ИСПОЛЬЗОВАНИЕ МЕДНЫХ КАТАЛИЗАТОРОВ НА МЕТАЛЛИЧЕСКИХ НОСИТЕЛЯХ ДЛЯ РИФОРМИНГА СПИРТОВ

Изобретение относится к дегидрированию или риформингу спиртов, в частности к способу дегидрирования первичного спирта, такого как метанол или этанол, для получения водорода, в частности для использования в топливном элементе с целью получения электрической энергии. В способе дегидрирования используют медьсодержащий катализатор, включающий в себя металлический носитель, при этом такой катализатор обладает повышенной активностью в газофазном риформинге первичных спиртов, также являются более устойчивыми и особенно активными для термического разложения этанола на водород, метан, монооксид углерода и диоксид углерода при умеренной температуре. Для решения поставленной задачи способ включает приведение в контакт исходной сырьевой смеси газов, содержащей спирт, с катализатором риформинга, чтобы получить смесь продуктов риформинга, содержащую водород, причем катализатор риформинга содержит металлический губчатый носитель и покрытие на меди, по меньшей мере, частично покрывающее поверхность данного ...

СПОСОБ ИЗГОТОВЛЕНИЯ ГРАНУЛ, ГРАНУЛА, ЗАГРУЗКА КАТАЛИЗАТОРОВ

Настоящее изобретение относится к способу изготовления гранул, к грануле, а также к наполнителю катализатора и к статичному смесителю с большим количеством гранул. Способ изготовления гранулы (10) для катализатора и/или статичного смесителя включает технологические этапы: нарезку и/или деформирование, по меньшей мере, слоя (12) металлического вспененного материала (14) до формы гранулы, причем металлический вспененный материал (14) имеет поры (26) с диаметром от 10 мкм до 10000 мкм, причем гранула имеет объём от 0,8 мм3до 30 см3и пористость 70% или более. Гранула (10) для катализатора или статичного смесителя, получаемая способом, содержит, по меньшей мере, слой (12) металлической пены (24). Способ изготовления гранул обеспечивает возможность целенаправленной оптимизации и регулирования гидромеханики в реакторах или колоннах, что оптимизирует в реакторе или колонне теплопередачу и транспорт масс, а также потерю давления. 4 н. и 11 з.п. ф-лы, 1 табл., 22 ил., 5 пр.

СПОСОБ ПОЛУЧЕНИЯ ДИОЛА

Изобретение относится к способу получения диола, в котором в качестве исходных материалов используют водный раствор сахара и водород, которые приводят в контакт с катализатором в воде в реакционной системе с получением диола. Используемым катализатором является композитный катализатор, состоящий из основного катализатора и сокатализатора. Основной катализатор представляет собой нерастворимый в воде кислотостойкий сплав, состоящий из никеля, одного или нескольких редкоземельных элементов, олова и алюминия, и необязательно (i) вольфрама, или (ii) вольфрама и молибдена, или (iii) вольфрама, молибдена и бора или фосфора. Сокатализатор представляет собой растворимую соль вольфрамовой кислоты и/или нерастворимое соединение вольфрам. Диол представляет собой этиленгликоль, и pH реакционной системы составляет 1–7. Технический результат - применение кислотостойкого недорогого и стабильного сплава, который не требует носителя, в качестве основного катализатора, и он может гарантировать высокий выход ...

КАТАЛИЗАТОР НА НОСИТЕЛЕ, ЕГО АКТИВИРОВАННАЯ ФОРМА И ИХ ПОЛУЧЕНИЕ И ПРИМЕНЕНИЕ

... 1. Катализатор на носителе, содержащий: органический полимерный материал-носитель и частицы сплава Ренея, поддерживаемые на органическом полимерном материале-носителе, где по существу все частицы сплава Ренея являются частично заделанными в органический полимерный материал-носитель.2. Катализатор по п. 1, где этот сплав Ренея содержит по меньшей мере один металл Ренея и по меньшей мере один способный выщелачиваться элемент.3. Катализатор по п. 2, где по меньшей мере один металл Ренея выбран из никеля, кобальта, меди и железа, и по меньшей мере один способный выщелачиваться элемент выбран из алюминия, цинка и кремния.4. Катализатор по п. 2, где массовое отношение металла Ренея к способному выщелачиваться элементу в сплаве Ренея составляет от 1:99 до 10:1.5. Катализатор по п. 4, где массовое отношение металла Ренея к способному выщелачиваться элементу в сплаве Ренея составляет от 1:10 до 4:1.6. Катализатор по п. 2, где сплав Ренея дополнительно содержит по меньшей мере один промотор, выбранный ...

СПОСОБ УДАЛЕНИЯ ОСТАТОЧНОГО АЛЮМИНИЯ ИЗ СКЕЛЕТНОГО НИКЕЛЕВОГО КАТАЛИЗАТОРА

Изобретение относится к химической промышленности, к способам получения и применения скелетных катализаторов на основе никеля в реакциях восстановления основных классов промышленно важных органических соединений: получении капролактама, анилина, спиртов и жиров. Способ заключается в циклической обработке гидрируемым соединением в водном растворе гидроксида натрия 25%, в среде водорода при температуре 55-65°С. При этом скелетный никелевый катализатор помещают в реактор гидрогенизации в растворе гидроксида натрия, при соотношении и объема катализатора (см) при ρ=4,5 г/см, объема щелочи (см) при ω=25%, объема реактора (см) - (1,1-3,3):(50-150):(300-400); герметизируют реактор; насыщают атмосферу водородом; вводят в избытке гидрируемое соединение (в качестве которого используют, например, или малеат натрия, или пропен-2-ол-1, или пероксид водорода), в количестве, достаточном для присоединения водорода на каждом грамме катализатора, - V/m- 20-60 см/г; перемешивают при частоте вращения 1500-3500 ...

СПОСОБ ПОЛУЧЕНИЯ (1R,2R)-3-(3-ДИМЕТИЛАМИНО-1-ЭТИЛ-2-МЕТИЛ-ПРОПИЛ)-ФЕНОЛА

... 1. Способ получения (1R,2R)-3-(3-диметиламино-1-этил-2-метил-пропил)-фенола или его соли присоединения кислоты, который включает стадию ! (а) взаимодействие соединения общей формулы (I), ! ! где R представляет собой -C1-6-алкил, -C3-8-циклоалкил, -C1-3-алкилен-фенил, -C1-3-алкилен-нафтил, тетрагидропиранил или -C(=O)-C1-6-алкил, ! с этилмагний галогенидом в инертной реакционной среде в условиях Гриньяра, ! (б) перенос таким образом полученного соединения общей формулы (II), ! ! где R имеет значение, указанное выше, ! на соединение общей формулы (III), ! ! где R имеет значение, указанное выше, ! необязательно в форме соли присоединения кислоты, ! (в) снятие защиты с полученного таким образом соединения общей формулы (III) с образованием (1R,2R)-3-(3-диметиламино-1-этил-2-метил-пропил)-фенола формулы (IV), ! ! (г) необязательно превращение таким образом полученного (1R, 2R)-3-(3-диметиламино-1-этил-2-метил-пропил)-фенола в соль присоединения кислоты. ! 2. Способ по п.1, отличающийся тем, ...

VERFAHREN ZUR HERSTELLUNG EINES KATALYSATORS FÜR DIE HYDRIERUNG VON NITRILEN IN AMINEN UND VERWENDUNG DIESES KATALYSATORS IN DER HYDRIERUNG

HERSTELLUNG VON METALLEN UND LEGIERUNGEN UNTER VERWENDUNG VON AUS EINEM KOHLENSTOFFHALTIGEN GAS ERZEUGTEM FESTEM KOHLENSTOFF

Verfahren zur Inertisierung eines sauerstoffempfindlichen Katalysators

Die Erfindung betrifft ein Verfahren zur Inertisierung eines sauerstoffempfindlichen heterogenen Katalysators (s-Kat) gegen Sauerstoff sowie einen gegenüber Sauerstoff unempfindlichen heterogenen Katalysator. Die Oberfläche des s-Kat wird mit einer ionischen Flüssigkeit benetzt. Die fest auf der Katalysatoroberfläche haftende ionische Flüssigkeit bildet einen Film, der den s-Kat vor Reaktionen mit Sauerstoff schützt.

HYDROGENIERUNG VON LANGKETTIGEN OLEFINISCHEN OELEN MIT EINEM RANEY-KATALYSATOR.

Hydrogenation of benzene to cyclohexane

... 570,843. Catalytic hydrogenation. IMPERIAL CHEMICAL INDUSTRIES, Ltd. April 12, 1943, No. 5857. Convention date, April 11, 1942. [Class 1 (i)] A nickel aluminium alloy hydrogenation catalyst is activated by the removal of a portion (e.g., 25 per cent.) of the aluminium content, and when the calayst has lost its activity in use this is restored by the removal of a further portion of the aluminium. The extraction is preferably effected in the reaction vessel by passing dilute caustic soda through the catalyst. The invention is particularly applicable to the conversion of benzene to cyclohexane.

Hydrogenation and dehydrogenation catalysts

A metal hydrogenation or dehydrogenation catalyst which is capable of adsorbing hydrogen but which does not contain reactive hydrogen is produced by treating the catalyst with a substance capable of chemical reaction with reactive hydrogen. Examples relate to treatment of Raney nickel in powder and electrode form with nitrobenzene and with hydrogen peroxide. Other suitable oxidizing substances are salts of hydrogen peroxide, alkali nitrates, permanganates and chlorates, inorganic and organic peroxydiphosphates and peroxydisulphates. A plurality of electrically connected metal electrodes may be treated simultaneously in a tank containing the oxidising substance. A partial vacuum may be maintained over the treating liquid.

Continuous hydrogenation of cyclopentadiene

There is disclosed a process for the preparation of cyclopentene from cyclopentadiene which comprises selectively hydrogenating cyclopentadiene in the liquid phase by continuously contacting cyclopentadiene with hydrogen while passing the mixture of hydrogen and cyclopentadiene through a highly dispersed form of nickel catalyst which nickel has been treated with ammonia.

ATTAINED A DOCTORATE POROUS CATALYST

PROCEDURE FOR REMOVING FROM SULFUR FROM LIQUID HYDROCARBONS

METHOD FOR PRODUCING [...]17BETALACTONEN OF 14BETA-

PROCEDURE FOR the PRODUCTION OF 17BETA LACTONEN OF 14BETA-HYDROXYSTEROIDEN

Porous catalyst body, in particular gas diffusion electrode, and procedure for its production

Procedure for the production of a porous, metal of containing sintered compact for the use as catalyst

PREPARATION OF 2-(2,2-DICYCLOHEXYLETHYL)PIPERIDINE

HYDROGENATION OF TRIGLYCERIDE VEGETABLE OILS IN PRESENCE OF RANEY CATALYST AND NICKEL ALLOY

PREPARATION OF CATALYSTS FROM BINARY ALLOYS

PRODUCTION OF AROMATIC DIAMINO COMPOUNDS USING A MODIFIED RANEY CATALYST

PRODUCTION OF AROMATIC DIAMINO COMPOUNDS USING A MODIFIED RANEY CATALYST Aromatic diamino compounds are produced by hydrogenating the corresponding dinitro compounds in the presence of a modified Raney catalyst. The modified Raney catalyst is obtained by treating an alloy made up of 50-95 wt % of aluminum, 4-45 wt % nickel and/or cobalt and 1-46 wt % of at least one modifying metal with an alkali material. The modifying metal is selected from the metals of the first, fourth, fifth, sixth, seventh and eighth subgroups of the Periodic Table of Elements. The hydrogenation is preferably carried out at from 170 to 250.degree.C and a pressure of 15-50 bar. The heat generated during hydrogenation is preferably used to produce steam.

PROCESS FOR PREPARING BUTANEDIOL OF HIGH QUALITY

This invention relates to an improved catalytic hydrogenation process for preparing butanediol from butynediol. More particularly, it is concerned with the first stage of a two stage process for obtaining butanediol of high quality using as a catalyst Raney nickel having a molybdenum compound adsorbed on the nickel.

METHOD FOR PRODUCING A PELLET, PELLET, CATALYST CHARGE, AND STATIC MIXER

The invention relates to a method for producing a pellet, in particular for a catalytic converter and/or static mixer. The method comprises a trimming and/or deforming of at least one layer of metal foam material into a pellet shape.

METHODS FOR THE VALORIZATION OF CARBOHYDRATES

There are provided methods for the valorization of carbohydrates. The methods comprise reacting a fluid comprising at least one carbohydrate with at least one metal catalyst or at least one metal catalytic system in a fluidized bed reactor so as to obtain at least one organic acid or a derivative thereof.

REGENERATION OF CATALYST FOR HYDROGENATION OF SUGARS

A process for regenerating catalysts that have been deactivated or poisoned during hydrogenation of biomass, sugars and polysaccharides is described, in which polymerized species that have agglomerated to catalyst surfaces can be removed by means of washing the catalyst with hot water at subcritical temperatures. A feature of the process regenerates the catalysts in situ, which allows the process to be adapted for used in continuous throughput reactor systems. Also described is a continuous hydrogenation process that incorporated the present regeneration process.

Procédé de réduction de produits à fonction carbonyle en produits à fonction alcoolique

Verfahren zum Aktivieren von körnigen Nickel-Aluminium-Katalysatoren

Verfahren zum Stabilisieren von Hydrierungskatalysatoren

Catalyseur d'hydrogénation et procédé de préparation de ce catalyseur

Doppelskelett-Katalysatorelektrode, insbesondere zum Einsatz in galvanischen Brennstoffelementen

Verfahren zur Herstellung von selektiv wirkenden Raney-Nickel-Hydrierkatalysatoren für die Herstellung von Wasserstoffperoxyd

Mono-isopropylamine made from acetone or - isopropylalcohol using modified raney ni cat

Catalyst is made by treating Ni/Al alloy with alkaline solution. A solution of a salt of an alkaline earth metal (pref. MgCl2) is added to the catalyst after decanting so that an alkaline earth metal hydroxide is formed in situ on the surface of the catalyst when it is dried. To carry out the reaction the feedstock, an amide forming agent (pref. NH3), and a gas which contains at least 50% by vol. H2 (pref. synthesis gas) in ratio 1:2 to 4:8 to 20 are passed over the catalyst. Suitable reaction conditions are 0.1 to 3.0 (pref. 0.6 to 2.0) 1/1/h at 120 degrees C - 200 degrees C and 36 to 70 atmos heres. The reaction is particularly selective, gives high yields, and the catalyst has a long life.

Poröser Katalysator für chemische und elektrochemische Reaktionen

Verfahren zur Aktivierung von Katalysatoren

Binary nickel alloy catalysts

Catalysts according to 715, 763 in which the secondary metal is chosen from Si, In and Ta, being present respectively as 6.4%, 5.0% and 5-10% the successive phase changes being substantially as indicated in the parent patent.

Verfahren zur Herstellung von aromatischen Aminen

Poröser Katalysatorkörper, insbesondere Gas-Diffusionselektrode für elektrochemische Zellen

Verwendung von Raney-Nickel zur Gewinnung von Wasserstoff

Verfahren zur Herstellung einer Platte, welche mindestens teilweise aus Raney-Metall besteht

Verfahren zu der Herstellung von a-Amino-w-lactamen

Procédé de préparation de catalyseurs en alliages binaires à base de nickel, ainsi que produits obtenus

Process for the stereoselective hydrogenation of cyclic compounds

The process of hydrogenation by means of elemental gaseous hydrogen in the presence of a hydrogenation catalyst applies to any cyclic compound possessing nonaromatic unsaturation, having a hydroxyl substituent at an asymmetric centre of the ring, and a carbon-carbon double bond which, after saturation by hydrogen, gives rise to an additional asymmetric centre in the ring. A stereoselective hydrogenation is produced which consists in the increased ease with which the H2 atom can approach the ring from the side where the -OH group is situated when working in the presence of a nickel catalyst whose active surface has, to a substantial degree, been deactivated by treatment with a modifier. The process applies, for example, to the preparation of d-isomenthol from d-trans-piperitol.

PROCEDURE FOR the PRODUCTION OF 2 (2,2-DICYCLOHEXYLAETHYL) - PIPERIDIN, AND/OR ITS SALTS.

PROCEDURE FOR THE PRODUCTION OF A RANEY NICKEL IRON CATALYST WITH HIGH EISENGEHALT.

PROCEDURE FOR THE PRODUCTION OF OPTICALLY ACTIVE ONE BETA METHYLCHOLIN.

СПОСОБ ПРОИЗВОДСТВА КАТАЛИЗАТОРА ДЛЯ ПОЛУЧЕНИЯ УГЛЕРОДНЫХ НАНОВОЛОКОН

Настоящее изобретение относится к способу производства катализатора для получения углеродных нановолокон путем приведения углеродных нановолокон, содержащих остатки металлического катализатора, в контакт с моноксидом углерода с образованием при этом карбонила металла и приведение указанного карбонила металла в контакт с твердыми пористыми частицами материала носителя катализатора.

PROCESS FOR THE DECOMPOSITION OF AMMONIA

Process of catalyst activation consisted granular alloys nickelaluminium

NEW LINEAR MANUFACTORING PROCESS Of OLEFIN STARTING FROM FATTY-ACID OR ESTER Of FATTY-ACID SATURATES

Process for the preparation of a catalyst and its reactivation

Process of activation of a catalyst

CATALYTIC METHOD FOR HYDROGENATING NITRO-COMPOUNDS

Process for the manufacture of catalysts for chemical reactions and electrochemical, as well as the products in conformity with those obtained by this process or similar process

electrode of catalysis to double framework

Improvements with catalysts

PROCEDE DE PREPARATION D'ORTHOTRIFLUOROMETHYLANILINE

LA PRESENTE INVENTION A POUR OBJET UN PROCEDE DE PREPARATION DE L'ORTHOTRIFLUOROMETHYLANILINE. SELON CE PROCEDE, DANS UNE PREMIERE ETAPE, ON FAIT REAGIR DU TRIFLUOROMETHYLBENZENE AVEC DU CHLORE GAZEUX EN PRESENCE D'UN CATALYSEUR DE CHLORATION JUSQU'A CONSOMMATION D'AU MOINS 90 DU TRIFLUOROMETHYLBENZENE, DANS UNE DEUXIEME ETAPE, ON EFFECTUE LA NITRATION DU MELANGE BRUT RESULTANT PAR ACTION D'UN MELANGE ACIDE SULFURIQUE-ACIDE NITRIQUE JUSQU'A DISPARITION DES CHLOROTRIFLUOROMETHYLBENZENES FORMES LORS DE LA PREMIERE ETAPE, DANS UNE TROISIEME ETAPE, APRES DECANTATION ET LAVAGE DE LA PHASE ORGANIQUE, ON SOUMET CETTE DERNIERE A UNE PREMIERE HYDROGENATION SOUS PRESSION EN PRESENCE D'UN CATALYSEUR D'HYDROGENATION CONSTITUE PAR DU NICKEL RANEY ETOU NICKEL RANEY DOPE AU CHROME EN MILIEU SOLVANT ORGANIQUE JUSQU'A DISPARITION COMPLETE DES NITROCHLOROTRIFLUOROMETHYLBENZENES, PUIS A UNE DEUXIEME HYDROGENATION EN PRESENCE D'UNE QUANTITE SUPPLEMENTAIRE DE NICKEL RANEY ET D'AU MOINS UNE BASE ALCALINE ET ...

COMPOSITE CATALYST AND PREPARATION METHOD THEREFOR

본 발명은 연속상으로서 탄소 및 분산상으로서 레이니(Raney) 합금 입자를 포함하는 복합 촉매를 개시하고 있다. 레이니 합금 입자는 연속상인 탄소 내에서 균일 또는 불균일하게 분산되며, 연속상 내 탄소는 하나 이상의 탄화성 유기 성분을 탄화시킴으로써 수득된다. 본 촉매는 양호한 입자 강도, 높은 촉매 활성 및 양호한 선택성을 가진다.

