Disperse dye mixtures which have a high degree of light fastness and build-up

A dye composition which contains a blue colored dye mixture which contains from 71 to about 90 wt % with respect to the total pigment fraction of a blue pigment which is represented by structural formula [1] wherein one of X 1 and X 2 represents NO 2 and the other represents OH, from about 10 to about 30 wt % with respect to the total pigment fraction of two different blue pigments which are different and are represented by structural formula [2] wherein R 1 represents —C 3 H 6 OCH 3 , —C 3 H 6 OC 2 H 5 or —C 3 H 6 OC 2 H 4 OCH 3 .

Process for preparing triorgano borates with low alcohol content

The present invention provides a process for preparing triorgano borates with low alcohol content.

METHODS OF FORMING 4-CHLORO-2-FLUORO-3-SUBSTITUTED-PHENYLBORONIC ACID PINACOL ESTERS AND METHODS OF USING THE SAME

Methods include formation of 4-chloro-2-fluoro-3-substituted-phenylboronic acid pinacol esters. The method comprises contacting a 1-chloro-3-fluoro-2-substituted benzene with an alkyl lithium to form a lithiated 1-chloro-3-fluoro-2-substituted benzene. The lithiated 1-chloro-3-fluoro-2-substituted benzene is contacted with an electrophilic boronic acid derivative to form a 4-chloro-2-fluoro-3-substituted-phenylboronate. The 4-chloro-2-fluoro-3-substituted-phenylboronate is reacted with an aqueous base to form a (4-chloro-2-fluoro-3-substituted-phenyl)trihydroxyborate. The (4-chloro-2-fluoro-3-substituted-phenyl)trihydroxyborate is reacted with an acid to form a 4 chloro-2-fluoro-3-substituted-phenylboronic acid. The 4-chloro-2-fluoro-3-substituted-phenylboronic acid is reacted with 2,3-dimethyl-2,3-butanediol to form 4-chloro-2-fluoro-3-substituted-phenylboronic acid pinacol esters. Methods of using 4-chloro-2-fluoro-3-substituted-phenylboronic acid pinacol esters to produce 6-(4-chloro-2-fluoro-3-substituted-phenyl)-4-aminopicolinates are also disclosed. 1. A method of forming a 4-chloro-2-fluoro-3-substituted-phenylboronic acid pinacol ester , comprising:contacting a 1-chloro-3-fluoro-2-substituted benzene with an alkyl lithium to form a lithiated 1-chloro-3-fluoro-2-substituted benzene;contacting the lithiated 1-chloro-3-fluoro-2-substituted benzene with an electrophilic boronic acid derivative to form a 4-chloro-2-fluoro-3-substituted-phenylboronate;reacting the 4-chloro-2-fluoro-3-substituted-phenylboronate with an aqueous base to form a (4-chloro-2-fluoro-3-substituted-phenyl)trihydroxyborate;reacting the (4-chloro-2-fluoro-3-substituted-phenyl)trihydroxyborate with an acid to form a 4-chloro-2-fluoro-3-substituted-phenylboronic acid; andreacting the 4-chloro-2-fluoro-3-substituted-phenylboronic acid with 2,3-dimethyl-2,3-butanediol.2. The method of claim 1 , reacting the 4-chloro-2-fluoro-3-substituted-phenylboronic acid with 2 claim 1 ,3-dimethyl-2 claim 1 , ...

PHARMACEUTICAL FORMULATIONS

This invention relates to compounds useful for treating fungal infections, more specifically topical treatment of onychomycosis and/or cutaneous fungal infections. This invention is directed to compounds that are active against fungi and have properties that allow the compound, when placed in contact with a patient, to reach the particular part of the skin, nail, hair, claw or hoof infected by the fungus. In particular the present compounds have physiochemical properties that facilitate penetration of the nail plate. 119.-. (canceled)20. A pharmaceutical formulation comprising:a) a pharmaceutically acceptable excipient which is alcohol;b) a compound which penetrates the nail plate and travels through the nail plate to a nail bed underlying said nail plate;c) an emollient which is a cyclic polydimethylsiloxane containing from about 3 to about 9 silicon atoms; and{'i': Trichophyton rubrum', 'Trichophyton mentagrophytes, 'having an efficacy coefficient against having an efficacy coefficient against or above 10;'}wherein the compound is present in said pharmaceutical formulation in a concentration of from about 0.5% to about 15%; and{'i': Trichophyton rubrum', 'Trichophyton mentagrophytes., 'wherein said pharmaceutical formulation is for ungual administration to a human suffering from onychomycosis mediated at least in part by said or'}21. The formulation of claim 20 , wherein the compound is present in said pharmaceutical formulation in a concentration of from about 1% to about 10%.22. The formulation of claim 20 , wherein the cyclic polydimethylsiloxane is cyclomethicone.23. The formulation of claim 20 , further comprising an emollient which is diisopropyl adipate.24. The formulation of claim 20 , wherein the emollient is present in an amount of from about 10% to about 50%.25. The formulation of claim 20 , wherein said pharmaceutically acceptable excipient is propanol or isopropanol.26. The formulation of claim 20 , wherein said pharmaceutically acceptable excipient ...

BORON-CONTAINING SMALL MOLECULES AS ANTI-PROTOZOAL AGENT

This invention provides, among other things, novel compounds useful for treating protozoal infections, pharmaceutical compositions containing such compounds, as well as combinations of these compounds with at least one additional therapeutically effective agent. 2. The compound of claim 1 , wherein Q is C═O.4. The compound of claim 3 , wherein Y is halo-substituted C-Calkyl claim 3 , or a salt thereof.5. The compound of claim 3 , wherein Y is C-Calkyl claim 3 , substituted with three halogens.6. The compound of claim 3 , wherein Y is CF.11. The compound of claim 10 , wherein Yis fluoro or chloro.12. The compound of claim 10 , wherein Y is trifluoromethyl.16. A combination comprising the compound of claim 1 , together with at least one other therapeutically active agent.17. A pharmaceutical formulation comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a) the compound of ; and'}b) a pharmaceutically acceptable excipient.18. The pharmaceutical formulation of claim 17 , wherein the pharmaceutical formulation is a unit dosage form.19. The pharmaceutical formulation of claim 17 , wherein the salt of said compound of a preceding claim is a pharmaceutically acceptable salt.20. A method of killing and/or preventing the growth of a protozoa claim 1 , comprising: contacting the protozoa with an effective amount of the compound of claim 1 , thereby killing and/or preventing the growth of the protozoa.21. The method of claim 1 , wherein the compound is according to .22Trypanosoma.. The method of claim 20 , wherein the protozoa is23Trypanosoma brucei.. The method of claim 20 , wherein the protozoa is24Trypanosoma bruceiTrypanosoma brucei brucei, Trypanosoma brucei gambienseTrypanosoma brucei rhodesiense.. The method of claim 23 , wherein the is a member selected from and25. A method of treating and/or preventing a disease in an animal claim 1 , comprising: administering to the animal a therapeutically effective amount of the compound of claim 1 , thereby treating and/ ...

BORON-CONTAINING SMALL MOLECULES AS ANTI-INFLAMMATORY AGENTS

Compounds and methods of treating anti-inflammatory conditions are disclosed. 2. The compound of claim 1 , wherein Ris a member selected from fluorine and chlorine.3. The compound of claim 1 , wherein Ris a member selected from ORand NRR.4. The compound of claim 1 , wherein Ris OR claim 1 , and Ris a member selected from H claim 1 , substituted or unsubstituted alkyl claim 1 , substituted or unsubstituted heteroalkyl claim 1 , substituted or unsubstituted cycloalkyl claim 1 , substituted or unsubstituted heterocycloalkyl claim 1 , substituted or unsubstituted aryl claim 1 , and substituted or unsubstituted heteroaryl.5. The compound of claim 1 , wherein Ris OR claim 1 , and Ris a member selected from H claim 1 , substituted or unsubstituted alkyl claim 1 , substituted or unsubstituted heteroalkyl and substituted or unsubstituted cycloalkyl.6. The compound of claim 1 , wherein Ris OR claim 1 , and Ris unsubstituted C-Calkyl.7. The compound of claim 1 , wherein Ris OR claim 1 , and Ris unsubstituted cycloalkyl.8. The compound of claim 1 , wherein Ris OR claim 1 , and Ris alkyl claim 1 , substituted with a member selected from substituted or unsubstituted C-Calkoxy.9. The compound of claim 1 , wherein Ris OR claim 1 , and Ris alkyl claim 1 , substituted with at least one halogen.10. The compound of claim 1 , wherein Ris OR claim 1 , and Ris alkyl claim 1 , substituted with at least one oxo moiety.12. The compound of claim 1 , wherein Ris NRR claim 1 ,{'sup': 4', '5, 'wherein Rand Rare members independently selected from H, substituted or unsubstituted alkyl, substituted or unsubstituted heteroalkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted heterocycloalkyl, substituted or unsubstituted aryl, and substituted or unsubstituted heteroaryl.'}13. The compound of claim 1 , wherein Ris NRR claim 1 , wherein{'sup': '4', 'Ris H or unsubstituted alkyl; and'}{'sup': '5', 'Ris unsubstituted alkyl or alkyl substituted with a member selected from hydroxyl ...

METAL BIS(MALONATO) BORATE MONOMERS, POLYMERS AND COPOLYMERS DERIVED THEREFROM, METHODS OF MAKING THE MONOMERS AND POLYMERS, AND ARTICLES DERIVED THEREFROM

Disclosed herein are novel metal bis(malonato)borate monomers and polymers formed by polymerizing the monomers. The monomers and the polymers have conductive properties, making them particularly useful in applications requiring materials with conductive properties. When the metal is lithium, the polymers are particularly well suited for use in lithium ion batteries. 2. The metal bis(malonato)borate monomer of claim 1 ,{'sub': 1', '2, 'wherein Zand Zare the same or different, and are selected from straight-chain alkylene, alkyleneoxy, alkylenoyl, alkylenoxycarbonyl, or alkylenethio, or arylene, having 2 to 20 carbon atoms.'}3. The metal bis(malonato)borate monomer of claim 1 ,{'sub': 1', '2, 'wherein Zand Zare the same or different, and are selected from straight-chain alkylene, alkyleneoxy, alkylenoyl, alkylenoxycarbonyl, alkylenethio, or arylene having 2 to 12 carbon atoms'}4. The metal bis(malonato)borate monomer of claim 1 ,{'sub': 1', '2, 'wherein Zand Zare the same or different, and are selected from straight chain alkylene, alkyleneoxy, or alkylenethio having 2 to 20 carbon atoms;'}5. The metal bis(malonato)borate monomer of claim 1 ,{'sub': 1', '2, 'wherein Zand Zare the same or different, and are selected from straight chain alkylene, alkyleneoxy, or alkylenethio having 7 to 11 carbon atoms.'}6. The metal bis(malonato)borate monomer of claim 1 , wherein each of R claim 1 , R claim 1 , R claim 1 , R claim 1 , Rand Rhas 1 to 8 carbon atoms.7. The metal bis(malonato)borate monomer of claim 1 , wherein Rand Rare the same claim 1 , and R claim 1 , R claim 1 , Rand Rare the same.8. The metal bis(malonato)borate monomer of claim 1 , wherein R claim 1 , R claim 1 , Rand Rare the H claim 1 , and Rand Rare the same.9. The metal bis(malonato)borate monomer of claim 1 , wherein M is Li.12. The metal bis(malonato)borate monomer of claim 11 , wherein nand nare 2 to 12.13. The metal bis(malonato)borate monomer of claim 11 , wherein nand nare 7 to 12.17. The metal bis( ...

DERIVATIVES OF 1-AMINO-2-CYCLOPROPYLETHYLBORONIC ACID

The present invention provides novel compounds useful as proteasome inhibitors. The invention also provides pharmaceutical compositions comprising the compounds of the invention and methods of using the compositions in the treatment of various diseases. 121.-. (canceled)24. The process of claim 22 , wherein the reaction of step (1) or step (3) or both is conducted in the presence of a peptide coupling reagent.25. The process of claim 24 , wherein the peptide coupling reagent is selected from the group consisting of a carbodiimide reagent claim 24 , phosphonium reagent claim 24 , and uronium reagent.26. The process of claim 24 , wherein the peptide coupling reagent is selected from one or more of the group consisting of dicyclohexylcarbodiimide (DCC) claim 24 , 1-(3-dimethylaminopropyl-3-ethylcarbodiimide (EDC) claim 24 , benzothiazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate (BOP) claim 24 , O-(1H-benzotriazol-1-yl)-N claim 24 ,N claim 24 ,N′N′-tetramethyluronium tetrafluoroborate (TBTU) and diisopropylethylamine (DIPEA).27. The process of claim 22 , further comprising converting the carboxylic acid moiety of compound (II) to an activated ester or acid halide prior to the reaction of step (1).28. The process of claim 27 , wherein said activated ester or acid halide is an O—(N-hydroxysuccinnimide) ester.29. The process of claim 22 , wherein the reaction of step (3) is conducted in the presence of a polar aprotic solvent.30. The process of claim 29 , wherein the polar aprotic solvent is tetrahydrofuran (THF) or dimethylformamide (DMF) or a combination thereof.31. The process of claim 22 , wherein the reaction of step (4) comprises reacting the compound of Formula (iv) with a mineral acid.32. The process of claim 31 , wherein the mineral acid is hydrochloric acid.33. The process of claim 22 , wherein the reaction of step (4) is conducted in the presence of an organic boronic acid acceptor claim 22 , a lower alkanol claim 22 , a Chydrocarbon solvent ...

NOVEL LIPOGENIC INHIBITORS AND USES THEREOF

The present invention provides resveratrol-based boron-containing analog! methods of use thereof in treatment of dyslipidemias and cancer. 2. The compound of claim 1 , or pharmaceutically acceptable salt thereof or stereoisomer thereof claim 1 , wherein when Ris —OCH claim 1 , then Rand Rare —OCH.4. The compound of claim 1 , or pharmaceutically acceptable salt thereof or stereoisomer thereof claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rare claim 1 , independently claim 1 , —H claim 1 , —OH claim 1 , halogen claim 1 , —OCH claim 1 , —O—CH—N(H)(Boc) claim 1 , —O—CH—NH claim 1 , or —O—CHNHC(═O)CHOCHOCHOCHOCHNH.5. The compound of claim 1 , or pharmaceutically acceptable salt thereof or stereoisomer thereof claim 1 , wherein Ris —OH and R claim 1 , R claim 1 , Rand Rare —H; or wherein Ris —OH and R claim 1 , R claim 1 , Rand Rare —H; or wherein Rand Rare halogen and Ris —H claim 1 , and Rand Rare claim 1 , independently claim 1 , —H or —OH; or wherein R claim 1 , R claim 1 , Rare —OCHand Rand Rare —H claim 1 ,6. The compound of claim 5 , or pharmaceutically acceptable salt thereof or stereoisomer thereof claim 5 , wherein Ris —OH and R claim 5 , R claim 5 , Rand Rare —H.7. The compound of claim 6 , or pharmaceutically acceptable salt thereof or stereoisomer thereof claim 6 , wherein Rand Rare —Cl and R claim 6 , R claim 6 , and Rare —H.1721.-. (canceled)2334.-. (canceled)35. A composition claim 1 , comprising the compound claim 1 , pharmaceutically acceptable salt or stereoisomer claim 1 , of .36. (canceled)38. (canceled)39. A method of treating a dyslipidemia in a subject comprising administering to the subject the compound claim 1 , or pharmaceutically acceptable salt thereof or stereoisomer thereof claim 1 , of in an amount effective to treat the dyslipidemia in the subject.4055.-. (canceled) This application claims benefit of U.S. Provisional Application No. 61/443,426, filed Feb. 16, 2011, the contents of which are hereby incorporated by ...

ACTIVITY-BASED PROBES FOR THE UROKINASE PLASMINOGEN ACTIVATOR

The present invention relates to selective trypsine-like serine protease activity-based probes, in particular urokinase plasminogen activator-activity based probes, the use thereof and methods for detecting selective urokinase activity by making use of said probes. 2. A compound according to wherein{'sub': 1', '2', '3, 'Rand Rare each independently selected from the group consisting of —H and —NH—(C═O)—CH;'}{'sub': '3', 'Ris guanidino and is at the para position;'}{'sub': 4', '4, 'L is —(C═O)—O—R-triazole- or —(C═O)—R-triazole-;'}{'sub': 4', '2', 'n', '1-4', 'm', '1-4', 'm', '2', 'o, 'Ris selected from the group consisting of —(CH)—, —(Calkyl-O)—, or —(Calkyl-O)—(CH)—;'}m is 1, 2, 3, or 4;n is 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10;o is 1, 2, 3, or 4; andY represents a detectable label.3. A compound according to wherein the detectable label can be instrumentally detected by magnetic resonance imaging claim 1 , X-ray imaging claim 1 , ultrasound claim 1 , nuclear medicine imaging claim 1 , multimodal imaging claim 1 , fluorescence imaging claim 1 , bioluminescence imaging claim 1 , microscopy claim 1 , mass detectors claim 1 , wave length detectors claim 1 , phosphorescent imaging claim 1 , or chemiluminescent imaging.4. A compound according to claim 1 , wherein the detectable label is selected from radio-isotopes claim 1 , fluorophores claim 1 , imaging agents for MRI claim 1 , X-ray responsive agents claim 1 , and biotin labels or derivatives thereof.6. An intermediate compound according to claim 5 , wherein{'sub': 1', '2', '3, 'Rand Rare each independently selected from the group consisting of —H and —NH—(C═O)—CH;'}{'sub': '3', 'Ris guanidino and is at the para position;'}{'sub': 4', '4', '3', '4', '4', '3, 'B is selected from the group consisting of —(C═O)—O—R-alkyne, —(C═O)—O—R—N, —(C═O)—R-alkyne-, or —(C═O)—R—N;'}{'sub': 4', '2', 'n', '1-4', 'm', '1-4', 'm', '2', 'o, 'Ris selected from the group consisting of —(CH)—, —(Calkyl-O)—, or —(Calkyl-O)—(CH)—;'}m is 1, 2, 3, ...

