CLASS SUPPORTED BY PEROXY CONNECTIONS BY TUNGSTEN AND DIPHOSPHONSÄURE AND PROCEDURE FOR THEIR PRODUCTION

OLEFIN DISPROPORTIONATION

PROCESS FOR THE SEPARATION OF CATALYST FROM PRODUCTS OBTAINED IN THE HYDROCARBOXYLATION OF UNSATURATED NITRILES

Catalytic process for the epoxidation of an olefin

The olefins of formula <IMAGE> in which the symbols R represent hydrogen or certain hydrocarbon radicals, are converted to the corresponding epoxides by reacting with hydrogen peroxide at pH 6-9, in the presence of a catalyst containing an arsenic, antimony or bismuth derivative, for example an organometallic derivative, and a derivative of an element of groups IVA, VA or VIA of the periodic system, for example a carbonyl derivative of molybdenum, tungsten, titanium or vanadium. The reaction is carried out between 0 and 100 DEG C and between 0 and 100 bars. The catalyst involved has a long lifetime and makes it possible to obtain good selectivity towards the epoxide.

Process for the preparation of alkylene glycol etherates of carboxylic acids

Urea solution for vehicles

PRODUCTION OF ALKYLENE GLYCOL ETHER ESTERS OF ORGANIC CARBOXYLIC ACIDS

IONIC LIQUIDS WITH A CATION COMPRISING A BASIC MOIETY

Use of ionic liquids as solvents in base-catalysed chemical reactions wherein the ionic liquid is composed of at least one species of cation and at least one species of anion, characterised in that a cation of the ionic liquid comprises a positively charge moiety and a basic moiety, and further wherein such ionic liquids may be used as promoters or catalysts for the chemical reactions.

Preparation of sub-visual molecular aggregrates composed of antimony phosphate derivatives

The present invention relates to a process comprises mixing, at temperatures between about about 90 DEG C. to 300 DEG C., a first reactant solution comprising less than about 5x10-3 moles/l of at least one antimony compound and at least one first diol having having 2 to about 16 carbon atoms with a second reactant solution comprising less than about 30x10-3 moles/l of at least one phosphorus stabilizer compound and at least one second diol to form sub-visual molecular aggregates comprising antimony phosphate derivatives. Sub-visual molecular aggregates comprising antimony phosphate derivatives which are stable in suspension are also disclosed.

Complex, Preparation Methods and Application Thereof

The invention is directed to a complex, including: a porous composite carrier including: a porous organic foam material containing open pores, each pore comprising a wall defining the pore; and a crosslinked product having aldehyde groups and immobilized on the surface of the walls of one or more pores of the porous organic foam materials, and a protein, polypeptide, or oligopeptide immobilized onto the porous composite carrier through a reaction between an amino group of the protein, polypeptide or oligopeptide and an aldehyde group of the composite carrier. The immobilized product has high specific surface area and high specific activity. The immobilization is simple and in low cost, and is suitable for industrial application. 1. A complex , comprising: a porous organic foam material containing open pores, each pore comprising a wall defining the pore; and', 'a crosslinked product having aldehyde groups and immobilized on the surface of the walls of one or more pores of the porous organic foam materials, and, 'a porous composite carrier comprisinga protein, polypeptide, or oligopeptide immobilized onto the porous composite carrier through a reaction between an amino group of the protein, polypeptide or oligopeptide and an aldehyde group of the composite carrier.2. The complex according to claim 1 , wherein the organic foam material is melamine foam.3. The complex according to claim 1 , wherein the porous composite carrier is in a form of granules claim 1 , straps claim 1 , sheets claim 1 , blocks claim 1 , or columns.4. The complex according to claim 1 , wherein the crosslinked product comprises chitosan and the aldehyde groups comprise glutaraldehyde or dialdehyde starch.5. The complex according to claim 1 , wherein the protein claim 1 , polypeptide claim 1 , or oligopeptide is transglucosidase.6. The complex according to claim 1 , wherein the protein claim 1 , polypeptide claim 1 , or oligopeptide is polymyxin B.7. The complex according to claim 1 , wherein the ...

Hydroformylation process

A process for hydroformylation of vinylidene olefins, such as C16 vinylidene olefins, comprises of contacting the olefins with carbon monoxide and hydrogen in the presence of a catalyst system. The catalyst system comprises of a source of platinum group metal cations, such as platinum or palladium; a source of anions, other than halide anions, such as acids having a pKa value of less than 3, measured at 18{C in aqueous solution, such as anions of phosphoric acid, sulphuric acid, sulphonic acid and trifluoroacetic acid; and a source of bidentate ligands of the formula (I), R1R2M1RM2R3R4 (I). In formula (I), M1 and M2 is independently a phosphorous, arsenic or antimony, R is a bivalent organic bridging group containing 1-4 atoms in the bridge, such as an ethylene group, R1 and R2 is independently a substituted or unsubstituted hydrocarbyl group or together is a bivalent substituted or non-substituted cyclic group where the two free valencies are linked to M1, and R3 and R4 is a substituted ...

