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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 491. Отображено 100.
04-01-2018 дата публикации

Article of Manufacture for Securing a Catalyst Substrate

Номер: US20180001261A1
Автор: Anderson Matthew, Somogyvari Arpad
Принадлежит: Cummins Emission Solutions Inc.

An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and the compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion. 113.-. (canceled)14. A method comprising:passing a heated exhaust stream into a aftertreatment substrate;thermally expanding the aftertreatment substrate into a compressible material defining the aftertreatment substrate; andas a result of thermally expanding the aftertreatment substrate into the compressible material defining the aftertreatment substrate, at least partially compressing corrugations of the compressible material.15. The method of claim 14 , further comprising confining the compressible material within an outer skin defining the compressible material.16. The method of claim 14 , further comprising positioning the aftertreatment substrate within the compressible material claim 14 , and applying a catalyst washcoat to the aftertreatment substrate after the positioning.17. The method of claim 16 , further comprising applying at least a portion of the catalyst washcoat to a substrate side of the compressible material.18. The method of claim 14 , wherein the compressible material is defined in part by an outer skin claim 14 , and wherein the compressible material is at least partially compressed between the outer skin and the aftertreatment substrate.19. The method of claim 14 , wherein the compressible material comprises a polymer-based thermoset.20. The method of claim 14 , wherein the compressible material comprises a thermoplastic material.21. The method ...

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Номер записи: 1
14-01-2016 дата публикации

Article of Manufacture for Securing a Catalyst Substrate

Номер: US20160008758A1
Автор: Anderson Matthew, Somogyvari Arpad
Принадлежит: Cummins Emission Solutions Inc.

An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and The compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion. 1. An aftertreatment component of an exhaust aftertreatment system , comprising:an aftertreatment substrate;a compressible material coupled to an outer surface the aftertreatment substrate; anda catalyst washcoat disposed on the aftertreatment substrate, wherein the catalyst washcoat is applied to the aftertreatment substrate after the compressible material is coupled to the aftertreatment substrate.2. The aftertreatment component of claim 1 , wherein the compressible material comprises a metal foil.3. The aftertreatment component of claim 1 , further comprising a catalyst washcoat disposed on the aftertreatment substrate.4. The aftertreatment component of claim 3 , wherein the catalyst washcoat is disposed on a substrate side of the compressible material.5. The aftertreatment component of claim 1 , further comprising an outer skin claim 1 , the outer skin defining the compressible material.6. The aftertreatment component of claim 5 , wherein the outer skin at least partially compresses the compressible material against the aftertreatment substrate.7. The aftertreatment component of claim 6 , wherein the outer skin applies a selected closure force to the aftertreatment substrate through the compressible material.8. The aftertreatment component of claim 1 , wherein the compressible material is in tension claim 1 , and wherein corrugations in the compressible material ...

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Номер записи: 2
17-01-2019 дата публикации

Doped carbonaceous materials for photocatalytic removal of pollutants under visible light, making methods and applications of same

Номер: US20190015818A1
Автор: Anindya Ghosh, Bijay P. CHHETRI
Принадлежит: University of Arkansas

A method of synthesizing a doped carbonaceous material includes mixing a carbon precursor material with at least one dopant to form a homogeneous/heterogeneous mixture; and subjecting the mixture to pyrolysis in an inert atmosphere to obtain the doped carbonaceous material. A method of purifying water includes providing an amount of the doped carbonaceous material in the water as a photocatalyst; and illuminating the water containing the doped carbonaceous material with visible light such that under visible light illumination, the doped carbonaceous material generates excitons (electron-hole pairs) and has high electron affinity, which react with oxygen and water adsorbed on its surface forming reactive oxygen species (ROS), such as hydroxyl radicals and superoxide radicals, singlet oxygen, hydrogen peroxide, that, in turn, decompose pollutants and micropollutants.

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Номер записи: 3
21-01-2021 дата публикации

PHOTOCATALYST TRANSFER FILM AND PRODUCTION METHOD THEREOF

Номер: US20210016249A1
Автор: FURUDATE Manabu, INOUE Tomohiro, YUYAMA Masahiro
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

Provided are a photocatalyst transfer film allowing a uniform and highly transparent photocatalyst layer to be transferred to the surfaces of various transfer base materials; and a production method thereof. The photocatalyst transfer film has, on a biaxially oriented polypropylene film, a photocatalyst layer containing a titanium oxide particle-containing photocatalyst, a silicon compound and a surfactant. The production method of the photocatalyst transfer film includes applying a photocatalyst coating liquid to a biaxially oriented polypropylene film; and performing drying. The photocatalyst coating liquid contains a titanium oxide particle-containing photocatalyst, a silicon compound, a surfactant and an aqueous dispersion medium. 1. A photocatalyst transfer film having , on a biaxially oriented polypropylene film , a photocatalyst layer containing a titanium oxide particle-containing photocatalyst , a silicon compound and a surfactant.2. The photocatalyst transfer film according to claim 1 , wherein the silicon compound is a hydrolysis condensate of a tetrafunctional silicon compound claim 1 , the hydrolysis condensate being obtained under the presence of an organic ammonium salt.3. The photocatalyst transfer film according to claim 1 , wherein the surfactant is an acetylene-based surfactant.4. The photocatalyst transfer film according to claim 1 , wherein the photocatalyst layer has a thickness of 20 to 300 nm.5. The photocatalyst transfer film according to claim 1 , wherein the biaxially oriented polypropylene film has a thickness of 12.5 to 100 μm.6. The photocatalyst transfer film according to claim 1 , wherein a protective layer containing a silicon compound is further laminated on the photocatalyst layer.7. A method for producing a photocatalyst transfer film claim 1 , comprising:applying a photocatalyst coating liquid to a biaxially oriented polypropylene film, the photocatalyst coating liquid containing a titanium oxide particle-containing photocatalyst ...

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Номер записи: 4
21-01-2021 дата публикации

CATALYTIC TEST PAPER PREPARED BY COMPOSITING METAL PARTICLE-EMBEDDED BACTERIAL CELLULOSE WITH PLANT FIBERS, AND METHOD THEREFOR

Номер: US20210016264A1
Автор: LI JUN, LV Fachuang, XIANG Zhouyang
Принадлежит: SOUTH CHINA UNIVERSITY OF TECHNOLOGY

Disclosed is a catalytic test paper prepared by compositing metal particle-embedded bacterial cellulose with plant fibers, and a preparation method therefor. Hydroxyl groups of bacterial cellulose are bonded with a nitrogen-containing or phosphorus-containing organic small molecule compound. By means of a chelation between a nitrogen or phosphorus atom with a metal, transition metal ions are adsorbed to a nanoporous surface of bacterial cellulose, and the transition metal ions are reduced in situ to obtain bacterial cellulose embedded with metal nanoparticles. The bacterial cellulose is composited with the plant fiber, and the catalytic test paper is prepared by a papermaking method. The catalytic test paper has the advantages of convenient use and recovery, high reusability, simple design, low manufacturing cost, higher catalytic efficiency, a green degradable support material, etc. 1. A method for preparing a catalytic test paper by compositing metal particle-embedded bacterial cellulose with plant fibers , characterized in that , the method comprises the following steps:(1) chemically bonding a nitrogen-containing or phosphorus-containing organic small molecule compound with hydroxyl groups in a structure of bacterial cellulose to obtain a functionalized bacterial cellulose having a nitrogen or phosphorus-containing group;(2) preparing an aqueous solution of an inorganic salt of a transition metal, adding the aqueous solution into the functionalized bacterial cellulose prepared in the step (1), stirring and reacting according to a solubility of the inorganic salt of the transition metal until the nitrogen-containing or phosphorus-containing group adsorbs transition metal ions onto a nanoporous surface of the bacterial cellulose till saturation, separating and washing with water;(3) reducing the transition metal ions adsorbed on the surface of the bacterial cellulose in the step (2) in situ to obtain bacterial cellulose embedded with transition metal nanoparticles ...

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Номер записи: 5
10-02-2022 дата публикации

LIGHT UPCONVERSION MICROCAPSULES

Номер: US20220040682A1
Автор: Campbell Eric J., Czaplewski-Campbell Sarah K., Kobilka Brandon M., Wertz Jason T.
Принадлежит:

A composition, method, and article of manufacture are disclosed. The composition is a microcapsule that includes a transparent shell encapsulating a mixture comprising light upconversion molecules. The method is a method of forming a microcapsule, which includes obtaining light upconversion molecules, forming an emulsion of the light upconversion molecules and a shell formation solution, and encapsulating the light upconversion molecules in a transparent shell. The article of manufacture comprises the microcapsule. 1. A microcapsule , comprising:a transparent shell encapsulating a mixture, the mixture comprising light upconversion molecules.2. The microcapsule of claim 1 , wherein the light upconversion molecules comprise a molecular sensitizer and a molecular annihilator.3. The microcapsule of claim 1 , wherein the mixture further comprises a non-polar solvent.4. The microcapsule of claim 1 , wherein the transparent shell is a urea-formaldehyde shell.5. The microcapsule of claim 1 , wherein the light upconversion molecules comprise a molecular sensitizer selected from the group consisting of a transition metal complex of a porphyrin and a transition metal complex of a phthalocyanine.6. The microcapsule of claim 1 , wherein the light upconversion molecules comprise a molecular annihilator selected from the group consisting of a furanyldiketopyrrolopyrrole and a perylene.7. A method of forming a microcapsule claim 1 , comprising:obtaining light upconversion molecules;forming an emulsion that includes the light upconversion molecules and a shell formation solution; andencapsulating the light upconversion molecules in a transparent shell.8. The method of claim 7 , wherein the light upconversion molecules comprise a molecular sensitizer and a molecular annihilator.9. The method of claim 8 , further comprising:forming a reaction system that includes the microcapsule, a photocatalyst, and a substrate; andexposing the reaction system to light having sufficient energy to ...

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Номер записи: 6
10-02-2022 дата публикации

SURFACE-MODIFIED LIGHT UPCONVERSION SILICA PARTICLES

Номер: US20220040683A1
Автор: Campbell Eric J., Czaplewski-Campbell Sarah K., Kobilka Brandon M., Wertz Jason T.
Принадлежит:

A composition, method, and article of manufacture are disclosed. The composition includes a silica particle with light upconversion molecules bound to its surface. The method includes obtaining silica particles and light upconversion molecules having sidechains with reactive functional groups. The method further includes binding the light upconversion molecules to surfaces of the silica particles. The article of manufacture includes the composition. 1. A composition , comprising:a silica particle; andlight upconversion molecules bound to a surface of the silica particle.2. The composition of claim 1 , wherein the light upconversion molecules comprise molecular sensitizers.3. The composition of claim 1 , wherein the light upconversion molecules comprise molecular annihilators.4. The composition of claim 1 , wherein the light upconversion molecules comprise molecular annihilators and molecular sensitizers.5. The composition of claim 1 , wherein the surface of the silica particle includes a first face and a second face.6. The composition of claim 5 , wherein the light upconversion molecules comprise molecular sensitizers bound to the first face of the silica particle.7. The composition of claim 6 , wherein the light upconversion molecules comprise molecular annihilators bound to the second face of the silica particle.8. A method of forming surface-modified particles claim 6 , comprising:obtaining silica particles;obtaining light upconversion molecules having sidechains with reactive functional groups; andbinding the light upconversion molecules to surfaces of the silica particles.9. The method of claim 8 , wherein the reactive functional groups are silyl groups.10. The method of claim 8 , further comprising forming a reaction environment claim 8 , the reaction environment comprising:the surface-modified particles;a photocatalyst; anda substrate.11. The method of claim 8 , wherein the silica particles are Janus particles.12. The method of claim 8 , wherein the light ...

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Номер записи: 7
26-01-2017 дата публикации

MEMBRANE TEMPLATE SYNTHESIS OF MICROTUBE ENGINES

Номер: US20170022620A1
Автор: Gao Wei, Sattayasamitsathit Sirilak, Wang Joseph
Принадлежит:

Methods, structures, devices and systems are disclosed for fabrication of microtube engines using membrane template electrodeposition. Such nanomotors operate based on bubble-induced propulsion in biological fluids and salt-rich environments. In one aspect, fabricating microengines includes depositing a polymer layer on a membrane template, depositing a conductive metal layer on the polymer layer, and dissolving the membrane template to release the multilayer microtubes. 126-. (canceled)27. A microstructure , comprising:a microtube having a large opening and a short opening at opposite ends of the microtube and a tube body connecting the large opening and the short opening and a spatially reducing size along a longitudinal direction from the large opening to the small opening;the microtube further including a layered wall structure defining the tube body, the layered wall structure having at least two layers, a first layer that is an external layer formed of a material capable of being functionalized, and a second layer that is an inner layer.28. The microstructure of claim 27 , wherein the first layer comprises a polymer material.29. The microstructure of claim 28 , wherein the polymer material comprises polyaniline (PANT) or polypyrrole (PPy) or poly(3 claim 28 ,4-ethylenedioxythiophene) (PEDOT).30. The microstructure of claim 27 , wherein the second layer comprises a material that is reactive with a fuel or is a catalyst of a fuel.31. The microstructure of claim 30 , wherein the material that is reactive with a fuel or is a catalyst of a fuel comprises a conductive metal.32. The microstructure of claim 30 , wherein the material that is a catalyst of a fuel comprises platinum.33. The microstructure of claim 27 , wherein the template comprises cyclopore polycarbonated membrane.34. The microstructure of claim 33 , wherein the cyclopore polycarbonated membrane comprises an asymmetrical claim 33 , conically-shaped pore structure.35. The microstructure of claim 34 , ...

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Номер записи: 8
01-02-2018 дата публикации

PROCESS FOR THE PREPARATION OF NANOPARTICLES OF NOBLE METALS IN HYDROGEL AND NANOPARTICLES THUS OBTAINED

Номер: US20180029000A1
Автор: Blosi Magda, Costa Anna Luisa
Принадлежит:

There is described a versatile and environment-friendly one-pot process for the preparation of nanoparticles of noble metals in hydrogel, obtainable at room temperature using quaternized hydroxyethylcellulose. 1. Hydrogel comprising water , at least one quaternary ammonium salt of hydroxyethylcellulose , and nanoparticles of at least one metal , wherein:said at least one metal is selected from Au, Ag, Cu, Pd, Pt, and mixtures thereof,said at least one quaternary ammonium salt of hydroxyethylcellulose is selected from polyquaternium-4, polyquatemium-10, polyquaternium-24 and polyquaternium-67,said nanoparticles of at least one metal of said nanoparticles have an average particle size distribution D50 of 10-100 nm, and are in a concentration of 0.3-5% m/m of the hydrogel.2. The hydrogel of claim 1 , wherein said at least one quaternary ammonium salt of hydroxyethylcellulose and said metal are in a molar ratio from 1:1 to 10:1.3. The hydrogel of claim 2 , wherein said at least one quaternary ammonium salt of hydroxyethylcellulose and said metal are in a molar ratio from 1.1:1 to 7:1.4. The hydrogel of claim 1 , wherein said at least one quaternary ammonium salt of hydroxyethylcellulose is polyquaternium-67.5. The hydrogel of claim 1 , wherein said metal is Ag or Au.6. Process for the preparation of hydrogel of nanoparticles of at least one metal of claim 1 , comprising the steps of:a) providing an aqueous solution of an inorganic salt of at least one metal,b) providing an aqueous solution of at least one quaternary ammonium salt of hydroxyethylcellulose,c) combining the solutions and mixing under stirring at room temperature, andd) reacting at room temperature for at least 5 hours, thus obtaining the hydrogel.7. The process of claim 6 , wherein in step c) pH is adjusted to basic pH.8. The process of claim 7 , wherein pH is adjusted by adding an inorganic base claim 7 , said base and said at least one metal being in a molar ratio from 1:1 to 5:1.9. Hydrogel obtainable ...

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Номер записи: 9
01-02-2018 дата публикации

PALLADIUM CATALYSTS WITH IMPROVED PERFORMANCE IN BIOLOGICAL ENVIRONMENTS

Номер: US20180029028A1
Автор: Kirkland Thomas, Levin Sergiy, Ohana Rachel Friedman, Wood Keith
Принадлежит:

Provided herein are palladium (Pd) catalysts with improved performance in biological environments. In particular, formulations, methods of preparations, and storage conditions are provided that provide improved performance of Pd catalysts under protein-rich conditions. 1. A Pd catalyst composition comprising phosphine-coordinated palladium ions , wherein phosphine ligand is present at 6-12 fold excess over palladium in the composition.2. The Pd catalyst composition of claim 1 , wherein the phosphine ligand is a strong π-acceptor aryl phosphine.3. (canceled)4. The Pd catalyst composition of claim 3 , wherein the phosphine ligand is selected from the group consisting of DANPHOS claim 3 , o-DANPHOS claim 3 , p-DANPHOS claim 3 , DAN2PHOS claim 3 , o-DAN2PHOS p-DAN2PHOS claim 3 , and DANPHOS/DAN2PHOS derivatives with alternative solubilizing groups.5. The Pd catalyst composition of claim 4 , wherein the phosphine ligand is o-DANPHOS.6. The Pd catalyst composition of claim 1 , wherein the palladium is provided as a Palladium(II) salt selected from the group consisting of: Palladium acetate (Pd(OAc)) claim 1 , Palladium trifluoroacetate (Pd(TFA)) claim 1 , Palladium nitrate (Pd(NO)) claim 1 , Palladium chloride (PdCl) claim 1 , Palladium bromide (PdBr) claim 1 , Sodium tetrachloropalladate (NaPdCl) claim 1 , Potassium tetrachloropalladate (KPdCl) claim 1 , Lithium tetrachloropalladate (LiPdCl) claim 1 , Sodium tetrabromopalladate (NaPdBr) claim 1 , Potassium tetrabromopalladate (KPdBr) claim 1 , Pd(dibenzylideneacetone) claim 1 , Pd(dibenzylideneacetone) claim 1 , and Buchwald precatalysts.7. The Pd catalyst composition of claim 1 , wherein the phosphine-coordinated palladium ions are in aqueous solution.8. The Pd catalyst composition of claim 1 , wherein the phosphine-coordinated palladium ions are lyophilized.910.-. (canceled)11. A method for the preparation of a Pd catalyst claim 1 , comprising combining a palladium(II) salt with a phosphine ligand in buffered or un- ...

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Номер записи: 10
04-02-2016 дата публикации

METAL ORGANIC FRAMEWORK MATERIALS

Номер: US20160031920A1
Автор: Afeworki Mobae, Nandi Partha, Nizami Quddus, Weston Simon C.
Принадлежит: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

An imidazolate framework material comprises a general structure, M-IM-M, wherein IM is an imidazolate or a substituted imidazolate linking moiety, such as a 4,5-dicyanoimidazolate or a hydrolyzed or substituted 4,5 dicyanoimidazolate linking moiety, wherein Mand Mcomprise the same or different metal cations, wherein at least one of Mand Mcomprises a trivalent metal cation and wherein neither Mnor Mcomprises a monovalent cation. 1. An imidazolate framework material comprising a general structure , M-IM-M , wherein IM is an imidazolate or a substituted imidazolate linking moiety , wherein Mand Mcomprise the same or different metal cations , wherein at least one of Mand Mcomprises a trivalent metal cation and wherein neither Mnor Mcomprises a monovalent cation.2. The material of claim 1 , wherein Mand Mare both trivalent metal cations.3. The material of claim 2 , wherein Mand Mare the same trivalent metal cation.4. The material of claim 1 , wherein at least one of Mand Mcomprises a lanthanide cation.5. An imidazolate framework material comprising a general structure claim 1 , M-IM-M claim 1 , wherein IM is a dicyanoimidazolate or a hydrolyzed or substituted dicyanoimidazolate linking moiety claim 1 , wherein Mand Mcomprise the same or different metal cations claim 1 , wherein at least one of Mand Mcomprises a trivalent metal cation and wherein neither Mnor Mcomprises a monovalent cation.6. The material of claim 5 , wherein Mand Mare both trivalent metal cations.7. The material of claim 6 , wherein Mand Mare the same trivalent metal cation.8. The material of claim 5 , wherein at least one of Mand Mcomprises a lanthanide cation.9. An imidazolate framework material comprising a general structure claim 5 , M-IM-M claim 5 , wherein IM is an imidazolate or a substituted imidazolate linking moiety claim 5 , wherein Mand Mcomprise the same or different metal cations claim 5 , wherein at least one of Mand Mcomprises a trivalent metal cation selected from the group consisting of ...

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Номер записи: 11
07-02-2019 дата публикации

HIGH ASPECT RATIO LAYERED DOUBLE HYDROXIDE MATERIALS AND METHODS FOR PREPARATION THEREOF

Номер: US20190039988A1
Автор: Al-Shahrani Abdullah A., Alabedi Gasan Selman, Greenwell Hugh Christopher, Hall John Adrian, Veerabhadrappa Manohara Gudiyor, Whiting Andrew
Принадлежит:

Embodiments are directed to adamantane-intercalated layered double-hydroxide (LDH) particles and the methods of producing adamantane-intercalated LDH particles. The adamantane-intercalated LDH particles have a general formula defined by [MAl(OH)](A).mHO, where x is from 0.14 to 0.33, m is from 0.33 to 0.50, M is chosen from Mg, Ca, Co, Ni, Cu, or Zn, and A is adamantane carboxylate. The adamantane-intercalated LDH particles further have an aspect ratio greater than 100. The aspect ratio is defined by the width of an adamantane-intercalated LDH particle divided by the thickness of the adamantane-intercalated LDH particle. 1. An adamantane-intercalated layered double-hydroxide (LDH) material in a form of adamantane-intercalated LDH particles , where the adamantane-intercalated LDH particles comprise:{'sub': 1-x', 'x', '2', 'x', '2, 'a general formula defined by [MAl(OH)](A).mHO, where x is from 0.14 to 0.33, m is from 0.33 to 0.50, M is chosen from Mg, Ca, Co, Ni, Cu, or Zn, and A is adamantane carboxylate; and'}an aspect ratio greater than 100, the aspect ratio defined by a width of an adamantane-intercalated LDH particle divided by a thickness of the adamantane-intercalated LDH particle.2. The adamantane-intercalated LDH material of where M is Mg.3. The adamantane-intercalated LDH material of where the aspect ratio is greater than 125.4. The adamantane-intercalated LDH material of where the aspect ratio is greater than 150.5. The adamantane-intercalated LDH material of where the aspect ratio is greater than 200.6. The adamantane-intercalated LDH material of where the adamantane-intercalated LDH particles have a particle diameter of 5 to 10 μm.7. The adamantane-intercalated LDH material of where the adamantane-intercalated LDH particles have characteristic peaks in an IR spectra at 1517 cm claim 1 , 1395 cm claim 1 , 2901 cm claim 1 , 2847 cm claim 1 , and 4302 cm. This application is a divisional application of U.S. patent application Ser. No. 15/449,207 filed Mar. ...

