02-08-2018 дата публикации
Номер: US20180215990A1
In one aspect, embodiments disclosed herein relate to a wellbore strengthening composition including at least one polymer capable of polymerizing through a free radical polymerization reaction from the group of epoxy acrylates, modified epoxy acrylates, epoxy precursors, modified epoxy vinyl esters, unsaturated polyesters, urethane (meth)acrylates, polyester acrylates, epoxy vinyl ester resins having the wherein R and R-Rmay be CH— or H and R-Rmay be H or Br, and polymer combinations thereof; and at least one initiator, wherein the resin is present in the amount from about 10 to about 90 weight percent. 112.-. (canceled)14. The method of claim 13 , wherein the initiator is selected from the group consisting of benzoyl peroxide claim 13 , dibenzoyl peroxide claim 13 , diacetyl peroxide claim 13 , di-t-butyl peroxide claim 13 , cumyl peroxide claim 13 , dicumyl peroxide claim 13 , dilauryl peroxide claim 13 , t-butyl hydroperoxide claim 13 , methyl ketone peroxide claim 13 , acetylacetone peroxide claim 13 , methylethyl ketone peroxide claim 13 , dibutylperoxyl cyclohexane claim 13 , di (2 claim 13 ,4-dichlorobenzoyl) peroxide claim 13 , diisobutyl peroxide claim 13 , t-butyl perbenzoate claim 13 , t-butyl peracetate claim 13 , and combinations thereof.15. The method of claim 13 , further comprising:introducing at least a monomer from the group of hydroxyethyl methacrylate (HEMA), hydroxypropyl methacrylate (HPMA), acrylic acid, methacrylic acid, methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, isodecyl acrylate, stearyl acrylate, lauryl acrylate, tridecyl acrylate, isoctyl acrylate, ethyoxylated bisphenol A diacrylate, ethoxylated hydroxyethyl acrylate, allyl acrylate, glycidyl methacrylate, 1,4-butanediol diacrylate (BDDA), 1,6-hexanediol diacrylate (HDDA), diethylene glycol diacrylate, 1,3-butylene glycol diacrylate, neopentyl glycol diacrylate, cyclohexane dimethanol diacrylate, dipropylene glycol diacrylate, ethoxylated bisphenol A diacrylate, ...
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