Process for the manufacture of primary diamines

The present invention relates to a process for the manufacture of a primary diamine by hydrogenation of a dinitrile compound in the presence of a catalyst. It relates more particularly to a process for the manufacture of hexamethylenediamine by hydrogenation of adiponitrile. The process consists in recovering the diamine formed by distillation in several distillation columns mounted in series and comprising separating the heavy impurities from the second distillation.

Activated Base Metal Catalysts

Nitro-compounds are hydrogenated with an activated Ni catalyst that has an average particle size (APS) less than 25 m and is doped with one or more elements from the list of Mg, Ce, Ti, V, Nb, Cr, W, Mn, Re, Fe, Ru, Co, Rh, Ir, Pt, Cu, Ag, Au and Bi via its/their addition to the alloy before activation and/or doped with one or more elements from the list of Mg, Ce, Ti, V, Nb, Cr, W, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Cu, Ag, Au and Bi by their adsorption onto the surface of the activated catalyst. This invention also includes the hydrogenation of nitro-compounds with an activated Ni catalyst that has and APS less than 20 m and is doped with one or more elements from the list of Mg, Ce, Ti, V, Nb, Cr, W, Mn, Re, Fe, Ru, Co, Rh, Tr, Pt, Pd, Mo, Cu, Ag, Au and Bi via its/their addition to the alloy before activation and/or doped with one or more elements from the list of Mg, Ce, Ti, V, Nb, Cr, W, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Cu, Pd, Pt, Mo, Ag, Au and Bi by their adsorption onto the surface ...

Raney catalyst, process for producing it and process for producing a sugar-alcohol using the same

To obtain a Raney catalyst for fixed bed permitting a continuous use with a high initial activity and to produce a high purity sugar-alcohol at a low cost using the same. For this object, sugar-alcohol is produced by: using the powder type Raney catalyst made by using for the hydrogenation under the hydrogen pressure a lump form Raney catalyst made by (i) the first step for melting nickel and aluminum, (ii) the second step for obtaining quenched lump alloy by quenching droplets of said melted mixture and (iii) the third step for classifying and activating said quenched lump alloy as it is or once it is broken, collecting said lump form Raney catalyst, crushing into powder and reactivating, and hydrogenating sugars under the hydrogen pressure.

METHOD OF PLATING METAL UNIFORMLY ON AND THROUGHOUT POROUS STRUCTURES

Process for the production of a hydrogenation catalyst

A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.

HIGHLY TURBULENT QUENCH CHAMBER

An apparatus for cooling a reactive mixture, comprising: a reactor configured to form the reactive mixture; a quench chamber comprising a frusto-conical body having a wide end, a narrow end, and a quench region formed between the wide and narrow end, wherein the quench chamber is configured to receive the reactive mixture from the plasma reactor through a reactive mixture inlet into the quench region, to receive a conditioning fluid through at least one fluid inlet, and to flow the conditioning fluid into the quench region, wherein the frusto-conical body is configured to produce a turbulent flow within the quench region with the flow of the conditioning fluid into the quench region, thereby promoting the quenching of the reactive mixture to form a cooled gas-particle mixture; and a suction generator configured to force the cooled gas-particle mixture out of the quench chamber.

HIGHLY TURBULENT QUENCH CHAMBER

Process for sulfur removal from hydrocarbon liquids

The present invention is directed to a method of desulfurization of a sulfur laden hydrocarbon liquid that comprises contacting the liquid with a sponge nickel metal alloy, removing the sulfur free liquid, regeneration of the alloy by contact with an aqueous solution of an oxidant and reusing the alloy for further desulfurization of additional sulfur laden liquid.

PRODUCTION METHOD FOR CAMPTOTHECIN DERIVATIVE

The invention offers a method of hydrogenating camptothecin in inert solvent in the presence of nickel catalyst, whereby selective hydrogenation of camptothecin can be very efficiently accomplished using the low-cost catalyst.

METHOD OF REDUCING EPOXIDIZED ORGANIC COMPOUND WITH HYDROGEN

In reduction of an epoxy group-containing organic compound, for example, a C5-C20 saturated or unsaturated epoxy cycloaliphatic compound, in the presence of a nickel catalyst, by bringing the compound into contact with hydrogen, the target compound can be produced at a high yield by adding a basic substance (for example, an alkali metal hydroxide, an alkali metal carbonate, an alkali metal alkoxide, and an amine compound having 1 to 3 C1-C12 alkyl groups), to the reduction reaction system, to thereby restrict production of by-products due to a side deoxidation reaction.

Process for the selective preparation of fluorinated aromatic amines and fluorinated aromatic amines with particularly low contents of defluorinated portions

Process for the preparation of linear olefins from fatty acids or esters of saturated fatty acids

A linear olefin is manufactured by contacting a fatty acid or ester with a catalyst comprising nickel and at least one metal from the group consisting of tin, germanium and lead at 200 DEG -400 DEG C.

СПОСОБ ПОЛУЧЕНИЯ ПЕРВИЧНЫХ ДИАМИНОВ

Изобретение относится к улучшенному способу производства первичных алифатических диаминов, таких как гексаметилендиамин, гидрированием динитрильного соединения, такого как адипонитрил, в присутствии катализатора гидрирования. Способ включает гидрирование динитрильного соединения с помощью водорода или газа, содержащего водород, в несколько стадий: проведение первой дистилляции потока Е0, выходящего из среды гидрирования, для выделения головной фракции Е1, содержащей воду и присутствующие в среде имины, и хвостовой фракции Q1, содержащей гидрированные соединения; проведение второй дистилляции потока Q1 для выделения головной фракции E2, содержащей гидрированные соединения, и хвостовой фракции Q2, содержащей соединения с более высокой температурой кипения, чем температура кипения первичного диамина; проведение третьей дистилляции головной фракции E2 для выделения хвостовой фракции Q3, содержащей гидрированные соединения, и головной фракции Е3, содержащей соединения с температурой кипения ...

СПОСОБ ПОЛУЧЕНИЯ (1R,2R)-3-(3-ДИМЕТИЛАМИНО-1-ЭТИЛ-2-МЕТИЛ-ПРОПИЛ)-ФЕНОЛА

FIELD: chemistry. SUBSTANCE: invention relates to an improved method of producing (1R,2R)-3-(3-dimethylamino-1-ethyl-2-methyl-propyl)-phenol or acid addition salt thereof. The method involves reaction of a compound of formula (V): , where R is -C 1-6 -alkyl, -C 3-8 -cycloalkyl, -C 1-3 -alkylene-phenyl, -C 1-3 -alkylene-naphthyl, tetrahydropyranyl or -C(=O)-C 1-6 -alkyl, with dimethylamine hydrochloride and paraformaldehyde in an inert reaction medium in Mannich conditions to obtain a compound of formula (VI): , separating the compound of formula (VI) by reaction with a chiral acid, and subsequent reaction with ethylmagnesium halide in an inert reaction medium in Grignard conditions to obtain a compound of formula (II): . Further, the compound of formula (II) undergoes dehydration and hydrogenation in the presence of a catalyst and hydrogen to obtain a compound of formula (III): , and protection is removed from the compound of formula (III) to obtain (1R,2R)-3-(3-dimethylamino-1-ethyl-2-methyl-propyl)-phenol. EFFECT: method enables to obtain a product with high output and high purity. 8 cl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 466 124 (13) C2 (51) МПК C07C 213/00 C07C 215/54 (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2009105817/04, 23.07.2007 (24) Дата начала отсчета срока действия патента: 23.07.2007 R U Приоритет(ы): (30) Конвенционный приоритет: 24.07.2006 EP 06015338.4 (72) Автор(ы): ХЕЛЛЬ Вольфганг (DE), ЦИММЕР Освальд (DE), БУШМАНН Хельмут Генрих (ES), ХОЛЕНЦ Йёрг (SE), ГЛАДОВ Штефан (CH) (73) Патентообладатель(и): ГРЮНЕНТАЛЬ ГМБХ (DE) (43) Дата публикации заявки: 27.08.2010 Бюл. № 24 (56) Список документов, цитированных в отчете о поиске: RU 2150465 С1, 10.06.2000. DD 124521 A1, 02.03.1977. WO 2004108658 A1, 16.12.2004. ЕР 0799819 А1, 08.10.1997. SU 446963 A3, 15.10.1974. KAMETANI T. et al. Synthesis of analgesics. XXVIII. Synthesis of 4-amino-3methyl-1, 2-diphenyl-2- ...

КАТАЛИЗАТОР ГИДРИРОВАНИЯ НИТРИЛОВ ДО АМИНОВ, СПОСОБ ЕГО ПОЛУЧЕНИЯ И СПОСОБ ГИДРИРОВАНИЯ С ИСПОЛЬЗОВАНИЕМ УКАЗАННОГО КАТАЛИЗАТОРА

Изобретение относится к способу каталитического гидрирования нитрилов до аминов. Оно относится также к катализатору гидрирования нитрилов до аминов типа никеля Ренея и активированному с помощью по крайней мере одного элемента, выбираемого из групп IIб, IVб - VIIб Периодической системы элементов. Этот катализатор обладает оптимизированной активностью, селективностью и стабильностью. Кроме того, он экономичен и удобен в употреблении. Катализатор согласно изобретению отличается тем, что его сплав-предшественник практически не содержит активирующего элемента перед щелочной обработкой и имеет содержание в нем алюминия, выраженное в массе по отношению к массе никеля, ниже или равное 6%, предпочтительно 5% и еще более предпочтительно 2,5-4,5%. Изобретение относится к способу получения указанного катализатора. Технический результат - повышение качества катализатора, упрощение способа его получения, а также повышение производительности и селективности гидрирования. 3 с. и 20 з.п. ф-лы, 2 табл.

СПОСОБ ПОЛУЧЕНИЯ СКЕЛЕТНОГО НИКЕЛЕВОГО КАТАЛИЗАТОРА ДЛЯ ГИДРИРОВАНИЯ НЕПРЕДЕЛЬНЫХ ОРГАНИЧЕСКИХ СОЕДИНЕНИЙ

Изобретение относится к химической промышленности, а именно к способам получения скелетного никелевого катализатора для применения в реакциях восстановления основных классов промышленно важных органических соединений газообразным водородом. Способ заключается в том, что берут никель-алюминиевый сплав в виде порошка со средним радиусом частиц 2÷100 мкм, обрабатывают гидроксидом щелочного металла на кипящей бане, отмывают катализатор от щелочи дистиллированной водой до нейтральной среды промывных вод (рН=7,0). В способе проводят предварительную термообработку никель-алюминиевого сплава в токе водорода (v=30 см/мин) при температуре 470÷570°С в течение 5÷15 минут, скорости нагрева от 25°С до 450÷470°С - 3,2÷10°С/мин, далее сплав помещают под слой воды, ставят на ледяную баню (t=0°С) прибавляют водный раствор гидроксида натрия (w=25 мас.%) до достижения концентрации последнего 3,7÷13,3% масс, выдерживают катализатор на ледяной бане в течение 1 часа, далее методом декантирования отделяют раствор ...

КОМПОЗИТНЫЙ КАТАЛИЗАТОР И СПОСОБ ЕГО ПОЛУЧЕНИЯ

СПОСОБ ПОЛУЧЕНИЯ ПЕРВИЧНЫХ АМИНОВ ГИДРИРОВАНИЕМ НИТРИЛОВ

... 1. Способ получения первичного амина гидрированием нитрилов, при котором реакция превращения протекает в реакционной смеси, которая содержит (а) по меньшей мере, один нитрил, (б) водород, (в) при необходимости аммиак и (г) по меньшей мере, один кобальтовый или никелевый катализатор, модифицированный ex situ адсорбцией карбоната щелочного металла или гидрокарбоната щелочного металла, который содержит карбонат или гидрокарбонат щелочного металла в количестве от 2 до 12 мас.%. 2. Способ по п.1, в котором модифицированный катализатор получают адсорбцией карбоната щелочного металла или гидрокарбоната щелочного металла из водного раствора концентрацией от 10 до 400 г/л. 3. Способ по п.2, в котором катализатор модифицируется водным раствором К2СО3 в концентрации от 50 до 200 г/л. 4. Способ по одному или более пп.1-3, в котором модифицированным катализатором является модифицированный никелевый катализатор Ренея. 5. Способ по одному или более пп.1-3, в котором гидрируется нитрил формулы R-CN, где ...

СПОСОБ ПОЛУЧЕНИЯ НИКЕЛЕВЫХ КАТАЛИЗАТОРОВ РЕНЕЯ, ПОЛУЧЕННЫЕ ЭТИМ СПОСОБОМ НИКЕЛЕВЫЕ КАТАЛИЗАТОРЫ РЕНЕЯ, ИХ ПРИМЕНЕНИЕ ДЛЯ ПОЛУЧЕНИЯ ОРГАНИЧЕСКИХ СОЕДИНЕНИЙ И СПОСОБ ГИДРИРОВАНИЯ ОРГАНИЧЕСКИХ НИТРОСОЕДИНЕНИЙ

... 1. Способ получения никелевых катализаторов Ренея, в соответствии с которым расплав сплава, содержащего от 40 до 95 мас.% алюминия, от 5 до 50 мас.% никеля, а также от 0 до 20 мас.% железа, от 0 до 15 мас.% церия, цериевого мишметалла, ванадия, ниобия, тантала, хрома, молибдена и/или марганца, а также, при необходимости, другие стеклообразующие элементы, подвергают контакту с одним или несколькими вращающимися охлаждающими валками или охлаждающими дисками, после чего расплаву предоставляют возможность остыть и затвердеть, причем поверхность охлаждающих валков структурирована поперечными канавками, а поверхность охлаждающих дисков структурирована канавками, направленными от оси вращения к краю, и затем быстро затвердевший сплав подвергают обработке органическими или неорганическими основаниями. 2. Способ получения никелевых катализаторов Ренея по п.1, в соответствии с которым расплав согласно методу переливания расплава выливают из плавильного тигля на вращающийся охлаждающий валок, после ...

СПОСОБ ПОЛУЧЕНИЯ КОМПОЗИЦИИ ПУТЕМ ИСПОЛЬЗОВАНИЯ СПИРТА В КАЧЕСТВЕ ИСХОДНОГО ВЕЩЕСТВА

... 1. Способ получения композиции с использованием спирта в качестве исходного вещества, содержащей, по меньшей мере, один компонент, выбранный из группы, состоящей из парафинов и спиртов, при этом способ содержит первый этап, на котором обеспечивают контакт спирта с катализатором превращения спирта, и второй этап, на котором продукт, полученный на первом этапе, подвергают реакции гидрирования. ! 2. Способ получения органического соединения по п.1, в котором исходным материалом является этанол. ! 3. Способ получения композиции по п.1 или 2, в котором катализатор превращения спирта одновременно вызывает обезвоживание и дегидрирование спирта. ! 4. Способ получения композиции по п.3, в котором катализатор превращения спирта является фосфатом кальция. ! 5. Способ получения композиции по п.4, в котором фосфат кальция является гидроксиапатитом. ! 6. Способ получения композиции по п.3, в котором катализатор превращения спирта является глинистым минералом. ! 7. Способ получения композиции по п.6, ...

ИСПОЛЬЗОВАНИЕ МЕДНЫХ КАТАЛИЗАТОРОВ НА МЕТАЛЛИЧЕСКИХ НОСИТЕЛЯХ ДЛЯ РИФОРМИНГА СПИРТОВ

... 1. Способ риформинга спирта, включающий в себя приведение в контакт исходной сырьевой смеси газов, содержащей спирт, с катализатором риформинга, чтобы получить смесь продуктов риформинга, содержащую водород, причем катализатор риформинга содержит медьсодержащую активную фазу на поверхности металлического губчатого носителя, при этом содержание меди в катализаторе риформинга больше, чем содержание меди в металлическом губчатом носителе. 2. Способ по п.1, в котором исходная сырьевая смесь газов содержит первичный спирт, выбранный из группы, состоящей из метанола, этанола и их смесей. 3. Способ по п.2, в котором способ дополнительно включает введение водорода из смеси продуктов риформинга и кислорода в топливный элемент для получения электроэнергии. 4. Способ по п.1, в котором катализатор риформинга имеет площадь поверхности от примерно 10 м2/г до примерно 100 м2/г, измеренную методом Брунауэра-Эмметта-Теллера. 5. Способ по п.4, в котором катализатор риформинга имеет площадь поверхности от ...

Способ получения @ -трифторметиланилина

СПОСОБ ПОЛУЧЕНИЯ О-ТРИФТОРМЕТИЛАНИЛИНА с использованием трифторметилбензола , нитрованием смесью азотной и серной кислот и восстановлением, -отличающийся тем, что, с целью упрощения процесса, трифторметилбензол хлорируют газообразным хлором в присутствии катализатора хлорирования, а именно SbCf с или FeCf,,+ Fe , или Sb, или 5ЬС1л в количест7 7 ве0,1-10 мас.% по отнощенйю к взятому трифторметилбензолу при 0-100 С до конверсии трифторметилбензола 95-99 мас.% с пос , ледующим нитрованием полученного неочищенного реакционного продукта при массовом отношении каждой кислоты к хлортрифторметилбензолам , содержащимся в реакционной среде, равном 0,5-5, до полного исчезновения хлортрифторметилбензолов при , гидрированием полученной после декантации и промьшки органической фазы в присутствии катализатора гидрирования - никеля Ренея и/или никеля Ренея с добавкой 0,75- 3,5 мас.% хрома в количестве 3-10 мас.% по отнощению к хлорнитротрифторметилбензолам в среде метанола при давлении 10-50 бар и i 20 ...

Способ делирофоризации металлического катализатора гидрирования

RANEY-EISENKATALYSATOREN UND DEREN VERWENDUNG ZUR HYDRIERUNG ORGANISCHER VERBINDUNGEN

Hydrogenation of oligonitrile with at least two nitrile groups, in the presence of a catalyst, which is pre-treated by contacting with a compound e.g. alkali metal carbonates and ammonium carbonate

Hydrogenation of oligonitrile with at least two nitrile groups in the presence of a catalyst, which is pre-treated by contacting with a compound A, before the hydrogenation process; where the compound A is e.g. alkaline metal carbonates, alkaline-earth metal carbonates, ammonium carbonate, alkaline metal hydrogencarbonate, alkaline-earth metal hydrogencarbonate, ammonium hydrogencarbonate and alkaline-earth metal oxycarbonate. Hydrogenation of oligonitrile with at least two nitrile groups in the presence of a catalyst, which is pre-treated by contacting with a compound A, before the hydrogenation process; where the compound A is alkaline metal carbonates, alkaline-earth metal carbonates, ammonium carbonate, alkaline metal hydrogencarbonate, alkaline-earth metal hydrogencarbonate, ammonium hydrogencarbonate, alkaline-earth metal oxycarbonate, alkaline metal carboxylate, alkaline-earth metal carboxylate, ammonium carboxylate, alkaline metal dihydrogen phosphate, alkaline-earth metal dihydrogen ...

