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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 25998. Отображено 100.
16-09-1996 дата публикации

УСТАНОВКА ДЛЯ ТЕСТИРОВАНИЯ КАТАЛИЗАТОРОВ ГИДРООБЛАГОРАЖИВАНИЯ НЕФТЯНЫХ ДИСТИЛЛЯТОВ

Номер: RU0000002814U1

Установка для тестирования катализаторов гидрооблагораживания нефтяных дистиллятов, содержащая блок подготовки сырья с нагревателем, реакторный блок с нагревателем и блок разделения продуктов, отличающаяся тем, что реакторный блок выполнен из четырех реакторов одинаковой высоты, при этом блок подготовки сырья и реакторный блок размещены в одном нагревателе, а нагреватель выполнен индукционным. (19) RU (11) (13) 2 814 U1 (51) МПК C10G 45/08 (1995.01) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К СВИДЕТЕЛЬСТВУ (21), (22) Заявка: 94039208/20, 19.10.1994 (46) Опубликовано: 16.09.1996 (57) Формула полезной модели Установка для тестирования катализаторов гидрооблагораживания нефтяных дистиллятов, содержащая блок подготовки сырья с нагревателем, реакторный блок с нагревателем и блок разделения продуктов, отличающаяся тем, что реакторный блок выполнен из четырех реакторов одинаковой высоты, при этом блок подготовки сырья и реакторный блок размещены в одном нагревателе, а нагреватель выполнен индукционным. R U 2 8 1 4 (54) УСТАНОВКА ДЛЯ ТЕСТИРОВАНИЯ КАТАЛИЗАТОРОВ ГИДРООБЛАГОРАЖИВАНИЯ НЕФТЯНЫХ ДИСТИЛЛЯТОВ Ñòðàíèöà: 1 U 1 U 1 (73) Патентообладатель(и): Насиров Рашид Кулам оглы 2 8 1 4 (72) Автор(ы): Насиров Р.К., Дианова С.А., Сурков В.В., Воронин А.И., Талисман Е.Л., Ковальчук Н.А. R U (71) Заявитель(и): Насиров Р.К., Дианова С.А., Сурков В.В., Воронин А.И., Талисман Е.Л., Ковальчук Н.А. RU 2 814 U1 RU 2 814 U1 RU 2 814 U1 RU 2 814 U1

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05-01-2012 дата публикации

Production of Low Color Middle Distillate Fuels

Номер: US20120000817A1
Автор: Stuart S. Shih
Принадлежит: ExxonMobil Research and Engineering Co

In a process for producing a low color diesel and/or kerosene fuel, a middle distillate feed can be supplied to a reactor having at least one first catalyst bed containing a first desulfurization and/or isomerization catalyst and at least one second catalyst bed containing a decolorization catalyst downstream from the first catalyst bed(s). The feed can be reacted with the hydrogen in the presence of the first catalyst at a temperature from about 290° C. to about 430° C. to produce a first liquid effluent, which can be cooled by about 10° C. to about 40° C. with a quench medium and cascaded to the at least one second catalyst bed. The cooled first liquid effluent can then be reacted with hydrogen in the presence of the decolorization catalyst at a temperature from about 280° C. to about 415° C. to produce a second effluent having an ASTM color less than 2.5.

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27-01-2005 дата публикации

УСТАНОВКА ТЕРМОМЕХАНИЧЕСКОГО КРЕКИНГА И ГИДРОГЕНИЗАЦИИ УГЛЕВОДОРОДОВ

Номер: RU0000043545U1

Установка термомеханического крекинга и гидрогенизации углеводородов, включающая бункер исходного материала и реактор, соединенные питающим устройством, отличающаяся тем, что реактор снабжен по меньшей мере одним излучателем акустических колебаний, связанным с генератором указанных колебаний. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 43 545 (13) U1 (51) МПК C10G 47/30 (2000.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21), (22) Заявка: 2004127084/22 , 13.09.2004 (24) Дата начала отсчета срока действия патента: 13.09.2004 (45) Опубликовано: 27.01.2005 (73) Патентообладатель(и): Общество с ограниченной ответственностью "НОВЫЕ ТЕХНОЛОГИИ БИЗНЕСА" (RU) U 1 4 3 5 4 5 R U Ñòðàíèöà: 1 U 1 Формула полезной модели Установка термомеханического крекинга и гидрогенизации углеводородов, включающая бункер исходного материала и реактор, соединенные питающим устройством, отличающаяся тем, что реактор снабжен по меньшей мере одним излучателем акустических колебаний, связанным с генератором указанных колебаний. 4 3 5 4 5 (54) УСТАНОВКА ТЕРМОМЕХАНИЧЕСКОГО КРЕКИНГА И ГИДРОГЕНИЗАЦИИ УГЛЕВОДОРОДОВ R U Адрес для переписки: 197136, Санкт-Петербург, а/я 55, пат.пов. Ю.В. Рыбакову, рег.№ 244 (72) Автор(ы): Ольховский Э.В. (RU) U 1 U 1 4 3 5 4 5 4 3 5 4 5 R U R U Ñòðàíèöà: 2 RU 5 10 15 20 25 30 35 40 45 50 43 545 U1 Полезная модель относится к термомеханическому крекингу и гидрогенизации химических веществ. Известны установки термомеханического крекинга и гидрогенизации углеводородов в жидкой или твердой форме, карбонатов, извести, нефтеносных сланцев и песков, маслянистых остатков нефтеперерабатывающих заводов и т.п. Наиболее близким по технической сущности к заявляемой полезной модели является устройство, описанное в патенте РФ, включающее бункер исходного материала и реактор, соединенные питающим устройством (1). Однако, КПД указанного устройства недостаточен. Задачей полезной модели является обработка углеродистого ...

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10-07-2013 дата публикации

УСТРОЙСТВО РИФОРМИНГА СМЕСИ ТЯЖЕЛЫХ ПИРОЛИЗНЫХ СМОЛ И КИСЛОЙ ВОДЫ

Номер: RU0000129924U1

Устройство для риформинга смеси тяжелых пиролизных смол характеризуется тем, что оно содержит емкость перемешивания (гомогенизации) смеси тяжелых пиролизных смол и кислой воды с размещенными в нижней ее части барботажным коллектором, связанным с источником кислой воды, и барботажным коллектором, связанным с источником тяжелых углеводородов, в емкости перемешивания размещен в верхней части патрубок вывода гомогенизированной смеси, соединенный с огнепреградителем, который связан с емкостью реактора риформинга, реактор риформинга с расположенными в верхней части патрубком отвода углеводородов (их гомологов) и водородосодержащего синтез-газа, и в нижней части - системой выгрузки кокса, при этом внутри реактора расположен ориентированный вдоль его осевой линии змеевик, соединенный с огнепреградителем, а на корпусе реактора установлены индукционные петли генератора тока высокой частоты. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 129 924 U1 (51) МПК C10G 35/16 (2006.01) C10G 49/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ 2013104149/04, 01.02.2013 (24) Дата начала отсчета срока действия патента: 01.02.2013 (72) Автор(ы): Шимченко Сергей Петрович (RU) (73) Патентообладатель(и): Шимченко Сергей Петрович (RU) R U Приоритет(ы): (22) Дата подачи заявки: 01.02.2013 (45) Опубликовано: 10.07.2013 Бюл. № 19 1 2 9 9 2 4 R U Формула полезной модели Устройство для риформинга смеси тяжелых пиролизных смол характеризуется тем, что оно содержит емкость перемешивания (гомогенизации) смеси тяжелых пиролизных смол и кислой воды с размещенными в нижней ее части барботажным коллектором, связанным с источником кислой воды, и барботажным коллектором, связанным с источником тяжелых углеводородов, в емкости перемешивания размещен в верхней части патрубок вывода гомогенизированной смеси, соединенный с огнепреградителем, который связан с емкостью реактора риформинга, реактор риформинга с расположенными в верхней части ...

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20-07-2013 дата публикации

УСТАНОВКА ДЛЯ ПОЛУЧЕНИЯ ДИЗЕЛЬНЫХ ТОПЛИВ

Номер: RU0000130311U1

Установка для получения дизельного топлива, включающая в себя ректификационную колонну, блок подготовки сырья, реакторный блок, состоящий из печи, реактора гидроочистки, теплообменников и холодильников, отличающаяся тем, что она дополнительно содержит перед блоком подготовки сырья блок экстракции серосодержащих соединений, состоящий из связанных между собой экстрактора, ректификационной колонны для отделения экстрагента, нагревателей и холодильников, а также блок стабилизации гидроочищенного продукта, включающий в себя сепаратор, теплообменник, колонну стабилизации и холодильник. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 130 311 U1 (51) МПК C10G 21/06 (2006.01) C10G 45/02 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ 2012143774/04, 04.10.2012 (24) Дата начала отсчета срока действия патента: 04.10.2012 (45) Опубликовано: 20.07.2013 Бюл. № 20 (73) Патентообладатель(и): Общество с ограниченной ответственностью "Институт по проектированию предприятий нефтедобывающей и нефтехимической промышленности", ООО "ЛЕНГИПРОНЕФТЕХИМ" (RU) 1 3 0 3 1 1 Адрес для переписки: 193313, Санкт-Петербург, ул. Подвойского, 14, корп.1, кв.741, В.А. Кузнецову R U Приоритет(ы): (22) Дата подачи заявки: 04.10.2012 (72) Автор(ы): Фомин Александр Степанович (RU), Кашин Олег Николаевич (RU), Сомов Вадим Евсеевич (RU), Лисицын Николай Васильевич (RU), Ермоленко Алла Дмитриевна (RU), Журавлев Артем Николаевич (RU), Гайле Александр Александрович (RU), Кузичкин Николай Васильевич (RU) 1 3 0 3 1 1 R U Формула полезной модели Установка для получения дизельного топлива, включающая в себя ректификационную колонну, блок подготовки сырья, реакторный блок, состоящий из печи, реактора гидроочистки, теплообменников и холодильников, отличающаяся тем, что она дополнительно содержит перед блоком подготовки сырья блок экстракции серосодержащих соединений, состоящий из связанных между собой экстрактора, ректификационной колонны для отделения ...

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20-03-2014 дата публикации

УСТАНОВКА ДЛЯ ПЕРЕРАБОТКИ НЕФТЕШЛАМОВ

Номер: RU0000138715U1

Установка для переработки нефтешламов, включающая сообщенные между собой устройство для обработки исходного сырья, устройство выделения конечных продуктов, соединенного с устройством для охлаждения и конденсации конечного продукта, отличающаяся тем, что устройство для обработки исходного сырья выполнено из трех, соединенных между собой диафрагм с разным диаметром сечений, на выходе которых установлен полый шар, в котором закреплен металлический шар, а устройство для выделения конечных продуктов состоит из блока подготовки, фильтров-адсорберов, каталитического реактора, источника водяного пара, причем блок подготовки выполнен в виде горизонтального расположенного тора, внутри которого установлены ребра, параллельно боковым стенкам, по всей длине корпуса, вход которого соединен с устройством для обработки исходного сырья и источником водяного пара, а выход с фильтрами-адсорберами, состоящими из корпуса, чугунного и керамического наполнителя, расположенного слоями друг за другом, под днищем которых расположены термостатические рубашки, выходы фильтров-адсорберов соединены с противоположно направленными входами каталитического реактора, который соединен с источником водяного пара. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 138 715 U1 (51) МПК C10G 47/32 (2006.01) C10G 47/02 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ 2013147315/04, 22.10.2013 (24) Дата начала отсчета срока действия патента: 22.10.2013 (72) Автор(ы): Зайченко Владимир Николаевич (RU) (73) Патентообладатель(и): Зайченко Владимир Николаевич (RU) R U Приоритет(ы): (22) Дата подачи заявки: 22.10.2013 (45) Опубликовано: 20.03.2014 Бюл. № 8 1 3 8 7 1 5 R U Формула полезной модели Установка для переработки нефтешламов, включающая сообщенные между собой устройство для обработки исходного сырья, устройство выделения конечных продуктов, соединенного с устройством для охлаждения и конденсации конечного продукта, отличающаяся тем, что устройство ...

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20-11-2016 дата публикации

Каталитический картридж для осуществления гетерогенных каталитических реакций

Номер: RU0000166263U1

1. Каталитический картридж для осуществления гетерогенных каталитических реакций с катализатором, состоящим из нитей, скрученных из каталитических микроволокон, отличающийся тем, что картридж содержит более чем один каталитический элемент, каждый из которых выполнен из каталитической нити с толщиной от 0.1 мм до 5 мм в форме петли, либо другой фигуры, включающей петлю.2. Каталитический картридж по п. 1, отличающийся тем, что каждый каталитический элемент содержит два плоских опорных полотна, расположенных параллельно друг другу на расстоянии от 1 мм до 50 мм и скрепленных между собой регулярно расположенными каталитическими элементами из каталитических нитей в форме петель или других фигур, включающих петлю.3. Каталитический картридж по п. 2, отличающийся тем, что плоские опорные полотна выполнены в форме тканых или плетеных полотен из нитей микроволокнистого катализатора.4. Каталитический картридж по п. 1, отличающийся тем, что каталитические микроволокна представляют собой стеклянные, металлические, минеральные, углеродные, полимерные или иные волокна диаметром от 1 мкм до 30 мкм, на поверхности которых находятся каталитически активные компоненты.5. Каталитический картридж по п. 4, отличающийся тем, что на поверхности микроволокон может находиться дополнительный слой вторичного носителя с развитой внутренней поверхностью, например, слой диоксида кремния, оксида алюминия, диоксида титана или активированного углерода.6. Каталитический картридж по п. 5, отличающийся тем, что в качестве активных компонентов на поверхности микроволокон он содержит благородные металлы, такие как: платина, палладий, золото, серебро и/или оксиды переходных металлов: РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 166 263 U1 (51) МПК B01J 8/00 (2006.01) B01J 35/06 (2006.01) B01J 21/00 (2006.01) B01J 23/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ТИТУЛЬНЫЙ (21)(22) Заявка: ЛИСТ ОПИСАНИЯ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ 2016109690/04, 17.03.2016 (24) Дата начала отсчета срока ...

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12-03-2018 дата публикации

ТРУБЧАТАЯ ПЕЧЬ КОНВЕКЦИОННОГО НАГРЕВА ТЕПЛОНОСИТЕЛЯ С ПРИНУДИТЕЛЬНОЙ РЕЦИРКУЛЯЦИЕЙ ДЫМОВЫХ ГАЗОВ

Номер: RU0000177784U1

Полезная модель относится к устройствам для нагрева теплоносителей (жидкостей, газов и других), конкретно к трубчатым печам и может быть использована в нефтяной, газовой, нефтеперерабатывающей и нефтехимической отраслях промышленности. Технический результат заявляемой полезной модели заключается в увеличении срока службы устройства за счет устранения воздействия пламени горелочного узла на стенки камеры сгорания, устранения перегрева стенок теплообменной камеры за счет введения камеры смешения и устранения перегрева трубного змеевика благодаря улучшению теплопередачи от горелочного узла к содержимому трубного змеевика за счет использования оребренных труб с внутренними турбулизирующими вставками, при снижении теплопотерь. Указанный технический результат достигается тем, что трубчатая печь содержит корпус с размещенной внутри камерой сгорания, снабженной горелочным узлом, и теплообменной камерой, снабженной по крайней мере одним трубным змеевиком; рециркуляционный вентилятор, вход которого соединен с выходом теплообменной камеры, согласно решению печь содержит камеру смешения, вход которой соединен с выходом камеры сгорания и выходом рециркуляционного вентилятора, а выход соединен с входом теплообменной камеры, камера смешения выполнена из двух концентрических обечаек, между которыми расположено спиральное ребро жесткости, образующее воздушный канал от выхода камеры смешения к входу камеры смешения; печь содержит дутьевой вентилятор, выход которого соединен с воздушным каналом у выхода камеры смешения; горелочный узел снабжен входом для воздуха, соединенным с воздушным каналом у входа камеры смешения; камера сгорания, камера смешения и теплообменная камера расположены в корпусе так, чтобы обеспечить направление потока газа в теплообменной камере под углом 90° относительно направления потока газа в камерах сгорания и смешения. Трубный змеевик выполнен из гладких или оребренных труб и снабжен внутренними турбулизирующими вставками в наиболее теплонапряженных зонах ...

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26-03-2018 дата публикации

УСТРОЙСТВО ДЛЯ ПОЛУЧЕНИЯ МИКРОКРИСТАЛЛОВ МАГГЕМИТА

Номер: RU0000178133U1

Полезная модель относится к устройствам, предназначенным для получения микрокристаллов высокодисперсного оксида железа в форме маггемита (γ-FeO) электрохимическим способом при комнатной температуре и атмосферном давлении, которые могут быть использованы в качестве основы для композиционных материалов, в частности, обладающих значительной удельной поверхностью и ярко выраженными ферромагнитными свойствами порошкообразных сорбентов, отделяемых под действием магнитного поля. Устройство содержит ванну с электролитом (40%-ным водным раствором гидроксида натрия), снабженную пластинчатыми железными электродами, подключенными к источнику постоянного тока. Устройство дополнительно оснащено постоянным магнитом, монтируемым на железном пластинчатом катоде, датчиком температуры и охладительным узлом, размещаемыми в объеме электролита, поддерживающими его температуру на уровне, не превышающем t=45°C. Технический результат, получаемый при реализации изобретения, состоит в значительном упрощении процесса получения микрокристаллов маггемита, повышении его эффективности и экономичности. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 178 133 U1 (51) МПК C25B 9/00 (2006.01) C25B 1/00 (2006.01) C10G 49/06 (2006.01) C25B 1/06 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (52) СПК C25B 9/00 (2017.08); C25B 1/00 (2017.08); C25B 1/06 (2017.08) (21)(22) Заявка: 2017135699, 05.10.2017 (24) Дата начала отсчета срока действия патента: 26.03.2018 Приоритет(ы): (22) Дата подачи заявки: 05.10.2017 (45) Опубликовано: 26.03.2018 Бюл. № 9 2000336495 A, 05.12.2000. RU 93007681 A, 30.04.1995. (54) УСТРОЙСТВО ДЛЯ ПОЛУЧЕНИЯ МИКРОКРИСТАЛЛОВ МАГГЕМИТА (57) Реферат: Полезная модель относится к устройствам, (40%-ным водным раствором гидроксида натрия), предназначенным для получения снабженную пластинчатыми железными микрокристаллов высокодисперсного оксида электродами, подключенными к источнику железа в форме маггемита (γ-Fe2O3) постоянного тока. Устройство ...

