DRY-MODIFIED ACID-ACTIVATED BLEACHING EARTH, PROCESS FOR PRODUCTION THEREOF AND USE THEREOF

31-08-2016 дата публикации
Номер:
AP2016009401A0
Принадлежит: Clariant Int Ltd
Контакты:
Номер заявки: 94-00-201601
Дата заявки: 23-02-2015

[1]

Oua^l

[2]

c-jjjij JfLlj Jj*-a3j C_j\jp Aj^Ia, U-ljjJ 4jU»J (jjlsUJ ^laJl jl djlaiil *=LoIa^HujIjj 4AjL&*AI AJauij^J AjIc.

[3]

jl S)l£*JI 4JI3V -JJ‘4-Jjpt ^ΐΛϋαΐΐ ^»jj u^»\l ^lajVl ^_j3 Q^li! < 4 ^ < i\l ^jx jjj£ (J^ ''' Lgjjjj-eVI 1 «jli.T*ilt Jj. ..^j jjl jj£-aJ .8ΛΐΜ^νΐ (JlllfijLuia 4jl}j Ljajl

[4]

. JJ^aSlil 4jjjI lllljS J 'w'i. ..Κ t ajkVill jjja-y-i ^jj dljjjll j|)Sluulj (j-o SjI& LuLJ (_g^t 4-jllc- 4jkj.lj 5JUilt JJ. -.a*~<\l 4_jjj| 4j3 JjVI 4,℮^λ·νλ11 (jj^J ^ic. 4℮^,λ·ν. /\i J, 1* .(ς-ℓ^ℓℓ ^Jlc. ^A^asSll L_ljjJ= ΗΡΒΕ^ CLnj^Lj^edj^A o^SXaA AjAaC- t2tA l-»^^^l"mi^A djVj^^e

[5]

• Alllc- oj|^ Sl£* S^SjaII £a (jJal! -ijjA 3Aljj OsjujI^J ^oa. AjAIc. £aw^ Ai^Jaxjj A^Laa λ-λ c_j!jj jtHj-o Αο1αλΑ1 oLa ^jjj djjj)ll -1ο^λΛα11 ^_kjik!ull ^J] ¢.1^ν^ ^Jlfr j-^-^a^\ L-jjjiAl IAa <ja lllljA^H ^l-laJludl

[6]

t-ljjj jjV S CJj&^a jaj^aaall AjIaC- ojjau^all ^lWn»V' CIjLiaS Cl£j .^»LaJI ^alijll t . vnj 4Α^111α11 AjaSAI £ya JISj ^£-^11 t du^ll /j-xs l1Aia£.1I Vj! ^jSj Jas^haAI

[7]

, ^al Jl^Jj-iL>U aLiI^A! ^tjl^AA LlSj Lljlij 3^»**^ ».cAl ^JAx*a£A\ ^JA j^a-aaJlj 4i]3j ^jl Aqj^ AjIIc- jJj--aaall AjjjVI β^Α <t n& A^JIjla ^j£-aJj jtIjjJM ^Uu) ^ic- A_LJa-<i^Jl ^l1a]Ij ^-Sj-dLi« qa SjOiS CjLixiS ^alshUll AdllxJl lT ilaldll Q^j .A-g^!)L*21 jJC-j Aal^oll cljlAcjtil 1η¾^ Ig i«fl jl AjjpVI LlllalSjU t_llj**iVl S^aat-all 4-AaC.j djlalik-aJl

[8]

.*hVl aJIo AjjjV ^ .^jeuJa 35m »1 a! util I Axilla]! jlj-cJl Aj3 Auill A-aJajVl -laj|JM (J^-eJ .ClljJ^JIj Q^A^llL ^IjC-SM cIjIIaI Ul*5 Ja JSoij

[9]

tl^lA ^-β . JSJlj AaK-o JJC- g_j^j Ljajl Ig jW Allatill

[10]

g!jjJ^]Il eilViil AjmiUx ^)JC- ^ La SjLC- L2j Jai3 (_pai^la ^jjmrnj] wia

[11]

C-jaJ A-iJlC. AjjjI AjjILoJIj tiilli ^^Ac. Sj!>lc- . Aiitsi (jjfi-i AaJOJ .l^JS t_J^t^All A yf\ oj^a-^^ fijLall ^t.^Vu J Axpl (j£-eJ V ^U^. tQy&jll jl QA ^Jc-SM jSUm'nII (J^jS <J>J tliJaji tiillil . ^)j> L_l|p jt dljJjll ό-0 <>^J<a5 t ^1ΐ51

[12]

c-jjp = SMBE) AllxiJl <-aJajVI l$jlc. (3^? 4 jAu-aSill Ajpl qa AjlHiJl AjAII (Jl&J ■laUiulIj djlal£j (jjj 3^* aJ^xx AjjjI (J.ixx ^a^W

[13]

^jx 3)utfj^a UjLixS £x ΛλχλΑλSjpu-yi (JlxAll jjJaJl A-u4x!Ax ^jj tU& . J^jLcJI ^1℮. JaLIj ^1λ. Axilla .lljx L a\,^<l LL* \i_^A\ l^J ."^jJajxll ^-3 j-ijn Vnti” 33^* (jxj A_illc- ft.vw^ Ao^Jsxuj A^Llux ℮,1λ /j-λ. WV\ ,Αλ^1α. aIjIs duxjjAj CLh^IjjIjI C5^j 0.2 (_5^ ^a»j ^Α. /^Jjx JJ-6 180 100 JljaJ A jar Ji}-i\j AjnJnti ^l^xll jl ^ax^ll AiSJixll ζ·^λχ^Π V <■* t-ulaJi j^glc- .^λ. /Jx 0*35 (JaVI ^ ζώ-ώ11 ^^Ic- C5^ 4(^jialxaiU aI&UlIxJI jjc.

