NOVEL COMPOUND, BLUE RESIN COMPOSITION FOR COLOR FILTER INCLUDING SAME, AND COLOR FILTER USING SAME
The present invention refers to solubility in weather resistance improved novel compounds, including the same blue resin composition and color filter for color filter using the same are disclosed. In order to render a color liquid crystal display device from the internal of the color filter, a plurality of color on a substrate, typically, the (R), rust (G), blue (B) pixel 3 of 10R are formed repeatedly assembled unit pixel structure. Such a color filter method number bath to a thermostable, light resistance, excellent chemical resistance using pigment pigment dispersion method is used to come. However, when the pigment dispersion by, in case of scattering pigment agglomeration is generated due to a color filter having high luminance and high resolution implementation of door number difficult to flow tides. Furthermore, repeat the process of destroying the teller for pigment dispersion during an electric generating more than diameter number of eco-friendly occurring in color filter number dielectric to tame. , the center without agglomeration of the pigment dispersion of light occurs, ink jet dyeing or by applying an electric without by a simple process of various sizes based on dye color filter number [...] permits the number of color filter process for preparing etc.. However, the dye pigment relative to color filter high intensity, in order to achieve high resolution and preventing constipation cancerous rain essential characteristic thermal stability, light resistance, chemical resistance such as ill, etc. is used to implement the method for dyeing a color filler door number. For the end of the method, one of ongoing studies of cationic dye dye reel methane orgin triazoles are disclosed. At a wavelength of 420 nm to 450 nm such triazole reel methane orgin the dye that is superior in light high transmittance, brightness and contrast ratio improvement in efficient color filter. However, blue for coloring composition for color filter employed primarily monomethyl ether acetate (PGMEA) solvent propylene glycol, propylene glycol monomethyl ether (PGME) with respect to the solubility is low, not foaming a commercial applications of electromagnetic wave disclosed. The victims of the present invention effort results for example, reel methane orgin [...] dimer (dimer) form as triazole compounds synthesized, synthesized compounds when replacing the anion, improved thermal stability and solubility checks the possible number of oxide, the arrears of work the present invention. The present invention refers to novel compounds for improved thermal stability and solubility [...] number are disclosed. In addition, the present invention refers to said compound including blue resin composition for color filter for [...] number are disclosed. In addition, the present invention refers to said blue resin composition for a color filter for color filter [...] number are disclosed. In order to solve said a number and, for the present invention refers to compounds represented by formula 1 number [...] substrate: [Formula 1] In said formula 1, A1 And A2 Benzene or naphthalene ring and independently, N is 0, 1, or 2 and, R1 To R8 Are each independently hydrogen, C1 - 20 Alkyl, C6 - 20 Aryl, or - (CH2 )m - OC (=O) - CH (Q1 ) (Q2 ) And, Wherein, C1 - 20 C alkyl and6 - 20 It will be biting or are each independently a substituted or unsubstituted, or halogen, hydroxy, C1 - 5 C alkyl and1 - 5 One or two selected independently from the group consisting alkoxy substituted 2 substituted 1, M is integer number of 1 to 3, Q1 And Q2 Are each independently a hydrogen or C1 - 10 Alkyl, R11 To R16 Are each independently hydrogen, halogen, hydroxy, C1 - 5 Alkyl, or C1 - 5 Alkoxy and, A1 a2 independently and each integer number of 0 to 6, A3 a6 independently to each integer number of 0 to 4, Halogen X, bis (trifluoromethane) sulfonic acid imide, or triple [...] among others. Represented by said formula 1 compounds, carbon center around two reel methane derivatives 2 the dog as compared with aryl group having 3 connected by ethylene oxide as compared with vertical or horizontal reel methane orgin compounds, nitrogen atoms in the molecule having positive ion salts of 2 2 anion exchange coupled to corresponding to the substrate. The, represented by said formula 1 compounds connector (linker) or to change the number of ethylene oxide acting as a kind of anion, solubility, a transmission can be a leveling agent. Specifically, said A1 And A2 Ring can be identical to one another. In this case, compounds represented by said formula 1 may have the form of a dimer. E.g., said A1 And A2 A ring may be a naphthalene both. In this case, can be advantageous in thermal properties. In said formula 1, n is the number of ethylene oxide in the stream, when n is 0 to 2 of triazole reel methane ethylene derivatives that are connected by a structure. E.g., Wednesday 2 n is 0 or 1. In said formula 1, R1 To R8 Are each independently hydrogen, C1 - 10 Alkyl, C6 - 10 Aryl, or - (CH2 )m - OC (=O) - CH (Q1 ) (Q2 ) May be, and wherein m is 1 or 2, Q1 And Q2 C each independently1 - 5 May be alkyl disclosed. For example, R1 To R8 Are each independently hydrogen, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec - butyl, tert - butyl, or - (CH2 )2 - OC (=O) - CH (Q1 ) (Q2 ) And, wherein, Q1 And Q2 Are each independently a hydrogen, methyl, ethyl, propyl, butyl or can be. The, R1 To R8 Can are identical to each other. The, capable of coupling an intramolecular displacement of substituents thereof