COMPOSITIONS AND METHODS FOR HIGH TEMPERATURE STABLE CATALYSTS

il¸ ; i¸ iÅ <', i l0 The present invention relates to catalyst compositions and methods for their preparation and use. In particular, this invention relates to catalyst compositions characterized by high stability thereby maintaining good catalytic activity.

Catalyst compositions exhibit a relatively high surface area per unit weight to allow the largest amount of reactants to contact the catalyst. Additionally, high surface area is constant when the catalyst composition contains a precious metal suck as platinum because of the cost of the metal and because of the dispersion required to prevent undue metal crystallite growth.

It is desirable to retain this high surface area for long periods of use under severe conditions which might include reaction temperatures of 1200°C. or higher.

Alumina is an excellent and relatively economical ; :i,! J ? 2Q t"ï " i i:,f • ? ,i , 1 'í'! b i:i ;i 29 I ;p carrier or support for any catalysts. Many crystalline forms of alumina, for example, chi, kappa, gamma, delta, eta, and theta, exhibit a very high surface area in relation to their weight.

A serious drawback of alumina as a catalyst carrier, however, is its transition temperature of about I000-1200°C. to the alpha form which results Æn a substantial reduction of the surface area.

t is thus extremely desirable to stabilize alumina-containing catalyst compositions based on high surface area aluminas to substantially prevent the transition to the low surface alpha form with a consequent loss in activìty.

It is therefore an object of this inventìon to provide catalyst compositions, as well as methods for their preparation and use, which exhÆblt higk temperature stability. Other objects and advantages will appear as the description proceeds.

Broadly, the catalyst composition of this invention cb/ - 1 - .i .I o"X .... ' :'.. , '.., , ." '.. • • , .

L ' , ,, ,,' . ""-.' . '' ' ";.ì\ .... " 10365 1 i" .,k" includes a catalytically-active, calcined composite characterized by a surface area of at least 20 square meters per gram (m2/g) after calcination for two hours at a temperature of 1200°C., said composite comprising or being a composite of alumina and a mixture of two metal oxide components wherein the first metal oxide component is selected from the group consisting of chromium, tungsten, and mixtures thereof and the second metal oxide component is selected from the group consisting of Group IVB metals and mixtures thereof. In preparing the catalyst composition, the composite is first calcined at a temperature of at least 850°C., and then a catalytically-effective amount of a platinum group metal is Added to the composite. A catalyst composition prepared in accordance wÆtk this invention exhibits high temperature stability and therèfore catalytic activity in a number of high temperature reactions, particularly high temperature combustion reactions.

The composite is formed by the calcinatìon of an intimate admixture of an aluminum compound and two metal oxide components wherein the first component is selected from the group consisting of chromium, tungsten, and mixtures thereof and the second component is selected from the group consisting of Group IVB metals and mixtures thereof. Preferably, for certain methods of preparation, the aluminum compound is alumina. These compounds, as indicated, if not already in oxide form must be capable of formìng or yielding tIleir respective oxides upon calcination in a r (oxygen) at a temperature of at least 850 C. The metal oxide or oxides mixture m y be considered as a high temperature stabilizing component for t11a alumina.

The relative amounts of alumina to the metal oxide abl ',L'a, . ....., '/i iI , .. .', . 5' q I ... i ..k ,,, i ]'i' i ,% r 1O36581 stabilizing component are governed largely by empirical criteria.

While it is not desired that this invention be limited by the following theory, a brief statement may provide a helpful framework to further elucidate the invention. It is thought that the addition of the stabilizing component to the alumina or alumina precursor and calcination of the mixture at a temperature of at least 850 C. converts any of the non-oxide compounds to oxides and allows the stabilizing component oxides to enter the alumina lattice and prevent or substantially reduce subsequent transition to alpha alumina.

All surface areas throughout the specification and the appended claims are measured by the B.E.T. or equivalent method.

The terminology used to describe the metals herein, that is, the Group IVB metals, is the terminology used in association with the common long orm of the Periodic Table of Elements. Thus the Group IVB metals are titanium, zirconium, hafnium and thorium.

The catalyst composition may also contain a minor amount of other ingredients, up to about 5 percent by weight of the composite, whichmay serve as promoters, activators, or other purpose for oxidation or reduction reactions. Such ingredients may include, for exa/aple, manganese, vanadium, copper, iron, cobalt, and nickel usually as the metal oxide or sulfide.

The calcined composite may be formed to any desired shape such as a powder, beads, or pellets. This shaping or fabricating is accomplished before calcination to promote particle adhesion. After calcination, a platinum group metal is added to the composite. Additionally, the composite can be applied or deposited on a relatively inert support or substrate and the platinum group metal then added, or the catalyst ch/ ï içl/ • i !i ,ií, í"' i, cbl 1O36581 composition can be applied or deposited onto the inert support.

For compositions made in accordance with this invention, the composite generally comprises about 80 to 95 weight percent alumina. The Group IVB metal oxide, may be present in about 2 to 15 weight percent of the composite, preferably about 5 to weight percent. The chromium and/or tungsten oxide may be present in about 2 to 15 weight percent, preferably about 5 to weight percent of the composite. The mixture OE Group IVB metal oxides and chromium and/or tungsten oxides may be present in about 5 to 20 weight percent, preferably about 5 to 15 weight percent of the composite. If the amount of alumina is too low, the resulting composite will not provide enough surface area to provide catalytic activity. If more alumina is present •than stated, it may hOt be stabilized sufficiently and will lose surface area in the transition to the alpha form.

