ELIMINATION OF ODORS FROM ORGANIC WASTES

A method and solution are provided for reducing air-polluting odors emanating from organic waste products produced by metabolic processes and from organic industrial waste including effluents. The method comprises contacting said wastes with an aqueous acid solution containing a water-soluble oxidizing agent selected from the group consisting of nitrates, chlorates and permanganates of ammonia and alkali metals, and also a precipitating agent selected from the group consisting of water soluble ferric and ferrous compounds.

Alzheimer hastalığının tedavi yöntemi.

Recombinant BCG overexpressing phoP-phoR

Provided are a live recombinant Mycobacterium bovis-BCG strain and a tuberculosis (TB) vaccine or immunogenic composition comprising a nucleic acid capable of overexpression, the nucleic acid encoding PhoP and PhoR proteins. A method for treatment or prophylaxis of a mammal against challenge by Mycobacterium tuberculosis or Mycobacterium bovis using the strain is also provided.

Fungizide Zusammensetzung für Acker- und Gartenbau enthaltend eine Benzamidoxim-Verbindung und ein Säureamid-Derivat

Clathrate, curing agent, cure accelerator, epoxy resin composition, and epoxy resin composition for encapsulation of semiconductor

It is an object of the present invention to provide a clathrate that suppresses a curing reaction at low temperature to promote an improvement in storage stability (one-component stability), and can effectively cure a resin by heating treatment. A clathrate suitable for the clathrate is a clathrate containing (b1) at least one selected from the group consisting of an aliphatic polyvalent carboxylic acid, 5-nitroisophthalic acid, 5-tert-butylisophthalic acid, 5-hydroxyisophthalic acid, isophthalic acid, and benzophenone-4,4′-dicarboxylic acid; and (b2) at least one selected from the group consisting of an imidazole compound represented by the following formula (I), and 1,8-diazabicyclo[5.4.0]undecene-7, at a molar ratio of 1:1.

PROCESS FOR PREPARATION OF 1-ALKYL-5-BENZOYL-1H-TETRAZOLE DERIVATIVES

The present invention provides a process for preparation of 1-alkyl-5-benzoyl-1H-tetrazole derivative including a step 1 of reacting a ketoamide derivative represented by formula (I) (in formula (I), A represents a halogen atom or the like; n represents an integer of 0 to 5; Y represents an alkyl group) with a halogenating agent to obtain an imidoyl halide derivative represented by formula (II) (in formula (II), A, n and Y are as defined above; X represents a halogen atom); and a step 2 of reacting the imidoyl halide derivative represented by formula (II) with an azide represented by formula (III) (in formula (III), M represents an alkali metal or the like; m represents 1 or 2) to obtain a 1-alkyl-5-benzoyl-1H-tetrazole derivative represented by formula (IV) (in formula (IV), A, n and Y are as defined above). 2. The process for preparation of 1-alkyl-5-benzoyl-1H-tetrazole derivative according to claim 1 , whereinin the step 1, the halogenating agent is at least one selected from the group consisting of phosgene, oxalyl chloride, thionyl chloride and phosphorus oxychloride.3. The process for preparation of 1-alkyl-5-benzoyl-1H-tetrazole derivative according to claim 1 , whereinin the step 2, the azide represented by formula (III) is sodium azide.4. The process for preparation of 1-alkyl-5-benzoyl-1H-tetrazole derivative according to claim 1 , whereinin the step 1, chloroform, methylene chloride or benzene is used as a solvent. The present invention relates to a process for preparation of 1-alkyl-5-benzoyl-1H-terazole derivatives. More specifically, the present invention relates to a process for preparation of 1-alkyl-5-benzoyl-1H-terazole derivatives, in which as a starting material thereof a relatively easily-producible and easily-available ketoamide derivative represented by formula (I) is used:(In formula, A represents a halogen atom, alkyl group, haloalkyl group, alkoxy group, haloalkoxy group, alkyl sulfonyl group, an optionally substituted aryl group, cyano ...

PHOTOSENSITIVE RESIN COMPOSITION FOR FLEXOGRAPHIC PRINTING HAVING EXCELLENT SOLVENT RESISTANCE

A photosensitive resin composition for flexographic printing having excellent resistance to an ink comprising an organic solvent and an emulsion ink used in flexographic printing, for example, a UV-curable ink or an ink using a vegetable oil or light naphtha and having excellent suitability for printing applications such as image reproducibility and print durability. The photosensitive resin composition for flexographic printing includes, at least, (a) one or more thermoplastic elastomers, (b) an acrylic-terminated liquid polybutadiene containing 1,2-bonds in an amount of 80% or more, (c) a photopolymerizable unsaturated monomer having at least one or more ethylenically unsaturated groups, and (d) a photopolymerization initiator. 1. A photosensitive resin composition for flexographic printing , comprising:component (a): a thermoplastic elastomer,component (b): a (meth)acrylic-modified liquid polybutadiene containing 1,2-bonds in an amount of 80% or more,component (c): a photopolymerizable unsaturated monomer having one or more ethylenically unsaturated groups, andcomponent (d): a photopolymerization initiator.2. The photosensitive resin composition for flexographic printing according to claim 1 , comprising from 18.0 to 95.0% by mass of the component (a); from 1.0 to 80.0% by mass of the component (b); from 1.0 to 30.0% by mass of the component (c); and from 0.1 to 10.0% by mass of the component (d).3. The photosensitive resin composition for flexographic printing according to claim 1 , wherein the component (b) is a liquid polybutadiene having a (meth)acrylic-modified polymer terminal and containing 1 claim 1 ,2-bonds in an amount of 80% or more.4. The photosensitive resin composition for flexographic printing according to claim 1 , wherein the component (b) has a number average molecular weight of 200 to 100 claim 1 ,000 and a viscosity at 45° C. of 4 Pa·s or more.5. A photosensitive resin plate material for flexographic printing claim 1 , wherein the ...

PROCESS FOR PRODUCTION OF CYCLIC SILANE COMPOUND AND/OR CYCLIC CARBOSILANE COMPOUND

The present invention relates to: a process for producing a cyclic silane compound, which comprises subjecting a chained polysilane to pyrolysis in the presence of an oxide of a transition metal belonging to Group 8 or Group 11 of the periodic table; and a process for producing a cyclic carbosilane compound, which comprises subjecting a chained polysilane to pyrolysis in the presence of a simple substance of a metal selected from the group consisting of transition metal elements and elements belonging to Groups 12 to 15 of the periodic table or a compound thereof. 1. A process for producing a cyclic silane compound , which comprises subjecting a chained polysilane to pyrolysis in the presence of an oxide of a transition metal belonging to Group 8 or Group 11 of the periodic table.4. The process for producing a cyclic silane compound according to claim 1 , wherein the cyclic silane compound is decamethylcyclopentasilane.5. The process for producing a cyclic silane compound according to claim 1 , wherein the transition metal belonging to Group 8 of the periodic table is iron and the transition metal belonging to Group 11 is copper.6. A process for producing a cyclic carbosilane compound claim 1 , which comprises subjecting a chained polysilane to pyrolysis in the presence of a simple substance of a metal selected from the group consisting of transition metal elements and elements belonging to Groups 12 to 15 of the periodic table or a compound thereof.7. The process for producing a cyclic carbosilane compound according to claim 6 , wherein the chained polysilane is a compound represented by formula (1).8. The process for producing a cyclic carbosilane compound according to claim 6 , wherein the cyclic carbosilane compound is 6- to 8-membered cyclic carbosilane compounds.9. The process for producing a cyclic carbosilane compound according to claim 6 , wherein the transition metal element is titanium claim 6 , manganese claim 6 , iron claim 6 , cobalt claim 6 , or ...

PROCESS FOR PRODUCING SUBSTITUTED METHYLAMINE COMPOUND AND TRIAZINE DERIVATIVE

The present invention provides a process that enables a substituted methylamine compound which is useful as an intermediate for the production of agricultural chemicals and medicines, to be produced easily, with good yield, and at low cost, and also provides a production intermediate thereof. The process comprises a step of reacting a hexamethylenetetraammonium salt compound represented by a formula (I) with a base to obtain an N-methylidene-substituted methylamine oligomer represented by a formula (II) or a mixture of two or more of the oligomers, and a step of hydrolyzing the N-methylidene-substituted methylamine oligomer represented by formula (II) or the mixture of two or more of the oligomers in the presence of an acid. 114-. (canceled) The present invention relates to a process that enables a substituted methylamine compound, such as a pyridylmethylamine compound, which is useful as an intermediate for the production of agricultural chemicals and medicines and the like, to be produced easily, with good yield, and at low cost, and also relates to an N-methylidene-substituted methylamine oligomer that acts as a production intermediate.Substituted methylamine compounds, including pyridylmethylamine compounds such as 2-chloro-5-pyridylmethylamine, are useful as intermediates for the production of agricultural chemicals and medicines.Conventionally, known processes for producing pyridylmethylamine compounds include a process in which 2-chloro-5-chloromethylpyridine is reacted with potassium phthalimide to obtain N-(2-chloro-5-pyridylmethyl)phthalimide, which is subsequently reacted with hydrazine (see Patent Document 1), a process in which 2-chloro-5-(chloromethyl)pyridine is reacted with hexamethylenetetramine to obtain 2-chloro-5-pyridylmethylhexamethylenetetraammonium chloride, and a hydrolysis is subsequently performed in the presence of a lower alcohol and a mineral acid (see Patent Document 2), and a process in which 2-chloro-5- ...

Dispersoid having metal-oxygen bonds, metal oxide film, and monomolecular film

Dispersoids having metal-oxygen groups that are suitable for the production of metal oxide thin-films at a low temperature of 200° C. or below and for the production of homogeneous organic-inorganic hybrid materials. The dispersoid having metal-oxygen bonds may be obtained by mixing a metal compound having at least three hydrolyzable groups with at least 0.5 mole but less than 2 moles of water per mole of the metal compound in an organic solvent, in the absence of an acid, a base, and/or a dispersion stabilizer, and at a temperature at or below the temperature at which the metal compound begins to hydrolyze, then raising the temperature to at least the temperature at which hydrolysis begins.

CLATHRATE COMPOUND, CURING CATALYST, COMPOSITION FOR FORMING CURED RESIN, AND CURED RESIN

A curing catalyst (clathrate compound) for which the curing reaction is suppressed at low temperatures, allowing an improvement in the one-pot stability, but which can effectively cure a resin upon heat treatment. The clathrate compound includes at least an isophthalic acid compound represented by Formula (I), where Rrepresents a C1 to C6 alkyl group, a C1 to C6 alkoxy group, a nitro group, or a hydroxyl group, and an imidazole compound represented by a Formula (II) where Rrepresents a hydrogen atom, a C1 to C10 alkyl group, a phenyl group, a benzyl group, or a cyanoethyl group, and Rto Reach independently represents a hydrogen atom, a nitro group, or a halogen atom, or a C1 to C20 alkyl group, phenyl group, benzyl group, or C1 to C20 acyl group that may have a substituent. 2. The clathrate compound according to claim 1 , wherein the isophthalic acid compound represented by formula (I) is 5-t-butylisophthalic acid claim 1 , 5-hydroxyisophthalic acid claim 1 , or 5-nitroisophthalic acid.3. The clathrate compound according to claim 1 , wherein the imidazole compound represented by formula (II) is imidazole claim 1 , 2-ethyl-4-methylimidazole claim 1 , 2-methylimidazole claim 1 , 2-n-butylimidazole claim 1 , 1-benzyl-2-methylimidazole claim 1 , 2-heptadecylimidazole claim 1 , 2-undecylimidazole or 2-phenyl-4-methyl-5-hydroxymethylimidazole.4. The clathrate compound according to claim 1 , wherein Ris a hydrogen atom.5. The clathrate compound according to claim 1 , wherein the compound is in a powdered form.6. A curing catalyst for an epoxy resin claim 1 , comprising a clathrate compound according to .7. A curing catalyst for an epoxy resin claim 2 , comprising a clathrate compound according to .8. A curing catalyst for an epoxy resin claim 3 , comprising a clathrate compound according to .9. A curing catalyst for an epoxy resin claim 4 , comprising a clathrate compound according to .10. A curing catalyst for an epoxy resin claim 5 , comprising a clathrate compound ...

HIGH-MOLECULAR-WEIGHT COPOLYMER

It is an object of the present invention to provide (1) a copolymer for a cured product that is satisfactory in properties, such as adhesion properties, as a chip stacking adhesive or the like. The present invention is a copolymer comprising repeating units represented by formula (I), formula (II), and formula (III), (wherein R, R, and Reach independently represent a hydrogen atom or a methyl group, Rrepresents an alkyl group or a cycloalkyl group, Rrepresents a hydrogen atom or a Cto Calkyl group, m, n, and k represent a molar ratio of the respective repeating units, m represents a positive number of 0 or more and less than 1, n and k each independently represent a positive number, and satisfy a relation of m+n+k=1), and having a weight-average molecular weight in the range of 50,000 to 200,000. 2. The copolymer according to claim 1 , wherein the repeating units represented by formula (I) and formula (II) and the repeating unit represented by formula (III) are bonded by block bonding.3. The copolymer according to claim 2 , wherein for the repeating units represented by formula (I) and formula (II) claim 2 , the repeating unit represented by formula (I) and the repeating unit represented by formula (II) are randomly bonded.4. The copolymer according to any one of to claim 2 , wherein a ratio of weight-average molecular weight (Mw) to number-average molecular weight (Mn) (Mw/Mn) is in the range of 1.01 to 1.50. The present invention relates to a copolymer suitable for insulating resin compositions used for surface protection films, interlayer insulating films, chip stacking adhesives, and the like for semiconductor devices and the like. This application claims priority to Japanese Patent Application No. 2009-181210 filed on Aug. 4, 2009, the content of which is incorporated herein.As a polymer for a cured product that is excellent in properties, such as electrical insulation properties, thermal shock resistance, and adhesion properties, a copolymer (A) having 10 to ...

FORMING MOLD OR ELECTROFORMING MOTHER DIE HAVING RELEASE LAYER AND METHOD FOR MANUFACTURING THE SAME

A forming mold or electroforming mother die including a mold or mother die, and a release layer composed of an organic thin film on a mold surface or mother die surface which is formed by contacting the mold or mother die with an organic solvent solution including a silane surfactant represented by formula [1] 1. A method for producing a forming mold or electroforming mother die comprising:forming a release layer composed of an organic thin film on a mod surface or mother die surface by contacting the mold or mother die with an organic solvent solution comprising: {'br': None, 'sub': n', '4-n, 'R—Si—X\u2003\u2003[1]'}, '(i) a silane surfactant represented by formula [1]'} R is selected from the group consisting of an optionally substituted hydrocarbon group having 1 to 20 carbon atoms, an optionally substituted halogenated hydrocarbon group having 1 to 20 carbon atoms, a hydrocarbon group having a linking group which has 1 to 20 carbon atoms, and a halogenated hydrocarbon group having a linking group which has 1 to 20 carbon atoms;', 'X is selected from the group consisting of a hydroxyl group, a halogen atom, an alkoxy group having 1 to 6 carbon atoms, and an acyloxy group; and', 'n represents an integer of 1 to 3, and, 'wherein(ii) a catalyst capable of interacting with the silane surfactant;wherein a moisture content of the organic solvent solution is set or maintained within a range of from 50 ppm to a saturated moisture content of the organic solvent.2. The method for producing a forming mold or electroforming mother die according to claim 1 , wherein the forming mold is a forming mold for molding resin.3. The method for producing a forming mold or electroforming mother die according to claim 1 , wherein the silane surfactant represented by formula [1] is n-octadecyltrimethoxysilane.4. The method for producing a forming mold or electroforming mother die according to claim 1 , wherein the catalyst capable of interacting with the silane surfactant is at least one ...

METHOD FOR PRODUCTION OF N-(2-AMINO-1,2-DICYANOVINYL)IMIDATES, METHOD FOR PRODUCTION OF N-(2-AMINO-1,2-DICYANOVINYL)FORMAMIDINE, AND METHOD FOR PRODUCTION OF AMINOIMIDAZOLE DERIVATIVES

A method for producing N-(2-amino-1,2-dicyanovinyl)imidates represented by the following formula (1-III) under low temperature conditions within a short period of time in high yield is provided. In addition, a method for producing N-(2-amino-1,2-dicyanovinyl)formamidine represented by the following formula (2-II) which is suitably applicable to a cyclization reaction for producing AlCN, AlCA or the like and which enhances yield of the cyclization reaction is provided. In addition, a method for producing aminoimidazole derivatives represented by the following formula (3-V) in high yield by using diaminomaleonitrile as a starting material is provided. 3. The method for producing aminoimidazole derivatives according to claim 2 , wherein the strong acid is trifluoroacetic acid claim 2 , methanesulfonic acid claim 2 , p-toluenesulfonic acid claim 2 , or condensed sulfuric acid.4. The method for producing aminoimidazole derivatives according to claim 2 , wherein step (B) is carried out by mixing a solution or suspension of the aforementioned compound represented by formula (3-II) in an aprotic organic solvent and an aqueous solution of the compound represented by formula (3-III).5. The method for producing aminoimidazole derivatives according to claim 1 , wherein the aforementioned aprotic organic solvent is tetrahydrofuran. This is a divisional of application Ser. No. 12/450,730 filed Oct. 9, 2009, which is a National Stage Application of PCT/JP2008/057490 filed Apr. 17, 2008, and claims the benefit of Japanese Patent Application Nos. 2007-111038, 2007-111039, and 2007-111041 all of which were filed on Apr. 19, 2007. The entire disclosures of the prior applications are hereby incorporated by reference herein in their entirety.The first mode of the present invention relates to a method for producing N-(2-amino-1,2-dicyanovinyl)imidates. More particularly, it relates to a method for producing N-(2-amino-1,2-dicyanovinyl)imidates (hereinafter, referred to as RMD in some ...

PROCESS FOR PRODUCTION OF MODIFIED POLYSILOXANE COMPOUND

A modified polysiloxane compound represented by formula (I): X(Y)n (I), where X represents a polymer block having a repeating unit represented by formula (II), Y represents a polymer block having a repeating unit represented by formula (III), and n represents 1 or 2, and having an X to Y weight ratio of 1/99≦X/Y≦90/10 and a number-average molecular weight of 1,000 to 100,000 is subjected to treat for elimination of a protecting group for a hydroxyl group by adding a non-aqueous solution containing hydrogen chloride in the presence of a non-aqueous solvent so that hydrogen chloride is 0.9 to 1.3 equivalents with respect to 1 equivalent of the repeating unit represented by formula (II). 2. The method for producing a modified polysiloxane compound according to claim 1 , wherein the modified polysiloxane compound has a molecular weight distribution of 1.05 to 1.5. The present invention relates to a method for the production of a modified polysiloxane compound, and particularly to a method for the production of a phenol structure-introduced, modified polysiloxane compound obtained by block copolymerization of a p-alkenylphenol unit and an organosiloxane unit as essential constituent units.This application claims priority to Japanese Patent Application No. 2009-192151 filed on Aug. 21, 2009, the content of which is incorporated herein.Organopolysiloxane compounds have excellent interface properties, such as thermal stability, water repellency, defoaming properties, and releasability, and thus are frequently used in various fields. Particularly, in recent years, because of the utilizing of their specific interface properties, uses as coating forming agents have expanded. In addition, the applications as modifiers for providing the temperature properties and interface properties of the organopolysiloxane compounds to various resins have also been actively developed.In other words, for example, dimethylpolysiloxane, methylphenylpolysiloxane, fatty acid-modified polysiloxanes ...

Method for production of n-(2-amino-1,2-dicyanovinyl)imidates, method for production of n-(2-amino-1,2-dicyanovinyl)formamidine, and method for production of aminoimidazole derivatives

A method for producing N-(2-amino-1,2-dicyanovinyl)formamidine, including the steps of reacting an N-(2-amino-1,2-dicyanovinyl)formimidate and ammonia by adding aqueous ammonia to a solution or suspension of an N-(2-amino-1,2-dicyanovinyl)formimidate in ether, or alternatively directly adding an N-(2-amino-1,2-dicyanovinyl)formimidate or adding a solution or suspension of an N-(2-amino-1,2-dicyanovinyl)formimidate in ether to a liquid containing ether and aqueous ammonia.