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29-06-2021 дата публикации

Устройство усовершенствованной микроповерхностной реакции гидрирования с нисходящим потоком и фиксированным слоем для производства нефтепродуктов

Номер: RU0000205181U1

Полезная модель относится к устройству усовершенствованной микроповерхностной реакции гидрирования с нисходящим потоком и фиксированным слоем для производства нефтепродуктов. Устройство включает в себя реактор с фиксированным слоем и генератор микроповерхностей, при этом генератор микроповерхностей расположен над реактором с фиксированным слоем для преобразования энергии давления водорода и/или кинетической энергии нефтепродукта во время реакции в поверхностную энергию пузырька и передачи поверхностной энергии пузырьку водорода, так что пузырек водорода дробится на микропузырьки и микропузырьки смешиваются с нефтепродуктом в процессе реакции для образования газожидкостной эмульсии; реактор с фиксированным слоем используется в качестве места протекания реакции гидрирования для образования стабильной усовершенствованной газожидкостной системы для реакции с фиксированным слоем, когда газожидкостная эмульсия поступает в реактор с фиксированным слоем; резервуар для разделения газа и жидкости соединен с реактором с фиксированным слоем для отделения газа от жидкости в смеси, являющейся результатом реакции в реакторе с фиксированным слоем. Устройство микроповерхностной реакции гидрирования с фиксированным слоем имеет преимущества низкого потребления энергии, низкого рабочего давления, большой площади межфазной границы массопереноса газ-жидкость, высокой видимой скорости реакции и высокой эффективности использования газа. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 205 181 U1 (51) МПК B01J 8/02 (2006.01) C10G 45/08 (2006.01) C10G 45/22 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (52) СПК B01J 8/02 (2021.02); C10G 45/08 (2021.02); C10G 45/22 (2021.02) (21)(22) Заявка: 2020129865, 06.06.2019 (24) Дата начала отсчета срока действия патента: Дата регистрации: 29.06.2021 15.03.2019 CN 201910196596.X (45) Опубликовано: 29.06.2021 Бюл. № 19 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 10.09.2020 (73) ...

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15-10-2021 дата публикации

УСТРОЙСТВО УСОВЕРШЕНСТВОВАННОЙ МИКРОПОВЕРХНОСТНОЙ РЕАКЦИИ ГИДРИРОВАНИЯ

Номер: RU0000207190U1

Полезная модель представляет собой устройство усовершенствованной микроповерхностной реакции гидрирования, которое включает корпус реактора, используемый в качестве реакционной камеры в процессе реакции гидрирования, обеспечивающий полноценное протекание реакции гидрирования, генератор микроповерхностей, соединенный с корпусом реактора для дробления водородного и/или жидкого реагента в генераторе микроповерхностей на микропузырьки и/или микрокапли с диаметром микронного уровня посредством механической и/или турбулентной микроструктуры в заданном режиме функционирования до того, как водород и жидкость и/или смесь твердых и жидких материалов в процессе реакции гидрирования войдут в корпус реактора, для увеличения площади межфазного переноса между водородом и жидкостью и/или смесью твердых и жидких материалов в процессе реакции гидрирования, повышения эффективности массопереноса между фазами реакции и улучшения реакции гидрирования при заданных условиях температуры и давления. Полезная модель эффективно решает проблему низкой скорости массопереноса из-за малой площади контакта границы раздела фаз реагентов при протекании реакции. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 207 190 U1 (51) МПК B01J 8/02 (2006.01) C10G 45/08 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (52) СПК B01J 8/02 (2021.08); C10G 45/08 (2021.08) (21)(22) Заявка: 2020129854, 06.06.2019 (24) Дата начала отсчета срока действия патента: Дата регистрации: 15.10.2021 15.03.2019 CN 201910196624.8 (45) Опубликовано: 15.10.2021 Бюл. № 29 (73) Патентообладатель(и): НАНКИН ЙАНЧАНГ РИЭКШН ТЕКНОЛОДЖИ РИСЁРЧ ИНСТИТЬЮТ КО. ЛТД (CN) (85) Дата начала рассмотрения заявки PCT на национальной фазе: 10.09.2020 (86) Заявка PCT: 2 0 7 1 9 0 Приоритет(ы): (30) Конвенционный приоритет: R U 06.06.2019 (72) Автор(ы): ЖАНГ Жибинг (CN), ЖОУ Женг (CN), ЖАНГ Фенг (CN), ЛИ Леи (CN), МЕНГ Веимин (CN), ВАНГ Баоронг (CN), ЙАНГ Гаодонг (CN), ЛУО Хуаксун (CN), ЙАНГ Гуокианг (CN), ...

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12-01-2012 дата публикации

Method and System for Synthesizing Liquid Hydrocarbon Compounds

Номер: US20120010304A1
Автор: Kazuhiko Tasaka

Provided is a method for synthesizing liquid hydrocarbon compounds wherein synthesizing liquid hydrocarbon compounds from a synthesis gas by a Fisher-Tropsch synthesis reaction. The method includes a first absorption step of absorbing a carbon dioxide gas, which is contained in gaseous by-products generated in the Fisher-Tropsch synthesis reaction, with an absorbent, and a second absorption step of absorbing a carbon dioxide gas, which is contained in the synthesis gas, with the absorbent which is passed through the first absorption step.

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19-01-2012 дата публикации

Multiphase contact and distribution apparatus for hydroprocessing

Номер: US20120014847A1
Принадлежит: Chevron USA Inc

Systems and apparatus for mixing, cooling, and distributing multiphase fluid mixtures within a reactor, wherein reactor internal apparatus of the present invention provides not only improved fluid mixing and distribution to each underlying catalyst bed surface, but also offers other advantages including: decreased mixing tray height; easier maintenance, assembly and disassembly; and decreased amounts of fabrication material. In an embodiment, fluid may be evenly distributed to a catalyst bed from a fluid distribution unit comprising a nozzle tray including a plurality of nozzles, wherein the nozzles include at least one liquid inlet disposed tangentially to an inner surface of the nozzle.

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22-03-2012 дата публикации

Process and device for separating liquid from a multiphase mixture

Номер: US20120070356A1
Принадлежит: SOLVAY SA

Process and device for separating liquid from a multiphase mixture contained in a vessel and comprising solid particles and at least one liquid phase forming together at least one suspension, and a gas phase in which at least part of the mixture is circulated through at least one cross-flow filter located outside the vessel, therefore separating said part of the mixture into a filtered liquid and a concentrate.

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19-04-2012 дата публикации

Process for producing middle distillates by hydroisomerization and hydrocracking of a heavy fraction derived from a fischer-tropsch effluent

Номер: US20120091034A1
Принадлежит: Eni Spa, IFP Energies Nouvelles IFPEN

The present invention describes a process for producing middle distillates from a C5+ liquid paraffinic fraction, termed a heavy fraction, with an initial boiling point in the range 15° C. to 40° C. produced by Fischer-Tropsch synthesis, comprising the following steps in succession: passing said C5+ liquid paraffinic fraction, termed a heavy fraction, over at least one ion exchange resin at a temperature in the range 80° C. to 150° C., at a total pressure in the range 0.7 to 2.5 MPa, at an hourly space velocity in the range 0.2 to 2.5 h −1 ; eliminating at least a portion of the water formed in step a); hydrogenating the unsaturated olefinic type compounds of at least a portion of the effluent derived from step b) in the presence of hydrogen and a hydrogenation catalyst; and hydroisomerization/hydrocracking of at least a portion of the hydrotreated effluent derived from step c) in the presence of hydrogen and a hydroisomerization/hydrocracking catalyst.

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03-05-2012 дата публикации

Fuel and base oil blendstocks from a single feedstock

Номер: US20120108869A1
Принадлежит: Chevron USA Inc

A method comprising the steps of providing a quantity of biologically-derived oil comprising triglycerides; processing the biologically derived oil so as to transesterify at least some of the triglycerides contained therein to yield a quantity of saturated monoesters and unsaturated monoesters; oligomerizing at least some of the unsaturated monoesters to yield a quantity of fatty acid ester oligomers; separating at least some of the saturated monoesters from the fatty acid ester oligomers; and hydrotreating at least some of the fatty acid ester oligomers to yield a quantity of alkanes.

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03-05-2012 дата публикации

Fuel and base oil blendstocks from a single feedstock

Номер: US20120108871A1
Автор: Stephen J. Miller
Принадлежит: Chevron USA Inc

A method comprising providing a fatty acyl mixture comprising: (i) a C 10 -C 16 acyl carbon atom chain content of at least 30 wt. % wherein at least 80% of the C 10 -C 16 acyl carbon atom chains are saturated; and (ii) a C 18 -C 22 acyl carbon atom chain content of at least 20 wt. % wherein at least 50% of the acyl C 18 -C 22 carbon atom chains contain at least one double bond; hydrolyzing the mixture to yield a quantity of C 10 -C 16 saturated fatty acids and C 18 -C 22 unsaturated fatty acids; oligomerizing at least some of the C 18 -C 22 unsaturated fatty acids to yield a quantity of C 36+ fatty acid oligomers; hydrotreating at least some of the C 10 -C 16 saturated fatty acids and at least some of the C 36+ fatty acid oligomers to yield a quantity of diesel fuel blendstock and C 36+ alkanes; and separating at least some of the diesel fuel blendstock from the C 36+ alkanes.

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17-05-2012 дата публикации

Hydroconversion multi-metallic catalyst and method for making thereof

Номер: US20120122653A1
Принадлежит: Chevron USA Inc

In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant. In the present disclosure, the metals can be recovered in an electro-coagulation reactor, wherein portion of the metal residuals in the supernatant reacts with the electrodes to form a slurry containing insoluble metal compounds. The insoluble metal compounds are isolated and recovered, forming an effluent stream. The insoluble metal compounds and/or the effluent stream can be further treated to form at least a metal precursor feed which can be used in the co-precipitation reaction.

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17-05-2012 дата публикации

Hydroconversion multi-metallic catalyst and method for making thereof

Номер: US20120122655A1
Принадлежит: Chevron USA Inc

In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant. In the present disclosure, the metals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of metal ions in at least one of the metal residuals, and for at least one of the metal residuals is recovered as a metal precursor feed, which can be recycled for use in the co-precipitation reaction. An effluent stream from the process to waste treatment contains less than 50 ppm metal ions.

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24-05-2012 дата публикации

Process for Cracking Heavy Hydrocarbon Feed

Номер: US20120125812A1
Принадлежит: EQUISTAR CHEMICALS LP

A process for cracking a heavy hydrocarbon feed comprising a vaporization step, a hydroprocessing step, and a steam cracking step is disclosed. The heavy hydrocarbon feed is passed to a first zone of a vaporization unit to separate a first vapor stream and a first liquid stream. The first liquid stream is passed to a second zone of the vaporization unit and contacted intimately with a counter-current steam produce a second vapor stream and a second liquid stream. The first vapor stream and the second vapor stream are cracked in the radiant section of the steam cracker to produce a cracked effluent. The second liquid stream reacted with hydrogen in the presence of a catalyst to produce a hydroprocessed product. A liquid hydroprocessed product is fed to the vaporization unit.

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21-06-2012 дата публикации

Increasing fuel smoke point

Номер: US20120152803A1
Автор: Stuart S. Shih
Принадлежит: ExxonMobil Research and Engineering Co

The present invention relates to processes for increasing smoke point of a fuel. The process can be carried out using an upgrading catalyst that contains at least one noble metal supported on an inorganic, porous crystalline phase material. The catalyst is particularly effective in increasing smoke point, while minimizing reduction in total aromatics content, particularly naphthalene content.

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21-06-2012 дата публикации

Method of making a catalyst

Номер: US20120157299A1
Принадлежит: ENERGIA TECHNOLOGIES Inc

Presented are one or more aspects and/or one or more embodiments of catalysts, methods of preparation of catalyst, methods of deoxygenation, and methods of fuel production.

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21-06-2012 дата публикации

Methods of deoxygenation and systems for fuel production

Номер: US20120157727A1
Принадлежит: ENERGIA TECHNOLOGIES Inc

Presented are one or more aspects and/or one or more embodiments of catalysts, methods of preparation of catalyst, methods of deoxygenation, and methods of fuel production.

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21-06-2012 дата публикации

Production of renewable fuels

Номер: US20120157742A1
Принадлежит: ConocoPhillips Co

The present disclosure relates to a process for the conversion of oxygen-containing hydrocarbons into long-chain hydrocarbons suitable for use as a fuel. These hydrocarbons may be derived from biomass, and may optionally be mixed with petroleum-derived hydrocarbons prior to conversion. The process utilizes a catalyst comprising Ni and Mo to convert a mixture comprising oxygenated hydrocarbons into product hydrocarbons containing from ten to thirty carbons. Hydro-conversion can be performed at a significantly lower temperature than is required for when utilizing a hydrotreating catalyst comprising Co and Mo (CoMo), while still effectively removing sulfur compounds (via hydrodesulfurization) to a level of 10 ppm (by weight) or less.

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05-07-2012 дата публикации

Hydroprocessing catalysts and methods for making thereof

Номер: US20120172199A1
Принадлежит: Chevron USA Inc

An improved process to make a slurry catalyst for the upgrade of heavy oil feedstock is provided. In the process, at least a metal precursor feedstock is portioned and fed in any of the stages: the promotion stage; the sulfidation stage; or the transformation stage of a water-based catalyst precursor to a slurry catalyst. In one embodiment, the promoter metal precursor feedstock is split into portions, the first portion is for the sulfiding step, the second portion is for the promotion step; and optionally the third portion is to be added to the transformation step in the mixing of the sulfided promoted catalyst precursor with a hydrocarbon diluent to form the slurry catalyst. In another embodiment, the Primary metal precursor feedstock is split into portions.

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19-07-2012 дата публикации

Method for upgrading heavy hydrocarbon oil

Номер: US20120181216A1
Принадлежит: Arisdyne Systems Inc

A process for upgrading hydrocarbon oil including mixing hydrocarbon oil with hydrogen gas and heating the hydrogen-enriched hydrocarbon oil before passing the oil through a cavitation apparatus to induce hydrotreating. Hydrotreating is achieved by hydrodynamically generating hydrogen-filled cavitation bubbles and collapsing the bubbles in the hydrocarbon oil under static pressure. The hydrotreating process can increase the API gravity of the hydrocarbon oil and reduce the viscosity of the hydrocarbon oil.

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19-07-2012 дата публикации

Method and arrangement for feeding heat-sensitive materials to fixed-bed reactors

Номер: US20120184792A1
Принадлежит: Neste Oyj

The invention relates to an arrangement for feeding heat-sensitive feedstock to a fixed-bed reactor system comprising means for product recycle and a fixed-bed reactor system comprising a fixed-bed reactor comprising at least one reaction zone having at least one catalyst bed and said reaction zone comprising a cold feed distributor arranged on top of each catalyst bed and a conventional distributor arranged above each cold feed distributor. Also a method is provided for feeding heat-sensitive feedstock to a fixed-bed reactor system wherein said fixed-bed reactor system comprises means for product recycle and a fixed-bed reactor comprising at least one reaction zone having at least one catalyst bed and said reaction zone comprising a cold feed distributor arranged on top of each catalyst bed and a conventional distributor arranged above each cold feed distributor.

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19-07-2012 дата публикации

Process for isomerizing a feed stream including one or more c4-c6 hydrocarbons

Номер: US20120184793A1
Автор: David J. Shecterle
Принадлежит: UOP LLC

One exemplary embodiment can be a process for isomerizing a feed stream including one or more C4-C6 hydrocarbons. The process may include contacting the feed stream in an isomerization reaction zone with an isomerization catalyst at isomerization conditions to produce an isomerization zone effluent; passing at least a portion of the isomerization zone effluent to a stabilizer zone and recovering a stabilizer overhead stream, a bottom stream, and a stripper feed stream; passing the stripper feed stream to a stripping zone and separating the stripper feed stream into a stripper overhead stream and a stripper bottom stream; and recycling at least a portion of the stripper bottom stream to a deisopentanizer zone and passing a stream from the deisopentanizer zone to the isomerization reaction zone. Usually, the stabilizer overhead stream includes one or more C5 − hydrocarbons, the bottom stream includes at least about 85%, by weight, one or more C6 + hydrocarbons, and a stripper feed stream including at least about 10%, by weight, one or more C5 + hydrocarbons. Often, a stripper overhead stream includes at least about 5%, by weight, one or more C4 − hydrocarbons and a stripper bottom stream includes at least about 90%, by weight, one or more C5 + hydrocarbons.