PROCESS FOR THE PREPARATION OF NOVEL POLYMORPHIC FORMS OF 5-FLUORO-1,3-DIHYDRO-1-HYDROXY-2,1- BENZOXABOROLE

Novel polymorphic forms of tavaborole, Form A and Form B, and methods of making same are disclosed. Methods are disclosed for the manufacture of the novel polymorphic Forms A and B. Methods include dissolving tavaborole in a pharmaceutically acceptable solvent to obtain a mixture, heating the mixture until a clear solution is obtained, cooling the clear solution, stirring the clear solution to obtain a crystalline product, filtering the crystalline product, and drying the crystalline product to obtain the pharmaceutically acceptable crystalline form of tavaborole. Pharmaceutical composition are disclosed including a pharmaceutically acceptable crystalline form of tavaborole Form A and/or Form B. 1. Crystalline form A of tavaborole.2. The crystalline form A of tavaborole of having an X-ray powder diffractogram (XRPD) comprising at least one peak at diffraction 2-theta angle selected from 26.96 claim 1 , 26.19 claim 1 , and 14.28±2° theta.3. The crystalline form A of tavaborole of having an XPRD pattern as shown in .4. Crystalline form B of tavaborole.5. The crystalline form B of tavaborole of having an XRPD comprising at least one peak at diffraction 2-theta angle selected from 25.51 claim 4 , 12.72 and 6.39±2° theta.6. The crystalline form B of tavaborole according to having an XPRD pattern as shown in .7. A method for preparation of a pharmaceutically acceptable crystalline form of tavaborole comprising the steps of:dissolving tavaborole in a pharmaceutically acceptable solvent to obtain a mixture;heating the mixture until a clear solution is obtained;cooling the clear solution;stirring the clear solution to obtain a crystalline product;filtering the crystalline product; anddrying the crystalline product to obtain the pharmaceutically acceptable crystalline form of tavaborole.8. The method of wherein the pharmaceutically acceptable solvent is selected from one or more of water claim 7 , methanol claim 7 , ethanol claim 7 , m-propanol claim 7 , IPA claim 7 , n- ...

THERAPEUTIC BORON-CONTAINING COMPOUNDS

The present invention relates to compounds of Formula (I) wherein Rand Rare hydrogen; Rand R, which may be the same or different, are hydrogen, a Calkyl group optionally substituted by an aryl group which may itself be substituted, the substituent group including an alkyl group or an —OR group in which R is a Calkyl group, with one or more hydrogen atoms optionally replaced with a halogen atom; or an aryl group which may be substituted, the substituent group including an alkyl group or an —OR group in which R is a Calkyl group, with one or more hydrogen atoms optionally replaced with a halogen atom; with the proviso that Rand Rare not both hydrogen; the atom of Rwhich is attached to C is either a saturated carbon atom or an atom which is part of a 1 substituted aromatic ring; (AA)is an amino acid, amino acid derivative, peptide of up to 5 amino acids or a peptidomimetic thereof which optionally incorporates an N-terminal capping group, when the group is (AA)an N-terminal capping group is present, covalently attached to the nitrogen atom shown in Formula (I) and the capping group comprises at least 5 non-hydrogen atoms; Ris hydrogen or a C20 alkyl group, when AA=0, Rmay form a cyclic group with the N-terminal capping group; Rand Rindependently of one another denote hydrogen or a Calkyl group; or together with the boron atom and the oxygen atoms, form a mono-, bi- or tricyclic, saturated or partly unsaturated, mono-, di-, tri- or tetra-Calkylated or phenylated ring sysem having 5-18 ring members; and salt forms and stereoisomers thereof. The invention further relates to pharmaceutical formulations containing these compounds and the use of these compounds in therapy, particularly as antimicrobial agents, more particularly as an agent effective in treating a infection or a infection. (I) 3. The compound of or wherein one of Rand Ris methyl and the other group is either a methyl group or a group larger than methyl.4. The compound of or wherein Ror Ris a Calkyl group ...

PROCESS OF MARKING A TEXTILE SUBSTRATE

The invention relates to the marking of textile products that have been dyed using a supercritical dyeing process. More particularly, the invention provides a process of marking a textile substrate with a tracer, said process comprising contacting the textile substrate with a supercritical or near-critical dyeing medium containing a dye and a tracer, said tracer being selected from a metal chelate and a chemiluminescent agent. The process of the present invention uses the supercritical or near-critical dyeing medium as a vehicle for depositing a tracer onto the textile substrate that is also dyed using this medium. The presence of the deposited tracer on the dyed textile can be detected using a simple and reliable authentication method. The invention also concerns a marked textile product obtained by the aforementioned process. Also provided are a dyeing composition that can be used in the aforementioned process as well as methods for authenticating textile products that have been marked using his process.

BORON-CONTAINING SMALL MOLECULES

This invention provides novel compounds, methods of using the compounds, and pharmaceutical formulations comprising the compounds. 120-. (canceled)25. The method of claim 24 , wherein Ris fluoro claim 24 , chloro claim 24 , or bromo; Ris hydrogen claim 24 , fluoro claim 24 , or chloro; and Ris fluoro claim 24 , chloro claim 24 , or bromo.26. The method of claim 21 , wherein the compound is selected from5-(5-(3,5-Dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)benzo[c][1,2]oxaborol-1(3H)-ol;5-(5-(3,5-Dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-3,3-dimethyl-benzo[c][1,2]oxaborol-1(3H)-ol;(S)-5-(5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-3,3-dimethyl benzo[c][1,2]oxaborol-1(3H)-ol;(R)-5-(5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-3,3-dimethylbenzo[c][1,2]oxaborol-1(3H)-ol;5-(5-(3,5-Dibromophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-3,3-dimethyl-benzo[c][1,2]oxaborol-1(3H)-ol;5-(5-(3-Chloro-5-(trifluoromethyl)phenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-3,3-dimethylbenzo[c][1,2]oxaborol-1(3H)-ol;3,3-Dimethyl-5-(5-(3,4,5-trichlorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)benzo[c][1,2]oxaborol-1(3H)-ol;5-(5-(3,5-Dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-3,3-dimethyl-benzo[c][1,2]oxaborol-1(3H)-ol;5-(5-(3,5-Dichloro-4-methylphenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-3,3-dimethylbenzo[c][1,2]oxaborol-1(3H)-ol;5-(5-(3,5-Dichloro-4-(trifluoromethyl)phenyl)-5-(trifluoromethyl)-4,5-dihydro isoxazol-3-yl)-3,3-dimethyl-benzo[c][1,2]oxaborol-1(3H)-ol;5-(5-(3,5-Dichloro-4-(difluoromethyl)phenyl)-5-(trifluoromethyl)-4,5-dihydro isoxazol-3-yl)-3,3-dimethyl-benzo[c][1,2]oxaborol-1(3H)-ol;5-(5-(3,5-Dichloro-4-(trifluoromethoxy)phenyl)-5-(trifluoromethyl)-4,5-dihydro-isoxazol-3-yl)-3,3-dimethylbenzo[c][1,2]oxaborol-1(3H)-ol;5-(5-(3,5-Dichlorophenyl)-5-(perfluoroethyl)-4,5-dihydroisoxazol-3-yl)-3,3-dimethylbenzo[c][1,2]oxaborol-1(3H)-ol;5-(5-(3,5 ...

METHOD OF DYE CLEARING TEXTILES

A process to remove excess dye from dyed polyester fabric comprising adding a solution of a weak organic acid to the fabric in a dyeing vessel, raising the temperature in the vessel to at least 80° C., allowing the acid to react with the fabric for at least 6 minutes and removing all liquid. 1. A process to remove excess dye from dyed polyester fabric comprising (a) adding a reduction clearing agent which is a weak organic acid or salt thereof to the fabric in a dyeing vessel , (b) raising the temperature in the vessel , (c) allowing the acid or salt thereof to remain in contact with the fabric for a period of time , (c1) raising the pH to between pH 9 and pH 12 , and (d) removing all liquid.2. The process according to which comprises the additional step of removing dyeing liquor from the dyeing vessel prior to (a).3. The process according to claim 1 , where in step (c) the weak organic acid or salt thereof remains in contact with the fabric for at least 6 minutes claim 1 , and/or for up to 60 minutes.4. The process according to claim 1 , where in step (b) the temperature in the vessel is raised to a value in the range of from 60 to 100° C.5. The process according to claim 1 , in which the weak organic acid is selected from those having at least 4 carbon atoms and a pKor pKvalue of at least 1.6. The process according to wherein the weak organic acid is ascorbic acid or salt thereof.7. The process according to wherein the weak organic acid is ascorbic acid.8. The process according to wherein the salt of the weak organic acid is selected from an alkali metal salt.9. The process according to comprising the additional step of rinsing the fabric with water at ambient temperature after the removal of all liquid.10. The process according to wherein an alkaline hydroxide is used to raise the pH.11. The process according to wherein the weak organic acid or salt thereof is added at a rate of from 80 g to 120 g per litre.12. The process according to wherein the weak organic ...

BORONATE ESTER COMPOUNDS AND PHARMACEUTICAL COMPOSITIONS THEREOF

The present invention provides novel compounds useful as proteasome inhibitors. The invention also provides pharmaceutical compositions comprising the compounds of the invention and methods of using the compositions in the treatment of various diseases. 2. The process of claim 1 , wherein the reaction of step (1) or step (3) or both is conducted in the presence of a peptide coupling reagent.3. The process of claim 2 , wherein the peptide coupling reagent is selected from the group consisting of a carbodiimide reagent claim 2 , phosphonium reagent claim 2 , and uronium reagent.4. The process of claim 3 , wherein the peptide coupling reagent is selected from one or more of the group consisting of dicyclohexylcarbodiimide (DCC) claim 3 , 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide (EDC) claim 3 , benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate (BOP) claim 3 , and O-(1H-benzotriazol-1-yl)-N claim 3 ,N claim 3 ,N′N′-tetramethyluronium tetrafluoroborate (TBTU).5. The process of claim 1 , further comprising converting the carboxylic acid moiety of compound (ii) to an activated ester or acid halide prior to the reaction of step (1).6. The process of claim 5 , wherein said activated ester or acid halide is an O—(N-hydroxysuccinnimide) ester.7. The process of claim 1 , wherein the reaction of step (3) is conducted in the presence of a solvent.8. The process of claim 7 , wherein the solvent is tetrahydrofuran.9. The process of claim 1 , wherein the reaction of step (4) is conducted in the presence of an aqueous mineral acid.10. The process of claim 9 , wherein the mineral acid is hydrochloric acid.11. The process of claim 1 , wherein the reaction of step (4) is conducted in the presence of an organic boronic acid acceptor.12. The process of claim 11 , wherein the organic boronic acid acceptor is i-BuB(OH).13. The process of claim 1 , wherein the reaction of step (5) is conducted in the presence of a solvent selected from the group consisting of ethyl ...

PROCESS FOR PRODUCING A CATIONIC DYEABLE POLYESTER AND THE CATIONIC DYEABLE POLYESTER PRODUCED THEREBY

A process for producing a cationic dyeable polyester includes the steps of: 2. The process according to claim 1 , wherein each Rrepresents hydrogen.3. The process according to claim 1 , wherein the sulfo group-containing aromatic dicarboxylic acid dyeable monomer is selected from the group consisting of 2-sulfoterephthalic acid monosodium salt claim 1 , 5-sulfoisophthalic acid monosodium salt claim 1 , and a combination thereof.4. The process according to claim 1 , wherein a molar ratio of the bis-hydroxy alkyl terephthalate monomer to the aromatic dicarboxylic acid monomer is in a range from 1.5:1 to 150:1.5. The process according to claim 1 , wherein a molar ratio of the bis-hydroxy alkyl terephthalate monomer to the sulfo group-containing aromatic dicarboxylic acid dyeable monomer is in a range from 1.3:1 to 100:1.6. The process according to claim 1 , wherein the aromatic dicarboxylic acid monomer is selected from the group consisting of terephthalic acid claim 1 , isophthalic acid claim 1 , phthalic acid claim 1 , diphenic acid claim 1 , 2 claim 1 ,6-naphthalic acid claim 1 , 1 claim 1 ,5-naphthalic acid claim 1 , and combinations thereof.7. The process according to claim 1 , wherein in step (a) claim 1 , the esterification reaction is implemented at a normal pressure.8. The process according to claim 1 , wherein in step (b) claim 1 , the polycondensation reaction is implemented in the presence of a transition metal-containing polycondensation catalyst.9. A cationic dyeable polyester produced by the process according to .10. The cationic dyeable polyester according to claim 9 , having an average aggregate radius of up to 2.3 nm. This application claims priority of Taiwanese Application No. 107126282, filed on Jul. 30, 2018.The disclosure relates to a process for producing a polyester, and more particularly to a process for producing a cationic dyeable polyester. The disclosure also relates to the cationic dyeable polyester produced by the process.A conventional ...

SYNTHESIS OF BORONIC ESTER AND ACID COMPOUNDS

The invention relates to the synthesis of boronic ester and acid compounds. More particularly, the invention provides improved synthetic processes for the large-scale production of boronic ester and acid compounds, including the peptide boronic acid proteasome inhibitor bortezomib. 43. The composition of any one of - claims 1 , wherein the solubility of water in the ether solvent is less than about 2% w/w.53. The composition of any one of - claims 1 , wherein the ether solvent is selected from the group consisting of tert-butyl methyl ether claims 1 , tert-butyl ethyl ether claims 1 , tert-amyl methyl ether claims 1 , isopropyl ether claims 1 , and mixtures thereof.63. The composition of any one of - claims 1 , wherein Ris Caliphatic claims 1 , Caryl claims 1 , or (Caryl)(Caliphatic).73. The composition of any one of - claims 1 , characterized by at least one of the following features:{'sup': '3', '(a) Ris chloro;'}{'sup': '2', '(b) Ris hydrogen; and'}{'sup': '1', 'sub': '1-4', '(c) Ris Caliphatic'}10. The composition of comprising at least about 20 moles of the boronic ester compound of formula (I).11. The composition of claim 3 , wherein the carbon atom to which R claim 3 , R claim 3 , and Rare attached has a diastereomeric ratio of at least about 97:3 claim 3 , relative to a chiral center in the R-Rchiral moiety.12. The composition of claim 3 , wherein all of the boronic ester compound of formula (I) present in the composition is produced in a single batch run.17. The process of or claim 3 , wherein the sterically hindered base is an alkali metal dialkylamide base of formula MN(R) claim 3 , wherein Mis selected from the group consisting of Li claim 3 , Na claim 3 , and K claim 3 , and each R claim 3 , independently claim 3 , is a branched or cyclic Caliphatic.18. The process of claim 16 , wherein the organic solvent in step (a) is selected from the group consisting of acetonitrile claim 16 , toluene claim 16 , hexane claim 16 , heptane claim 16 , and mixtures ...

DISPERSE DYE MIXTURES, THEIR PREPARATION AND USE

The present invention relates to dye mixtures containing at least one dye of formula (I) and at least either a dye of formula (II) and/or at least one dye of formula (III) where R-R, n, o, X and D-Dare each as defined in claim . These dye mixtures are useful for dyeing or printing hydrophobic materials in particular. 117-. (canceled)19. The dye mixture as claimed in claim 18 , containing compounds of formula I where{'sup': '1', 'Ris hydrogen, —NHCO-methyl, methyl or hydroxyl,'}{'sup': '2', 'Ris hydrogen or methoxy,'}{'sup': '3', 'sub': 2', '4', '2', '3, 'Ris hydrogen, benzyl, 2-cyanoethyl, methyl, ethyl, n-propyl, n-butyl or —CH—COO—CH—CO—CH,'}{'sup': '4', 'Ris hydrogen or methyl,'}{'sup': '5', 'Ris methyl,'}{'sup': '6', 'Ris hydrogen,'}{'sup': '7', 'Ris hydrogen or methyl, and'}n is 0 or 1.20. The dye mixture as claimed in claim 18 , containing compounds of formula II where{'sup': '8', 'Ris hydrogen, methyl, —NHCO-methyl or hydroxyl,'}{'sup': '9', 'Ris hydrogen, chlorine, methoxy or methyl,'}{'sup': '10', 'sub': x', '2x', '3', 'x', '2x', '2', '5', 'x', '2x', '3', 'x', '2x', '2', '5', 'x', '2x', '3, 'Ris hydrogen, methyl, ethyl, benzyl, —CH—O—CHwhere x=1 or 2, —CH—COO—CHwhere x=1 or 2, —CH—COO—CHwhere x=1 or 2, —CH—OCO—CHwhere x=1 or 2 and —CH—OCO—CHwhere x=1 or 2,'}{'sup': '11', 'Ris hydrogen or methyl,'}{'sup': '12', 'sub': x', '2x', '3', 'x', '2x', '2', '5', 'x', '2x', '3', 'x', '2x', '2', '5', 'x', '2x', 'y', '2y', 'x', '2x', 'y', '2y', 'x', '2x', 'y', '2y', 'z', '2z', '6', '5, 'Ris methyl, ethyl, 2-(N-phthalimidoyl)ethyl, cyanomethyl, 2-cyanoethyl, —CH—OCO—CHwhere x=1 or 2, —C—H—OCO—CHwhere x=1 or 2, —CH—COO—CHwhere x=1 or 2, —CH—COO—CHwhere x=1 or 2, —CH—OCO—CH—(N-phthalimidoyl) where x and y are each independently=1 or 2, —CH—COO—CH—(N-phthalimidoyl) where x and y are each independently=1 or 2, —CH—COO—CH—OCO—CH—CHwhere x, y and z are each independently=1 or 2,'}X is —CO—O—, —O—CO— or —O—, andm is 0 or 1.21. The dye mixture as claimed in claim 19 , containing ...

LEATHER-LIKE SHEET AND FIBER STRUCTURE

A leather-like sheet including: a fiber structure including fibers dyed with a dye containing a blue cationic dye having an azo bond; and an elastic polymer applied into internal voids of the fiber structure, wherein the leather-like sheet further includes a polyhydric phenol derivative having anionic properties, or the fiber structure is disclosed. Also disclosed is a fiber structure including fibers dyed with a dye containing a blue cationic dye having an azo bond, or a leather-like sheet including the fiber structure and an elastic polymer applied into internal voids of the fiber structure, wherein the leather-like sheet has a color difference (ΔE) before and after a moist heat treatment, determined when subjected to the moist heat treatment at 80° C. and a humidity of 90% for 48 hours, of ΔE≤2. 1: A leather-like sheet , comprising:a fiber structure comprising fibers comprising a dye comprising a blue cationic dye having an azo bond; and an elastic polymer in internal voids of the fiber structure,wherein the leather-like sheet further comprises a polyhydric phenol derivative having anionic properties.2: The leather-like sheet of claim 1 , wherein the blue cationic dye having the azo bond comprises C.I. Basic Blue 54.3: The leather-like sheet of claim 1 , wherein the fibers have a fineness of 0.05 to 1 dtex.4: The leather-like sheet of claim 1 , wherein the fibers are polyester fibers.5: The leather-like sheet of claim 1 , which has a color difference (ΔE) before and after a moist heat treatment claim 1 , determined when subjected to the moist heat treatment at 80° C. and a humidity of 90% for 48 hours claim 1 , of ΔE≤2.6: The leather-like sheet of claim 1 , which has a surface having an L* of ≤35 in a color coordinate space (L*a*b* color space).7: The leather-like sheet of claim 1 , which is a suede-like artificial leather having a napped surface.8: A leather-like sheet claim 1 , comprising:a fiber structure comprising fibers comprising a dye comprising a blue ...