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Номер записи: 12
12-02-2015 дата публикации

ZEOLITE NANOSHEET MEMBRANE

Номер: US20150045206A1
Автор: AGRAWAL KUMAR VAROON, Tsapatsis Michael
Принадлежит: Regents of the University of Minnesota

Oxide materials, thin films, coatings, and methods of preparing the same are disclosed herein. In certain embodiments the oxide material can have an MWW type framework or an MFI type framework. In one embodiment, the method includes: providing a suspension of an exfoliated layered oxide material in a solvent; and filtering the suspension through a porous support to provide a film of the oxide material, optionally directly on the porous support. Secondary grown films of the oxide material and methods of preparing the same are also provided. Thin zeolite films are attractive for a wide range of applications including molecular sieve membranes and catalytic membrane reactors, permeation barriers, low dielectric constant materials for microelectronics and sensor components for selective sensing. 1. An oxide material comprising exfoliated layers with a zeolite framework structure.2. The oxide material of further comprising a polymer having a glass transition temperature below about 150° C.3. The oxide material of wherein the polymer is selected from the group consisting of polystyrene claim 2 , polypropylene claim 2 , a polyolefin claim 2 , a polymethacrylate claim 2 , polyvinylalcohol claim 2 , a polyacrylamide claim 2 , a polycaprolactone claim 2 , a copolymer of ethylene claim 2 , a copolymer of propylene claim 2 , a copolymer of acetate claim 2 , poly(ethylene terephthalate) claim 2 , a nylon claim 2 , a polysulfone claim 2 , a polyimide claim 2 , a polyamidimide claim 2 , a polybenzaimidazole claim 2 , and combinations thereof.4. The oxide material of wherein the oxide material has an MFI type framework.5. An exfoliated oxide material (MIN-4) having an X-ray diffraction pattern substantially as illustrated in .6. The exfoliated oxide material of wherein the oxide material (MIN-4) has an MFI type framework.7. The exfoliated oxide material of having layers of 3.2±0.3 nm thickness.8. The exfoliated oxide material of claim 7 , wherein at least some of the layers have a ...

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Номер записи: 13
09-02-2017 дата публикации

ELECTROLESS METALLIZATION OF DIELECTRICS WITH ALKALINE STABLE PYRAZINE DERIVATIVE CONTAINING CATALYSTS

Номер: US20170042039A1
Автор: Liu Feng, Rzeznik Maria
Принадлежит: Rohm and Haas Electronic Materials LLC

Pyrazine derivatives which contain one or more electron donating groups on the ring are used as catalytic metal complexing agents in aqueous alkaline environments to catalyze electroless metal plating on metal clad and un-clad substrates. The catalysts are monomers and free of tin and antioxidants. 2. The method of claim 1 , wherein the one or more pyrazine derivatives are chosen from 2 claim 1 ,6-dimethylpyrazine claim 1 , 2 claim 1 ,3-dimethylpyrazine claim 1 , 2 claim 1 ,5-dimethylpyrazine claim 1 , 2 claim 1 ,3 claim 1 ,5-trimethylpyraizine claim 1 , 2-acetylpyrazine claim 1 , aminopyrazine claim 1 , ethylpyrazine claim 1 , methoxypyrazine claim 1 , 3 claim 1 ,4-dimethylpyrazine and 2-(2′-hydroxyethyl)pyrazine.3. The method of claim 1 , wherein a molar ratio of the one or more pyrazine derivatives to the metal ions is 1:1 to 4:1.4. The method of claim 1 , wherein the metal ions are chosen from palladium claim 1 , silver claim 1 , gold claim 1 , platinum claim 1 , copper claim 1 , nickel and cobalt.5. The method of claim 1 , wherein the metal on the substrate is copper claim 1 , copper alloy claim 1 , nickel or nickel alloy.6. The method of claim 1 , wherein the aqueous alkaline catalyst solution has a pH of 8.5 or greater.7. The method of claim 6 , wherein the aqueous alkaline catalyst solution has pH of 9 or greater.8. The method of claim 1 , wherein the substrate comprising the dielectric further comprises a plurality of through-holes.9. The method of claim 8 , wherein the substrate comprising the dielectric further comprises metal cladding. The present invention is directed to electroless metallization of dielectrics with alkaline stable pyrazine derivative containing catalysts. More specifically, the present invention is directed to metallization of dielectrics with alkaline stable pyrazine derivative containing catalysts as a replacement for palladium/tin colloidal catalysts.Conventional printed circuit boards (PCBs) consist of laminated non-conductive ...

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Номер записи: 14
18-02-2021 дата публикации

WATER STABLE COPPER PADDLEWHEEL METAL ORGANIC FRAMEWORK (MOF) COMPOSITIONS AND PROCESSES USING THE MOFS

Номер: US20210046447A1
Автор: Siu Paul Wai-Man
Принадлежит: NuMat Technologies Inc.

This invention relates to a Cu-BTC MOF which is water stable. The Cu-BTC MOF has open coordination sites and has been post synthesis modified by partially occupying the open sites with a ligand such as acetonitrile (CHCN). The resultant MOF retains at least 40% of its as synthesized surface area after exposure to liquid water at 60° C. for 6 hours. This is an unexpected result versus the MOF which has not been post treated with ligands such as acetonitrile. This MOF can be used to abate contaminants such as ammonia in gas streams and especially air streams. 1. A metal organic framework (MOF) composition comprising:{'sub': '3', 'a coordination product of a copper metal ion and 1,3,5-benzenetricarboxylic acid (BTC) ligand the MOF characterized in that the copper has open coordination sites which are at least partially occupied by acetonitrile (CHCN) and it retains at least 40% of its as synthesized surface area after exposure to liquid water at room temperature for 6 hours.'}2. The composition of further characterized in that the MOF has an as synthesized Brunauer-Emmett-Teller (BET) surface area of at least 1200 m/g.3. The composition of further characterized in that the MOF has a gravimetric uptake capacity for ammonia of at least 0.3 g of ammonia per gram of MOF measured at 675 torr and 25° C.4. The MOF of further characterized in that the MOF has a pore volume of at least 0.5 cc/g.5. The MOF of where the MOF retains at least 50% of its synthesized surface area after exposure to liquid water at room temperature for 6 hours.6. The MOF of further characterized in that the MOF is formed into a shaped body selected from pellets claim 1 , spheres claim 1 , disks claim 1 , monolithic body claim 1 , irregularly shaped particles claim 1 , extrudates claim 1 , and mixtures thereof.7. The MOF of further characterized in that the MOF is deposited as a layer on a support selected from a monolith claim 1 , spherical support claim 1 , ceramic foam claim 1 , woven fabrics claim 1 ...

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Номер записи: 15
25-02-2021 дата публикации

STRONGLY LEWIS ACIDIC METAL-ORGANIC FRAMEWORKS FOR CONTINUOUS FLOW CATALYSIS

Номер: US20210053042A1
Автор: Feng Xuanyu, Ji Pengfei, LIN WENBIN
Принадлежит:

Lewis acidic metal-organic framework (MOF) materials comprising triflate-coordinated metal nodes are described. The materials can be used as heterogenous catalysts in a wide range of organic group transformations, including Diels-Alder reactions, epoxide-ring opening reactions, Friedel-Crafts acylation reactions and alkene hydroalkoxylation reactions. The MOFs can also be prepared with metallated organic bridging ligands to provide heterogenous catalysts for tandem reactions and/or prepared as composites with support particles for use in columns of continuous flow reactor systems. Methods of preparing and using the MOF materials and their composites are also described. 1. A method for preparing a catalyst , said method comprising:{'sub': '2', '(a) providing a parent metal-organic framework (MOF), wherein the parent MOF comprises periodic repeats of a coordination complex comprising (i) an organic bridging ligand and (ii) a metal-containing secondary building unit (SBU), wherein said metal-containing SBU comprises a metal oxo cluster comprising a metal ion M and one or more terminal or bridging OH or OHligands; and'}{'sub': '2', '(b) reacting the parent MOF with a silyl triflate to replace one or more of the one or more terminal or bridging OH or OHligands with a triflate ligand.'}2. The method of claim 1 , wherein the SBU is selected from the group consisting of Zr-oxo cluster claim 1 , a Fe-oxo cluster claim 1 , a Cr-oxo cluster claim 1 , and an A-oxo cluster.3. The method of claim 1 , wherein the organic bridging ligand is substituted with one or more carboxylate claim 1 , pyridine claim 1 , and/or phosphonate moieties.4. The method of claim 3 , wherein the organic bridging ligand is trimesic acid (BTC).5. The method of claim 1 , wherein the parent MOF is provided by contacting a parent precursor MOF with a strong acid claim 1 , wherein the parent precursor MOF comprises periodic repeats of a coordination complex comprising: (i) the organic bridging ligand and (ii ...

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Номер записи: 16
23-02-2017 дата публикации

ELECTRODEPOSITION COATING MATERIAL COMPOSITION AND CATALYST FOR ELECTRODEPOSITION COATING MATERIAL

Номер: US20170051160A1
Автор: Haneda Hideo, Nakada Makoto, NAKAGAWA Yuya, Sasaoka Shinichi, Wazaki Takahiro
Принадлежит: Nitto Kasei Co., Ltd.

Provided is an organic tin-free cationic electrodeposition coating composition which does not contain organic tin compound and can sustain a superior coating curability under currently used baking conditions, and to a catalyst for the composition. A catalyst for electrodeposition coating composition containing a bismuth compound (A), wherein: the bismuth compound is a compound having a ligand prepared from a β-diketone represented by Chemical Formula (1) is provided. 5. An electrodeposition coating composition comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the catalyst for electrodeposition coating composition of ; and'}a base resin (B).6. The electrodeposition coating composition of claim 5 , wherein the base resin (B) contains a blocked isocyanate claim 5 , or the electrodeposition coating composition contains a curing agent (C) comprising a blocked isocyanate compound. The present invention relates to an organic tin-free electrodeposition coating composition which does not contain organic tin compound and can sustain a superior coating curability under currently used baking conditions, and to a catalyst contained in the composition and promotes a crosslinking reaction.In general, a coating is applied onto the surface of a metal material for protecting the material from corrosion and to maintain its beautiful appearance during its use. Here, in cases where parts such as automobiles and electrical equipments having a pocket portion are coated, electrodeposition is widely applied in primer coating since it has superior deposition property and is low in environmental pollution when compared with air spray coating and electrostatic spray coating. In particular, a cationic electrodeposition coating is widely used as a coating method for primer coating with respect to objects to be coated that are large and require high corrosion resistance such as a body of automobiles. This is since the cationic electrodeposition coating enables sequential coating.In ...

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Номер записи: 17
05-03-2015 дата публикации

PARTICLES, PARTICLE DISPERSION, PARTICLE-DISPERSED RESIN COMPOSITION, PRODUCING METHOD THEREFOR, RESIN MOLDED ARTICLE, PRODUCING METHOD THEREFOR, CATALYST PARTICLES, CATALYST SOLUTION, CATALYST COMPOSITION, CATALYST MOLDED ARTICLE, TITANIUM COMPLEX, TITANIUM OXIDE PARTICLES AND PRODUCING METHOD THEREFOR

Номер: US20150065340A1
Автор: FUKUOKA Takahiro, Fukuzaki Saori, Hatakeyama Yoshiharu, Nagase Junichi, Nagatsuka Tatsuki, Shibata Shusaku
Принадлежит: NITTO DENKO CORPORATION

Organic-inorganic composite particles that can be dispersed in a solvent and/or a resin as primary particles having an organic group on the surface of inorganic particles, the organic-inorganic composite particles having negative birefringence. 1. Catalyst particles comprising inorganic particles with a catalytic action and an organic group that binds to the surface of the inorganic particles , and having a configuration that does not allow the inorganic particles to contact with each other by steric hindrance of the organic group.2. The catalyst particles according to claim 1 , having a catalytic action for a gas and/or a liquid.3. The catalyst particles according to claim 1 , having a photocatalytic action for a gas and/or a liquid.4. The catalyst particles according to claim 1 , dispersed as primary particles in a solvent and/or a resin.5. The catalyst particles according to claim 1 , containing a plurality of mutually different types of organic groups.6. The catalyst particles according to claim 1 , wherein the organic group is bound to the surface of the inorganic particles via a binding group claim 1 , and the binding group contains a phosphoric acid group and/or a phosphoric acid ester group.7. The catalyst particles according to claim 1 , wherein the inorganic particles contain an oxide.8. The catalyst particles according to claim 1 , wherein the inorganic particles contain at least one oxide selected from the group consisting of TiO claim 1 , WOand SrTiO.9. The catalyst particles according to claim 8 , wherein the inorganic particles further contain at least one inorganic substance selected from the group consisting of Pt claim 8 , Pd claim 8 , Cu claim 8 , CuO claim 8 , RuOand NiO.10. The catalyst particles according to claim 1 , wherein the catalyst particles have an average maximum length of 450 nm or less. This is a divisional of U.S. application Ser. No. 13/640,911 filed Dec. 31, 2012, which is a national stage of PCT/JP2011/059040 filed Apr. 11, 2011, ...

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Номер записи: 18
17-03-2016 дата публикации

UREA HYDROLYSIS REACTOR FOR SELECTIVE CATALYTIC REDUCTION

Номер: US20160074809A1
Автор: Goffe Randal A.
Принадлежит: PACCAR INC

This disclosure features a urea conversion catalyst located within a urea decomposition reactor (e.g., a urea decomposition pipe) of a diesel exhaust aftertreatment system. The urea conversion catalyst includes a refractory metal oxide and a cationic dopant. The urea conversion catalyst can decrease the temperature at which urea converts to ammonia, can increase the urea conversion yield, and can decrease the likelihood of incomplete urea conversion. 1. A urea decomposition reactor , comprising:a urea conversion catalyst;wherein the urea conversion catalyst comprises a refractory metal oxide and a cationic dopant.2. The urea decomposition reactor of claim 1 , wherein the refractory metal oxide is selected from the group consisting of cerium oxide claim 1 , titanium oxide claim 1 , zirconium oxide claim 1 , aluminum oxide claim 1 , silicon oxide claim 1 , hafnium oxide claim 1 , vanadium oxide claim 1 , niobium oxide claim 1 , tantalum oxide claim 1 , chromium oxide claim 1 , molybdenum oxide claim 1 , tungsten oxide claim 1 , ruthenium oxide claim 1 , rhodium oxide claim 1 , iridium oxide claim 1 , nickel oxide claim 1 , and any combination thereof.3. The urea decomposition reactor of claim 1 , wherein the refractory metal oxide is selected from the group consisting of titanium oxide claim 1 , zirconium oxide claim 1 , cerium oxide claim 1 , and any combination thereof.4. The urea decomposition reactor of claim 1 , wherein the refractory metal oxide is zirconium oxide or cerium oxide.5. The urea decomposition reactor of claim 1 , wherein the cationic dopant is an oxide comprising Mg claim 1 , Ni claim 1 , Ti claim 1 , V claim 1 , Nb claim 1 , Ta claim 1 , Cr claim 1 , Mo claim 1 , W claim 1 , W claim 1 , Mn claim 1 , Fe claim 1 , Zn claim 1 , Ga claim 1 , Al claim 1 , In claim 1 , Ge claim 1 , Si claim 1 , Sn claim 1 , Co claim 1 , Ni claim 1 , Ba claim 1 , La claim 1 , Ce claim 1 , and Nb.6. The urea decomposition reactor of claim 1 , wherein the urea conversion ...

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Номер записи: 19
17-03-2016 дата публикации

UREA HYDROLYSIS REACTOR FOR SELECTIVE CATALYTIC REDUCTION

Номер: US20160074839A1
Автор: Goffe Randal A.
Принадлежит: PACCAR INC

This disclosure features a urea conversion catalyst located within a urea decomposition reactor (e.g., a urea decomposition pipe) of a diesel exhaust aftertreatment system. The urea conversion catalyst includes a refractory metal oxide and a cationic dopant. The urea conversion catalyst can decrease the temperature at which urea converts to ammonia, can increase the urea conversion yield, and can decrease the likelihood of incomplete urea conversion. 1. A urea decomposition reactor , comprising:a urea conversion catalyst;wherein the urea conversion catalyst comprises a refractory metal oxide and a cationic dopant.2. The urea decomposition reactor of claim 1 , wherein the refractory metal oxide is selected from the group consisting of cerium oxide claim 1 , titanium oxide claim 1 , zirconium oxide claim 1 , aluminum oxide claim 1 , silicon oxide claim 1 , hafnium oxide claim 1 , vanadium oxide claim 1 , niobium oxide claim 1 , tantalum oxide claim 1 , chromium oxide claim 1 , molybdenum oxide claim 1 , tungsten oxide claim 1 , ruthenium oxide claim 1 , rhodium oxide claim 1 , iridium oxide claim 1 , nickel oxide claim 1 , and any combination thereof.3. The urea decomposition reactor of claim 1 , wherein the refractory metal oxide is selected from the group consisting of titanium oxide claim 1 , zirconium oxide claim 1 , cerium oxide claim 1 , and any combination thereof.4. The urea decomposition reactor of claim 1 , wherein the refractory metal oxide is zirconium oxide or cerium oxide.5. The urea decomposition reactor of claim 1 , wherein the cationic dopant is an oxide comprising Mg claim 1 , Ni claim 1 , Ti claim 1 , V claim 1 , Nb claim 1 , Ta claim 1 , Cr claim 1 , Mo claim 1 , W claim 1 , W claim 1 , Mn claim 1 , Fe claim 1 , Zn claim 1 , Ga claim 1 , Al claim 1 , In claim 1 , Ge claim 1 , Si claim 1 , Sn claim 1 , Co claim 1 , Ni claim 1 , Ba claim 1 , La claim 1 , Ce claim 1 , and Nb.6. The urea decomposition reactor of claim 1 , wherein the urea conversion ...

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Номер записи: 20
05-03-2020 дата публикации

Photocatalytic coating, process for producing photocatalytic coating, and process for producing photocatalytic body

Номер: US20200070124A1
Автор: Yoshitaka Kawase
Принадлежит: Sharp Corp

This photocatalytic coating contains at least a photocatalytic particle, a binder and water. The binder includes a water-soluble hydrolysate of a silane coupling agent having an ethylene oxide structure. A content of the water-soluble hydrolysate of the silane coupling agent having the ethylene oxide structure is preferably 0.5% by weight or more and 20% by weight or less, based on a weight of a total solid content contained in the photocatalytic coating.

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Номер записи: 21
19-03-2015 дата публикации

COMPOUNDS HAVING LOW IONIZATION ENERGY

Номер: US20150080571A1
Автор: Lichtenberger Dennis, Murillo Carlos
Принадлежит: The Arizona Board of Regents on Behalf of the University of Arizona

The present invention provides compounds that are soluble in a non-polar solvent and having a low ionization energy and negative oxidation potentials in tetrahydrofuran (THF). The present invention also provides a method for producing and using the same. 1. A compound comprising a metal and an anionic organic ligand , wherein said compound has an onset ionization energy of about 4 eV or less and is soluble in an organic solvent , and wherein said metal is selected from the group consisting of tungsten and chromium.2. The compound of claim 1 , wherein said compound is soluble in an aprotic organic solvent.3. The compound of claim 1 , wherein said compound is soluble in a nonpolar organic solvent.4. The compound of claim 1 , wherein said compound has an oxidation potential in THF of about −1.5 V or less.5. The compound of claim 4 , wherein said compound has an oxidation potential in THF of about −1.8 V or less.6. The compound of claim 1 , wherein said compound has an onset ionization energy of about 3.6 eV or less.7. The compound of claim 1 , wherein the solubility of said compound in THF is at least 0.1 g/L.8. The compound of claim 7 , wherein the solubility of said compound in THF is at least 1 g/L.9. The compound of claim 1 , wherein the solubility of said compound in benzene is at least 0.1 g/L.10. The compound of claim 7 , wherein the solubility of said compound in benzene is at least 1 g/L.11. A compound comprising a metal and an organic ligand claim 7 , wherein said compound has an oxidation potential in THF of about −1.5 V or less claim 7 , and is soluble in an organic solvent claim 7 , and wherein said metal is selected from the group consisting of tungsten and chromium.12. The compound of claim 11 , wherein said compound has an oxidation potential in THF of about −1.8 V or less.13. The compound of claim 11 , wherein said compound has an onset ionization energy of about 4 eV or less.14. The compound of claim 13 , wherein said compound has an onset ionization ...

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Номер записи: 22
29-03-2018 дата публикации

Use of Novel catalyst and method for treating PCB inked polymer waste by the novel catalyst

Номер: US20180086892A1
Автор: CHEN Chien-Tien
Принадлежит:

A novel catalyst, a use thereof and a method for treating PCB inked waste by using the same are disclosed. The catalyst of the present disclosure is represented by the following formula (I): 1. A catalyst , representing by the following formula (I):{'br': None, 'sub': 'a', 'sup': m+', 'n−, '[M(O)]X\u2003\u2003(I)'}wherein M is an element of Group IB, Group IVB, Group VB, Group VIB, Group VIIB or Group VIIIB;{'sub': 2', 'n', '3', '12', '25', '2', '6', '4', '2', 'n', '4', '3', '2', '25, 'X is Cl, Br, I, OAc, OC(O)(CF)CF, OC(O)CH, [(OSOCH-CHCH)], OTf, OTs, SO, SOC Hor acetylacetonate (acac);'}a is an integral of 0 to 3;m is an integral of 2 to 4; andn is an integral of 1 or 2.2. The catalyst of claim 1 , wherein a is 0 claim 1 , and M is Ti claim 1 , Zr claim 1 , Hf claim 1 , V claim 1 , Fe claim 1 , Cu or Mn.3. The catalyst of claim 1 , wherein M(O)is VO claim 1 , VO claim 1 , ZrO claim 1 , HfO claim 1 , WO claim 1 , MoO claim 1 , CrOor ReO.4. A use of a catalyst for degrading inks or acylating or recycling polymers claim 1 , wherein the catalyst is representing by the following formula (I):{'br': None, 'sub': 'a', 'sup': m+', 'n−, '[M(O)]X\u2003\u2003(I)'}wherein M is an element of Group IB, Group IVB, Group VB, Group VIB, Group VIIB or Group VIIIB;{'sub': 2', 'n', '3', '12', '25', '2', '6', '4', '2', 'n', '4', '3', '12', '25, 'X is Cl, Br, I, OAc, OC(O)(CF)CF, OC(O)CH, [(OSOCH-CHCH)], OTf, OTs, SO, SOCHor acetylacetonate (acac);'}a is an integral of 0 to 3;m is an integral of 2 to 4; andn is an integral of 1 or 2.5. A method for treating a PCB inked polymer waste claim 1 , comprising the following steps: {'br': None, 'sub': 'a', 'sup': m+', 'n−, '[M(O)]X\u2003\u2003(I)'}, 'mixing a PCB inked polymer waste, a catalyst representing by the following formula (I), a reagent and a first solvent to obtain a mixturewherein M is an element of Group IB, Group IVB, Group VB, Group VIB, Group VIIB or Group VIIIB;{'sub': 2', 'n', '3', '12', '25', '2', '6', '4', '2', 'n', '4', '3 ...