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26-07-2012 дата публикации

Molecular Sieve Of MFS Framework Type With Controllable Average Size, Its Method of Making And Use

Номер: US20120190896A1
Принадлежит: ExxonMobil Chemical Patents Inc

A method of making a crystalline molecular sieve of MFS framework type, preferably ZSM-57, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure-directing-agent (R) and water, said alkali metal (M) comprising potassium, and having the following mole composition (expressed in terms of oxide): YO 2 :( p )X 2 O 3 :( q )OH − :( r )R:( s )H 2 O, wherein (p) is in the range from 0.005 to 0.05, (q) is in the range from 0.01 to 3, (r) is in the range from 0.03 to 2 and (s) is in the range from 10 to 75 (based on total weight of said synthesis mixture); wherein the crystals of molecular sieve formed having an average diameter (D) of less than or equal to 1.5 micron and an average thickness (T) of less than or equal to 300 nanometers.

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16-08-2012 дата публикации

Hydroprocessing Catalyst Prepared with Waste Catalyst Fines and Its Use

Номер: US20120205290A1
Принадлежит: Shell Oil Co

A hydroprocessing catalyst composition that comprises a shaped support that is formed from a mixture of inorganic oxide powder and catalyst fines and wherein the shaped support has incorporated therein at least one metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition is prepared by incorporating into the shaped support a metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition has particular application in the catalytic hydroprocessing of petroleum derived feedstocks.

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16-08-2012 дата публикации

Selective isomerization and oligomerization of olefin feedstocks for the production of turbine and diesel fuels

Номер: US20120209046A1
Принадлежит: US Department of Navy

A process from converting alcohol feedstock to diesel/turbine fuels.

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23-08-2012 дата публикации

Process for hydrotreating naphtha fraction and process for producing hydrocarbon oil

Номер: US20120211401A1
Принадлежит: Individual

A process for hydrotreating a naphtha fraction that includes a step of estimating the difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature, based on the reaction temperature of the Fischer-Tropsch synthesis reaction and the ratio of the flow rate of the treated naphtha fraction returned to the naphtha fraction hydrotreating step relative to the flow rate of the treated naphtha fraction discharged from the naphtha fraction hydrotreating step, a step of measuring the difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature, and a step of adjusting the reaction temperature of the naphtha fraction hydrotreating step so that the measured difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature becomes substantially equal to the estimated difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature.

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04-10-2012 дата публикации

Apparatus for producing diesel

Номер: US20120251403A1
Принадлежит: UOP LLC

An apparatus is disclosed for hydrocracking hydrocarbon feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The hydrocracking unit and the hydrotreating unit shares the same recycle gas compressor. A warm separator separates recycle gas and hydrocarbons from diesel in the hydrotreating effluent, so fraction of the diesel is relatively simple. The warm separator also keeps the diesel product separate from the more sulfurous diesel in the hydrocracking effluent, and still retains heat needed for fractionation of lighter components from the low sulfur diesel product.

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04-10-2012 дата публикации

Dispersed metal sulfide-based catalysts

Номер: US20120252660A1
Принадлежит: Intevep SA

The invention provides a catalyst composition, which includes an emulsion of an aqueous phase in an oil phase, wherein the aqueous phase comprises an aqueous solution containing a group 6 metal and a group 8, 9 or 10 metal. The metals can be provided in two separate emulsions, and these emulsions are well suited for treating hydrocarbon feedstocks.

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22-11-2012 дата публикации

Oil and polar additive impregnated composition useful in the catalytic hydroprocessing of hydrocarbons, a method of making such catalyst, and a process of using such catalyst

Номер: US20120295786A1
Принадлежит: Shell Oil Co

A composition that comprises a support material having incorporated therein a metal component and impregnated with both hydrocarbon oil and a polar additive. The composition that is impregnated with both hydrocarbon oil and polar additive is useful in the hydrotreating of hydrocarbon feedstocks, and it is especially useful in applications involving delayed feed introduction whereby the composition is first treated with hot hydrogen, and, optionally, with a sulfur compound, prior to contacting it with a hydrocarbon feedstock under hydrodesulfurization process conditions.

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13-12-2012 дата публикации

Apparatus and method for hydroconversion

Номер: US20120315202A1
Принадлежит: Chevron Corp

An apparatus is disclosed for the hydroconversion of hydrocarbon feedstock with a hydrogen gas at elevated temperature and pressure with the use of a catalyst. The apparatus is a reactor vessel with a grid plate distributor for improved gas liquid distribution. The distributor comprises a grid plate and a bubble cap assembly with a plurality of tubular risers extending through the grid plate. Each tubular riser has an upper section above the grid plate and a lower section below the grid plate, the lower section terminated with an open bottom end for ingress of the hydrogen gas and hydrocarbon feedstock, the upper section having a closed top terminated with a housing cap. Each tubular riser has at least a vertical slot and a least a side hole sufficiently sized such that in operation, the liquid level in the zone below the grid plate is above the vertical slot and below the side hole opening.

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14-02-2013 дата публикации

Olefin Hydration Process with an Integrated Membrane Reactor

Номер: US20130041186A1
Принадлежит: Saudi Arabian Oil Co

An olefin hydration process and reactor are provided, wherein an integrated membrane selectively removes alcohol product from the reactor, thereby allowing for increased yields.

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07-03-2013 дата публикации

Catalytical hydrodesulfurization of kerosene in two steps on cobalt-molybdenum catalyst and intermediate stripping

Номер: US20130056391A1
Принадлежит: Indian Oil Corp Ltd

A process for selective removal of mercaptan from aviation turbine fuel feed includes mixing aviation turbine fuel feed with hydrogen, at a pressure in a range from 3 bar to 20 bar to obtain a reaction mixture. The reaction mixture is heated at a temperature range of 150° C. to 350° C. to obtain a heated mixture. The heated mixture is reacted with a hydrotreating catalyst in a rector to obtain a reactor effluent, and H 2 S gas is stripped from the reactor effluent to obtain a stripper bottom product. Moisture is removed from the stripper bottom product to obtain aviation turbine fuel product having less than 10 ppm mercaptan. The aviation fuel product has improved properties such as color and acidity. Embodiments also relate to an aviation turbine fuel product having less than 10 ppm mercaptan prepared by the described process of the present invention.

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14-03-2013 дата публикации

Hydrotreating of Aromatic-Extracted Hydrocarbon Streams

Номер: US20130062255A1
Автор: Omer Refa Koseoglu
Принадлежит: Saudi Arabian Oil Co

Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by first subjecting the entire feed to an extraction zone to separate an aromatic-rich fraction containing a substantial amount of the aromatic refractory and sterically hindered sulfur-containing compounds and an aromatic-lean fraction containing a substantial amount of the labile sulfur-containing compounds. The aromatic-rich fraction is contacted with isomerization catalyst, and the isomerized aromatic-rich fraction and the aromatic-lean fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level.

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14-03-2013 дата публикации

Integrated Isomerization and Hydrotreating Process

Номер: US20130062257A1
Автор: Omer Refa Koseoglu
Принадлежит: Saudi Arabian Oil Co

Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A low boiling temperature fraction contains refractory, sterically hindered sulfur-containing compounds, which have a boiling point at or above the target cut point temperature. A high boiling temperature fraction, having a boiling point below the target cut point temperature, is substantially free of refractory sulfur-containing compounds. The high boiling temperature fraction is contacted with isomerization catalyst, and the isomerized effluent and the low boiling temperature fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level.

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21-03-2013 дата публикации

HYDROCONVERSION MULTI-METALLIC CATALYST AND METHOD FOR MAKING THEREOF

Номер: US20130068662A1
Принадлежит:

A method for hydroprocessing a hydrocarbon feedstock is provided. The method comprises contacting the feedstock with a catalyst under hydroprocessing conditions, wherein the catalyst is formed by sulfiding an unsupported catalyst precursor of the general formula A[(M)(OH)(L)](MO), wherein Mis selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof; L is one or more oxygen-containing ligands, and L has a neutral or negative charge n<=0, Mis at least a Group VIB metal having an oxidation state of +6; M: Mhas an atomic ratio between 100:1 and 1:100; v−2+P*z−x*z+n*y*z=0; and 0≦y≦−P/n; 0≦x≦P; 0≦v≦2; 0≦z. In one embodiment, the catalyst precursor further comprises a cellulose-containing material. In another embodiment, the catalyst precursor further comprises at least a diluent (binder). In one embodiment, the diluent is a magnesium aluminosilicate clay. 1. A process for hydroprocessing a hydrocarbon feedstock which comprises contacting the hydrocarbon feedstock with a catalyst under hydroprocessing conditions ,{'sub': v', 'x', 'y', 'Z', '4, 'sup': P', 'n', 'VIB, 'wherein the catalyst is formed by sulfiding an unsupported catalyst precursor composition having a formula A[(M) (OH)(L)](MO),'}whereinA is at least one of an alkali metal cation, an ammonium, an organic ammonium and a phosphonium cation,{'sup': P', 'P', 'P, 'Mis selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, P is oxidation state with Mhaving an oxidation state of either +2 or +4 depending on the selection of M,'}L is at least one organic oxygen-containing ligand,{'sup': 'VIB', 'Mis at least a Group VIB metal, having an oxidation state of +6,'}{'sup': P', 'VIB, 'M: Mhas an atomic ratio of 100:1 to 1:100,'}v−2+P*z−x*z+n*y*z=0; and0 Подробнее

21-03-2013 дата публикации

PROCESS FOR THE CONVERSION OF RENEWABLE OILS TO LIQUID TRANSPORTATION FUELS

Номер: US20130072731A1

The present invention relates to production of fuels or fuel blendstocks from renewable sources. Various embodiments provide a method of producing a hydrocarbon product by hydrotreating a feedstock including at least one of a renewable triacylglyceride (TAG), renewable free fatty acid (FFA), and renewable fatty acid C-Calkyl ester (C-CFAE) in the presence of a nonsulfided hydrotreating catalyst to produce a first product including hydrocarbons. In some examples, the first product can be subjected to further chemical transformations such as aromatization, cracking, or isomerization to produce a second product including hydrocarbons. In various embodiments, the first or second hydrocarbon product with minimal or substantially no further processing can be suitable as a liquid transportation fuel or fuel blendstock, including fuels such as gasoline, naptha, kerosene, jet fuel, and diesel fuels. 1. A method of producing a hydrocarbon product , the method comprising:{'sub': 1', '5', '1', '5', '1', '5', '1', '5, 'hydrotreating a feedstock comprising at least one of a renewable triacylglyceride (TAG), renewable fatty acid, renewable fatty acid C-Calkyl ester (C-CFAE), and a mixture thereof, in the presence of a nonsulfided hydrotreating catalyst, to produce a first product comprising hydrocarbons and optionally to produce unconverted starting material comprising the at least one of the renewable triacylglyceride (TAG), the renewable fatty acid, the renewable fatty acid C-Calkyl ester (C-CFAE), and the mixture thereof;'}{'sub': 1', '5, 'wherein the renewable TAG, renewable FFA, and renewable C-CFAE comprise fatty acid units that have an even number of carbon atoms;'}wherein in the first product, a proportion of at least one of hydrocarbons with an odd-number of carbon atoms, cyclic hydrocarbons, and hydrocarbons with an even-number of carbon atoms, is dependent on the temperature used during the hydrotreating.2. The method of claim 1 , wherein greater than 90 mol % of the ...

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28-03-2013 дата публикации

PROCESS FOR HYDROCONVERSION OF PETROLEUM FEEDSTOCKS VIA A SLURRY TECHNOLOGY ALLOWING THE RECOVERY OF METALS FROM THE CATALYST AND FROM THE FEEDSTOCK USING A COKING STEP

Номер: US20130075303A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for hydroconversion of heavy petroleum feedstocks comprising a hydroconversion step of the feedstock in at least one reactor containing a slurry catalyst and allowing the recovery of metals in the unconverted residual fraction, in particular those used as catalysts, The process comprises a hydroconversion step, a gas/liquid separation step, a coking step, a combustion step, a metals extraction step and a step of preparing catalytic solutions which are recycled to the hydroconversion step. 1. Process for hydroconversion of heavy petroleum feedstocks containing metals comprising:a) a step of hydroconversion of the feedstock in at least one reactor containing a slurry catalyst containing at least one metal, and optionally a solid additive,b) a step of separation of the hydroconversion effluent without decompression into a so-called light fraction containing the compounds boiling at a maximum temperature of 500° C. and a residual fraction,b′) optionally a fractionation step comprising a separation under vacuum of said residual fraction as obtained in step b), and a vacuum residue with a high concentration of metals is obtained,c) a step of coking of said residual fraction as obtained in step b) and/or of said vacuum residue as obtained in step b′) making it possible to obtain a solid effluent containing coke,d) a step of combustion of said solid effluent containing coke at a temperature comprised between 200 and 700° C. making it possible to obtain ashes with a high concentration of metals,e) a step of extraction of the metals from the ashes obtained in the combustion step,f) a step of preparation of metallic solution(s) containing at least the metal of the catalyst which is/are recycled(s) as catalyst in the hydroconversion step.2. Process according to in which said so-called light fraction originating from the separation step without decompression is subjected to at least one hydrotreatment and/or hydrocracking step.3. Process according to claim 1 , in which ...

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28-03-2013 дата публикации

Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker

Номер: US20130075304A1
Автор: Yu-Hwa Chang
Принадлежит: Individual

Methods and systems for hydrocracking a heavy oil feedstock include using a colloidal or molecular catalyst (e.g., molybdenum sulfide) and provide for concentration of the colloidal or molecular catalyst within the lower quality materials requiring additional hydrocracking in one or more downstream reactors. In addition to increased catalyst concentration, the inventive systems and methods provide increased reactor throughput, increased reaction rate, and of course higher conversion of asphaltenes and lower quality materials. Increased conversion levels of asphaltenes and lower quality materials also reduces equipment fouling, enables the reactor to process a wider range of lower quality feedstocks, and can lead to more efficient use of a supported catalyst if used in combination with the colloidal or molecular catalyst.

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28-03-2013 дата публикации

Device for Conditioning Process Gases for the Heat Treatment of Metallic Work Pieces in Industrial Furnaces

Номер: US20130078152A1
Принадлежит: IPSEN, INC.

In a device for preparing process gases () for heat treatments of metallic materials/workpieces, the respective process gas () is to be fed into at least one treatment chamber () in an industrial furnace () having been practically fully prepared, homogenised and heated, and the method is to be carried out both with newly built and particularly with already existing installations of industrial furnaces () with the aid of the device, wherein the process gas () is prepared with compression at temperatures uncoupled from the temperature in the treatment chamber (), in a process separate from the heat treatment process in the treatment chamber (), and in a temperature range up to about 1250° C., and is rendered usable for economical and low-emission heat treatment (FIG. ). 1. A device for carrying out a method for preparing process gases , including{'b': 2', '2', '2', '2', '1', '2', '2', '2', '3, 'a) a closable preparation chamber (.) with catalyst (..) and temperature adjustment device (..) for preparing the process gases (),'}{'b': 1', '4', '2', '3, 'b) a functionally integrated process gas compressor (., .),'}{'b': 2', '4', '3', '1', '3', '2', '3', '1', '1', '2', '2', '1', '4', '2', '3, 'c) equipment (.) for measuring the inflow of treatment media (., .) of the process gas (), the equipment being connected functionally to the treatment chamber (.) of the industrial furnace, to the preparation chamber (.), and to the process gas compressor (., .),'}{'b': 2', '5', '2', '2', '3', '1', '3', '2', '3', '1', '1', '1', '3', '1', '3', '2, 'd) a switching unit (.) for controlling and adjusting at least one of the parameters of the process gas to be prepared in preparation chamber (.) for the purpose of feeding the treatment media (., .), feeding the prepared process gas () into treatment chamber (.) of the industrial furnace (), and the C level, as well as extracting at least one of the treatment media (., .).'}2. The device as recited in claim 1 , characterized by{'b': 2', '2 ...

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28-03-2013 дата публикации

CATALYST AND METHOD OF CATALYST MANUFACTURE

Номер: US20130079568A1
Принадлежит: JOHNSON MATTHEY PLC

The catalyst of the invention is a particulate catalyst in the form of particles having a minimum dimension of at least 0.8 mm, including a transition metal or a compound thereof dispersed on a porous support material, characterised in that said catalyst particles comprise at least 35% w/w total transition metal; and the transition metal surface area of said catalyst is at least 110 mper gram of transition metal and the tapped bulk density of a bed of the catalyst particles is at least 0.7 g/ml. The method of making a catalyst includes multiple steps of impregnation of a porous support with a metal ammine solution followed by drying, calcination and reduction of the dried material. The catalyst is useful in hydrogenation reactions. 1. A particulate catalyst in the form of particles having a minimum dimension of at least 0.8 mm , comprising a transition metal or a compound thereof dispersed on a porous support material , wherein said catalyst particles comprise at least 35% w/w total transition metal; and the transition metal surface area of said catalyst is at least 110 mper gram of transition metal and the tapped bulk density of a bed of the catalyst particles is at least 0.7 g/ml.2. A catalyst according to claim 1 , n wherein the porous support comprises a transition alumina.3. A catalyst according to claim 1 , wherein the porous support material has a bimodal pore size distribution.4. A catalyst according to claim 3 , wherein the porous support material has a pore size distribution claim 3 , as measured by mercury porosimetry claim 3 , in which at least 20% of the total pore volume is contained in pores having a diameter of from 100 nm-700 nm and at least 30% of the total pore volume is contained in pores having a diameter of from 5 nm-20 nm5. A catalyst according to claim 1 , wherein the porous support material has a pore volume of at least 1.0 ml/g.6. A catalyst according to claim 1 , wherein the porous support is in the form of extruded cylinders or lobed ...