[14]

jjx S^U^I ^\c. ^ua-CL^JU Ajajxii&ll JJ^S'W A-jjjl (3^J V Aajjj .^»LxxJl 5Jl)J AJaA*i|^J 1^'jjl ^ajj ^xll ^ΗΡΒΕ^ p-IjSM Axllc- jj^^l Axjpl A A_aJjU3l iilSj J^o A.sKxll ^jjc- ζ·ΐΑϋ^1 AJaJ^uJI AjIxc- ^j£xj ^℮ . ^^x'sUj

[15]

.Aji.^ix's^l L-flj> «-i\l oLjx ^-Ic. ^jj V u,n,«\ ^ΐ11 SjLq WO 96/33621 ^sj l_AL^I i^_LxSj A_Alu,i£jJj£ ^jialx^l(xx Aj&udi^J Jjjjilj % S V ¢. lx ^jJ^x JjxuJaJJ

[16]

• A-JjJa^^C' ΰ^^ΛΑΑ s^lx ^ja ^-u^auJI ajjjI ^j& WO 99/02256 k_AUi ^ *q^^j ^χ AJaiouj dllj °/° 10 % 8 ¢ℓ^ ^ ^5' 4 aja'N*^ ^jl 3^3¾ 13 ¢.ℓχ * (jlj Aiji^j (_£jjJax5l jl ^JC-t_jxaAaJl ^Sjxll (Jjl^xSl

[17]

•ujj^-t0//° J >4.-1.,,^I ^Jj2 jl UjΛTill A*_1 (liji ’ijjSAxll Jjj-aaoll y Ijjl jjj j^yi ^jlill (JxlxllLJlojj jl % 10 4-}]aAj t % 12 (J) % 8 sjlc^ L$J^* <3^J ' £ eje^" (Ai

[18]

-(JSt JJ, -.a~*'M tAllall s5a ^ (Qybjllj elljJ_)ll Ajalj JJ. -.S% Ajjpl ^>uj*Jl (Jla-all ijj$J i^jjil'u (jln’lj Loj3 4_u*_all L-llUull ^Λλ jjS-all ClJI jl ^ijj tjj^iijll ^xj .^-liallj

[19]

llSjj i^Uall JjAii djjJl ,·) Aj VI U3J iJAall (Jjful (Jc. .AjaVL^all jaCj t4g<‘<\l UJjjl! j«ajJaJJ jl t _ u2l]j J] AiLiJaVI-J . J > I ji^al jj j ^. W<j jl jSxJ (dujll . Ai-uls ^jl2-c j *. > >> μ1

[20]

l^jiiaiajj <aJl*-aSI .1*1 £ya jlill ajljj j»aa ‘j4aVl aiA ajjltx QjSa ^^all

[21]

i"il •'J I'jii ..a 4 Cjlaixj-all aJIjl ^aJUJ l^JIllla . (Jtlxll (_Jjju-u ^JiS- 41_iIAa1! ^jj-s l aljjY

[22]

^Iglllsij -X ^jjaxa. Λδλ (Jljxilj <■ OQ-V aU cIjjjH Jaie. ^JJ 4 (__)iaj*ll l.lgJ aLaJj 4 JlSI aIj^jiJ £il.lx]| aljjj Sj-lSll .aJLib 20 (^J 15 ^1ΐχχ Jaij^aj ^a 95 V 1 . /j ]^llj % 0.2 a_Luoj ^Jllxll · - ^Α℮ 4^)^ΐ a-lx ajLjaj <ali 4 Lllllxxj^ail alljj *■ QJ^Vl

[23]

.* ΐ . (jjjSjxll .Ijlall aJai-uljl 4(J\lxll -* i UJ U * *]3 ^1)] 4^e,jx **Q C-Jllaal! j i. ^.a"' a \-vj^J a iUj j '■ ^a*i a Wj* 4^jiii^jx ^1℮ ^ ^ -*»^' aix (Jjjxll 4ϋujll ^1ΐ1ΐ _Jl*^aSlll Qjjj % 0·5 % 0.1 £-« £xj^all ajx (Jjjxll tlujll ^jxu. '1»^' .^ajiiilla (_j|jj (jjjJ ℅ 2 <j!J % 0·3 AiL-Ia] ^aaj 4% 95 llljjil (jj’Nta'l ^aa <jl .l*aj ¢·1λ11 1-jl. „“' ^aa ς ^1ΐ1ℓΐ . aajai 20 (_£jla*x 1»» ■ ^· -lie- laalall liLjai till j -I*! ^aai . _jj ■ .1*1 .aliAl 30 a-lxl % 95 -lac- i-lajil 4. nil"! jaiij (jla 100 JS-M (-W"1ls^")

[24]

(jx JalleJI aU,.,lj' (JliLall (Jilui LS^ 4jJx»3iMxll 4_l]jp 4¾] j>aa 4

[25]

* ^ ^.όΐΤ.Μ

[26]

^j-ajJaJJ U5ji (jajjiaJl JJ>e3 jaJJ i{_yajx2\ I^J . ,j^s aj^jj ^aJU l. JJa-aSall ^»J Λ;ΰΛ^11 ij^aLia.Vl AAjjV dujJI J5Li. q* ^ 240 200 Jl^Lall Jjf'-1 2ΧΡ· ^1)^· .lie- ^iaia^ix 1^.* ■ ^1-νΛ a^jl^l ^1)] ^aa clalj di\g5^|_g Sjel! Ljaal (j^inj i _jLi 3 (_jlj 1 (J>^j 4 jla ^ 5 (j* (Jsl Ailalx l-»» >>»

[27]

-JsS (jllxll (Jlaxll (Jaajx W2 ΐ _ i\lax\l tiiaa^l ^^aL ^jl <-ia-1 4 jjjSail Jxj tjjJ L)^J J^-“ daa^ll (ja.^alj (j! t _ ΐ·^j V 4(J\ax]l (Jaaj-“ ^5^" ·^℮5¾ >^ill LOVibOnd ^ya.a.Vi 03^^ a^uS ^jiajiJI 11^2 jjjIxx Λ^1 (jj£a ^3j _J>^»^I Jj _)i-<al (_jxaJajj |jl - _ i'n.j tAjaliLi^all jiit ojlajl lie. (j_jSa (jl ^jtaua (jiltj 4^CV

[28]

jj Caajll (jj^j (j^ 4tflij 0j5le .ajlill (_paiajx ^jj^ i ifl jl Ij-la. (_gjie^a t^aajll

[29]