Mischkatalysator fuer die Zersetzung von Hydrazin

RANEY-NICKEL-EISEN-KATALYSATOR

Doppelskelett-Katalysatorelektrode und Verfahren zu ihrer Herstellung

Verfahren zur Herstellung eines Hydrierungskatalysators auf Nickelbasis

A supported catalyst, its activated form, and their preparation and use

METHOD OF ACTIVATING RANEY ALLOYS

... 1,206,981. Activating Raney alloys. TORAY INDUSTRIES Inc. 13 Oct., 1967, No. 46847/ 67. Heading BIE. [Also in Divisions C2 and C5] Raney alloys are activated by treatment with water-in the presence of at least 1/20th part of a substance selected from aluminas, amines, lactams, N-substituted lactams having at least one hydrogen atom on the carbon atom adjacent to the CO group, oximes, N-substituted acid amides having at least one hydrogen atom on either the carbon atom adjacent to the CO of the amide group or the nitrogen atom of the amide group N:N' and N:N:N' urea derivatives and precursor(s) therefor.

Microencapsulated catalyst

The present invention relates to a catalyst system. In particular the invention relates to a catalyst in the form of metal or an alloy that is encapsulated within a polymer shell or matrix. More specifically the invention is directed towards reactive catalytic metals that may be pyrophoric or otherwise reactive in air and/or susceptible to oxidation. In particular, the invention is concerned with catalysts based on nickel. Raney or sponge nickel is highly hazardous: a self-igniting solid; produces hazardous fumes when burning; causes irritation of the respiratory tract, nasal cavities; causes pulmonary fibrosis if inhaled; ingestion may lead to convulsions and intestinal disorders; causes eye and skin irritation; and chronic exposure may lead to pneumonitis and sensitization (“nickel itch”). The invention provides metal catalysts that avoid such problems and have a good shelf life and working life.

Method for preparing a terpenylcyclohexanol

A method for preparing a terpenylcyclohexanol using a terpenylphenol is described. A method for preparing a terpenylcyclohexanol by hydrogenation of a terpenylphenol is also described wherein the method includes hydrogenating the latter in a liquid phase, in the presence of a Raney nickel catalyst including residual aluminium and doped with a mixture of iron and chromium.

Nano-skeletal catalyst

A method of producing a catalyst material with nano-scale structure, the method comprising: introducing a starting powder into a nano-powder production reactor, the starting powder comprising a catalyst material; the nano-powder production reactor nano-sizing the starting powder, thereby producing a nano-powder from the starting powder, the nano-powder comprising a plurality of nano-particles, each nano-particle comprising the catalyst material; and forming a catalyst precursor material from the nano-powder, wherein the catalyst precursor material is a densified bulk porous structure comprising the catalyst material, the catalyst material having a nano-scale structure.

Process for the production of hexamethlenediamine

It is described a process for the production of hexamethylenediamine by hydrogenation of adiponitrile, comprising an improved step of regeneration of the catalyst. Also described are an equipment for the production of hexamethylenediamine, and a washing apparatus ( 14 ) for implementing the catalyst regeneration step.

METHOD FOR ACTIVATING A FIXED CATALYST BED WHICH CONTAINS MONOLITHIC SHAPED CATALYST BODIES OR CONSISTS OF MONOLITHIC SHAPED CATALYST BODIES

A process for activating a fixed catalyst bed is disclosed. The fixed catalyst bed includes monolithic shaped catalyst bodies or include monolithic shaped catalyst bodies including at a first metal selected from Ni, Fe, Co, Cu, Cr, Pt, Ag, Au and Pd, and a second component selected from Al, Zn and Si. The fixed catalyst bed, for activation, is treated with an aqueous base having a strength of not more than 3.5% by weight. The base is selected from alkali metal hydroxides, alkaline earth metal hydroxides and mixtures thereof. The fixed catalyst bed has a temperature gradient during the activation and the temperature differential between the coldest point in the fixed catalyst bed and the warmest point in the fixed catalyst bed is kept at not more than 50 K. 1. A process for activating a fixed catalyst bed comprising monolithic shaped catalyst bodies or consisting of monolithic shaped catalyst bodies comprising at least one first metal selected from Ni , Fe , Co , Cu , Cr , Pt , Ag , Au and Pd , and comprising at least one second component selected from Al , Zn and Si , and wherein the fixed catalyst bed , for activation , is subjected to a treatment with an aqueous base having a strength of not more than 3.5% by weight , wherein the base is selected from alkali metal hydroxides , alkaline earth metal hydroxides and mixtures thereof , and wherein the fixed catalyst bed has a temperature gradient during the activation and the temperature differential between the coldest point in the fixed catalyst bed and the warmest point in the fixed catalyst bed is kept at not more than 50 K.2. A process for providing a reactor comprising an activated fixed catalyst bed , in whicha) a fixed catalyst bed comprising monolithic shaped catalyst bodies or consisting of monolithic shaped catalyst bodies comprising at least one first metal selected from Ni, Fe, Co, Cu, Cr, Pt, Ag, Au and Pd, and comprising at least one second component selected from Al, Zn and Si, is introduced into a ...

METHOD FOR PROVIDING A CATALYTICALLY ACTIVE FIXED BED FOR HYDROGENATING ORGANIC COMPOUNDS

Described herein is a process for providing a catalytically active fixed bed for hydrogenation of organic compounds, in which a fixed bed including monolithic shaped bodies as catalyst supports or consisting of monolithic shaped bodies is introduced into a reactor and the fixed bed is then contacted with at least one catalyst or a precursor thereof. The fixed beds laden with a catalyst that are obtained in this way are especially suitable for the hydrogenation of organic compounds in the presence of CO, wherein the conversion is at least 90%. They are notable in that only a very small proportion, if any, of the catalyst introduced is released into the reaction medium. 1. A process for providing a catalytically active fixed bed comprising monolithic shaped bodies as catalyst supports or consisting of monolithic shaped bodies laden with a catalyst comprising at least one metal selected from Ni , Fe , Co , Cu , Cr , Pt , Ag , Au , Pd , Mn , Re , Ru , Rh and Ir , in whicha) a fixed bed comprising monolithic shaped bodies or consisting of monolithic shaped bodies is introduced into a reactor,b) the fixed bed is contacted with a suspension of the at least one catalyst or the precursor thereof in a liquid medium, and the suspension of the at least one catalyst or the precursor thereof is at least partly conducted in a liquid circulation stream, the catalyst or the precursor comprising at least one metal selected from Ni, Fe, Co, Cu, Cr, Pt, Ag, Au, Pd, Mn, Re, Ru, Rh and Ir, to obtain a fixed bed laden with the catalyst or the precursor,c) the laden fixed bed obtained in step b) is optionally subjected to an activation,{'sub': 1', '4, 'd) the laden fixed bed obtained in step b) or the activated fixed bed obtained in step c) is optionally subjected to a treatment with a wash medium selected from water, C-C-alkanols, and mixtures thereof, and'}e) the fixed bed obtained after the activation in step c) or after the treatment in step d) is optionally contacted with a dopant ...

Process for producing 1,3-butanediol and for optionally further producing (r)-3-hydroxybutyl (r)-3-hydroxybutyrate

A process is described for producing 1,3-butanediol, wherein an ester of poly-(R)-3-hydroxybutyrate such as formed by transesterification with an alcohol is reduced by hydrogenation in the presence of a skeletal copper-based catalyst to provide 1,3-butanediol. The 1,3-butanediol may be transesterified by reaction with additional poly-(R)-3-hydroxybutyrate ester to produce (R)-3-hydroxybutyl (R)-3-hydroxybutyrate.

METHOD FOR THE PREPARATION OF C3-C12-ALCOHOLS BY CATALYTIC HYDROGENATION OF THE CORRESPONDING ALDEHYDES

The present invention relates to a process for preparing C-Calcohols by catalytically hydrogenating the corresponding aldehydes at a temperature in the range of 50-250° C. and a pressure in the range of 5-150 bar in the presence of a supported activated Raney-type catalyst, characterized in that the support body is a metal foam and the metal is selected from the group consisting of cobalt, nickel and copper and mixtures thereof. 112-. (canceled)13. A process for preparing C-Calcohols by catalytically hydrogenating the corresponding aldehydes at a temperature in the range of 50-250° C. and a pressure in the range of 5-150 bar in the presence of a supported activated Raney-type catalyst , wherein the supported activated Raney-type catalyst comprises a support body that is a metal foam and the metal is selected from the group consisting of: cobalt; nickel; copper; and mixtures thereof.14. The process of claim 13 , wherein a C-Caldehyde is used in the hydrogenation.15. The process of claim 13 , wherein isononanal or butyraldehyde is used as the aldehyde in the hydrogenation.16. The process of claim 13 , wherein the metal is nickel.17. The process of claim 13 , wherein the supported activated Raney-type catalyst contains 85-95% by weight of nickel and 5-15% by weight of aluminium claim 13 , based on the total weight of the catalyst.18. The process of claim 17 , wherein the supported activated Raney-type catalyst additionally contains up to 3% by weight of molybdenum claim 17 , based on the total weight of the catalyst.19. The process of claim 13 , wherein the supported activated Raney-type catalyst has the following properties:{'sup': '2', 'a) a BET surface area of 1-200 m/g, and'}b) macroscopic pores in the range of 100-5000 μm.20. The process of claim 13 , wherein the supported activated Raney-type catalyst is cylindrical claim 13 , annular claim 13 , cuboidal claim 13 , parallelepipedal or cubic.21. The process of claim 20 , wherein the supported activated Raney-type ...

Methods for Preparing Diol

Provided is a method for preparing a diol. In the method, a saccharide and hydrogen as raw materials are contacted with a catalyst in water to prepare the diol. The employed catalyst is a composite catalyst comprised of a main catalyst and a cocatalyst, wherein the main catalyst is a water-insoluble acid-resistant alloy; and the cocatalyst is a soluble tungstate and/or soluble tungsten compound. The method uses an acid-resistant, inexpensive and stable alloy needless of a support as a main catalyst, and can guarantee a high yield of the diol in the case where the production cost is relatively low. 1. A method for preparing a diol , characterized by:(a) adding an unsupported main catalyst comprising nickel, one or more rare earth elements, tin and aluminium, and optionally i) tungsten, ii) tungsten and molybdenum, or iii) tungsten, molybdenum and boron or phosphorus to a slurry bed reactor;(b) increasing the reaction system pressure to 5-12 MPa and the reaction temperature to 150-260° C.;(c) adding a soluble tungstic acid salt cocatalyst, hydrogen and a sugar to the slurry bed reactor, wherein the sugar and cocatalyst are fed continuously into the slurry bed reactor in the form of an aqueous sugar solution having a sugar concentration from 20-60 wt % and further comprising the soluble tungstic acid salt cocatalyst to provide gas and a liquid comprising a diol;(d) continuously passing the gas and reaction liquid out of the reactor through a filter to intercept catalyst and(e) separating the diol from the gas and reaction liquid.2. The method for preparing a diol as claimed in claim 1 , characterized in that the diol is ethylene glycol.3. The method for preparing a diol as claimed in claim 2 , characterized in that the reaction system pH is 1-7; more preferably claim 2 , the reaction system pH is 3-6.4. The method for preparing a diol as claimed in claim 1 , characterized in that the sugar is selected from one or more of five-carbon monosaccharides claim 1 , ...

ISOIDIDE MANUFACTURE AND PURIFICATION

Methods are provided for the conversion of isosorbide to isoidide, wherein the isosorbide contains sorbitan impurities. The impurities in the isosorbide subjected to epimerization are converted to hydrodeoxygenation products. A method for synthesizing isoidide, comprising, providing an isosorbide containing one or more sorbitans; and, epimerizing the isosorbide to form an epimerization product comprising isoidide and hydrodeoxygenation products. 1. A method for synthesizing isoidide , comprising ,providing an isosorbide containing one or more sorbitans; and,epimerizing the isosorbide to form an epimerization product comprising isoidide and hydrodeoxygenation products.2. The method of claim 1 , wherein the isosorbide containing one or more sorbitans is obtained from one or more intermediate process streams in a process for producing at least a technical grade isosorbide product through the dehydration of sorbitol claim 1 , or from adding sorbitans to a technical grade or better isosorbide.3. The method of claim 2 , wherein the isosorbide containing one or more sorbitans is obtained by adding one or more sorbitans to one or more intermediate process streams containing isosorbide claim 2 , or by adding additional of the one or more sorbitans to one or more intermediate process streams containing both isosorbide and one or more sorbitans.4. The method of claim 2 , wherein the isosorbide containing one or more sorbitans is obtained from one or more of incompletely purified isosorbide claim 2 , partially purified isosorbide claim 2 , intermediately purified isosorbide streams claim 2 , recycled distillation bottoms from isosorbide manufacturing claim 2 , isosorbide crude reaction mixture claim 2 , extracts from a series of simulated moving bed ion exclusion isosorbide purification steps claim 2 , combined ion-excluded claim 2 , ion-exchanged isosorbide mixtures claim 2 , degassed isosorbide residue claim 2 , commercially available isosorbide and combinations of any ...

METHOD FOR THE PRODUCTION OF GLYCOLS FROM A CARBOHYDRATE FEED

Implementations of the disclosed subject matter provide methods for producing ethylene glycol from a carbohydrate feed may include contacting, in a first reactor under hydrogenation conditions, the carbohydrate feed with a bi-functional catalyst system. The bi-functional catalyst system may include a heterogeneous hydrogenation catalyst, and a soluble retro-Aldol catalyst. The carbohydrate feed may include a concentration of carbohydrate, in the total solution entering the first reactor, of 5-40 wt % in a solvent. An intermediate product stream may be obtained from the first reactor including ethylene glycol. The hydrogenation conditions may include a temperature in the range of from 180-250° C. 1. A method for producing ethylene glycol from a carbohydrate feed comprising: 1) a heterogeneous hydrogenation catalyst, and', 'wherein the carbohydrate feed comprises a concentration of carbohydrate, in the total solution entering the first reactor, of 5-40 wt % in a solvent;', '2) a soluble retro-Aldol catalyst; and,'}], 'a) contacting, in a first reactor under hydrogenation conditions, the carbohydrate feed with a bi-functional catalyst system comprisingb) obtaining an intermediate product stream, from the first reactor, comprising ethylene glycol; and wherein the hydrogenation conditions comprise a temperature in the range of from 180-250° C.2. The method of claim 1 , wherein the carbohydrate feed comprises a concentration of carbohydrate claim 1 , in the total solution entering the first reactor claim 1 , of at least 10 wt % in a solvent.3. The method of claim 2 , wherein the solvent is HO.4. The method of claim 1 , further comprising running the reaction under pH controlled conditions and wherein the pH of the reaction is in the range of from 2-7.5. The method of claim 1 , wherein the first reactor is pre-loaded with the heterogeneous hydrogenation catalyst and the soluble retro-Aldol catalyst is continuously added to the first reactor.6. The method of claim 5 , ...

ISOTHERMAL CHEMICAL PROCESS

Endothermic reactions (those whose heat of reaction is positive) may be controlled in a truly isothermal fashion with external heat input applied directly to the solid catalyst surface itself and not by an indirect means external to the actual catalytic material. This heat source can be supplied uniformly and isothermally to the catalyst active sites solely by conduction using electrical resistance heating of the catalytic material itself or by an electrical resistance heating element with the active catalytic material coating directly on the surface. By employing only conduction as the mode of heat transfer to the catalytic sites, the non-uniform modes of radiation and convection are avoided permitting a uniform isothermal chemical reaction to take place. 1. A method comprising the steps of:conducting an isothermal endothermic chemical reactions over a heterogeneous catalysts;and heating an electrically conductive catalytic material by electrical resistance whereby said electrically resistance comprises the only heat source for the endothermic process.2. The method of claim 1 , further including the step of:employing an electrical resistance heating device in direct physical contact with an active heterogeneous catalytic agent disposed on the outer surface of said electrically conductive catalytic material; andsaid electrically conductive catalytic material directly contacting a reacting fluid.3. The method of claim 1 , further including the step of:applying at least one wash coat between said electrical resistance heating device and the said active heterogeneous catalytic agent.4. The method for carrying out isothermal endothermic reactions as in claims 1 , wherein the electrical resistance heating device is heated by means of direct electrical current.5. The method for carrying out isothermal endothermic reactions as in claims 2 , wherein the electrical resistance heating device is heated by means of direct electrical current.6. The method for carrying out ...

2-(3-(AMINOMETHYL)-3,5,5-TRIMETHYLCYCLOHEXYL)PROPANE-1,3-DIAMINE, A PROCESS FOR ITS PRODUCTION AND USE

A compound of the structural formula 1 120-. (canceled)22. A hardener in epoxy resin composition comprising a 2 (3 (aminomethyl)-3 ,5 ,5-trimethylcyclohexyl)propane-1 ,3-diamine (CPDA) as a hardener in epoxy resin composition.24. An epoxy resin composition comprising the 2 (3 (aminomethyl)-3 claim 22 ,5 claim 22 ,5-trimethylcyclohexyl)propane-1 claim 22 ,3-diamine (CPDA) of .26. The epoxy resin composition of wherein the epoxy resin is selected from the group consisting of polyepoxides based on bisphenol A diglycidyl ether claim 25 , bisphenol F diglycidyl ether and cycloaliphatic types.27. The epoxy resin composition of wherein the epoxy resin is selected from the group consisting of epoxy resins based on bisphenol A and bisphenol F.28. The epoxy resin composition of wherein the epoxy resin is selected from the group consisting of polyepoxides based on bisphenol A diglycidyl ether.29. The epoxy resin composition of wherein the epoxy resin is selected from the group consisting of polyepoxides based on bisphenol F diglycidyl ether.30. The epoxy resin composition of wherein the epoxy resin is selected from the group consisting of polyepoxides based on bisphenol A diglycidyl ether and bisphenol F diglycidyl ether. This application is a divisional of and claims priority to U.S. patent application Ser. No. 15/604,988, entitled “2-(3-(AMINOMETHYL)-3,5,5-TRIMETHYLCYCLOHEXYL)PROPANE-1,3-DIAMINE, A PROCESS FOR ITS PRODUCTION AND USE” filed on May 25, 2017, which claims priority to EP Application No. 16173867.9 filed Jun. 10, 2016, the disclosures of which are expressly incorporated herein by reference.The present invention relates to a novel amine having the name 2-(3-(aminomethyl)-3,5,5-trimethylcyclohexyl) propane-1,3-diamine (AM-CPDA), referred to hereinbelow as AM-CPDA, to a process for its production and to its use.2-(3-(aminomethyl)-3,5,5-trimethylcyclohexyl) propane-1,3-diamine (AM-CPDA), referred to hereinbelow as AM-CPDA, has the chemical structure depicted in ...

A metal complex catalyst, preparation method thereof, and use thereof in preparing d,l-menthol

The present invention discloses a metal complex catalyst, its preparing method and its application in preparing D,L-menthol, the metal complex catalyst includes weight percent elements as follows: 70-85% of Ni, 8-10% of Al, 5-10% of V, and 2-10% of Co. When this metal complex catalyst is applied in preparing D,L-menthol through thymol hydrogenation, it has the characteristics of high reaction activity and quick racemization of chiral compound. Meanwhile, a certain kind of alkali added in isomerization is the key to reducing light constituent byproduct. The whole process comes in good reaction selectivity, simple preparing technology, low production cost, and environment-friendly synthetic route.

Method for Increasing UV Transmittance of Ethylene Glycol

The present invention provides a method for increasing the UV transmittance of ethylene glycol. The method uses an ethylene glycol solution and hydrogen as raw materials, and uses an alloy catalyst comprising nickel, one or more rare-earth elements, tin, and aluminum, the contents thereof in parts by weight being 10-90, 1-5, 1-60, and 5-9, respectively. The method of the present invention uses an inexpensive, stable-in-aqueous-phase, carrier-free alloy as a catalyst, and continuously adds hydrogen to reduce unsaturated impurities in ethylene glycol. In application of the method of the present invention in continuous industrial-scale production, the use of this type of alloy catalyst could be especially significant for the achievement of long-term system stability and control of production costs.