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04-04-2013 дата публикации

Method for the hydroconversion of oil feedstocks using slurry technology, allowing the recovery of metals from the catalyst and the feedstock, comprising an extraction step

Номер: US20130081976A1
Принадлежит: IFP Energies Nouvelles IFPEN

A process for the hydroconversion of heavy oil feedstocks comprises a step for hydroconversion of the feedstock in at least one reactor containing a catalyst in slurry mode used to recover metals from the residual unconverted fraction, especially those used as catalysts. The process comprises a hydroconversion step, a gas/liquid separation step, at least one liquid/liquid extraction step, a combustion step, a metals extraction step and a step for the preparation of catalytic solutions which are recycled to the hydroconversion step.

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04-04-2013 дата публикации

HYDROPROCESSING OF HEAVY HYDROCARBON FEEDS USING SMALL PORE CATALYSTS

Номер: US20130081977A1

Heavy oil feeds are hydroprocessed in the presence of a solvent and in the presence of a catalyst with a median pore size of about 85 Å to about 120 Å under conditions that provide a variety of benefits. The solvent can be an added solvent or a portion of the liquid effluent from hydroprocessing. The processes allow for lower pressure processing of heavy oil feeds for extended processing times or extended catalyst lifetimes be reducing or mitigating the amount of coke formation on the hydroprocessing catalyst. 1. A process for producing a hydroprocessed product , comprising:{'sup': '−1', 'exposing a combined feedstock comprising a heavy oil feed component and a solvent component to a hydroprocessing catalyst comprising a Group VIII non-noble metal and a Group VI metal and having a median pore size of about 85 Å to about 120 Å, under effective hydroprocessing conditions to form a hydroprocessed effluent, the effective hydroprocessing conditions including a total pressure of about 1500 psig (10.3 MPag) or less, a temperature of at least about 360° C., and a liquid hourly space velocity of the fraction of the combined feedstock boiling above 1050° F. (566° C.) of at least about 0.10 hr;'}separating the hydroprocessing effluent to form at least a liquid effluent; andfractionating a first portion of the liquid effluent to form at least a distillate product and a bottoms product, the bottoms product having an ASTM D86 distillation point of at least about 600° F. (316° C.)2. The process of claim 1 , wherein the hydroprocessing catalyst is a bulk catalyst claim 1 , the hydroprocessing catalyst having a median pore size of about 85 Å to about 100 Å.3. The process of claim 1 , wherein the solvent component comprises a recycle component claim 1 , the process further comprising recycling a second portion of the liquid effluent to form the recycle component.4. The process of claim 3 , wherein the ratio of the recycle component to the heavy oil feed component on a weight basis is ...

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04-04-2013 дата публикации

USE OF LOW BOILING POINT AROMATIC SOLVENT IN HYDROPROCESSING HEAVY HYDROCARBONS

Номер: US20130081978A1

This invention is directed to a process for producing a hydroprocessed product. The invention is particularly advantageous in that substantially less hydrogen is absorbed during the process relative to conventional hydroprocessing methods. This benefit is achieved by using a particular solvent as a co-feed component. In particular, the solvent component contains at least one single ring aromatic compound and has a relatively low boiling point range compared to the heavy hydrocarbon oil component used as another co-feed component. 1. A process for producing a hydroprocessed product , comprising:sending to a hydroprocessing zone a combined feed comprised of a heavy hydrocarbon oil component, wherein the heavy hydrocarbon oil component has a ASTM D86 10% distillation point of at least 650° F. (343° C.), and a solvent component containing at least one single ring aromatic compound in which the solvent has an ASTM D86 10% distillation point of at least 120° C. (248° F.) and a 90% distillation point of not greater than 300° C. (572° F.); andcontacting the combined feed with a hydroprocessing catalyst in the presence of hydrogen in the hydroprocessing zone to form a hydroprocessed product.2. The process of claim 1 , wherein the heavy hydrocarbon oil component has an initial ASTM D86 boiling point of at least 650° F. (343° C.).3. The process of claim 1 , wherein the heavy hydrocarbon oil component has an ASTM D86 10% distillation point of at least 750° F. (399° C.).4. The process of claim 1 , wherein the heavy hydrocarbon oil component contains at least 0.0001 grams of Ni/V/Fe claim 1 , on a total elemental basis of nickel claim 1 , vanadium and iron.5. The process of claim 1 , wherein the heavy hydrocarbon oil component contains at least 50 wppm elemental nitrogen claim 1 , based on total weight of the heavy hydrocarbon oil component.6. The process of claim 5 , wherein the heavy hydrocarbon oil component contains at least 500 wppm elemental sulfur claim 5 , based on total ...

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04-04-2013 дата публикации

USE OF SUPERCRITICAL FLUID IN HYDROPROCESSING HEAVY HYDROCARBONS

Номер: US20130081979A1

This invention is directed to a process for producing a hydroprocessed product. The invention is particularly advantageous in that substantially longer run length can be attained relative to conventional hydroprocessing methods. This benefit is achieved by using a particular solvent as a co-feed component. In particular, the solvent component is comprised of at least one or more supercritical solvent compounds. 1. A process for producing a hydroprocessed product , comprising:sending to a hydroprocessing zone a combined feed comprised of a heavy hydrocarbon oil component, wherein the heavy hydrocarbon oil component has a ASTM D86 10% distillation point of at least 650° F. (343° C.), and a solvent component in which a majority of the solvent is comprised of at least one supercritical hydrocarbon compound having a critical temperature and pressure; andcontacting the combined feed with a hydroprocessing catalyst in the presence of hydrogen at a temperature and pressure above the critical temperature and pressure of the at least one supercritical hydrocarbon compound to form the hydroprocessed product.2. The process of claim 1 , wherein the heavy hydrocarbon oil component has an initial ASTM D86 boiling point of 650° F. (343° C.) or greater.3. The process of claim 1 , wherein the heavy hydrocarbon oil component contains at least 0.0001 grams of Ni/V/Fe claim 1 , on a total elemental basis of nickel claim 1 , vanadium and iron.4. The process of claim 1 , wherein the combined feed is comprised of from 30 wt % to 90 wt % of the heavy hydrocarbon oil component and from 10 wt % to 70 wt % of the solvent component claim 1 , based on total weight of the combined feed.5. The process of claim 1 , wherein the contacting of the combined feed with the hydroprocessing catalyst in the presence of hydrogen is carried out at a hydrogen partial pressure from 550 psig (3792 kPa-g) to 3000 psig (20684 kPa-g).6. The process of claim 1 , wherein the solvent component is comprised of more ...

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11-04-2013 дата публикации

PROCESS FOR THE HYDROCONVERSION OF PETROLEUM FEEDSTOCKS VIA SLURRY TECHNOLOGY ALLOWING THE RECOVERY OF METALS FROM THE CATALYST AND FEEDSTOCK USING A LEACHING STEP

Номер: US20130087481A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for the hydroconversion of heavy oil feedstocks comprises a step for hydroconversion of the feedstock in at least one reactor containing a catalyst in slurry mode used to recover metals from the residual unconverted fraction, especially those used as catalysts. The process comprises a hydroconversion step, a gas/liquid separation step, a liquid/liquid extraction step, a grinding step, a leaching step, a combustion step, a metals extraction step and a step for the preparation of catalytic solutions which are recycled to the hydroconversion step. 1. A process for the hydroconversion of heavy oil feedstocks containing metals , comprising:a. a step for hydroconversion of the feedstock in at least one reactor containing a catalyst in the form of a slurry containing at least one metal, and optionally a solid additive;b. a step for separation of the hydroconversion effluent without decompression into a fraction termed the light fraction containing compounds boiling at 500° C. at most and into a residual fraction;b′. an optional step for fractionation, comprising vacuum separation of said residual fraction as obtained in step b) to obtain a vacuum residue which is concentrated in metals;c. a step for liquid/liquid extraction of said residual fraction as obtained in step b) and/or said vacuum residue as obtained in step b′) using a solvent with a saturated nature in order to obtain a solid extract which is concentrated in metals and a raffinate;d. a step for grinding the solid extract which is concentrated in metals obtained from the liquid/liquid extraction step;e. a step for leaching the ground extract in the presence of water, a solvent with a saturated nature and a surfactant in order to obtain a solid extract and a leachate;f. a step for combustion of said solid extract obtained from the leaching step in the presence of oxygen in order to obtain ash which is concentrated in metals;g. a step for extraction of metals from the ash obtained in the combustion step; ...

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25-04-2013 дата публикации

SYSTEM, APPARATUS AND PROCESS FOR EXTRACTION OF BITUMEN FROM OIL SANDS

Номер: US20130098805A1
Принадлежит: SUNCOR ENERGY, INC.

A separation process and system for extracting hydrocarbons from a mixture. In some embodiments, a process for separating a bitumen froth stream containing bitumen froth, water and fine solids into a bitumen enriched froth stream and a water and fine solids stream, comprises: (a) receiving the bitumen froth stream in a concentrator vessel, (b) distributing the bitumen froth stream in the concentrator vessel as a substantially uniform and generally horizontal flow of the bitumen froth stream at a first flow velocity, (c) slowing the bitumen froth stream to a second flow velocity, slower than the first flow velocity, in a separation region of the concentrator vessel to promote separation of the bitumen froth from the water and fine solids, and then (d) collecting a bitumen enriched froth stream and (e) collecting a separate water and fine solids stream. Related embodiments of systems and apparatus may also be provided. 1. A process for separating a bitumen froth stream containing bitumen froth , water and fine solids into a bitumen enriched froth stream and a water and fine solids stream , the process comprising:receiving the bitumen froth stream in a concentrator vessel;distributing the bitumen froth stream in the concentrator vessel as a substantially uniform and generally horizontal flow of the bitumen froth stream at a first flow velocity;slowing the bitumen froth stream to a second flow velocity, slower than the first flow velocity, in a separation region of the concentrator vessel to promote separation of the bitumen froth from the water and fine solids, the bitumen froth accumulating as a bitumen froth layer atop a water layer with the fine solids settling within the water layer;collecting the bitumen froth layer as the bitumen enriched froth stream; andcollecting the water layer and fine solids as the water and fine solids stream.2. The process of wherein the bitumen froth layer is continuously collected at an overflow outlet while the water layer and fine ...

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25-04-2013 дата публикации

CATALYST, ELECTRODE, FUEL CELL, GAS DETOXIFICATION APPARATUS, AND METHODS FOR PRODUCING CATALYST AND ELECTRODE

Номер: US20130101920A1
Принадлежит: Sumitomo Electric Industries, Ltd.

Provided are a catalyst, an electrode, a fuel cell, a gas detoxification apparatus, and the like that can promote a general electrochemical reaction causing gas decomposition or the like. A catalyst according to the present invention is used for promoting an electrochemical reaction and is chain particles formed of an alloy particles containing nickel (Ni) and at least one selected from the group consisting of iron (Fe), cobalt (Co), chromium (Cr), tungsten (W), and copper (Cu). 1. A catalyst used for promoting an electrochemical reaction , comprising:an alloy containing nickel (Ni) and at least one selected from the group consisting of iron (Fe), cobalt (Co), chromium (Cr), tungsten (W), and copper (Cu).2. The catalyst according to claim 1 , being chain particles in which particles that have a diameter of 0.5 μm or less and are formed of the alloy are connected to form an elongated shape.3. The catalyst according to claim 2 , wherein the chain particles have branches and form dendritic chain particles in which the branched chain particles are intertwined.4. The catalyst according to claim 1 , wherein the alloy contains 0.5% or less by weight of titanium (Ti).5. The catalyst according to claim 1 , being a woven fabric formed of fibers of the alloy or a metal-fiber woven fabric including a plated layer of the alloy.6. The catalyst according to claim 1 , being a porous plated body formed of the alloy or a porous plated body including a plated layer of the alloy.7. The catalyst according to claim 1 , being particles that are formed of the alloy and have an average diameter of 100 μm or less.8. The catalyst according to claim 1 , being present with a solid electrolyte and disposed in a form of a film of the alloy or a deposit of the alloy so as to cover a surface of the solid electrolyte.9. The catalyst according to claim 1 , wherein oxygen is bonded to a surface of the alloy or the alloy is covered with an oxide layer.10. An electrode formed by sintering the catalyst ...

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02-05-2013 дата публикации

Diesel fuel production process employing direct and indirect coal liquefaction

Номер: US20130104611A1
Принадлежит: Accelergy Corp

A combined Direct Coal Liquefaction (DCL)/Fischer Tropsch (F-T) process and system for producing high Cetane diesel fuel by converting at least 70% of the feed coal by DCL operating at 50 to 70% conversion and gasifying the bottoms and between 0 and 30% of the feed coal to produce H2 for supply to the DCL and to upgrading and syngas for being converted to diesel by F-T. Diesel blendstocks produced by the DCL and the F-T in a ratio of 3 to 1 to 14 to 1 are blended to produce diesel fuel having a Cetane Number of at least 50.

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02-05-2013 дата публикации

Self-activating hydroprocessing catalyst and process for treating heavy hydrocarbon feedstocks

Номер: US20130105357A1
Автор: Opinder K. BHAN
Принадлежит: Shell Oil Co

A self activating catalyst for treating heavy hydrocarbon feedstocks that comprises a calcined particle comprising a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound and then forming the co-mulled mixture into a particle that is calcined to thereby provide the calcined particle. The self activating catalyst may be activated when it is contacted under suitable process conditions with a heavy residue feedstock having high nickel, vanadium and sulfur concentrations.

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02-05-2013 дата публикации

Nozzle Reactor Systems and Methods of Use

Номер: US20130105361A1
Принадлежит: MARATHON OIL CANADA CORPORATION

A nozzle reactor system for increasing the conversion rate of material feed injected into the nozzle reactor system. The system includes two or more nozzle reactors aligned in parallel. A main stream of material to be upgraded is divided such that one stream is produced for each nozzle reactor in the system. Each nozzle reactor includes an interior reactor chamber and an injection passage and material feed passage that are each in material injecting communication with the interior reactor chamber. Furthermore, the injection passage is aligned transversely to the injection passage. The injection passage is configured to accelerate cracking material passed therethrough to a supersonic speed. The product produced from each of the nozzle reactors is combined into one product stream. 1. A nozzle reactor system comprising:a stream dividing apparatus comprising a first output port and a second output port;a first nozzle reactor having a feed material injection port in fluid communication with the first output port of the stream dividing apparatus, and an ejection end;a second nozzle reactor having a feed material injection port in fluid communication with the second output port of the stream dividing apparatus, and an ejection end; anda mixing apparatus having a first input port in fluid communication with the ejection end of the first nozzle reactor, and a second input port in fluid communication with the ejection end of the second nozzle reactor.2. The nozzle reactor system as recited in claim 1 , wherein: a reactor body having an interior reactor chamber with an injection end and an ejection end;', 'an injection passage mounted in the nozzle reactor in material injecting communication with the interior reactor chamber, the injection passage having (a) an enlarged volume injection section, an enlarged volume ejection section, and a reduced volume mid-section intermediate the enlarged volume injection section and enlarged volume ejection section, (b) a material injection ...

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23-05-2013 дата публикации

SLURRY BED HYDROPROCESSING AND SYSTEM USING FEEDSTOCK CONTAINING DISSOLVED HYDROGEN

Номер: US20130126392A1
Автор: KOSEOGLU Omer Refa
Принадлежит: Saudi Arabian Oil Company

A system and process for conversion of heavy feedstocks in a slurry bed hydroprocessing reactor is provided in which (a) hydrogen gas is dissolved in the liquid feedstock by mixing and/or diffusion, (b) the mixture is flashed to remove and recover any light components and hydrogen, leaving a hydrogen-enriched feedstock. A homogenous and/or heterogeneous catalyst is added to the feedstock upstream of the inlet of the slurry bed hydroprocessing reactor. 1. A process for converting a liquid hydrocarbon feedstock into lower molecular weight hydrocarbon compounds in a slurry bed reactor , the process comprising:a. mixing the liquid hydrocarbon feedstock and an excess of hydrogen gas in a mixing zone under predetermined conditions of temperature and hydrogen partial pressure to dissolve a portion of the hydrogen gas in the liquid hydrocarbon feedstock to produce a mixture of hydrogen-enriched liquid hydrocarbon feedstock and undissolved hydrogen gas;b. introducing the mixture produced in step (a) into a flashing zone under predetermined conditions to separate undissolved hydrogen gas and light hydrocarbon components and recovering a hydrogen-enriched liquid hydrocarbon feedstock;c. introducing the hydrogen-enriched liquid hydrocarbon feedstock into a reaction zone containing at least one slurry bed reactor with at least one catalyst or catalyst precursor and reacting the feedstock to convert at least a portion of the feedstock into lower boiling point hydrocarbons; andd. recovering converted hydrocarbon products from the slurry bed reactor.2. The process of in which at least a portion of unconverted liquid feedstock is recovered from the slurry bed reactor and is recycled to form a portion of the liquid hydrocarbon feedstock.3. The process of in which the at least one catalyst is selected from a liquid homogeneous catalyst precursor and a small particulate heterogeneous catalyst4. The process of in which fresh catalyst is added to the unconverted feedstock upstream of one ...