METHOD FOR PRODUCING ARYL, HETEROARYL, OR ALKENYL-SUBSTITUTED UNSATURATED HYDROCARBON

The present invention relates to a method for producing aryl-, heteroaryl- or alkenyl-substituted unsaturated hydrocarbons, containing: reacting aryl halides, heteroaryl halides or alkenyl halides with alkynes or alkenes in the presence of a palladium catalyst to obtain a crude product, and subsequently distillatively purifying the crude product in the presence of a compound having at least one NC═S group. 1. A method for producing aryl- , heteroaryl- or alkenyl-substituted unsaturated hydrocarbons , comprising:reacting aryl halides, heteroaryl halides or alkenyl halides with alkynes or alkenes in the presence of a palladium catalyst to obtain a crude product, and subsequentlydistillatively purifying said crude product in the presence of a compound having at least one NC═S group.2. The method for producing aryl- claim 1 , heteroaryl- or alkenyl-substituted unsaturated hydrocarbons according to claim 1 , wherein the compound having at least one NC═S group is dithiocarbamates or thioureas.3. The method for producing aryl- claim 1 , heteroaryl- or alkenyl-substituted unsaturated hydrocarbons according to claim 1 , wherein extraction with solvent is performed after the reaction of aryl halides claim 1 , heteroaryl halides or alkenyl halides with allcynes or alkenes but before said distillative purification.4. The method for producing aryl- claim 1 , heteroaryl- or alkenyl-substituted unsaturated hydrocarbons according to claim 1 , wherein the compound having at least one NC═S group is used in an amount of 0.1 to 2 mol % based on aryl- claim 1 , heteroaryl- or alkenyl-substituted unsaturated hydrocarbons contained in the crude product before distillation.5. The method for producing aryl- claim 1 , heteroaryl- or alkenyl-substituted unsaturated hydrocarbons according to claim 1 , wherein the compound having at least one NC═S group is used in an amount of 0.2 to 0.5 mol % based on aryl- claim 1 , heteroaryl- or alkenyl-substituted unsaturated hydrocarbons contained in the ...

COATING AGENT COMPRISING HYDROXYALKYL CELLULOSE

There are provided a coating agent containing a hydroxyalkyl cellulose in which a content of hydroxyalkyl groups within the hydroxyalkyl cellulose is within a range of 40 to 50% by mass, preferably a coating agent containing a hydroxyalkyl cellulose in which the content of hydroxyalkyl groups is within a range of 40 to 50% by mass and also a viscosity of 2% aqueous solution at 20° C. is within a range of 3.0 to 5.9 mPa·s; and a solid preparation coated with the coating agent. 1. A coating agent comprising a hydroxyalkyl cellulose in which a content of hydroxyalkyl groups within the hydroxyalkyl cellulose is within a range of 40 to 50% by mass.2. The coating agent according to claim 1 , which is used for coating a tablet.3. The coating agent according to claim 1 , wherein a viscosity of 2% aqueous solution of the hydroxyalkyl cellulose at 20° C. is within a range of 3.0 to 5.9 mPa·s.4. The coating agent according to claim 1 , wherein an alkyl group in the hydroxyalkyl cellulose is a propyl group.5. A solid preparation coated with the coating agent of .6. The coating agent according to claim 2 , wherein a viscosity of 2% aqueous solution of the hydroxyalkyl cellulose at 20° C. is within a range of 3.0 to 5.9 mPa·s.7. The coating agent according to claim 2 , wherein an alkyl group in the hydroxyalkyl cellulose is a propyl group.8. A solid preparation coated with the coating agent of . The present invention relates to a coating agent containing a hydroxyalkyl cellulose. More specifically, the present invention relates to a coating agent suitable for obtaining a coating film of solid preparations for medicine, agricultural chemicals or food.Priority is claimed on Japanese Patent Application No. 2009-202247, filed Sep. 2, 2009, the content of which is incorporated herein by reference.Hydroxypropyl celluloses are non-ionic polymers in which a hydroxyl group in the glucose (CHO) unit serving as a structural unit of cellulose is etherified with a hydroxypropyl group. With ...

HYDROXYPROPYL CELLULOSE PARTICLES

Hydroxypropyl cellulose particles which contain 50-100 weight % of particles with a particle size that is larger than 150 μm and not larger than 355 μm. 1. Hydroxypropyl cellulose particles which contain 50-100 weight % of particles with a particle size that is larger than 150 μm and not larger than 355 μm.2. The hydroxypropyl cellulose particles according to claim 1 , wherein said hydroxypropyl cellulose particles contain 100 weight % of particles with a particle size that is larger than 150 μm and not larger than 355 μm.3. Hydroxypropyl cellulose particles which contain 50-100 weight % of particles with a particle size that is larger than 250 μm and not larger than 355 μm.4. The hydroxypropyl cellulose particles according to claim 3 , wherein said hydroxypropyl cellulose particles contain 100 weight % of particles with a particle size that is larger than 250 μm and not larger than 355 μm.5. Hydroxypropyl cellulose particles which contain 50-100 weight % of particles with a particle size that is larger than 180 μm and not larger than 250 μm.6. The hydroxypropyl cellulose particles according to claim 5 , wherein said hydroxypropyl cellulose particles contain 100 weight % of particles with a particle size that is larger than 180 μm and not larger than 250 μm.7. The hydroxypropyl cellulose particles according to claim 1 , wherein the content of hydroxypropyl groups is 53.4-77.5 weight % claim 1 , and viscosity at 20° C. in a 2% aqueous solution is in a range of 100-5000 mPa·s.8. The hydroxypropyl cellulose particles according to claim 3 , wherein the content of hydroxypropyl groups is 53.4-77.5 weight % claim 3 , and viscosity at 20° C. in a 2% aqueous solution is in a range of 100-5000 mPa·s.9. The hydroxypropyl cellulose particles according to claim 5 , wherein the content of hydroxypropyl groups is 53.4-77.5 weight % claim 5 , and viscosity at 20° C. in a 2% aqueous solution is in a range of 100-5000 mPa·s. The present invention relates to hydroxypropyl cellulose ...

Nitrogen-containing heterocyclic compound and salt thereof, and a fungicide for agricultural and horticultural use

The present invention provides a nitrogen-containing heterocyclic compound represented by formula (I) and salt thereof, which is useful as an active ingredient of a fungicide for agricultural and horticultural use, having an assured effect and being safely usable.

METHOD FOR PRODUCING POLYBUTADIENE

An object of the present invention is to provide a method for producing a polybutadiene by anionic polymerization at a low temperature, in which the microstructures thereof is controlled to polybutadienes having diverse physical properties. The present invention provides a method for producing a polybutadiene by anionic polymerization of 1,3-butadiene in the presence of a polymerization initiator and under the conditions of a reaction temperature not higher than the boiling point of butadiene, wherein the polymerization is performed in the presence of a potassium salt in an aprotic polar solvent or in a mixed solvent of an aprotic polar solvent and a nonpolar solvent. The potassium salt is preferably potassium t-butoxide, and the solvent is preferably a mixed solvent of tetrahydrofuran and hexane. The resultant polybutadiene can be used in an adhesive composition and in a plate-making material composition used for flexographic printing plates. 1. A method for producing a polybutadiene by anionic polymerization of 1 ,3-butadiene in the presence of a polymerization initiator and under the conditions of a reaction temperature not higher than the boiling point of butadiene , wherein the polymerization is carried out in the presence of a potassium salt in an aprotic polar solvent or in a mixed solvent of an aprotic polar solvent and a nonpolar solvent.2. The method for producing a polybutadiene according to claim 1 , wherein the potassium salt is potassium t-butoxide.3. The method for producing a polybutadiene according to claim 1 , wherein the mixed solvent of an aprotic polar solvent and a nonpolar solvent is a mixed solvent of tetrahydrofuran and hexane.4. A polybutadiene produced by the method according to claim 1 , having a microstructure ratio of 1 claim 1 ,2-structure/1 claim 1 ,4-structure ranging from 55/45 to 80/20 (% by mole) and having a molecular weight distribution ranging from 1.01 to 1.30.5. A plate-making material composition for flexographic printing ...

STYRENE POLYMER AND MANUFACTURING METHOD THEREFOR

A method for manufacturing a styrene polymer having a low number average molecular weight and a low polydispersity index, wherein the polymer has a number average molecular weight of 2000 or less and a polydispersity index of 1.01 to 1.10. For this purpose, the method includes polymerizing a styrene monomer in a solvent comprising an ether group-containing solvent in the presence of a polymerization initiator represented by formula [II], an organometallic compound represented by formula [III], and an organic potassium compound, at a temperature between −10° C. or higher and a boiling point of the solvent or lower. 1. A styrene polymer having a number average molecular weight of 2000 or less and a polydispersity index (Mw/Mn) of 1.01 to 1.10.5. The method for manufacturing a styrene polymer according to claim 3 , wherein the compound represented by formula [III] is dialkyl zinc claim 3 , dialkyl magnesium claim 3 , or trialkyl aluminum.8. The method for manufacturing a styrene polymer according to claim 3 , wherein the ether group-containing solvent is tetrahydrofuran. The present invention relates to a new styrene polymer having a low molecular weight and a low polydispersity index, and a method for manufacturing the same. Further, with respect to the manufacturing method, the present invention relates to a manufacturing method which can be applied not only to a new styrene polymer having a low molecular weight and a low polydispersity index, but also to a wide range of styrene polymers.The present application claims priority to Japanese Patent Application No. 2010-8509 filed on Jan. 18, 2010, the contents of which are incorporated herein by reference.There has been known a manufacturing method in which a styrene monomer is polymerized by anionic polymerization to obtain a styrene polymer having a low molecular weight and a low polydispersity index.For example, Patent Document 1 has disclosed a method for manufacturing a polymer having a low molecular weight and a ...

Polybutadiene derivative composition

An object of the present invention is to provide a composition containing a stabilizer which does not turn yellow upon curing and which acts as a polymerization inhibitor during production and storage of a (meth)acrylic modified (hydrogenated) polybutadiene. The curable composition is characterized in that it contains 0.1-99.9999% by weight of component (A) which is a (meth)acrylic modified (hydrogenated) polybutadiene, and 0.0001-10% by weight of component (B) which is a compound represented by formula (IV).

NITROGEN-CONTAINING HETEROCYCLIC COMPOUND AND AGRICULTURAL FUNGICIDE

Provided is an agricultural fungicide that contains at least one selected from the group consisting of a novel nitrogen-containing heterocyclic compound represented by Formula (I), a salt thereof, or an N-oxide compound thereof. In Formula (I), R represents a group represented by CRRRor a cyano group. Rto Reach independently represents a hydrogen atom, an unsubstituted or substituted Calkyl group, an unsubstituted or substituted hydroxyl group, or the like. R4 or R5 represents a halogeno group or the like. Y or Z represents a carbon atom or the like, and A or D represents a benzene ring or the like. X represents an oxygen atom or a nitrogen atom or the like. 4. An agricultural fungicide comprising claim 1 , as an active ingredient claim 1 , at least one selected from the group consisting of the nitrogen-containing heterocyclic compound claim 1 , the salt thereof claim 1 , and the N-oxide compound thereof claim 1 , of .5. An intermediate product of the nitrogen-containing heterocyclic compound claim 1 , the salt thereof claim 1 , or the N-oxide compound thereof claim 1 , of claim 1 , the intermediate product being selected from the group consisting of 8-fluoro-3-hydroxyquinoline claim 1 , 7 claim 1 ,8-difluoro-3-hydroxyquinoline claim 1 , 7 claim 1 ,8-difluoro-3-iodoquinoline claim 1 , 8-fluoro-3-hydroxy-2-methylquinoline claim 1 , and 7 claim 1 ,8-difluoro-3-hydroxy-2-methylquinoline. The present invention relates to novel nitrogen-containing heterocyclic compounds and an agricultural fungicide which contains at least one selected from the group consisting of the nitrogen-containing heterocyclic compounds as an active ingredient.Priority is claimed on Japanese Patent Application No. 2010-000194, filed Jan. 4, 2010, the content of which is incorporated herein by reference.In agricultural crop cultivation, a variety of control agents are used to deal with crop diseases. However, there are very few agents which fully satisfy the requirements for use as a control agent ...

TETRAZOLYLOXIME DERIVATIVE OR SALT THEREOF AND FUNGICIDE

There are provided a tetrazolyloxime derivative, a salt thereof, and a fungicide, that have excellent control effects against plant diseases. The fungicide contains, as an active ingredient, at least one selected from the group consisting of tetrazolyloxime derivatives represented by formula (6) and salts thereof. In formula (6), X represents a halogen atom, A represents a tetrazolyl group, R represents a halogen atom or the like, D represents a single bond or an oxygen atom, E represents a single bond or an alkylene chain, Rand Reach independently represents an alkoxy group or the like, and Rrepresents a hydrogen atom or an alkyl group. 3. A fungicide comprising , as an active ingredient thereof , at least one selected from the group consisting of the tetrazolyloxime derivative and the salt thereof according to or . The present invention relates to a novel tetrazolyloxime derivative or a salt thereof, and a fungicide containing, as an active ingredient thereof, at least one selected therefrom.The present application claims priority on the basis of Japanese Patent Application No. 2010-043348, filed in Japan on Feb. 26, 2010, the contents of which are incorporated herein by reference.In the cultivation of agricultural and horticultural crops, numerous fungicides have been proposed for use against damage to those crops. However, since conventional fungicides have inadequate control effects against plant diseases, have limited use due to the appearance of chemical-resistant pathogens, cause chemical damage or contamination of plants, or demonstrate potent toxicity against humans, livestock and fish, these fungicides are not considered to always be satisfactory. Thus, there is a strong need for the development of a novel fungicide that has few of these disadvantages and can be used safely.In relation to the present invention, the following Patent Documents 1 to 6 propose tetrazolyloxime derivatives having structures that resemble that of a compound according to the ...

PROCESS FOR PREPARATION OF t-BUTOXYCARBONYLAMINE COMPOUNDS

Provided is a process for the preparation of t-butoxycarbonylamine compounds, which comprises using phosgene or a phosgene equivalent, t-butanol, and an organic base. Even when applied to a primary or secondary amine compound having low nucleophilicity, the process enables highly selective preparation of a t-butoxycarbonylamine compound at a low cost. In the process, a t-butoxycarbonylamine compound is prepared using: phosgene or a phosgene equivalent; t-butanol; an organic base; and either a primary or secondary amine compound or a primary or secondary ammonium salt. 1. A process for producing a t-butoxycarbonylamine compounds comprising the use of phosgene or a phosgene equivalent , t-butanol , an organic base and a primary or secondary amine compound or primary or secondary ammonium salt , which includes any one of following processes (a) to (f):(a) a process comprising the addition of a solution containing a primary or secondary amine compound and an organic base to a solution containing phosgene or a phosgene equivalent and t-butanol;(b) a process comprising the addition of a solution containing a primary or secondary amine compound, an organic base and t-butanol to a solution containing phosgene or a phosgene equivalent;(c) a process comprising a substantially simultaneous addition of a solution containing a primary or secondary amine compound, a solution containing an organic base and a solution containing phosgene or a phosgene equivalent to a solution containing t-butanol;(d) a process comprising the addition of a solution containing a primary or secondary amine compound and a solution containing an organic base to a solution containing t-butanol while blowing in phosgene gas;(e) a process comprising the addition of a solution containing t-butanol, a primary or secondary amine compound and an organic base to a reaction solution while blowing in phosgene gas; and,(f) a process comprising the addition of an organic base to a solution containing phosgene or a ...

REDUCTION TREATMENT METHOD FOR BALLAST WATER

The present invention relates to a method for reduce treating ballast water which has been subjected to a biocidal treatment with a chlorine-based oxidizing agent or an oxygen-based oxidizing agent, by using a tablet or pellet of sodium sulfite. 1. A method for reduce treating ballast water which has been subjected to a biocidal treatment with a chlorine-based oxidizing agent or an oxygen-based oxidizing agent , by using a tablet or pellet of sodium sulfite.2. The method for reduce treating ballast water according to claim 1 , comprising bringing the ballast water which has been subjected to the biocidal treatment into contact with the tablet or pellet of sodium sulfite.3. The method for reduce treating ballast water according to claim 1 , comprising dissolving or suspending the tablet or pellet of sodium sulfite in water claim 1 , and adding the resulting aqueous solution or suspension to the ballast water which has been subjected to the biocidal treatment.4. The method for reduce treating ballast water according to claim 1 , comprising filling a container with the tablet or pellet of sodium sulfite claim 1 , and allowing the ballast water which has been subjected to the biocidal treatment to pass through an inner cavity of the container claim 1 , thereby bringing it into contact with the tablet or pellet of sodium sulfite.5. The method for reduce treating ballast water according to claim 1 , wherein the ballast water which has been subjected to the biocidal treatment with the chlorine-based oxidizing agent is one obtained by electrolysis of a ballast water.6. A tablet or pellet comprising sodium sulfite and an excipient.7. The tablet or pellet according to claim 6 , wherein the excipient comprises sodium chloride.8. The tablet or pellet according to claim 6 , wherein the excipient is substantially composed of sodium chloride.9. The tablet or pellet according to claim 6 , wherein a weight ratio of sodium sulfite to the excipient is from 40/60 to 60/40.10. The ...

NOVEL COPOLYMER

The present invention provides a novel copolymer useful as a dispersing agent for a pigment or the like. The novel copolymer contains a block chain (A) consisting of a polymer comprising at least one repeating unit selected from the group consisting of a repeating unit having a tertiary amino group and a repeating unit having a quaternary ammonium base; and a block chain (B) consisting of a copolymer comprising a repeating unit having a polyoxyalkylene chain and a repeating unit having an acidic group. The at least one repeating unit selected from the group consisting of a repeating unit having a tertiary amino group and a repeating unit having a quaternary ammonium base is, for example, a repeating unit represented by the following formula (II), and the repeating unit having a polyoxyalkylene chain is, for example, a repeating unit represented by the following formula (III): 1. A copolymer comprising:a block chain (A) consisting of a polymer comprising at least one repeating unit selected from the group consisting of a repeating unit having a tertiary amino group and a repeating unit having a quaternary ammonium base; anda block chain (B) consisting of a copolymer comprising a repeating unit having a polyoxyalkylene chain and a repeating unit having an acidic group. The present invention relates to a novel copolymer useful as a dispersing agent. The present application claims the benefit of priority from Japanese Patent Application No. 2010-092984, filed on Apr. 14, 2010, the contents of which are incorporated herein by reference.Copolymer-type pigment dispersing agents have been developed in a variety of fields.In the field of top coats for automotive finish, a pigment dispersion resin capable of providing an aqueous pigment dispersion that has, for example, low viscosity even at a high pigment concentration and is good at chromogenic properties as well as good in finished appearance and film performances of a coated film has been developed. Patent Document 1 ...

NITROGEN-CONTAINING HETEROCYCLIC COMPOUND AND METHOD FOR PRODUCING SAME

There are provided a nitrogen-containing heterocyclic compound such as a substituted amino-pyridine-N-oxide compound represented by formula (1), which is useful as a synthetic intermediate for an agrochemical and the like; and a method for producing the nitrogen-containing heterocyclic compound. (In formula (1), Rand Reach represents a hydrogen atom or an unsubstituted or substituted alkyl group; Rrepresents a hydrogen atom, an unsubstituted or substituted alkylcarbonyl group or the like; Rrepresents an unsubstituted or substituted alkylcarbonyl group, an unsubstituted or substituted arylcarbonyl group or the like; A represents a hydroxyl group, a thiol group or the like; m represents any one of integers of 1 to 4; k represents any one of integers of 0 to 3; and k+m≦4.) 3. The method for producing a substituted amino-6-methylpyridine-N-oxide derivative according to claim 2 , wherein Rin formula (2) and in formula (1-a) is a hydrogen atom.4. The method for producing a substituted amino-6-methylpyridine-N-oxide derivative according to claim 2 , wherein the quaternary nitrogen cation represented by Q in formula (3) is a quaternary ammonium.5. The method for producing a substituted amino-6-methylpyridine-N-oxide derivative according to claim 2 , wherein the tungstophosphoric acid salt represented by formula (3) is obtained without an isolation operation after preparation.7. The method for producing a nitrogen-containing heterocyclic compound according to claim 6 , wherein all of ato ain formula (4) and formula (5) represent carbon atoms.10. The method for producing a nitrogen-containing heterocyclic compound according to claim 8 , wherein Rrepresents an unsubstituted or substituted alkylcarbonyl group claim 8 , an unsubstituted or substituted arylcarbonyl group claim 8 , or an unsubstituted or substituted alkoxycarbonyl group.11. The method for producing a nitrogen-containing heterocyclic compound according to claim 6 , wherein the halogenating agent is at least one ...