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Номер записи: 23
28-03-2019 дата публикации

DISSOCIABLE NANOPARTICLES WITH INTER ALIA TRANSITION-METAL COMPLEX CATALYSTS

Номер: US20190091673A1
Автор: CLARDY Susan, FLYER Alec Nathanson, Spears Benjamin, Stern Eric, Vacic Aleksandar
Принадлежит:

Nanoparticles for use in assay methods for detecting analytes in samples, which comprise a signal inducing agent, e.g. a transition-metal catalyst or a chemiluminophore, a chemiluminophore precursor, a soluble absorber, or a soluble absorber precursor. After binding to an analyte, the nanoparticle is dissociated by a chemical or physical trigger, e.g. an organic solvent or ultrasound, to release the signal inducing agent, which releases a detectable signal via a physical or chemical reaction. The nanoparticles comprising a chemiluminophore, a chemiluminophore precursor, a soluble absorber, or a soluble absorber precursor can also effect chemical reactions that serve as signal amplifiers. 2. The nanoparticle of claim 1 , wherein each Z is N.3. The nanoparticle of claim 1 , wherein each of Rand Ris selected claim 1 , independently claim 1 , from the group consisting of hydrogen claim 1 , halogen claim 1 , and Calkyl claim 1 , or wherein Rand Rlink to form a Ccycloaliphatic group.7. The nanoparticle of claim 1 , wherein Ris an optionally-substituted aryl or heteroaryl group.8. The nanoparticle of claim 1 , wherein one of any one of R claim 1 , R claim 1 , and Rcomprises an amino group claim 1 , an azido group claim 1 , a thiol group claim 1 , an alkenyl group claim 1 , an alkynyl group claim 1 , a carboxylic acid group claim 1 , a carboxylic ester group claim 1 , a N-hydroxysuccinimide ester group claim 1 , an isothiocyanate group claim 1 , an isocyanide group claim 1 , a maleimide claim 1 , an aldehyde claim 1 , a norbornyl claim 1 , a cyclooctenyl claim 1 , or a tetrazine group.9. The nanoparticle of any one of to claim 1 , wherein A is —CRR.10. The nanoparticle of any one of to claim 1 , wherein A is —NR—.11. The nanoparticle of any one of to claim 1 , wherein the embedding of the catalyst in the matrix is not primarily governed by electrostatic interactions;15. The nanoparticle of any one of - claim 1 , wherein each of Rand Ris selected claim 1 , independently ...

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Номер записи: 24
28-03-2019 дата публикации

METHODS OF USING MULTI-LIGAND METAL COMPLEXES TO PERFORM OXIDATIVE CATALYTIC PRETREATMENT OF LIGNOCELLULOSIC BIOMASS

Номер: US20190091674A1
Автор: Bansal Namita, Bhalla Aditya, Hegg Eric L., Hodge David B., Li Zhenglun, Mathrubootham Vaidyanathan
Принадлежит:

A homogeneous catalyst is provided comprising one or more metals; and at least two metal coordinating ligands wherein the homogeneous catalyst is a multi-ligand metal complex_adapted for use with an oxidant in an oxidation reaction to catalytically pretreat lignocellulosic biomass. In one embodiment, the homogenous catalyst is copper (II) 2, 2′ bipyridine ethylenediamine (Cu(bpy)en). Related methods are also disclosed. 110-. (canceled)11. A method comprising:catalytically delignifying alkaline-pretreated lignocellulosic biomass with a homogeneous multi-ligand metal complex catalyst and an oxidant in an oxidation reaction, wherein said metal complex comprises a combination of a metal-ligand complex and at least one metal coordinating ligand selected from pyridine, 1,10-phenanthroline, ethylenediamene, histidine, glycine and combinations thereof, wherein radicals formed during the oxidation reaction react with lignin present in the alkaline-pretreated lignocellulosic biomass to solubilize the lignin to produce a catalytically delignified lignocellulosic biomass.12. The method of wherein the alkaline-pretreated lignocellulosic biomass claim 11 , the multi-ligand metal complex and the oxidant form a solution having a pH of at least 11.5.13. The method of wherein the oxidant is hydrogen peroxide claim 12 , the radicals formed during the oxidation reaction are hydroxyl radicals claim 12 , and the multi-ligand metal complex is a multi-ligand copper complex.14. The method of wherein the copper complex is a copper(II) 2 claim 13 ,2′-bipyridine complex (Cu(bpy)) modified to contain at least one additional metal-coordinating ligand.15. The method of wherein said additional metal-coordinating ligand is ethylenediamine.16. The method of wherein the oxidant is added at a gradual rate equal to or less than a rate of consumption of the oxidant by the alkaline-pretreated lignocellulosic biomass and the multi-ligand metal complex.17. (canceled)18. The method of wherein the method ...

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Номер записи: 25
02-04-2020 дата публикации

DELAYED CURE MICRO-ENCAPSULATED CATALYSTS

Номер: US20200101451A1
Автор: Anderson Lawrence G., Hartman Madeline
Принадлежит:

Controlled release polyurea microcapsules can be prepared from a combination of polyisocyanates using emulsion polymerization. Encapsulated catalysts prepared using the polyurea microcapsules can be used to control the cure rate of coatings and sealants. 1. A microcapsule comprising a polyurea shell at least partially encapsulating a core , wherein the polyurea shell comprises a reaction product of reactants comprising:a combination of polyisocyanates, wherein the combination of polyisocyanates comprises an alicyclic diisocyanate and an acyclic diisocyanate; anda crosslinker, wherein the crosslinker comprises a polyamine2. The microcapsule of claim 1 , wherein the alicyclic diisocyanate comprises isophorone diisocyanate.3. The microcapsule of claim 1 , wherein the acyclic diisocyanate comprises hexamethylene diisocyanate.4. The microcapsule of claim 1 , wherein the combination of polyisocyanates comprises an alicyclic diisocyanate trimer claim 1 , an acyclic diisocyanate trimer claim 1 , or a combination thereof.5. The microcapsule of claim 4 , wherein the alicyclic diisocyanate trimer comprises an isophorone diisocyanate trimer and/or the acyclic diisocyanate trimer comprises hexamethylene diisocyanate trimer.6. The microcapsule of claim 1 , wherein the combination of polyisocyanates comprises isophorone diisocyanate and hexamethylene diisocyanate.7. The microcapsule of claim 1 , wherein an equivalents ratio of the alicyclic diisocyanate to the acyclic diisocyanate is from 10:90 to 90:10.8. The microcapsule of claim 1 , wherein the polyamine comprises diethylenetriamine9. The microcapsule of claim 1 , wherein the polyurea shell further comprises a silica nanopowder claim 1 , calcium carbonate claim 1 , or a combination thereof; and a weight stabilizer.10. The microcapsule of claim 1 , wherein the core comprises a catalyst.11. The microcapsule of claim 10 , wherein the core further comprises a plasticizer.12. A composition comprising the microcapsule of .13. An ...

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Номер записи: 26
07-05-2015 дата публикации

CROSS-LINKED GRAPHENE NETWORKS

Номер: US20150122800A1
Автор: Alyoubi Abdulrahman O., Asiri Abdullah M, Gallastegui Ainara Garcia, Shaffer Milo
Принадлежит:

The present invention relates to a method for the production of cross-linked graphene and graphene oxide networks, which are selected from aerogels and xerogels with improved performance and characteristics thereof. The invention is also concerned with graphene and graphene oxide networks, which are selected from aerogels and xerogels produced by such processes and uses thereof. 1. A method of producing an aerogel or xerogel comprising graphene , graphene oxide or a mixture thereof , comprising the steps of: a) dispersing graphene , graphene oxide or a mixture thereof in a solvent compatible therewith; b) cross-linking said graphene , graphene oxide or a mixture thereof via functional groups present on the graphene and/or the graphene oxide , or with a linking molecule comprising at least two functional sites capable of reacting with the surface of said graphene and/or graphene oxide , to form a covalently cross-linked gel network; and c) removing said solvent to produce a cross-linked aerogel or xerogel with a solvent content of less than 10%.2. The method according to claim 1 , wherein said cross-linking is carried out by direct reaction between the surface oxides on the graphene oxide surface.3. The method according to claim 1 , wherein said graphene oxide is oxidised graphene and wherein said cross-linking is carried out with a molecule selected from the group consisting of alkyl diamines claim 1 , aromatic diamines claim 1 , alkyl diols claim 1 , aromatic diols claim 1 , polyols claim 1 , bis-sodium alkoxides claim 1 , dicarboxylic acids claim 1 , di acid chlorides claim 1 , di siloxane halides claim 1 , di siloxane alkoxides and mixtures thereof.4. The method according to claim 2 , wherein said surface oxides are selected from the group consisting of hydroxide claim 2 , carboxylate claim 2 , lactone claim 2 , hydroxyl claim 2 , quinine claim 2 , carboxylic acid groups claim 2 , and mixtures thereof claim 2 , preferably a combination of hydroxide and carboxyl ...

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Номер записи: 27
04-05-2017 дата публикации

PLASMONIC ASSISTED SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

Номер: US20170121472A1
Автор: Bourke, JR. Frederic Avery, Vo-Dinh Tuan
Принадлежит:

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent. 1. (canceled)2. A system for producing a change in a medium to be treated , comprising:an energy source capable of producing an initiation energy comprising one or more of x-rays, gamma rays, or an electron beam;a container holding the medium to be treated;an energy modulation agent surrounded by an encapsulation, disposed inside or in a vicinity of the medium to be treated, and separated physically from the medium to be treated by the encapsulation; andsaid energy modulation agent comprising a photon emitter which emits at least one of ultraviolet and visible light upon interaction with said initiation energy, wherein said at least one of ultraviolet and visible light stimulates a chemical or biological process in the medium.3. The system of claim 2 , wherein the energy modulation agent comprises at least one of a sulfide claim 2 , a telluride claim 2 , a selenide and an oxide semiconductor.4. The system of claim 2 , wherein said at least one of ultraviolet and visible light stimulates claim 2 , for said chemical or biological process claim 2 , a change in an organism activity of the medium.5. The system of claim 2 , wherein said container comprises at least one of an aluminum container claim 2 , a quartz container claim 2 , a glass container claim 2 , a plastic container or a combination thereof.6. The system of claim 2 , wherein said encapsulation comprises at ...

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Номер записи: 28
14-05-2015 дата публикации

Nanocatalyst for heavy crude oil upgrading and method for synthesizing same

Номер: US20150129463A1
Автор: Alimorad Rashidi, Alireza Mahjoub, Amir Hossein Bornaee, Mahshad Alaei, Mohsen Ghanami
Принадлежит: RESEARCH INSTITUTE OF PETROLEUM INDUSTRY (RIPI)

A dispersing-type nanocatalyst for catalytic hydrocracking of heavy oil, a method for preparing the same, and the use thereof in catalytic hydrocracking of heavy oil. The present invention is also directed to reducing the operational temperature of catalytic hydrocracking of heavy crude oil, and also increasing the yield of the process by utilizing a lower concentration of said nanocatalyst.

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Номер записи: 29
18-05-2017 дата публикации

GREEN METHODS FOR PREPARING HIGHLY CO2 SELECTIVE AND H2S TOLERANT METAL ORGANIC FRAMEWORKS

Номер: US20170137450A1
Автор: BELMABKHOUT Youssef, Eddaoudi Mohamed, SHEKHAH Osama
Принадлежит:

A green route for preparing a metal organic framework include mixing metal precursor with a ligand precursor to form a solvent-free mixture; adding droplets of water to the mixture; heating the mixture at a first temperature after adding the water; and isolating the metal organic framework material including the metal and the ligand. 1. A method for preparing a metal organic framework comprising:mixing a metal precursor with a ligand precursor to form a mixture;adding water to the mixture;heating the mixture at a first temperature after the water is added to the mixture; andisolating a two-dimensional metal organic framework intermediate structure.2. The method of claim 1 , wherein the metal of the metal precursor is selected from a group consisting of Ni claim 1 , Cu claim 1 , Zn claim 1 , Fe claim 1 , and Co.3. The method of claim 1 , wherein the metal includes Ni.4. The method of claim 1 , wherein the metal precursor includes metal hexafluorosilicate.5. The method of claim 1 , wherein the ligand precursor includes pyrazine claim 1 , 4 claim 1 ,4′-Bipyridin claim 1 , 1 claim 1 ,4-Diazabicyclo[2.2.2]octane claim 1 , or 1 claim 1 ,2-bis(4-pyridyl)acetylene.6. The method of claim 1 , wherein the ligand precursor includes a nitrogen-containing heterocyclic ligand.7. The method of claim 1 , wherein the molar ratio of the ligand precursor to the metal precursor is about 3:1 to about 6:1.8. The method of claim 1 , further comprising forming SIFSIX-Ni-3 metal organic framework.9. The method of claim 1 , wherein the water to mixture ratio can be from about 1:1 to about 1:210. The method of claim 1 , wherein the two-dimensional metal organic framework intermediate structure is H2S tolerant.11. A method for preparing a metal organic framework comprising:mixing a metal precursor with a ligand precursor to form a mixture;adding water to the mixture;heating the mixture at a first temperature after the water is added to the mixture; heating the mixture to a second temperature; ...

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Номер записи: 30
07-08-2014 дата публикации

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

Номер: US20140222117A1
Автор: Frederic Avery Bourke, JR., Tuan Vo-Dinh
Принадлежит: Duke University, Immunolight LLC

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

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Номер записи: 31
04-06-2015 дата публикации

Copper Containing Complex, Condensation Reaction Compositions Containing the Complex, and Methods for the Preparation and Use of the Compositions

Номер: US20150152301A1
Автор: Brandstadt Kurt, Cook Simon, Diamond Gary, Hall Keith, Lower Loren, Surgenor Avril, Taylor Richard, Tonge James, Tzou Ming-Shin
Принадлежит: Dow Corning Corporation

A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin. 2. The composition of claim 1 , where the condensation reaction produces a reaction product having a visual viscosity value ranging from 2 to 5 when tested according to the method of Example 2.3. The composition of claim 1 , where the precursor has general formula Cu-A claim 1 , where subscript a is 1 or 2 claim 1 , andwhere each A is independently a monovalent organic group and subscript a has a value of 1 or 2.4. The composition of claim 3 , where one of the following conditions is met:where each A is independently selected from an aryl group and a carboxylic ester group; orwhere each A is independently mesityl or ethylhexanoate.5. (canceled)7. The composition of claim 1 , further comprising at least one additional ingredient distinct from ingredients (A) and (B) claim 1 , where the at least one additional ingredient is selected from the group consisting of: (C) the crosslinker; (D) the drying agent; (E) the extender claim 1 , the plasticizer claim 1 , or the combination thereof; (F) the filler; (G) the treating agent; (H) the biocide; (J) the flame retardant; (K) the surface modifier; (L) the chain lengthener; (M) the endblocker; (N) the nonreactive binder; (O) the anti-aging additive; (P) the water release agent; (Q) the pigment; (R) the rheological additive; (S) the vehicle; (T) the tackifying agent; (U) the corrosion inhibitor; and the combination thereof.8. A method comprising: exposing the composition of to moisture to prepare a reaction product.9. A reaction product prepared by the method of claim 8 , where one of the following conditions is satisfied:where the reaction product has a form selected from a gum, a gel, a rubber, and a resin;orwhere the reaction product has a form selected from ...

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Номер записи: 32
01-06-2017 дата публикации

Electroless metallization of dielectrics with alkaline stable pyrazine derivative containing catalysts

Номер: US20170156216A9
Автор: Feng Liu, Maria Rzeznik
Принадлежит: Rohm and Haas Electronic Materials LLC

Pyrazine derivatives which contain one or more electron donating groups on the ring are used as catalytic metal complexing agents in aqueous alkaline environments to catalyze electroless metal plating on metal clad and un-clad substrates. The catalysts are monomers and free of tin and antioxidants.

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Номер записи: 33
08-06-2017 дата публикации

COMPOSITE POWDER, HYBRID MATERIAL THEREOF, AND COMPOSITE THIN FILM THEREOF

Номер: US20170156338A1
Автор: Cheng Kuo-Pin, Chuang Kuan-Ting, Kuo Dong-Hau, Kuo Yen-Rong, Lee Jiunn-Yih, Ma Meng-Wei, Wu Chang-Mou, YANG Yi-Yuan, Yu Fu-An
Принадлежит:

Provided is a composite powder used for the visible light catalytic and anti-bacterial purposes. The composite powder includes a plurality of N-type semiconductor particles and a plurality of P-type semiconductor nano-particles. The P-type semiconductor nano-particles cover surfaces of the N-type semiconductor particles respectively. A weight ratio of the N-type semiconductor particles and the P-type semiconductor nano-particles is in a range of 1:0.1 to 1:0.5. A PN junction is provided between each of the N-type semiconductor particles and the corresponding P-type semiconductor nano-particles. 1. A composite powder used for the visible light catalytic and anti-bacterial purposes , comprising:a plurality of N-type semiconductor particles; anda plurality of P-type semiconductor nano-particles covering surfaces of the N-type semiconductor particles respectively, and a weight ratio of the N-type semiconductor particles and the P-type semiconductor nano-particles is in a range of 1:0.1 to 1:0.5, whereina PN junction is provided between each of the N-type semiconductor particles and the corresponding P-type semiconductor nano-particles.2. The composite powder according to claim 1 , wherein a material of the N-type semiconductor particles comprises zinc oxide claim 1 , and a material of the P-type semiconductor nano-particles comprises silver oxide.3. The composite powder according to claim 1 , wherein a particle size of the N-type semiconductor particles is in a range of 0.1 μm to 5 μm claim 1 , and a particle size of the P-type semiconductor nano-particles is in a range of 1 nm to 50 nm.4. The composite powder according to claim 1 , wherein the P-type semiconductor nano-particles are uniformly distributed on the surfaces of the N-type semiconductor particles.5. A composite thin film used for the visible light catalytic and anti-bacterial purposes claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the composite powder according to , wherein the ...

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Номер записи: 34
22-09-2022 дата публикации

CORE-SATELLITE MICELLE INCLUDING TETRA-BLOCK COPOLYMER AND PREPARATION METHOD THEREOF

Номер: US20220298284A1
Автор: Ahn Seonghyeon, Kim Jin Kon
Принадлежит:

Proposed are a core-satellite micelle containing a tetra-block copolymer and a preparation method thereof. The core-satellite micelle includes a core, a shell surrounding the core, and a plurality of satellite domains positioned inside the shell. The core-satellite micelle contains a tetra-block copolymer represented by Structural Formula 1 below. The shell includes a first-monomer first block A1 and a first-monomer second block A2, and the satellite domain includes a second-monomer first block B1 and a second-monomer second block B2. The core-satellite micelle is foiled through self-assembly of the tetra-block copolymer, thereby having a larger interfacial contact area than existing block-copolymer micelles. Therefore, the core-satellite micelle can be used in next-generation nanotechnology applications such as drug delivery systems, porous catalyst materials, and sensors. 1. A core-satellite micelle comprising a core , a shell surrounding the core , and a plurality of satellite domains disposed inside the shell ,wherein the core-satellite micelle contains a tetra-block copolymer represented by Structural Formula 1 below,the shell contains a first-monomer first block A1 and a first-monomer second block A2,the satellite domain contains a second-monomer first block B1, and{'b': '2', 'claim-text': {'br': None, 'A1-B1-A2-B2 \u2003\u2003[Structural Formula 1]'}, 'the core contains a second-monomer second block B,'}In Structural Formula 1,A1 is the first-monomer first block,B1 is the second-monomer first block,A2 is the first-monomer second block, andB2 is the second-monomer second block.2. The core-satellite micelle according to claim 1 , wherein the satellite domains surround the core.3. The core-satellite micelle according to claim 2 , wherein the plurality of satellite domains forms a satellite domain layer.4. The core-satellite micelle according to claim 1 , wherein the core-satellite micelle contains the first-monomer second block A2 between the core and the ...

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Номер записи: 35
14-05-2020 дата публикации

Method of Preparing Bio-Polyols from Epoxidized Fatty Acid Esters

Номер: US20200148614A1
Автор: Li Chiu-Ping, Lin Ya-Shiuan, Tsai Ming-Tsang, Tu You-Liang
Принадлежит:

A method of preparing bio-polyols from epoxidized fatty acid esters, wherein the bio-polyols are synthesized via hydroxylation with epoxidized fatty acid esters and ring-opening reagent, using the acidic ionic liquids as catalysts. The bio-polyols are used to synthesize bio-polyurethane and bio-polyurethane foams. The acidic ionic liquids in this process is used in esterification, epoxidation, and ring-opening reaction to synthesize bio-polyols. The ionic liquids catalysts have several advantages such as easy to separate, reusable, and may reduce pollution. 1. A method of preparing bio-polyols from epoxidized fatty acid esters comprising steps of:replacing amphoteric compound by using alkyl sulfonic acid, wherein the alkyl sulfonic acid are synthesized with Brønsted strong acid to produce Brønsted acid IL, a molar ratio of the alkyl sulfonic acid and the Brønsted strong acid is within 1.0 to 1.5;mixing the epoxidized fatty acid esters and the Brønsted acid IL at a predetermined ratio, adding alcohols for using as ring-opening reagent, thus producing reaction solution, wherein the reaction solution is heated within a temperature of 30° C. to 100° C. for 1 to 24 hours to cause ring-opening hydroxylation, wherein a molar ratio of the alcohols and the epoxidized fatty acid esters is within 4 to 20, and a molar ratio of the Brønsted acid IL and the epoxidized fatty acid esters is within 0.01 to 0.15; andextracting and layering the reaction solution by using deionized water to acquire upper-layer solution and lower-layer solution, wherein the lower-layer solution consists of ionic liquid which is concentrated and dried to recycle reusable ionic liquid, and the upper-layer solution consists of bio-polyols which are extracted by using the deionized water and alkaline water and then dehydrated.2. The method as claimed in claim 1 , wherein the alkyl sulfonic acid is CH claim 1 , and the n is a positive integer within 3 to 6.3. The method as claimed in claim 1 , wherein the Br ...

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Номер записи: 36
24-06-2021 дата публикации

Method for producing carbon monoxide

Номер: US20210188650A1
Автор: Arnaud Imberdis, Thibault Cantat
Принадлежит: Commissariat a lEnergie Atomique et aux Energies Alternatives CEA

The present invention concerns a method of production for carbon monoxide using a derivative of formic acid, in particular an alkyl formate. It also concerns a method chosen from among, the method of production of methanol, the method of production of acetic acid (Monsanto and Cativa methods), the method of hydroformylation of olefins (oxo and aldox method, the method of production of hydrocarbons (Fischer-Tropsch method), or the method of carbonylation of nickel (Mond method), comprising a step of production of carbon monoxide using an alkyl formate of formula (I) by the method according to the invention. It further concerns a “CO pump” or “CO liquid storage” method comprising a step of production of carbon monoxide using an alkyl formate of formula (I) according to the method of the invention.

