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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 6333. Отображено 100.
05-01-2012 дата публикации

Halogen-free flame-retardant resin composition, wire and cable

Номер: US20120003473A1
Автор: Akira Suzuki, Hiroshi Kimura, Katsuhisa Shishido, Kenichiro Fujimoto, Kentaro Segawa
Принадлежит: Hitachi Cable Ltd

A halogen-free flame-retardant resin composition includes 100 parts by, weight of base polymer of polyolefin resin, not less than 50 parts by weight and not more than 250 parts by weight of metal hydroxide, not less than 1 part by weight and not more than 50 parts by weight of calcium borate, not less than 1 part by weight and not more than 50 parts by weight of zinc stannate, and less than 30 seconds of burning time after removal of flame in a vertical flame test complying with CODE 895 OR 3 rd edition, appendix 6 of the UIC standard.

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Номер записи: 1
12-01-2012 дата публикации

Multi-layer-core golf ball having highly-neutralized polymer outer core layer

Номер: US20120010022A1
Автор: Michael J. Sullivan, Murali Rajagopalan
Принадлежит: Individual

A golf ball including an inner core layer formed from a thermoset rubber composition and having a first surface hardness; a thermoplastic outer core layer having a second surface hardness, an inner surface hardness, and being formed from a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to fully-neutralize the acid groups of the copolymer; an inner cover layer; and an outer cover layer; wherein the first surface hardness is less than the second surface hardness by at least 5 Shore C and less than the inner surface hardness by at least 5 Shore C.

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Номер записи: 2
03-05-2012 дата публикации

Polyethylene Moulding Composition

Номер: US20120108752A1
Автор: Bernd Lothar Marczinke, Diana DÖTSCH, Joachim Berthold, Johannes-Gerhard MÜLLER
Принадлежит: BASELL POLYOLEFINE GMBH

A novel polyethylene composition is described. The composition is suitable for manufacturing especially stretched bands or tapes, also coined raffia in the art.

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Номер записи: 3
17-05-2012 дата публикации

Multi-layer golf ball providing improved speed

Номер: US20120122611A1
Автор: Dean A. Snell, Eric Loper, Hyun Jin Kim
Принадлежит: TaylorMade Golf Co Inc

The present invention is directed to a multi-layer golf ball comprising at least one core or core layer, at least one intermediate layer, and at least one cover layer. The core has a diameter of about 1.20 to about 1.56 in. and a PGA compression of about 40 to about 90. The intermediate layer comprises a modified ionomeric polymer, and it has a thickness of about 0.01 to about 0.10 in. and a Shore D hardness of about 30 to about 70. The cover layer has a Shore D hardness of about 40 to about 75. The multi-layer golf balls of the present invention provide high driver ball speed and/or a high Coefficient of Restitution, while maintaining excellent shot feel.

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Номер записи: 4
31-05-2012 дата публикации

Charge-dynamic polymers and delivery of anionic compounds

Номер: US20120134926A1
Автор: Adam D. Miller, David M. Lynn
Принадлежит: WISCONSIN ALUMNI RESEARCH FOUNDATION

The present invention provides dynamic charge state cationic polymers that are useful for delivery of anionic molecules. The dynamic charge state cationic polymers are designed to have cationic charge densities that decrease by removal of removable functional groups from the polymers. The present invention also provides interpolyelectrolyte complexes containing the polymers complexed to a polyanion. Methods for using the interpolyelectrolyte complexes to deliver anionic compounds are also provided.

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Номер записи: 5
31-05-2012 дата публикации

Stable reactive thermosetting formulations of reducing sugars and amines

Номер: US20120135152A1
Автор: Barry Weinstein, Charles Damien Rodowski, Charles James Rand, Drew Elliot Williams, William Christopher Finch
Принадлежит: Rohm and Haas Co

The present invention provides stable aqueous thermosetting binder compositions having a total solids content of 15 wt. % or higher, preferably, 20 wt. % or higher, and having extended shelf life comprising one or more reducing sugar, one or more primary amine compound, and one or more stabilizer acid or salt having a pKa of 8.5 or less. The total amount of stabilizer used may range from 5 to 200 mole %, based on the total moles of primary amine present in the binder. The stabilizer may be an organic stabilizer chosen from a monocarboxylic acid, a dicarboxylic acid, a fatty acid, an acid functional fatty acid ester, an acid functional fatty acid ether, or an inorganic stabilizer chosen from a mineral acid, a mineral acid amine or ammonia salt, and a Lewis acid, and mixtures thereof. The compositions can be used to provide binders for substrate materials including, for example, glass fiber.

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Номер записи: 6
06-12-2012 дата публикации

Painted Polyolefin Articles

Номер: US20120308752A1
Автор: Gloria Stucchi, Jose Manu Rego, Robert Hai-Feng He, Shuwen Peng, Stephen Yau-Sang Cheng
Принадлежит: Dow Global Technologies LLC

Articles having a Shore A hardness of 50 to 95 and made from polyolefin compositions comprising an ethylene-alpha-olefin interpolymer (random or block or a mixture of the two) are paintable without the need for a primer or other surface treatment with paints free of phthalate-based plasticizer and designed to paint SBS- or SEBS-type rubber based compositions. These polyolefin compositions are free of (1) phthalate-based plasticizer, (2) halogen-containing polymer, and (3) leachable, small polymeric units derived from styrene monomer. In addition, the content of the alpha-olefin in the polyolefin composition is at least 9.7 mole percent.

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Номер записи: 7
06-12-2012 дата публикации

Multi-layered cores for golf balls containing ionomer and non-ionomer layers

Номер: US20120309562A1
Автор: Mark I. Binette, Michael J. Sullivan
Принадлежит: Individual

Multi-piece golf balls having a solid core of at least one layer and cover of at least one layer are provided. At least one of the core layers comprises a thermoplastic ionomer composition and at least one of the core layers comprises a thermoplastic non-ionomer composition. Preferably, the ionomer composition is a highly neutralized ethylene acid copolymer. Preferably, the non-ionomer composition is a thermoplastic elastomer selected from polyester-polyether block copolymers, polyether-amide block copolymers, and blends thereof. The resulting ball has high resiliency and rebounding properties.

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Номер записи: 8
21-03-2013 дата публикации

ADHESIVE COMPOSITION, ADHESIVE TAPE, METHOD FOR PROCESSING SEMICONDUCTOR WAFER AND METHOD FOR PRODUCING TSV WAFER

Номер: US20130071658A1
Автор: Nomura Shigeru, Sugita Daihei, Tonegawa Toru
Принадлежит: Sekisui Chemical Co., Ltd.

The present invention aims to provide an adhesive composition having high adhesive strength, as well as being easily detachable and having excellent heat resistance, an adhesive tape comprising the adhesive composition, a method for treating a semiconductor wafer using the adhesive tape, and a method for producing a TSV wafer. The present invention relates to an adhesive composition comprising: an adhesive component; and a tetrazole compound represented by the following formula (1), formula (2), or formula (3), or its salt: 2. The adhesive composition according to claim 1 ,wherein the tetrazole compound has a maximum molar extinction coefficient of 100 or higher at a wavelength of 250 to 400 nm, and has a nonvolatile matter component of 80% or higher which is measured using a thermobalance after heating of the compound from 100° C. to 200° C.3. The adhesive composition according to claim 1 ,wherein the tetrazole compound has a maximum molar extinction coefficient of 100 or higher at a wavelength of 270 to 400 nm, and has a nonvolatile matter component of 80% or higher which is measured using a thermobalance after heating of the compound from 100° C. to 200° C.4. The adhesive composition according to claim 1 ,wherein the adhesive component contains a curable adhesive whose elastic modulus increases by stimulus.5. The adhesive composition according to claim 1 , further comprising a photosensitizer.6. The adhesive composition according to claim 5 ,wherein the photosensitizer is a polycyclic aromatic compound having at least one alkoxy group.7. The adhesive composition according to claim 5 ,wherein the photosensitizer is a substituted alkoxy polycyclic aromatic compound having an alkoxy group which is partially substituted by a glycidyl group or a hydroxy group.8. An adhesive tape claim 5 , comprising:a base material; and{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'an adhesive layer which is disposed on one face of the base material and which comprises the ...

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Номер записи: 9
11-04-2013 дата публикации

PHTHALATE-FREE ISOCYANURATE FORMULATIONS

Номер: US20130090426A1
Автор: Augustin Thomas, Sanders Josef
Принадлежит:

The present invention relates to novel low-monomer-content, low-viscosity, high-activity preparations made of isocyanurates containing isocyanate groups and of phthalate-free plasticizers, to use of the same as adhesion promoters with improved adhesion for coating compositions based on plasticized polyvinyl chloride, and also to coatings and coated substrates. 1. Preparations characterized in that they comprise A) from 15 to 50% by weight isocyanurates containing isocyanate groups and B) from 85 to 50% by weight of n- or isoalkyl monobenzoates , with the proviso thati) the isocyanurate containing isocyanate groups is produced through trimerization of a mixture of 2,4-diisocyanatotoluene and 2,6-diisocyanatotoluene andii) the total of all the percentages by weight is 100%.2. Preparations according to claim 1 , characterized in that they comprise from 20 to 35% by weight of isocyanurates containing isocyanate groups and from 80 to 65% by weight of n- or isoalkyl monobenzoates.3. Preparations according to or claim 1 , characterized in that the isocyanurates containing isocyanate groups are produced from a mixture of isomeric diisocyanatotoluenes comprising from 65 to 95% by weight of 2 claim 1 ,4-diisocyanatotoluene and from 5 to 35% by weight of 2 claim 1 ,6-diisocyanatotoluene with catalysis by phenolic catalysts comprising dialkylamino groups.4. Preparations according to at least one of to claim 1 , characterized in that the n- or isoalkyl monobenzoates comprise >90% by weight of n- or isononyl benzoate.5. Use of preparations according to any of to as adhesion promoters for coating compositions based on plasticized polyvinyl chloride.6. Use according to claim 5 , characterized in that the coating compositions are used for producing substrates.7. Use according to claim 6 , characterized in that the coated substrates are used as tarpaulins claim 6 , billboards claim 6 , air-supported structures and other textile buildings claim 6 , flexible containers claim 6 , ...

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Номер записи: 10
18-04-2013 дата публикации

GLUE COMPOSITION COMPRISING THE SOLVENT N - ACETYLMORPHOLINE

Номер: US20130096242A1
Автор: Jensen Mikael
Принадлежит: NORDCOLL A/S

The present disclosure relates to glues comprising a solution of at least one water-insoluble synthetic organic polymer selected from the group consisting of PVC and ABS, said glue comprising the solvent N-Acetylmorpholine. The subject matter further relates to use of the glue for joining surfaces of articles made from material comprising water-insoluble synthetic organic polymers selected from the group comprising PVC and ABS and to use of N-Acetylmorpholine in the manufacturing of glue comprising at least one water-insoluble synthetic organic polymer selected from the group consisting of PVC and ABS. 1. A glue comprising a solution of at least one water-insoluble synthetic organic polymer selected from the group consisting of PVC and ABS , said glue comprising the solvent N-Acetylmorpholine.2. Glue according to further comprising one or more solvents selected from the group comprising 1-ethyl-2-pyrrolindone and N-methyl-2-pyrrolidone.32. Glue according to claim 1 , wherein N-Acetylmorpholine constitutes between 0.5 and 99.5% of the total content of the glue by weight claim 1 , such as between 1 and 80% claim 1 , such as between 2 and 70% claim 1 , such as between 2 and 60% claim 1 , such as between 2 and 50% claim 1 , such as between 2 and up to 40% claim 1 , such as between 2 and up to 30% claim 1 , such as between 2 and up 20% claim 1 , such as 3% claim 1 , 4% claim 1 , 4.5% claim 1 , 5% claim 1 , 6% claim 1 , 7% claim 1 , 8% claim 1 , 9% claim 1 , 10% claim 1 , 11% claim 1 , 12% claim 1 , 13% claim 1 , 14% claim 1 , 15% claim 1 , 16% claim 1 , 17% claim 1 , 18% claim 1 , 19% claim 1 , or 20% of the total weight of the glue.4. Glue according to claim 2 , wherein N-methyl-2-pyrrolidone constitutes less than 5% of the total content of the glue by weight.5. Glue according to claim 1 , wherein the total concentration of the solvents is between 50-99.9% by weight of the total content of the glue claim 1 , such as between 60-90% claim 1 , such as between 70-90% claim ...

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Номер записи: 11
02-05-2013 дата публикации

METHYLENEBIS (FATTY ACID AMIDE) COMPOSITION, ADHESIVE SHEET, AND METHOD FOR MANUFACTURING THEREOF

Номер: US20130108867A1
Автор: ASAI Fumiteru, Ishiguro Shigeki, Matsumoto Masamichi, NAGATOMO Aya, OKAWA Yuji, Ooishi Michihito, Sekiguchi Yuka, Senda Hiroki, SUGIMURA Toshimasa, Yutou Takumi
Принадлежит: NITTO DENKO CORPORATION

The present invention provides a methylenebis(fatty acid amide) composition containing as a main component a methylenebis(fatty acid amide) obtained by reacting a fatty acid monoamide with formaldehyde, a content of impurities which consist of the fatty acid monoamide and a fatty acid from which the fatty acid monoamide is constituted is 0 to less than 2 wt %, and a adhesive sheet containing the methylenebis(fatty acid amide) composition. 1. A methylenebis(fatty acid amide) composition containing as a main component a methylenebis(fatty acid amide) obtained by reacting a fatty acid monoamide with formaldehyde , a content of impurities which consist of the fatty acid monoamide and a fatty acid from which the fatty acid monoamide is constituted is 0 to less than 2 wt %.2. The methylenebis(fatty acid amide) composition according to claim 1 , wherein the methylenebis(fatty acid amide) is a compound represented by Formula (I).{'br': None, 'sup': 1', '2, 'sub': '2', 'R—Am—CH—Am—R\u2003\u2003(I)'}{'sup': 1', '2, 'sub': 6', '23, '(where in the formula, Rand Rindependently from one another represent a C-Csaturated or unsaturated hydrocarbon group, and Am represents a secondary amide group.)'}3. The methylenebis(fatty acid amide) composition according to claim 1 , wherein the methylenebis(fatty acid amide) obtained by reacting the fatty acid monoamide with formaldehyde is one in which impurities which consist of the fatty acid monoamide and the fatty acid from which the fatty acid monoamide is constituted are removed by extraction using a solvent that dissolves the fatty acid monoamide and the fatty acid and does not dissolve the methylenebis(fatty acid amide).4. A adhesive sheet formed from a thermoplastic resin film on one surface of which is formed a pressure-sensitive adhesive layer claim 1 , either of the thermoplastic resin film or the pressure-sensitive adhesive layer contains the methylenebis(fatty acid amide) composition of .5. The adhesive sheet of claim 4 , wherein ...

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Номер записи: 12
02-05-2013 дата публикации

Fluoropolymer Blend and Articles Thereof

Номер: US20130109790A1
Автор: Chou Shih-Hung, Fujita Jun, Fukushi Tatsuo, Lamanna William M., Miyazawa Haruhiko, Toyota Atsushi
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

Described herein is a composition, article and method thereof, wherein the composition comprises (i) a fluoropolymer and (ii) an ionic liquid. 1. A composition comprising (i) a fluoropolymer having a first glass transition temperature and (ii) an ionic liquid , wherein the blend of (i) and (ii) has a single , second glass transition temperature , which is different from the first glass transition temperature.2. A composition comprising(i) from 5% to 95% by weight of a fluoropolymer versus the weight of the composition and wherein the fluoropolymer has a first solubility parameter, and{'sup': '1/2', '(ii) from 0.01% to 95% by weight of an ionic liquid versus the weight of the composition wherein the ionic liquid has a second solubility parameter and wherein the absolute value of the first solubility parameter minus the second solubility parameter is less than or equal to 4 (cal/cc).'}3. The composition according to claim 1 , wherein the fluoropolymer is a copolymer.4. The composition according to claim 1 , wherein the anion of the ionic liquid comprises a perfluoroalkyl group.5. The composition according to claim 1 , wherein the cation portion of the ionic liquid is selected from N-ethyl-N′-methylimidazolium N-methyl-N-propylpiperidinium claim 1 , N claim 1 ,N claim 1 ,N-trimethyl-N-propylammonium claim 1 , N-methyl-N claim 1 ,N claim 1 ,N-tripropylammonium claim 1 , N claim 1 ,N claim 1 ,N-trimethyl-N-butylammoniuim claim 1 , N claim 1 ,N claim 1 ,N-trimethyl-N-methoxyethylammonium claim 1 , N-methyl-N claim 1 ,N claim 1 ,N-tris(methoxyethyl)ammonium claim 1 , N-methyl-N claim 1 ,N claim 1 ,N-tributylammonium claim 1 , N claim 1 ,N claim 1 ,N-trimethyl-N-hexylammonium claim 1 , N claim 1 ,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium claim 1 , 1-propyl-tetrahydrothiophenium claim 1 , 1-butyl-tetrahydrothiophenium claim 1 , glycidyltrimethylammonium claim 1 , N-ethyl-N-methylmorphonium claim 1 , N claim 1 ,N claim 1 ,N-trioctylammonium claim 1 , N-methyl-N claim 1 ,N ...

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Номер записи: 13
09-05-2013 дата публикации

Method to form an aqueous dispersion of an ionomer-polyolefin blend

Номер: US20130116373A1
Автор: Richard Allen Hayes
Принадлежит: EI Du Pont de Nemours and Co

Disclosed is a method to form an aqueous dispersion comprising a blend composition comprising or consisting essentially of about 75 to about 99.9 weight of an ionomer composition and about 0.1 to about 25 weight % of an ethylene acrylate ester copolymer composition, a grafted polyolefin composition or a combination thereof, the method comprising mixing the solid blend composition with water heated to a temperature from about 80 to about 100° C.

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Номер записи: 14
09-05-2013 дата публикации

Propylene polymer compositions

Номер: US20130116385A1
Автор: Caputo Tiziana, Ciarafoni Marco, Massari Paola
Принадлежит: Basell Poliolefine Italia, S.r.l.

A propylene polymer composition comprising: 1. A propylene polymer composition comprising:A) 70-94% wt of a propylene-ethylene copolymer comprising from 2.5 to 5% wt of ethylene derived units; andB) 6-30% wt of a second propylene-ethylene copolymer comprising from 35 to 60% wt of ethylene derived units;said propylene polymer composition having an MFR L according to ISO 1133, condition L, of from 0.1 to 5 g/10 min, and an Intrinsic Viscosity of the fraction soluble in xylene [XSIV] at room temperature from 1 to 4.5 dl/g.2. The propylene polymer composition according to having a Flexural Modulus of between 300 MPa and 500 MPa.3. The propylene polymer composition according to wherein the component A) is a propylene-ethylene copolymer comprising from 3.1 to 5% wt of ethylene derived units.4. The propylene polymer composition according to wherein the component B) is a propylene-ethylene copolymer comprising from 41 to 55% wt of ethylene derived units.5. A film comprising a propylene polymer composition according to .6. A moulded article comprising a propylene polymer composition according to . This application is the U.S. national phase of International Application PCT/EP2011/057475, filed May 10, 2011, claiming priority to European Patent Application 10163355.0 filed May 20, 2010, and the benefit under 35 U.S.C. 119(e) of U.S. Provisional Application No. 61/396,478, filed May 27, 2010; the disclosures of International Application PCT/EP2011/057475, European Patent Application 10163355.0 and U.S. Provisional Application No. 61/396,478, each as filed, are incorporated herein by reference.The present invention relates to a propylene polymer composition having an optimum balance of properties in particular an improved balance of mechanical properties and excellent physical properties.The propylene polymer composition of the present invention is particularly suitable for the production of injection moulded articles and films. For this particular application is very needed ...

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Номер записи: 15
16-05-2013 дата публикации

CURING AGENT COMPOSITION FOR EPOXY RESIN ADHESIVE FOR POROUS MATERIAL

Номер: US20130123390A1
Автор: Amano Tetsuya, Iwata Ritsuo, Ogata Tomohide, Suzuki Katsunori
Принадлежит: YAMAHA CORPORATION

An adhesive for a porous material is made of a curing agent composition and a principal component including an epoxy resin. The curing agent composition for the epoxy resin adhesive includes a water-based polyaminoamide curing agent or a water-based polyamide curing agent, having both a hydrophilic group and lipophilic group, tertiary amine, and water. The water-based polyaminoamide curing agent or the water-based polyamide curing agent is a condensate which is produced via a condensation reaction of polyaminoamide or polyamide with a dimer acid or trimer acid. The adhesive for a porous material precluding formaldehyde indicates a long pot life while demonstrating high adhesion in a short period of time. 1. A curing agent composition for an epoxy resin adhesive , including:a water-based polyaminoamide curing agent including both a hydrophilic group and lipophilic group, or a water-based polyamide curing agent including both a hydrophilic group and lipophilic group;a tertiary amine; andwater.2. The curing agent composition for the epoxy resin adhesive according to claim 1 , wherein the water-based polyaminoamide curing agent is a condensate which is produced via a condensation reaction of a polyaminoamide with a dimer acid or trimer acid.3. The curing agent composition for the epoxy resin adhesive according to claim 1 , wherein the water-based polyamide curing agent is a condensate which is produced via a condensation reaction of a polyamide with a dimer acid or trimer acid.4. An adhesive for a porous material claim 1 , comprising a principal component including an epoxy resin; anda curing agent composition including a water-based polyaminoamide curing agent including both a hydrophilic group and lipophilic group, or a water-based polyamide curing agent including both a hydrophilic group and lipophilic group;a tertiary amine; andwater.5. The adhesive for a porous material according to claim 4 , further including a polyfunctional acrylic oligomer.6. The adhesive for a ...

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Номер записи: 16
23-05-2013 дата публикации

Tackifiers For Composite Articles

Номер: US20130131230A1
Автор: Bouguettaya Mohamed, Foley Nicholas
Принадлежит: BASF SE

A composite article comprises a plurality of lignocellulosic pieces and an adhesive system disposed on the plurality of lignocellulosic pieces for bonding the plurality of lignocellulosic pieces. The adhesive system comprises a binder component and a tackifier component. The tackifier component comprises a homo- and/or co-polymer of vinyl acetate. The tackifier component is useful for maintaining orientation of the plurality of lignocellulosic pieces during manufacture of the composite article. The composite article may be various engineered lignocellulosic composites, such as particleboard. 1. A composite article comprising:a plurality of lignocellulosic pieces; andan adhesive system disposed on said plurality of lignocellulosic pieces for bonding said plurality of lignocellulosic pieces; a binder component, and', 'a tackifier component comprising a homo- and/or co-polymer of vinyl acetate for maintaining orientation of said plurality of lignocellulosic pieces during manufacture of said composite article., 'wherein said adhesive system comprises'}2. A composite article as set forth in wherein said polymer is polyvinyl acetate.3. A composite article as set forth in wherein said polymer is an ethylene-vinyl acetate (EVA) copolymer.4. A composite article as set forth in wherein said polymer is a vinyl-acetate ethylene (VAE) copolymer.5. A composite article as set forth in wherein said adhesive system is formed from said binder and said tackifier components.6. A composite article as set forth in wherein said polymer comprises;{'sub': 2', '13, 'i) a vinyl ester of a Cto Calkyl carboxylic acid ester,'}ii) ethylene,{'sub': 1', '20, 'iii) a Cto Calkyl (meth)acrylate,'}iv) an ethylenically unsaturated carboxylic acid, orv) combinations thereof.7. A composite article as set forth in wherein said polymer comprises said i) vinyl ester of a Cto Calkyl carboxylic acid ester which is selected from the group of a vinyl acetate or other vinyl ester of carboxylic acid with a linear ...

