21-03-2013 дата публикации
Номер: US20130071580A1
Provided are processes for the low temperature deposition of silicon-containing films using activated SiH-containing precursors. The SiH-containing precursors may have reactive functionality such as halogen or cyano moieties. Described are processes in which halogenated or cyanated silanes are used to deposit SiN films. Plasma processing conditions can be used to adjust the carbon, hydrogen and/or nitrogen content of the films. 1. A method of forming a layer on a substrate surface , the method comprising:providing a substrate surface reactive to halides or cyano moieties;exposing the substrate surface reactive to halides or cyano moieties to a halogenated or cyanated carbosilane precursor including carbon, silicon and hydrogen to form a layer containing carbon, silicon and hydrogen;at least partially dehydrogenating the layer containing carbon, silicon and hydrogen; andnitriding the layer containing carbon, silicon and hydrogen.2. The method of claim 1 , wherein nitriding the layer comprises exposing the layer containing carbon claim 1 , silicon and hydrogen to a nitrogen-containing plasma.3. The method of claim 1 , wherein the substrate surface is at a temperature less than about 200° C. during forming the layer.4. The method of claim 1 , wherein the carbosilane precursor is monohalogenated.6. The method of claim 1 , wherein the carbosilane precursor contains a bridging methylene group claim 1 , wherein the carbon in the methylene group is bonded to two silicon atoms.7. The method of claim 1 , wherein the carbosilane precursor is selected from the group consisting of 1 claim 1 ,3-disilapropane claim 1 , 1 claim 1 ,3 claim 1 ,5-trisilapentane claim 1 , 1 claim 1 ,3-disilabutane claim 1 , 1 claim 1 ,3-disilacyclobutane and 1 claim 1 ,3 claim 1 ,5-trisilacyclohexane.8. The method of claim 1 , wherein dehydrogenating the layer containing carbon claim 1 , silicon and hydrogen comprises exposing the layer containing carbon claim 1 , silicon and hydrogen to a plasma ...
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