. Axuli iuj SAuili <tax]j jjiaj Λ-1χ1 tiiUxS-liiJ UjJ a_j_uLita. jajSall iuilj ^aa (jl ^a/ia 4^^℮,1 Aae-la (jx 4jajSall tijajll 5allx]l SljeJI ailxiaVla £_c . ajjLaii]! Lilujll a -ν. \'» χ slAa-o ο1λ℮1 sje.jxll Aalxail ‘ **1^ . a_ii£_c ^jjc-j sJUiiij aiajja Ja| ailSjjj a^ijix ja^' siaiaj (j£xa1 ^j~. ; uJlujll jajS (jj»«~45l a^,la. lilliA Jljj V ‘lii

[30]

.tlujll 0a_je. ^ jjLxill (JjaS ^1 «-ja41l QjJ Sjlx ΕΡ 2099561 Β1 J ΕΡ 1893329 Β1 ,> aijjxxll <aU41 uj^ (Jlalj SMBES ^^aaV β^Α ^aa 4^jVl (^a^- .Aalle- tlalj j j > aaslll ^JjaS? 0Ja^ ax^la .qjijILi % 10 «.Le (jijja-o1j liLjULJI ℅ 3 (JftlsSU 3_j]\e Sjja. 0)jlU % 60 ^ija. ¢·^/ΐ·^ yaiXij ^l^JI SMBEs s2a ^4jj *■. ufcCy^a (jjjllj % 10 ,_yi] ℮·1λ11 J_5j0a-a (_p»ak lillj -1*J .℮ℓχΰ £SU^a1I lift £A <]iLt ^aJJj . LmJ *J ^■' * JJCj ‘ (j_jSLl ·℮^4ΐ £^1$ ij-'*^ ‘ “3^ 4ja*4_yJ ζ·ℓ2Λ/1 (^3

[31]

.(■Jjjxll e3& (j-ojJaJJ V JJ*^-fl-^A i__ljjj 4. 40jLo aSLa 4j1aC. Jjjijj (j& ajUc. (jl^ 4<j]lc. 4jt_uu ^jAjJaJJ ^cliia ^Jj (_JjLoill (JLa^all <-JjJC i _ tW 1J i ^JUsiij

[32]

• cjyk.illj l2jjJ^ll jjjtjj t3^*-y

[33]

~~ . 1 3_iLa^ll ^jl ^*\n. C1iIaj-u ^j-ajJaiju AjlaC- ^ t 13λ (JjjjAJ ^JJ

[34]

. AjljIjII AjIasJI j, *-V. \r. ν-^. AaLaxli ili\i l a ’ Q ^ ^jj l**m-v 4cjl^ ^J£L2j ^u^aj i-jJjj A_aLac. Vjl

[35]

¢1λ (jji*-ο ,_jAJaJJ {_^ill ^laJ) (jjlail -iali. ^aJ£j t(_jJaikio ¢.1λ ^ Vjl ¢.1λ11-1 (_£jj^a*ll (_)JoAaJi ^1λ31 i‘j) q (_jjiLuil <_5^c') (jj_9^4 % 5- % 1 3_ia2aj (_J-eii-Us ζΰ411 jjj^aSall i_j|p jjl I <j1a& <Lej*u . jS^oil j_JjjJa*JI JJ& jl jJ t-iL-oll ύ-0 ΰυ^ ζ·1ϋ1 uk ·ΰύα^ °/° 40 (_Pj % 20 «-^> ^.ciXu j j i-A^all 11 x_o ^Lait Jj^Ia δλ-1 (_ajit^jll Sjl-I^kj xjj^-ljl Jlillj

[36]

1λλ Lo_j<oC. (JSI a <!LaC.j · «1^ ■» JJC- (J» c?^l? (_g^jJaxll JJC. jl 3 Λ/'t-, 2 U, „1J< lg_ilft (JJ. ^>-v\l j^«i _J^ ly*' tdli j»Cj .AjJjlalll dlULaxll .3_lJJ^aj]l <fLaVl £tj-iajA jA, La£ CCjjJ^t jl _JJ>ji<3ll QykJ Sjl_L4<a ^cjlli

[37]

(JS4iJ (^≤αα11 (jx 4aai Ja^jpx ΐ. gjq%j £-ljikVt AjLaC. Jaitul ^η·¾ .<5Uall lililgiuil jl JJjS -^S*J (Ji ^>JlL.3 V t_juaiJI > ijsVllI (J_>ia LS^-6 £ya ¢.1α11 *S^‘^uAjoiIIj ^jl c fll Λΐ61 'i^J.W 1

[38]

¢.1λ11 isy'' * ^>jj ·ο)^4 ℅ 40 (_^j ℅ 20 (_£■!] IjL-al % 70 ^] % 50 ,j,c jJS) ■ >»aj 14 (^J 1 3jjaxj qj£j (_^3SI t^j.nai«H t aJ<e A j-iΐnljj cjjiaall 13α Aljj (j|j__>3u 0^4j ℮·1α11 W4j) 4 2 (JSjolJj ^faul 1 ijlg-ill Ja! ¢.1λ (Jaj ^>jj ‘‘’ij-x < ^ tllljji-ell AJlxiSI 2 Uaill j^ya ^-ΐ.Κ4,ΐ11

[39]

(jjlall ‘ '1- -41 jjjS-all ^jaLoil (Ji4l ^ΐΐ4ΐ^3 (j3aia. ^>JJ ^aJ (jxj Oj^ll (_>4lS ^-ο -(jjjilj % 70 ,^j % 50 ¢-1-β (_gj3*a λ «.Lallj ^ℓ^2ΐ (j4a^ (jl tj>3-»^j Olj/s. WV\ ^3ΐ1 I 3j\^r- |al ^ 1i >1 Lkiajl .QjijlU % 40 (jft ¢·1λ11 diUj)3->xl (JIjaSI (^1℮. ¢·1-βLj£Jls js■ jyj C-iL-all ^£^*Ja*ll hnVnti^ i-fljiLallt Jxj % 20 ^Α) *1*5) clllj^jaA <jjSj i)l& £A •Cxx^ % 40 °/° 30 *1* ijLal

[40]

