УГЛЕРОДНЫЕ ТЕЛА И ФЕРРОМАГНИТНЫЕ УГЛЕРОДНЫЕ ТЕЛА

Изобретение касается области модифицированных углеродных изделий. Предложено ферромагнитное углеродное тело, содержащее частично графитизированный активированный уголь и металлические частицы ферромагнитного металла, выбранного из группы, состоящей из железа, никеля, кобальта и/или их сплавов и их комбинаций. Размер ферромагнитного тела составляет от 100 нм до 20 мм, вычисленная БЭТ-методом площадь его поверхности составляет от 300 до 1000 м/г, общий объем пор составляет от 0,1 до 0,6 мл/г, средний диаметр пор составляет от 3 до 8 нм. Ферромагнитное углеродное тело содержит 10-70% по весу графитизированного углерода. Предложен также способ получения и использования ферромагнитного тела. Изобретение обеспечивает получение частично графитизированного тела с усовершенствованными характеристиками, в котором количество и расположение графитизированного углерода может быть управляемым. 8 н. и 8 з.п. ф-лы, 17 ил., 6 табл., 6 пр. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 641 124 C2 (51) МПК B01J 20/20 (2006.01) B01J 21/18 (2006.01) C01B 31/08 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК B01J 20/20 (2015.12); B01J 21/18 (2015.12); C01B 31/089 (2015.12) (21)(22) Заявка: 2015128060, 12.12.2013 (24) Дата начала отсчета срока действия патента: Дата регистрации: 16.01.2018 13.12.2012 EP 12197061.0 (43) Дата публикации заявки: 16.01.2017 Бюл. № 2 (56) Список документов, цитированных в отчете о поиске: EP 2383374 A1, 02.11.2011. US 2010/ 291167 A1, 18.11.2010. WO 2010/098668, 02.09.2010. WO 2010/109216, 30.09.2010. SU 1836145 А3, 23.08.1993. (45) Опубликовано: 16.01.2018 Бюл. № 2 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 13.07.2015 2 6 4 1 1 2 4 (73) Патентообладатель(и): БАСФ КОРПОРЕЙШН (US) Приоритет(ы): (30) Конвенционный приоритет: R U 12.12.2013 (72) Автор(ы): ХУКСТРА Якобус (NL), БРАНДТС Йим Алойсиус Мария (NL), ВАГЕМАКЕР Лорианне (NL), ГЕУС Джон Вильхельм (NL), ЕННЕСКЕНС Леонардус Вейнанд (NL) ...

Doped carbonaceous materials for photocatalytic removal of pollutants under visible light, making methods and applications of same

A method of synthesizing a doped carbonaceous material includes mixing a carbon precursor material with at least one dopant to form a homogeneous/heterogeneous mixture; and subjecting the mixture to pyrolysis in an inert atmosphere to obtain the doped carbonaceous material. A method of purifying water includes providing an amount of the doped carbonaceous material in the water as a photocatalyst; and illuminating the water containing the doped carbonaceous material with visible light such that under visible light illumination, the doped carbonaceous material generates excitons (electron-hole pairs) and has high electron affinity, which react with oxygen and water adsorbed on its surface forming reactive oxygen species (ROS), such as hydroxyl radicals and superoxide radicals, singlet oxygen, hydrogen peroxide, that, in turn, decompose pollutants and micropollutants.

КОМПОЗИЦИЯ, ИМЕЮЩАЯ АКТИВНЫЙ МЕТАЛЛ ИЛИ ЕГО ПРЕДШЕСТВЕННИК, АМИНОВЫЙ КОМПОНЕНТ И НЕ СОДЕРЖАЩУЮ АМИНА ПОЛЯРНУЮ ДОБАВКУ, ИСПОЛЬЗУЕМАЯ В КАТАЛИТИЧЕСКОЙ ОБРАБОТКЕ ВОДОРОДОМ УГЛЕВОДОРОДОВ, СПОСОБ ИЗГОТОВЛЕНИЯ ТАКОГО КАТАЛИЗАТОРА

1. Композиция, содержащая: материал подложки, который нагружен предшественником активного металла, аминовым компонентом и не содержащей амина полярной добавкой.2. Композиция по п. 1, в которой упомянутый аминовый компонент выбирают из группы соединений, состоящей из соединений - простых эфир-аминов, алкиламиносоединений и аминоксидных соединений.3. Композиция по п. 2, в которой упомянутые соединения - простые эфир-амины включают в себя соединения, которые выбирают из семейства соединений, имеющих следующую формулу: R-O-(CH)NH, где R представляет собой алкильную функциональную группу, содержащую от 4 до 14 атомов углерода, а n представляет собой целое число в диапазоне от 1 до 6.4. Композиция по п. 3, в которой упомянутые аминоксидные соединения включают в себя соединения, которые выбирают из семейства соединений, имеющих следующую формулу: [вставить рисунок R1, R2 и R3]NO, где R1 представляет собой либо атом водорода, либо алкильную функциональную группу, R2 представляет собой либо атом водорода, либо алкильную функциональную группу, и R3 представляет собой либо атом водорода, либо алкильную функциональную группу, где общее число атомов углерода, включенных в R1 и R2 и R3, находится в диапазоне от 8 атомов углерода до 40 атомов углерода.5. Композиция по п. 4, в которой упомянутые алкиламиносоединения включают в себя соединения, которые выбирают из группы аминосоединений, состоящей из первичныхаминов, имеющих от 8 до 20 атомов углерода, вторичных аминов, имеющих от 8 до 20 атомов углерода, и третичных аминов, имеющих от 8 до 20 атомов углерода.6. Композиция по п. 5, в которой упомянутую не содержащую амина полярную добавку выбирают из соединений, име РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (51) МПК B01J 27/19 (11) (13) 2014 102 535 A (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2014102535/04, 26.06.2012 (71) Заявитель(и): ШЕЛЛ ИНТЕРНЭШНЛ РИСЕРЧ МААТСХАППИЙ Б.В. (NL) Приоритет(ы): (30) Конвенционный приоритет: 28.06. ...

Verfahren zur Herstellung von Metall-N-heterocyclischen Carben-Komplexen

Article for securing a catalyst substrate

An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and the compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion.

Article for securing a catalyst substrate

PLASMONIC ASSISTED SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of the plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

SUPPORTED HYDROPROCESSING CATALYSTS COMPRISING METAL, AMINE, AND NON-AMINE POLAR ADDITIVES

A composition that comprises a support material that is loaded with an active metal or metal precursor, selected from Group 6 and Group 9 and 10 metals, an amine component, and a non-amine containing polar additive. The composition is useful in the hydroprocessing of hydrocarbon feedstocks. The composition is prepared by incorporating a metal solution into a support material followed by incorporating there¬ in an amine component and a non-amine containing polar additive.

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

탄소체 및 강자성 탄소체

... 본 발명은 개질된 탄소 제품의 분야에 관한 것이다. 더욱 상세하게는, 본 발명은 부분 흑연화된 활성탄체의 분야에 관한 것이다. 본 발명은 탄소체 및 강자성 탄소체, 활성탄으로부터 이들 체의 생산, 및 예를 들면 수처리에서 및 전기 화학적 적용에서 탄소체 및 강자성체의 용도에 관한 것이다.

IMPROVEMENT IN METHOD OF ORNAMENTING ARTICLE MATERIALS

A method for producing a nitrogen functionalised surface

A Method for producing a nitrogen functionalised surface

A method is provided for applying a coating containing reactive nitrogen functionality contained within an aromatic heterocyclic structure to a substrate. The method includes subjecting said substrate to a plasma discharge of a monomer possessing said heterocyclic nitrogen functionality.

A method for producing a nitrogen functionalised surface

POLYMER-SUPPORTED METAL NANOPARTICLES, PROCESS FOR PRODUCTION THEREOF AND POLYMERIC NANOREACTORS PRODUCED THEREFROM

A process for producing polymer-supported metal nanoparticles involves confinement of metal nanoparticles in polymeric nanotubes or nanosheets in an aqueous environment using hydrophobic reactants. Metal nanoparticles supported in the polymeric nanotubes or nanosheets are substantially monodisperse and have an average particle size of 4 nm or less. The polymer-supported metal nanoparticles are useful in fuel cells, sensors, bioanalysis, biological labeling or semi-conductors, especially as catalysts.

КОМПОЗИЦИЯ, ИМЕЮЩАЯ АКТИВНЫЙ МЕТАЛЛ ИЛИ ЕГО ПРЕДШЕСТВЕННИК, АМИНОВЫЙ КОМПОНЕНТ И НЕ СОДЕРЖАЩУЮ АМИНА ПОЛЯРНУЮ ДОБАВКУ, ИСПОЛЬЗУЕМАЯ В КАТАЛИТИЧЕСКОЙ ОБРАБОТКЕ ВОДОРОДОМ УГЛЕВОДОРОДОВ, СПОСОБ ИЗГОТОВЛЕНИЯ ТАКОГО КАТАЛИЗАТОРА

FIELD: chemistry. SUBSTANCE: invention relates to a composition which is impregnated by an amine component and an amine-free polar additive and which is suitable in catalytic hydrogen processing of hydrocarbons, a method of producing said composition. Composition contains substrate material, which is loaded with an active metal precursor, an amine component and amine-free polar additive. Metal element is a metal selected from metals of Groups of 6, 9 and 10 of IUPAC periodic table, as well as phosphorus, wherein metal of Group 6 is selected from chromium, molybdenum and tungsten, and metal of Groups 9 and 10 is selected from cobalt and nickel. Amine component is selected from a group of compounds, consisting of ether amine compounds, alkyl or alkenyl amine compounds and amine oxide compounds, wherein ether amine compounds are selected from compounds having a flash temperature of at least 80 °C and molecular weight more than 160; alkyl or alkenyl amine compounds are selected from compounds having molecular weight ranging from 100 to 320; and amine oxide compounds are selected from compounds having 8 to 40 carbon atoms. Said amine-free polar additive is selected from dimethyl formamide and N-formylmorpholine. Weight ratio of said amine-free polar additive to said amine compound ranges from 0.25:1 to 6:1. Method of preparing composition includes: feeding metal-containing solution into substrate material, to provide substrate material comprising a metal included therein, and introducing both amine component, and amine-free polar additive to said substrate material comprising metal included therein. EFFECT: use of amine compound in combination with an amine-free polar additive provides high catalytic activity in process of dehydrosulphurisation or hydrodenitrogenation of hydrocarbon material. 10 cl, 5 tbl, 2 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (51) МПК B01J 27/19 B01J 31/02 B01J 27/24 B01J 23/85 B01J 37/02 B01J 37/18 ФЕДЕРАЛЬНАЯ СЛУЖБА B01J 37/20 ПО ИНТЕЛЛЕКТУАЛЬНОЙ ...

УГЛЕРОДНЫЕ ТЕЛА И ФЕРРОМАГНИТНЫЕ УГЛЕРОДНЫЕ ТЕЛА

A catalyst composition and a catalytic process for conversion of biomass to crude bio oil

The present disclosure provides a catalyst composition for conversion of biomass to crude bio oil. The composition comprises at least one metal compound, at least one support and at least one stabilizing/solubilizing agent. Also disclosed are processes for the preparation of catalyst composition, and hydrothermal conversion of biomass to crude bio oil.

Carbon bodies and ferromagnetic carbon bodies

The invention is in the field of modified carbon products. More in particular, the invention is in the field of graphitized activated carbon bodies. The invention is directed to carbon bodies and ferromagnetic carbon bodies, the production of these bodies from activated carbon, and the applications of the carbon bodies and ferromagnetic carbon bodies, for instance in water treatment and in electrochemical applications.

Carbon bodies and ferromagnetic carbon bodies

The invention is in the field of modified carbon products. More in particular, the invention is in the field of graphitized activated carbon bodies. The invention is directed to carbon bodies and ferromagnetic carbon bodies, the production of these bodies from activated carbon, and the applications of the carbon bodies and ferromagnetic carbon bodies, for instance in water treatment and in electrochemical applications.

IMPROVEMENT IN METHOD OF ORNAMENTING ARTICLE MATERIALS

SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

A method and a system for producing a change in a medium. The method places in a vicinity of the medium at least one energy modulation agent. The method applies an initiation energy to the medium. The initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the energy modulation agent.