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23-05-2013 дата публикации

HIGH SURFACE AREA COMPOSITION FOR USE IN THE CATALYTIC HYDROCONVERSION OF A HEAVY HYDROCARBON FEEDSTOCK, A METHOD MAKING SUCH COMPOSITION AND ITS USE

Номер: US20130126393A1
Принадлежит: SHELL OIL COMPANY

A catalyst composition that is especially useful in the hydroconversion of pitch, micro carbon residue and sulfur contents of a heavy hydrocarbon feedstock without the excessive formation of sediment. The catalyst composition is a reasonably high surface area composition containing alumina and a low molybdenum content with a high ratio of nickel-to-molybdenum. The catalyst composition further has a unique pore distribution that in combination with the special metals loading provide for good conversion of pitch and micro carbon residue without an excessive yield of sediment. 1. A catalyst composition comprising a molybdenum component in an amount of greater than or equal to 5 wt. % and less than 11 wt. % , with the wt. % being based on the total weight of said catalyst composition and assuming said molybdenum component is in the oxide form (MoO) regardless of its actual form , and a nickel component present in an amount such that said catalyst composition has a weight ratio of said nickel component-to-said molybdenum component exceeding 0.25 , with said weight ratio being computed assuming said nickel component and said molybdenum component are each in the oxide form regardless of their actual forms , and wherein said catalyst composition has a total surface area in the range of from 240 m/g to 360 m/g , a total pore volume in the range of from 0.65 cc/g to 1.1 cc/g and a pore size distribution such that from 11% to 30.5% of the total pore volume is present in macropores of diameter greater than or equal to 250 Å.2. A catalyst composition as recited in claim 1 , having a pore size distribution such that from 50% to 80% of the total pore volume of said catalyst composition is present as pores having diameters in the range of from 55 Å to 115 Å claim 1 , and from 16% to 30% of the total pore volume of said catalyst composition is present in macropores of diameter greater than 500 Å.3. A catalyst composition as recited in claim 2 , wherein more than 20% of the total ...

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23-05-2013 дата публикации

SYSTEM AND APPARATUS TO EXTRACT AND REDUCE DISSOLVED HEMI-CELLULOSIC SOLIDS IN BIOMASS FOLLOWING PRE-HYDROLYSIS

Номер: US20130129573A1
Принадлежит: ANDRITZ INC.

A system for washing processed biomass and removing dissolved solids from the biomass including: a pre-hydrolysis reactor vessel having an outlet to discharge a biomass slurry, wherein the pre-hydrolysis reactor vessel is operated at conditions that promote hydrolysis of the biomass; a retention tank receiving the biomass slurry discharged through the outlet of the pre-hydrolysis reactor vessel, wherein the retention tank receives recovered wash liquid and is configured to dilute the biomass slurry in the tank with the recovered wash liquid and discharge diluted biomass slurry, and a drain device including a biomass slurry inlet receiving the discharged diluted biomass slurry from the retention tank, a solids outlet to discharge concentrated biomass slurry, and a liquid drain to discharge liquid extracted from the discharged diluted biomass slurry, wherein the liquid drain is in fluid communication with the retention tank such that the discharged liquid flows to the retention tank. 1. A system for washing processed biomass and removing dissolved solids from the biomass comprising:a pre-hydrolysis reactor vessel having an outlet to discharge a biomass slurry, wherein the pre-hydrolysis reactor vessel is operated at conditions that promote hydrolysis of the biomass;a retention tank receiving the biomass slurry discharged through the outlet of the pre-hydrolysis reactor vessel, wherein the retention tank receives recovered wash liquid and is configured to dilute the biomass slurry in the tank with the recovered wash liquid and discharge diluted biomass slurry; anda drain device including a biomass slurry inlet receiving the discharged diluted biomass slurry from the retention tank, a solids outlet to discharge concentrated biomass slurry, and a liquid drain to discharge liquid extracted from the discharged diluted biomass slurry, wherein the liquid drain is in fluid communication with the retention tank such that the discharged liquid flows to the retention tank.2. The ...

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23-05-2013 дата публикации

ACTIVATION OF DUAL CATALYST SYSTEMS

Номер: US20130130893A1

Methods are provided for liquid phase activation of dewaxing and/or hydrofinishing catalysts that include a molecular sieve or other acidic crystalline support. The methods are compatible with activating the catalysts as part of a catalyst system that also includes a hydrotreating catalyst. 1. A method for activating a catalyst system , comprising:exposing a catalyst system to a first liquid activation feed under effective reducing conditions for at least about 24 hours, the catalyst system including at least one catalyst that comprises a Group VIII non-noble metal on an amorphous support and at least one catalyst that comprises a Group VIII noble metal on an acidic support, the effective reducing conditions including a hydrogen partial pressure of at least about 500 psig (145 MPag) and a temperature of at least about 200° C.; andexposing the catalyst system to a second liquid activation feed under effective sulfiding conditions.2. The method of claim 1 , wherein the catalyst with an amorphous support is a hydrotreating catalyst.3. The method of claim 1 , wherein the catalyst comprising a Group VIII noble metal on an acidic support comprises a dewaxing catalyst with Pt claim 1 , Pd claim 1 , or a combination thereof on a support including a molecular sieve.4. The method of claim 1 , wherein the catalyst comprising a Group VIII noble metal on an acidic support comprises a hydrofinishing catalyst with Pt claim 1 , Pd claim 1 , or a combination thereof on a support comprising an M41S family support.5. The method of claim 1 , wherein the catalyst system is provided in a single reactor.6. The method of claim 1 , wherein first liquid activation feed comprises a distillate boiling range feed with a sulfur content of less than about 100 wppm and a water content of less than about 100 wppm.7. The method of claim 6 , wherein first liquid activation feed has a nitrogen content of less than about 250 wppm.8. The method of claim 1 , wherein the second liquid activation feed ...

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06-06-2013 дата публикации

Process for producing hydrocarbon oil and system for producing hydrocarbon oil

Номер: US20130143971A1

Hydrocarbon oil obtained by Fischer-Tropsch synthesis reaction using a slurry bed reactor holding a slurry of a liquid hydrocarbon in which a catalyst is suspended; the hydrocarbon oil is fractionated into a distilled oil and a column bottom oil containing the catalyst fine powder by a rectifying column; at least part of the column bottom oil is transferred to a storage tank, and the catalyst fine powder is sedimented to the bottom of the storage tank to capture the catalyst fine powder; a residue of the column bottom oil is transferred from the rectifying column to a hydrocracker, and/or the supernatant of the column bottom oil from which the catalyst fine powder is captured by the storage tank is transferred from the storage tank to the hydrocracker; and using the hydrocracker, the residue of the column bottom oil and/or the supernatant of the column bottom oil is hydrocracked.

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06-06-2013 дата публикации

PROFITABLE METHOD FOR CARBON CAPTURE AND STORAGE

Номер: US20130144093A1
Автор: Abhari Ramin
Принадлежит:

The present invention generally relates to a method for sequestering carbon dioxide. Biomass is converted into paraffinic hydrocarbons. The paraffinic hydrocarbons are steam cracked into olefins. The olefins are polymerized into non-biodegradable polyolefins. 1. A method comprising steam cracking paraffinic hydrocarbons into olefins , wherein the paraffinic hydrocarbons are derived from a biomass.2. The method of claim 1 , wherein the paraffinic hydrocarbons are produced by gasification followed by Fischer-Tropsch conversion3. The method of claim 2 , wherein the biomass is wood chips.4. The method of claim 1 , wherein the paraffinic hydrocarbons are produced by the hydrotreating of fatty acids and/or fatty acid esters.5. The method of claim 4 , wherein the fatty acids and/or fatty acid esters are oils from plants.6. The method of claim 4 , wherein the fatty acids and/or fatty acid esters are fats from animals.7. The method of claim 4 , wherein the fatty acids and/or fatty acid esters are oils from algae.8. The method of claim 7 , wherein the algae are grown in ponds and/or photo-bioreactors with COsupplied from stationary emission sources.9. The method of claim 8 , wherein the stationary emission source is a coal-fired power plant.10. The method of claim 1 , wherein the olefins comprise ethylene claim 1 , propylene claim 1 , butenes claim 1 , and butadiene.11. The method of claim 1 , wherein bio-derived hydrogen is produced as byproduct of steam cracking.12. The method of claim 1 , wherein bio-derived pyrolysis gasoline is produced as byproduct of steam cracking.13. The method of claim 12 , wherein the pyrolysis gasoline is used as motor gasoline blend stock.14. The method of claim 13 , wherein the pyrolysis gasoline is hydrogenated prior to use as motor gasoline.15. The method of claim 1 , wherein bio-derived fuel gas is produced as byproduct of steam cracking.16. The method of claim 1 , wherein the pyrolysis fuel oil yield is less than 1 wt % of the paraffinic ...

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13-06-2013 дата публикации

METHODS AND UNITS FOR MITIGATION OF CARBON OXIDES DURING HYDROTREATING

Номер: US20130149210A1
Принадлежит: BP CORPORATION NORTH AMERICA INC.

This invention relates to methods and units for mitigation of carbon oxides during hydrotreating hydrocarbons including mineral oil based streams and biological oil based streams. A hydrotreating unit includes a first hydrotreating reactor for receiving a mineral oil based hydrocarbon stream and forming a first hydrotreated product stream, and a second hydrotreating reactor for receiving a biological oil based hydrocarbon stream and forming a second hydrotreated product stream. 1. (canceled)2. (canceled)3. (canceled)4. (canceled)5. (canceled)6. (canceled)7. (canceled)8. (canceled)9. A hydrotreating unit for processing mineral oil based hydrocarbon streams , biological oil based hydrocarbon streams , and combinations thereof , the unit comprising:a first hydrotreating reactor for receiving a mineral oil based hydrocarbon stream and forming a first hydrotreated product stream; anda second hydrotreating reactor for receiving a biological oil based hydrocarbon stream and forming a second hydrotreated product stream.10. The unit of claim 9 , wherein a common hydrogen stream supplies both the first hydrotreating reactor and the second hydrotreating reactor claim 9 , and the hydrogen stream comprises make-up hydrogen and recycle hydrogen.11. The unit of claim 9 , wherein a make-up hydrogen stream connects to the second hydrotreating reactor and a recycle hydrogen stream connects to the first hydrotreating reactor.12. The unit of claim 9 , wherein a make-up hydrogen stream connects to the first hydrotreating reactor and a recycle hydrogen stream connects to the second hydrotreating reactor.13. The unit of claim 9 , wherein the first hydrotreating reactor comprises a cobalt and molybdenum catalyst claim 9 , and the second hydrotreating reactor comprises a nickel and molybdenum catalyst.14. The unit of claim 9 , further comprising a carbon dioxide removal system on a hydrogen recycle stream.15. A hydrotreating unit for processing mineral oil based hydrocarbon streams claim 9 ...

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20-06-2013 дата публикации

Methods for deoxygenating biomass-derived pyrolysis oil

Номер: US20130152454A1
Принадлежит: UOP LLC

Methods for deoxygenating a biomass-derived pyrolysis oil are provided. In an embodiment, a method for deoxygenating a biomass-derived pyrolysis oil comprises the steps of combining a biomass-derived pyrolysis oil stream with a heated low-oxygen-pyoil diluent recycle stream to form a heated diluted pyoil feed stream. The heated diluted pyoil feed stream has a feed temperature of about 150° C. or greater. The heated diluted pyoil feed stream is contacted with a first deoxygenating catalyst in the presence of hydrogen at first hydroprocessing conditions effective to form a low-oxygen biomass-derived pyrolysis oil effluent.

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27-06-2013 дата публикации

Production Apparatus of Composite Silver Nanoparticle

Номер: US20130164187A1
Автор: Komatsu Teruo

A production apparatus of composite silver nanoparticle including: a device for arranging a silver salt microparticle and at least an alcohol solvent selected from alcohols having a carbon number of 1 to 12; a raw material mixer for preparing an alcohol solution by mixing the silver salt microparticle into the alcohol solvent added more excessively than the mol number of the silver salt microparticle to make an excess alcohol solution; a reactor for generating a composite silver nanoparticle by heating the excess alcohol solution at a generation temperature PT generating an aldehyde for a generation time with a heater, in which a silver core is formed by reducing the silver salt microparticle by the alcohol solvent and/or the aldehyde and the composite silver nanoparticle having an organic coating layer originated from the alcohol solvent around the silver core is formed, and a chiller for cooling the alcohol solution 123-. (canceled)24. A production apparatus of composite silver nanoparticle comprisinga means for arranging a silver salt microparticle and at least an alcohol solvent selected from alcohols with a carbon number of 1 to 12 composed of methanol, ethanol, propanol, buthanol, pentanol, hexanol, heptanol, othanol, nonanol, decanol, undecanol and dodecanol,a raw material mixer for preparing an alcohol solution by mixing of said silver salt microparticle into said alcohol solvent added more excessively than the mol number of said silver salt microparticle so as to become an excess alcohol solution,a reactor for generating a composite silver nanoparticle by heating said excess alcohol solution at a generation temperature PT generating an aldehyde for a generation time with a heater, in which a silver core is formed through reducing of said silver salt microparticle by said alcohol solvent and/or said aldehyde and said composite silver nanoparticle having an organic coating layer originated from said alcohol solvent around said silver core is formed, anda ...

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27-06-2013 дата публикации

PROCESS FOR THE PREPARATION OF A CATALYST WHICH CAN BE USED IN HYDROTREATMENT AND HYDROCONVERSION

Номер: US20130165316A1
Принадлежит:

A process for the preparation of a catalyst from a catalytic precursor comprising a support based on alumina and/or silica-alumina and/or zeolite and comprising at least one element of group VIB and optionally at least one element of group VIII, by impregnation of said precursor with a solution of a C1-C4 dialkyl succinate. An impregnation step for impregnation of said precursor which is dried, calcined or regenerated, with at least one solution containing at least one carboxylic acid other than acetic acid, then maturing and drying at a temperature less than or equal to 200° C., optionally a heat treatment at a temperature lower than 350° C., followed by an impregnation step with a solution containing at least one C1-C4 dialkyl succinate followed by maturing and drying at a temperature less than 200° C. without subsequent calcination step. The catalyst is used in hydrotreatment and/or hydroconversion. 2. A process according to characterised in that the catalytic precursor is a catalyst which has been regenerated.3. A process according to characterised in that that the catalytic precursor contains all of the elements of groups GVIB and if they are present all of the elements of group V111.4. A process according to characterised in that the dialkyl succinate is dimethyl succinate.5. A process according to characterised in that the carboxylic acid is citric acid.6. A process according to characterised in that steps 1) and/or 2) are performed in the presence of water and/or ethanol.7. A process according to characterised in that the maturing steps are performed at a temperature between 17 and 60° C.8. A process according to characterised in that the drying operation in step 1) is performed at a temperature between 100 and 180° C.9. A process according to characterised in that the drying operation in step 2) is performed at a temperature between 50 and 160° C.10. A process according to characterised in that the solution of step 1) and/or step 2) contains at least one ...

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27-06-2013 дата публикации

Catalytic refining of terpenes of pulp origin

Номер: US20130165721A1
Принадлежит: STORA ENSO OYJ

Biobased p-cymene and methods of producing same, which can further be converted to terephtalate. Further, a method is described for converting crude sulfate turpentine recovered from chemical wood pulping into p-cymene and eventually to terephtalic acid of biological origin, and and products thereof respectively. In said method, both conversion and desulfurization is realized in one reaction step. The disclosure is also related to use of zeolite catalysts in said method.

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27-06-2013 дата публикации

Process for conversion of paraffinic feedstocks obtained from the biomass of middle distillate bases employing at least one izm-2 zeolite-based catalyst

Номер: US20130165730A1
Принадлежит: IFP Energies Nouvelles IFPEN

The invention relates to a process for conversion of a paraffinic feedstock that has a number of carbon atoms of between 9 and 25, whereby said paraffinic feedstock is produced starting from renewable resources, employing a catalyst that comprises at least one hydrogenating-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table, taken by themselves or in a mixture, and a substrate that comprises at least one IZM-2 zeolite and at least one binder, with said process being carried out at a temperature of between 150 and 500° C., at a pressure of between 0.1 MPa and 15 MPa, at an hourly volumetric flow rate of between 0.1 and 10 h −1 , and in the presence of a total quantity of hydrogen mixed with the feedstock such that the hydrogen/feedstock ratio is between 70 and 2,000 Nm 3 /m 3 of feedstock.

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04-07-2013 дата публикации

PROCESS FOR THE HYDRODESULPHURIZATION OF A GASOLINE CUT IN THE PRESENCE OF A SUPPORTED SULPHIDE CATALYST PREPARED USING AT LEAST ONE CYCLIC OLIGOSACCHARIDE

Номер: US20130168292A1
Принадлежит: IFP ENERGIES NOUVELLES

Hydrodesulphurization of a gasoline cut containing hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting the gasoline cut with at least one catalyst having an active phase of at least one metal from group VIII and at least one metal from group VIB deposited on a support, said catalyst being prepared using a process of: 1. A process for the hydrodesulphurization of a gasoline cut containing hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less , said process consisting of bringing said gasoline cut into contact with at least one catalyst the active phase of which comprises at least one metal from group VIII and at least one metal from group VIB deposited on a support formed from at least one oxide , said catalyst being prepared using a process comprising at least:i) at least one step for bringing at least said support into contact with at least one solution containing at least one precursor of at least said metal from group VIII and at least one precursor of at least said metal from group VIB;ii) at least one step for bringing at least said support into contact with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits;iii) at least one drying step to obtain at least said metal from group VIII and at least said metal from group VIB in the oxide form; then 'the steps i) and ii) possibly being carried out separately, in any order, or simultaneously.', 'iv) at least one sulphurization step such that said active phase is in the sulphide form;'}2. A hydrodesulphurization process according to claim 1 , in which said gasoline cut originates from a fluid catalytic cracking unit.3. A hydrodesulphurization process according to claim 1 , in which said gasoline cut has a sulphur content in the range 200 to 5000 ppm by weight.4. A hydrodesulphurization process according to claim 1 , ...