can is bound to nitrogen is 4 may all be the same. In said formula 1, R11 To R16 Are each independently hydrogen, halogen, methyl, methoxy or be. For example, R11 To R16 All can be hydrogen. In said formula 1, each substituent R to a6 a111 To R16 Is the number of document containing, for example, are each independently 0, 1 or Wednesday 2 a6 a1 to 2000. In said formula 1, X is chloride, or bis (trifluoromethane) sulfonic acid imide be a. The, use of a bis (trifluoromethane) sulfonic acid imide and thermostable solubility improving side preferably. According to one in the embodiment, represented by said formula 1 - 1 can be represented by: [Formula 1 - 1] In said formula 1 - 1, N and R1 To R8 Defining aforementioned efined. Specific example compounds represented by said formula 1 compounds of formula then is cited: [Formula V] [Formula V-a BTFI] [Formula VIII] [Formula VIII-a BTFI] [Formula IX] [Formula IX-a BTFI] [Formula X] [Formula X-a BTFI] On the other hand, the transmission wavelength range of 420 nm to 540 nm said formula 1 compound can exhibit. The, blue dye compounds can be used as said. In order to make the transmission wavelength of said adjusting the number of ethylene oxide of the first, specifically compound in an increase the number of processors increases fire onto a transmission wavelength range of be. In addition, blue resin composition for color filter represented by said formula 1 compounds [...] solubility solvents (25 °C) 3 (g/100g solvent) is greater than or disclosed. For example, in particular, propylene glycol monomethyl ether acetate (PGMEA) solubility in solvent (25 °C) is 3 (g/100g solvent) or more, specifically 3 to 30 may be (g/100g solvent), the number of color filter by an inkjet process can be easily composed. On the other hand, compounds represented by said formula 1 - 1 example 1 a compound such as method number by bath 1308.: [Compound 1] In said reactive 1, R1 To R4 And X is efined previously defined. the step 1, p - toluene sulfonyl chloride compound represented by said formula 2 compounds represented by said formula 3 as a step number bath so produced, dimers of the glycol compound in toluene for numerical control machine number end p - substituted alcoholic beverage gun neel crossroad are disclosed. Said reaction, can be carried out using a base such as sodium hydroxide at room temperature. Said step is 2, compounds represented by said formula 3 by reacting said formula 4 compound comprises an amine to 1 - naphthylamine in order to step number tank are disclosed. Said graft copolymer at a temperature of about 50 °C to 200 °C can be performed during 3 to 7. the step 3, compound represented by said formula 5 by reacting said formula 4 compound represented by said formula 1 - 1 step number bath compounds are disclosed. The, oxy halide such as phosphorus compound to halogen anion in the form of number can be compound salt is introduced into a high pressure liquid coolant. Said reaction is toluene, methylene chloride in organic solvent such as 1 to 48 can be performed during time. On the other hand, after said step 3, there can be additional sense of honor reaction performed. For example, bis (trifluoromethane) sulfonic acid imide anion exchanging halogen anion of said compound in order, said number in step 3 bis (trifluoromethane) sulfonic acid imide lithium salt can be reacted with compounds produced therewith, said reaction is methanol, ethanol, tert - butanol in alcohol solvent can be performed during time of 1 to 48. In said number tank method A in formula 11 And A2 When the ring is naphthalene only illustratively described but, said reactive structure of formula 1 1 and high pressure liquid coolant be appropriately by replacing number refer to number of compounds which pivotably oxide starting material. On the other hand, the present invention refers to the above-mentioned blue resin composition for color filter dye compounds including number [...] substrate. Said resin composition in addition to the above-described formula 1 compounds of additional dye, binder resin, reactive unsaturated compound, can be disclosure number further includes a polymer and a solvent. Said formula 1 are the novel reel methane orgin dye include use with dye, a xanthene dye generally used a blue resin composition for color filter, aza porphyrin dye, cyanine dye is used as the enabled, limited to are not correct. On the other hand, spring between said binder resin components to improve stability of the composition is used for imparting, if resin used for color filter resin composition generally used without a number pivotably. For example, binder resin cellulose resin, acrylic resin, alkyd resin, melamine resin, epoxy resin, polyvinyl alcohol, polyamide, polyamide - imine, be a or poly amide. In particular, polymerizable monomer a single polymers and copolymers, e.g. styrene, α - methylstyrene, a minute particle, aromatic vinyl compound such as vinyl benzyl methyl ether; methyl (meth) acrylate, ethyl (meth) acrylate, butyl (meth) acrylate, 2 - hydroxyethyl (meth) acrylate, 2 - hydroxy butyl (meth) acrylate, benzyl (meth) acrylate, cyclohexyl (meth) acrylate, unsaturated carboxylic acid ester compound such as phenyl (meth) acrylate; 2 - aminoethyl (meth) acrylate, dimethyl aminoethyl (meth) acrylate such as 2 - unsaturated carboxylic acid aminoalkyl ester compound; vinyl acetate, vinyl iodobenzoic acid such as carboxylic acid vinyl ester compound; unsaturated carboxylic acid glycidyl ester compound such as glycidyl (meth) acrylate; (meth) acrylonitrile cyanation of vinyl compounds such as; or (meth) acrylamide