PLASMONIC ASSISTED SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

PLASMONIC ASSISTED SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

PROCESSES FOR REMOVING ENTRAINED IONIC LIQUID FROM A HYDROCARBON PHASE

One or more processes for recovering entrained ionic liquid from a hydrocarbon phase containing droplets of ionic liquid are described. The processes includes contacting the hydrocarbon phase containing the droplets of ionic liquid with a retaining material in a separation zone. The droplets of ionic liquid are retained by the retaining material. The ionic liquid may be recovered from the retaining material with a solvent or desorbent. The retaining material may be regenerated and the ionic liquid may be reactivated. The retaining material may be used in a wash vessel to retain or remove contaminant solids within the reactor or other vessels. 1. A process for removing ionic liquid catalyst from a stream including hydrocarbons and an ionic liquid catalyst , the process comprising:separating a mixture comprising hydrocarbons and ionic liquid catalyst into a hydrocarbon phase and an ionic liquid catalyst phase, the hydrocarbon phase including ionic liquid catalyst droplets; and,separating the ionic liquid catalyst droplets from the hydrocarbon phase by retaining the ionic liquid catalyst droplets with a retaining material for retaining ionic liquid catalyst droplets to provide an ionic liquid catalyst lean hydrocarbon stream having a viscosity less than 1 centipoise.2. The process of further comprising:removing ionic liquid catalyst from the retaining material with a solvent.3. The process of wherein the retaining material comprises an adsorbent material.4. The process of wherein the adsorbent material comprises an oxide claim 3 , a salt claim 3 , an ion exchange resin claim 3 , activated carbon claim 3 , a polymer claim 3 , a natural fiber claim 3 , a zeolite claim 3 , a molecular sieve claim 3 , or a combination thereof.5. The process of further comprising:desorbing ionic liquid catalyst from the adsorbent material with a desorbent.6. The process of further comprising:regenerating the adsorbent material after the ionic liquid catalyst has been desorbed from the ...

A catalyst composition and a catalytic process for conversion of biomass to crude bio oil

The present disclosure provides a catalyst composition for conversion of biomass to crude bio oil. The composition comprises at least one metal compound, at least one support and at least one stabilizing/solubilizing agent. Also disclosed are processes for the preparation of catalyst composition, and hydrothermal conversion of biomass to crude bio oil.

A COMPOSITION HAVING AN ACTIVE METAL OR PRECURSOR, AN AMINE COMPONENT AND A NON-AMINE CONTAINING POLAR ADDITIVE USEFUL IN THE CATALYTIC HYDROPROCESSING OF HYDROCARBONS, A METHOD OF MAKING SUCH COMPOSITION

A composition that comprises a support material that is loaded with an active metal or metal precursor, selected from Group 6 and Group 9 and 10 metals, an amine component, and a non-amine containing polar additive. The composition is useful in the hydroprocessing of hydrocarbon feedstocks. The composition is prepared by incorporating a metal solution into a support material followed by incorporating there¬ in an amine component and a non-amine containing polar additive.

LIGHT UPCONVERSION MICROCAPSULES

A composition, method, and article of manufacture are disclosed. The composition is a microcapsule that includes a transparent shell encapsulating a mixture comprising light upconversion molecules. The method is a method of forming a microcapsule, which includes obtaining light upconversion molecules, forming an emulsion of the light upconversion molecules and a shell formation solution, and encapsulating the light upconversion molecules in a transparent shell. The article of manufacture comprises the microcapsule.

NOVEL PHOSPHINES, SYNTHESIS THEREOF AND THEIR USE IN CATALYSIS

The present invention relates to a novel class of benzimidazolyl/imidazolyl phosphine ligands, methods of preparing such ligands via a simple one-pot protocol, and applications of the ligands in catalytic reactions. 120-. (canceled)22. The phosphine ligand of wherein the two Rare linked to one another.23. The phosphine ligand of claim 21 , wherein two or more of R claim 21 , Rand Rof formula (1) claim 21 , when adjacent to one another claim 21 , are linked to one another to form a condensed ring system.24. The phosphine ligand of claim 21 , wherein two or more of R claim 21 , R claim 21 , R claim 21 , Rand Rof formula (2) claim 21 , when adjacent to one another claim 21 , are linked to one another to form a condensed ring system.25. The phosphine ligand of claim 21 , selected from the group consisting of:2-(dicyclohexylphosphino)-N,N-diisopropyl-1H-benzo[d]imidazole-1-carboxamide (2a),2-(di-tert-butylphosphino)-N,N-diisopropyl-1H-benzo[d]imidazole-1-carboxamide (2b),2-(diisopropylphosphino)-N,N-diisopropyl-1H-benzo[d]imidazole-1-carboxamide (2c),2-(diphenylphosphino)-N,N-diisopropyl-1H-benzo[d]imidazole-1-carboxamide (2d),2-(diethylphosphino)-N,N-diisopropyl-1H-benzo[d]imidazole-1-carboxamide (2e),2-(dicyclohexylphosphino)-N,N-diisopropyl-5,6-dimethyl-1H-benzo[d]imidazole-1-carboxamide (2i),2-(di-tert-butylphosphino)-N,N-diisopropyl-5,6-dimethyl-1H-benzo[d]imidazole-1-carboxamide (2j),2-(diisopropylphosphino)-N,N-diisopropyl-5,6-dimethyl-1H-benzo[d]imidazole-1-carboxamide (2k),2-(diphenylphosphino)-N,N-diisopropyl-5,6-dimethyl-1H-benzo[d]imidazole-1-carboxamide (2l),2-(di-o-tolylphosphino)-N,N-diisopropyl-5,6-dimethyl-1H-benzo[d]imidazole-1-carboxamide (2m),2-(dicyclopentylphosphino)-N,N-diisopropyl-5,6-dimethyl-1H-benzo[d]imidazole-1-carboxamide (2n),2-(dicyclohexylphosphino)-1-(2,4,6-triisopropylphenylsulfonyl)-1H-benzo[d]imidazole (2o),2-(di-tert-butylphosphino)-1-(2,4,6-triisopropylphenylsulfonyl)-1H-benzo[d]imidazole (2p),2-(dicyclohexylphosphino)-1-( ...

SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME

A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with an organophosphorous compound and a weak acid to form a catalyst composition; and reducing the catalyst composition to form the catalyst. A method of making a selective hydrogenation catalyst comprising contacting an alumina support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with silver nitrate and potassium fluoride to form a mixture; contacting the mixture with an organophosphorous compound and a weak acid to form a catalyst precursor; and reducing the catalyst precursor to form the catalyst.

PHOTOCATALYTIC SYSTEM AND APPLICATIONS THEREOF

The present invention relates to novel poly(heptazine imides), a photocatalytic system comprising such poly(heptazine imides) and a sulfur source as well as the application thereof in photocatalytic reactions.

PLASMONIC ASSISTED SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

PLASMONIC ASSISTED SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERNAL SOURCE

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of the plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

POLYMER-SUPPORTED METAL NANOPARTICLES, PROCESS FOR PRODUCTION THEREOF AND POLYMERIC NANOREACTORS PRODUCED THEREFROM

A process for producing polymer-supported metal nanoparticles involves confinement of metal nanoparticles in polymeric nanotubes or nanosheets in an aqueous environment using hydrophobic reactants. Metal nanoparticles supported in the polymeric nanotubes or nanosheets are substantially monodisperse and have an average particle size of 4 nm or less. The polymer-supported metal nanoparticles are useful in fuel cells, sensors, bioanalysis, biological labeling or semi-conductors, especially as catalysts.

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

Article of manufacture for securing a catalyst substrate

Composition can be mono, photocatalytic product and its preparation method

A COMPOSITION HAVING AN ACTIVE METAL OR PRECURSOR, AN AMINE COMPONENT AND A NON-AMINE CONTAINING POLAR ADDITIVE USEFUL IN THE CATALYTIC HYDROPROCESSING OF HYDROCARBONS, A METHOD OF MAKING SUCH COMPOSITION

METHODS OF DISCOVERING OR DEVELOPING NOVEL MATERIALS AND MOLECULES

The present inventions relates to methods of discovering or developing novel material or compound. In particular, the methods include the steps of using of general expert knowledge to identify currently available molecules, setting forth desired properties for a target molecule, designing a set of test molecule from the currently available molecule using computational methods (the test molecules having desired properties in the computational models); synthesizing the test molecules, testing the test molecules in real experiments, and identifying the target molecule which is the test molecule that has the desired properties.

Carbon bodies and ferromagnetic carbon bodies

The invention is in the field of modified carbon products. More in particular, the invention is in the field of graphitized activated carbon bodies. The invention is directed to carbon bodies and ferromagnetic carbon bodies, the production of these bodies from activated carbon, and the applications of the carbon bodies and ferromagnetic carbon bodies, for instance in water treatment and in electrochemical applications.

Systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium. The method places in a vicinity of the medium at least one energy modulation agent. The method applies an initiation energy to the medium. The initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the energy modulation agent.

Carbon bodies and ferromagnetic carbon bodies

A composition having an active metal or precursor, an amine component and a non-amine containing polar additive useful in the catalytic hydroprocessing of hydrocarbons, a method of making such composition

6족, 9족 및 10족 금속으로부터 선택된 활성 금속 또는 금속 전구체, 아민 성분, 및 아민 비-함유 극성 첨가제가 로딩된 지지체 물질을 포함하는 조성물이 제공된다. 상기 조성물은 탄화수소 공급원료의 수소화공정에 유용하다. 상기 조성물은 금속 용액을 지지체 물질 내에 혼입시킨 다음 거기에 아민 성분 및 아민 비-함유 극성 첨가제를 혼입시킴으로써 제조된다. There is provided a composition comprising an active metal or metal precursor selected from Group 6, Group 9 and Group 10 metals, an amine component, and a support material loaded with an amine non-containing polar additive. The composition is useful for the hydrogenation process of hydrocarbon feedstocks. The composition is prepared by incorporating a metal solution into a support material and then incorporating an amine component and an amine non-containing polar additive therein.

METHOD AND SYSTEM FOR SELECTING A BEST CASE SET OF FACTORS FOR A CHEMICAL REACTION

A method selects a best case set of factors of a chemical reaction by defining a chemical experimental space by (i) identifying relationships between factors of a candidate chemical reaction space; and (ii) determining a chemical experimental space comprising a table of test cases for each of the factors based on the identified relationships between the factors with the identified relationships based on researcher specified n-tuple combinations between identities of the relationships. A combinatorial high throughput screening (CHTS) method is effected on the chemical experimental space to select the best case set of factors. A system for selecting a best case set of factors of a chemical reaction, comprises a processor, reactor and an evaluator. The processor defines a chemical experimental space by (i) identifying relationships between factors of a candidate chemical reaction space; and (ii) determining the chemical experimental space comprising a table of test cases for each of the factors ...

PLASMONIC ASSISTED SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

A method and a system for producing a change in a medium disposed in an artificial container. The method places inavicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent. 1243.-. (canceled)244. A radiation-cured article , comprising:a radiation-cured medium; andat least one of an energy modulation agent and a plasmonics agent distributed throughout the medium;said energy modulation agent being a substance which converted an initiation energy to a light which cured the radiation-cured medium by polymerization of polymers in the radiation-cured medium.245. The article of claim 244 , wherein said at least one energy modulation agent comprises luminescent agents including at least one of a sulfide claim 244 , a telluride claim 244 , a selenide and an oxide semiconductor.246. The article of claim 245 , wherein the energy modulation agent comprises at least one of YO; ZnS; ZnSe; MgS; CaS; Mn claim 245 , Er ZnSe; Mn Er MgS; Mn claim 245 , Er CaS; Mn claim 245 , Er ZnS; Mn claim 245 ,Yb ZnSe; Mn claim 245 ,Yb MgS; Mn claim 245 , Yb CaS; Mn claim 245 ,Yb ZnS:Tb claim 245 , Er; ZnS:Tb; YO:Tb; YO:Tb claim 245 , Er; ZnS:Mn; ZnS:Mn claim 245 ,Er.247. The article of claim 245 , wherein said luminescent agents comprise nanotubes claim 245 , nanoparticles claim 245 , chemilumiscent particles claim 245 , and bioluminescent particles claim 245 , and mixtures thereof.248. The article of claim 245 , wherein said luminescent agents comprise semiconducting or metallic materials.249. The article of claim 245 , wherein said luminescent agents comprise ...

DOPED CARBONACEOUS MATERIALS FOR PHOTOCATALYTIC REMOVAL OF POLLUTANTS UNDER VISIBLE LIGHT, MAKING METHODS AND APPLICATIONS OF SAME

A method of synthesizing a doped carbonaceous material includes mixing a carbon precursor material with at least one dopant to form a homogeneous/heterogeneous mixture; and subjecting the mixture to pyrolysis in an inert atmosphere to obtain the doped carbonaceous material. A method of purifying water includes providing an amount of the doped carbonaceous material in the water as a photocatalyst; and illuminating the water containing the doped carbonaceous material with visible light such that under visible light illumination, the doped carbonaceous material generates excitons (electron-hole pairs) and has high electron affinity, which react with oxygen and water adsorbed on its surface forming reactive oxygen species (ROS), such as hydroxyl radicals and superoxide radicals, singlet oxygen, hydrogen peroxide, that, in turn, decompose pollutants and micropollutants.