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Номер записи: 17
13-06-2013 дата публикации

METHOD OF PRODUCING FLUOROPOLYMERS USING ACID-FUNCTIONALIZED MONOMERS

Номер: US20130150519A1
Автор: Durali Mehdi, Hedhli Lotfi
Принадлежит: Arkema Inc.

A fluoropolymer latex is obtained by emulsion polymerization of one or more fluoromonomers in the presence of one or more acid-functionalized monomers such as vinyl sulfonic acid or a salt thereof. A fluorosurfactant need not be present. 1. A process for preparing a fluoropolyrner in an aqueous reaction medium , comprising:a) forming an aqueous emulsion comprising at least one radical initiator, at least one acid-functionalized monomer or salt thereof, and at least one fluoromonomer, andb) initiating polymerization of said at least one fluoromonomer.2. The process of claim 1 , wherein the process uses no surfactant.3. The process of claim 1 , wherein the process uses no fluorosurfactant.4. The process of claim 1 , wherein the aqueous emulsion additionally comprises a surfactant other than a fluorosurfactant.5. The process of claim 1 , wherein said acid-functionalized monomer or salt thereof is functionalized with at least one acid group selected from the group consisting of sulfonic acid groups claim 1 , phosphonic acid groups and carboxylic acid groups and salts thereof.6. The process of claim 1 , wherein said acid-functionalized monomer or salt thereof is vinyl sulfonic acid or a salt thereof.7. The process of claim 1 , wherein said acid-functionalized monomer or salt thereof is selected from the group consisting of vinyl sulfonic acid claim 1 , acrylic acid claim 1 , methacrylic acid claim 1 , vinyl phosphonic acid claim 1 , itaconic acid claim 1 , and salts thereof.8. The process of claim 1 , wherein the acid-functionalized monomer or salt thereof has a structure selected from:{'sub': '3', 'R—CH=CH—SOM;'}{'sub': 3', '3, 'MOS—R—CH=CH—SOM;'}{'sub': '2', 'R—CH=CH—COM;'}{'sub': 2', '2, 'CH=C(R)—COM;'}{'sub': 2', '3', '2, 'CH=CH—POM;'}{'sub': 3', '2, 'R—CH=CH—POM; and'}{'sub': 3', '2, 'R—CH=C(R)—POM;'}where R is a hydrogen atom or a hydrocarbon portion, and where N is a monovalent cation selected from the group consisting of hydrogen ion, alkali metal ions, ammonium ...

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Номер записи: 18
13-06-2013 дата публикации

HOLE TRANSPORT COMPOSITION

Номер: US20130150536A1
Автор: CHESTERFIELD REID JOHN
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

There is provided a hole transport composition having (i) a first hole transport polymer having crosslinkable groups, and (ii) a second hole transport polymer having substantially no crosslinkable groups. There is also provided a crosslinked hole transport layer and an electronic device containing the crosslinked hole transport layer. 1. A hole transport composition comprising (i) a first hole transport polymer having crosslinkable groups , and (ii) a second hole transport polymer having substantially no crosslinkable groups2. The hole transport composition of claim 1 , wherein the first hole transport polymer has a narrower band gap than the second hole transport polymer.3. The hole transport composition of claim 1 , wherein the first hole transport polymer is a copolymer of a triarylamine derivative and a fluorene derivative and the second hole transport polymer is a triarylamine polymer.45.-. (canceled)911.-. (canceled) This application claims priority tinder 35 §119(e) from U.S. Provisional Application No. 61/053,679 filed May 16, 2008 which is incorporated by reference in its entirety.1. Field of the DisclosureThis disclosure relates in general to hole transport compositions having more than one component. Such layers are useful in electronic devices.2. Description of the Related ArtIn organic photoactive electronic devices, such as organic light emitting diodes (“OLED”), that make up OLED displays, the organic active layer is sandwiched between two electrical contact layers. In an OLED the organic photoactive layer emits light through the light-transmitting electrical contact layer upon application of a voltage across the electrical contact layers.It is well known to use organic electroluminescent compounds as the active component in light-emitting diodes. Simple organic molecules, conjugated polymers, and organometallic complexes have been used. Devices that use photoactive materials frequently include one or more charge transport layers, which are positioned ...

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Номер записи: 19
20-06-2013 дата публикации

MODIFIED HIGH CIS CONJUGATED DIENE COPOLYMER AND MANUFACTURING METHOD OF THE SAME

Номер: US20130158205A1
Автор: Cheng Kuei-Lun, Lee Chih-Cheng
Принадлежит: CHI MEI CORPORATION

A modified conjugated diene polymer and a manufacturing method for the same are provided. The modified conjugated diene polymer is manufactured by the method including, forming a conjugated diene polymer by a polymerization step and making it react with a first modifier and then react with a second modifier. The modified conjugated diene polymer has over 97% of cis-1,4 structure. A PDI of the modified conjugated diene polymer is bigger than 1.8 and smaller than 2.5. The first modifier has a chemical formula of X—R1-Si(R2). The second modifier has a chemical formula of R3-Si(R4). 1. A modified conjugated diene polymer , manufactured by a method comprising forming a conjugated diene polymer by a polymerization step and enabling the conjugated diene polymer to react with a first modifier and then react with a second modifier to obtain the modified conjugated diene polymer , whereinthe modified conjugated diene polymer has a cis-1,4-structure and the cis-1,4-structure is higher than 97%,the polydispersity index (PDI) of the modified conjugated diene polymer is greater than 1.8 and less than 2.5,{'sub': '3', 'the first modifier has a chemical formula of X—R1-Si(R2), wherein X is a functional group selected from the group consisting of an epoxypropoxy group, an isocyanate group, and a 2-(3,4-epoxycyclohexyl group), R1 is an alkyl group with 2˜3 carbon atoms, R2 is an alkyl group with 2˜3 carbon atoms or an alkoxy group with 1˜3 carbon atoms;'}{'sub': '3', 'the second modifier has a chemical formula of R3-Si(R4), wherein R3 is selected from the group consisting of an alkyl group, an alkoxy group, an aromatic group, an aryloxy group and a cycloalkyl group with 1˜12 carbon atoms, R4 is selected from the group consisting of an alkyl group, an alkoxy group, an aryloxy group and a cycloalkyl group with 1˜12 carbon atoms.'}2. The modified conjugated diene polymer according to claim 1 , wherein the polymerization step is performed with an existence of a catalyst composition claim ...

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Номер записи: 20
04-07-2013 дата публикации

VINYL CHLORIDE RESIN AGGREGATE PARTICLES, PROCESS FOR PRODUCING SAME, AND GLOVE OBTAINED USING SAME

Номер: US20130167287A1
Автор: Ishihara Morio, Matsumura Kunihiko, Nagamitsu Manabu, UEDA Takashi
Принадлежит: KANEKA CORPORATION

The present invention provides: vinyl chloride-based resin aggregate particles that can be produced through a heat treatment while inhibiting scale formation within a vessel for the heat treatment and that provide a plastisol with non-infiltrating property and a satisfactory sagging property; a process for producing the particles; and a glove obtained using the particles. The vinyl chloride-based resin aggregate particles of the present invention are characterized in that the aggregate particles have a mean volume particle diameter of 10 to 60 μm, the percentage of particles having a particle diameter of 10 to 60 μm is at least 50 vol. %, and a plastisol containing 100 weight parts of the aggregate particles and 160 weight parts of di-2-ethylhexyl phthalate satisfies the relationship 3≦η70/η40≦1000 where η40 is the viscosity at a shear rate of 1 sof the plastisol that has been retained at 40° C. for 10 minutes and η70 is the viscosity at a shear rate of 1 sof the plastisol that has been warmed from 40° C. at 10° C./min. and retained at 70° C. for 3 minutes. The vinyl chloride-based resin aggregated particles are obtained by flocculating a vinyl chloride-based resin through a two-stage heat treatment consisting of a primary heat treatment and a secondary heat treatment. 1. Vinyl chloride-based resin aggregate particles , wherein the aggregate particles have a mean volume particle diameter of 10 to 60 μm , and the percentage of particles having a particle diameter of 10 to 60 μm is at least 50% by volume ,{'sup': −1', '−1, 'a plastisol comprising 100 parts by weight of the aggregate particles and 160 parts by weight of di-2-ethylhexyl phthalate satisfies a relationship of 3≦η70/η40≦1000 when η40 is a viscosity at a shear rate of 1 sof a plastisol retained at 40° C. for 10 minutes and η70 is a viscosity at a shear rate of 1 sof a plastisol that has been warmed from 40° C. at 10° C./min. and retained at 70° C. for 3 minutes.'}2. The vinyl chloride-based resin aggregate ...

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Номер записи: 21
18-07-2013 дата публикации

Golf Ball Including A Blend Of Highly Neutralized Acid Polymers And Method Of Manufacture

Номер: US20130184102A1
Автор: Arthur Molinari, Chen-Tai Liu, Chien-Hsin Chou, Hideyuki Ishii, Yasushi Ichikawa
Принадлежит: Nike Inc

A golf ball having a core layer, a mantle layer enclosing the core layer, and a cover layer enclosing the mantle layer. At least one of the layers includes a blend of at least two highly neutralized acid polymers having low flexural moduli. The relative proportion of one highly neutralized acid polymer to the other highly neutralized acid polymer is between about 10:90 and about 90:10.

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Номер записи: 22
18-07-2013 дата публикации

ADHESIVE COMPOSITIONS AND USE THEREOF

Номер: US20130184384A1
Автор: Eodice Andrea, Liu Yayun, Paul Charles W., Xiao Allison
Принадлежит: Henkel Corporation

The invention provides hot melt adhesives that comprise a templating agent, a polymer and a wax. It has been discovered that hot melt adhesives with an effective amount of templating agent have improved heat resistance than adhesives. The adhesives find particular use as case, carton, and tray forming, and as sealing adhesives, including heat sealing applications, for example in the packaging of cereals, cracker and beer products. 1. A hot melt adhesive composition comprising:a. a polymer component;b. a wax; andc. a templating agent; andwherein the templating agent is provided in an effect amount such that the ΔH of the adhesive is increased by at least 5% over an adhesive composition without the templating agent;wherein the average crystal size in the adhesive composition is increased by at least 10% over the adhesive composition without the templating agent; andwherein the heat resistance of the adhesive is increased by at least 5° F. over an adhesive composition without the templating agent.2. The adhesive of claim 1 , comprising a templating agent in an amount of about 0.01 wt % to less than about 0.5 wt % claim 1 , based on the total weight of the adhesive.3. The adhesive of wherein the polymer is a crystalline or semi-crystalline polymer.4. The adhesive of wherein the polymer is selected from the group consisting of ethylene vinyl acetate claim 3 , metallocene polyolefin claim 3 , ethylene butyl acrylate or mixtures thereof.5. The adhesive of wherein the polymer is an ethylene vinyl acetate.6. The adhesive of wherein the templating agent is a sugar and sugar alcohol derivatives claim 1 , or has a structure of:{'br': None, 'Ar-L1-X-L2-R'}wherein X is a sugar or a sugar alcohol;Ar is a substituted or unsubstituted aryl-containing functional group;R is H, alky, alkenyl, hydroxyl, alkoxy and alkyl-halide, or a substituted or unsubstituted aryl-containing functional group; andL1 and L2, independently, are acetal or ether functional group.7. The adhesive of claim 6 ...

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Номер записи: 23
01-08-2013 дата публикации

METHOD AND MATERIALS FOR SEPARATING NUCLEIC ACID MATERIALS

Номер: US20130193364A1
Автор: Wu Betty
Принадлежит:

Nucleic acid material can be effectively separated from a fluid under mild conditions by the use of a positively charged polymer which binds the nucleic acid material. Disclosed is a novel positively charged polymer which may be employed in the separation process. This polymer comprises an acidified polyamine, such as polyethyleneimine which has been reacted with a nonacidified polyethyleneimine in a coupling reaction. The acidified polyethyleneimine may be a coarboxylated and/or sulfonated polyethyleneimine. 1. A method for preparing a partially positively charged polyethyleneimine polymer , said method comprising the steps of:providing a first volume of a polyethyleneimine polymer;reacting said first volume of polyethyleneimine polymer with an acidifying agent so as to produce an acidified polyethyleneimine;providing a second volume of a polyethyleneimine polymer; andreacting said second volume of polyethyleneimine with said acidified polyethyleneimine so as to couple at least some of said carboxylated polyethyleneimine to said polyethyleneimine of said second volume.2. The method of claim 1 , wherein said acidifying agent is a carboxylating agent or a sulfonating agent.3. The method of claim 1 , wherein said acidifying agent is sodium chloroacetate.4. The method of claim 1 , wherein said first volume of polyethyleneimine and/or said second volume of polyethyleneimine has a molecular weight of approximately 400 to 200 claim 1 ,000.5. A system for separating a nucleic acid material from a fluid claim 1 , said system comprising:a positively charged polymer which is operative to bind said nucleic acid material; anda releasing agent, said releasing agent comprising a solution of an alkaline material and a glycol, said solution having a pH of no more than 12, said agent being operative to cause said nucleic acid material to be released from said polymer.6. The system of claim 5 , wherein said polyethyleneimine derivatized solid matrix material comprises a carboxylated ...

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Номер записи: 24
08-08-2013 дата публикации

FILM AND METHOD OF MANUFACTURING THE SAME, LAMINATED FILM OR SHEET, AND LAMINATED BODY

Номер: US20130202847A1
Автор: Abe Yoshinori, Konokawa Yuhei
Принадлежит: MITSUBISHI RAYON CO., LTD.

Provided is a film having high crystallinity, transparency, and surface smoothness, a lamination of the film, a sheet of the film, and a laminated body. A film contains vinylidene fluoride-based resin (A) and acrylic-based resin (B). The film has at least one surface with arithmetic mean roughness of 0.1 to 20 nm. The at least one surface has crystal fusion heat of 18 to 40 J/g and a haze value of 3.5 or less, the crystal fusion heat being measured using a differential scanning calorimeter. 1. A film containing vinylidene fluoride-based resin (A) and acrylic-based resin (B) , wherein the film has at least one surface with arithmetic mean roughness of 0.1 to 20 nm ,the film having crystal fusion heat of 18 to 40 J/g and a haze value of 3.5 or less, and the crystal fusion heat being measured using a differential scanning calorimeter.2. A method of manufacturing a film containing vinylidene fluoride-based resin (A) and acrylic-based resin (B) , wherein the film has at least one surface with arithmetic mean roughness of 0.1 to 20 nm , the film having crystal fusion heat of 18 to 40 J/g and a haze value of 3.5 or less , and the crystal fusion heat being measured using a differential scanning calorimeter , comprising:melt-extruding a resin composition containing 75 to 95% by mass of the vinylidene fluoride-based resin (A) and 5 to 25% by mass of the acrylic-based resin (B),wherein the vinylidene fluoride-based resin (A) has a melt mass-flow rate equal to or more than 10 [g/10 minutes], andthe melt mass-flow rate is measured in compliance with JISK7210 under conditions of 230° C. and a load of 3.8 kg.3. A method of manufacturing a film , comprisingmelt-extruding a resin composition containing 75 to 95% by mass of vinylidene fluoride-based resin (A) and 5 to 25% by mass of acrylic-based resin (B), andsubsequently bringing the obtained melt extrudate into contact with at least one chill roll having the surface temperature of 35 to 75° C.,wherein the vinylidene fluoride-based ...

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Номер записи: 25
15-08-2013 дата публикации

Multi-Core Golf Ball Having Increased Initial Velocity

Номер: US20130210545A1
Автор: Arthur Molinari, Chen-Tai Liu, Chien-Hsin Chou, Chin-Shun Ko, Hideyuki Ishii, Jun Ichinose, Yasushi Ichikawa
Принадлежит: Nike Inc

A golf ball having certain relationships and values of its initial velocities at various club head speeds is provided. The golf ball may achieve an initial velocity of at least about 173 mph at a club head speed of about 125 mph, therefore achieving an increased total shot distance. The golf ball has multiple layers making up its core, and the golf ball may be a four piece golf ball.

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Номер записи: 26
12-09-2013 дата публикации

HIGH-DENSITY POLYETHYLENE COMPOSITIONS AND METHOD OF MAKING THE SAME

Номер: US20130237670A1
Автор: Elley-Bristow Dale M., Gillespie David T., Hazlitt Lonnie G., JR. William J., Kay Thomas W., Michie, Whited Stephanie M.
Принадлежит: Dow Global Technologies Inc.

The instant invention is a high-density polyethylene composition, method of producing the same, articles made therefrom, and method of making such articles. The high-density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm, and a melt index (I) in the range of 0.5 to 10 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm, and a melt index (I) in the range of 50 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I) of at least 1, a density in the range of 0.950 to 0.960 g/cm, and g′ of 1. 1. A high-density polyethylene composition comprising:{'sup': '3', 'sub': '21.6', 'a first component, said first component is an ethylene alpha-olefin copolymer having a density in the range of 0.921 to 0.936 g/cm, and a melt index (I) in the range of 0.5 to 5 g/10 minutes; and'}{'sup': '3', 'sub': '2', 'a second component, said second component is an ethylene polymer having a density in the range of 0.970 to 0.975 g/cm, and a melt index (I) in the range of 500 to 1000 g/10 minutes;'}{'sub': 2', 'w', 'n, 'sup': '3', 'wherein said high-density polyethylene composition has a melt index (I) of from 1 to 20 g/10 minutes, a density in the range of 0.950 to 0.960 g/cm, and g′ of 1, and a molecular weight distribution (M/M) in the range of 7 to 17;'}wherein said high-density composition has an environmental stress crack resistance of at least 150 hours measured via ASTM D-1693 condition B, 10 percent Igepal, or at least 300 hours measured via ASTM D-1693 condition B, 100 percent Igepal.2. A high-density polyethylene composition according to claim 1 , wherein said first component has a density in the range of 0.924 to 0.932 g/cm.3. A high-density polyethylene composition according to claim 1 , wherein ...

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Номер записи: 27
19-09-2013 дата публикации

Methods of Mercaptanizing Olefinic Hydrocarbons and Compositions Produced Therefrom

Номер: US20130240780A1
Автор: Cameron Colin, Marrion Alastair Robert, Matson Michael S., NETEMEYER Eric J., Refvik Mitchell D., Wright Anthony Colin
Принадлежит: CHEVRON PHILLIPS CHEMICAL COMPANY LP

The present invention discloses processes for forming polythiol compositions from olefinic hydrocarbons such as cyclooctadiene, cyclododecatriene, and trivinylcyclohexane. The polythiol compositions produced from these processes, including the sulfur-containing compounds of these compositions, also are described. 2. The process of claim 1 , wherein the hydrocarbon compound comprises butadiene claim 1 , isoprene claim 1 , cyclobutadiene claim 1 , cyclopentadiene claim 1 , cyclohexadiene claim 1 , cyclooctadiene claim 1 , norbornadiene claim 1 , vinylcyclohexene claim 1 , vinylnorbornene claim 1 , divinylbenzene claim 1 , cyclopentadiene dimer claim 1 , trivinylcyclohexane claim 1 , trivinylbenzene claim 1 , cycloheptatriene claim 1 , dimethyl heptatriene claim 1 , octatriene claim 1 , cyclooctatriene claim 1 , cyclododecatriene claim 1 , cyclooctatetraene claim 1 , cyclododecatetraene claim 1 , a polybutadiene claim 1 , or any combination thereof.317-. (canceled)18. A polythiol composition derived from cyclododecatriene comprising sulfur-containing compounds claim 1 , the sulfur-containing compounds of the polythiol composition comprising:i) an average of at least 20 wt. % thiol sulfur; andii) an average of from 0.1 to 8 wt. % sulfide sulfur.19. The composition of claim 18 , wherein:the sulfur-containing compounds of the polythiol composition comprise from 30 to 80 wt. % trimercaptocyclododecane; orthe sulfur-containing compounds of the polythiol composition comprise from 10 to 60 wt. % dimercaptocyclododecene; orthe sulfur-containing compounds of the polythiol composition comprise less than or equal to 5 wt. % monomercaptocyclododecadiene; orthe sulfur-containing compounds of the polythiol composition comprise less than or equal to 30 wt. % sulfide compounds; orany combination thereof.20. The composition of claim 19 , wherein:the polythiol composition comprises less than 2.5 wt. % cyclododecatriene; ora weight ratio of trimercaptocyclododecane to ...

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Номер записи: 28
19-09-2013 дата публикации

PLASTISOL FOR SPRAY-MOLDED PLASTIC ARTICLES

Номер: US20130244017A1
Автор: Cassata Brent, Horton Stephen D., Tresino John
Принадлежит: POLYONE CORPORATION

A plastisol is disclosed comprising poly(vinyl halide) and a trimellitate plasticizer and a second plasticizer, with the trimellitate plasticizer comprising between about 60 and about 90 weight percent of the total plasticizer content. The plastisol can be made into a polymeric skin using spray molding techniques. The plastisol can be sprayed on a slush mold surface.

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Номер записи: 29
26-09-2013 дата публикации

SINGLE PELLET POLYMERIC COMPOSITIONS

Номер: US20130253121A1
Автор: Ashbaugh John, Li Fengkui, Rauscher David
Принадлежит: FINA TECHNOLOGY, INC.

A pellet composed of a polymeric blend having a composition of between 99.5-51 wt % polyolefin and 0.5-49.9 wt % polylactic acid. 1. A pellet comprising:a polymeric blend having a composition of between 99.5-51 wt % polyolefin and 0.5-49.9 wt % polylactic acid.2. The pellet of claim 1 , wherein the polyolefin is polypropylene or polyethylene.3. The pellet of claim 2 , wherein the polyolefin is polyethylene claim 2 , and the polyethylene is high density polyethylene (HDPE) claim 2 , low density polyethylene (LDPE) or linear low density polyethylene (LLDPE).4. The pellet of claim 2 , wherein the polyolefin is polypropylene claim 2 , and the polypropylene is a propylene homopolymer claim 2 , propylene copolymer claim 2 , or a high melt strength polypropylene.5. The pellet of claim 4 , wherein the propylene homopolymer is a high crystallinity polypropylene homopolymer.6. The pellet of claim 5 , wherein the high crystallinity polypropylene homopolymer comprises isotactic polypropylene.7. The pellet of claim 4 , wherein the propylene copolymer is a propylene random copolymer or a propylene heterophasic copolymer.8. The pellet of claim 4 , wherein the high melt strength polypropylene is a semi-crystalline polypropylene or propylene copolymer matrix comprising a heterophasic copolymer.9. The pellet of wherein the polyolefin is prepared using a Zieger-Natta catalyst.10. The pellet of wherein the polyolefin is prepared using a metallocene catalyst.11. The pellet of wherein the polylactic acid is amorphous or semi-crystalline.12. The pellet of claim 11 , wherein the pellet further comprises an additive selected from the group consisting of stabilizers claim 11 , ultra-violet screening agents claim 11 , oxidants claim 11 , anti-oxidants claim 11 , anti-static agents claim 11 , ultraviolet light absorbents claim 11 , fire retardants claim 11 , processing oils claim 11 , mold release agents claim 11 , coloring agents claim 11 , pigments/dyes claim 11 , nucleators claim 11 , ...