METHOD FOR DECOLORIZATION OF A DYED POLYESTER FIBER

A method for decolorization of a dyed polyester fiber includes: separately providing a dyed polyester fiber stained with a dye, and a solvent capable of dissolving the dye; heating the solvent to produce a fresh vapor of the solvent, the temperature of the fresh vapor ranging between the glass transition temperature and the melting point of the polyester fiber; condensing the fresh vapor to form a condensed fluid of the solvent; contacting the dyed polyester fiber with the condensed fluid of the solvent that has a temperature sufficient to dissolve the dye such that the dye is extracted from the dyed polyester fiber so as to form a dye-containing solution and a decolorized polyester fiber; and separating the dye-containing solution from the decolorized polyester fiber. 1. A method for decolorization of a dyed polyester fiber , comprising the steps of:(a) separately providing a dyed polyester fiber stained with a dye, and a solvent that is capable of dissolving the dye;(b) heating the solvent to produce a fresh vapor of the solvent, the temperature of the fresh vapor ranging between the glass transition temperature and the melting point temperature of the polyester fiber;(c) condensing the fresh vapor to form a condensed fluid of the solvent;(d) contacting the dyed polyester fiber with the condensed fluid of the solvent that has a temperature sufficient to dissolve the dye such that the dye is extracted from the dyed polyester fiber so as to form a dye-containing solution and a decolorized polyester fiber; and(e) separating the dye-containing solution from the decolorized polyester fiber.2. The method as claimed in claim 1 , wherein the solubility parameter of the solvent is from 17 to 40 (J/cm).3. The method as claimed in claim 1 , wherein the solvent is selected from the group consisting of xylene claim 1 , 1-hexanol claim 1 , ethylene glycol claim 1 , diethylene glycol claim 1 , 1 claim 1 ,3-propanediol claim 1 , 1 claim 1 ,4-butanediol claim 1 , dimethylformamide ...

NAPPED ARTIFICIAL LEATHER DYED WITH CATIONIC DYE, AND METHOD FOR MANUFACTURING THE SAME

Disclosed is a napped artificial leather dyed with a cationic dye, including: a non-woven fabric of a cationic dyeable polyester fiber having a fineness of 0.07 to 0.9 dtex; and an elastic polymer provided inside the non-woven fabric, wherein the napped artificial leather has L* value≦50, a grade of color difference determined in an evaluation of color migration to PVC under a load 0.75 kg/cm at 50° C. for 16 hours, of 4 or more, a tear strength per mm of thickness of 30 N or more, and a peel strength of 3 kg/cm or more. 1. A napped artificial leather dyed with a cationic dye , comprising:a non-woven fabric of cationic dyeable polyester fibers having a fineness of 0.07 to 0.9 dtex; and an elastic polymer provided inside the non-woven fabric, [{'br': None, 'L*value≦50,'}, 'a grade of color difference, determined in an evaluation of color migration to PVC under a load of 0.75 kg/cm at 50° C. for 16 hours, of 4 or more,', 'a tear strength per mm of thickness of 30 N or more, and', 'a peel strength of 3 kg/cm or more., 'wherein the napped artificial leather has'}2. The napped artificial leather according to claim 1 , wherein the napped artificial leather has a chlorine content of 90 ppm or less.3. The napped artificial leather according to claim 1 , wherein the napped artificial leather has a Martindale abrasion loss (12 KPa) of 100 mg or less after 35000 times of rubbing.4. The napped artificial leather according to claim 1 , wherein the cationic dyeable polyester fibers are filaments.6. The napped artificial leather according to claim 5 , wherein the cationic dyeable polyester fibers contain claim 5 , as the dicarboxylic acid unit claim 5 , a 1 claim 5 ,4-cyclohexanedicarboxylic acid unit and an adipic acid unit each in a range of 1 to 6 mol %.7. The napped artificial leather according to claim 5 , wherein the cationic dyeable polyester fibers contain claim 5 , as the dicarboxylic acid unit claim 5 , an isophthalic acid unit in a range of 1 to 6 mol %.8. The napped ...

METHOD FOR SYNTHESIZING BORONATE ESTER COMPOUND, SODIUM SALT OF BORONATE ESTER COMPOUND, AND METHOD FOR SYNTHESIZING THE SAME

An object is to establish a technology with which a boronate ester compound can be easily and efficiently synthesized at a low cost with a small number of steps without the need for a complex chemical method and reagents that need to be carefully handled. A further object is to establish a sodium salt of a boronate ester compound that is a novel compound and a technology for synthesizing the sodium salt of a boronate ester compound. Provided are a sodium salt of a boronate ester compound and a method for synthesizing a boronate ester compound or a sodium salt of a boronate ester compound that includes reacting, in a reaction solvent, an organic chloride with a dispersion product obtained by dispersing sodium in a dispersion solvent to obtain an organic sodium compound, and reacting the obtained organic sodium compound with a borate ester compound to obtain a boronate ester compound or a sodium salt of a boronate ester compound. 3. The method for synthesizing a boronate ester compound according to claim 1 ,wherein a molar ratio of the dispersion product obtained by dispersing sodium in a dispersion solvent to the organic chloride is at least 2.6. The method for synthesizing a sodium salt of a boronate ester compound according to claim 5 ,wherein a molar ratio of the dispersion product obtained by dispersing sodium in a dispersion solvent to the organic chloride is at least 2. The present invention relates to a method for synthesizing a boronate ester compound, a sodium salt of a boronate ester compound, and a method for synthesizing a sodium salt of a boronate ester compound.BACKGROUND ARTOrganic boron compounds such as boronate ester compounds are used for natural product total synthesis and organic synthesis reactions of various functional materials such as medicines, agricultural chemicals, electronic materials such as liquid crystal and organic EL, and intermediate products thereof, for example. In particular, organic boronic acid compounds are often used as ...

Garment with customizable face covering

Disclosed herein is a customized garment a method of forming the customized garment. The method involves first forming a garment having an integrated gaiter coupled to a neckline of the customized garment. The integrated gaiter has a customizable insert coupled to a front portion of the integrated gaiter. The integrated gaiter is stretched over a platen so that an entirety of the customizable insert is flat. Heat transfer sublimation is used to transfer imagery from sublimation paper to the customizable insert.

SYNTHETIC METHODS FOR DIBORON REAGENTS AND RELATED COMPOUNDS

The disclosure is directed to diboron compounds, related methods of making, and related intermediate boron and diboron compounds used to make the same. The diboron compounds can be used as reagents to prepare chemical intermediates that are used in pharmaceutical, agrochemical, and specialty electronics industries. The disclosed processes and compounds provide simplified synthetic paths that significantly reduce steps, improve scalability, and minimize costs for producing the diboron reagents. 2. A method for forming the boron compound of claim 1 , the method comprising:(a) reacting at least one of an alkane diol and an alkane dithiol with a boron trihalide to form a product; and{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(b) reacting the product of part (a) with at least one of a tri(alkyl and/or aryl) amine and a tri(alkyl and/or aryl) phosphine to form the boron compound of .'}4. A method for forming a diboron compound claim 1 , the method comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(a) reacting the boron compound of with a metal to form a diboron compound.'}5. A method for forming a tetraalkoxy diboron compound claim 1 , the method comprising:{'claim-ref': {'@idref': 'CLM-00003', 'claim 3'}, '(a) reacting the diboron compound of with one or more alkanols having at least one hydroxy group to form the tetraalkoxy diboron compound.'}9. A method for forming a diboron compound claim 1 , the method comprising:{'claim-ref': {'@idref': 'CLM-00006', 'claim 6'}, '(a) reacting the boron compound of with a metal to form the diboron compound.'}10. A method for forming a tetraalkoxy diboron compound claim 1 , the method comprising:{'claim-ref': {'@idref': 'CLM-00008', 'claim 8'}, '(a) reacting the diboron compound of with one or more alkanols having at least one hydroxy group to form the tetraalkoxy diboron compound.'}11. A method for forming a diboron compound claim 1 , the method comprising: (i) the 4-coordinate boron compound comprises (A) a boron ...

WATERLESS DYEING METHOD AND YARN PRODUCED BY WATERLESS DYEING

A polymer phase colored performance fabric is disclosed, which is formed of a fabric of a solution dyed yarn woven with an elastic yarn, the fabric comprising at least 60% by volume of the solution dyed yarn. The solution dyed yarn is formed of a synthetic substance in a polymer phase that is combined with a colored dye, the combination producing a polymer phase colorant comprising a masterbatch of colored chips, a portion of which is heated to a liquid polymer colorant. The liquid polymer colorant is extruded to form a thread-shaped colored fiber of the synthetic substance, which is then cooled to form the solution dyed yarn. 1. A method of producing a polymer phase colored performance fabric , the method comprising:combining a synthetic substance in a polymer phase with a colored dye, the combining to produce a polymer phase colorant comprising a masterbatch of colored chips;heating at least a portion of the masterbatch of colored chips to melt the portion of the masterbatch to a liquid polymer colorant;extruding the liquid polymer colorant to form a thread-shaped colored fiber of the synthetic substance;cooling the thread-shaped colored fiber of the synthetic substance to form a solution dyed yarn; andweaving the solution dyed yarn with an elastic yarn to produce the polymer phase colored performance fabric, the polymer phase colored performance fabric being formed of at least 60% by volume of the solution dyed yarn.2. The method in accordance with claim 1 , wherein the weight of the polymer phase colored performance fabric is between 15 and 70 denier.3. The method in accordance with claim 1 , wherein combining the insoluble dye with the synthetic substance in the polymer phase further comprises includes enabling the insoluble dye to molecularly bond with the synthetic substance in the polymer phase.4. The method in accordance with claim 1 , wherein the synthetic substance in the polymer phase is polyethylene terephthalate claim 1 , and wherein the masterbatch of ...

SILYLATION OF AROMATIC HETEROCYCLES BY DISILANES USING POTASSIUM ALKOXIDE CATALYSTS

The present invention describes chemical systems and methods for silylating heteroaromatic organic substrates using at least alkoxide base, preferably a potassium alkoxide base and at least one organodisilane and (b) at least one alkoxide base. Both methods and compositions for affecting these transformations are disclosed. 2. The method of claim 1 , wherein the mixture and substrate are free of added transition-metal compounds or catalysts.3. The method of claim 1 , wherein at least one R is hydrogen claim 1 , and each remaining R is independently Calkyl.4. The method of claim 1 , wherein the at least one potassium alkoxide comprises a Calkyl moiety.5. The method of claim 1 , wherein the at least one potassium alkoxide comprises a Caryl or Caryl heteroaryl moiety.6. The method of claim 1 , wherein the at least one potassium alkoxide comprises potassium methoxide claim 1 , potassium ethoxide claim 1 , potassium propoxide claim 1 , or potassium butoxide.7. The method of claim 1 , wherein the at least one potassium alkoxide comprises potassium tent-butoxide.8. The method of claim 1 , wherein the substrate comprises an optionally substituted furan claim 1 , pyrrole claim 1 , thiophene claim 1 , pyrazole claim 1 , or imidazole moiety.9. The method of claim 1 , wherein the substrate comprises an optionally substituted benzofuran claim 1 , benzopyrrole claim 1 , benzothiophene claim 1 , indole claim 1 , azaindole claim 1 , dibenzofuran claim 1 , xanthene claim 1 , dibenzopyrrole claim 1 , pyridine claim 1 , a pyrrolopyridine claim 1 , a pyrrolopyrimidine claim 1 , or a dibenzothiophene.10. The method of claim 1 , wherein the substrate comprises an optionally substituted furan claim 1 , pyrrole claim 1 , thiophene claim 1 , pyrazole claim 1 , imidazole claim 1 , triazole claim 1 , isoxazole claim 1 , oxazole claim 1 , thiazole claim 1 , isothiazole claim 1 , oxadiazole claim 1 , pyridine claim 1 , pyridazine claim 1 , pyrimidine claim 1 , pyrazine claim 1 , triazone claim ...

COMPOUNDS CONTAINING ALKYL-ALKOXY-CYANO-BORATE ANIONS

The invention relates to new compounds containing alkyl-alkoxy-cyano-borate anions, their preparation and their use, in particular as part of electrolyte formulations for electrochemical or optoelectronic devices. 1. Compounds of formula I{'br': None, 'sup': z+', '1', '−, 'i': 'z', 'sub': '2', '[Kt][(R)B(CN)(OR*)]\u2003\u2003I'}in which{'sup': '1', 'Rdenotes a straight-chain or branched alkyl group having 1 to 20 C atoms which optionally may contain at least one Cl, Br or I atom, at least one CN group and/or one or more oxygen or sulphur atoms, a straight-chain or branched alkenyl group having 2 to 20 C atoms and having one or more double bonds or a straight-chain or branched alkinyl group having 1 to 20 C atoms and having one or more triple bonds and optionally may have a double bond,'}z is 1, 2, 3 or 4,R* denotes a straight-chain or branched alkyl group having 1 to 20 C atoms and{'sup': 'z+', '[Kt] is an inorganic or organic cation.'}3. A compound of formula I according to claim 1 , characterized in that R′ in formula I is each independently a straight-chain or branched alkyl group having 1 to 4 C atoms or a straight-chain or branched alkyl group having 1 to 4 C atoms in which one H atom is substituted by Br or CN or a straight-chain or branched alkyl group having 1 to 4 C atoms containing one oxygen atom.4. Process for the preparation of a compound of formula I according to claim 1 , {'br': None, 'sup': z+', '1', '−, 'sub': '3', '[Kt][(R)BF]\u2003\u2003II'}, 'comprising the reaction of a compound of formula II'}{'sup': 'z+', 'in which [Kt] and R′ have a meaning as for the compound of formula I, with'} {'br': None, 'sub': '3', '(Alkyl)SiOR*\u2003\u2003III,'}, 'a compound of formula III'}in which “Alkyl” each independently denotes a straight-chain or branched alkyl having 1 to 8 C atoms and R* has a meaning as for the compound of formula I,and trialkylsilylcyanide, in which the alkyl groups are each independently of one another straight-chain or branched alkyl ...

High wet fast disperse dye mixtures of n-[4-(5-fluoro-2,4-dinitro-phenylazo)-phenyl]-amine derivatives and n-[4-(4-nitro-phenylazo)-phenyl]-amine derivatives

The present invention is directed to dye mixtures comprising dyes of formula (1) and dyes of formula (2), the process of the production and the use of the dye mixtures.

DERIVATIVES OF 1-AMINO-2-CYCLOPROPYLETHYLBORONIC ACID

The present invention provides novel compounds useful as proteasome inhibitors. The invention also provides pharmaceutical compositions comprising the compounds of the invention and methods of using the compositions in the treatment of various diseases. 2. The compound of claim 1 , wherein P is R—C(O)— claim 1 , R—O—C(O)— claim 1 , R—N(R)—C(O)— claim 1 , R—S(O)— claim 1 , or R—N(R)—S(O)—;{'sup': c', 'D', '1', 'D, 'sub': 1-6', '1-6, 'Ris selected from the group consisting of Caliphatic, Cfluoroaliphatic, —R, -T-R, and'}{'sup': 1', '2c, 'claim-text': [{'sup': 1', '3a', '3b', '5', '5, 'sub': '1-6', 'Tis a Calkylene chain substituted with 0-2 independently selected Ror R, wherein the alkylene chain optionally is interrupted by —C(R)═C(R)—, —C═C—, or —O—;'}, {'sup': 'D', 'Ris a substituted or unsubstituted monocyclic, bicyclic or tricyclic ring system;'}, {'sup': 2c', '5', '6', '6', '6', '4', '4', '4', '5', '4', '4', '4', '6', '4', '6', '4', '4', '5', '4', '5', '5', '4, 'sub': 2', '2', '2', '2', '2', '2', '2', '2', '2', '2', '2', '2, 'Ris halo, —OR, —SR, —S(O)R, —SOR, —SON(R), —N(R), —NRC(O)R, —NRC(O)N(R), —NRCOR, —N(R)SOR, —N(R)SON(R), —O—C(O)R, —OC(O)N(R), —C(O)R, —COR, or —C(O)N(R);'}, {'sup': 3a', '4, 'sub': 1-4', '2', '1-4', '2', '2', '1-4', '2', '1-4, 'each Rindependently is selected from the group consisting of —F, —OH, —O(Calkyl), —CN, —N(R), —C(O)(Calkyl), —COH, —CO(Calkyl), —C(O)—NH, and —C(O)—NH(Calkyl);'}, {'sup': 3b', '3a', '7, 'sub': '1-3', 'each Rindependently is a Caliphatic substituted or unsubstituted with Ror R;'}, {'sup': '7', 'each Ris a substituted or unsubstituted aromatic group; and'}], 'T-R;'}{'sup': '4c', 'sub': 1-4', '1-4', '6-10', '1-4, 'Ris hydrogen, Calkyl, Cfluoroalkyl, or Car(C)alkyl, the aryl portion of which is substituted or unsubstituted.'}4. The compound of claim 3 , wherein A is 0.5. The compound of claim 3 , wherein each Ris independently Caliphatic claim 3 , Cfluoroaliphatic claim 3 , or —(CH)—CH—R claim 3 , and m is 0 or 1.6. The ...

TRANSFER TEXTILE PRINTING METHOD

The object is to provide a transfer textile printing method that satisfies general versatility, simplicity, fixing property, color development property and fineness. 1. A transfer textile printing method comprisinga step (1) of preparing a transfer paper,a step (2) of forming a pattern using a pigment ink on the transfer paper to obtain a printed transfer paper,a step (3) of bringing the printed transfer paper and a textile printing medium into close contact with each other and heating and pressurizing,a step (4) of performing a heat treatment without pressurizing while the printed transfer paper and the textile printing medium remain in close contact with each other, anda step (5) of removing the printed transfer paper from the textile printing medium, wherein the transfer textile printing method comprises the step (3), the step (4), and the step (5) in this order.2. A transfer textile printing method comprisinga step (1) of preparing a transfer paper,a step (2) of forming a pattern using a pigment ink on the transfer paper to obtain a printed transfer paper,a step (3) of bringing the printed transfer paper and a textile printing medium into close contact with each other and heating and pressurizing,a step (4) of releasing the pressurization, and performing a heat treatment without pressurizing while the printed transfer paper and the textile printing medium remain in close contact with each other, anda step (5) of removing the printed transfer paper from the textile printing medium,wherein the step (4) is executed after the step (3), and the step (5) is executed after the step (4).3. The transfer textile printing method according to claim 1 , further comprising a step (6) of washing the textile printing medium with water after the step (5).4. The transfer textile printing method according to claim 1 , wherein in the step (3) claim 1 , the heating is performed at a temperature of 120° C. or higher and 200° C. or lower claim 1 , and the heating and pressurizing time ...

