24-02-2022 дата публикации
Номер: US20220056275A1
Принадлежит:
A coupling agent formulation for cellulosic material-polymer composites is provided. The formulation includes a) at least one organic peroxide; and b) at least one of i) at least one zinc-containing reagent; and/or ii) at least one silicon-containing reagent. The coupling agent formulations produce polymer matrix cellulosic material composites with improved strength and aging characteristics. The improved strength may be related to physical properties such as improved stiffness, toughness or tensile strength. A masterbatch utilizing the coupling agent formulation is provided, as well as a method making the masterbatch. 1. A coupling agent formulation for cellulosic material-polymer composites comprising:a) at least one organic peroxide; and {'br': None, 'sup': 1', '2', '3', '4, 'SiRRRR\u2003\u2003(I);'}, 'b) at least one of i) at least one zinc-containing reagent; and/or ii) at least one silicon-containing reagent having structure (I){'sup': 1', '2', '3', '4', '1', '2', '3', '4, 'wherein at least one of R, R, R, or Rcomprises at least one unsaturation and the remaining R, R, R, or Rare hydrogen or alkyl or alkoxy groups and may be the same or different.'}2. The coupling agent formulation of claim 1 , further comprising: {'br': None, 'sup': 5', '6', '7', '8, 'SiRRRR\u2003\u2003(II);'}, 'c) at least one silicon-containing reagent having structure (II){'sup': 5', '6', '7', '8', '1', '2', '3', '4, 'wherein R, R, R, or Rdo not comprise an unsaturation and are hydrogen or alkyl or alkoxy groups and may be the same or different from each other and may be the same or different from the R, R, R, or Rgroups that do not contain an unsaturation.'}3. The coupling agent formulation of claim 1 , comprising the at least one silicon-containing reagent of formula (I) and further comprising at least one of boric acid claim 1 , sodium tetraborate decahydrate claim 1 , sodium tetraborate pentahydrate claim 1 , sodium tetraborate anhydrous claim 1 , disodium octaborate tetrahydrate claim ...
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