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Номер записи: 37
21-05-2020 дата публикации

HYDROTREATING CATALYST WITH A TITANIUM CONTAINING CARRIER AND SULFUR CONTAINING ORGANIC ADDITIVE

Номер: US20200156051A1
Автор: ALCANIZ JANA JUAN, AU YEUNG KAR MING, BERGWERFF JACOB ARIE, VEERMAN WILHELMUS CLEMENS JOZEF
Принадлежит:

Generally, it is disclosed a catalyst for use in a hydrotreating hydrocarbon feedstocks and the method of making such catalyst. It is generically provided that the catalyst comprises at least one Group VIB metal component, at least one Group VIII metal component, about (1) to (about (30) wt % C, and preferably about (1) to about (20) wt % C, and more preferably about (5) to about 15 wt % C of one or more sulfur containing organic additive and a titanium-containing carrier component, wherein the amount of the titanium component is in the range of about (3) to (about (60) wt %, expressed as an oxide (Ti) and based on the total weight of the catalyst. The titanium-containing carrier is formed by co-extruding or precipitating a titanium source with a Al precursor to form a porous support material comprising Alor by impregnating a titanium source onto a porous support material comprising Al. 2. The catalyst of wherein the Group VIB metal component is in an amount of about 15 to about 30 wt % expressed as an oxide based on the total weight of the catalyst.3. The catalyst of wherein the Group VIII metal component is in an amount of about 2 to about 8 wt % expressed as an oxide based on the total weight of the catalyst.4. The catalyst according to wherein the Group VIB metal component comprises molybdenum and/or tungsten.5. The catalyst according to wherein the Group VIII metal component comprises nickel and/or cobalt.6. The catalyst of wherein the at least one sulfur containing organic component comprises a mercapto carboxylic acid.7. The catalyst of wherein the mercapto carboxylic acid is thioglycolic acid claim 6 , thiolactic acid claim 6 , thiopropionic acid claim 6 , mercapto succinic acid or cysteine.8. The catalyst of further comprising a phosphorous component in the amount of about 1 to about 8% expressed as oxide based on the total weight of the catalyst.9. The catalyst of wherein the at least one sulfur containing organic additive component is in amount of about 1 ...

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Номер записи: 38
25-06-2015 дата публикации

USE OF CERTAIN MANGANESE-ACCUMULATING PLANTS FOR CARRYING OUT ORGANIC CHEMISTRY REACTIONS

Номер: US20150174566A1
Автор: ESCANDE Vincent, GRISON Claude
Принадлежит:

The use, after heat treatment, of manganese accumulating plants for carrying out chemical reactions. 1Alyxia, Azolla, Beauprea, Beaupreopsis, Bridelia, Crotalaria, Dicranopteris, Dipteris, Eugenia, Gleichenia, Gossia, Macadamia, Maytenus, Pinus, Phytolacca, Spermacone, Stenocarpus, VirotiaGrevillea. A method for preparing a catalyst for organic synthesis reactions , comprising , preparing a composition containing at least one mono- or polymetallic agent , the metal or metals of which are selected from metals originating from , after heat treatment , of a plant or of a part of a plant belonging to one of the genera selected from or that has accumulated manganese (Mn) and optionally a metal or several metals in particular selected from magnesium (Mg) , zinc (Zn) , copper (Cu) , iron (Fe) , calcium (Ca) , cadmium (Cd) , aluminium (Al) , said agent begin a catalyst for implementing organic synthesis reactions involving said agent as catalyst.2Alyxia, Azolla, Beauprea, Beaupreopsis, Bridelia, Crotalaria, Dicranopteris, Dipteris, Eugenia, Gleichenia, Gossia, Helanthius, Macadamia, Maytenus, Pinus, Spermacone, Stenocarpus, VirotiaGrevillea. A method for implementing organic synthesis reaction , comprising providing a composition containing a catalyst for an organic synthesis reaction , said composition prepared by the heat treatment of a plant or of a part of a plant belonging to one of the genera selected from or that has accumulated manganese (Mn) and optionally a metal or several metals in particular selected from magnesium (Mg) , zinc (Zn) , copper (Cu) , iron (Fe) , calcium (Ca) , cadmium (Cd) , aluminium (Al) and containing at least one mono- or polymetallic agent , the metal or the metals of which are selected from the metals originating from said plant , said composition being practically devoid of organic matter , said agent being said catalyst.3Beauprea gracilis, Beauprea montana, Beaupreopsis paniculata, Garcinia amplexicaulis, Grevillea exul, Grevillea ...

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Номер записи: 39
25-06-2015 дата публикации

MOLECULARLY IMPRINTED CATALYSTS AND METHODS OF MAKING AND USING THE SAME

Номер: US20150174568A1
Автор: HU Xiaobin
Принадлежит: EMPIRE TECHNOLOGY DEVELOPMENT LLC

Molecularly imprinted catalysts are disclosed. The catalysts can include a core and a layer at least partially encapsulating the core. The core can include a titania-based photocatalyst. The layer can include titania covalently coupled to one or more silane coupling agents having an organic functional group. The layer can also include one or more molecular-sized cavities configured to selectively receive one or more contaminants. Also disclosed herein are methods of making and using the molecularly imprinted catalyst, as well as apparatuses and compositions including the molecularly imprinted catalyst. 1. A molecularly imprinted catalyst comprising:a core comprising a titania-based photocatalyst; anda layer at least partially encapsulating the core, the layer comprising titania covalently coupled to one or more silane coupling agents having an organic functional group, wherein the layer further comprises one or more molecular-sized cavities configured to selectively receive one or more contaminants.2. The catalyst of claim 1 , wherein the titania-based photocatalyst comprises at least 50% by weight titania.3. The catalyst of claim 1 , wherein the titania-based photocatalyst comprises doped titania.4. The catalyst of claim 1 , wherein the titania-based photocatalyst comprises an anatase phase.5. The catalyst of claim 1 , wherein the core has a largest dimension less than or equal to about 1 μm.6. The catalyst of claim 1 , wherein the molecular-sized cavities have a largest dimension less than or equal to about 100 nm.78-. (canceled)9. The catalyst of claim 1 , wherein the silane coupling agents comprise at least one of N-(2-aminoethyl)-3-aminopropyltrimethoxysilane claim 1 , N-(2-aminoethyl)-3-aminopropylmethyldimethoxysilane claim 1 , 3-aminopropylmethyldiethoxysilane claim 1 , 3-aminopropyltriethoxysilane claim 1 , 3-aminopropyltrimethoxysilane claim 1 , (N-trimethoxysilylpropyl)polyethyleneimine claim 1 , trimethoxysilylpropyldiethylenetriamine claim 1 , 3- ...

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Номер записи: 40
25-06-2015 дата публикации

PHOTOCATALYTIC TIO2 COATINGS ON THE POLYMER SURFACES ACTIVATED WITH VISIBLE LIGHT, METHOD OF THEIR PREPARATION AND USE THEREOF

Номер: US20150174569A1
Автор: Buchalska Marta, Labuz Przemyslaw, Macyk Wojciech, Sadowski Rafal
Принадлежит: UNIWERSYTET JAGIELLONSKI

The invention relates to visible-light active photocatalytic coatings of titanium oxide (IV) on polymer surfaces, characterized in that are applied to a substrate which is the organic polymer material used in medicine, food and pharmaceutical packaging, and the coating is nanocrystalline titanium oxide (IV) or nanocrystalline titanium oxide (IV) surface-modified with organic compound. The invention also includes a method for the preparation of photocatalytic coatings of titanium oxide (IV) according to the invention, comprising the step of activating the surface of a polymeric material with low-temperature plasma technology, and then the synthesis of nanocrystalline titanium oxide (IV) coating and the modification of the surface layer with organic compounds. The invention also relates to the application of photocatalytic coating of titanium oxide (IV) according to the invention for sterilization of plastic elements used in medicine, food and pharmaceuticals packaging and application to production of selected products from the group consisting of: photosterilizing materials, photobactericidal, photofungicidal, photocatalytic materials. 1. An article of manufacture comprisinga) a substrate which is an organic polymer material used in medicine, food or pharmaceutical packaging, selected from the group consisting of polyurethane (PU), polycarbonate (PC), polyvinyl chloride (PVC), and polytetrafluoroethylene (PTFE), andb) a coating on the substrate which coating nanocrystalline titanium oxide(IV), or nanocrystalline titanium oxide(IV) surface-modified with an organic compound.3. The article according to claim 1 , characterized in that the nanocrystalline titanium oxide(IV) is surface-modified with an organic compound selected from the group consisting of: phthalic acid claim 1 , 4-sulfophthalic acid claim 1 , 4-amino-2-hydroxybenzoic acid claim 1 , 3-hydroxy-2-naphthyl acid claim 1 , salicylic acid claim 1 , 6-hydroxysalicylic acid claim 1 , 5-hydroxysalicylic acid claim ...

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Номер записи: 41
30-05-2019 дата публикации

Polyolefin-based Film

Номер: US20190161590A1
Автор: Cho Sol, Hong Dae Sik, Jang Chang-Hwan, Kwon Hyun Jee, Kwon Oh Joo, Lee Ki Soo, Park Sung Ho, Park Sung Hyun, Shin Eun Ji
Принадлежит: LG CHEM, LTD.

The present disclosure provides a polyolefin-based film including an olefin polymer which is controlled in the content of the branched polymer structure in the polymer and the weight average molecular weight of the main chain in the structure to exhibit excellent processability and transparency. Therefore, the polyolefin-based film not only exhibits high transparency independent of processing conditions, but also reduces the increase in film haze even when the thickness of the film increases. 1. A polyolefin-based film comprising an olefin polymer satisfying the following conditions (a) to (d):{'sup': 3', '3, '(a) a density: 0.910 g/cmto 0.930 g/cm'}(b) a melt index (measured according to ASTM D1238 at a temperature of 190° C. under a load of 2.16 kg): 0.5 g/10 min to 2.0 g/10 min(c) a content of a branched polymer structure: 1 to 7 wt % based on the total weight of the olefin polymer(d) a weight average molecular weight of main chain in the branched polymer structure: 100,000 to 600,000 g/mol.2. The polyolefin-based film of claim 1 , wherein MFRR (21.6/2.16) claim 1 , a value that the melt flow rate (MFR) measured at a temperature of 190° C. under a load of 21.6 kg according to ISO 1133 is divided by the melt flow rate (MFR) measured at a temperature of 190° C. under a load of 2.16 kg according to ISO 1133 claim 1 , is 20 or more and less than 40.3. The polyolefin-based film of claim 1 , wherein the olefin polymer has a weight average molecular weight of 90 claim 1 ,000 g/mol to 600 claim 1 ,000 g/mol.4. The polyolefin-based film of claim 1 , wherein the olefin polymer has a Z average molecular weight (Mz+1) of 400 claim 1 ,000 g/mol to 600 claim 1 ,000 g/mol.5. The polyolefin-based film of claim 1 , wherein the olefin polymer has a polydispersity index of 1 to 3.6. The polyolefin-based film of claim 1 , wherein the olefin polymer is a copolymer of ethylene and an alpha-olefin.7. The polyolefin-based film of claim 1 , wherein the olefin polymer is a copolymer of ...

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Номер записи: 42
22-06-2017 дата публикации

Composite material used for catalyzing and degrading nitrogen oxide and preparation method and application thereof

Номер: US20170173571A1
Автор: Chen Dongyun, LU Jianmei
Принадлежит:

The invention discloses a composite material used for catalyzing and degrading nitrogen oxide and its preparation method and application thereof. The invention of the hollow g-CNnanospheres/reduced graphene oxide composite-polymer carbonized nanofiber material is prepared as follow: 1) the preparation of silica nanospheres; 2) the preparation of hollow g-CNnanospheres; 3) the preparation of graphene oxide; 4) the preparation of surface modified hollow g-CNnanoparticles preparation; 5) the preparation of composites; 6) the preparation of composite-polymer carbon nanofiber material. The raw materials used in the process is low cost and easy to get; the operation of the invention is simple and convenient without the use of expensive equipment in the whole process; the composite has high adsorption efficiency of ppb level nitrogen oxide with good repeatability. 1. A preparation method of a hollow graphite phase carbon nitride nanosphere/reduction-oxidation graphene composite and polymer carbide nano fiber material , comprises the following steps:(1) preparation of silica nanospheres:in accordance with a mass ratio of concentrated ammonia:ethanol:water:ethyl silicate =1:15˜20:1˜5:1˜2, add ethyl silicate into a mixture of concentrated ammonia, ethanol and water, after mixing, keep standing for 1˜2 hours, then in accordance with a mass ratio of ethyl silicate:a mixture of ethyl silicate and octadecyltrimethoxysilane=1:1-2, add the mixture of ethyl silicate and octadecyltrimethoxysilane, mixing evenly and keep standing for 3˜5 hours, a resulted mixture is centrifugated, dried and calcined for 6˜8 hours at 550˜570° C., and then washed with 1M hydrochloric acid and dried, to obtain the silica nanospheres,(2) preparation of hollow graphite phase carbon nitride nanospheres:under vacuum condition, use the silica nanospheres in the step (1) as a template and mix with cyanamide in accordance with the mass ratio of 1:3˜7 and stir for 3˜5 hours, ultrasonic treat for 2˜3 hours, and ...

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Номер записи: 43
13-06-2019 дата публикации

POLYORGANIC FUNCTIONAL GROUPS MODIFIED SILICA, PROCESSES TO MAKE AND USE THEREOF

Номер: US20190176124A1
Автор: WILSON John Robert
Принадлежит: SI-NOVATION LTD

The invention relates to new compositions of polyorganic functional groups modified silica. The compositions contain a wide range of different functional groups such as mercapto, sulfide, thiourea, amines and amides in the same composition and each of these functional groups are present in an array of numerous different oligomers, configurations and stereochemistry. These functional groups have a strong affinity for metals and particular targets. Combining a high number of these functional groups together in the same composition enhances the overall binding affinity of the functionalised material. Combination with different structural configurations further enhances the capacity to bind to diverse structural variations in the targets found in actual process, product and waste streams. This multitude of binding mechanisms enables very high levels of purification and target removal as well as selectivity to be achieved in product, process and waste streams. The compounds are useful for the purification of products and for the removal of unwanted organic and inorganic compounds from product, process and waste streams, as chromatography medium for the purification and separation of metals, metal complexes and organic and biological compounds, for solid phase extraction, for solid phase synthesis, for metal mediated heterogeneous catalysis, for metal ion abstraction and for the immobilisation of bio-molecules. 2. A composition as claimed in wherein for General Formula I [Y][A][B][B][C][C][C][C][D][D][D][D][D][D][E][F][G][U][X]Y is Si(O); X is (O)SiCHSH; A is [(O)Si(CH)SCHCHS—CHCHCHSR][(O)Si(CH)SCHCHSCHCHCHS(CH)Si(O)][(O)Si(CH)SCHCH—CHSCHCHSR]; Bis [(O)Si(CH)SCHCHCHSH][(O)Si(CH)SCHCHCHSCHCH—SH][(O)Si(CH)SCHCHCHSCHCHSCHCHCH—S(CH)Si(O)]; Bis [(O)Si(CH)SCHCHCHSH][(O)Si(CH)SCHCHCHSCHCHCH—SH][(O)Si(CH)SCHCHCHSCHCHCHSCHCHCHS(CH)Si(O)]; Cis [(O)Si(CH)SCHCHSCHCHSCHCHSH][(O)Si(CH)SCHCHSCHCHSCHCHS(CH)Si(O)]; Cis [(O)Si(CH)SCHCHCHS—CHCHSCHCHCHSH][(O)Si(CH)SCHCHCHSCHCHSCHCHCHS(CH)Si( ...

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Номер записи: 44
13-06-2019 дата публикации

EXHAUST GAS CATALYST FOR INTERNAL COMBUSTION ENGINES

Номер: US20190176140A1
Автор: Ikeda Shinji, ISHIKAWA Norio, Otsuki Hiroshi, SAKUMA Tetsuya, TAKADA Keishi
Принадлежит: TOYOTA JIDOSHA KABUSHIKI KAISHA

An exhaust gas catalyst includes: catalyst particles that clean exhaust gas; and magnetic particles that are placed around the catalyst particles and that generate heat upon absorption of microwaves. Each of the magnetic particles includes: a core portion composed of a ferromagnetic material capable of generating heat upon absorption of microwaves; and a shell portion coating a surface of the core portion, the shell portion having a property of permitting passage of microwaves, the shell portion being superior to γ-alumina or θ-alumina in a property of blocking gases. 1. An exhaust gas catalyst for an internal combustion engine , comprising:catalyst particles that clean exhaust gas of the internal combustion engine; andmagnetic particles that are placed around the catalyst particles and that generate heat upon absorption of microwaves, wherein each of the magnetic particles includes:a core portion composed of a ferromagnetic material capable of generating heat upon absorption of microwaves; anda shell portion coating a surface of the core portion, the shell portion having a property of permitting passage of microwaves, the shell portion being superior to γ-alumina or θ-alumina in a property of blocking gases.2. The exhaust gas catalyst according to claim 1 , wherein the shell portion is composed of at least one material of: i) silicon nitride; ii) aluminum nitride; iii) manganese oxide; iv) α-alumina; and v) silica.3. The exhaust gas catalyst according to claim 1 , wherein the shell portion is composed of at least one material of: i) α-alumina; and ii) silica.4. The exhaust gas catalyst according to claim 1 , wherein a BET specific surface area of the shell portion is less than 180 m/g.5. The exhaust gas catalyst according to claim 1 , wherein a BET specific surface area of the shell portion is less than 105 m/g.6. The exhaust gas catalyst according to claim 1 , wherein a pore volume of the shell portion is less than 0.7 cm/g.7. The exhaust gas catalyst according to ...

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Номер записи: 45
09-07-2015 дата публикации

Composite Material Consisting of a Catalyst/Phase-Change Material, Related Manufacturing Methods and Use of Such a Material in Catalytic Reactions

Номер: US20150190796A1
Автор: BEDEL Laurent, Gavillet Jérôme
Принадлежит: Commissariat A L'Energie Atomique Et Aux Energies Alternatives

Material with hybrid particles () each consisting of a particle () of a phase-change material (PCM) interfaced with a catalytic material () in solid form, the size of the hybrid particles being between 0.1 mm and 10 mm, preferably between 1 mm and 5 mm. 116.-. (canceled)17. A material with hybrid particles each consisting of a particle of a phase-change material interfaced with a catalytic material in solid form , the size of the hybrid particles being between 0.1 mm and 10 mm.18. The material with hybrid particles as claimed in claim 17 , wherein the size of the hybrid particles is between 1 mm and 5 mm.19. The material with hybrid particles as claimed in claim 17 , the PCM material being selected from paraffins claim 17 , nitride-based eutectic materials claim 17 , nitrates claim 17 , hydroxides claim 17 , fluorides claim 17 , carbonate claim 17 , molten salts such as NaNO claim 17 , NaNO claim 17 , NaOH claim 17 , LiOH claim 17 , NaCl claim 17 , metal alloys such as AlSi claim 17 , capable of containing one or more heat-conducting elements such as carbon nanotubes claim 17 , metals such as Cu claim 17 , Al claim 17 , Si.20. The material with hybrid particles as claimed in claim 17 , the catalytic material covering an area between 1 and 100% of the outer surface of each hybrid particle.21. The material with hybrid particles as claimed in claim 20 , the catalytic material covering an area between 10 and 100% of the outer surface of each hybrid particle.22. The material with hybrid particles as claimed in claim 17 , comprising a continuous layer claim 17 , of a material different than the catalytic material encapsulating the PCM material.23. The material with hybrid particles as claimed in claim 17 , the catalytic material being in the form of a continuous layer encapsulating the PCM material.24. The material with hybrid particles as claimed in claim 17 , the catalytic material being in the form of a discontinuous layer partially covering the PCM material.25. The ...

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Номер записи: 46
09-07-2015 дата публикации

SELF-CLEANING, ANTI-SMOG, ANTI-MOULD PHOTOCATALYTIC POWDERED WATER BASED PAINT

Номер: US20150190797A1
Автор: BERNARDONI Massimo
Принадлежит: C.I.M. CALCI IDRATE MARCELLINA S.r.l.

A photocatalytic powdered water based paint is described comprising photocatalytic binding cement, inert micronized limestone, low viscosity cellulose, fluidifying agent, anti-foaming agent, vinyl polymer and pigments. The water based paint is characterized by the fact of comprising at least one and preferably all the following further additives: metakaolin, titanium dioxide, calcium formate and kieselguhr. 1. Photocatalytic powdered paint for use diluted in water , comprising Portland cement admixed with nanoparticle photocatalytic Titanium Dioxide , the size of said Titanium Dioxide nanoparticles being lower than 5 nanometers; inert limestone with a maximum grain-size distribution lower than 100 microns; cellulose with viscosity lower than 1 ,000 mPas; fluidizer; antifoam; vinyl polymer and pigments , comprising at least one and preferably all the following further additives: metakaolin , calcium formate and kieselguhr.3. Paint according to claim 2 , wherein said pigments are coated with a cellulose-based film that claim 2 , when comes in contact with water claim 2 , dissolves releasing the pigment claim 2 , said film preferably dissolving in a time lower than 2 seconds and more preferably in less than 1 second.4. Paint according to claim 3 , wherein said pigments are formed into granules whose dimensions have a grain-size range from 200 to 500 microns.6. Paint obtained with the method according to . The present invention relates to a photocatalytic powdered water based paint, i.e. a powdered compound that becomes a water based paint once diluted in water, that has considerable advantageous characteristics in addition to its main property of converting pollutants present in the air by photocatalysis, it being also able to remove bad smells, to prevent mould and bacterial cultures from developing on the supports painted therewith, as well as to prevent dark marks from developing on the surfaces because of its self-cleaning function and to prevent heat from being ...

