILIC FLUOROELASTOMERS MPROVE MILL PROCESSING, LOW TEMPERATURE FLEXIBILITY AND VOLUME L IN LOW AROMATIC CONTENT FLUIDS

COBALT BEARING POLYMERIC COMPOSITIONS

The invention relates to polymeric cobalt bearing compounds, in particular for use as metal-rubber adhesion promoters (RAPs) in tires, belts and hoses. Known active substances are a.o. cobalt stearates, naphthenates, resinates, decanoates, boro-decanoates and many other forms of acylates. While these substances appear to enhance the metal-rubber adhesion, all of them also come with significant drawbacks, a.o. linked to the relatively high bioavailability of cobalt in these substances. The invention concerns more particularly a polymer comprising Co-carboxylate sequences, with a Co content of at least 3% by weight, and with a mean molecular weight of more than 2000. Several synthesis methods, allowing to reach relatively high Co concentrations in the polymer, illustrate the invention. The invented polymers show a strongly reduced bioavailability of Co compared to currently available products, as demonstrated by aqueous leaching tests. As RAPs, they perform similarly to commercial products ...

POLYMETHYLALUMINOXANE OF ENHANCED SOLUTION STABILITY

Polymethylaluminoxane compositions having increased solution stability in organic solvent and, in some cases, increased polymerization activity, which comprise moieties derived from an organic compound containing an electron- rich heteroatom (e.g., from Group V and/or Group VI of the Periodic, Table) and a hydrocarbyl moiety. These compositions can be formed by reaction of trimethylaluminum, the organic compound, and water. They can also be formed by ruction of pre-formed polymethylaluminoxane the organic compound, which can be a hydrocarbyl group-containing compound containing an electron-rich heteroatom (e.g., oxygen, nitrogen, or sulfur), either-with or without an active hydrogen atom connected to the heteroatom. The organic compound, in some embodiments, has also been found to be effective in increasing the catalytic activity of modified polymethylaluminoxane which, in addition to methyl, contain C2 and higher alkyl groups for enhanced solution stability.

MACROMONOMERS HAVING REACTIVE END GROUPS

... 2115143 9304099 PCTABS00020 Rigid-rod macromonomers, and methods for preparing such macromonomers, having a polyaromatic backbone, solubilizing side groups, and reactive end groups are provided. The macromonomers are chemically incorporated into polymer systems to provide stronger, stiffened polymers.

MIXER SYSTEM FOR THE PRODUCTION OF WATER-THINNABLE COATING COMPOSITIONS

The present invention relates to a mixer system for the production of water-thinnable coating compositions having a precisely defined color shade, from various base colors, which mixer system is characterized in that it comprises A) various base colors A which contain less than 5% by weight of water, at least one color and/or effect pigment, organic solvent, at least one water-dilutable or water-dispersible acrylic polyurethane resin (A1) and/or polyacrylate resin (A2) and optionally auxiliaries and additives, and B) at least one pigment-free component B which contains water. The present invention also relates to a process for the production of coating compositions using this mixer system and to the use of the mixer system for the production of aqueous basecoats for the coating of automobile stagecoaches ¢sic! and/or plastic parts, in particular for automotive refinishing.

PRODUCTION OF HYDROCARBON-SOLUBLE HYDROCARBYLALUMINOXANES

Novel aluminum-containing compositions having increased paraffin-solubility are produced from a methylaluminoxane composition having lower paraffinsolubility. These compositions are formed by mixing in liquid phase (A) at least one aluminum trialkyl (or solution or suspension formed therefrom), where the aluminum trialkyl has at least 30 carbon atoms in the molecule, where each alkyl group thereof is bifurcated in the 2-position into a pair of branches, where one such branch has n carbon atoms and the other such branch has at least n + 2 carbon atoms, and where n is at least 3; and (B) at least one methylaluminoxane composition having lower heptane-solubility (or a solution or slurry formed therefrom). Preferably, the resultant mixture is agitated at one or more elevated temperatures at which the mixture becomes even more homogeneous. The aluminum trialkyl preferably is one or more in which there are at least 36 carbon atoms in the molecule, in which n is at least 4 and in which the longer ...

COMPOSITION FOR TREATMENT OF CELLULOSE-CONTAINING MATERIAL and PRODUCTS BASED ON THEM

АЛКОКСИПРОИЗВОДНЫЕ ТИТАНА КАК ГИДРОФОБИЗАТОРЫ ЖИВОТНЫХ КОЖ И ИЗДЕЛИЙ ИЗ НИХ И СОСТАВ КОМПОЗИЦИИ ДЛЯ ПРОПИТКИ

Изобретение касается алкоксипроизводных титана, которые являются частично гидролитически конденсированными, общей формулы: [(R'O)Tio3-x/2(OR)x]n, где: R – алифатический, насыщенный, нормального или изостроения алкильный радикал ряда С1-С4 или частично -R'; R' – алифатический, насыщенный, нормального или изостроения алкильный радикал ряда С6-С23; x = 0,1-3; n = до 30, с содержанием алкоксигрупп OR ряда С1-С4 от 60 до 1,5 % масс., как гидрофобизаторов животной кожи и изделий из неё. Также изобретение касается состава композиции для пропитки, содержащего указанные соединения и растворитель.

Modified alumoxane catalyst activator

Organic/inorganic hybrid material, composition for synthesizing the same and process for producing the hybrid material

An organic-inorganic hybrid material chelating a metal atom of a metal oxide matrix 103 in a pendant shape is synthesized, where the organic compound (the functional chelating agent) 104 is able to develop a function of a coloring property, a light-emitting property, or semiconductivity by chelating a metal atom. As a synthesis method, sol (a composition for coating application) including a metalalkoxide and/or a metal salt and a functional chelating agent may be prepared and the organic-inorganic hybrid material may be synthesized by sol-gel method. Due to the above-mentioned structure, it is possible to synthesize an organic-inorganic hybrid material that has an organic group directly bonded to a metal oxide matrix and is able to develop a different function from that of a mere metal oxide. In other words, it is possible to realize a functional organic-inorganic hybrid material that develops a coloring property, a light-emitting property, or semiconductivity due to the organic group directly ...

POWDER FORMED OF "CUCUR-SHELL" TYPE PARTICLES COMPRISING RARE EARTH-BASED COORDINATION POLYMERS, METHOD FOR OBTAINING SAME, MATERIAL AND USE THEREOF

POLYMERIC PHOSPHATES OF 2-ARYLOXYETHYLE

COMPOSITION OF SETTING BINDER FOR COMPOSITE PROPELLANT AND APPLICATION

Thermoelectric materials using finely dispersed and long-tangled thread shaped carbon nano tubeand preparation method thereof

POLYCARBONATE RESIN COMPOSITION AND MOLDED BODY

This polycarbonate resin composition contains: (A) 100 parts by mass of a resin mixture containing a specific polycarbonate-polyorganosiloxane copolymer (A-1) and a specific polycarbonate-polyorganosiloxane copolymer (A-2), where in component (A), the siloxane unit content in the polycarbonate-polyorganosiloxane copolymer (A-1) is 1.0-15.0 mass% and the siloxane unit content in the polycarbonate-polyorganosiloxane copolymer (A-2) is 0.1-2.8 mass%; and (B) 0.01-0.08 parts by mass of at least one selected from an alkali metal salt of an organic sulfonic acid and an alkaline earth metal salt of an organic sulfonic acid.

IONENE POLYMERS AND THEIR USE AS ANTIMICROBIAL AGENTS

Disclosed are ionene polymers having antimicrobial activity. "Ionene polymers" as used in this invention are cationic polymers in which a substantial proportion of the atoms providing the positive charge are quaternized nitrogens located in the main polymeric chain or backbone of the polymer rather than in pendant groups. Also disclosed are antimicrobial compositions comprising ionene polymers and methods for treating microbial infections in mammals comprising the step of administering to a mammal, a therapeutically effective amount of at least one antimicrobial composition of the invention. Also disclosed are antimicrobial compositions comprising at least one ionene polymer and methods for preventing, inhibiting or eliminating the growth, dissemination, and/or the accumulation of microorganisms on a susceptible surface (including, but not limited to, the formation of biofilms on a susceptible surface) comprising the step of contacting suchsurface with a composition of the invention.

Polyacid/polyalkylene oxide gels and methods for their delivery

The present invention relates to improved methods for delivering bioadhesive, bioresorbable, anti-adhesion compositions. Antiadhesion compositions can be made of intermacromolecular complexes of carboxyl-containing polysaccharides, polyethers, polyacids, polyalkylene oxides, multivalent cations and/or polycations. The polymers are associated with each other, and are then used as fluids, gels or foams. By providing a product bag, the compositions can be delivered as gels or as sprays. By dissolving propellant gases in the compositions, the materials can be delivered as foams, which have decreased density, and therefore can adhere to surfaces that previously have been difficult to coat with antiadhesion gels. Delivery systems can also provide mechanisms for expelling more product, and for directing the flow of materials leaving the delivery system. Bioresorbable, bioadhesive, anti-adhesion, and/or hemostatic compositions are useful in surgery to prevent the formation and reformation of post-surgical ...