such as unsaturated amide compound such as polymerizable monomer between useful copolymers, in particular acrylic resin is preferably photopolymerization. As an example of the acrylic resin, methacrylic acid/benzyl methacrylate copolymer, methacrylic acid/benzyl methacrylate/styrene copolymers, methacrylic acid/benzyl methacrylate/2 - hydroxy ethyl meta [khu relay [thu copolymer, styrene/2 - hydroxy benzyl methacrylate/methacrylic acid/ethyl meta [khu relay [thu but as to the copolymer, which are not limited to the, alone or in combination with them 2 is used in combination at least one disapproval. Said acrylic resin a weight average molecular weight may be 3,000 to 150,000 g/mol, specifically 5,000 to 50,000 g/mol may be, more specifically implementation being 20,000 to 30,000 g/mol. A weight average molecular weight of said acrylic resin of said range, excellent adhesion to substrate physical, chemical properties are pleasant, can be coated with a suitable viscosity of the composition. Said acrylic resin has an acid value of 15 to 60 mgKOH/g may be, specifically 20 to 50 mgKOH/g implementation being. Acrylic resin has an acid value of constituent esters when said that the resolution of the pixel can be is excellent. Said acrylic resin to the total resin composition for color filter blue0. 1 To 30% by weight can be included, specifically5 To 20% by weight can be included. Color filter if said number tank ultraviolet range has an improved good surface smoothness when developing excellent crosslinked can be achieved. On the other hand, reactive unsaturated compounds are the thermosetting monomer or an oligomer, photocurable monomer or an oligomer, or a combination of these can be. Specifically, photocurable monomer containing one or more double bond within the molecule can be preferred. Said photocurable monomer include, glycerol acrylate, tree [thol it buys in d pen hit arc relay [thu, ethylene glycol d arc relay [thu, tree [...], 1, 4 - butanediol methacrylate, 1, 6 - hexane d the d arc relay [thu which comes, neopentylglycol [...], in pen hit tree [thol d arc relay [thu, [...], pentaerythritol methacrylate, in d pen hit tree [thol tree arc relay [thu, in d pen hit tree [thol arc relay [thu, [...], bisphenol A isobornyl methacrylate, methyl roll propane tree arc relay [thu tree, cresol novolak epoxy acrylate, ethylene glycol dimethacrylate, d ethylene glycol d meta [khu relay [thu, TEG dimethacrylate, propylene glycol dimethacrylate, 1, 4 - butanediol dimethacrylate, 1, 6 - hexane d the d meta [khu relay [thu which comes, or combinations thereof can be used but, limited to are not correct. Said reactive unsaturated compound to the total resin composition for a color filter blue 0. 1 To 30% by weight and be included with the, 5 to 20% by weight can be specifically included. Photopolymerizable monomer range in pattern characteristic of a color filter if said number tank and developing excellent disclosed. On the other hand, disclosure number disclosure number comprises a thermosetting polymer, or a combination of these photopolymerization disclosure number can be. For example, [...] acetoacetoxy-functional compounds, benzophenone-based compound, the [khu it buys ton orgin thio compounds, benzo phosphorus-based compounds, triazine compound, oxime-based compound, or combinations thereof such as primarily photopolymerization disclosure number can be used. Said process for lung rice field orgin compounds include 2, 2 '- to d [thok at the time of oh three toe lung rice field, 2, 2' - d department [thok city oh three toe lung rice field, 2 - hydroxy - 2 - methyl pro bloom the lung rice field, p-a t - butyl with tree claw oh three toe lung rice field, with d claw oh three toe lung rice field p a-t - butyl, 4 - chloro phenylacetophenone, 2, 2' - dichloro - 4 - lung stipend city oh three toe lung rice field, 2 - methyl - 1 - (4 - (methyl thio) phenyl) - 2 - wool pulley roh propane - 1 - one, 2 - dimethylamino - 2 - (4 - methyl - benzyl) - 1 - (4 - morpholin - 4 - yl - phenyl) - butane - 1 - one can be user information. Said benzophenone compound benzophenone, benzoyl iodobenzoic acid, benzoyl iodobenzoic acid methyl, 4 - phenyl benzophenone, hydroxybenzophenone, acrylated benzophenone, 4, 4 '- bis (dimethylamino) benzophenone, 4, 4' - bis (diethylamino) benzophenone, 4, 4 '- dimethylamino benzophenone, 4, 4' - dichloro benzophenone, 3, 3' - dimethyl - 2 - the maul [thok city it cuts trillion lung rice field can be use. Said thio the [khu it buys ton orgin compounds include thio xanthone, mote oak from ton 2 - methyl, isopropyl thio xanthone, 2, 4 - diethyl thio xanthone, 2, 4 - diisopropyl thio xanthone, 2 - chloro mote oak from ton can be use. Said benzo phosphorus-based compounds include the preparation of an, benzo methyl ether, for the preparation of an ethyl ether, isopropyl ether for the preparation of an, for the preparation of an isobutyl ether, benzyl d methyl [khey mask can be use. Triazine compounds include 2, 4, 6 - trichloro said - s - triazine, 2 - phenyl 4, 6 - bis (trichloromethyl) - s - triazine, 2 - (3 ', 4' - [...]) - 4, 6 - bis (trichloromethyl) - s - triazine, 2 - (4 '- the maul [thok it is sour but the [phu) - 4, 6 - bis (trichloromethyl) - s - triazine, 2 - (p - methoxyphenyl) - 4, 6 - bis (trichloromethyl) - s - triazine, 2 - (p - tolyl) - 4, 6 - bis (trichloro methyl) - s - triazine, 2 - biphenyl 4, 6 - bis (trichloro methyl) - s - triazine, bis (trichloromethyl) - 6 - styryl - s - triazine, 2 - (naphtho - 1 - yl) - 4, 6 - bis (trichloromethyl) - s - triazine, 2 - (4 - the maul [thok it is sour but the [phu