STAR POLYMER AND METHOD OF PRODUCING SAME

The present invention provides a styrene-based star polymer with narrow dispersion and suitable as a resist material, etc. A star polymer of the present invention is represented by the formula A[C(Y)X](wherein A represents a polyvalent aliphatic hydrocarbon group with 4-15 carbons, C represents a carbon atom, X represents a styrene-based polymer chain, Y represents a hydroxy group or an oxo group, m represents an integer of 1 or 2, and n represents any integer from 2 to 5, with the proviso that if Y is a hydroxy group, m is 2, and if Y is an oxo group, m is 1). The star polymer can be produced by reacting a styrene-based polymer having an anionic end, and an aliphatic carboxylic acid ester represented by A(COOR)(wherein R represents an alkyl group having 1-8 carbons, and A and n are as defined for the above formula). 1. A star polymer represented by the formula A[C(Y)X](wherein A represents a polyvalent aliphatic hydrocarbon group having 4-15 carbons , C represents a carbon atom , X represents a styrene-based polymer chain , Y represents a hydroxy group or an oxo group , m represents an integer of 1 or 2 , and n represents any integer from 2 to 5 , with the proviso that if Y is a hydroxy group , m is 2 , and if Y is an oxo group , m is 1).2. The star polymer according to claim 1 , wherein the styrene-based polymer is a homopolymer or copolymer of hydroxystyrene.3. A method for producing the star polymer according to claim 1 , comprising reacting a styrene-based polymer having an anionic end with an aliphatic carboxylic acid ester represented by A(COOR)(wherein R represents an alkyl group having 1-8 carbons claim 1 , and A represents a polyvalent aliphatic hydrocarbon group having 4-15 carbons and n represents any integer from 2 to 5). The present invention relates to a star polymer and a method for producing the same. The present invention particularly relates to a styrene-based star polymer with narrow dispersion which is suitable as a resist material, etc. and a ...

CURABLE POWDER COATING COMPOSITION, AND CURED PRODUCT OF SAME

Disclosed is an epoxy or epoxy-polyester curable powder coating composition which can form a favorable cured coating film excellent in adhesion and solvent resistance and is excellent in storage stability. The curable powder coating composition of the present invention contains the following component (A) and component (B): (A) an epoxy resin or an epoxy-polyester hybrid resin; and (B) a clathrate complex which contains (b1) at least one selected from the group consisting of a carboxylic acid compound and a tetrakisphenol compound represented by the following formula (I), and (b2) at least one selected from compounds represented by formula (II). The carboxylic acid compound preferably includes an aromatic carboxylic acid. 2. The curable powder coating composition according to claim 1 , wherein the carboxylic acid compound in (b1) is an aromatic carboxylic acid compound.4. The curable powder coating composition according to claim 3 , wherein the isophthalic acid compound is 5-t-butyl isophthalic acid claim 3 , 5-nitroisophthalic acid claim 3 , or 5-hydroxyisophthalic acid.5. The curable powder coating composition according to claim 1 , wherein the imidazole compound or the imidazoline compound represented by formula (II) represents imidazole claim 1 , 2-ethyl-4-methylimidazole claim 1 , 1-methylimidazole claim 1 , 2-methylimidazole claim 1 , 4-methylimidazole claim 1 , 1 claim 1 ,2-dimethylimidazole claim 1 , 1-benzyl-2-methylimidazole claim 1 , 2-heptadecylimidazole claim 1 , 2-undecylimidazole claim 1 , 2-phenylimidazole claim 1 , 2-phenyl-4-methyl-5-hydroxymethylimidazole claim 1 , 2-methylimidazoline or 2-phenylimidazoline.6. A cured product of the curable powder coating composition according to .7. The curable powder coating composition according to claim 2 , wherein the imidazole compound or the imidazoline compound represented by formula (II) represents imidazole claim 2 , 2-ethyl-4-methylimidazole claim 2 , 1-methylimidazole claim 2 , 2-methylimidazole claim ...

PROCESS FOR PRODUCTION OF REPLICA MOLD FOR IMPRINTING USE

The present invention provides a method for producing a replica mold for imprinting use which is inexpensive and has good properties including strength and flexibility. The method for producing a replica mold according to the present invention comprises the steps of: (A) coating a substrate with an organic-inorganic hybrid material; (B) semi-curing the coated surface with heat and/or an electromagnetic ray to produce a substrate for fine raised and depressed pattern formation; (C) pressing a master mold having a predetermined fine raised and depressed pattern formed thereon against the substrate for fine raised and depressed pattern formation by an imprinting method to transfer the fine raised and depressed pattern onto the substrate; and (D) irradiating the substrate for fine raised and depressed pattern formation onto which the fine raised and depressed pattern is transferred with an electromagnetic ray to cure the substrate. 1. A method for producing a replica mold comprising the steps of:(A) coating a substrate with an organic-inorganic hybrid material;(B) semi-curing a coated surface with heat and/or an electromagnetic ray to produce a substrate for fine raised and depressed pattern formation;(C) pressing a master mold having a predetermined fine raised and depressed pattern formed thereon against the substrate for fine raised and depressed pattern formation by an imprinting method to transfer the fine raised and depressed pattern onto the substrate; and(D) irradiating the substrate for fine raised and depressed pattern formation onto which the fine raised and depressed pattern is transferred with an electromagnetic ray to cure the substrate.2. The method for producing a replica mold according to claim 1 , further comprising the step of (E) applying a mold releasing layer onto a surface of the fine raised and depressed pattern obtained in the step (D).3. The method for producing a replica mold according to claim 1 , wherein the organic-inorganic hybrid material ...

NOVEL COPOLYMER

An object of the present invention is to provide a novel copolymer useful as a dispersing agent for a pigment or the like. The novel copolymer contains: a block chain (A) comprising at least one repeating unit selected from the group consisting of a repeating unit having a tertiary amino group and a repeating unit having a quaternary ammonium salt group; and a block chain (B) comprising a repeating unit having an acidic group and a repeating unit represented by the following formula (I) (wherein Rrepresents a hydrogen atom or a C1-C3 alkyl group; and Rrepresents an aliphatic hydrocarbon group or an alicyclic hydrocarbon group), wherein the repeating unit represented by formula (I) has a copolymerization ratio of 90 mass % or more in the block chain (B). The present invention relates to a novel copolymer useful as a dispersing agent. The present application claims the benefit of priority from Japanese Patent Application No. 2010-148859, filed on Jun. 30, 2010, the contents of which are incorporated herein by reference.Copolymer-type pigment dispersing agents have been developed in a variety of fields.Pigment dispersing agents that improve, for example, the dispersibility, fluidity, storage stability, post-drying redissolution properties and substrate adhesion of pigments for ink, particularly, carbon black, have been developed. Patent Document 1 discloses a pigment composition comprising a pigment, an organic dye derivative containing an acidic functional group, an alkali-soluble resin and an organic solvent, wherein the alkali-soluble resin having an amino group and/or a quaternary ammonium group thereof has a basic equivalent of 3000 to 20000 g/eq and an acid number of 30 to 200 mgKOH/g. Specifically, the document describes a random copolymer of n-butyl methacrylate, methyl methacrylate, methacrylic acid and dimethylaminoethyl methacrylate, or the like as the alkali-soluble resin.Since the random copolymer of n-butyl methacrylate, methyl methacrylate, methacrylic ...

Organic-inorganic complex and composition for forming same

It is an object of the present invention to provide a polysiloxane-based organic-inorganic complex in which the surface has higher hardness than the inside, the organic-inorganic complex having high surface hardness and anti-Newton ring properties, having a low haze factor, being capable of preventing glare, and being further capable of also having anti-glare properties. The organic-inorganic complex of the present invention is made using an organic-inorganic complex-forming composition containing the following components a) to d): a) an organic silicon compound represented by formula (I): R n SiX 4-n , and/or a condensate thereof; b) a silanol condensation catalyst; c) an electromagnetic ray-curable compound; and d) metal compound particles that are a mixture of metal compound particles having an isoelectric point of less than 5 as a metal oxide and metal compound particles having an isoelectric point of 5 or more as a metal oxide.

OPTICALLY ACTIVE AMMONIUM SALT COMPOUND, PRODUCTION INTERMEDIATE THEREOF, AND PRODUCTION METHOD THEREOF

An optically active bisbenzyl compound or a racemic bisbenzyl compound represented by formula (2) that has axial chirality. An optically active azepine derivative or a racemic azepine derivative represented by formula (3). Methods of producing an optically active quaternary ammonium salt compound represented by formula (8). This is a divisional of application Ser. No. 11/817,585 filed Sep. 25, 2009, which is a National Stage application of PCT/JP2006/304091 filed Mar. 3, 2006, and claims the benefit of Japanese Patent Application Nos. 2005-059694 and 2005-192757 filed Mar. 3, 2005 and Jun. 30, 2005. The entire disclosures of the prior applications are hereby incorporated by reference herein in their entirety.The present invention relates to a compound of an optically active quaternary ammonium salt which is useful as a chiral phase transfer catalyst and more specifically, relates to a novel optically active quaternary ammonium salt, and an intermediate and production method for producing said compound.Priority is claimed on Japanese Patent Applications No. 2005-059694, filed Mar. 3, 2005, and No. 2005-192757, filed Jun. 30, 2005, the contents of which are incorporated herein by reference.Many compounds regarding optically active spiro quaternary ammonium salts have been known to date. Examples thereof include the compound described in Patent document 1 and represented by the following formulaand the compound described in Patent document 3, and the documents disclose that these compounds perform extremely effectively as a phase transfer catalyst for synthesizing optically active α-amino acids regardless of being natural or not. However, the optically active Spiro quaternary ammonium salts described in these documents are expensive since they are constituted from two kinds of binaphthyl derivatives having different substituents, and thus they are not necessarily satisfactory for industrial use.Moreover, the compound represented by the following formula is described in ...

RECORDING MATERIAL USING PHENOL COMPOUND

An object of the present invention is to provide a recording material or a recording sheet that is excellent not only in whiteness of a background but also in storage property for a background and an image, and further has excellent dynamic sensitivity. In order to achieve the object, a phenol compound represented by Formula (I) [wherein Rrepresents a hydroxyl group or a halogen atom, p represents 0 or an integer of 1 to 5, Rand Reach independently represent a hydrogen atom or a C-Calkyl group, Rrepresents a hydrogen atom, a C-Calkyl group, an optionally substituted phenyl group or an optionally substituted benzyl group; and a bond shown with a wavy line represents E- or Z-form, or a mixture thereof] and having a color space b* of 10 or less, and preferably having brightness by Hunter of 75 or more, is used as a recording material. 2. The phenol compound according to claim 1 , wherein the phenol compound has brightness by Hunter of 75 or more.4. The phenol compound according to claim 3 , wherein the base is a weak alkaline inorganic compound.5. The phenol compound according to claim 3 , wherein the crystallization is conducted by using a polar solvent as a crystallization solvent.6. A recording material comprising a color former and at least one phenol compound according to .7. A recording sheet comprising claim 6 , on a support claim 6 , a recording material layer made of a recording material according to . The present invention relates to a thermal or pressure sensitive recording material utilizing color development caused through a reaction between a color former and a color developer.This application claims the benefit of priority of the prior Japanese Patent Application No. 2010-195363, filed on Sep. 1, 2010, the entire contents of which are incorporated herein by reference.Recording materials utilizing color development caused through a reaction between a color former and a color developer are widely used as thermal recording paper for outputting/recording by ...

Nitrogen-containing heterocyclic compound and pest control agent

The present invention offers compounds or their salts expressed by formula (I) (in the formula, X indicates an alkyl group, or the like; Y indicates an alkyl group; Z indicates a respectively independent nitro group, or the like; n indicates any integer from 0 to 3; A indicates carbon atom, or the like, and hydrogen atom is bonded thereto in the case where the carbon atom is not substituted with Z; D indicates oxygen atom, or the like; W indicates hydrogen atom, or the like; R 1 and R 2 indicate respectively independent hydrogen atoms, or the like; R 1 and R 2 may be bonded, and may form a heterocycle together with the nitrogen atom between R 1 and R 2 ).

LIQUID CURABLE EPOXY RESIN COMPOSITION AND ADHESIVE AGENT CONTAINING SAME

An object of the present invention is to provide a curable epoxy resin composition containing an epoxy resin, wherein the composition is excellent in storage stability and curing characteristics and provides a cured product excellent in characteristics, particularly organic solvent resistance; an adhesive agent consisting of the composition; and an adhesive agent consisting of a curable epoxy resin composition excellent in adhesive strength. The curable epoxy resin composition of the present invention is a liquid curable epoxy resin composition containing the following (A) and (B): (A) an epoxy resin or an epoxy-polyester hybrid resin; and (B) a clathrate containing the following (b1) and (b2): (b1) at least one compound selected from the group consisting of a carboxylic acid compound represented by the formula A(COOH)(wherein A represents a C1-C6 chain hydrocarbon group optionally having a substituent, a C3-C10 monocyclic hydrocarbon group optionally having a substituent, or a C6-C10 bicyclic hydrocarbon group optionally having a substituent; and a represents 2 or 3) and the like; and (b2) at least one compound selected from the group consisting of a compound represented by formula (II) and 1,8-diazabicyclo[5.4.0]undecene-7. 4. The liquid curable epoxy resin composition according to claim 3 , wherein the compound represented by formula (V) is 5-t-butylisophthalic acid claim 3 , 5-hydroxyisophthalic acid claim 3 , or 5-nitroisophthalic acid.5. An adhesive agent containing a liquid curable epoxy resin composition according to .6. The adhesive agent according to claim 5 , wherein the number of moles of component (b2) in component (B) is 0.008 to 0.4 with respect to 1 mol of epoxy group of component (A).8. An adhesive agent containing a liquid curable epoxy resin composition according to .9. An adhesive agent containing a liquid curable epoxy resin composition according to .10. An adhesive agent containing a liquid curable epoxy resin composition according to .11. The ...

METHOD FOR PRODUCING TERMINAL ACRYLIC-MODIFIED POLYBUTADIENE OR TERMINAL ACRYLIC-MODIFIED HYDROGENATED POLYBUTADIENE, AND COMPOSITION CONTAINING SAME

The present invention provides a method for producing a terminal acrylic-modified polybutadiene or terminal acrylic-modified hydrogenated polybutadiene that does not become white and turbid, without using an organotin compound. The production method of the present invention comprises reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organobismuth compound and a tetraalkoxyzirconium compound. 4. The production method according to claim 1 , wherein the tetraalkoxyzirconium compound is a compound represented by formula (IX):{'br': None, 'sup': '21', 'sub': '4', 'Zr—(OR)\u2003\u2003(IX)'}{'sup': '21', '(wherein Rrepresents a C1 to C20 alkyl group having a straight chain or a branched chain, and may be the same or different.)'}6. The terminal acrylic-modified polybutadiene or terminal acrylic-modified hydrogenated polybutadiene composition according to claim 5 , wherein the at least one selected from an organobismuth compound and a tetraalkoxyzirconium compound is contained in an amount of 0.001 parts by weight to 10 parts by weight with respect to 100 parts by weight of the terminal acrylic-modified polybutadiene or terminal acrylic-modified hydrogenated polybutadiene represented by formula (X).8. The production method according to claim 2 , wherein the tetraalkoxyzirconium compound is a compound represented by formula (IX):{'br': None, 'sup': '21', 'sub': '4', 'Zr—(OR)\u2003\u2003(IX)'}{'sup': '21', '(wherein Rrepresents a C1 to C20 alkyl group having a straight chain or a branched chain, and may be the same or different.)'} The present invention relates to a method for producing a terminal acrylic-modified polybutadiene or terminal acrylic-modified hydrogenated polybutadiene. In addition, the present invention relates to a ...

NOVEL COPOLYMER

An object of the present invention is to provide a novel copolymer useful as a pigment dispersing agent in the field of color liquid crystal displays and the like. A copolymer of the present invention contains a block chain (A) comprising at least one repeating unit selected from the group consisting of a repeating unit having a tertiary amino group and a repeating unit having a quaternary ammonium base; and a block chain (B) comprising a repeating unit represented by formula (I) (wherein Rrepresents a hydrogen atom or the like, Rand Reach independently represent a hydrogen atom or the like, Q represents an oxygen-containing saturated heterocyclic group optionally having an alkyl group as a substituent or the like, and n represents an integer of 0 to 6), and a repeating unit represented by formula (II) (wherein Rrepresents a hydrogen atom or the like and Rrepresents a saturated aliphatic hydrocarbon group or the like), and a copolymerization ratio of the repeating unit represented by formula (II) is 90 wt % or more in the block chain (B) excluding the repeating unit represented by formula (I). 3. The copolymer according to claim 1 , wherein the copolymer has ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) of 1.01 to 2.00.4. The copolymer according to claim 1 , wherein the copolymer has a weight average molecular weight (Mw) of 2000 to 50000. The present invention relates to a novel copolymer useful as a dispersing agent. The present application claims the benefit of priority from Japanese Patent Application No. 2010-249493, filed on Nov. 8, 2010, the contents of which are incorporated herein by reference.Copolymer-type pigment dispersing agents have been developed in a variety of fields.In the field of, for example, color liquid crystal displays, a copolymer-type pigment dispersing agent is used as a dispersing agent for a pigment to be contained in a radiosensitive composition used for forming a color layer. In this ...

PROCESS FOR PRODUCING ORGANIC THIN FILM LAMINATE USING SOLID OR OILY MATERIAL FOR ORGANIC THIN FILM FORMATION APPLICATIONS

A solid material or an oily material for forming an organic thin film is produced by hydrolyzing and condensing at least one kind of organic metal compound expressed by Formula (1) in a lower alcohol-based solvent in the presence of water and an acid with a concentration of 0.5% to 5% by mass in the resultant reaction solution. The solid material or oily material that is obtained is dissolved in an organic solvent, and a substrate is brought into contact with a solution that is obtained to form a highly functional organic thin film on the substrate. 1. A method for producing an organic thin film-laminated plate , the method comprising: [{'br': None, '[Chemical Formula 1]'}, {'br': None, 'sup': '1', 'sub': n', 'm−n, 'RMX\u2003\u2003(I),'}], 'process (A): a process of hydrolyzing and/or condensing at least one kind of organic metal compound expressed by Formula (I) in a lower alcohol-based solvent or a mixed solvent containing the lower alcohol-based solvent in the presence of water and an acid with a concentration of 0.5% to 5% by mass in the resultant reaction solution, or a process of hydrolyzing and/or condensing the organic metal compound in a solvent that contains at least one kind selected from an aliphatic ether-based solvent and an aliphatic ketone-based solvent and does not contain the lower alcohol solvent in the presence of water and an acid of 0.1 to 20 moles with respect to 1 mole of the organic metal compound expressed by Formula (I),'}{'sup': 1', '1, 'wherein in the formula, Rrepresents a hydrocarbon group having 1 to 30 carbon atoms and optionally having a substituent group, or a halogenated hydrocarbon group having 1 to 30 carbon atoms and optionally having a substituent group, M represents at least one kind of metal atom selected from the group consisting of Si, Ge, Sn, Ti, and Zr, X represents a hydroxyl group or a hydrolysable group, n represents any integer of 1 to (m−1), m represents an atomic valence of M, in a case where n is 2 or more, Ris ...