Process of Dyeing Patterns of Textile

A dyeing process includes weaving patterns on a textile of nylon, CD yarn and polyester; pouring acidic dye, cationic dye and dispersive dye into a dyeing machine; adding auxiliary coloring agent, homogeneous coloring agent and coloring retardant into the dyeing machine wherein the auxiliary coloring agent is prepared by adding 1 g of acetic acid to 1 liter of water to form a solution which is adjusted to have a pH between 4 and 5; the homogeneous coloring agent is prepared by adding 1 g of homogeneous coloring agent to 0.1 kg of textile; and the color retardant is prepared by adding 1 g of sodium sulfate to 1,000 g of water; putting the textile in the dyeing machine to dye as a finished textile. Each pattern woven by a different textile material has a color corresponding to the applied dye. The color of patterns is the color of the dye applied to the patterns. 1. A process of dyeing patterns of a textile , comprising the steps of:(A) weaving a plurality of patterns on a textile formed of a plurality of textile materials including nylon, cationic polyester yarn (CD yarn) and polyester;(B) simultaneously pouring acidic dye, cationic dye and dispersive dye into a dyeing machine wherein color depth of the dispersive dye is less than that of each of the acidic dye and the cationic dye;(C) adding auxiliary coloring agent, homogeneous coloring agent and coloring retardant into the dyeing machine wherein the auxiliary coloring agent is prepared by adding 1 g of acetic acid to 1 liter of water to form a solution, and the solution is adjusted to have a pH between 4 and 5 wherein adjustment of the pH between 4 and 5 occurs after the step of pouring acidic dye, cationic dye and dispersive dye into the dyeing machine; the homogeneous coloring agent is one used by nylon, and is prepared by adding 1 g of homogeneous coloring agent to 0.1 kg of textile; and the color retardant is prepared by adding 1 g of sodium sulfate to 1,000 g of water;(D) putting the textile in the dyeing ...

BORON-CONTAINING SMALL MOLECULES

This invention relates to compounds useful for treating fungal infections, more specifically topical treatment of onychomycosis and/or cutaneous fungal infections. This invention is directed to compounds that are active against fungi and have properties that allow the compound, when placed in contact with a patient, to reach the particular part of the skin, nail, hair, claw or hoof infected by the fungus. In particular the present compounds have physiochemical properties that facilitate penetration of the nail plate. 9. The pharmaceutical formulation of claim 6 , wherein Ris a member selected from a negative charge claim 6 , H and a salt counterion.10. The pharmaceutical formulation of claim 9 , wherein Rand Rare H.11. The pharmaceutical formulation of claim 6 , wherein one member selected from Rand Ris H and the other member selected from Rand Ris a member selected from halo claim 6 , methyl claim 6 , cyano claim 6 , methoxy claim 6 , hydroxymethyl and p-cyanophenyloxy.12. The pharmaceutical formulation of claim 6 , wherein Rand Rare members independently selected from fluoro claim 6 , chloro claim 6 , methyl claim 6 , cyano claim 6 , methoxy claim 6 , hydroxymethyl claim 6 , and p-cyanophenyl.13. The pharmaceutical formulation of claim 6 , wherein Ris a member selected from a negative charge claim 6 , H and a salt counterion; Ris H; Ris F and Ris H.14. The pharmaceutical formulation of claim 6 , wherein Ris a member selected from a negative charge claim 6 , H and a salt counterion; Ris H; Ris 4-cyanophenoxy and Ris H.15. The pharmaceutical formulation of claim 4 , wherein Rand R claim 4 , along with the atoms to which they are attached claim 4 , are joined to form a phenyl group.17. The pharmaceutical formulation of claim 4 , wherein said excipient is a pharmaceutically acceptable topical carrier.18. The pharmaceutical formulation of claim 4 , wherein said compound is present in said pharmaceutical formulation in a concentration of from about 1% to about 10%.19. A ...

METHOD FOR PREPARING BORATE ESTER ON BASIS OF TRICYCLOPENTADIENYL RARE EARTH METAL COMPLEX

Disclosed is a method for preparing a borate ester on the basis of a tricyclopentadienyl rare earth metal complex, the method comprising the following steps: uniformly stirring and mixing a catalyst, a borane and a carbonyl compound for reaction to prepare a borate ester, wherein the catalyst is a tricyclopentadienyl rare earth metal complex; and the molecular formula of the tricyclopentadienyl rare earth metal complex can be expressed as: Ln(Cp), wherein Ln represents a rare metal selected from one of lanthanide elements. The preparation method has a higher catalytic activity, mild reaction conditions, a product that is easy to post-treat, a short reaction time, a low catalyst consumption amount, and a good range of applicable substrates, and can be used for industrial production. 3. The method according to claim 1 , wherein the dosage of tricyclopentadienyl rare earth metal complex is 0.01-1% of molar amount of carbonyl compounds; wherein the molar ratio of the borane and carbonyl compounds is 1-1.2:1.4. The method according to claim 1 , wherein the reaction is carried out in organic solvents; wherein the reaction time between 30 min-1 h; wherein the reaction is at room temperature.5. The method according to claim 1 , further comprising: when the reaction is over claim 1 , subtracting pressure and detaching solvent of reaction solution claim 1 , placing n-hexane into the residual liquid claim 1 , and getting various substituted borate esters.8. The method according to claim 6 , wherein the dosage of tricyclopentadienyl rare earth metal complex is 0.01-1% of molar amount of carbonyl compounds; wherein the molar ratio of the borane and carbonyl compounds is 1-1.2:1; wherein the reaction time between 30 min-1 h; wherein the reaction is at room temperature.9. (canceled) This invention belongs to the field of organic synthesis, and particularly relates to a method for preparing borate ester on the basis of tricyclopentadienyl rare earth metal complex.Borate esters are ...

BORON-CONTAINING SMALL MOLECULES

Compounds, pharmaceutical formulations, and methods of treating anti-inflammatory conditions and/or helminth-associated diseases are disclosed. 2. The compound of claim 1 , wherein Ris fluorine or chlorine.3. The compound of claim 1 , wherein Ris OR claim 1 , and Ris selected from the group consisting of substituted or unsubstituted alkyl claim 1 , substituted or unsubstituted heteroalkyl claim 1 , substituted or unsubstituted cycloalkyl claim 1 , substituted or unsubstituted heterocycloalkyl claim 1 , substituted or unsubstituted aryl claim 1 , and substituted or unsubstituted heteroaryl.4. The compound of claim 1 , wherein Ris OR claim 1 , and Ris selected from the group consisting of substituted or unsubstituted alkyl claim 1 , substituted or unsubstituted heteroalkyl and substituted or unsubstituted cycloalkyl.6. A pharmaceutical formulation comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(a) the compound of , or a pharmaceutically acceptable salt thereof; and'}(b) a pharmaceutically acceptable excipient.7. A method of decreasing the release of a cytokine or a chemokine claim 1 , the method comprising: contacting a cell with the compound of or a pharmaceutically acceptable salt thereof claim 1 , wherein the release of the cytokine or chemokine by the cell is decreased.8. A method of treating a condition or disease claim 1 , in an animal claim 1 , the method comprising administering to the animal a therapeutically effective amount of the compound of or a pharmaceutically acceptable salt thereof claim 1 , thereby treating the condition or disease.9. The method of claim 8 , wherein the condition is selected from the group consisting of schistosomiasis claim 8 , psoriasis claim 8 , atopic dermatitis claim 8 , rheumatoid arthritis claim 8 , an inflammatory bowel disease claim 8 , asthma and chronic obstructive pulmonary disease.10. The method of claim 8 , wherein the condition or disease is a helminth-associated disease.11. A method of inhibiting a ...

DECOLORIZATION METHOD FOR DYED FIBER CLOTH

A decolorization method for a dyed fiber cloth is provided. The decolorization method for the dyed fiber cloth includes steps of: providing a fiber cloth attached with a dye, extracting the dye attached on the fiber cloth by an extractant, and applying a microwave to evaporate the extractant so as to obtain a dried and decolored fiber cloth. 1. A decolorization method for a dyed fiber cloth , comprising:providing a fiber cloth attached with a dye;extracting the dye attached on the fiber cloth by an extractant; andapplying a microwave to evaporate the extractant so as to obtain a dried and decolored fiber cloth.2. The decolorization method according to claim 1 , wherein the fiber cloth is extracted at a temperature ranging from 70° C. to 130° C.3. The decolorization method according to claim 1 , further comprising separating a part of the extractant by filtration before applying the microwave.4. The decolorization method according to claim 3 , wherein claim 3 , after the filtration claim 3 , based on a total weight of the fiber cloth and the extractant remained on the fiber cloth being 100 wt % claim 3 , a residue of the extractant remaining on the fiber cloth ranges from 5 wt % to 70 wt %.5. The decolorization method according to claim 1 , wherein claim 1 , after applying the microwave claim 1 , based on a total weight of the fiber cloth and the extractant remained on the fiber cloth being 100 wt % claim 1 , a residue of the extractant remaining on the fiber cloth ranges from 0 wt % to 5 wt %.6. The decolorization method according to claim 1 , further comprising condensing and collecting the extractant after applying the microwave claim 1 , and a recovery rate of the extractant being higher than or equal to 90%.7. The decolorization method according to claim 1 , wherein a weight ratio of the extractant to the fiber cloth ranges from 10 to 30.8. The decolorization method according to claim 1 , wherein claim 1 , when applying the microwave claim 1 , a direction of ...

ORGANIC LIGHT-EMITTING ELEMENT

The present invention provides an organic light-emitting element, comprising a substrate, a first electrode, more than one organic layer film comprising a light-emitting layer, and a second electrode. The light-emitting element further comprises a cover layer. The cover layer is located on the second electrode, and comprises a high refractive layer and a low refractive layer. A material for the low refractive layer of the cover layer is a boron complex organic small molecular compound. The organic light-emitting element provided by the present invention can achieve high light-emitting efficiency and color reproducibility. The organic light-emitting element of the present invention can be used for an organic EL display, a backlight source of a liquid crystal display, illumination, a sign board, an identification lamp, etc. 1. An organic light-emitting element , comprising a substrate , a first electrode , more than one organic layer film comprising a light-emitting layer , and a second electrode , wherein the light-emitting element further comprises a cover layer; the cover layer comprises a low refractive layer; and the low refractive layer is formed from an organic small molecular compound.2. The organic light-emitting element according to claim 1 , wherein the cover layer is disposed on the second electrode claim 1 , and the cover layer comprises a high refractive layer and the low refractive layer.3. The organic light-emitting element according to claim 2 , wherein the high refractive layer has a refractive index of 1.8 or more; and the low refractive layer has a refractive index of 1.5 to 1.7.4. The organic light-emitting element according to claim 2 , wherein a difference between the refractive index of the high refractive layer and the refractive index of the low refractive layer is 0.3 or more.5. The organic light-emitting element according to claim 1 , wherein the high refractive layer is formed from at least one of the following inorganic compounds and ...

POLYMERIC COMPOUND AND ELECTRONIC ELEMENT

A polymer compound including a structural unit represented by formula (I) or a structural unit represented by formula (III) and a structural unit represented by formula (II) has high photoelectric conversion efficiency when used in an organic photoelectric conversion device. 1. A compound represented by formula (IX):wherein Rand Rare the same or different and represent a hydrogen atom or a substituent, and Wand Ware the same or different and represent a boric acid residue or a boric acid derivative residue. This is a divisional of U.S. patent application Ser. No. 13/504,030, filed Apr. 25, 2012, which is a 371 National Stage Entry of PCT/JP2010/069234, filed Oct. 22, 2010, which claims priority to Japanese Patent Application No. 2009-248796, filed Oct. 29, 2009. The entire disclosures of the prior applications are considered part of the disclosure of the accompanying divisional application, and are hereby incorporated by reference.The present invention relates to a polymer compound, and an electronic device using the same.Since a polymer compound containing a π-conjugated structure absorbs light in a visible light range and peripheral regions of visible light and also has emission characteristics, conduction characteristics, semiconductor characteristics and the like, an examination of the polymeric compound on application to electronic devices such as an organic electroluminescence device, a switching device, a photoelectric conversion device and the like has been made.A polymer compound, which has two or more kinds of structural unit and also contains a π-conjugated structure, has plural functions derived from each structural unit, and thus the polymer compound is expected as a compound whose advancement in performance can be anticipated. Therefore, an application study as a material suited for use in an electronic device has made progress compared with a homopolymer containing one kind of a structural unit.There has been proposed, as a polymer compound which ...

METHOD FOR MARKING A TEXTILE THREAD WITH A FLUORESCENT ELEMENT, TEXTILE THREAD PRODUCED BY THE MARKING METHOD, AND USE OF SAID TEXTILE THREAD FOR WEAVING AN ITEM OF CLOTHING

A method for marking a textile thread by a fluorescent element has the following successive steps: placing a textile thread and at least one fluorescent element in a reaction chamber, introducing a fluid into the reaction chamber, increasing the temperature and pressure in the reaction chamber up to a temperature and a pressure so as to transform the fluid into a supercritical fluid and to mark the textile thread by the fluorescent element. The fluorescent element is chosen from organolanthanide complexes. 117-. (canceled)18. Method for marking a textile thread by a fluorescent element comprising the following successive steps:placing a textile thread and at least one fluorescent element in a reaction chamber,introducing a fluid into the reaction chamber,increasing the temperature and pressure in the reaction chamber up to a temperature, higher than the critical temperature of the fluid, and up to a pressure, higher than the critical pressure of the fluid, so as to transform the fluid into a supercritical fluid and to mark the textile thread by the fluorescent element,wherein the fluorescent element is chosen from organolanthanide complexes.19. Method according to claim 18 , wherein the supercritical fluid introduced into the reaction chamber is liquid carbon dioxide.20. Method according to claim 18 , wherein the textile thread comprises from 1% to 88.5% by weight of polyester.21. Method according to claim 20 , wherein the polyester is ethylene polyterephtalate.22. Method according to claim 18 , wherein the fluorescent element is a europium complex.23. Method according to claim 18 , wherein the weight ratio between the textile thread and the fluorescent element is comprised between 1% and 20% by weight.24. Method according to claim 18 , wherein the pressure and temperature are maintained during a period of at least 15 minutes.25. Method according to claim 24 , wherein the pressure and temperature are maintained during a period comprised between 15 minutes and 10 ...

Disperse Azo Dyes, a Process for the Preparation Thereof and the Use Thereof

The present invention relates to azo dyes of formula 2. An azo dye of formula (1) according to claim 1 , wherein X denotes hydrogen or bromo.3. An azo dye of formula (1) according to claim 1 , wherein Rdenotes methyl claim 1 , ethyl claim 1 , n-propyl claim 1 , i-propyl or n-butyl.4. An azo dye of formula (1) according to claim 1 , wherein Rand Rrepresent 2-methoxyethyl claim 1 , 3-methoxypropyl claim 1 , 4-methoxybutyl claim 1 , 2-ethoxyethyl claim 1 , 3-ethoxypropyl or 4-ethoxybutyl.5. A dichromatic or trichromatic dye mixture comprising at least one azo dye of formula (1) according to and at least one further disperse dye.6. A process for dyeing or printing semi-synthetic or synthetic hydrophobic fibre materials claim 1 , in which process a dye of formula (1) according to is applied to the said materials or incorporated into them.7. (canceled)8. A semi-synthetic or especially synthetic hydrophobic fibre material dyed or printed by the process according to .9. A semi-synthetic or especially synthetic textile material dyed or printed by the process according to . The present invention relates to disperse azo dyes based on aminophthalimides as the diazotizing component and 2,6-aminosubstituted 3-cyano-4-methylpyridines as coupling components and to the use thereof in dyeing or printing semi-synthetic and especially synthetic fibre materials, more especially textile materials.Azo dyes based on aminophthalimides as the diazotizing component are known, for example, from U.S. Pat. No. 3,980,634 and WO 2014/016072, and azo dyes derived from 2,6-aminosubstituted 3-cyano-4-methylpyridines as coupling components are described in GB 1561772. It has, however, been found that the dyeings or prints obtained using the currently known dyes do not in all cases satisfy today's requirements, especially in respect of light fastness and fastness to washing. There is therefore a need for new dyes that especially have good light fastness properties.Surprisingly, we found that azo dyes ...

COMPOSITIONS AND METHODS FOR TREATING CANCER WITH ABERRANT LIPOGENIC SIGNALING

The technology described herein relates to pinacolyl boronate substituted stilbenes for the treatment of cancers, e.g. cancers expressing abnormally high levels of SREBP1. 3. A method of treating cancer in a subject claim 1 , the method comprising administering to the subject an inhibitor of sterol regulatory binding protein 1 (SREBP1) of .4. The method of claim 3 , further comprising a first step of selecting a subject having cancer cells which express abnormal levels of sterol regulatory binding protein 1 (SREBP1).5. The method of claim 4 , wherein the cells which express abnormal levels of sterol regulatory binding protein 1 (SREBP1) are cells which have abnormal levels of SREBP1 polypeptide.6. The method of claim 3 , further comprising a first step of selecting a subject having cancer cells which express abnormal amounts of Erb2.7. The method of claim 3 , further comprising a first step of selecting a subject having cancer cells which express abnormal amounts of at least one gene selected from the group consisting of:FASN, SCD1 or ACLY.8. The method of claim 3 , wherein the subject has an endometrial cancer.9. The method of claim 3 , wherein the cancer is selected from the group consisting of:prostate cancer; breast cancer; colorectal cancer; colorectal carcinoma; hepatocarcinoma; endometrial adenocarcinoma; uterine cancer; leukemia; lung cancer; central nervous system cancer; melanoma; ovarian cancer; renal cancer; and pancreatic cancer.10. A pharmaceutical composition comprising a compound of .11. The composition of claim 10 , further comprising a pharmaceutically acceptable carrier. This application is a continuation of co-pending U.S. application Ser. No. 14/410,352 filed Dec. 22, 2014, which is a 35 U.S.C. §371 National Phase Entry Application of International Application No. PCT/US2013/044887 filed Jun. 10, 2013, which designates the U.S., and which claims benefit under 35 U.S.C. §119(e) of U.S. Provisional Application No. 61/663,875 filed Jun. 25, 2012, ...

METHOD FOR DYEING GOLF BALLS AND DYED GOLF BALLS

A golf ball of a first color is dyed to a second color with an anionic or nonionic disperse dye. Either or both of a pigmented coating layer or an optional clear coating layer on the pigmented coating layer comprises a member selected from the group consisting of polyurethanes, polyureas, polyamides, and combinations thereof, which can be dyed by the anionic or nonionic disperse dye.