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04-07-2013 дата публикации

Reaction device for producing hydrocarbons from synthesis gas

Номер: US20130171040A1

Disclosed is a reaction device for producing hydrocarbons from synthesis gas, in which hydrocarbons, olefins, oxygenates, etc., are produced over a Fischer-Tropsch catalyst by using synthesis gas, so that catalyst particles can easily be from a slurry which is discharged to the outside. That is, the present invention provides a reaction device for producing hydrocarbons from synthesis gas, in which an internal filter system for separating particles enlarged due to a agglomeration phenomenon of a catalyst is installed inside the reactor, and an separating device is separately disposed outside, such that it is possible to recirculate only particles having a size appropriate for performing F-T synthesis in the slurry phase, and additionally, it is possible to effectively discharge and process a catalyst aggregated due to a combination of fine catalyst particles, the catalyst chipped off during the operation, etc., liquid hydrocarbon, resulting water, etc., in the slurry phase reactor.

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11-07-2013 дата публикации

FLAKES MANAGEMENT IN HYDROCARBON PROCESSING UNITS

Номер: US20130175157A1
Принадлежит: TOTAL RAFFINAGE MARKETING

The instant invention discloses a method for the improvement of flakes recovery from hydrocarbon processing units and in particular slurry reactors as well as slurry flakes obtained thereof. 1. A method for the separation of solids contained in a solid containing treated hydrocarbon feedstock issued from an industrial unit , wherein an ultimate reactor is fed with an ultimate catalyst , an ultimate hydrocarbon feedstock and an ultimate hydrogen containing gas , and wherein after reaction , the resulting ultimate treated hydrocarbon feedstock undergoes a liquid-solid filtration before a final fractionation is performed.2. A method according claim 1 , wherein claim 1 , before reaction and before filtration claim 1 , a penultimate hydrocarbon feedstock undergoes a penultimate treatment in a penultimate reactor fed with a penultimate catalyst and/or the ultimate catalyst claim 1 , and a penultimate hydrogen containing gas claim 1 , to obtain the ultimate hydrocarbon feedstock.3. A method according to claim 1 , wherein the final fractionation is a vacuum fractionation.4. A method according to claim 1 , wherein the final fractionation is a combination of an atmospheric fractionation followed by a vacuum fractionation.5. A method according to claim 1 , wherein the resulting ultimate treated hydrocarbon feedstock undergoes flash separation to remove gaseous species before liquid-solid filtration.6. A method according to claim 1 , wherein the industrial unit is a slurry plant.7. A method according to claim 1 , wherein filtration allows separating the catalyst from the remaining solid residues contained in the ultimate treated hydrocarbon feedstock.8. A method according to claim 7 , wherein filtration is performed with at least two filters having different porosities so as to discriminate the catalyst from the remaining solid residues.9. A method according to claim 7 , wherein the catalyst is recycled.10. A method according to claim 7 , wherein the catalyst is reused.11. A ...

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11-07-2013 дата публикации

HYDROCRACKING CATALYST FOR HYDROCARBON OIL, METHOD FOR PRODUCING HYDROCRACKING CATALYST, AND METHOD FOR HYDROCRACKING HYDROCARBON OIL WITH HYDROCRACKING CATALYST

Номер: US20130175202A1
Принадлежит:

The present invention relates to a hydrocracking catalyst for hydrocarbon oil comprising a support containing a framework-substituted zeolite-1 in which zirconium atoms and/or hafnium atoms form a part of a framework of an ultrastable y-type zeolite and a hydrogenative metal component carried thereon and a method for producing the same. The hydrocracking catalyst of the present invention makes it easy to diffuse heavy hydrocarbon oils such as VGO, DAO and the like into mesopores, is improved in a cracking activity and makes it possible to obtain a middle distillate at a high yield as compared with catalysts prepared by using zeolite comprising titanium and/or zirconium carried thereon. 1. A hydrocracking catalyst for hydrocarbon oil comprising a hydrogenative metal component carried on a support containing an ultra-stable Y-type zeolite , wherein the above ultra-stable Y-type zeolite is a framework-substituted zeolite (hereinafter referred to as a framework-substituted zeolite-1) in which a part of aluminum atoms constituting a zeolite framework thereof is substituted with zirconium atoms and/or hafnium atoms.2. A hydrocracking catalyst for hydrocarbon oil according to claim 1 , wherein said zeolite-1 contains from 0.1 to 5 mass % zirconium atoms and/or hafnium atoms as calculated as the oxide basis.3. The hydrocracking catalyst for hydrocarbon oil according to or claim 1 , wherein said zeolite-1 further contains titanium atoms.4. The hydrocracking catalyst for hydrocarbon oil according to claim 3 , wherein in the zeolite-1 claim 3 , a part of the aluminum atoms forming the zeolite framework is further substituted with titanium atoms.5. The hydrocracking catalyst for hydrocarbon oil according to or claim 3 , wherein said zeolite-1 contains from 0.1 to 5 mass % titanium atoms as calculated as the oxide basis.6. The hydrocracking catalyst for hydrocarbon oil according to any of to claim 3 , wherein the support contains the zeolite-1 and inorganic oxide excluding the ...

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11-07-2013 дата публикации

HYDROGEN TREATMENT OF IMPURE TALL OIL FOR THE PRODUCTION OF AROMATIC MONOMERS

Номер: US20130178650A1
Принадлежит: STORA ENSO OYJ

A method of manufacturing aromatic hydrocarbons, which are suitable for the production of terephthalic acid, from tall oil-based raw material. According to the invention, the raw material that contains tall oil or its fraction is catalytically deoxygenated with hydrogen, and one or more aromatic hydrocarbons that can be converted into terephthalic acid are separated from the deoxygenated reaction yield. The deoxygenation catalyst is a NiMo catalyst and, in addition, a cracking catalyst can be used, such as an acidic zeolite catalyst. The separated hydrocarbon can be p-xylene, o-xylene or p-cymene. According to the invention, these can be converted by oxidation and, when needed, by a re-arrangement reaction into terephthalic acid that is suitable for the source material of the manufacture of bio-based polyethylene terephthalate. 120-. (canceled)21. A method of manufacturing aromatic hydrocarbons from a tall oil-based raw material , the method comprising:feeding, into a fixed catalyst bed, hydrogen gas and a bio oil, which consists of 2-90% of tall oil fatty acids, 2-98% of tall oil resin acids and, optionally, other vegetable oils;catalytically deoxygenating the bio oil in the bed with hydrogen;cooling the flow exiting the bed, and dividing the flow into a hydrocarbon-bearing liquid phase and a gas phase; andrecovering one or more aromatic hydrocarbons selected from a group comprising o-xylene, m-xylene, p-xylene and a cymene, such as p-cymene, from the hydrocarbon-bearing liquid phase.22. The method according to claim 21 , wherein the bio oil contains at least 25% of tall oil resin acids.23. The method according to claim 21 , wherein the bio oil has been separated from crude tall oil by distillation.24. The method according to claim 21 , wherein a deoxygenation catalyst and a cracking catalyst are used claim 21 , which are different from each other and located sequentially apart from each other in the catalyst bed that is formed by a solid bed material.25. The ...

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11-07-2013 дата публикации

PROCESS FOR MAKING A DISTILLATE PRODUCT AND/OR C2-C4 OLEFINS

Номер: US20130178672A1
Принадлежит: SHELL OIL COMPANY

A process for making a distillate product and one or more C2-C4 olefins from a FCC feedstock containing a cellulosic material and a hydrocarbon co-feed is provided. 1. A process for making a distillate product and one or more C2-C4 olefins comprising:a) contacting a FCC feedstock with a FCC catalyst at a temperature of at least 400° C. in a riser reactor to produce a distillate product and a spent FCC catalyst, wherein the FCC feedstock comprises a cellulosic material and a hydrocarbon co-feed;b) separating at least a portion of the distillate product from the spent FCC catalyst;c) regenerating the spent FCC catalyst to produce a regenerated FCC catalyst;d) contacting an intermediate reactor feedstock with at least a portion of the regenerated FCC catalyst at a temperature of at least 500° C. in an intermediate reactor to produce one or more C2-C4 olefins and a used regenerated FCC catalyst;e) separating at least a portion of the one or more C2-C4 olefins from the used regenerated catalyst; andf) providing at least a portion of the used regenerated FCC catalyst as FCC catalyst in step a).2. The process of wherein the FCC feedstock comprises a hydrocarbon co-feed and at least one cellulosic material selected from the group consisting of a solid cellulosic material claim 1 , a pyrolysis oil derived from cellulosic material claim 1 , and a mixture thereof.3. The process of wherein the hydrocarbon co-feed comprises at least 8 wt % elemental hydrogen claim 1 , based on the total weight of the hydrocarbon co-feed on a dry basis.4. The process of wherein the hydrocarbon co-feed comprises in the range from at least 20 wt % to at most 100 wt % of at least one paraffin claim 1 , based on the total weight of the hydrocarbon co-feed.5. The process of wherein the combination of the cellulosic material and the hydrocarbon co-feed has an overall molar ratio of hydrogen to carbon (H/C) of equal to or more than 1.1 (1.1/1).6. The process of wherein the cellulosic material is a solid ...

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11-07-2013 дата публикации

METHOD AND DEVICE FOR LIMITING THE DEGASSING OF TRITIATED WASTE ISSUED FROM THE NUCLEAR INDUSTRY

Номер: US20130178686A1

A method and device for limiting the degassing of tritiated waste issued from the nuclear industry are provided. The method reduces an amount of generated tritiated hydrogen (Tor HT) and/or tritiated water (HTO or TO) including at least one piece of tritiated waste from the nuclear industry. The method includes placing the package in contact with a mixture including manganese dioxide (MnO) combined with a component that includes silver; and placing the package in contact with a molecular sieve. 1. A method for reducing an amount of tritiated hydrogen (Tor HT) and/or tritiated water (HTO or TO) generated by at least one package including at least one piece of tritiated waste from the nuclear industry , the method comprising:{'sub': '2', 'placing the package in contact with a mixture including manganese dioxide (MnO) combined with a component comprising silver; and'}placing the package in contact with at least one molecular sieve.2. The method according to claim 1 , wherein the silver is in the mixture appearing as at least one of a silver oxide claim 1 , a silver salt claim 1 , and a silver complex.3. The method according to claim 1 , wherein the silver appears as silver oxide in the mixture claim 1 , in which the mass concentration of manganese dioxide in the mixture ranging from 80% to 99% claim 1 , and in which the mass concentration of silver oxide in the mixture is ranging from 20% to 1%.4. The method according to claim 3 , wherein the mass concentrations of manganese dioxide and silver oxide in the mixture are about 90% and 10% claim 3 , respectively.5. The method according to claim 1 , wherein the mixture includes a platinum compound in which the mass concentration in the mixture is ranging from 0.1% to 1%.6. The method according to claim 5 , wherein the platinum compound is made of platinum black 10% Pt.7. The method according to claim 5 , wherein the silver appears as silver oxide in the mixture claim 5 , in which the mass concentration of manganese dioxide ...

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18-07-2013 дата публикации

CATALYST FOR USE IN HYDROCONVERSION, COMPRISING AT LEAST ONE ZEOLITE AND METALS FROM GROUPS VIII AND VIB, AND PREPARATION OF THE CATALYST

Номер: US20130180886A1
Принадлежит:

The invention concerns a catalyst containing a support comprising at least one binder and at least one zeolite having at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms, said catalyst comprising phosphorus, at least one C1-C4 dialkyl succinate, acetic acid and a hydrodehydrogenating function comprising at least one element from group VIB and at least one element from group VIII, the Raman spectrum of the catalyst comprising bands at 990 and/or 974 cm, characteristic of at least one Keggin heteropolyanion, the characteristic bands of said succinate and the characteristic principal band of acetic acid at 896 cm. 1. A catalyst containing a support comprising at least one binder and at least one zeolite having at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms , said catalyst comprising phosphorus , at least one C1-C4 dialkyl succinate , acetic acid and a hydrodehydrogenating function comprising at least one element from group VIB and at least one element from group VIII , the Raman spectrum of the catalyst comprising bands at 990 and/or 974 cm , characteristic of at least one Keggin heteropolyanion , the characteristic bands of said succinate and the characteristic principal band of acetic acid at 896 cm.2. A catalyst according to claim 1 , in which the dialkyl succinate is dimethyl succinate and in which the Raman spectrum of the catalyst has principal bands at 990 and/or 974 cmwhich are characteristic of Keggin heteropolyanions claim 1 , and at 853 cm claim 1 , which is characteristic of dimethyl succinate and at 896 cm claim 1 , which is characteristic of acetic acid.3. A catalyst according to claim 1 , in which the dialkyl succinate is diethyl succinate claim 1 , dibutyl succinate or diisopropyl succinate.4. A catalyst according to claim 1 , comprising a support constituted by alumina and zeolite.5. A catalyst according to claim 1 , comprising a support constituted ...

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18-07-2013 дата публикации

Methods for Producing Hydrocarbon Products from Bio-Oils and/or Coal-Oils

Номер: US20130184505A1
Автор: Maxwell Ian Ernest
Принадлежит: IGNITE ENERGY RESOURCES LIMITED

The present invention relates to a method for producing a hydrocarbon product from coal and/or biomass comprising the following steps: converting the coal to a coal-oil and/or converting the biomass to bio-oil, optionally processing the coal-oil and/or bio-oil in a hydroprocessing reaction to remove one or more of oxygen, nitrogen or sulfur from hydrocarbon compounds in the coal-oil and/or bio-oil; and using at least a portion of the coal-oil and/or bio-oil as a feedstock in a cracking reaction to convert hydrocarbon compounds in the feedstock into a mixture of smaller hydrocarbon compounds comprising the hydrocarbon product. 1. A method for producing a hydrocarbon product from coal comprising the following steps:converting the coal to a coal-oil by thermal or hydrothermal conversion;processing the coal-oil in a hydroprocessing reaction to remove one or more of oxygen, nitrogen or sulfur from hydrocarbon compounds in the coal-oil; andusing at least a portion of the coal-oil as a feedstock in a cracking reaction to convert hydrocarbon compounds in the feedstock into a mixture of smaller hydrocarbon compounds comprising the hydrocarbon product.2. A method for producing a hydrocarbon product from biomass comprising the following steps:converting the biomass to bio-oil by thermal or hydrothermal conversion;processing the bio-oil in a hydroprocessing reaction to remove one or more of oxygen, nitrogen or sulfur from hydrocarbon compounds in the bio-oil; andusing at least a portion of the bio-oil as a feedstock in a cracking reaction to convert hydrocarbon compounds in the feedstock into a mixture of smaller hydrocarbon compounds comprising the hydrocarbon product.3. The method of claim 2 , wherein the feedstock is comprised of at least:(i) 50% of said bio-oil and said hydrocarbon product is at least a 50% renewable product;(ii) 75% of said bio-oil and said hydrocarbon product is at least a 75% renewable product; or(iii) 90% of said bio-oil and said hydrocarbon product is ...

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25-07-2013 дата публикации

Process for hydrotreating a hydrocarbon cut with a boiling point of more than 250°c in the presence of a sulphide catalyst prepared using a cyclic oligosaccharide

Номер: US20130186806A1
Принадлежит: IFP Energies Nouvelles IFPEN

Preparation of a catalyst having at least one metal from group VIII, at least one metal from group VIB and at least one support; in succession: i) one of i1) contacting a pre-catalyst with metal from group VIII, metal from group VIB and support with a cyclic oligosaccharide naming at least 6 α-(1,4)-bonded glucopyranose subunits; i2) contacting support with a solution containing a precursor of metal from group VIII, a precursor of said metal from group VIB and a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; or i3) contacting support with a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits followed by contacting solid derived therefrom with a precursor of metal from group VIII and a precursor of metal from group VIB.

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01-08-2013 дата публикации

INTEGRATED SOLVENT DEASPHALTING AND STEAM PYROLYSIS PROCESS FOR DIRECT PROCESSING OF A CRUDE OIL

Номер: US20130197289A1
Принадлежит: Saudi Arabian Oil Company

A process is provided that is directed to a steam pyrolysis zone integrated with a solvent deasphalting zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated solvent deasphalting and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals comprises charging the crude oil to a solvent deasphalting zone with an effective amount of solvent to produce a deasphalted and demetalized oil stream and a bottom asphalt phase; thermally cracking the deasphalted and demetalized oil stream in the presence of steam to produce a mixed product stream; separating the mixed product stream; recovering olefins and aromatics from the separated mixed product stream; and recovering pyrolysis fuel oil from the separated mixed product stream. 1. An integrated solvent deasphalting and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals , the process comprising:a. charging the crude oil to a solvent deasphalting zone with an effective amount of solvent to produce a deasphalted and demetalized oil stream and a bottom asphalt phase;b. thermally cracking the deasphalted and demetalized oil stream in the presence of steam to produce a mixed product stream;c. separating the thermally cracked mixed product stream;d. recovering olefins and aromatics from the separated mixed product stream; ande. recovering pyrolysis fuel oil from the separated mixed product stream.2. The integrated process of claim 1 , wherein step (c) comprises compressing the thermally cracked mixed product stream with plural compression stages;subjecting the compressed thermally cracked mixed product stream to caustic treatment to produce a thermally cracked mixed product stream with a reduced content of hydrogen sulfide and carbon dioxide;compressing the thermally cracked mixed product stream with a reduced content of hydrogen sulfide and ...