Generally, to provide the advantages of this invention, it is necessary for the stabilizing component to be in intimate association with the alumina during pre-calcining. An intimate admixture may be achieved, for example, by forming a slurry of alumina with water soluble compounds of the stabilizing components.

there desired, hydrated alumina, such as aluminum trihydrate is admixed with aqueous solutions of the mixture of the metal salts oZ this invention to permit scrption of the stabilizing components by the alumina. The solids are then recovered from the slurry and calcined to provide the mixed oxide composite. The particulate alumina is preferably in finely dÆvìded or colloidal form to provide maximum sorption area. For example, finely divìded freshly precipitated aluminum trÆhydrate having a partìcle size of percent to 90 percent smaller than 325 mesh is useful. When i iii, i i t 'ë1 ) i, il'k '4 ,2¸ !0 Æ036581 large particle size alumina is used, the sorption of the stabilizing components from solution and subsequent calcination will provide at least a stabilized outer portion of the alumina.

Another method of preparing intimate admixture of alumina and stabilizing components is to coprecipitate all of the components, including the alumina, from aqueous solutions.

yarious methods of coprecipitation are suitable. Such methods include, for example, surface adsorption where one or more components in ionic form are sorbed on the surface of a preç itating solid; and inclusion, in which the coprecipitated cQm ound or compounds bave dimensions and a chemical composition thick will fit into tke crystal structure of a precipitating solid without causing appreciable distortion.

In coprecipitation, a suitable precipitant, usually a base, is added to an aqueous solution of the compounds. This c n also be done by concurrent addition of both the precipitant nd the compound solution to a vessel containing water. Preferably the precipitant is selected such that undesirable or unnecessary €ompounds are volatilisable and decomposable upon calcination at 850°C. or above, or removable by washing or extraction. The precipitant is capable of initìating and completing essentially multaneous coprecipitation of the components. Suitable precipitants are ammonium compounds such as ammonium hydroxide or ammonium carbonate as well as other hydroxides and carbonates oZ the alkali metals, The precipitant may be in dilute or concentrated aqueous solution. The rapidity of addition of the precipitant and the degree of agitation used will vary depending upon the precipitate desired. Dilute precipitant solutions, slow addition, ab/ - s - ï" !i! i0 and vigorous agitation generally favor a coarser precipitate.

The temperature during the addition of precipitant may be from about 0° to 90°C. Higher temperatures generally produce a coarser precipitate. The precipitant is added until a pH of about to 9.0 is reached. At this time the coprecipitated mixture is recovered from the slurry, washed if desired, and digested or recrystallized if desired.

The intimate admixture of alumina and stabilizing components are calcined at a temperature of at least about 850°C., preferably about 900 to 1200°C., but not at such a high temperature Q for such a long period of time to unduly sinter the composite.

Tke conditions of the calcination are such as to provide a catalytically-active composite having a relatively high surface area of at least about 25 square meters per gram, and preferably at least about 75. Calcination is preferably conducted while the admixture is unsupported and in free-flowing condition. This is preferable for economic reasons and to prevent undue sintering.

Calcination in air to form the composite, and prior to the addition of a platinum group metal, is an integral part of the subject invention. It is found that an intimate admixture of the stabilizing components and the alumina is stable when calcined at such temperatures before any further preparative steps are performed. Since both the alumina and the stabilizing components are intimately admixed, the concurrent heating in close association substantially reduces any undesirable alumina transitions. Additionally, calcination before deposit on an inert substrate promotes adhesion of the calcined composite to the substrate thus allowing the use of higher space velocities with the finished catalyst composition with less chance of erosion.

•:' cb/ .i., • • . • r .

í i0 obl 1036581 Further, calcination substantially reduces the possibility of reaction of the stabilizing component and alumina component with the substrate. Any such reactions between the alumina and the substrate promotes the formation of inactive forms of alumina thereby reducing its surface area and activity. If the stabilizing component were to react with the substrate, it would reduce the effective amount of this component available for stabilization.

A further advantage of such calcination is economic because less heat in smaller furnaces is required to calcine the resulting powder composite before it is placed on an inert support. Further, t is essential that the calcination is conducted before the Addition of a platinum group metal component to prevent loss of such component by occlusion.

SuÆtablealuminum-containing compounds are alumina, the gamma, eta, kappa, delta, and theta forms of alumina and for coprecipitation, the water soluble aluminum compounds such as salts, for example, the aluminum halides, aluminum nitrate, aluminum acetate, and aluminum sulfate.

The Group IVB metal oxides, i.e,, the oxides of titanium zirconium thorium and hafnium, are added to the alumina in the form of their water soluble precursors. Thus, for example, water soluble IVB metal salts such as the nìtrates, acetates, halides, and sulfates and the l'Lke might be employed. Suitable water soluble compounds are Zr NO3 )4 , ZrCI4 , friS04 )2 , ZrOCI2 ,Ti2 (C2 04 )3 , and HfoC12.