LOW TEMPERATURE COLOURING METHOD

The present invention relates to a method of colouring polymer substrates at low temperatures. The method comprises subjecting the polymer substrate that is to be coloured to a colouring liquor comprising a solvent in which the colourant has a high solubility and then adding a solvent in which the colourant has a low solubility, typically water. 2. (canceled)3. (canceled)4. A method of claim 1 , wherein the second solvent system is water.5. A method of claim 1 , wherein the first solvent system and the second solvent system are miscible.6. (canceled)7. A method of claim 1 , wherein the first solvent system is a polar organic solvent or a mixture of polar organic solvents.8. A method of claim 7 , wherein the first solvent system comprises acetone.9. A method of claim 7 , wherein the first solvent system comprises a solvent selected from glycerol claim 7 , ethylene glycol diacetate (EGD) claim 7 , triethylene glycol monomethyl (TGM) claim 7 , dipropylene glycol methyl ether (DME) and 1-methoxy-2-propanol.10. A method of claim 1 , wherein the polymer substrate is a fibre substrate.11. A method of claim 10 , wherein the fibre substrate comprises fibres selected from: a polyester claim 10 , nylon claim 10 , a polyurethane claim 10 , wool claim 10 , silk claim 10 , cotton or a mixture thereof.12. A method of claim 11 , wherein the fibre substrate comprises polyester fibres.13. A method of claim 12 , wherein the fibre substrate comprises polyester fibres and at least one fibre selected from cotton claim 12 , regenerated cellulose claim 12 , wool claim 12 , silk claim 12 , polyamide claim 12 , a different polyester claim 12 , polyvinylchloride claim 12 , polyacrylonitrile claim 12 , mohair claim 12 , cashmere and a polyurethane.14. A method of claim 13 , wherein the fibre substrate comprises a material that is a blend of polyester fibres and at least one fibre selected from cotton claim 13 , regenerated cellulose claim 13 , wool claim 13 , silk claim 13 , polyamide claim 13 ...

Artificial Marble Chip, Method of Preparing the Same and Artificial Marble Including the Same

Disclosed herein is an artificial marble chip having a color gradient from a surface thereof to inside. 1. An artificial marble chip having a color gradient from a surface thereof to an interior portion thereof.2. The artificial marble chip according to claim 1 , comprising:a core; anda colored portion surrounding the core,wherein the colored portion has a color gradient.3. The artificial marble chip according to claim 1 , wherein the color gradient is generated such that brightness or chroma of color gradually increases from the surface thereof to an interior portion thereof.4. The artificial marble chip according to claim 2 , wherein the colored portion has a first color and the core has a second color claim 2 , and wherein a mixed color of the first color and the second color is gradated in the colored portion.8. The artificial marble chip according to claim 2 , wherein the core is free from a colorant.9. The artificial marble chip according to claim 1 , comprising: about 100 parts by weight of an acrylic resin claim 1 , about 100 parts by weight to about 200 parts by weight of inorganic fillers claim 1 , and about 0.001 parts by weight to about 10 parts by weight of a colorant.10. The artificial marble chip according to claim 9 , wherein the inorganic fillers comprise at least one selected from among silica claim 9 , alumina claim 9 , calcium carbonate claim 9 , aluminum hydroxide claim 9 , and magnesium hydroxide.11. The artificial marble chip according to claim 1 , wherein the artificial marble chip has a ratio of minor axis to major axis of about 1:1 to about 1:5 in cross-section.12. A method of preparing an artificial marble chip having a color gradient from a surface thereof to inside claim 1 , comprising:bringing a seed chip into contact with a mixture comprising a colorant and an acrylic monomer to allow the colorant to permeate the seed chip.13. The method according to claim 12 , wherein the seed chip comprises an acrylic resin and inorganic fillers.14. ...

Disperse Azo Dyes, A Process for the Preparation Thereof and the Use Thereof

The present invention relates to azo dyes of formula (1), wherein Rdenotes C-Calkyl which is unsubstituted or substituted by one or more C-Calkoxy groups, hydroxyl groups, amino groups, cyano groups or halogen atoms and which may be interrupted one or more times by the radical —O—, —S—, —COO— or —OOC—: Ris hydrogen or C-Calkyl; either Ris cyano and Ris halogen or Ris halogen and Ris cyano; and Ar represents a carbocyclic or heterocyclic aromatic radical, to the process for the preparation thereof, to mixtures containing said dyes and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fibre materials, more especially textile materials. 2. An azo dye of formula (1) according to claim 1 , wherein Rdenotes unsubstituted C-Calkyl.3. An azo dye of formula (1) according to claim 1 , wherein Rdenotes methyl claim 1 , ethyl claim 1 , n-propyl claim 1 , i-propyl or n-butyl.4. An azo dye of formula (1) according to claim 1 , wherein Ris cyano and Ris bromo.6. An azo dye of formula (1) according to claim 5 , wherein Ar is a radical of the formula (2a) wherein Ris —NH—CO—R.7. An azo dye of formula (1) according to claim 5 , wherein Ar is a radical of the formula (2a) wherein Rand Reach independently of the other are methyl claim 5 , ethyl claim 5 , n-propyl claim 5 , n-butyl claim 5 , allyl claim 5 , benzyl claim 5 , 4-nitrobenzyl claim 5 , 4-methoxybenzyl claim 5 , 3-methoxybenzyl claim 5 , 2-cyanoethyl claim 5 , 2-methoxyethyl claim 5 , 2-phenylethyl claim 5 , 1 -methoxycarbonylethyl claim 5 , 2-methoxycarbonylethyl claim 5 , methoxycarbonylmethyl claim 5 , 1 -ethoxycarbonylethyl claim 5 , 2-ethoxycarbonylethyl claim 5 , ethoxycarbonylmethyl claim 5 , 2-hydroxy-3-phenoxypropyl or 2-hydroxy-3-i-propoxypropyl.8. An azo dye of formula (1) according to claim 5 , wherein Ar is a radical of the formula (2a) wherein Ris hydrogen claim 5 , methyl or methoxy.11. A dye mixture comprising{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(A)10-90 ...

BORYL ETHERS, CARBONATES, AND CYCLIC ACETALS AS OXIDATIVELY-TRIGGERED DRUG DELIVERY VEHICLES

A compound, or a pharmaceutically acceptable salt thereof, having a structure of: 2. The compound of claim 1 , wherein L includes an —O— claim 1 , —C(O)— claim 1 , or —O—C(O)—O—.3. The compound of claim 1 , wherein —B-L- together form a boryl ether claim 1 , boryl carbonate or boryl cyclic acetal.6. The compound of claim 1 , wherein X includes a therapeutically active moiety.7. The compound of claim 1 , wherein X includes a detectable moiety.8. The compound of claim 6 , wherein the therapeutically active moiety is an anticancer agent claim 6 , a neurological agent claim 6 , or an antioxidant.9. The compound of claim 1 , wherein at least one of R-Rincludes a targeting moiety.10. The compound of claim 1 , wherein X includes a targeting moiety.11. The compound of claim 9 , wherein the targeting moiety targets a cell.12. The compound of claim 1 , wherein L is configured to undergo cleavage upon reaction of the compound with a reactive oxygen species.13. The compound of claim 12 , wherein the reactive oxygen species is hydrogen peroxide.14. The compound of claim 13 , wherein the hydrogen peroxide is endogenous hydrogen peroxide within a cell within a subject.15. The compound of claim 13 , wherein the hydrogen peroxide is exogenous hydrogen peroxide provided or generated within a cell within a subject.16. A pharmaceutical composition comprises a compound of claim 1 , and at least one pharmaceutically acceptable additive or excipient.17. A method for treating a reactive oxygen species-mediated condition in a subject claim 1 , comprising administering a therapeutically effective amount of a compound of to the subject in need thereof.18. The method of claim 17 , wherein the reactive oxygen species-modulated condition is cancer.19. The method of claim 17 , wherein the reactive oxygen species-modulated condition is a neurodegenerative disease.20. The method of claim 17 , wherein L in the compound is cleaved upon reaction with hydrogen peroxide within the subject. This ...

USE OF N-BUTYLLITHIUM FOR CATALYZING HYDROBORATION OF IMINE AND BORANE

The present invention relates to the use of n-butyllithium for catalyzing the hydroboration of an imine and a borane. A catalyst, the borane and the imine are sequentially stirred and mixed uniformly, and are reacted for 1-2 h; the mixture is exposed to air to terminate the reaction; and the reaction liquid is subjected to reduced pressure to remove the solvent, so as to obtain a borate with different substituents. The n-butyllithium disclosed in the present invention can be used for catalyzing the hydroboration of the imine and the borane in high activity under room temperature conditions, the amount of the catalyst is only 4-5 mol % of the molar weight of the imine, and the yield of the reaction can reach 90% or more. 1. A method of preparing a borate ester comprising:reacting an imine with a borane in an organic solvent and in the presence of n-butyllithium as a catalyst at room temperature under anhydrous, oxygen-free, and inert gas conditions for 1-2 hours; andstirring in air to stop reaction and to obtain the borate ester.3. The method of claim 1 , wherein the organic solvent is tetrahydrofuran.4. The method of claim 1 , wherein an amount of n-butyllithium is 4% to 5% of a molar amount of the imine.5. The method of claim 1 , wherein a molar ratio of the imine to the borane is 1:1 to 1:1.2.6. The method of claim 5 , wherein the molar ratio of the imine to the borane is 1:1.2. The present application is a Continuation Application of PCT/CN2018/109370, filed on Oct. 8, 2018, which is incorporated by reference for all purposes as if fully set forth herein.The invention relates to the application of the commercial n-butyllithium reagent, in particular to the high-efficiency application of n-butyllithium in the catalytic hydroboration reaction of imine and borane.Amine compounds and their derivatives are ubiquitous in nature, especially in the biological world, and have extremely important physiological functions. They are important organic compounds in the fields ...

Application of lithium 4-methoxyaniline in catalysis of hydroboration reaction of imine and borane

The present invention relates to the application of lithium 4-methoxyaniline in catalysis of the hydroboration reaction of an imine and a borane. A catalyst, a borane and an imine are successively stirred and mixed until uniform, reacted for 1 to 2 hours, and then exposed to air so as to stop the reaction, and the reaction liquid is subjected to decompression to remove a solvent therein, so as to obtain a borate with different substituents. The lithium 4-methoxyaniline disclosed in the present invention can catalyze the hydroboration reaction of an imine and a borane in a high activity manner at room temperature, wherein the amount of the catalyst is merely 4-5 mol % of the molar amount of the imine, and the yield of the reaction can reach 90% or more. The yield of a borate with different substituents can reach 99% with mild reaction conditions under an optimized condition.

APPLICATION OF 4-MEPHNHLI IN CATALYZING HYDROBORATION REACTION OF IMINE AND BORANE

The present invention relates to an application of 4-MePhNHLi, in particular, to an application of 4-MePhNHLi in catalyzing hydroboration reaction of imine and borane. A catalyst, borane, and imine are stirred and mixed uniformly in sequence for reaction for 1-2 hours, the reaction is terminated by exposure to air, and the solvent in the reaction liquid is removed under reduced pressure to obtain borate esters having different substituents. According to the present invention, 4-MePhNHLi can catalyze hydroboration reaction of imine and borane at high activity at room temperature, the amount of catalyst is only 4-5 mol % of the molar mass of imine, and the reaction can reach a yield of more than 90%; compared with an existing catalytic system, simple 4-MePhNHLi is used, the reaction conditions are mild, and the yield of borate esters having different substituents can reach 99% in optimized conditions. 1. A method of preparing a borate ester comprising:reacting an imine with a borane in an organic solvent and in the presence of 4-MePhNHLi as a catalyst at room temperature under anhydrous, oxygen-free, and inert gas conditions for 1-2 hours; andstirring in air to stop reaction and to obtain the borate ester.3. The method of claim 1 , wherein the organic solvent is tetrahydrofuran.4. The method of claim 1 , wherein an amount of 4-MePhNHLi is 4% to 5% of a molar amount of the imine.5. The method of claim 1 , wherein a molar ratio of the imine to the borane is 1:1 to 1:1.2.6. The method of claim 5 , wherein the molar ratio of the imine to the borane is 1:1.2. The present application is a Continuation Application of PCT/CN2018/109377, filed on Oct. 8, 2018, which is incorporated by reference for all purposes as if fully set forth herein.The invention relates to the application of 4-MePhNHLi, in particular to the high-efficiency application of 4-MePhNHLi in the catalytic hydroboration reaction of imine and borane.Amine compounds and their derivatives are ubiquitous in nature ...

COMPOSITIONS AND METHODS FOR TREATING CANCER WITH ABERRANT LIPOGENIC SIGNALING

The technology described herein relates to pinacolyl boronate substituted stilbenes for the treatment of cancers, e.g. cancers expressing abnormally high levels of SREBP 1. 3. A method of treating cancer in a subject claim 1 , the method comprising administering to the subject an inhibitor of sterol regulatory binding protein 1 (SREBP1) of .4. The method of claim 3 , further comprising a first step of selecting a subject having cancer cells which express abnormal levels of sterol regulatory binding protein 1 (SREBP1).5. The method of claim 4 , wherein the cells which express abnormal levels of sterol regulatory binding protein 1 (SREBP1) are cells which have abnormal levels of SREBP1 polypeptide.6. The method of claim 3 , further comprising a first step of selecting a subject having cancer cells which express abnormal amounts of Erb2.7. The method of claim 3 , further comprising a first step of selecting a subject having cancer cells which express abnormal amounts of at least one gene selected from the group consisting of:FASN, SCD1 or ACLY.8. The method of claim 3 , wherein the subject has an endometrial cancer.9. The method of claim 3 , wherein the cancer is selected from the group consisting of:prostate cancer; breast cancer; colorectal cancer; colorectal carcinoma; hepatocarcinoma; endometrial adenocarcinoma; uterine cancer; leukemia; lung cancer; central nervous system cancer; melanoma; ovarian cancer; renal cancer; and pancreatic cancer.10. A pharmaceutical composition comprising a compound of .11. The composition of claim 10 , further comprising a pharmaceutically acceptable carrier.1218.-. (canceled) This application claims benefit under 35 U.S.C. §119(e) of U.S. Provisional Application No. 61/663,875 filed Jun. 25, 2012, the contents of which are incorporated herein by reference in their entirety.The instant application contains a Sequence Listing which has been submitted in ASCII format via EFS-Web and is hereby incorporated by reference in its entirety. ...

Textile treatment for sublimation ink transfers

Compositions and methods for treating textile materials so as to facilitate transfer of an image thereto using a dye sublimation transfer system are provided. The compositions are applied to the textile in the form of an aqueous pretreatment composition, which comprises a polymer resin and a crosslinking agent. The resin and crosslinking agent are cured upon the textile material to form an image-receiving area. The sublimation transfer system is then applied to the image-receiving area to form a finished, image-bearing textile product.

Disperse Azo Dyes

The present invention relates to disperse azo dyes of formula 2. The dye of formula (1) according to claim 1 , wherein Ris cyano.3. The dye of formula (1) according to claim 2 , wherein Ris chloro.4. The dye of formula (1) according to claim 1 , wherein Ris hydrogen.5. The dye of formula (1) according to claim 1 , wherein Ris methyl claim 1 , ethyl claim 1 , methoxycarbonylmethyl or 2-methoxycarbonylethyl.7. A dye mixture comprising at least one dye of formula (1) according to and at least one further dye selected from the group consisting of C.I. Disperse Blue 60 claim 1 , C.I. Disperse Blue 79:1 claim 1 , C.I. Disperse Blue 72:2 claim 1 , C.I. Disperse Blue 148 claim 1 , C.I. Disperse Blue 149 claim 1 , C.I. Disperse Blue 165 claim 1 , C.I. Disperse Blue 165:1 claim 1 , C.I. Disperse Blue 207 claim 1 , C.I. Disperse Blue 284 claim 1 , C.I. Disperse Blue 295 claim 1 , C.I. Disperse Blue 316 claim 1 , C.I. Disperse Blue 337 claim 1 , C.I. Disperse Blue 354 claim 1 , C.I. Disperse Blue 366 claim 1 , C.I. Disperse Blue 367 claim 1 , C.I. Disperse Blue 368 claim 1 , C.I. Disperse Blue 376 claim 1 , C.I. Disperse Blue 378 claim 1 , C.I. Disperse Blue 380 claim 1 , C.I. Disperse Green 9 claim 1 , C.I. Disperse Violet 107 claim 1 , the compounds of formulas (101)-(179) described in WO 2014/016072 claim 1 , the compounds of formulas (101)-(106) described in WO 2009/013122 and the compounds of formulas II-2 claim 1 , II -3 claim 1 , II-4 and III-1-III-8 described in CN 101955691.8. A process for dyeing or printing semi-synthetic or synthetic hydrophobic fibre material which comprises applying to or incorporating into the hydrophobic fibre material at least one dye of formula (1) according to or the dye mixture according to .9. A process according to claim 8 , wherein the hydrophobic fibre material contains polyester fibres.10. A material dyed or printed according to either or . The present invention relates to disperse dyes having an acetylamino-substituted aniline coupling ...

Apparatus and Method For Applying Colors and Performance Chemicals On Carpet Yarns

Disclosed are processes for application of dyes and topical chemistries to single yarns during a yarn rewind process. The process foregoes the need for downstream environmentally unfavorable dyeing and low PH chemical treatment processes on the finished carpet. Further, neutral pH dye solutions can be used instead of the prior art low pH dye solutions. The single, treated yarn can then be twisted, weaved and tufted, twisted yarn under dry conditions, and the twisted yarn subsequently weaved or weaved and tufted, into a finished fabric or carpet. Also disclosed are systems, BCF yarns, and carpets made from the BCF yarn treated by the disclosed processes. 1. A process for applying a treatment to a single or twisted BCF yarn comprising:a. providing a single or twisted BCF yarn;b. winding said yarn on a take up reel;c. providing at least one rotating roll including a plurality of wicks for providing a treatment;d. contacting said wicks with said treatment;e. contacting said BCF yarn with said wicks; andf. heat setting said BCF yarn.2. The process of claim 1 , further comprising a second rotating roll or multiple rotating rolls.3. The process of claim 1 , wherein said treatment is selected from the group consisting of a dye composition claim 1 , an anti-soil composition claim 1 , an anti-stain composition and combinations thereof.4. The process of claim 1 , wherein said at least one rotating roll includes wicks evenly distributed on a yarn contacting surface of said at least one rotating roll.5. The process of claim 1 , wherein said at least one rotating roll includes wicks only in selected sections of said yarn contacting surface of said at least one rotating roll.6. The process of claim 5 , wherein said at least one rotating roll includes a portion of said yarn contacting surface where no wicks are present.7. The process of claim 1 , wherein said BCF yarn is processed at a yarn speed of about 50 m/min to about 1000 m/min.8. The process of claim 1 , wherein said at ...