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Номер записи: 30
03-10-2013 дата публикации

HEAT-PEELABLE PRESSURE-SENSITIVE ADHESIVE SHEET

Номер: US20130260120A1
Автор: Hirayama Takamasa, Murata Akihisa, SHIMOKAWA Daisuke
Принадлежит: NITTO DENKO CORPORATION

There are provided a base material-less double-sided pressure-sensitive adhesive sheet without warping due to shrinkage of a base material after heat treatment, and having good peelability in heat peeling, and a method for manufacturing electronic parts or semiconductors by using the pressure-sensitive adhesive sheet. A heat-peelable pressure-sensitive adhesive sheet which is a base material-less double-sided pressure-sensitive adhesive sheet including a heat-expandable pressure-sensitive adhesive layer containing heat-expandable microspheres and a pressure-sensitive adhesive layer different from the heat-expandable pressure-sensitive adhesive layer and laminated thereon, wherein the pressure-sensitive adhesive layer has a higher elastic modulus than the heat-expandable pressure-sensitive adhesive layer. 1. A heat-peelable pressure-sensitive adhesive sheet , wherein the heat-peelable pressure-sensitive adhesive sheet is a base material-less double-sided pressure-sensitive adhesive sheet comprising: a heat-expandable pressure-sensitive adhesive layer containing heat-expandable microspheres; and a pressure-sensitive adhesive layer different from the heat-expandable pressure-sensitive adhesive layer and laminated thereon , wherein the pressure-sensitive adhesive layer has a higher elastic modulus than the heat-expandable pressure-sensitive adhesive layer.2. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the pressure-sensitive adhesive layer has an elastic modulus of 500 MPa or lower.3. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the pressure-sensitive adhesive layer comprises an energy ray-curable pressure-sensitive adhesive.4. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the pressure-sensitive adhesive layer comprises a thermosetting pressure-sensitive adhesive.5. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein an elastic ...

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Номер записи: 31
03-10-2013 дата публикации

PHTHALATE-FREE ISOCYANURATE FORMULATIONS

Номер: US20130261236A1
Автор: Augustin Thomas, Sanders Josef
Принадлежит:

The present invention relates to novel low-monomer low-viscosity high-activity formulations composed of isocyanurate containing isocyanate groups, exclusively based on 2,4-diisocyanatotoluene and phthalate-free plasticizers, to the use thereof as adhesion promoters with improved adhesion for coating compositions based on plasticized polyvinyl chloride, and to coatings and coated substrates. 1. Preparations , characterized in that these compriseA) from 15 to 50% by weight of isocyanurate containing isocyanate groupsB) from 84.99 to 49.99% by weight of n- or isoalkyl monobenzoates andC) a residual content of 2,4-TDI in the range from 0.01 to 0.099% by weight and have a viscosity in the range from 5000 to 18 000 mPas/23° C., with the proviso thati) the isocyanurate containing isocyanate groups is produced exclusively via trimizerization of 2,4-diisocyanatotoluene andii) the total of all of the percentages by weight is 100%.2. Preparations according to claim 1 , characterized in that the n- or isoalkyl monobenzoates comprise >90% by weight of n- or isononyl benzoate.3. Preparations according to or claim 1 , characterized in that they comprise from 20 to 35% by weight of isocyanurate containing isocyanate groups and from 79.99 to 64.99% by weight of n- or isoalkyl monobenzoates claim 1 , preferably n- or isononyl benzoates.4. Use of preparations according to any of to as adhesion promoters for coating compositions based on plasticized polyvinyl chloride.5. Use according to claim 4 , characterized in that the coating compositions are used for the production of substrates.6. Use according to claim 5 , characterized in that the coated substrates are used as tarpaulins claim 5 , billboards claim 5 , air-supported structures and other textile structures claim 5 , flexible containers claim 5 , polygonal roofs claim 5 , awnings claim 5 , protective apparel claim 5 , conveyor belts claim 5 , flock carpets or foamed synthetic leather.7. Use according to or claim 5 , characterized ...

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Номер записи: 32
10-10-2013 дата публикации

ENHANCED DURABILITY OF STRUCTURAL ADHESIVES

Номер: US20130266813A1
Автор: Faulkner Douglas L.
Принадлежит: GM GLOBAL TECHNOLOGY OPERATIONS LLC

An exemplary embodiment discloses a structural adhesive including a structural adhesive; and, a hydrophobic material additive comprising a material selected from the group consisting of oil and carbon black. 1. A structural adhesive comprising:a structural adhesive; and,a hydrophobic material additive comprising an oil.2. The structural adhesive of claim 1 , wherein said structural adhesive is selected from the group consisting of epoxy claim 1 , polyurethane claim 1 , acrylic claim 1 , and cyanoacrylate.3. The structural adhesive of claim 1 , wherein the structural adhesive comprises an epoxy.4. The structural adhesive of claim 1 , wherein said hydrophobic material further comprises carbon black.5. The structural adhesive of claim 4 , wherein said carbon black comprises a material suitable for use as a pigment.6. (canceled)7. The structural adhesive of claim 1 , wherein said oil comprises a vacuum pump oil.8. The structural adhesive of claim 1 , wherein said oil comprises a carbon based oil.9. The structural adhesive of claim 1 , wherein said oil comprises a siloxane based oil.10. The structural adhesive of claim 1 , wherein said hydrophobic material is present is said structural adhesive in an amount of about 0.1 wt % to about 10 wt %.11. A method of bonding structural materials comprising:providing a first member comprising a metal;applying a structural adhesive to said first member, said structural adhesive comprising a hydrophobic material additive wherein the hydrophobic material additive comprises an oil;joining a second member comprising a metal to said first member; andcuring said structural adhesive and said hydrophobic material additive to form a bond between said first and second members.12. The method of claim 11 , wherein said hydrophobic material additive is mixed with the structural adhesive including at least one of prior to or following application of the structural adhesive to the first member.13. The method of claim 11 , wherein said hydrophobic ...

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Номер записи: 33
10-10-2013 дата публикации

Benzoxazines and Compositions Containing the Same

Номер: US20130267659A1
Автор: Harriman Mark, Ward Steven
Принадлежит: CYTEC TECHNOLOGY CORP.

Disclosed herein are monofunctional benzoxazine compounds having at least one electron-withdrawing group. The monofunctional benzoxazine compounds may be combined with one or more multifunctional benzoxazine compounds to form a unique benzoxazine blend. This benzoxazine blend may be combined with additional components such as catalysts and toughening agents to form a curable resin composition suitable for forming resinous films or composite materials. The presence of monofunctional benzoxazine improves the processability of the benzoxazine-based resin composition by reducing the viscosity of the resin composition, and results in improved tack and drape in the films and composite materials formed from the composition without the loss of modulus in the cured resin. 2. The benzoxazine blend of claim 1 , wherein claim 1 , with reference to Formula I and R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , said alkyl is Calkyl claim 1 , said cycloalkyl is Ccycloalkyl claim 1 , and said cycloalkyl and aryl groups are optionally substituted by Calkyl claim 1 , halogen or amine groups.3. The benzoxazine blend of claim 1 , wherein claim 1 , with reference to Formula I and X claim 1 , X claim 1 , X claim 1 , X claim 1 , said alkyl is Calkyl claim 1 , said cycloalkyl is Ccycloalkyl claim 1 , and wherein the cycloalkyl and aryl groups are optionally substituted by Calkyl claim 1 , halogen or amine groups.6. The benzoxazine blend of claim 5 , wherein X is F or Cl claim 5 , and Y is OCH.7. The benzoxazine blend of claim 1 , wherein the weight ratio of multifunctional benzoxazine to substituted monofunctional benzoxazine is within the range of 99.9:0.1 to 50:50.8. The benzoxazine blend of claim 1 , wherein the multifunctional benzoxazine compound is a di-functional benzoxazine.10. The benzoxazine blend of claim 9 , wherein Zis selected from —[C(R)(R)]-arylene-[C(R)(R)]— claim 9 , and the chain linking the two benzoxazine groups further comprises claim 9 , or is interrupted ...

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Номер записи: 34
17-10-2013 дата публикации

HOT-SEALABLE COATING SYSTEMS AND METHOD FOR JOINING SURFACES

Номер: US20130269874A1
Автор: Achten Dirk, Büchner Jörg, Kraus Harald, Wintermantel Matthias
Принадлежит: Bayer Intellectual Property GmbH

Hot-sealable coating systems and method for joining surfaces The present invention relates to a hot-sealable coating system, comprising a polyurethane and/or polyurethane-polyurea polymer (I) and an olefin vinyl acetate copolymer (II). The polyurethane and/or polyurethane-polyurea polymer (I) is obtainable by the reaction of (A) at least one diol and/or polyol component, (B) at least one di-and/or polyisocyanate component, (C) at least one component having sulphonate and/or carboxylate groups, (D) mono-, di-and/or tri-amino-functional and/or hydroxyamino-functional compounds (as appropriate), (E) other isocyanate—reactive compounds (as appropriate). The polyurethane and/or polyurethane-polyurea polymer (I) has a glass transition temperature of ≦10 ° C. and the olefin vinyl acetate copolymer (II) has a minimum film forming temperature (white point temperature) of >+40° C. The invention also relates to the use of the coating system and a method for joining surfaces in which the coating system according to the invention is used. 115-. (canceled)16. A hot-sealable coating system , comprising: (A) at least one diol and/or polyol component,', '(B) at least one di- and/or polyisocyanate component,', '(C) at least one component having sulphonate and/or carboxylate groups,', '(D) mono-, di- and/or tri-amino-functional and/or hydroxyamino-functional compounds, as appropriate,, '(I) a polyurethane and/or polyurethane-polyurea polymer which is obtained by the reaction of(E) other isocyanate-reactive compounds, as appropriate; and(II) an olefin vinyl acetate copolymer,wherein the polyurethane and/or polyurethane-polyurea polymer (I) has a glass transition temperature of <10° C.;the glass transition temperature being determined by differential scanning calorimetry according to DIN 65467 at a heating rate of 20 K/min;andwherein the olefin vinyl acetate copolymer (II) has a minimum film forming temperature (white point temperature) of >40° C.;the minimum film forming temperature ...

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Номер записи: 35
17-10-2013 дата публикации

Coupled Polymers And Methods For Making Same

Номер: US20130274408A1
Автор: Yan Yuan-Yong
Принадлежит: BRIDGESTONE CORPORATION

Carbanionic polymer chains that contain polyene mer can be coupled after being reacted to include, at their respective termini, at least one, and preferably one, unit that is the radical of a cyclic polysiloxane. The coupled polymers are useful in preparing rubber compounds from which vulcanizates are made. 3. The method of wherein r is an integer of from 2 to 7 inclusive.4. The method of wherein r is 2 or 3.5. The method of wherein the collective molecular weight of the repeating siloxane units is no more than 400 g/mol.6. The method of wherein the collective molecular weight of the repeating siloxane units is no more than 360 g/mol.7. The method of wherein the collective molecular weight of the repeating siloxane units is no more than 340 g/mol.8. The method of wherein the collective molecular weight of the repeating siloxane units is no more than 320 g/mol.9. The method of wherein said method is characterized by said polyvalent compound being free of halogen atoms and alkoxy groups.10. The method of wherein said polyvalent compound is selected from silanes and polyisocyanates.11. The method of wherein said method is characterized by said functional initiator being defined by formula (IV) where Ris an Rgroup.12. The method of wherein said Rgroup comprises at least two ORsubstituent groups.13. The method of wherein Ris a phenyl group.14. The method of wherein said phenyl group comprises at least two ORsubstituent groups.15. (canceled)17. The method of wherein said method is characterized by said functional initiator being defined by formula (III) where Rcomprises at least two ORsubstituent groups.18. The method of wherein said method is characterized by said functional initiator being defined by formula (III) where Ris a substituted or unsubstituted phenyl group having at least one ORsubstituent group.19. The method of wherein Rcomprises at least two ORsubstituent groups.20. The method of further comprising blending said coupled polymers with particulate fillers ...

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Номер записи: 36
07-11-2013 дата публикации

COMPOSITION FOR STRUCTURAL ADHESIVE

Номер: US20130292054A1
Автор: Curet Arnaud
Принадлежит:

The invention relates to a composition for a structural acrylic adhesive that comprises an adhesion promoter including a phosphate ester and a high molecular-weight polyamine as a polymerisation accelerator. 2. The composition of claim 1 , further comprising an acid monomer that can be polymerized by free radicals.3. The composition of claim 2 , characterized in that said acid monomer that can be polymerized by free radicals is chosen from the group of maleic acid claim 2 , crotonic acid claim 2 , isophthalic acid claim 2 , fumaric acid claim 2 , methacrylic acid and acrylic acid.4. The composition of claim 1 , further comprising a compound chosen among isobornyl acrylate (IBXA) claim 1 , 2-hydroxyethyl methacrylate (HEMA) claim 1 , 2-hydroxypropyl methacrylate (HPMA) claim 1 , 2-(perfluorooctyl)ethyl acrylate (POA) claim 1 , tetrahydrofurfuryl acrylate (THFA) and isobutoxy-methylacrylamide (IBMA)5. The composition of claim 1 , further comprising a mixture of HEMA and HPMA.6. The composition of claim 1 , wherein said R3 group comprises at least one tertiary amine linked to an aromatic group.9. The composition of claim 1 , wherein said phosphate-ester-based adhesion promoter is methacrylated.10. The composition of claim 1 , wherein said phosphate-ester-based adhesion promoter is the 2-hydroxyethyl methacrylate phosphate ester or a mixture of 2-hydroxyethyl methacrylate monophosphate and diphosphate esters.11. The composition of claim 1 , further comprising an amine (d) selected from the group consisting of substituted or unsubstituted toluidines claim 1 , anilines and phenols.12. The composition of claim 1 , wherein said metallic acrylate monomer (e) is chosen in the group consisting of zinc diacrylate claim 1 , zinc dimethacrylate claim 1 , zinc monomethacrylate claim 1 , iron diacrylate claim 1 , iron dimeth-acrylate claim 1 , iron monomethacrylate claim 1 , calcium diacrylate claim 1 , calcium dimethacrylate claim 1 , calcium mono-methacrylate claim 1 , magnesium ...

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Номер записи: 37
07-11-2013 дата публикации

ADHESIVE RESIN COMPOSITION AND HOT MELT ADHESIVE OBTAINED THEREFROM

Номер: US20130296476A1
Автор: Matsunaga Koji, Yasui Hiroto
Принадлежит:

Object: To provide adhesive resin compositions improved in heat resistance without deteriorations in adhesive strength and flexibility.

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Номер записи: 38
14-11-2013 дата публикации

Vinyl Chloride Resin Composition Comprising Diethylhexylcyclohexane for Wallpaper

Номер: US20130303640A1
Автор: Jang Yeon Su, Kim Jae Song, Sim Ki Jo, YOON Kyong Jun
Принадлежит: Hanwha Chemical Corporation

The present invention relates to a vinyl chloride resin composition containing diethylhexylcyclohexane as a plasticizer. Diethylhexylcyclohexane may replace controversial phthalate based plasticizers to prevent environmental contamination and have significantly low initial viscosity and low-temperature viscosity and a remarkably low low-temperature viscosity with the passage of time as compared to the existing phthalate based plasticizers and dioctyl terephthalate, which is a non-phthalate based plasticizer, such that the vinyl chloride resin composition containing the diethylhexylcyclohexane plasticizer may have excellent workability and generate less volatile organic compounds, thereby making it possible to apply this composition to develop eco-friendly products. 1. A vinyl chloride resin composition comprising:40 to 120 parts by weight of a plasticizer including diethylhexylcyclohexane;0.5 to 7 parts by weight of a stabilizer;0.5 to 5 parts by weight of a blowing agent;30 to 150 parts by weight of a filler; and{'sub': '2', '1 to 20 parts by weight of titanium dioxide (TiO), based on 100 parts by weight of a vinyl chloride resin.'}2. The vinyl chloride resin composition of claim 1 , wherein the plasticizer further includes dioctyl terephthalate claim 1 , di-isononyl phthalate claim 1 , or a mixture thereof.3. The vinyl chloride resin composition of claim 1 , wherein the stabilizer is at least one selected from a group consisting of Ca—Zn based compounds claim 1 , K—Zn based compounds claim 1 , Ba—Zn based compounds claim 1 , organic Tin based compounds claim 1 , metallic soap based compounds claim 1 , phenolic compounds claim 1 , phosphoric acid ester based compounds claim 1 , and phosphorous acid ester based compounds.4. The vinyl chloride resin composition of claim 1 , wherein the blowing agent is at least one selected from a chemical blowing agent claim 1 , a physical blowing agent claim 1 , and a mixture thereof.5. The vinyl chloride resin composition of claim ...

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Номер записи: 39
14-11-2013 дата публикации

Chlorhexidine Gluconate Containing Solvent Adhesive

Номер: US20130303656A1
Автор: Van de Pol Vicky, Wibaux Anne Marie
Принадлежит:

Methods for incorporating chlorhexidine salts into solvent based adhesives are described. The methods involve freeze drying an aqueous solution of the chlorhexidine salt and obtaining the chlorhexidine salt in a particulate form. The dry powder can then be dissolved into an appropriate solvent used with the adhesive of interest. Also described are particles including chlorhexidine salts that are incorporated in adhesives. Also described are various medical products utilizing the adhesive and chlorhexidine compound, and related methods of use. 1. A method of forming chlorhexidine in solid form , the method comprising:providing an aqueous solution of at least one chlorhexidine salt;actively drying the aqueous solution to thereby obtain the at least one chlorhexidine salt in solid form.2. The method of wherein the aqueous solution contains the at least one chlorhexidine salt in a total concentration by weight of from about 1% to the solubility limit of the at least one chlorhexidine salt.3. The method of wherein the at least one chlorhexidine salt includes chlorhexidine gluconate or chlorhexidine digluconate.4. The method of wherein the aqueous solution of at least one chlorhexidine salt includes the chlorhexidine salt in a concentration of from about 1% to about 60%.5. The method of wherein the concentration of chlorhexidine gluconate or chlorhexidine digluconate is from about 20% to about 40%.6. The method of wherein actively drying includes at least one of freeze drying and spray drying.7. The method of wherein freeze drying is performed at a temperature within a range of from about −80° C. to about 10° C.8. The method of wherein the temperature is from about −50° C. to about 0° C.9. The method of wherein the temperature is about −20° C.10. The method of wherein freeze drying is performed at a pressure within a range of from about 0.01 bars to about 0.95 bars.11. The method of wherein the pressure is from about 0.10 bars to about 0.50 bars.12. The method of wherein ...

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Номер записи: 40
14-11-2013 дата публикации

Process For Preparing A Thixotroping Agent And Use Thereof

Номер: US20130303804A1
Автор: Austermann Tobias, Mack Helmut, Walther Burkhard
Принадлежит: Construction Research & Technology GmbH

The invention provides a process for preparing a thixotropic agent based on a urea derivative, in which the components α) comprising at least one amine and β) comprising at least one isocyanate, are supplied separately to a mixing means and are mixed with one another, the reaction mixture being discharged by spraying or squirting from the mixing means. Further disclosed is the use of the thixotropic agent in a fluid system. The process is especially suitable for preparing adhesives and sealants. 1. Process for preparing a thixotropic agent based on a urea derivative , wherein the componentsα) comprising at least one amine andβ) comprising at least one isocyanate,are supplied separately to a mixing means and are mixed with one another, the reaction mixture being discharged by spraying or squirting from the mixing means.2. Process according to claim 1 , wherein this mixing means is a spray head.3. Process according to claim 1 , wherein components α) and β) are introduced with a pressure of at least 40 to 200 bar into the mixing means.4. Process according to claim 1 , wherein the molar ratio of the amine groups of the amine-comprising component to the isocyanate groups of the isocyanate-comprising component is 5:1 to 1:5.5. Process according to claim 1 , wherein the amine of component α) comprises N-n-alkylamine and/or N-n-alkenylamine and/or secondary N-alkylamine having 1 to 22 carbon atoms and/or polyetheramines.6. Process according to claim 1 , wherein the isocyanate of component β) comprises hexamethylene 1 claim 1 ,6-diisocyanate (HDI) claim 1 , 1-isocyanato-3 claim 1 ,3 claim 1 ,5-trimethyl-5-isocyanatomethylcyclohexane (IPDI) claim 1 , 2 claim 1 ,4- and/or 2 claim 1 ,6-tolylene diisocyanate (TDI) and/or 4 claim 1 ,4′- claim 1 , 2 claim 1 ,4′- and/or 2 claim 1 ,2′-diphenylmethane diisocyanate (MDI) claim 1 , m-xylene diisocyanate (MXDI) claim 1 , m- or p-tetramethylxylene diisocyanate (m-TMXDI claim 1 , p-TMXDI) claim 1 , Desmodur 3600® (product of Bayer AG ...

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Номер записи: 41
28-11-2013 дата публикации

SEALANT ARTICLES AND COMPOSITIONS USEFUL THEREIN

Номер: US20130312904A1
Автор: Ferguson Gregory A., HOWARD Don K., PACHL Jeffrey T., RORIE Grady C.
Принадлежит: Henkel AG & Co. KGaa

A sealant article useful for sealing a substrate surface having a first surface and a second surface is provided. The first surface comprises a deformable composition that is capable of conforming to a substrate surface when subjected to heat and/or pressure. The second surface of the sealant article has been at least partially cured by exposing said surface to an amount of radiation effective to induce at least partial curing of the second surface of the sealant article. Prior to such curing, the second surface also is comprised of the deformable composition. Such at least partial curing is effective to render the second surface less deformable than the first surface. 1. A deformable composition capable of being cured by exposure to radiation , said deformable composition comprising at least one thermoplastic , at least one (meth)acrylate-functionalized monomer or oligomer , at least one thermally activatable free radical initiator , and at least one filler.2. The deformable composition of claim 1 , additionally comprising at least one tackifier.3. The deformable composition of claim 1 , additionally comprising at least one reactive tackifier.4. The deformable composition of claim 1 , additionally comprising at least one liquid diene homopolymer or copolymer containing pendant vinyl groups.5. The deformable composition of claim 1 , comprising at least one thermally activatable free radical initiator selected from the group consisting of organic peroxides.6. The deformable composition of claim 1 , comprising at least one thermoplastic copolymer of ethylene and at least one comonomer selected from the group consisting of vinyl acetate claim 1 , (meth)acrylic acid claim 1 , and C1 to C6 alkyl esters of (meth)acrylic acid.7. The deformable composition of claim 1 , comprising at least one thermoplastic that is an ethylene/vinyl acetate copolymer.8. The deformable composition of claim 1 , additionally comprising at least one photoinitiator.9. The deformable composition ...