Metal-nitrogen polymer compositions comprising organic electrophiles

The compositions of this invention comprise uncrosslinked reaction mixtures comprising (1) at least one organic monomer, oligomer or polymer comprising a multiplicity of organic, electrophilic substituents, and (2) at least one metal-containing polymer comprising a metal-nitrogen polymer. Preferred compositions of this invention comprise reaction mixtures comprising (1) at least one organic monomer, oligomer or polymer comprising a multiplicity of organic, electrophilic substituents, and (2) at least one of: silicon-nitrogen polymers, aluminum-nitrogen polymers and boron-nitrogen and polymer combinations thereof comprising a multiplicity of sequentially bonded repeat units the compositions comprising the reaction products of the reaction mixtures, and the compositions obtained by crosslinking the reaction products of the reaction mixtures. The crosslinking may be effected through at least one of thermal-based, radiation-based free radical-based or ionic-based crosslinking mechanisms. Furthermore ...

Curing accelerator, epoxy resin composition, and semiconductor device

A curing accelerator which is suitable for various curable resin compositions, an epoxy resin composition having excellent curability, storage stability and fluidity, and a semiconductor device having excellent solder cracking resistance and moisture resistance reliability are provided. The epoxy resin composition includes a compound (A) having two or more epoxy groups in one molecule, a compound (B) having two or more phenolic hydroxyl groups in one molecule, trisubstituted phosphoniophenolate or a salt thereof as a curing accelerator (C), and an inorganic filler (D).

Flame-retardant, stress crack resistant polycarbonate ABS moulding composition

A polyphosphazene composition stabilized against thermal aging and use therof

COMPOSITION FOR FORMATION OF POSITIVE METAL OXIDE THIN FILM PATTERN AND FORMING METHOD OF POSITIVE METAL OXIDE THIN FILM PATTERN

PROBLEM TO BE SOLVED: To form a positive metal oxide thin film pattern by a solgel method. SOLUTION: This compsn. for formation of a positive metal oxide thin film pattern contains a metal alkoxide and a compd. which generates an etching assistant by irradiation of light. The compsn. is applied on a substrate and irradiated with light so that the difference in the solubility between the irradiated part and the non-irradiated part due to the photolytic reaction in the irradiated part is used for patterning. The metal alkoxide reacts with the etching assistant produced by irradiation of light and changed to be soluble with a solvent. In the irradiated part, the metal alkoxide becomes soluble with a solvent, while in the non-irradiated part, a hydrolyzable metal alkoxide is hydrolyzed with the water content in air to produce a metal hydroxide which is insoluble with the solvent. By developing the film with a solvent after irradiation of light, only the irradiated part is dissolved and removed ...

POLYPHOSPHAZENE BLEND COMPOSITION FOAMED BODY

Полимерная композиция

MISCHUNGEN AUS VOLL-AROMATISCHEN POLYESTERN UND/ODER POLYCARBONATEN UND/ODER POLYESTERCARBONATEN, AROMATISCHEN POLYPHOSPHONATEN UND POLYEPOXIDEN, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ZUR HERSTELLUNG VON FORMKOERPERN, FOLIEN UND FASERN

VERFAHREN ZUR HERSTELLUNG VON LOESUNGEN VON IM WESENTLICHEN LINEAREN POLYDIHALOPHOSPHAZENEN

Beschlagfreier Film, optischer Gegenstand und Verfahren zur Herstellung

POLY-(ALKOXYARYLOXYPHOSPHAZEN)-ELASTOMERE UND VERFAHREN ZU DEREN HERSTELLUNG

POLY-FLUOROALKOXYPHOSPHAZENES-

... 1463242 Polyphosphazene polymers HORIZONS RESEARCH Inc 21 Jan 1975 [25 Jan 1974] 2672/75 Heading C3R The physical properties of polyfluoroalkoxy phosphazene polymers of molecular weight between 3 Î 104 and 3 Î 106 are improved by adding to them lower molecular weight phosphazene oils of formula where n is 3 to 100 and R F and R1 F are m being from 1 to 10, q being from 1 to 20 and Z being F or H. The polymer may have units of formula where Q and Q1 are randomly distributed groups -OCH 2 CF 3 and -OCH 2 CF 2 CF 2 CF 3 . Fillers and curing agents also may be added. In examples fluoroalkoxyphosphazene oils are added to poly(fluoroalkoxyphosphazene) polymers, the compositions also containing magnesium oxide, silica and carbon black as fillers and dicumyl peroxide as a curing agent.

Thin film solar cell

[Object] A thin-film solar cell which can be produced using an inexpensive raw material and has improved conversion efficiency has been desired. [Solution] A thin-film solar cell according to the present invention includes at least one organic semiconductor and a coordination polymer. The coordination polymer contains a repeating unit which includes a complex produced by coordinating at least one ligand to at least one metal ion, the metal ion being selected from ions of transition metal elements, and the ligand being capable of coordinating to the metal ion and selected from sulfur-containing compounds, nitrogen-containing compounds, oxygen-containing compounds, and phosphorus-containing compounds.

Metalloporphyrin Polymer Functionalized Substrate

A method is provided for fabricating a metalloporphyrin polymer on a substrate. The method creates a functionalized substrate by attaching an anchor group of a linker, including a terminal alkyne group, to a substrate surface. The functionalized substrate is then exposed to metalloporphyrin monomers, where each metalloporphyrin monomer includes at least two terminal alkyne groups. A plurality of metalloporphyrin monomers (e.g., zinc porphyrin monomers) are thus linked via the metalloporphyrin monomer terminal alkyne groups, forming a metalloporphyrin polymer attached to the substrate. In one aspect, linking the plurality of metalloporphyrin monomers via the metalloporphyrin monomer terminal alkyne groups includes forming butadiyne groups between adjacent metalloporphyrins. Then, forming the metalloporphyrin polymer attached to the substrate includes attaching the metalloporphyrin polymer, via a metalloporphyrin monomer terminal alkyne group, to the terminal alkyne group of an associated linker. Alternatively stated, the metalloporphyrin polymer is attached to the substrate via a polyalkyne group.

TRUE NANOSCALE ONE AND TWO-DIMENSIONAL ORGANOMETALS CONTINUATION

A number of new classes of polymers with the potential for electrical conduction are introduced sharing a common theme, having metal atoms in direct contact with each other, bound in one and two-dimensional structures guided by steric, dipole and coordinating ligand factors. These new classes include a new family of metallole polymers in a polycyclic arrangement, both standing alone and with chains of metal atoms coordinated to their electronegative backbone atoms, new polymers of group 13 and 14 metals and metalloids, with substituents connected through an electronegative bonding atom, and a new class of close stacked porphyrin polymers, assembled with short molecular linkers perpendicular to the faces of the porphyrin units. These new materials empower new classes of capacitors, batteries and electrical conductors, even superconductors. 2. The polymer of claim 1 , where metal atoms in the zero oxidation state claim 1 , in tandem conductive chains claim 1 , are co-deposited with and coordinated to the heteroatoms in the polymer claim 1 , one atom of metal per nitrogen.3. The polymer of claim 2 , where the metal atoms are either silver or copper.4. The polymer of used to store electrical power.5. The polymer of claim 4 , where the polymer participates in a redox reaction as a component in the anode or the cathode of a battery.6. The polymer of where the polymer is produced under the influence of magnetic claim 1 , electric and/or electromagnetic fields strong enough to orient the polymer molecules directionally.23. The polymer of claim 22 , where the polymer participates in a redox reaction as a component in the anode or the cathode of a battery.24. The polymer of claim 1 , where there are at least 50 repeating units claim 1 , consistent with the plain meaning distinction between the scientific definitions of the words “oligomer” and “polymer.”25. The polymer of claim 21 , where there are at least 50 repeating units claim 21 , consistent with the plain meaning ...

MONOMERS, OLIGOMERIC COMPLEXES, COORDINATION POLYMERS, AND METHODS FOR THEIR PREPARATION AND USE

A hydrogel composition is formed by conveying separate first and second liquid components subject to a selectively applied application pressure P(A) into an outlet path for mixing and discharge. A liquid flushing agent is automatically conveyed into the outlet path subject to a substantially constantly applied purge pressure P(P) when the application of P(A) is interrupted, to continuously flush residual hydrogel composition from the outlet path. 1. A monomer compound ligand comprising:{'sup': 1', '2', '3', '4, 'four pyridyl groups defined as pyridyl group Py, pyridyl group Py, pyridyl group Py, and pyridyl group Py; and'}a central linker portion; wherein:{'sup': 1', '2', '3', '4, 'pyridyl group Pyis covalently bonded to the central linker portion, pyridyl group Pyis covalently bonded to the central linker portion, pyridyl group Pyis covalently bonded to the central linker portion, and pyridyl group Pyis covalently bonded to the central linker portion; and'}{'sub': '2', 'the central linker portion includes at least one of a phenylenediamine group, a phenyl group, a terphenyl group, a biphenyl group, poly-aromatic hydrocarbon (PAH) group, or a (methylbenzene)group.'}2. The monomer compound of claim 1 , wherein the central linker portion comprises a phenylenediamine group and the phenylenediamine group has a 1 claim 1 ,4 (para) orientation of the first amine group and second amine group.3. The monomer compound of claim 1 , having the structure (PyPy)N—CH—N (PyPy).4. The monomer compound of claim 1 , wherein Pyand Pyare the same claim 1 , and Pyand Pyare the same.5. The monomer compound of claim 1 , wherein Py claim 1 , Py claim 1 , Py claim 1 , Pyare the same.6. The monomer compound of claim 1 , wherein the monomer compound is N claim 1 ,N claim 1 ,N′ claim 1 ,N′-tetra(4-pyridyl)-1 claim 1 ,4-phenylenediamine.7. The monomer compound of claim 1 , wherein the monomer compound is N claim 1 ,N-di(2-pyridyl)-N′ claim 1 ,N′-di(4-pyridyl)-1 claim 1 ,4-phenylenediamine.815-. ...

