수지 혼합물

13-10-2016 дата публикации
Номер:
KR0101666262B1
Контакты:
Номер заявки: 00-13-102082946
Дата заявки: 15-07-2013

[1]

The present application the resin mixture, pellets, number of molded articles of resin using the same bath method relates to and resin molded product.

[2]

Process for the processing resin plastic and tensile strength ranges from hereinafter, has excellent properties of heat resistance or other and modulus, so as to, automobile parts, helmet, electric machinery parts capable of decreasing setting time, spinning machine component, for a multiplicity of uses pipes and the like, or toys at least two images is used as KIPO &.

[3]

For example, plastic resin extruding or injecting to form a moulding article when bath number, said mechanical properties of molded articles of improved adhesive and surface hardness said plastic good resin. under trillion number molded article after mixing.

[4]

The present application the resin mixture. under public affairs number and pellets.

[5]

The present application one embodiment of resin number 1; and with a mark represented by the general formula 1 - α constant of [...] (/ export houwink) 0 value. 1 to 0. 5 in number 2 number the resin mixture, including resin. under public affairs.

[6]

[General formula 1]

[7]

[η]=KMα

[8]

In said general formula,

[9]

The η fiber, wherein the optical fiber exhibits intrinsic viscosity of resin number 2,

[10]

The M exhibits molecular weight of resin number 2,

[11]

Α K and the number 2 [...] at the 40 °C resin applied is constant when dissolved.

[12]

The present application number 1 another implementation of a core is formed; and said [...] with a mark represented by general formula 1 - α (/ export houwink) of constant 0 value. 1 to 0. 5 in number 2 including the cells are inserted formed pellets. under public affairs number.

[13]

The present application of the resin mixture, said another implementation that the melt form a mixture; and said molten blend including work to a number of method bath number of resin moldings. under public affairs.

[14]

The present application of said another implementation to melt the pellets melt form a mixture; and said a molten blend number of resin moldings. under public affairs number of method bath.

[15]

The present application of another implementation includes resin number 2 resin and number 1, said number 2 said resin represented by general formula 1 with a mark - [...] (/ export houwink) of constant α value is 0. 1 to 0. 5. under public affairs number molded article in.

[16]

Resin mixture according to an example implementation specifically hereinafter, pellets, resin using the same of molded articles of method bath number and resin molded product is provided to rapidly and to reduce a memory to a.

[17]

In the present specification, "mixture" 2 the at least one different. can also be a mixture of the resin. Type of mixture, but not one specially number, one within a matrix of 2 when mixed resin that is at least one, at least one 2 or when to the mixing of pellets may comprise an. The other resins said has the different physical property may have, for example, the same physical property as the surface energy, melt viscosity or solubility parameter can be.

[18]

"Melt processing" the molten mixture (melt blend) temperature then fused to form an (Tm) to melt the resin mixture to a temperature above its melting point, said molten blend disclosed is a molded article uses out to increase the thickness of the initiator, for example, injection molding, extrusion molding, hollow molded, transfer molding, film-blowing, fiber spinning, Calanderrring printing or foam such as molding.

[19]

"Resin moldings" resin pellets formed from the vitrifiable means any suitable (product), the first substrate are assembled said resin moldings but not one number, for example, automobile parts, electronic parts is provided, machine parts, functional film, toy or pipe can be.

[20]

One in an example, a melt processing resin mixture can be formed by. In addition while maintaining has the different physical property mixture resin melt viscosity increased and the good workability which can be under public affairs number. Thus, resin molded product comprises improved mechanical properties may have and surface properties, said resin mixture, when using a time and production costs of resin moldings ends of the lamps and is mounted, an excellent processing can be under public affairs number.

[21]

Said resin obtained from a mixture, number 1 resin include desired physical properties of molded articles of as a resin mainly determined, desired type and of molded articles of a process involving can be selected according to conditions. Such has a synthetic resin which is generally include resin number 1 in special number, use can be made of, without the.