-jjl^ jI^aJ ajjA (J^ **M (jSLaJ USj α1α1λ-α ui^W ^jJaAaJI £a ^ℓ^31 (jjJall ^jaJa Axj ajjAa'"* <, ΐ.laj laij (JJ$VilI A,Lta]l ^-1α ^-5) ^1^5) ^jJal) ·^)^α L l-a^JC. ^£^α51 L$J)k ^T 5) JJC- t-lL^II (_£^jJa*Jl

[41]

.^jJU % 40 % 30 cUi-Il *U)

[42]

^2ΐ) AC-ja^aII Qa SjHaAJI A_2^ail £a A-p^ a ojj > AjIaC- <Ja*J Aj^JaxJ) ^)JC. jl Ij L^L^Ja^Ja ^jJaAa Cc^IuIIa tciLpjuj

[43]

.lajj J j\jj ^S^aII ciSj^laUI jLe S^>aJI <_paAa <jl C-flUujSI .^j>m jl' ^g > >»*} £A ^^CJA Ja2)La ^ jl Ia^jLoj (j^a 1αλ,^1 . tlliBl clljj A-«-ala *(^Uj5) uliJ^il _jjA-aSj A_u«ala <Jl*B ^alie JS-JuJ

[44]

~% 1 ^-1α AjJaAj ^£^)α51 ^£^Ja*A) ^JJC- j\jj L-iL^ll (j[_^jJaxll ^jaAall Al» »*1 cliJ^ % 3-% 1 Aj^tij ^ji c_flLujjSI ^laJI ijjj (^1ά) C5^) OJL^W % 5

[45]

Ja ^J^la £\|jP^^) Α-2αλ5 C-UtiLiA (j' ^Α51 *Ia5\j ^jxll ^jJall

[46]

Aij-aj Ia£ ^laJI ^1^α1 Aj-ala A_ii*JaSl «,Ua£>l ^δδ .I^jIluu]! ~c1±uSaja ^UJ! oJall *\jJ jSill Ua & .ΕΡ 1893329 Β1 and ΕΡ 2099561 Β1 Λ ν^^,^- Λ Q VjkJajj^ 1 L^_j>^al^a^ l^A.^&jljk^aa AjAaJj ^*^liSjj ^| £ju\jb^_5 Α3^α^3^α11

[47]

• AjjIj^j^Ij AjjUajSJI i^U-adalj DMBE) t-ela J^xa ^)Ju-a5j t-jjjj A-^^la _jju*sOl) c_j^jj LiJ^l ^SjJ

[48]

• \^3j ^JU^afi2i AjjjI j j ^ . fL \ ^^Jjjk^aiiilj ΑΒ^^^3^α11 ^2αχ11 A^axAil^j (_J_^j.^aall *^δλ Iajjj .(jjlLe JSJu ^Ic. ¢.1α ^jja-A jj*^Siill t-j]j3 (JajJoIj 4(3jL2I (JIa-a13 C5^ Lli^W ℅ 10 ¢-1α11 ^j'"- A-a^.iLo ^AC.J AJlISa AiJ^la ^ju Ajjjl L_ajiaj O^l^j c*J) 4W 20 dlUjjjA a ^ipaiU ^jj>i^iqnM Ajjpl JjA^JaJJ (JI^aSI diljjja-A ^jA-Jalj ^\ ^u^aaa5l Ajjjl ^jaJa jjSaj t^aliA JSjaJ % 40 <^5^ Αλ1^α1 ^Ac. CjlfilallA ^ AjjaA^ll ^Λα^39ο11 l_j^)j > »1^ ^1ia-aV αΚΛκα jj-1 A_2^ ¢-1α 25 (J^oa (^gAc- c_ila (JaAA cljlalaaA % 40 ^J % 20 t jAaj^jSja 63 (JV^A L_ljlaJI IAa ^aJJ .^jaJaSI (Ja[jC- (jL-aoSI % 65 40tJA-°J_)S;iA

[49]

- u!ijj£a^jj ^43 ^Ac- ώΑ)ℓ℮-1 A^j-i-ajA^I ^alaJI j|^a] iJuAaJ ^jLajV^ ^ \£jLJ| (Ja j ^Αα11 Α-ΐΐϋ1 1 (i_al_a. (JS2ij (Ja*a <L>~alA.) _jii-aSull L_lljJ ^ΐΛϋυΐΐ Ljajl jjjJ Jjj-oaj uie jjj£j]| (JaUIu jl (J.>»aj . tlljjjll jl jj j_j&All idljjjll jl/j

[50]

. π KajlH A U. „ljj A . jA. l jj. jilli i_jjjj Ajjjj l$Jj 4A_}MI ^Jljl bjliiklj tluj Ajjjj I3& j * · '-"v . LJjjjll jl/j jjA-^l Ajajj AjLjla IjJojI Ajljjll ^1;μΛ^Π j3jJ 1^**1*^ V-» - ^ p. la.^^1 ^JJ . A_jjljj-. 11 A_ljVl2i δα1α11 / ia ^Ljtj i_Jjj jA jA^aLall Cujil (Jj-oS iAIIa Aju ^Jjj (<-si?. (J^Aj (Jaxa A_k*alk) jJaoSu i-ijjpJ .^jAujoll a U, ..Ijj J'lLJI Jiiuu ^ic.

[51]

4^AjAjl ' al^. ,Τ.' ^Αλλ11 4_jJp AjIaxI Aa*ju1-1a]1 A_ia\j]I 3α1α11 jj£j Jju j3]| ϋϋ-β11; ** ~J~'^ - . ■' Ju^s 4-t-al^ alaIIj ^ixJl ^IaJ! j-Oall (J52u ^3 jl JIa 150 jo j£l (J. jj 1^Λ. /^Α^Α jua 120 jA jjSV Ajlill <lll& sAAi-c Aj-».J-ajj A-^Laa j,j^ λΑΑλ-α Aj^Ja-ui A^.1 ma a t-fr-A. alt t^Jj ■ »H (J^. .‘*Μ ■ a ja > >> η jl j^Aj . y^-jA jjla j_jjj iiillA (jlj AiLAaVlj ·^ /^jo JAa 280 ‘^?. /^jo jjo 300 .^a, /cl* 0.35 jA jJ^I Αϋℓχϋ ^1α^1 ^-aLuia 1ΐ1ν·4α11 15jljnill (Ja. "t'lfi^.n (3¾. jjla (_ja 4jaI& jj& aj)_jj^aJ Ajllc. AajaJ Ajalla-oil j^>uV (J^ -(AjjaSaab ^yajJaAJ % 60 (JsqM (jift iSi02 sjj-a ^ t_JjjA2kA (jjSj\jAi ijJazla Ja.AjIj ^aJ (jAj ISjLaJI (^α Aa.lj ^A_jAjl llij .(jjjilj ℅ 70 (jA Jj£l (J■ f-iAj <i-ali 1% 63 (jA ϋ^3¾ tf‘j )^U % 85 a>a (Jsl I5j\j..i\l (_J^ - AjjjSaau j_pal jj5j\ji.A' tSj'1''A tp-jA^n