Composition and Preparation for Hafnium Carbide Ceramic Precursor

Metal containing polymer compositions, useful for the production of high temperature metal carbide ceramics are described, including poly(carbohafnocene) compositions and related poly(carbometallocene) compositions, as well as compositions formed from the reaction of hafnium chloride and 2-butyne-1,4-diol. Methods of synthesizing such compositions are provided.

Electrode Catalyst and Method for Producing the Same

An electrode catalyst obtained by calcining a metal phthalocyanine polymer having a repeating structural unit obtained by the amide bonding of a structural unit represented by general formula (1a) to a structural unit represented by general formula (2a) to form a calcined body, then treating the calcined body with an acid. Formula (1a) (wherein L is a divalent or trivalent metal ion belonging to Period 3 to Period 5 on the long-form periodic table.) Formula (2a) (wherein M is a divalent or trivalent metal ion belonging to Period 3 to Period 5 on the long-form periodic table.) 2. The electrode catalyst according to claim 1 , wherein the L and the M are each independently a metal ion selected from the group consisting of Co claim 1 , Ni and Fe.36.-. (canceled)7. The electrode catalyst according to claim 1 , wherein the acid is aqua regia.8. (canceled)9. The electrode catalyst according to claim 1 , wherein the calcination is carried out at 800° C. to 1000° C. claim 1 , in a reducing gas atmosphere.11. The electrode catalyst according to claim 10 , wherein the L and the M are each independently a metal ion selected from the group consisting of Co claim 10 , Ni and Fe.1214.-. (canceled)15. The electrode catalyst according to claim 10 , wherein the ratio of the total amount of the L and the M is 50 to 99.9% by weight claim 10 , based on the total amount of the L and the M contained in the metal phthalocyanine polymer before calcination.1617.-. (canceled)18. The electrode catalyst according to claim 10 , wherein the calcination is carried out at 800° C. to 1000° C. claim 10 , in a reducing gas atmosphere.20. The electrode catalyst according to claim 19 , wherein the L and the M are each independently a metal ion selected from the group consisting of Co claim 19 , Ni and Fe.2124.-. (canceled)25. The electrode catalyst according to claim 19 , wherein the acid is aqua regia.26. (canceled)27. The electrode catalyst according to claim 19 , wherein the calcination is carried ...

METHOD FOR PRODUCING FLUORINE-CONTAINING POLYMER AND COMPOSITION THEREOF

An object of the present disclosure is to provide a method for producing a fluorine-containing polymer and a composition containing the fluorine-containing polymer. 1. A composition comprising:(A) a fluorine-containing polymer comprising as a main component a structural unit containing a fluorine-containing aliphatic ring; and(B) an aprotic solvent,wherein the fluorine-containing aliphatic ring of the fluorine-containing polymer (A) contains one, two, or three etheric oxygen atoms as a ring-constituting atom;when the fluorine-containing aliphatic ring contains a plurality of etheric oxygen atoms, the etheric oxygen atoms are not adjacent to each other; andthe fluorine-containing polymer (A) is present in an amount of 20 mass % or more based on the mass of the composition.2. The composition according to claim 1 , wherein the fluorine-containing polymer (A) is present in an amount of 20 mass % to 65 mass % based on the mass of the composition.3. The composition according to or claim 1 , wherein the fluorine-containing polymer (A) is present in an amount of greater than 20 mass % to 65 mass % based on the mass of the composition.4. The composition according to any one of to claim 1 , wherein the aprotic solvent (B) is at least one solvent selected from the group consisting of a perfluoroaromatic compound claim 1 , a perfluorotrialkylamine claim 1 , a perfluoroalkane claim 1 , a hydrofluorocarbon claim 1 , a perfluorocyclic ether claim 1 , a hydrofluoroether claim 1 , and an olefin compound containing at least one chlorine atom.5. The composition according to any one of to claim 1 , wherein the aprotic solvent (B) is a hydrofluoroether.6. The composition according to any one of to claim 1 , wherein the aprotic solvent (B) has a global warming potential (GWP) of 400 or less.7. The composition according to any one of to claim 1 , wherein the aprotic solvent (B) is at least one hydrofluoroether selected from the group consisting of {'br': None, 'sub': 2', 'p', '2', 'q, 'F( ...

µ-POLYOXO CROSSLINKED PHTHALOCYANINE COMPOUND, PREPARING METHOD THEREOF, AND NEAR INFRARED RAY ABSORBING AND REFLECTING COMPOSITION USING THE SAME

Disclosed herein are a μ-polyoxo crosslinked phthalocyanine compound, a preparing method thereof; and a near infrared ray absorbing and reflecting composition using the same, and more particularly, a μ-polyoxo crosslinked phthalocyanine compound having high absorption at a wavelength of 800 to 950 nm and high reflectance at a wavelength of 1200 nm or more, a preparing method of a μ-polyoxy crosslinked phthalocyanine compound simultaneously having near infrared ray absorption and reflection properties as described above, and a near infrared ray absorbing and reflecting composition using the μ-polyoxo crosslinked phthalocyanine compound. According to the exemplary embodiment of the present invention, there is provided a μ-polyoxo crosslinked molybdenum phthalocyanine compound capable of absorbing and reflecting near infrared ray at the same time. 2. The μ-polyoxo crosslinked molybdenum phthalocyanine compound of claim 1 , wherein it absorbs near infrared ray at a wavelength of 800 to 950 nm and reflects near infrared ray at a wavelength of 1200 nm or more.3. The μ-polyoxo crosslinked molybdenum phthalocyanine compound of claim 1 , wherein a difference between absorption of near infrared ray at a wavelength of 800 to 950 nm and reflectance of near infrared ray at a wavelength of 1200 nm or more is 30% or more.4. A preparing method of the μ-polyoxo crosslinked molybdenum phthalocyanine compound of claim 1 , the preparing method comprising: oxo crosslinking at least one non-metal phthalocyanine and phthalocyanine substituted with a molybdenum metal to each other.6. The μ-polyoxo crosslinked molybdenum phthalocyanine compound of claim 5 , wherein it absorbs near infrared ray at a wavelength of 800 to 950 nm and reflects near infrared ray at a wavelength of 1200 nm or more.7. The μ-polyoxo crosslinked molybdenum phthalocyanine compound of claim 5 , wherein a difference between absorption of near infrared ray at a wavelength of 800 to 950 nm and reflectance of near infrared ...

POLYMER-GRAPHENE LIQUID CRYSTAL FIBER AND A CARBON FIBER PRODUCED BY THE SAME AND METHOD FOR MANUFACTURING THE SAME

Provided is a manufacturing method of a graphene-based liquid crystal fiber including: polymerizing a first aromatic monomer on a graphene-based compound to prepare a graphene composite in which a first aromatic polymer is surface-polymerized on the graphene-based compound; wet-spinning the graphene composite to manufacture a hydrogel fiber; and polymerizing a second aromatic monomer on the hydrogel fiber to fill pores of the hydrogel fiber with a second aromatic polymer. 1. A manufacturing method of a graphene-based liquid crystal fiber comprising:(a) polymerizing a first aromatic monomer on a graphene-based compound to prepare a graphene composite in which a first aromatic polymer is surface-polymerized on the graphene-based compound;(b) wet-spinning the graphene composite to manufacture a hydrogel fiber; and(c) polymerizing a second aromatic monomer on the hydrogel fiber to fill pores of the hydrogel fiber with a second aromatic polymer.2. The manufacturing method of a graphene-based liquid crystal fiber of claim 1 , wherein a weight ratio of the graphene-based compound to the first aromatic monomer is 1:0.01 to 1:10.3. The manufacturing method of a graphene-based liquid crystal fiber of claim 1 , wherein in a process of (a) claim 1 , the first aromatic polymer which is surface-polymerized on the graphene-based compound forms a surface layer with a thickness of 0.1 to 1 nm.4. The manufacturing method of a graphene-based liquid crystal fiber of claim 1 , wherein in a process of (a) claim 1 , the surface polymerization of the first aromatic monomer is oxidation polymerization of the first aromatic monomer on a surface of the graphene-based compound.5. The manufacturing method of graphene-based liquid crystal fiber of claim 1 , wherein a weight ratio of the graphene composite to the second aromatic monomer is 1:0.1 to 1:100.6. The manufacturing method of graphene-based liquid crystal fiber of claim 1 , wherein the first aromatic monomer and the second aromatic ...

TWO-COMPONENT ANTI-CANCER COMPOSITION

Gold(I) complexes and gold(I) dithiocarbamate polymers as anticancer therapeutics. The Au(I) ion within the gold(I) complexes is coordinated to two phosphine ligands. The repeating unit formed by Au(I) ion coordinating to dithiocarbamte ligands are connected by Au(I)-Au(I) interactions within the gold(I) dithiocarbamate polymers. Also disclosed are methods of synthesis, pharmaceutical compositions incorporating the gold(I) complexes, pharmaceutical compositions incorporating the gold(I) dithiocarbamate polymers, and methods of treating cancer. 2: The composition of claim 1 , wherein the anion is a halide ion claim 1 , a trifluoromethanesulfonate ion claim 1 , a hexafluorophosphate ion claim 1 , a tetrafluoroborate ion claim 1 , or a perchlorate ion.3: The composition of formula (I) of claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rare a hydrogen claim 1 , and X is Cl.4: The composition of further comprising a pharmaceutically acceptable carrier and/or excipient.5: The composition of claim 4 , which comprises 0.01-100 μM of the gold(I) complex relative to the total volume of the composition.6: The composition of claim 4 , wherein the pharmaceutically acceptable carrier and/or excipient is at least one selected from the group consisting of an organic solvent claim 4 , an inorganic salt claim 4 , a surfactant claim 4 , and a polymer.720-. (canceled) This application claims the benefit of priority of U.S. Provisional Application No. 62/486,169 filed Apr. 17, 2017, the entire contents of which are herein incorporated by reference.This project was funded by the National Plan for Science and Innovation (MARIFAH)-King Abdulaziz City for Science and Technology (KACST) through the Science and Technology Unit at King Fahd University of Petroleum and Minerals (KFUPM) of Saudi Arabia, award No. 14-MED64-4.Aspects of this technology are described in an article “Synthesis, ...