[22]

Number 1 resin include, for example, ABS (acrylonitrile butadiene styrene) resin, polystyrene resin, ASA (acrylonitrile styrene acrylate) resin, acrylate - acrylonitrile - butadiene - styrene copolymer or a styrene - butadiene - styrene block copolymer such as parts by weight of a styrene resin; density polyethylene orgin resin, density polyethylene orgin a polyol such as polypropylene and resin or polyolefin resin; °c by alloying an ester-based thermoplastic elastomer or an olefin-based thermoplastic elastomer such as thermoplastic elastomer; poly [...] resin or at least one polyoxyethylene-type absorbent agents such as a super poly [...] resin; view polybutylene terephthalate resin or polyethylene terephthalate absorbent agents such as a super polyester resin; polyvinyl chloride resin; polycarbonate resin; poly [...] resin; vinyl a polyalcohol resin; polyamide-containing resin; acrylate resin; engineering plastic; copolymers thereof, : or mixtures thereof. Said engineering plastic characterized by good mechanical and thermal exhibit oil absorption properties at a plastic, use can be made of, . For example, polyether ketone, polysulfone and polyimide plastic engineering and the like can be used. One in an example number 1 resin include acrylonitrile, butadiene, styrene and comprises the steps of polymerizing an such as monomer, use can be made of, of the copolymer.

[23]

In one embodiment number 1 resin an arc furnace, nitrile 3 to 12 parts by weight; butadiene 5 to 15 parts by weight; styrene 15 to 30 parts by weight; and (meth) acryl-based monomer 50 to 70 parts by weight of mixture of solvent monomers including can be polymerized from.

[24]

Said resin obtained from a mixture represented by number 2 connected to a resin with a mark - 1 (/ export houwink) [...] α constant of 0 value. 1 to 0. 5 polymer that is capable of using optical.

[25]

[General formula 1]

[26]

[η]=KMα

[27]

In said general formula,

[28]

The η fiber, wherein the optical fiber exhibits intrinsic viscosity of resin number 2,

[29]

The M exhibits molecular weight of resin number 2,

[30]

Α K and the number 2 [...] at the 40 °C resin applied is constant when dissolved.

[31]

Said mark - [...] type for under public affairs number inherent viscosity and molecular weight relationship a manner corresponding to the technical field is publicly known. A unique molecular weight of polymer from type said in viscosity may be determined from the data provided, .vice versa. Said α value (parameter) in formula constant K and rely on the solvent-based - a particular polymer, the GPC is determined.

[32]

In one embodiment, can be polymer the beginning basin resin number 2. More particularly, said connected to a polymer the beginning basin general formula and 2. of 3.

[33]

[General formula 2]

[34]

0. 01 VL=VH=0. 07 VL

[35]

[General formula 3]

[36]

0. 9 WH=WL=1. 1 WH

[37]

In said general formula 2 and 3,

[38]

VHthe 220 °C and1000 s-1the beginning basin unit moves simultaneously at the same distance and exhibits the melting point of the polymer,

[39]

VLthe 220 °C and1000 s-1the same polymer and the beginning basin said unit moves simultaneously at the same distance as a monomer component, to ensure the melting point of the polymer linear polymerized,

[40]

WHthe the beginning basin fiber, wherein the optical fiber exhibits a weight average molecular weight of polymer,

[41]

WLthe linear exhibits a weight average molecular weight of polymer.

[42]

Thus in one embodiment, the same polymer the beginning basin of identical polymerization as a monomer component, similar weight flexible bumper structure for a linear polymer has an average molecular weight than the melting point of the 0. 01 to 0. 7 times also melting, for example 0. 05 to 0. 5 times, or 0. 1 to 0. 3 have a degree melting times. the beginning basin polymer the same as a monomer component, polymerized linear polymer compared to degree lower melting melting resin composition of portion of the sacrificial layer is patterned excellent photoresist pattern is formed can be workability has been.

[43]

The present specification, groups, or with an polymer the beginning basin in having several arbitrarily shaped branched the beginning basin least structural units 1 ., is a polymer that have enhanced. Said the beginning basin may different unit structure, . groups may be the same.

[44]

Reference to drawing 'structural units the beginning basin' more as further described.. Also 1 and 2 as shown in at least 1 of structural units the beginning basin disclosure of the side branch point (10a) has. the beginning basin bifurcation the structural units (10a, 11, 12, 13) and free from korean Bank number number of, disclosure of the side branch point (10a) to a branching point only may be in construction. In one embodiment at least structural units the beginning basin 1 generation bifurcation (11) can include a,

[45]

In embodiment 2 generation bifurcation (12) and 3 generation bifurcation (13) can be conforms to the shape. In addition, groups, or with an generation regular is represents the order of the side branch. Typical generation possibility a 1 to 10 and, end groups (the beginning basin structural units (12) distal end of, the beginning basin polymer (10) a distal end which of a metal material) the tightness is combined with the ease of a generation possibility is preferably from 2 to 8, 3 to 7 and, and more preferably in a, . is most desirable if 3 to 5.

