30-07-2020 дата публикации
Номер: US20200239725A1
Принадлежит:
Provided herein are coated substrates. Also provided herein are methods for attaching phosphonates, phosphonic acids, or derivatives thereof to an organic or an inorganic substrate (e.g., a metal oxide substrate) via phosphonate chemistry to form the coated substrates provided herein. 2. The coated substrate of claim 1 , wherein Jis{'sub': 2', '2', '3', '3', '2', '6', '2', '2', '9', '2', '6', '2', '9, 'sup': (+)', '4', '4, '—(CH)N(CH), —(CH)NH, —(CH)COOH, —(CH)Ror —(CH)R.'}3. The coated substrate of claim 1 , wherein Jis —(CH)R.4. The coated substrate of claim 1 , wherein Jis —(CH)R.5. The coated substrate of claim 1 , wherein Jis —(CH)N(CH).6. The coated substrate of claim 1 , wherein Jis —(CH)NH. The coated substrate of claim 1 , wherein Jis —(CH)COOH.13. The method of claim 12 , wherein Rand Jare —(CH)N(CH) claim 12 , —(CH)NH claim 12 , or —(CH)COOH.15. The method of claim 14 , wherein Jis —(CH)NH.17. The method of claim 16 , wherein Jis —(CH)COOH. This application is a U.S. national phase of PCT/US2018/055497, filed Oct. 11, 2018, which claims the benefit of U.S. Provisional Patent Application No. 62/570,852, filed Oct. 11, 2017, the entire disclosure each of which is incorporated herein by reference.Described are coated substrates and methods for attaching phosphonates, phosphonic acids, or derivatives thereof to organic or inorganic substrates via phosphonate chemistry.Provided herein are coated substrates. Also provided herein are methods for attaching phosphonates, phosphonic acids, or derivatives thereof to an organic or an inorganic substrate (e.g., a metal oxide substrate) via phosphonate chemistry to form the coated substrates provided herein.Provided herein are phosphonate-coated materials and methods of preparation thereof.In some embodiments, phosphonates or phosphonic acids are used in the preparation of metal-phosphonate compounds. In some embodiments, phosphonic acids are used in the synthesis of hybrid materials by grafting ligand or polymer ...
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