METHOD OF TREATING CANCER WITH A TWO-COMPONENT ANTI-CANCER COMPOSITION

Gold(I) complexes and gold(I) dithiocarbamate polymers as anticancer therapeutics. The Au(I) ion within the gold(I) complexes is coordinated to two phosphine ligands. The repeating unit formed by Au(I) ion coordinating to dithiocarbamte ligands are connected by Au(I)—Au(I) interactions within the gold(I) dithiocarbamate polymers. Also disclosed are methods of synthesis, pharmaceutical compositions incorporating the gold(I) complexes, pharmaceutical compositions incorporating the gold(I) dithiocarbamate polymers, and methods of treating cancer. 16-. (canceled)8. The method of claim 7 , wherein the cancer is resistant to cisplatin.9. (canceled)10. The method of claim 7 , wherein 1-300 mg/kg of gold(I) complex of formula (I) is administered per body weight of the subject.1120-. (canceled) This application claims the benefit of priority of U.S. Provisional Application No. 62/486,169 filed Apr. 17, 2017, the entire contents of which are herein incorporated by reference.This project was funded by the National Plan for Science and Innovation (MARIFAH)-King Abdulaziz City for Science and Technology (KACST) through the Science and Technology Unit at King Fahd University of Petroleum and Minerals (KFUPM) of Saudi Arabia, award No. 14-MED64-4.Aspects of this technology are described in an article “Synthesis, Characterization and in vitro Cytotoxicity of Gold(I) Complexes of 2-(Diphenylphosphanyl)ethylamine and Dithiocarbamates” published in Journal of Inorganic and General Chemistry, 2016, 642, (24), 1454-1459, on Nov. 3, 2016, which is incorporated herein by reference in its entirety.The present invention relates to therapeutic gold(I) complexes, a pharmaceutical composition thereof, and a method of treating cancer. The present invention further relates to therapeutic gold(I) dithiocarbamate polymers, a pharmaceutical composition thereof, and a method of treating cancer.The “background” description provided herein is for the purpose of generally presenting the context of the ...

GOLD(I) COMPLEXES, PHARMACEUTICAL COMPOSITIONS THEREOF, AND METHODS OF TREATING CANCER

Gold(I) complexes and gold(I) dithiocarbamate polymers as anticancer therapeutics. The Au(I) ion within the gold(I) complexes is coordinated to two phosphine ligands. The repeating unit formed by Au(I) ion coordinating to dithiocarbamte ligands are connected by Au(I)-Au(l) interactions within the gold(I) dithiocarbamate polymers. Also disclosed are methods of synthesis, pharmaceutical compositions incorporating the gold(I) complexes, pharmaceutical compositions incorporating the gold(I) dithiocarbamate polymers, and methods of treating cancer. 2: The gold(I) complex of formula (I) of claim 1 , wherein the anion is a halide ion claim 1 , a trifluoromethanesulfonate ion claim 1 , a hexafluorophosphate ion claim 1 , a tetrafluoroborate ion claim 1 , or a perchlorate ion.3: The gold(I) complex of formula (I) of claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rare a hydrogen claim 1 , and X is Cl.4: A composition comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the gold(I) complex of formula (I) of ; and'}a pharmaceutically acceptable carrier and/or excipient.5: The composition of claim 4 , which comprises 0.01-100 μM of the gold(I) complex relative to the total volume of the composition.6: The composition of claim 4 , wherein the pharmaceutically acceptable carrier and/or excipient is at least one selected from the group consisting of an organic solvent claim 4 , an inorganic salt claim 4 , a surfactant claim 4 , and a polymer.7: A method of treating cancer claim 4 , comprising administering the composition of to a subject in need of therapy.8: The method of claim 7 , wherein the cancer is resistant to cisplatin.9: The method of claim 7 , wherein the cancer is at least one selected from the group consisting of lung cancer claim 7 , colon cancer claim 7 , and breast cancer.10: The method of claim 7 , wherein 1-300 mg/kg of gold(I) complex of formula (I) ...

CRYSTALLINE COPPER-BASED COORDINATION POLYMERS AND THEIR USE

A method of preparing a crystalline copper-based coordination polymer comprises preparing a mixture of copper ions and a first quaternized carboxylate pyridyl ligand; adding a second polypyridyl ligand; and forming crystals of a copper-based coordination polymer therefrom. The crystalline copper-based coordination polymer is suitable for providing a sensing platform for detecting the presence of one or more target nucleic acid sequences such as viral RNA, in particular Dengue virus and/or Zika virus RNA with high selectivity and high specificity. A method of detecting at least a first target nucleic acid sequence, in particular from a viral RNA, in particular it is Flavivirus RNA, in a sample is also provided. Further provided is a kit including the crystalline copper-based coordination polymer and an oligonucleotide probe. 4. The method of claim 3 , wherein X is Br.8. The method of claim 1 , wherein step (i) comprises steps of:a) preparing a first pre-mixture comprising mixing the first pyridyl ligand and a solvent;b) preparing a second pre-mixture comprising mixing a copper salt and a solvent;c) adding the second pre-mixture to the first pre-mixture;d) stirring the mixture at a temperature of about 20° C. to about 30° C. for at least about 10 min.9. The method of claim 8 , wherein the copper salt is a hydrate of CuSOand wherein both of the solvent in step a) and the solvent in step b) independently comprise water.10. The method of claim 9 , wherein the first pyridyl ligand claim 9 , the copper salt and the second pyridyl ligand are used in a molar ratio of about 1:1:1.11. The method of claim 1 , wherein step (iii) of subjecting the mixture of step (ii) to conditions under which crystals of the copper-based coordination polymer are formed in particular includes steps of:a) stirring the mixture at a temperature of about 20° C. to about 30° C.;b) filtering the mixture for obtaining a filtrate and a residue;c) heating the filtrate to a temperature of at least about 80 ...

CRYSTALLINE LANTHANUM-CARBOXYLATE COORDINATION POLYMERS AND THEIR USE

The present invention relates in a first aspect to a method of preparing a crystalline lanthanum-carboxylate coordination polymer and the crystalline lanthanum-carboxylate coordination polymer obtained or obtainable by the method. In another aspect of the present invention, also provides a method of detecting a target nucleic acid sequence in a sample. 2. (canceled)3. (canceled)4. (canceled)5. (canceled)6. The method of claim 1 , wherein step (i) comprises steps of:a) preparing a first pre-mixture comprising mixing the pyridyl ligand and a solvent;b) preparing a second pre-mixture comprising mixing a lanthanum salt and a solvent;c) adding the second pre-mixture to the first pre-mixture.7. The method of claim 6 , wherein the lanthanum salt is a hydrate of La(NO)and wherein both of the solvent in step a) and the solvent in step b) independently comprise an aliphatic alcohol claim 6 , water or a mixture thereof8. The method of comprising steps of:(i) preparing a mixture comprising lanthanum ions and a pyridyl ligand which pyridyl ligand is a quaternized carboxylate pyridyl ligand and subjecting the mixture to conditions under which a precipitate is formed and separating the precipitate;(ii) subjecting the precipitate of step (i) to conditions under which crystals of the lanthanum-carboxylate coordination polymer are formed;(iii) separating the crystals of the lanthanum-carboxylate coordination polymer from the mixture;and wherein step (ii) comprises steps of:a) adding a solvent, which solvent comprises water to the precipitate at a temperature of between about 20° C. and about 30° C.;b) allowing the mixture after step a) to stand at a temperature between about 20° C. and about 30° C. for at least about 72 hours for forming crystals of the lanthanum-carboxylate coordination polymer.9. The method of claim 8 , wherein subjecting the mixture to conditions under which a precipitate is formed in step (i) comprises stirring the mixture for between about 15 min and about 60 ...

TRUE NANOSCALE ONE AND TWO-DIMENSIONAL ORGANOMETALS

A number of new classes of polymers with the potential for electrical conduction are introduced sharing a common theme, having metal atoms in direct contact with each other, bound in one and two-dimensional structures guided by steric, dipole and coordinating ligand factors. These new classes include a new family of metallole polymers in a polycyclic arrangement, for use both standing alone, and with chains of metal atoms coordinated to their electronegative backbone atoms, new polymers of group 13 and 14 metals and metalloids, with substituents connected through an electronegative bonding atom, and a new class of close stacked porphyrin polymers, assembled with short molecular linkers perpendicular to the faces of the porphyrin units. These new materials empower new classes of capacitors, batteries and electrical conductors, even superconductors. 1. A polycylic heteroatom rich polymer with a repeating unit as depicted in either , , , or .2. The polymer of claim 1 , where metal atoms in the zero oxidation state are co-deposited with and coordinated to the heteroatoms in the polymer.3. The polymer of claim 2 , where the metal atoms are either silver or copper claim 2 , and the heteroatoms are nitrogen.4. The polymer of used to store or provide electrical power.5. The polymer of claim 4 , where the polymer participates in a redox reaction as a component in the anode or the cathode of a battery.6. The polymer of where the polymer is produced under the influence of magnetic claim 1 , electric and/or electromagnetic fields to orient the polymer molecules.7. A two-dimensional organometal polymer comprising claim 1 ,a) Group 14 metallic atoms, with each such metallic atom with metallic bonds to three other such metallic atoms, arranged in planar polycyclic hexagonal rings,b) where each such metallic atom also has a fourth bond to an anti-metal substituent, where the fourth bond is to an anti-metal atom from Group 15, 16 or 17, in the anti-metal substituent,c) synthesized ...