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15-08-2013 дата публикации

INTEGRATED PROCESS FOR UPGRADING HEAVY OIL

Номер: US20130206642A1
Принадлежит: CHINA UNIVERSITY OF PETROLEUM-BEIJING

The invention provides an integrated process for processing heavy oil, wherein the integrated process at least comprises: solvent deasphalting is carried out for heavy oil material, and de-oiled asphalt phase is mixed with dispersing agent and then entered a thermal cracking reactor to undergo thermal cracking reactions. Upgraded oil can be obtained through the mixture of the de-asphalted oil and thermal cracking oil separated from thermal cracking reaction products. The solvent and heavy gas oil, which are separated from the thermal cracking reaction products, are respectively recycled back to the solvent deasphalting process as solvent and as mixed feed to remove asphaltene. The integrated process of the present invention solves the problems that solvent is difficult to be separated from asphalt with high softening point in solvent deasphalting process and hard asphalt is difficult to be transported. 1. A integrated process for processing heavy oil , comprising at least the following processes , wherein:a heavy oil feedstock, which substantially does not comprise <350° C. atmospheric distillates, is used as feed and subjected to solvent deasphalting process in an extraction tower with an extraction solvent, a de-asphalted oil and a de-oiled asphalt phase including the extraction solvent are collected;the de-oiled asphalt phase including the extraction solvent is mixed with a dispersing solvent and then enters into a thermal cracking reactor to be subjected to a thermal cracking process, so as to obtain thermal cracking reaction product and coke, the thermal cracking reaction product is led out, gas, solvent, thermal cracking oil and 450° C.+ heavy gas oil are separated therefrom;the solvent separated from the thermal cracking product is recycled back to the solvent deasphalting process to be recycled, the 450° C.+ heavy gas oil is recycled back to the solvent deasphalting process to be used as mixed feed;upgraded oil is obtained through mixing the de-asphalted oil ...

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15-08-2013 дата публикации

Hydrolysis of used ionic liquid catalyst for disposal

Номер: US20130211175A1
Принадлежит: Chevron USA Inc

We provide a process and apparatus for preparing a used catalyst for disposal, comprising: a. hydrolyzing a used ionic liquid catalyst comprising an anhydrous metal halide to produce a hydrolyzed product; and b. separating the hydrolyzed product into a liquid phase and a solid phase; wherein the liquid phase comprises a non-water-reactive aqueous phase and a hydrocarbon phase; and wherein the solid phase comprises a solid portion of the hydrolyzed product, that is not water reactive. A vessel is used for the hydrolyzing and a separator is used for the separating.

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22-08-2013 дата публикации

Biorefinery for conversion of carbothdrates and lignocellulosics via primary hydrolysate cmf to liquid fuels

Номер: US20130217932A1
Автор: SECK Karl A.
Принадлежит:

A method of making alkanes from lignocellulosic sources of C5 and C6 sugars. Suitable biomass feedstocks are converted into alkane-based fuels such as diesel and jet fuel blendstocks. Sugar monomers from the feedstocks are converted to chlormethylfurfural (CMF) with a levulinic acid (LA) byproduct. The CMF and LA are converted to ethyl levulinate (EL) and hydroxymethylfurfural (HMF), which are then combined into longer chain molecules via aldol condensation reactions. The condensation products are partially or fully saturated by mild hydrotreating, followed by deoxygenation to form alkanes with boiling ranges suitable for use as liquid fuels. 1. A method of making an alkane liquid fuel the method comprising the steps of:(a) converting carbohydrate and lignocellulosic feedstock into chlormethylfurfural (CMF) and levulinic acid (LA) by treatment with hydrochloric acid in a biphasic reactor;(b) converting of the CMF and LA into hydroxymethylfurfural (HMF) and ethyl levulinate (EL);(c) combining the HMF and EL from step (b) into longer carbon chain molecules via an aldol condensation reaction;(d) partially or fully saturating the condensation products from step (c) by mild hydrotreating; and(e) deoxygenating the products from step (d) to form alkanes in a boiling range suitable for liquid fuels.2. The method of claim 1 , wherein step (b) comprises the step of:adjusting ratios of the HMF and EL to control the carbon chain length of the condensation products from step (c).3. The method of claim 1 , wherein step (d) comprises the step of:producing a cyclic ether compound.4. The method of claim 3 , wherein the step of producing a cyclic ether compound comprises the step of:producing a cyclic ether compound that includes at least one tetrahydrofuran group.5. The method of claim 1 , wherein step (c) comprises the step of:combining the products from step (b) using a catalyst for the aldol condensation reaction.6. The method of claim 5 , wherein the step of combining the ...

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22-08-2013 дата публикации

Method of Making Catalyst, Catalyst Made Thereby and Use Thereof

Номер: US20130217936A1
Автор: Cheng Jane C., Levin Doron
Принадлежит: ExxonMobil Chemical Patents Inc.

The invention concerns a method of making a catalyst adapted for isomerization of xylenes. 1. In the method of making a metal-containing zeolite catalyst by competitive ion exchange , the improvement comprising preparation of said metal-containing zeolite catalyst by competitive ion exchange in the presence of ammonium acetate.2. The method according to claim 1 , wherein said zeolite is selected from at least one of ZSM-5 claim 1 , ZSM-11 claim 1 , ZSM-12 claim 1 , ZSM-18 claim 1 , MCM-68 claim 1 , MCM-22 claim 1 , Beta claim 1 , mordenite claim 1 , and mixtures thereof.3. The method according to claim 1 , wherein the metal in said metal-containing zeolite comprises at least one metal from Groups 8-10 of the Periodic Table.4. The method according to claim 1 , wherein said metal-containing zeolite includes at least one of platinum or rhenium dispersed in the amount of from 0.01 wt % to 1.20 wt % claim 1 , preferably 0.01 wt % to less than 1.00 wt % claim 1 , more preferably 0.01 wt % to 0.50 wt % claim 1 , based on the weight of said metal-containing zeolite.5. The method according to claim 1 , wherein said metal-containing zeolite is silicone-selectivated.6. The method according to claim 1 , wherein said catalyst includes a support selected from alumina claim 1 , silica claim 1 , clay claim 1 , aluminosilicates claim 1 , and mixtures thereof.7. A catalyst made by the process according to .8. The catalyst made by the process of claim 7 , further comprising an acetate moiety.9. A catalyst system including a first bed comprising a first metal-containing zeolite catalyst adapted for dealkylation of ethylbenzene and ethylene saturation claim 7 , and a second bed comprising a second metal-containing zeolite catalyst claim 7 , different from said first catalyst and adapted for xylene isomerization claim 7 , wherein at least one of said first catalyst and said second catalyst is prepared by competitive ion exchange in the presence of ammonium acetate.10. The catalyst system ...

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29-08-2013 дата публикации

Process for the Hydrotreatment of Vegetal Materials

Номер: US20130219774A1
Принадлежит: BTG BIOMASS TECHNOLOGY GROUP B.V.

The present invention relates to a process for the hydrotreatment of a vegetal biomass. Specifically, the present invention relates to a process for the hydrotreatment of a vegetal biomass comprising: a) subjecting said vegetal biomass to a hydrotreatment in a first reactor, said hydrotreatment comprises contacting said vegetal biomass in an aqueous medium and a metal oxide, a mixed metal oxide, or a metal-metalloid oxide catalyst comprising at least 35% by weight of metal oxide, mixed metal oxide, or metal-metalloid oxide relative to the total weight of the catalyst, with hydrogen at a pressure in the range of 10 to 400 bar and at a temperature in the range of 50° C. to 300° C. until a predetermined level of the hydrotreatment of said biomass is obtained and wherein the metal oxide, a mixed metal oxide, or a metal-metalloid oxide catalyst comprises nickel. Further, the present invention relates to a metal oxide, mixed metal oxide or metal-metalloid oxide catalyst. Furthermore, the present invention relates to the use of the catalyst. 1. Process for the hydrotreatment of a vegetal biomass comprising:a) subjecting said vegetal biomass to a hydrotreatment in a first reactor, said hydrotreatment comprises contacting said vegetal biomass in an aqueous medium and a metal oxide, a mixed metal oxide, or a metal-metalloid oxide catalyst comprising at least 35% by weight of metal oxide, mixed metal oxide, or metal- metalloid oxide relative to the total weight of the catalyst, with hydrogen at a pressure in the range of 10 to 400 bar and at a temperature in the range of 50° C. to 300° C. until a predetermined level of the hydrotreatment of said biomass is obtained and wherein the metal oxide, a mixed metal oxide, or a metal-metalloid oxide catalyst comprises nickel.2. Process according to claim 1 , wherein the process further comprises:b) subjecting the mixture of step a) to a second hydrotreatment in a second reactor and contacting the hydrotreated vegetal biomass in an ...

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29-08-2013 дата публикации

PROCESS FOR HYDROCRACKING A HYDROCARBON FEEDSTOCK

Номер: US20130220885A1
Принадлежит: Haldor Topsoe A/S

A hydrocracking process comprising the steps of: (a) combining a hydrocarbonaceous feedstock and a heavy bottom fraction recycle stream with a hydrogen-rich gas to obtain a mixture comprising hydrocarbonaceous feedstock and hydrogen; (b) catalytically hydrocracking the mixture comprising hydrocarbonaceous feedstock and hydrogen in a hydrocracking zone to obtain a hydrocracked effluent; (c) separating the hydrocracked effluent into a first vapour portion and a first liquid portion in a separation zone; (d) heating the first liquid portion to form a vapourised first liquid portion; (e) feeding the vapourised first liquid portion to a fractionation section producing individual product fractions including a heavy bottom fraction comprising unconverted oil at the bottom zone of the fractionation section; (f) withdrawing from the fractionation section the heavy bottom fraction; (g) splitting the heavy bottom fraction in a stream for stripping and a heavy bottom fraction recycle stream; (h) stripping the stream for stripping, with a stripping medium, in a counter current stripping column to form an overhead vapour and a stripped liquid; (i) feeding the overhead vapour to the fractionation section, to a recycle stream or to a position upstream the fractionation section; and (j) removing at least a part of the stripped liquid from the counter current stripping column as a net purge of unconverted oil. 1. A hydrocracking process comprising the steps of:(a) combining a hydrocarbonaceous feedstock and a heavy bottom fraction recycle stream with a hydrogen-rich gas to obtain a mixture comprising hydrocarbonaceous feedstock and hydrogen;(b) catalytically hydrocracking the mixture comprising hydrocarbonaceous feedstock and hydrogen in a hydrocracking zone to obtain a hydrocracked effluent;(c) separating the hydrocracked effluent into a first vapour portion and a first liquid portion in a separation zone;(d) heating the first liquid portion to form a vapourised first liquid portion ...

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29-08-2013 дата публикации

TITANIA-BOUND ZEOLITE EU-2 COMPOSITION AND METHOD OF MAKING AND USING SUCH COMPOSITION

Номер: US20130220887A1
Принадлежит: SHELL OIL COMPANY

Catalyst composition useful in the catalytic dewaxing of a waxy hydrocarbon feedstock which catalyst composition includes a mixture of zeolite EU-2 and titania and may further include a noble metal. The zeolite EU-2 has a molar bulk ratio of silica-to-alumina (SAR) of greater than 100:1. The zeolite or mixture may have been dealuminated such as by acid leaching using a fluorosilicate salt or by steam treating. 1. A catalyst composition comprising a mixture comprising titania and zeolite EU-2 having a molar bulk ratio of silica-to-alumina (SAR) of greater than 100:1.2. A catalyst composition as recited in claim 1 , wherein said zeolite EU-2 is present in said composition in an amount of at most 70% wt and said titania is present in said composition in an amount of no more than 90% wt claim 1 , with such % wt being based on the dry weight of said composition.3. A catalyst composition as recited in claim 2 , further comprising a noble metal selected from the group consisting of platinum and palladium.4. A catalyst composition as recited in claim 1 , wherein said mixture contains zeolite EU-2 particles of which the average aluminium concentration is at least 1.1 times the aluminium concentration at the surface of the EU-2 particles.5. A catalyst composition as recited in claim 1 , wherein said catalyst composition is substantially free of silica other than the silica contained in said zeolite EU-2 framework.6. A catalyst composition as recited in claim 1 , wherein said catalyst composition is substantially free of alumina other than the alumina contained in said zeolite EU-2 framework.7. A catalyst composition as recited in claim 1 , wherein said titania has a surface area surface exceeding 100 m/gm.8. A method for preparing a catalyst composition claim 1 , wherein said method comprises: preparing a mixture comprising titania and zeolite EU-2 having a molar bulk ratio of silica-to-alumina (SAR) of greater than 100:1 and forming said mixture into a particle.9. A method ...

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29-08-2013 дата публикации

METHOD FOR PREPARING HYDROREFINING CATALYST

Номер: US20130225400A1
Принадлежит: PETROCHINA COMPANY LIMITED

A method for preparing hydrorefining catalyst comprises the following steps: (1) mixing an aqueous ammonia solution with a polyamine complexing agent to form a mixed solvent; (2) adding a cobalt salt to the mixed solvent, dissolving the cobalt salt, and then adding a molybdenum salt and optional salts of other active components, and dissolving them to prepare an impregnating solution; and (3) impregnating a support with the impregnating solution, followed by aging, drying, and activating the impregnated support to form a hydrorefining catalyst. The hydrorefining catalyst prepared by this method has good activity, selectivity and stability in use. 1. A method for preparing hydrorefining catalyst , comprising:supporting active components on a support, the active components comprising cobalt and molybdenum, wherein mixing an aqueous ammonia with a polyamine complexing agent to form a mixed solvent;adding a salt comprising the active component cobalt to the mixed solvent, dissolving the cobalt salt, and then adding a molybdenum salt or a molybdenum salt and salts of other active components and promoters, and dissolving them to prepare an impregnation solution; andimpregnating a support with the impregnating solution, followed by aging, drying and activating the impregnated support to obtain the hydrorefining catalyst.2. The method for preparing hydrorefining catalyst according to claim 1 , wherein a nickel salt claim 1 , a tungsten salt and/or a soluble alkali or carbonate compound of a Group IA element is added during formulation of the impregnation solution.3. The method for preparing hydrorefining catalyst according to claim 1 , wherein the impregnation solution has a pH value of above 10 claim 1 ,4. The method for preparing hydrorefining catalyst according to claim 1 , wherein the polyamine complexing agent is one or more of EDTA claim 1 , triethylene tetramine claim 1 , triethanolamine and ethylenediamine.5. The method for preparing hydrorefining catalyst according ...

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05-09-2013 дата публикации

Method for efficiently operating an ebbulated bed reactor and an efficient ebbulated bed reactor

Номер: US20130228494A1
Принадлежит: Headwaters Heavy Oil LLC

A hydroprocessing method and system involves introducing heavy oil and well-dispersed metal sulfide catalyst particles, or a catalyst precursor capable of forming the well-dispersed metal sulfide catalyst particles in situ within the heavy oil, into a hydroprocessing reactor. The well-dispersed or in situ metal sulfide catalyst particles are formed by 1) premixing a catalyst precursor with a hydrocarbon diluent to form a precursor mixture, 2) mixing the precursor mixture with heavy oil to form a conditioned feedstock, and 3) heating the conditioned feedstock to decompose the catalyst precursor and cause or allow metal from the precursor to react with sulfur in the heavy oil to form the well-dispersed or in situ metal sulfide catalyst particles. The well-dispersed or in situ metal sulfide catalyst particles catalyze beneficial upgrading reactions between the heavy oil and hydrogen and eliminates or reduces formation of coke precursors and sediment.

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05-09-2013 дата публикации

INTEGRATED SOLVENT DEASPHALTING AND STEAM PYROLYSIS PROCESS FOR DIRECT PROCESSING OF A CRUDE OIL

Номер: US20130228496A1
Принадлежит: Saudi Arabian Oil Company

A process is provided that is directed to a steam pyrolysis zone integrated with a solvent deasphalting zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated solvent deasphalting and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals comprises charging the crude oil to a solvent deasphalting zone with an effective amount of solvent to produce a deasphalted and demetalized oil stream and a bottom asphalt phase; thermally cracking the deasphalted and demetalized oil stream in the presence of steam to produce a mixed product stream; separating the mixed product stream; recovering olefins and aromatics from the separated mixed product stream; and recovering pyrolysis fuel oil from the separated mixed product stream. 1. An integrated solvent deasphalting and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals , the process comprising:a. charging the crude oil to a solvent deasphalting zone with an effective amount of solvent to produce a deasphalted and demetalized oil stream and a bottom asphalt phase;b. thermally cracking the deasphalted and demetalized oil stream in the presence of steam to produce a mixed product stream;c. separating the thermally cracked mixed product stream;d. recovering olefins and aromatics from the separated mixed product stream; ande. recovering pyrolysis fuel oil from the separated mixed product stream.2. The integrated process of claim 1 , wherein step (c) comprisescompressing the thermally cracked mixed product stream with plural compression stages;subjecting the compressed thermally cracked mixed product stream to caustic treatment to produce a thermally cracked mixed product stream with a reduced content of hydrogen sulfide and carbon dioxide;compressing the thermally cracked mixed product stream with a reduced content of hydrogen sulfide and ...