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Номер записи: 42
28-11-2013 дата публикации

RAPIDLY CURING COMPOUND HAVING GOOD ADHESIVE PROPERTIES

Номер: US20130317169A1
Автор: Futscher Michael, Luft Werner
Принадлежит: TREMCO ILLBRUCK PRODUKTION GMBH

A curable compound is provided, which can be obtained as a mixture of at least two components to be stored separately, of which one component includes a silane-modified polymer and the component of a second component includes an acid or basic salt containing water of crystallization. An aminic adhesion promoter is contained in one or both components or a further component, with the stipulation that no component contains all three substances. Additionally, a method is provided for accelerating the curing of a silane-modified polymer, in which an acid or basic salt containing water of crystallization is added to the silane-modified polymer. 117-. (canceled)18. A curable compound , which can be obtained as a mixture of at least two components to be stored separately , a first component comprises a silane-modified polymer , and the first component or a second component comprises an acid or basic salt containing water of crystallization , and an aminic adhesion promoter is contained in at least one of the first component , the second component or a third component , wherein the adhesion promoter is an aminic silane or a siloxane compound , provided that none of the components contains a silane-modified polymer and an acid or basic salt containing water of crystallization , and an aminic adhesion promoter , wherein the silane-modified polymer is a silane-modified polyether or a silane-modified polyurethane or a mixture thereof different from silicones and having a structure{'br': None, 'sub': 3', '3, '(alkyl-O)—Si—X-polymer-X—Si—(O-alkyl)'}{'br': None, 'or'}{'br': None, 'sub': 2', '2, '(alkyl-O)(alkyl)-Si—X-polymer-X—Si-(alkyl)(O-alkyl)'}wherein X is an alkylene compound group, andwherein the salt containing water of crystallization is a hydroxide phosphate.19. The compound according to claim 18 , wherein a cation of the salt is selected from ammonium and metal cations of metals of main group III or subgroup VIII of the Periodic Table.20. The compound according to claim ...

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Номер записи: 43
05-12-2013 дата публикации

AQUEOUS AMINE-CARBOHYDRATE THERMOSETS HAVING REDUCED WEIGHT LOSS UPON CURE AND IMPROVED EARLY DRY STRENGTH

Номер: US20130323492A1
Автор: Finch William Christopher, Lee Haksu, RAND Charles J., RODOWSKI C. Damien, WEINSTEIN Barry
Принадлежит: Rohm and Haas Company

The present invention provides thermosetting aqueous binder compositions comprising one or more reducing sugar, one or more diprimary diamine or poly(primary amine), and from 7 to 45 wt. %, based on total solids, of one or more polysaccharide having a dextrose equivalent (DE) value of from 5 to 30. The compositions provide treated articles, such as fiberglass mat. The binders provide articles having a dramatically reduced binder weight loss upon cure and a reduction in cure energy needed to achieve early dry strength. 1. An aqueous thermosetting binder composition comprise i) one or more reducing sugar , ii) one or more diprimary diamine or poly(primary amine) , wherein the weight ratio of the total diprimary diamine or poly(primary amine) solids to total reducing sugar solids ranges from 1.2:1 to 0.12:1; iii) from 7 to 45 wt. % , based on total solids , of one or more polysaccharide having a dextrose equivalent (DE) value of from 5 to 30.2. The composition as claimed in claim 1 , wherein the reducing sugar is dextrose.3. The composition as claimed in claim 1 , wherein the diprimary diamine or poly(primary amine) is a diprimary diamine.4. The composition as claimed in claim 3 , wherein diprimary diamine is hexamethylene diamine (NMDA).5. The composition as claimed in claim 1 , wherein the one or more polysaccharide has a DE value of from 7 to 23.6. The compositions as claimed in claim 5 , wherein the one or more polysaccharide is a maltodextrin.7. The composition as claimed in claim 1 , wherein the one or more polysaccharide is present in the amount of from 10 to 30 wt. % based on total solids.8. The composition as claimed in claim 1 , further comprising one or more stabilizer.9. A method of using the aqueous thermosetting binder composition as claimed in comprising:applying the binder composition to or mixing it with a substrate and then heating the thus treated substrate or mixture to cure the binder at from 100 to 400° C.10. A treated fiber matt containing a ...

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Номер записи: 44
05-12-2013 дата публикации

PRESSURE-SENSITIVE ADHESIVE COMPOSITION AND PRESSURE-SENSITIVE ADHESIVE SHEET

Номер: US20130323498A1
Автор: OOTAKE Hironao, TAKAHASHI Akiko, Yamamoto Kenichi
Принадлежит: NITTO DENKO CORPORATION

The pressure-sensitive adhesive composition provided by the present invention comprises an acrylic polymer as a base polymer and a tackifier resin having a softening point of 125° C. or above. The tackifier resin content is less than 20 parts by mass relative to 100 parts by mass of the acrylic polymer. 1. A pressure-sensitive adhesive composition comprising an acrylic polymer as a base polymer , and a tackifier resin having a softening point of 125° C. or above , wherein the tackifier resin content is less than 20 parts by mass relative to 100 parts by mass of the acrylic polymer.2. The pressure-sensitive adhesive composition according to comprising a solvent that comprises primarily water or ethyl acetate.4. The pressure-sensitive adhesive composition according to claim 1 , wherein the tackifier resin is selected from rosin-based resins claim 1 , rosin derivative resins and terpene-based resins.6. The pressure-sensitive adhesive composition according to claim 2 , wherein the tackifier resin is selected from rosin-based resins claim 2 , rosin derivative resins and terpene-based resins.7. The pressure-sensitive adhesive composition according to claim 3 , wherein the tackifier resin is selected from rosin-based resins claim 3 , rosin derivative resins and terpene-based resins.8. The pressure-sensitive adhesive composition according to claim 5 , wherein the tackifier resin is selected from rosin-based resins claim 5 , rosin derivative resins and terpene-based resins.9. A pressure-sensitive adhesive sheet comprising a pressure-sensitive adhesive layer claim 5 , wherein the pressure-sensitive adhesive layer comprises an acrylic polymer as a base polymer and a tackifier resin having a softening point of 125° C. or above claim 5 , with the tackifier resin content being less than 20 parts by mass relative to 100 parts by mass of the acrylic polymer.10. The pressure-sensitive adhesive sheet according to satisfying the following property:(A) in a light-press repulsion ...

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Номер записи: 45
12-12-2013 дата публикации

TREAD COMPOUND COMPRISING TRIALKOXYMERCAPTOALKYL-SILANES

Номер: US20130331523A1
Автор: Privitera Davide
Принадлежит: BRIDGESTONE CORPORATION

A method of producing a rubber compound, including a first mixing step of mixing at least one cross-linkable unsaturated-chain polymer base, silica, and a silane coupling agent in the mercaptoalkyl-silane class; and a final mixing step, in which a curing system is added to the mix. The silane coupling agent is used in adsorbed form on dibenzothiazyl disulphide. 1. A method of producing a rubber compound , comprising a first mixing step of mixing at least one cross-linkable unsaturated-chain polymer base , silica , and a silane coupling agent in the mercaptoalkyl-silane class; and a final mixing step , in which a curing system is added to the mix; said method being characterised in that said silane coupling agent is used in adsorbed form on dibenzothiazyl disulphide.2. A method of producing a rubber compound claim 1 , as claimed in claim 1 , characterized in that claim 1 , at said first mixing step claim 1 , the mix comprises 10 to 100 phr of silica with a superficial area of 170 to 230 m/g.3. A method of producing a rubber compound claim 2 , as claimed in claim 2 , characterized in that claim 2 , at said first mixing step claim 2 , the mix comprises 1 to 20 phr of a silane coupling agent in the trialkoxymercaptoalkyl-silane class.4. A method of producing a rubber compound claim 1 , as claimed in claim 1 , characterized in that said silane coupling agent is used in adsorbed form on 0.5 to 6 phr of said dibenzothiazyl disulphide.5. A method of producing a rubber compound claim 1 , as claimed in claim 1 , characterized in that said silane coupling agent is also used in adsorbed form on 5 to 10 phr of carbon black.6. A method of producing a rubber compound claim 1 , as claimed in claim 1 , characterized in that said silane coupling agent has the formula (I){'br': None, 'sup': 1', '2', '3, 'sub': '2', 'RRSi—R—SH \u2003\u2003(I)'}where:{'sup': 1', '2', '3, 'Rrepresents a linear, cyclic or branched alkoxyl group with 1 to 8 carbon atoms; Rrepresents a linear, cyclic or ...

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Номер записи: 46
26-12-2013 дата публикации

Fluoropolymer Resin Treatment Employing Melt Extrusion and Exposure to Oxygen Source to Reduce Discoloration

Номер: US20130345368A1
Автор: BROTHERS PAUL DOUGLAS, Chapman Gregory Allen, Gangal Subhash Vishnu
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

Process for reducing thermally induced discoloration of melt-processible fluoropolymer resin produced by polymerizing fluoromonomer in an aqueous medium to form aqueous fluoropolymer dispersion and isolating said fluoropolymer from said aqueous medium to obtain said fluoropolymer resin. The process comprises: 1. Process for reducing thermally induced discoloration of melt-processible fluoropolymer resin , said fluoropolymer resin produced by polymerizing fluoromonomer in an aqueous dispersion medium to form aqueous fluoropolymer dispersion and isolating said fluoropolymer from said aqueous medium to obtain said fluoropolymer resin , said process comprising:melt extruding said fluoropolymer resin to produce molten fluoropolymer resin; andexposing said molten fluoropolymer resin to an oxygen source during said melt extruding.2. The process of wherein said process reduces thermally induced discoloration by at least about 10% as measured by ° A) change in L* on the CIELAB color scale.3. The process of wherein said aqueous fluoropolymer dispersion contains hydrocarbon surfactant which causes said thermally induced discoloration.4. The process of wherein said fluoropolymer dispersion is polymerized in the presence of hydrocarbon surfactant.5. The process of wherein said oxygen source is air claim 1 , oxygen rich gas claim 1 , or ozone containing gas.6. The process of wherein the fluoropolymer resin is heated to a temperature above its melting point up to a temperature of about 400° C.7. The process of wherein said melt extruding is carried out in a melt extruder having at least one high shear section and molten fluoropolymer resin is exposed to said oxygen source in said high shear section.8. The process of wherein said exposing of fluoropolymer resin to an oxygen source during said melt extruding is carried out in multiple stages.9. The process of wherein the fluoropolymer resin has an initial thermally induced discoloration value (L*) at least about 4 L units on the ...

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Номер записи: 47
02-01-2014 дата публикации

ADHESIVE COMPOSITION AND USE THEREOF

Номер: US20140000806A1
Автор: Han Yi, He Bangfang, Shi Yifang, Zhao Xiaodong
Принадлежит: Celanese International Corporation

The invention discloses an adhesive composition suitable for bonding wood, in particular hardwood. The adhesive composition comprises a vinyl acetate-ethylene copolymer-based emulsion, a vinyl alcohol polymer, and a polyisocyanate. The process for preparing the adhesive composition and use of the same are also disclosed. 1. An adhesive composition , comprising: (1) 70 to 95% by weight of a moiety derived from vinyl acetate;', '(2) 5 to 30% by weight of a moiety derived from ethylene; and', '(3) 0 to 5% by weight of a moiety derived from other ethylenic unsaturated monomers,, '(a) 1 to 50% by weight of a vinyl acetate-ethylene copolymer-based emulsion, wherein the copolymer comprises, based on the total weight of the copolymerwherein the copolymer-based emulsion is formed by emulsion polymerization of the monomers in the presence of 0 to 3% by weight of an at least partially water-soluble polymeric protective colloid and 1 to 5% by weight of a surfactant, based on the total weight of the monomers,(b)15 to 1% by weight of a vinyl alcohol polymer; and(c) 25 to 5% by weight of a polyisocyanate, based on the total weight of the composition.2. The composition according to claim 1 , wherein the surfactant is selected from anionic surfactants or nonionic surfactants.3. The composition according to claim 2 , wherein the anionic surfactants are selected from alkylsulfonates claim 2 , arylsulfonates claim 2 , alkylsulfates claim 2 , sulfonated alkyl esters claim 2 , alkali salts of fatty acids claim 2 , or mixtures thereof.4. The composition according to claim 2 , wherein the nonionic surfactants are selected from alkyl polyoxyethylene ethers.5. The composition according to claim 1 , wherein the polymeric protective colloid is selected from polyvinyl alcohol claim 1 , cellulosic ethers claim 1 , or mixtures thereof.6. The composition according to claim 5 , wherein the polyvinyl alcohol has a degree of alcoholysis of 75 to 95% claim 5 , preferably 80 to 90%.7. The composition ...

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Номер записи: 48
02-01-2014 дата публикации

ACCELERATORS FOR TWO STEP ADHESIVE SYSTEMS

Номер: US20140000807A1
Автор: Birkett David P., Hurlburt Lynnette, Jacobine Anthony F., Messana Andrew D., Mullen David, OUYANG Jiangbo, Schall Joel D., Shah Smita, Wyer Martin
Принадлежит:

Benzoylthiourea or benzoylthiourethane derivatives as cure accelerators in primers for two step adhesive systems are provided. 1. FieldBenzoylthiourea or benzoylthiourethane derivatives as cure accelerators in primers for two step adhesive systems are provided.2. Brief Description of Related TechnologyCurable adhesive and sealant compositions oftentimes rely on curatives to make them commercially attractive options for end users. Curable adhesive and sealant compositions come in one part formats, two part formats and two step formats depending on the performance profile they are designed to meet and the constituents used to prepare the compositions. Anaerobic adhesives are prominent one part compositions and generally are well-known. See e.g., R. D. Rich, “Anaerobic Adhesives” in 29, 467-79, A. Pizzi and K. L. Mittal, eds., Marcel Dekker, Inc., New York (1994), and references cited therein. Their uses are legion and new applications continue to be developed.Conventional anaerobic adhesives ordinarily include a free-radically polymerizable acrylate ester monomer, together with a peroxy initiator and an inhibitor component. Oftentimes, such anaerobic adhesive compositions also contain accelerator components to increase the speed with which the composition cures.Anaerobic cure-inducing compositions ordinarily used in commercial anaerobic adhesive and sealant compositions to induce and accelerate cure ordinarily include saccharin, toluidines, such as N,N-diethyl-p-toluidine (“DE-p-T”) and N,N-dimethyl-o-toluidine (“DM-o-T”), acetyl phenylhydrazine (“APH”), maleic acid, and quinones, such as napthaquinone and anthraquinone. See e.g. U.S. Pat. Nos. 3,218,305 (Krieble), 4,180,640 (Melody), 4,287,330 (Rich) and 4,321,349 (Rich).GC Corporation submitted to the U.S. Patent and Trademark Office a patent application, which published as U.S. Patent Application Publication No. 2010/0249266, and is directed to a polymerizable composition comprising a first paste and a second paste ...

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Номер записи: 49
02-01-2014 дата публикации

ACCELERATOR/OXIDANT/PROTON SOURCE COMBINATIONS FOR TWO PART CURABLE COMPOSITIONS

Номер: US20140004366A1
Автор: Hurlburt Lynette, Jacobine Anthony F., Messana Andrew D., Schall Joel D.
Принадлежит: Henkel Corporation

Benzoylthiourea or benzoylthiourethane derivatives, together with oxidants and a source of protons, acting as cure accelerators for two part curable compositions are provided. 2. The composition of claim 1 , wherein the (meth)acrylate component is represented by HC═CGCOR claim 1 , wherein G may be hydrogen or alkyl groups having from 1 to about 4 carbon atoms claim 1 , and Rmay be selected from alkyl claim 1 , cycloalkyl claim 1 , alkenyl claim 1 , cycloalkenyl claim 1 , alkaryl claim 1 , aralkyl or aryl groups having from 1 to about 16 carbon atoms claim 1 , any of which may be optionally substituted or interrupted as the case may be with silane claim 1 , silicon claim 1 , oxygen claim 1 , halogen claim 1 , carbonyl claim 1 , hydroxyl claim 1 , ester claim 1 , carboxylic acid claim 1 , urea claim 1 , urethane claim 1 , carbonate claim 1 , amine claim 1 , amide claim 1 , sulfur claim 1 , sulfonate claim 1 , and sulfone.3. The composition of claim 1 , wherein the oxidant is a member selected from the group consisting of cumene hydroperoxide claim 1 , para-menthane hydroperoxide claim 1 , t-amyl hydroperoxide claim 1 , 1 claim 1 ,1 claim 1 ,3 claim 1 ,3-tetramethylbutyl hydroperoxide claim 1 , t-butyl hydroperoxide claim 1 , t-butyl perbenzoate claim 1 , benzoyl peroxide claim 1 , dibenzoyl peroxide claim 1 , 1 claim 1 ,3-bis(t-butylperoxyisopropyl)benzene claim 1 , diacetyl peroxide claim 1 , butyl 4 claim 1 ,4-bis(t-butylperoxy)valerate claim 1 , p-chlorobenzoyl peroxide claim 1 , t-butyl cumyl peroxide claim 1 , t-butyl perbenzoate claim 1 , di-t-butyl peroxide claim 1 , dicumyl peroxide claim 1 , 2 claim 1 ,5-dimethyl-2 claim 1 ,5-di-t-butylperoxyhexane claim 1 , 2 claim 1 ,5-dimethyl-2 claim 1 ,5-di-t-butyl-peroxyhex-3-yne claim 1 , 4-methyl-2 claim 1 ,2-di-t-butylperoxypentane and combinations thereof.4. The composition of claim 1 , wherein the proton source is selected from the group consisting of water claim 1 , alcohols claim 1 , acids claim 1 , and aldehydes ...

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Номер записи: 50
09-01-2014 дата публикации

BONDING COMPOSITION AND BOARD

Номер: US20140011042A1
Автор: Sugawara Ryo, Umemura Kenji
Принадлежит: Panasonic Corporation

The purpose of the present invention is to provide a bonding composition having high adhesion, from which formaldehyde is hardly released. The present invention relates to a bonding composition cured through heating and pressing. The bonding composition contains a polyvalent carboxylic acid. 1. A bonding composition to be cured through heating and pressing , comprising:a polyvalent carboxylic acid having a plurality of carboxyl groups in a molecule;a saccharide; andp-toluenesulfonic acid.217.-. (canceled)18. A bonding composition to be cured through heating and pressing , comprising:a polyvalent carboxylic acid having a plurality of carboxyl groups in a molecule; anda furan compound.19. The bonding composition according to claim 18 , further comprising a saccharide.20. The bonding composition according to claim 19 , further comprising p-toluenesulfonic acid.21. The bonding composition according to claim 1 , whereinthe bonding composition is at least in form of an aqueous solution where the polyvalent carboxylic acid is dissolved in water or an aqueous dispersion where the polyvalent carboxylic acid is dispersed in water.22. The bonding composition according to claim 18 , further comprising a thickening agent.23. The bonding composition according to claim 1 , wherein:a composition ratio in parts by mass of the polyvalent carboxylic acid to a total of the polyvalent carboxylic acid and the saccharide is 10 or more and less than 100:100; anda composition ratio in parts by mass of the saccharide to the total of the polyvalent carboxylic acid and the saccharide is more than 0 and not more than 90:100.24. A board obtained through heating and pressing element pieces such as fibers claim 23 , fragments and single plates derived from woody or herbaceous plants claim 23 , which the bonding composition according to is applied to or sprayed on claim 23 , to cure the bonding composition.25. A board obtained through heating and pressing element pieces such as inorganic fibers and ...

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Номер записи: 51
09-01-2014 дата публикации

COATED PRESSURE SENSITIVE ADHESIVE GRANULES

Номер: US20140011912A1
Автор: Hatfield Stephen F., PETRY Gerald, Puerkner Eckhard
Принадлежит: Henkel AG & Co. KGaa

The hot melt pressure-sensitive adhesive (PSA) in the form of a granulate, the granulate comprises a core made of a hot melt pressure-sensitive adhesive and an outer layer, surrounding said core, made of a composition that is not pressure-sensitively adhesive, where the outer layer contains: 5 to 35 wt % of a hydrogenated styrene block copolymer; 20 to 65 wt % of at least one oil; and 0 to 15 wt % additives. 1. A hot melt pressure-sensitive adhesive in the form of a granulate , the granulate comprises:(1) a core made of the hot melt pressure-sensitive adhesive and '(a) 5 to 35 wt % of a styrene block copolymer, (b) 20 to 65 wt % of at least one oil, and (c) 0 to 15 wt % additives, and', '(2) an outer layer, surrounding said core, made from a composition comprising'}wherein the outer layer is not a pressure-sensitive adhesive.2. The hot melt pressure-sensitive adhesive according to claim 1 , wherein the composition further comprises 5 to 30 wt % of a polyolefin copolymer selected from LDPE or EVA.3. The hot melt pressure-sensitive adhesive according to claim 1 , wherein the oil is selected from hydrocarbon oil claim 1 , paraffin oils claim 1 , naphthenic oil or medicinal white oils.4. The hot melt pressure-sensitive adhesive according to claim 3 , wherein the quantity of oil in the outer layer is greater than the combined quantities of oil and plasticizer in the core.5. The hot melt pressure-sensitive adhesive according to claim 1 , wherein the weight of the outer layer is 5 to 20 wt % of the total weight of the granulate.6. The hot melt pressure-sensitive adhesive according to claim 1 , wherein the outer layer has a softening point range of 80 to 135° C.7. The hot melt pressure-sensitive adhesive according to claim 1 , wherein the granulate is free-flowing.8. The hot melt pressure-sensitive adhesive according to claim 1 , wherein the outer layer comprises a casing made from the composition comprising:(a) 5 to 30 wt % of a styrene block copolymer;(b) 5 to 30 wt % of ...

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Номер записи: 52
16-01-2014 дата публикации

Selectively-Releasable Adhesives and Articles That Incorporate Them

Номер: US20140018718A1
Автор: Rosing Howard
Принадлежит:

In one embodiment, a selectively-releasable adhesive includes a base adhesive compound and a releasing compound that is blended with the base adhesive compound, the releasing compound being capable of decreasing the adhesive strength of the base adhesive compound when a releasing agent is applied to the selectively-releasable adhesive. 1. A selectively-releasable adhesive comprising:a base adhesive compound; anda releasing compound that is blended with the base adhesive compound, the releasing compound being capable of decreasing the adhesive strength of the base adhesive compound when a releasing agent is applied to the selectively-releasable adhesive.2. The selectively-releasable adhesive of claim 1 , wherein the base adhesive compound comprises approximately 50 to 95 percent weight of the selectively-releasable adhesive and the releasing compound comprises approximately 5 to 50 percent weight of the selectively-releasable adhesive.3. The selectively-releasable adhesive of claim 1 , wherein the base adhesive compound comprises approximately 80 to 90 percent weight of the selectively-releasable adhesive and the releasing compound comprises approximately 20 to 10 percent weight of the selectively-releasable adhesive.4. The selectively-releasable adhesive of claim 1 , wherein the base adhesive compound is an acrylic polymer adhesive claim 1 , a silicone adhesive claim 1 , a rubber adhesive claim 1 , a polyurethane adhesive claim 1 , a hydrocolloid blended with an adhesive claim 1 , or a mixture thereof.5. The selectively-releasable adhesive of claim 1 , wherein the base adhesive compound is an acrylic polymer adhesive.6. The selectively-releasable adhesive of claim 1 , wherein the releasing compound is an uncured prepolymer formed from a multifunctional alcohol and a multifunctional carboxylic acid.7. The selectively-releasable adhesive of claim 6 , wherein the multifunctional alcohol is selected from the group consisting of glycerol claim 6 , monomeric carbohydrates ...