PRODUCTION PROCESS OF OPTICALLY ACTIVE 3-QUINUCLIDINOL DERIVATIVE

A process is provided for efficiently producing an optically active 3-quinuclidinol derivative of high optical purity using a readily available ruthenium compound as an asymmetric reduction catalyst. This process is a process for producing an optically active 3-quinuclidinol derivative represented by the following formula (III) comprising asymmetrically hydrogenating a 3-quinuclidinone derivative represented by the following formula (I) in the presence of a ruthenium compound (II) represented by formula (II): Ru(X)(Y)(P)[RRC*(NRR)-A-RRC*(NRR)] (in the formulas, R represents a hydrogen atom or C7 to C18 aralkyl group and the like, X and Y represent hydrogen atoms or halogen atoms and the like, Px represents a phosphine ligand, n represents 1 or 2, R1 to R8 represent hydrogen atoms or C1 to C20 alkyl groups and the like, * represents an optically active carbon atom and A represents an ethylene group and the like). 15-. (canceled) The present invention relates to a process for producing optically active 3-quinuclidinol derivatives that are useful as production raw materials of physiologically active substances, and particularly pharmaceuticals.The present application claims priority on Japanese Patent Application No. 2007-230973, filed on Sep. 6, 2007, and Japanese Patent Application No. 2008-032311, filed on Feb. 13, 2008, the contents of which are incorporated herein by reference.Many alkaloids, and particularly those compounds having an azabicyclo ring structure, are useful as physiologically active substances. In particular, optically active 3-quinuclidinol derivatives are important compounds as production raw materials of pharmaceuticals.A conventionally known process for industrial production of optically active 3-quinuclidinol consists of direct asymmetric hydrogenation of 3-quinuclidinone using inexpensive hydrogen gas for the hydrogen source in the presence of an asymmetric hydrogenation catalyst (Patent Documents 1 to 4).In this production process, an ...

HYDROXYALKYL CELLULOSE

The present invention provides a hydroxyalkyl cellulose having a viscosity of 1.10 mPa·s to 1.95 mPa·s in a 2%-concentration aqueous solution at 20° C., and a solid formulation containing the hydroxyalkyl cellulose. 1. A hydroxyalkyl cellulose that has a viscosity of 1.10 mPa·s to 1.95 mPa·s in a 2%-concentration aqueous solution at 20° C.2. A solid formulation comprising the hydroxyalkyl cellulose according to .3. The solid formulation according to claim 2 , whereinthe solid formulation is a tablet.4. The solid formulation according to claim 2 , whereinthe content of the hydroxyalkyl cellulose in the solid formulation is 1% by weight to 30% by weight.5. Coating particles comprising:core particles; anda coating layer that covers the core particles, whereinthe coating layer contains a hydroxyalkyl cellulose that has a viscosity of 1.10 mPa·s to 1.95 mPa·s in a 2%-concentration aqueous solution at 20° C.6. The coating particles according to claim 5 , whereina volume average primary particle size of the core particles 5 μm to 1000 μm.7. The coating particles according to claim 5 , whereinthe content of the hydroxyalkyl cellulose in the coating layer is 1% by weight to 50% by weight.8. The coating particles according to claim 5 , whereinthe coating layer further contains drug particles.9. The coating particles according to claim 8 , whereina volume average primary particle size of the drug particles is smaller than a volume average primary particle size of the core particles. The present invention relates to a hydroxyalkyl cellulose that is suitable for producing an orally-disintegrating agent, a gastro-soluble solid formulation, an entero-soluble solid formulation, a slow-release solid formulation, a bitterness-suppressing solid formulation, and the like.Priority is claimed on Japanese Patent Application No. 2010-270172, filed Dec. 3, 2010, the content of which is incorporated herein by reference.A method of producing an orally-disintegrating agent or the like, which ...

REWRITABLE RECORDING MATERIAL

A rewritable recording material can be provided which contains at least one kind of phenolic compounds represented by formula (I) and which is capable of stably repeating coloring and discoloring for a long period of time as well as exerting superior storage properties such as heat resistance and moisture and heat resistance of the colored image and light resistance of the background. Also provided are a composition for forming a rewritable color-forming layer which is capable of forming a color-forming layer of the recording material, and a composition of a color-developing agent for a rewritable recording material. 2. The method of claim 1 , wherein the phenolic compound is incorporated into a rewritable color-forming layer of a rewritable recording material comprising a color-forming layer on a substrate claim 1 , wherein the color-forming layer contains a color-forming compound.3. The method of claim 2 , wherein the substrate is a paper claim 2 , synthetic resin film or synthetic resin sheet. The present application is a Continuation of U.S. application Ser. No. 13/138,302, filed Feb. 1, 2010, which claims priority to Japanese Patent Application Nos. 2009-22195 and 2009-158763 respectively filed on Feb. 3, 2009 and Jul. 3, 2009, the entire contents of which are hereby incorporated by reference.The present invention relates to a rewritable recording material capable of forming and erasing the colored image.Recording materials that utilize color formation resulted by reaction of a color-forming compound and a color-developing agent makes it possible to carry out recording in a short time with a relatively simple device without conducting cumbersome treatments such as developing/fixing. Such recording materials are thus widely used for thermal recording papers used for output recording such as for a facsimile and a printer.On the other hand, there is proposed a so-called rewritable recording material that can form and erase the colored image on a color-forming ...

AGRICULTURAL CHEMICAL COMPOSITION AND FRUIT BAG

The present invention provides an agricultural chemical composition containing an agricultural chemical active ingredient A, a sorbitan fatty acid ester and a wax, and a production process thereof. In addition, the present invention provides an agricultural chemical sheet or a fruit bag in which the agricultural chemical composition is retained, and a production process thereof. 112-. (canceled)13. A production process of agricultural chemical sheet or fruit bag comprisingmelting an agricultural chemical composition by heating, andcoating or impregnating the melt in a sheet base material or a bag base material, whereinthe agricultural chemical composition includes an agricultural chemical active ingredient A, a sorbitan fatty acid ester and a wax, andthe agricultural chemical active ingredient A is a neonicotinoid-based compound.14. The production process of agricultural chemical sheet or fruit bag according to claim 13 , whereinThe neonicotinoid-based compound has a saturated solubility in water at 25° C. of 500 ppm or more.15. The production process of agricultural chemical sheet or fruit bag according to claim 13 , whereinthe neonicotinoid-based compound is at least one selected from the group consisting of nitenpyram, imidacloprid, acetamiprid, thiamethoxam, clothianidin and dinotefuran.16. The production process of agricultural chemical sheet or fruit bag according to claim 13 , whereinthe neonicothinoid-based compound is acetamiprid.17. The production process of agricultural chemical sheet or fruit bag according to claim 13 , whereinthe agricultural chemical composition further includes an agricultural chemical active ingredient B composed of an organic salt.18. The production process of agricultural chemical sheet or fruit bag according to claim 17 , whereinThe agricultural chemical active ingredient B is iminoctadine albesilate.19. The production process of agricultural chemical sheet or fruit bag according to claim 13 , whereinthe wax is microcrystalline ...

PROCESS FOR PRODUCTION OF FLUOROSULFONYLIMIDE AMMONIUM SALT

A compound [I] such as ammonium N-(chlorosulfonyl)-N-(fluorosulfonyl)imide is reacted with hydrogen fluoride to obtain a compound [II] such as ammonium N,N-di(fluorosulfonyl)imide. The obtained compound [II] is reacted with an alkali metal compound or the like to obtain a compound [IV] such as an N,N-di(fluorosulfonyl)imide alkali metal salt. 4. The process disclosed according to claim 3 , wherein the fluorosulfonylimide ammonium salt represented by formula II is reacted with an alkali metal hydroxide or a tertiary amine compound claim 3 , and M in formula IV represents an alkali metal cation or a tertiary ammonium cation. The present invention relates to a process for producing a fluorosulfonylimide ammonium salt. More specifically, the present invention relates to a process for producing a fluorosulfonylimide ammonium salt with good efficiency and maximum suppression of the contamination of metal impurities that degrade electrolyte properties and the like.Priority is claimed on Japanese Patent Application No. 2011-027563, filed Feb. 10, 2011, the content of which is incorporated herein by reference.Fluorosulfonylimide salts are useful compounds in a wide variety of fields, and are used as electrolytes, as additives added to the electrolytes of fuel cells, and as selective electron withdrawing compounds and the like (see Patent Document 1). Fluorosulfonylimide alkali metal salts and various fluorosulfonylimide onium salts can be obtained by reactions using an alkali metal compound or an onium compound. Fluorosulfonylimide ammonium salts are useful as production intermediates for fluorosulfonylimide alkali metal salts and fluorosulfonylimide onium salts other than the ammonium salts.Various processes have been proposed for synthesizing fluorosulfonylimide ammonium salts. For example, Non-Patent Document 1 discloses a process of synthesizing a di(fluorosulfonyl)imide ammonium salt from di(fluorosulfonyl)imide and ammonia.Patent Document 2 discloses a process for ...

PROCESS FOR PRODUCING FLUORINE-CONTAINING SULFONYLIMIDE SALT

By reacting a fluorine-containing sulfonylimide ammonium salt such as ammonium N,N-di(fluorosulfonyl)imide with an alkali metal hydroxide such as lithium hydroxide, potassium hydroxide or sodium hydroxide under reduced pressure and at a low temperature of approximately 40° C., a fluorine-containing sulfonylimide alkali metal salt such as lithium N,N-di(fluorosulfonyl)imide, potassium N,N-di(fluorosulfonyl)imide or sodium N,N-di(fluorosulfonyl)imide is obtained. 2. The process for producing a fluorine-containing sulfonylimide salt according to claim 1 , wherein the at least one compound is selected from the group consisting of alkali metal hydroxides and onium hydroxides. The present invention relates to a process for producing a fluorine-containing sulfonylimide salt. More specifically, the present invention relates to a process for efficiently producing a fluorine-containing sulfonylimide alkali metal salt or a fluorine-containing sulfonylimide onium salt (excluding the ammonium salt) from a fluorine-containing sulfonylimide ammonium salt.Priority is claimed on Japanese Patent Application No. 2011-046739, filed Mar. 3, 2011, the content of which is incorporated herein by reference.Fluorine-containing sulfonylimide salts are useful compounds in a wide variety of fields, and are used as electrolytes, as additives added to the electrolytes of fuel cells, and as selective electron withdrawing materials and the like (see Patent Document 1).Various processes have been proposed for synthesizing fluorine-containing sulfonylimide salts. For example, Patent Document 2 proposes a process for producing a fluorine-containing sulfonylimide salt by reacting a fluorine-containing sulfonylimide onium salt with an alkali metal compound. Specifically, in Patent Document 2, triethylammonium N-(fluorosulfonyl)-N-(trifluoromethylsulfonyl)imide and an aqueous solution prepared by dissolving lithium hydroxide monohydrate are mixed together under normal pressure, and the solvent is then ...

GLUTAMIC ACID BENZYL ESTER N-CARBOXYLIC ANHYDRIDE

An object of the present invention is to provide crystal polymorphs which have a high bulk density and are excellent in storage stability, among crystal polymorphs of a glutamic acid benzyl ester N-carboxylic anhydride. According to the present invention, the crystal polymorphs of glutamic acid benzyl ester N-carboxylic anhydride that have a bulk density of 0.45 g/cmor higher can be obtained by dissolving glutamic acid benzyl ester N-carboxylic anhydride in a solvent which has been heated at a temperature equal to or higher than 40° C. and lower than a boiling point thereof and is in an amount of 0.5 L or more per mol of the glutamic acid benzyl ester N-carboxylic anhydride, adding a poor solvent which is in an amount of 1.4 L or more per mol of the glutamic acid benzyl ester N-carboxylic anhydride at a temperature equal to or higher than 40° C. and lower than a boiling point thereof, precipitating crystals at a temperature equal to or higher than 40° C. and lower than a boiling point thereof, and cooling the crystals. 1. A glutamic acid benzyl ester N-carboxylic anhydride that includes crystal polymorphs (crystals A) having peaks at 6.5° , 13.0° , and 19.5° at an angle of diffraction (2 θ°) in a powder X-ray diffraction diagram using CuKα rays as an X-ray source and has a bulk density of 0.45 g/cmor greater.2. The glutamic acid benzyl ester N-carboxylic anhydride according to that includes the crystals A claim 1 ,wherein the crystals A differ from each other in terms of preferred orientation and have peaks at 15.0°, 17.3°, 18.9°, 19.9°, 21.2°, 23.2°, 23.9°, 25.0°, and 27.7° at an angle of diffraction (2 θ°) in a powder X-ray diffraction diagram using CuKα rays as an X-ray source.3. A method for crystallizing a glutamic acid benzyl ester N-carboxylic anhydride claim 1 , comprising:dissolving glutamic acid benzyl ester N-carboxylic anhydride in a solvent which has been heated at a temperature equal to or higher than 40° C. and lower than a boiling point thereof and ...

CROSS-LINKED CYCLIC AMINE COMPOUNDS AND AGENTS FOR PEST CONTROL

Cyclic amine compounds represented by formula (1) 116-. (canceled)19. Cyclic amine compounds according to claim 17 , wherein Cyrepresents a pyridazyl group substituted by halogen claim 17 , nitro claim 17 , or haloalkyl.20. Agents for pest control comprising at least one of the cyclic amine compounds of . The present invention relates to novel cyclic amine compounds and agents for pest control which contain these cyclic amine compounds or the like as active ingredients.Priority is claimed on Japanese Patent Application No. 2005-294126, filed Oct. 6, 2005, Japanese Patent Application No. 2005-294127, filed Oct. 6, 2005, Japanese Patent Application No. 2005-297803, filed Oct. 12, 2005, Japanese Patent Application No. 2005-297804, filed Oct. 12, 2005, Japanese Patent Application No. 2006-016877, filed Jan. 25, 2006, and Japanese Patent Application No. 2006-182314, filed Jun. 30, 2006, the contents of which are incorporated herein by reference.Although many compounds which have insecticidal/acaricidal activities are conventionally known, there are problems such as insufficient effect thereof, limitation of use thereof because of drug resistance problems, occurrence of phytotoxicity or contamination in plant bodies, or strong toxicity against mammalians, fish, or the like.As compounds with backbones similar to those of the compounds of the present invention, compounds represented by the formula below are known.In the formula, X represents —O—, —N(R)—, —S—, or the like and Rrepresents a substituted saturated heterocyclic group or the like. As a representative of such compounds, the compound represented by the formula below is known (refer to Patent document 1).Moreover, the compounds represented by the formula below are known.In the formula, X represents —CH— or the like; Z represents a bonding or the like; Rrepresents an optionally substituted aryl or an optionally substituted heteroaryl; and Rand Rrepresent —(CH)— or the like together. However, when Rand Rrepresent —(CH ...

PRODUCTION PROCESS FOR FLUOROSULFONYLIMIDE AMMONIUM SALT

A compound [II] such as ammonium N,N-di(fluorosulfonyl)imide is obtained by reacting a compound [I] such as N,N-di(chlorosulfonyl)imide and NHF (HF). A compound [IV] such as an N,N-di(fluorosulfonyl)imide alkali metal salt is obtained by reacting the obtained compound [II] and an alkali metal compound or the like. 3. The process for producing a fluorosulfonylimide salt according to claim 2 , wherein the at least one compound is selected from the group consisting of alkali metal compounds claim 2 , onium compounds and organic amine compounds. The present invention relates to a process for producing a fluorosulfonylimide ammonium salt. More specifically, the present invention relates to a process for producing a fluorosulfonylimide ammonium salt with good efficiency and maximum suppression of the contamination of metal impurities that degrade electrolyte properties and the like.Priority is claimed on Japanese Patent Application No. 2011-046738, filed Mar. 3, 2011, the content of which is incorporated herein by reference.Fluorosulfonylimide salts are useful compounds in a wide variety of fields, and are used as electrolytes, as additives added to the electrolytes of fuel cells, and as selective electron withdrawing materials and the like (see Patent Document 1). Fluorosulfonylimide alkali metal salts and various fluorosulfonylimide onium salts can be obtained by cation exchange reactions using an alkali metal compound or an onium compound. Fluorosulfonylimide ammonium salts are useful as production intermediates for fluorosulfonylimide alkali metal salts and fluorosulfonylimide onium salts other than ammonium salts.Various methods have been proposed for synthesizing fluorosulfonylimide ammonium salts. For example, Non-Patent Document 1 discloses a method of synthesizing a di(fluorosulfonyl)imide ammonium salt from di(fluorosulfonyl)imide and ammonia.Patent Document 2 discloses a method of synthesizing a bis[di(fluorosulfonyl)imide] onium salt by reacting di( ...

FUNGICIDAL AQUEOUS SUSPENSION COMPOSITION FOR AGRICULTURE AND HORTICULTURE

Provided is a fungicidal aqueous suspension composition for agriculture and horticulture, comprising: a component (A) in the form of a specific oxime compound, salt thereof or N-oxide thereof, a component (B) in the form of at least one type of compound selected from the group consisting of a polyoxyalkylene alkyl ether, polyoxyalkylene fatty acid ester, polyoxyalkylene sorbitan fatty acid ester and silicone-based surfactant, and a component (C) in the form of at least one type of compound selected from the group consisting of a nonionic surfactant and anionic surfactant other than component (B). 5. The fungicidal aqueous suspension composition for agriculture and horticulture according to claim 1 , wherein the polyoxyalkylene alkyl ether of component (B) is a polyoxyalkylene vegetable oil ether.6. The fungicidal aqueous suspension composition for agriculture and horticulture according to claim 5 , wherein the polyoxyalkylene vegetable oil ether of component (B) is a polyoxyethylene castor oil ether claim 5 , polyoxypropylene castor oil ether or polyoxyethylene polyoxypropylene castor oil ether.7. The fungicidal aqueous suspension composition for agriculture and horticulture according to claim 1 , wherein the polyoxyalkylene fatty acid ester of component (B) is a polyoxyalkylene oleic acid ester or polyoxyalkylene lauric acid ester.8. The fungicidal aqueous suspension composition for agriculture and horticulture according to claim 1 , wherein the polyoxyalkylene sorbitan fatty acid ester of component (B) is a polyoxyalkylene sorbitan monooleic acid ester or polyoxyalkylene sorbitan monolauric acid ester.9. The fungicidal aqueous suspension composition for agriculture and horticulture according to claim 1 , wherein the silicone-based surfactant of component (B) is a polyoxyalkylene-modified polysiloxane.10. The fungicidal aqueous suspension composition for agriculture and horticulture according to claim 1 , wherein the content of component (A) is in an amount of 1% ...

Polybutadiene derivative composition

A composition containing a stabilizer that does not turn yellow upon curing and acts as a polymerization inhibitor during production and storage of a (meth)acrylic modified (hydrogenated) polybutadiene. The curable composition contains 0.1-99.9999% by weight of component (A), which is a (meth)acrylic modified (hydrogenated) polybutadiene, and 0.0001-10% by weight of component (B), which is a compound represented by formula (IV).

TETRAZOYLOXIME DERIVATIVE AND PLANT DISEASE CONTROL AGENT

According to the present invention, a tetrazoyloxime derivative and a salt thereof, which are excellent in a control effect against plant disease injury, and a plant disease controlling agent containing the same as an active ingredient are provided. 2. The tetrazoyloxime derivative according to claim 1 , wherein Y is a methyl group claim 1 , or a salt thereof. This application is a Divisional of U.S. application Ser. No. 12/733,023, which is the U.S. National Stage application of PCT/JP2008/064253, filed Aug. 7, 2008, which claims priority from Japanese application no. JP 2007-206297, filed Aug. 8, 2007.The present invention relates to a novel tetrazoyloxime derivative, and a plant disease control agent containing the same as an active ingredient.This application claims priority on Japanese Patent Application No. 2007-206297 filed on Aug. 8, 2007, the disclosure of which is incorporated by reference herein.In the cultivation of agricultural and horticultural crops, a large number of controlling agents have been used against crop injury. However, many of them are hardly satisfactory as controlling agents because of insufficient control efficacy, restrictions on their use due to appearance of pathogenic fungi having drug resistance, phytotoxicity or pollution on plants, or strong toxicity on humans, domestic animals and fishes. Therefore, there has been required to develop plant disease controlling agents applicable safely and having less of the drawbacks mentioned above.Relating to the present invention, Patent Documents 1 to 3 disclose tetrazoyloxime derivatives having a structure similar to that of the compounds of the present invention.However, even the compounds described in these patent documents do not have necessarily a sufficient control effect.Under these circumstances of prior arts, the present invention has been made and an object thereof is to provide a tetrazoyloxime derivative or a salt thereof, which is excellent in a control effect against plant ...