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12-09-2013 дата публикации

Upgrading Hydrocarbon Pyrolysis Products

Номер: US20130233764A1
Принадлежит: ExxonMobil Chemical Patents Inc

The invention relates to upgraded pyrolysis products, processes for upgrading products obtained from hydrocarbon pyrolysis, equipment useful for such processes, and the use of upgraded pyrolysis products.

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12-09-2013 дата публикации

METHOD OF PRODUCING REGENERATED HYDROTREATING CATALYST AND METHOD OF PRODUCING PETROLEUM PRODUCTS

Номер: US20130233769A1
Принадлежит: JX NIPPON OIL & ENERGY CORPORATION

A method of producing a regenerated hydrotreating catalyst, including a first step of preparing a hydrotreating catalyst that has been used for hydrotreatment of a petroleum fraction and has a metal element selected from Group 6 elements of the periodic table; a second step of performing regeneration treatment for part of the catalyst prepared in the first step, then performing X-ray absorption fine structure analysis for the catalyst after the regeneration treatment, and obtaining regeneration treatment conditions in which a ratio IS/IO of a peak intensity IS of a peak attributed to a bond between the metal element and a sulfur atom to a peak intensity IO of a peak attributed to a bond between the metal element and an oxygen atom is in the range of 0.1 to 0.3 in a radial distribution curve obtained from an extended X-ray absorption fine structure spectrum. 1. A method of producing a regenerated hydrotreating catalyst , comprising:a first step of preparing a hydrotreating catalyst that has been used for hydrotreatment of a petroleum fraction and has a metal element selected from Group 6 elements of the periodic table;{'sub': S', 'O', 'S', 'O, 'a second step of performing regeneration treatment for part of the catalyst prepared in the first step, then performing X-ray absorption fine structure analysis for the catalyst after the regeneration treatment, and obtaining regeneration treatment conditions in which a ratio I/Iof a peak intensity Iof a peak attributed to a bond between the metal element and a sulfur atom to a peak intensity Iof a peak attributed to a bond between the metal element and an oxygen atom is in the range of 0.1 to 0.3 in a radial distribution curve obtained from an extended X-ray absorption fine structure spectrum; and'}a third step of performing regeneration treatment under regeneration treatment conditions determined based on the second step, for the other part of the catalyst prepared in the first step.2. The method of producing a regenerated ...

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19-09-2013 дата публикации

Photochemical Processes and Compositions for Methane Reforming Using Transition Metal Chalcogenide Photocatalysts

Номер: US20130239469A1

The present invention provides a transition metal chalcogenide photocatalyst, a reactor using the transition metal chalcogenide photocatalyst, and methods of making and using a transition metal chalcogenide photocatalyst for reforming CHwith CO. 1. A photocatalyst for reforming methane with COcomprising:{'sub': 4', '2, 'a transition metal chalcogenide photocatalyst chemically stable in an environment comprising CHand CO, wherein the transition metal chalcogenide photocatalyst comprises Ti, V, Cr, Mn, Fe, Co, Ni, Zr, Nb, Mo, Tc, Ru, Rh, Pt, Hf, Ta, W, Re, Os, Ir, Pt or combinations thereof.'}2. The photocatalyst of claim 1 , wherein the transition metal chalcogenide photocatalyst comprises TiS claim 1 , VS claim 1 , CrS claim 1 , MnS claim 1 , FeS claim 1 , CoS claim 1 , NiS claim 1 , ZrS claim 1 , NbS claim 1 , MoS claim 1 , TcS claim 1 , RuS claim 1 , RhS claim 1 , PtS claim 1 , HfS claim 1 , TaS claim 1 , WS claim 1 , ReS claim 1 , OsS claim 1 , IrS claim 1 , PtSor combinations thereof.3. The photocatalyst of claim 1 , wherein the transition metal chalcogenide photocatalyst comprises CoSand MoS; CoSand WS; NiSand MoS; or NiSand WS.4. The photocatalyst of claim 1 , wherein the transition metal chalcogenide photocatalyst is supported on a conductive inert support optionally consisting of carbon having a surface area exceeding about 120 g/m.5. A gas reforming electrode for reforming CHwith COcomprising:a conductive web; and{'sub': 4', '2, 'a transition metal chalcogenide photocatalyst applied on at least one face of the conductive web and is chemically stable in an environment comprising CHand CO.'}6. The gas reforming electrode of claim 5 , wherein said conductive web is a carbon cloth.7. The gas reforming electrode of claim 5 , wherein said catalyst is mixed with an optionally perfluorinated hydrophobic binder.8. The gas reforming electrode of claim 5 , wherein the transition metal chalcogenide photocatalyst comprises Ti claim 5 , V claim 5 , Cr claim 5 , Mn claim ...

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19-09-2013 дата публикации

Process unit for flexible production of alkylate gasoline and distillate

Номер: US20130243672A1
Принадлежит: Chevron USA Inc

A process unit, comprising: a) an alkylation reactor; and b) a control system that enables the alkylation reactor to be operated in an alkylate mode and in a distillate mode; wherein the alkylation reactor can switch back and forth from operating in the alkylate mode to the distillate mode.

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19-09-2013 дата публикации

Method For The Production Of Conjugated Polyunsaturated Fatty Acids With Heterogenous Catalysts

Номер: US20130245299A1
Принадлежит:

The present invention relates to an improved process for the production of conjugated polyunsaturated fatty acids (PUFA), preferably conjugated linoleic acid (CLA), using finely dispersed heterogeneous metal catalysts on a mesoporous support, in the absence of Hg. The present invention also relates to a method to increase the large microporosity and (optionally) the small mesoporosity of a zeolite, thus obtaining a modified zeolite having a large and highly accessible internal surface. 1. A method for preparing conjugated polyunsaturated fatty acids by isomerisation of a nonconjugated PUFA comprising contacting a starting material containing a nonconjugated PUFA with a heterogeneous catalyst containing a finely dispersed catalytic metal supported on an inorganic nanoporous Si based material and wherein the dispersion of said metal as calculated by CO chemosorption is at least 30%.2. The method according to wherein the isomerisation reaction occurs in the absence of Hin the reaction medium or associated with the catalyst.3. The method according to or wherein said finely dispersed metal is a noble metal or Ni.4. The method according to wherein said finely dispersed metal is Ru or Rh.5. The method according to to wherein said inorganic nanoporous Si based support is a mesoporous zeolite or zeolite-like material having microporous and mesoporous porosity.6. The method according to wherein said inorganic nanoporous Si based support has a Si/Al ratio of at least 30.7. The method according to or wherein said heterogeneous catalyst has a low Brønsted acidity by the presence of large monovalent alkali metal cations associated with said support.8. The method according to wherein said heterogeneous catalyst is a Ru/Cs claim 7 , Ru/Rb claim 7 , Ru/K claim 7 , Ru/Na claim 7 , Rh/Cs claim 7 , Rh/Rb claim 7 , Rh/K claim 7 , or Ru/Na loaded zeolite of the MFI- claim 7 , BEA- claim 7 , MOR or FAU-type.9. The method according to to claim 7 , wherein said PUFA in said starting ...

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19-09-2013 дата публикации

PROCESS AND SYSTEM FOR PRODUCING FUEL COMPONENTS

Номер: US20130245342A1
Принадлежит: UPM-KYMMENE CORPORATION

The present invention relates to a process and system for producing fuel components, and more particularly to a process and system for producing fuel components from a material of biological origin. The process is a two-step or a three-step process comprising purifying of the feed material by evaporating and refining the purified feed material in the presence of at least one catalyst to form a mixture of hydrocarbon compounds from which mixture liquid hydrocarbon compounds are separated and further fractionated into fuel components. The present invention relates further to fuel components obtained by the process of the present invention as well as to the use of the fuel components and a mixture comprising the fuel components. 1. A process for producing fuel components from a material of biological origin , comprising the following stepsa) evaporating the material of biological origin for removing impurities from the material of biological origin to produce purified biological material,whereby the evaporating is accomplished in two, three or more evaporation steps, andthe first evaporation step is performed at a temperature of 50-250° C. and a pressure of 5-100 mbar,b) hydroprocessing said purified biological material in the presence of hydrogen gas and at least one catalyst to form a mixture of hydrocarbon compounds,c) separating gaseous compounds from said mixture of hydrocarbon compounds to obtain liquid hydrocarbon compounds,d) fractionating said liquid hydrocarbon compounds to obtain fuel components, ande) recycling a portion of the liquid hydrocarbon compounds obtained from the separation or fractionation back to the hydroprocessing.2. The process according to claim 1 , characterized in that the evaporating is accomplished in three evaporation steps.3. The process according to claim 1 , characterized in that the evaporating is accomplished in two evaporation steps.4. The process according to claim 1 , characterized in that the evaporating is performed in an ...

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26-09-2013 дата публикации

Bacterial Production of Jet Fuel and Gasoline Range Hydrocarbons

Номер: US20130247452A1
Автор: Bradin David
Принадлежит:

Methods for forming hydrocarbon products from bacteria, namely, bacteria which produce fatty acids, are disclosed. The methods involve the bacterial production of fatty acids, the thermal decarboxylation of the resulting fatty acids, the hydrocracking and isomerization of the decarboxylation product, and the distillation to yield the desired hydrocarbon fractions. The products can be isolated in the gasoline, jet and/or diesel fuel ranges. Thus, bacteria can be used to produce products in the gasoline, jet and/or diesel fuel ranges which are virtually indistinguishable from those derived from their petroleum-based analogs. 1. A method of forming a hydrocarbon product , comprising the steps of:a) cultivating bacteria which produce a fatty acid product, to provide a source of fatty acids,b) isolating the fatty acids,c) performing thermal decarboxylation on the fatty acids to form a thermal decarboxylation product stream,d) hydrocracking the thermal decarboxylation product stream, andc) isolating a product in the gasoline, jet, or diesel fuel range.2. The method of claim 1 , wherein the product is in the jet range.3. The method of claim 1 , wherein all or a portion of the product is subjected to isomerization conditions.4. The method of claim 1 , wherein all or a portion of the product is subjected to hydrogenation claim 1 , hydrotreatment claim 1 , and/or hydrofinishing conditions.5. The method of claim 3 , wherein the product is in the jet range.6. The method of claim 4 , wherein all or a portion of the product is subjected to isomerization conditions.7. The method of claim 3 , wherein all or a portion of the product is subjected to hydrogenation claim 3 , hydrotreatment claim 3 , and/or hydrofinishing conditions.8. The method of claim 1 , wherein the product is in the diesel or gasoline range.9. The method of claim 8 , wherein all or a portion of the product is subjected to hydrogenation claim 8 , hydrotreatment claim 8 , and/or hydrofinishing conditions.10. The ...

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26-09-2013 дата публикации

PLATINUM-FREE MONOMETALLIC AND BIMETALLIC NANOPARTICLES AS RING-OPENING CATALYSTS

Номер: US20130248414A1
Принадлежит: GOVERNORS OF THE UNIVERSITY OF ALBERTA

Nanoparticle catalyst compositions and methods for preparation of same are described. The nanoparticle catalysts are platinum-free and are useful in effecting selective ring-opening reactions, for example in upgrading heavy oil. The catalyst may be of monometallic composition, or may comprise an alloyed or core-shell bimetallic composition. The nanoparticles are of controlled size and shape. 1. A ring-opening catalyst composition comprising: a primary non-platinum transition metal having ring-opening catalytic activity; and', 'a secondary transition metal;, 'a plurality of monodispersed nanoparticles, each of the monodispersed nanoparticles having a size between 1-5 nm in diameter, and each of the monodispersed nanoparticles comprising2. The ring-opening catalyst composition as in claim 1 , further comprising a capping agent.3. The bimetallic nanoparticle ring-opening catalyst as in claim 1 , wherein the primary transition metal has suitable activity and selectivity in catalyzing single-cleavage ring-opening reactions.4. The bimetallic nanoparticle ring-opening catalyst as in claim 1 , wherein the primary transition metal is a metal selected from the group consisting of: palladium claim 1 , ruthenium claim 1 , rhodium claim 1 , iridium claim 1 , and rhenium.5. The bimetallic nanoparticle ring-opening catalyst as in claim 1 , wherein the primary transition metal is iridium.6. The bimetallic nanoparticle ring-opening catalyst as in claim 1 , wherein the secondary transition metal is a catalytically active transition metal.7. The bimetallic nanoparticle ring-opening catalyst as in claim 6 , wherein the secondary transition metal has ring-opening catalytic activity.8. The bimetallic nanoparticle ring-opening catalyst as in claim 6 , wherein the secondary transition metal is a hydrodesulfurization catalyst.9. The bimetallic nanoparticle ring-opening catalyst as in claim 6 , wherein the secondary transition metal is a hydrogenation catalyst.10. The bimetallic nanoparticle ...

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03-10-2013 дата публикации

PROCESS FOR HYDRODEOXYGENATION AND PROCESS FOR UPGRADING OF PYROLYSIS OIL RESULTING FROM BIOMASS, WHICH ARE CAPABLE OF OPERATING CONTINUOUSLY

Номер: US20130255138A1
Принадлежит: TOTAL RAFFINAGE MARKETING

The invention relates to a process for hydrodeoxygenation (HDO) of pyrolysis oil and also to a process for upgrading of pyrolysis oil implementing said HDO process, and also to processing of the aqueous phase resulting from the HDO by steam pre-reforming and then steam reforming. 1. A process for the catalytic hydrodeoxygenation (HDO) of biomass pyrolysis oil and/or of the ligneous organic phase resulting from the phase separation of biomass pyrolysis oil to which water has been added , comprising a plurality of catalytic beds arranged in series and distributed in one or more reactors which is/are equipped with means for controlling the temperature , and characterized by:{'sup': 'st', 'the injection of the pyrolysis oil at the top of the 1catalytic bed,'}the fractional injection of the hydrogen:{'sup': st', 'st, 'the 1injection of hydrogen is carried out at the top of the 1catalytic bed,'}{'sub': 2', '2', '2', '2, 'the other injection or injections of Hbeing carried out between 2 catalytic beds and being chosen so that the difference between 2 successive Hinjection temperatures does not exceed 50° C., ΔTmax≦50° C., with ΔTmax=[rank (n+1) Hinjection temperature]−[rank (n) Hinjection temperature],'}the separation of the liquid effluents at the outlet of the final catalytic bed into a liquid phase and an organic phase, it being possible for a portion of the organic phase optionally to be recycled in the reactor, for example to be reinjected with the pyrolysis oil,preferably, the amount of hydrogen injected into a bed is equal to the stoichiometric amount necessary to achieve a target ΔT in this bed,{'sup': 'st', 'and/or, preferably, the amount of hydrogen injected at the top of the 1bed is such that the water of the pyrolysis oil is not evaporated.'}2. The process as claimed in claim 1 , characterized in that the pressure in the HDO reactor or reactors is between 5 and 20 MPa preferably between 10 and 15 MPa.3. The process as claimed in claim 1 , characterized in that ...

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03-10-2013 дата публикации

Hydrocarbon conversion process

Номер: US20130256190A1
Принадлежит: UOP LLC

One exemplary embodiment can be a process for hydrocarbon conversion. The process can include providing a feed to a slurry hydrocracking zone, obtaining a hydrocarbon stream including one or more C16-C45 hydrocarbons from the at least one separator, providing another feed to a hydrocracking zone, and providing hydrogen from a three-stage compressor to the slurry hydrocracking zone and the hydrocracking zone. Moreover, the slurry hydrocracking zone may include a slurry hydrocracking reactor and at least one separator.

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03-10-2013 дата публикации

CATALYTIC PROCESSES AND SYSTEMS FOR BASE OIL PRODUCTION FROM HEAVY FEEDSTOCK

Номер: US20130260985A1
Принадлежит: Chevron U.S.A. INC.

A catalyst system is provided for dewaxing a heavy hydrocarbon feedstock to form a lubricant base oil. A layered catalyst system of the present invention may comprise a first hydroisomerization dewaxing catalyst disposed upstream from a second hydroisomerization dewaxing catalyst. Each of the first and second hydroisomerization dewaxing catalysts may be selective for the isomerization of n-paraffins. The first hydroisomerization catalyst has a first level of selectivity for the isomerization of n-paraffins, the second hydroisomerization dewaxing catalyst has a second level of selectivity for the isomerization of n-paraffins, and a layered catalyst system comprising the first and second hydroisomerization dewaxing catalysts has a third level of selectivity for the isomerization of n-paraffins. The third level of selectivity may be higher than each of the first level of selectivity and the second level of selectivity. 2. The layered catalyst according to claim 1 , wherein:the first hydroisomerization catalyst has a higher concentration of the molecular sieve than the second hydroisomerization catalyst,the first hydroisomerization catalyst has a higher concentration of the Group VIII metal than the second hydroisomerization catalyst,each of the first hydroisomerization catalyst and the second hydroisomerization catalyst further comprises a metal modifier selected from the group consisting of Mg, Ca, Sr, Ba, K, La, Pr, Nd, Cr, and combinations thereof, and wherein the first hydroisomerization catalyst and the second hydroisomerization catalyst are disposed within a single reactor.3. The layered catalyst according to claim 1 , wherein:the molecular sieve of each of the first hydroisomerization catalyst and the second hydroisomerization catalyst comprises zeolite SSZ-32,the Group VIII metal of each of the first hydroisomerization catalyst and the second hydroisomerization catalyst comprises Pt, and wherein the ratio of the volume of the first hydroisomerization catalyst ...

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