PROCEDURE FOR RECUPERATION OF EDELMETAL.

METHOD FOR PRODUCING BISPHENOL CATALYSTS AND BISPHENOLS

METHANOL HOMOLOGATION USING IRON-COBALT CATALYST

PROCESS FOR HYDROXYLATING OLEFINS USING A SUPPORTED OSMIUM CATALYST

ABSTRACT OF THE DISCLOSURE A process for hydroxylating olefins using a sup-ported osmium catalyst such as Os3(CO)12 adsorbed on a support, such as MgO, and optionally in conjunction with a co-catalyst such as NaI, is disclosed.

PROCESS FOR THE SEPARATION OF CATALYST FROM PRODUCTS OBTAINED IN THE HYDROCARBOXYLATION OF UNSATURATED NITRILES

... (5239) A process is provided which includes the separation of a hydrocarboxylation-type catalyst together with the hydrocarboxylation solvent from a reaction mixture containing an oxygenated cyanocompound product, the hydrocarboxylation catalyst and the hydrocarboxylation solvent by contacting the reaction mixture with a hydrocarbon to form a hydrocarbon/ solvent conjugate phase, and separating the resulting hydrocarbon phase from the solvent phase.

PROCESS FOR THE PRODUCTION OF ACETALDEHYDE BY THE REACTION OF METHANOL WITH SYNTHESIS GAS

PROCESS Of EPOXYDATION

PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS, NOVEL CARBONYLATION LIGANDS AND CATALYST SYSTEMS INCORPORATING SUCH LIGANDS

Process for producing acetic anhydride

A process for producing acetic anhydride which comprises reacting methyl acetate or dimethyl ether with carbon monoxide in the presence of a catalyst comprising (a) nickel or a nickel compound, (b) at least one halide selected from the group consisting of bromides, iodides and mixtures thereof and (c) at least one organic nitrogen group compound and together with a specific co-catalyst is disclosed. According to this invention acetic anhydride is produces by using highly active non-expensive catalyst and co-catalyst.

オレフィンのカルボニル化によりカルボン酸またはそのエステルを製造する方法

... 本発明は、温度100~270℃および圧力30~100バールで水またはアルコールの存在下にオレフィンと一酸化炭素とからカルボン酸またはそのエステルを製造するための方法において、ハロゲン不含の触媒系として、a)ニッケルまたはニッケル化合物、b)クロム、モリブデン、タングステン、レニウム、ルテニウム、オスミウム、ロジウム、イリジウム、パラジウム、白金、銀、金またはこれらの金属の化合物の群の少なくとも1種の金属、c)第三級または第四級窒素化合物、リン化合物またはヒ素化合物および窒素含有複素環式化合物の群からの少なくとも1種の非金属化合物からなる混合物を使用することを特徴とする、カルボン酸またはそのエステルの製造方法に関する。 ...

PROCESS FOR PRODUCING ACETIC ANHYDRIDE

PROCESS FOR THE PRODUCTION OF ACETALDEHYDE BY THE REACTION OF METHANOL WITH SYNTHESIS GAS

Case 4571 ABSTRACT OF THE DISCLOSURE Acetaldehyde is produced by reacting methanol with hydrogen and carbon monoxide at elevated temperature and pressure in the presence of a catalyst comprising cobalt, an iodide or a bromide and one of the elements arsenic, antimony or bismuth, either in the form of the free element or a compound thereof, and in the additional presence of one or more of the following additives: (i) an inert liquid such as chlorobenzene, decanoic acid, a polydimethylsiloxane fluid or a methyl phenyl silicone fluid, (ii) an acid and/or an acid derivative such as acetic acid, acetic anhydride, propionic acid, phenylacetic acid, benzoic acid, methyl acetate or butyl acetate. (iii) an oxygen-containing organic compound such as 1,4-dioxane, tetrahydrofuran, di-n-propylether, diphenylether, acetone, acetaldehyde, n-propanol or n-butanol. (iv) a non-polar solvent such as an alkane, benzene or an alkyl-substituted benzene. The presence of the additive suppresses by-product formation and thereby improves the yield and selectivity to acetaldehyde.