Water soluble compounds of chromium and tungsten which can be used are, for example, chromium acetate, chromium nitrate, chromium halides, chromium oxide chromium acid), chromium oxalate, and complexes of chromium such as chloropentamine chromium chloride, il , i!I r' t''' r }..íi!.

o, 10,36581 20• tungsten halides, tungsten oxy-salts, such as tungsten dioxydichloride, ammonium tungstate, and the like.

A platinum group metal is added to the calcined composite to form the catalyst compositions of this invention, which are found to be effective for long time high temperature reactions.

Suck metals are usually added or •incorporated in amounts sufficient to provide significant activity. The platinum group metals useful a;e platinumt rutheniumr palladium, iridium, and rhodium. The choice of metalr metal combinations or alloys is governed largely by activity, specificity, volatility, deactivation by specific components included with the reactants, and economics.

The quantity of platinum group metal added to the calcined composite depends first on design requirements such as activity and lire ànd second on economics. Theoretically, the maximum amount of such metal is enough to cover the maximum amount of surface available without causing undue metal crystallite growth and loss of activity during use. Two major competing phenomena are involved in such surface treatment. It is desirable to completely cover the substrate surface to provide the greatest amount of platinum group metal coverage, thereby obtaining maximum activity but if the surface were to be completely covered, such coverage would promote growth between adjacent crystallites, which growth would then decrease the surface area and greatly reduce activity. A balance of maximum coverage coupled with proper dispersion thus must be achieved to formulate a practical catalyst. An ancillary consideration in relation to the amount :i:::.ï of platinum group metal £s the aiÆowable s ze o2 the catalyst ,Q housìng. If the size is small, the amount of platinum group metal component used is preferably increased within the aboveab/ - 8 - ?L , , L, - ,.i ..... '." Hi.

• //i «ii • ;:rl L'Z • i0 i¸'' i :ï 1 , j k! • ! •i i¸ 29 : cb/ 1O36581 described limits. For example, for automobile exhaust treatment, the allowable size is relatively small, especially if unitary honeycomb type supports are used and a higher loading may be desirable, Economics, of course, dictates the use of the least amount of platinum group meta! component possible while accomplishing the main objective of promoting the reaction. Generally, the amount of platinum• group metal used is a minor portion of the catalyst composite and typically does not exceed about 20 weight percent of the calcined composite. The amount may be about 0.i to percent and is preferably about 0.2 to i0 percent to economically maintain good activity with prolonged use. These percentages are based on the weight of the c icined composite. If the composite Æs used on an inert substrate, the composite may be, for example, about I0 percent of tke weight of the substrate and the percent weight o£ platinum group metal in relation to the total weight of substrate and composite will be correspondingly less.

During preparation of the catalyst composition, various compounds and/or complexes as well as elemental dispersions of any of the platinum• group metals may be•used to achieve deposition o the metal on the composite. Water soluble platinum group metal compounds or complexes may be used. "The platinum group metal m y be precipitated from solution, for example, as a sulfide by contact witk hydrogen sulfide. The only limitation on the carrier liquids is that the liquids should not react with the platinum group metal compound and be removable by volatilization or decomposition upon subsequent heating and/or vacuum, which may be accomplished as p rt o the preparation or in t1 use of the completed catalyst composition. Suitable platinum group metal compounds are, for example, chloroplatinic acid, potassium t, : ii i i0 platinum chloride, ammonium platinum thiocyanate, platinum tetrammine hydroxide, platinum group metal chlorides, oxides, sulfides, and nitrates, platinum tetrammine chloride palladium terrine chloride, sodium palladium chloride, hexammine rhodium çhloride, and hexammine iridium chloride. If a mixture of platinum d palladium is desired, the platinum and palladium may be in Water soluble form, for example, as amine hydroxides or they may be present as chloçoplatinic acid and palladium nitrate when used in preparing the catalyst of the present invention. The platinum group metal ay be present in the catalyst composition in elemental or combined forms, e.g., as an oxide or sulfide. During subsequent treatment such as by calcining or upòn use, essentially all of the platinum group metal is converted to the elemental form.

While these catalyst compositions are useful in many reactions, they are not necessarily equivalent in all processes nor are those which are useful in the same process necessarily exactly equivalent to each other.

While it is not essential, the catalyst compositions of this invention preferably have a relatively catalytically-inert support or substrate. The supports which can be employed in th s invention are preferably unitary, skeletal structures of ;elatÆyely large size, e.g., honeycombs. However, smaller particle forms may be used, e.g«, pellets or spheres. The size of these pellets can be altered depending upon the system, its design and operating parameters in which they are to be used, but may range from about 1/64 to I/2", preferably 1/32 to 1/4", in diameter; and their lengths are about 1/64 to i", preferably about 1/32 to i/4".

When a support is used, the calcined composite is obl - fO - • • ':" ' ,ï .."., ..,. ,'..!: . i,'i.,., , • ' " -":i" ; " • ï .....

',,', i :ii i!i /',/i ii:!i! i0 generally present in a minor amount of the total catalyst composition, which is usually about 2 to 30 weight percent preferably about 5 to 20 weight percent, based on the total weight of the composite and support. The amount used depends on economics, size limitations, and design characteristics.

These supports whether of the unitary-skeletal type or pellets açe preferably constructed of a substantially inert, rigid material capable o2 maintaining its shape and strength at high temperatures, for example, up to about 1800°C. The support typic lly has a low thermal coefficient of expansion, good t ermal shock resistance« and low thermal conductivity. While a support having a porous surface is preferred, the surface may be relatively non-porousr but in such event it is desirable to roughen the surface to improve adhesion of deposited compositions.

