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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Применить Всего найдено 7. Отображено 7.
15-04-1980 дата публикации

CATALYST AND PROCESS FOR PREPARING MALEIC ANHYDRIDE FROM C4 HYDROCARBONS

Номер: CA1075670A

A catalyst complex useful for converting normal C4 hydrocarbons to maleic anhydride in vapor phase comprising as components vanadium, phosphorus and an element Me. wherein Me is selected from the group consisting of: i) B at least one element selected from the group consisting of Zn, Cr, U, W, Cd, Ni and Si, ii) a mixture of two or more elements selected from the group consisting of Zn, Cr, Cd, Ni, B and Si, iii) a mixture of U and at least one element selected from the group consisting of Zn, Cr, W, Cd, Ni and Si, and iv) a mixture of W and at least one element selected from the group consisting of Zn, Cr, Cd, Ni and Si.

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29-04-1980 дата публикации

CATALYST TREATMENT

Номер: CA1076547A

In the production of maleic anhydride from benzene employing a molybdenum-vanadium-oxygen oxidation catalyst, addition of a volatilizable compound of a phosphorus halide or an organo phosphorus compound is added to the catalyst to deactivate a portion of the catalyst whereby progressive nonselectivity of a portion of the catalyst resulting in a decrease in anhydride yield is overcome and high yields of anhydride are maintained.

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29-01-1980 дата публикации

CATALYST TREATMENT

Номер: CA1070701A

OXIDATION OF HYDROCARBONS Molybdenum - vanadium oxygen oxidation catalyst for producing maleic anhydride from benzene is regenerated and stabilized by the addition of a compound of Mo, Ni, Co, Mn or U, preferably a volatile compound, to the catalyst, after a decline in activity.

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23-11-1982 дата публикации

PARTIAL OXIDATION CATALYST

Номер: CA1136115A

IMPROVED PARTIAL OXIDATION CATALYST An improvement in the oxidation catalyst used for the partial oxidation of n-butane and containing vanadium and phosphorus mixed oxides which comprises adding a zinc compound in an amount of from about 0.15 to 0.001/1 Zn/V to the catalyst during the digestion of the reduced vanadium component by concentrated phosphoric acid. The addition of zinc produces a catalyst which is more easily activated and which is very stable to heat upset of the reaction system. Small amounts of lithium and silicon compounds also have additional desirable catalytic effects without dimunition of the zinc compound benefit.

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15-08-1978 дата публикации

PROCESS FOR THE PRODUCTION OF 2-CHLOROBUTADIENE-1,3 FROM 3,4-DICHLOROBUTENE-1

Номер: CA1036622A

IMPROVED PROCESS FOR THE PRODUCTION OF 2-CHLOROBUTADIENE-1,3 FROM 3,4-DICHLOROBUTENE-1 A process is described whereby 2-chlorobutadiene-1,3 is produced from 3, 4-dichlorobutene-1 in a two-phase reaction system wherein the reaction predominantly occurs in the organic phase and the production of undesirable by-products, particularly 1-chlorobutadiene-1,3 and acetaldehyde, is suppressed. The practice of the process results in a brine effluent from the reactor containing small amounts of organic materials resulting in a waste product which is less polluting and more easily cleaned. The organic phase is selected from primary and secondary alcohols, alkoxyethanols and mixtures thereof, preferably alkoxyethanols wherein the alkyl group has two or more carbon atoms. Surprisingly, I have discovered that the selection of the organic phase of the reaction system is made by a screening test wherein a two-phase system of a 20% brine and 3,4-dichlorobutene-1 is prepared and the alcohol or alkoxyethanol ...

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27-09-1983 дата публикации

CATALYST STRUCTURE FOR THE PARTIAL OXIDATION OF N- BUTANE TO PRODUCE MALEIC ANHYDRIDE

Номер: CA1154423A

IMPROVED CATALYST STRUCTURE FOR THE PARTIAL OXIDATION OF n-BUTANE TO PRODUCE MALEIC ANHYDRIDE Phosphorus-Vanadium oxidation catalyst prepared as tablets with a hole in the center produce higher yields of maleic anhydride from C4's, particularly n-butane than the same catalyst without the hole.

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15-04-1980 дата публикации

OXIDATION CATALYSTS AND PROCESS REPARING ANHYDRIDE FROM ALKANES

Номер: CA1075671A

A catalyst complex useful for the partial oxidation of alkanes to the corresponding anhydrides, e.g., converting normal C4 hydrocarbons to maleic anhydride in vapor phase, comprising as components vanadium, phosphorus, oxygen, Nb, Cu, Mo, Ni, Co and Cr. Preferred are those compositions containing in addition one or more of Ce, Nd, Ba, Hf, U, Ru, Re, Li or Mg.

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