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

A Method for producinga nitrogen functionalised surface

Photocatalyst transfer film and production method thereof

Provided are a photocatalyst transfer film allowing a uniform and highly transparent photocatalyst layer to be transferred to the surfaces of various transfer base materials; and a production method thereof. The photocatalyst transfer film has, on a biaxially oriented polypropylene film, a photocatalyst layer containing a titanium oxide particle-containing photocatalyst, a silicon compound and a surfactant. The production method of the photocatalyst transfer film includes applying a photocatalyst coating liquid to a biaxially oriented polypropylene film; and performing drying. The photocatalyst coating liquid contains a titanium oxide particle-containing photocatalyst, a silicon compound, a surfactant and an aqueous dispersion medium.

Composite material used for catalyzing and degrading nitrogen oxide and preparation method and application thereof

本发明公开了一种用于催化降解氮氧化物的复合材料及其制备方法和用途。本发明的中空石墨相氮化碳纳米球/还原氧化石墨烯复合物-聚合物碳化纳米纤维材料通过下法制备：1）二氧化硅纳米球的制备；2）中空石墨相氮化碳纳米球的制备；3）氧化石墨烯的制备；4）表面修饰的中空石墨相氮化碳纳米球的制备；5）复合物的制备；6）复合物-聚合物碳化纳米纤维材料的制备。本发明的制备方法在制备过程中所采用的原材料成本低廉、容易获得；操作简单、方便，整个过程中没有使用昂贵的设备；所得的复合材料对ppb级别的氮氧化物吸附效率高，重复性好。

DOPED CARBONACEOUS MATERIALS FOR PHOTOCATALYTIC REMOVAL OF POLLUTANTS UNDER VISIBLE LIGHT, MAKING METHODS AND APPLICATIONS OF SAME

A method of synthesizing a doped carbonaceous material includes mixing a carbon precursor material with at least one dopant to form a homogeneous/heterogeneous mixture; and subjecting the mixture to pyrolysis in an inert atmosphere to obtain the doped carbonaceous material. A method of purifying water includes providing an amount of the doped carbonaceous material in the water as a photocatalyst; and illuminating the water containing the doped carbonaceous material with visible light such that under visible light illumination, the doped carbonaceous material generates excitons (electron-hole pairs) and has high electron affinity, which react with oxygen and water adsorbed on its surface forming reactive oxygen species (ROS), such as hydroxyl radicals and superoxide radicals, singlet oxygen, hydrogen peroxide, that, in turn, decompose pollutants and micropollutants.

N-heterocyclic carbene (NHC) based ligands and related methods

Polydentate macrocyclic NHCs (NHC ligands) and related methods are disclosed. Such ligands advantageously facilitate a variety of ligand coordination modes and stabilize oxidation states of metal complexes with a number of coordination environments and shapes. The NHC ligands described herein comprise pendant groups configured to facilitate a variety of reactions including: cis-trans isomerization, proton shuttling and facilitating changes in coordination environments as a result of redox reactions.

DECORATION OF MATERIALS

A METHOD FOR PRODUCING A NITROGEN FUNCTIONALISED SURFACE

Verfahren zur Herstellung von Metall-N-heterocyclischen Carben-K omplexen

Die vorliegende Erfindung betrifft Metall-N-heterocyclische Carben-Komplexe (Metall-NHC-Komplexe) sowie deren Synthese. Im Unterschied zu klassischen Synthesen wird hierbei im letzten Reaktionsschritt nicht die M-CCarben Bindung geknüpft, sondern in einer modularer Dreikomponenten-Templatsynthese der Ringschluss des NHC vollzogen. Hieraus ergibt sich eine hohe Synthese-Modularität. Die erfindungsgemäß hergestellten Komplexe sind insbesondere als Katalysatoren verwendbar. The present invention relates to metal-N-heterocyclic carbene complexes (metal NHC complexes) and their synthesis. In contrast to classical syntheses, in the last reaction step not the M-C-color bond is attached, but in a modular three-component template synthesis the ring closure of the NHC is performed. This results in a high synthesis modularity. The complexes prepared according to the invention are usable in particular as catalysts.

PLASMONIC ASSISTED SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

탄소체 및 강자성 탄소체

... 본 발명은 개질된 탄소 제품의 분야에 관한 것이다. 더욱 상세하게는, 본 발명은 부분 흑연화된 활성탄체의 분야에 관한 것이다. 본 발명은 탄소체 및 강자성 탄소체, 활성탄으로부터 이들 체의 생산, 및 예를 들면 수처리에서 및 전기 화학적 적용에서 탄소체 및 강자성체의 용도에 관한 것이다.

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

DIRECT ANTI-MARKOVNIKOV ADDITION OF ACIDS TO ALKENES

A method of making an anti-Markovnikov addition product is carried out by reacting an acid with an alkene or alkyne in a dual catalyst reaction system to the exclusion of oxygen to produce said anti-Markovnikov addition product; the dual catalyst reaction system comprising a single electron oxidation catalyst in combination with a hydrogen atom donor catalyst. Compositions useful for carrying out such methods are also described.

Composition having an active metal or precursor, an amine component and a non-amine containing polar additive useful in the catalytic hydroprocessing of hydrocarbons, a method of making such catalyst, and a process of using such catalyst

A composition that comprises a support material that is loaded with an active metal or metal precursor, an amine component, and a non-amine containing polar additive. The composition is useful in the hydroprocessing of hydrocarbon feedstocks. The composition is prepared by incorporating a metal solution into a support material followed by incorporating therein an amine component and a non-amine containing polar additive.

Method for producing a nitrogen functionalised surface

A method is provided for applying a coating containing reactive nitrogen functionality contained within an aromatic heterocyclic structure to a substrate. The method includes subjecting said substrate to a plasma discharge of a monomer possessing said heterocyclic nitrogen functionality.

Artificial zeolites

Zeolites are industrially important materials possessing high Bronsted acidity and shape-selectivity. However, their inherently small pores restrict application for catalytic conversion of bulky molecules. A method of synthesis of ‘artificial’ zeolites. The artificial zeolites have well-tailored Bronsted and Lewis acid sites prepared on mesostructured silica to circumvent this limitation. This novel approach utilizes atomic layer deposition to tailor both porosity and acid speciation, providing exquisite control over catalytic behavior and enabling systematic studies.

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

METHODS OF DISCOVERING OR DEVELOPING NOVEL MATERIALS AND MOLECULES

The present inventions relates to methods of discovering or developing novel material or compound. In particular, the methods include the steps of using of general expert knowledge to identify currently available molecules, setting forth desired properties for a target molecule, designing a set of test molecule from the currently available molecule using computational methods (the test molecules having desired properties in the computational models); synthesizing the test molecules, testing the test molecules in real experiments, and identifying the target molecule which is the test molecule that has the desired properties.

POLYMER-SUPPORTED METAL NANOPARTICLES, PROCESS FOR PRODUCTION THEREOF AND POLYMERIC NANOREACTORS PRODUCED THEREFROM

A process for producing polymer-supported metal nanoparticles involves confinement of metal nanoparticles in polymeric nanotubes or nanosheets in an aqueous environment using hydrophobic reactants. Metal nanoparticles supported in the polymeric nanotubes or nanosheets are substantially monodisperse and have an average particle size of 4 nm or less. The polymer-supported metal nanoparticles are useful in fuel cells, sensors, bioanalysis, biological labeling or semi-conductors, especially as catalysts.

CARBON BODIES FERROMAGNETIC AND PRODUCTION PROCESS

Cuerpos de carbono y cuerpos de carbono ferromagnéticos, a la producción de estos cuerpos a partir de carbón activado, y a las aplicaciones de los cuerpos de carbono y cuerpos de carbono ferromagnéticos, por ejemplo, en el tratamiento de aguas y en aplicaciones electroquímicas.

Catalytic carbon fiber contactor

A fiber bundle contactor may include: a flow path defined by a conduit; a catalytic carbon fiber bundle disposed in the conduit; and an inlet allowing fluid flow into the flow path. A method may include: introducing into vessel a hydrocarbon comprising mercaptan sulfur, an aqueous caustic solution, and an oxidizer; reacting at least a portion of the mercaptan sulfur and the aqueous caustic solution to produce a mercaptide; and reacting the mercaptide and the oxidizer in the presence of a catalytic carbon fiber bundle to produce a disulfide oil.

A METHOD FOR PRODUCING A NITROGEN FUNCTIONALISED SURFACE

A method is provided for applying a coating containing reactive nitrogen functionality contained within an aromatic heterocyclic structure to a substrate. The method includes subjecting said substrate to a plasma discharge of a monomer possessing said heterocyclic nitrogen functionality.

Systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium. The method places in a vicinity of the medium at least one energy modulation agent. The method applies an initiation energy to the medium. The initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the energy modulation agent.

RADICAL GENERATING CATALYST, METHOD FOR PRODUCING RADICAL, METHOD FOR PRODUCING OXIDATION REACTION PRODUCT, DRUG, AND DRUG FOR USE IN AGRICULTURE AND LIVESTOCK INDUSTRY

The present invention is intended to provide a radical generating catalyst that can generate (produce) radicals under mild conditions. In order to achieve the above object, the first radical generating catalyst of the present invention includes: at least one selected from the group consisting of amino acids, peptides, phospholipids, and salts thereof. The second or third radical generating catalyst of the present invention includes an ammonium salt represented by the following chemical formula (XI) (excluding peroxodisulfate) and having a Lewis acidity of 0.4 eV or more. 1. A radical generating catalyst comprising:at least one selected from the group consisting of amino acids, proteins, peptides, phospholipids, and salts thereof, whereinthe radical generating catalyst catalyzes radical generation from a radical source, andthe radical source comprises an oxoacid or an ion or salt thereof.2. The radical generating catalyst according to claim 1 , further comprising:ammonium.5. (canceled)6. The radical generating catalyst according to claim 4 , whereinthe ammonium is at least one selected from the group consisting of benzethonium chloride, benzalkonium chloride, hexadecyltrimethylammonium chloride, tetramethylammonium chloride, ammonium chloride, methylammonium chloride, tetrabutylammonium chloride, cetylpyridinium chloride, hexadecyltrimethylammonium bromide, dequalinium chloride, edrophonium, didecyldimethylammonium chloride, benzyltriethylammonium chloride, oxytropium, carbachol, glycopyrronium, safranin, sinapine, tetraethylammonium bromide, hexadecyltrimethylammonium bromide, suxamethonium, sphingomyelin, ganglioside GM1, denatonium, trigonelline, neostigmine, paraquat, pyridostigmine, phellodendrine, pralidoxime methiodide, betaine, betanin, bethanechol, betalain, lecithin, adenine, guanine, cytosine, thymine, uracil, and cholines.7. (canceled)12. The radical generating catalyst according to claim 1 , whereinthe amino acid is at least one selected from the group ...

Herstellungsartikel zur Sicherung eines Katalysator-Substrats

Eine Nachbehandlungskomponente zur Verwendung in einem Abgasnachbehandlungssystem. Die Nachbehandlungskomponente umfasst ein Nachbehandlungssubstrat und ein komprimierbares Material. Das komprimierbare Material kann aus einem plastischen Thermoset, einem gummierten Material oder einer Metallfolie bestehen, die eine selektive Expansion des Substrats in dem komprimierbaren Material erlaubt, während gleichzeitig Kosten gespart und die herstellungstechnische Komplexität verringert wird. Bei verschiedenen Ausführungen können das Nachbehandlungssubstrat und die komprimierbaren Materialien separat geformt und miteinander verbunden, oder gleichzeitig durch Koextrusion hergestellt werden.

Adamantane-intercalated layered double hydroxide

Embodiments are directed to adamantane-intercalated layered double-hydroxide (LDH) particles and the methods of producing adamantane-intercalated LDH particles. The adamantane-intercalated LDH particles have a general formula defined by [M1-xAlx(OH)2](A)x.mH2O, where x is from 0.14 to 0.33, m is from 0.33 to 0.50, M is chosen from Mg, Ca, Co, Ni, Cu, or Zn, and A is adamantane carboxylate. The adamantane-intercalated LDH particles further have an aspect ratio greater than 100. The aspect ratio is defined by the width of an adamantane-intercalated LDH particle divided by the thickness of the adamantane-intercalated LDH particle.

Method and system for selecting a best case set of factors for a chemical reaction

A method selects a best case set of factors of a chemical reaction by defining a chemical experimental space by (i) identifying relationships between factors of a candidate chemical reaction space; and (ii) determining a chemical experimental space comprising a table of test cases for each of the factors based on the identified relationships between the factors with the identified relationships based on researcher specified n-tuple combinations between identities of the relationships. A combinatorial high throughput screening (CHTS) method is effected on the chemical experimental space to select the best case set of factors. A system for selecting a best case set of factors of a chemical reaction, comprises a processor, reactor and an evaluator. The processor defines a chemical experimental space by (i) identifying relationships between factors of a candidate chemical reaction space; and (ii) determining the chemical experimental space comprising a table of test cases for each of the factors ...