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Номер записи: 47
04-06-2020 дата публикации

RADICAL GENERATING CATALYST, METHOD FOR PRODUCING RADICAL, METHOD FOR PRODUCING OXIDATION REACTION PRODUCT, DRUG, AND DRUG FOR USE IN AGRICULTURE AND LIVESTOCK INDUSTRY

Номер: US20200171118A1
Автор: SHIBATA Takekatsu, TAKAMORI Kiyoto
Принадлежит:

The present invention is intended to provide a radical generating catalyst that can generate (produce) radicals under mild conditions. In order to achieve the above object, the first radical generating catalyst of the present invention includes: at least one selected from the group consisting of amino acids, peptides, phospholipids, and salts thereof. The second or third radical generating catalyst of the present invention includes an ammonium salt represented by the following chemical formula (XI) (excluding peroxodisulfate) and having a Lewis acidity of 0.4 eV or more. 1. A radical generating catalyst comprising:at least one selected from the group consisting of amino acids, proteins, peptides, phospholipids, and salts thereof, whereinthe radical generating catalyst catalyzes radical generation from a radical source, andthe radical source comprises an oxoacid or an ion or salt thereof.2. The radical generating catalyst according to claim 1 , further comprising:ammonium.5. (canceled)6. The radical generating catalyst according to claim 4 , whereinthe ammonium is at least one selected from the group consisting of benzethonium chloride, benzalkonium chloride, hexadecyltrimethylammonium chloride, tetramethylammonium chloride, ammonium chloride, methylammonium chloride, tetrabutylammonium chloride, cetylpyridinium chloride, hexadecyltrimethylammonium bromide, dequalinium chloride, edrophonium, didecyldimethylammonium chloride, benzyltriethylammonium chloride, oxytropium, carbachol, glycopyrronium, safranin, sinapine, tetraethylammonium bromide, hexadecyltrimethylammonium bromide, suxamethonium, sphingomyelin, ganglioside GM1, denatonium, trigonelline, neostigmine, paraquat, pyridostigmine, phellodendrine, pralidoxime methiodide, betaine, betanin, bethanechol, betalain, lecithin, adenine, guanine, cytosine, thymine, uracil, and cholines.7. (canceled)12. The radical generating catalyst according to claim 1 , whereinthe amino acid is at least one selected from the group ...

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Номер записи: 48
06-07-2017 дата публикации

PARTICLES, PARTICLE DISPERSION, PARTICLE-DISPERSED RESIN COMPOSITION, PRODUCING METHOD THEREFOR, RESIN MOLDED ARTICLE, PRODUCING METHOD THEREFOR, CATALYST PARTICLES, CATALYST SOLUTION, CATALYST COMPOSITION, CATALYST MOLDED ARTICLE, TITANIUM COMPLEX, TITANIUM OXIDE PARTICLES AND PRODUCING METHOD THEREFOR

Номер: US20170189895A1
Автор: FUKUOKA Takahiro, Fukuzaki Saori, Hatakeyama Yoshiharu, Nagase Junichi, Nagatsuka Tatsuki, Shibata Shusaku
Принадлежит: NITTO DENKO CORPORATION

Organic-inorganic composite particles that can be dispersed in a solvent and/or a resin as primary particles having an organic group on the surface of inorganic particles, the organic-inorganic composite particles having negative birefringence. 1. A method for producing particles that can be dispersed in a solvent and/or a resin as primary particles , the primary particles being organic-inorganic composite particles having a hydrophobic group and/or a hydrophilic group and a binding group on the surface of inorganic particles , the binding group chemically bonding the hydrophobic group and/or the hydrophilic group to the surface of the inorganic particles , the organic-inorganic composite particles having negative birefringence ,comprising subjecting a metal hydroxide containing an alkaline earth metal, a carbonic acid source, and an organic compound to a hydrothermal synthesis to obtain the organic-inorganic composite particles,wherein a surface coverage by an organic group in the organic-inorganic composite particles is 30% or greater, andwherein the binding group is at least one selected from the group consisting of a carboxyl group, an amino group and a sulfo group.2. The method for producing particles according to claim 1 , wherein inorganic parts of the composite particles comprise a carbonate containing the alkaline earth metal and/or a composite oxide containing the alkaline earth metal.3. The method for producing particles according to claim 1 , wherein the primary particles are obtained by surface-treating the inorganic particles with the organic compound claim 1 , and the organic compound contains a binding group capable of binding to the surface of the inorganic particles and the hydrophobic group and/or the hydrophilic group serving as the organic group.4. The method for producing particles according to claim 1 , having an aspect ratio of 1000 or less.5. The method for producing particles according to claim 1 , having a maximum length of 200 μm or less. ...

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Номер записи: 49
22-07-2021 дата публикации

Method of producing cylindrical film-coated honeycomb structure and method of producing catalyst

Номер: US20210220811A1
Автор: Kazuhiro Sekiyama, Ryoma Oishi, Shingo Ishikawa, Takashi Yamada, Yoshinori Takahashi
Принадлежит: NE Chemcat Corp

Provided is a method of producing a film-coated cylindrical honeycomb structure formed with a coating liquid on an outer portion of a cylindrical honeycomb structure including partition walls and the outer portion, the partition walls forming a plurality of cells, the outer portion serving as a circumferential side. In the method, the cylindrical honeycomb structure is mounted between at least two rollers such that the circumferential side of the cylindrical honeycomb structure contacts with circumferential sides of the rollers, the coating liquid supplied from an application part is deposited on the cylindrical honeycomb structure while being rotated, and then the deposited coating liquid is dried or cured to form the film on the outer portion.

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Номер записи: 50
23-07-2015 дата публикации

POLYMERIC AND SOLID-SUPPORTED CATALYSTS, AND METHODS OF DIGESTING CELLULOSIC MATERIALS USING SUCH CATALYSTS

Номер: US20150202607A1
Автор: ANDOH Joseph, BAYNES Brian M., Fichtali Jaouad, GEREMIA John M.
Принадлежит: MIDORI RENEWABLES, INC.

Provided herein are catalysts useful in non-enzymatic saccharification processes. The catalysts can be polymeric catalysts or solid-supported catalysts with acidic and ionic moieties. Provided are also methods for hydrolyzing cellulosic materials into monosaccharides and/or oligosaccharides using the catalysts described herein. 1. A catalyst comprising a solid support , acidic moieties attached to the solid support , and ionic moieties attached to the solid support ,wherein the solid support comprises a material, wherein the material is selected from the group consisting of carbon, silica, silica gel, alumina, magnesia, titania, zirconia, clays, magnesium silicate, silicon carbide, zeolites, ceramics, and any combinations thereof,wherein each acidic moiety independently has at least one Bronsted-Lowry acid, andwherein each ionic moiety independently has at least one nitrogen-containing cationic group or at least one phosphorous-containing cationic group, or a combination thereof.2. The catalyst of claim 1 , wherein each Bronsted-Lowry acid is independently selected from the group consisting of sulfonic acid claim 1 , phosphonic acid claim 1 , acetic acid claim 1 , isophthalic acid claim 1 , boronic acid claim 1 , and perfluorinated acid.3. The catalyst of claim 1 , wherein one or more of the acidic moieties are directly attached to the solid support.4. The catalyst of claim 1 , wherein one or more of the acidic moieties are attached to the solid support by a linker.5. The catalyst of claim 1 , wherein each ionic moiety is selected from the group consisting of pyrrolium claim 1 , imidazolium claim 1 , pyrazolium claim 1 , oxazolium claim 1 , thiazolium claim 1 , pyridinium claim 1 , pyrimidinium claim 1 , pyrazinium claim 1 , pyradizimium claim 1 , thiazinium claim 1 , morpholinium claim 1 , piperidinium claim 1 , piperizinium claim 1 , pyrollizinium claim 1 , phosphonium claim 1 , trimethyl phosphonium claim 1 , triethyl phosphonium claim 1 , tripropyl phosphonium ...

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Номер записи: 51
23-07-2015 дата публикации

DEODORIZING MATERIAL, PROCESS FOR MANUFACTURING DEODORIZING MATERIAL, AND DEODORIZING DEVICE

Номер: US20150202608A1
Автор: Masaoka Yoshikuni, OHARA Toshihiko, Tagawa Masatake
Принадлежит:

A deodorizing material is a cured substance that is obtained by dissolving a photosensitizing colorant in an unsaturated polyester resin composition which contains unsaturated polyester and a monomer copolymerizable with the unsaturated polyester and which is in a liquid state at a room temperature, and by adding a curing agent to let the liquid cured. This deodorizing material changes from the base state to the singlet excitation state, and further to the triplet excitation state upon irradiation with light in a gas phase containing oxygen and odor components. This energy is given to the oxygen molecules to produce singlet oxygen. The oxidation action of the produced singlet oxygen decomposes the odor components. 1. A deodorizing material comprising a cured substance that is obtained by dissolving a rose bengal in an unsaturated polyester resin composition which contains unsaturated polyester and a monomer copolymerizable with the unsaturated polyester and which is in a liquid state at a room temperature , and by adding a curing agent to let the liquid cured ,wherein the rose bengal is excited upon irradiation with light in a gas phase containing oxygen and an odor component, gives energy to the oxygen to produce singlet oxygen, thereby decomposing the odor component.2. (canceled)3. (canceled)4. The deodorizing material according to claim 1 , wherein the rose bengal of equal to or greater than 1.5 g but smaller than 3.0 g is dissolved in the unsaturated polyester resin composition of 100 ml.5. A deodorizing material producing method comprising:dissolving a rose bengal in an unsaturated polyester resin composition which contains unsaturated polyester and a monomer copolymerizable with the unsaturated polyester, and which is in a liquid state at a room temperature; andadding a curing agent to let the liquid cured.6. (canceled)7. (canceled)8. The deodorizing material producing method according to claim 5 , wherein the rose bengal of equal to or greater than 1.5 g but ...

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Номер записи: 52
27-06-2019 дата публикации

METHOD FOR PREPARING LAMINAR ZINC HYDROXIDE ORGANIC-INORGANIC NANOCOMPOSITES FOR USE IN THE REMOVAL AND DEGRADATION OF DYES FROM TEXTILE EFFLUENTS

Номер: US20190193061A1
Автор: BENAVENTE ESPINOSA Eglantina Javiera, DEVIS RUIZ Sindy Milagros, DIAZ JALAFF Leslie Gabriela, GONZALEZ MORAGA Guillermo Antonio Alberto, LOZANO ZARTO Harold Ivan
Принадлежит:

The present invention relates to a method for removing dyes from textile effluents and other organic substances using nanocomposites based on zinc hydroxides and carboxylic acids capable of adsorbing and degrading. More specifically, the present invention consists of a method to generate new zinc hydroxide-based materials, which allows removal and degradation of methylene blue and other organic compounds from wastewater from industrial effluents, particularly those from textile industry. 1. A method for preparing laminar zinc hydroxide organic-inorganic nanocomposites for use in the removal and degradation of dyes from textile effluents , comprising:a) dissolving in a vessel at least a zinc salt, oxide or hydroxide in distilled water until reaching a molar concentration of 0.1 to 5.0 M;b) dissolving in a vessel at least a carbonate of alkali metals, alkaline-earth metals, other metals and metalloids in distilled water until reaching a molar concentration of 0.1 to 5.0 M;c) forming a suspension by dropwise adding to a volume of the aqueous solution prepared in step (a), a volume of the aqueous carbonate solution prepared in step (b);d) heating the suspension obtained in step (c), between 15-120° C. under constant stirring ranging from 5 to 10,000 rpm for a homogenization time between 0.1 min and 24 hours;e) adjusting the reaction mixture of step (d) to a pH between 4 and 12.5 with an alkali solution with a molar concentration of 0.1 to 12.0 M;f) homogenizing the suspension obtained in step (e) between 0.1 min and 24 hours at a temperature of 15-120° C. under constant stirring ranging between 5 to 10,000 rpm;g) adding a volume of a molecular or polymeric surfactant solution with a molar concentration of 0.1 to 12.0 M, where the surfactant comprises compounds having linear, branched or aromatic hydrocarbon chains with 2 or more carbon atoms, with hydrophilic groups;h) homogenizing the resulting suspension in step (g) between 0.1 min and 24 hours at a temperature of 15- ...

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Номер записи: 53
27-06-2019 дата публикации

METHODS OF PRODUCING ORGANOSILICA MATERIALS AND USES THEREOF

Номер: US20190194414A1
Автор: Calabro David C., Li Quanchang, Zhou Huaxing
Принадлежит:

Methods of preparing organosilica materials using a starting material mixture comprising at least one compound of Formula [(RO)SiCH](Ia) and at least one compound of Formula [R′ROSiCH](Ib), wherein each R′ independently represents an RO—, an R group, or an (RO)Si—CH— group, at least one R′ being (RO)Si—CH—; and R represents a C-Calkyl group, in the absence of a structure directing agent and/or porogen are provided herein. Processes of using the organosilica materials, e.g., for gas separation, etc., are also provided herein. 1. A method for preparing an organosilica material , the method comprising:{'sub': 2', '2', '3', '2', '3, '(a) providing a starting material mixture comprising at least one compound of Formula [(RO)SiCH](Ia) and at least one compound of Formula [R′ROSiCH](Ib), wherein'}{'sub': 3', '2', '3', '2, 'each R′ independently represents an RO— group, an R group, or an (RO)Si—CH— group, at least one R′ being (RO)Si—CH—; and'}{'sub': 1', '4, 'R represents a C-Calkyl group;'}(b) adding the starting material mixture into an acidic or basic aqueous mixture such that the resulting solution contains essentially no structure directing agent;(c) curing the solution to produce a pre-product; and{'sup': 1', '2', '1', '2, 'sub': 2', '3', '1', '4', '1', '4', '1', '4, '(d) drying the pre-product to obtain the organosilica material which is a polymer comprising independent siloxane units of Formula [RRSiCH](I), wherein each Rrepresents a hydroxyl group, a C-Calkoxy group, or an oxygen atom bonded to a silicon atom of another siloxane unit and each Rrepresents a hydroxyl group, a C-Calkoxy group, a C-Calkyl group, or an oxygen atom bonded to a silicon atom of another siloxane, wherein the organosilica material has an average pore diameter greater than about 1.0 nm.'}2. The method of claim 1 , wherein R represents a methyl or ethyl group claim 1 , preferably an ethyl group.3. The method of claim 1 , wherein the ratio between Formula (Ia) and Formula (Ib) is about 1:10 to ...

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Номер записи: 54
19-07-2018 дата публикации

PROCESS FOR PREPARING ALKYL PYROGLUTAMIC ACIDS

Номер: US20180201578A1
Автор: Henton Daniel R., Ng Sze-Sze, Rand Cynthia L.
Принадлежит: Dow Global Technologies LLC

Disclosed are compounds of formulae: 17.-. (canceled)9. A composition according to further comprising at least one additive claim 8 , excipient or diluent.10. A composition according to claim 8 , comprising at least two compounds of formula (II).1320.-. (canceled) This application claims benefit of U.S. Provisional Application Ser. No. 61/576,023, filed Dec. 15, 2011, the disclosure of which is incorporated herein by reference in its entirety.This disclosure relates to compounds and compositions suitable for use in surfactants. In particular, the disclosure relates to alkyl pyroglutamic acid compounds.The large shift towards environmentally friendly surfactants has resulted in the need for the industry to provide readily biodegradable and non-toxic surfactants and additives. Surfactants and additives with renewable content can be preferable to their synthetic counterparts with demand being driven by life sustainability initiatives, preferred buying programs and consumer trends.Alcohol ethoxy sulfates (AES) is a class of anionic surfactant commonly used in personal care shampoo formulation. The trace byproduct from the manufacturing processes of AES (alkoxylation and sulfation), and the skin irritancy associated with AES are not desirable in personal care applications. An ethylene oxide-free (EO-free) and sulfate-free surfactant that is non-irritating is much more preferable in personal care.Common EO-free and sulfate-free surfactant personal care surfactants are fatty acid soaps, betaines, alpha olefin sulfonates, sulfosuccinates, esters, alkyl polyglucosides, fatty acyl amino acids, fatty amine oxides, and quaternaries. Two common commercially available amino acid surfactants are acyl glutamate and acyl sarcosinate. Acyl glutamate is derived from natural fatty acids and natural glutamic acid, while acyl sarcosinate is derived from natural fatty acids and synthetic glycine. In either case, these amino acid surfactants are commonly accepted as non-toxic and mild. ...

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Номер записи: 55
04-07-2019 дата публикации

HYDROCARBON CONVERSION USING UZM-50

Номер: US20190201881A1
Автор: Galey Melissa M., Miller Mark A., Mowet John, Nicholas Christopher P., Nicholas Collette
Принадлежит:

A new aluminosilicate zeolite designated UZM-50, methods of making the zeolite, and its use as a catalyst in hydrocarbon conversion processes are described. This zeolite is represented by the empirical formula: 2. The process of wherein there are no more than three peaks of at least strong intensity in the x-ray diffraction pattern.3. The process of wherein there are no more than two peaks of at least strong intensity in the x-ray diffraction pattern.4. The process of wherein the catalyst has an InterPeak distance of greater than 14.75°2θ and less than 15.25°2θ as determined using Cu x-rays of 1.5418 Å wavelength.5. The process of wherein the catalyst has a Peak 1 FWHM of greater than about 1.25°2θ and less than 2.00°2θ as determined using Cu x-rays of 1.5418 Å wavelength.6. The process of wherein the catalyst has a CI value in a range of 1 to 3.7. The process of wherein x has a value of from 0 to 0.5 claim 1 , and y has a value from 6 to 50.8. The process of wherein the average diameter of the smallest feature observed by SAXS is less than 11 nm.9. The process of wherein the average diameter of the smallest feature observed by SAXS is less than 10 nm.10. The process of wherein the catalyst has a Nmicropore volume of about 0.14 to about 0.2 mL/g.11. The process of wherein the ratio of the Nmesopore volume to total pore volume≥0.88.12. The process of wherein the hydrocarbon conversion process is selected from the group consisting of oligomerization claim 1 , hydrocracking claim 1 , hydroisomerization claim 1 , hydrotreating claim 1 , hydrodenitrogenation claim 1 , hydrodesulfurization claim 1 , naphthene ring opening claim 1 , paraffin isomerization claim 1 , olefin isomerization claim 1 , conversion of an aromatic molecule to another aromatic molecule claim 1 , polyalkylbenzene isomerization claim 1 , di sproportionation of alkylbenzenes claim 1 , aromatic alkylation claim 1 , paraffin alkylation claim 1 , paraffin cracking claim 1 , naphthene cracking claim 1 , ...

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Номер записи: 56
13-08-2015 дата публикации

METAL COMPLEX AND METHOD FOR PRODUCING HYDROGEN PEROXIDE

Номер: US20150225236A1
Автор: Kato Kenji, Nagata Masaki, Ogo Seiji
Принадлежит:

An object of the present invention is to provide a novel method for producing hydrogen peroxide by direct synthesis that is capable of taking the place of the conventional anthraquinone process, and to provide a catalyst used in the production method. 2: The metal complex according to claim 1 , wherein the number of carbon atoms of the alkyl group is 1 to 4 claim 1 , the number of carbon atoms of the aralkyl group is 7 to 10 claim 1 , the number of carbon atoms of the aryl group is 6 to 9 claim 1 , the number of carbon atoms of the alkoxy group is 1 to 4 claim 1 , the number of carbon atoms of the aralkyloxy group is 7 to 10 claim 1 , and the number of carbon atoms of the aryloxy group is 6 to 9.3: The metal complex according to claim 1 , represented by the formula (1) claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , Rand Rrepresent hydrogen atoms claim 1 , Rand Rrepresent methyl groups claim 1 , one of X claim 1 , Y and Z represents OH claim 1 , the remaining two represent HO claim 1 , and An1 represents a nitrate ion.4: The metal complex according to claim 1 , represented by the formula (2) claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , Rand Rrepresent hydrogen atoms claim 1 , Rand Rrepresent methyl groups claim 1 , Y represents HO and An2 represents a nitrate ion.5: The metal complex according to claim 1 , represented by the formula (3) claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , Rand Rrepresent hydrogen atoms claim 1 , Rand Rrepresent methyl groups claim 1 , Y represents HO and An3 represents a nitrate ion.6: The metal complex according to claim 1 , represented by the formula (4) claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , Rand Rrepresent hydrogen atoms claim 1 , Rand Rrepresent methyl groups claim 1 , X and Y represent HO and An4 represents a nitrate ion.8: The metal complex according to claim 1 , represented by the formula (1).9: The ...

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Номер записи: 57
11-07-2019 дата публикации

PHOTOCATALYST LAMINATE

Номер: US20190210007A1
Автор: FURUDATE Manabu, INOUE Tomohiro, MASUDA Kohei, Yoshii Ryosuke
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

A photocatalyst laminate which is composed of an undercoat layer provided on a substrate and a photocatalyst layer laminated on the surface of the undercoat layer. The undercoat layer contains (A) 100 parts by mass of a resin component and (B) 0.1-50 parts by mass of fine core-shell particles, each of which has a core that is formed of a fine tetragonal titanium oxide solid solution particle wherein tin and manganese are solid-solved and a shell that is formed from silicon oxide on the outside of the core. This photocatalyst laminate is not susceptible to decrease in the photocatalyst function even under outdoor exposure for a long period of time, and is thus capable of providing a coated article that exhibits excellent weather resistance. 1. A photocatalyst laminate adapted to be disposed on a substrate , the laminate comprising an undercoat layer and a photocatalyst layer laid on a surface of the undercoat layer ,said undercoat layer comprising(A) 100 parts by weight of a resin component and(B) 0.1 to 50 parts by weight of core/shell nanoparticles each consisting of a core in the form of a tetragonal titanium oxide solid-solution nanoparticle having tin and manganese incorporated in solid solution and a shell of silicon oxide around the core.2. The photocatalyst laminate of wherein the undercoat layer has a thickness of 0.01 to 10 μm and the photocatalyst layer has a thickness of 0.01 to 10 μm.3. The photocatalyst laminate of or wherein the resin component is one or more resins selected from the group consisting of silicone resins claim 1 , silicone-modified resins claim 1 , and fluoro-resins.4. The photocatalyst laminate of claim 1 , having a Haze value of up to 5.5. The photocatalyst laminate of wherein the photocatalyst layer has a contact angle with water of up to 30° on its surface after UV exposure in an accumulative UV energy quantity of 1 claim 1 ,500 MJ/m.6. The photocatalyst laminate of wherein the shell of silicon oxide on the surface of the core/shell ...

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Номер записи: 58
19-08-2021 дата публикации

ETHYLENE SENSOR

Номер: US20210255159A1
Автор: Da Silveira Andre Rafaela, Fong Darryl, Luo Shaoxiong, Swager Timothy
Принадлежит: Massachusetts Institute of Technology

Wacker oxidation can be used as a signal transduction mechanism for the selective and sensitive detection of ethylene in air via chemiresistive sensing. Using this system, the senescence of lisianthus flowers and carnations can be monitored. 1. A sensor comprising:a conductive region in electrical communication with at least two electrodes, the conductive region including a conductive material and a palladium based catalyst material in contact with the conductive material.2. The sensor of claim 1 , wherein the conductive material includes a p-type conductor or an n-type conductor.3. The sensor of claim 1 , wherein the conductive material includes a carbon nanotube claim 1 , a carbon nanotube including a coordinating group claim 1 , graphite claim 1 , or graphene.4. The sensor of claim 3 , wherein the carbon nanotube including a coordinating group includes pyridyl functionalized carbon nanotubes.5. The sensor of claim 1 , wherein the conductive material includes silica/zinc oxide nanoparticle and/or nanofiber.6. The sensor of claim 1 , wherein the palladium based catalyst includes Pd(II).7. The sensor of claim 1 , wherein the palladium based catalyst includes a Pd(II) salt and a nitrite salt claim 1 , a Pd(II) salt with a Cu(II) salt and a nitrite salt claim 1 , or a Pd-Cu heterobimetallic complex and a nitrite salt.8. The sensor of claim 7 , wherein the palladium based catalyst includes an alkyl ammonium nitrite salt.9. The sensor of claim 1 , wherein the conductive material includes a metal oxide.10. The sensor of claim 1 , wherein the conductive material includes an inorganic semiconductor.11. The sensor of claim 1 , wherein the sensor includes an ionic liquid solvent.12. The sensor of claim 1 , wherein the sensor includes an oil or flexible polymer.13. The sensor of claim 1 , wherein the sensor includes a liquid material.14. The sensor of claim 13 , wherein the liquid material includes an aromatic alcohol.15. The sensor of claim 1 , wherein the sensor includes a ...