PROTECTED ORGANOBORONIC ACIDS WITH TUNABLE REACTIVITY, AND METHODS OF USE THEREOF

Disclosed are a range of protected organoboronic acid reagents useful in the modular assembly of complex organic compounds. The reactivities of the protected organoboronic acid reagents may be varied predictably by changes to the number and identities of their substituents. Also disclosed are methods of using the protected organoboronic acid reagents in the synthesis of organic compounds. 2. The compound of claim 1 , wherein Ris selected from the group consisting of substituted or unsubstituted alkyl claim 1 , heteroalkyl claim 1 , cycloalkyl claim 1 , heterocycloalkyl claim 1 , alkenyl claim 1 , heteroalkenyl claim 1 , alkynyl claim 1 , heteroalkynyl claim 1 , aryl claim 1 , heteroaryl claim 1 , aralkyl claim 1 , and heteroaralkyl.3. The compound of claim 2 , wherein Ris substituted with a halogen.4. The compound of any one of to claim 2 , wherein Ris selected from the group consisting of substituted or unsubstituted alkyl claim 2 , heteroalkyl claim 2 , cycloalkyl claim 2 , and heterocycloalkyl.5. The compound of claim 4 , wherein Ris selected from the group consisting of isopropyl and cyclohexyl.6. The compound of any one of - claim 4 , wherein Rand Rare not identical.7. The compound of any one of - claim 4 , wherein Rand Rare identical.8. The compound of claim 7 , wherein each of Rand Ris H.9. The compound of any one of - claim 7 , wherein Rand Rare not identical.10. The compound of any one of - claim 7 , wherein Rand Rare identical.11. The compound of any one of - claim 7 , wherein each of Rand Ris H.12. The compound of any one of - claim 7 , wherein each of Rand Ris methyl.13. The compound of any one of - claim 7 , wherein each of Rand Ris ethyl.14. The compound of any one of - claim 7 , wherein Rand Rare not identical.15. The compound of any one of - claim 7 , wherein Rand Rare identical.16. The compound of any one of - claim 7 , wherein each of Rand Ris H.17. The compound of any one of - claim 7 , wherein Rand Rare not identical.18. The compound of any one ...

TREATMENT LIQUID COMPOSITION FOR INK JET PIGMENT TEXTILE PRINTING, TREATMENT LIQUID COMPOSITION SET FOR INK JET PIGMENT TEXTILE PRINTING, AND INK JET TEXTILE PRINTING METHOD

A treatment liquid composition for ink jet pigment textile printing according to the invention is used by being attached to a fabric and contains a cationic compound, a nonionic fluorine-based surfactant, a resin particle, and water. 1. A treatment liquid composition for ink jet pigment textile printing , which is used by being attached to a fabric in ink jet pigment textile printing , the treatment liquid composition for ink jet pigment textile printing comprising:a cationic compound;a nonionic fluorine-based surfactant;a resin particle; andwater.2. The treatment liquid composition for ink jet pigment textile printing according to claim 1 , whereinthe fabric contains polyester or polyester mixed yarn.3. The treatment liquid composition for ink jet pigment textile printing according to claim 1 , whereinthe cationic compound is a polyvalent metal salt, an organic acid, or a cationic resin.4. The treatment liquid composition for ink jet pigment textile printing according to claim 1 , whereinthe cationic compound contains either calcium nitrate or calcium chloride.5. The treatment liquid composition for ink jet pigment textile printing according to claim 1 , whereinthe nonionic fluorine-based surfactant has an HLB value within a range of 6 or more and 15 or less.6. The treatment liquid composition for ink jet pigment textile printing according to claim 1 , whereinthe nonionic fluorine-based surfactant has a polyoxyethylene group and an alkyl fluoride group.7. The treatment liquid composition for ink jet pigment textile printing according to claim 1 , whereinthe resin particle is a nonionic or cationic resin particle.8. An ink jet pigment textile printing set comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the treatment liquid composition for ink jet pigment textile printing according to ; and'}a pigment textile printing ink jet ink composition containing a pigment, a resin particle, and water.9. An ink jet pigment textile printing set comprising:{'claim- ...

HIGH WET FAST DISPERSE DYE MIXTURES

The present invention is directed to dye mixtures comprising dye(s) of formula (1) 13. A process for the production of a dye mixture according to claim 1 , comprisinga) mixing at least one dye of formula (1) with at least one dye of any one of formula (3a) to (3i) andb) homegenizing the mixture obtained in step a)forms another aspect of the present invention.14. Aqueous solution comprising the dye mixture according to . This invention relates to high wet fast disperse dye mixtures.Disperse azo dyes of formula (1) and their production process are already known, e.g. from EP 3 063 228, but they do have some deficiencies in application properties.Surprisingly it was now found that specific dyes of formula (1) mixed with selected other disperse dyes of formulae (3a) to (3i) have improved application properties on polyester and polyester blends especially in wet fastnesses, built-up and lightfastness properties.The dyes of formula (3a) to (3i) are also known and can be prepared according to known procedures, for example from WO 2009/037215, WO 2008/049758, WO 2005/056690, WO 2000/040656, U.S. Pat. No. 3,980,634, EP 0 667 376, WO 2002/068539, WO 2002/074864, EP 0 436 940, EP 0 555 179, EP 0 894 830 and WO 2004/044058.The present invention thus is directed to a dye mixture comprising at least one dye of formula (1)andat least one dye selected from the group consisting of dyes of formulae (3a), (3b), (3c), (3d), (3e), (3f), (3g), (3h) and (3i)wherein independent from each otherRis hydrogen, (C-C)-alkyl, (C-C)-alkenyl, —(CH)—O—(C-C)-alkyl, —(CH)—O—CO—(C-C)-alkyl, —(CH)—COO—Ror —(CH)—CN,Ris hydrogen, —NH—CO—(C-C)-alkyl or (C-C)-alkyl,Ris hydrogen or (C-C)-alkyl,Rand Rare hydrogen, (C-C)-alkyl, (C-C)-alkenyl, —(CH)—O—(C-C)-alkyl, —(CH)—O—CO—(C-C)-alkyl, —(CH)—COO—(C-C)-alkyl or —CHCH—COO—(C-C)-alkyl,Rand Rare hydrogen, (C-C)-alkyl, (C-C)-alkoxy or halogen,Rand Rare hydrogen, —(CH)—O—CO—(C-C)-alkyl or —(CH)—COO—(C-C)-alkyl,Rand Rare hydrogen, (C-C)-alkyl, (C-C)-alkenyl, —(CH)—O ...

Disperse Azo Dyes, A Process for the Preparation Thereof and the Use Thereof

The present invention relates to azo dyes of formula 2. The azo dye of formula (1) according to claim 1 , wherein Rdenotes unsubstituted C-Calkyl.3. The azo dye of formula (1) according to claim 1 , wherein Rdenotes methyl claim 1 , ethyl claim 1 , n-propyl claim 1 , i-propyl or n-butyl.4. The azo dye of formula (1) according to claim 1 , wherein Ris cyano and Ris bromo.5. The azo dye of formula (1) according to claim 1 , wherein Ar is a radical of the formula (2a) wherein Rand Reach independently of the other are methyl claim 1 , ethyl claim 1 , n-propyl claim 1 , n-butyl claim 1 , allyl claim 1 , benzyl claim 1 , 4-nitrobenzyl claim 1 , 4-methoxybenzyl claim 1 , 3-methoxybenzyl claim 1 , 2-cyanoethyl claim 1 , 2-methoxyethyl claim 1 , 2-phenylethyl claim 1 , 1-methoxycarbonylethyl claim 1 , 2-methoxycarbonylethyl claim 1 , methoxycarbonylmethyl claim 1 , 1-ethoxycarbonylethyl claim 1 , 2-ethoxycarbonylethyl claim 1 , ethoxycarbonylmethyl claim 1 , 2-hydroxy-3-phenoxypropyl or 2-hydroxy-3-i-propoxypropyl.6. The azo dye of formula (1) according to claim 1 , wherein Ar is a radical of the formula (2a) wherein Ris hydrogen claim 1 , methyl or methoxy.7. A dichromatic or trichromatic dye mixture comprising at least one azo dye of formula (1) according to and at least one further disperse dye.8. A process for dyeing or printing semi-synthetic hydrophobic fibre material comprising applying the dye of formula (1) according to to the semi-synthetic hydrophobic fibre material.9. A semi-synthetic hydrophobic fibre material dyed or printed by the process according to .10. A process for dyeing or printing synthetic hydrophobic fibre material comprising applying the dye of formula (1) according to to the synthetic hydrophobic fibre material.11. A synthetic hydrophobic fibre material dyed or printed by the process according to . This application is a continuation application of U.S. patent application Ser. No. 14/413,583, filed Jan. 8, 2015, pending, which was the National Phase ...

COMPOSITIONS AND METHODS FOR IMPROVING GLUCOSE UPTAKE

A compound includes the structure of general Formula (II), pharmaceutically acceptable salts thereof, and/or solvates thereof: wherein R, R, R, are independently selected from the group consisting of null, hydroxy, alkoxy, and halo, or Rand Rtaken together form a cyclic boronate ester and Ris null; wherein when four bonds to boron are present, boron bears a formal negative charge and the structure further comprises a countercation that is potassium or sodium, X, X, X, and Xare independently selected from the group consisting of O, CH, and N, with the proviso that no more than two of combined O and N are selected, and Z is selected from the group consisting of hydrogen, alkyl, aryl, heteroaryl, and halogen, any of which may be optionally substituted. Such compounds can increase glucose uptake by cells and preferably do not substantially increase adipogenesis. 3. A pharmaceutical composition comprising a compound of and a pharmaceutically acceptable vehicle.4. A method of treating a disease comprising administering to a subject a therapeutically effective amount of a compound of .6. The method of claim 4 , wherein the disease is selected from the group consisting of hyperglycemia claim 4 , insulin resistance claim 4 , metabolic syndrome claim 4 , polycystic ovary syndrome (PCOS) claim 4 , prediabetes claim 4 , diabetes type 1 claim 4 , diabetes type 2 claim 4 , hepatic steatosis claim 4 , NAFLD claim 4 , non-alcoholic steato-hepatitis (NASH) claim 4 , and liver dysfunction (e.g. claim 4 , liver dysfunction characterized by fatty liver and/or insulin resistance) claim 4 , and combinations thereof. This application claims the benefit of U.S. Patent Application No. 61/714,899 filed on Oct. 17, 2012, the entire teaching of which is incorporated herein by reference.As the epidemic of obesity continues unabated, infectobesity, obesity of infectious origin, has been receiving increasing attention in the recent years (Rossner S., Lakartidningen. 102(24-25):1896-8 (2005); ...

TWO STEP DYEING PROCESS FOR PROTECTIVE YARNS AND TEXTILES MADE FROM HIGH TENACITY FIBERS

The present invention is a method for coloring knit, woven, or non-woven protective textiles made from yarns containing at least 20% synthetic high tenacity fibers, such as para-aramid or liquid crystal polyester (“LCP”), and for package-dyeing and skein-dyeing of such yarns. In embodiments, the textile is scoured to remove any impurities. A base coating of an adhesion promoting primer is then applied, which is typically a polymer or elastomer. The textile is typically immersed at zero tension in the primer liquor for an extended period. Afterward, the primer is dried and then cured at an elevated temperature to cross-link the primer and provide wash-fastness. A dye or printing ink of substantially any desired color and intensity is then applied. The protective yarns can include staple fibers and/or continuous filament fibers. The invention is further applicable to drum coating, jig processing, dye beck and other dying and coating processes. 1. A colorized yarn or textile comprising:a yarn containing at least 20% protective fibers, or a textile constructed from yarns containing at least 20% protective fibers, where protective fibers are defined as fibers having a tenacity of at least 12 gpd;a primer layer coating substantially all of the fibers, the primer layer being cross-linked sufficiently to render it insoluble under garment-washing conditions, the primer layer including molecular binding sites that are compatible for attachment of ink or dye molecules thereto; anda coloration layer including at least one of a substantive dye and pigment, the coloration layer being attached to the primer layer by a polymeric binding layer.2. The yarn or textile of claim 1 , wherein the protective fibers are liquid crystal polymer fibers.3. The yarn or textile of claim 1 , wherein the protective fibers are para-aramid.4. The yarn or textile of claim 1 , wherein the protective fibers are liquid crystal polyester fibers.5. The yarn or textile of claim 1 , wherein the primer ...

MARK-FABRIC MATERIAL AND MARK FORMING METHOD

A mark-fabric material includes a mark-fabric including, in the following sequence, microfibers, an adhesive layer including a thermoplastic resin having a melt flow rate of 100 g/10 min or less, and a release sheet. 1. A mark-fabric material , comprising , in the following sequence:a mark-fabric comprising microfibers;an adhesive layer including a thermoplastic resin having a melt flow rate of 100 g/10 min or less; anda release sheet.2. The mark-fabric material of claim 1 , wherein the microfibers comprise polyester.3. The mark-fabric material of claim 1 , wherein the mark-fabric is a 100% polyester woven fabric claim 1 , knitted fabric claim 1 , or non-woven fabric.4. The mark-fabric material of claim 1 , wherein the weight of the mark-fabric is from 100 g/mto 250 g/m.5. The mark-fabric material of claim 1 , wherein the mark-fabric is a white color.6. A mark forming method claim 1 , comprising:forming a pattern with a sublimating dye on a mark-fabric material including, in the following sequence, a mark-fabric comprising microfibers, an adhesive layer including a thermoplastic resin having a melt flow rate of 100 g/10 min or less, and a release sheet, by sublimation transfer using sublimation conditions of from 185° C. to 210° C. and from 30 seconds to 90 seconds.7. The mark forming method of claim 6 , wherein the microfibers comprise polyester.8. The mark forming method of claim 6 , wherein the mark-fabric is a 100% polyester woven fabric claim 6 , knitted fabric claim 6 , or non-woven fabric.9. The mark forming method of claim 6 , wherein the weight of the mark-fabric is from 100 g/mto 250 g/m.10. The mark forming method of claim 6 , wherein the mark-fabric is a white color.11. The mark-fabric material of claim 1 , wherein:the microfibers comprise polyester; andthe mark-fabric is a 100% polyester woven fabric, knitted fabric, or non-woven fabric.12. The mark-fabric material of claim 1 , wherein:the microfibers comprise polyester;the mark-fabric is a 100% ...

TEXTILE TREATMENT FOR SUBLIMATION INK TRANSFERS

Compositions and methods for treating textile materials so as to facilitate transfer of an image thereto using a dye sublimation transfer system are provided. The compositions are applied to the textile in the form of an aqueous pretreatment composition, which comprises a polymer resin and a crosslinking agent. The resin and crosslinking agent are cured upon the textile material to form an image-receiving area. The sublimation transfer system is then applied to the image-receiving area to form a finished, image-bearing textile product. 19-. (canceled)10. An aqueous composition for use with sublimation transfer systems on cotton-containing textile materials , said composition comprising:from about 5% to about 30% by weight of one or more water-dispersible polymer resins;from about 0.25% to about 10% by weight of one or more melamine crosslinking agents; andfrom about 60% to about 90% by weight of water.11. The composition according to claim 10 , wherein the one or more water-dispersible polymer resins comprises a polyester-polyurethane resin.12. The composition according to claim 10 , wherein the one or more melamine crosslinking agents comprises an alkylated melamine-formaldehyde resin.13. The composition according to claim 21 , wherein the one or more plasticizers comprises a benzoic acid.14. A cotton-containing textile material having a quantity of the composition of applied to at least an image-receiving area thereof.15. The textile material according to claim 14 , wherein the composition is applied to the textile material in an amount of from about 0.05 to about 1 g/in.16. The textile material according to claim 14 , wherein at least a portion of the water in the composition is removed after application to the textile material.17. The textile material according to claim 14 , wherein the one or more water-dispersible polymer resins and the one or more melamine crosslinking agents are reacted on the textile material to form a crosslinked-polymer coating.18. The ...

METHODS AND APPARATUSES FOR PROCESSING TEXTILE FIBERS, KETTLE AUTOMATIC OPERATION DEVICES, AND TEXTILE FIBER PRODUCTS

A method for processing textile fibers is provided. The method comprises: adding a plurality of raw materials for processing textile fibers into a plurality of kettles; preparing supercritical carbon dioxide; obtaining one or more natural plant dyes and one or more natural plant extracts from the plurality of raw materials, and dissolving the one or more natural plant dyes and the one or more natural plant extracts in the supercritical carbon dioxide; dyeing and functionally modifying the textile fibers simultaneously by using the supercritical carbon dioxide carrying a mixture of the one or more natural plant dyes and the one or more natural plant extracts; performing a post-process to recycle the supercritical carbon dioxide; and performing a cleaning process to clean the one or more natural plant dyes and one or more natural plant extracts. 1. A method for processing textile fibers , comprising:adding a plurality of raw materials for processing textile fibers into a plurality of kettles;preparing supercritical carbon dioxide;obtaining one or more natural plant dyes and one or more natural plant extracts from the plurality of raw materials, and dissolving the one or more natural plant dyes and the one or more natural plant extracts in the supercritical carbon dioxide;dyeing and functionally modifying the textile fibers simultaneously by using the supercritical carbon dioxide carrying a mixture of the one or more natural plant dyes and the one or more natural plant extracts;performing a post-process to recycle the supercritical carbon dioxide; andperforming a cleaning process to clean the one or more natural plant dyes and one or more natural plant extracts.2. The method of claim 1 , wherein adding the plurality of raw materials for processing textile fibers into the plurality of kettles includes:automatically opening, using a kettle automatic operation device, kettle covers of a natural plant dye extraction kettle, a natural plant dyes and extracts kettle, and a ...