toe 1 - yl) - 4, 6 - bis (trichloromethyl) - s - triazine, 2 - 4 - trichloromethyl (fipronil piperidinyl) - 6 - triazine, 2 - 4 - trichloromethyl (4' - [...]) - 6 - triazine can be use. Said oxime compound 1, 2 - octane dione, 2 - [4 - (phenylthio) phenyl] - 1 - (o - benzoyl oxime) - 1, 2 - octane dione, 1 - (o - acetyl oxime) - 1 - [9 - ethyl - 6 - (2 - methyl benzoyl) - 9H - carbazole - 3 - yl] ethane on can be use. In addition to the disclosure number of said photopolymerization, cover neck of compound, diketone ton type compounds, sulfonium borate-based compounds, diazo, bead [...] compounds and the like can be also used as photopolymerization disclosure number. Said polymerization disclosure number 0 to the total resin composition for color filter is blue. 1 To 5% by weight and be included with the, 1 to 3% by weight can be specifically included. Polymerization disclosure number is said range if, for pattern forming process is performed sufficiently deep-seated in number jaws color filter layer is preferably fine, transmittance can be improved. On the other hand, special number smooth cannot be said solvent, e.g., methanol, alcohol such as ethanol; dichloro ethyl ether, n - monobutyl ether, dee child wheat ether, methyl phenyl ether, tetra draw [phyu column such as ether; ethylene glycol methyl ether, ethylene glycol ethyl ether, propylene glycol methyl ether such as glycol ethers; it will count with brush [pu methyl acetate, ethyl it will count with brush [pu acetate, diethyl it will count with brush [pu acetate such as it will count with brush [pu acetate current; methyl ethyl carboxylic expense [thol, diethyl expense [thol, diethylene glycol monomethyl ether, diethylene glycol mono ethyl ether, diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether, diethylene glycol such as carboxylic expense [thol type d ethyl ether; propylene glycol monomethyl ether acetate, propylene glycol propyl ether acetate such as propylene glycol alkyl ether acetate current; toluene, O-xylene aromatic hydrocarbons; methyl ethyl ketone, cyclohexanone 1, 4 - hydroxy - 4 - methyl - 2 - pentanone, methyl - n - propyl ketone, methyl - n - butyl [khey rice field, methyl - n - oh wheat ketone, ketones such as 2 - [heyp other rice field; ethyl acetate, acetic acid - n - butyl, isobutyl acetate such as saturated aliphatic monocarboxylic acid alkyl esters; methyl lactate, lactic acid alkyl esters such as ethyl lactate; methyl hydroxy acetate, ethyl hydroxy acetate, butyl hydroxy acetate such as hydroxy acetic acid alkyl esters; methoxymethyl acetate, [...] acetate, maul [thok father-in-law [thil acetate, ethoxymethyl acetate, acetic acid alkoxyalkyl esters such as [...] acetate; methyl 3 - hydroxy propionate, ethyl 3 - hydroxy propionate such as 3 - hydroxypropionic acid alkyl esters; 3 - methyl propionate, ethyl 3 - propionate, ethyl 3 - [...], 3 - alkoxy propionic acid alkyl esters such as methyl 3 - [...]; methyl 2 - hydroxy propionate, ethyl 2 - hydroxy propionate, 2 - hydroxypropionic acid alkyl esters such as 2 - hydroxy propionate profile; 2 - methyl propionate, ethyl 2 - propionate, ethyl 2 - [...], 2 - alkoxy propionic acid alkyl esters such as methyl 2 - [...]; methyl 2 - hydroxy - 2 - methyl propionate, ethyl 2 - hydroxy - 2 - 2 - hydroxy - 2 - methyl propionic acid alkyl esters such as methyl propionate; methyl 2 - methoxy - 2 - methyl propionate, ethyl 2 - ethoxy - 2 - methyl propionic acid alkyl esters such as methyl propionate 2 - alkoxy - 2 -; 2 - hydroxy ethyl propionate, 2 - hydroxy - 2 - methylethyl propionate, hydroxyethyl acetate, methyl 2 - hydroxy - 3 - methyl father hit roh a [thu such as esters; or blood base empty mountain such as ethyl ketone acid esters; N - methyl formamide, N, N - dimethyl formamide, N - methyl leading which will not be a gun roentgen per hour at one meter, N - methylacetamide, N, N - dimethylacetamide, N - methylpyrrolidone, removed with dimethyl sulfoxide, benzyl ethyl ether, d [heyk thread ether, acetamide neel acetone, isophorone, capric acid theory it buys, the acids are capric acid, 1 - octanol, 1 - nonanol, benzyl alcohol, benzyl acetate, ethyl iodobenzoic acid, oxalic acid diethyl, maleic acid diethyl, γ - butyrolactone, ethylene carbonate, propylene carbonate, or the like and it will count with brush [pu phenyl acetate, these can be used alone or in mixed at least one 2. Said solvent compatible and reactive in one aspect, glycol ethers such as ethylene glycol mono ethyl ether; it will count with brush [pu ethyl acetate such as ethylene glycol alkyl ether acetate current; 2 - hydroxyethyl propionate such as esters; diethylene glycol monomethyl ether such as diethylene glycols; propylene glycol monomethyl ether acetate, propylene glycol propyl ether acetate such as propylene glycol alkyl ether acetate for increasing preferably. In addition, blue resin composition for color filter when the spot preventing said specks, leveling properties, or washed with [...] by on to prevent, malonic acid; 3 - amino - 1, 2 - propanediol; vinyl or (meth) acrylic silane coupling aminooxy groups having number; number can be further comprises 100 weight. On the other hand, the present invention refers to a blue resin composition using the above-mentioned color filter prepared by the number number [...] substrate. Such a color filter according to a conventional method number can be high pressure liquid coolant, e.g., said blue resin composition, green resin composition and on red resin composition, inkjet, spin coating, roll coating or the like using a suitable method by using a thick-coated at. Then, in order to