Conductive polymer compositions

A process for preparing an electrically conductive polymer composition which comprises preparing a blend of a solution of an intrinsically conductive polymer and a thermosetting, thermoplastic or elastomeric polymer and removing the solvent, the intrinsically conductive polymer being employed in a weight ratio to the second polymer of from about 0.005:1 to 3:1, the solution having a solids content of from about 2 to 75 weight percent, and the intrinsically conductive polymer being an electrically conductive, stacked macrocyclic metal complex polymer based upon porphyrin or a derivative thereof which comprises an organic bridging ligand containing conjugated pi-electrons allowing delocalization along the polymer chain and in which the metal atom is Fe, R, Rh, Co, Mn or Cr.

Conducting polymer transition metal hybrid materials and sensors

Conductive properties are optimized in conducting polymers, made up of organic units and metal ions, by tailoring the position of metal ions with respect to conductive pathways or by selecting components such that the redox potential of organic units and metal ions differs by no more than 250 mV. Very small devices, and articles in which a high percentage of metal ions are redox active, are provided. Articles that can serve as sensors include metal ions with at least one free reactive site that can accommodate an analyte for conductivity change detection. Chemoresistive devices, field effect transistors, and signal amplifiers are provided.

Aluminum nitride from inorganic polymers

This invention provides a process for manufacturing aluminum-nitrogen polymers (i.e., polymers having a backbone of alternating aluminum and nitrogen atoms) in which portions of the polymer have an organic substituent on each aluminum and nitrogen atom. The novel polymers so produced are useful for making green shapes pyrolyzable to AlN articles suitable for high performance applications. The process generally comprises reacting an organic nitrile having the formula R 1 CN with a trialkylaluminum compound having the formula R 2 R 3 R 4 Al, and optionally heating the reaction product, to form an organoaluminum imine, and heating the organoaluminum imine to a temperature of at least 300° C. and less than 600° C. for at least two hours to form an aluminum-nitrogen polymer. The polymer or the imine can be pyrolyzed to form an aluminum nitride ceramic article. In the foregoing formulae, R 1 is an alkyl, cycloalkyl, aryl, aralkyl, hetero(ar)alkyl, or heterocyclic-substituted alkyl group, and R 2 , R 3 , and R 4 are each independently an alkyl, aryl, or aralkyl group, wherein any alkyl moiety comprises 1-12 carbon atoms, and wherein heteroatoms are selected from nitrogen, oxygen, and silicon.

Process of preparing titanoxane polymers

A method of synthesis high polymer containing selenium

一种合成含硒高聚物的方法，涉及含硒高聚物的制备方法。先在0℃环境温度条件下，将硼氢化钠的乙醇溶液、硒粉、N,N’‑二异丙基硒脲和二卤化物混合均匀，然后将混合物升温至20～60℃进行搅拌反应，反应结束后过滤，取得固相即含硒高聚物。所述二卤化物为二氯乙烷、二氯甲烷、二氯丙烷、对二苄氯、间二苄氯、邻二苄氯、二溴乙烷或对二苄溴中的至少任意一种。这些二卤代烃可以顺利聚合成高聚物链。本发明方法不需要使用高敏感性的丁基锂试剂、反应步骤简短、原料易得。因此，适合大规模生产，有较好的应用前景。

Production of conductive polymer composition

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

The preparation method and display device hardened layer material, harden layer material

在本申请所提供的硬化层材料、硬化层材料的制备方法及显示装置中，通过含有苯环的锗氧化合物和含有环氧官能团的锗氧化合物聚合，从而形成硬化层材料，其中，通过在锗氧聚合物中加入不同的环氧官能团，能够显著改善锗氧聚合物的热稳定性，有效防止黄化，提高其光学性能，从而提高硬化层材料的光透过率，形成光透过率好的硬化层材料、硬化层材料的制备方法及显示装置。

Preparation method of selenium-containing polymer taking carbamate bond as core

本发明公开了一种氨基甲酸酯键为核的含硒聚合物的制备方法，该制备方法为：（1）在惰性氛围中，将多异氰酸酯、含氰基醇、催化剂加入至反应体系，升温反应2~4 h，薄层色谱跟踪至反应结束，通过柱分离得到含氰基氨基甲酸酯单体；（2）在惰性氛围中，将单质硒、含氰基氨基甲酸酯单体、2,4‑己二炔‑1,6‑二醇加入到有机溶剂中，室温反应，后续分离多余硒粉，甲醇中沉淀，过滤得到氨基甲酸酯键为核的含硒聚合物。该含硒聚合物具有较好的溶解性、分散性、热稳定性、高折射率、高透光率等性能，可用于OLED感光材料领域。

HIGHLY CONDUCTIVE ORGANOMETALLIC POLYMERS

Polymères organométalliques. Ils sont dérivés des composés tétrathiapentalène et tétraselenapentalène. La formule développée des polymères selon l'invention est une des formules suivantes : Organometallic polymers. They are derived from the compounds tetrathiapentalene and tetraselenapentalene. The structural formula of the polymers according to the invention is one of the following formulas:

Process for the production of linear or cross-linked polymeric metal complexes, and the resulting products

A process for the production of polymeric compounds, by the addition of from 0.8 to 1.5 equivalents of an alkali metal hydroxide to a complex containing 1 mole of nitrilotriacetic acid per mole of ions of yttrium, ar are earth metal of atomic number 58 to 71, or of a mixture of such metals. There may be an excess of up to 50% of nitrilotriacetate ion present as its sodium salt, or an excess of up to 40% mol (relative to original quantity of nitrilotriacetate) of any polyvalent metal with power of co-ordination less than or equal to that of the rear earth or Y may be present, or added later, this excess of metal ions leading to the formation of gels. In Example 2, 0.1932 g. of [Nd3+][N(CH2-3O2-)3]. 3H2O are suspended in water, and an equivalent amount of 0.1N potassium hydroxide slowly added with stirring, and the mixture digested for half an hour on the water-bath. On making up to 50 ml., a clear, highly viscous solution forms after some time. In Example 5, 8% of neodymium, calculated on the original weight of Nd present, is added to a solution as made in the last example, in the form of a solution of its chloride, and mixed well in, to give a stiff gel.ALSO:A process for the production of polymeric compounds, by the addition of from 0.8 to 1.5 equivalents of an alkali metal hydroxide to a complex containing 1 mole of nitrilotriacetic acid per mole of metal ions, the metal here being yttrium, or a rare earth of atomic number 58 to 71, or a mixture of such metals. There may be an excess of up to 50% of nitrilotriacetate ion present as its sodium salt, or an excess of up to 40 mol per cent (relative to original quantity of nitrilotriacetate) or any polyvalent metal with a power of coordination less than or equal, to that of the rare earth or Y may be present, or added later, this excess of metal ions leading to the formation of gels. In Example 2, 0.1932 g. of [Nd3+] [N(CH2 Co2)3]. 3H2O are suspended in 5 ml. of water, and an equivalent amount (5 ml.) of 0.1N ...

Resin composition which exhibits anisotropism when melted

A resin composition of the invention, exhibiting the anisotropism when melted, comprises (1) a resin having rigid structure and exhibiting the anisotropism when melted and (2) a resin having a rigid structure portion and a soft structure portion, both resins having been uniformly mixed with each other.

Coating agent composition, coating method and coated article

Electroconductive thin film

This invention relates to an electroconductive thin film prepared by forming a polymerized thin film on a substrate in a vacuum reactor by the decomposition of a metal complex starting material by glow discharge, said metal complex having a ligand selected from the group consisting of acetylacetonate and at least partially fluorinated acetylacetonate.

Manufacturing process of artificial resins

Flame-resistant forming material

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Process for improving moisture resistance or epoxy resins by addition of chromium ions

A product and process for preparing the same to improve the moisture resistance properties of epoxidized TGMDA and DGEBA resin systems by chemically incorporating chromium (lll) ions therein without impairing the mechanical strength properties of the resins.

Sensitizers for photographic emulsions-by reaction of silver salts wi - andsilver complexing agents

Highly conducting organometallic polymers

HIGHLY CODUCTING ORGANOMETALLIC POLYMERS Abstract of the Disclosure This specification discloses highly conducting organometallic polymers having units chosen from the following recurring units and

ORGANOMETALLIC POLYMER

New polymeric porphyrin compounds useful in electrical and optical uses

Polymer composition

A crosslinkable composition comprising (A) a silyl poiym- er, for example an ethylene/vinyl trimethoxy silane copolymer, and (B) a silanol condensation catalyst which is an organic polymer having its polymer chains bridged by dihydrocarbyl tin (IV) containing units of the formula .O.SnR 1 R 2 O. Also disclosed are aliphatic alpha-olefin/unsaturated carboxyl compound copolymers containing similar dihydrocarbyl tin (IV) bridges. The compositions can be theremoformed into articles, e.g. cable insulation, and crosslinked by water treatment.