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Номер записи: 53
23-01-2014 дата публикации

Fast Curing CPVC Solvent Cement

Номер: US20140020828A1
Автор: Hampton, III Forest, Parhar Amrit Kaur
Принадлежит:

A composition and method of using the composition are described. The composition is useful for quickly bonding chlorinated polyvinylchloride during installation and repair operations. Embodiments of the composition include at least one volatile organic solvent, chlorinated polyvinylchloride dissolved in the solvent and the composition is substantially free of cyclohexanone. 1. A solvent cement for bonding CPVC pipe and other molded articles , comprising:a first solvent selected from the group consisting of THF, MEK, ACE in an amount from 0 to 80% by weight;a second solvent selected from the group consisting of THF, MEK and ACE in an amount from 0 to 10% by weight;at least one chlorinated thermoplastic resin in an amount of between 12 and 22% by weight, dissolved in the solvent; andwherein the solvent cement is substantially free of cyclohexanone.2. The cement of wherein:the first solvent is THF and is present in amount of 65 to 80% by weight;the second solvent is ACE and is present in an amount of 0 to 6% by weight; andthe thermoplastic resin is CPVC present in an amount of 15-20%.3. The cement of claim 2 , comprising THF in an amount of 70 to 75% by weight.4. The cement of comprising ACE in an amount of 5% by weight.5. The cement of wherein the thermoplastic resin is CPVC.6. The cement of claim 5 , wherein the CPVC is present in an amount of 17-18% by weight.7. The cement of claim 2 , further comprising stabilizers and thickeners.8. The cement of claim 2 , wherein CPVC is present in an amount of 18%; THF is present in an amount of 73%; and ACE is present in an amount of 5%.9. A method for bonding two CPVC articles claim 2 , comprising:applying a solvent cement composition to a surface to be bonded on a first CPVC article, the composition comprising a first volatile organic solvent in an amount from 0 to 80% by weight, a second volatile organic solvent in an amount from 0 to 10% by weight, CPVC in an amount from 12-22%, and wherein the composition is substantially ...

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Номер записи: 54
30-01-2014 дата публикации

REACTIVE HOT MELT ADHESIVE

Номер: US20140027056A1
Автор: Suen Wu
Принадлежит: Henkel Corporation

The present invention relates to silane reactive hot melt adhesive compositions having improved green strength, the production of such adhesives and the use of such adhesives. 1. A silane reactive hot melt adhesive composition comprising:a silane modified polymer and 0.1% to 15% of acid functional wax.2. The silane reactive hot melt adhesive composition of further comprising adhesion promoter.3. The silane reactive hot melt adhesive composition of further comprising an aminosilane adhesion promoter.4. The silane reactive hot melt adhesive composition of further comprising an aminosilane adhesion promoter wherein the molar ratio of acid functionality from the acid functional wax and amino functionality of the aminosilane (R) is equal to or less than 1.8.5. The silane reactive hot melt adhesive composition of further comprising an aminosilane adhesion promoter wherein the molar ratio of acid functionality from the acid functional wax and amino functionality of the aminosilane (R) is about 0.3 to about 1.2.6. The silane reactive hot melt adhesive composition of being free of isocyanate functionality.7. The silane reactive hot melt adhesive composition of further comprising one or more of a tackifier selected from rosin ester claim 1 , aromatic tackifier or mixtures thereof; an acrylic polymer; and a catalyst.10. The silane reactive hot melt adhesive composition of claim 1 , wherein the silane modified polymer has a backbone structure selected from polyurethane claim 1 , polyether claim 1 , polyester claim 1 , polyacrylate or polyolefin.13. The silane reactive hot melt adhesive composition of claim 1 , further comprising a rosin tackifier selected from the group consisting of fully or partially hydrogenated rosin esters.14. The silane reactive hot melt adhesive composition of claim 1 , further comprising an aromatic tackifier selected from the group consisting of alpha-methyl styrene resins claim 1 , Chydrocarbon resins claim 1 , aliphatic-modified aromatic Chydrocarbon ...

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Номер записи: 55
30-01-2014 дата публикации

RE-PEELABLE WATER DISPERSION TYPE ACRYL-BASED PRESSURE-SENSITIVE ADHESIVE COMPOSITION, PRESSURE-SENSITIVE ADHESIVE SHEET, AND OPTICAL MEMBER

Номер: US20140030515A1
Автор: Amano Tatsumi, Mitsui Kazuma, Morimoto Yu, Yonezaki Kousuke
Принадлежит: NITTO DENKO CORPORATION

An aim of the prevention invention is to provide a re-peelable water dispersion type acryl-based pressure-sensitive adhesive composition, which can prevent electrification at the time of peeling off under low humidity environments (an antistatic property for peeling off in low humidity) independently of an adherend and which can form a pressure-sensitive adhesive layer excellent in adherability and re-peelable properties. The re-peelable water dispersion type acryl-based pressure-sensitive adhesive composition of the present invention contains an acrylic emulsion-based polymer composed of a (meth)acrylic acid alkyl ester in an amount of 70 to 99.5% by weight and a carboxyl-containing unsaturated monomer in an amount of 0.5 to 10% by weight as raw material monomers, a crosslinking agent, and an ionic compound, wherein the acrylic emulsion-based polymer has an average particle diameter of 130 to 550 nm. 1. A re-peelable water dispersion type acryl-based pressure-sensitive adhesive composition comprising an acrylic emulsion-based polymer composed of a (meth)acrylic acid alkyl ester in an amount of 70 to 99.5% by weight and a carboxyl-containing unsaturated monomer in an amount of 0.5 to 10% by weight as raw material monomers , a crosslinking agent , and an ionic compound , whereinthe acrylic emulsion-based polymer has an average particle diameter of 130 to 600 nm.2. The re-peelable water dispersion type acryl-based pressure-sensitive adhesive composition according to claim 1 , wherein the ionic compound contains an imide-containing anion.3. The re-peelable water dispersion type acryl-based pressure-sensitive adhesive composition according to claim 1 , wherein the ionic compound contains a sulfonyl-containing anion.4. The re-peelable water dispersion type acryl-based pressure-sensitive adhesive composition according to claim 1 , wherein the ionic compound contains a fluoroalkyl-containing anion.6. The re-peelable water dispersion type acryl-based pressure-sensitive ...

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Номер записи: 56
06-02-2014 дата публикации

RESIN COMPOSITION, PRESSURE-SENSITIVE ADHESIVE COMPOSITION, PRESSURE-SENSITIVE ADHESIVE LAYER, PRESSURE-SENSITIVE ADHESIVE SHEET, AND SURFACE PROTECTIVE FILM

Номер: US20140039123A1
Автор: ANDO Masahiko, ISEKI Toru, JO Souya, SASAKI Shogo
Принадлежит: NITTO DENKO CORPORATION

A resin composition includes: a polyol (A) having two or more OH groups; a polyfunctional isocyanate compound (B); and a catalyst (C), in which: the content ratio of the polyfunctional isocyanate compound (B) with respect to 100 parts by weight of the polyol (A) is 1 part by weight to 100 parts by weight; and the catalyst (C) includes an iron complex compound. The resin composition can serve as a pressure-sensitive adhesive composition that is a material for forming a pressure-sensitive adhesive layer containing a polyurethane-based resin, the resin composition showing extremely high reactivity without any use of a tin compound as a catalyst, allowing a cross-linking reaction between a polyol and a polyfunctional isocyanate compound to rapidly progress, and being capable of providing a pressure-sensitive adhesive layer having high transparency. Also provided are a pressure-sensitive adhesive sheet and a surface protective film each including such pressure-sensitive adhesive layer. 1. A resin composition , comprising:a polyol (A) having at least two OH groups;a polyfunctional isocyanate compound (B); anda catalyst (C),wherein:a content ratio of the polyfunctional isocyanate compound (B) with respect to 100 parts by weight of the polyol (A) is 1 part by weight to 100 parts by weight; andthe catalyst (C) comprises an iron complex compound.2. A resin composition according to claim 1 , wherein the catalyst (C) comprises an iron chelate compound.3. A pressure-sensitive adhesive composition claim 1 , comprising the resin composition according to .4. A pressure-sensitive adhesive layer claim 3 , which is obtained by curing the pressure-sensitive adhesive composition according to .5. A pressure-sensitive adhesive sheet claim 3 , comprising:a backing layer; and{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, 'the pressure-sensitive adhesive layer according to formed on at least one surface of the backing layer.'}6. A surface protective film claim 3 , comprising:a backing ...

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Номер записи: 57
13-02-2014 дата публикации

Polymeric Composition for Cement Based Substructures

Номер: US20140044879A1
Автор: Leaman Michael Ray
Принадлежит: UNISEAL SOLUTIONS INC.

The present invention is directed to a composition capable of inhibiting moisture vapor emission from concrete structures and enhancing adhesion of a finish material to the concrete structure comprising an aqueous mixture of a first copolymer of mer units formed from vinylidene halide and a C1-C2 alkyl acrylate with a second copolymer of mer units formed from vinylidene halide and a C4-CS alkyl acrylate and to the method of forming a moisture barrier/adhesion promoter coating on concrete comprising applying from 2.8 to 5.6 liters (0.75 to 1.5 gallons) of an aqueous carrier having from 10 to 50 weight percent of the mixture of copolymers stated above per 14 m2 (150 square feet) of the free surface of a concrete structure. 1. A composition composed of an aqueous mixture of at least one first copolymer comprising mer units derived from vinylidene halide and mer units derived from C-Calkyl acrylate , said mer units derived from C-Calkyl acrylate being present in from 5 to 40 weight percent of the first copolymer; and at least one second copolymer comprising mer units derived from vinylidene halide and mer units derived from C-Calkyl acrylate , said mer units derived from C-Calkyl acrylate being present in from 3 to 40 weight percent of the second copolymer , wherein said first copolymer and said second copolymer are in a weight ratio of 90:10 to 10:90; the first and second copolymers together form from 10 to 50 weight percent of the aqueous mixture; and the aqueous mixture has a pH of 1.5 to 3.5.2. The composition of wherein the first copolymer comprises from 5 to 15 weight percent of mer units derived from a C-Calkyl acrylate and the second copolymer comprises from 3 to 10 weight percent of mer units derived from C-Calkyl acrylate.3. The composition of wherein the first copolymer comprises a first copolymer comprising mer units of methyl acrylate and vinylidene chloride; and the second copolymer comprises mer units of butyl acrylate and vinylidene chloride.4. The ...

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Номер записи: 58
20-02-2014 дата публикации

POLYMERIC SURFACE OXIDATION USING PERACIDS

Номер: US20140051812A1
Автор: Burmaster Brian
Принадлежит:

A method for oxidizing polymeric surfaces to render them hydrophilic and more amenable to wetting is disclosed. The method comprises reacting the surface of a hydrophobic polymer with a peracid, especially Caro's acid, under conditions effective to render the surface more hydrophilic. Although strong oxidants can easily carbonize or discolor the surface of organic polymers, polymers can be rendered more hydrophilic without these problems when process conditions are carefully controlled. Specifically, treatment of the polymer surface with a peracid such as Caro's acid requires judicious selection of oxidation temperature, acid concentration, and peroxide content to achieve reaction rates that provide the desired level of hydrophilicity without charring or otherwise damaging the polymer. 1. A method which comprises reacting the surface of a hydrophobic polymer with a peracid under conditions effective to render the surface more hydrophilic.2. The method of wherein the peracid is selected from the group consisting of Caro's acid and peroxyphosphoric acid.3. The method of wherein the peracid is Caro's acid.4. The method of wherein the Caro's acid comprises at least 2 wt. % of hydrogen peroxide and less than 90 wt. % of sulfuric acid.5. The method of wherein the Caro's acid comprises at least 3 wt. % of hydrogen peroxide and less than 85 wt. % of sulfuric acid.6. The method of wherein the sulfuric acid is present in an amount within the range of 70 to 90 wt. %.7. The method of wherein the hydrogen peroxide is present in an amount within the range of 2 to 15 wt. %.8. The method of wherein the Caro's acid comprises at least 5 wt. % of water.9. The method of wherein the Caro's acid comprises at least 10 wt. % of water.10. The method of wherein the reacted surface has carboxylic acid groups claim 1 , sulfonic acid groups claim 1 , or both.11. The method of wherein the hydrophobic polymer is polypropylene.12. The method of wherein the reacted surface when wetted with water ...

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Номер записи: 59
06-03-2014 дата публикации

POLYMER PREPARING METHOD AND POLYMER PREPARED BY THE SAME

Номер: US20140066573A1
Автор: KIM Su Jeong, Yoon Jeong Ae
Принадлежит: LG CHEM, LTD.

Provided is a polymer preparing method. By additionally inputting a catalytic reducing agent that reduces an inactivated metal complex compound catalyst to an activated metal complex compound catalyst, a polymer polymerized at a high conversion ratio of a monomer can be provided. 1. A polymer preparing method comprising:bringing a catalyst, a ligand, a halogenated polymer compound, and a polymeric monomer into contact with one another; andadditionally inputting a catalytic reducing agent.2. The method of claim 1 , wherein the catalytic reducing agent is additionally input when a conversion ratio of the polymeric monomer is 10% or more.3. The method of claim 1 , wherein the catalytic reducing agent is input in an amount of 10 parts to 2000 parts by weight with respect to 100 parts by weight of the catalyst.4. The method of claim 1 , wherein the catalyst includes one selected from the group consisting of Cu(0) claim 1 , Fe(0) claim 1 , CuTe claim 1 , CuSe claim 1 , CuS claim 1 , and CuO.5. The method of claim 4 , wherein the catalyst further includes a compound represented by the following Chemical Formula 1:{'br': None, 'sub': '2', 'Cu(II)X/L \u2003\u2003[Chemical Formula 1]'}where, in Chemical Formula 1, X represents a halogen element and L represents a ligand.6. The method of claim 1 , wherein the catalytic reducing agent is an organic reducing agent capable of donating electrons or an inorganic reducing agent capable of donating electrons.7. The method of claim 6 , wherein the organic reducing agent includes one or more selected from the group consisting of peroxides claim 6 , azo compounds claim 6 , ascorbic acid claim 6 , monosaccharide compounds claim 6 , phenol compounds claim 6 , amine compounds claim 6 , and hydrazine compounds.8. The method of claim 6 , wherein the inorganic reducing agent includes at least one selected from the group consisting of metal compounds or zerovalent metals.9. A polymer preparing method comprising:forming a mixture by mixing a ...

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Номер записи: 60
13-03-2014 дата публикации

Labels Compatible with Recycling

Номер: US20140069587A1
Автор: AKELEY James P., BLACKWELL Christopher J., RACKOVAN Mitchell J.
Принадлежит: AVERY DENNISON CORPORATION

The present invention relates to adhesive compositions, facestocks and/or packaging labels containing same, where such compositions, facestocks and/or labels are designed to facilitate the recyclability of a plastic article formed from any suitable polymer or mixture of polymers (e.g., a polyethylene terephthalate (PET), recycled polyethylene terephthalate (rPET), high density polyethylene (HDPE), polyvinyl chloride (PVC), low density polyethylene (LDPE), polypropylene (PP), polystyrene (PS), polyesters, recycled polyesters, polylacticacid (PLA), biopolymers, cellulose or other types of polymers or plastics). In another embodiment, the present invention relates to a method for removing an adhesive composition, facestock and/or packaging label containing same, from a plastic article that is to be recycled and/or subjected to multi-generational recycling. 1. A method of removing a facestock/adhesive construction from one or more articles to be recycled , the method comprising the steps of: a face layer, wherein the face layer is formed from a facestock material selected from olefin polymers, polystyrene, PET, rPET, polylactic acid, biopolymers, cellulose, and combinations thereof; and', 'an adhesive layer,, '(a) supplying at least one article to be later recycled, the article having attached thereto at least one facestock/adhesive construction including'}wherein the facestock is able to be removed from a plastic or metal article in a manner that enables recycling of the plastic or metal article; and(b) subjecting the article containing the at least one facestock/adhesive construction to at least one caustic solution until the facestock/adhesive construction releases from the article to be recycled.2. The method of claim 1 , wherein the temperature of the caustic solution is between 75° C. and 95° C.3. The method of claim 1 , where the concentration of caustic material in the caustic solution is 10% or less.4. The method of any of claim 1 , where the caustic solution ...

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Номер записи: 61
27-03-2014 дата публикации

RESIN COMPOSITION

Номер: US20140087152A1
Автор: Nakamura Shigeo, TSURUI Kazuhiko, YODA Masanori
Принадлежит: AJINOMOTO CO., INC.

Resin compositions which contain an epoxy resin, an alkoxy oligomer, and an inorganic filler provide insulating layers that have a surface with not only low arithmetic mean roughness but also low root mean square roughness in a wet roughening step and that are capable of forming thereon a plated conductive layer having a sufficient peel strength that can be formed while maintaining the glass transition temperature and thermal expansion coefficient. 1. A resin composition , comprising (A) at least one epoxy resin , (B) at least one alkoxy oligomer , and (C) at least one inorganic filler.2. A resin composition according to claim 1 , wherein at least part of said at least one alkoxy oligomer (B) is reacted with said at least one inorganic filler (C) to form a reaction product.3. A resin composition according to claim 2 , which is formed by reacting said at least one alkoxy oligomer (B) and said at least one inorganic filler (C) in advance and then adding the resultant product to said at least one epoxy resin (A).4. A resin composition according to claim 3 , formed by reacting said at least one alkoxy oligomer (B) and said at least one inorganic filler (C) at a temperature of 50 to 150° C. for a time of 0.5 to 3 hours in advance and adding the resultant product to said at least one epoxy resin (A).5. A resin composition according to claim 2 , wherein a carbon amount per unit surface area of said at least one inorganic filler (C) is 0.05 mg/mor more.6. A resin composition according to claim 5 , wherein a value of [the amount (mg) of carbon atom in said at least one alkoxy oligomer (B) reacted with said at least one inorganic filler (C)/surface area (m) of said at least one inorganic filler (C)] is 0.05 mg/mor more.7. A resin composition according to claim 1 , wherein a content of said at least one alkoxy oligomer (B) is 0.1 to 5% by mass when a content of said at least one inorganic filler (C) is defined as 100% by mass.8. A resin composition according to claim 1 , ...

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Номер записи: 62
27-03-2014 дата публикации

Branched Polyethylenes by Hydrosilation Grafting to Improve Processability of Polyethylene

Номер: US20140088213A1
Автор: Donna J. Crowther, Jianya Cheng, Pradeep P. Shirodkar, Rahul R. KULKARNI
Принадлежит: ExxonMobil Chemical Patents Inc

This invention relates to blends of polyalphaolefins (PAOs) and polyhydrosilane-modified polyolefins, methods to prepare the blends and methods to prepare polyhydrosilane-modified polyolefins.

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Номер записи: 63
27-03-2014 дата публикации

Hydrosilation of Vinyl-Terminated Macromonomers

Номер: US20140088263A1
Автор: Brant Patrick, Crowther Donna J., Lopez-Barron Carlos R., Lovell Jacqueline A., NG Man Kit, Ruff Charles J.
Принадлежит:

This invention relates to the reaction product(s) of a polyalkylhydrosiloxane and a vinyl terminated macromonomer (VTM). 1. The reaction product of a polyalkylhydrosiloxane and one or more vinyl terminated macromonomers (VTMs).2. The reaction product of claim 1 , wherein the VTM is one or more of:(i) a vinyl terminated oligomer or co-oligomer having at least 5% allyl chain ends;{'sup': '1', 'sub': 4', '40, '(ii) a vinyl terminated oligomer or co-oligomer having an Mn of at least 160 g/mol (measured by H NMR) comprising of one or more Cto Chigher olefin derived units, where the higher olefin polymer comprises substantially no propylene derived units; and'}wherein the higher olefin polymer has at least 5% allyl chain ends;{'sup': '1', 'sub': 5', '40, '(iii) a co-oligomer having an Mn of 300 g/mol or more (measured by H NMR) comprising (a) from 20 mol % to 99.9 mol % of at least one Cto Chigher olefin derived units, and (b) from 0.1 mol % to 80 mol % of propylene derived units, wherein the higher olefin copolymer has at least 40% allyl chain ends;'}{'sup': '1', 'sub': '4', '(iv) a co-oligomer having an Mn of 300 g/mol or more (measured by H NMR), and comprises (a) from 80 mol % to 99.9 mol % of at least one Colefin derived unit, (b) from 0.1 mol % to 20 mol % of propylene derived units; and wherein the vinyl terminated macromonomer has at least 40% allyl chain ends relative to total unsaturation;'}{'sup': '1', '(v) a co-oligomer having an Mn of 300 g/mol to 30,000 g/mol (measured by H NMR) comprising 10 mol % to 90 mol % propylene derived units and 10 mol % to 90 mol % of ethylene derived units, wherein the co-oligomer has at least X % allyl chain ends (relative to total unsaturations), where: 1) X=(−0.94*(mol % ethylene incorporated)+100), when 10 mol % to 60 mol % ethylene derived units are present in the co-oligomer, 2) X=45, when greater than 60 mol % and less than 70 mol % ethylene derived units are present in the co-oligomer, and 3) X=(1.83*(mol % ethylene ...

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Номер записи: 64
27-03-2014 дата публикации

Oxygenation of Vinyl-Terminated Macromonomers

Номер: US20140088266A1
Автор: Harris David T., Stewart Ian C.
Принадлежит:

This invention relates to relates to a polyolefin composition comprising one or more of the following formulae: 2. The polyolefin composition of claim 1 , wherein the VTM is one or more of:(i) a vinyl terminated polymer having at least 5% allyl chain ends;{'sup': '1', 'sub': 4', '40, '(ii) a vinyl terminated polymer having an Mn at least 160 g/mol, preferably of at least 200 g/mol (measured by H NMR) comprising of one or more Cto Chigher olefin derived units, where the higher olefin polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends;'}{'sup': '1', 'sub': 5', '40, '(iii) a copolymer having an Mn of 300 g/mol or more (measured by H NMR) comprising (a) from about 20 mol % to about 99.9 mol % of at least one Cto Chigher olefin, and (b) from about 0.1 mol % to about 80 mol % of propylene, wherein the higher olefin copolymer has at least 40% allyl chain ends;'}{'sup': '1', 'sub': '4', '(iv) a copolymer having an Mn of 300 g/mol or more (measured by H NMR), and comprises (a) from about 80 mol % to about 99.9 mol % of at least one Colefin, (b) from about 0.1 mol % to about 20 mol % of propylene; and wherein the vinyl terminated macromonomer has at least 40% allyl chain ends relative to total unsaturation;'}{'sup': '1', '(v) a co-oligomer having an Mn of 300 g/mol to 30,000 g/mol (measured by H NMR) comprising 10 mol % to 90 mol % propylene and 10 mol % to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends (relative to total unsaturations), where: 1) X=(−0.94*(mol % ethylene incorporated)+100), when 10 mol % to 60 mol % ethylene is present in the co-oligomer, 2) X=45, when greater than 60 mol % and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 mol % to 90 mol % ethylene is present in the co-oligomer;'}(vi) a propylene oligomer, comprising more than 90 mol % propylene and less than 10 mol % ethylene ...