SURFACE MODIFIED METALLIC FOAM BODY, PROCESS FOR ITS PRODUCTION AND USE THEREOF

A metallic foam body containing an alloy skin which is up to 50 μm thick can be obtained by a process including (a) providing a metallic foam body comprising a first metallic material; (b) applying a second metallic material which contains a first metallic compound that is leachable as such and/or that can be transformed by alloying into a second metallic compound that is leachable and different from the first metallic compound on a surface of the foam body (a), by coating the metallic foam body with an organic binder and a powder of the second metallic material; (c) forming a skin on foam body (b) by alloying the first and the second metallic material; and (d) leaching out with a leaching agent at least a part of the first and/or the second metallic compound. 1. Surface modified metallic foam body containing an unmodified core and an alloy skin , obtainable by a process comprising the steps:(a) providing a metallic foam body comprising a first metallic material;(b) applying a second metallic material which is different from the first metallic material and which contains a first metallic compound that is leachable as such and/or that can be transformed by alloying into a second metallic compound that is leachable and different from the first metallic compound on a surface of the metallic foam body (a), by coating the surface of the metallic foam body with an organic binder and a powder of the second metallic material;(c) forming an alloy skin of the metallic foam body obtained in step (b) by alloying the first metallic material and the second metallic material; and(d) treating the alloyed metallic foam body obtained in step (c) with an agent that is capable of leaching out the leachable first and/or second metallic compound from the alloy skin of the metallic foam body, to leach out at least a part of the first and/or the second metallic compound from the alloy skin of the metallic foam body;wherein the thickness of the alloy skin is in the range of up to 50 μm as ...

HETEROGENEOUS CATALYST PROCESS AND NICKEL CATALYST

The present invention relates to heterogeneous catalysts and methods of making and using the same. In various embodiments, the present invention provides a method of making a hydrogenation catalyst including particulate nickel metal (Ni(0)). The method includes calcining first nickel(II)-containing particles in an atmosphere including oxidizing constituents to generate second nickel(II)-containing particles. The method also includes reducing the second nickel(II)-containing particles in a reducing atmosphere while rotating or turning the second nickel(II)-containing particles at about 275° C. to about 360° C. for a time sufficient to generate the particulate nickel metal (Ni(0)), wherein the particulate nickel metal (Ni(0)) is free flowing. 1. A method of making a heterogeneous catalyst comprising particulate nickel metal (Ni(0)) , the method comprising:calcining first nickel(II)-containing particles in an atmosphere comprising oxidizing constituents to generate second nickel(II)-containing particles; andreducing the second nickel(II)-containing particles in a reducing atmosphere while rotating or turning the second nickel(II)-containing particles at about 275° C. to about 360° C. for a time sufficient to generate the particulate nickel metal (Ni(0)), wherein the particulate nickel metal (Ni(0)) is free flowing.2. The method of claim 1 , wherein neither water nor steam are added to the reducing atmosphere.3. The method of wherein the second nickel(II)-containing particles comprise basic nickel carbonate claim 1 , nickel oxide claim 1 , nickel carbonate claim 1 , nickel bicarbonate claim 1 , nickel oxalate claim 1 , nickel formate claim 1 , nickel squarate claim 1 , nickel hydroxide claim 1 , nickel nitrate claim 1 , nickel cyanate claim 1 , nickel sulfate and combinations thereof.4. The method of claim 1 , wherein calcining comprises heating the first nickel(II)-containing particles in an atmosphere comprising the oxidizing constituents at a temperature of about 350 ...

Process for the manufacture of spirocyclic substituted benzofuroquinolizines

The present invention relates to a process for the manufacture of N-(2-((2R,12bS)-2′-oxo-1,3,4,6,7,12b-hexahydrospiro[benzofuro[2,3-a]quinolizine-2,4′-imida-zolidine]-3′-yl)ethyl)-methanesulfonamide, where in the process trimethylsilyl cyanide is used.

METHOD FOR THE SELECTIVE PRODUCTION OF N-METHYL-PARA-ANISIDINE

The invention “Method for selective synthesis of N-methyl-para-anisidine” relates to chemical technology processes, namely to catalytic alkylation of aromatic amines and nitro compounds. 1. The process for synthesis of N-methyl-para-anisidine , consist in that N-alkylation of para-nitroanisole and/or para-anisidine is performed in vapor phase on dehydrogenating catalyst at a temperature 180-260° C. and atmospheric pressure with subsequent product isolation using rectification.2. The process of wherein N-methyl-para-anisidine is produced claim 1 , correspondingly claim 1 , from para-nitroanisole.3. The process of wherein N-methyl-para-anisidine is produced claim 1 , correspondingly claim 1 , from para-anisidine.4. The process of wherein N-alkylation is performed in nitrogen stream.5. The process of wherein N-alkylation is performed in hydrogen stream.6. The process of wherein the catalyst has the following composition: CuO—55%; ZnO—10.5%; CrO—13.5%; AlO0 the rest.7. The process of wherein the catalyst has the following composition CuO—25%; ZnO—25%; CaO—5%; AlO—the rest.8. The process of wherein the catalyst has the following composition: CuO—25-45%; BaO—2-10%; TiO—15-35%; CrO—the rest.9. The process of wherein the catalyst has the following composition: CuO—35-45%; ZnO—25-35%; NiO—3-8%; AlO—the rest.10. The process of wherein the catalyst has the following composition: CuO—12-19% MnO—2-3%; CrO—1.0-1.4%; FeO—1.0-1.4%; CoO—0.5-0.8%; AlO—the rest.11. The process of wherein Raney nickel catalyst is used.12. The process of wherein BASF Cu-E403TR catalyst is used with the following composition: copper chromite—67-71% claim 6 , copper—11-15% claim 6 , copper oxide—8-21% claim 6 , graphite—0-4% claim 6 , chromium (3+) oxide—0-3%.13. The process of wherein BASF Cu-0203T 1/8 catalyst is used with the following composition: copper oxide—75-100% claim 6 , chromium (3+) oxide—0.1-1%.14. The process of wherein BASF Cu-E406 TR catalyst is used with the following composition: Cu—36% ...

SUPPORTED CATALYST, ITS ACTIVATED FORM, AND THEIR PREPARATION AND USE

A supported catalyst and preparation method thereof, the catalyst comprising an organic polymer material carrier and Raney alloy particles supported on the organic polymer material carrier, wherein substantially all of the Raney alloy particles are partially embedded in the organic polymer material carrier. The catalyst can be used in hydrogenation, dehydrogenation, amination, dehalogenation or desulfuration reactions. 1. A supported catalyst , comprising: an organic polymer material support and Raney alloy particles supported on the organic polymer material support , wherein substantially all of the Raney alloy particles are partially embedded into the organic polymer material support.2. The catalyst of claim 1 , wherein the Raney alloy comprises at least one Raney metal and at least one leachable element.3. The catalyst of claim 2 , wherein the at least one Raney metal is chosen from nickel claim 2 , cobalt claim 2 , copper claim 2 , and iron claim 2 , and the at least one leachable element is chosen from aluminum claim 2 , zinc claim 2 , and silicon.4. The catalyst of claim 2 , wherein the weight ratio of the Raney metal to the leachable element in the Raney alloy is from 1:99 to 10:1.5. The catalyst of claim 4 , wherein the weight ratio of the Raney metal to the leachable element in the Raney alloy is from 1:10 to 4:1.6. The catalyst of claim 2 , wherein the Raney alloy further comprises at least one promoter chosen from Mo claim 2 , Cr claim 2 , Ti claim 2 , and Ru in an amount of from 0.01 wt. % to 5 wt. % claim 2 , based on the total weight of the Raney alloy.7. The catalyst of any one of to claim 2 , wherein the organic polymer material is a plastic or a modified plastic.8. The catalyst of any one of to claim 2 , wherein the organic polymer material is chosen from polyolefins claim 2 , polyamides claim 2 , polystyrenes claim 2 , epoxy resins claim 2 , phenolic resins claim 2 , and mixtures and blends thereof.9. The catalyst of any one of to claim 2 , wherein ...

PROCESSES TO PRODUCE ELAGOLIX

The present invention relates to a scalable process for the making of elagolix, its salts and the process of intermediate compounds. 128-. (canceled)30. The process of wherein the organic solvent is selected from the group consisting of dimethylformamide claim 29 , dimethylacetamide claim 29 , acetonitrile claim 29 , n-butanol claim 29 , tert-butanol claim 29 , 1 claim 29 ,4-dioxane claim 29 , dimethyl sulfoxide claim 29 , N-methylpyrrolidone claim 29 , sulfolane claim 29 , and mixtures thereof.31. The process of claim 29 , wherein the organic solvent is dimethylformamide or N-methylpyrrolidone.34. The process of claim 33 , wherein the solvent is selected from the group consisting of dichloromethane claim 33 , toluene claim 33 , 1 claim 33 , 4-dioxane claim 33 , tetrahydrofuran claim 33 , methyltetrahydrofuran claim 33 , and mixtures thereof.35. The process of claim 33 , wherein the solvent is tetrahydrofuran.37. The process of claim 36 , wherein the acid is hydrochloric acid.39. The process of wherein the acidic deprotection is conducted in the presence of hydrochloric acid.42. The process of claim 41 , wherein the solvent is selected from the group consisting of dimethylformamide claim 41 , dimethylacetamide claim 41 , acetonitrile claim 41 , tetrahydrofuran claim 41 , methyltetrahydrofuran claim 41 , isopropanol claim 41 , n-butanol claim 41 , tert-butanol claim 41 , 1 claim 41 ,4-dioxane claim 41 , dimethyl sulfoxide claim 41 , N-methylpyrrolidone claim 41 , sulfolane and mixtures thereof.43. The process of claim 41 , wherein the solvent is isopropanol.46. The process of claim 45 , wherein the transition-metal catalyst is Pd/C or Raney nickel.48. The process of wherein the amines are selected from the group consisting of tetramethylethylenediamine claim 47 , diisopropylamine claim 47 , diethylamine claim 47 , di-sec-butylamine claim 47 , pentamethyldiethylenetriamine claim 47 , and combinations thereof. The present invention relates to process for preparing the ...

Fluid recirculation system for use in vapor phase particle production system

A method of and system for recirculating a fluid in a particle production system. A reactor produces a reactive particle-gas mixture. A quench chamber mixes a conditioning fluid with the reactive particle-gas mixture, producing a cooled particle-gas mixture that comprises a plurality of precursor material particles and an output fluid. A filter element filters the output fluid, producing a filtered output. A temperature control module controls the temperature of the filtered output, producing a temperature-controlled, filtered output. A content ratio control module modulates the content of the temperature-controlled, filtered output, thereby producing a content-controlled, temperature-controlled, filtered output. A channeling element supplies the content-controlled, temperature-controlled, filtered output to the quench chamber, wherein the content-controlled, filtered output is provided to the quench chamber as the conditioning fluid to be used in cooling the reactive particle-gas mixture.

METHOD FOR PRODUCING 2,5-BIS(AMINOMETHYL)FURAN

The present invention is to provide a production method that can produce 2,5-bis(aminomethyl)furan efficiently. The production method for 2,5-bis(aminomethyl)furan includes reacting 5-(halogenated methyl)furfural with hydrogen and an amine compound using a hydrogenation catalyst to obtain 2,5-bis(aminomethyl)furan. 1. A production method for 2 ,5-bis(aminomethyl)furan , comprising:reacting 5-(halogenated methyl)furfural with hydrogen and an amine compound using a hydrogenation catalyst to obtain 2,5-bis(aminomethyl)furan.2. The production method according to claim 1 , wherein the 5-(halogenated methyl)furfural is 5-(chloromethyl)furfural.3. The production method according to claim 1 , wherein the 5-(halogenated methyl)furfural is derived from at least one type selected from the group consisting of woody biomass claim 1 , cellulose claim 1 , and C6 saccharides that are saccharides having 6 carbon atoms.4. The production method according to claim 1 , wherein the amine compound is ammonia or an amide represented by RCONH claim 1 , where R represents a hydrogen atom or —CHwhere n is an integer of 1 or more.5. The production method according to claim 1 , wherein the hydrogenation catalyst is a catalyst containing at least one type selected from the group consisting of Fe claim 1 , Co claim 1 , Ni claim 1 , Cu claim 1 , Ru claim 1 , Rh claim 1 , Pd claim 1 , Ir claim 1 , Pt claim 1 , Re claim 1 , and Os.6. The production method according to claim 1 , wherein the reaction is performed at a hydrogen pressure of more than 0 MPaG and 25 MPaG or less.7. The production method according to claim 1 , wherein the reaction is performed at a hydrogen pressure of more than 0 MPaG and less than 9 MPaG.8. The production method according to claim 1 , further comprising separating 2 claim 1 ,5-bis(aminomethyl)furan from the catalyst.9. The production method according to claim 2 , wherein the 5-(halogenated methyl)furfural is derived from at least one type selected from the group ...

Acid-Resistant Alloy Catalyst

Disclosed is an acid-resisting alloy catalyst comprising nickel, one or more rare earth elements, stannum and aluminum. The acid-resistant alloy catalyst is low-cost and stable, and does not need a carrier, and can be stably used in continuous industrial production, thus achieving a low production cost. 1. An acid-resistant alloy catalyst comprising nickel , one or more rare earth elements , tin and aluminum.2. The acid-resistant alloy catalyst of comprising in parts by weight claim 1 , 10-90 parts nickel claim 1 , 1-5 parts rare earth element claim 1 , 1-60 parts tin and 5-9 parts aluminum.3. The acid-resistant alloy catalyst of claim 1 , further comprising tungsten.4. The acid-resistant alloy catalyst of comprising claim 3 , in parts by weight claim 3 , 10-90 parts nickel claim 3 , 1-5 parts rare earth element claim 3 , 1-60 parts tin claim 3 , 5-9 parts aluminum and 1-90 parts tungsten.5. The acid-resistant alloy catalyst of claim 1 , further comprising tungsten and molybdenum.6. The acid-resistant alloy catalyst of comprising claim 5 , in parts by weight claim 5 , 10-90 parts nickel claim 5 , 1-5 parts rare earth element claim 5 , 1-60 parts tin claim 5 , 5-9 parts aluminum claim 5 , 1-90 parts tungsten and 0.5-20 parts molybdenum.7. The acid-resistant alloy catalyst of claim 1 , further comprising tungsten claim 1 , molybdenum claim 1 , and one of boron or phosphorus.8. The acid-resistant alloy catalyst of comprising claim 7 , in parts by weight claim 7 , 10-90 parts nickel claim 7 , 1-5 parts rare earth element claim 7 , 1-60 parts tin claim 7 , 5-9 parts aluminum claim 7 , 1-90 parts tungsten claim 7 , 0.5-20 parts molybdenum claim 7 , and 0.01-5 parts boron or phosphorus.9. The acid-resistant alloy catalyst of claim 1 , wherein the rare earth element is selected from the group consisting of lanthanum (La) claim 1 , cerium (Ce) and samarium (Sm). The present invention relates to an alloy catalyst, in particular to an acid-resistant alloy catalyst.Due to their ...

Process for producing aromatic primary diamines

A process for the production of aromatic primary amines, by reacting an aromatic dialdehyde with hydrogen and ammonia or an ammonia-liberating compound, in the presence of a hydrogenation catalyst and an amine, wherein the molar ratio of the amine to the aromatic dialdehyde is no less than 1:4 at the start of the reaction.

Methods for the valorization of carbohydrates

There are provided methods for the valorization of carbohydrates. The methods comprise reacting a fluid comprising at least one carbohydrate with at least one metal catalyst or at least one metal catalytic system in a fluidized bed reactor so as to obtain at least one organic acid or a derivative thereof.

METHOD FOR THE HYDROGENATION OF ORGANIC COMPOUNDS IN THE PRESENCE OF CO AND A FIXED CATALYST BED WHICH CONTAINS MONOLITHIC SHAPED CATALYST BODY

A process for hydrogenating a hydrogenatable organic compound in a reactor including a fixed catalyst bed. The fixed catalyst bed includes monolithic shaped catalyst bodies having pores and/or channels. The catalyst bodies include at least one element selected from Ni, Fe, Co, Cu, Cr, Pt, Ag, Au, Pd, Mn, Re, Ru, Rh and Ir. The CO content in the gas phase within the reactor during hydrogenation is within a range from 0.1 to 10,000 ppm by volume. In any section in the normal plane to flow direction through the fixed catalyst bed, at least 90% of the pores and channels have an area of not more than 3 mm. 1. A process for hydrogenating a hydrogenatable organic compound in at least one reactor comprising a fixed catalyst bed comprising monolithic shaped catalyst bodies or consisting of monolithic shaped catalyst bodies comprising at least one element selected from Ni , Fe , Co , Cu , Cr , Pt , Ag , Au , Pd , Mn , Re , Ru , Rh and Ir , wherein the CO content in the gas phase within the reactor during the hydrogenation is within a range from 0.1 to 10 000 ppm by volume and wherein the fixed catalyst bed comprises shaped catalyst bodies having pores and/or channels , and wherein , in any section in the normal plane to flow direction through the fixed catalyst bed , at least 90% of the pores and channels , have an area of not more than 3 mm.2. The process according to claim 1 , wherein the compound used for hydrogenation is selected from butyne-1 claim 1 ,4-diol claim 1 , butene-1 claim 1 ,4-diol claim 1 , 4-hydroxybutyraldehyde claim 1 , hydroxypivalic acid claim 1 , hydroxypivalaldehyde claim 1 , n-butyraldehyde claim 1 , isobutyraldehyde claim 1 , n-valeraldehyde claim 1 , isovaleraldehyde claim 1 , 2-ethylhex-2-enal claim 1 , 2-ethylhexanal claim 1 , the isomeric nonanals claim 1 , cyclododeca-1 claim 1 ,5 claim 1 ,9-triene claim 1 , benzene claim 1 , furan claim 1 , furfural claim 1 , phthalic esters claim 1 , acetophenone and alkyl-substituted acetophenones.3. The ...

Supported Catalyst, Its Activated Form, and their Preparation and Use

A supported catalyst and preparation method thereof, the catalyst comprising an organic polymer material carrier and Raney alloy particles supported on the organic polymer material carrier, wherein substantially all of the Raney alloy particles are partially embedded in the organic polymer material carrier. The catalyst can be used in hydrogenation, dehydrogenation, amination, dehalogenation or desulfuration reactions. 1. A supported catalyst , comprising: an organic polymer material support and Raney alloy particles supported on the organic polymer material support , wherein substantially all of the Raney alloy particles are partially embedded into the organic polymer material support.2. The catalyst of claim 1 , wherein the Raney alloy comprises at least one Raney metal and at least one leachable element.3. The catalyst of claim 2 , wherein the at least one Raney metal is chosen from nickel claim 2 , cobalt claim 2 , copper claim 2 , and iron claim 2 , and the at least one leachable element is chosen from aluminum claim 2 , zinc claim 2 , and silicon.4. The catalyst of claim 2 , wherein the weight ratio of the Raney metal to the leachable element in the Raney alloy is from 1:99 to 10:1.5. The catalyst of claim 4 , wherein the weight ratio of the Raney metal to the leachable element in the Raney alloy is from 1:10 to 4:1.6. The catalyst of claim 2 , wherein the Raney alloy further comprises at least one promoter chosen from Mo claim 2 , Cr claim 2 , Ti claim 2 , and Ru in an amount of from 0.01 wt. % to 5 wt. % claim 2 , based on the total weight of the Raney alloy.7. The catalyst of any one of to claim 2 , wherein the organic polymer material is a plastic or a modified plastic.8. The catalyst of any one of to claim 2 , wherein the organic polymer material is chosen from polyolefins claim 2 , polyamides claim 2 , polystyrenes claim 2 , epoxy resins claim 2 , phenolic resins claim 2 , and mixtures and blends thereof.9. The catalyst of any one of to claim 2 , wherein ...