Transparency and method of making and using a thin transparent radiation sensitive film consisting essentially of titanium dioxide

Process for improving moisture resistance of epoxy resins by addition of chromium ions

PROCESS FOR IMPROVING MOISTURE RESISTANCE OF EPOXY RESINS BY ADDITION OF CHROMIUM IONS ABSTRACT A product and process for preparing the same to improve the moisture resistance properties of epoxidized TGMDA and DGEBA resin systems by chemically incorporating chromium (III) ions therein without impairing the mechanical strength properties of the resins.

Electrode catalyst and method for producing same

An electrode catalyst which is characterized by being obtained by: forming a fired body by firing a metal phthalocyanine polymer that has a repeating structural unit wherein a structural unit represented by general formula (1a) and a structural unit represented by general formula (2a) are bonded with each other by an amide bond; and then treating the fired body with an acid. (In general formula (1a), L represents a divalent or trivalent metal ion of an element of the third to fifth rows of the long form periodic table.) (In general formula (2a), M represents a divalent or trivalent metal ion of an element of the third to fifth rows of the long form periodic table.)

Organosiloxane compounds containing polyoxometalate groups

This invention provides organosiloxane compounds containing silicon-bonded polyoxometalate (POM) structures that are present as pendant groups. The invention also provides methods for preparing these materials.

Silicone paste - consisting of mixt of colloidal inorg filler and polysiloxane mixt contg titanium/boron atoms

Process for the preparation of synthetic resins

Novel titanic acid monomer and polymer thereof, and production method and use thereof

POLYMER INCORPORATING PHOSPHORUS ATOMS AND PROCESS FOR SYNTHESIS

Conductive polymer compositions

Process for the production of high molecular weight metal complexes

Di-thiocarbamyl-pyridines

Composition

本発明の課題は、大気中でも安定で、低温乾燥で溶媒除去可能な有機薄膜を形成することのできる組成物を提供することである。本発明の組成物は、金属アルコキシド又は金属カルボキシレート、及び前記金属アルコキシド又は金属カルボキシレートの中心金属に配位可能なキレート化剤を含有する組成物であって、前記金属アルコキシド又は金属カルボキシレートが、フッ化アルコキシ基を有する、金属アルコキシド又は金属カルボキシレートの単量体若しくは重合体であり、前記キレート化剤の含有量が前記金属アルコキシド又は金属カルボキシレートの単量体１モルに対し１モル以下であることを特徴とする。 An object of the present invention is to provide a composition capable of forming an organic thin film that is stable in the atmosphere and can be solvent-removed by low-temperature drying. The composition of the present invention is a composition containing a metal alkoxide or a metal carboxylate and a chelating agent capable of coordinating the central metal of the metal alkoxide or the metal carboxylate, wherein the metal alkoxide or the metal carboxylate is a composition. , A metal alkoxide or metal carboxylate monomer or polymer having a fluorinated alkoxy group, and the content of the chelating agent is 1 mol or less with respect to 1 mol of the metal alkoxide or metal carboxylate monomer. It is characterized by being.

Arsenic modified polysulfide plastics

HIGH CONDUCTIVITY POLYMERS

Composition, cured product and method for producing same, and member, electronic component, and fiber

一種組成物，含有：（A）具有選自由Al、Sc、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Ga、Ge、Y、Zr、Nb、Mo、In、Sn、Sb、Hf、Ta、W及Bi所組成的群組中的金屬原子與氧原子的重複結構的聚金屬氧烷（以下稱為「（A）聚金屬氧烷」）；及（B）具有下述通式（1）所表示的基的胺化合物（以下稱為「（B）胺化合物」），且組成物中的（B）胺化合物的含量相對於（A）聚金屬氧烷100重量份而為1重量份～30重量份。本發明提供一種能夠形成耐裂紋性優異且具有高密度的硬化體的、包含聚金屬氧烷的組成物。

Preparation of zinc polyesters

Organic-inorganic hybrid polymer, method for production thereof, and method for control of molecular weight

　ビス（ターピリジン）化合物と遷移金属イオンとからなる有機－無機ハイブリッドポリマーにおいて、分子量の分散が極めて小さい有機－無機ハイブリッドポリマーおよび、所望の分子量に調整でき分子量の分散も極めて小さくできる有機－無機ハイブリッドポリマーの製造方法ならびに分子量調整方法を提供する。 　合成後の有機－無機ハイブリッドポリマーを溶媒に溶解することにより得られるポリマー分子量と、当該溶媒に溶解させるポリマー濃度との分子量－濃度対応関係を予め導出する工程と、有機－無機ハイブリッドポリマーを合成後、予め導出した前記分子量－濃度対応関係に基づき、得ようとする分子量に対応する濃度で有機－無機ハイブリッドポリマーを溶媒に溶解させ、分散値が２．０以下である所望の分子量の有機－無機ハイブリッドポリマーを得る工程とにより有機－無機ハイブリッドポリマーを製造する。

Conductive thin film

Phthalocyanine polymers with good processability, producing method thereof, and polymer compositions and photosensitive polymer films produced therefrom

본발명은 유기 용매에 가용성이 있으며, 근적외선과 가시광선에 높은 감도를 가지고, 가공성이 우수한 프탈로시아닌 중합체, 이의 제조 방법, 이를 이용한 중합체 조성물 및 감광성 중합체 박막에 관한 것이다.

New phosphine based polymer compound, useful in coordination chemistry to coordinate metal ions

Phosphine based polymer compound (I), is new. Phosphine based polymer compound of formula (X 1>-(CH 2-P(=X 4>)(CH 2X 2>)-CH 2-X 3>) n-CH 2-P(=X 4>)(CH 2X 2>)-CH 2-X 1>) (I), is new. X 1>OH, NHR or SiR 1>R 2>(OH); X 2>OH, NHR or polymer chain; X 3>NR, -OSi(R 1>)(R 2>)O-, -OSi(R 1>)(OCH 2X 2>)O- or (SiO 2) m; X 4>free pair, O, S, Se, Te or NR 3>; R, R 1>-R 4>alkyl or aryl; and n, m : 10-1000 (where n is preferably greater than 100).

Conductive polymer compositions

Flame resistant moulding compounds based on styrene polymers

This invention relates to flame resistant moulding compounds produced from mixtures of styrene polymers halogenated organic compounds, special polyphosphonic acid amides and optionally conventional additives.

Resin composition which exhibits anistotropism when melted

ABSTRACT OF THE DISCLOSURE A resin composition of the invention, exhibiting the anisotropism when melted, comprises (1) a resin having rigid structure and exhibiting the anisotropism when melted and (2) a resin having a rigid structure portion and a soft structure portion, both resins having -been uniformly mixed with each other.

Preparation of electrically conductive polymers

O.Z. 0050/034810 Abstract of the Disclosure: A process for the preparation of electrically conductive polymers which are stable to air and have conductivities greater than 1 x 10-3 S/cm, by reacting a cation of a metal of group VII or VIII or of sub-group I of the periodic table with an organic chelat-ing compound to give a metal chelate and oxidizing the latter to form a polymer, wherein the organic chelating compound is a 1,9-substituted phenalene of the general formula I , where X is 0, NH, S, Se or Te and Y is OH, NH2 or SH. The electrically conductive polymers are useful for the production of solar cells, the conversion and fix-ing of radiation, the production of electrical and magne-tic switches and the antistatic treatment of plastics.

PROCESS FOR PREPARING A THERMOSTABLE AMIDE-ALDEHYDE RESIN AS WELL AS A PREPARATION MANUFACTURED FROM THIS.

Curable composition, method for manufacturing an epoxy resin/inorganic polymer composite material using said curable composition, and epoxy resin/inorganic polymer composite material

The disclosed curable composition contains: (A) a group 4 metal alkoxide partially modified by a carboxylic acid, each molecule of which has a functional group which reacts to hydroxyl groups or epoxy groups, or a polyvalent carboxylic acid anhydride; and (B) an epoxy compound. Said group 4 metal is preferably zirconium or titanium. Using the disclosed curable composition makes it easy to form a homogenous epoxy resin/inorganic polymer composite material that is highly transparent, has a high index of refraction, and comprises a cured epoxy resin and a group 4 metal oxide.

Reversible self-assembly of imbedded metallomacrocycles within a macromolecular superstructure

In accordance with the present invention, there is provided a method for preparing a reversible, self-assembly of an imbedded hexameric metallomacrocycle within a macromolecular superstructure. The method occurs by an intramolecular mechanism in which a macromolecular skeleton possesses multiple ligands capable of reversible assembly-disassembly triggered by the presence of metal ions.

Halogen-containing resins stabilized with organo-tin mercapto compounds

メタロ超分子ポリマー、エレクトロクロミック素子、及びメタロ超分子ポリマーの製造方法

金属カチオンと有機配位子とが配位結合によって交互に連なって形成されるメタロ超分子ポリマーであって、前記有機配位子が、下記式（Ｂ）で表されるトリス（ターピリジン）化合物と、下記式（Ｌ）で表されるビス（ターピリジン）化合物と、を含むメタロ超分子ポリマーは、高い着色効率を有する。

Verfahren zur herstellung von elektrisch leitfaehigen polykondensaten und deren verwendung in der elektrotechnik und zur antistatischen ausruestung von kunststoffen.