[46]

In one embodiment, a structural units the beginning basin, as shown in also 1, having branched repetitions irregular branch hyperlinks to can have a structural units, also 2 as shown in branched iterations rules having dendrimers may be structural units.

[47]

the beginning basin containing structural units said polymer in a variety of shapes, may be present. Also 1 and 2 as shown in focus structure (10) from one or 1 2 the beginning basin having branched of material may have a form.

[48]

In another embodiment, the beginning basin polymer as a material of, as shown in 3 also, core (30) and said structural units the beginning basin coupled to core (31) 3 a can be polymer situ formation of reinforcing members in and including one or more. One for example, structural units the beginning basin (31) is 0.2 to 3.2mm2 and the one or the number of 4 3. Plurality of the beginning basin structural units (31) branch hyperlinks has can be a structural units, may be unit dendrimer structure. the beginning basin plurality of in addition structural units (31) but may be different from the user each other, symmetrically structure in terms of. groups may be the same.

[49]

In another embodiment the beginning basin polymer as a material of, as shown in 4 also, core (40) and said structural units the beginning basin coupled to core (41) includes, said core (40) form linear polymer polymerised in the linear polymer can be.

[50]

the beginning basin of core or focus structure (10, 30, 40) email widow, a web page or any number of branched disclosure point (10a, 30a) of the clip base and the cover, branched disclosure point (10a, 30a) subsequent the beginning basin structural units (31, 41) a mean structure of portion external grudge number.

[51]

Core or focus the group polyfunctional constituting a structure, (1) 1 to 20 carbon atoms as, O, NH, N (CH3), S, SO2is heteroatom such as a nonfunctional monomer which can be substituted or hydroxyl, carboxyl group, or an acyl group fluorine atom, chlorine atom, bromine atoms, iodine atoms of a halogen, such substituted 1015 per square meter, (2) 5 arylene groups of 6 to 20 carbon atoms, (3) an elongated coupled [...][...] such alkyl, (4) said (1) to (3) of each of carbon atoms including a gel composition consisting of polyhydric are disengaged to atomic hydrogen which combines the of, (5) multivalent hetero ventilation, (6) multivalent hetero placed between the heat exchange element and said (1) to (4) bind hydrogen giga hydrocarbons can be mentionned groups.

[52]

In one embodiment core structures include for cyclodextrin derivatives including an arylalkyl group. Triphenylphosphate which is marked as a chemical for cyclodextrin said formula 1 of alpha-CD, β-CD, or Γ-CD includes.

[53]

[Formula 1]

[54]

[55]

For example, cyclodextrin itself it difficult for contaminants to take on the role of an disclosure number polymerization, is spread on a application in halogen element a group of hydroxy for cyclodextrin, for example bromine for cyclodextrin substituted nuclear reactor, use can be made of, derivatives. The present specification in said hydroxyl groups in at the derivatives of cyclodextrin substituted "nX-β-CD" corresponding advertisement based on the shown list designated, the substituted N in said may indicate the number of hydroxyl groups in at, the X exhibits elemental halogen.

[56]

the beginning basinthe beginning basin used in the present invention of structural units, i.e. may be aromatic [...], may be is aliphatic. One for example the beginning basin structural units derived from an acrylate monomer can be.

[57]

An alkyl acrylate monomer (metadata) acrylate include, for example, 1 to 40 carbon atoms alkyl, alkyl 1 to 30 carbon atoms, 1 to 20 carbon atoms alkyl, alkyl 1 to 10 carbon atoms, 1 to 5 carbon atoms alkyl, alkyl 1 to 4 carbon atoms, 1 to 3 carbon atoms 1 to 2 carbon atoms alkyl or alkyl (metadata), use can be made of, acrylate. For example, said alkyl (metadata) acrylate content of monomer mixture included to either a full-monomer 50 to 97 parts by weight 100 reference parts by weight, 60 to 95 parts by weight, 65 to 90 parts by weight, 50 to 80 parts by weight, 50 to 75 parts by weight, 50 to 70 parts by weight, 55 to 80 parts by weight, 60 to 80 parts by weight, 55 to 75 parts by weight or 60 to 70 part by weight can be.