Process and catalyst for preparing 1,4-butanediol

The present invention relates to a process for preparing 1,4-butanediol (BDO) by hydrogenating 2-butyne-1,4-diol (BYD) or 4-hydroxybutanal (4-HBA) in the presence of a catalyst of the Raney type having a porous foam structure, wherein the macroscopic pores have sizes in the range of 100 to 5000 μm, and a bulk density of up to 0.8 kg/L.

FIXED CATALYST BED COMPRISING METAL FOAM BODIES

The present invention relates to a fixed bed of catalytically active metal foam bodies having a volume of not more than 500 mL which consist to an extent of at least 95 wt % of metals. The fixed bed is used for catalytic reactions in a three-phase reaction mixture. 117-. (canceled)18. A fixed bed comprising catalytically active metal foam bodies for catalytic reaction of at least one reactant component in a liquid phase and at least one gaseous component , wherein the catalytically active metal foam bodies have a volume of not more than 500 millilitres , comprise at least 95 wt % of metals and are arranged as bulk goods in a packed bed.19. The fixed bed of claim 18 , wherein the catalytically active metal foam bodies comprise one or more metals selected from the group consisting of: nickel claim 18 , cobalt claim 18 , iron claim 18 , silver claim 18 , platinum claim 18 , chromium claim 18 , molybdenum and tungsten.20. The fixed bed of claim 19 , wherein the catalytically active metal foam bodies further comprise up to 25 wt % of Al.21. The fixed bed claim 18 , wherein the catalytically active metal foam bodies have an oxygen content of not more than 7500 ppm.22. The fixed bed of claim 18 , wherein the catalytically active metal foam bodies are present in the fixed bed as a loose fill material claim 18 , wherein a volume of 1 L of this loose fill material has a weight of not more than 0.8 kg.23. The fixed bed of claim 18 , wherein the catalytically active metal foam bodies are in the form of cylindrical claim 18 , ring-shaped claim 18 , cuboid claim 18 , parallelepipedal or cubic bodies.24. The fixed bed of claim 23 , wherein the catalytically active metal foam bodies have a cylindrical shape claim 23 , wherein the cylindrical shape has been generated by winding a metal foam sheet.25. The fixed bed of claim 24 , wherein the metal foam sheet has been corrugated before winding.26. The fixed bed of claim 18 , wherein the catalytically active metal foam bodies have ...

CATALYTIC REACTOR

A catalytic reactor for industrial-scale hydrogenation processes is described. The catalytic reactor contains a catalytic fixed bed that comprises a support structure and a catalyst. During operation of the reaction in the catalytic reactor, the fixed bed is filled with reaction medium to at least 85% by volume. A very high contact area of the catalyst with the reaction medium is at the same time provided. The support structure is formed from material webs having a thickness of 5 to 25 μm, with a crosslinking density of at least 3 mmpresent. The support structure consists of metals selected from elements of groups 8, 6 and 11 of the periodic table of the elements and mixtures thereof. 112-. (canceled)13. A catalytic reactor , comprising a catalytic fixed bed having a volume V , a support structure and a catalyst , wherein , during a reaction , the catalytic fixed bed is filled with a reaction medium to at least 85% by volume and the contact area of the catalyst with the reaction medium is at least 2000 mper mvolume of the catalytic fixed bed; and wherein:{'sup': '−3', 'a) the support structure is formed from material webs having a thickness of 5 to 25 μm, with a crosslinking density of at least 3 mmpresent;'}b) the support structure consists of metals selected from elements of groups 8, 6 and 11 of the periodic table of the elements and mixtures thereof;c) the support structure is catalytically inert and serves as a support body for a catalyst that is applied to the support structure in the form of a catalytically active coating.14. The catalytic reactor of claim 13 , wherein the proportion of the catalyst applied to the support structure through coating is 2 to 500 kg per mvolume of the catalytic fixed bed.15. The catalytic reactor of claim 14 , wherein the catalyst comprises: 60% to 99.8% by weight of support oxides and 0.2% to 10% by weight of catalytically active components claim 14 , wherein the percentages are claim 14 , in each case claim 14 , based on the ...

PROCESS FOR RECOVERING A METALLIC COMPONENT

A process for recovering a metallic component from a hydrocarbon product stream is disclosed. The hydrocarbon product stream is subjected to a thermal oxidation. A process for preparing glycols from a saccharide-containing feedstock is additionally disclosed. 1. A process for recovering a metallic component from a hydrocarbon product stream comprising steps of:(a) subjecting the hydrocarbon product stream to a thermal oxidation at a temperature of from 300 to 750° C., thereby providing a solid residue; and(b) collecting the solid residue.2. A process according to claim 1 , wherein the metallic component comprises one or more compound claim 1 , complex or elemental material comprising tungsten claim 1 , molybdenum claim 1 , lanthanum or tin claim 1 , or wherein the metallic component comprises an alkali metal.3. A process according to claim 2 , wherein the metallic component comprises one or more material selected from the list consisting of tungstic acid claim 2 , molybdic acid claim 2 , ammonium tungstate claim 2 , ammonium metatungstate claim 2 , ammonium paratungstate claim 2 , tungstate compounds comprising at least one Group I or II element claim 2 , metatungstate compounds comprising at least one Group I or II element claim 2 , paratungstate compounds comprising at least one Group I or II element claim 2 , heteropoly compounds of tungsten claim 2 , heteropoly compounds of molybdenum claim 2 , tungsten oxides claim 2 , molybdenum oxides and combinations thereof.4. A process according to claim 1 , wherein the temperature of the thermal oxidation is from 350 to 500° C.5. A process according to claim 1 , wherein the solid residue is dissolved in a solvent claim 1 , thereby providing a solution.6. A process for preparing glycols from a saccharide-containing feedstock comprising steps of:(i) providing a saccharide-containing feedstock, water and hydrogen to a reactor, wherein the reactor contains at least two active catalytic components, said active catalyst ...

Catalyst with Supplement Component for Hydroprocessing of Bio-feedstock

A process for hydrogenation of oxygen-containing organic products, oil refinery products or mixtures thereof, wherein the process comprises bringing the organic products, oil refinery products, or mixtures thereof into contact with a catalyst according to claim 1 in the presence of hydrogen gas at a temperature in the range of 200 to 500° C. and at a pressure in the range of 10 to 1000 bar.

PROCESSES AND CATAYLST SYSTEMS FOR PRODUCING MONOETHANOLAMINE FROM GLYCOLALDEHYDE

Improvements in catalyst systems and associated processes for the conversion of glycolaldehyde to monoethanolamine are disclosed. The catalyst systems exhibit improved selectivity to this desired product and consequently reduced selectivity to byproducts such as diethanolamine and ethylene glycol. These beneficial effects are achieved through the use of acids, and particularly Lewis acids, as co-catalysts of the reductive amination reaction, in conjunction with a hydrogenation catalyst.

COMPOSITE CATALYST AND PREPARATION METHOD THEREFOR

Disclosed is a composite catalyst, comprising carbon in a continuous phase and Raney alloy particles in a dispersed phase. The Raney alloy particles are dispersed evenly or unevenly in the carbon in a continuous phase, and the carbon in a continuous phase is obtained by carbonizing at least one carbonizable organic substance. The catalyst has good particle strength, high catalytic activity, and good selectivity. 1. An activated catalyst , comprising carbon as a continuous phase , activated Raney alloy particles as a dispersed phase dispersed in the continuous phase , and at least one promoter selected from the group consisting of Mo , Cr , Ti , Pt , Pd , Rh and Ru ,wherein the activated Raney alloy particles comprise at least one first metal selected from the group consisting of nickel, cobalt, copper and iron, andwherein the activated catalyst has a porous structure.2. The activated catalyst of claim 1 , wherein the activated Raney alloy particles have a content of from 10 wt. % to 90 wt. % claim 1 , based on the total weight of the activated catalyst.3. The activated catalyst of claim 1 , wherein the activated Raney alloy particles have a content of from 40 wt. % to 80 wt. % claim 1 , based on the total weight of the activated catalyst.4. The activated catalyst of claim 1 , wherein the at least one promoter has a content of from 0.01 wt % to 5 wt % of the total weight of the Raney alloy particles.5. The activated catalyst of claim 1 , wherein that the activated Raney alloy particles have an average particle size of from 0.1 micron to 1000 microns.6. The activated catalyst of claim 1 , wherein the activated catalyst is in a shape selected from the group consisting of sphere claim 1 , semi-sphere claim 1 , ring claim 1 , semi-ring claim 1 , trilobal extrudate claim 1 , cylinder claim 1 , semi-cylinder claim 1 , hollow cylinder claim 1 , prism claim 1 , cube claim 1 , cuboid claim 1 , tablet claim 1 , pellet claim 1 , tooth claim 1 , and irregular particles.7. The ...

METHOD FOR ACID TREATMENT CONDITIONING OF A CATALYST IN THE PRODUCTION OF GLYCOLS

Implementations of the disclosed subject matter provide methods for producing ethylene glycol from a carbohydrate feed which may include conditioning a heterogeneous hydrogenation catalyst by treatment with a protic acid resulting in an acid-conditioned heterogeneous hydrogenation catalyst. Next, in a reactor under hydrogenation conditions, the carbohydrate feed may be contacted with a bi-functional catalyst system comprising the acid-conditioned heterogeneous hydrogenation catalyst, and a soluble retro-Aldol catalyst. An intermediate product stream may be obtained from the reactor including ethylene glycol. 1. A method for producing ethylene glycol from a carbohydrate feed comprising:a) conditioning a heterogeneous hydrogenation catalyst by treatment with a protic acid resulting in an acid-conditioned heterogeneous hydrogenation catalyst; 1) the acid-conditioned heterogeneous hydrogenation catalyst, and', '2) a soluble retro-Aldol catalyst;, 'b) contacting, in a first reactor under hydrogenation conditions, the carbohydrate feed with a bi-functional catalyst system comprisingc) obtaining an intermediate product stream, from the first reactor, comprising ethylene glycol.2. The method of claim 1 , wherein the protic acid is at least one selected from the group consisting of: organic acid claim 1 , mineral acid claim 1 , and combinations thereof.3. The method of claim 2 , wherein the organic acid is at least one selected from the group consisting of: formic acid claim 2 , acetic acid claim 2 , propionic acid claim 2 , butyric acid claim 2 , glycolic acid claim 2 , lactic acid claim 2 , citric acid claim 2 , benzoic acid claim 2 , and combinations thereof.4. The method of claim 3 , wherein the organic acid is at least one selected from the group consisting of: lactic acid claim 3 , glycolic acid claim 3 , and combinations thereof.5. The method of claim 2 , wherein the mineral acid is at least one selected from the group consisting of: HCl claim 2 , HSO claim 2 , HPO ...

Acid-Resistant Alloy Catalyst

Disclosed is an acid-resistant alloy catalyst comprising nickel, one or more rare earth elements, stannum and aluminum. The acid-resistant alloy catalyst is low-cost and stable, and does not need a carrier, and can be stably used in continuous industrial production, thus achieving a low production cost. 1. A composite catalyst comprising (i) an acid-resistant alloy catalyst , characterized by comprising nickel , one or more rare earth elements , tin and aluminium and (ii) a cocatalyst consisting of a soluble tungstic acid salt and/or an insoluble tungsten compound.2. The composite catalyst of claim 1 , wherein the acid-resistant alloy catalyst comprises in parts by weight claim 1 , 10-90 parts nickel claim 1 , 1-5 parts rare earth element claim 1 , 1-60 parts tin and 5-9 parts aluminium.3. The composite catalyst of claim 1 , wherein the acid-resistant alloy catalyst further comprises tungsten.4. The composite catalyst of claim 3 , wherein the acid-resistant alloy catalyst comprises in parts by weight claim 3 , 10-90 parts nickel claim 3 , 1-5 parts rare earth element claim 3 , 1-60 parts tin claim 3 , 5-9 parts aluminium and 1-90 parts tungsten.5. The composite catalyst of claim 1 , wherein the acid-resistant alloy catalyst further comprises tungsten and molybdenum.6. The composite catalyst of claim 5 , wherein the acid-resistant alloy catalyst comprises in parts by weight claim 5 , 10-90 parts nickel claim 5 , 1-5 parts rare earth element claim 5 , 1-60 parts tin claim 5 , 5-9 parts aluminium claim 5 , 1-90 parts tungsten and 0.5-20 parts molybdenum.7. The composite catalyst of claim 1 , wherein the acid-resistant alloy catalyst further comprises tungsten claim 1 , molybdenum claim 1 , and boron or phosphorus.8. The composite catalyst of claim 7 , wherein the acid-resistant alloy catalyst comprises in parts by weight claim 7 , 10-90 parts nickel claim 7 , 1-5 parts rare earth element claim 7 , 1-60 parts tin claim 7 , 5-9 parts aluminium claim 7 , 1-90 parts ...

PROCESS FOR THE PREPARATION OF GLYCOLS

A process for the preparation of glycols from a saccharide-containing feedstock having the steps of: (a) preparing a reaction mixture in a reactor vessel comprising the saccharide-containing feedstock, a solvent, hydrogen, a catalyst component with retro-aldol catalytic capabilities and a first hydrogenation catalyst comprising an element selected from groups 8, 9 and 10 of the periodic table; (b) monitoring the hydrogenation activity in the reactor vessel; (c) when the activity of the first hydrogenation catalyst declines, as indicated by the crossing of a threshold, supplying into the reaction mixture in the reactor vessel a catalyst precursor comprising one or more elements selected from groups 8, 9, 10 and 11 of the periodic table; and (d) converting the catalyst precursor in the presence of hydrogen in the reactor vessel to a second hydrogenation catalyst to supplement the declined hydrogenation activity in the reactor vessel. 1. A process for the preparation of glycols from a saccharide-containing feedstock comprising the steps of:(a) preparing a reaction mixture in a reactor vessel comprising the saccharide-containing feedstock, a solvent, a catalyst component with retro-aldol catalytic capabilities and a first hydrogenation catalyst comprising an element selected from groups 8, 9 and 10 of the periodic table;(b) supplying hydrogen gas into the reaction mixture in the reactor vessel;(c) monitoring the hydrogenation activity in the reactor vessel;(d) when the hydrogenation activity declines, supplying into the reaction mixture in the reactor vessel a catalyst precursor comprising one or more elements selected from groups 8, 9, 10 and 11 of the periodic table; and(e) converting the catalyst precursor in the presence of hydrogen in the reactor vessel to a second hydrogenation catalyst to supplement the declined hydrogenation activity in the reactor vessel.2. The process according to wherein the catalyst precursor comprises one or more cations selected from a ...

FULL CONTINUOUS FLOW PREPARATION METHOD OF 2-METHYL-4-AMINO-5-AMINOMETHYLPYRIMIDINE

A full continuous flow preparation method of 2-methyl-4-amino-5-aminomethylpyrimidine. A mixed solution of cyanoacetamide, N,N-dimethylformamide and a catalyst is mixed with phosphorus oxychloride in a first micro-mixer, and then the reaction mixture undergoes continuous flow reaction in a microchannel reactor to obtain (dimethylaminomethylene) malononitrile. The reaction mixture is subjected to continuous quenching, extraction and separation, and the organic phase is concentrated, mixed with a methanol solution, and then reacted with an organic base to obtain 2-methyl-4-amino-5-cyanopyrimidine. After the mixed liquid is continuously filtered, the filter cake is dissolved in methanol, mixed with hydrogen in a second micro-mixer, and then transported to a fixed-bed reactor for hydrogenation reaction. The products are concentrated, dried and purified to obtain the desired 2-methyl-4-amino-5-aminomethylpyrimidine. 2. The method of claim 1 , wherein in step (1) claim 1 , the catalyst is a pyridine compound; and a molar ratio of cyanoacetamide to N claim 1 ,N-dimethylformamide to the catalyst to phosphorus oxychloride is 1:(1-10):(0.05-0.8):(1-10).3. The method of claim 1 , wherein in step (1) claim 1 , the microchannel reactor consists of a first part and a second part; a reaction temperature of the first part is −20-80° C. claim 1 , and a reaction temperature of the second part is −20-80° C.; a residence time of the reaction mixture in the first part is 0.2-30 minutes claim 1 , and a residence time of the reaction mixture in the second part is 1-60 minutes; and a back pressure of the microchannel reactor is 0.1-5 MPa.4. The method of claim 1 , wherein in step (2) claim 1 , a mass fraction of the inorganic base in the aqueous solution of the inorganic base is 5-50%; the inorganic base is selected from the group consisting of lithium carbonate claim 1 , sodium carbonate claim 1 , potassium carbonate claim 1 , lithium bicarbonate claim 1 , sodium bicarbonate claim 1 , ...

Process for production of aromatic compounds comprising at least two amine functions

Provided is a process for the production of an aromatic compound comprising at least two amine functions, comprising reacting an aromatic compound having at least one hydroxyl function and at least one aldehyde function with a second reactant having an amine function, in the presence of a reductant agent and a catalyst comprising at least one metal element in elemental form and/or at least one metal oxide.

Nano-skeletal catalyst

A method of producing a catalyst material with nano-scale structure, the method comprising: introducing a starting powder into a nano-powder production reactor, the starting powder comprising a catalyst material; the nano-powder production reactor nano-sizing the starting powder, thereby producing a nano-powder from the starting powder, the nano-powder comprising a plurality of nano-particles, each nano-particle comprising the catalyst material; and forming a catalyst precursor material from the nano-powder, wherein the catalyst precursor material is a densified bulk porous structure comprising the catalyst material, the catalyst material having a nano-scale structure.

METHOD FOR PRODUCING HEXAMETHYLENEDIAMINE

The invention relates to a method for producing hexamethylenediamine, wherein a) a muconic acid starting material is provided, which is selected from among muconic acid, esters of muconic acid, lactones of muconic acid, and mixtures thereof, b) the muconic acid starting material is subjected to a reaction with hydrogen in the presence of at least one hydrogenation catalyst in order to form 1,6-hexanediol, and c) the 1,6-hexanediol obtained in step b) is subjected to amination in the presence of an amination catalyst in order to obtain hexamethylenediamine. The invention further relates to hexamethylenediamine which can be produced by means of said method. 126.-. (canceled)2823. The process according to claim , wherein the muconic acid starting material provided in step a) originates from a renewable source.2923. The process according to claim , wherein the muconic acid starting material provided in step a) has a C-to-C isotope ratio in the range from 0.5×10to 5×10.3023. The process according to claim , wherein the hydrogenation in step b) is effected using a muconic acid starting material selected from the group consisting of muconic acid , muconic acid monoesters , muconic acid diesters , poly(muconic acid esters) and mixtures thereof.3123. The process according to claim , wherein the hydrogenation in step b) is effected using a muconic acid starting material selected from the group consisting of lactones (III) , (IV) and (V) and mixtures thereof: t ,?3223. The process according to claim , wherein the hydrogenation in step b) is effected in the liquid phase in the presence of a solvent selected from the group consisting of water , aliphatic Cto Calcohols , aliphatic Cto Cdiols , ethers and mixtures thereof.3323. The process according to claim , wherein the hydrogenation in step b) is effected in the liquid phase in the presence of water as the sole solvent.3423. The process according to claim , wherein the hydrogenation in step b) is effected using a muconic acid ...