Polymer-supported metal nanoparticles, process for production thereof and polymeric nanoreactors produced therefrom

A process for producing polymer-supported metal nanoparticles involves confinement of metal nanoparticles in polymeric nanotubes or nanosheets in an aqueous environment using hydrophobic reactants. Metal nanoparticles supported in the polymeric nanotubes or nanosheets are substantially monodisperse and have an average particle size of 4 nm or less. The polymer-supported metal nanoparticles are useful in fuel cells, sensors, bioanalysis, biological labeling or semi-conductors, especially as catalysts.

Composite material used for catalyzing and degrading nitrogen oxide and preparation method and application thereof

The invention discloses a composite material used for catalyzing and degrading nitrogen oxide and its preparation method and application thereof. The invention of the hollow g-C3N4 nanospheres/reduced graphene oxide composite-polymer carbonized nanofiber material is prepared as follow: 1) the preparation of silica nanospheres; 2) the preparation of hollow g-C3N4 nanospheres; 3) the preparation of graphene oxide; 4) the preparation of surface modified hollow g-C3N4 nanoparticles preparation; 5) the preparation of composites; 6) the preparation of composite-polymer carbon nanofiber material. The raw materials used in the process is low cost and easy to get; the operation of the invention is simple and convenient without the use of expensive equipment in the whole process; the composite has high adsorption efficiency of ppb level nitrogen oxide with good repeatability.

HYDROCHLORIC ACID STRIPPING PROCESS FOR IONIC LIQUID REGENERATION PROCESS

A method for regenerating deactivated acidic ionic liquid is described. The method involves reducing a level of free hydrochloric acid in the deactivated acidic ionic liquid in a removal zone using at least one of heat, a stripping fluid, reduced pressure, and liquid-liquid extraction to form a deactivated acidic ionic liquid having a reduced level of free hydrochloric acid; and regenerating the deactivated acidic ionic liquid having the reduced level of free hydrochloric acid.

Verfahren zur Herstellung von Metall-N-heterocyclischen Carben-Komplexen

Verfahren zur Herstellung von Metall-N-heterocyclischen Carben-Komplexen (Metall-NHC-Komplexen) mittels modularer Dreikomponenten-Templatsynthese, umfassend die Umsetzung einer Metallligandverbindung MLmL'n mit der Formel (II), eines CH-aziden Isocyanids mit der allgemeinen Formel (III) und eines Imins mit der allgemeinen Formel (IV).wobei M aus Au, Rh, Ir oder Ru ausgewählt ist, L und L' ein für das jeweilige Metall geeigneter Ligand sind, welcher durch die Koordination auch m und n, die Anzahl der Liganden, vorgibt, wobei m und n jeweils 0, 1, 2, 3 oder 4 sind, Ar aus einer un-, mono- oder disubstituierten Phenylgruppe ausgewählt ist, wobei die Substituenten unabhängig voneinander aus der Gruppe α, bestehend aus einem Wasserstoffatom, einem geradkettigen oder verzweigtkettigen (C1-C15)-Alkylrest, einem (C1-C15)-Thioalkylrest, einem (C3-C15)-Cycloalkylrest, der ein oder mehrere Heteroatome aufweisen kann, einem (C1-C15)-Alkoxyrest, einer Trifluormethylgruppe, Brom, Chlor und Fluor ausgewählt sind, Ar' aus einem geradkettigen oder verzweigtkettigen (C1-C15)-Alkylrest oder aus einer un-, mono- oder disubstituierten Phenylgruppe ausgewählt ist, wobei die Substituenten unabhängig voneinander aus der Gruppe α, bestehend aus einem Wasserstoffatom, einem geradkettigen oder verzweigtkettigen (C1-C15)-Alkylrest, einem (C1-C15)-Thioalkylrest, einem (C3-C15)-Cycloalkylrest, der ein oder mehrere Heteroatome aufweisen kann, einem (C1-C15)-Alkoxyrest, einer Trifluormethylgruppe, Brom, Chlor und Fluor ausgewählt sind, R aus einem geradkettigen oder verzweigtkettigen, unsubstituierten oder substituierten (C1-C15)-Alkylrest, wobei die Substituenten terminale Phenylreste sein können und die Alkylreste durch Etherverbindungen verknüpft sein können, einem (C3-C15)-Cycloalkylrest, der ein oder mehrere Heteroatome, wie beispielsweise O oder S, aufweisen kann, einer un-, mono- oder disubstituierten Phenyl- oder Benzylgruppe ausgewählt sind, wobei die Substituenten unabhängig ...

Ganzzell-basierte Biohybridkatalysator-Systeme

Die vorliegende Erfindung betrifft ein Biohybridkatalysator-System, umfassend oder bestehend aus (a) einer intakten, nicht-menschlichen Zelle und (b) einem oder mehreren künstlichen Metalloenzym(en) bestehend aus (b1) einem Proteingerüst und (b2) einem an das Proteingerüst angebundenen, katalytisch aktiven Metallkomplex, wobei das/die Metalloenzym(e) in der Zellmembran verankert und/oder an der Zelloberfläche der Zelle angebunden ist/sind. Gemäß weiteren Aspekten betrifft die vorliegende Erfindung ebenfalls ein Verfahren zur Herstellung eines solchen Biohybridkatalysator-Systems und die Verwendung eines solchen Biohybridkatalysator-Systems als Katalysator zur Katalyse von chemischen Reaktionen.

N-HETEROCYCLIC CARBENE (NHC) BASED LIGANDS AND RELATED METHODS

Polydentate macrocyclic NHCs (NHC ligands) and related methods are disclosed. Such ligands advantageously facilitate a variety of ligand coordination modes and stabilize oxidation states of metal complexes with a number of coordination environments and shapes. The NHC ligands described herein comprise pendant groups configured to facilitate a variety of reactions including: cis-trans isomerization, proton shuttling and facilitating changes in coordination environments as a result of redox reactions.

Photocatalyst transfer film and method for manufacturing same

Provided are a photocatalyst transfer film which enables transfer processing of a uniform and highly transparent photocatalyst layer onto the surface of various transfer substrates, and a method for manufacturing the same. The photocatalyst transfer film comprises a biaxially drawn polypropylene film and a photocatalyst layer disposed thereon, said photocatalyst layer comprising a photocatalyst containing titanium oxide particles, a silicon compound and a surfactant. The method for manufacturing a photocatalyst transfer film is characterized by comprising applying a photocatalyst coating solution, which comprises a photocatalyst containing titanium oxide particles, a silicon compound, a surfactant and an aqueous dispersion medium, to a biaxially drawn polypropylene film and drying.

SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

A method and a system for producing a change in a medium. The method places in a vicinity of the medium at least one energy modulation agent. The method applies an initiation energy to the medium. The initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the energy modulation agent.

고체 산 촉매, 및 산화물의 제조 방법

... 기질을 산소와 오존의 공존 하에서 산화시킬 때 사용하는 산소-오존 공존 하 산화 반응용의 고체 산 촉매이며, 해당 기질을 높은 전화율로 산화시킬 수 있는 고체 산 촉매를 제공한다. 본 발명의 산소-오존 공존 하 산화용 고체 산 촉매는, 기질 (A)를 산소와 오존의 공존 하에서 산화시킬 때 사용하는 산화 반응용의 고체 산 촉매로서, 해미트의 산도 함수 (H0)이 -9 이하인 강산 또는 초강산을 적어도 표면에 갖는 담체에, 전이 금속이 단체, 화합물 또는 이온의 형태로 담지되어 있는 것을 특징으로 한다. 상기 담체는, 불소화술폰산계 수지를 포함하는 펠릿 혹은 분립체, 또는 고체 표면에 불소화술폰산계 수지의 피막이 형성된 담체인 것이 바람직하다.

Un metodo para endurecer un medio endurecible por radiacion que comprende colocar una composicion dentro de un objeto para ser endurecido, la aplicacion de al menos uno elegido entre rayos x, rayos gama o haz de electrones a traves del objeto y dentro de la composicion.

UN MÉTODO PARA ENDURECER UN MEDIO ENDURECIBLE POR RADIACIÓN QUE COMPRENDE: COLOCAR UNA COMPOSICIÓN DENTRO DE UN OBJETO PARA SER ENDURECIDO, DICHA COMPOSICIÓN COMPRENDIENDO 1) UN MEDIO ENDURECIBLE POR RADIACIÓN NO ENDURECIDO Y 2) UN AGENTE MODULADOR DE LA ENERGÍA; APLICAR AL MENOS UNO ELEGIDO ENTRE RAYOS X, RAYOS GAMMA O UN HAZ DE ELECTRONES A TRAVÉS DEL OBJETO Y DENTRO DE LA COMPOSICIÓN, DONDE LA ENERGÍA DE INICIACIÓN INTERACTÚA CON EL AGENTE MODULADOR DE LA ENERGÍA EL CUAL EMITE LUZ DENTRO DEL MEDIO ENDURECIBLE POR RADIACIÓN PARA DIRECTA O INDIRECTAMENTE ENDURECER EL MEDIO NO ENDURECIDO POR POLIMERIZACIÓN DE POLÍMEROS EN EL MEDIO; Y CON LA LUZ EMITIDA, ENDURECER EL MEDIO ENDURECIBLE POR RADIACIÓN POR ACTIVACIÓN DE UN FOTOINICIADOR EN EL MEDIO ENDURECIBLE POR RADIACIÓN.

HIGH ASPECT RATIO LAYERED DOUBLE HYDROXIDE MATERIALS AND METHODS FOR PREPARATION THEREOF

고분자 표면상의 가시광 활성화 방식 산화티타늄　광촉매 코팅, 그 제조방법 및 그 사용

... 본 발명은 고분자 표면상의 가시광 활성 방식 산화티타늄(IV) 광촉매 코팅에 관한 것으로, 이 코팅은 의약품, 식품 및 제약 포장용 유기 고분자 물질인 기판에 적용되며, 나노결정성 산화티타늄(IV), 또는 유기화합물에 의해 표면 개질된 나노결정성 산화티타늄(IV)으로 이루어진다. 또한 본 발명은 산화티타늄(IV) 광촉매 코팅의 제조방법에 관한 것으로 고분자 물질의 표면을 저온 플라즈마법에 의해 활성화시키는 단계, 나노결정성 산화티타늄(IV) 코팅을 합성시키는 단계, 및 c) 표면층을 유기화합물에 의해 개질시키는 단계를 포함한다. 또한 본 발명은 산화티타늄(IV) 광촉매 코팅의 적용에 관한 것으로, 이 코팅은 의약품, 식품 및 제약 포장용 플라스틱 성분의 살균에 적용되며, 광살균성 물질, 광에 의한 살세균성 물질, 광에 의한 살진균성 물질, 및 광촉매성 물질로 이루어진 군에서 선택된 제품의 제조에도 적용된다.

CATALYST FOR CELLULOSE HYDROLYSIS

The present invention is directed to an imprinted mesoporous silica catalyst functionalized with a carboxylic acid group, capable of binding and hydrolyzing at least one glucose substrate into glucose. 1. A biomimetic catalyst , said catalyst comprising:a polymeric silica matrix,at least one active site imprinted into said matrix, andat least one carboxylic acid functionality in said active site.2. The biomimetic catalyst of claim 1 , wherein said catalyst is capable of catalyzing hydrolysis of at least one glucose substrate.3. The bimimetic catalyst according to wherein said catalyst has an activity of at least 20 μmoles·min/mg catalyst.4. The bimimetic catalyst according to wherein said catalyst has an activity of at least 80 μmoles·min/mg catalyst.5. The biomimetic catalyst of claim 1 , prepared by reacting at least one tetraorthosilicate and at least one functionalized silane in the presence of at least one imprinting molecule to form a polymeric silica matrix impregnated with said at least one imprinting molecule claim 1 , wherein at least 1 mol percent of said at least one functionalized silane comprises a carboxylic acid or carboxylic acid precursor functionalized silane; isolating said impregnated polymeric silica matrix; and removing said at least one imprinting molecule from said impregnated polymeric silica matrix via washing or burning to form a silica matrix imprinted with the structure of said at least one imprinting molecule.6. The biomimetic catalyst of claim 1 , wherein said at least one functionalized silane comprises a carboxylic acid precursor and said process further comprises hydrolyzing said carboxylic acid precursor.7. The biomimetic catalyst of claim 6 , wherein said carboxylic acid precursor is a nitrile group.8. The biomimetic catalyst of claim 1 , wherein said at least one imprinting molecule is selected from the group consisting of cellobiose claim 1 , hydroxyethyl cellulose claim 1 , Avicel claim 1 , cellulose and beta glucan.9. The ...