PROCESSES FOR MAKING POLYISOBUTYLENE COMPOSITIONS

Methods of making polyisobutylene and catalyst systems are described. Polyisobutylene compositions and catalyst system compositions are also described. In some embodiments, a method of making a catalyst system includes: providing a support material; calcining the support material; and forming a catalyst system by adding to the support material (a) a mixture comprising BF3, (b) a mixture comprising BF3 and a complexing agent, or (c) both. In some embodiments, a method of making a polymer composition includes providing a catalyst system comprising: (a) a support material; and (b) BF3; providing a feedstock comprising isobutylene; forming a reaction mixture comprising the feedstock and the catalyst system; contacting the isobutylene with the catalyst system; and obtaining a polymer composition.

OLIGOMERISATION OF OLEFINIC COMPOUNDS IN THE PRESENCE OF AN OLIGOMERISATION CATALYST, AND A CATALYST ACTIVATOR INCLUDING A HALOGENATED ORGANIC GROUP

According to the present invention there is provided a process for producing an oligomeric product by the oligomerssation of at least one olefinic compound, by contacting the at least one olefinic compound with the combination of an otigomerisation catalyst and a catalyst activator. The catalyst activator is a compound which includes at least one halogenated organic group which is bound to one or more binding atoms selected from the group consisting of a group 5A atom and a group 6A atom, which one or more binding atoms are in turn bound to a central atom selected from the group consisting of a group 3A atom, and a group 3B to 7B transition metal atom. The oligomerisation catalyst includes the combination of i) a source of a transition metal; and ii) a ligating compound of the formula (R1)m X1 (Y) X2 (R2)n The invention also relates to a combination of an oligomerisation catalyst and a catalyst activator as set out above and to the use of such a combination in an oligomerisation process ...

PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS, NOVEL CARBONYLATION LIGANDS AND CATALYST SYSTEMS INCORPORATING SUCH LIGANDS

A novel bidentate ligand of general formula (I) is described together with a process for the carbonylation of ethylenically unsaturated compounds. The group X1 may be defined as a univalent hydrocarbyl radical of up to 30 atoms containing at least one nitrogen atom having a pKb in dilute aqueous solution at 18°C of between 4 and 14 wherein the said at least one nitrogen atom is separated from the Q2 atom by between 1 and 3 carbon atoms. The group X2 is defined as X1, X3 or X4 or represents a univalent radical of up to 30 atoms having at least one primary, secondary or aromatic ring carbon atom wherein each said univalent radical is joined via said at least one primary, secondary or aromatic ring carbon atom(s) respectively to the respective atom Q2. Q1 and Q2 each independently represent phosphorus, arsenic or antimony.

NICKEL CONTAINING COMPOSITION CATALYST; PROCESS FOR THE DIMERIZATION AND THE OLIGOMERIZATION OF OLEFINS

L'invention concerne une composition catalytique et un procédé pour la dimérisation, la codimérisation, et l'oligomérisation des oléfines, ladite composition résultant du mélange d'au moins un complexe du nickel bivalent contenant deux molécules de phosphine tertiaire, d'au moins un complexe du nickel ne contenant pas d'eau et de phosphine et d'au moins un halogénure d'alkylaluminium. Ce mélange est particulièrement utilisable dans les compositions liquides non-aqueuses à caractère ionique, par exemple celles que font les halogénures d'ammonium quaternaires et/ou les halogénures de phoshonium quatenaire avec les halogénures d'aluminium et/ou les halogénures d'alkylaluminium. The invention relates to a catalytic composition and a process for the dimerization, codimerization, and oligomerization of olefins, said composition resulting from the mixture of at least one bivalent nickel complex containing two molecules of tertiary phosphine, of at least one nickel complex containing no water and phosphine and at least one alkylaluminum halide. This mixture is particularly usable in non-aqueous liquid compositions of ionic nature, for example those made by quaternary ammonium halides and / or quaternary phoshonium halides with aluminum halides and / or alkylaluminum halides.

PRODUCTION OF ALKYLENE GLYCOL ETHER ESTERS OF ORGANIC CARBOXYLIC ACIDS

PROCESSO PARA PREPARAR ETANOL POR CONTATO DE UMA MISTURA DE MONOXIDO DE CARBONO HIDROGENIO E METANOL COM UM SISTEMA CATALISADOR