[58]

One in an example acrylic polymer for polymerization of a monomer with functional groups bulky the monomer mixture may further comprise the KIPO &. Bulky with functional groups a monomer formed from a monomer mix including hydrodynamic linear polymers to increase a volume (hydrodynamic volume), having a lower melt viscosity can be under public affairs number 2 number resin.

[59]

One in an example bulky with functional groups can be a alkyl (metadata) acrylate can be. the monomer mixture, for example, the aforementioned acrylic polymer main electrode is disposed units forming a alkyl (metadata) acrylate; and bulky alkyl including 2 (metadata) acrylate having at least one alkyl (metadata) may comprise an acrylate. Having bulky alkyl (metadata) acrylate include, for example, 3 to 20 carbon atoms, 3 to 12 carbon atoms, 3 to 6 carbon atoms, 5 to 20 carbon atoms, 7 to 20 carbon atoms, 12 to 20 to 10 carbon atoms of carbon number 20 alkyl (metadata) acrylate; of carbon number 40 to 5, 5 to 25 carbon atoms, 5 to 16 carbon atoms, 6 to 40 carbon atoms, 10 to 40 carbon atoms, 12 to 40 carbon atoms of carbon number 16 to 40 of cycloaliphatic (metadata) acrylate (alicyclic (meth) acrylate) as to the aromatic hydrocarbon KIPO &. Specifically, 3 to 20 carbon atoms said alkyl (metadata) acrylate include, for example, idle small pro it will bloom (metadata) acrylate, small butyl idle (metadata) acrylate, it shakes off, the butyl (metadata) acrylate or 2 - ethylhexyl (metadata) acrylate as to the aromatic hydrocarbon and, said 5 to 40 carbon atoms of cycloaliphatic (metadata) acrylate include, for example, cyclohexyl (metadata) acrylate or idle neel cow step (isobornyl) (metadata) acrylate as to the aromatic hydrocarbon KIPO &.

[60]

Having such bulky alkyl (metadata) acrylate content of number 2 plastic fusion viscosity and, according to its intended use may properly number [...]. For example, bulky alkyl (metadata) acrylate content of having, monomer mixture included to either a full-monomer 3 to 50 parts by weight 100 reference parts by weight, 10 to 40 parts by weight, 15 to 40 parts by weight, 20 to 40 parts by weight, 10 to 30 parts by weight 10 to 35 parts by weight, 15 to 35 parts by weight or 20 to 30 parts by weight may be adjusted to a..

[61]

Other in an example bulky with functional groups a monomer include aromatic (metadata) acrylate (aromatic (meth) acrylate) that is capable of using optical. Aromatic (metadata) acrylate include, for example, 6 to 40 carbon atoms, 6 to 25 carbon atoms of carbon number 16 to 6 aromatic (metadata) acrylate as to the aromatic hydrocarbon KIPO &. Specifically, aromatic 40 to 6 carbon atoms (metadata) acrylate include, for example, naphthyl (naphthyl) (metadata) acrylate, phenyl (phenyl) (metadata) acrylate, do not sprout three Neel (anthracenyl) (metadata) acrylate or benzyl (metadata) (benzyl), use can be made of, acrylic, and the like.

[62]

Such aromatic (metadata) acrylate content of having also the aforementioned bulky alkyl (metadata) acrylate and such as use of resin number 2 may [...] number according to the purpose. For example, aromatic (metadata) acrylate content of, monomer mixture included to either a full-monomer 3 to 50 parts by weight 100 reference parts by weight, 10 to 40 parts by weight, 15 to 40 parts by weight, 20 to 40 parts by weight, 10 to 30 parts by weight 10 to 35 parts by weight, 15 to 35 parts by weight or 20 to 30 parts by weight may be adjusted to a..

[63]

One in an example the beginning basin structural units 1 to 4 linear alkyl carbon atoms having alkyl (meth) acrylate; and

[64]

3 to 20 carbon atoms having alkyl alkyl (meth) acrylate, 5 to 40 carbon atoms of cycloaliphatic (Alicyclic) a relief Image using rings (meth) acrylate, and 6 to 40 aromatic rings (aromatic) an aryl (meth) acrylate to selected from the group consisting of one or more organic (meth) acrylate can be derived from mixture of solvent monomers including..

[65]

The above-mentioned the beginning basin general type of polymer the manufacturing method is publicly known art, for example, thesis (Prog. Polym. Sci. 29 (2004) 183 - 275) to look up an KIPO & or the like.