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Номер записи: 59
18-08-2016 дата публикации

Process for preparing alkyl pyroglutamic acids

Номер: US20160237033A1
Автор: Cynthia L. Rand, Daniel R. Henton, Sze-Sze Ng
Принадлежит: Dow Global Technologies LLC

Disclosed are compounds of formulae: and salts, hydrates, or solvates thereof, where R 1 , R 2 , R 3 , R 5 , and R 6 are defined herein, compositions containing these compounds, methods of preparing these compounds, and methods of using these compounds in a variety of applications, such as a surfactant or additive in personal care products.

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Номер записи: 60
17-08-2017 дата публикации

METHOD OF DEVELOPMENT AND USE OF CATALYST-FUNCTIONALIZED CATALYTIC PARTICLES TO INCREASE THE MASS TRANSFER RATE OF SOLVENTS USED IN ACID GAS CLEANUP

Номер: US20170232380A1
Автор: Lippert Cameron A., Liu Kunlei, Widger Leland R.
Принадлежит:

The present invention relates to methods for improving carbon capture using entrained catalytic-particles within an amine solvent. The particles are functionalized and appended with a COhydration catalyst to enhance the kinetics of COhydration and improve overall mass transfer of COfrom an acid gas. 1: A biphasic scrubbing solution comprising an amine solvent with particles suspended therein , wherein the particles have a surface-appended carbonic anhydrase mimic catalyst and further wherein the particles have a width of less than about 500 microns.2: The biphasic scrubbing solution of claim 1 , wherein the particles are hydrophobic.3: The biphasic scrubbing solution of claim 1 , wherein the particles comprise activated carbon particles.4: The biphasic scrubbing solution of claim 1 , wherein the particles are functionalized to increase positive zeta potential.5: The biphasic scrubbing solution of claim 4 , wherein the particles are functionalized by oxidation.6: The biphasic scrubbing solution of claim 4 , wherein the particles are functionalized by an appended with a functional group selected from the group consisting of an alcohol claim 4 , a primary amine claim 4 , a tertiary amine claim 4 , and an amino silane.7: The biphasic scrubbing solution of claim 1 , wherein the surface-appended carbonic anhydrase mimic catalyst comprises a bidentate transition-metal ligand complex.11: The biphasic scrubbing solution of claim 1 , wherein the particles have a width of between about 0.1 and 500 microns.12: The biphasic scrubbing solution of claim 1 , wherein the particles have a width of less than 100 nanometers.13: The biphasic scrubbing solution of claim 1 , wherein the amine solvent is selected from the group consisting of monoethanolamine (MEA) claim 1 , 1-amino-2-propanol (1A2P) claim 1 , 3-amino-1-propanol claim 1 , 2-amino-1-propanol claim 1 , 2-amino-1-butanol claim 1 , 1-amino-2-butanol claim 1 , 3-amino-2-butanol claim 1 , 2-(methylamino)ethanonol (MAE) claim 1 , ...

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Номер записи: 61
26-08-2021 дата публикации

Enhanced Reduction Bioremediation Method Using In-situ Alcoholysis

Номер: US20210260566A1
Автор: Alden David F., BIRK Gary M.
Принадлежит:

The present subject matter relates to a composition for in-situ remediation of soil and aquifer comprising of a water miscible oil; a solvent (for dissolving the vegetable oil to form a solution); and a catalyst (selected from enzymes biocatalysts, particularly lipases, alkaline compounds, heat or combinations thereof). The present subject matter provides a process for the preparation of the composition and application of the same for surface remediation. Further, the present subject matter provides an in-situ alcoholysis remediation method to reduce contaminant concentrations in aquifer and soil by enabling the generation of both soluble and slowly fermenting electron donors required for the anaerobic remediation of organohalide compounds contaminating soils and groundwater. The method of remediation includes mixing an engineered water-soluble oil or water miscible oil with a solvent and adding a catalyst to groundwater to promote the formation of fatty acid alkyl esters, carboxylic acid salts and glycerol. 1. A composition for in-situ remediation of soil and aquifer , said composition consisting essentially of:(a) a water miscible oil consisting of a vegetable oil and a surfactant;(b) a solvent miscible with water and adapted to dissolve the vegetable oil to form a solution; and(c) a catalyst selected from the group consisting of an enzyme defined by a biocatalyst, an alkaline compound, heat or combinations thereof.2. The composition as claimed in claim 1 , wherein the composition is used for removal of contaminants defined by at-least one of:recalcitrant organic and inorganic contaminants selected from the group consisting of halogenated straight-chain and aromatic hydrocarbons; perchlorate derivatives;explosives selected from the group consisting of nitroaromatic compound, nitramine compounds, nitrate esters, and energetic munitions residuals; nitrates; and oxidized metals; anda combination thereof.3. The composition as claimed in claim 1 , wherein said solvent ...

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Номер записи: 62
03-09-2015 дата публикации

Coatable Composition, Photocatalytic Articles, and Methods of Making the Same

Номер: US20150246350A1
Автор: Chen Xue-hua, Jing Naiyong, Sun Fuxia
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

A method of making a coatable composition includes: providing a first composition comprising silica nanoparticles dispersed in an aqueous liquid vehicle, wherein the silica nanoparticles have an average particle size of less than or equal to 100 nanometers, wherein the first composition has a pH greater than 6; acidifying the first composition to a pH of less than or equal to 4 using inorganic acid to provide a second composition; and dissolving at least one metal compound in the second composition to form the coatable composition, wherein said at least one metal compound comprises a titanium compound. Coatable compositions and photocatalytic compositions, preparable by the method, are also disclosed. Photocatalytic articles including the photocatalytic compositions are also disclosed. 1. A method of making a coatable composition , the method comprising:providing a first composition comprising silica nanoparticles dispersed in an aqueous liquid vehicle, wherein the silica nanoparticles have an average particle size of less than or equal to 100 nanometers, wherein the first composition has a pH greater than 6;acidifying the first composition to a pH of less than or equal to 4 using inorganic acid to provide a second composition; anddissolving at least one metal compound in the second composition to form the coatable composition, wherein said at least one metal compound comprises a titanium compound.2. The method of claim 1 , wherein the silica nanoparticles have an average particle size of less than or equal to 50 nanometers.3. The method of claim 1 , wherein the at least one metal compound further comprises a zinc compound.4. The method of claim 1 , wherein the at least one metal compound further comprises a tin compound.5. The method of claim 1 , wherein the coatable composition is essentially free of organic non-volatile compounds.6. The method of claim 1 , wherein the first composition further comprises polymer particles dispersed in the aqueous liquid vehicle.7. ...

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Номер записи: 63
13-11-2014 дата публикации

Protected reduced metal catalyst

Номер: US20140336287A1
Автор: Albertus Jacobus Sandee, Robert TERORDE
Принадлежит: BASF Corp

The invention relates to a process for producing a protected reduced supported metal catalyst powder, in particular catalysts used in a variety of chemical reactions, such as the hydrogenation of hydrocarbon compounds in petrochemical and oleo-chemical processes; the hydrogenation of unsaturated fats and oils, and unsaturated hydrocarbon resins; and in the Fischer Tropsch process. This invention also relates to a composition comprising said catalyst and a liquid. In accordance with the invention there is provided a process for preparing a protected, reduced metal catalyst on a support, wherein said supported catalyst is in the form of a powder, which process comprises contacting and mixing said supported catalyst with a liquid in an inert atmosphere and wherein the amount of liquid corresponds to up to five times the amount required for incipient wetness.

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Номер записи: 64
20-11-2014 дата публикации

COMPOSITION AND A METHOD OF MAKING AND USE OF SUCH COMPOSITION

Номер: US20140339135A1
Автор: GABRIELOV Alexei Grigorievich, GILLESPIE William Douglas, Smegal John Anthony, Wolohan Peter
Принадлежит:

A composition and method of making such a composition that has application in the hydroprocessing of hydrocarbon feedstocks. The method comprises selecting an organic additive by the use of a correlation model for predicting catalytic activity as a function of a physical property that is associated with the organic additive and incorporating the organic additive into a support material to provide the additive impregnated composition. 1. A composition for use in the hydroprocessing of a hydrocarbon feedstock , wherein said composition comprises: a support material having incorporated therein a metal component and an organic additive selected by the use of a correlation model , wherein said correlation model provides for estimating a predicted catalytic activity of said composition that has been prepared with said organic additive having a characteristic complexation energy , and wherein said organic additive is selected from a group consisting of amide compounds , amine compounds , nitrile compounds , pyrrolidone compounds , urea compounds , and oxalate compounds , wherein said organic additive is capable of forming a metal complex with a transition metal , and wherein said organic additive has said complexation energy of an absolute value of greater than 470 kcal/mol.2. A composition as recited in claim 1 , wherein said metal component is selected from the group of Group 9 or Group 10 metals consisting of cobalt and nickel present in said composition in an amount in the range of from 0.5 wt. % to 20 wt. % claim 1 , and the group of Group 6 metals consisting of molybdenum and tungsten present in said composition in an amount in the range of from 5 wt. % to 50 wt. % claim 1 , wherein the weight percents are based on the weight of the dry support material with the metal component as the elemental form regardless of its actual form.3. A composition as recited in claim 2 , wherein said support material a porous refractory oxide selected from the group of refractory ...

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Номер записи: 65
08-08-2019 дата публикации

CATALYST FOR CURABLE COMPOSITIONS CONTAINING HEXAHYDROTRIAZINE STRUCTURAL UNITS

Номер: US20190240649A1
Автор: BURCKHARDT Urs, CANNAS Rita
Принадлежит: SIKA TECHNOLOGY AG

A compound containing at least one hexahydrotriazine unit of formula (I) having at least one amidine or guanidine group and to the use thereof as a catalyst for the crosslinking of a functional compound, in particular a polymer including silane groups. The compound contains at least one hexahydrotriazine unit of formula (I) is producible in a simple process from readily available feedstocks, odorless at room temperature, non-volatile and largely non-toxic. The compound accelerates the crosslinking of functional polymers surprisingly well and by simple variation of the substituents is variable such that it has very good compatibility in different polymers as a result of which such compositions do not have a propensity for migration-based defects such as separation, exudation or substrate contamination. 2. A compound as claimed in claim 1 , wherein A is a divalent hydrocarbyl radical which has 2 to 50 carbon atoms and optionally contains heteroatoms in the form of ether oxygen or secondary or tertiary amine nitrogen or siloxane units.4. A compound as claimed in claim 3 , wherein Ris a hydrogen radical or an alkyl radical having 1 to 4 carbon atoms claim 3 , and Rand Rtogether are R.5. A compound as claimed in claim 3 , wherein Ris —NRR claim 3 , R claim 3 , Rand Rare each a hydrogen radical claim 3 , and Rand Rare each independently an alkyl claim 3 , cycloalkyl or aralkyl radical which has 1 to 12 carbon atoms and optionally contains an ether oxygen or tertiary amine nitrogen.7. A compound as claimed in claim 6 , wherein X is a radical selected from -A-Z claim 6 , methyl claim 6 , ethyl claim 6 , propyl claim 6 , isopropyl claim 6 , butyl claim 6 , isobutyl claim 6 , sec-butyl claim 6 , tert-butyl claim 6 , hexyl claim 6 , octyl claim 6 , 2-ethylhexyl claim 6 , cyclohexyl claim 6 , benzyl claim 6 , methoxyethyl claim 6 , methoxyethoxyethyl claim 6 , trimethoxysilylpropyl claim 6 , triethoxysilylpropyl and ω-alkoxypoly(dimethylsiloxane)prop-3-yl having an average ...

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Номер записи: 66
20-11-2014 дата публикации

CATALYST FOR PRODUCING PARAXYLENE BY CO-CONVERSION OF METHANOL AND/OR DIMETHYL ETHER AND C4 LIQUEFIED GAS, METHOD FOR PREPARING THE SAME AND METHOD FOR USING THE SAME

Номер: US20140343337A1
Автор: Liu Zhongmin, Xu Lei, Yu Zhengxi
Принадлежит: Dalian Institute of Chemical Physics, Chinese Academy of Sciences

This application provides a catalyst for producing paraxylene by co-conversion of methanol and/or dimethyl ether and Cliquefied gas, and preparation and application thereof. The catalyst is an aromatization molecular sieve catalyst with a shape-selective function co-modified by bimetal and siloxane compound. Methanol and/or dimethyl ether and Cliquefied gas are fed in reactor together, wherein aromatization reaction occurring on a modified shape-selective molecular sieve catalyst. The yield of aromatics is effectively improved, in which paraxylene is the main product. In products obtained by co-conversion of methanol and/or dimethyl ether and Cliquefied gas, the yield of aromatics is greater than 70 wt %, and the content of paraxylene in aromatics is greater than 80 wt %, and the selectivity of paraxylene in xylene is greater than 99 wt %. 2. The catalyst according to claim 1 , wherein said siloxane compound is tetraethoxysilane.3. The catalyst according to claim 1 , wherein the molecular sieve in said aromatization molecular sieve catalyst with a shape-selective function is HZSM-5 and/or HZSM-11 zeolite molecular sieve.4. The catalyst according to claim 1 , wherein the loading amount of said Zinc is 0.5-8 wt % of the total weight of said catalyst; and the loading amount of said Gallium is 0.5-8 wt % of the total weight of said catalyst; and the loading amount of said siloxane compound claim 1 , which is based on silicon oxide claim 1 , is 0.5-10 wt % of the total weight of said catalyst.54. A method for preparing any one of catalysts according to - claim 1 , comprising the steps as follows:(a) the molecular sieve is impregnated in a solution containing at least one soluble salt of one of Zinc and Gallium, then filtered, dried and calcined to obtain a metal-modified molecular sieve;(b) said metal-modified molecular sieve obtained from step (a) is impregnated in a solution containing at least one soluble salt of the other of Zinc and Gallium, then filtered, dried and ...

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Номер записи: 67
07-09-2017 дата публикации

METATITANIC ACID PARTICLE AND METHOD FOR PRODUCING THE SAME

Номер: US20170253621A1
Автор: HIROSE Hidekazu, IWANAGA Takeshi, KASHIMA Yasunobu, OKUNO Hiroyoshi, SUGITATE Atsushi, TAKEUCHI Sakae, YAMADA Wataru, YOSHIKAWA Hideaki
Принадлежит: FUJI XEROX CO., LTD.

A metatitanic acid particle surface-treated with a silane compound having a hydrocarbon group has absorption at a wavelength of about 400 nm or more and about 800 nm or less in an ultraviolet-visible absorption spectrum, and has an absorption peak at a wave number of about 2700 cmor more and about 3000 cmor less in an infrared absorption spectrum. 1. A metatitanic acid particle surface-treated with a silane compound having a hydrocarbon group ,wherein the metatitanic acid particle has absorption at a wavelength of about 400 nm or more and about 800 nm or less in an ultraviolet-visible absorption spectrum, and{'sup': −1', '−1, 'the metatitanic acid particle has an absorption peak at a wave number of about 2700 cmor more and about 3000 cmor less in an infrared absorption spectrum.'}2. The metatitanic acid particle according to claim 1 ,{'sup': 1', '2, 'sub': n', 'm, 'wherein the silane compound is a compound represented by general formula RSiR,'}{'sup': 1', '2', '1', '2, 'where Rrepresents a saturated or unsaturated aliphatic hydrocarbon group having 1 to 20 carbon atoms or an aromatic hydrocarbon group, Rrepresents a halogen atom or an alkoxy group, n represents an integer of 1 to 3, and m represents an integer of 1 to 3, where n+m=4; when n represents an integer of 2 or 3, a plurality of Rmay represent the same group or different groups; and when m represents an integer of 2 or 3, a plurality of Rmay represent the same group or different groups.'}3. The metatitanic acid particle according to claim 2 , wherein Rin the general formula RSiRrepresents a saturated hydrocarbon group.4. The metatitanic acid particle according to claim 3 , wherein Rin the general formula RSiRrepresents a linear saturated hydrocarbon group.5. The metatitanic acid particle according to claim 2 , wherein Rin the general formula RSiRrepresents an aromatic hydrocarbon group having 6 to 27 carbon atoms.6. The metatitanic acid particle according to claim 5 , wherein the aromatic hydrocarbon group ...

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Номер записи: 68
24-09-2015 дата публикации

PHOTOCATALYST COATING COMPOSITION

Номер: US20150266012A1
Автор: KANEKO Shotaro, KATAOKA Kyoko, Shichi Tetsuya, TAMURA Mari
Принадлежит:

There is provided a photocatalyst coating composition that is capable of forming a smooth and even photocatalyst coated film without the formation of aggregated particles. The photocatalyst coating composition according to the present invention includes photocatalyst particles, inorganic oxide particles other than the photocatalyst particles, a dispersion medium composed mainly of water, and a thickening agent, wherein the composition has a viscosity of 0 mPa·s or more to 10 mPa·s or less and, when the concentration of the composition is condensed tenfold, has a viscosity of not less than 40 mPa·s as determined under conditions of a shear rate of 1.0 sand a temperature of 25° C. with a rheometer. 1. A photocatalyst coating composition comprising photocatalyst particles , inorganic oxide particles other than the photocatalyst particles , a dispersion medium mainly composed of water , and a thickening agent , wherein{'sup': '−1', 'the composition has a viscosity of 0 mPa·s or more to 10 mPa·s or less and, when the concentration of the composition is condensed tenfold, has a viscosity of not less than 40 mPa·s as determined under conditions of a shear rate of 1.0 sand a temperature of 25° C. with a rheometer.'}2. The photocatalyst coating composition according to claim 1 , wherein the composition claim 1 , when the concentration thereof is condensed tenfold claim 1 , has a viscosity of not less than 80 mPa·s as determined under conditions of a shear rate of 1.0 sand a temperature of 25° C. with a rheometer.4. The photocatalyst coating composition according to claim 1 , wherein the content of the thickening agent is 0.01% or more by mass to 1% or less by mass.5. The photocatalyst coating composition according to claim 1 , wherein the thickening agent is a clay-based thickening agent claim 1 , an organic-based thickening agent claim 1 , or a combination of the clay-based thickening agent and the organic-based thickening agent.6. A photocatalyst coated film consisting of ...

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Номер записи: 69
24-09-2015 дата публикации

PHOTOCATALYST

Номер: US20150266013A1
Автор: LEUNG Wallace Woon Fong, Pei Chun
Принадлежит:

A photocatalyst includes a composite fiber having at least two crystalline semi-conductors that provide a heterojunction structure in the composite fiber. 1. A photocatalyst comprising a composite fiber including at least two crystalline semi-conductors , wherein the crystalline semi-conductors provide a heterojunction structure in the composite fiber.2. The photocatalyst of claim 1 , wherein the at least two crystalline semi-conductors have band position alignments which allow vectorial displacement of electrons and holes.3. The photocatalyst of claim 2 , wherein one of the crystalline semi-conductors is an n-type semi-conductor selected from the group consisting of titanium dioxide claim 2 , bismuth oxide claim 2 , zinc oxide claim 2 , and combinations thereof.4. The photocatalyst of claim 2 , wherein one of the crystalline semi-conductors is a p-type semi-conductor selected from the group consisting of copper (I) oxide claim 2 , copper (II) oxide claim 2 , cadmium telluride claim 2 , and combinations thereof.5. The photocatalyst of claim 1 , wherein one of the crystalline semi-conductors is prepared from a precursor solution including bismuth oxide in a concentration from about 0.1% to about 1% claim 1 , zinc oxide in a concentration from about 0.1% to about 1% claim 1 , and titanium dioxide in a concentration from about 1% to about 10%.6. The photocatalyst of claim 1 , wherein the composite fiber has a nanostructure.7. The photocatalyst of claim 1 , whereinthe photocatalyst is capable of removing a contaminant from a fluid stream, andthe contaminant comprises a pollutant.8. The photocatalyst of claim 1 , wherein the composite fiber further comprises a polymer coating.9. The photocatalyst of claim 1 , furthers comprising a substrate holding the composite fiber.10. The photocatalyst of claim 9 , wherein the substrate is transparent to light and is gas permeable.11. The photocatalyst of claim 9 , wherein the substrate is flexible.12. The photocatalyst of claim 9 , ...

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Номер записи: 70
15-08-2019 дата публикации

MODIFIED POROUS ORGANIC FRAMEWORK AND MANUFACTURING METHOD THEREOF, POROUS ORGANIC FRAMEWORK COMPOSITE AND MANUFACTURING METHOD THEREOF

Номер: US20190247839A1
Автор: LIN Chia-Her, LO Sheng-Han, LU Kuang-Lieh
Принадлежит:

A method for manufacturing a modified porous organic framework includes steps as follows. A mixed solution is provided. The mixed solution includes a porous organic framework, a plurality of group donors and a solvent. The porous organic framework includes a plurality of first ligands. Each of the first ligands includes at least one tetrazine group. Each of the group donors includes a reactive group and a modifying group covalently connected with each other. The reactive groups are alkenyl groups, alkynyl groups, aldehyde groups, ketone groups or a combination thereof. A modifying step is conducted, wherein at least one of the reactive groups of the group donors is reacted with at least one of the tetrazine groups of the first ligands, so that at least one of the modifying groups of the group donors is covalently connected with the porous organic framework, whereby the modified porous organic framework is obtained. 1. A method for manufacturing a modified porous organic framework , comprising:providing a mixed solution, wherein the mixed solution comprises a porous organic framework, a plurality of group donors and a solvent, the porous organic framework comprises a plurality of first ligands, each of the first ligands comprises at least one tetrazine group, each of the group donors comprises a reactive group and a modifying group covalently connected with each other, and the reactive groups of the group donors are alkenyl groups, alkynyl groups, aldehyde groups, ketone groups or a combination thereof; andconducting a modifying step, wherein at least one of the reactive groups of the group donors is reacted with at least one of the tetrazine groups of the first ligands, so that at least one of the modifying groups of the group donors is covalently connected with the porous organic framework, whereby the modified porous organic framework is obtained.2. The method for manufacturing the modified porous organic framework of claim 1 , wherein each of the group donors is ...