INCLUSION COMPLEX CONTAINING EPOXY RESIN COMPOSITION FOR SEMICONDUCTOR ENCAPSULATION

A solid semiconductor sealing composition that includes (A) an epoxy resin, and (B) a clathrate complex. The clathrate complex contains (b1) at least one of 5-hydroxyisophthalic acid and 5-nitroisophthalic acid; and (b2) at least one of 2-ethyl-4-methylimidazole and 2-phenyl-4-methyl-5-hydroxymethylimidazole. A method of sealing a solid semiconductor using the sealing composition. 1. A method of sealing a semiconductor comprising: (A) an epoxy resin; and', (b1) at least one of 5-hydroxyisophthalic acid and 5-nitroisophthalic acid, and', '(b2) at least one of 2-ethyl-4-methylimidazole and 2-phenyl-4-methyl-5-hydroxymethylimidazole., '(B) a clathrate complex comprising], 'applying to the semiconductor a composition comprising2. A solid semiconductor sealing composition comprising:(A) an epoxy resin; (b1) at least one of 5-hydroxyisophthalic acid and 5-nitroisophthalic acid; and', '(b2) at least one of 2-ethyl-4-methylimidazole and 2-phenyl-4-methyl-5-hydroxymethylimidazole; and, '(B) a clathrate complex comprising(C) an inorganic filler.3. The solid semiconductor sealing composition according to claim 2 , wherein the inorganic filler is present in an amount of 70 to 95 wt % with respect to a total weight of the sealing composition. This is a Continuation of application Ser. No. 12/733,462 filed Mar. 3, 2010, which in turn is a U.S. national stage application of International Application No. PCT/JP2008/002603 filed Sep. 19, 2008. The disclosure of the prior applications is hereby incorporated by reference herein in its entirety.The present invention relates to an epoxy resin composition for sealing a semiconductor, wherein a clathrate complex is used as a curing agent and/or curing accelerator.Epoxy resin compositions comprising epoxy resin, curing agent, curing accelerator and other additives are used as a sealant of semiconductor devices or electrical parts such as transistor, IC, LSI, etc. Conventionally, amine compounds or imidazole compounds, etc. were used as ...

METHOD FOR PRODUCING DICHLOROPYRAZINE DERIVATIVE

A method for producing a hydroxypyrazine derivative represented by formula (I) (wherein Rrepresents a halogen atom), the method including reacting a pyrazine derivative represented by formula (III) (wherein Rrepresents a nitrile group, an N-unsubstituted or N-substituted carbamoyl group, an ester group or a carboxyl group, M represents a cation capable of forming a salt, and n represents a number corresponding with the valence of M) with a halogenating agent. Also, a method for producing a dichloropyrazine derivative represented by formula (II) (wherein Rrepresents a nitrile group, an N-unsubstituted or N-substituted carbamoyl group, an ester group, a carboxyl group, or a group formed as a result of a change in the functional group of Rduring chlorination), the method including reacting the hydroxypyrazine derivative (I) with a chlorinating agent. According to the present invention, a dichloropyrazine derivative can be produced efficiently at low cost, and a hydroxypyrazine derivative that functions as a production intermediate for the dichloropyrazine derivative can be produced efficiently at low cost. 14-. (canceled)6. The method for producing a hydroxypyrazine derivative according to claim 5 , wherein M is a cation formed from a metal element belonging to group I claim 5 , group IIa or group Ma of a periodic table of elements. The present invention relates to a method for producing a dichloropyrazine derivative that is useful as an intermediate for an agrochemical or pharmaceutical product, and a method for producing a hydroxypyrazine derivative that functions as a production intermediate for the dichloropyrazine derivative.Priority is claimed on Japanese Patent Application No. 2009-016221, filed Jan. 28, 2009, the content of which is incorporated herein by reference.Compounds represented by formula (IV) below are known to be very effective against a variety of viruses, and particularly the influenza virus.(wherein Rrepresents a hydrogen atom or a halogen atom, ...

HYDROXYALKYLCELLULOSE MICROPARTICLES

Provided is a method of producing hydroxyalkylcellulose microparticles, the method including generating a pulse shock wave, and supplying a hydroxyalkylcellulose aqueous solution to the pulse shock wave generation region, thereby crushing and drying the hydroxyalkylcellulose aqueous solution. According to the production method, hydroxyalkylcellulose microparticles having a volume-average particle size of at least 0.1 μm but less than 15 μm are obtained. By mixing the hydroxyalkylcellulose microparticles with a principal agent and subjecting the resulting mixture to a tablet compression, a solid preparation having excellent tensile strength and disintegration properties can be obtained. 126-. (canceled)27. A method of producing hydroxyalkylcellulose microparticles , the method comprising generating a pulse shock wave , and supplying a hydroxyalkylcellulose aqueous solution to a pulse shock wave generation region , thereby crushing and drying the hydroxyalkylcellulose aqueous solution.28. The method of producing hydroxyalkylcellulose microparticles according to claim 27 , wherein a concentration of the hydroxyalkylcellulose aqueous solution is within a range from 1 to 5% by weight.29. The method of producing hydroxyalkylcellulose microparticles according to claim 27 , wherein a shape of obtained hydroxyalkylcellulose microparticles is spherical.30. The method of producing hydroxyalkylcellulose microparticles according to any one of claims 27 , wherein the hydroxyalkylcellulose supplied as an aqueous solution has a viscosity at 20° C. for a 2% aqueous solution that is within a range from 2.0 to 20.0 mPa·s.31. The method of producing hydroxyalkylcellulose microparticles according to any one of claims 27 , wherein the hydroxyalkylcellulose supplied as an aqueous solution has a hydroxyalkyl group content within a range from 40 to 80% by weight.32. The method of producing hydroxyalkylcellulose microparticles according to any one of claims 27 , wherein the ...

LIQUID INSECTICIDE COMPOSITION

A liquid insecticide composition is provided containing a neonicotinoid-based compound, a silicone-based surfactant, and a water-soluble organic solvent. Furthermore, a method is provided for enhancing an insecticidal effect which includes using a silicone-based surfactant in combination with a neonicotinoid-based compound as an insecticidal active ingredient. 1. A liquid insecticide composition containing a neonicotinoid-based compound , a silicone-based surfactant , and a water-soluble organic solvent.2. The liquid insecticide composition according to claim 1 ,wherein the neonicotinoid-based compound is acetamiprid.3. The liquid insecticide composition according to claim 1 ,wherein the silicone-based surfactant is polyether-modified polysiloxane.4. The liquid insecticide composition according to claim 1 ,wherein the silicone-based surfactant is polyoxyethylene-modified heptamethyltrisiloxane.6. The liquid insecticide composition according to claim 1 ,wherein the neonicotinoid-based compound is 0.1 parts by mass to 60 parts by mass; the water-soluble organic solvent is 35 parts by mass to 95 parts by mass; and the silicone-based surfactant is 1 part by mass to 15 parts by mass in the total 100 parts by mass of the neonicotinoid-based compound, the water-soluble organic solvent, and the silicone-based surfactant.7. The liquid insecticide composition according to claim 1 , further comprising a non-silicone-based nonionic surfactant.8. The liquid insecticide composition according to claim 7 ,wherein the non-silicone-based nonionic surfactant is a polyoxyalkylene block polymer.9. The liquid insecticide composition according to claim 7 ,wherein the neonicotinoid-based compound is 0.1 parts by mass to 60 parts by mass; the water-soluble organic solvent is 35 parts by mass to 95 parts by mass; and the total amount of the silicone-based surfactant and the non-silicone-based nonionic surfactant is 1 part by mass to 30 parts by mass in the total 100 parts by mass of the ...

NITROGENATED HETEROCYCLIC COMPOUND AND AGRICULTURAL OR HORTICULTURAL FUNGICIDE

An agricultural or horticultural fungicide contains as an active ingredient thereof at least one compound selected from the group consisting of nitrogenated heterocyclic compounds represented by formula (I) (wherein, R represents a group represented by CRRRor a cyano group, Rto Rrepresent hydrogen atoms, alkyl groups or hydroxyl groups, or the like, Xrepresents a halogeno group or the like, m represents an integer of 0 to 5, Xrepresents a halogeno group or the like, n represents an integer of 0 to 3, B represents a carbon atom or a nitrogen atom, D represents a 5- to 7-membered hydrocarbon ring, and Ato Arepresent carbon atoms or nitrogen atoms, provided that Ato Ado not all represent carbon atoms when B represents a carbon atom) and salts thereof. 2. The nitrogenated heterocyclic compound or salt thereof according to claim 1 , wherein D in formula (I) represents a benzene ring.3. The nitrogenated heterocyclic compound or salt thereof according to claim 2 , wherein Ain formula (I) represents a nitrogen atom and A claim 2 , Aand Arepresent carbon atoms.4. The nitrogenated heterocyclic compound or salt thereof according to claim 3 , wherein B in formula (I) represents a carbon atom.5. The nitrogenated heterocyclic compound or salt thereof according to claim 2 , wherein B in formula (I) represents a nitrogen atom and A claim 2 , Aand Arepresent carbon atoms.6. The nitrogenated heterocyclic compound or salt thereof according to claim 5 , wherein Ain formula (I) represents a nitrogen atom.7. An agricultural or horticultural fungicide comprising as an active ingredient thereof at least one compound selected from the group consisting of nitrogenated heterocyclic compounds or salts thereof claim 5 , according to any one of to . The present invention relates to an agricultural or horticultural fungicide that demonstrates reliable effects and can be used safely, and to a nitrogenated heterocyclic compound that is useful as an active ingredient of an agricultural or ...

METHOD FOR PRODUCING HYDROGENATED UNSATURATED POLYHYDROXYHYDROCARBON POLYMER

Provided is a method for producing a hydrogenated unsaturated polyhydroxyhydrocarbon polymer capable of suppressing side reactions such as a hydrogenolysis reaction of a terminal hydroxyl group and achieving a high hydrogenation rate in a short reaction time. A hydrogenated unsaturated polyhydroxyhydrocarbon polymer is obtained by a method including: hydrogenating an unsaturated polyhydroxyhydrocarbon polymer under the presence of a hydrogenation catalyst and a reaction solvent in the following two stages (I) and (II): (I) carrying out a hydrogenation reaction in a temperature range of 80° C. to 130° C. until a hydrogenation rate of at least 30 mol % is achieved; and then (II) carrying out a hydrogenation reaction at a temperature higher than 130° C. until a hydrogenation rate of at least 98 mol % is achieved. 1. A method for producing a hydrogenated unsaturated polyhydroxyhydrocarbon polymer comprising:hydrogenating an unsaturated polyhydroxyhydrocarbon polymer in a hydrogen atmosphere under the presence of a hydrogenation catalyst and a reaction solvent in the following two stages (I) and (II):(I) carrying out a hydrogenation reaction in a temperature range of 80° C. to 130° C. until a hydrogenation rate of at least 30 mol % is achieved; and then(II) carrying out a hydrogenation reaction at a temperature higher than 130° C. until a hydrogenation rate of at least 98 mol % is achieved.2. The method according to claim 1 , wherein a hydrogen pressure in stage (I) is equal to or less than 6 MPa.3. The method according to claim 1 , wherein a hydrogen pressure in stage (II) is equal to or more than 2 MPa.4. The method according to claim 1 , wherein the hydrogenation catalyst is at least one selected from the group consisting of a nickel-based catalyst claim 1 , a cobalt-based catalyst claim 1 , a ruthenium-based catalyst claim 1 , a rhodium-based catalyst claim 1 , a palladium-based catalyst and a platinum-based catalyst. The present invention relates to a method for ...

HETEROARYLPYRIMIDINE COMPOUND AND FORMULATION FOR CONTROLLING HARMFUL ORGANISMS

The present invention relates to a compound represented by the following Formula (I) or a salt thereof, which exhibits superior insecticidal activity, acaricidal activity, and/or nematicidal activity, which exhibits superior safety, and which can be advantageously synthesized industrially, and also relates to a formulation for controlling harmful organisms containing the same as an active ingredient. 2. A formulation for controlling harmful organisms claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in claim 1 , N-oxide compounds thereof claim 1 , stereoisomers claim 1 , tautomers claim 1 , hydrates claim 1 , and salts thereof claim 1 , as an active ingredient.3. An insecticidal formulation or an acaricidal formulation claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in claim 1 , N-oxide compounds thereof claim 1 , stereoisomers claim 1 , tautomers claim 1 , hydrates claim 1 , and salts thereof claim 1 , as an active ingredient.4. A formulation for controlling ectoparasites claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in claim 1 , N-oxide compounds thereof claim 1 , stereoisomers claim 1 , tautomers claim 1 , hydrates claim 1 , and salts thereof claim 1 , as an active ingredient.5. A formulation for controlling endoparasites or for expelling endoparasites claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in claim 1 , N-oxide compounds thereof claim 1 , stereoisomers claim 1 , tautomers claim 1 , hydrates claim 1 , and salts thereof claim 1 , as an active ingredient. The present invention relates to a heteroarylpyrimidine compound and a formulation for controlling harmful organisms. More particularly, the present invention relates to a heteroarylpyrimidine compound which has superior insecticidal activity and/or acaricidal activity, exhibits ...

ARYLAZOLE COMPOUND AND PEST CONTROL AGENT

A compound represented by Formula (I), or a salt or N-oxide compound thereof is provided. 3. A pest control agent comprising at least one compound according to claim 1 , a salt thereof claim 1 , or an N-oxide compound thereof as an active ingredient and a carrier.4. A method for controlling a pest or mite on or in a subject comprising the step of administrating to the subject an effective amount of at least one compound according to claim 1 , a salt thereof claim 1 , or an N-oxide compound thereof claim 1 ,{'i': 'Polyphaga', 'wherein the pest or mite is one or more selected from the group consisting of: butterflies and moths of the order Lepidoptera; pests of the order Thysanoptera; pests of the order Hemiptera; pests of the order ; pests of the order Diptera; pests of the order Orthoptera; and mites of the subclass Acari.'}5. A method for controlling an insect or acarus on or in a subject comprising the step of administrating to the subject an effective amount of at least one compound according to claim 1 , a salt thereof claim 1 , or an N-oxide compound thereof.6. A method for controlling an ectoparasite on or in a subject comprising the step of administrating to the subject an effective amount of at least one compound according to claim 1 , a salt thereof claim 1 , or an N-oxide compound thereof.7. A method for controlling or expelling an endoparasite in a subject comprising the step of administrating to the subject an effective amount of at least one compound according to claim 1 , a salt thereof claim 1 , or an N-oxide compound thereof. This application is a Divisional of U.S. application Ser. No. 16/061,783, which is the U.S. National Stage application of PCT/JP2016/087358, filed Dec. 15, 2016, which claims priority from Japanese Patent Application No. 2015-245712, filed on Dec. 16, 2015, Japanese Patent Application No. 2016-060605, filed on Mar. 24, 2016, and Japanese Patent Application No. 2016-198677, filed on Oct. 7, 2016, the contents of which are ...

ECTOPARASITE CONTROL AGENT

wherein, in formula (III), Xrepresents a C1-6 alkyl group which is unsubstituted or has a substituent, or other groups; ml represents any integer of 0 to 5; A represents an oxygen atom or a sulfur atom; each of Rand Rindependently represents a hydrogen atom, a C1-6 alkyl group which is unsubstituted or has a substituent, or other groups; Rrepresents a hydrogen atom or a C1-6 alkyl group which is unsubstituted or has a substituent; B represents an oxygen atom or a sulfur atom; Qrepresents a C7-11 aralkyl group which is unsubstituted or has a substituent X, or other groups; and each of R, R, R, and Rindependently represents a hydrogen atom, a C1-6 alkyl group which is unsubstituted or has a substituent, or other groups. 4. A formulation , comprising:{'claim-ref': [{'@idref': 'CLM-00001', 'claims 1'}, {'@idref': 'CLM-00003', '3'}], 'at least one compound selected from the 1-heterodiene compounds and salts thereof according to any one of to ; and'}at least one acceptable carrier.5. The formulation according to claim 4 , further comprising:at least one additional effective component.6. The formulation according to claim 4 , which is a pharmaceutical formulation for humans.7. The formulation according to claim 4 , which is a pharmaceutical formulation for animals.8. A method for suppressing parasites in the body or on the body surface of an animal requiring suppression of parasite by parasitic organisms claim 4 ,{'claim-ref': [{'@idref': 'CLM-00001', 'claims 1'}, {'@idref': 'CLM-00003', '3'}], 'wherein an effective amount of at least one compound selected from the 1-heterodiene compounds and salts thereof according to any one of to is administered to the animal.'}9. The method according to claim 8 ,wherein at least one other effective component is administered to the animal.10. The method according to claim 8 ,wherein the animal is a human.11. The method according to claim 8 ,wherein the animal is a pet.12. The method according to claim 11 ,wherein the pet is a dog or a ...

DIARYL-AZOLE COMPOUND AND FORMULATION FOR CONTROLLING HARMFUL ORGANISM

A compound represented by Formula (I), or a salt thereof: 2. The compound according to claim 1 , or a salt thereof claim 1 ,wherein Ar represents an unsubstituted or substituted, 5-membered heteroaryl group.4. A formulation for controlling harmful organisms claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in claim 1 , and salts thereof claim 1 , as an active ingredient.5. An insecticidal formulation or an acaricidal formulation claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in claim 1 , and salts thereof claim 1 , as an active ingredient.6. A formulation for controlling ectoparasites claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in claim 1 , and salts thereof claim 1 , as an active ingredient.7. A formulation for controlling endoparasites or for expelling endoparasites claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in claim 1 , and salts thereof claim 1 , as an active ingredient. The present invention relates to a diaryl-azole compound and a formulation for controlling harmful organisms. In particular, the present invention relates to a diaryl-azole compound which has superior insecticidal activity and/or acaricidal activity, exhibits superior safety, and can be industrially-advantageously synthesized, and also relates to a formulation for controlling harmful organisms containing the same as an active ingredient.This application is a Divisional of U.S. application Ser. No. 16/329,198, which is the U.S. National Stage application of PCT/JP2017/033103, filed Sep. 13, 2017, which claims priority to Japanese Patent Application No. 2016-180467, filed on Sep. 15, 2016 in Japan, and Japanese Patent Application No. 2017-89266, filed on Apr. 28, 2017 in Japan, the content of which is incorporated herein by reference.Various compounds having an ...

METHOD FOR PRODUCING DISULFONYLAMINE ALKALI METAL SALT

The present invention provides a method for producing a disulfonylamine alkali metal salt, including a step of subjecting a disulfonylamine onium salt represented by formula [I] (wherein each of Rand Rindependently represents a fluorine atom or a fluorinated alkyl group having 1 to 6 carbon atoms, provided that at least one of Rand Rrepresents a fluorine atom, and each of R, R, Rand Rindependently represents a hydrogen atom or the like) to a cation exchange reaction in an organic solvent, thereby producing a disulfonylamine alkali metal salt represented by formula [II] (wherein M represents an alkali metal cation, and Rand Rare as defined in formula [I]), and a step of filtering the organic solvent solution containing the disulfonylamine alkali metal salt through a filter having a particle retention size of 0.1 to 10 μm to obtain a filtrate.