[66]

In one example core cyclodextrin and, structural units derived from an acrylate monomer the beginning basin a hydroxy group cyclodextrin in the case of resin number 2 some or all of the halogen element has a compound having a a structure a conductive layer is used as the disclosure number, said halogen end atom migration radical polymerization (ATRP: Atom transfer radical polymerization) by growing chain using can be under trillion number. Atom migration radical polymerization is also publicly known art, is to encapsulate the typical is a, for example thesis (Macromolecules, 2012, 45 (10), pp 4015 - 4039) can be reference to.

[67]

Resins in one exemplary reference parts by weight 100 resin number 1 mixture 0. 1 to 50 parts by weight of resin number 2 may comprise an. In addition, another exemplary reference parts by weight 100 resin number 1 resins in mixture 1 to 30 parts by weight, 1 to 20 parts by weight or 1 to 15 parts by weight may comprise an. Such content when number 1 number 2 resin and including resin, a relatively expensive contrast resin number 1 number 2 resin content to mirror by the number number the resin mixture, the number can be under public affairs.

[68]

The above-mentioned resin mixture at the pelletizing by extrusion may be bath number. Said resin having high viscosity by using mixture of resin and number 1 pellets are prepared by the method number may comprise an resin number 2.

[69]

One embodiment, pellets are number 1 resin; and said [...] with a mark represented by general formula 1 - α (/ export houwink) of constant 0 value. 1 to 0. 5 in number 2 number. under public affairs pellets including resin.

[70]

Kind of resin number 2 resin and said number 1 the present invention relates to a and physical 25mbps and aforementioned specifically have, specifically dispensed to the content.

[71]

While, the above-mentioned resin mixture is a melt processing or pellet under public affairs number can be resin molded article.

[72]

One embodiment, to melt the resin mixture to form a molten mixture (melt blend); and said molten blend including work to a number of method bath number of resin moldings. under public affairs.

[73]

As described above, since the polymer the beginning basin resin said number 2 degree lower melting melting resin composition of portion of the sacrificial layer is patterned excellent photoresist pattern is formed can be workability has been.

[74]

Melt processing the resin mixture, the step be yield under shear stress. For example melt processing the step extrusion and/or injection processing method can be performed by.

[75]

In addition, melt processing the resin mixture, used at a stage in which number 1 number 2 resin and is applied along the of the type of resin in which temperature can be different. For example, and of satisfactory anti-production of styrene resin number 1, number 2 the event of the use of a acrylic resin resin melt processing temperatures to about 210 to 270 °C may be the number.

[76]

Method bath number of resin moldings melting of a mixture in said resin contains the thus-obtained, i.e. molten resin composition of said curing the workpiece may further include any. Said hardening of the for example, thermosetting or UV curing can be. In addition, said resin moldings the chemical or physical treatment can be further.

[77]

One in an example of resin moldings the method bath number said resin mixture to melt the molten blend prior to forming the further bath number number 2 resin may include. Number 2 resin superior processability and on resin moldings, so that the semiconductor, for example, . is capable of imparting the high hardness. Their use in the associated tub number number 2 resin 360degree specifically that described above the dispensed content.

[78]

Embodiment other, number of resin moldings to melt the pellet method bath molten form a mixture; and said work to a molten blend may comprise an.

[79]

One in an example the above pellets melt processing extruding the resin mixture, through it is possible, KIPO & under trillion number. Thus melted injection pellets are prepared by the method number by number are resin molded parts may be bath. However, and not limited to, other in an example said direct resin mixture, injection such as melt processing by number are resin molded parts. may be bath.

[80]

While, embodiment of the other of, resin molded product comprises number 1 and number 2 may comprise resin, said resin said number 2 with a mark represented by general formula 1 - α constant of [...] (/ export houwink) 0 value. 1 to 0. 5 polymer may comprise an.

[81]

Said number 1 which determining a property of an object of molded articles of resin, the molding said number 2 timer in processibility and mechanical properties given to dispersants which are able to, said number 1 number 2 resin and the second time control resin 25mbps and the proximal end communicates content, associated dispensed to a description of content.

[82]

One in an example, said resin molded product comprises automobile parts, helmet, electric machinery parts capable of decreasing setting time, spinning machine parts, toys, such as can be used to the ball number.

