10-10-2013 дата публикации
Номер: US20130264512A1
A method of preparing a boron-doped transition metal pnictide magnetocaloric material, the method including: contacting a transition metal halide; a pnictogen element, a pnictogen oxide, or a combination thereof; a boron-containing oxide; and a reducing metal to provide a mixture; and heat treating the mixture to prepare the boron-doped transition metal pnictide magnetocaloric material. 1. A method of preparing a boron-doped transition metal pnictide magnetocaloric material , the method comprising: a transition metal halide;', 'a pnictogen element, a pnictogen oxide, or a combination thereof;', 'a boron-containing oxide; and', 'a reducing metal to provide a mixture; and, 'contacting'}heat-treating the mixture to prepare the boron-doped transition metal pnictide magnetocaloric material.2. The method of claim 1 , wherein the transition metal halide comprises a halide of Mn claim 1 , Fe claim 1 , Co claim 1 , Ni claim 1 , Cr claim 1 , V claim 1 , Cu claim 1 , Nb claim 1 , Y claim 1 , La claim 1 , Ce claim 1 , Pr claim 1 , Nd claim 1 , Pm claim 1 , Sm claim 1 , Eu claim 1 , Gd claim 1 , Tb claim 1 , Dy claim 1 , Ho claim 1 , Er claim 1 , Tm or Yb claim 1 , or a combination thereof.3. The method of claim 1 , wherein the transition metal halide comprises a transition metal fluoride claim 1 , a transition metal chloride claim 1 , a transition metal bromide claim 1 , a transition metal iodide claim 1 , or a combination thereof.4. The method of claim 3 , wherein the transition metal halide comprises MnF claim 3 , MnF claim 3 , MnCl claim 3 , MnCl claim 3 , MnBr claim 3 , MnI claim 3 , FeF claim 3 , FeF claim 3 , FeCl claim 3 , FeCl claim 3 , FeBr claim 3 , FeBr claim 3 , FeI claim 3 , FeI claim 3 , CoF claim 3 , CoF claim 3 , CoF claim 3 , CoCl claim 3 , CoCl claim 3 , CoBr claim 3 , CoI claim 3 , NiF claim 3 , NiCl claim 3 , NiI claim 3 , CrF claim 3 , CrF claim 3 , CrF claim 3 , CrF claim 3 , CrF claim 3 , CrCl claim 3 , CrCl claim 3 , CrCl claim 3 , CrBr claim 3 , CrBr ...
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