ARTIFICIAL ZEOLITES

Zeolites are industrially important materials possessing high Bronsted acidity and shape-selectivity. However, their inherently small pores restrict application for catalytic conversion of bulky molecules. A method of synthesis of ‘artificial’ zeolites. The artificial zeolites have well-tailored Bronsted and Lewis acid sites prepared on mesostructured silica to circumvent this limitation. This novel approach utilizes atomic layer deposition to tailor both porosity and acid speciation, providing exquisite control over catalytic behavior and enabling systematic studies. 1. A method of increasing Bronsted acidity comprising:forming amorphous silica-alumina on a substrate;depositing a material having a silicon-oxygen species by atomic layer deposition; andforming a plurality of silanol functional groups on the amorphous silica-alumina substrate.2. The method of claim 1 , wherein for a portion of the plurality of silanol functional groups claim 1 , further comprising forming a bridge with an adjacent aluminum atom;3. The method of claim 2 , wherein the portion of the plurality of silanol functional groups bridged with an adjacent aluminum atom for a Bronsted acid site.4. The method of claim 1 , wherein the deposited material is silica.5. The method of claim 1 , wherein forming the amorphous silica-alumina comprises depositing an aluminum containing material by ALD.6. The method of claim 4 , wherein the deposition of the aluminum containing material compress a single exposure to trimethyl Aluminum (TMA).7. The method of claim 5 , wherein the deposition of aluminum further comprises a water exposure following the single TMA exposure claim 5 , followed by a purge and then a TMSiOH exposure.8. The method of claim 6 , wherein the deposition of the silicon-oxygen material comprises at least one TMSiOH ALD cycle.9. The method of claim 7 , wherein the deposition of the silicon-oxygen material comprises between 3 and 30 TMSiOH ALD cycles.10. The method of claim 1 , wherein a ...

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

Processes for removing entrained ionic liquid from a hydrocarbon phase

One or more processes for recovering entrained ionic liquid from a hydrocarbon phase containing droplets of ionic liquid are described. The processes includes contacting the hydrocarbon phase containing the droplets of ionic liquid with a retaining material in a separation zone. The droplets of ionic liquid are retained by the retaining material. The ionic liquid may be recovered from the retaining material with a solvent or desorbent. The retaining material may be regenerated and the ionic liquid may be reactivated. The retaining material may be used in a wash vessel to retain or remove contaminant solids within the reactor or other vessels.

PHOTOCATALYST TRANSFER FILM AND PRODUCTION METHOD THEREOF

Provided are a photocatalyst transfer film allowing a uniform and highly transparent photocatalyst layer to be transferred to the surfaces of various transfer base materials; and a production method thereof. The photocatalyst transfer film has, on a biaxially oriented polypropylene film, a photocatalyst layer containing a titanium oxide particle-containing photocatalyst, a silicon compound and a surfactant. The production method of the photocatalyst transfer film includes applying a photocatalyst coating liquid to a biaxially oriented polypropylene film; and performing drying. The photocatalyst coating liquid contains a titanium oxide particle-containing photocatalyst, a silicon compound, a surfactant and an aqueous dispersion medium. 1. A photocatalyst transfer film having , on a biaxially oriented polypropylene film , a photocatalyst layer containing a titanium oxide particle-containing photocatalyst , a silicon compound and a surfactant.2. The photocatalyst transfer film according to claim 1 , wherein the silicon compound is a hydrolysis condensate of a tetrafunctional silicon compound claim 1 , the hydrolysis condensate being obtained under the presence of an organic ammonium salt.3. The photocatalyst transfer film according to claim 1 , wherein the surfactant is an acetylene-based surfactant.4. The photocatalyst transfer film according to claim 1 , wherein the photocatalyst layer has a thickness of 20 to 300 nm.5. The photocatalyst transfer film according to claim 1 , wherein the biaxially oriented polypropylene film has a thickness of 12.5 to 100 μm.6. The photocatalyst transfer film according to claim 1 , wherein a protective layer containing a silicon compound is further laminated on the photocatalyst layer.7. A method for producing a photocatalyst transfer film claim 1 , comprising:applying a photocatalyst coating liquid to a biaxially oriented polypropylene film, the photocatalyst coating liquid containing a titanium oxide particle-containing photocatalyst ...

Preparation of catalyst, useful for hydrogenating an unsaturated substrate, comprises reacting a metal pre-catalyst with an acid

Preparation of hydrogenation catalyst from a pre-catalyst (I) comprises reacting (I) with an acid. Preparation of hydrogenation catalyst from a pre-catalyst (I) of formula: (M1M2M3(PP1)(PP2)(PP3)(mu 3-L1)(mu 3-L2)n+>(Am)n->) comprises reacting (I) with an acid. n, m : 1-3; M1-M3a transition metal; PP1-PP3multidentate ligand; mu 3-L1, mu 3-L2bridging ligand; and A : anion. Independent claims are included for: (1) hydrogenation catalyst obtained by the above process; and (2) a method for the catalytic hydrogenation of unsaturated substrate comprising mixing the unsaturated substrate with the hydrogenation catalyst.

Composition having an active metal or precursor, an amine component and a non-amine containing polar additive useful in the catalytic hydroprocessing of hydrocarbons, a method of making such catalyst, and a process of using such catalyst

A composition that comprises a support material that is loaded with an active metal or metal precursor, an amine component, and a non-amine containing polar additive. The composition is useful in the hydroprocessing of hydrocarbon feedstocks. The composition is prepared by incorporating a metal solution into a support material followed by incorporating therein an amine component and a non-amine containing polar additive.

For catalyzing the degradation of the oxides of nitrogen composite material and its preparation and use

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

Photothermal Catalytic Method for Production of Hydrogen Peroxide without Sacrificial Reagents on Basis of Porphyrin-based Supermolecule

A photothermal catalytic method for production of hydrogen peroxide without a sacrificial reagent on the basis of a porphyrin-based supermolecule is provided. The method includes the following steps: uniformly mixing a porphyrin-based supermolecule photocatalyst with a concentration of 0.3-1.5 g/L with ultrapure water, conducting irradiation with a visible light for a period of time under stirring at a temperature of 40-80° C. and an O 2 flow rate of 50-150 mL/min, and then filtering and concentrating a reaction liquid to obtain an aqueous hydrogen peroxide solution with a high concentration. According to the new photothermal catalytic method for preparing the hydrogen peroxide provided in the present disclosure, no organic solvent (such as ethanol, isopropanol and benzyl alcohol) is used as a sacrificial reagent, and the method is environmentally friendly and free of pollution. O 2 is used as an oxygen source, sunlight is used as an energy source, and the method is low in energy consumption and high in safety (compared with an industrial anthraquinone method for synthesizing hydrogen peroxide). The method is simple in operation, mild in reaction conditions and high in production of the hydrogen peroxide.

Catalytic Carbon Fiber Contactor

A fiber bundle contactor may include: a flow path defined by a conduit; a catalytic carbon fiber bundle disposed in the conduit; and an inlet allowing fluid flow into the flow path. A method may include: introducing into vessel a hydrocarbon comprising mercaptan sulfur, an aqueous caustic solution, and an oxidizer; reacting at least a portion of the mercaptan sulfur and the aqueous caustic solution to produce a mercaptide; and reacting the mercaptide and the oxidizer in the presence of a catalytic carbon fiber bundle to produce a disulfide oil.

Systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium. The method places in a vicinity of the medium at least one energy modulation agent. The method applies an initiation energy to the medium. The initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the energy modulation agent.

Article for securing a catalyst substrate

COMPOSITION HAVING AN ACTIVE METAL OR PRECURSOR, AN AMINE COMPONENT AND A NON-AMINE CONTAINING POLAR ADDITIVE USEFUL IN THE CATALYTIC HYDROPROCESSING OF HYDROCARBONS, A METHOD OF MAKING SUCH CATALYST, AND A PROCESS OF USING SUCH CATALYST

A composition that comprises a support material that is loaded with an active metal or metal precursor, an amine component, and a non-amine containing polar additive. The composition is useful in the hydroprocessing of hydrocarbon feedstocks. The composition is prepared by incorporating a metal solution into a support material followed by incorporating therein an amine component and a non-amine containing polar additive. 1. A method of making a composition , wherein said method comprises: incorporating a metal-containing solution into a support material to provide a metal-incorporated support material; and incorporating both an amine component and a non-amine containing polar additive into said metal-incorporated support material to thereby provide an impregnated composition comprising said support material , said amine component , and said non-amine containing polar additive.2. A method as recited in claim 1 , further comprising: contacting said impregnated composition under suitable hydrogen treatment conditions with hydrogen to thereby provide a hydrogen-treated composition.3. A method as recited in claim 2 , wherein prior to said incorporating of said amine component and said non-amine containing polar additive into said metal-incorporated support material claim 2 , said metal-incorporated support material is dried so as to contain a volatiles content in the range of from 3 to 20 wt. % LOI.4. A method as recited in claim 1 , wherein the weight ratio of said non-amine containing polar additive to said amine component is in the range of upwardly to 10:1; wherein said amine component is selected from the group of compounds consisting of ether amine compounds claim 1 , alkyl amine compounds claim 1 , and amine oxide compounds; and wherein said amine compound has a molecular weight greater than 160 and a flash point of at least 80° C.5. A method as recited in claim 4 , wherein said amine component is an ether amine compound.6. A method as recited in claim 5 , wherein ...

Article of Manufacture for Securing a Catalyst Substrate

An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and the compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion.

Article of Manufacture for Securing a Catalyst Substrate

An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and The compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion.

Surface-modified light upconversion silica particles

A composition, method, and article of manufacture are disclosed. The composition includes a silica particle with light upconversion molecules bound to its surface. The method includes obtaining silica particles and light upconversion molecules having sidechains with reactive functional groups. The method further includes binding the light upconversion molecules to surfaces of the silica particles. The article of manufacture includes the composition.

HIGH ASPECT RATIO LAYERED DOUBLE HYDROXIDE MATERIALS AND METHODS FOR PREPARATION THEREOF

Embodiments are directed to adamantane-intercalated layered double-hydroxide (LDH) particles and the methods of producing adamantane-intercalated LDH particles. The adamantane-intercalated LDH particles have a general formula defined by [MAl(OH)](A).mHO, where x is from 0.14 to 0.33, m is from 0.33 to 0.50, M is chosen from Mg, Ca, Co, Ni, Cu, or Zn, and A is adamantane carboxylate. The adamantane-intercalated LDH particles further have an aspect ratio greater than 100. The aspect ratio is defined by the width of an adamantane-intercalated LDH particle divided by the thickness of the adamantane-intercalated LDH particle. 1. An adamantane-intercalated layered double-hydroxide (LDH) material in a form of adamantane-intercalated LDH particles , where the adamantane-intercalated LDH particles comprise:{'sub': 1-x', 'x', '2', 'x', '2, 'a general formula defined by [MAl(OH)](A).mHO, where x is from 0.14 to 0.33, m is from 0.33 to 0.50, M is chosen from Mg, Ca, Co, Ni, Cu, or Zn, and A is adamantane carboxylate; and'}an aspect ratio greater than 100, the aspect ratio defined by a width of an adamantane-intercalated LDH particle divided by a thickness of the adamantane-intercalated LDH particle.2. The adamantane-intercalated LDH material of where M is Mg.3. The adamantane-intercalated LDH material of where the aspect ratio is greater than 125.4. The adamantane-intercalated LDH material of where the aspect ratio is greater than 150.5. The adamantane-intercalated LDH material of where the aspect ratio is greater than 200.6. The adamantane-intercalated LDH material of where the adamantane-intercalated LDH particles have a particle diameter of 5 to 10 μm.7. The adamantane-intercalated LDH material of where the adamantane-intercalated LDH particles have characteristic peaks in an IR spectra at 1517 cm claim 1 , 1395 cm claim 1 , 2901 cm claim 1 , 2847 cm claim 1 , and 4302 cm. This application is a divisional application of U.S. patent application Ser. No. 15/449,207 filed Mar. ...

Photocatalytic coating, process for producing photocatalytic coating, and process for producing photocatalytic body

This photocatalytic coating contains at least a photocatalytic particle, a binder and water. The binder includes a water-soluble hydrolysate of a silane coupling agent having an ethylene oxide structure. A content of the water-soluble hydrolysate of the silane coupling agent having the ethylene oxide structure is preferably 0.5% by weight or more and 20% by weight or less, based on a weight of a total solid content contained in the photocatalytic coating.

PLASMONIC ASSISTED SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent. 1. (canceled)2. A system for producing a change in a medium to be treated , comprising:an energy source capable of producing an initiation energy comprising one or more of x-rays, gamma rays, or an electron beam;a container holding the medium to be treated;an energy modulation agent surrounded by an encapsulation, disposed inside or in a vicinity of the medium to be treated, and separated physically from the medium to be treated by the encapsulation; andsaid energy modulation agent comprising a photon emitter which emits at least one of ultraviolet and visible light upon interaction with said initiation energy, wherein said at least one of ultraviolet and visible light stimulates a chemical or biological process in the medium.3. The system of claim 2 , wherein the energy modulation agent comprises at least one of a sulfide claim 2 , a telluride claim 2 , a selenide and an oxide semiconductor.4. The system of claim 2 , wherein said at least one of ultraviolet and visible light stimulates claim 2 , for said chemical or biological process claim 2 , a change in an organism activity of the medium.5. The system of claim 2 , wherein said container comprises at least one of an aluminum container claim 2 , a quartz container claim 2 , a glass container claim 2 , a plastic container or a combination thereof.6. The system of claim 2 , wherein said encapsulation comprises at ...