The support may be metallic or ceramic in nature, or a combination thereof. The preferred supports, whether in skeletal or other form, are composed primarily of refractory metal oxide including combìned oxide forms, e.g., alumino-silicates. Suit- ble Support materials include cordierite, cordieritelalpha alumina silicon nitride, silicon carbide, zircon-mullite, @ odu.mene, alumina sìlicaagnesia, and zirconium silicate.

Examples of other suitable refractory ceramic materials are sillimanite, magnesium silicates, zircon, petalite, alpha-alumina, and aluminosilicates0 Although the support may be a glass ceramics Ai ks preferably unglazed and may be essentially entirely crystalline in form and marked by the absence of any significant amount of glassy or amorphous matrices. Further, the structure may have considerably accessible porosity, preferably having a water pore volume of at least about 10 percent. Such supports are described ab/ - ll - • !t" " "t L; • IO365 I in U. S. Patent No. 3,565,830.

The geometric, superficial, or apparent surface area of the skeletal or'honeycomb type supports, including the walls of the gas low channels is generally about 0.5 to 6, and preferably 1 to 5, square meters per liter of support. This surface area is sufficient for deposition of a satisfactory quantity of the composite or the finished catalyst composition. The plurality of channels, about 100 to 2500, preferably 150 to 500 per square inch of cross-sectional area, may be distributed across the entire face of the structure and frequently they define an open area in excess of 60 percent of the total area of the support.

The walls must be thick enough to provide rigidity and integrity to the structure while maintaining good apparent surface area.

The wall thickness is thus in the range of about 2 'ho 25 mils.

The flow channels can be of any shape and size consistent with the desired superficial surface area and should be large enough to permit relatively free passage of the gaseous reaction mixture; preferably 'the length of the channels is at least about 0.i inch to nsure sufficient contact "or residence time to cause the desired reaction. Although the channels are generally parallel, they may be multi-directional and may communicate with one or more adjacent channels.

In one manner of preparing structures provided with catalyst compositions of this invention, an aqueous slurry of the essentially water insoluble calcined composite of alumina and stabilizing component is contacted with the support. The solid content of the slurry forms an adherent deposit on the support, and the resulting supported composite is dried or calcined for a second time at a temperature which provides cb/ • v .,L• :• 1,: ........ •,[.1 • • , z ' ç '« ",v 'ï, il" !•4 J, •,,, /• i !/, r' ! '/ ' i ' r .I !:» .i: ! t!i.; ," .r" ! r,, , • ' '[' i IV' , .! 29 , d / a relatively catalytically-active product. The second drying or calcination takes place at a temperature low enough to prevent undue sintering of the mixture. Suitable calcination temperatures are generally about 300-700°C to insure catalytic activity without undue sintering, preferably about 400-600°C. After this second calcination the coating on the support has a surface area oK at least about 75 s.m.p.g. Lower temperatures can be employed to d;y the composite if the second calcination is not performed.

After the coated support is dried or calcined, a platinum • group metal component is added to enhance the catalytic activity of the composite. The platinum group metal may be added to the coated support n the manner previously described. Preferably, this addition is made from an aqueous or other solutïon to ±mprignate or deposit the platinum group metal component on the coated support.

After addition of the platinum group metal, the resulting Structure is dried and may be calcined for a third time under conditions whick provide a composition having characteristics that enhance selected reactions. This final calcination stabilizes the completed catalyst composition so that during the initial @rages of use, the activity of the catalyst is not materially altered. The temperature of this final calcination must be low enough to prevent substantial sintering of the underlying coating W Ch would cause substantiel occlusion of the platinum group metal component, Thus the calcination may be conducted at temperatures of about 300-700QC., preferably about 400-600«C.

An alternative method of making the catalyst compositions of this invention if a relatively inert support is used involves adding the platinum group metal component to the calcined composite before the composite is deposited on the support.

i i iï'- • ïl ' i f ' ,,j , , l , í b •'r ; i ;' I r l0 1036581 For example, an aqueous slurry of the calcined composite can be prepared and the platinum group metal component added to the slurry nd mixed intimately therewith. The platinum group metal component can be in the form already described and may be precipitated as previously described. The final mixture containing the platinum group metal may then be dried or calcined to provide a catalyticallyactive composition in a for suitable for deposition on a support Of or use without such deposition as a finished catalyst in either finely divided or macrosize forms. Subsequent calcinations or drying may be conducted as described above. The calcined aterial generally has a surface area of at least about 25 s.m.p.g., Fe erably at least about 75 s.m.p.g The following are examples of the general method of preparation of some representative stabilized catalytic composites and compositions of this invention. All percentages, parts, and proportions herein and in the appended claims are by weight unless otherwise indicated.

EXAMPLE I A stabilized Cr2 03 , ZrO2 , and• AI2 03 composite slip is prepared by dissolving 3.95 grams of CrO3 and 12.24 grams of zirconyl nitrate 03% as ZrO2 1 in water and diluted to a total volume of 80.3 ml. 51 grams of activated AI2 03 powder is stirred into the solution with constant agitation for i0 minutes. The total solution is then evaporated to dryness under heat and with agitation, transferred to a drying oven at 120°C., and dried overnight. The dried solids are ground to less than mesh and calcined at 970° for 1 hour. Five grams of the composite containing 5% cllromia, 10% zirconia, and 85% alumina is then tested Æor retention of surface area by calcining at 1200°C.' for 4 hours.

ch/ m -L 1.