METHOD FOR MANUFACTURING A FOAMED FABRIC

A method for manufacturing a foamed fabric includes providing a fabric which includes at least one layer including a plurality of first foamable filaments made from a first foamable polymeric material, infusing the fabric with a supercritical fluid in a pressurized vessel, subjecting the infused fabric to a depressurizing process to permit the at least one layer to undergo an initial stage of foaming so as to obtain a pre-foamed fabric, placing the pre-foamed fabric in a mold cavity, and heating the mold cavity to obtain a molded foamed fabric. 1. A method for manufacturing a foamed fabric , comprising:a) providing a fabric which includes at least one layer including a plurality of first foamable filaments made from a first foamable polymeric material;b) infusing the fabric with a supercritical fluid in a pressurized vessel;c) subjecting the infused fabric to a depressurizing process to permit the at least one layer to undergo an initial stage of foaming so as to obtain a pre-foamed fabric;d) placing the pre-foamed fabric in a mold cavity; ande) heating the mold cavity to obtain a molded foamed fabric.2. The method according to claim 1 , wherein in b) claim 1 , the supercritical fluid is formed at a temperature ranging from 90° C. to 180° C. under a pressurized atmosphere.3. The method according to claim 1 , wherein in b) claim 1 , the supercritical fluid contains a dye dispersed or dissolved therein so as to impart the dye to the infused fabric.4. The method according to claim 3 , wherein the dye is coated onto a carrier to form a dye-coated carrier dispersed in the supercritical fluid.5. The method according to claim 1 , wherein in a) claim 1 , the at least one layer further includes a plurality of second foamable filaments which are made from a second foamable polymeric material and which are woven with the first foamable filaments.6. The method according to claim 5 , wherein the first foamable polymeric material has foamability different from that of the second ...

DISPERSE DYE COMPOSITION, DISPERSE DYE AND PREPARATION METHOD AND USE THEREOF

A disperse dye composition, disperse dye and preparation method and use thereof. The disperse dye is suitable for fabrics, particularly for dyeing and printing of dacron and blended fabrics thereof. 133-. (canceled)35: The disperse dye composition according to claim 34 , wherein Xin formula (6) is a cyano group or a nitro group claim 34 , Xis a cyano group claim 34 , Ris hydrogen.36: The disperse dye composition according to claim 34 , wherein Xin formula (3) is chlorine claim 34 , Xin formula (6) is a cyano group or a nitro group claim 34 , Xis a cyano group claim 34 , Ris hydrogen.45: The disperse dye composition according to claim 34 , wherein based on the total weight of said composition claim 34 , comprising:Component A in the amount of 2˜73% by weight,Component B in the amount of 7˜40% by weight,Component C in the amount of 20˜58% by weight,Optionally, Component D in the amount of 0˜70% by weight,Optionally, Component E in the amount of 0˜10% by weight,Optionally, Component F in the amount of 0˜47% by weight, andOptionally, Component G in the amount of 0˜47% by weight.46: A disperse dye claim 34 , wherein said disperse dye contains the disperse dye composition according to and auxiliary materials.47: The disperse dye according to claim 46 , wherein said auxiliary materials comprise assistants and water.48: The disperse dye according to claim 47 , wherein said assistants comprise one or a combination of two or more of the following substances: a naphthalenesulfonic acids-formaldehyde condensate claim 47 , lignin sulfonate claim 47 , sodium sulphate claim 47 , a surfactant claim 47 , a bactericide or other dispersion agents for dyes.49: The disperse dye according to claim 47 , wherein the weight ratio of the assistants to the disperse dye composition is 0.3˜4:1.50: The disperse dye according to claim 46 , wherein the disperse dyes present as liquid with a solid content of 20˜50% after ground by a sand mill or a grinder; or the disperse dyes present as powder or ...

DYED ARTIFICIAL LEATHER BASE MATERIAL, NAPPED ARTIFICIAL LEATHER, RESIN LAYER-EQUIPPED ARTIFICIAL LEATHER, SHOES, DECORATING SHEET, AND DECORATIVE MOLDED BODY

Disclosed is an artificial leather base material having a surface with a lightness L* value of ≤50 and including a fiber base material that includes cationic dye-dyeable polyester fibers and an elastic polymer, the artificial leather base material being dyed with at least one cationic dye. Also provided is a resin layer-equipped artificial leather, a napped artificial leather, and a shoe that use the artificial leather base material is used. Also provided is a decorating sheet including the artificial leather base material, and a decorative molded body using the same.

HIGH WET FAST DISPERSE DYE MIXTURES

This invention relates to disperse azo dye mixtures, which have Navy or Black colour and are AOX-free. 128.-. (canceled)31. The dye mixture according to claim 29 , wherein independent from each other{'sup': '1', 'sub': 1', '2, 'Ris hydrogen or (C-C)-alkyl,'}{'sup': '2', 'sub': 1', '2, 'Ris (C-C)-alkyl,'}{'sup': 3', '6, 'sub': 1', '2', '2', 'n', '2', 'n', '1', '2', '2', 'n', '2', 'm', '1', '2, 'Rto Ris (C-C)-alkyl, (CH)-phenyl, (CH)—COO—(C-C)-alkyl or (CH)—COO(CH)—CO—(C-C)-alkyl,'}{'sup': 1', '2, 'Xand Xare hydrogen, bromo, chloro, nitro or cyano,'}{'sup': 3', '7, 'Xand Xare nitro or cyano,'}{'sup': '4', 'Xis hydrogen, nitro or cyano,'}{'sup': 5', '6, 'Xand Xare hydrogen, bromo, chloro, nitro or cyano,'}{'sup': '8', 'Xis hydrogen, nitro or cyano,'}{'sup': '1', 'sub': 1', '4', '2', 'm, 'Yis (C-C)-alkyl or (CH)-phenyl,'}{'sup': '2', 'sub': 2', 'm, 'Yis phenyl or (CH)-phenyl,'}{'sup': '3', 'sub': 1', '2, 'Yis hydrogen, or (C-C)-alkyl'}{'sup': '4', 'sub': 1', '8', '2', 'm, 'Yis (C-C)-alkyl or (CH)-phenyl,'}{'sup': '5', 'sub': 1', '2', '1', '2, 'Yis hydrogen, (C-C)-alkyl or (C-C)-alkoxy, and'}n and m is 1 or 2.32. The dye mixture according to claim 29 , wherein independent from each other{'sup': '1', 'Ris hydrogen or methyl,'}{'sup': '2', 'Ris methyl or ethyl,'}{'sup': 3', '6, 'sub': 1', '2', '2', 'n', '2', 'n', '1', '2', '2', 'n', '2', 'm', '1', '2, 'Rto Ris (C-C)-alkyl, (CH)-phenyl, (CH)—COO—(C-C)-alkyl or (CH)—COO(CH)—CO—(C-C)-alkyl,'}{'sup': 1', '2, 'Xand Xare hydrogen, bromo, chloro, nitro or cyano,'}{'sup': 3', '4', '7, 'X, Xand Xare nitro,'}{'sup': 5', '6, 'Xand Xare hydrogen, bromo, chloro, nitro or cyano,'}{'sup': '8', 'Xis hydrogen,'}{'sup': 1', '2, 'sub': 2', 'm, 'Yand Yare (CH)-phenyl,'}{'sup': '3', 'Yis hydrogen or methyl,'}{'sup': '4', 'sub': 1', '8', '2', 'm, 'Yis (C-C)-alkyl or (CH)-phenyl,'}{'sup': '5', 'Yis hydrogen, O-methyl or O-ethyl, and'}n and m is 1 or 2.33. The dye mixture according to claim 29 , wherein independent from each other{'sup': '1', ' ...

REACTIVE COMPOUND

A reactive compound represented by the following formula (I): 2. The reactive compound according to claim 1 , wherein Arand Arare a trivalent heterocyclic group. The present invention relates to a reactive compound having a specific structure.In late years, COreleased into the atmosphere is required to reduce for prevention of global warming. There is a suggestion on adoption of a solar system using a silicon based solar battery of pn junction type as one embodiment of electronic devices. However, monocrystal silicon, polycrystal silicon and amorphous silicon as materials of a silicon based solar battery need high temperature and high vacuum processes in production thereof.In contrast, for an organic film solar battery containing an organic layer containing a polymer compound, high temperature and high vacuum processes used for production of a silicon based solar battery can be omitted, thus, the organic film solar battery can possibly be produced at low cost via only an application process, and is attracting attention recently. As a polymer compound used in an organic film solar battery, a polymer compound composed of a repeating unit (A) and a repeating unit (B) is known (Patent document 1).Patent document 1: Japanese Patent Application National Publication (Lai-open) No. 2009-506519However, since most monomers used for synthesis of the abov-described polymer compound are in the form of oil, it is hard to improve its purity by r-crystallization and the like, and precise control of polymerization thereof is difficult.The present invention has an object of providing a reactive compound capable of easily improving its purity.The present invention is as described below.[1] A reactive compound represented by the formula (I):[In the formula (I), Z represents a divalent group. A plurality of Y may be the same or different, and represent a monovalent boronate residue having at least one hydroxyl group, Arand Armay be the same or different, and represent a trivalent ...

Aox-free navy and black disperse dyes

This invention relates to disperse azo dye mixtures, which have Navy or Black colour and are AOX-free.

METHODS FOR PRODUCING BORYLATED ARENES

Methods for the borylation of aromatic compounds using cobalt catalysts are provided. 2. The process of claim 1 , wherein the aromatic substrate is selected from the group consisting of a substituted or unsubstituted aryl compound claim 1 , a substituted or unsubstituted six-membered heteroaromatic compound claim 1 , a substituted or unsubstituted five-membered heteroaromatic compound claim 1 , and combinations thereof.9. The process of claim 1 , wherein the borylation reagent comprises a B—B bond claim 1 , a B—H bond claim 1 , or a combination thereof.11. The process of claim 1 , wherein the catalytic cobalt complex comprises a cobalt(I) complex.12. The process of claim 1 , wherein the catalytic cobalt complex comprises a cobalt chelate complex comprising a bidentate ligand.23. The process of claim 1 , wherein the catalytic cobalt complex comprises PyCo(CHSiMe) claim 1 , [(Cp*Co)-μ-(η:η-toluene)] claim 1 , or a combination thereof.24. The process of claim 1 , wherein the aromatic substrate is contacted with the catalytic cobalt complex and the borylation reagent at a temperature of from greater than 25° C. to 85° C.26. The process of claim 25 , wherein X is a substituted or unsubstituted phenyl or a substituted or unsubstituted pyridyl.29. The process of claim 25 , wherein the borylation reagent comprises a B—B bond claim 25 , a B—H bond claim 25 , or a combination thereof.31. The process of claim 25 , wherein the catalytic cobalt complex comprises a cobalt(II) complex.42. The process of claim 25 , wherein the catalytic cobalt complex comprises PyCo(CHSiMe) claim 25 , [(Cp*Co)-μ-(η:η-toluene)] claim 25 , an N-heterocyclic carbene-ligated cobalt complex claim 25 , or a combination thereof.43. The process of claim 25 , wherein the aromatic substrate is contacted with the catalytic cobalt complex and the borylation reagent at a temperature of from greater than 25° C. to 80° C. This application claims the benefit of U.S. Provisional Patent Application Ser. No. 62/012, ...

AQUEOUS DYEING COMPOSITION AND PROCESS FOR SYNTHETIC SUBSTRATES

A composition of matter for aqueous dyeing of synthetic substrates and a method of aqueous dyeing of a synthetic substrate. 1. A composition of matter for solution dyeing of synthetic substrates , said composition comprising:i. water, and for every 1200 milliliters of water,ii. 500 to 725 milliliters of propylene glycol;iii. 167 to 450 milliliters of surfactant;iv. 0 to 250 milliliters of pine oil;v. 0 to 2 50 milliliters of acetic acid;vi. 0 to 250 milliliters of limonene;vii. 0 to 350 milliliters of naphthalene hydrocarbon,viii. 0 to 250 milliliters of dye penetrant, andix. a predetermined amount of dye.2. A method of aqueous dyeing of a synthetic substrate claim 1 , said method comprising contacting said synthetic substrate with a composition of matter as claimed in for a predetermined period of time at a predetermined temperature and pressure until a desired color and color intensity of said synthetic substrate is achieved. This application is a utility application claiming priority from U.S. Provisional patent application Ser. No. 62/013,013, filed Jun. 17, 2014.For years scientist and chemists in the carpet industry have believed aqueous dyeing of polyester carpet was impossible. They have said, the only viable way to color polyester was to solution dye it (adding a pigment when the polymer was in a liquid or molten state).Some individuals and carpet mills have experimented with aqueous dyeing, but to the inventor's knowledge have not been successful. There is chemistry available that is used in the dyeing of cloth for upholstery fabric and clothing, but the amount of chemical products necessary for the aqueous dyeing of polyester carpet is prohibitive and not practical. In dyeing carpet only light colors can be achieved, using known chemistry.Prior art chemicals are not environmentally friendly. With the exception of the formulas using naphthenic hydrocarbons, the materials in this invention for dyeing polyester carpet are environmentally friendly. The ...

BORON-CONTAINING SMALL MOLECULES

Compounds, pharmaceutical formulations, and methods of treating anti-inflammatory conditions and/or helminth-associated diseases are disclosed. 2. The compound of claim 1 , wherein Ris fluorine or chlorine.3. The compound of claim 1 , wherein Ris OR claim 1 , and Ris selected from the group consisting of substituted or unsubstituted alkyl claim 1 , substituted or unsubstituted heteroalkyl claim 1 , substituted or unsubstituted cycloalkyl claim 1 , substituted or unsubstituted heterocycloalkyl claim 1 , substituted or unsubstituted aryl claim 1 , and substituted or unsubstituted heteroaryl.4. The compound of claim 1 , wherein Ris OR claim 1 , and Ris selected from the group consisting of substituted or unsubstituted alkyl claim 1 , substituted or unsubstituted heteroalkyl and substituted or unsubstituted cycloalkyl.6. A pharmaceutical formulation comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(a) the compound of , or a pharmaceutically acceptable salt thereof; and'}(b) a pharmaceutically acceptable excipient.7. A method of decreasing the release of a cytokine or a chemokine claim 1 , the method comprising: contacting a cell with the compound of or a pharmaceutically acceptable salt thereof claim 1 , wherein the release of the cytokine or chemokine by the cell is decreased.8. A method of treating a condition or disease claim 1 , in an animal claim 1 , the method comprising administering to the animal a therapeutically effective amount of the compound of or a pharmaceutically acceptable salt thereof claim 1 , thereby treating the condition or disease.9. The method of claim 8 , wherein the condition is selected from the group consisting of schistosomiasis claim 8 , psoriasis claim 8 , atopic dermatitis claim 8 , rheumatoid arthritis claim 8 , an inflammatory bowel disease claim 8 , asthma and chronic obstructive pulmonary disease.10. The method of claim 8 , wherein the condition or disease is a helminth-associated disease.11. A method of inhibiting a ...

WATERLESS STAINING TECHNIQUE FOR TEXTILE

Anhydrous dyeing method for textile, including the steps of: using a pure dye as a plating material and a textile fabric as a substrate, and depositing the dye onto a surface of the textile fabric by using a physical vapor deposition technique. The color of plated textile fabric is fixed through steaming, heat setting or other post-processing methods. The invention achieves the purpose of dyeing textile fabric by depositing dye onto the surface of the textile fabric uniformly and densely using a physical vapor deposition technology, and fixing the color in a finishing step. The process is simple and convenient, produces no waste water discharge, has a high utilization rate of dye, and is operable and feasible for mass production. 1. An anhydrous dyeing method for textile , comprising the steps of: (a) suspending substantially uniformly dried particles of a dye in a closed space with a predetermined degree of vacuum at a predetermined temperature; (b) passing a fabric to be dyed through the closed space to allow the dried dye particles adhere directly from a suspension state in the air to the surface of the fabric to achieve a dyeing effect , wherein the enclosed space does not contain supercritical carbon dioxide.2. The anhydrous dyeing method according to claim 1 , wherein the dried particles are of a natural dye or a synthetic dye.3. The anhydrous dyeing method according to claim 1 , wherein the dye is in the form of powder claim 1 , granule or lump before being suspended in the air.4. The anhydrous dyeing method according to claim 1 , wherein the fabric is a fabric of a synthetic fiber selected from polyester claim 1 , acetate claim 1 , polyamide claim 1 , polypropylene claim 1 , polyvinyl chloride claim 1 , acrylic claim 1 , or a fabric of a natural fiber selected from cotton claim 1 , linen claim 1 , silk claim 1 , viscose fibers claim 1 , or a fabric of a blended fiber from said synthetic fibers and said natural fibers.5. The anhydrous dyeing method according ...

TRANSPARENCY-ENHANCED FABRIC USING POLYESTER-ETHER BLOCK COPOLYMER YARN, AND MANUFACTURING METHOD THEREFOR

The present invention relates to a transparency-enhanced fabric using a polyester-ether block copolymer yarn, and a manufacturing method therefor and, more specifically, the method comprises the steps of: manufacturing a polyester-ether block copolymer yarn; manufacturing a textile by using the yarn; and manufacturing a transparency-enhanced fabric by thermally contracting the textile. According to a transparency-enhanced fabric using a polyester-ether block copolymer yarn and a manufacturing method therefor, of the present invention, a polyester-ether block copolymer mono-yarn is used such that the present invention has enhanced transparency allowing a see-through effect and, simultaneously, has excellent stretchability, air permeability, and wear strength. 1. A transparency-enhanced fabric that is a heat-shrinked textile which is woven using a polyester-ether block copolymer yarn.2. The transparency-enhanced fabric according to claim 1 ,characterized in that the surface of the textile is a mono-yarn of a polyester ether block copolymer, and the back surface is consisted of a heterogeneous yarn of polyester, nylon or CDP.3. The transparency-enhanced fabric according to claim 1 ,characterized in that the length and width are respectively shrunk by 10˜30% through a hot air method using a tenter, a heating method using a thermal cylinder drum, or a shrinking method in water using a dyeing machine.4. The transparency-enhanced fabric according to claim 2 ,characterized in that the back surface of the textile is formed by any one printing method of gravure method, rotary method, digital printing method, and screen printing method.5. The transparency-enhanced fabric according to or claim 2 , characterized in that the textile which is heat-shrinked is embodied with a color by dyeing using any one of a disperse dye claim 2 , an acid dye claim 2 , and a basic dye.6. A method of manufacturing a transparency-enhanced fabric characterized by comprising the steps of: ...