produce a desired pattern color filter UV light, electron beam or X and irradiation, treatment of the same alkali developer to manicure company overlaying layer portion dissolved and Image color filter a desired pattern formed therein. These procedures required R, G, it goes to the B according to a number of color, a color filter having the desired pattern can be implementing. The compounds of the present invention, the metathesizable anion in the form of dimers having reel methane orgin triazole compound solubility and excellent thermal stability has a wider transmission wavelength is, chemical resistance and heat resistance can be [...] number use blue color filter resin composition characterized disclosed. Figure 1 shows a also, in the embodiment 1, 3, 5 and 7 and comparison light embodiments of compounds components are disclosed. Hereinafter, preferred embodiment of the present invention to aid in understanding a number etched. In the embodiment of the present invention is to more easily understand for however number being ball only, in the embodiment of the present invention content is restricted to by are not correct. In the embodiment for compounds prepared by the number analysis in conducting as follows: nuclear magnetic resonance (NMR) spectral analysis can performed using Bruker Avance 300 spectrometer (Bruker yarn number bath) a transparent conductive layer, the chemical mobile (chemical shift) was analyzed the ppm. In addition, MALDI-a TOF using Bruker Autoflex Speed TOF/TOF (Bruker yarn number bath) using molecular weight measurement is conducting. In addition, the starting material for the compounds of the [tu reach which it will know the seller from publicly known in the embodiment each sigma as excellent, as well as without positive number. In the embodiment 1: Represented by the following formula V number bath (Step 1 - 1) Bis (4 - (bis (2 - hydroxyethyl) amino)Phenyl)Meta discussion Number bath 4, 4' - Die [phul base oro it cuts trillion lung rice field 5 g (22. 9 Mmol) ethanolamine die 33. 72 G (320. 8 Mmol) stirring after adding heated above 170 °C-gate. D ethyl ether and water recycling system by adding, to a table number 6 compound represented by said formula I after reduced pressure drying [...] positive number. 22 G (16. 03 Mmol) by Congress. 1 H NMR (300 MHz, CD3 OD): 7. 63 (D, 4H), 6. 81 (D, 4H), 3. 76 (T, 8H), 3. 64 (T, 8H) 13 C NMR (75 MHz, CD3 OD): 196. 53, 152. 83, 133. 54, 126. 72, 111. 82, 60. 18, 54. 76 (Step 1 - 2) ((Carbonyl bis (4, 1 - phenylene)) bis (aza they will be four trees)) tetrakis (toFrom an - 2, 1 - diyl-) Tetrakis (2 - ethyl [...]) of Number bath A compound having a formula I 5 g 1 - 1 step number in said high pressure liquid coolant (12. 87 Mmol) in 300 ml of methane to biocatalytic, [heyk it buys the claw which will be roh the id ethyl 2 - 12. 56 G (77. 22 Mmol) triethylamine and 2. 93 G (28. 96 Mmol) stirring by adding heated above 60 °C-gate. After reaction, cooling is performed at room temperature after adding the degassed water layer separated concentrated formula II compounds represented by positive number obtained is performed by a table number compound 6. 2 G (6. 95 Mmol) by Congress. 1 H NMR (300 MHz, CDCl3 ): 7. 74 (D, 4H), 6. 82 (D, 4H), 4. 30 (T, 8H), 3. 72 (T, 8H), 2. 28 (M, 4H), 1. 24 - 1. 55 (M, 32H), 0. 87 (T, 24H) 13 C NMR (75 MHz, CDCl3 ): 193. 68, 176. 43, 150. 27, 132. 56, 127. 19, 110. 87, 60. 93, 49. 62, 47. 52, 31. 80, 29. 74, 25. 49, 22. 73, 14. 06, 11. 95 (Step 1 - 3) ethylene Di (p - toluene sulfonate) of Number bath Ethylene glycol 5 g (80. 55 Mmol) and 4 - toluene sulfonyl chloride 33. 78 G (177. 21 Mmol) reconstituted with 100 ml tetrahydrofuran mixable and agitating a-gate. Then, sodium hydroxide 11. 27 G (281. 93 Mol) stirring at room temperature for 1 to 3 adding at least water-gate. After reaction, d ethyl ether and water filled layer is performed by table number compound represented by formula III cream after separation positive number 26. 85 G (72. 49 Mmol) by Congress. 1 H NMR (300 MHz, CDCl3 ): 7. 72 (D, 4H), 7. 35 (D, 4H), 4. 18 (S, 4H), 2. 45 (S, 6H) 13 C NMR (75 MHz, CDCl3 ): 145. 41, 132. 49, 130. 10, 128. 10, 66. 82, 21. 80 (Step 1 - 4) N1,N2-Di (naphthalene - 1 - yl) ethylenediamine Number bath A compound having a high pressure liquid coolant in said step number 1 - 3 formula III 5 g (13. 49 Mmol), 1 - naphthylamine 6. 76 G (47. 24 Mmol) water melting agent and calcium carbonate 3. 57 G (33. 74 Mmol) stirring-gate. Dichloro methane obtained after separation agents and reaction end filled layer after positive number table number 1 represented by formula IV compound to dry organic layer. 68 G (5. 39 Mmol) by Congress. 1 H NMR (300 MHz, CDCl3 ): 7. 79 (D, 4H), 7. 32 - 7. 44 (M, 8H), 6. 77 (D, 2H), 4. 67 (S, 2H), 3. 74 (S, 4H) 13 C NMR (75 MHz, CDCl3 ): 143. 35, 134. 47, 128. 84, 126. 66, 126. 01, 125. 10, 123. 86, 120. 06, 118. 28, 105. 01, 43. 64 (Step 1 - 5) represented by the following formula V number bath A compound having a formula II high pressure liquid coolant in said step 1 - 2 number 30. 02 G (33. 61 Mmol) followed by addition of stirring is toluene 100 ml-gate. Then, oxychloride 24. 54 G (160. 04 Mmol) stirring 1 to add time-gate. Then, a compound having a formula IV number in said step 1 - 4 high pressure liquid coolant 5 g (16. 00 Mmol) after adding, with respect to the reflux. After reaction, cooling is performed at room temperature after adding the water, stir-gate. After separation layer, a compound represented by formula V obtained cream have a positive number table number compound 9. 02 G (4. 37 Mmol) by Congress. 