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Номер записи: 71
14-10-2021 дата публикации

HYBRID MATERIAL AND METHOD FOR THE PRODUCTION THEREOF

Номер: US20210316288A1
Автор: Backov Renal, Deleuze Herve, Sanchez Clement, UNGUREANU Simona
Принадлежит:

The invention relates to a material in the form of a cellular solid monolith consisting of an inorganic oxide polymer. Said monolith comprises macropores which have an average size dof 4 μm to 50 μm, mesopores that have an average size dof 20 to 30 Å, and micropores which have an average size dof 5 à 10 Å, said pores being interconnected. The inorganic oxide polymer has organic groups R of formula —(CH)—R, wherein 0≤n≤5, and Ris selected from among a thiol group, a pyrrole group, an amino group having one or more optional, optionally substituted alkyl, alkylamino, or aryl substituents, an alkyl group, or a phenyl group optionally having an alkyl-type substituent R. The disclosed material can be used as a substrate for a metal catalyst and for decontaminating liquid or gaseous media. 1. A material in the form of a solid cellular monolith comprising a polymer of an inorganic oxide , wherein:{'sub': A', 'E', 'I, 'said cellular monolith has macropores having a mean size dfrom 4 μm to 50 μm, mesopores having a mean size dfrom 20 to 30 Å and micropores having a mean size dfrom 5 to 10 Å, said pores being interconnected;'}{'sub': 2', 'n, 'sup': 1', '1, 'the inorganic oxide polymer carries organic R groups corresponding to the formula —(CH)—Rin which 0≤n≤5, and Rrepresents a thiol group, a pyrrolyl group, an alkyl group, an amino group that may carry one or more possibly substituted alkyl, alkylamino or aryl substituents, or a phenyl group that may carry an alkyl substituent.'}2. The material as claimed in claim 1 , wherein the inorganic oxide is an oxide of one or more elements claim 1 , at least one of these elements being of the type capable of forming an alkoxide.3. The material as claimed in claim 2 , wherein at least one of the metals is chosen from Si claim 2 , Ti claim 2 , Zr claim 2 , Th claim 2 , Nb claim 2 , Ta claim 2 , V claim 2 , W and Al.4. The material as claimed in claim 2 , wherein the oxide is a mixed oxide additionally containing B and Sn.5. The material ...

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Номер записи: 72
01-10-2015 дата публикации

CATALYST FOR CELLULOSE HYDROLYSIS

Номер: US20150273454A1
Автор: Roth Stephen
Принадлежит: United Catalyst, LLC

The present invention is directed to an imprinted mesoporous silica catalyst functionalized with a carboxylic acid group, capable of binding and hydrolyzing at least one glucose substrate into glucose. 1. A biomimetic catalyst , said catalyst comprising:a polymeric silica matrix,at least one active site imprinted into said matrix, andat least one carboxylic acid functionality in said active site.2. The biomimetic catalyst of claim 1 , wherein said catalyst is capable of catalyzing hydrolysis of at least one glucose substrate.3. The bimimetic catalyst according to wherein said catalyst has an activity of at least 20 μmoles·min/mg catalyst.4. The bimimetic catalyst according to wherein said catalyst has an activity of at least 80 μmoles·min/mg catalyst.5. The biomimetic catalyst of claim 1 , prepared by reacting at least one tetraorthosilicate and at least one functionalized silane in the presence of at least one imprinting molecule to form a polymeric silica matrix impregnated with said at least one imprinting molecule claim 1 , wherein at least 1 mol percent of said at least one functionalized silane comprises a carboxylic acid or carboxylic acid precursor functionalized silane; isolating said impregnated polymeric silica matrix; and removing said at least one imprinting molecule from said impregnated polymeric silica matrix via washing or burning to form a silica matrix imprinted with the structure of said at least one imprinting molecule.6. The biomimetic catalyst of claim 1 , wherein said at least one functionalized silane comprises a carboxylic acid precursor and said process further comprises hydrolyzing said carboxylic acid precursor.7. The biomimetic catalyst of claim 6 , wherein said carboxylic acid precursor is a nitrile group.8. The biomimetic catalyst of claim 1 , wherein said at least one imprinting molecule is selected from the group consisting of cellobiose claim 1 , hydroxyethyl cellulose claim 1 , Avicel claim 1 , cellulose and beta glucan.9. The ...

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Номер записи: 73
01-10-2015 дата публикации

Cellular porous monoliths containing condensed tannins

Номер: US20150274921A1
Автор: Alain CELZARD, Andrzej SZCZUREK, Antonio Pizzi, Vanessa FIERRO
Принадлежит: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS, UNIVERSITE DE LORRAINE

A method for producing polyHIPE porous monoliths, of the polyHIPE type or in the form of a rigid foam, by hardening solutions of condensed tannins in the presence of oil and/or air or in the presence of a non-water-miscible volatile solvent and/or air. Also disclosed is the use of these materials in the areas of catalysis, chromatography, heat and sound insulation, tissue engineering and medication release and as a floral foam.

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Номер записи: 74
22-09-2016 дата публикации

FUNCTIONAL AIR FILTER

Номер: US20160271598A1
Автор: HAYASHI Yasuhiro, Mukai Kiyotoshi, SANO Masataka
Принадлежит:

Provided is a functional air filter which can maintain a sufficient function of suppressing breeding of mold and undesired bacteria for a long period thus being hygienic, exhibiting high safety and possessing deodorizing property. In a functional air filter which is manufactured by, at intersections between wefts and warps made of a thermoplastic sheath-core type composite monofilament which is a composite fiber consisting of a core material and a sheath material made of a resin having a lower melting point than the core material, heat-fusing the sheath materials to each other, the composite monofilament is configured such that some particles blended into the sheath material are exposed from a surface of the sheath material. The particle is a mixed particle where fine particles are fixedly adhered to a surface of a coarse particle. 1. A functional air filter which is manufactured by , at intersections between wefts and warps made of a thermoplastic sheath-core type composite monofilament which is a composite fiber consisting of a core material and a sheath material made of a resin having a lower melting point than the core material , heat-fusing the sheath materials to each other , whereinthe composite monofilament is configured such that some particles blended into the sheath material are exposed from a surface of the sheath material.2. The functional air filter according to claim 1 , wherein the particle is a mixed particle where fine particles are fixedly adhered to a surface of a coarse particle.3. The functional air filter according to claim 2 , wherein the coarse particle is made of silica claim 2 , alumina claim 2 , zirconia claim 2 , titania or a mixture of the elements claim 2 , and the fine particle is a metal particle made of platinum claim 2 , gold claim 2 , silver claim 2 , copper claim 2 , nickel or stainless steel or a material which is produced by mixing catechin into the metal particle.4. The functional air filter according to claim 1 , wherein the ...

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Номер записи: 75
22-09-2016 дата публикации

Hydrogen Generating System

Номер: US20160272489A1
Автор: CHEN Yunzhong, Han Ming, TANG Ee Ho Gareth, Wang Lei
Принадлежит: TEMASEK POLYTECHNIC

The present invention relates to a solid fuel, a system and a method for generating hydrogen. The solid fuel comprises sodium borohydride, catalyst loaded fibres and a binder, wherein the catalyst loaded fibres and the binder form a scaffold structure within which the sodium borohydride is positioned. The system comprises a fuel cartridge containing the solid fuel of the present invention for generating hydrogen gas, a reactor configured to house the fuel cartridge, a tank for storing water, a pump and a liquid conduit for conveying water from the tank to the fuel cartridge housed within the reactor to induce a hydrolysis reaction of the solid fuel contained in the fuel cartridge and a controller for regulating flow of the water. 1. A solid fuel for generating hydrogen , comprising:sodium borohydride particles, catalyst loaded fibres and a binder, wherein the sodium borohydride particles are loosely disposed within a scaffold structure formed by the catalyst loaded fibres and the binder.2. The solid fuel according to claim 1 , wherein the catalyst loaded fibres comprises carbon fibres claim 1 , glass fibres claim 1 , ceramic fibres or any combinations thereof.3. The solid fuel according to claim 2 , wherein the catalyst loaded fibres comprises carbon fibres.4. The solid fuel according to claim 2 , wherein the catalyst loaded fibres comprises glass fibres.5. The solid fuel according to claim 2 , wherein the catalyst loaded fibres comprises ceramic fibres.6. The solid fuel according to claim 3 , wherein the carbon fibres each having a diameter from 1 to 20 microns.7. The solid fuel according to claim 3 , wherein the carbon fibres each having a length from 20 to 200 microns.8. The solid fuel according to claim 1 , wherein the catalyst loaded fibres comprises a catalyst which is a salt selected from the group consisting of cobalt chloride and nickel chloride claim 1 , or powder of a precious metal selected from the group consisting of platinum claim 1 , iridium and ...

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Номер записи: 76
21-09-2017 дата публикации

HIGH ASPECT RATIO LAYERED DOUBLE HYDROXIDE MATERIALS AND METHODS FOR PREPARATION THEREOF

Номер: US20170267623A1
Автор: Al-Shahrani Abdullah A., Alabedi Gasan Selman, Greenwell Hugh Christopher, Hall John Adrian, Veerabhadrappa Manohara Gudiyor, Whiting Andrew
Принадлежит:

Embodiments are directed to adamantane-intercalated layered double-hydroxide (LDH) particles and the methods of producing adamantane-intercalated LDH particles. The method comprises adding to an aqueous solution a first precursor and a second precursor to form an initial mixture, where the first precursor is Al(OH)or AlO, the second precursor is a hydroxide M(OH)or an oxide MO, where M is a metal of oxidation state +2; and the initial mixture has a M/Al molar ratio of from 1 to 5. The method also comprises adding to the initial mixture an amount of adamantane to form a reaction mixture having an Al/adamantane molar ratio of from 0.5 to 2; and heating the reaction mixture to produce adamantane-intercalated LDH particles, where the adamantane-intercalated LDH particles have aspect ratios greater than 100.

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Номер записи: 77
20-08-2020 дата публикации

HIGH PURITY TRISILYLAMINE, METHODS OF MAKING, AND USE

Номер: US20200262849A1
Автор: KETOLA BARRY M., Maddock Jesse A., REKKEN BRIAN D., Telgenhoff Michael D., Zhou Xiaobing
Принадлежит: Dow Silicones Corporation

A composition, comprising: trisilylamine and less than 5 ppmw of halogen. A method of making a silylamine comprising combining ammonia and a compound comprising aminosilane functionality, where the compound comprising aminosilane functionality is according to formula (I) RN(R)a(SiH)(I), where Ris an organic polymer, a C-hydrocarbyl group or —SiR, where Ris Chydrocarbyl, Ris a C-hydrocarbyl group, H, or -SiR, where Ris as defined above, subscript a is 0 or 1, provided that Rand Rmay be the same or different except if Ris phenyl, Ris not phenyl, under sufficient conditions to cause a reaction to form a silylamine and a byproduct. 1. A composition , comprising: trisilylamine and less than 5 ppmw of halogen.2. A composition as in claim 1 , wherein the composition comprises less than 1 ppmw of halogen.3. A method of making a silylamine claim 1 , the method comprising: combining ammonia and a compound comprising aminosilane functionality claim 1 , where the compound comprising aminosilane functionality is according to formula (I){'br': None, 'sup': 1', '2, 'sub': a', '3', '2−a, 'RN(R)(SiH)\u2003\u2003(I),'}{'sup': 1', '3', '3', '2', '3', '1', '3', '1', '2', '1', '2, 'sub': 1-20', '3', '1-6', '1-20', '3, 'where Ris an organic polymer, a Chydrocarbyl group or —SiR, where Ris Chydrocarbyl, Ris a Chydrocarbyl group, H, or —SiR, where Ris as defined above, subscript a is 0 or 1, provided that Rand Rmay be the same or different except if Ris phenyl, Ris not phenyl,'}under sufficient conditions to cause a reaction to form a silylamine and a byproduct.4. A method according to wherein the product is trisilylamine claim 3 , N(SiH).5. A method as in claim 3 , wherein the sufficient conditions include a temperature from −20° C. to 150° C. and a pressure greater than 102 kPa.6. A method as in claim 5 , wherein the temperature is from 0° C. to 75° C.7. A method as in claim 3 , wherein Ris alkyl and each Ris independently Ror H.8. A method as in claim 7 , wherein Ris branched alkyl ...

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Номер записи: 78
18-12-2014 дата публикации

Catalytic Membranes And Applications Thereof

Номер: US20140371340A1
Автор: Qian Xianghong, ULBRICHT MATHIAS, WICKRAMASINGHE Sumith Ranil, Yang Qian
Принадлежит:

In one aspect, catalytic membranes are described herein. In some embodiments, a catalytic membrane comprises a surface functionalized with a polymer, the polymer comprising cellulose solubilization functionalities and acid functionalities for the catalytic hydrolysis of cellulose and/or hemicellulose. 133-. (canceled)34. A catalytic membrane comprising:a surface functionalized with cellulose solubilization functionalities and acid functionalities for the catalytic hydrolysis of cellulose, wherein the cellulose solubilization functionalities are pendant along a polymer chain attached to the surface and comprise one or more imidazolium salts.37. The catalytic membrane of claim 34 , wherein the acid functionalities have a pKa ranging from about 1 to about 5.38. The catalytic membrane of claim 37 , wherein the acid functionalities comprise sulfonic acid claim 37 , carboxylic acid or phosphonic acid functionalities or mixtures thereof.39. The catalytic membrane of claim 34 , wherein at least one of the cellulose solubilization functionalities is functionalized with at least one of the acid functionalities for the catalytic hydrolysis of cellulose.40. The catalytic membrane of claim 34 , wherein the acid functionalities are pendant along the polymer chain.41. The catalytic membrane of claim 40 , wherein the polymer comprises a block of repeating units comprising the cellulose solubilization functionalities and a block of repeating units comprising the acid functionalities.42. The catalytic membrane of claim 40 , wherein the polymer comprises a random distribution of repeating units comprising the cellulose solubilization functionalities and repeating units comprising the acid functionalities.43. The catalytic membrane of claim 40 , wherein the polymer comprises a statistical distribution of repeating units comprising the cellulose solubilization functionalities and repeating units comprising the acid functionalities.44. The catalytic membrane of claim 40 , wherein the ...

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Номер записи: 79
06-10-2016 дата публикации

CADMIUM SULFIDE QUANTUM DOTS

Номер: US20160288106A1
Автор: Jensen Stephen C., Weiss Emily A.
Принадлежит:

Provided herein are compositions comprising cadmium sulfide quantum dot photocatalysts and methods and systems utilizing as much (e.g., for the reduction of a nitrobenzene to an aniline). 1. A system comprising:(a) a cadmium sulfide (CdS) quantum dot (QD); and(b) a nitrobenzene compound.2. The system of claim 1 , wherein the nitrobenzene compound is selected from the group consisting of: nitrobenzene claim 1 , 4-nitrobenzoic acid claim 1 , methyl 4-nitrobenzoate claim 1 , 1-chloro-4-nitrobenzene claim 1 , 1-fluoro-4-nitrobenzene claim 1 , 4-nitroaniline claim 1 , 1-tertbutyl-4-nitrobenzene claim 1 , 2 claim 1 ,4 claim 1 ,6-tri-tertbutyl-nitrobenzene claim 1 , 1 claim 1 ,3-dimethyl-2-nitrobenzene claim 1 , 1 claim 1 ,3-dimethyl-5-nitrobenzene claim 1 , 2 claim 1 ,4 claim 1 ,6-trinitrotoluene claim 1 , 2 claim 1 ,4-dinitrotoluene claim 1 , 2 claim 1 ,6-dinitrotoluene claim 1 , 2 claim 1 ,3-dinitrotoluene claim 1 , 2 claim 1 ,5-dinitrotoluene claim 1 , 3 claim 1 ,4-dinitrotoluene claim 1 , 3 claim 1 ,5-dinitrotoluene claim 1 , 1 claim 1 ,3 claim 1 ,5-trinitrobenzene claim 1 , 2 claim 1 ,4 claim 1 ,6-trinitrophenol claim 1 , and 2 claim 1 ,4 claim 1 ,6-trinitro-1 claim 1 ,3-benzenediol.2. (canceled)3. The system of claim 1 , further comprising one or more solvents.4. The system of claim 3 , wherein the one or more solvents comprise water and/or methanol.5. (canceled)6. The system of claim 1 , further comprising one or more sacrificial reductants.7. The system of claim 6 , wherein the one or more sacrificial reductants comprise an alcohol claim 6 , a thiol claim 6 , a carboxylate claim 6 , and/or ascorbic acid.8. The system of claim 6 , wherein the one or more sacrificial reductants comprise methanol and/or 3-mercaptopropionic acid.9. The system of claim 1 , further comprising an aniline.10. (canceled)11. The system of claim 9 , wherein the aniline is selected from the group consisting of: aniline claim 9 , 4-aminobenzoic acid claim 9 , methyl 4-aminobenzoate claim 9 , 1 ...

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Номер записи: 80
06-10-2016 дата публикации

PHOTOCATALYST USING REDUCING ORGANIC SUBSTANCE

Номер: US20160288110A1
Автор: Morikawa Claudio Kendi, SHINOHARA Makoto
Принадлежит: NATIONAL RESEARCH AND DEVELOPMENT AGENCY NATIONAL AGRICULTURE AND FOOD RESEARCH ORGANIZATION

A photocatalyst including, as an active component, a reaction product obtained by mixing a reducing organic substance having iron-reducing ability or a feedstock for supplying the reducing organic substance with an iron-supplying source in the presence of water, in which the reaction product exhibits a photocatalytic activity when irradiated with light having a wavelength of ultraviolet light, visible light, or infrared light. An organic substance degradation method or a sterilization method including bringing the photocatalyst into contact with an object to be degraded or an object to be sterilized and irradiating the photocatalyst with light having a wavelength of ultraviolet light, visible light, or infrared light. 1. A photocatalyst comprising , as an active component , a reaction product obtained by mixing a reducing organic substance having iron-reducing ability or a feedstock for supplying the reducing organic substance with an iron-supplying source in the presence of water.2. The photocatalyst according to claim 1 , wherein the reducing organic substance comprises at least one of a polyphenol and ascorbic acid.3. The photocatalyst according to claim 2 , wherein the reducing organic substance comprises a polyphenol claim 2 , said polyphenol comprises:at least one compound selected from the group consisting of chlorogenic acid, caffeic acid, tannic acid, and catechin, orat least one compound which has, in its molecule, at least one compound selected from the group consisting of chlorogenic acid, caffeic acid, tannic acid, and catechin.4. The photocatalyst according to claim 1 , wherein the feedstock for supplying the reducing organic substance comprises at least one plant body selected from the group consisting of a fruit claim 1 , a seed claim 1 , a stem and leaf claim 1 , a bud claim 1 , a flower claim 1 , a root claim 1 , and an underground stem claim 1 , or a processed product of the plant body.5. (canceled)6. The photocatalyst according to claim 1 , ...

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Номер записи: 81
06-10-2016 дата публикации

METHOD FOR CONTINUOUS PRODUCTION OF ALIGNED NANOSTRUCTURES ON A RUNNING SUBSTRATE AND RELATED DEVICE

Номер: US20160289826A1
Автор: Boulanger Pascal, CHARON Emeline, MAYNE Martine, Pinault Mathieu, Reynaud Cécile
Принадлежит: Commissariat A L'Energie Atomique Et Aux Energies Alternatives

The invention relates to a method for continuously manufacturing aligned nanostructures on a running support, which comprises conveying the support through a heated space and synthesising, in this space, aligned nanostructures on the support by catalytic chemical vapour deposition. The heated space is divided into n consecutive zones in the conveying direction of the support (n being an integer ≧2), and the synthesis of the nanostructures results from heating and injection operations, in each of these n zones, of a flux of an aerosol containing a catalytic precursor and a source precursor of the material of the nanostructures to be formed, carried by a carrier gas. The injection operations are made by modifying, in at least two of the n zones, at least one parameter chosen among the flow rate of the carrier gas flux, the chemical composition of the carrier gas, the mass concentration of the catalytic precursor in the catalytic precursor and source precursor mixture. The invention also relates to a device for implementing this method. 1: A method for continuously manufacturing aligned nanostructures on a running support , the method comprisingconveying the support through a heated space in a conveying direction, andsynthesising, in this space, the aligned nanostructures on the support by catalytic chemical vapour deposition,whereinthe heated space is divided into n consecutive zones in the conveying direction of the support, n being an integer higher than or equal to 2,the synthesis of the nanostructures results from heating operations and injection operations, in each of the n zones, of a flux of an aerosol containing a mixture of a catalytic precursor and a source precursor of a material of the nanostructures to be formed, conveyed by a carrier gas, andthe injection operations are made by modifying, in at least two of the n zones, at least one parameter selected from the group consisting of a flow rate of the carrier gas flux, a chemical composition of the carrier ...

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Номер записи: 82
12-09-2019 дата публикации

Condensation reaction and/or addition reaction curable coating composition

Номер: US20190276699A1
Автор: Dagmar Schemschat, Dirk Benning, Hildegund Diekmann, Hubert THEIL, Ignacia Rump, Martin Geuting, Silke Przybilla
Принадлежит: BASF COATINGS GMBH

Provided herein is a coating composition curable by condensation and/or addition reactions and including (A) at least one polymer as binder, (B) at least one crosslinking agent that can be reacted by condensation and/or addition reaction with component (A), and (C) at least one specific complex as catalyst. Also provided herein is a use of the complex for catalyzing the curing of coating compositions curable by condensation and/or addition reaction.

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Номер записи: 83
12-09-2019 дата публикации

OXIDASE ACTIVITY OF POLYMERIC COATED CERIUM OXIDE NANO-PARTICLES

Номер: US20190277841A1
Автор: Asati Atul, Kaittanis Charalambos, Nath Sudip, Perez Jesus Manuel, Santra Santimukul
Принадлежит:

Methods, systems, compositions include biocompatible polymer coated nanoceria that function as aqueous redox catalyst with enhanced activity at an acidic to moderately alkaline pH value between 1 and 8. The compositions are used as oxidizing agents for decomposition, decontamination or inactivation of organic contaminants, such as, pesticides and chemical warfare agents. Another use includes nanoceria as targetable nanocatalyst prepared by conjugating various targeting ligands to the nanoparticle coating to form a colorimetric or fluorescent probe in immunoassays and other molecule binding assays that involve the use of a molecule in solution that changes the color of the solution or emits a fluorescent signal, where localization of nanoceria to organs or tissue is assessed by treatment with an oxidation sensitive dye or other detection devices. Versatility and uses of the nanoceria compositions are controlled by pH value, choice of dye substrate and thickness of the polymer coating on the ceria nanoparticles. 120-. (canceled)21. A method of tuning the oxidase activity of a biocompatible polymer coated ceria nanoparticle comprising:selecting a chromogenic dye substrate for oxidation;preparing an aqueous solution in which the substrate and a plurality of biocompatible polymer coated ceria nanoparticles are contained; andadjusting the pH of the aqueous solution containing the substrate and the plurality of coated ceria nanoparticles to tune the oxidase activity of the coated ceria nanoparticles in at least one of the following pH adjustments, a pH value between 1 and 4 to increase the oxidation rate, a pH value between 5 and 7 to decrease the oxidation rate, and a pH value between 8 and 12 to stop oxidation activity and thereby tuning the oxidase activity of the plurality of coated ceria nanoparticles.22. A method of tuning the oxidase activity of a biocompatible polymer coated ceria nanoparticle comprising:coating ceria nanoparticles using a biocompatible polymer of ...