.,!, i:•:; :'.'....

o I..

• i !i!:i" t, i jd , ,j <i Z • 10.

obl It is found that the surface area after such calcination is 35,3 m2/g.

EXAMPLE Il A 2 kilogram batch of the composite of EXAMPLE I is prepared in the same manner except Cr(NO3 )3 .9H2 0 is used in place of CrO3. The dried solids are calcined for 4 hours at I000°C.

186 trams of the calcined powder thus prepared are mixed with 286 l, H2 0 and 13 ml. conc. HN03 , and ball-milled for 19 hours at 68 RpM in a u. s. Stoneware 1-gallon mill jar. 330 ml. of the resulting slip having a density of 1.46 g/cc and a pH of 3.57 re diluted with 1% nitric acid to a viscosity of about 8 cps.

A l" x 3" zircon mullite honeycomb having about 5 corrugations eç square inch of cross-sectional area is dipped into the agitated, diluted slip, drained, blown with air, dried at 120°C.

or 2 1/2 hours, and calcined at 500°C. for 2 hours. The adherent Composite makes up approximately 14.6 weight percent of the coated honeycomb.

EXAMPLE III A honeycomb, coated with the chromic-zirconia-alumina composite slip of EXAMPLE I is prepared as in EXAMPLE II.

The coated honeycom5 i8 then dipped into a solution containing 18Q0 grams of Na2 PdC14 5.10% Pd) dissolved in 51 cc water.

After standinç for 30 minutes with intermittent raising and lower- ng of the honeycomb into the solution, the honeycomb is withdrawn from the solution, drained, and excess solution blown off. The honeycomb ks then treated with 2% NaHCO3 for one hour, heated in this solution to 95°C. for 1.5 minutes to accomplish hydrolysis.

The coated honeycomb is then transferred to a sodium formate solution and heated in this solution for reduction of the metal.

•t .1i ' - • • i' ,;,. ï J, • ;J i i ï .. "• t' ii i ? • F; " i iii', ,'iii •j i:;¸ il 'I :L•I i0 abl 103658X The cylinder is removed from the sodium formate« the excess solution blown off and the cylinder is let stand overnight. The cylinder is then washed chloride-free using deionized water. The resulting impregnated honeycomb is drained, dried overnight at II0°C., and calcined ìn flowing air for 2 hours at 500°c. The finished catalyst contains about 0.54 weight percent Pd.

EXAMPLE IV A composite is prepared by coprecipitation. The composition is the same as that in EXÆ4PLE I, i.e., I0 percent zirconia, 5 percent chromia, and 85 percent alumina. 187.7 . 9ça s of aluminum nitrater 6.1 grams of zirconyl nitrate 49.03% as ZrO2) and 7.9 grams of chromium nitrate are dissolved in one liter of water and the solution is transferred to a dropping runnel. A second solution containing 400 ml of 28.3% NH3) a2 monlum hydroxide and 1600 ml water was prepared in a dropping runnel. 2500 ml of water is added to a 6 liter beaker with vigorous mechanical stirring. The mixed nitrate solution is then added at room temperature to the water in the beaker over a period of about 30 minutes. The ammonia solution is added concurrently th the nitrate solution at such a rate as to keep the pH of the slurry in the beaker at 9.0. Stirring is continued for 15 minutes after the coprecipitatìon is complete. The slurry is allowed to stand overnight« filtered, and reslurried in 2 liters of water.

The second slurry is filtered, excess water removed, and dried at room temperature. The filter cake is ground to a powder, dried Æor 1 day at room temperature, and overnight at ll0°C. The surface area of the composite is good after calclnatìon at 1200°C. for 2 hours. Other oxide combinations of aluminum together with mixtures of Cr, W, and IVB metal oxides will be found to retain good surface -'. il.

:i • Y - L, .•.

v " " ?, "< . "'i ,., ., i .. . Q" " "' ." . " :ì;:Z :» »v', .••2 !i.ii ! $ i i!i ,ri v /i y i!/. ? I036581 area after calcination at 1200°C. for 2 hours.

In the practice of this invention the catalytic compositions re particularly useful when employed with the high temperat re oxidation of carbonaceous fuels. For example, they may be used advantageously in a method employing a catalytically-supported thermal combustion of carbonaceous fuel, as more fully described in U. S. Patent No. 3,928,961 (Dec. 30/75) and Canadian Patent No. 1,003,651 Jan. 18/771, of W. C. Pfefferle, assigned to the ss gnee hereof. This method includes the essentially adiabatic i0 combustion of at least a portion of a carbonaceous fuel admixed With air in the presence of a catalytic composition of this invention at an operating temperaturè substantially above the instantaneous auto,ignition temperature of the fuel-air admixture but below a temperature treat would result in any substantial formation of oxides of nitrogen.

Flammable mixtures of most fuels with air are normally such as to burn at relatively high temperatures, i.e., about 3300 F. and above, which inherently results in the formation of substantial amounts of nitrogen oxides or NOx. However, little or no NOx is formed in a system which burns the fuel catalytically t relatively low temperatures.