樹脂組成物、硬化膜の製造方法、多層膜付き基板、パターン付き基板の製造方法、パターン硬化膜の製造方法および樹脂組成物の製造方法

［（Ｒ２）ｄ（Ｒ３）ｅ（ＯＲ４）ｆＳｉＯｇ／２］で表される構成単位と、［（Ｒ１）ｂＭＯｃ／２］で表される構成単位と、を有する重合体、および、１－オクタノール／水分配係数ｌｏｇ　Ｐｏｗが３以下の溶剤を含む樹脂組成物。Ｒ２は、複数存在する場合はそれぞれ独立に、アリール基またはアラルキル基、Ｒ３は、複数存在する場合はそれぞれ独立に、水素原子、直鎖もしくは分岐の脂肪族炭化水素基、または、芳香族炭化水素基、Ｒ４は、複数存在する場合はそれぞれ独立に、水素原子、または、直鎖もしくは分岐の脂肪族炭化水素基、ｄは１以上３以下の数、ｅは０以上２以下の数、ｆは０以上３未満の数、ｇは０超３以下の数、ｄ＋ｅ＋ｆ＋ｇ＝４である。ＭはＦｅ、Ｃｏ、Ｎｉ、Ｃｕ、Ｚｎ、Ｇａ、Ｇｅ、Мｏ、Ｐｄ、Ａｇ、Ｓｎ、Ｃｓ、Ｂａ、ＷおよびＨｆからなる群から選ばれる少なくとも１種であり、Ｒ１は、複数存在する場合はそれぞれ独立に、水素原子、ヒドロキシ基、ハロゲン基、アルコキシ基、直鎖もしくは分岐の脂肪族炭化水素基、または、芳香族炭化水素基、ｂは０以上６未満の数、ｃは０超６以下の数、ｂ＋ｃ＝３～６である。

一种含硒醚基团的聚合物的合成方法及其产品和降解方法

本发明公开了一种含硒醚基团的聚合物的合成方法，以二双键单体、一氧化碳、硒粉和水为原料，加入碱作为催化剂，于自生压力下进行一步聚合反应，制备得到含硒醚基团的聚合物；二双键单体选自二丙烯酸酯类单体、双丙烯酰胺类单体、双乙烯基砜类单体、双马来酰亚胺类单体中的一种或多种；二双键单体、硒粉和水的摩尔比为1：(0.1～10.0)：(0.1～10.0)；反应体系中一氧化碳的压力为0.1～5.0MPa；聚合反应的温度为20～160℃，时间为0.5～120h。本发明仅需一步反应制备得到含硒醚基团的聚合物，聚合物的重均分子量最高可达140kg/mol、分子量分布窄，具有优异的力学性能，且可在温和条件下迅速降解。

Inorganic plastic

一种高折射率紫外光固化纳米压印胶

本发明属于纳米压印技术领域，公开了一种高折射率紫外光固化纳米压印胶，由高折射率紫外光固化树脂与光引发剂一起溶于有机溶剂中获得，其中，该树脂由烷氧基钛和含双键的β‑二酮进行螯合反应引入双键；通过含邻苯基苯氧基的化合物进行反应在侧链上引入芳香环提高折射率；并通过水解缩合反应进一步降低有机基团含量，旋蒸除去副产物后得到。该树脂可以在紫外光下固化成膜，589纳米波长下折射率最高可以超过1.72，该树脂既可以制备高折射率纳米压印胶，通过紫外纳米压印获得高分辨率纳米结构，也可用于制备高折射率涂膜。

Composition and preparation for hafnium carbide ceramic precursor

Metal containing polymer compositions, useful for the production of high temperature metal carbide ceramics are described, including poly(carbohafnocene) compositions and related poly(carbometallocene) compositions, as well as compositions formed from the reaction of hafnium chloride and 2-butyne-1,4-diol. Methods of synthesizing such compositions are provided.

Composition and preparation for hafnium carbide ceramic precursor

Metal containing polymer compositions, useful for the production of high temperature metal carbide ceramics are described, including poly(carbohafnocene) compositions and related poly(carbometallocene) compositions, as well as compositions formed from the reaction of hafnium chloride and 2-butyne-1,4-diol. Methods of synthesizing such compositions are provided.

Polimeri ad alta conduttivita'.

Thin film solar cell

薄膜太陽電池

【課題】安価な原料を使用しながら、変換効率を向上させることができる薄膜太陽電池が望まれていた。【解決手段】本発明に係る薄膜太陽電池は、１種または２種以上の有機半導体と、配位高分子を備え、配位高分子が、遷移金属元素の中から選ばれる１種または２種以上の金属イオンに、金属イオンに配位可能な１種または２種以上の含硫黄化合物、含窒素化合物、含酸素化合物、含燐化合物からなる配位子が配位した錯体の繰り返し単位を含有するものであることを特徴とする。【選択図】図１

박막 태양전지

(과제) 저렴한 원료를 사용하면서 변환 효율을 향상시킬 수 있는 박막 태양전지가 소망되고 있었다. (해결 수단) 본 발명에 의한 박막 태양전지는 1종 또는 2종 이상의 유기 반도체와 배위 고분자를 구비하고, 배위 고분자가 전이금속 원소 중에서 선택되는 1종 또는 2종 이상의 금속 이온에 금속 이온에 배위 가능한 1종 또는 2종 이상의 황 함유 화합물, 질소 함유 화합물, 산소 함유 화합물, 인 함유 화합물로 이루어진 배위자가 배위한 착체의 반복단위를 함유하는 것을 특징으로 한다.

薄膜太陽能電池

薄膜太阳能电池

本发明的课题是期望一种薄膜太阳能电池，其不仅能够使用廉价的原料，而且能够使转换效率提高。本发明的解决手段是：有关本发明的薄膜太阳能电池，其特征为具备1种或两种以上的有机半导体和配位聚合物，该配位聚合物是含有包含能配位于金属离子的1种或两种以上的含硫化合物、含氮化合物、含氧化合物、含磷化合物的配体配位于由过渡金属元素之中所选出的1种或两种以上的金属离子而成的络合物的重复单元。

薄膜太陽電池

Thin film solar cell

樹脂組成物、固化膜的製造方法、附有多層膜之基板、附有圖案之基板的製造方法、圖案固化膜的製造方法及樹脂組成物的製造方法

一種樹脂組成物，其包含具有由[(R 2 ) d (R 3 ) e (OR 4 ) f SiO g/2 ]所示之構成單元與由[(R 1 ) b MO c/2 ]所示之構成單元的聚合物及1-辛醇／水分配係數log P ow 為3以下的溶劑。R 2 在存在多個的時候分別獨立為芳基或芳烷基，R 3 在存在多個的時候分別獨立為氫原子、直鏈或分枝的脂族烴基或者芳烴基，R 4 在存在多個的時候分別獨立為氫原子或者直鏈或分枝的脂族烴基，d為1以上且3以下之數，e為0以上且2以下之數，f為0以上且未達3之數，g為超過0且3以下之數，d＋e＋f＋g＝4。M係選自由Fe、Co、Ni、Cu、Zn、Ga、Ge、Mo、Pd、Ag、Sn、Cs、Ba、W及Hf而成之群組之至少1種，R 1 在存在多個的時候分別獨立為氫原子、羥基、鹵基、烷氧基、直鏈或分枝的脂族烴基或者芳烴基，b為0以上且未達6之數，c為超過0且6以下之數，b＋c＝3～6。

Metalloporphyrin polymer functionalized substrate

A method is provided for fabricating a metalloporphyrin polymer on a substrate. The method creates a functionalized substrate by attaching an anchor group of a linker, including a terminal alkyne group, to a substrate surface. The functionalized substrate is then exposed to metalloporphyrin monomers, where each metalloporphyrin monomer includes at least two terminal alkyne groups. A plurality of metalloporphyrin monomers (e.g., zinc porphyrin monomers) are thus linked via the metalloporphyrin monomer terminal alkyne groups, forming a metalloporphyrin polymer attached to the substrate. In one aspect, linking the plurality of metalloporphyrin monomers via the metalloporphyrin monomer terminal alkyne groups includes forming butadiyne groups between adjacent metalloporphyrins. Then, forming the metalloporphyrin polymer attached to the substrate includes attaching the metalloporphyrin polymer, via a metalloporphyrin monomer terminal alkyne group, to the terminal alkyne group of an associated linker. Alternatively stated, the metalloporphyrin polymer is attached to the substrate via a polyalkyne group.

アンダーフィル材、有機金属酸化物の製造方法、電子部品装置及びその製造方法

本発明の課題は、接続部の電池効果と付着イオン物質、水分吸湿による腐食や電食の発生を抑制した信頼性の高いアンダーフィル材、それに用いる有機金属酸化物の製造方法、電子部品装置及びその製造方法を提供することである。　本発明のアンダーフィル材は、下記一般式（１）で表される構造を有する有機金属酸化物を含有することを特徴とする。　一般式（１）　Ｒ－［Ｍ（ＯＲ １ ） ｙ （Ｏ－） ｘ－ｙ ］ ｎ －Ｒ （式中、Ｒは、水素原子、炭素数１個以上のアルキル基、アルケニル基、アリール基、シクロアルキル基、アシル基、アルコキシ基、又は複素環基を表す。ただし、Ｒは置換基としてフッ素原子を含む炭素鎖でもよい。Ｍは、金属原子を表す。ＯＲ １ は、フッ化アルコキシ基を表す。ｘは金属原子の価数、ｙは１とｘの間の任意な整数を表す。ｎは重縮合度をそれぞれ表す。）

Composition and preparation for hafnium carbide ceramic precursor

Metal containing polymer compositions, useful for the production of high temperature metal carbide ceramics are described, including poly(carbohafnocene) compositions and related poly(carbometallocene) compositions, as well as compositions formed from the reaction of hafnium chloride and 2-butyne-1,4-diol. Methods of synthesizing such compositions are provided.