1 H NMR (300 MHz, CDCl3 ): 10. 82 (S, 2H), 8. 99 (D, 2H), 6. 86 - 7. 69 (M, 26H), 4. 34 (T, 20H), 3. 78 (T, 16H), 2. 29 (M, 8H), 1. 25 - 1. 60 (M, 64H), 0. 87 (T, 48H) 13 C NMR (75 MHz, CD3 OD): 177. 39, 176. 92, 155. 78, 155. 54, 145. 51, 140. 16, 137. 62, 130. 29, 129. 60, 128. 71, 127. 33, 127. 04, 124. 51, 124. 07, 114. 23, 106. 93, 62. 10, 50. 73, 48. 43, 32. 78, 30. 74, 26. 43, 23. 66, 14. 45, 12. 30 2050 [M MS (MALDI-a TOF)+ ] In the embodiment 2: Formula V -BTFI Compound number of bath Number 1 in a formula V compound having a high pressure liquid coolant said in the embodiment 1. 00 G (0. 48 Mmol) to methanol 50 ml applied after dissolving, lithium bis (trifluoromethane) sulfonic acid imide (Li provided BTFI) 0. 28 G (1. 00 Mmol) was replaced by the addition of a salt. After reaction, after a table number compounds represented by formula V-a BTFI filled cream or water recycling system 1. 00 G (0. 48 Mmol) by Congress. 1 H NMR (300 MHz, CDCl3 ): 9. 41 (S, 2H), 8. 99 (D, 2H), 6. 86 - 7. 69 (M, 26H), 4. 34 (T, 20H), 3. 78 (T, 16H), 2. 29 (M, 8H), 1. 25 - 1. 60 (M, 64H), 0. 87 (T, 48H) 13 C NMR (75 MHz, CD3 OD): 177. 39, 176. 92, 155. 78, 155. 54, 145. 51, 140. 16, 137. 62, 130. 29, 129. 60, 128. 71, 127. 33, 127. 04, 124. 51, 124. 07, 114. 23, 106. 93, 62. 10, 50. 73, 48. 43, 32. 78, 30. 74, 26. 43, 23. 66, 14. 45, 12. 30 2050 [M MS (MALDI-a TOF)+ ] In the embodiment 3: Represented by the following formula VIII number bath (Step 3 - 1) Ethylene Glycol Di (p - toluene sulfonate) of Number bath TEG 5 g (33. 3 Mmol) and 4 - toluene sulfonyl chloride 13. 96 G (73. 2 Mmol) reconstituted with 100 ml tetrahydrofuran mixable and agitating a-gate. Then, sodium hydroxide 4. 66 G (116. 5 Mmol) stirring at room temperature for 1 to 3 adding at least water-gate. After reaction, d ethyl ether and water filled layer is performed after separation by positive number table 13 compounds represented by formula VI cream number. 74 G (29. 97 Mmol) by Congress. 1 H NMR (300 MHz, (CD3 )2 SO): 8. 27 (D, 4H), 7. 94 (D, 4H), 4. 61 (T, 4H), 4. 10 (T, 4H), 3. 91 (S, 4H), 2. 90 (S, 6H) 13 C NMR (75 MHz, CDCl3 ): 144. 91, 132. 91, 129. 88, 127. 91, 70. 62, 69. 28, 68. 68, 21. 61 (Step 3 - 2) N, N' -(( (Oxy) ethane - 1, 2 - [...]) bis (1 - 2, 1 - diyl-)) bis (me [phuMask [leyn - 1 - amine) number of bath A compound having a high pressure liquid coolant in said step 3 - 1 formula VI number 5 g (10. 90 Mmol), 1 - naphthylamine 5. 46 G (38. 16 Mmol) water melting agent and calcium carbonate 2. 89 G (27. 26 Mmol) stirring-gate. Dichloro methane obtained after separation agents and reaction end filled layer after positive number table number 1 represented by formula VII compounds to dry organic layer. 74 G (4. 36 Mmol) by Congress. 1 H NMR (300 MHz, (CD3 )2 CO): 8. 00 (D, 2H), 7. 77 (D, 2H), 7. 74 (M, 6H), 7. 18 (D, 2H), 6. 62 (D, 2H), 5. 43 (S, 2H), 3. 84 (T, 4H), 3. 71 (S, 4H), 3. 45 (T, 4H) 13 C NMR (75 MHz, CDCl3 ): 143. 58, 134. 41, 128. 65, 126. 62, 125. 81, 124. 79, 123. 81, 120. 15, 117. 70, 104. 64, 70. 30, 69. 50, 43. 69 (Step 3 - 3) represented by the following formula VIII number bath A compound having a formula II high pressure liquid coolant in said in the embodiment 1 number 5 g (5. 59 Mmol) followed by addition of stirring is toluene 100 ml-gate. Then, oxychloride 4. 09 G (26. 65 Mmol) stirring 1 to add time-gate. Then, a formula VII compound having a high pressure liquid coolant in said step 3 - 2 number 1. 06 G (2. 66 Mmol) after adding, with respect to the reflux. After reaction, cooling is performed at room temperature after adding the water, stir-gate. After separation layer, a compound represented by formula VIII obtained cream have a positive number table number compound 2. 48 G (1. 12 Mmol) by Congress. 1 H NMR (300 MHz, (CD3 )2 SO): 8. 73 (S, 2H), 8. 47 (D, 2H), 6. 89 - 7. 45 (M, 26H), 4. 27 (T, 16H), 3. 88 (T, 16H), 3. 76 (T, 4H), 3. 63 (M, 8H), 2. 18 (M, 8H), 1. 13 - 1. 43 (M, 64H), 0. 75 (T, 48H) 13 C NMR (75 MHz, CD3 OD): 178. 13, 177. 55, 156. 19, 155. 02, 145. 06, 140. 43, 137. 89, 130. 38, 129. 75, 128. 68, 127. 40, 127. 35, 124. 59, 123. 30, 114. 35, 106. 10, 71. 63, 70. 21, 62. 21, 50. 65, 48. 50, 44. 62, 32. 83, 30. 78, 26. 46, 23. 69, 14. 43, 12. 28 2150 [M MS (MALDI-a TOF)+ ] In the embodiment 4: Formula VIII -BTFI Compound number of bath A high pressure liquid coolant in said in the embodiment 3 formula VIII compound number 1. 00 G (0. 45 Mmol) to methanol 50 ml is applied to the cyanuric acid, lithium bis (trifluoromethane) sulfonic acid imide (Li provided BTFI) 0. 28 G (1. 00 Mmol) was replaced by the addition of a salt. After reaction, after a table number compound represented by formula VIII-a BTFI filled cream or water recycling system 1. 00 G (0. 45 Mmol) by Congress. 1 H NMR (300 MHz, (CD3 )2 SO): 10. 11 (S, 2H), 8. 47 (D, 2H), 6. 89 - 7. 45 (M, 26H), 4. 27 (T, 16H), 3. 88 (T, 16H), 3. 76 (T, 4H), 3. 63 (M, 8H), 2. 18 (M, 8H), 1. 13 - 1. 43 (M, 64H), 0. 75 (T, 48H) 13 C NMR (75 MHz, CD3 OD): 178. 13, 177. 55, 156. 19, 155. 02, 145. 06, 140. 43, 137. 89, 130. 38, 129. 75, 128. 68, 127. 40, 127. 35, 124. 59, 123. 30, 114. 35, 106. 10, 71. 63, 70. 21, 62. 21, 50. 65, 48. 50, 44. 62, 32. 83, 30. 78, 26. 46, 23. 69, 14. 43, 12. 28 2150 [M MS (MALDI-a TOF)+ ] In the embodiment 5: Number tank represented by the following formula IX 4, 4' - Bis (die ethylamino) benzophenone 5 g (15. 41 Mmol) followed by addition of stirring is toluene 100 ml-gate. Then, oxychloride 11. 25 G (73. 38 Mmol) stirring 1 to add time-gate. Said formula IV compound 2. 29 G (7. 