DIRECT ANTI-MARKOVNIKOV ADDITION OF ACIDS TO ALKENES

A method of making an anti-Markovnikov addition product is carried out by reacting an acid with an alkene or alkyne in a dual catalyst reaction system to the exclusion of oxygen to produce said anti-Markovnikov addition product; the dual catalyst reaction system comprising a single electron oxidation catalyst in combination with a hydrogen atom donor catalyst. Compositions useful for carrying out such methods are also described. 1. A method of making an anti-Markovnikov addition product , comprising:reacting an acid with an alkene or alkyne in a dual catalyst reaction system to the exclusion of oxygen to produce said anti-Markovnikov addition product;said dual catalyst reaction system comprising a single electron oxidation catalyst in combination with a hydrogen atom donor catalyst.2. The method of claim 1 , wherein said anti-Markovnikov addition product is produced regioselectively in a ratio of at least 5:1 of anti-Markovnikov addition product as compared to the corresponding Markovnikov addition product.4. The method of claim 3 , wherein A claim 3 , B claim 3 , and C are each independently selected from the group consisting of halo claim 3 , aryl claim 3 , cyano claim 3 , carboxyl claim 3 , and carbonyl groups.5. The method of claim 1 , wherein said single electron oxidation catalyst is a photocatalyst.6. The method of claim 5 , wherein said photocatalyst comprises a carbocyclic or heterocyclic aromatic compound containing ring nitrogen heteroatoms.7. The method of claim 6 , wherein said photocatalyst comprises an anthracene claim 6 , aza-anthracene or polyaza-anthracene nucleus which is unsubstituted claim 6 , substituted or polysubstituted at any position with halogen claim 6 , and/or with one or more lower alkyl or cycloalkyl radicals claim 6 , and/or with other phenyl substituents.8. The method of claim 5 , wherein said photocatalyst has a reduction potential of about −1.0 V to +0.1 V against a saturated calomel reference electrode in 100 percent acetonitrile ...

Selective Hydrogenation Catalyst and Methods of Making and Using Same

A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with an organophosphorus compound and a weak acid to form a catalyst composition; and reducing the catalyst composition to form the catalyst. A method of making a selective hydrogenation catalyst comprising contacting an alumina support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with silver nitrate and potassium fluoride to form a mixture; contacting the mixture with an organophosphorus compound and a weak acid to form a catalyst precursor; and reducing the catalyst precursor to form the catalyst. 1. A method of making a selective hydrogenation catalyst comprising:contacting a support with a palladium-containing compound to form a supported-palladium composition;contacting the supported-palladium composition with an organophosphorus compound and a weak acid to form a selective hydrogenation catalyst composition; andreducing the selective hydrogenation catalyst composition to form the selective hydrogenation catalyst.2. The method of wherein the organophosphorus compound is represented by the general formula (R)(OR′)P═O claim 1 , wherein x and y are integers ranging from 0 to 3 and x plus y equals 3 claim 1 , wherein each R is hydrogen claim 1 , a hydrocarbyl group claim 1 , or combinations thereof; and wherein each R′ is a hydrocarbyl group3. The method of wherein the organophosphorus compound comprises a phosphine oxide claim 1 , a phosphinate claim 1 , a phosphonate claim 1 , a phosphate claim 1 , or combinations thereof.4. The method of wherein the organophosphorus compound is a product of an organophosphorus compound precursor represented by the general formula of (R)(OR′)P claim 1 , wherein x and y are integers ranging from 0 to 3 and x plus y equals 3 claim 1 , wherein ...

PLASMONIC ASSISTED SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent. 1173-. (canceled)174. A system for curing of a radiation-curable medium , comprising:a mechanism configured to supply an uncured radiation-curable medium including an activatable agent and at least one of a plasmonics agent and an energy modulation agent into the uncured radiation-curable medium; andan initiation energy source configured to apply an initiation energy throughout a region including the uncured radiation-curable medium,wherein the initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly cure the medium by polymerization of polymers in the medium.175. The system of claim 174 , wherein the energy modulation agent is configured to emit light at an energy different from the initiation energy.176. The system of claim 175 , wherein the plasmonics agent 1) enhances or modifies said light from the energy modulation agent or 2) enhances or modifies the initiation energy.177. The system of claim 174 , wherein the initiation energy source comprises:an external energy source; oran energy source that is at least partially in a container holding the medium.178. The system of claim 174 , wherein the initiation energy source comprises at least one of an x-ray source claim 174 , a gamma ray source claim 174 , an electron beam source claim 174 , an UV radiation source claim 174 , a microwave source claim 174 , or a ...

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

Methods of making cerium oxide polyaniline composite nanospheres and methods of use

Methods of synthesizing cerium oxide and polyaniline nanocomposites, including nanospheres enclosing a hollow core, are specified. Properties of the cerium oxide and polyaniline nanocomposites are described, as well as a method of using the nanocomposites as photocatalysts for the reduction of an aromatic nitro compound using visible light. A method for reusing the nanocomposites as photocatalysts is also discussed.

PHOTOCATALYTIC TIO2 COATINGS ON THE POLYMER SURFACES ACTIVATED WITH VISIBLE LIGHT, METHOD OF THEIR PREPARATION AND USE THEREOF

The invention relates to visible-light active photocatalytic coatings of titanium oxide (IV) on polymer surfaces, characterized in that are applied to a substrate which is the organic polymer material used in medicine, food and pharmaceutical packaging, and the coating is nanocrystalline titanium oxide (IV) or nanocrystalline titanium oxide (IV) surface-modified with organic compound. The invention also includes a method for the preparation of photocatalytic coatings of titanium oxide (IV) according to the invention, comprising the step of activating the surface of a polymeric material with low-temperature plasma technology, and then the synthesis of nanocrystalline titanium oxide (IV) coating and the modification of the surface layer with organic compounds. The invention also relates to the application of photocatalytic coating of titanium oxide (IV) according to the invention for sterilization of plastic elements used in medicine, food and pharmaceuticals packaging and application to production of selected products from the group consisting of: photosterilizing materials, photobactericidal, photofungicidal, photocatalytic materials. 1. An article of manufacture comprisinga) a substrate which is an organic polymer material used in medicine, food or pharmaceutical packaging, selected from the group consisting of polyurethane (PU), polycarbonate (PC), polyvinyl chloride (PVC), and polytetrafluoroethylene (PTFE), andb) a coating on the substrate which coating nanocrystalline titanium oxide(IV), or nanocrystalline titanium oxide(IV) surface-modified with an organic compound.3. The article according to claim 1 , characterized in that the nanocrystalline titanium oxide(IV) is surface-modified with an organic compound selected from the group consisting of: phthalic acid claim 1 , 4-sulfophthalic acid claim 1 , 4-amino-2-hydroxybenzoic acid claim 1 , 3-hydroxy-2-naphthyl acid claim 1 , salicylic acid claim 1 , 6-hydroxysalicylic acid claim 1 , 5-hydroxysalicylic acid claim ...

METHOD FOR SYNTHESIZING INDOMETHACIN AND ANALOGUE THEREOF

The present disclosure belongs to the technical field of indomethacin synthesis, and discloses a method for synthesizing an indomethacin and an analogue thereof. The method for synthesizing an indomethacin and an analogue thereof includes steps of: introducing an alkyl group, an aromatic ring or a heteroaromatic ring directly at the C2 position of indole, a carboxylic acid fragment at the C3 position of the indole, and an aroyl group at the N1 position of the indole through palladium-catalyzed reactions. The present disclosure solves a problem: most of the existing indomethacin synthesis methods are achieved by construction of an indole ring and modification; simple structural changes of an indomethacin molecule based on this synthetic strategy often require de novo synthesis; the late modification and structure-activity relationship study of the indomethacin molecule have lengthy synthetic steps. 1. A method for synthesizing an indomethacin and analogues thereof , wherein the method comprises the steps of:introducing an alkyl group, an aromatic ring or a heteroaromatic ring directly at the C2 position of an indole, introducing a carboxylic acid fragment at the C3 position of the indole, and introducing an aroyl group at the N1 position of the indole through palladium-catalyzed reactions.3. The method for synthesizing an indomethacin and analogues thereof according to claim 2 , wherein in the chemical formulas: R claim 2 , R claim 2 , R claim 2 , R claim 2 , and Rare either identical or different; Ris selected from the group consisting of alkyl group claim 2 , alkoxy group claim 2 , halogen claim 2 , ester group claim 2 , amide claim 2 , amino group claim 2 , a substituted aromatic or heteroaromatic ring at one or more of the C4 claim 2 , C5 claim 2 , C6 and C7 positions of the indole 1 claim 2 , either mono-substituted or poly-substituted; Ris a fragment in a halogenated compound used in reaction (2) and is selected from the group consisting of alkyl group claim 2 ...

Composite material used for catalyzing and degrading nitrogen oxide and preparation method and application thereof

The invention discloses a composite material used for catalyzing and degrading nitrogen oxide and its preparation method and application thereof. The invention of the hollow g-CNnanospheres/reduced graphene oxide composite-polymer carbonized nanofiber material is prepared as follow: 1) the preparation of silica nanospheres; 2) the preparation of hollow g-CNnanospheres; 3) the preparation of graphene oxide; 4) the preparation of surface modified hollow g-CNnanoparticles preparation; 5) the preparation of composites; 6) the preparation of composite-polymer carbon nanofiber material. The raw materials used in the process is low cost and easy to get; the operation of the invention is simple and convenient without the use of expensive equipment in the whole process; the composite has high adsorption efficiency of ppb level nitrogen oxide with good repeatability. 1. A preparation method of a hollow graphite phase carbon nitride nanosphere/reduction-oxidation graphene composite and polymer carbide nano fiber material , comprises the following steps:(1) preparation of silica nanospheres:in accordance with a mass ratio of concentrated ammonia:ethanol:water:ethyl silicate =1:15˜20:1˜5:1˜2, add ethyl silicate into a mixture of concentrated ammonia, ethanol and water, after mixing, keep standing for 1˜2 hours, then in accordance with a mass ratio of ethyl silicate:a mixture of ethyl silicate and octadecyltrimethoxysilane=1:1-2, add the mixture of ethyl silicate and octadecyltrimethoxysilane, mixing evenly and keep standing for 3˜5 hours, a resulted mixture is centrifugated, dried and calcined for 6˜8 hours at 550˜570° C., and then washed with 1M hydrochloric acid and dried, to obtain the silica nanospheres,(2) preparation of hollow graphite phase carbon nitride nanospheres:under vacuum condition, use the silica nanospheres in the step (1) as a template and mix with cyanamide in accordance with the mass ratio of 1:3˜7 and stir for 3˜5 hours, ultrasonic treat for 2˜3 hours, and ...

Coatable Composition, Photocatalytic Articles, and Methods of Making the Same

A method of making a coatable composition includes: providing a first composition comprising silica nanoparticles dispersed in an aqueous liquid vehicle, wherein the silica nanoparticles have an average particle size of less than or equal to 100 nanometers, wherein the first composition has a pH greater than 6; acidifying the first composition to a pH of less than or equal to 4 using inorganic acid to provide a second composition; and dissolving at least one metal compound in the second composition to form the coatable composition, wherein said at least one metal compound comprises a titanium compound. Coatable compositions and photocatalytic compositions, preparable by the method, are also disclosed. Photocatalytic articles including the photocatalytic compositions are also disclosed. 1. A method of making a coatable composition , the method comprising:providing a first composition comprising silica nanoparticles dispersed in an aqueous liquid vehicle, wherein the silica nanoparticles have an average particle size of less than or equal to 100 nanometers, wherein the first composition has a pH greater than 6;acidifying the first composition to a pH of less than or equal to 4 using inorganic acid to provide a second composition; anddissolving at least one metal compound in the second composition to form the coatable composition, wherein said at least one metal compound comprises a titanium compound.2. The method of claim 1 , wherein the silica nanoparticles have an average particle size of less than or equal to 50 nanometers.3. The method of claim 1 , wherein the at least one metal compound further comprises a zinc compound.4. The method of claim 1 , wherein the at least one metal compound further comprises a tin compound.5. The method of claim 1 , wherein the coatable composition is essentially free of organic non-volatile compounds.6. The method of claim 1 , wherein the first composition further comprises polymer particles dispersed in the aqueous liquid vehicle.7. ...