[52]

1 <jU. .Α1 Ja, - i" 'jX -... j_jU j_p5jlji ΐΛ1 a jj^j4 ^A_jaj . j ) ^Ij ¢.1α11: Ajill ^liJI 4_mlall aI^aII eA& jj^J .('/)$1U % 75 jA (JSl Si02 yjA<a ^^3 i_1j.uva]I Sohling et alM Clay Minerals (2009) 44, jA \Ssj ajJiAa j^S

[53]

.525-537 and Emmerich et al., Clay Minerals (2010) 45, 477-488 aIjaII IajA^j i al^ (_|5.Tj mJajlaII jJj-<aajJI 4jjjI ^tliV ^j1a*J (_JauIIa]I jj^J ^jAal^ .ΕΡ 1893329 Β1 and ΕΡ 2099561 Β1 J ^ ^ ^

[54]

Κ >i 1 ^ L ^.1^·^ - \ Λ . ^ΐΜ l ^ j ' .Qj jjjUb ^3 ^ℓ^11 A j~,j aIjaII lA^b

[55]

Ajj^JajS\I AjAaal (JjifiUlU j,. ^»",11 <_jlA - a.ΐ,11 \ i qq^ a\I jjl-.ll ill j5αα11 jA (’] AJ 4 j^lio (J5iTij hjj^aA ujjjAIj jjAAll ^C. jAli jj^J jl 4 jja.1 4 «A>3 SjJai. V c5^' JU -11 α21α21 aJI^I liij 1αλ £^ja A- ^ •% 40 -20 ¢·1α jj3^> a aIc. 5Jl*a

[56]

aHaSM .A^LaVIai_jij Iaj3 (Jj■ -.α111 < p-^uiajA ^>aa :Αΐℓχ1ΐ jliii.'ilj (jjjlaj "A1L1I (JJ^all J^3 *■ ajhjjj

[57]

Ipjjjll JjAj AaL £ .AOCS Cc 13ν-45 J Uaj (Lovibond <jjl <A) Ajjjl! <A άΑ <A £

[58]

.AOCS Cc 13d-55 J lia, ^5ll : (AjjULall t Jla-all <lla) lilljlaLJI (jaaxaj ^aAJI ^jalall Lj uill A$] .H2SO4 (j-a (jjjlL % 3 J 4 l-iji* η lilli aAll £a (jjlall Jala. ^aJj (jAj (JSjLj Η2Ο j_ya % 10 *• a^all (Jj)^*** jjx jaA. 100 -LA. A JajlaJI ‘ °J°A (Ai ·^Αΐ½ (% 96) H2SO4 ^jx 2.83 J ¢·Α11 (j* ^Λ. 208 £X

[59]

l_sljj 4J3.1 4-ia2a lilii % 10 _jA a All jjjl'a a ^ 1 10 .Lc- jLLlI ‘ijjtA % 40 (jl) % 20 IjJxjjfAa 63 (_A-ix ^jic. JVlxll dlLIaLa) ^ Axjli

[60]

·(ΰΐΑΐ % 65 (jlj % 40 : JpxjjA® 25 (_Aia ^jlc. <-aLa41 (JVlall illlalaLx I JA^aII ■ ’-»\l JJC. jl 1 Λ, a\I riirH £-a jaAJ! (jjiall (jJjlS-uV I lijiui ill % 35 a A ^Jjaa-e <UlaVl ^ Llli JJC. A ^1 A jaAJI (jAall t ajA"1 V$' A ^aJaxll jl i_lAall (JJjjJasLI ^j>»a-\l ^ja jjlL % 3 £-e (jLj L&A ^JaA. ^aJ ‘(jijA (Jajxil iJjlAiaLa) AjAaill ji^afijll (_llj£ 4iL lajlaJI ^jaJa A I^LIL .4 l-ijiuU ^aJ

[61]

^ic- (J-*- ‘'^11 i~iU\y\a % 40 A] % 20 4 jaajjfLx 63 AiAJI .(tjjjllj % 65 % 40 ‘jAjjAia 25 (_Aia

[62]

^gjUill Cjj^II JJ >

[63]

- ~ ., lifij (Jja ^λα^11 Aja ^Jl^all djjjll (jljA 1^» ■ t" 1^5 ja 120 ~ 100 -^ε· JJ| <1^11 t^jjp QA tjjjfi-} °/° 1·60- % 0·30 £-a ja-ela ^ajS Ais _jj- (A 30 -20 oAal jU ^Α 100_30 jjc. ·ηwi ^jj ^ΐ La) 5¼ cuvette Lovibond \k^a 5jjAaj (CV _>*A)

[64]

30) jAAL ^jaJlsLa a U. Ali ^ilaaaVL {JA a_A A® A1

[65]

5j£jla ^JjAaJ La A^jI ζώΑ1 d.U^ll <J^Aj .(jL ^La 1 < i^a 270 -220 ^jc- 1Α11 t_A 4^j1)1I “dl)j1 *<teAl dilj a^j1)1I ^IjjJ LlA1 .(Lovibond

[66]