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Номер записи: 84
13-10-2016 дата публикации

HYDROLYSIS OF AN ESTER COMPOUND

Номер: US20160297734A1
Автор: Bonneviot Laurent, CLACENS Jean-Marc, DECAMPO Floryan, Fan Zhaoyu, FENG Xiaoshuang, MALCOURONNE Guillaume, Zhou Wenjuan
Принадлежит:

The present invention concerns a process to carry out an ester hydrolysis wherein the ester compound (c) is made from at least an alcohol (a) and a carboxylic acid (b), and wherein said alcohol (a) and said carboxylic acid (b) are forming a biphasic liquid system when mixed together; comprising at least a step of producing an ester compound (c)/water emulsion by using as stabilizing species amphiphilic solid particles of nanometric dimension and optionally a catalyst X. 1. A process for carrying out an ester hydrolysis of an ester compound (c) made from at least an alcohol (a) and a carboxylic acid (b) , and wherein said alcohol (a) and said carboxylic acid (b) form a biphasic liquid system when mixed together; the process comprising:a) Producing an ester compound (c)/water emulsion by using amphiphilic solid particles of nanometric dimension as stabilizing species and optionally a catalyst X;b) hydrolyzing the ester compound (c), by setting the temperature, andc) Isolating the resulting compounds.2. The process according to claim 1 , wherein the immiscibility of alcohol (a) and carboxylic acid (b) is defined according to protocol P claim 1 , protocol P comprising:blending alcohol (a) and carboxylic acid (b) together,setting a temperature T, which is 5° C. above the highest of the melting points of alcohol (a) or carboxylic acid (b), under atmospheric pressure,stirring the blend for 5 mins, andsettling for 30 mins.3. The process according to claim 1 , wherein alcohol (a) is a hydrophilic alcohol of formula (I) as follows:{'br': None, 'sup': '1', 'i': 'p', 'R(OH)\u2003\u2003(I)'}{'sup': '1', 'wherein Rrepresents the skeleton moiety of the alcohol, p is an integer ranging from 1 to 20.'}4. The process according to claim 3 , wherein Rrepresents the skeleton moiety of a glycerol and p is 3.5. The process according to claim 1 , wherein alcohol (a) is selected from the group consisting of: ethylene glycol claim 1 , diethylene glycol claim 1 , polyethylene glycol claim 1 , ...

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Номер записи: 85
19-09-2019 дата публикации

HYDROGEN GENERATING SYSTEM

Номер: US20190284046A1
Автор: CHEN Yunzhong, Han Ming, TANG Ee Ho Gareth, Wang Lei
Принадлежит:

The present invention relates to a solid fuel, a system and a method for generating hydrogen. The solid fuel comprises sodium borohydride, catalyst loaded fibres and a binder, wherein the catalyst loaded fibres and the binder form a scaffold structure within which the sodium borohydride is positioned. The system comprises a fuel cartridge containing the solid fuel of the present invention for generating hydrogen gas, a reactor configured to house the fuel cartridge, a tank for storing water, a pump and a liquid conduit for conveying water from the tank to the fuel cartridge housed within the reactor to induce a hydrolysis reaction of the solid fuel contained in the fuel cartridge and a controller for regulating flow of the water. 111.-. (canceled)12. A process for producing a solid fuel for the generation of hydrogen , the process comprising:pre-mixing a catalyst with fibres to obtain a catalyst loaded fibres;mixing the catalyst loaded fibres with sodium borohydride particles to obtain a first mixture;grinding the first mixture;adding a binder to the first mixture to obtain a second mixture;subjecting the second mixture to heat;cooling the heated mixture to obtain the solid fuel wherein the sodium borohydride particles are loosely disposed within a scaffold structure formed by the catalyst loaded fibres and the binder; andwherein the catalyst is selected from the group consisting of cobalt chloride, nickel chloride, chloroplatinic acid and chloroiridic acid or powder of a precious metal selected from the group consisting of platinum, iridium and ruthenium; andwherein the fibres are selected from the group consisting of carbon, glass, ceramic and combinations thereof.13. The process according to claim 12 , wherein pre-mixing the catalyst with fibres comprises:soaking the fibres in a solution containing the catalyst;refluxing the solution containing the fibres for a predetermined period;separating the fibres from the solution; anddrying the fibres to obtain the ...

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Номер записи: 86
29-10-2015 дата публикации

A CATALYST COMPOSITION AND A CATALYTIC PROCESS FOR CONVERSION OF BIOMASS TO CRUDE BIO OIL

Номер: US20150306575A1
Автор: APEGAONKAR Supriya, Bhujade Ramesh, JASRA Raksh, Mandan Chidambaram, Mantri Kshudiram, Sharma Nagesh
Принадлежит: RELIANCE INDUSTRIES LIMITED

The present disclosure provides a catalyst composition for conversion of biomass to crude bio oil. The composition comprises at least one metal compound, at least one support and at least one stabilizing/solubilizing agent. Also disclosed are processes for the preparation of catalyst composition, and hydrothermal conversion of biomass to crude bio oil. 1. A catalyst composition for conversion of biomass to crude bio oil; said composition comprising:i. at least one metal in an amount of 0.1 to 15 wt. %, wherein the metal is selected from the group consisting of group Ib, group IIb metals, group IVb metals, group Vb metals, group VIb metals, group VIIb metals, group VIII metals and noble metals;ii. at least one support in an amount of 30 to 96 wt %; andiii. at least one solubilizing agent in an amount of 4 to 50 wt. %, said solubilizing agent selected from the group consisting of ammonia solution, piperidine, pyrrolidine, morpholine, piperazine hydrate, 2-methylcyclohexyl amine, cyclohexylamine and hexamethyleneimine.2. The catalyst composition as claimed in claim 1 , wherein said support is selected from the group consisting of alumina claim 1 , silica claim 1 , zirconia claim 1 , alumina-silica claim 1 , zeolite and molecular sieves.3. The catalyst composition as claimed in claim 1 , wherein said support comprises a) 30 to 100 wt % at least one carrier selected from the group consisting of alumina claim 1 , silica claim 1 , zirconia claim 1 , alumina-silica claim 1 , zeolite and molecular sieves; b) 0.001 to 70 wt % of at least one binder selected from the group consisting of aluminophosphate claim 1 , psuedoboehmite claim 1 , alumina oxide claim 1 , silica and ludox silica solution.4. The catalyst composition as claimed in claim 1 , wherein said support comprises a) 30 to 100 wt % at least one carrier selected from the group consisting of nano-structured aluminum oxide claim 1 , nano-structured silicon oxide claim 1 , nano-structured zirconium oxide claim 1 , nano- ...

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Номер записи: 87
29-10-2015 дата публикации

HIGH ACTIVITY HYDROTREATING CATALYSTS

Номер: US20150306591A1
Автор: Jia Jifei, Maesen Theodorus Ludovicus Michael, RADLOWSKI Cecelia, SATERNUS Henry, YU Xianghua
Принадлежит:

This disclosure relates to supported multi-metallic catalysts for use in the hydrotreating of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIB metal, at least one Group VIII metal and an organic acid. The catalyst precursor is thermally treated to partially decompose the organic acid, then sulfided. The catalysts have a high carbon-as-carboxyl to total carbon ratio (C/C) as a result of a unique post-metal calcination method employed during the manufacture of the catalyst. As a result, the hydrotreating catalysts have lower percent weight loss-on-ignition, higher activity and longer catalyst life. 2. The catalyst composition of claim 1 , further comprising a phosphorus component.3. The catalyst composition of claim 2 , wherein the phosphorus component is present in an amount of from 1 to 10 wt. % claim 2 , based on the bulk dry weight of the catalyst claim 2 , calculated as PO.4. The catalyst composition of claim 1 , wherein the inorganic catalyst support is selected from the group consisting of alumina claim 1 , silica claim 1 , and alumina-silica.5. The catalyst composition of claim 1 , wherein the metal portion of the partially oxidized metal organic component comprises at least one Group VIB metal and at least one Group VIII metal.6. The catalyst composition of claim 5 , wherein the at least one Group VIB metal is Mo and the at least one Group VIII metal is Ni.7. The catalyst composition of claim 1 , wherein the organic portion of the metal-organic component claim 1 , prior to partial oxidation claim 1 , is a hydroxycarboxylic acid.8. The catalyst composition of claim 7 , wherein the hydroxycarboxylic acid is selected from the group consisting of glycolic acid claim 7 , lactic acid claim 7 , glyceric acid claim 7 , gluconic acid claim 7 , malic acid claim 7 , tartaric acid claim 7 , mucic acid claim 7 , and citric acid.9. The catalyst composition of claim ...

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Номер записи: 88
10-09-2020 дата публикации

Improvements in or relating to organic compounds

Номер: US20200283363A1
Автор: Fridtjof Schroder, Nicole Pfeiffer
Принадлежит: Givaudan SA

An allylic oxidation process includes forming a mixture containing α-Guaiene and an iron (III)-X porphyrin complex catalyst in a sustainable solvent, introducing molecular oxygen into the mixture, and effecting allylic oxidation to produce an α,ß-unsaturated ketone, Rotundone.

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Номер записи: 89
10-09-2020 дата публикации

An improved process for the preparation of trifloxystrobin

Номер: US20200283373A1
Автор: Deepak Babasaheb PHASAGE, Kamlesh Kantilal LODHA, Lakonda Nagaprasada RAO, Sandip Popatrao UDAWANT, Santosh Kumar GHOSH, Sudhir Nambiar
Принадлежит: Hikal Ltd

The present invention relates to an improved process for the preparation of trifloxystrobin of formula (I), which is simple, economical, efficient, user and environment friendly, moreover commercially viable with higher yield and chemical purity.

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Номер записи: 90
26-09-2019 дата публикации

PHOTOCATALYST

Номер: US20190291090A1
Автор: LEUNG Wallace Woon Fong, Pei Chun
Принадлежит:

A photocatalyst includes a composite fiber having at least two crystalline semi-conductors that provide a heterojunction structure in the composite fiber. 115-. (canceled)16. A device for removing a contaminant from a fluid stream , the device comprising a photocatalyst including a composite fiber , whereinthe composite fiber includes at least three n-type crystalline semiconductor materials,the n-type crystalline semiconductor materials form a heterojunction structure in the composite fiber, andthe n-type crystalline semiconductor materials include bismuth oxide, titanium dioxide, and zinc oxide.17. The device of claim 16 , wherein the photocatalyst is activated by light incident on the photocatalyst and selected from the group consisting of ultra-violet light claim 16 , visible light claim 16 , and combinations of ultra-violet light and visible light.18. The device of claim 16 , including a filter located upstream of the photocatalyst in the device.19. The device of claim 16 , wherein the photocatalyst has a pleated configuration.20. The device of claim 16 , wherein the photocatalyst protrudes into the fluid stream from an internal wall of the device.21. A method comprising: the photocatalyst comprises a composite fiber,', 'the composite fiber includes at least three n-type crystalline semiconductor materials,', 'the n-type crystalline semiconductor materials form a heterojunction structure in the composite fiber, and', 'the n-type crystalline semiconductor materials include bismuth oxide, titanium dioxide, and zinc oxide; and, 'placing a device including a photocatalyst adjacent a fluid stream, wherein'}activating the photocatalyst, for photocatalytic reaction, with light incident on the photocatalyst for removing a contaminant from the fluid stream.22. The method of claim 21 , wherein the photocatalyst includes a substrate holding the composite fiber therein.23. The method of claim 21 , wherein the photocatalyst is positioned substantially tangentially with ...

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Номер записи: 91
17-09-2020 дата публикации

COMPOSITIONS OF CERTAIN MANGANESE ACCUMULATING PLANTS

Номер: US20200290032A1
Автор: ESCANDE Vincent, GRISON Claude
Принадлежит:

Compositions of manganese accumulating plants.

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Номер записи: 92
25-10-2018 дата публикации

SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

Номер: US20180304225A1
Автор: Bourke, JR. Frederic A.
Принадлежит: MMUNOLIGHT, LLC

A method and a system for producing a change in a medium. The method places in a vicinity of the medium at least one energy modulation agent. The method applies an initiation energy to the medium. The initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the energy modulation agent. 1. (canceled)2: A system for producing a change in a medium disposed in an artificial container , comprising:a mechanism configured to provide to the medium 1) an activatable agent and 2) at least one energy modulation agent, wherein said energy modulation agent is configured to emit light into the medium upon interaction with an initiation energy; andan initiation energy source configured to apply the initiation energy to the medium, wherein the initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium.3: The system of claim 2 , wherein the energy modulation agent is configured to emit said light at an energy different from the initiation energy.4: The system of claim 2 , wherein:the initiation energy source comprises an external energy source; orthe initiation energy source comprises an energy source that is at least partially in the artificial container holding the medium or that is exposed through an opening in the artificial container; oran external energy source directed to a structural element in which a gap therein was prefilled with the uncured radiation-curable medium to thereby cure the uncured radiation curable medium in the gap; ora directed or focused beam of the initiation energy which cures the uncured radiation curable medium to produce a patterned element.5: The system of claim 2 , wherein the initiation energy source comprises at least one of at least one of an x-ray source claim 2 , a gamma ray source claim 2 , an electron beam ...

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Номер записи: 93
03-11-2016 дата публикации

Functionalized zinc oxide nanoparticles for photocatalytic water splitting

Номер: US20160318010A1
Автор: Leena GEORGE, Radhamonyamma Nandini Devi
Принадлежит: Council of Scientific and Industrial Research CSIR

The present invention relates to a photocatalyst composition having visible light activity for hydrogen production through water splitting. More particularly, the present invention discloses a photocatalyst composition comprising a zinc oxide nanoparticles and a conjugated organic moiety selected from the group consisting of oligothiophenes, azo dyes, and perylenes.

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Номер записи: 94
24-09-2020 дата публикации

CONDENSATION REACTION AND/OR ADDITION REACTION CURABLE COATING COMPOSITION

Номер: US20200299537A9
Автор: Benning Dirk, Diekmann Hildegund, Geuting Martin, Przybilla Silke, Rump Ignacia, Schemschat Dagmar, Theil Hubert
Принадлежит:

Provided herein is a coating composition curable by condensation and/or addition reactions and including (A) at least one polymer as binder, (B) at least one crosslinking agent that can be reacted by condensation and/or addition reaction with component (A), and (C) at least one specific complex as catalyst. Also provided herein is a use of the complex for catalyzing the curing of coating compositions curable by condensation and/or addition reaction. 2. The coating composition as claimed in claim 1 , wherein component (A) comprises (meth)acrylate (co)polymers claim 1 , polyesters claim 1 , alkyds claim 1 , polyurethanes claim 1 , polylactones claim 1 , polycarbonates claim 1 , polyethers claim 1 , epoxy resins claim 1 , epoxy resin-amine adducts claim 1 , polyureas claim 1 , polyamides claim 1 , polyimides claim 1 , polyester-polyurethanes claim 1 , polyether-polyurethanes claim 1 , and/or polyester-polyether-polyurethanes.3. The coating composition as claimed in claim 1 , wherein component (A) comprises hydroxyl and/or carboxyl groups.4. The coating composition as claimed in claim 1 , wherein the at least one crosslinking agent comprises free or blocked polyisocyanates or aminoplast resins.5. The coating composition as claimed in claim 1 , wherein component (A) comprises at least one hydroxyl-group-containing polymer and component (B) comprises at least one blocked isocyanate.6. The coating composition as claimed in claim 1 , wherein metal cation (M) comprises V(III) claim 1 , V(IV) claim 1 , Cr(III) claim 1 , Mn(III) claim 1 , Fe(II) claim 1 , Fe(III) claim 1 , Co(II) claim 1 , Co(III) claim 1 , Ni(II) claim 1 , Cu(II) claim 1 , Bi(III) and/or Zn(II).7. The coating composition as claimed in claim 1 , wherein all radicals Rto Rconsist of hydrogen and optionally carbon.8. The coating composition as claimed in claim 1 , wherein the radical Ris an acyclic radical having 2 to 4 carbon atoms.9. The coating composition as claimed in claim 1 , wherein the radicals Rand ...

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Номер записи: 95
19-11-2015 дата публикации

Ultra-thin Metal Oxide and Carbon-Metal Oxide Films Prepared by Atomic Layer Deposition (ALD)

Номер: US20150329963A1
Автор: Falconer John L., LI JianHua, Liang Xinhua, Weimer Alan W.
Принадлежит:

Ultra-thin porous films are deposited on a substrate in a process that includes laying down an organic polymer, inorganic material or inorganic-organic material via an atomic layer deposition or molecular layer deposition technique, and then treating the resulting film to introduce pores. The films are characterized in having extremely small thicknesses of pores that are typically well less than 50 nm in size.

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Номер записи: 96
01-10-2020 дата публикации

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

Номер: US20200306717A1
Автор: Frederic A. Bourke, Jr., Tuan Vo-Dinh
Принадлежит: Duke University, Immunolight LLC

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

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Номер записи: 97
24-10-2019 дата публикации

GREEN METHODS FOR PREPARING HIGHLY CO2 SELECTIVE AND H2S TOLERANT METAL ORGANIC FRAMEWORKS

Номер: US20190322690A1
Автор: BELMABKHOUT Youssef, Eddaoudi Mohamed, SHEKHAH Osama
Принадлежит:

A green route for preparing a metal organic framework include mixing metal precursor with a ligand precursor to form a solvent-free mixture; adding droplets of water to the mixture; heating the mixture at a first temperature after adding the water; and isolating the metal organic framework material including the metal and the ligand. 1. A method of preparing a metal organic framework , comprising:grinding a metal node precursor with a ligand precursor to form a mixture of precursors;wetting the mixture of precursors with one or more drops of water; andheating the wetted mixture to an activation temperature to obtain a metal organic framework.2. The method of claim 1 , wherein metal node precursor includes a metal selected from the group consisting of Ni claim 1 , Cu claim 1 , Zn claim 1 , Fe claim 1 , or Co.3. The method of claim 1 , wherein the metal node precursor includes M-SiF claim 1 , wherein M includes a metal selected from the group consisting of Ni claim 1 , Cu claim 1 , Zn claim 1 , Fe claim 1 , or Co.4. The method of claim 1 , wherein the ligand precursor includes pyridine claim 1 , 4 claim 1 ,4′-Bipyridin claim 1 , pyrazine claim 1 , pyrimidine claim 1 , pyridazine claim 1 , triazine claim 1 , thiazole claim 1 , oxazole claim 1 , pyrrole claim 1 , imidazole claim 1 , pyrazole claim 1 , triazole claim 1 , oxadiazole claim 1 , thiadiazole claim 1 , quinoline claim 1 , benzoxazole claim 1 , benzimidazole claim 1 , 1 claim 1 ,4-Diazabicyclo[2.2.2]octane claim 1 , or 1 claim 1 ,2-bis(4-pyridyl)acetylene.5. The method of claim 1 , wherein the ligand precursor is present in stoichiometric excess of the metal node precursor.6. The method of claim 1 , wherein the activation temperature includes temperatures up to about 45° C.7. The method of claim 1 , wherein the activation temperature includes temperatures up to about 120° C.8. The method of claim 1 , wherein the metal organic framework is a two-dimensional metal organic framework.9. The method of claim 1 , ...

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Номер записи: 98
10-12-2015 дата публикации

MULTI-LIGAND METAL COMPLEXES AND METHODS OF USING SAME TO PERFORM OXIDATIVE CATALYTIC PRETREATMENT OF LIGNOCELLULOSIC BIOMASS

Номер: US20150352540A1
Автор: Bansal Namita, Bhalla Aditya, Hegg Eric L., Hodge David B., Li Zhenglun, Mathrubootham Vaidyanathan
Принадлежит:

A homogeneous catalyst is provided comprising one or more metals; and at least two metal coordinating ligands wherein the homogeneous catalyst is a multi-ligand metal complex_adapted for use with an oxidant in an oxidation reaction to catalytically pretreat lignocellulosic biomass. In one embodiment, the homogenous catalyst is copper (II) 2,2′ bipyridine ethylenediamine (Cu(bpy)en). Related methods are also disclosed. 1. A homogeneous catalyst comprising:one or more metals; andat least two metal coordinating ligands, wherein the homogeneous catalyst is a multi-ligand metal complex adapted for use with an oxidant in an oxidation reaction to catalytically pretreat lignocellulosic biomass.2. The homogeneous catalyst of wherein the multi-ligand metal complex is a multi-ligand copper complex.3. The homogeneous catalyst of wherein said metals capable of interacting with the multi-ligand metal complex are selected from aluminum claim 2 , zinc claim 2 , nickel claim 2 , magnesium and combinations thereof.4. The homogenous catalyst of wherein said metals are selected from Fe(II) claim 3 , Fe(III)) claim 3 , Cu(I) claim 3 , Cu(II) claim 3 , Co(III) claim 3 , Co(VI)) claim 3 , V(II) claim 3 , V(III) claim 3 , V(IV) claim 3 , V(V) and combinations thereof.5. The homogeneous catalyst of wherein the metal coordinating ligand is selected from pyridine claim 1 , 1 claim 1 ,10-phenanthroline claim 1 , ethylenediamene claim 1 , histidine claim 1 , glycine and combinations thereof.6. The homogeneous catalyst of comprising copper (II) 2 claim 1 ,2′ bipyridine ethylenediamine (Cu(bpy)en).7. The homogeneous catalyst of wherein the oxidant is selected from air claim 1 , oxygen claim 1 , hydrogen peroxide claim 1 , persulfate claim 1 , percarbonate and sodium peroxide and/or ozone.8. The homogenous catalyst of wherein the lignocellulosic biomass contains more than trace amounts of at least one transition metal.9. The homogenous catalyst of wherein the transition metal is selected from iron ...

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Номер записи: 99
10-12-2015 дата публикации

Catalyst Composition With Increased Bulk Active Site Accessibility For The Catalytic Thermoconversion Of Biomass To Liquid Fuels And Chemicals And For Upgrading Bio-Oils

Номер: US20150352541A1
Автор: Dennis Stamires, Michael Brady
Принадлежит: Kior Inc

Processes for making a catalytic system and catalytic systems for converting solid biomass into fuel or specialty chemical products, or for upgrading bio-oils are described. The catalyst system may comprise a non-zeolitic matrix with a hierarchical pore structure ranging from 300 to about 10 4 Angstrom pore size, a zeolite, such as MFI-type or IM-5 zeolite, and a binder.

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Номер записи: 100