[83]

The present application for assisting in the removal of the resin mixture improved mechanical properties in the second and surface hardness and molds for molding resins which having good workability which can be under public affairs number article.

[84]

the beginning basin Figure 1. concerns a one example of structure. Figure 2 in another example of a structure the beginning basin concerns a.. One example of polymer structure and the beginning basin Figure 3 concerns a.. In another example of a polymer structure and the beginning basin Figure 4 concerns a..

[85]

Hereinafter in the embodiment and comparison to said detail the resin mixture but described, said resin composition of it became at the time of number a range number in the embodiment by one are not.

[86]

Hereinafter in the embodiment and comparison in the same physical property as the corresponding advertisement based on the shown list evaluation of the following manner, to operate close to the loop frequency characteristics evaluation showed to table 1.

[87]

1. Absolute molecular weight and/export houwink parametric measurement

[88]

In the embodiment and comparison obtained in and molecular weight and absolute resin number 2/export houwink parameter α value using Viscotek yarn it was determined that the TDA302 number.

[89]

Specifically, in the embodiment and comparison in each specimen or the resultant resin (tetrahydrofuran) 0 to for ease of application. 1 weight % to syringe filter solution senses a rotation velocity of the disk (0. 02 micro m) after triggers foreign particles from the object by passing through at least one number, 100 micro l is charged into the measured was carried out to. [...] which agent composed of solvent using, 40 °C, 0. Jordi DVB mixed bed column by passing in speed of 8 ml/min measuring was carried out to.

[90]

2. Measuring of melt viscosity of

[91]

Capillary rheometer using (Capillary Rheometer 1501, Gottfert yarn), it was determined that melt viscosity.

[92]

Specifically, capillary die (Capillary die) (Barrel) then, the decoding equipment to a barrel, in the embodiment or comparative in the resultant resin a was divided turn fills 3. And, to 100 in processing temperature at which processing 220 °C1000 s-1a shear rate of (shear rate) according to shear viscosity (shear viscosity, pa * s) long since determined the.

[93]

3. Melt flow index measuring

[94]

In the embodiment and comparison in ASTM D1238 based on the number of pellets extrusion prepared by the method a (pellet) (Melt flow index) [...] TOYOSEIKI MELT INDEXER yarn was by using f-B01.

[95]

Specifically, in the embodiment and comparison e.g. obtained at the extrusion a capillary heated to 220 °C pellets (Capillary) after is filled, of 10 kg was state that a bending load is applied. Constant 1 from that point the supernatant may be processed to recover the test piece through the capillary minutes after measuring the weight is computation melt through a was terms of index-flow. Each specimen out for at times was detects and measuring 5.

[96]

4. Strength for measuring

[97]

ASTM D256 in the embodiment and comparison based on the strength of the test piece obtained in it was determined that. Specifically, pendulum end which rest on the immobile shaped groove V delivered to the head-end for weight (Notch) the test piece the gripper (kg * cm/cm) the energy necessary, thus destroying the hair an impact tester (Impact 104, Tinius Olsen yarn) it was determined that using. 1/8 "1/4 and" measuring times out for at specimen 5 was detects and

[98]

5. Pencil hardness for measuring

[99]

Pencil durometer (chung Buk deck) using 500g load constant by means of the heating in the embodiment and comparison under surface of the test piece obtained in it was determined that pencil hardness. 9H to 6B a standard pencil (mitsubishi yarn) the center portion of the metal mixture, Ni-containing alloy at an angle of 45 applies a scratch surface has been observed on the rate of change of (ASTM 3363 - 74). The result of the measurements is average value of experiments 5 iterations.

[100]

Number - memorablenumber 2 resin number bath

[101]

Memorable number 1

[102]

Atom migration radical polymerization (atom transfer radical polymerization) copper chloride catalyst (I) 1 (copper (I) chloride, CuCl). 47g and hinders nitrogen are input, in 5 liters reactor for forming a by substituting a toluene as the solvent (toluene) (methyl methacrylate) methyl methacrylate and 1800g 1200g, ligands pen hit methyl D ethylene tree amine (N, N, N', N ", N" - pentamethyldiethylenetriamine) 2. 58g of oxygen have a water the triggers number, 80 °C 400 rpm is set in agitating while mixed in 30 minutes. Oxygen is blocked in disclosure number radical polymerization atom migration at conditions to produce 21Br-β-CD 23. 96g is closed after charging for the treatment of the solid type, 80 °C in the polymerized during time 2. Said polymeric product by a 30 °C by an exposure to oxygen, for vertically long number catalyst for after alumina column (alumina column), the hexane (hexane) 3 times washing and drying in an oven to a number 2 resin was under trillion number.