34 Mmol) after adding, with respect to the reflux. After reaction, cooling is performed at room temperature after adding the water, stir-gate. After separation layer, a compound represented by formula IX obtained cream have a positive number table number compound 2. 86 G (3. 08 Mmol) by Congress. 1 H NMR (300 MHz, CDCl3 ): 9. 76 (S, 2H), 9. 04 (D, 2H), 7. 13 - 7. 49 (M, 18H), 6. 67 (D, 8H), 4. 23 (S, 4H), 3. 53 (Q, 16H), 1. 28 (T, 24H) 13 C NMR (75 MHz, CD3 OD): 176. 59, 155. 23, 153. 43, 142. 88, 140. 64, 137. 31, 128. 94, 128. 78, 128. 34, 126. 61, 126. 40, 124. 29, 123. 50, 113. 62, 105. 42, 46. 34, 43. 92, 12. 94 MS (MALDI-a TOF) 925. 3 [M+ ] In the embodiment 6: Formula IX -BTFI Compound number of bath Compounds of formula IX in a high pressure liquid coolant 1 number said in the embodiment 5. 00 G (1. 08 Mmol) applied to a 50 ml methanol after dissolving, lithium bis (trifluoromethane) sulfonic acid imide (Li provided BTFI) 0. 62 G (2. 15 Mmol) was added to salt substituting. After reaction, after a table number compound represented by formula IX-a BTFI filled cream or water recycling system 1. 00 G (1. 08 Mmol) by Congress. 1 H NMR (300 MHz, CDCl3 ): 9. 84 (S, 2H), 9. 04 (D, 2H), 7. 13 - 7. 49 (M, 18H), 6. 67 (D, 8H), 4. 23 (S, 4H), 3. 53 (Q, 16H), 1. 28 (T, 24H) 13 C NMR (75 MHz, CD3 OD): 176. 59, 155. 23, 153. 43, 142. 88, 140. 64, 137. 31, 128. 94, 128. 78, 128. 34, 126. 61, 126. 40, 124. 29, 123. 50, 113. 62, 105. 42, 46. 34, 43. 92, 12. 94 MS (MALDI-a TOF) 925. 3 [M+ ] In the embodiment 7: Represented by the following formula X number bath 4, 4' - Bis (diethylamino) benzophenone 5 g (15. 41 Mmol) followed by addition of stirring is toluene 100 ml-gate. Then, oxychloride 11. 25 G (73. 38 Mmol) stirring 1 to add time-gate. Then, said formula VII compound 2. 94 G (7. 34 Mmol) after adding, with respect to the reflux. After reaction, cooling is performed at room temperature after adding the water, stir-gate. After separation layer, a compound represented by formula X is performed cream obtained positive number table number compound 3. 13 G (3. 08 Mmol) by Congress. 1 H NMR (300 MHz, (CD3 )2 SO): 8. 48 (D, 2H), 8. 36 (S, 2H), 6. 71 - 7. 41 (M, 26H), 3. 76 (T, 4H), 3. 64 (S, 4H), 3. 56 (Q, 20H), 1. 16 (T, 24H) 13 C NMR (75 MHz, (CD3 )2 SO): 174. 17, 153. 59, 151. 35, 141. 12, 139. 16, 135. 63, 127. 96, 127. 22, 126. 61, 125. 31, 124. 59, 122. 86, 122. 72, 112. 57, 103. 72, 69. 87, 68. 36, 44. 72, 42. 84, 12. 55 MS (MALDI-a TOF) 1015. 5 [M+ ] In the embodiment 8: Formula X -To BTFI By the following number bath A compound having a formula X number 1 high pressure liquid coolant in said in the embodiment 7. 00 G (0. 92 Mmol) applied to a 50 ml methanol after dissolving, lithium bis (trifluoromethane) sulfonic acid imide 0. 52 G (1. 84 Mmol) was added to salt substituting. After reaction, after a table number compound represented by the formula X-a BTFI filled cream or water recycling system 1. 00 G (0. 92 Mmol) by Congress. 1 H NMR (300 MHz, (CD3 )2 SO): 9. 66 (D, 2H), 8. 36 (S, 2H), 6. 71 - 7. 41 (M, 26H), 3. 76 (T, 4H), 3. 64 (S, 4H), 3. 56 (Q, 20H), 1. 16 (T, 24H) 13 C NMR (75 MHz, (CD3 )2 SO): 174. 17, 153. 59, 151. 35, 141. 12, 139. 16, 135. 63, 127. 96, 127. 22, 126. 61, 125. 31, 124. 59, 122. 86, 122. 72, 112. 57, 103. 72, 69. 87, 68. 36, 44. 72, 42. 84, 12. 55 MS (MALDI-a TOF) 1015. 5 [M+ ] Comparison example: Victoria Blue BO compounds Participant a widely used compound as well as comparing to a clover Victoria Blue BO compound formula XI: Experiment example 1: transmission measurement High pressure liquid coolant in said in the embodiment 1, 3, 5 and 7 for measuring permeability number compounds and comparison embodiments of compounds, each compound UV-a Vis spectrophotometer (UV3600 Plus, Shimadzu yarn number bath) sensing element to conducting. Said analysis, each compound dissolved in chloroform solvent and 2% by weight, film by spin coating on a glass slide same embodiment too soon and, also 1 have shown to result. As shown in the fig. 1, a high pressure liquid coolant in said formula 1 compounds compared to the number in the embodiment represented by embodiments of Victoria Blue BO indicates a wider transmission wavelength range can be compared to known compounds. This, in high pressure liquid coolant compounds compared to the transmission wavelength red and blue number said in the embodiment as compared to embodiments of compound movement can be simultaneously because the contents of the mobile. The, represented by said formula 1 compounds are identified that are capable of using blue resin composition for a color filter dyes. Experiment example 2: solubility evaluation High pressure liquid coolant in said in the embodiment 1 to 8 relate to compound solubility in solvent compounds and comparison number (25 °C) for measuring, propylene glycol monomethyl ether acetate (PGMEA) 30 minutes after dissolving each compound to 0. 