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Номер записи: 65
05-01-2017 дата публикации

FLUORINE RUBBER COMPOSITION, CROSSLINKED RUBBER MOLDED BODY AND METHOD FOR PRODUCING SAME

Номер: US20170002153A1
Автор: Osumi Naoki, Toda Sayaka
Принадлежит: NIPPON VALQUA INDUSTRIES, LTD.

Provided are: a fluorine rubber composition which contains a hydrogen atom-containing fluorine rubber and a hydrogen atom-containing fluororesin; a crosslinked rubber molded body which uses this fluorine rubber composition; and a method for producing this crosslinked rubber molded body. It is preferable that the hydrogen atom-containing fluororesin is composed of at least one compound that is selected from the group consisting of polyvinylidene fluorides, vinylidene fluoride-hexafluoropropylene copolymers, tetrafluoroethylene-ethylene copolymers and vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene copolymers. 1. A fluorine rubber composition comprising a hydrogen atom-containing fluorine rubber and a hydrogen atom-containing fluororesin.2. The fluorine rubber composition according to claim 1 , wherein a content of said hydrogen atom-containing fluororesin is 1 to 50 parts by weight relative to 100 parts by weight of said hydrogen atom-containing fluorine rubber.3. The fluorine rubber composition according to claim 1 , wherein the fluorine rubber composition further comprises an organic peroxide and a co-crosslinking agent.4. The fluorine rubber composition according to claim 1 , wherein said hydrogen atom-containing fluororesin is at least one compound selected from the group consisting of polyvinylidene fluoride claim 1 , a vinylidene fluoride-hexafluoropropylene copolymer claim 1 , a tetrafluoroethylene-ethylene copolymer and a vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene copolymer.5. The fluorine rubber composition according to claim 1 , wherein the fluorine rubber composition contains no inorganic filler.6. A crosslinked rubber molded body comprising a crosslinked product of the fluorine rubber composition according to .7. The crosslinked rubber molded body according to claim 6 , wherein the crosslinked rubber molded body is a sealing material for semiconductor manufacturing devices.8. A method for producing a crosslinked rubber molded ...

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Номер записи: 66
04-01-2018 дата публикации

VINYL CHLORIDE-VINYL ACETATE COPOLYMER AND METHOD OF PREPARING THE SAME

Номер: US20180002466A1
Автор: LEE Chan Hee, LEE Hyun Min, Lee Kwang Jin, YOUK Kyung Seog
Принадлежит:

The present invention relates to a vinyl chloride-vinyl acetate copolymer, which may exhibit excellent tensile strength even during low-temperature processing, and a method of preparing the same. The copolymer according to the present invention may exhibit excellent tensile strength even during low-temperature processing by including a vinyl acetate-derived unit in a specific ratio and having a specific range of polydispersity index, for example, a polydispersity index of 2.1 to 2.4, at a degree of polymerization of 1,200 to 1,300. Thus, the vinyl chloride-vinyl acetate copolymer according to the present invention and the method of preparing the same may be easily applied to industries that need them, particularly, automotive industry or polyvinyl chloride resin industry. 1. A vinyl chloride-vinyl acetate copolymer which has a polydispersity index (PDI) of 2.1 to 2.4 at a degree of polymerization of 1 ,200 to 1 ,300 and comprises 4 wt % to 7 wt % of a vinyl acetate-derived unit.2. The vinyl chloride-vinyl acetate copolymer of claim 1 , wherein the copolymer has a polydispersity index (PDI) of greater than 2.1 and less than 2.3.3. The vinyl chloride-vinyl acetate copolymer of claim 1 , wherein the copolymer has a weight-average molecular weight (Mw) of 160 claim 1 ,000 g/mol to 165 claim 1 ,000 g/mol.4. The vinyl chloride-vinyl acetate copolymer of claim 1 , wherein the copolymer comprises 5 wt % to 6 wt % of the vinyl acetate-derived unit.5. The vinyl chloride-vinyl acetate copolymer of claim 1 , wherein the copolymer has a tensile strength of 10 MPa to 14 MPa claim 1 , andwherein the tensile strength is measured according to ASTM D638 after a sample having a width of 6.25 mm and a thickness of 1.5 mm is prepared by heat-treating the copolymer at 130° C. for 30 minutes.6. The vinyl chloride-vinyl acetate copolymer of claim 1 , wherein the copolymer has an elongation (%) of 600% to 1 claim 1 ,100% claim 1 , andwherein the elongation is measured according to ASTM D638 ...

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Номер записи: 67
07-01-2021 дата публикации

LOW-DIELECTRIC ADHESIVE COMPOSITION

Номер: US20210002523A1
Автор: KAWAKUSU Tetsuo, MIKAMI Tadahiko, SONODA Ryo
Принадлежит: TOYOBO CO., LTD.

The present invention aims to provide an adhesive composition which exhibits high adhesive property not only to the conventional polyimide and polyester film but also to a metal substrate, can achieve high solder heat resistance and exhibits excellent low-dielectric characteristics. According to the present invention, there is provided an adhesive composition containing an acid-modified polyolefin (a), an oligo-phenylene ether (b) having a number-average molecular weight of 3000 or less, and an epoxy resin (c), wherein the adhesive composition satisfies the following requirement(s) (A) and/or (B): 1. An adhesive composition containing an acid-modified polyolefin (a) , an oligo-phenylene ether (b) having a number-average molecular weight of 3000 or less , and an epoxy resin (c) , wherein the adhesive composition satisfies the following requirement(s) (A) and/or (B):(A) The adhesive composition contains more than 20 parts by mass and 60 parts by mass or less of the epoxy resin (c) to 100 parts by mass of the acid-modified polyolefin (a);(B) The adhesive composition further contains a polycarbodiimide (d).2. The adhesive composition according to claim 1 , wherein the acid value of the acid-modified polyolefin (a) is 5 to 40 mg KOH/g.4. The adhesive composition according to claim 1 , wherein the adhesive composition contains 0.05 to 200 part(s) by mass of the oligo-phenylene ether (b) having a number-average molecular weight of 3000 or less to 100 parts by mass of the acid-modified polyolefin (a).5. The adhesive composition according to claim 1 , wherein the adhesive composition contains 0.5 to 20 part(s) by mass of the polycarbodiimide (d) to 100 parts by mass of the acid-modified polyolefin (a).6. The adhesive composition according to claim 1 , wherein the adhesive composition has a relative dielectric constant (ε) at 1 GHz of 3.0 or less and a dielectric tangent (tan δ) at 1 GHz of 0.02 or less.7. A adhesive sheet which contains the adhesive composition mentioned in ...

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Номер записи: 68
03-01-2019 дата публикации

NONAQUEOUS SOL-GEL FOR ADHESION ENHANCEMENT OF WATER-SENSITIVE MATERIALS

Номер: US20190002739A1
Автор: HUFF Daniel W., KENNEDY Dennis K., Moore James A.
Принадлежит:

The present disclosure provides sol-gel films and substrates, such as vehicle components, having a sol-gel film disposed thereon. At least one sol-gel formulation has about 10 wt % or less water content based on the total weight of the sol-gel formulation and comprises an organosilane, a metal alkoxide, an acid stabilizer, and an organic solvent. At least one vehicle component comprises a sol-gel coating system comprising a metal substrate and a sol-gel formulation disposed on the metal substrate. The sol-gel formulation has about 10 wt % or less water content based on the total weight of the sol-gel formulation and comprises an organosilane, a metal alkoxide, an acid stabilizer, and an organic solvent. 1. A sol-gel formulation comprising:an organosilane;a metal alkoxide;an acid stabilizer; andan organic solvent, wherein the sol-gel formulation has about 10 wt % or less water content based on the total weight of the sol-gel formulation.2. The sol-gel formulation of claim 1 , wherein the sol-gel formulation has from about 0.1 wt % to about 20 wt % organosilane claim 1 , from about 0.1 wt % to about 10 wt % metal alkoxide claim 1 , and from about 0.1 wt % to about 10 wt % acid stabilizer based on the total weight of the sol-gel formulation.3. The sol-gel formulation of claim 2 , wherein the sol-gel formulation has a water content from about 0.1 wt % to about 3 wt % based on the total weight of the sol-gel formulation.4. The sol-gel formulation of claim 3 , wherein the sol-gel formulation has a water content of about 0.5 wt % or less based on the total weight of the sol-gel formulation.5. The sol-gel formulation of claim 1 , wherein the organic solvent is one or more of alcohol claim 1 , ethylene glycol claim 1 , propylene glycol claim 1 , polyethylene glycol claim 1 , polypropylene glycol claim 1 , an ether claim 1 , tetrahydrofuran claim 1 , N-methyl-2-pyrrolidone claim 1 , and dimethyl sulfoxide.6. The sol-gel formulation of claim 5 , wherein the organic solvent is ...

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Номер записи: 69
03-01-2019 дата публикации

NONAQUEOUS SOL-GEL FOR ADHESION ENHANCEMENT OF WATER-SENSITIVE MATERIALS

Номер: US20190002740A1
Автор: HUFF Daniel W., KENNEDY Dennis K., Moore James A.
Принадлежит:

The present disclosure provides methods for forming sol-gels, sol-gel films and substrates, such as vehicle components, having a sol-gel film disposed thereon. At least one method of forming a sol-gel includes mixing a metal alkoxide, an acid stabilizer, and an organic solvent to form a first mixture having about 10 wt % or less water content based on the total weight of the first mixture. The method includes mixing an organosilane with the first mixture to form a second mixture having about 10 wt % or less water content based on the total weight of the second mixture. 1. A method of forming a sol-gel , comprising:mixing a metal alkoxide, an acid stabilizer, and an organic solvent to form a first mixture having about 10 wt % or less water content based on the total weight of the first mixture; andmixing an organosilane with the first mixture to form a second mixture having about 10 wt % or less water content based on the total weight of the second mixture.2. The method of claim 1 , wherein mixing to form the first mixture comprises dispersing claim 1 , emulsifying claim 1 , suspending claim 1 , or dissolving the metal alkoxide and acid stabilizer in the organic solvent.3. The method of claim 1 , further comprising incubating the second mixture at a temperature from about 10° C. to about 100° C.4. The method of claim 1 , further comprising curing the second mixture at a temperature from about 10° C. to about 150° C.5. The method of claim 1 , further comprising depositing the first mixture or the second mixture onto a metal substrate that comprises one or more of aluminum claim 1 , aluminum alloy claim 1 , nickel claim 1 , iron claim 1 , iron alloy claim 1 , steel claim 1 , titanium claim 1 , titanium alloy claim 1 , copper claim 1 , and copper alloy.6. The method of claim 5 , further comprising cleaning the metal substrate by degreasing claim 5 , alkaline washing claim 5 , chemical etching claim 5 , chemically deoxidizing claim 5 , and/or mechanically deoxidizing the ...

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Номер записи: 70
13-01-2022 дата публикации

BRANCHED AMINO ACID SURFACTANTS FOR INKS, PAINTS, AND ADHESIVES

Номер: US20220010161A1
Автор: Asirvatham Edward
Принадлежит:

Inks, paints, adhesives, and paint strippers may be formulated to include one or more branched surfactants, from one or more surfactant classes, such as derivatives of amino acids that have surface-active properties. 2. The formulation of claim 1 , wherein the fixer agent is a metal carboxylate.3. The formulation of claim 1 , further comprising at least one of:a humectant;an acid;an aqueous vehicle; anda colorant.6. The formulation of claim 5 , further comprising at least one of:one or more driers;one or more solvents; andone or more pigments.9. The formulation of claim 8 , further comprising at least one of:one or more driers;one or more solvents; andone or more pigments.12. The formulation of claim 11 , further comprising a filling agent.15. The formulation of claim 14 , further comprising at least one of:a wax;a corrosion inhibitor;an organic solvent; anda thickener.18. The formulation of claim 17 , wherein the one or more co-solvents are selected from aromatic alcohols claim 17 , aromatic ethers claim 17 , and aliphatic alcohols.19. The formulation of claim 17 , further comprising at least one of:a wax;a corrosion inhibitor;an organic solvent; anda thickener. This application claims priority to Provisional Application No. 63/051,191, filed Jul. 13, 2020, which is herein incorporated by reference in its entirety.The present disclosure pertains to branched surfactants for use in adhesives and paints. Such branched surfactants may include derivatives of amino acids wherein the derivatives have surface-active properties.Surfactants (molecules with surface-active properties) are widely used in commercial formulations of inks, paints, adhesives, and paint strippers. The surfactants may be included as emulsifiers, wetting agents, foaming agents, dispersants, and/or agents to improve spreadability.The surfactants may be uncharged, zwitterionic, cationic, or anionic. Although in principle any surfactant class (e.g., cationic, anionic, nonionic, amphoteric) is suitable, ...

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Номер записи: 71
01-01-2015 дата публикации

GRAFTED POLYMERS AS OLEOPHOBIC LOW ADHESION ANTI-WETTING COATINGS

Номер: US20150005454A1
Автор: Badesha Santokh S., CHIDAMBARESWARAPATTAR Chakkaravarthy, Gervasi David J., Kanungo Mandakini, Kelly Matthew M., ROETKER Michael S., Sambhy Varun
Принадлежит: XEROX CORPORATION

An oleophobic grafted polymer includes a crosslinked fluoroelastomer and a perfluorinated polyether grafted to the crosslinked fluoroelastomer. A process for making an oleophobic grafted polymer includes crosslinking a fluoroelastomer with an aminofunctionalized silane and grafting an alkoxysilane-terminated perfluorinated polyether to the crosslinked fluoroelastomer. 1. An oleophobic grafted polymer comprising:a crosslinked fluoroelastomer; anda perfluorinated polyether grafted to the crosslinked fluoroelastomer.2. The oleophobic grafted polymer of claim 1 , wherein the fluoroelastomer is crosslinked with an aminofunctionalized silane.3. The oleophobic grafted polymer of claim 2 , wherein the aminofunctionalized silane provides graft attachment points.4. The oleophobic grafted polymer of claim 2 , wherein the aminofunctionalized silane comprises an aminoalkylsilane-modified polysiloxane.6. The oleophobic grafted polymer of claim 5 , wherein the linker L comprises a C-Calkyl terminating in a functional group capable of covalently linking to a terminal hydroxyl functionality group of the perfluorinated polyether.7. The oleophobic grafted polymer of claim 5 , wherein the fluoroelastomer (FE) is a polymer comprising a monomer unit selected from the group consisting of vinylidene fluoride claim 5 , tetrafluorethylene claim 5 , hexafluoropropylene claim 5 , perfluoromethylvinylether and combinations thereof.8. The oleophobic grafted polymer of claim 5 , wherein the fluoroelastomer (FE) has a fluorine content of at least about 65 percent.9. The oleophobic grafted polymer of claim 5 , wherein the fluoroelastomer (FE) has a molecular weight in a range from about 50 claim 5 ,000 to about 70 claim 5 ,0000 daltons as measured by gel permeation chromatography.10. The oleophobic grafted polymer of claim 5 , wherein the perfluorinated polyether (PFPE) is an alkoxysilane-terminated perfluorinated polyether having an average molecular weight in a range from about 1 claim 5 ,500 ...

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Номер записи: 72
27-01-2022 дата публикации

FLUORO-THERMOPLASTIC ELASTOMER BLENDS

Номер: US20220025166A1
Автор: "OBrien Gregory S.", CAPELOT Mathieu Y., Hauser Adam W., Mehlmann Florence
Принадлежит:

Disclosed is a thermoplastic elastomer composition comprising a blend of at least two fluoropolymers. The first fluoropolymer has from 0 to 30 weight percent of a monomer J selected from the group consisting of hexafluoropropene (HFP), fluorinated or perfluorinated vinyl ethers, 2,3,3,3-tetrafluoropropene, trifluoropropene, 1-chloro-3,3,3-trifluoro propene or combinations thereof. The second fluoropolymer has at least 30 weight percent, preferably at least 35 weight percent, of monomer T selected from the group consisting of hexafluoropropene (HFP), fluorinated or perfluorinated vinyl ethers, 2,3,3,3-tetrafluoropropene, trifluoropropene, 1-chloro-3,3,3-trifluoro propene or combinations thereof. 1. A fluoropolymer composition comprising a fluoropolymer blend comprising fluoropolymer S and fluoropolymer H wherein:H comprises from 0 to 30 weight percent, of a monomer J selected from the group consisting of hexafluoropropene (HFP), fluorinated or perfluorinated vinyl ethers, 2,3,3,3-tetrafluoropropene, trifluoropropene, 1-chloro-3,3,3-trifluoro propene or combinations thereof;S comprises at least 35 weight percent, of monomer T selected from the group consisting of hexafluoropropene (HFP), fluorinated or perfluorinated vinyl ethers, 2,3,3,3-tetrafluoropropene, trifluoropropene, 1-chloro-3,3,3-trifluoro propene or combinations thereof, andwherein, the amount of H is from 20 to 80 weight % of the composition, and the amount of S is from 80 to 20 weight % of the composition.2. A fluoropolymer composition comprising a fluoropolymer blend comprising fluoropolymer S and fluoropolymer H wherein:H comprises from 0 to 30 weight percent, of a monomer J selected from the group consisting of hexafluoropropene (HFP), fluorinated or perfluorinated vinyl ethers, 2,3,3,3-tetrafluoropropene, trifluoropropene, 1-chloro-3,3,3-trifluoro propene or combinations thereof;S comprises at least 30 weight percent, of monomer T selected from the group consisting of hexafluoropropene (HFP), ...

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Номер записи: 73
08-01-2015 дата публикации

Live poly(n-vinyl lactam) reactive stabilizers for dispersed phase polymerization

Номер: US20150011657A1
Автор: Destarac Mathias, Wilson James
Принадлежит:

The present invention concerns a method for preparing a polymer comprising a step (EI) for dispersed phase polymerization in the presence of a reactive stabiliser, wherein the following are brought into contact in an aqueous phase:—at least one ethylenically unsaturated monomer;—at least one source of free radicals; and—a reactive stabiliser comprising a polymer chain including monomer units (N-vinyl lactam) and a thiocarbonylthio-S group (C═S)—. 1. A process for preparing a polymer , comprising a step (E1) of dispersed-phase polymerization in the presence of a reactive stabilizer , wherein the following are placed in contact in an aqueous phase:at least one ethylenically unsaturated monomer;at least one source of free radicals; anda reactive stabilizer comprising a polymer chain including N-(vinyllactam) monomer units and a thiocarbonylthio group —S(C═S)—.2. The process as claimed in claim 1 , wherein in said step (E1) claim 1 , the ethylenically unsaturated monomer is in dispersed form.3. The process as claimed in claim 1 , wherein said step (E1) is performed at a temperature below 40° C.4. (currently amended 1) The process as claimed in claim 3 , wherein the source of free radicals used in said step (E1) is a redox polymerization initiator.5. The process as claimed in claim 4 , wherein the redox initiator comprises tert-butyl hydroperoxide (t-BuOOH) as oxidizing agent claim 4 , combined with a reducing agent selected from the group consisting of ascorbic acid and sodium sulfite.7. The process as claimed in claim 6 , wherein the reactive stabilizer used in said step (E1) claim 6 , is monomers N-vinylpyrrolidone claim 6 , N-vinylpiperidone or N-vinylcaprolactam.8. The process as claimed in claim 1 , wherein the thiocarbonylthio group present on the reactive stabilizer is a xanthate or a dithiocarbamate.9. The process as claimed in claim 1 , wherein the monomers used in said step (E1) are vinyl ester monomers of formula CH2═CH—O—(C═O)—R claim 1 , wherein Rrepresents ...

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Номер записи: 74
14-01-2021 дата публикации

Solvent Cement Formulations

Номер: US20210009866A1
Автор: Parhar Amrit, Perez Willie
Принадлежит:

Provided are solvent cement formulations comprising some or all of tetrahydrofuran, cyclohexanone, methyl ethyl ketone, acetone, a thermoplastic resin, silica, and, a solvent soluble acrylic copolymer associative thickener. The disclosed formulations contain a reduced complement of volatile organic compounds (VOCs) relative to conventional cement formulations, yet are capable of meeting the requirements for regular-, medium-, and heavy-duty applications. The use of specialized associative thickener components confers a required degree of viscosity while enabling a reduction in the concentration of VOCs, such as tetrahydrofuran. 1. A solvent cement formulation comprising:20-31% tetrahydrofuran;21-29% cyclohexanone;0-14% methyl ethyl ketone;21-35% acetone;10-17% polyvinyl chloride;1-4% silica; and,0.01-0.05% of a solvent soluble acrylic copolymer associative thickener,wherein the percent value of all named components do not exceed 100.2. The solvent cement formulation according to comprising:23-31% tetrahydrofuran;21-29% cyclohexanone;0-5% methyl ethyl ketone;27-35% acetone;11-17% polyvinyl chloride;1-4% silica; and,0.01-0.05% of said thickener.3. The solvent cement formulation according to comprising:25-29% tetrahydrofuran;23-27% cyclohexanone;0-2% methyl ethyl ketone;29-34% acetone;12-16% polyvinyl chloride;2-3% silica; and,0.02-0.04% of said thickener.4. The solvent cement formulation according to comprising:about 27% tetrahydrofuran;about 25% cyclohexanone;about 31.5% acetone;about 14% polyvinyl chloride;about 2.5% silica; and,about 0.03% of said thickener,the formulation containing no methyl ethyl ketone.5. The solvent cement formulation according to having an initial viscosity of at least 2500 cP.6. The solvent cement formulation according to having an initial viscosity of about 2500 cP to about 5000 cP.7. The solvent cement formulation according to having a next day viscosity at 140° F. of at least 3000 cP.8. The solvent cement formulation according to having a ...

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Номер записи: 75
10-01-2019 дата публикации

FLOOR COVERING WITH UNIVERSAL BACKING AND METHODS OF MAKING AND RECYCLING

Номер: US20190010646A1
Автор: Higgins Kenneth B.
Принадлежит:

A dimensionally stable universal floor covering includes a tufted textile having stitches and a reinforcement layer of fibers and adhesive providing dimensional stability for the entire floor covering. The fibers and adhesive are mixed and then moved by an applicator towards the stitches. A slip path is formed to improve the movement of the fibers and adhesive. A releasable adhesive or gecko-like cover system is provided which also provides additional strength and stability and a releasable attachment of the universal floor covering to a supporting surface. 1. A method of manufacturing a universal floor covering which can be used as either a broadloom or modular floor covering , the method comprising the steps of:manufacturing either a broadloom or modular floor covering from a group of components including a tufted textile substrate having a primary backing substrate extending in a first direction and a plurality of yarns tufted through the primary backing substrate, the primary backing substrate having a face side and a back side opposite the face side, a portion of each yarn forming a stitch portion having an end that is located on the back side of the primary backing substrate, and spaces existing between the stitch portions;said group of components further including a composition pool having adhesive and reinforcement fibers;moving the tufted textile substrate relative to an applicator having an engagement surface, and providing space between the stitch portions of the yarns and the applicator;mixing the adhesive and reinforcement fibers for separating fibers and for moving fibers and adhesive against the engagement surface of the applicator;forming a slip path on the engagement surface of the applicator for separating the fibers and adhesive from frictional engagement with the applicator;applying controlled pressure with the applicator in a second direction towards the primary backing substrate and forming a relatively rigid reinforcement layer of fibers and ...