CATALYST SYSTEM AND PROCESS FOR THE PRODUCTION OF GLYCOLS

The invention provides a catalyst system comprising: a) one or more sodium metatungstate-containing species; and b) one or more catalytic species suitable for hydrogenation; and a process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor in the presence of a solvent and said catalyst system. 1. A catalyst system comprising:a) one or more sodium metatungstate-containing species; andb) one or more catalytic species suitable for hydrogenation.2. The catalyst system according to claim 1 , wherein the weight ratio of the one or more sodium metatungstate-containing species to the one or more catalytic species suitable for hydrogenation is at least 1:1 claim 1 , on the basis of the total weight of the catalyst system.3. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are selected from one or more transition metals from Groups 8 claim 1 , 9 or 10 of the Periodic Table claim 1 , or compounds thereof.4. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are selected from one or more transition metals selected from the group of cobalt claim 1 , iron claim 1 , platinum claim 1 , palladium claim 1 , ruthenium claim 1 , rhodium claim 1 , nickel claim 1 , iridium claim 1 , and compounds thereof.5. The catalyst system according claim 1 , wherein the one or more catalytic species suitable for hydrogenation are solid claim 1 , unsupported species.6. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are on solid catalyst supports.7. The catalyst system according to claim 6 , wherein the solid catalyst support is selected aluminas claim 6 , silicas claim 6 , zirconium oxide claim 6 , magnesium oxide claim 6 , zinc oxide claim 6 , titanium oxide claim 6 , carbon claim 6 , activated carbon ...

CATALYST SYSTEM AND PROCESS FOR THE PRODUCTION OF GLYCOLS

The invention provides a catalyst system comprising: a) one or more catalytic species comprising silver and tungsten therein; and b) one or more catalytic species suitable for hydrogenation; and a process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor in the presence of a solvent and said catalyst system. 1. A catalyst system comprising:a) one or more catalytic species comprising silver and tungsten therein; andb) one or more catalytic species suitable for hydrogenation.2. The catalyst system according to claim 1 , wherein the one or more catalytic species comprising silver and tungsten therein are selected from silver tungstate-containing species and/or silver phosphotungstate-containing species.3. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are selected from one or more transition metals from Groups 8 claim 1 , 9 or 10 of the Periodic Table claim 1 , and compounds thereof.4. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are selected from one or more transition metals selected from the group of cobalt claim 1 , iron claim 1 , platinum claim 1 , palladium claim 1 , ruthenium claim 1 , rhodium claim 1 , nickel claim 1 , iridium claim 1 , and compounds thereof.5. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are solid claim 1 , unsupported species.6. The catalyst system according to claim 1 , wherein the one or more catalytic species comprising silver and tungsten therein and/or the one or more catalytic species suitable for hydrogenation are on a solid catalyst supports.7. The catalyst system according to claim 6 , wherein the solid catalyst supports are selected from aluminas claim 6 , silicas claim 6 , zirconium oxide claim 6 , magnesium oxide claim 6 ...

REGENERATION OF CATALYST FOR HYDROGENATION OF SUGARS

A process for regenerating catalysts that have been deactivated or poisoned during hydrogenation of biomass, sugars and polysaccharides is described, in which polymerized species that have agglomerated to catalyst surfaces can be removed by means of washing the catalyst with hot water at subcritical temperatures. A feature of the process can regenerate the catalysts in situ, which allows the process to be adapted for used in continuous throughput reactor systems. Also described is a continuous hydrogenation process that incorporated the present regeneration process. 1. A method of regenerating hydrogenation catalyst activity in-situ , the method comprising: a) providing a hydrogenation reactor , said reactor being configured to have a first and a second vessel , said first vessel having a first catalyst and said second vessel having a second catalyst , said first and second catalysts being either the same or a different material; and b) rinsing each respective vessel and catalyst with subcritical deionized water of between about 130° C.-250° C. for an extended period.2. The method according to claim 1 , wherein said method further comprises: introducing a subcritical deionized aqueous solution containing HOin a concentration of ≦7% by volume to said first catalyst in said first vessel of said reactor when catalytic activity of said first catalyst decreases to a predetermined level; or introducing periodically an aqueous salt solution to either 1) said first catalyst in first vessel or 2) said second catalyst when catalytic activity of said second catalyst decreases to a predetermined level; removing respectively said aqueous HOsolution from said first vessel and said aqueous salt solution from said first or second vessels of said reactor.3. The method according to claim 1 , wherein said first and second vessels are arranged either in serial communication or in parallel communication with each other.4. The method according to claim 1 , wherein said first or second ...

CATALYST SYSTEM AND PROCESS FOR THE PRODUCTION OF GLYCOLS

The invention provides a catalyst system comprising: a) one or more Group 1 metal phosphotungstate-containing species; and b) one or more catalytic species suitable for hydrogenation; and a process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor in the presence of a solvent and said catalyst system. 1. A catalyst system comprising:a) one or more Group 1 metal phosphotungstate-containing species; andb) one or more catalytic species suitable for hydrogenation.2. The catalyst system according to claim 1 , wherein the one or more Group 1 metal phosphotungstate-containing species are selected from sodium phosphotungstate-containing species and/or caesium phosphotungstate-containing species.3. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are selected from one or more transition metals from Groups 8 claim 1 , 9 or 10 of the Periodic Table claim 1 , and compounds thereof.4. The catalyst system according to Claim 1 , wherein the one or more catalytic species suitable for hydrogenation are selected from one or more transition metals selected from the group of cobalt Claim 1 , iron Claim 1 , platinum Claim 1 , palladium Claim 1 , ruthenium Claim 1 , rhodium Claim 1 , nickel Claim 1 , iridium Claim 1 , and compounds thereof.5. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are solid claim 1 , unsupported species.6. The catalyst system according to claim 1 , wherein the one or more Group 1 metal phosphotungstate-containing species and/or the one or more catalytic species suitable for hydrogenation are on solid catalyst supports.7. The catalyst system according to claim 6 , wherein the solid catalyst supports are selected from aluminas claim 6 , silicas claim 6 , zirconium oxide claim 6 , magnesium oxide claim 6 , zinc oxide claim 6 , ...

METHOD FOR IMPROVING CATALYTIC ACTIVITY

The present invention relates to a method for improving the catalytic activity of an oxygen evolution reaction (OER) catalyst comprising a substrate with a catalytic metallic composite coating. The method comprises exposing the metallic composite coating to a reducing agent to thereby increase oxygen vacancy density in the metallic composite coating. 1. A method for improving the catalytic activity of an oxygen evolution reaction (OER) catalyst comprising a substrate with a catalytic metallic composite coating , the method comprising:(i) exposing the metallic composite coating to a reducing agent,to thereby increase oxygen vacancy density in the metallic composite coating.2. The method according to claim 1 , wherein the metallic composite coating comprises a bimetallic composite.3. The method according to claim 2 , wherein the bimetallic composite is a bimetallic oxide composite claim 2 , a bimetallic hydroxide composite or a mixture thereof.4. The method according to claim 2 , wherein the bimetallic composite is selected from the group consisting of a nickel-iron composite claim 2 , a nickel-cobalt composite claim 2 , a manganese-iron composite claim 2 , a manganese-cobalt composite claim 2 , or a manganese-zinc composite.5. The method according to claim 4 , wherein the bimetallic composite is a nickel-iron composite.6. The method according to claim 5 , wherein the nickel-iron composite comprises a nickel-iron oxide claim 5 , a nickel-iron hydroxide claim 5 , or a mixture thereof.7. The method according to claim 5 , wherein the nickel-iron composite has a formula of NiFe(OH) claim 5 , wherein x is a number between about 0.1 and about 2 and y is a number between about 0.1 and about 2.8. The method according to claim 1 , wherein the metallic composite is porous.9. The method according to claim 1 , wherein the metallic composite is amorphous.10. The method according to claim 9 , wherein the amorphous metallic composite coating comprises nanosheets claim 9 , nanoflakes ...

NANO-SKELETAL CATALYST

A method of producing a catalyst material with nano-scale structure, the method comprising: introducing a starting powder into a nano-powder production reactor, the starting powder comprising a catalyst material; the nano-powder production reactor nano-sizing the starting powder, thereby producing a nano-powder from the starting powder, the nano-powder comprising a plurality of nano-particles, each nano-particle comprising the catalyst material; and forming a catalyst precursor material from the nano-powder, wherein the catalyst precursor material is a densified bulk porous structure comprising the catalyst material, the catalyst material having a nano-scale structure. 1. A method of producing a catalyst material with nano-scale structure , the method comprising:providing a starting powder into a nano-powder production reactor, the starting powder comprising a catalyst material;nano-sizing the starting powder in the nano-powder production reactor, thereby producing a nano-powder from the starting powder, the nano-powder comprising a plurality of nano-particles, each nano-particle comprising the catalyst material; andforming a catalyst precursor material from the nano-powder, wherein the catalyst precursor material is a densified bulk porous structure comprising the catalyst material and a filler material, the catalyst material having a nano-scale structure; andremoving filler material from the bulk structure of the catalyst precursor to form a nano-scale skeletal structure comprising the catalyst material.2. (canceled)3. The method of claim 1 , wherein the step of nano-sizing the starting powder includes:generating a plasma flow within the nano-powder production reactor;and applying the plasma flow to the starting powder.4. The method of claim 1 , wherein the step of forming a catalyst precursor material includes pressing the nano-powder.5. The method of claim 1 , wherein the step of forming a catalyst precursor material includes bonding the nano-powder using spark ...

2-(3-(aminomethyl)-3,5,5-trimethylcyclohexyl)propane-1,3-diamine, a process for its production and use

A compound of the structural formula 1 Also disclosed is a process for producing 2-(3-(aminomethyl)-3,5,5-trimethylcyclohexyl)propane-1,3-diamine by A) reacting isophorone nitrile and malononitrile to afford the intermediate 2-(3-cyano-3,5,5-trimethylcyclohexylidene)malononitrile, and B) hydrogenating 2-(3-cyano-3,5,5-trimethylcyclohexylidene)malononitrile in the presence of at least one catalyst. In another embodiment, the hydrogenation in step B) of the process is performed at 20-120° C. and at 20-300 bar.

Composite catalyst and preparation method therefor

Disclosed is a composite catalyst, comprising carbon in a continuous phase and Raney alloy particles in a dispersed phase. The Raney alloy particles are dispersed evenly or unevenly in the carbon in a continuous phase, and the carbon in a continuous phase is obtained by carbonizing at least one carbonizable organic substance. The catalyst has good particle strength, high catalytic activity, and good selectivity.

PROCESS FOR PREPARING 3 AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE

Process for preparing isophoronediamine, characterized in that 1. A process for preparing isophoronediamine , whereinA) isophoronenitrile is subjected directly in one stage to aminating hydrogenation to give isophoronediamine in the presence of ammonia, hydrogen, a hydrogenation catalyst and possibly further additions, and in the presence or absence of organic solvents; orB) isophoronenitrile is first converted fully or partly in at least two or more than two stages to isophoronenitrile imine, and this isophoronenitrile imine is subjected to aminating hydrogenation to give isophoronediamine as a pure substance or in a mixture with other components and/or isophoronenitrile, in the presence of at least ammonia, hydrogen and a catalyst;where the catalyst has the following properties:I.the catalyst has, after the activation, in its entirety, the following composition in per cent by weight (% by weight), where the proportions add up to 100% by weight, based on the metals present:cobalt: 55% to 95% by weightaluminium: 5% to 45% by weightchromium: 0% to 3% by weightnickel: 0% to 7% by weight andII.the catalyst is in the form of irregular particles as a granular material and, after the activation, has particle sizes of 1 to 8 millimetres (mm).2. The process for preparing isophoronediamine according to claim 1 , whereinI.the catalyst has, after the activation, in its entirety, the following composition in per cent by weight (% by weight), where the proportions add up to 100% by weight, based on the metals present:cobalt: 55% to 90% by weightaluminium: 5% to 44.5% by weightchromium: 0.5% to 5% by weight3. The process for preparing isophoronediamine according to claim 1 , whereinI.the catalyst has, after the activation, in its entirety, the following composition in per cent by weight (% by weight), where the proportions add up to 100% by weight, based on the metals present:cobalt: 55% to 88% by weightaluminium: 5% to 44.5% by weightnickel: 0.5% to 7% by weight4. The process ...

Methods for Preparing Diol

Provided is a method for preparing a diol. In the method, a saccharide and hydrogen as raw materials are contacted with a catalyst in water to prepare the diol. The employed catalyst is a composite catalyst comprised of a main catalyst and a cocatalyst, wherein the main catalyst is a water-insoluble acid-resistant alloy; and the cocatalyst is a soluble tungstate and/or soluble tungsten compound. The method uses an acid-resistant, inexpensive and stable alloy needless of a support as a main catalyst, and can guarantee a high yield of the diol in the case where the production cost is relatively low. 1. A method for preparing a diol , characterized in that the method uses a sugar and hydrogen as starting materials , which are brought into contact with a catalyst in water to prepare a diol; the catalyst used is a composite catalyst , consisting of a main catalyst and a cocatalyst ,whereinthe main catalyst is a water-insoluble acid-resistant alloy;the cocatalyst is a soluble tungstic acid salt and/or an insoluble tungsten compound.2. The method for preparing a diol as claimed in claim 1 , characterized in that the diol is ethylene glycol.3. The method for preparing a diol as claimed in claim 2 , characterized in that the reaction system pH is 1-7; more preferably claim 2 , the reaction system pH is 3-6.4. The method for preparing a diol as claimed in or claim 2 , characterized in that the sugar is selected from one or more of five-carbon monosaccharides claim 2 , disaccharides and oligosaccharides claim 2 , six-carbon monosaccharides claim 2 , disaccharides and oligosaccharides claim 2 , soluble five-carbon polysaccharides claim 2 , and soluble six-carbon polysaccharides.5. The method for preparing a diol as claimed in claim 4 , characterized in that the soluble five-carbon polysaccharides and soluble six-carbon polysaccharides are five-carbon polysaccharides and six-carbon polysaccharides which can dissolve under the reaction conditions of the system.6. The method for ...

Process for producing a tetrahydrofuran compound comprising at least two amine functional groups

The present invention concerns a process for preparing a tetrahydrofuran compound comprising at least two amine functional groups by reacting a furan compound comprising at least two nitrogen-containing functional groups with hydrogen in the presence of a hydrogenation catalyst.

METHOD FOR MANUFACTURING CATALYSTS WITH REDUCED ATTRITION

The present invention discloses an inventive method for manufacturing a catalyst using alloy granules having a high-Ni content. The inventive method may include providing alloy granules comprising aluminum and nickel, and treating the alloy granules with an alkaline solution to form the catalyst. A content of the nickel in the alloy granules may be within a range of about 43 wt % to about 60 wt %. The alloy granules may have effective diameters within a range of about 1 mm to about 10 mm. The catalyst may have an attrition value of less than about 7.0%. 1. A method for manufacturing a catalyst , comprisingproviding alloy granules comprising aluminum and nickel, andtreating the alloy granules with an alkaline solution to form the catalyst,wherein a content of the nickel in the alloy granules is within a range of about 43 wt % to about 60 wt %.2. The method of claim 1 , wherein the alloy granules have effective diameters within a range of about 1 mm to about 10 mm.3. The method of claim 1 , wherein the content of the nickel in the alloy granules is within a range of about 45 wt % to about 58 wt %.4. The method of claim 1 , wherein the content of the nickel in the alloy granules is within a range of about 50 wt % to about 56 wt %.5. The method of claim 1 , wherein the content of the nickel in the alloy granules is within a range of about 50 wt % to about 53 wt %.6. The method of claim 1 , wherein the alloy granules have effective diameters within a range of about 2 mm to about 6 mm.7. The method of claim 1 , wherein the alkaline solution comprises sodium hydroxide.8. The method of claim 7 , wherein a concentration of the sodium hydroxide in the alkaline solution is within a range of 1 wt % to 20 wt %.9. The method of claim 7 , wherein a concentration of the sodium hydroxide in the alkaline solution is within a range of 1 wt % to 15 wt %.10. The method of claim 7 , wherein a concentration of the sodium hydroxide in the alkaline solution is within a range of 1 wt % to 10 ...

PROCESS FOR PRODUCING 1,3-BUTANEDIOL AND FOR OPTIONALLY FURTHER PRODUCING (R)-3-HYDROXYBUTYL (R)-3-HYDROXYBUTYRATE

A process is described for producing 1,3-butanediol, wherein an ester of poly-(R)-3-hydroxybutyrate such as formed by transesterification with an alcohol is reduced by hydrogenation in the presence of a skeletal copper-based catalyst to provide 1,3-butanediol. The 1,3-butanediol may be transesterified by reaction with additional poly-(R)-3-hydroxybutyrate ester to produce (R)-3-hydroxybutyl (R)-3-hydroxybutyrate. 1. A process for producing 1 ,3-butanediol , comprising contacting an ester of poly-(R)-3-hydroxybutyrate with a source of hydrogen in the presence of a skeletal copper-based catalyst under elevated temperature conditions , wherein the term ester of poly-(R)-3-hydroxybutyrate refers to an ester formed by reaction of poly-(R)-3-hydroxybutyrate with an alcohol and wherein the term skeletal copper-based catalyst refers to a porous catalytic alloy based material comprising copper and aluminum.2. The process of claim 1 , wherein the ester of poly-(R)-3-hydroxybutyrate is a methyl claim 1 , ethyl claim 1 , propyl claim 1 , butyl claim 1 , pentyl or hexyl ester.3. The process of claim 2 , wherein the ethyl ester is used.4. The process of any one of - claim 2 , wherein the process is conducted continuously claim 2 , using a fixed catalyst bed.5. The process of claim 4 , wherein the skeletal copper-based catalyst is a promoted or unpromoted copper-aluminum alloy catalyst containing from 10 to 60 weight percent of aluminum and with the balance consisting of copper and any promoters present.6. The process of claim 5 , wherein the catalyst contains from 20 to 55 weight percent of aluminum.7. The process of claim 1 , conducted at a reactor temperature between 120 degrees Celsius and 220 degrees Celsius claim 1 , a liquid hourly space velocity of from 0.1 hrto 2 hrand a hydrogen supply at a pressure of from 5.5 MPa claim 1 , gauge to 17.2 MPa claim 1 , gauge.8. The process of claim 7 , conducted at a reactor temperature between 150 degrees Celsius and 220 degrees Celsius ...

Process for the preparation of (1r,2r)-3-(3-dimethylamino-1-ethyl-2-methyl-propyl)-phenol

The present invention relates to a process for the preparation of (1 R,2R)-3- dimethylamino-1-ethyl-2-methyl-propyl)-phenol.

Process for the preparation of a hydrogenation catalyst

The invention concerns the production of a hydrogenation catalyser based on an aluminium/transition metal alloy. The proposed method involves producing a kneadable material from the alloy and an auxiliary agent, moulding the kneadable material into moulded articles, calcinating these articles and then treating them with an alkali metal hydroxide, using (a) polyvinyl alcohol and water or (b) stearic acid as the auxiliary agent. The invention also concerns methods of hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha , omega -dinitriles to alpha , omega -aminonitriles; and the use of the catalysers thus produced for hydrogenation and hydrogenolysis.

Process for the Preparation of (1R,2R)-3-(3-dimethylamino-1-ethyl-2-methylpropyl)-phenol

The present invention relates to a process for the preparation of (1R,2R)- 3 -dimethylamino- 1 -ethyl- 2 -methyl-propyl)-phenol.

Surface modified metallic foam body, process for its production and use thereof

The invention relates to a surface modified metallic foam body, obtainable by a process comprising the steps: (a) providing a metallic foam body comprising a first metallic material; (b) applying a second metallic material which is different from the first metallic material and which contains a first metallic compound that is leachable as such and/or that can be transformed by alloying into a second metallic compound that is leachable and different from the first metallic compound on a surface of the metallic foam body; (c) forming an alloy skin of the metallic foam body obtained in step (b) by alloying the first metallic material and the second metallic material; and (d) treating the alloyed metallic foam body obtained in step (c) with an agent that is capable of leaching out the leachable first and/or second metallic compound from the alloy skin of the metallic foam body. The invention moreover relates to a process for the production of the surface modified metallic foam body and a use of the surface modified metallic foam body.