[103]

Memorable number 2

[104]

Methyl methacrylate monomer 1620g and cyclohexyl methacrylate (cyclohexyl methacrylate) for 180g and under the outside number used in the range of a, memorable number 1 number 2 in the same method was under trillion number resin.

[105]

Memorable number 3

[106]

3L distilled reactor of polyvinyl alcohol in number and dispersion 1500g 4g was and dissolving are input, in 2% aqueous solution. Methyl methacrylate 800g and said reactor, use of Saccharomyces cerevisiae [...] n - 2 in number mobile chain. 4g and 2 valeronitriles dimethyl bis azo in disclosure number. 4g further have a water, 400 rpm is set in agitating while mixed. 60 °C in said mixture and polymerizing in age reacted time 3, number 2 in the form of the bead cooled to 30 °C obtained resin. Then 3 times said number 2 resin and dehydrating after the then being washed with distilled water, was very dry in an oven to a.

[107]

In the embodiment 1

[108]

Number 1 resin (methyl [...] 60 parts by weight, acrylonitrile 7 parts by weight, butadiene 10 parts by weight and styrene thermoplastic resin part transmits the next command weight 23) number in 90 parts by weight of a memorable said number 1 number 2 under trillion after mixing 10 parts by weight of resin, in twin screw extruder (Leistritz yarn) pellets by extruding to a temperature of 240 °C (pellet) is obtained. And, such pellets in EC100 Φ 30 injection machine (ENGEL yarn), injected to a temperature of 240 °C number was under trillion specimen resin moldings.

[109]

In the embodiment 2

[110]

Obtained in a memorable said number 2 10 parts by weight of resin number 2, in the embodiment 1 the same used in 90 parts by weight resin number 1 to number and under the outside, mixed with an a, the same method in the embodiment 1 was under trillion specimen in number.

[111]

Comparedexample 1

[112]

Resin pellet number 1 in the embodiment 1 in 100 parts by weight of a dry, in an oven to a, EC100 Φ 30 injection machine (ENGEL yarn), injected to a temperature of 240 °C in specimen resin moldings adaptation small number.

[113]

[114]

Comparedexample 2

[115]

Number 1 resin (methyl [...] 60 parts by weight, acrylonitrile 7 parts by weight, butadiene 10 parts by weight and styrene thermoplastic resin part transmits the next command weight 23) in 90 parts by weight of a memorable said number number 2 number 3 under trillion after mixing 10 parts by weight of resin, in twin screw extruder (Leistritz yarn) pellets by extruding to a temperature of 240 °C (pellet) is obtained. And, such pellets in EC100 Φ 30 injection machine (ENGEL yarn), injected to a temperature of 240 °C number was under trillion specimen resin moldings.

[116]

In the embodiment 1In the embodiment 2Compared example 1Compared example 2
Number 1 resinNumber 1 resinXG 568XG 568XG 568XG 568
Also melting point (pa * s)370370370370
Number 2 resinNumber 2 resinMemorable number 1Memorable number 2-Memorable number 3
Also melting point (pa * s)160140-1330
Absolute molecular weight (kg/mol)102K115K-108K
Molecular weight distribution1. 21. 2-2
Α value0. 2230. 287-0. 684
Melt flow index (g/10min)24. 126. 11817
Pencil strengthH2HFH
Strength measurement1/8 "5. 48. 8105. 2
1/4 "5. 39104. 9

[117]

/Export houwink parameters of said in the embodiment α is synthesized polymer situ formation of reinforcing members in and through a subscriber of confirming corresponding advertisement based on the shown list, said in the embodiment according to impact hardness pencil molded product comprises resin prepared by the method number and reduction in strength without melt flow for the coating layer has an index capable of confirming the..



[118]

The present invention relates to a resin composite, a pallet, a method for manufacturing a resin molded article, and the resin molded article. According to an embodiment of the present invention, provided is a resin composite comprising: a first resin; and a second resin in which a constant value α of Mark-Houwink formula represented by normal formula 1 is 0.1 to 0.5. The resin composite of the present invention has improved mechanical properties and surface hardness, and excellent processability.