. JJaaaSjll PtJ ΑΑ alijjjll allilll _jAl duj ■ ^*»"'1 ^juauilL C-ASa^al) ^aAJl ^jaAll (j-a η ^iall JJa^ajll C_lljj ’. 1 <JLa jl % 26-2 jl ℅ 21 ·5 a A fJjt'LA (jna.alL A A jaAJI lAA-1 A t5JA JS tilyiAl (_paxaJ ujjlL ℅ 3 ^χ (ΕΡ 1893392 Β1 J Uaj) % 27.6 . jji *-1Ac- 3 (A®’ JjJ^Al tAiaJaj alall (jjii °^° 10 (A) ΑΑ £Λ AjjlLall i_j|jp qa Cjljjc. 3 £-0 Ciaill jij tluj jj.-^i'aj ¢Λ Tonsil® Supreme 112 FF, Clariant Produkte ) sjjaJ Jk. SMBE

[67]

Jja cjaill Cijj jj^Sj ^ 4,jiyiil li$] .((Deutschland) GmbH 30 S-lal ^ 110 Aic- jlj(_?1a 30 lr» »'<-! CiaJ <_ijjj (jT?J % 0.60 £λ (_paAaJI <Ga

[68]

ulsj^l] (GV) ^»J3 -Ij-laJj 4--S^JP .Αΐώ^ <ii]j AiLjaVU 10a ^frja. aJI)I ^ .51/4” cuvette ^ Lovibond liA ζύℓ2ΐ CLu^ll Uiajl . (jlj 1 ^ 230 tAjsjSJ 30) jliJU A lit Jyj

[69]

.5¼ CUVette AjjIjlaj . ^jj ■ .0^1 dlLllaC- jjtij 1 jjjLi.
Ai]j)A *m
(qjA* <J£5 *>*)GV ^)λλ1*>?■)CV
0.040.60.031.4Tonsil® Supreme 112 FF
0·0180.30.026.01.1 A ‘mil ate % 16·2) 4ϋ^β t«.L4l (u3j2U % 10
0.0160.30.015.81.2 OjjlII ui* % 21.5) <aia-c 4 ς. Loll (ujjlb % 10
0.0180.30.014.61.3 fcjJI Cite % 27.6) ^J| 4ϋ≥^ο («.L4| (ώ^ % ΐο

[70]

j L*'jj '■ da* ^Ic. ^ ^ ^ ^ϋ3 ' ^■ dl dLjiuiil \ 4 In > »‘1 all ^jj■ ^β^11 Ajjpl 1 ^s«j ¢^10αλ11 ^j3 lA^j (Lovibond AF 995 J lisj 4·6-6·0 OV ciialli

[71]

.(^jjjla ¢^Λ. 0·02 ^) Ajliil Ida. AJIjlj (0.3 CV j*^IJ <]j)j dlUo*!!) a.liaJI ' --a"'!' jJalLi J» <*ij V AiUollj L_ajsal]l jl (J1_1a1I IcA

[72]

jjc. ^jojuaslll t_)jjj (J. ^>® (jjjatau ^jj ^gJtlLij Jal «.Ls iSj'^ * (AJ ajj■ ^ηΐ <aaa-*]l j|^a]|
2
(^dojl) iyt)(cliA1°ty Lsj"nA u»H
5132.3(AjjISjjI) 2.1 <jjc.
739.0(^jjlLo ^.) 2.1 “Cue.
5034.8(Ajj\£jjI) 2.2 “dje-
5036.8(Ajj1£ujI) 2.3
649.0(5ujlLa Αλ1C.) 2.3 ^UJC-

[73]

. 1ΰ¾ aIjIs (^jjlLa <n»5 1.3 1 · 1 ΐ aa^. (jjJall £a (Jji-iil Cluj ji-aajj (jdll ><aa :2 (J^-®-® j ^11-a % 35 £.ℓ-ο * cAi *-ASa-all ^laJI ^jjlnll dil IJ& 3 ^ J * 1 ^au ^Ija. «Le ^jia-a A] (» HO ^ W^® cA ® «*<•»'» *■ ^3·ν (ΕΡ 1893392 Β1 J ISsj) Jl (jjl*jj ^®^ (A-aSio (J5 <aaa*4lj ¢.Lall (A*1 *•-*' 'J»ll (JjlVl j>J_j . j*j 3$11j % 9 ^jlJ ^laJI (jjlall 4.UC. (ja 3-lla. (j£ ^ j»a 10 AiUlaj jaJU 1·^ .l$J

[74]

^ulCujp Cilj A«_i ,4jj3J 10 0Λλ1 96·5 ·11℮· ^ .'A*!? jalaJI Cluj (j-e ^ 100

[75]

^j-ejll (JjC* ‘“"' (At? 1η^·1 (_£aLa (j>^ __)2j-^alall (jjlnll dujll lijK ajjA^aJ i_sla (jjfLil (^lall jula]! (jjjjjda cA^) (jj>Jt.l (jlill ^Ja*21 .ζΐ11ΰ21 2 Jjd>. .

[76]

(^‘^»®1 C^7 (J1 ^*®' ^udjj 4-lejl ^jajJolu l**®® ^aJ4?~ ' ^ [jl Λΐΐ51

[77]

.(jna.iillj Clj^a]! <11^ djjjil Ajjc. j__' ■ ^««*1 (Jja-ill dLjj (jx ^j[j__)1I <lljlj jjU-aaull lu CV 3 (J^dajj Tonsil® ) SMBE u 5jjlLa (^La % 8.9 -j % 34.8 £-® ^-4=j) 2.2 s->!>^ .(Supreme 112 FF, Clariant Produkte (Deutschland) GmbH 3 Jj-d.