Process for the production of a hydrogenation catalyst

A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.

Preparation of a hydrogenation catalyst

A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.

Integrated process for simultaneous production of oxo-alcohols and plasticizers

Disclosed herein are methods and systems for the simultaneous production of oxo-alcohols comprising n-butanol, isobutanol, and 2-ethylhexanol. Also disclosed are methods and systems for simultaneous production of plasticizers using the disclosed oxo-alcohols.

Raney catalyst, process for producing it and process for producing a sugar-alcohol using the same

To obtain a Raney catalyst for fixed bed permitting a continuous use with a high initial activity and to produce a high purity sugar-alcohol at a low cost using the same. For this object, sugar-alcohol is produced by: using the powder type Raney catalyst made by using for the hydrogenation under the hydrogen pressure a lump form Raney catalyst made by (i) the first step for melting nickel and aluminum, (ii) the second step for obtaining quenched lump alloy by quenching droplets of said melted mixture and (iii) the third step for classifying and activating said quenched lump alloy as it is or once it is broken, collecting said lump form Raney catalyst, crushing into powder and reactivating, and hydrogenating sugars under the hydrogen pressure.

catalyst system and process for glycol production

a invenção fornece um sistema catalisador que compreende: a) uma ou mais espécies que contêm metatungstato de sódio; e b) uma ou mais espécies cata-líticas adequadas para hidrogenação; e um processo para a preparação de monoeti-lenoglicol a partir de material de partida que compreende um ou mais sacarídeos, colocando-se o dito material de partida em contato com hidrogênio em um reator na presença de um solvente e do dito sistema catalisador. The invention provides a catalyst system comprising: a) one or more species containing sodium metatungstate; and b) one or more catalytic species suitable for hydrogenation; and a process for preparing monoethylene glycol from starting material comprising one or more saccharides by contacting said starting material with hydrogen in a reactor in the presence of a solvent and said catalyst system.

catalyst system and process for glycol production

a invenção fornece um sistema catalisador que compreende: a) uma ou mais espécies que contêm fosfotungstato de metal de grupo 1; e b) uma ou mais espécies catalíticas adequadas para hidrogenação; e um processo para a prepara-ção de monoetileno glicol a partir do material de partida que compreende um ou mais sacarídeos, colocando-se o dito material de partida em contato com hidrogênio em um reator na presença de um solvente e do dito sistema catalisador. The invention provides a catalyst system comprising: a) one or more group 1 metal phosphotungstate-containing species; and b) one or more catalytic species suitable for hydrogenation; and a process for the preparation of monoethylene glycol from the starting material comprising one or more saccharides, contacting said starting material with hydrogen in a reactor in the presence of a solvent and said catalyst system.

Activated Raney-metal catalysts made of hollow bodies

The use of ir, near ir, visable and uv radiation for the preparation of catalysts

The preparation of activated hollow bodies (e.g., spheres) with an organic (e.g., polyvinyl alcohol) and optionally inorganic binder (e.g., Ni or Co powders) containing suspension of the desired Raney-type alloy comprised of a catalytic metal, a caustic leachable metal and optionally one or more promoters. The catalytic metal can be from groups VIII and Ib and mixtures thereof optionally promoted with metals from groups Ia, IIa, IIIb, IVb, Vb, VIb, VIIb, VIII, Ib, IIb, IIIa and IVa with one or more caustic leachable materials such as Zn, Al and Si. The alloy suspension is initially sprayed onto a fluidized bed of evaporable carrier (e.g., styrofoam). This spraying can be performed in 1 or more steps depending on the need to either produce a thicker shell or to produce a catalyst with a designed layering of different alloys and/or metals. After impregnation, the coated evaporable carrier (e.g., styrofoam) is optionally dried and then calcined in equipment capable of treating the material with infrared, near infrared, visable, microwave and ultraviolet radiation. The hollow bodies of alloy are then activated in a caustic solution.

The use of ir, near ir, visible and uv radiation for the preparation of catalysts

The preparation of activated hollow bodies (e.g., spheres) with an organic (e.g., polyvinyl alcohol) and optionally inorganic binder (e.g., Ni or Co powders) containing suspension of the desired Raney-type alloy comprised of a catalytic metal, a caustic leachable metal and optionally one or more promoters. The catalytic metal can be from groups VIII and Ib and mixtures thereof optionally promoted with metals from groups Ia, IIa, IIIb, IVb, Vb, VIb, VIIb, VIII, Ib, IIb, IIIa and IVa with one or more caustic leachable materials such as Zn, Al and Si. The alloy suspension is initially sprayed onto a fluidized bed of evaporable carrier (e.g., styrofoam). This spraying can be performed in 1 or more steps depending on the need to either produce a thicker shell or to produce a catalyst with a designed layering of different alloys and/or metals. After impregnation, the coated evaporable carrier (e.g., styrofoam) is optionally dried and then calcined in equipment capable of treating the material with infrared, near infrared, visable, microwave and ultraviolet radiation. The hollow bodies of alloy are then activated in a caustic solution.

Activated base metal catalysts

본 발명에서, 니트로-화합물은, 활성화 동안 및/또는 활성화 후에 Mg, Ca, Ba, Ti, Zr, Ce, Nb, Cr, Mo, W, Mn, Re, Fe, Co, Ir, Ni, Cu, Ag, Au, Rh, Ru 및 Bi의 목록으로부터의 1종 이상의 원소로 도핑되고, 여기서 활성화 전에 Ni/Al 합금은 Ti, Ce, V, Cr, Mo, W, Mn, Re, Fe, Ru, Co, Rh, Ir, Pd, Pt 및 Bi의 목록으로부터의 1종 이상의 도핑 원소를 함유하지 않을 수 있으나, 바람직하게는 이들을 함유할 수 있는 활성화된 Ni 촉매에 의해 수소화된다. Ni/Al 합금이 활성화 전에 1종 이상의 상기한 적합한 합금 도핑 원소를 함유하는 경우, 생성된 촉매는 Mg, Ca, Ba, Ti, Zr, Ce, V, Nb, Cr, Mo, W, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au 및 Bi의 목록으로부터의 1종 이상의 원소가 촉매의 표면 상에 흡착됨으로써 이들로 도핑될 수 있다. In the present invention, the nitro-compound is preferably selected from the group consisting of Mg, Ca, Ba, Ti, Zr, Ce, Nb, Cr, Mo, W, Mn, Re, Fe, Co, Ir, Ni, Cu, Cu, V, Cr, Mo, W, Mn, Re, Fe, Ru, and Co before the activation, wherein the Ni / Al alloy is doped with at least one element from the list of Ag, Au, , Rh, Ir, Pd, Pt and Bi, but is preferably hydrogenated by an activated Ni catalyst which may contain them. When the Ni / Al alloy contains at least one of the above-mentioned suitable alloying elements before activation, the resulting catalyst may be selected from the group consisting of Mg, Ca, Ba, Ti, Zr, Ce, V, Nb, Cr, Mo, One or more elements from the list of Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au and Bi may be doped into them by adsorption onto the surface of the catalyst. 활성화된 베이스 금속 촉매, 니트로-화합물, 니트로화 방향족 화합물, 수소화 Activated base metal catalysts, nitro-compounds, nitroaromatic aromatics, hydrogenation

Activated base metal catalysts

본 발명에서, 니트로-화합물은, 활성화 전에 Ni/Al 합금이 Cu, Ag 및 Au의 목록으로부터의 1종 이상의 원소를 또한 함유하는 활성화된 Ni 촉매에 의해 수소화된다. 상기 촉매는 또한, 상기에 언급된 IB족 원소와 함께, 다른 원소들을 활성화 전에 Ni/Al 합금에 첨가함으로써 이들로 도핑될 수 있고/거나, 이들은 합금의 활성화 동안 또는 활성화 후에 촉매의 표면 상에 흡착될 수 있다. 상기에 언급된 IB족 원소와 함께 활성화 전에 합금에 도핑되는 적합한 원소는 Mg, Ti, Ce, Cr, V, Mo, W, Mn, Re, Fe, Co, Ir, Ru, Rh, Pd, Pt 및 Bi의 목록으로부터의 1종 이상의 원소이다. 활성화 전에 합금에 상기에 언급된 IB족 원소가 미리 도핑되어 있는 촉매의 표면 상에 흡착될 수 있는 적합한 도핑 원소는 Mg, Ca, Ba, Ti, Ce, V, Cr, Mo, W, Mn, Re, Fe, Ru, Co, Rh, Ir, Pd, Pt, Ni, Cu, Ag, Au 및 Bi의 목록으로부터의 1종 이상의 원소이다. In the present invention, the nitro-compound is hydrogenated by an activated Ni catalyst wherein the Ni / Al alloy also contains at least one element from the list of Cu, Ag and Au before activation. The catalyst can also be doped with them by adding other elements to the Ni / Al alloy prior to activation, together with the above mentioned Group IB elements, and / or they are adsorbed onto the surface of the catalyst during or after activation of the alloy. Can be. Suitable elements that are doped into the alloy prior to activation with the above mentioned Group IB elements are Mg, Ti, Ce, Cr, V, Mo, W, Mn, Re, Fe, Co, Ir, Ru, Rh, Pd, Pt and One or more elements from the list of Bi. Suitable doping elements which can be adsorbed onto the surface of the catalyst which are previously doped with the above-mentioned Group IB elements in the alloy prior to activation are Mg, Ca, Ba, Ti, Ce, V, Cr, Mo, W, Mn, Re At least one element from the list of Fe, Ru, Co, Rh, Ir, Pd, Pt, Ni, Cu, Ag, Au and Bi. 활성화된 베이스 금속 촉매, 니트로-화합물, 니트로화 방향족 화합물, 수소화 Activated base metal catalysts, nitro-compounds, nitroaromatic aromatics, hydrogenation

提供含有掺杂的结构化催化剂成型体的催化剂固定床的方法

本发明涉及一种提供包含掺杂的结构化催化剂成型体的催化剂固定床的新方法，涉及一种包括呈固定内装形式的该类催化剂固定床的反应器并且涉及如此得到的催化剂固定床和反应器在氢化反应中的用途。

Improved multiphase low mixing processes

FIELD: chemistry.SUBSTANCE: invention relates to methods for the continuous production of sugar-alcohol products, including sorbitol, and can be used in the chemical industry. Disclosed is a method for improving a continuous multiphase reaction system comprising a porous nickel catalyst, one or more reactants in the gaseous phase and one or more reagents in the liquid phase, comprising supplying the liquid-phase reactant to the reactor in a target concentration through an inlet and at one or more locations downstream along the reactor in the axial direction of the fluid flow, wherein hydrogen is a gas-phase reactant, and it is used for the hydrogenation of sugar to obtain a sugar-alcohol product, wherein the supply of liquid-phase reactant can be carried out in a concentration greater than the target concentration, provided that the downstream feed does not give a concentration of the liquid reactant in the reactor that exceeds the target concentration.EFFECT: novel methods of obtaining valuable products, improved in relation to the formation of by-products, catalyst deactivation and yields of the required products are disclosed.20 cl, 3 ex, 6 tbl, 3 dwg РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 677 641 C2 (51) МПК C07C 29/00 (2006.01) B01J 8/22 (2006.01) C07H 1/00 (2006.01) B01J 25/02 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C07C 29/00 (2006.01); B01J 8/22 (2006.01); C07H 1/00 (2006.01); B01J 25/02 (2006.01) (21)(22) Заявка: 2016133290, 20.01.2015 (24) Дата начала отсчета срока действия патента: Дата регистрации: (73) Патентообладатель(и): Арчер Дэниелс Мидлэнд Компани (US) 18.01.2019 (56) Список документов, цитированных в отчете о поиске: WO 2011084352 A2, 14.07.2011. 10.02.2014 US 61/937,803 (43) Дата публикации заявки: 15.03.2018 Бюл. № 8 (45) Опубликовано: 18.01.2019 Бюл. № 2 (86) Заявка PCT: C 2 C 2 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 12.09.2016 Grezee E. et al, ...

라니 촉매, 이의 제조방법 및 이를 사용한 당알콜의 제조방법

높은 초기 활성과 함께 연속적인 사용을 가능케하는 고정층을 위한 라니 촉매의 제조방법 및 이를 사용하여 저비용으로 고순도의 당알콜을 제조하는 방법. 이를 위해, 당알콜을; 수소화를 위해 수소압하에 (i) 니켈 및 알루미늄을 용융시키는 제1단계, (ii) 상기 용융 혼합물의 소적을 담금함으로써 담금된 덩어리 합금을 수득하는 제2단계 및 (iii) 상기 담금된 덩어리 합금을 그대로 또는 부수어서 분류 및 활성화하는 제3단계에 의해 만들어진 덩어리 형태의 라니 촉매를 사용하여, 덩어리 형태의 라니 촉매를 채집한 후, 분말로 분쇄하고 재활성시켜 수득한 덩어리 형태의 라니 촉매를 사용하여, 수소압하에 당을 수소화하는 것에 의해 제조된다.

Proceso para preparar terpinen-4-ol

Un proceso para preparar terpinen-4-ol a partir de limonen-4-ol mediante una reacción de hidrogenación en presencia de un catalizador de níquel y de al menos un solvente orgánico. Reivindicación 8: El proceso de acuerdo con cualquiera de las reivindicaciones 1 a 7, caracterizado porque limonen-4-ol de la fórmula (1) se prepara mediante isomerización de terpinolen epóxido de la fórmula (2).

Metal Catalysts

加氢催化剂的制备

本发明涉及按以下步骤制备以铝和过渡金属的合金为基础的加氢催化剂:由合金和辅助剂制得捏合的材料;将经捏合的材料制成模制品;熔烧模制品;用碱金属氢氧化物处理经焙烧的模制品,其中所用的辅助剂为(a)聚乙烯醇和水,或(b)硬脂酸。本发明还涉及加氢和氢解的方法,尤其是脂族α,ω－氨基腈的部分加氢;还涉及由此制得的催化剂在加氢和氢解中的应用。

阮内镍催化剂的制备方法及其在有机化合物氢化中的应用

本发明涉及阮内镍催化剂的制备方法。在该方法中，将包含40至95wt％的铝，5至50wt％的镍，0至20wt％的铁，0至15wt％的一种或多种选自铈、铈混合金属、钒、铌、钽、铬、钼以及锰的过渡金属以及可用的其它玻璃形成元素的合金熔体与一个或多个旋转冷却辊或冷却板接触，使合金熔体冷却固化。冷却辊的表面具有横向凹槽构造，冷却板的表面具有由旋转轴向外延伸凹槽的构造。接着将在冷却辊或冷却板上快速固化的合金用一种或多种有机或无机碱进行处理。

Improved multiphase low mixing processes

고체 촉매, 기체상 중의 하나 이상의 반응물질 및 액체상 중의 하나 이상의 반응 물질을 포함하는 특정 다상 반응 시스템의 성능을 개선하기 위한 공정이 기재되며, 본 공정에서 액체상 중의 반응물질의 목표 최대 농도는 부산물 형성, 촉매 불활성화 및 원하는 생성물의 수율의 관점에서 개선된 값을 제공하기 위하여 확인되고, 이러한 목표 농도는 연속 공정에서의 하류 측에서, 또는 이와 같은 공정의 반-배치 작동 방식에서는 배치의 초기로부터 나중 시점에서, 근접하고 바람직하게는 달성되지만, 실질적으로 초과되지 않는다. A process for improving the performance of a specific multiphase reaction system comprising a solid catalyst, one or more reactants in the gaseous phase and one or more reactants in the liquid phase is described, in which the target maximum concentration of reactants in the liquid phase is by-product formation, Identified to provide improved values in terms of catalyst deactivation and yield of the desired product, these target concentrations are identified downstream in a continuous process, or in semi-batch mode of operation of such processes, from the beginning of the batch to the later point in time. At, close and preferably are achieved, but not substantially exceeded.

PROCESS FOR THE PRODUCTION OF CATALYSTS

Process for preparing a hydrogenation catalyst

Activated base metal catalysts

生产芳香族伯二胺的方法

用于通过在氢化催化剂和胺的存在下使芳香族二醛与氢和氨或释放氨的化合物反应生产芳香族伯胺的方法，其中在该反应开始时该胺与该芳香族二醛的摩尔比是不低于1∶4。

System For Producing Alcohol From Olefin

본 발명은 올레핀으로부터 알데히드를 제조하는 하이드로포밀화 반응부; 촉매/알데히드 분리부; 상기 알데히드를 수소화하여 알코올을 제조하는 수소화 반응부; 및 증류장치부를 포함하는 올레핀으로부터 알코올을 제조하는 시스템에 관한 것이다. 상기 하이드로포밀화 반응장치는 내부에 구비되는 분산판에 의하여 반응원료인 올레핀 및 합성 가스의 접촉 표면적이 넓어 충분한 반응 면적을 제공하고, 반응 혼합물이 순환함에 따라 반응원료가 반응혼합물과 충분히 혼합되어 알데히드의 제조효율이 우수하고, 상기 수소화 반응부는 부반응을 억제하여 알코올의 제조효율을 높인다. The present invention hydroformylation reaction unit for producing an aldehyde from olefins; A catalyst / aldehyde separation unit; Hydrogenation reaction unit for producing an alcohol by hydrogenating the aldehyde; And a system for producing an alcohol from an olefin comprising a distillation unit section. The hydroformylation reactor provides a sufficient reaction area due to the wide contact surface area of the olefin and the synthesis gas as a reaction material by means of a dispersion plate provided therein, and the reaction material is sufficiently mixed with the reaction mixture as the reaction mixture is circulated. The production efficiency of the excellent, the hydrogenation reaction unit to suppress side reactions to increase the production efficiency of alcohol. 올레핀, 합성가스, 하이드로포밀화, 알데히드, 벤투리, 분산판, 알코올, 수소화 단계, 알돌 축합, 분별 증류. Olefins, syngas, hydroformylation, aldehydes, venturis, dispersion plates, alcohols, hydrogenation steps, aldol condensation, fractional distillation.

Patent RU2016133290A3

ВИ“? 2016133290” АЗ Дата публикации: 04.09.2018 Форма № 18 ИЗИМ-2011 Федеральная служба по интеллектуальной собственности Федеральное государственное бюджетное учреждение 5 «Федеральный институт промышленной собственности» (ФИПС) ОТЧЕТ О ПОИСКЕ 1. . ИДЕНТИФИКАЦИЯ ЗАЯВКИ Регистрационный номер Дата подачи 2016133290/04(051589) 20.01.2015 РСТ/О$2015/011951 20.01.2015 Приоритет установлен по дате: [ ] подачи заявки [ ] поступления дополнительных материалов от к ранее поданной заявке № [ ] приоритета по первоначальной заявке № из которой данная заявка выделена [ ] подачи первоначальной заявки № из которой данная заявка выделена [ ] подачи ранее поданной заявки № [Х] подачи первой(ых) заявки(ок) в государстве-участнике Парижской конвенции (31) Номер первой(ых) заявки(ок) (32) Дата подачи первой(ых) заявки(ок) (33) Код страны 1. 61/937,803 10.02.2014 05 Название изобретения (полезной модели): [Х] - как заявлено; [ ] - уточненное (см. Примечания) УЛУЧШЕННЫЕ МНОГОФАЗНЫЕ СПОСОБЫ С ПЛОХИМ СМЕШИВАНИЕМ РЕАГЕНТОВ Заявитель: Арчер Дэниелс Мидлэнд Компани, 0$ 2. ЕДИНСТВО ИЗОБРЕТЕНИЯ [Х] соблюдено [ ] не соблюдено. Пояснения: см. Примечания 3. ФОРМУЛА ИЗОБРЕТЕНИЯ: [Х] приняты во внимание все пункты (см. Примечания) [ ] приняты во внимание следующие пункты: [ ] принята во внимание измененная формула изобретения (см. Примечания) 4. КЛАССИФИКАЦИЯ ОБЪЕКТА ИЗОБРЕТЕНИЯ (ПОЛЕЗНОЙ МОДЕЛИ) (Указываются индексы МПК и индикатор текущей версии) С07С 29/00 (2006.01) ВОТ. 5/22 (2006.01) С07Н 1/00 (2006.01) ВО1. 25/02 (2006.01) 5. ОБЛАСТЬ ПОИСКА 5.1 Проверенный минимум документации РСТ (указывается индексами МПК) С07С 29/00 ВО11 8/22 СО7Н 1/00 ВО11 25/02 5.2 Другая проверенная документация в той мере, в какой она включена в поисковые подборки: 5.3 Электронные базы данных, использованные при поиске (название базы, и если, возможно, поисковые термины): СТРО, РЕРАТБ пес, РУУРТ, ЕАРАТГУ, Ебрасепе, СооЗе, РАТЕМТЫСОРЕ, Рабзеагсв, КОРТО, ТРО, зсепсе Оиес, ОЗРТО 6. _ ДОКУМЕНТЫ, ОТНОСЯЩИЕСЯ К ПРЕДМЕТУ ...