For a true catalytic oxidation reaction, one can plot temperature against rate of reaction. For any given catalyst and set of reaction conditions, as the temperature is initially increased, the reaction rate is also increased. This rate of increase is exponential with temperature° As the temperature is raised further, tlle reaction rate then passes through a transition zone where the limiting parameters determing reaction 29 rate shift fro catalytic to mass transfer° When the catalytic cb/ - 17 - ;ï./ iL Il i i1iJ 20• rate increases to such an extent that the reactants cannot be transferred to the catalytic surface fast enough to keep up with the catalytic reaction rate« the reaction shifts to mass transfer control, and the observed reaction rate changes much less with further temperature increases. The reaction is then said to be m ss transfer limited. In mass transferrcontrolled catalytic reactions, one cannot distinguish between a more active catalyst and a less active catalyst because the intrinsic catalyst activity is not determinative of the rate of reaction. Regardless of any ncrease in catalytic activity above that required for mass transfer €ontçol, a greater catalytic conversion rate cannot be achieved oÇ the sa e set of conditions.

It has been discovered that it is possible to achieve essentially adiabatic combustion in the presence of a catalyst at a reaction rate many times greater than •the mass transfer limited rate. That is, catalytically-supported, thermal combustion su ímounts the mass transfer limitation. If the operating temperature of the •catalyst is increased substantially into the mass transfer limited region, the reaction rate again begins to increase exponentially witk temperature. This is an apparent contradiction of catalytic technology and the laws of mass transfer kinetics.

The phenomena may be explained by the fact that the catalyst Surface and the gas layer near the catalyst surface are above a temperature at which thermal combustion occurs at a rate higher than the catalytic rate, and the temperature of the catalyst surface is above the instantaneous auto-ignition temperature of the fuel-air admixture (defined hereinbelow). The fuel molecules entering this layer spontaneously burn without transport to the catalyse surface. As combustion progresses, it is belìeved that i, cb/ ••k 7!"' .v,.

6581 the layer becomes deeper. The total gas is ultimately raised to a temperature at which thermal reactions occur in the entire gas stream rather than only near the surface of the catalyst. At this point, the thermal reactions continue even without further contact of the gas with the catalyst as the gas passes through the combustion zone.

The term "instantaneous auto-ignition temperature" 'Z '.I i,!':,• i0 for a fuel-air admixture as used herein and in the appended claims iS defined to mean that the ignition lag of the fuel-air admixture entering the catalyst is negligible relative to the residence time in the combustion zone of the mixture undergoing combustion.

This method tan employ an amount of fuel equivalent in heating value of about 300-1000 pounds of propane per hour per cubÆc foot of catalyst. There is no necessity of maintaining fuel-to-air ratios in the flammable range, and consequently loss y.,, of combustion [flame out due to variations in the fuel-to-air ratio is not as serious a problem as it is in conventional combustors.

The adiabatic flame temperature of fuel-air admixtures at any set of conditions (e.g., initial temperature and, to a lesser extent, pressure) is established by the ratio of fuel to air.

The admixtures utilized are generally within the inflammable i:?, ii:ì , 1:,: ch! ÍI, .

range or are fuel-lean outside of the inflammable range, but there may be instances of a fuel-air admixture having no clearly defined inflammable range but nevertheless having a theoretical adiabatic flame temperature within the operating conditions of the invention. The proportions of the fuel and ir charged to the combustion zone are typically such that there is a stoichiometric excess o oxygen based on complete conversion of the fuel i'.

¢. ï iii' 1036581 to carbon dioxide and water. Preferably, the free oxygen content is at least about 1.5 times the stoichiometric amount needed for complete combustion of the fuel. Although the method is described With particularity to air as the non-fuel component, it is well understood that oxygen is the required element to support proper combustion. Where desired, the oxygen content of the non-fuel i • . il " / iii» i ' r r :

ï i ï" i0 cb/ component can be varied and the term "air" as used herein refers to the non-fuel components of the admixtures. The fuel-air admixture fed to the combustion zone may have as low as i0 percent ree oxygen by volume or less, which may occur, for example, upon utilization as a source of oxygen of a waste stream wherein a ortion of this oxygen has been reacted. In turbine operations, the weight ratio of air to fuel charged .to the combustion system ÆS often above about 30:1 and some turbines are designed for airto,fuel ratios of up to about 200 or more:l.

The carbonaceous fuels may be gaseous or liquid at normal temperature and pressure. Suitable hydrocarbon fuels may inclure, for example, low molecular weight aliphatic hydrocarbons @uch as methane, ethane, propane, butane, pentane; gasoline; aromatic hydrocarbons such as benzene, toluene, ethylbenzene, xylene,; naphtha; diesel fuel; jet fuel; other middle distillate uels; hydrotreated heavier fuels; and the like. Among the other useful carbonaceous fuels are alcohols such as methanol, ethanol, isopropanol; ethers such as diethylether and aromatic ethers such S ethylphenyl ether; and carbon monoxide. In burning diluted fuels containing inerts, for example, low BTU coal gas, fuel-air d ixtures with ad abatìc flame temperatures wlthìn the range Specified herein may be eithër fuel rich or fuel lean. Where fuel rich mixtures are utilized, additional air or fuel-air • " " .i .....

i i%,, ' ' ï' , i 'i •/I i' ii Ä ,'i i:i•! !,í.I ii:i admixture may be added to the catalyst zone effluent to provide an overall excess of air for complete combustion of fuel components to carbon dioxide and water. As stated previously, thermal reactions continue beyond the catalyst zone, provided the effluent temperature is substantially above the instantaneous auto-ignition •temperature.