[78]

(Jjajll djjj jj.^vh jVi Ja 100 j f 120 Jjft Η3ΡΟ4 % 0·02 ijjU^aiUI c_ilj5 jji# % 1.6 j jji<-iTi\l) («^i 120 0A*1 jUt|yLa 1 < j f 270 -240 ^ ^ 20 soJ
^jljjll ^llj)jj ■<lull
(SYS cuvette) CV j*J\)(%” cuvette) CV j*J
2.57.4Tonsil® Supreme 112 FF
2.117.934.8) 2.2 (t/jl^l
2.115.6(aU ℅ 8.9) 2.2 ^AjjlLo

[79]

t^gkuA ¢.1λ j"'-' -*) (jimJjllj ^^jll ^LiJI jjiall djj^ial t (Jj^t ill duj Ji*-^· ■iljxll jl ftC-J -AljUaHa gjljj jjjllj % 9 Jlja- ¢·1α 'lg^'Vj (% 34·8 . ("lajaVi jj£l" ^ . ,<\. ..ΐ _K ,Τ, ΐ ^jl) 4cjall (juijl Ajllxi (Jal ajLa j 4 i j-iTi jjn<uaUj Aila-all 2u^V ijju* ^) SMBE Tonsil® Supreme 112 FF ^ kjlUL ^ .^jljjll 4j|jl JxJ oj'uui-Q ^ljlIj ^hajoiIIj t jdlall j£-lal t^Ajilfr oJja. dllj 4jj ha-all

[80]

4c.jllail Ajjhill dljjjll jJj^ailill JJjh 3 (J^-hs (jJaAi. j-e % 3 ^ilj-a) 4laj-iljJ hills Aihjaih 2 (Jh« (ja ^IhJI jjlall ^IjaII <aJl*-o

[81]

^W jj. -«a~AI Jjjlj jlhii.1 ^»Jj DMBES jajhhl 4-mjlVu aJj£ JaliJij liLjfLuill . ((j-o-ill -She. dijj tdialll j.Aj l" nj thjj-*all JjS duj4 θΑϋ^ duj) Ag-jUfill 4-ώℓαΐ11 dljjjl! 4 QQ-v a\I ajhall £A (% 34 · 8 0·1-β JJ*d ') (ja^dlh 4 411 S-ihail AjjliLa ^-1 i*djh Ο^Λ Tonsil® Supreme 112 FF, Clariant ) SMBE j (A 8.9 *ha cii^) "^" 4 Jjl^a. ^ ^jlullj Jj*-alii3l ζ-^ ^ .(Produkte (Deutschland) GmbH .7 Jj 4 Jj-^

[82]

3JljJ i3ijiL 30 sd4 jb J* 30 j 100 ·3ΐ℮· jj■ <-i?ill i-ijp ciiw % 1·50 -j jji^»s"ill) (3iib 60 Sdal jh Ja3 10 * 1 < J j» 240 dc. ^jljjll

[83]

*>•) (du^°OV ^A2k!*>) (uj4-°OV jxaJ
0.002.30.052.6Tonsil® Supreme sjL. 112 FF 4jjlLo
0.011.60.12.18.9) 2.2 % 3 + (*L % F^Cit ui>?
0.142.20.193.12.2 <3j& (*L % 34.8) ΰΐ^ ℅ 3 + ((_gj\£jj|) H3Cit
5 Jj-i?.
(Jj3 uluj ji^aSj AJjjJ tAijaj 30 s.i*l jb ^1λ 30 j 100 <-sj_£ ujj^ 0·30 -j jj.^i^II) 30 βΛώ1 jb ^gie 1 < J f 220 -^℮·
*il)jA m 11
0?“) j;l3jJjK (du^“ d^GV ^ΛΛ·1*>■) ddjjj^ (ΰλΑ-° <J£lOV
0.100.80.115.4Tonsil® Supreme sjU 112 FF
0.070.60.0716.68.9) 2.2 3ΰρΑ

[84]

% 3 + (*U % H3Cit (jjjj (5jjtLc 4jje)
o.ll1.00.1216.32·2 <jj& (¢·ℓχ % 34.8) ui*? % 3 + (gjjisy) H3Cit
6
dialll jju Cluj J' ‘ **«Ti 5JjJ tAliSj 30 jlj ^1β 30 j 110 ·ϋ≈· ji-oaoll s-’Ip CiA>i % 0·60 j jji<*i^iM) (<La.s 30 s.iel jUt5la 1 < j 230
5Jljj
*>■) OAuj^ (uj4^ <J^1OV(ϋ,¾^0OV ^)Α^1
0.040.60.031.4Tonsil® Supreme silo 112 FF <jjlLe
0.030.40.038.28.9) 2.2 % 3 + (*L % H3Cittjjjj (4j;lLe Ajjc.)
0.040.40.043.12·2 4jjc. (*L % 34.8) άΐ^ % 3 + ^^ylSjjl) H3Cit

[85]

¢.1λ (jAjJail: DMBE (-ala. (J£j0u (J-IxaII ji^aadll i-jIjj (_£l) gUla
7
) ^ tg. l** ^iA^aSJ 5Jljl tAiAs 30 όΛχ1 jli ^1λ 100 j 100 ^ΰ℮· j-u,Aijll <->1jj (ji>j % 1.00 j 60 0Λλ1 jU ^^la ^ 10 * 1 ^ J j» 240 -lie-
AJIjJ<iutll
ajp.) Jjijj^KOV JAa.1*>?“) (ofcA*OV JAa.1
0.0021.30.011.4Tonsil® Supreme sjLs 112 FF 5jjlLa
0.0041.20.011.68.9) 2.2 fcaJI % 3 + (¢ℓβ % HsOit (4-jjlLa 4-ΐ^.)
0.031.30.061.82.2 (¢·1λ % 34.8) a!# % 3 + (^1≤άΛ) H3Cit

[86]

5Jlj) .IxJ aAla. o-lia. ^% 34.8 ς^1ℓ℮·

[87]

Αε·^11Λ ^LfiA pLe dlUA^a] _JJ‘ .-a'tti _jJljIj :4 Jllo ‘ ~*.ό1ΐ1 jjj iliyj (_jU"n LeJ3 hfoij ^Jlc. pLe a ^ja. J-i*ij ^rTull t-S^j-iaJ (_j*xaj <lift t a\Λή^1 % 34·8 j % 8·9 pLall jjj'*'<1 ££jlj(_si ^ℓΑ QjfL) <lljl ^xj . ^‘‘U^aSlAa ρ^αα.4 -*ja) .^IjpA pLe (J^A-a £a h'n* 4-jl . jtLax pLall (_jjpa-a ^jc i_a^k-aj ^>A3I alul£

[88]