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Номер записи: 76
19-01-2017 дата публикации

METHOD FOR CURING AN ADHESIVE USING MICROWAVE IRRADIATION

Номер: US20170015871A1
Автор: Kalb Roland, Wutti Robert
Принадлежит:

A method for curing a polymer adhesive composition using microwaves, characterized in that the adhesive composition contains an ionic liquid [A][B], wherein [A] represents a cation, [B]represents an anion, and a represents an integer. 1. A method for curing a polymer adhesive composition comprising:curing the polymer adhesive composition using microwaves, and wherein the{'sup': +', 'a−, 'sub': 'a', 'adhesive composition contains an ionic liquid [A][B],'}{'sup': '+', 'where [A] represents a cation,'}{'sup': 'a−', '[B] represents an anion and'}“a” represents an integer.4. A method according to claim 1 , wherein [B] is selected from:{'sub': 2', '3, 'sup': '−', 'fluoride, chloride, bromide, iodide, dicyanamide, thiocyanate; perchlorate, hexafluorophosphate, nitrite, nitrate, sulphate, hydrogen sulphate, carbonate, hydrogen carbonate, alkyl carbonate, methyl carbonate, aryl carbonate; phosphate; hydrogen phosphate; dihydrogen phosphate; sulfamate HN—SO, deprotonated acesulfame (6-methyl-2,2-dioxo-oxathiazine-4-olate), deprotonated saccharine (1,1-dioxo-3-one-1,2-benzothiazolate), cyclamate (deprotonated cyclohexane sulfamic acid),'}{'sup': i', 'j', 'k', 'l', '−', 'i', '1, 'sub': 1', '30', '3', '12', '2', '30', '3', '12, 'a tetra-substituted borate of the general formula (Va) [BRRRR], wherein Rto Rindependently of each other represent fluoro or (C-C)alkyl, (C-C)cycloalkyl, (C-C)alkenyl, (C-C)cycloalkenyl, aryl or saturated or unsaturated heterocyclyl, in particular heteroaryl, wherein the 6 residues last mentioned independently of each other are unsubstituted or substituted by'}one or several halogen and/or{'sub': 1', '30', '3', '7, 'sup': c', 'c', 'c', 'd', 'c', 'c', 'c', 'd, '1 to 3 residues selected from the group consisting of (C-C)alkyl, aryl, saturated or unsaturated heterocyclyl, in particular heteroaryl, (C-C)cycloalkyl, halogen, Or, SR, NRR, COR, COOR, CO—NRR, acrylate, methacrylate, cyanoacrylate, epoxide, vinyl, vinyl ether, vinyl ester, styrene, allyl, phenol, ...

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Номер записи: 77
21-01-2016 дата публикации

Gold Nanoparticle Conjugates and Uses Thereof

Номер: US20160017065A1
Автор: Boyes Stephen G., Hotchkiss Jay, Rowe Misty D.
Принадлежит:

The disclosure generally relates to formation of polymers grafted to or polymerized from the surface of gold nanoparticles. The polymers are functionalized to include therapeutic agents and/or targeting agents at their surface, thereby allowing both therapeutic and targeting compounds to be directed to specific cells in a patient.

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Номер записи: 78
21-01-2016 дата публикации

POLYVINYLIDENE FLUORIDE COMPOSITION

Номер: US20160017136A1
Автор: Amin-Sanayei Ramin, HOCHSTETTER Gilles, HUGON Lionel, LABOUR Thomas, LANNUZEL Thierry, Ramfel Barbara
Принадлежит: Arkema France

The invention relates to a composition comprising: a homopolymer of vinylidene fluoride (VDF) and at least one other fluorinated monomer copolymerizable with VDF, the weight proportion of said copolymer in the composition being between 10 to 35%; and a plasticisizer, the weight proportion of said plasticizer in the composition being between 1 to 5%. The invention also relates to a method for producing said composition and the use thereof for producing various items.

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Номер записи: 79
18-01-2018 дата публикации

ADHESIVE COMPOUND WITH REDUCED YELLOWNESS INDEX

Номер: US20180016476A1
Автор: KEITE-TELGENBÜSCHER Klaus, REICHENBACH Anita, Schuh Christian
Принадлежит: TESA SE

Adhesive compounds and methods contain at least one reactive resin, at least one elastomer, at least one polar photoinitiator and, optionally, a non-aqueous solvent. The adhesive compounds and method further containing a non-ionic surfactant for reducing the yellowness index of the cured adhesive compound, having a reduced yellowing tendency after the crosslinking step. The adhesive compound may be preferably a pressure-sensitive adhesive compound and the elastomer may be preferably a non-polar elastomer. 1. An adhesive composition comprising at least one reactive resin', 'at least one elastomer', 'at least one polar photoinitiator, and, 'an adhesive base composed of'}optionally, a nonaqueous solvent,whereinthe adhesive composition further comprises a nonionic surfactant for reducing the yellowness index of the cured adhesive composition.2. The adhesive composition according to claim 1 , wherein the adhesive composition is pressure-sensitively adhesive.3. The adhesive composition according to claim 1 , wherein the elastomer is apolar.4. The adhesive composition according to claim 1 , wherein the reactive resin is a cyclic ether selected from epoxides and oxetanes.5. The adhesive composition according to claim 1 , wherein the adhesive composition further comprises at least one at least partially hydrogenated tackifier resin.6. The adhesive composition according to claim 1 , wherein the adhesive composition it is subjected to thermal or radiation-induced curing.7. The adhesive composition according to claim 1 , wherein the fraction of nonionic surfactant claim 1 , based on the amount of reactive resin claim 1 , is 1 to 50%.8. The adhesive composition according to claim 1 , wherein the adhesive base has a water vapor permeation rate claim 1 , after the activation of the reactive resin component claim 1 , of less than 100 g/md.9. The adhesive composition according to claim 1 , wherein the adhesive composition is soluble in nonaqueous solvents.10. An adhesive tape ...

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Номер записи: 80
17-01-2019 дата публикации

PLASTICIZING COMPOSITION

Номер: US20190016873A1
Автор: Martinz Daniel, Rhers Bouchra
Принадлежит: Rhodia Operations

The invention relates to a plasticizing composition comprising a vinyl chloride resin and a plasticizing agent which comprises at least one diester having the general formula (I), derived from a diacid selected from succinic acid, glutaric acid, adipic acid, ethylsuccinic acid, methylglutaric acid and mixtures thereof wherein: A is a Cto Clinear or branched aliphatic chain, and R is an alkyl, a cycloalkyl or an aryl. The plasticizing agent according to the present invention has a good performance for different types of formulations (foam, film and paste). Said plasticizer gels rapidly, has a very low viscosity, and ages very well. Efficient debubblizing is one of the key properties thereof. The foams prepared with said plasticizer have very low densities, a high expansion rate, and excellent qualities. 111.-. (canceled)12. A plastisol comprising:a vinyl chloride resin; and {'br': None, 'RO—OC-A-CO—OR\u2003\u2003(I)'}, 'a plasticizing agent which comprises at least one diester of general formula (I)derived from a diacid selected from succinic acid, glutaric acid, adipic acid, ethylsuccinic acid, methylglutaric acid and mixtures thereof, [{'sub': 4', '6, 'A is linear or branched Cto Caliphatic, and'}, 'R is alkyl, cycloalkyl or aryl,, 'in whichwherein the plastisol is in the form of a paste, film, or foam.13. The plastisol of claim 12 , wherein R is a substituted or unsubstituted cycloalkyl of 5 to 6 carbon atoms selected from cyclopentyl or cyclohexyl or an aryl chosen from benzyl claim 12 , phenyl claim 12 , and their isomers.14. The plastisol of claim 12 , wherein R is a branched or unbranched alkyl having from 4 to 10 carbon atoms selected from n-butyl claim 12 , t-butyl claim 12 , n-pentyl claim 12 , n-hexyl claim 12 , n-heptyl claim 12 , n-octyl claim 12 , ethylhexyl claim 12 , isooctyl claim 12 , n-nonyl claim 12 , isononyl claim 12 , n-decyl or isodecyl.15. The plastisol of claim 12 , wherein the plasticizing agent is a mixture of:from 70% to 95% by weight of ...

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Номер записи: 81
16-01-2020 дата публикации

POLYETHYLENE COMPOSITION AND FILM HAVING OUTSTANDING PROPERTIES

Номер: US20200017666A1
Автор: Aubee Norman, Molloy Brian, VanAsseldonk Lawrence, Wang Qinyan, Wang XiaoChuan, Zoricak Peter
Принадлежит: NOVA CHEMICALS (INTERNATIONAL) S.A.

A polyethylene composition comprises a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M/Mof <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 50,000 to 200,000 and a molecular weight distribution M/Mof <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 200,000 and a molecular weight distribution M/Mof <2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a composition distribution breadth index, CDBIobtained from a crystallization elution fractionation (CEF) analysis of <45 weight %. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ≥200 MPa (at a film thickness of about 1 mil), a seal initiation temperature (SIT) of ≤85° C. (at a film thickness of about 2 mil), an area of hot tack window (AHTW) of ≥220 Newtons·C° (at a film thickness of about 2 mil), an oxygen transmission rate (OTR) of ≥600 cmper 100 inch(at a film thickness of about 1 mil), a dart impact strength of ≥400 g/mil, and a machine direction (MD) tear strength of ≥400 g/mil. 1. A polyethylene composition comprising:{'sub': w', 'w', 'n, 'from 15 to 80 wt % of a first polyethylene which is an ethylene copolymer, the first polyethylene having a weight average molecular weight Mof from 70,000 to 250,000, a molecular weight distribution M/Mof <2.3 and from 5 to 100 short chain branches per thousand carbon atoms;'}{'sub': w', 'w', 'n, 'from 5 to 50 wt % of a second polyethylene which is an ethylene copolymer or an ethylene homopolymer, the second polyethylene having a weight average molecular weight, Mof from 50,000 to 200,000, a molecular weight distribution M/Mof <2.3 and from 0 to 15 short chain branches ...

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Номер записи: 82
21-01-2021 дата публикации

POLYPROPYLENE COMPOSITION AND MOLDED ARTICLE

Номер: US20210017367A1
Автор: KANNO SHITOSHI, NAKAJIMA Takeshi, Tsukahara Takeshi, TSURUMI NOBUYUKI, YAMAMOTO KUNIO
Принадлежит: BASELL POLIOLEFINE ITALIA S.R.L.

A polypropylene composition made from or containing: 2. The polypropylene composition according to claim 1 , wherein the ethylene-derived unit in component (1) is present at a concentration of 1.8 to 4% by weight claim 1 , based upon the total weight of the propylene/ethylene copolymer.3. The polypropylene composition according to claim 1 , wherein the viscosity ratio is in the range of 0.45 to 0.75.4. The polypropylene composition according to claim 1 , wherein components (1) and (2) are copolymers obtained by polymerizing propylene and ethylene using a catalyst comprising:(a) a solid catalyst comprising magnesium, titanium, a halogen, and an electron donor compound selected from succinate-based compounds, and(b) an organoaluminum compound and(c) optionally an external electron donor compound.5. An injection-molded article comprising the polypropylene composition according to . In general, the present disclosure relates to the field of chemistry. More specifically, the present disclosure relates to polymer chemistry. In particular, the present disclosure relates to polypropylene compositions and molded articles thereof.It is believed that polypropylene is useful in food containers because of polypropylene's physical and hygienic properties. In some instances, polypropylene containers have poor in impact resistance at low temperatures. In some instances, polypropylene containers should have sufficient transparency to reveal the contents of the containers as well as stiffness for shape stability. As such, polypropylene should have a good balance between transparency, impact resistance at low temperatures, and stiffness.[1] In general embodiments, the present disclosure provides a polypropylene composition made from or containing:(i) component (1) made from or containing a propylene/ethylene copolymer containing more than 1.5% by weight and not more than 4% by weight of an ethylene-derived unit, based upon the total weight of the propylene/ethylene copolymer;(ii) ...

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Номер записи: 83
22-01-2015 дата публикации

PREPARATION METHOD OF GRANULAR OXIDE ADSORBENT, AND WATER TREATMENT METHOD USING SAME

Номер: US20150021267A1
Автор: Choo Kwang-Ho
Принадлежит:

The present invention relates to a preparation method of a granular oxide adsorbent for water treatment in which a metal oxide is bound to the surface of polymer particles, and more specially, to a preparation method of a granular oxide adsorbent, comprising the following steps: putting polymer particles in an acidic solution; adding polymer particles to a metal oxide aqueous solution and adjusting a pH; and washing and drying the obtained product. Accordingly, a granular oxide adsorbent prepared by the preparation method is provided and is utilized in water treatment and the like. 1. A method for preparing a granular oxide adsorbent comprising the steps of:placing polymer particles in an acidic solution;washing the polymer particles;adding the polymer particles to an aqueous metal oxide solution, adjusting the pH to pH 5 to pH 10 while agitating the solution; andwashing and drying the polymer particles.2. The method for preparing a granular oxide adsorbent of claim 1 , wherein a polymer of the polymer particles has a sulfonate group.3. The method for preparing a granular oxide adsorbent of claim 2 , wherein the polymer of the polymer particles is sulfonated polystyrene.4. The method for preparing a granular oxide adsorbent of claim 1 , wherein the acidic solution is one or more types selected from the group consisting of hydrochloric acid claim 1 , nitric acid and sulfuric acid.5. The method for preparing a granular oxide adsorbent of claim 4 , wherein a pH of the acidic solution ranges from pH 1 to pH 3.6. The method for preparing a granular oxide adsorbent of claim 1 , wherein the metal oxide is one or more types selected from the group consisting of iron oxide claim 1 , aluminum oxide and titanium oxide.7. The method for preparing a granular oxide adsorbent of claim 6 , wherein the iron oxide is one or more types selected from the group consisting of ferrihydrite claim 6 , magnetite claim 6 , hematite and goethite.8. A granular oxide adsorbent prepared using the ...

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Номер записи: 84
26-01-2017 дата публикации

CONVENIENT FLOOR TILE

Номер: US20170021598A1
Автор: Chen Ben-Yuan
Принадлежит:

A convenient floor tile comprises a convenient tiling layer, a base layer and a surface layer which are superimposed in sequence from bottom to top. A composition of the base layer includes PVC, a plasticizer, a stabilizer and an anti-precipitation agent. The anti-precipitation agent is made from CPE, PEG and an absorbent. The composition and material are calculated in parts by weight: 100 parts of PVC, 30-50 parts of the plasticizer, 0.5-2 parts of the stabilizer, 0.5-5 parts of CPE, 0.5-5 parts of PEG and 0.5-15 parts of the absorbent. 1. A convenient floor tile comprising a convenient tiling layer , a base layer and a surface layer which are superimposed in sequence from bottom to top; wherein a composition of said base layer includes PVC , a plasticizer , a stabilizer and an anti-precipitation agent , a material of said anti-precipitation agent being made from CPE , PEG and an absorbent , said composition and said material being calculated in parts by weight: 100 parts of said PVC , 30-50 parts of said plasticizer , 0.5-2 parts of said stabilizer , 0.5-5 parts of said CPE , 0.5-5 parts of said PEG and 0.5-15 parts of said absorbent.2. The convenient floor tile as claimed in claim 1 , wherein said plasticizer is at least one of DINP and DOTP.3. The convenient floor tile as claimed in claim 1 , wherein said stabilizer is at least one of calcium stearate and zinc stearate.4. The convenient floor tile as claimed in claim 1 , wherein a grain size of said absorbent is 50 nm to 500 nm.5. The convenient floor tile as claimed in claim 1 , wherein said absorbent is at least one of carbonate claim 1 , a layered silicate and an oxide.6. The convenient floor tile as claimed in claim 5 , wherein said carbonate is calcium carbonate claim 5 , said layered silicate is an organic montmorillonite claim 5 , and said oxide is silicon dioxide.7. The convenient floor tile as claimed in claim 1 , wherein said convenient tiling layer is a hot melt adhesive. (a) Technical Field of the ...

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Номер записи: 85
17-04-2014 дата публикации

ADHESIVE COMPOSITION

Номер: US20140107263A1
Автор: FUKUDA Kenichi, SHIONO Mikio
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

An adhesive composition is provided comprising (A) a linear polyfluoro compound having at least two alkenyl groups and a perfluoropolyether structure in its main chain, (B) a fluorinated organohydrogensiloxane having at least two SiH groups, (C) a hydrosilylation catalyst, (D) hydrophobic silica powder, (E) a fluorinated acetylene alcohol, and (F) an organosiloxane containing a SiH group and an epoxy and/or trialkoxysilyl group. A cured product of the composition has a smooth and uniform surface. 1. An adhesive composition comprising(A) 100 parts by weight of a linear polyfluoro compound having at least two alkenyl groups per molecule and a perfluoropolyether structure in its main chain,(B) a fluorinated organohydrogensiloxane having at least two silicon-bonded hydrogen atoms (i.e., SiH groups) per molecule, in an amount to provide 0.5 to 3.0 moles of SiH groups per mole of alkenyl groups on component (A),(C) a platinum group metal-based hydrosilylation catalyst in an amount to provide 0.1 to 500 ppm of platinum group metal,(D) 0.5 to 30 parts by weight of hydrophobic silica powder,(E) 0.05 to 3.0 parts by weight of a fluorinated acetylene alcohol, and(F) 0.1 to 10 parts by weight of an organosiloxane containing at least one silicon-bonded hydrogen atom and at least one epoxy and/or trialkoxysilyl group bonded to a silicon atom via a carbon atom or via carbon and oxygen atoms per molecule.3. The adhesive composition of claim 1 , wherein the fluorinated organohydrogensiloxane (B) contains at least one monovalent perfluoroalkyl claim 1 , monovalent perfluorooxyalkyl claim 1 , divalent perfluoroalkylene or divalent perfluorooxyalkylene group per molecule claim 1 ,5. The adhesive composition of claim 1 , wherein the organosiloxane (F) has at least one monovalent perfluoroalkyl or monovalent perfluorooxyalkyl group which is bonded to a silicon atom through a divalent linking group containing a carbon atom or carbon and oxygen atoms. This non-provisional application ...

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Номер записи: 86
17-04-2014 дата публикации

Fluoroelastomer Compositions Having Self-Bonding Characteristics and Methods of Making Same

Номер: US20140107280A1
Автор: Eberhard Joan, Gurevich Eugene, Luo Jiazhong
Принадлежит: Greene, Tweed of Delaware, Inc.

Self-bonding curable fluoroelastomer compositions are provided wherein the compositions including a) a fluoropolymer composition having at least one curable fluoropolymer; and b) a compound selected from the group consisting of aluminum acrylates, silicon acrylates, and ammonia acrylates, wherein the self-bonding curable fluoroelastomer composition is able to bond directly to a substrate. Bonded structures formed of such self-bonding compositions and a substrate having a surface bonded thereto are also described herein along with a method for bonding a self-bonding curable fluoroelastomer composition to a substrate surface. The fluoroelastomers herein may encompass both non-fully fluorinated (FKM) and fully fluorinated (FFKM) elastomers. 1. A self-bonding curable fluoroelastomer composition , comprisinga fluoropolymer composition having at least one curable fluoropolymer; andb) a compound selected from the group consisting of aluminum acrylates, silicon acrylates, ammonia acrylates, and combinations thereat wherein the self-bonding curable fluoroelastomer composition is able to bond directly to a substrate.2. The self-bonding curable fluoroelastomer composition according to claim 1 , wherein the curable fluoropolymer has at least two monomers and at least one curesite monomer claim 1 , wherein the at least two monomers comprise tetrafluoroethylene and vinylidene fluoride.3. The self-bonding curable fluoroelastomer composition according to claim 2 , wherein the fluoroelastomer composition comprises at least one curing agent.4. The self-bonding curable fluoroelastomer composition according to claim 3 , further comprising at least one of a curing agent claim 3 , co-curing agent claim 3 , and a cure accelerator.5. The self-bonding curable fluoroelastomer composition according to claim 1 , comprising at least two curable fluoropolymers.6. The self-bonding curable fluoroelastomer composition according to claim 5 , wherein the at least two curable fluoropolymers are in a ...

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Номер записи: 87
17-04-2014 дата публикации

Flame Retarding Adhesives

Номер: US20140107282A1
Автор: Aloshyna ep Lesuffleur Marie, Bharti Vivek, Clapper Jason D., Harrison Peter J., Jing Naiyong, Plepys Anthony R., Pyun Eumi, Ross Richard B., Sharma Neeraj, Tran Thu-Van T.
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

Pressure sensitive adhesives having flame retarding properties include a (meth)acrylate-based block copolymer, and at least 10% by weight of a halogen-free flame retarding agent. The adhesives may contain additional optional additives such as tackifying resins, plasticizers, and the like. The adhesives are prepared by blending the (meth)acrylate-based block copolymer, and the halogen-free flame retarding agent either in solvent or by a solventless process. 1. An adhesive comprising:a (meth)acrylate-based block copolymer; andat least 10% by weight of a halogen-free flame retarding agent, wherein the adhesive is a flame retardant pressure sensitive adhesive.2. The adhesive of claim 1 , wherein the pressure sensitive adhesive is optically clear.3. The adhesive of claim 1 , further comprising at least one additional additive.4. The adhesive of claim 3 , wherein the at least one additive comprises a tackifying resin claim 3 , an anti-oxidant claim 3 , an inorganic filler claim 3 , a UV stabilizer claim 3 , a plasticizer claim 3 , a softening agent claim 3 , or combination thereof.5. The adhesive of claim 1 , wherein the (meth)acrylate-based block copolymer comprises a (meth)acrylate di-block claim 1 , tri-block claim 1 , or star block copolymer.6. The adhesive of claim 1 , wherein the (meth)acrylate-based block copolymer comprises a tri-block copolymer comprising:at least two A endblock polymeric units that are each derived from a first monoethylenically unsaturated monomer comprising a (meth)acrylate, wherein each Aendblock has a glass transition temperature of at least 50° C.; andat least one B midblock polymeric unit that is derived from a second monoethylenically unsaturated monomer comprising a (meth)acrylate or vinyl ester, wherein each B midblock has a glass transition temperature no greater than 20° C.; and wherein at least one of the first monoethylenically unsaturated monomer or the second monoethylenically unsaturated monomer comprises a (meth)acrylate monomer ...

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Номер записи: 88
10-02-2022 дата публикации

COMPOSITES HAVING A THERMOPLASTIC MATRIX

Номер: US20220041849A1
Автор: Beyer Horst, Franosch Jürgen, Ries Hans, Szentivanyi Andreas
Принадлежит: EVONIK OPERATIONS GMBH

The present invention is directed to continuous fiber-reinforced composites having a matrix of modified PVDF. The composite may be a semifinished product or a product or finished part manufactured therefrom. A product according to the invention is pelletized long-fiber material, while a finished part according to the invention is especially a thermoplastic composite pipe. 1. A composite composed of a polymer matrix and continuous fibers embedded therein , where the polymer matrix consists to an extent of at least 80% by weight of a mixture comprising the following components:a) low-viscosity PVDF as the main component, i.e. to an extent of at least 50 parts by weight, and 'where the sum total of the parts by weight of a) and b) is 100, and', 'b) from 1 to 50 parts by weight of an acrylate copolymer, where the acrylate copolymer contains from 1% to 30% by weight of units having carboxylic anhydride units,'}where the proportion by volume of the continuous fibers in the composite is also from 10% to 80% by weight,where the percentages of the polymer matrix and of the continuous fibers are each based on the total mass or total volume of the composite.2. The composite according to claim 1 , wherein the PVDF is a homopolymer or a copolymer.4. The composite according to claim 1 , wherein it is a unidirectionally continuous fiber-reinforced tape.5. The elongate long-fiber-reinforced pellets having a length of from 4 to 60 mm claim 1 , produced by cutting a composite in strand form according to .6. A thermoplastic composite pipe (TCP) comprising the following components from the inside outward:I. a tubular liner having one or more layers, the outer surface of which consists of a polyamide molding compound or PVDF molding compound; a) from 50 to 99 parts by weight of PVDF and', 'where the sum total of the parts by weight of a) and b) is 100 and where the proportion by volume of the continuous fibers in the composite is from 10% to 80% by weight,', 'b) from 1 to 50 parts by ...