45 Micro m of the line using the solution containing Syringe filter, where a stand-alone number after solvent, the remaining solute weight were measured. The measurement shown for table 1. As shown in the table 1, compared to the number represented by said formula 1 compounds in a high pressure liquid coolant in the embodiment as compared to embodiments of Victoria Blue BO compound 3 (g/100g PGMEA) represents excellent water solubility of more than can be know. In particular, substituted amine as - (CH2 )2 - OC (=O) - CH (C2 H5 ) (C4 H9 ) Exhibit high solubility (g/100g PGMEA) or more compounds having the structure 19, rather than bis (trifluoromethane) sulfonic imide anion as chloride salt compound form a higher solubility is also used for having taken can be. The, compounds of the present invention when tank number one in the embodiment according to blue resin composition, said compounds are readily dissolved in solvent composition an inkjet unit performs the color filter using the same number can be easily composed. Experiment example 3: thermostable evaluation High pressure liquid coolant in said in the embodiment 1 to 8 relate to compounds number compounds and thermal stability compared to evaluate, each compound make quantity analytical analysis (TGA) (Thermogravimetric Analyzer Q500, TA Instruments yarn number bath) was the weight using a embodiment. Specifically, one embodiment 10 10 °C component up said analysis under conditions characterized in that it has, as a result of measuring a signal indicating weight (%) 230 °C, 250 °C T (%) and generates a signal indicating weightd (Eye weight losses of 5%) therefrom. The measurement shown to table 2. As shown in the table 2, compared to the number represented by said formula 1 compounds in a high pressure liquid coolant in the embodiment as compared to embodiments of Victoria Blue BO compound 230 °C and 250 °C indicating high weight, Td Knowing represents excellent thermal stability can be significantly improved. In particular, substituted amine as - (CH2 )2 - OC (=O) - CH (C2 H5 ) (C4 H9 ) Compound having at least one ethyl compounds having improved thermal stability of more than used to indicate, this - (CH2 )2 - OC (=O) - CH (C2 H5 ) (C4 H9 ) Of oxygen and - NH with hydrogen at hydrogen bonding due to determine the other. Thus, in the embodiment according to blue color filter resin composition of the present invention compound number during one process for preparing 230 °C Baking required temperature in very low weight losses, high brightness, high resolution and preventing constipation cancerous rain to enable implementation of the color filter are exclusively of vehicle from the outside. The present invention relates to a compound in a form of a dimer, a blue resin composition for a color filter comprising the same, and a color filter using the same, wherein the compound is a triarylmethane based compound having excellent solubility and thermal stability, and a wide transmittance, so as to provide a blue resin composition for a color filter excellent in heat resistance. COPYRIGHT KIPO 2017 A compound having a formula 1: [formula 1] In said formula 1, A1 And A2 A ring may independently benzene or naphthalene and, n is 0, 1, or 2 and, R1 To R8 Are each independently hydrogen, C1 - 20 Alkyl, C6 - 20 Aryl, or - (CH2 )m - OC (=O) - CH (Q1 ) (Q2 ) And, wherein, C1 - 20 C alkyl and6 - 20 It will be biting or are each independently a substituted or unsubstituted, or halogen, hydroxy, C1 - 5 C alkyl and1 - 5 1 Selected independently from the group consisting alkoxy substituted one or two substituted 2, m is integer number of 1 to 3, Q1 And Q2 Are each independently a hydrogen or C1 - 10 Alkyl, R11 To R16 Are each independently hydrogen, halogen, hydroxy, C1 - 5 Alkyl, or C1 - 5 Alkoxy and, each integer number of 0 to 6 a2 a1 and independently, to each integer number of 0 to 4 a3 a6 independently, halogen X, bis (trifluoromethane) sulfonic acid imide, or triple [...] among others. According to Claim 1, A1 And A2 Characterized loop on the same each other, compound. According to Claim 1, R1 To R8 Are each independently hydrogen, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec - butyl, tert - butyl, or - (CH2 )2 - OC (=O) - CH (Q1 ) (Q2 ) And, wherein, Q1 And Q2 Are each independently a hydrogen, methyl, ethyl, propyl, or butyl characterized a, compound. According to Claim 1, R1 To R8 Characterized are equal to each other a, compound. According to Claim 1, R11 To R16 Are each independently hydrogen, halogen, methyl, the maul [thok poet or characterized, compound. According to Claim 1, X is chloride, or bis (trifluoromethane) sulfonic acid imide to be characterized, compound. According to Claim 1, characterized to represented by the formula 1 - 1, compound: [formula 1 - 1] In said formula 1 - 1, n and R1 To R8 Efined according to Claim 1 is defined. According to Claim 1, compounds represented by a formula selected from the group consisting characterized, compound: [formula V] [Formula V-a BTFI] [Formula VIII] [Formula VIII-a BTFI] [Formula IX] [Formula IX-a BTFI] [Formula X] [Formula X-a BTFI] Any one of Claim 1 to Claim 8 compound including, blue resin composition for color filter. According to Claim 9 blue resin compositions can be used to number the bath for color filter, color filter. Ethylene oxide number (n) Substituent (R1 - R8 ) Anion (X) G/100g PGMEA solubility In the embodiment 1 0 - (CH2 )2 - OC (=O) - CH (C2 H5 ) (C4 H9 ) Cl 19. 4 In the embodiment 2 0 - (CH2 )2 - OC (=O) - CH (C2 H5 ) (C4 H9 ) BTFI 23. 1 In the embodiment 3 2 - (CH2 )2 - OC (=O) - CH (C2 H5 ) (C4 H9 ) Cl 19. 8 In the embodiment 4 2 - (CH2 )2 - OC (=O) - CH (C2 H5 ) (C4 H9 ) BTFI 24. 5 In the embodiment 5 0 - C2 H5 Cl 3. 1 In the embodiment 6 0 - C2 H5 BTFI 4. 5 In the embodiment 7 2 - C2 H5 Cl 3. 1 In the embodiment 8 2 - C2 H5 BTFI 4. 9 Comparison example - - C2 H5 /H Cl 0. 03 230 °C (%) generates a signal indicating weight Weight (%) generates a signal indicating 250 °C Td (°C) In the embodiment 1 93. 36 87. 86 225. 89 In the embodiment 2 99. 56 99. 24 288. 98 In the embodiment 3 94. 78 90. 14 229. 52 In the embodiment 4 99. 74 99. 61 288. 84 In the embodiment 5 95. 49 84. 05 232. 40 In the embodiment 6 99. 20 98. 07 259. 35 In the embodiment 7 92. 23 82. 02 237. 87 In the embodiment 8 99. 37 97. 96 261. 10 Comparison example 82. 92 69. 10 177. 70
