08-08-2013 дата публикации
Номер: US20130199820A1
The invention relates to a crosslinkable polymer composition comprising (a) a polyolefin bearing hydrolysable silane groups and a silanol condensation catalyst compound, as well as to an article, preferably a cable, thereof. Also the use of the silanol condensation catalyst compound for crosslinking an article, preferably a layer of a cable is provided. 2. A power cable according to claim 1 , wherein in compounds (I) and (II) Me is Ti claim 1 , Zr or Hf.3. A power cable according to claim 1 , wherein in compounds of formula (I): n is 1 to 3; m is 1 to 3 and claim 1 , o is 0 or 1; and wherein in compounds of formula (II): n is 1 to 3; m is 1 to 3 and claim 1 , o is 0 or 1.4. A power cable according to claim 1 , wherein in compounds (I) and (II) the heteroatom is selected from O claim 1 , S claim 1 , P claim 1 , N claim 1 , Si claim 1 , B or halogen.5. A power cable according to claim 1 , wherein in compounds (I) and (II) each Ris independently —X—R claim 1 , wherein w is 0 or 1; X is a heteroatom selected from O claim 1 , S claim 1 , P claim 1 , N claim 1 , Si claim 1 , B or halogen; and Ris selecteda linear or branched (C1-C50)alkyl group, a linear or branched (C1-C30)alkyl group, a linear or branched (C1-C20)alkyl group; or{'sub': p', 'p', 'e', 'f, 'a linear or branched (C1-C20)alkyl(O—(C1-C20)alkyl)or (C1-C20)alkyl(O—(C1-C20)alkenyl)or (C1-C20)alkyl-O(C1-C20)alkyl)(C1-C20)alkenyl), wherein each p is independently 1, 2 or 3, e is 0, 1 or 2 and f is 0, 1 or 2; or a linear or branched (C1-C12)alkyl(O—(C1-C12)alkyl)p or (C1-C12)alkyl(O—(C1-C12)alkenyl)p, wherein each p is independently 1 or 2.'}6. A power cable according to claim 1 , wherein in compounds (I) and (II) at least 1 of Ris independently —Y—R; Y is —OC(═O)— claim 1 , —C(═O)—O—C(═O)— claim 1 , —NRC(═O)— claim 1 , —OC(═O)NR— claim 1 , —OC(═O)O— claim 1 , —NRC(═O)OR— claim 1 , —C(═O)NC(═O)— claim 1 , —OS(═O)— claim 1 , —OP(═O)— claim 1 , —NRS(═O) claim 1 , —OS(═O)NR claim 1 , —SC(═O)— claim 1 , —OPR(═O)O claim ...
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