Composition and preparation for hafnium carbide ceramic precursor

Metal containing polymer compositions, useful for the production of high temperature metal carbide ceramics are described, including poly(carbohafnocene) compositions and related poly(carbometallocene) compositions, as well as compositions formed from the reaction of hafnium chloride and 2-butyne-1,4-diol. Methods of synthesizing such compositions are provided.

탄화하프늄 세라믹 전구체에 대한 조성물 및 제조

폴리(카르보하프노센) 조성물 및 관련 폴리(카르보메탈로센) 조성물 뿐만 아니라, 염화하프늄 및 2-부틴-1,4-디올의 반응으로부터 형성된 조성물을 포함한, 고온 금속 탄화물 세라믹의 제조에 유용한 금속 함유 중합체 조성물이 기재되어 있다. 그러한 조성물의 합성 방법이 제공된다.

炭化ハフニウムセラミック前駆体に関する組成物および調製

ポリ（カーボハフノセン）組成物および関連あるポリ（カーボメタロセン）組成物、ならびに塩化ハフニウムおよび２－ブチン－１，４－ジオールの反応から形成された組成物を含む、高温金属炭化物セラミックを生成するのに有用な金属含有ポリマー組成物が、記述される。そのような組成物を合成する方法が提供される。好ましい実施形態では、ポリ（カーボハフノセン）ポリマーを形成するための方法は、ビス（シクロペンタジエニル）ハフニウム二ハロゲン化物を提供する工程、およびビス（シクロペンタジエニル）ハフニウム二ハロゲン化物を式ＸＭｇ（ＣＨ２）ｊＭｇＸ（式中、Ｘはハロゲン化物であり、ｊは４または５である）のジ－Ｇｒｉｇｎａｒｄ試薬と反応させる工程を含む。

一种主链为金属元素的高分子及其制备方法和应用

本发明涉及一种主链为金属元素的高分子及其制备方法和应用，一种主链为金属元素的高分子，包括主链和配体，所述主链为由通过化学键相连的金属原子组成，化学结构式满足以下通式： 式中，n为重复单元数，n大于10；M为金属原子，M选自过渡金属中的一种或多种；所述主链上的金属原子通过配位键与配体相连。所述金属主链高分子的制备步骤包含：配体的合成以及金属主链高分子的合成。本发明所制备的金属主链高分子为未来设计新的功能高分子开辟了新的途径。

Covalently fixed porphyrin polymer having porphyrin metal complex substituted with coordinating hetero aromatic ring as constituting unit thereof,and method of producing the same

A covalently linked linear porphyrin polymer represented by formula (1): wherein R represents an alkyl group or  (wherein a, b and d independently represent H, an alkyl group or aryl group); X represents —O—, —S—, >NR 101 (wherein R 101 represents H or an alkyl group), —CH 2 — or a single bond; Y represents ═O, ═S, or 2H; m represents an integer of 0 to 4; n represents an integer of 0 to 6; Z represents a five- or six-membered, nitrogen-containing, coordinating hetero aromatic ring group; M represents an ion of metal selected from typical metals and transition metals; Q 1 represents a single bond or a linear, divalent linking group; and p 1 represents an integer of 2 or more.

一种主链为金属元素的高分子及其制备方法和应用

本发明涉及一种主链为金属元素的高分子及其制备方法和应用，一种主链为金属元素的高分子，包括主链和配体，所述主链为由通过化学键相连的金属原子组成，化学结构式满足以下通式： 式中，n为重复单元数，n大于10；M为金属原子，M选自过渡金属中的一种或多种；所述主链上的金属原子通过配位键与配体相连。所述金属主链高分子的制备步骤包含：配体的合成以及金属主链高分子的合成。本发明所制备的金属主链高分子为未来设计新的功能高分子开辟了新的途径。

一种含Ti的Si-C-N陶瓷先驱体及其合成方法和应用

本发明公开了一种含Ti的Si‑C‑N陶瓷先驱体及其合成方法和应用，将聚甲基硅烷先置于反应釜中，将反应釜升温至80～120℃，然后将含乙烯基聚硅氮烷(Vi‑PSN)滴加进反应釜，第一次回流反应，冷却至室温后，再将TiCl 4 滴加至反应釜内，第二次回流反应，即得含Ti的Si‑C‑N陶瓷先驱体。本发明的合成方法，先将Vi‑PSN与PMS反应，将烯基基团及N元素带入到PMS的分子结构中，然后再利用TiCl 4 中的Ti‑Cl键与PMS中的Si‑H反应，对PMS进行灭活处理，同时给先驱体引入Ti元素。所得Si‑C‑N陶瓷先驱体在空气中稳定；并且Ti元素的存在，能够提高陶瓷先驱体与基材之间的粘结性以及烧结陶瓷自身的致密度，从而在一定程度上提高复材的力学性能。

一类主链含金属元素的a-d-a型聚合物及制备方法与其应用

本发明公开了一类主链含金属元素的A‑D‑A型聚合物及制备方法与其应用。该制备方法以A‑D‑A单元为核心，以炔‑金属化合物‑炔单元为纽带，将金属原子引入到共聚物中，制备的聚合物具有宽光谱范围的吸收和高的载流子迁移率。本发明基于此类主链含金属元素的A‑D‑A型聚合物可作为活性层，应用在有机/聚合物光电探测器或有机/聚合物太阳电池或有机/聚合物场效应晶体管中。

アンダーフィル材、有機金属酸化物の製造方法、電子部品装置及びその製造方法

本発明の課題は、接続部の電池効果と付着イオン物質、水分吸湿による腐食や電食の発生を抑制した信頼性の高いアンダーフィル材、それに用いる有機金属酸化物の製造方法、電子部品装置及びその製造方法を提供することである。本発明のアンダーフィル材は、下記一般式（１）で表される構造を有する有機金属酸化物を含有することを特徴とする。一般式（１） Ｒ−［Ｍ（ＯＲ１）ｙ（Ｏ−）ｘ−ｙ］ｎ−Ｒ（式中、Ｒは、水素原子、炭素数１個以上のアルキル基、アルケニル基、アリール基、シクロアルキル基、アシル基、アルコキシ基、又は複素環基を表す。ただし、Ｒは置換基としてフッ素原子を含む炭素鎖でもよい。Ｍは、金属原子を表す。ＯＲ１は、フッ化アルコキシ基を表す。ｘは金属原子の価数、ｙは１とｘの間の任意な整数を表す。ｎは重縮合度をそれぞれ表す。）

Method of assembly of molecular-sized nets and scaffolding

有機／金属ハイブリッドポリマーを含む固体電解質及びその製造方法、並びにそれを用いた二次電池

本発明は、カチオンによる高いイオン伝導度を有し、耐熱性に優れた固体電解質及びその製造方法、並びにそれを用いた二次電池に関する。本発明の固体電解質は、アニオン性官能基及び３価の金属イオンを有するアニオン性有機／金属錯体と、Ｌｉ＋、Ｎａ＋、Ｋ＋及びＭｇ２＋からなる群から選択されるカウンターカチオンとを有する有機／金属ハイブリッドポリマーを含有する。【選択図】 図１

Polymeric chelates of hydroxy-substituted anthraquinones and the process for their preparation

高折射率的杂混有机－无机聚合物涂层

提供新颖的组合物及使用这些组合物形成金属氧化物薄膜或涂层的方法。组合物包含分散或溶解在有机体系中的有机金属低聚物和有机聚合物。组合物具有长储存寿命，可通过方便和可靠的制备方法制得。固化所述组合物，使组合物转化为分散有机聚合物或低聚物的金属氧化物薄膜。固化后的薄膜具有高折射率，高光学透明度，在膜厚度大于约1微米时具有良好的机械稳定性。

一种超高温陶瓷前驱体及其制备方法和应用

本发明属于陶瓷材料技术领域，特别涉及一种超高温陶瓷前驱体及其制备方法和应用。一种超高温陶瓷前驱体，其结构式为： 其中，m的取值为2‑25；M为难熔金属元素。本发明以含双酚基的芳香族化合物、含硅化合物以及茂金属化合物为单体，以三乙胺为催化剂和缚酸剂，提高酚基的反应活性，通过缩聚反应，实现‑OH与Si‑Cl或Zr‑Cl的缩聚取代反应，形成通过Si‑O或Zr‑O键连接起来的前驱体，通过调节主链上难熔金属元素以及难熔金属元素与硅元素的含量比来得到不同的有机硅聚合物，种类丰富且热稳定性好。

有機無機複合体、構造体及び有機無機複合体の製造方法

【課題】有機無機複合体の機能性及び熱的安定性をより高める。【解決手段】本発明の有機無機複合体は、金属元素を含む無機骨格と、金属元素に対して炭素を含む共有結合を介して結合した陽イオン交換基及び／又は配位結合により金属イオンを固定化しうる官能基（固定化官能基）と、陽イオン交換基及び／又は固定化官能基により固定化された金属イオンと、を備え、ドメインサイズが２０ｎｍ以下であるものである。この有機無機複合体は、金属Ｍ1及び酸素を含む無機骨格と、炭素を含む結合基Ｒ1を介して無機骨格に共有結合した基Ｒ2と、基Ｒ2に固定化された金属イオンＭ2とを備えているものとしてもよい。この有機無機複合体は、その構成体の大きさであるドメインサイズが、２０ｎｍ以下であるものとしてもよい。【選択図】図１