NOVEL INCLUSION COMPOUND

An object of the present invention is to provide a novel curing agent or a curing accelerator for epoxy resin. The curing agent or a curing accelerator for epoxy resin of the present invention is a clathrate compound comprising the following (a1) and (a2):

CRYSTALLINE MODIFICATION OF N-(2-(3-PHENYLUREIDO)PHENYL)BENZENESULFONAMIDE AND RECORDING MATERIAL USING SAME

The disclosure provides a novel crystal form of N-(2-(3-phenylureido)phenyl)benzenesulfonamide, which is crystalline modification thereof specified by an X-ray diffraction diagram having peaks at diffraction angles (2θ±0.1°) of 23.60°, 20.80°, 12.24° and 13.80° in a powder X-ray diffractometry using Cu-Kα ray. 1. A crystalline modification of N-(2-(3-phenylureido)phenyl)benzenesulfonamide specified by an X-ray diffraction diagram having peaks at diffraction angles (2θ±0.1°) of 23.60° , 20.80° , 12.24° and 13.80° in a powder X-ray diffractometry using Cu-Kα ray.2. The crystalline modification of N-(2-(3-phenylureido)phenyl)benzenesulfonamide according to claim 1 , wherein a melting point is 160-162° C.3. A recording material comprising a color former claim 1 , wherein the recording material comprises the crystalline modification of N-(2-(3-phenylureido)phenyl)benzenesulfonamide according to .4. A recording sheet having a recording material layer formed from the recording material according to .5. A recording material comprising a color former claim 2 , wherein the recording material comprises the crystalline modification of N-(2-(3-phenylureido)phenyl)benzenesulfonamide according to .6. A recording sheet having a recording material layer formed from the recording material according to . The present invention relates to a novel crystal form of N-(2-(3-phenylureido)phenyl)benzenesulfonamide. The present application claims priority of Japanese Patent Application No. 2015-035568 filed on Feb. 25, 2015 and priority of Japanese Patent Application No. 2015-065613 filed on Mar. 27, 2015, the contents of which are incorporated herein by reference.The recording material employing color development through a reaction between a color former and a color-developing agent, since record may be made by a relatively simple apparatus in a short time without applying a complicated treatment such as development and fixation, are widely used in e.g., thermal recording paper for output- ...

RECORDING MATERIAL AND RECORDING SHEET

An object of the invention is to provide a recording material and recording sheet having excellent color-developing performance, storage stability, etc. A recording material having good color-developing performance and storage stability may be obtained by using a specific compound having a benzhydrol skeleton as an additive in a recording material employing color development through a reaction between a color former and a color-developing agent. 4. The recording material according to claim 1 , wherein the color former is a fluoran dye.5. A recording sheet having a recording material layer formed from the recording material according to on a support.6. The recording material according to claim 2 , wherein the color former is a fluoran dye.7. The recording material according to claim 3 , wherein the color former is a fluoran dye.8. A recording sheet having a recording material layer formed from the recording material according to on a support.9. A recording sheet having a recording material layer formed from the recording material according to on a support.10. A recording sheet having a recording material layer formed from the recording material according to on a support.11. A recording sheet having a recording material layer formed from the recording material according to on a support.12. A recording sheet having a recording material layer formed from the recording material according to on a support. The present invention relates to a recording material employing color development through a reaction between a color former and a color-developing agent, and a recording sheet using the recording material.The present application claims priority of Japanese Patent Application No. 2015-019879 filed on Feb. 4, 2015, the content of which is incorporated herein by reference.The recording material employing color development through a reaction between a color former and a color-developing agent, since record may be made by a relatively simple apparatus in a short time without ...

ZINC SALT OF ISOTHIAZOLONE COMPOUND, METHOD FOR REDUCING IRRITATION CAUSED BY ISOTHIAZOLONE COMPOUND, ANTIBACTERIAL AND ANTIFUNGAL METHOD USING ZINC SALT OF ISOTHIAZOLONE COMPOUND, AND ANTIBACTERIAL AND ANTIFUNGAL COMPOSITION

A method for reducing irritation caused by an isothiazolone compound represented by formula (1) by converting the isothiazolone compound represented by formula (1) into a zinc salt, where Rand Reach independently represents a hydrogen atom, a halogen atom, or an alkyl group of 1 to 20 carbon atoms, and Rand Rmay bind to each other to form a substituted or unsubstituted carbocycle. 2. The method according to claim 1 , further comprising using at least one solvent selected from the group consisting of water claim 1 , alcohol-based solvents claim 1 , ketone-based solvents claim 1 , ether-based solvents claim 1 , amide-based solvents claim 1 , glycol-based solvents claim 1 , glycol ether-based solvents claim 1 , glycol diester-based solvents claim 1 , glycol ester ether-based solvents claim 1 , and ester-based solvents.3. The method according to claim 1 , further comprising mixing at least one isothiazolone compound represented by formula (1) and at least one zinc compound claim 1 , excluding the zinc salt of an isothiazolone compound represented by formula (1) claim 1 , at a predetermined ratio.4. The method according to claim 2 , further comprising mixing at least one isothiazolone compound represented by formula (1) and at least one zinc compound claim 2 , excluding the zinc salt of an isothiazolone compound represented by formula (1) claim 2 , at a predetermined ratio.5. The method according to claim 3 , wherein the zinc salt is obtained by mixing the compound represented by formula (1) and the zinc compound so that a molar ratio between the compound represented by the formula (1) and the zinc compound is from 1:10 to 10:1.6. The method according to claim 4 , wherein the zinc salt is obtained by mixing the compound represented by formula (1) and the zinc compound so that a molar ratio between the compound represented by the formula (1) and the zinc compound is from 1:10 to 10:1. This is a divisional of application Ser. No. 13/067,622 filed Jun. 15, 2011, which is a ...

PRODUCTION METHOD FOR INCLUSION COMPOUND

A method for producing a thermodynamically more stable clathrate compound including at least one compound selected from the group consisting of 1,1,2,2-tetrakis(4-hydroxyphenyl)ethane, 5-hydroxyisophthalic acid, and 5-nitroisophthalic acid as a host compound and an imidazole compound as a guest compound. The method for producing a clathrate compound includes: a mixing step of mixing a mixed solvent including a protic solvent, at least one compound selected from the group consisting of 1,1,2,2-tetrakis(4-hydroxyphenyl)ethane, 5-hydroxyisophthalic acid and 5-nitroisophthalic acid, and an imidazole compound; and a heating step. 3. The method for producing a clathrate compound according to claim 1 , wherein the mixed solvent comprises a first solvent which is at least one solvent selected from the group consisting of water and methanol and a second solvent which is at least one solvent selected from the group consisting of an alcoholic solvent claim 1 , an ester-based solvent claim 1 , a ketone-based solvent claim 1 , an aliphatic hydrocarbon-based solvent claim 1 , and an aromatic hydrocarbon-based solvent claim 1 , the second solvent being a solvent different from the first solvent.4. The method for producing a clathrate compound according to claim 1 , wherein the imidazole compound represented by formula (I) is 2-phenyl-4-methyl-5-hydroxymethylimidazole or 2-ethyl-4-methylimidazole.5. The method for producing a clathrate compound according to claim 2 , wherein the mixed solvent comprises a first solvent which is at least one solvent selected from the group consisting of water and methanol and a second solvent which is at least one solvent selected from the group consisting of an alcoholic solvent claim 2 , an ester-based solvent claim 2 , a ketone-based solvent claim 2 , an aliphatic hydrocarbon-based solvent claim 2 , and an aromatic hydrocarbon-based solvent claim 2 , the second solvent being a solvent different from the first solvent.6. The method for producing a ...

METHOD FOR PRODUCING POLYESTER

A cyclic ester such as lactides and the like is mixed, in an organic solvent, with an alkyl aluminum compound such as trimethyl aluminum, triethyl aluminum and the like, and then, to the resulting mixture, at least one selected from the group consisting of an organic lithium ring-opening polymerization catalyst, an organic sodium ring-opening polymerization catalyst, an organic potassium ring-opening polymerization catalyst, an organic zinc ring-opening polymerization catalyst, an organic magnesium ring-opening polymerization catalyst, an organic tin ring-opening polymerization catalyst, an organic calcium ring-opening polymerization catalyst, an organic titanium ring-opening polymerization catalyst, and an amine ring-opening polymerization catalyst to allow ring-opening polymerization of the cyclic ester, thereby a polyester is obtained. 1. A method for producing polyester , the method comprising: {'br': None, 'sub': n', '3-n, 'RAl X'}, 'mixing, in an organic solvent, a cyclic ester with an alkyl aluminum compound represented by a formula [I]wherein, in the formula [I], n represents an integer from 1 to 3, R each independently represents a linear or branched C1-20 alkyl group, and X each independently represents a halogen atom or a hydrogen atom; and thenmixing the resulting mixture with at least one ring-opening polymerization catalyst selected from the group consisting of an organic lithium ring-opening polymerization catalyst, an organic sodium ring-opening polymerization catalyst, an organic potassium ring-opening polymerization catalyst, an organic zinc ring-opening polymerization catalyst, an organic magnesium ring-opening polymerization catalyst, an organic tin ring-opening polymerization catalyst, an organic calcium ring-opening polymerization catalyst, an organic titanium ring-opening polymerization catalyst, and an amine ring-opening polymerization catalyst to allow ring-opening polymerization of the cyclic ester.2. The method for producing polyester ...

PROCESS FOR PRODUCING ORGANOLITHIUM COMPOUND AND PROCESS FOR PRODUCING SUBSTITUTED AROMATIC COMPOUND

A method for producing an organolithium compound includes the step of reacting an aromatic compound or a halogenated unsaturated aliphatic compound and a lithiating agent in the presence of a coordinating compound containing three or more elements having a coordinating ability in a molecule, at least one thereof being a nitrogen element, or a coordinating compound containing three or more oxygen elements having a coordinating ability in a molecule, at least one of the groups containing the oxygen elements having a coordinating ability being a tertiary alkoxy group, at a temperature of −40° C. to 40° C. 1. A ligand represented by formula (3):wherein, in formula (3),{'sup': 2b', '21, 'sub': '2', 'Lrepresents —O— or —N(—CH—R)—,'}{'sup': '21', 'Rrepresents a hydrogen atom or a C1-6 alkyl group,'}{'sup': 1b', '22', '23', '24, 'Lrepresents —ORor —N(R)R,'}{'sup': 3b', '221', '231', '241, 'Lrepresents —ORor —N(R)R,'}{'sup': 22', '221, 'Rand Reach, independently, represents a C1-6 alkyl group,'}{'sup': 23', '231, 'Rand Reach, independently, represents a methyl group, an ethyl group, or an n-propyl group,'}{'sup': 24', '241', '2b', '1b', '22', '3b', '231', '241', '2b', '3b', '221', '1b', '23', '24, 'Rand Reach, independently, represents a C1-6 alkyl group (provided that when Lis —O— and Lis —OR, Lis —N(R)Rand, when Lis —O— and Lis —OR, Lis —N(R)R),'}{'sup': 1b', '2b, 'nand neach, independently, represents an integer of 1 to 3,'}{'sup': 1b', '2b, 'Rand Rrepresent a C1-6 alkyl group,'}{'sup': 3b', '4b', '5b', '6b', '7b', '8b', '2b', '1b', '3b', '1b', '2b', '1b', '2b', '3b', '4b', '5b', '6b', '7b', '8b, 'sub': 3', '3', '3, 'R, R, R, R, Rand Reach, independently, represents a hydrogen atom or a C1-6 alkyl group (provided that when Lis —N—CH, Land Lis —N(CH)CHand nand nare 1, R, R, R, R, R, R, Rand Rare not simultaneously methyl groups) and'}{'sup': 1b', '2b', '3b', '4b', '5b', '6b', '7b', '8b, 'a ring may be formed between (Ror R) and (Ror R) or between (Ror R) and (Ror R).'} The ...

HALOGENATED ANILINE AND METHOD FOR PRODUCING SAME

The present invention provides a halogenated aniline represented by formula (I) (wherein each of Xand Xindependently represents a chlorine atom, a bromine atom or an iodine atom), a method for producing the halogenated aniline, and other aspects. 1. (canceled)34.-. (canceled)6. The method for producing a halogenated nitrobenzene according to claim 5 , wherein fuming sulfuric acid and concentrated nitric acid are added to the halogenated benzene represented by formula (III) to nitrate the halogenated benzene.7. The method for producing a halogenated nitrobenzene according to claim 5 , wherein fuming sulfuric acid and fuming nitric acid are added to the halogenated benzene represented by formula (III) to nitrate the halogenated benzene.810.-. (canceled)11. A method for producing 1 claim 5 ,2-dichloro-4 claim 5 ,5-difluorobenzene claim 5 , comprising a step of chlorinating 1 claim 5 ,2-difluorobenzene. The present invention relates to a novel halogenated aniline, which can be used as a production raw material for compounds that are useful as electronic materials, medicines, and agricultural chemicals and the like, as well as a method for producing the halogenated aniline.Priority is claimed on Japanese Patent Application No. 2012-280691, filed Dec. 25, 2012, the content of which is incorporated herein by reference.The compound 2,3-difluoroaniline is the starting raw material for producing 2-[2-fluoro-6-(7,8-difluoro-2-methylquinolin-3-yloxy)phenyl]propan-2-ol and 2-[2-fluoro-6-(7,8-difluoroquinolin-3-yloxy)phenyl]propan-2-ol, which are known as active ingredients for agricultural and horticultural germicides (Patent Document 1).Further, 2,3-difluoroaniline is also used in the production of medicines such as antibiotics (Patent Document 2), c-Met protein kinase inhibitors (Patent Document 3), drugs for Alzheimer's disease (Patent Document 4), Aurora B kinase inhibitors (Patent Document 5), and drugs for neuropathic pain (Patent Document 6).Moreover, 2,3-difluoroaniline ...

HETEROARYL SULFONAMIDE COMPOUND AND FORMULATION FOR CONTROLLING HARMFUL ORGANISMS

The present invention relates to a compound represented by formula (I) or a salt thereof which has excellent insecticidal, acaricidal and/or nematicidal activity, exhibits excellent safety, and can be advantageously synthesized industrially, and also relates to a formulation for controlling harmful organisms which contains the same. 2. A formulation for controlling harmful organisms claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in and salts thereof claim 1 , as an active ingredient.3. An insecticidal or acaricidal formulation claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in and salts thereof claim 1 , as an active ingredient.4. A nematicidal formulation claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in and salts thereof claim 1 , as an active ingredient.5. A formulation for controlling endoparasite or parasiticidal formulation claim 1 , comprising at least one compound selected from the group consisting of the compounds as recited in and salts thereof claim 1 , as an active ingredient. The present invention relates to a heteroaryl sulfonamide compound and a formulation for controlling harmful organisms. More specifically, the present invention relates to a heteroaryl sulfonamide compound which has excellent insecticidal activity, acaricidal activity and/or nematicidal activity, exhibits excellent safety, and can be advantageously synthesized industrially, and also relates to a formulation for controlling harmful organisms containing the same as an active ingredient.The present application claims priority on Japanese Patent Application No. 2018-033602, filed in Japan on Feb. 27, 2018, the content of which is incorporated herein by reference.Various compounds having insecticidal and/or acaricidal activity and/or nematicidal activity have been proposed. In order to practically use such ...

PARASITE CONTROL AGENT FOR PARASITICIDE

A parasite-control or parasiticide agent that exhibits excellent effects of controlling or expelling parasites, particularly endoparasites and that can be used safely contains at least one selected from the group consisting of compounds represented by formula (I) and salts thereof as an active ingredient thereof 2. The parasite-control or parasiticide agent according to claim 1 , wherein Rand Reach indenpendently represents an unsubstituted or substituted C1-6 alkyl group claim 1 , and{'sup': '5', 'Rrepresents an unsubstituted or substituted C6-10 aryl group, an unsubstituted or substituted heteroaryl group, or an unsubstituted or substituted C1-6 alkylaminocarbonyl group.'}3. The parasite-control or parasiticide agent according to claim 1 , wherein Rrepresents an unsubstituted or substituted C1-6 alkyl group claim 1 , and Rrepresents a hydrogen atom.4. The parasite-control or parasiticide agent according to claim 1 , wherein A represents a nitrogen atom.5. The parasite-control or parasiticide agent according to claim 1 , wherein A represents a group represented by CR claim 1 , and Rrepresents a hydrogen atom.6. The parasite-control or parasiticide agent according to claim 1 , wherein the parasite-control or parasiticide agent targets an endoparasite.7. A method for controlling or expelling an endoparasite that is parasitic in warm-blooded animals or fishes claim 6 , comprising administering a parasite-control or parasiticide agent of to the warm-blooded animals or the fishes at an effective dose.8. The parasite-control or parasiticide agent according to claim 6 , wherein the parasite-control or parasiticide agent targets nematodes.9. A method for controlling or expelling nematodes that are parasitic in warm-blooded animals or fishes claim 8 , comprising administering a parasite-control or parasiticide agent of to the warm-blooded animals or the fishes at an effective dose. The present invention relates to a composition useful as a medicine or an animal drug, and ...

Composition for treatment of ballast water

The present invention relates to a method for reduce treating ballast water which has been subjected to a biocidal treatment with a chlorine-based oxidizing agent or an oxygen-based oxidizing agent, by using a tablet or pellet of sodium sulfite.

Compound, method for producing compound, and method for purifying compound

The present invention provides a compound characterized by being represented by general formula (I): (wherein, A represents a halogen atom, alkyl group, haloalkyl group, alkoxy group, haloalkoxy group, alkylsulfonyl group, unsubstituted or substituted aryl group, cyano group or nitro group, n represents an integer of 0 to 5 (and A may be mutually the same or different when n is 2 or more), Y represents an alkyl group, M represents an alkaline metal or alkaline earth metal, and m represents an integer of 1 or 2).

PYRIDINE N-OXIDE COMPOUND AND PEST CONTROL AGENT

An object of the present invention is to provide a pyridine N-oxide compound that is excellent in pest control activity, particularly, insecticidal activity and/or acaricidal activity, is excellent in safety, and may be industrially advantageously synthesized. The pyridine N-oxide compound of the present invention is a compound of the formula (II), a stereoisomer, tautomer or hydrate thereof or a salt of any of these compounds, wherein Rrepresents a substituted or unsubstituted C1-6 alkylsulfonyl group; Rrepresents a hydrogen atom, a substituted or unsubstituted C1-6 alkyl group, or the like; Arepresents an oxygen atom, a sulfur atom, or the like; Aand Aeach independently represent a carbon atom or a nitrogen atom; X represents a substituted or unsubstituted C1-6 alkyl group, a substituted or unsubstituted C1-6 alkoxy group, or the like; and n represents an integer of 0 to 2.

Method for manufacturing agricultural and horticultural granule formulation

Provided is a method for producing an agricultural and horticultural granule, the method including molding a powdered agrochemical composition into granules using a lateral extrusion granulator, characterized in that: the lateral extrusion granulator includes a hopper for feeding a kneaded product of the powdered agrochemical composition with water, a screw for kneading and extruding the kneaded product, a screw casing for accommodating the screw, a screen for molding the kneaded product into strands, the screen being provided on a screw casing wall parallel to a screw shaft on a side away from the hopper, and a cooling unit for cooling a screw casing wall on a bearing side of a screw on a side away from the hopper; and the powdered agrochemical composition contains 20 to 80% by weight in total of a component having a water solubility of 4,000 to 500,000 ppm at a water temperature of 20° C. and a pH of 3 to 9.

PHENOXYUREA COMPOUND AND PEST CONTROL AGENT

A compound of formula (I) or a salt thereof: 1. (canceled)3. (canceled)4. An acaricidal agent comprising at least one selected from the group consisting of the compounds according to and salts thereof as an active ingredient.57.-. (canceled) The present invention relates to a phenoxyurea compound and a pest control agent. More specifically, the present invention relates to a phenoxyurea compound which has excellent insecticidal activity and/or acaricidal activity, and nematicidal activity, is excellent in safety and can be synthesized in an industrially favorable manner; and a pest control agent containing this compound as an active ingredient.The present application claims priority based on JP2018-074961 that was filed in Japan on Apr. 9, 2018, and the contents thereof are incorporated herein by reference.Various compounds having insecticidal/acaricidal activities and nematicidal activity have been proposed. In order to put such a compound to practical use as an agricultural chemical, it is required not only to have sufficiently high efficacy, but also to be difficult to cause drug resistance, not to cause phytotoxicity to plants or soil pollution, and to have low toxicity to livestock and fish, or the like.Incidentally, Patent Document 1 discloses compounds of formulas (A), (B) and (C), and the like.Patent Documents 2 and 3 disclose compounds of formula (D) and formula (E), and the like.Patent Document 4 discloses a compound of formula (F), and the like.Further, Patent Document 5 discloses compounds of formula (G) and formula (H), and the like.An object of the present invention is to provide a phenoxyurea compound which is excellent in pest control activity such as insecticidal/acaricidal activities and nematicidal activity, excellent in safety and can be synthesized in an industrially favorable manner; and a pest control agent containing this compound as an active ingredient.As a result of intensive studies in order to solve the above problems, the present ...