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Номер записи: 89
23-01-2020 дата публикации

POLYMER COMPOSITIONS FOR UV CURABLE PRIMERS

Номер: US20200024486A1
Автор: Chen Yong Chun, Feng Shaoguang, Wan Qichun, Yu Haiyang
Принадлежит:

Polymer compositions for UV curable primer formulations, as described herein. The primer formulations contain a modifier selected from the following: at least one modifier selected from a) through d) below: a) R1R2C═CR3-(CO)—Z (Formula A), as described herein, b) an acrylate-containing oligomer that has a Mn≤1500 g/mol, and an acid value from 50 to 500 mg KOH/g; c) a random terpolymer comprising, in polymerized form, vinyl chloride, vinyl acetate, and at least one of the following: a hydroxyl-containing alkyl acrylate, a hydroxyl-containing alkyl meth-acrylate, or a combination thereof or d) any combination of a) through c). Such primer formulations are useful for the binding of olefin-based polymer foams. 2. The composition of claim 1 , wherein the composition further comprises at least one photoinitiator.3. The composition of claim 1 , wherein the weight ratio of component A to the sum weight of components B claim 1 , C and D claim 1 , A/(B+C+D) claim 1 , is from 0.10 to 0.75.4. The composition of claim 1 , wherein the component A is present in an amount from 5 to 35 wt % claim 1 , based on the weight of the composition.5. The composition of claim 1 , wherein the component A is a random terpolymer (subcomponent c) that comprises the following properties: i) Mw from 10 claim 1 ,000 to 100 claim 1 ,000 g/mole; ii) from 70 to 95 wt % vinyl chloride claim 1 , based on the weight of the terpolymer claim 1 , iii) from 5 to 15 wt % vinyl acetate claim 1 , based on the weight of the terpolymer; and iv) from greater than zero to 15 wt % claim 1 , based on the weight of the terpolymer claim 1 , of a hydroxyl-containing alkyl acrylate claim 1 , where alkyl group comprises 1 to 6 carbons claim 1 , or a hydroxyl-containing alkyl methacrylate where the alkyl group comprises 1 to 6 carbons.7. The composition according to claim 1 , wherein component D) is selected from the group consisting of the following: 1 claim 1 ,6 Hexanediol diacrylate (HDDA) claim 1 , tri propylene glycol ...

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Номер записи: 90
17-02-2022 дата публикации

RAISED TEMPERATURE RESISTANT PIPES COMPRISING AN ETHYLENE-BASED POLYMER

Номер: US20220049797A1
Автор: AL-SAIF Nasser Abdullah, Banat Yahya, MOKDAD Abdelhamid
Принадлежит:

The present invention relates to a pipe comprising an ethylene-based polymer, wherein the ethylene-based polymer: ⋅ comprises ≥0.10 mol % of units derived from 1-hexene, with regard to the total molar quantity of polymeric units of the ethylene-based polymer; ⋅ has an M/Mas determined in accordance with ASTM D6474 (2012) of ≥2.5 and ≤4.0, preferably of ≥2.5 and ≤3.4; ⋅ has a density as determined in accordance with ASTM D792 (2008) of ≥925 and ≤945 kg/m; and ⋅ in the molecular weight range of log(M) between 4.0 and 5.5, has a comonomer branch content of between 2 and 15 comonomer-derived branches per 1000 carbon atoms in the polymer, as determined via C NMR. Such pipe provides a desirably high long-term strength, as demonstrated by its high strain hardening modulus, as well as desirably high impact strength, as demonstrated by its high Charpy impact strength. Further, such pipe may be compliant with the PE-RT requirements of ISO 22391-1 (2009). For example, such pipe may be used for containing water at temperatures in the range of 40° C. to 80°. 1. Pipe comprising an ethylene-based polymer , wherein the ethylene-based polymer:comprises ≥0.10 mol %, of units derived from 1-hexene, with regard to the total molar quantity of polymeric units of the ethylene-based polymer;{'sub': ['w', 'N'], '#text': 'has a molecular weight distribution M/Mas determined in accordance with ASTM D6474 (2012) of ≥2.5 and ≤4.0;'}{'sup': '3', '#text': 'has a density as determined in accordance with ASTM D792 (2008) of ≥925 and ≤945 kg/m; and'}{'sub': 'w', 'sup': '13', '#text': 'in the molecular weight range of log(M) between 4.0 and 5.5 has a comonomer branch content of between 2 and 15 comonomer-derived branches per 1000 carbon atoms in the polymer, as determined via C NMR.'}2. Pipe according to claim 1 , wherein the ethylene-based polymer has a comonomer incorporation ratio of ≥1.50 claim 1 , wherein the comonomer incorporation ratio is defined as the ratio between the quantity of comonomer ...

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Номер записи: 91
04-02-2021 дата публикации

RESIN FILM AND ORGANIC ELECTROLUMINESCENT DEVICE

Номер: US20210032490A1
Автор: Inoue Hiroyasu
Принадлежит: ZEON CORPORATION

Provided is a resin film including: a resin containing a polymer; a hygroscopic particle dispersed in the resin and having a primary particle diameter of 40 nm or more and 80 nm or less and a refractive index of 1.2 or more and 3.0 or less; and an organic solvent-soluble dispersant. Preferably the resin is a silicon-containing resin. Preferably the silicon-containing resin is a silicon-containing thermoplastic resin. Preferably the silicon-containing thermoplastic elastomer contains a graft polymer having a silicon-containing group as the polymer. An organic electroluminescent device including the resin film is also provided. 1. A resin film comprising: a resin containing a polymer; a hygroscopic particle dispersed in the resin and having a primary particle diameter of 40 nm or more and 80 nm or less and a refractive index of 1.2 or more and 3.0 or less; and an organic solvent-soluble dispersant.2. The resin film according to claim 1 , wherein the resin is a silicon-containing resin.3. The resin film according to claim 2 , wherein the silicon-containing resin is a silicon-containing thermoplastic resin.4. The resin film according to claim 3 , wherein the silicon-containing thermoplastic resin is a silicon-containing thermoplastic elastomer.5. The resin film according to claim 4 , wherein the silicon-containing thermoplastic elastomer contains a graft polymer having a silicon-containing group as the polymer.6. The resin film according to claim 5 , wherein the polymer has a structure obtained by graft polymerization of a monomer having a silicon-containing group and a copolymer selected from the group consisting of a styrene-butadiene block copolymer claim 5 , a styrene-butadiene-styrene block copolymer claim 5 , a styrene-isoprene block copolymer claim 5 , a styrene-isoprene-styrene block copolymer claim 5 , a hydrogenated product thereof claim 5 , and a mixture thereof.7. The resin film according to claim 1 , further comprising a plasticizer.8. The resin film ...

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Номер записи: 92
05-02-2015 дата публикации

TELECHELIC POLYOLEFIN AND PREPARATION THEREOF

Номер: US20150038647A1
Автор: "DAgosto Franck", Boisson Christophe, German Ian
Принадлежит:

Telechelic polyolefin of formula(I) and its derivatives: 1. A telechelic polyolefin of formula (I) and derivatives thereof:{'br': None, 'sub': 2', '2', 'p, 'CH═CH—(CH)-A-Z \u2003\u2003(I)'}wherein:{'b': '95', 'sub': 2', '2, 'A represents a (co)polymer comprising at least mol % of (CH-CH) units;'}Z is selected from the group consisting of halogens; thiols and their derivatives; azides; amines; alcohols; the carboxylic acid function; isocyanates;silanes; phosphorous derivatives; dithioesters; dithiocarbamates; dithiocarbonates;{'sub': 2', 'p', '2, 'trithiocarbonates; alkoxyamines; the vinyl function; dienes; and the group -A-(CH)—CH═CH; and'}p is a whole number between 1 and 20.2. A telechelic polyolefin or derivative thereof according to claim 1 , wherein A is a linear polyethylene of formula (CH—CH) claim 1 , n being a whole number between 7 and 3600.3. A telechelic polyolefin or derivatives thereof according to claim 1 , wherein the telechelic polyolefin is represented by the formula CH═CH—(CH)—(CH—CH)-I claim 1 , I being an iodine atom claim 1 , p being a whole number between 6 and 9 claim 1 , and n being a whole number between 17 and 360.4. A process for preparing the telechelic polyolefin or derivative thereof according to claim 1 , comprising the following steps: {'br': None, 'sub': 2', 'p', '2', 'm, 'Y(A-(CH)—CH═CH)\u2003\u2003(II)'}, 'preparing a compound of formula (II)wherein m is 2 or 3; andwhen m=2, Y is an alkaline earth metal; and{'b': '13', 'when m=3, Y is an element of group ; and'}{'sub': 2', 'p', '2', '2', 'p', '2, 'cleaving the bond between Y and A-(CH)—CH═CH, and functionalizing A-(CH)-CH═CHwith Z.'}5. A process according to claim 4 , wherein the preparing the compound of formula (II) is achieved in the presence of a transition metal or lanthanide complex claim 4 , and a transfer agent of formula (III):{'br': None, 'sub': 2', 'p', '2', 'm, 'Y((CH)—CH═CH)\u2003\u2003(III).'}6. A process according to claim 5 , wherein the transition metal or ...

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Номер записи: 93
09-02-2017 дата публикации

HYDROGENATED BLOCK COPOLYMER HAVING ALKOXYSILYL GROUP AND USE THEREFOR

Номер: US20170037157A1
Автор: Ishiguro Atsushi, KOHARA Teiji, Kurihara Ryuta
Принадлежит: ZEON CORPORATION

Provided are: an alkoxysilyl group-containing hydrogenated block copolymer produced by introducing an alkoxysilyl group into a hydrogenated block copolymer that is obtained by hydrogenating 90% or more of unsaturated bonds of a block copolymer that includes at least two polymer blocks [A] and at least one polymer block [B], the polymer block [A] including a repeating unit derived from an aromatic vinyl compound as a main component, the polymer block [B] including a repeating unit derived from a linear conjugated diene compound as a main component, and a ratio (wA:wB) of a weight fraction wA of the polymer block [A] in the block copolymer to a weight fraction wB of the polymer block [B] in the block copolymer being 20:80 to 60:40; a method for producing the same; a solar cell element encapsulating material; a sheet; a laminated sheet; a multilayer sheet; and a method for encapsulating a solar cell element. The alkoxysilyl group-containing hydrogenated block copolymer exhibits low hygroscopicity, a low water vapor permeability, transparency, weatherability, and flexibility, maintains excellent adhesion to glass even when exposed to a high-temperature/high-humidity environment for a long time, and can encapsulate a solar cell element without applying a special waterproof treatment. 1. A method for producing an alkoxysilyl group-containing hydrogenated block copolymer produced by introducing an alkoxysilyl group into a hydrogenated block copolymer that is obtained by hydrogenating 90% or more of the carbon-carbon unsaturated bonds of the main chain , the side chain , and the aromatic ring of a block copolymer that comprises at least two polymer blocks [A] and at least one polymer block [B] , the polymer block [A] including a repeating unit derived from an aromatic vinyl compound as a main component , the polymer block [B] including a repeating unit derived from a linear conjugated diene compound as a main component , and a ratio (wA:wB) of a weight fraction wA of the ...

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Номер записи: 94
09-02-2017 дата публикации

Golf ball resin composition and golf ball

Номер: US20170037231A1
Автор: Hiroshi TADAOKA, Kazuyoshi Shiga, Masanori Taguchi, Takahiro Shigemitsu
Принадлежит: Dunlop Sports Co Ltd

An object of the present invention is to provide a golf ball resin composition having high resilience and flexibility. The present invention provides a golf ball resin composition, comprising (A) at least one resin component selected from the group consisting of (a-1) a binary copolymer, (a-2) an ionomer resin consisting of a metal ion-neutralized product of a binary copolymer, (a-3) a ternary copolymer, and (a-4) an ionomer resin consisting of a metal ion-neutralized product of a ternary copolymer, (B) a saturated fatty acid, (C) an unsaturated fatty acid, and (D) a carboxyl group modified diene polymer having at least two carboxyl groups and/or an anhydride of the carboxyl groups; and having a neutralization degree of more than 80 mole %, wherein a total amount of (B) the saturated fatty acid, (C) the unsaturated fatty acid and (D) the carboxyl group modified diene polymer ranges from 100 parts by mass to 200 parts by mass with respect to 100 parts by mass of (A) the resin component.

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Номер записи: 95
09-02-2017 дата публикации

FLOOR COVERINGS WITH UNIVERSAL BACKING AND METHODS OF MAKING, INSTALLING, AND RECYCLING

Номер: US20170037554A1
Автор: Higgins Kenneth B.
Принадлежит:

A dimensionally stable floor covering comprises a tufted textile substrate and a reinforcement layer attached to the textile substrate. The reinforcement layer includes an adhesive backing compound and reinforcement fibers surrounded by the adhesive backing. The fibers may form a continuous layer on the back side of the floor covering or may be dispersed within the adhesive backing compound. The adhesive backing compound may be hot water-soluble to facilitate recycling of the floor covering. The floor covering may optionally include additional backing layers (including cushions) and may be used as a broadloom carpet, a carpet tile, or other modular floor covering products. Methods of manufacturing, installing, and recycling the present floor coverings are also provided. 1. A recyclable floor covering having a universal reinforcing backing layer which can be applied to both broadloom and modular floor coverings , the recyclable floor covering comprising:a tufted textile substrate having a primary backing substrate extending in a first direction and a plurality of yarns tufted through the primary backing substrate, the primary backing substrate having a face side and a back side opposite the face side, a portion of each yarn forming a stitch portion having an end that is located on the back side of the primary backing substrate, and an interstitial space existing between the end of each stitch portion;a reinforcement layer of fibers laying predominately in the first direction and the fibers being in substantial alignment with each other for forming a reinforcement layer of the fibers that is substantially parallel to the backing substrate, the ends of the stitch portions engaging the reinforcement layer of fibers for separating the reinforcement layer of fibers from the backing substrate and the engagement of the reinforcement layer of fibers with the stitch portions providing dimensional stability for the entire floor covering, and the reinforcement layer of fibers ...

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Номер записи: 96
12-02-2015 дата публикации

HEAT SEALABLE NYLON FILM AND METHOD OF MAKING IT

Номер: US20150044403A1
Автор: Deng Fenghua, Robinson Julian Neal, Tayler Moira
Принадлежит:

A composite film includes a nylon base film and a coextensive layer of adhesive composition that includes one or more polymers, wherein the one or more polymers taken together include in polymerized form: a) ethylene; b) one or more ester-containing monomers, constituting in a range from 5 to 50 wt % of the one or more polymers; and c) one or more carboxylic acid-containing monomers and optionally salt(s) thereof, constituting in a range from 0.5 to 20 wt % of the one or more polymers. A package may be prepared, including a lid made from the composite film heat sealed to a tray. A bag for packaging raw or processed meat may be made from the composite film. A food item may be contained in the package or bag. 1. A composite film comprising a nylon base film and a coextensive layer of adhesive composition comprising one or more polymers , wherein the one or more polymers taken together comprise in polymerized form:a) ethylene;b) one or more ester-containing monomers, constituting in a range from 5 to 50 wt % of the one or more polymers; andc) one or more carboxylic acid-containing monomers and optionally salt(s) thereof, constituting in a range from 0.5 to 20 wt % of the one or more polymers.2. The composite film of claim 1 , wherein the one or more carboxylic acid-containing monomers and optionally salts thereof constitute in a range from 2 to 5 wt % of the one or more polymers.3. The composite film of claim 1 , wherein the one or more ester-containing monomers constitute in a range from 15 to 30 wt % of the one or more polymers.4. The composite film of claim 1 , wherein the one or more polymers comprisea) an ethylene vinyl acetate copolymer having a vinyl acetate content in a range from 5-35 wt %; andb) an ethylene (meth)acrylic acid copolymer and optionally salt(s) thereof having a (meth)acrylic acid content in a range from 2-15 wt %.5. The composite film of claim 4 , wherein the vinyl acetate content is in a range from 15-25 wt %.6. The composite film of claim 4 , ...

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Номер записи: 97
06-02-2020 дата публикации

SEALING MEMBER

Номер: US20200040175A1
Автор: Gunji Yasuhiro, IRIE Shiori, OKAMOTO Takuya, OWADA Akihiro, SHINADA Takashi, Yamamoto Noriaki, YANAGAWA Hajime
Принадлежит:

[Object] To provide a ring-shaped sealing member having both the sealing property and slidability. 1. A sealing member that is formed in a ring shape and has a sliding surface , comprising:100 parts by weight of fluorine rubber; and0.5 to 50 (inclusive) parts by weight of a particulate resin, the particulate resin including a compatible portion and a lubrication portion, the compatible portion having compatibility with the fluorine rubber, the lubrication portion having lubricity with respect to the fluorine rubber, whereina Shore A hardness measured using the sliding surface as a pressing surface is not less than 80.2. The sealing member according to claim 1 , whereinthe particulate resin is present on the sliding surface.3. The sealing member according to claim 1 , whereinthe particulate resin is dispersed in the fluorine rubber.4. The sealing member according to claim 1 , whereinthe particulate resin contains not less than 40 weight % of silicone.5. The sealing member according to claim 4 , whereinthe particulate resin is formed by a silicone-acrylic copolymer.6. The sealing member according to claim 1 , further comprisingcarbon distributed in the fluorine rubber.7. The sealing member according to claim 1 , whereina surface roughness Rz of a counterpart material on which the sliding surface slides is not less than 0.5 z and not more than 18.0 z in accordance with JIS B 6001-1982.8. The sealing member according to claim 1 , whereinthe surface roughness Rz of the sliding surface is not less than 0.5 z and not more than 10.0 z in accordance with JIS B 6001-1982.9. The sealing member according to claim 1 , whereinthe sliding surface includes no parting line.10. The sealing member according to claim 2 , whereinthe particulate resin is dispersed in the fluorine rubber. The present invention relates to a sealing member having slidability.Rubber is suitable as a sealing member because it is capable of ensuring a sealing property by its own rubber elasticity (repulsive ...

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Номер записи: 98
15-02-2018 дата публикации

HIGH IMPACT BLENDS OF VINYLIDENE FLUORIDE-CONTAINING POLYMERS

Номер: US20180044515A1
Автор: "OBrien Gregory S.", Amin-Sanayei Ramin, HENRY James J., ZERAFATI Saeid
Принадлежит:

The invention relates to blends containing polymers of vinylidene fluoride, having low ductile-brittle transition temperatures and having excellent low temperature impact properties while maintaining the positive aspects of unmodified vinylidene fluoride-containing polymers. The blends of this invention are produced by adding a core-shell impact modifier (CSIM) comprised of a polysiloxane core and a shell compatible with vinylidene fluoride-containing polymer. The blends are further characterized by the presence of a heterogeneous copolymer composition comprised of two or more distinct phases and/or at least one flame and smoke suppressant. The preparation of these new blends can be done by conventional thermoplastic compounding techniques such as twin screw compounding; alternatively, the CSIM can be introduced earlier, such as in the latex. The unique properties of the new blends make them useful in end-use applications where those properties provide performance advantages, such as in wires & cables and in oil and gas applications. 1. A resin composition comprised of a vinylidene fluoride-containing polymer and a core-shell impact modifier comprised of a polysiloxane core and a shell of a non-elastomeric polymeric material compatible with the vinylidene fluoride-containing polymer , wherein the resin composition additionally has at least one of characteristics a) , b) , c) or d):a) the resin composition is additionally comprised of at least one flame and smoke suppressant;b) the vinylidene fluoride-containing polymer is a heterogeneous copolymer composition comprised of two or more distinct phases;c) the vinylidene fluoride-containing polymer is in the form of a powder having distinct particles having a weight average particle size on less than 500 nm, or agglomerate particles in the range of 0.5 to 200 microns,d) the resin composition is in the form of an aqueous dispersion.2. The resin composition of claim 1 , wherein the vinylidene fluoride-containing polymer ...

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Номер записи: 99
19-02-2015 дата публикации

Mixture of Benzoxazine, Epoxy and Anhydride

Номер: US20150051315A1
Автор: Arguelles Leo, Kincaid Derek, Kuang Wenfeng, Subrahmanian K.P., Wang Dong
Принадлежит:

The present disclosure provides a phenolic-free composition containing a benzoxazine, epoxy resin and acid anhydride. The phenolic-free composition, upon curing, renders void free cured articles having well balanced thermal, chemical and mechanical properties. The phenolic-free composition may be used in a variety of applications, such as in coatings, structural composites and encapsulating systems for electronic and electrical components. 6. The phenolic-free composition of wherein the epoxy resin is selected from a polyglycidyl epoxy compound; a non-glycidyl epoxy compound; an epoxy cresol novolac compound; an epoxy phenol novolac compound and mixtures thereof.7. The phenolic-free composition of wherein the acid anhydride is selected from a monoanhydride claim 1 , a dianhydride claim 1 , a polyanhydride claim 1 , an anhydride-functionalized compound claim 1 , a modified dianhydride adduct and mixtures thereof.8. The phenolic-free composition of wherein the acid anhydride is a monoanhydride selected from maleic anhydride claim 7 , phthalic anhydride claim 7 , succinic anhydride claim 7 , itaconic anhydride claim 7 , citraconic anhydride claim 7 , nadic methyl anhydride claim 7 , methylhexahydrophthalic anhydride claim 7 , methyltetrahydrophthalic anhydride claim 7 , tetrahydrophthalic anhydride claim 7 , hexahydrophthalic anhydride claim 7 , trimellitic anhydride claim 7 , tetrahydrotrimellitic anhydride claim 7 , hexahydrotrimellitic anhydride claim 7 , dodecenylsuccinic anhydride and mixtures thereof.9. The phenolic-free composition of wherein the acid anhydride is a dianhydride selected from 1 claim 7 ,2 claim 7 ,5 claim 7 ,6-naphthalene tetracarboxylic dianhydride claim 7 , 1 claim 7 ,4 claim 7 ,5 claim 7 ,8-naphthalene tetracarboxylic dianhydride claim 7 , 2 claim 7 ,3 claim 7 ,6 claim 7 ,7-naphthalene tetracarboxylic dianhydride claim 7 , 2-(3′ claim 7 ,4′-dicarboxyphenyl) 5 claim 7 ,6-dicarboxybenzimidazole dianhydride claim 7 , 2-(3′ claim 7 ,4′- ...

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Номер записи: 100