The fuel air admixture is generally passed to the catalyst in the combustion zone at a gas velocity prior to or at the inlet to the catalyst in excess of the maximum flame i0 propagating velocity. This may be accomplished by increasing the air flow or by proper design of the inlet to a combustion chamber, e.g., restricting the size of the orifice. This avoids flashback that causes the formation of NOx. Preferably, this velocity is maintained adjacent to the catalyst inlet.

Suitable linear gas velocities are usually above about three feet per second, but it should be understood that considerably higher velocities may be required depending upon such factors as temperature, pressure, and composition. At least a significant portion of the combustion occurs in the catalytìc zone and may be essentially flameless.

The carbonaceous fuel, which when burned with a stoiohiometric amount of air (atmospheric composition) at the combustion inlet temperature usuàlly has an adiabatic flame temperature of at least about 3300°F., is combusted essentially adiabatically in the catalyst zone. Although the instantaneous auto-ignition temperature of a typical fuel may be below about 2000°F., stable, adiabatic combustion of the fuel be!ow about 3300°F., is extremely difficult to achieve in practical primary combustion systems.

29 It is for this reason that even with gas turbines limited to cb/ - 21 - .z "À i0 operating temperatures of 2000°F., the primary combustion is typically at temperatures in excess of 4000°F. As stated above, combustion in this method is characterized by using a fuel-air admixture, having an adiabatic flame temperature substantially above the instantaneous auto-ignition temperature of the admixture but below a temperature that would result in any substantial formation of NOx. The limits of this adiabatic flame temperature are governed largely by residence time and pressure. Generally, adiabatic flame temperatures of the admixtures are in the range of about 1700°F. to 3200°F., and preferably are about 2000°F.

to 3000OF. Operating at temperature much in excess of 3200°F.

results in the significant formation of NOx even at short contact times; this derogates from the advantages of this invention vis-a-- vis a conventional thermal system. A higher temperature within the defined range is desirable, however, because the system will require less catalyst and thermal reactions are an order of magnitude or more faster, but the adiabatic flame temperature employed can depend on such factors as the desired composition of the effluent and the overall design of the system. It thus Will be observed that a fuel which would ordinarily burn at such a high temperature as to form NOx is successfully combusted within he defined temperature range without significant formation of NOx.

The catalyst used in this method generally operates at a temperature approximating the theoretical adiabatic flame temperature of the fuel-air admixture charged to the combustion zone. The entire catalyst may not be at these temperatures, but preferably a major portion, or essentially all, of the catalyst surface is at such operating temperatures. These temperatures are usually in the range of about 1700-3200oF., ab/ 1« i lp; r ;.<i preferably about 2000°F. to about 3000°F. The temperature of the catalyst zone is controlled by controlling the combustion of the fuel-air admixture, i.e., adiabatic flame temperature, as well as the uniformity of the mixture. Relatively higher energy fuels can be admixed with larger amounts of air in order to maintain the desired temperature in a combustion zone. At the higher end of the temperature range, shorter residence times of the gas in the combustion zone appear to be desirable in order to lessen the change of forming NO .

The residence time is governed largely by temperature, pressure, and space throughput; and generally is measured in milliçeconds. The residence time of the gases in the catalytic combustion zone and any subsequent thermal combustion zone may be below about 0.i second, preferably below about 0.05 second.

The gas space velocity may often be, for example, in the range of about 0.5 to i0 or more million cubic feet of total gas standard temperature and pressure) per cubic foot of total combustion zone per hour. For a stationary turbine burning diesel fuel, typical residence times could be about 30 milliseconds or less; whereas in an automotive turbine engine burning gasoline, the typical residence tìme may be about 5"milliseconds or less.

The total residence time in the combustion system should be suffic ent to provide essentially complete combustion of the fuel, but no so long as to result in the formation of NOxo A method employing the catalysts of the present invention is exemplified in a test in which the fuel is essentially completely combusted, and a low emissions effluent is produced.

The combustion system comprises a source of preheated air supplied under pressure. A portion of the air is passed through a pipe cb/ v:-¸.- . ....

i il1 ii• ! i • • il i « i i! ï¸ ; ! r k • ï • • / i'? i i f t i;i L:I•II i «', 'i Ä ì to the combustion zone, and the remainder is used to cool and dilute the combustion effluent. Unleaded gasoline fuel is atomized into the air passing to the combustion zone countercurrent to the air f!ow to insure intimate mixing.

The catalyst is of the monolithic, honeycomb-type having a nominal 6-inch diameter and is disposed within a metal housing as two separate pieces each having parallel flow channels 2 1/4 nohes in length extending therethrough. There is a small space of about 1/4 inch between these pieces. Both pieces of catalyst i0 have approximately 100 flow channels per square inch of crosssection with the walls of the channels having a thickness of ils. The catalysts have similar compositions and are composed of a zircon mullite honeycomb support which carries a composite coating of alumina, chromia, and zirconia containing palladium.