PROCESS FOR PRODUCTION OF CYCLIC SILANE COMPOUND AND/OR CYCLIC CARBOSILANE COMPOUND

A process for producing a cyclic silane compound, in which a chained polysilane is subjected to pyrolysis in the presence of an oxide of a transition metal belonging to Group 8 or Group 11 of the periodic table; and a process for producing a cyclic carbosilane compound, that includes subjecting a chained polysilane to pyrolysis in the presence of a simple substance of a metal selected from the group consisting of transition metal elements and elements belonging to Groups 12 to 15 of the periodic table, or a compound thereof. 1. A process for producing a cyclic carbosilane compound , comprising:subjecting a chained polysilane to pyrolysis in the presence of a simple substance of a metal selected from the group consisting of transition metal elements and elements belonging to Groups 12 to 15 of the periodic table, or a compound thereof.3. The process according to claim 1 , wherein the cyclic carbosilane compound is 6- to 8-membered cyclic carbosilane compounds.4. The process according to claim 1 , wherein the transition metal element is titanium claim 1 , manganese claim 1 , iron claim 1 , cobalt claim 1 , or palladium claim 1 , and the element belonging to Groups 12 to 15 of the periodic table is aluminum claim 1 , silicon claim 1 , zinc claim 1 , cadmium claim 1 , tin claim 1 , antimony claim 1 , lead claim 1 , or bismuth. This is a Division of application Ser. No. 13/259,554 filed Sep. 23, 2011, which in turn is a National Stage of PCT/JP2010/056473 filed Apr. 9, 2010, and claims the benefit of Japanese Patent Application No. 2009-096720 filed on Apr. 13, 2009, and Japanese Patent Application No. 2009-096721 filed on Apr. 13, 2009. The disclosure of the prior applications is hereby incorporated by reference herein in its entirety.The present invention relates to a process for producing a cyclic silane compound and/or a cyclic carbosilane compound. More specifically, it relates to a process for providing a cyclic silane compound or a cyclic carbosilane compound from ...

Calcium hypochlorite composition

The present invention provides a composition containing an aluminate and calcium hypochlorite, wherein the content of the aluminate is 1.0 part by weight to less than 2 parts by weight based on 100 parts by weight of the composition.

PYRIDINE COMPOUND AND USE THEREOF

The present invention provides a compound represented by formula (I) (in the formula, Rto Reach represent a hydrogen atom, an unsubstituted or G-substituted C1-6 alkyl group or the like, A represents an oxygen atom or the like, Cy represents a C6-10 aryl group or the like), an N-oxide compound thereof, a tautomer or salt thereof. The present invention also provides an agricultural and horticultural fungicide, harmful organism control agent and insecticidal/acaricidal agent containing at least one compound selected from the group consisting of a compound represented by formula (I), a tautomer and salt thereof, as an active ingredient. 2. An agricultural and horticultural fungicide comprising as an active ingredient at least one selected from the group consisting of the pyridine compound claim 1 , the N-oxide compound thereof claim 1 , and the tautomer and salt thereof according to .3. A harmful organism control agent comprising as an active ingredient at least one selected from the group consisting of the pyridine compound claim 1 , the N-oxide compound thereof claim 1 , and the tautomer and salt thereof according to .4. (canceled)5. (canceled) The present invention relates to a pyridine compound and use thereof such as agricultural and horticultural fungicides, harmful organism control agents, insecticidal agents or acaricidal agents, or the like.Priority is claimed on Japanese Patent Application No. 2016-046046, filed Mar. 9, 2016, the content of which is incorporated herein by reference.In cultivation of agricultural and horticultural crops, a large number of control agents for crop diseases have been proposed. Most of those proposed control agents are not always satisfactory because the controlling effect thereof is insufficient, the use thereof is restricted due to the emergence of drug-resistant pathogenic bacteria, phytotoxicity or pollution to plants occurs, or the toxicity to livestocks and fish and the environmental impact were great. Therefore, an ...

COMPOUND CONTAINING PYRIDINE RING AND METHOD FOR PRODUCING HALOGENATED PICOLINE DERIVATIVE AND TETRAZOLYLOXIME DERIVATIVE

Disclosed is a compound containing a pyridine ring This application is a Divisional of U.S. application Ser. No. 13/583,733, which is the US National Stage application of PCT/JP2011/055809, filed Mar. 11, 2011, which claims priority from Japanese Application Nos. JP 2010-056718, filed Mar. 12, 2010, JP 2010-115703, filed May 19, 2010, and JP 2010-127207, filed Jun. 2, 2010, the entire contents of which are incorporated herein by reference.The present invention relates to (1) a compound containing a pyridine ring that is ideal as an agrochemical intermediate, (2) a production method that enables a 2-substituted amino-6-halomethylpyridine derivative, which is useful as a synthetic intermediate for agrochemicals and the like, to be obtained in high yield, and (3) an industrially advantageous method for producing a tetrazolyloxime derivative that exhibits a superior antagonistic effect against plant diseases.Priority is claimed on Japanese Patent Application No. 2010-056718, filed Mar. 12, 2010, Japanese Patent Application No. 2010-127207, filed Jun. 2, 2010, and Japanese Patent Application No. 2010-115703, filed May 19, 2010, the contents of which are incorporated herein by reference.Examples of methods for producing halomethylpyridine derivatives include a method disclosed in Patent Document 1, in which 2-chloro-5-chloromethylpyridine is produced by adding a chlorinating agent such as oxalyl chloride dropwise to an acetonitrile solution of 2-chloro-5-acetaminomethylpyridine and dimethylformamide, and then heating the mixture at 80° C.Patent Document 2 discloses a method for producing chloromethylpyridines by reacting an aminomethylpyridine with a nitrosating agent or a diazotizing agent, in the presence of a diluent, and if necessary in the presence of hydrogen chloride, and at a temperature within a range from −20° C. to +50° C.Further, Patent Document 3 discloses a method for producing 6-chloro-2-(chloromethyl)pyridine that features reducing 6-chloro-2-( ...

COMPOUND CONTAINING PYRIDINE RING AND METHOD FOR PRODUCING HALOGENATED PICOLINE DERIVATIVE AND TETRAZOLYLOXIME DERIVATIVE

Disclosed is a compound containing a pyridine ring 1. A method for producing a tetrazolyloxime derivative represented by formula (10), the method comprising: a step C1 in which a halogenated picoline derivative represented by formula (7) is reacted with a tetrazolylhydroxyimino derivative represented by formula (8) to obtain a tetrazolyloxime derivative represented by formula (9); and a step C2 in which the tetrazolyloxime derivative represented by formula (9) obtained in the step C1 is treated with a base,{'sup': '2C', 'Rrepresents an unsubstituted or substituent-containing alkoxycarbonyl group, or an unsubstituted or substituent-containing acyl group,'}X represents a halogen atom,{'sup': 3', '3', '3', '3', '3, 'sub': p', '2, 'Z represents a halogen atom, a cyano group, a nitro group, a hydroxyl group, a thiol group, a formyl group, a carboxyl group, an unsubstituted or substituent-containing amino group, an unsubstituted or substituent-containing alkyl group, an unsubstituted or substituent-containing alkenyl group, an unsubstituted or substituent-containing alkynyl group, an unsubstituted or substituent-containing aryl group, an unsubstituted or substituent-containing heterocyclic group, OR, S(O)R, CORor COR(wherein Rrepresents an unsubstituted or substituent-containing amino group, an unsubstituted or substituent-containing alkyl group, an unsubstituted or substituent-containing alkenyl group, an unsubstituted or substituent-containing alkynyl group, an unsubstituted or substituent-containing aryl group, or an unsubstituted or substituent-containing heterocyclic group, and p represents a number of oxygen atoms in parentheses, and is an integer of 0 to 2), and'}m represents a number of Z substituents and is an integer of 0 to 3, and when m is 2 or more, a plurality of the Z substituents may be identical to, or different from, each other, andwithin formula (8), Y represents an unsubstituted or substituent-containing alkyl group,A represents a halogen atom, an ...

COMPOUND CONTAINING PYRIDINE RING AND METHOD FOR PRODUCING HALOGENATED PICOLINE DERIVATIVE AND TETRAZOLYLOXIME DERIVATIVE

Disclosed is a compound containing a pyridine ring 1. A compound comprising a pyridine ring, represented by formula (1):{'sup': '1', 'sub': '1-2', 'Rrepresents a Calkoxycarbonyl group, an acetyl group, or a benzoyl group that may be substituted with a nitro group,'}{'sup': 3', '3', '3', '3', '3, 'sub': p', '2, 'Z represents a halogen atom, a cyano group, a nitro group, a hydroxyl group, a thiol group, a formyl group, a carboxyl group, an unsubstituted or substituent-containing amino group, an unsubstituted or substituent-containing alkyl group, an unsubstituted or substituent-containing alkenyl group, an unsubstituted or substituent-containing alkynyl group, an unsubstituted or substituent-containing aryl group, an unsubstituted or substituent-containing heterocyclic group, OR, S(O)R, CORor COR(wherein Rrepresents an unsubstituted or substituent-containing amino group, an unsubstituted or substituent-containing alkyl group, an unsubstituted or substituent-containing alkenyl group, an unsubstituted or substituent-containing alkynyl group, an unsubstituted or substituent-containing aryl group, or an unsubstituted or substituent-containing heterocyclic group, and p represents a number of oxygen atoms in parentheses, and is an integer of 0 to 2),'}m represents a number of Z substituents and is an integer of 0 to 3, and when m is 2 or more, a plurality of the Z substituents may be identical to, or different from, each other,X represents a halogen atom, andn represents a number of X substituents and is an integer of 0 to 3, and when n is 2 or more, a plurality of X atoms may be identical to, or different from, each other.wherein Rrepresents a Calkoxy group, a Calkoxy-Calkoxy group, a Calkoxy-Calkyl group, a 1,3-dioxane-2-yl-Calkyl group, or a CRC(═NOR) group (wherein each of Rand Rindependently represents a Calkyl group), This application is a Divisional of U.S. application Ser. No. 13/583,733, which is the US National Stage application of PCT/JP2011/055809, filed Mar. 11 ...

Nitrogen-containing heterocyclic compound and method for producing same

There are provided a nitrogen-containing heterocyclic compound such as a substituted amino-pyridine-N-oxide compound represented by formula (1), which is useful as a synthetic intermediate for an agrochemical and the like; and a method for producing the nitrogen-containing heterocyclic compound. (In formula (1), R 1 and R 2 each represents a hydrogen atom or an unsubstituted or substituted alkyl group; R 3 represents a hydrogen atom, an unsubstituted or substituted alkylcarbonyl group or the like; R 4 represents an unsubstituted or substituted alkylcarbonyl group, an unsubstituted or substituted arylcarbonyl group or the like; A represents a hydroxyl group, a thiol group or the like; m represents any one of integers of 1 to 4; k represents any one of integers of 0 to 3; and k+m≦4.)

ADHESIVE COMPOSITION

A novel adhesive composition that exhibits excellent adhesiveness even to materials having poor adhesiveness, such as polyolefin materials. The adhesive composition includes a polymer having a partial structure represented by formula [I] (where Rto Reach independently represent an unsubstituted or substituted aryl group; Rand R, Rand R, or Rand Rare optionally bonded by a single bond; A represents an unsubstituted or substituted arylene group; G represents a carbon atom, a silicon atom, or a germanium atom; and * represents a bonding position). 3. The adhesive composition according to claim 2 , wherein the polymer having the repeating unit represented by formula [II] is a polymer consisting of one or more repeating units represented by formula [II].4. The adhesive composition according to claim 1 , wherein the adhesive composition is for a plastic material.5. The adhesive composition according to claim 1 , wherein the adhesive composition is for a polyolefin material.6. A film formed with the adhesive composition according to .7. The adhesive composition according to claim 2 , wherein the adhesive composition is for a plastic material.8. The adhesive composition according to claim 3 , wherein the adhesive composition is for a plastic material.9. The adhesive composition according to claim 2 , wherein the adhesive composition is for a polyolefin material.10. The adhesive composition according to claim 3 , wherein the adhesive composition is for a polyolefin material.11. A film formed with the adhesive composition according to .12. A film formed with the adhesive composition according to .13. A film formed with the adhesive composition according to .14. A film formed with the adhesive composition according to .15. A film formed with the adhesive composition according to .16. A film formed with the adhesive composition according to .17. A film formed with the adhesive composition according to .18. A film formed with the adhesive composition according to . The present ...

PLANT GROWTH ACCELERATOR

A plant growth accelerator or an agent for growing vigourous seedlings, which comprises a compound represented by formula (1) as an active ingredient: 2. A method for accelerating a plant growth by using 3-(3-bromo-6-fluoro-2-methylindol-1-ylsulfonyl)-N ,N-dimethyl-1H-1 ,2 ,4-triazole-1-sulfonamide as an active ingredient as an active ingredient for accelerating a plant growth.3. The method for accelerating a plant growth according to claim 1 , wherein the method is for seed treatment.5. A method for growing vigourous seedlings by using 3-(3-bromo-6-fluoro-2-methylindol-1-ylsulfonyl)-N claim 1 ,N-dimethyl-1H-1 claim 1 ,2 claim 1 ,4-triazole-1-sulfonamide as an active ingredient as an active ingredient for growing vigourous seedlings.6. The method for growing vigourous seedlings according to claim 4 , wherein the method is for seed treatment.7. The method for accelerating a plant growth according to claim 2 , wherein the method is for seed treatment.8. The method for growing vigourous seedlings according to claim 5 , wherein the method is for seed treatment. The present invention relates to a plant growth accelerator or an agent for growing vigourous seedlings.This application is a Continuation of U.S. application Ser. No. 14/425,113, which is a National Stage application of PCT/JP2013/005204, filed on Sep. 3, 2013, which claims priority to Japanese Patent Application No. 2012-195757, filed on Sep. 6, 2012, the disclosures of which are hereby incorporated by reference.For example, the box seedling method of rice leads to a super-dense seeding due to being adapted to a rice transplanter. Thus, making a mistake in controlling temperature, humidity, and the like can result in the poor growth of rice seedlings and the reduced quality of seedlings. After being transplanted to a paddy field, the seedlings having reduced quality are easily affected by pests and pathogens and are less resistant to changes in weather conditions because of their poor survival properties. Thus, ...

NITROGEN-CONTAINING HETEROCYCLIC COMPOUND AND METHOD FOR PRODUCING SAME

There are provided a nitrogen-containing heterocyclic compound such as a substituted amino-pyridine-N-oxide compound represented by formula (1), which is useful as a synthetic intermediate for an agrochemical and the like; and a method for producing the nitrogen-containing heterocyclic compound. (In formula (1), Rand Reach represents a hydrogen atom or an unsubstituted or substituted alkyl group; Rrepresents a hydrogen atom, an unsubstituted or substituted alkylcarbonyl group or the like; Rrepresents an unsubstituted or substituted alkylcarbonyl group, an unsubstituted or substituted arylcarbonyl group or the like; A represents a hydroxyl group, a thiol group or the like; m represents any one of integers of 1 to 4; k represents any one of integers of 0 to 3; and k+m≦4.) 120-. (canceled) The present invention relates to a nitrogen-containing heterocyclic compound and a method for producing the same. More specifically, the present invention relates to: (1) a substituted amino-pyridine-N-oxide derivative which is useful as a synthetic intermediate of agricultural chemicals or the like; (2) a method for producing a substituted amino-6-methylpyridine-N-oxide derivative; and (3) a method for producing a haloalkyl, nitrogen-containing heterocyclic derivative.Priority is claimed on Japanese Patent Application No. 2010-087915, filed Apr. 6, 2010, Japanese Patent Application No. 2010-087916, filed Apr. 6, 2010, and Japanese Patent Application No. 2010-107195, filed May 7, 2010, the contents of which are incorporated herein by reference.A 2-substituted amino-6-methylpyridine-N-oxide derivative is useful as an intermediate for the synthesis of chemical substances for pharmaceuticals and agrochemicals such as the tetrazolyloxime derivative disclosed in Patent Document 1 since the halogenation or the like of a methyl group at position 6 is easy.In general, pyridine-N-oxide derivatives can be obtained by the oxidation of pyridine derivatives. For example, in Patent Document 2, a ...

NITROGEN-CONTAINING HETEROCYCLIC COMPOUND AND METHOD FOR PRODUCING SAME

There are provided a nitrogen-containing heterocyclic compound such as a substituted amino-pyridine-N-oxide compound represented by formula (1), which is useful as a synthetic intermediate for an agrochemical and the like; and a method for producing the nitrogen-containing heterocyclic compound. (In formula (1), Rand Reach represents a hydrogen atom or an unsubstituted or substituted alkyl group; Rrepresents a hydrogen atom, an unsubstituted or substituted alkylcarbonyl group or the like; Rrepresents an unsubstituted or substituted alkylcarbonyl group, an unsubstituted or substituted arylcarbonyl group or the like; A represents a hydroxyl group, a thiol group or the like; m represents any one of integers of 1 to 4; k represents any one of integers of 0 to 3; and k+m≦4.) 120-. (canceled)22. The method according to claim 21 , wherein all of ato ain formula (4) and formula (5) represent carbon atoms.25. The method according to claim 23 , wherein Rrepresents an unsubstituted or substituted alkylcarbonyl group claim 23 , an unsubstituted or substituted arylcarbonyl group claim 23 , or an unsubstituted or substituted alkoxycarbonyl group.26. The method according to claim 24 , wherein Rrepresents an unsubstituted or substituted alkylcarbonyl group claim 24 , an unsubstituted or substituted arylcarbonyl group claim 24 , or an unsubstituted or substituted alkoxycarbonyl group.27. The method according to claim 21 , wherein the halogenating agent is at least one selected from the group consisting of thionyl chloride claim 21 , thionyl bromide claim 21 , phosphorus oxychloride claim 21 , sulfuryl chloride claim 21 , phosgene claim 21 , diphosgene and triphosgene.28. The method according to claim 27 , wherein the halogenating agent is at least one selected from the group consisting of thionyl chloride claim 27 , thionyl bromide and sulfuryl chloride.29. The method according to claim 27 , wherein the halogenating agent is at least one selected from the group consisting of ...

RECORDING MATERIAL AND COMPOUND

An object of the present invention is to provide a recording material or a recording sheet using, as a color-developing agent, a non-phenol-based compound good in color developing performance and the like. A compound represented by the following formula (I) is used as the color-developing agent: 2. A recording sheet having a recording material layer formed with the recording material according to on a support. The present invention relates to a thermal or pressure-sensitive recording material employing color development through a reaction between a color former and a color-developing agent.The present application claims priority based on Japanese Patent Application No. 2017-113439 filed on Jun. 8, 2017, and the contents thereof are incorporated herein by reference in their entirety.Recording materials that employ color development through a reaction between a color former and a color-developing agent allow recording in a short time using a relatively simple apparatus without performing complicated treatments such as development and fixation and are thus widely used in thermal recording paper for output recording in facsimiles, printers, etc., or pressure-sensitive copying paper or the like for forms for simultaneous multiple copying. These recording materials are required to immediately develop colors, maintain the whiteness of an uncolored part (hereinafter, referred to as a “background”), and offer high colorfastness of colored images. For this purpose, attempts have been made to develop color former, color-developing agents, storage stabilizers, etc. Nevertheless, few recording materials have well-balanced, sufficiently satisfactory color-developing sensitivity, background and image storage property, etc.On the other hand, although a phenol color-developing agent such as 4,4′-isopropylidene diphenol shows good color-developing performance, such an agent can correspond to an endocrine disruptor and is not allowed to be used for some users. Therefore, a color- ...