NOVEL BORONIC ESTERS AND METHODS FOR MAKING THE SAME

There is provide herein a compound of Formula (1): 2. The compound of claim 1 , wherein:{'sup': 1', '2', '3', '4', '5, 'R, R, R, R, and Rare each independently selected from the group consisting of H, an alkyl group, a heteroalkyl group, a cycloalkyl group, an alkenyl group, a heteroalkenyl group, an alkynyl group, a heteroalkynyl group, an aryl group, a heteroaryl group, a heterocyclic group, and an acyl group.'}3. The compound of claim 1 , wherein the organic group is substituted with one or more halide claim 1 , hydroxyl claim 1 , acyloxyl or acyl group.4. The compound of claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , Rare H and Ris CH.5. The compound of claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , Rare H and Ris a long chain organic compound.7. The process of claim 6 , wherein Ris alkyne claim 6 , alkene claim 6 , or an aromatic hydrocarbon.8. The process of claim 7 , wherein R claim 7 , R claim 7 , R claim 7 , and Rare H claim 7 , Ris CH claim 7 , and Ris alkyne.9. The process of claim 6 , wherein oxidizing the compound of formula (2) is performed with at least one conditions and/or reagents selected from RuCl.3HO claim 6 , HIO claim 6 , MeCN claim 6 , and 23° C.11. The compound of claim 10 , wherein:{'sup': 1', '2', '3', '4', '5', '6', '7, 'R, R, R, R, R, R, and Rare each independently selected from the group consisting of H, an alkyl group, a heteroalkyl group, a cycloalkyl group, an alkenyl group, a heteroalkenyl group, an alkynyl group, a heteroalkynyl group, an aryl group, a heteroaryl group, a heterocyclic group, and an acyl group.'}12. The compound of claim 10 , wherein the organic group is substituted with one or more halide claim 10 , hydroxyl claim 10 , acyloxyl or acyl group.13. The compound of claim 10 , wherein R claim 10 , R claim 10 , R claim 10 , R claim 10 , Rare H claim 10 , Ris CH claim 10 , and Ris H or an organic group.17. The process of claim 15 , wherein R claim 15 , R claim 15 , R claim 15 , and Rare H claim 15 , and Ris ...

PROCESS FOR DYEING A TEXTILE SUBSTRATE CONTAINING RESIDUAL OLIGOMERS

A process for dyeing a textile substrate containing residual oligomers includes the steps of: 1. A process for dyeing a textile substrate containing residual oligomers , comprising the steps of:a) attaching the textile substrate on a mounting carrier to constitute a substrate-loaded carrier which is to be subjected to supercritical dyeing in a dyeing autoclave; andb) overlying the textile substrate of the substrate-loaded carrier with a micro-porous film which includes pores having a pore size such that when the textile substrate is dyed in the dyeing autoclave, a dye-containing supercritical fluid is allowed to pass through the micro-porous film to permit the textile substrate to be dyed while the residual oligomers entrained in the supercritical fluid are retained by the micro-porous film.2. The process according to claim 1 , wherein the pore size of the pores of the micro-porous film is smaller than a particle size of the residual oligomers.3. The process according to claim 2 , wherein the pore size of the pores of the micro-porous film is in a range from 0.1 μm to 1.0 μm.4. The process according to claim 3 , wherein the pore size of the pores of the micro-porous film is in a range from 0.2 μm to 0.8 μm.5. The process according to claim 1 , wherein the micro-porous film has a thickness in a range from 10 mm to 90 mm.6. The process according to claim 1 , wherein the micro-porous film is made from a polymeric material.7. The process according to claim 6 , wherein the polymeric material is polytetrafluoroethylene.8. The process according to claim 6 , wherein the polymeric material is polyurethane.9. The process according to claim 6 , wherein the polymeric material is polypropylene.10. The process according to claim 1 , wherein the textile substrate is made from a polyester material.11. The process according to claim 1 , wherein the dye-containing supercritical fluid includes a disperse dye.12. The process according to claim 1 , wherein in step a) claim 1 , the ...

Alkoxylated phenol derivatives

Alkoxylated phenols (I) with 21-40 oxyalkylene groups per molecule, are new. Alkoxylated phenols of formula (I) with 21-40 oxyalkylene groups per molecule, are new. R<1>, R<2>, R<3> = H, optionally substituted cyclohexyl or optionally substituted phenyl (at least one of these groups is not H); R<4>, R<5> = methyl or H; and n = 21-40. Independent claims are also included for: (a) a method for the production of (I) by reacting the corresponding phenol with n mol equivs. of the corresponding alkylene oxide (i.e. ethylene oxide substituted with R<4> and R<5> at positions 1 and 2); and (b) formulations containing active pharmaceutical or agrochemical ingredients and compounds (I).

Color dyeing system for plastic films

A process for the continuous dyeing of plastic films, such as polyethylene terephthalate, is characterized by passing the film through a dye bath comprised of dye stuffs dissolved, suspended or dispersed in a liquid carrier comprised at least in part of a polymer, preferably a polyol, having at least one free hydroxyl group and a molecular weight within the range of from about 200 to about 600. The hydrogen bonding provided by the hydroxyl group, together with the high molecular weight and high boiling point of the polyol, mitigate against migration of the dye stuff out of the film, i.e., fading of the film, and impart long lasting color fastness to the film. Rapid diffusion of the dye bath into the film is enhanced by thermal and ultrasonic energization of the bath.

Black mixtures of reactive azo dyes and their use in dyeing fibrous materials containing hydroxy and/or carbonamide groups

Dye mixtures are described of one or more disazo dyes of the formula (1) and one or more monoazo dyes of the formula (2) <IMAGE> in which R<1>, R<2>, R<3>, R<4>, R<5> and R<6> are identical to or different from one another and are each hydrogen, methyl, ethyl, methoxy, ethoxy, sulpho or carboxyl, Y independently at each occurrence is vinyl, ss-chloroethyl,ss-thiosulphatoethyl or ss-sulphatoethyl, and M is hydrogen or an alkali metal. The dye mixtures contain from 50 to 95% by weight of the disazo dye(s) of the formula (1) and from 5 to 50% by weight of the dye(s) of the formula (2). The mixtures may also contain a yellow or red dye to influence the shade. They are used for dyeing and printing fibre materials by procedures analogous known to those for fibre-reactive dyes.

4‑(1‑羟基‑1,3‑二氢苯并[c][1,2]氧杂硼杂环戊二烯‑5‑基氧基)苯氰的制备方法

本发明公开了一种抗炎药含硼小分子4‑(1‑羟基‑1,3‑二氢苯并[c][1,2]氧杂硼杂环戊二烯‑5‑基氧基)苯氰(化合物I)的制备方法，其包括如下步骤：在有机溶剂中，以化合物II为起始物料，在强碱存在下与硼酸酯反应生成硼酸中间体，不经分离，继续进行环合反应，“一锅法”制备化合物I。本路线采用“一锅法”制得化合物I，避免了繁琐的保护脱保护步骤，操作简便、环境友好、有明显成本优势，适用于工业化大规模生产。

Application of 2,6-dimethylanilino lithium in catalyzing hydroboration of carbonyl compound and borane

Disclosed is an application of 2,6-dimethylanilino lithium in catalyzing hydroboration of a carbonyl compound and borane. In an anhydrous oxygen-free environment, borane is added in an inert gas atmosphere to a reaction flask having been subjected to dehydration and deoxidation treatment, then a catalyst 2,6-dimethylanilino lithium is added and uniformly mixed, a carbonyl compound is further added to carry out hydroboration, and the reaction is terminated by exposure to air to obtain a borate. The present invention has found for the first time that 2,6-dimethylanilino lithium is extremely efficient in catalyzing the hydroboration of carbonyl compounds, and thus provides a novel solution for the preparation of borates by hydroboration of carbonyl compounds with borane. The 2,6-dimethylanilino lithium has high catalytic activity for the hydroboration of the carbonyl compound and borane with mild reaction conditions, a short reaction time, and a high reaction yield. The reaction is simple and controllable, involves simple post-treatment, and employs a solvent-free system, thereby reducing environmental pollution. The disclosed catalyst is widely applicable to aromatic aldehydes (ketones) having different substitution positions and different electronic effects and to heterocyclic aldehydes (ketones) and fatty aldehydes (ketones), thereby providing more choices for obtaining borate compounds with different substituent structures.

Method for preparing borate ester on basis of tricyclopentadienyl rare earth metal complex

Disclosed is a method for preparing a borate ester on the basis of a tricyclopentadienyl rare earth metal complex, the method comprising the following steps: uniformly stirring and mixing a catalyst, a borane and a carbonyl compound for reaction to prepare a borate ester, wherein the catalyst is a tricyclopentadienyl rare earth metal complex; and the molecular formula of the tricyclopentadienyl rare earth metal complex can be expressed as: Ln(Cp) 3 , wherein Ln represents a rare metal selected from one of lanthanide elements. The preparation method has a higher catalytic activity, mild reaction conditions, a product that is easy to post-treat, a short reaction time, a low catalyst consumption amount, and a good range of applicable substrates, and can be used for industrial production.

三茂稀土金属配合物作为催化剂在催化酮和频哪醇硼烷合成反应中的应用

本发明公开了三茂稀土金属配合物作为催化剂在催化酮和频哪醇硼烷合成反应中的应用，包括以下步骤，将催化剂、硼烷与酮搅拌混合均匀，反应制备硼酸酯；三茂稀土金属配合物的分子式可表示为：Ln(Cp) 3 ，Ln表示稀土金属，选自镧系元素中的镧、钇、钕、镱、钐中的一种。该制备方法具有更高的催化活性，同时反应条件温和，产物后处理容易，反应时间短，催化剂用量低，并有很好的底物适用范围，而且可以进行工业化生产。

基于苯胺基锂制备硼酸酯的方法

本发明公开了基于苯胺基锂制备硼酸酯的方法，无水无氧环境下，惰性气体氛围中，在经过脱水脱氧处理的反应瓶中加入硼烷，然后加入催化剂苯胺基锂，混合均匀，再加入酮，发生硼氢化反应，暴露于空气中终止反应，得到硼酸酯；所述酮为芳香酮或者杂环酮。本发明首次发现苯胺基锂能极其高效的催化芳香酮或者杂环酮与硼烷发生硼氢化反应，为采用羰基化合物与硼烷发生硼氢化反应制备硼酸酯提供了新的方案。

Norfloxacin intermediate

내용 없음. No content.

Method of producing anhydrides of 6-fluoro-7-chloro-1-methylamino-4-oxo-1,4-dihydroquinoline-3-carbolic acid and boric acids

New 6-fluoro-7-chloro-1-methylamino-4-oxo-1,4-dihydro-quinoline-3-carboxylic acid/boric acid anhydrides of general formula (I), (wherein R and R<1> stand for halogen; an aliphatic acyloxy group comprising 2-6 carbon atoms and optionally substituted by halogen; or an aromatic acyloxy group comprising 7-11 carbon atoms). The new compounds of general formula (I) are valuable intermediates useful in the preparation of the antibacterial agent 6-fluoro-1-methylamino-7-(4-methyl-piperazino)-4-oxo-1,4-dihydro-quinoline-3-carboxylic acid. The new compounds of general formula (I) may be prepared by reacting a compound of formula (II), or a compound of general formula (III), (wherein R<2> stands for alkyl comprising 1-4 carbon atoms) with hydrogen fluoro borate of the formula (IV), or a borone trihalide of general formula (V), (wherein X stands for fluorine, chlorine or bromine) or a complex thereof formed with an ether or a borone derivative of general formula (VI), (wherein R<3>, R<4> and R<5> stand for alkyl comprising 1-5 carbon atoms and optionally substituted by halogen or aryl comprising 6-10 carbon atoms).

Activation of aluminum in preparation of aluminum alkyls

A kind of dyeing and printing process of cloth

本发明涉及印染技术领域领域，公开了一种布料的印染工艺，包括：S1、对布料进行翻布、烧毛、退浆、煮练以及漂白处理；S2、对S1中的布料进行预定型；S3、使用低温等离子体照射S2中得到的布料从而对布料进行刻蚀，低温等离子体照射的基本步骤为：将S2中得到的布料放入低温等离子体处理设备的处理腔中，随后抽真空使处理腔中的真空度小于3Pa，然后通入工作气体，控制一定的处理时间、功率和压力；S4、对S3中得到的布料进行染色；S5、对S4中染色后的布料进行脱水定型，得到成品。本发明通过对布料进行低温等离子处理，使得布料表面出现凹凸不平，降低纤维表面对光的反射能力，改进纤维的表观色泽。

Dyeing method and dye composition used therein

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Rapid disperse dyeing of polyester substrates

Disclosed is a method of rapid dyeing a substrate comprising polyester fibres at a temperature above 100 DEG C. comprising bringing into contact with the substrate an aqueous dyebath containing a mixture of at least two disperse dyes having each individually specific physicochemical properties.

Application of trisilicon amine rare earth complex for catalyzing hydroboration reaction between aldehyde and borane

An application of a trisilicon amine rare earth complex for catalyzing hydroboration reaction between an aldehyde and a borane. The trisilicon amine complex La[N(SiMe 3 ) 2 ] 3 can provide, under mild conditions, a highly catalytic effect for a hydroboration reaction between an aldehyde and a borane. The usage volume of a catalyst is only 0.1-0.5% of the molar quantity of the aldehyde. The reaction has a very fast reaction speed and reaches a yield exceeding 90% after a 10-minute reaction. When compared to a catalytic system of the prior art, the invention uses less catalyst, improves yield, requires less time, and can be used under mild conditions.

Bis(borate) preparation technology

本发明公开了一种制备联硼酸酯的工艺。硼烷络合物和相应的二醇反应生成相应的醇硼烷，随后在铁催化剂存在下发生自身偶联形成联硼酸酯。该方法合成步骤短，安全性高，反应条件温和，适合多种联硼酸酯的合成。

Method for imitating batik effect on marked textile materials from polyether fibres

Сущность изобретени : способ имитации эффекта батика на напечатанных текстильных материалах из полиэфирных волокон состоит в обработке материала 2,5-3,5%-ным водным раствором сульфата меди с последующей сушкой, печатанием водным составом, содержащим дисперсный краситель, интенсификатор амидного типа и загуститель присулон SPE-909S, механической обработкой и зрелением. Устойчивость окраски к раствору мыла при 40&amp;deg; С - 5 баллов, к поту 4-5 баллов, к трению (сухому и мокрому) - 4 балла, к .свету - 5-7 баллов (в зависимости от типа красител ). 3 табл.

Textile printing method, an ink, printed cloth in the same method and the processing products thereof

本发明所揭示的是一种印花方法，在该方法中根据喷墨装置至少在布上使用两种墨以进行印花，它至少包括三步：(a)布料上用到的两种油墨至少有一部分相互重叠，(b)对已使用墨的布料进行热处理；和(c)清洗热处理过的布料，其中布料是由可用分散染料染色的纤维组成的，每种油墨包含一具体的着色剂，分散着色剂的化合物和一种水成液介质。

Dyeing method for calcium alginate fibers

本发明属于纤维染色技术领域，具体涉及一种海藻酸钙纤维染色的方法。本发明所述的海藻酸钙纤维的染色方法，是采用含有多乙烯多胺骨架结构的染料对海藻酸钙纤维进行染色。本发明从根本上避免了传统染料染色过程中需要加入无机盐促染而导致的纤维损伤这一弊病，纤维染色后强力损失小；同时，相对于一般直接染料与纤维之间较弱的分子间作用力和氢键的作用，该染料分子与纤维之间的作用力更强，从而使其具有更高的上染率和皂洗牢度等优势，染色后的纤维颜色均匀、鲜艳，满足海藻酸钙纤维染色要求，是一种节能环保的染色方法。

Application of o-methyl aniline lithium in catalyzing imine and borane hydroboration reaction

本发明涉及邻甲基苯胺基锂的应用，具体涉及邻甲基苯胺基锂在催化亚胺和硼烷的硼氢化反应中的应用。依次将催化剂、硼烷和亚胺搅拌混合均匀，反应1～2小时，暴露于空气中终止反应，反应液减压除去溶剂，得到不同取代基的硼酸酯。本发明公开的邻甲基苯胺基锂可以在室温条件下高活性的催化亚胺和硼烷的硼氢化反应，催化剂用量仅为亚胺摩尔量的4~5mol%，反应可达到90%以上的收率，与已有的催化体系相比，利用了简单的邻甲基苯胺基锂，反应条件温和，在优化条件下不同取代基的硼酸酯的产率可达99%。

A kind of method that borate is prepared based on triscyclopentadienyl rare earth metal complex

本发明公开了一种基于三茂稀土金属配合物制备硼酸酯的方法，包括以下步骤，将催化剂、硼烷与醛搅拌混合均匀，反应制备硼酸酯；所述催化剂为三茂稀土金属配合物；三茂稀土金属配合物的分子式可表示为：Ln(Cp) 3 ，Ln表示稀土金属，选自镧系元素的一种。该制备方法具有更高的催化活性，同时反应条件温和，产物后处理容易，反应时间短，催化剂用量低，并有很好的底物适用范围，而且可以进行工业化生产。

Dye composition and dyeing method of hydrophobic fibers using the same

폴리에스테르 섬유 및 다른 섬유 특히 아세테이트 섬유와의 혼방품의 염색에 있어서 견뢰성이 우수하고, 동색 염색성 및 환원내성이 우수한 염색물을 얻는다. 특정의 구조식으로 표시되는 분산염료를 배합한 염료 조성물을 조제하고, 이것을 사용하여 소수성 섬유 특히 폴리에스테르 섬유와 다른 섬유와의 혼방품을 염색함으로써 고견뢰성 또한 염색성의 균형이 대단히 양호한 혼방품의 염색물을 얻을 수 있다.

Patent JPS51109381A

Orange disperse dye composition having excellent moisture resistance

본 발명은 고 습윤견뢰도의 오렌지색 분산염료 조성물에 관한 것으로서, 더욱 상세하게는 하기 화학식1의 오렌지색 분산염료와 하기 화학식2의 오렌지색 분산염료가 소정의 함량비로 함유되어 있어 폴리에스테르 섬유의 침염 및 저온염색 가공에서 높은 염착률과 고 습윤견뢰도를 나타내고, 특히 폴리에스테르와 나일론의 교직물 및 폴리에스테르와 스판덱스 혼방섬유와 같이 고견뢰도가 요구되는 고급소재의 염색가공에 적합한 오렌지색 분산염료 조성물에 관한 것이다. [화학식 1] [화학식 2] 상기 X, Y 및 R 1 내지 R 5 는 발명의 상세한 설명에 정의한 바와 같다. The present invention relates to an orange dispersion dye composition having a high wetting fastness and more particularly to an orange dispersion dye composition of the following formula 1 and an orange dispersion dye of the following formula 2 at a predetermined ratio, Which is suitable for dyeing high quality materials requiring high fastness such as polyester and nylon woven fabrics and polyester and spandex blend fibers, which exhibit high dyeing rate and high wet fastness in processing. [Chemical Formula 1] (2) X, Y and R 1 to R 5 are as defined in the description of the invention.

Application of the n-BuLi in catalysis aldehyde and borine hydroboration

本发明公开了正丁基锂在催化醛与硼烷硼氢化反应中的应用，硼氢化反应的方法包括以下步骤：无水无氧环境下，惰性气体氛围下，在经过脱水脱氧处理的反应瓶中加入硼烷，然后加入催化剂正丁基锂，混合均匀，再加入醛，进行硼氢化反应。反应完成后暴露于空气中终止反应，得到产物。本发明公开的催化剂对于不同取代位置、不同电子效应的芳香醛以及对杂环醛，脂肪醛有着较好的普适性，为得到不同取代基结构的硼酸酯化合物提供更多的选择。