SOLID ACID CATALYST AND METHOD FOR PRODUCING OXIDE

Provided is a solid acid catalyst for use in oxidation of a substrate in the coexistence of oxygen and ozone (solid acid catalyst for oxygen-ozone-coexisting oxidation). The solid acid catalyst enables oxidation of the substrate with a high conversion. This solid acid catalyst for oxygen-ozone-coexisting oxidation is a solid acid catalyst for use in an oxidation reaction to oxidize a substrate (A) in the coexistence of oxygen and ozone. The solid acid catalyst includes a transition metal in the form of an elementary substance, a compound, or an ion, and a support supporting the transition metal. The support includes, at least in its surface, a strong acid or super strong acid having a Hammett acidity function (H) of −9 or less. The support is preferably a pellet or particle made of a fluorinated sulfonic acid resin, or a support including a solid and a layer of a fluorinated sulfonic acid resin disposed on the solid. 1. A solid acid catalyst for use in an oxidation reaction to oxidize a substrate (A) in coexistence of oxygen and ozone , the solid acid catalyst comprising:a transition metal in a form of an elementary substance, a compound, or an ion; and {'sub': '0', 'a strong acid or super strong acid having a Hammett acidity function (H) of −9 or less,'}, 'a support supporting the transition metal, the support comprising, at least on a surface thereof,'} (A1) compounds containing a heteroatom and a carbon-hydrogen bond at a position adjacent to the heteroatom;', '(A2) compounds containing a carbon-heteroatom double bond;', '(A3) compounds containing a methine carbon atom;', '(A4) compounds containing an unsaturated bond and a carbon-hydrogen bond at a position adjacent to the unsaturated bond;', '(A5) alicyclic compounds;', '(A6) conjugated compounds;', '(A7) amine compounds;', '(A8) aromatic compounds;', '(A9) straight chain alkanes; and', '(A10) olefins., 'the substrate (A) comprising a compound selected from the group consisting of2. A solid acid catalyst for ...

HIGH ASPECT RATIO LAYERED DOUBLE HYDROXIDE MATERIALS AND METHODS FOR PREPARATION THEREOF

Embodiments are directed to adamantane-intercalated layered double-hydroxide (LDH) particles and the methods of producing adamantane-intercalated LDH particles. The method comprises adding to an aqueous solution a first precursor and a second precursor to form an initial mixture, where the first precursor is Al(OH)or AlO, the second precursor is a hydroxide M(OH)or an oxide MO, where M is a metal of oxidation state +2; and the initial mixture has a M/Al molar ratio of from 1 to 5. The method also comprises adding to the initial mixture an amount of adamantane to form a reaction mixture having an Al/adamantane molar ratio of from 0.5 to 2; and heating the reaction mixture to produce adamantane-intercalated LDH particles, where the adamantane-intercalated LDH particles have aspect ratios greater than 100.

A CATALYST COMPOSITION AND A CATALYTIC PROCESS FOR CONVERSION OF BIOMASS TO CRUDE BIO OIL

The present disclosure provides a catalyst composition for conversion of biomass to crude bio oil. The composition comprises at least one metal compound, at least one support and at least one stabilizing/solubilizing agent. Also disclosed are processes for the preparation of catalyst composition, and hydrothermal conversion of biomass to crude bio oil. 1. A catalyst composition for conversion of biomass to crude bio oil; said composition comprising:i. at least one metal in an amount of 0.1 to 15 wt. %, wherein the metal is selected from the group consisting of group Ib, group IIb metals, group IVb metals, group Vb metals, group VIb metals, group VIIb metals, group VIII metals and noble metals;ii. at least one support in an amount of 30 to 96 wt %; andiii. at least one solubilizing agent in an amount of 4 to 50 wt. %, said solubilizing agent selected from the group consisting of ammonia solution, piperidine, pyrrolidine, morpholine, piperazine hydrate, 2-methylcyclohexyl amine, cyclohexylamine and hexamethyleneimine.2. The catalyst composition as claimed in claim 1 , wherein said support is selected from the group consisting of alumina claim 1 , silica claim 1 , zirconia claim 1 , alumina-silica claim 1 , zeolite and molecular sieves.3. The catalyst composition as claimed in claim 1 , wherein said support comprises a) 30 to 100 wt % at least one carrier selected from the group consisting of alumina claim 1 , silica claim 1 , zirconia claim 1 , alumina-silica claim 1 , zeolite and molecular sieves; b) 0.001 to 70 wt % of at least one binder selected from the group consisting of aluminophosphate claim 1 , psuedoboehmite claim 1 , alumina oxide claim 1 , silica and ludox silica solution.4. The catalyst composition as claimed in claim 1 , wherein said support comprises a) 30 to 100 wt % at least one carrier selected from the group consisting of nano-structured aluminum oxide claim 1 , nano-structured silicon oxide claim 1 , nano-structured zirconium oxide claim 1 , nano- ...

SYSTEMS AND METHODS FOR INTERIOR ENERGY-ACTIVATION FROM AN EXTERIOR SOURCE

A method and a system for producing a change in a medium. The method places in a vicinity of the medium at least one energy modulation agent. The method applies an initiation energy to the medium. The initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the energy modulation agent. 1. (canceled)2: A system for producing a change in a medium disposed in an artificial container , comprising:a mechanism configured to provide to the medium 1) an activatable agent and 2) at least one energy modulation agent, wherein said energy modulation agent is configured to emit light into the medium upon interaction with an initiation energy; andan initiation energy source configured to apply the initiation energy to the medium, wherein the initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium.3: The system of claim 2 , wherein the energy modulation agent is configured to emit said light at an energy different from the initiation energy.4: The system of claim 2 , wherein:the initiation energy source comprises an external energy source; orthe initiation energy source comprises an energy source that is at least partially in the artificial container holding the medium or that is exposed through an opening in the artificial container; oran external energy source directed to a structural element in which a gap therein was prefilled with the uncured radiation-curable medium to thereby cure the uncured radiation curable medium in the gap; ora directed or focused beam of the initiation energy which cures the uncured radiation curable medium to produce a patterned element.5: The system of claim 2 , wherein the initiation energy source comprises at least one of at least one of an x-ray source claim 2 , a gamma ray source claim 2 , an electron beam ...

Carbon Bodies and Ferromagnetic Carbon Bodies

The invention is in the field of modified carbon products. More in particular, the invention is in the field of graphitized activated carbon bodies. The invention is directed to carbon bodies and ferromagnetic carbon bodies, the production of these bodies from activated carbon, and the applications of the carbon bodies and ferromagnetic carbon bodies, for instance in water treatment and in electrochemical applications.

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

g-C3N4 FILM PRODUCTION METHOD, AND USE OF SAID FILM

In order to provide g-CNcapable of being simply and easily handled, a g-CNfilm is produced by heating, as a starting material, a compound represented by XY, wherein X is a guanidium ion or the like ion, and Y is an anion, to vaporize the compound or its reactant, and depositing the compound or the reactant over a surface of a base material heated, the surface carrying negative electric charges or having π electrons, so that the compound or the reactant is polymerized on the base material to generate g-CN. 2. The method according to claim 1 , wherein{'sup': m−', '2−', '2−', '−', '5', '−', '5, 'sub': 3', '4, 'the constituent Y is selected from CO, SO, Cl, and RCOO where Ris selected from an alkyl group, an alkenyl group, a halogenated alkyl group, a carboxy group, a carboxyalkyl group each of which has 1 to 10 carbon atoms, and a phenyl group which may be substituted with another group.'}3. The method according to claim 1 , wherein{'sup': m−', '2−', '−, 'sub': 3', '3, 'the constituent Y is selected from CO and CHCOO.'}4. The method according to claim 1 , wherein{'sup': '+', 'the constituent X is selected from the guanidium ion, the melaminium ion, the melamium ion, and the melemium ion.'}5. The method according to claim 1 , wherein{'sup': '+', 'the constituent X is the guanidium ion.'}6. The method according to claim 1 , whereinthe base material is a substrate which is made from a material selected from glass, quartz glass, indium tin oxide (ITO) glass, fluorine-doped tin oxide (FTO) glass, silicon, graphite, and a glassy carbon.7. The method according to claim 1 , whereinthe compound and the base material are heated at a temperature in a range of 300° C. to 700° C.8. A graphitic carbon nitride film produced by the method according to .9. A base material having the graphitic carbon nitride film according to fixed on a surface thereof.10. An electrically conductive substrate having the graphitic carbon nitride film according to fixed on a surface thereof.11. A method ...

Article of Manufacture For Securing a Catalyst Substrate

An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and the compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion. 1. An aftertreatment component for an exhaust gas aftertreatment system , the aftertreatment component comprising:a shell;a ceramic substrate at least partially positioned within the shell; anda cylindrical sleeve comprising corrugations, the cylindrical sleeve positioned between the shell and the ceramic substrate such that the corrugations contact the shell and the ceramic substrate;wherein the corrugations comprise at least one of a thermoset material, a rubberized material, a plastic material, a thermoplastic material, a polymeric material, a silicone material, an elastomeric material, or a foam material.2. The aftertreatment component of claim 1 , wherein the corrugations are coupled to the ceramic substrate.3. The aftertreatment component of claim 1 , further comprising a catalyst layer applied to the ceramic substrate and the corrugations.4. The aftertreatment component of claim 1 , wherein:the corrugations maintain the ceramic substrate within the shell;the corrugations facilitate thermal expansion of the ceramic substrate within the shell; andthe corrugations facilitate thermal contraction of the ceramic substrate within the shell.5. The aftertreatment component of claim 1 , wherein the cylindrical sleeve has a melting point that is greater than 700° C.6. The aftertreatment component of claim 1 , wherein the cylindrical sleeve surrounds the ceramic substrate. ...

Solid-phase catalysts comprising supported frustrated lewis pairs

Solid-phase catalysts comprising a frustrated Lewis pair (FLP) immobilized on a support having a hydroxylated surface are disclosed. Also described are methods of making the solid-phase catalysts as well as their uses in hydrogenation reactions of olefins. The solid-supported FLPs present numerous catalytic advantages over FLPs known heretofore, including reduced reactor fouling, improved separation procedures and the ability to use the catalysts in continuous flow applications. Preferred FLPs comprise B(C6F5)3, B(C6CI5)(C6F5)2, P(tBu)3 and tetramethylpiperidine (TMP); preferred supports are silica and layered double hydroxides, in particular hydrotalcite.

Selective hydrogenation catalyst and methods of making and using same

A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with an organophosphorus compound and a weak acid to form a catalyst composition; and reducing the catalyst composition to form the catalyst. A method of making a selective hydrogenation catalyst comprising contacting an alumina support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with silver nitrate and potassium fluoride to form a mixture; contacting the mixture with an organophosphorus compound and a weak acid to form a catalyst precursor; and reducing the catalyst precursor to form the catalyst.

Doped carbonaceous materials for photocatalytic removal of pollutants under visible light, making methods and applications of same

A method of synthesizing a doped carbonaceous material includes mixing a carbon precursor material with at least one dopant to form a homogeneous/heterogeneous mixture; and subjecting the mixture to pyrolysis in an inert atmosphere to obtain the doped carbonaceous material. A method of purifying water includes providing an amount of the doped carbonaceous material in the water as a photocatalyst; and illuminating the water containing the doped carbonaceous material with visible light such that under visible light illumination, the doped carbonaceous material generates excitons (electron-hole pairs) and has high electron affinity, which react with oxygen and water adsorbed on its surface forming reactive oxygen species (ROS), such as hydroxyl radicals and superoxide radicals, singlet oxygen, hydrogen peroxide, that, in turn, decompose pollutants and micropollutants.

Active metal or precursor, amine component and compositions of polar additive without amine and preparation method thereof for hydrocarbon catalytic hydrogenation treatment

一种包含载体材料的组合物，其中所述载体材料负载有选自第6和第9‑10族金属的活性金属或金属前体、胺组分和不含胺的极性添加剂。所述组合物可用于烃原料加氢处理。所述组合物通过向载体材料中结合金属溶液和随后向其中结合胺组分和不含胺的极性添加剂而制备。

Method for producing g-C3N4 film and use thereof

Plasmonics assisted systems and methods for internal energy activity from external sources

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

Plasmonic assisted systems and methods for interior energy-activation from an exterior source

High aspect ratio layered double-hydroxide material and preparation method

实施例涉及插入有金刚烷的层状双氢氧化物(LDH)颗粒和制备插入有金刚烷的LDH颗粒的方法。所述方法包含向水溶液中加入第一前体和第二前体以形成初始混合物，其中所述第一前体是Al(OH) 3 或Al 2 O 3 ，所述第二前体是氢氧化物M(OH) 2 或氧化物MO，其中M是氧化态为+2的金属；且所述初始混合物的M/Al摩尔比为从1至5。所述方法还包含向所述初始混合物中加入一定量的金刚烷以形成Al/金刚烷摩尔比为从0.5至2的反应混合物；和加热所述反应混合物以制备插入有金刚烷的LDH颗粒，其中所述插入有金刚烷的LDH颗粒具有大于100的纵横比。

High aspect ratio layered double hydroxide materials and methods for preparation thereof

Method of producing adamantane-intercalated LDH particles (i) [preferably Ad-COOH; Mg/AI-LDH] comprising adding to an aqueous solution a first precursor, AI(OH)3, and a second precursor, a hydroxide M(OH)2 or an oxide MO [preferably M= Mg, Ca, Co, Ni, Cu, Zn], to form an initial mixture, the initial mixture having an M/ Al molar ratio of from 1 to 5, adding to the initial mixture an amount of adamantane [preferably Ad-COOH] to form a reaction mixture having an Al/adamantane molar ratio of from 0.5 to 2, and heating the reaction mixture to produce (i), having an aspect ratio, i.e. width/thickness of particles, of greater than 100.