Photocatalyst composition of matter

Process for preparation of (1R,2R)-3-(3-dimethylamino-1-ethyl-2-methyl-propyl)-phenol

本发明涉及(1R，2R)-3-(3-二甲胺基-1-乙基-2-甲基丙基)苯酚的制备方法。

Process for production of composition by using alcohol as starting material

에탄올 등의 알코올을 원료로 하여, 화학공업 원료나 연료조성물로서 유용한 유기화합물의 제조방법을 포함하는 조성물을 제공한다. 알코올을 출발원료로 하여 유기화합물을 제조하는 방법에 있어서, 알코올을 하이드록시 인회석 등의 알코올 변환촉매와 접촉시킨다(제 1공정). 제 1공정에 있어서의 생성물로서, 알코올류나 알데히드류 등의 함산소 화합물, 물, 탄소수 4~12의 탄화수소류 등을 포함하는 액상과, 파라핀류, 올레핀류, 디엔류, 알코올류 등을 함유하는 경질가스인 기상으로 이루어지는 전반응 생성물과, 상기 전반응 생성물로부터 경질가스를 제거한 액상 전반응물과, 상기 전반응 생성물로부터 경질가스, 미반응 알코올 및 생성수를 제거한 액상 탈수반응물에 각각 수소를 첨가한다(제 2공정). 그 결과, 연료의 산화 안정도가 개선된 내연기관용 연료조성물이 얻어진다. Provided is a composition comprising a method for producing an organic compound useful as a chemical raw material or a fuel composition, using an alcohol such as ethanol as a raw material. In a method for producing an organic compound using alcohol as a starting material, alcohol is brought into contact with an alcohol conversion catalyst such as hydroxyapatite (first step). As a product in a 1st process, Oxygen compounds, such as alcohols and aldehydes, Pre-reaction products comprising a liquid phase containing water, hydrocarbons having 4 to 12 carbon atoms and the like, a gaseous gas containing paraffins, olefins, dienes, alcohols, and the like, and light gases from the pre-reaction products. Hydrogen is added to the removed liquid prereactant and the liquid dehydration reactant from which light gas, unreacted alcohol and product water are removed from the prereaction product (second step). As a result, a fuel composition for an internal combustion engine with improved oxidation stability of the fuel is obtained.

Hydrogenation catalyst and its preparation

An amorphous alloy catalyst for hydrogenation and its preparation method are disclosed herein. The catalyst essentially consists of nickel ranging between 60 and 98 wt %, iron ranging between 0 and 20 wt %, one doping metal element selected from the group consisting of chromium, cobalt, molybdenum, manganese and tungsten ranging between 0 and 20 wt %, and aluminum ranging between 0.5 and 30 wt % based on the weight of said catalyst, wherein the weight percentages of iron and the doping metal element component may not be zero at the same time; and just one broad diffusion peak appears at about 2 θ=45±1° on the XRD patterns of the catalyst within 2 θ range from 20 to 80°. The catalyst herein can be used in processes for hydrogenation of unsaturated compounds such as olefin, alkyne, aromatics, nitro, carbonyl groups, nitrile and soon, and for hydrorefining of caprolactam in particular.

Method for conditioning catalysts by means of membrane filtration

The present invention relates to a method of conditioning suspended catalysts, wherein at least part of the catalyst-comprising reaction medium is taken from one or more reactors and the suspended, at least partially inactivated catalysts are separated off and purified by means of at least one membrane filtration, with at least one of the membrane filtrations being carried out as a diafiltration.

Process for production of 2-propanol

2-프로판올을 종래보다도 고순도로 얻을 수 있는, 불순물의 부생을 억제한 고순도 2-프로판올의 제조 방법을 제공하는 것을 목적으로 한다. 본 발명의 2-프로판올의 제조 방법은, 아세톤을 수소화 촉매의 존재하에서 수소와 반응시켜, 2-프로판올을 제조하는 방법으로서, 상기 반응이, 물과 아세톤을 포함하는 원료 혼합물을, 수소화 촉매의 존재하에서 수소와 반응시킴으로써 행해져, 상기 원료 혼합물이 물과 아세톤과의 합계 100중량% 당, 물을 1.2~4.0중량% 함유하는 것을 특징으로 한다.

A hydrogenation catalyst and its preparation

본 발명은 비결정성 합금 수소화 촉매 및 이의 제조 방법에 관한 것이다. 상기 촉매는 상기 촉매의 중량 기준으로 60에서 98 wt% 범위의 Ni과, 0에서 20 wt% 범위의 Fe와, 0에서 20 wt% 범위의 Cr, Co, Mo, Mn, W로 구성된 군으로부터 선택된 금속 원소와, 0.5에서 30 wt% 범위의 Al을 포함하며, 여기서 상기 Fe 및 Cr, Co, Mo, Mn, W로 구성된 군으로부터 선택된 금속 원소의 중량 퍼센트는 동시에 0이 되지 않으며; 상기 촉매의 XRD 패턴은 20°에서 80°범위의 2Θ내의 2Θ = 45±1°에서 하나의 넓은 산란 피크를 가진다. 본 발명에 의한 상기 촉매는 방향족 탄화수소, 알킨, 알켄,, 니트로 화합물, 카르보닐 화합물, 니트릴기 등과 같은 불포화 화합물의 수소화에 사용되기 적합하며, 특히 카프로락탐의 수소 정제에 적합하다. The present invention relates to an amorphous alloy hydrogenation catalyst and a method for producing the same. The catalyst is selected from the group consisting of Ni in the range of 60 to 98 wt%, Fe in the range of 0 to 20 wt% and Cr, Co, Mo, Mn, W in the range of 0 to 20 wt% by weight of the catalyst. A metal element and Al in the range of 0.5 to 30 wt%, wherein the weight percentages of Fe and metal elements selected from the group consisting of Cr, Co, Mo, Mn, W are not zero at the same time; The XRD pattern of the catalyst has one broad scattering peak at 2Θ = 45 ± 1 ° within 2Θ ranging from 20 ° to 80 °. The catalysts according to the invention are suitable for use in the hydrogenation of unsaturated compounds such as aromatic hydrocarbons, alkynes, alkenes, nitro compounds, carbonyl compounds, nitrile groups and the like, in particular for hydrogen purification of caprolactam.

IMPROVED MULTI-PHASE METHODS WITH BAD REAGENT MIXING

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2016 133 290 A (51) МПК C07C 29/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2016133290, 20.01.2015 (71) Заявитель(и): Арчер Дэниелс Мидлэнд Компани (US) Приоритет(ы): (30) Конвенционный приоритет: 10.02.2014 US 61/937,803 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 12.09.2016 R U (43) Дата публикации заявки: 15.03.2018 Бюл. № 08 (72) Автор(ы): ДАССОРИ Карлос Густаво (US), МА Чи-Чен (US), ВЭРПИ Тодд (US) (86) Заявка PCT: (87) Публикация заявки PCT: WO 2015/119767 (13.08.2015) R U (54) УЛУЧШЕННЫЕ МНОГОФАЗНЫЕ СПОСОБЫ С ПЛОХИМ СМЕШИВАНИЕМ РЕАГЕНТОВ (57) Формула изобретения 1. Способ улучшения непрерывной многофазной реакционной системы, содержащей твердый катализатор, один или несколько реагентов в газообразной фазе и один или несколько реагентов в жидкой фазе, предусматривающий подачу жидкофазного реагента в реактор в целевой концентрации через впускное отверстие и в одно или несколько местоположений ниже по потоку вдоль реактора в осевом направлении потока текучей среды. 2. Способ улучшения непрерывной многофазной реакционной системы, содержащей твердый катализатор, один или несколько реагентов в газообразной фазе и один или несколько реагентов в жидкой фазе, предусматривающий подачу жидкофазного реагента в реактор через впускное отверстие реактора в целевой концентрации жидкофазного реагента, а затем подачу жидкофазного реагента в реактор в одном или нескольких местоположениях ниже по потоку в осевом направлении потока текучей среды в концентрации или концентрациях, которые больше чем целевая концентрация, при условии, что одна или несколько подач ниже по потоку не дает концентрацию жидкого реагента в реакторе, которая, по существу, превышает целевую концентрацию. 3. Способ по п. 1 или 2, где эффект одной или нескольких подач ниже по потоку заключается в достижении концентрации жидкофазного реагента в реакторе, которая находится в пределах ...

Method of obtaining composition using alcohol as raw material

FIELD: chemistry. SUBSTANCE: present invention relates to a method of obtaining compositions which contain organic compounds and are suitable as chemical industrial material or a fuel composition using alcohol, for example ethanol, as a raw material. The method comprises a first step for bringing at least one alcohol selected from methanol, ethanol, propanol, butanol, pentanol, hexanol, heptanol and octanol into contact with at least one alcohol conversion catalyst selected from phosphate or clay mineral. The alcohol conversion catalyst simultaneously causes dehydration and dehydrogenation of the alcohol. The method comprises a second step where the product obtained at the first step undergoes hydrogenation to obtain a composition. The obtained composition contains at least one component selected from a group consisting of paraffins and alcohols. The invention also relates to compositions which are obtained using said method and are used as internal combustion engine fuel compositions. EFFECT: high efficiency of the method. 53 cl, 1 dwg, 17 tbl, 5 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 467 057 (13) C2 (51) МПК C10L 1/02 (2006.01) C10G 3/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2010108276/05, 16.09.2008 (24) Дата начала отсчета срока действия патента: 16.09.2008 (73) Патентообладатель(и): КАБУСИКИ КАЙСЯ САНГИ (JP) (43) Дата публикации заявки: 20.10.2011 Бюл. № 29 2 4 6 7 0 5 7 (45) Опубликовано: 20.11.2012 Бюл. № 32 (56) Список документов, цитированных в отчете о поиске: US 4304951 A1, 08.12.1981. US 4981491 A1, 01.01.1991. EP 1052234 A1, 15.11.2000. RU 2131905 C1, 20.06.1999. JP 1223195 A1, 06.09.1989. 2 4 6 7 0 5 7 R U (86) Заявка PCT: JP 2008/002547 (16.09.2008) C 2 C 2 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 13.04.2010 (87) Публикация заявки РСТ: WO 2009/034719 (19.03.2009) Адрес для переписки: 125009, Москва, а/я 332, ЗАО "Инэврика" (54) СПОСОБ ПОЛУЧЕНИЯ ...

Method of production of 3-dimethylaminopropylamine at low pressure

FIELD: chemistry. SUBSTANCE: invention pertains to the method of obtaining 3-dimethylaminopropylamine, used as an intermediate product in organic synthesis. Description is given of the method of obtaining the 3-dimethylaminopropylamine with high purity degree from N,N-dimethylaminopropyonitrile with use of hydrogenation method at low pressure. The method involves contacting nitrile with hydrogen at low pressure in the presence of a catalyst, under conditions allowing for turning the nitrile into 3-dimethylaminopropylamine with high output and purity of over 99%. EFFECT: high output. 15 cl, 2 tbl, 3 ex ÐÎÑÑÈÉÑÊÀß ÔÅÄÅÐÀÖÈß RU (19) (11) 2 326 108 (13) C2 (51) ÌÏÊ C07C 209/48 (2006.01) ÔÅÄÅÐÀËÜÍÀß ÑËÓÆÁÀ ÏÎ ÈÍÒÅËËÅÊÒÓÀËÜÍÎÉ ÑÎÁÑÒÂÅÍÍÎÑÒÈ, ÏÀÒÅÍÒÀÌ È ÒÎÂÀÐÍÛÌ ÇÍÀÊÀÌ (12) ÎÏÈÑÀÍÈÅ ÈÇÎÁÐÅÒÅÍÈß Ê ÏÀÒÅÍÒÓ (21), (22) Çà âêà: 2005123396/04, 12.12.2003 (72) Àâòîð(û): ÓÎÐÄ Ãðåãîðè Äæ. (US), ÁËÀÍ×ÀÐÄ Áðàéàí Ê. (US) (24) Äàòà íà÷àëà îòñ÷åòà ñðîêà äåéñòâè ïàòåíòà: 12.12.2003 (73) Ïàòåíòîîáëàäàòåëü(è): ÑÎËÞÒÈÀ ÈÍÊ. (US) R U (30) Êîíâåíöèîííûé ïðèîðèòåò: 23.12.2002 (ïï.1-15) US 10/327,765 09.12.2003 (ïï.1-15) US 10/731,733 (43) Äàòà ïóáëèêàöèè çà âêè: 20.01.2006 2 3 2 6 1 0 8 (45) Îïóáëèêîâàíî: 10.06.2008 Áþë. ¹ 16 (56) Ñïèñîê äîêóìåíòîâ, öèòèðîâàííûõ â îò÷åòå î ïîèñêå: ÅÐ 0316761 À2, 24.05.1989. RU 2131297 C1, 10.06.1999. SU 399110 A1, 27.11.1974. US 5869653 A, 09.02.1999. US 5874625 A, 23.02.1999. (85) Äàòà ïåðåâîäà çà âêè PCT íà íàöèîíàëüíóþ ôàçó: 25.07.2005 2 3 2 6 1 0 8 R U (87) Ïóáëèêàöè PCT: WO 2004/060853 (22.07.2004) C 2 C 2 (86) Çà âêà PCT: US 03/39447 (12.12.2003) Àäðåñ äë ïåðåïèñêè: 129010, Ìîñêâà, óë. Á.Ñïàññêà , 25, ñòð.3, ÎÎÎ "Þðèäè÷åñêà ôèðìà Ãîðîäèññêèé è Ïàðòíåðû", ïàò.ïîâ. Å.Å.Íàçèíîé, ðåã. ¹ 517 (54) ÑÏÎÑÎÁ ÏÐÎÈÇÂÎÄÑÒÂÀ 3-ÄÈÌÅÒÈËÀÌÈÍÎÏÐÎÏÈËÀÌÈÍÀ (ÄÌÀÏÀ) ÏÐÈ ÍÈÇÊÎÌ ÄÀÂËÅÍÈÈ (57) Ðåôåðàò: Èçîáðåòåíèå îòíîñèòñ ê ñïîñîáó ïîëó÷åíè 3äèìåòèëàìèíîïðîïèëàìèíà, èñïîëüçóåìîãî â êà÷åñòâå ïðîìåæóòî÷íîãî ïðîäóêòà â îðãàíè÷åñêîì ñèíòåçå. Îïèñûâàåòñ ñïîñîá ïîëó÷åíè 3 ...

Method of producing amines

FIELD: chemistry. SUBSTANCE: invention relates to an improved method of producing diamine compounds by hydrogenation of compounds which contain nitrile groups, reaction with hydrogen or a hydrogen-containing gas, in the presence of a Raney nickel based hydrogenation catalyst which contains iron, chromium and zinc as doping elements. The hydrogenation catalyst contains the following, with respect to weight content of metal elements: Al - 2-10%; Fe - 0.3-3%; Cr - 0.5-5%; Zn - 0.5-5%; Ni - the balance up to 100%. EFFECT: method increases selectivity of the process and reduces formation of impurities. 7 cl, 1 tbl, 6 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 484 084 (13) C2 (51) МПК C07C 209/48 (2006.01) C07C 211/12 (2006.01) B01J 25/02 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2011113984/04, 01.09.2009 (24) Дата начала отсчета срока действия патента: 01.09.2009 (72) Автор(ы): ЛЕТУРНЕЭР Дидье (FR), ВЕРДЬЕ Стефан (FR) (73) Патентообладатель(и): РОДИА ОПЕРАСЬОН (FR) R U Приоритет(ы): (30) Конвенционный приоритет: 09.09.2008 FR 08/04935 (43) Дата публикации заявки: 20.10.2012 Бюл. № 29 C 2 2 4 8 4 0 8 4 C 2 R U (56) Список документов, цитированных в отчете о поиске: RU 2190469 С2, 10.10.2002. FR 2722784 A1, 26.01.1996. RU 2131297 C1, 10.06.1999. RU 2233266 С2, 27.07.2004. RU 2272023 С1, 20.03.2006. FR 2905948 A1, 21.03.2008. FR 2722709 А, 26.01.1996. ФРЕЙДЛИН Л.Х. и др. Каталитическое восстановление динитрилов // Успехи Химии. Т.XXXIII, 1964, вып.6, стр.664-686. (85) Дата начала рассмотрения заявки PCT на национальной фазе: 11.04.2011 (86) Заявка PCT: EP 2009/061268 (01.09.2009) (87) Публикация заявки РСТ: WO 2010/028982 (18.03.2010) Адрес для переписки: 129090, Москва, ул. Б. Спасская, 25, стр.3, ООО "Юридическая фирма Городисский и Партнеры" (54) СПОСОБ ПОЛУЧЕНИЯ АМИНОВ (57) Реферат: Изобретение относится к улучшенному способу получения диаминовых соединений гидрированием соединений, содержащих ...

Nickel and cobalt plated sponge catalysts

本发明公开了新型的镀镍和/或镀钴海绵基催化剂。所述催化剂的活性和/或选择性可与传统的镍和/或钴海绵催化剂(例如Raney  镍或Raney  钴催化剂)相媲美，但所需的镍和/或钴的量减少。本发明的催化剂包含涂覆在至少部分海绵载体表面上的镍和/或钴。优选所述海绵载体包含至少一种除涂层中所含金属之外或与之不同的金属。本发明还公开了电镀催化剂的制备方法以及在制备有机化合物中使用所述催化剂的方法。

A kind of composite catalyst and preparation method thereof

本发明公开了一种复合型催化剂，其包括：其包括：连续相碳、分散相雷尼合金粒子，其中分散相雷尼合金粒子均匀或不均匀地分散在连续相碳中，所述的连续相碳是由可碳化的有机物及其混合物高温碳化后得到的。该催化剂具有颗粒强度好、催化活性高和选择性好等优点。

Long cool-down tube with air input joints

A conduit system comprising: a conduit formed by a surface extending from a first end to a second end, wherein the conduit is configured to channel a mixture stream from the first end to the second end; and a plurality of fluid delivery features disposed along the conduit between the first end and the second end, wherein each fluid delivery feature is configured to deliver a conditioning fluid into the conduit in an annular formation in a direction angled towards the second end in the same direction as the flow of the mixture stream, thereby providing a sheath of conditioning fluid between the conduit surface and the mixture stream.