08-10-2020 дата публикации
Номер: US20200317903A1
Принадлежит:
Composites comprising polymeric nanofibers, metal oxide nanoparticles, and optional surface-segregating surfactants and precursor compositions are disclosed. Also disclosed are nonwoven mats formed from the composites and methods of making and using the composites. The composites enable the deployment of nanostructured materials for water treatment within a self-contained membrane with high water fluxes, as well as a number uses. 1. A precursor composition , comprising:at least one polymer;at least one non-aqueous solvent for said polymer;optionally, at least one surface-segregating surfactant;metal oxide nanoparticles;optionally, carbon nanotubes, graphene, or a combination thereof; andoptionally, a porogen.2. The precursor composition of claim 1 ,wherein said polymer is polyacrylonitrile (PAN), polymethyl methacrylate, polystyrene, polyvinylidene difluoride (PVDF), ethylene-vinyl acetate (EVA), or mixtures thereof.3. The precursor composition of claim 1 ,wherein said polymer is present at a level of about 5% by weight to about 15% by weight, based on the total weight of the precursor composition.4. The precursor composition of claim 1 ,wherein said non-aqueous solvent is ethanol, glacial acetic acid, N,N-dimethyl acetamide, tetrahydrofuran, acetone, N,N-dimethyl formamide, or mixtures thereof.5. The precursor composition of claim 1 ,wherein said non-aqueous solvent is present at a level of about 80% by weight to about 95% by weight, based on the total weight of the precursor composition.6. The precursor composition of claim 1 ,wherein said metal oxide is an iron oxide, iron oxyhydroxide, aluminum oxide, or a mixture thereof.7. The precursor composition of claim 6 ,wherein said iron oxide is hematite, goethite, ferrihydrite, magnetite, or a mixture thereof.8. The precursor composition of claim 1 ,wherein said metal oxide is present at a level of about 0.1% by weight to about 10% by weight, based on the total weight of the precursor composition.9. The precursor ...
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