Selective hydrogenation catalyst and its preparation and application

一种制备选择性氢化催化剂的方法，其包括使载体与含钯化合物接触以形成负载型钯组合物；使所述负载型钯组合物与有机磷化合物和弱酸接触以形成催化剂组合物；和还原所述催化剂组合物以形成催化剂。一种制备选择性氢化催化剂的方法，其包括使氧化铝载体与含钯化合物接触以形成负载型钯组合物；使所述负载型钯组合物与硝酸银和氟化钾接触以形成混合物；使所述混合物与有机磷化合物和弱酸接触以形成催化剂前体；和还原所述催化剂前体以形成催化剂。

SYSTEMS ASSISTED BY PLASMONICS AND METHODS FOR AN INTERNAL ENERGY ACTIVATION FROM AN EXTERNAL SOURCE

Un método y un sistema para producir un cambio en un medio dispuesto en un recipiente artificial. El método ubica en la vecindad del medio por lo menos uno de un agente de plasmonica y de un agente de modulacion de energía. El método aplica una energía de iniciacion a través del recipiente artificial hasta el medio. La energía de iniciacion interactua con el agente de plasmonica o el agente de modulacion de energía para producir directamente o indirectamente el cambio en el medio. El sistema incluye una fuente de energía de iniciacion configurada para aplicar una energía de iniciacion al medio para activar por lo menos uno del agente de plasmonica y del agente de modulacion de energía. A method and system to produce a change in a medium arranged in an artificial container. The method locates at least one of a plasmonic agent and an energy modulation agent in the vicinity of the medium. The method applies an initiation energy through the artificial vessel to the medium. The initiation energy interacts with the plasmonic agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate at least one of the plasmonic agent and the energy modulation agent.

Plasmonic agent assisted sterilization system with initiation energy source

A sterilization system includes a plasmonics agent and an initiation energy source. The initiation energy interacts with the plasmonics agent to directly or indirectly sterilize a medium to be sterilized.

High aspect ratio layered double hydroxide materials and methods for preparation thereof

High aspect ratio layered double hydroxide material and its preparation method

PHOTOCATALYTIC TiO2 COATINGS ON THE POLYMER SURFACES ACTIVATED WITH VISIBLE LIGHT, METHOD OF THEIR PREPARATION AND USE THEREOF

The invention relates to visible-light active photocatalytic coatings of titanium oxide (IV) on polymer surfaces, characterized in that are applied to a substrate which is the organic polymer material used in medicine, food and pharmaceutical packaging, and the coating is nanocrystalline titanium oxide (IV) or nanocrystalline titanium oxide (IV) surface-modified with organic compound. The invention also includes a method for the preparation of photocatalytic coatings of titanium oxide (IV) according to the invention, comprising the step of activating the surface of a polymeric material with low-temperature plasma technology, and then the synthesis of nanocrystalline titanium oxide (IV) coating and the modification of the surface layer with organic compounds. The invention also relates to the application of photocatalytic coating of titanium oxide (IV) according to the invention for sterilization of plastic elements used in medicine, food and pharmaceuticals packaging and application to production of selected products from the group consisting of: photosterilizing materials, photobactericidal, photofungicidal, photocatalytic materials.

Polymer-supported metal nanoparticles, process for production thereof and polymeric nanoreactors produced therefrom

High aspect ratio layered double hydroxide materials and methods for preparation thereof

Method of producing adamantane-intercalated LDH particles (i) [preferably Ad-COOH; Mg/AI-LDH] comprising adding to an aqueous solution a first precursor, AI(OH)3, and a second precursor, a hydroxide M(OH)2 or an oxide MO [preferably M= Mg, Ca, Co, Ni, Cu, Zn], to form an initial mixture, the initial mixture having an M/ Al molar ratio of from 1 to 5, adding to the initial mixture an amount of adamantane [preferably Ad-COOH] to form a reaction mixture having an Al/adamantane molar ratio of from 0.5 to 2, and heating the reaction mixture to produce (i), having an aspect ratio, i.e. width/thickness of particles, of greater than 100.

Systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium. The method places in a vicinity of the medium at least one energy modulation agent. The method applies an initiation energy to the medium. The initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the energy modulation agent.

Selective hydrogenation catalyst and methods of making and using same

A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with an organophosphorous compound and a weak acid to form a catalyst composition; and reducing the catalyst composition to form the catalyst. A method of making a selective hydrogenation catalyst comprising contacting an alumina support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with silver nitrate and potassium fluoride to form a mixture; contacting the mixture with an organophosphorous compound and a weak acid to form a catalyst precursor; and reducing the catalyst precursor to form the catalyst.

PHOTOCATALYTIC TiO2 COATINGS ON THE POLYMER SURFACES ACTIVATED WITH VISIBLE LIGHT, METHOD OF THEIR PREPARATION AND USE THEREOF

Plasmonic assisted systems and methods for interior energy-activation from an exterior source.

A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

Catalyst for generating free radical, method for producing oxidation reaction product, chemical, and chemical for agricultural and livestock use

本发明的目的在于，提供能够在温和的条件下产生(制造)自由基的自由基产生催化剂。为了实现前述目的，本发明中的第1自由基产生催化剂的特征在于，包含选自氨基酸、肽、磷脂和它们的盐中的至少一种。本发明中的第2或第3自由基产生催化剂的特征在于，包含路易斯酸度为0.4eV以上的铵盐(不包括过二硫酸盐)。

Regeneration of an ionic liquid catalyst using metal complexes

A method for regenerating deactivated ionic liquid catalyst containing conjunct polymer. The deactivated ionic liquid catalyst containing the conjunct polymer is contacted with either at least one metal complex having a general formula M1 n+ R n , or at least one metal complex having a general formula [M2 a+ ] x [M3 b+ y R z ] (xa/(z−by)) . The conjunct polymer reacts with the reagent and can be extracted from the ionic liquid. The mixture is separated into a hydrocarbon effluent and an ionic liquid effluent.

Photocatalytic transfer film and its manufacturing method

Systems and methods for interior energy-activation from an exterior source

A method and a system for producing a change in a medium. The method places in a vicinity of the medium at least one energy modulation agent. The method applies an initiation energy to the medium. The initiation energy interacts with the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the energy modulation agent.

Carbon bodies and ferromagnetic carbon bodies

본 발명은 개질된 탄소 제품의 분야에 관한 것이다. 더욱 상세하게는, 본 발명은 부분 흑연화된 활성탄체의 분야에 관한 것이다. 본 발명은 탄소체 및 강자성 탄소체, 활성탄으로부터 이들 체의 생산, 및 예를 들면 수처리에서 및 전기 화학적 적용에서 탄소체 및 강자성체의 용도에 관한 것이다.

自由基产生催化剂、自由基的制造方法、氧化反应产物的制造方法、药剂和农畜产用药剂

本发明的目的在于，提供能够在温和的条件下产生(制造)自由基的自由基产生催化剂、使用上述自由基产生催化剂的自由基的制造方法和使用上述自由基的制造方法的氧化反应产物的制造方法、药剂、农畜产用药剂。为了实现前述目的，本发明的第1药剂的特征在于，其包含自由基产生催化剂和自由基产生源，所述自由基产生源是选自亚卤酸、亚卤酸根离子和亚卤酸盐中的至少一种，所述自由基产生催化剂包含选自氨基酸、蛋白质、肽、磷脂和它们的盐中的至少一种，所述自由基产生催化剂的路易斯酸度为0.4eV以上，所述自由基产生催化剂在pH为5.5以上的液体中，催化来自所述自由基产生源的自由基产生。

Surface-modified light upconversion silica particles

A composition, method, and article of manufacture are disclosed. The composition includes a silica particle with light upconversion molecules bound to its surface. The method includes obtaining silica particles and light upconversion molecules having sidechains with reactive functional groups. The method further includes binding the light upconversion molecules to surfaces of the silica particles. The article of manufacture includes the composition.

ラジカル発生触媒、ラジカルの製造方法、酸化反応生成物の製造方法、薬剤および農畜産用薬剤

Article of manufacture for securing a catalyst substrate

An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and the compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion.

Article of manufacture for securing a catalyst substrate

An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and the compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion.

海绵负载的手性有机催化剂

本发明提供了一种海绵负载的手性有机催化剂，所述海绵负载的手性有机催化剂由海绵、Linker试剂和催化剂制成，所述海绵为3D多孔结构的聚合物骨架，且所述海绵含有表面基团，所述Linker试剂至少含有两个活性官能团，所述催化剂为非金属的手性有机催化剂，且所述Linker试剂通过所述活性官能团与所述海绵的表面基团化学键合、负载在所述海绵表面，所述催化剂通过与所述Linker试剂的活性官能团键合、连接在所述海绵表面，其中，所述手性有机催化剂包括脯氨酸类催化剂、α‑氨基酸类催化剂、咪唑啉酮类催化剂、寡肽类催化剂、金鸡纳类催化剂、平面手性催化剂、二芳基类催化剂、二元胺类催化剂、其他含杂环的催化剂。

ラジカル発生触媒、ラジカルの製造方法、酸化反応生成物の製造方法、薬剤および農畜産用薬剤

【課題】温和な条件下でラジカルを発生させることが可能なラジカル発生触媒を提供する。【解決手段】第１のラジカル発生触媒は、アミノ酸、ペプチド、リン脂質、およびそれらの塩からなる群から選択される少なくとも一つを含むことを特徴とする。第２または第３のラジカル発生触媒は、式：Ｎ＋（Ｒ１１）（Ｒ２１）（Ｒ３１）（Ｒ４１）Ｘ－で表されるアンモニウム塩を含み、かつ、アンモニウム塩のルイス酸性度が０．４ｅＶ以上である。式中、Ｒ１１、Ｒ２１、Ｒ３１、およびＲ４１、は、それぞれ水素原子もしくは芳香環であるか、またはアルキル基であり、前記アルキル基は、エーテル結合、カルボニル基、エステル結合、若しくはアミド結合、または芳香環が含まれていてもよく、Ｒ１１、Ｒ２１、Ｒ３１、およびＲ４１のうち２つ以上が一体化し、それらが結合するＮ＋とともに環状構造を形成していてもよい。【選択図】なし

Photocatalytic system and applications thereof

The present invention relates to novel poly(heptazine imides), a photocatalytic system comprising such poly(heptazine imides) and a sulfur source as well as the application thereof in photocatalytic reactions.

光催化剂转印膜及其制造方法

本发明提供一种光催化剂转印膜及其制造方法，所述光催化剂转印膜能够均匀地将高透明性的光催化剂层转印加工至各种转印基材的表面。一种光催化剂转印膜，其在双向拉伸聚丙烯膜上具有包含含有氧化钛粒子的光催化剂、硅化合物以及表面活性剂的光催化剂层。一种光催化剂转印膜的制造方法，该方法包括：将包含含有氧化钛粒子的光催化剂、硅化合物、表面活性剂以及水性分散介质的光催化剂涂敷液涂布在双向拉伸的聚丙烯膜上，并进行干燥。

光触媒転写フィルム及びその製造方法

様々な転写基材表面に、均一で透明性が高い光触媒層を転写加工することができる光触媒転写フィルム及びその製造方法の提供。 二軸延伸ポリプロピレンフィルム上に、酸化チタン粒子を含む光触媒、ケイ素化合物及び界面活性剤を含有する光触媒層を有する光触媒転写フィルム。 酸化チタン粒子を含む光触媒、ケイ素化合物、界面活性剤及び水性分散媒を含む光触媒塗工液を、二軸延伸ポリプロピレンフィルムに塗布し、乾燥することを特徴とする光触媒転写フィルムの製造方法。

Corpo de carbono ferromagnético, processos para a produção de um corpo de carbono ferromagnético e de um corpo de carbono, uso de um corpo de carbono ferromagnético, e, catalisador

corpo de carbono ferromagnético, processos para a produção de um corpo de carbono ferromagnético e de um corpo de carbono, uso de um corpo de carbono ferromagnético, e, catalisador a invenção está no campo dos produtos de carbono modificados. mais em particular, a invenção está no campo dos corpos de grafite de carbono ativadas. a invenção é dirigida a órgãos de carbono e corpos ferromagnéticos de carbono, à produção destes corpos de carvão ativado, e às aplicações dos corpos de carbono e corpos ferromagnéticos de carbono, por exemplo em tratamento de água e em aplicações eletroquímicas.