HETEROCYCLIC COMPOUND AND AGRICULTURAL OR HORTICULTURAL FUNGICIDE

A compound of formula (I) (in the formula (I), Rrepresents a substituted or unsubstituted C1-6 alkyl group or the like, Rrepresents a substituted or unsubstituted 5- or 6-membered heteroaryl group, Rrepresents a substituted or unsubstituted C1-6 alkyl group, a substituted or unsubstituted C1-6 alkoxycarbonyl group or the like, Y represents an oxygen atom or NH, Arepresents a sulfur atom, an oxygen atom, or NR, Rrepresents a C1-6 alkyl group, Ais a carbon atom or a nitrogen atom, X represents a substituent, n represents the chemically acceptable number of X, and is an integer of 0 to 3, and, when n is 2 or more, X may be identical to or different from each other), or a salt thereof is provided. 2. The compound or the salt thereof according to claim 1 , wherein claim 1 , in the formula (I) claim 1 , X represents a substituted or unsubstituted C1-6 alkyl group claim 1 , a substituted or unsubstituted C2-6 alkenyl group claim 1 , a substituted or unsubstituted C2-6 alkynyl group claim 1 , a hydroxy group claim 1 , a substituted or unsubstituted C1-6 alkoxy group claim 1 , a substituted or unsubstituted C1-6 alkoxycarbonyl group claim 1 , a substituted or unsubstituted C1-6 alkylthio group claim 1 , a substituted or unsubstituted C3-8 cycloalkyl group claim 1 , a substituted or unsubstituted C6-10 aryl group claim 1 , a halogeno group claim 1 , a cyano group claim 1 , a group of formula: “—NRR” (wherein Rand Reach independently represents a hydrogen atom claim 1 , a C1-6 alkyl group claim 1 , or a C1-6 alkoxycarbonyl group) claim 1 , or a group of formula: “—C(R)═NOR” (wherein Rand Reach independently represents a hydrogen atom or a C1-6 alkyl group).5. An agricultural or horticultural fungicide comprising at least one selected from the group consisting of compounds and salts thereof of claim 1 , as an active ingredient thereof. The present invention relates to a heterocyclic compound and an agricultural or horticultural fungicide. Furthermore, the present invention ...

Aryloxyurea compound and pest control agent

The present invention provides an aryloxyurea compound or salt thereof, and a pest control agent including the aryloxyurea compound or salt thereof as an active ingredient. The aryloxyurea compound has a superior acaricidal and/or insecticidal activity, superior safety, and can be synthesized advantageously and industrially. The compound of the present invention includes aryloxyurea compounds represented by the following formula or salts thereof: in the formula, Cy represents an unsubstituted or X-substituted phenyl group or the like, X represents a halogen atom or the like, R 1 represents an ethyl group or the like, R 2 represents a hydrogen atom or the like, R 3 and R 4 represents a methyl group or the like, X 1 represents a methylthio group or the like, m1 represents an integer of 1 to 4, X 2 represents a methyl group or the like, m2 is an integer of 0 to 3.

ALUMINUM-HALOGEN FUEL CELL

An aluminum-halogen fuel cell has a positive electrode (), a negative electrode (), and an electrolyte () containing an ionic liquid represented by formula (1) or the like. In formula (1), Rrepresents an unsubstituted or substituent-containing C1 to C20 alkyl group, Rrepresents a C1 to C4 alkyl group or the like, each of Rand Rindependently represents a hydrogen atom or the like, X represents AlClor the like, and Y represents AlClor the like. 2. The aluminum-halogen fuel cell according to claim 1 , wherein the negative electrode is formed from scrap aluminum.3. The aluminum-halogen fuel cell according to claim 1 , wherein a temperature of the electrolyte is 40° C. or higher.4. The aluminum-halogen fuel cell according to claim 3 , wherein a temperature of the electrolyte is 60° C. or higher.5. The aluminum-halogen fuel cell according to any one of claim 1 , wherein the positive electrode has an uneven surface.6. A method of producing aluminum chloride or aluminum bromide claim 1 , comprising using the aluminum-halogen fuel cell according to any one of . The present invention relates to a fuel cell (hereafter referred to as an aluminum-halogen fuel cell) which extracts the energy generated when aluminum is halogenated as electrical power.Priority is claimed on Japanese Patent Application No. 2011-159583, filed Jul. 21, 2011, and Japanese Patent Application No. 2012-020362, filed Feb. 1, 2012, the contents of which are incorporated herein by reference.The theoretical energy density of aluminum per unit volume is 8,050 Ah/l, which is equivalent to approximately 4 times that of lithium. Accordingly, if aluminum or an aluminum alloy can be used as the negative electrode of a cell, then a cell having a high energy density can be realized at low cost. Further, because the electrode potential of aluminum is −1.66 V (vs. the standard hydrogen electrode), indicating lower potential, by combining aluminum with an appropriate positive electrode active material, there is a ...

ORGANIC-INORGANIC COMPLEX, AND COMPOSITION FOR FORMING SAME (As Amended)

The organic-inorganic complex of the present invention is made using an organic-inorganic complex-forming composition containing the following components a) to c): a) at least one organic silicon compound represented by the formula (I) RSiXand in which a molar ratio of an organic silicon compound in which a solubility parameter of R (SP1) obtained by a Fedors' estimation method is smaller than a solubility parameter of an electromagnetic ray-curable compound (SP2) obtained by the Fedors' estimation method and a difference between the SP1 and the SP2 is 2.0 or more (Si1) to an organic silicon compound in which SP1 is smaller than SP2 and a difference between the SP1 and the SP2 is less than 2.0 or an organic silicon compound in which SP1 is larger than SP2 (Si2) (Si1:Si2) is within the range of 8:2 to 10:0, and/or a condensate of the organic silicon compound; b) an electromagnetic ray-curable compound; and c) metal compound particles. 1. An organic-inorganic complex-forming composition comprising: {'br': None, 'sub': n', '4-n, 'RSiX\u2003\u2003(I)'}, 'a) at least one organic silicon compound represented by formula (I)(wherein R represents an organic group having a carbon atom directly bonded to Si, and X represents a hydroxyl group or a hydrolyzable group; and n represents 1 or 2, wherein when n is 2, each R is the same or different, and when (4−n) is 2 or more, each X is the same or different) and wherein a molar ratio of an organic silicon compound in which a solubility parameter of R(SP1) obtained by a Fedors' estimation method is smaller than a solubility parameter of an electromagnetic ray-curable compound (SP2) obtained by the Fedors' estimation method and a difference between the SP1 and the SP2 is 2.0 or more (Si1) to an organic silicon compound in which SP1 is smaller than SP2 and a difference between the SP1 and the SP2 is less than 2.0 or an organic silicon compound in which SP1 is larger than SP2 (Si2) (Si1:Si2) is within the range of 8:2 to 10:0, and/or ...

HARMFUL ORGANISM CONTROL METHOD AND HARMFUL ORGANISM CONTROL COMPOSITION

The present invention provides a harmful organism control method including applying 3-endo-[2-propoxy-4-(trifluoromethyl)phenoxyl]-9-[5-(trifluoromethyl)-2-pyridyloxy]-9-azabicyclo[3.3.1]nonane in combination with an insecticidal or acaricidal active ingredient such as an active ingredient of an insecticidal or acaricidal agent having an action mechanism classified by the IRAC code. 1. A harmful organism control method , comprising applying 3-endo-[2-propoxy-4-(trifluoromethyl)phenoxy]-9-[5-(trifluoromethyl)-2-pyridyloxy]-9-azabicyclo[3.3.1]nonane to an object in combination with an insecticidal or acaricidal active ingredient.2. The control method according to claim 1 , wherein the insecticidal or acaricidal active ingredient is an active ingredient of an insecticidal or acaricidal agent having an action mechanism classified by the IRAC code.3. The control method according to claim 1 , wherein the insecticidal or acaricidal active ingredient is at least one selected from the group consisting of (1) acetylcholinesterase inhibitor claim 1 , (2) GABA-gated chloride ion channel blocker claim 1 , (3) sodium channel modulator claim 1 , (5) nicotinic acetylcholine receptor allosteric modulator claim 1 , (6) glutamate-gated chloride ion channel allosteric modulator claim 1 , (7) juvenile hormone analogs claim 1 , (8) other non-specific (multi-site) inhibitors claim 1 , (9) chordotonal organ TRPV channel modulator claim 1 , (10) acari growth inhibitor claim 1 , (11) microorganism-derived insect midgut inner membrane disrupting agent claim 1 , (12) mitochondrial ATP synthase inhibitor claim 1 , (13) oxidative phosphorylation uncoupler that disrupts proton gradient claim 1 , (14) nicotinic acetylcholine receptor channel blocker claim 1 , (15) chitin biosynthesis inhibitor type 0 claim 1 , (16) chitin biosynthesis inhibitor type 1 claim 1 , (17) diptera insect molting inhibitor claim 1 , (18) molting hormone receptor agonist claim 1 , (19) octopamine receptor agonist claim 1 , ...

ZINC SALT OF ISOTHIAZOLONE COMPOUND, METHOD FOR REDUCING IRRITATION CAUSED BY ISOTHIAZOLONE COMPOUND, ANTIBACTERIAL AND ANTIFUNGAL METHOD USING ZINC SALT OF ISOTHIAZOLONE COMPOUND, AND ANTIBACTERIAL AND ANTIFUNGAL COMPOSITION

A method for reducing irritation caused by an isothiazolone compound represented by formula (1) by converting the isothiazolone compound represented by formula (1) into a zinc salt. 2. The method according to claim 1 , further comprising using at least one solvent selected from the group consisting of water claim 1 , alcohol-based solvents claim 1 , ketone-based solvents claim 1 , ether-based solvents claim 1 , amide-based solvents claim 1 , glycol-based solvents claim 1 , glycol ether-based solvents claim 1 , glycol diester-based solvents claim 1 , glycol ester ether-based solvents claim 1 , and ester-based solvents.3. The method according to claim 1 , further comprising mixing at least one isothiazolone compound represented by formula (1) and at least one zinc compound claim 1 , excluding the zinc salt of an isothiazolone compound represented by formula (1) claim 1 , at a predetermined ratio.4. The method according to claim 2 , further comprising mixing at least one isothiazolone compound represented by formula (1) and at least one zinc compound claim 2 , excluding the zinc salt of an isothiazolone compound represented by formula (1) claim 2 , at a predetermined ratio.5. The method according to claim 3 , wherein the zinc salt is obtained by mixing the compound represented by formula (1) and the zinc compound so that a molar ratio between the compound represented by the formula (1) and the zinc compound is from 1:10 to 10:1.6. The method according to claim 4 , wherein the zinc salt is obtained by mixing the compound represented by formula (1) and the zinc compound so that a molar ratio between the compound represented by the formula (1) and the zinc compound is from 1:10 to 10:1. CROSS-REFERENCE TO PRIOR APPLICATIONThis is a continuation of application Ser. No. 14/141,111 filed Dec. 26, 2013, which is a continuation of application Ser. No. 13/067,622 filed Jun. 15, 2011, which is a continuation of application Ser. No. 12/452,688 filed Jan. 27, 2010, which is a ...

COMPOSITION FOR PREPARING EMULSION OR MICROEMULSION

A composition for preparing an emulsion or microemulsion, the composition including the following components (A) to (D): 1. A composition for preparing an emulsion or microemulsion , the composition comprising the following components (A) to (D):component (A): an active ingredient having a solubility in water at 20° C. of 200 ppm or less;component (B): a water-insoluble solvent having no alcohol group;component (C): at least one nonionic surfactant selected from the group consisting of a polyoxyalkylene alkyl ether, a polyoxyalkylene alkenyl ether, a polyoxyalkylene alkyl amino ether, and a polyoxyalkylene alkenyl amino ether; andcomponent (D): a monohydric alcohol having 8 to 12 carbon atoms.2. The composition for preparing an emulsion or microemulsion according to claim 1 , further comprising a component (E) which is water.3. The composition for preparing an emulsion or micro emulsion according to claim 2 ,wherein relative to the mass of the composition, the component (A) is from 1 to 30% by mass, the component (B) is from 5 to 40% by mass, the component (C) is from 10 to 80% by mass, the component (D) is from 1 to 20% by mass, and the component (E) is equal to or less than 60% by mass;relative to the mass of the component (B), the component (A) is equal to or less than 100% by mass; anda component (G) which is a nonionic surfactant other than the component (C) may be contained, and the total amount of the component (C) and the component (G) is from 100 to 1,000% by mass, relative to the mass of the component (B).4. The composition for preparing an emulsion or microemulsion according to claim 3 ,wherein the total amount of the component (C) and the component (G), relative to the mass of the composition, is from 20 to 80% by mass.5. The composition for preparing an emulsion or microemulsion according to claim 1 ,wherein the component (A) is at least one active ingredient selected from the group consisting of an insecticide, a bactericide, a fungicide, a ...

NITROGEN-CONTAINING HETEROCYCLIC COMPOUND AND METHOD FOR PRODUCING SAME

There are provided a nitrogen-containing heterocyclic compound such as a substituted amino-pyridine-N-oxide compound represented by formula (1), which is useful as a synthetic intermediate for an agrochemical and the like; and a method for producing the nitrogen-containing heterocyclic compound. (In formula (1), Rand Reach represents a hydrogen atom or an unsubstituted or substituted alkyl group; Rrepresents a hydrogen atom, an unsubstituted or substituted alkylcarbonyl group or the like; Rrepresents an unsubstituted or substituted alkylcarbonyl group, an unsubstituted or substituted arylcarbonyl group or the like; A represents a hydroxyl group, a thiol group or the like; m represents any one of integers of 1 to 4; k represents any one of integers of 0 to 3; and k+m≦4.) 120-. (canceled)22. The method according to claim 21 , wherein the reaction is carried out in a presence of a halogen ion source that is soluble in an organic solvent.23. The method according to claim 22 , wherein the halogen ion source that is soluble in an organic solvent is a halogenated ammonium salt or a halogenated phosphonium salt.24. The method according to claim 22 , wherein the halogen ion source that is soluble in an organic solvent is a tertiary or quaternary alkyl ammonium halide salt having an alkyl group of Cor more claim 22 , or an alkyl phosphonium halide salt having an alkyl group of Cor more.25. The method according to claim 21 ,wherein the halogenating agent is at least one selected from the group consisting of thionyl chloride, thionyl bromide, phosphorus oxychloride, sulfuryl chloride, phosgene, diphosgene and triphosgene.26. The production method according to claim 22 ,wherein the halogenating agent is at least one selected from the group consisting of thionyl chloride, thionyl bromide, phosphorus oxychloride, sulfuryl chloride, phosgene, diphosgene and triphosgene.27. The production method according to claim 23 ,wherein the halogenating agent is at least one selected from the ...

Adsorption method

A method of selectively and efficiently adsorbing an anion such as a phosphate ion which adversely affect the environment when discharged without any treatment, or an anion which can be used beneficially when recovered, from waste water or a solution including such ion using an adsorbent. A method of adsorbing an anion of interest from an aqueous solution (A) containing the anion of interest and the other anion using an anion adsorbent, including performing at least (1) a step of contacting the aqueous solution (A) having a pH of 5.8 or less with the anion adsorbent to allow the anions to be adsorbed to the anion adsorbent, and then (2) a step of contacting water or an aqueous solution (B) having a pH of 5.2 to 11 with the anion adsorbent to desorb at least a part of the other anion adsorbed to the anion adsorbent from the anion adsorbent.

(hetero)aryl sulfonamide compound and formulation for controlling harmful organisms

In formula (I), Ar1 is a benzene ring or a 5- to 6-membered heteroaryl ring, R1 is a C1 to C6 alkyl group, a halogeno group, or the like, n represents the number of R1 and is 0, 1, 2, or 3, and in the case of n being 2 or more, two or more R1 may be the same as or different from one another, R2 is a C1 to C6 alkyl group, a C1 to C6 haloalkyl group, or the like, R3 is a hydrogen atom, a C1 to C6 alkyl group, a C1 to C6 alkylcarbonyl group, or the like, and AR2 represents a substituted or unsubstituted heteroaryl group.

ORGANIC-INORGANIC HYBRID

An organic-inorganic hybrid forming composition, which is capable of forming an organic-inorganic hybrid with less yellow coloring than conventional ones, while maintaining the surface hardness. The organic-inorganic hybrid forming composition includes: a) a condensate of an organosilicon compound represented by the formula (I): RSiX(I) (where R represents an organic group having a carbon atom directly bonded to Si in the formula; X each independently represents a hydroxyl group or a hydrolyzable group; and n represents 1 or 2, and when n is 2, each R is the same or different), which is obtained by condensing the organosilicon compound represented by the formula (I) in the presence of a zirconium complex; b) an electromagnetic ray-curable compound; and c) a photopolymerization initiator. 1. An organic-inorganic hybrid forming composition comprising: {'br': None, 'sub': n', '4-n, 'RSiX\u2003\u2003(I)'}, 'a) a condensate of an organosilicon compound represented by the formula (I)(wherein R represents an organic group having a carbon atom directly bonded to Si in the formula; X each independently represents a hydroxyl group or a hydrolyzable group; and n represents 1 or 2, and when n is 2, each R is the same or different),which is obtained by condensing the organosilicon compound represented by the formula (I) in the presence of a zirconium complex;b) an electromagnetic ray-curable compound; andc) a photopolymerization initiator.2. The organic-inorganic hybrid forming composition according to claim 1 , wherein at least one of the organosilicon compounds represented by the formula (I) is an organosilicon compound represented by the formula (I-1):{'br': None, 'sup': '1', 'sub': n', '4-n, 'RSiX\u2003\u2003(I-1)'}{'sup': 1', '1', '1, '(wherein n represents 1 or 2, and when n is 2, each Ris the same or different; Rrepresents an organic group having a carbon atom directly bonded to Si in the formula, and at least one Rrepresents a vinyl group-containing hydrocarbon group; ...

PYRIDINIUM SALT AND PEST CONTROL AGENT

Provided are: a compound represented by Formula (I) or Formula (II) (wherein A represents an oxygen atom or a sulfur atom, Xrepresents a substituted or unsubstituted C1-6 alkyl group or the like, m is any integer of 0 to 5, Xrepresents a C2-8 haloalkyl group or the like, Xrepresents a halogeno group or the like, n is any integer of 0-4, Z is a counter ion, and q is 1 or 2); and a pest control agent containing the compound as an active agent. 2. A pest control agent comprising at least one selected from compounds of as an active ingredient thereof.3. An insecticide or acaricide comprising at least one selected from compounds of as an active ingredient thereof.4. An ectoparasite control agent comprising at least one selected from compounds of as an active ingredient thereof.5. An endoparasite control agent or expellant comprising at least one selected from compounds of as an active ingredient thereof. The present invention relates to a pyridinium salt and a pest control agent. In more detail, the present invention relates to a pyridinium salt that has excellent insecticidal activity and/or acaricidal activity, and excellent safety, and that can be synthesized industrially advantageously, as well as a pest control agent containing the same as an active ingredient thereof.The present invention claims priority on the basis of Japanese Patent Application No. 2019-100657 filed in Japan on May 29, 2019, the contents of which are incorporated herein by reference.Various compounds having insecticidal and/or acaricidal activity have been proposed. In the case where such compounds are used as agrochemicals, the compounds are required not only to exhibit high activity, but also to exhibit less possibility of causing chemical resistance, harmful effects on plants, or soil pollution, and to exhibit low toxicity to domestic animals or fish.Patent Document 1 discloses a compound of formula (A) which has acaricidal activity.Non-patent Document 1 discloses a compound of formula (B) ...

Tree trunk injection

The present invention provides a tree trunk injection agent whereby pathogenic fungi and/or pests in trees can be effectively controlled merely by a short-time application in a low chemical dose, and a method for controlling tree diseases using the tree trunk injection agent. According to one embodiment of the present invention, the tree trunk injection agent is obtained by adding, to an aqueous solution of an insecticidal component such as acetamiprid, a hardly soluble fungicidal component such as thiophanate-methyl so as to suspend the hardly soluble fungicidal component, wherein a particle size based on 50% volume of the fungicidal component is 4 μm or less, or adding thereto at least one fungicidal component selected from a group consisting of triflumizole and metconazole.