Number 1 resin; and [...] with a mark represented by general formula 1 - α (/ export houwink) of constant 0 value. 1 to 0. 5 in number 2 includes resin, said number 2 resin the beginning basin molecular and, said said core a core and a polymer the beginning basinthe beginning basin coupled to one or more structural units including situ formation of reinforcing members in and polymer resin mixture 3: [general formula1][ η]=KMαsaidin general formula, the η fiber, wherein the optical fiber exhibits intrinsic viscosity of resin number 2, number 2 the M exhibits a weight average molecular weight of resin, K and the number 2 resin α when dissolved [...] at the 40 °C applied is constant.

According to Claim 1, number 1 - 1 producing resin, polyolefin resin, thermoplastic elastomer, poly [...] resin, polyester resin, polyvinyl chloride resin, polycarbonate resin, poly [...] resin, vinyl a polyalcohol resin, polyamide resin, acrylate resin, engineering plastic, copolymers thereof, resin mixture, or the mixture thereof.

Number ablation

According to Claim 1, 2 and connected to a polymer the beginning basin general formula 3 mixture resin building of: [general formula 2] 0. 01 VL=VH=0. 07 VL [general formula 3] 0. 9 WH=WL=1. 1 WHsaidin general formula 2 and 3, VHthe 220 °C and1000 s-1unit moves simultaneously at the same distance and exhibits the melting point of the polymer the beginning basin, VLthe 220 °C and1000 s-1the same polymer and the beginning basin said unit moves simultaneously at the same distance as a monomer component, to ensure the melting point of the polymer linear polymerized, WHthe fiber, wherein the optical fiber exhibits a weight average molecular weight of polymer the beginning basin, WLthe linear exhibits a weight average molecular weight of polymer.

Number ablation

According to Claim 1, core for cyclodextrin derivatives and are, structural units the beginning basin resins derived from an acrylate monomer mixture.

According to Claim 1, the beginning basin structural units 1 to 4 linear alkyl carbon atoms having alkyl (meth) acrylate; and alkyl having 2 to 20 alkyl (meth) acrylate, 5 to 40 carbon atoms of cycloaliphatic (Alicyclic) a relief Image using rings (meth) acrylate, and 6 to 40 aromatic rings (aromatic) an aryl (meth) acrylate to one or more selected from the group consisting of organic (meth) acrylate resins derived from mixture of solvent monomers including mixture.

According to Claim 7, mixture of solvent monomers alkyl (meth) acrylate 60 to 95 parts by weight; and organic (meth) acrylate resin mixture including 5 to 40 parts by weight of.

According to Claim 1, reference number 1 resin 100 parts by weight 0. 1 to 50 parts by weight of resin mixture including resin number 2.

Number 1 resin; and [...] with a mark represented by general formula 1 - α (/ export houwink) of constant 0 value. 1 to 0. 5 in number 2 includes resin, said number 2 resin the beginning basin molecular and, a core and a polymer the beginning basin said core coupled to said one or more structural units the beginning basin 3 pellets polymer situ formation of reinforcing members in and including: [general formula1][ η]=KMαsaidin general formula, the η fiber, wherein the optical fiber exhibits intrinsic viscosity of resin number 2, number 2 the M exhibits a weight average molecular weight of resin, K and the number 2 resin α when dissolved [...] at the 40 °C applied is constant.

According to Claim 1 the resin mixture, that the melt form a mixture; and said molten blend including work to a method bath number of resin moldings.

According to Claim 11, melting and work to a working under a shearing stress number of resin moldings method bath.

According to Claim 11, after said melt and treating a further including curing the method bath number of resin moldings.

According to Claim 13, hardening of the thermally cured or UV cured a method bath number of resin moldings.

According to Claim 10 to melt the pellets melt form a mixture; and said molten blend including work to a method bath number of resin moldings.

Number 1 number 2 resin and includes resin, said number 2 connected to a resin with a mark - 1 represented by (/ export houwink) [...] α constant of 0 value. 1 to 0. 5 in the beginning basin molecular and, a core and a polymer the beginning basin said core coupled to said one or more structural units the beginning basin 3 are resin molded parts polymer situ formation of reinforcing members in and including: [general formula1][ η]=KMαsaidin general formula, the η fiber, wherein the optical fiber exhibits intrinsic viscosity of resin number 2, number 2 the M exhibits a weight average molecular weight of resin, K and the number 2 resin α when dissolved [...] at the 40 °C applied is constant.