The catalyst for these runs is made by slurrying 3655 grams of activated alumina powder, less than 40 mesh in size, in a mixer with a solution prepared by dissolving 1131 grams Cr NO3)3.gH20 and 877 grams zirconyl nitrate (49.03% as ZrO2) n 1500 ml. H2 0. The mixture is dried at 120°C. over a weekend.

The dried solids are crushed and screenedto less than 40 mesh, and the powder is calcined for four hours at 10 00°C. to•form the composite of this invention° 3000 grams of the composite is charged to a 3 1/2 gallon ball mill along with 3000 ml. H2 0 and 145.4 grams of palladium nitrate. The mill is rolled for 17 hours at 54 RPM. 1600 grams of the as-recovered slurry are diluted with about 200 ml, of a 1 percent nitric acid solution. The zircon mullite honeycomb is dipped in the diluted slurry and held for one minute, and then withdrawn from the slip and blown wìth air 29 to remove the excess. The coated honeycomb is dried for 16 hours at - 24 - . • . " , .... • • ," "" , • k ., .L •. ...

i:i i rr' • "ï, I, ;,L 10365S1 ll0°C, and then calcined for 2 hours at 500°C.

The upstream or initial catalyst in the housing has a catalytic coating which comprises about 14 weight percent of the catalyst. This coating is 85 weight percent alumina, 5 weight percent Cr2 03 and i0 weight percent ZrO2 based on these components.

The catalyse also contains about 0.23 weight percent palladium Calculated) disposed in the composite. The subsequent-in-line catalyst has a similar coating of alumina, zirconia, and chromia which is about ii.0 weight percent of the catalyst. The catalyst also contains about 16 weight percent palladium (•calculated) disposed in the coating.

Provision is made for contacting the fuel mixed with a portion of the total air stream with the catalyst. That portion of the total air stream not mixed with the fuel is added to the combustion effluent immediately upon its exit from the catalyst zone. This dilution or secondary air cools the combustion effluent and samples of the mixture are taken for analysis. Thermocouples are located adjacent the initial catalyst inlet and at the sampling position to detect the temperatures of these locations.

The catalysts are brought to reaction temperature by contact wÆth preheated air, and subsequent contact with the airfuel mixture which causes combustion and raised the catalyst temperature further. The results obtained using this system during operation in accordance with the combustion method of the present invention are found to result in low emission of pollutants.

The catalysts of this invention can also be used for selected oxidation reactions at lower temperatures. In a typicàl oxidation they can be employed to promote the reaction of various 29 chemical feedstocks by contacting the feeds bock or compound with ab/ - 25 - i,/ -i i i • i' " i ',,'i vi',:

ï" « 'i 1086581 the catalyst in the presence of free oxygen preferably molecular oxygen. Although some oxidation reactions may occur at relatively low temperatures, many are conducted at elevated temperatures of about 150°C. to 900°C., and generally, these reactions occur with the feedstock in the vapor phase. The feeds generally are materials which are subject to oxidation and contain carbon, and may, therefore, be termed carbonaceous, whether they are organic or inorganic Æn character. The catalysts of this invention are particularly useful in promoting the oxidation of hydrocarbons, oxygencontaining organic components, for example, aldehydes, organic cids, and other intermediate products of combustion, such as carbon monoxide, and the like. These materials are frequently present in exhaust gases from tke combustion of carbonaceous fuels, and thus the catalysts of the present invention are particularly useful in promoting the oxidation of such materials thereby purifying the exhaust gases. Such oxidation can be accomplished by contacting the gas stream with the catalyst and molecular or free oxygen. The oxygen may be present in the gas stream as part of the effluent, or may be added as air or in some other desired form having a greater or lesser oxygen concentration. The products from such oxidation contain a greater weight ratio of oxygen to carbon than in the material subjected to oxidation and in the case o exhaust purification these final oxidation products are much legs harmful than the partially oxidized materials. Many such reaction systems are known in the art.

el. / .æ• .i/.

i!iii k, i 'I , k t i i I • ;ï ï I' , lti LJ ji" ,i % 1O36581 THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

I. A catalyst composition characterized by a surface area of at least 20 m2/g after calcination for two hours at 1200°C.

comprising Ca) a catalytically-active, calcined composite of alumina, and a mixture of two metal components wherein the first component is selected from the group cons±sting of an oxide of chromium, tungsten, and mixtures thereof and the second component is selected from the group consisting of an oxide of a Group IVB metal, and mixtures thereof, and (b[ a catalytically-effective amount of platinum group metal added thereto after calcination of said composite at a temperature of at least 850°C.

2. A composition as defined in claim 1 wherein said composite contains about 80 to 95 weight percent of said alumina, about 2 to 15 weight percent of said first component oxide and about 2 to 15 weight percent of said second component oxide.

3. A composition as defined in claim 2 wherein said first component oxide is predominantly chromia and wherein said second Component oxide is predominantly zirconia.

4. A composìtion as defined in claim 1 wherein said platinum group metal is present in an amount of about 0°I to 20 percent y weight of said compòsite and is selected from the group consisting oz platinum, palladium, platinum-palladium alloys, and mixtures thereof.

5. A composition as defined in claim 1 wherein said composite is pellets.

6e A catalyst composition consisting essentially of (a) an • iI .

.... L .... k ,