% 3 5iLUaJ lilli AiuUai/lj 2 (Jluxll (jjlall .iljx 4^11λ-ο C u!i oja .diilll jj‘ ^a**^ j)1 ^ DMBE 3 JLi« ^LjawiII Aiia-dl ajLoll £a (% 34.8 <Aj % 21 ¢1λ (jjfi-> .a) (JmaihUj Aiia-all ajLell 4-jjlLa ej^j Tonsil® Supreme 112 FF, Clariant ) ΗΡΒΕ j (% 8.9 *1» tjJ^) "si*" .8 Jj^?. ^ gjtuilj ^ .(Produkte (Deutschland) GmbH
8 (Jj-ia.
cliilll jii jLic. cluj 511j) tAijsj 30 s^*l jIj 30 j j» 110 ·ϋ≈· ^1Ρ Cii>} % 0-60 -j jj.^MI) (<3j2J 30 4.1*1 jlj 1 < j (> 230 -lit Jjljjil
JU ^■a‘*i\lA n» 11
*>■) JAu4* (luA°CV*>) JAll4* (lυΑ4CV
0.040.60.031.4Tonsil® Supreme ό·ΐℓβ 112 FF AjjtLa
0.030.40.038.28.9) 2.2 % 3 + (¢ℓβ % HaOit (5jjlLe Ajjc.)
0.030.40.024.02.2 ^jjc. (.U % 21.0) ui>? % 3 + (^l£il) H3Cit
0.020.40-023.62.2 ^ (*U % 25.3) ui>? °/° 3 + (^1≤^1) H3Cit
0.030.40·023.32.2 ajjc.

[89]

H 1^ΛΥλ1 ^)Jj\j I 5 J'lLCi l* .Ac^jlL&1) 4jL*^}1 AjjjJaxil Jjjjall -^»j■ *' ^ t3
(*U % 30.5) oj>? % 3 + (gytSul) H3Cit
0.040.40.043.12.2 ^jjc. (*L % 34.8) id# % 3 + (yylSLl) H3Cit
8 3j-^
dialil jii jLic. Cluj j < ■--°' 5Jlj] t<LSj 30 jU ^gla 30 j j» 110 ·ϋο· ji^asoll i_i|_p (jj^j % 0·60 u jjt^'ill) 30 β-^4 jU lsLh 1 < j j» 230 -ilc-
5-lljJ
*>■) 3^OV*j*) 33χΐ4^ ((4*3° 3^1CV
0.040·60.031.4Tonsil® Supreme SAl. 112 FF AjjlLe
0.030.40.038.28.9) 2.2 M ℅ 3 + («.La % H3Cit 4ij&)

[90]

cjAA^j l A,^\i ■.!-»•\i % 3 ^sLja] Oajoil

[91]

.(Jlialll jlijLi£)^ ^U^ioJl _JJj\j jliiikl ^aJj DMBES (iiL^Ia^la (J*aa^. ii-^uILa ^qo-vaW £^La]| £A )% 34*8 ¢-ℓ-β SS''^ ^) 4-JjULe ^ tAjjlj o^-o Tonsil® Supreme 112 FF, Clariant ) ΗΡΒΕ j (% 8*9 *L lsj^) "s^" .9 ^ .(Produkte (Deutschland) GmbH

[92]

21-t, j 'Au J< Λ. ΐ .j < ■ ■''n.**' £ufi*£ (J^-^ AjI u-aljouSi
0.040.40.043.12·2 3jj& (*L ℅ 34.8) ui*? % 3 + (^jISSjI) H3Cit
0.030.40-013.88.9) 2.2 % 3 + (*U ℅ H3Cit
0.040.60.032.72·2 A-uc. (*U % 34.8) ai*s % 3 + l^IuILa (^jISjjI)
0.020.40.014.78.9) 2.2 ^ % 3 + (*L % U''1'®^ Lii>? (SjjlLa
0·030.50.021.72.2 (*U % 34.8) ύ1χ % 3 + ΐ-¾^ !■» (4j>\£u1)

[93]

ΐ■ ,,-χΛ^1 .<^JjjJa^la u^LlilL* ^Jl..MUdl ¢.1λ11 lsS'^* aJL^ ^ 1λλ ^¢.ℓ-β % 34.8) Aaaa-&J1 SjLall a]!^.

[94]

.DMBE J j^eSall Jac. [^lia J^Aj ¢·1λ11 jj*^ ·(^·^° % 8·9) cs^bll



[95]

The invention relates to a process for producing a bleaching earth, comprising the steps of drying a water-rich raw clay to a reduced water content, mixing the raw clay having a reduced water content with a solid organic and/or concentrated inorganic acid, and grinding the mixture of raw clay having a reduced water content and solid organic and/or concentrated inorganic acid, in which case the bleaching earth then has a water content of 20% to 40% by weight. The invention further encompasses a bleaching earth obtainable by this process and to the use thereof for bleaching of raw animal or vegetable oil.



Process for producing a bleaching earth, comprising the steps of

- drying a water-rich raw clay to a reduced water content,

- mixing the raw clay having a reduced water content with 1%-5% by weight (based on the weight of the raw clay) of a solid organic and/or concentrated inorganic acid,

- grinding the mixture of raw clay having a reduced water content and solid organic and/or concentrated inorganic acid,

characterized in that the bleaching earth has a water content of 20% to 40% by weight.

Process according to Claim 1, characterized in that the water-rich raw clay has a water content of 50% to 70% by weight.

Process according to Claim 1 or 2, characterized in that the bleaching earth has a water content of 30% to 40% by weight.

Process according to any of Claims 1 to 3, characterized in that the solid organic acid is selected from the group comprising citric acid, malic acid and tartaric acid.

Process according to any of Claims 1 to 3, characterized in that the concentrated inorganic acid is selected from the group comprising sulfuric acid and phosphoric acid.

Process according to any of Claims 1 to 5, characterized in that the proportion of solid organic acid or concentrated inorganic acid is 1%-3% by weight, based on the weight of the raw clay.

Process according to any of Claims 1 to 6, characterized in that the water-rich raw clay contains a mixed smectite-silica gel phase.

Bleaching earth obtainable by the process according to any of Claims 1 to 7.

Use of the bleaching earth according to Claim 8 for refining of fats and/or oils.

Method of refining fats and/or oils, wherein

- a crude oil obtained from vegetable or animal material is provided,

- the crude oil is subjected to bleaching by treating it with a bleaching earth according to Claim 8, and

- the bleached oil is separated from the bleaching earth.