СПОСОБ ФОТОАКТИВАЦИИ И ПРИМЕНЕНИЕ КАТАЛИЗАТОРА ПОСРЕДСТВОМ ОБРАЩЕННОЙ ДВУСТАДИЙНОЙ ПРОЦЕДУРЫ

... 1. Способ применения фотолатентного катализатора (а), в котором композицию, включающую указанный катализатор, подвергают облучению до последующей обработки, характеризующийся тем, что фотолатентным катализатором является (а1) фотолатентная кислота формулы VI , в которой Ra2 обозначает непосредственную связь, S, О, СН2, (CH2)2, CO или NR96; Ra3, Ra4, Ra5 и Ra6 независимо друг от друга обозначают Н, С1-С20алкил, С3-С8циклоалкил, С1-С20алкоксигруппу, С2-С20алкенил, CN, ОН, галоген, С1-С6алкилтиогруппу, фенил, нафтил, фенил-С1-С7алкил, нафтил-С1 -С3алкил, феноксигруппу, нафтилоксигруппу, фенил-С1-С7алкилоксигруппу, нафтил-C1-С3алкилоксигруппу, фенил-С2-С6алкенил, нафтил-С2-С4алкенил, S-фенил, (CO)Ra8, O(CO)Ra8, (CO)ORa9, SO2Ra8, OSO2Ra8; Ra7 обозначает С1-С20алкил, С1-С20гидроксиалкил, , или Ra8 обозначает Н, С1-С12алкил, С1-С12гидроксиалкил, фенил, нафтил или бифенилил; Ra9 обозначает непосредственную связь, S, О или СН2; Ra10, Ra11, Ra12 и Ra13 независимо друг от друга обладают одним из значений ...

POLYMERGETRÄGERTE PHOTOSENSIBILISATOREN

METHANOL HOMOLOGATION USING IRON-COBALT CATALYST

RECOVERY OF NOBLE METAL CATALYST

CATALYST SYSTEM AND PROCESS FOR PRODUCING ETHANOL USING SAID NOVEL CATALYST SYSTEM

PROCESS FOR HYDROXYLATING OLEFINS USING A SUPPORTED OSMIUM CATALYST

Novel nickel-containing composition for catalysis and olefin dimerisation and oligomerisation process

COMPOSE PRESENTING A CATALYTIC ROLE IN THE EXCHANGES OF SUBSTITUTIONSNUCLEOPHILES AND PROCESS OF SYNTHESIS OF THESE COMPOSE

METHOD FOR ACTIVATING AND IMMOBILIZING CATIONIC TRANSITION METAL CATALYSTS USING IONIC FLUIDS AND COMPRESSED CO2

The invention relates to a novel method for activating cationic transition metal catalysts using a solvent mixture containing one or several ionic fluids and compressed CO2. The cationic transition metal catalyst can also be immobilized.

MESOPOROUS POLYMER COLLOIDS

The invention provides a particulate material comprising porous polymeric microparticles having a mesoporous structure. A process for making the particles is also presented. The process comprises impregnating a porous microparticulate template material with a liquid comprising one or more monomers. The one or more monomers are then polymerised in and/or on the template material to form a polymer, and the template material is then removed to produce the particulate material.

Organoclay triphase catalysts

In a method of carrying out organic conversions via heterogeneous phase transfer catalysis by contacting immiscible liquid phases containing respective substances capable of interacting, with a solid catalyst to promote the transfer of reactive species from one liquid phase to another, the improvement comprises employing as catalyst a cation exchanged form of a 2:1 layered silicate clay with layer charge densities in the range of above 0.4 to 2.0 containing an onium ion containing one or more alkyl hydrocarbon chains and maintaining the materials in emulsified form by having a sufficient chain length of an alkyl group relative to the charge density of the clay.

MESOPOROUS POLYMER COLLOIDS

The invention provides a particulate material comprising porous polymeric microparticles having a mesoporous structure. A process for making the particles is also presented. The process comprises impregnating a porous microparticulate template material with a liquid comprising one or more monomers. The one or more monomers are then polymerised in and/or on the template material to form a polymer, and the template material is then removed to produce the particulate material.

Klasse von Peroxy-Verbindungen gestützt auf Wolfram und Diphosphonsäure und Verfahren zu deren Herstellung

Basic ionic liquids

Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporating such ligands

A novel bidentate ligand of general formula (I) is described together with a process for the carbonylation of ethylenically unsaturated compounds. The group Xmay be defined as a univalent hydrocarbyl radical of up to 30 atoms containing at least one nitrogen atom having a pKb in dilute aqueous solution at 18°C of between 4 and 14 wherein the said at least one nitrogen atom is separated from the Q atom by between 1 and 3 carbon atoms. The group Xis defined as X, X or X or represents a univalent radical of up to 30 atoms having at least one primary, secondary or aromatic ring carbon atom wherein each said univalent radical is joined via said at least one primary, secondary or aromatic ring carbon atom(s) respectively to the respective atom Q. Q and Q each independently represent phosphorus, arsenic or antimony.

METHANOL HOMOLOGATION USING IRON-COBALT CATALYST

Basic ionic liquids

New catalysts used to facilitate SN2 and more particularly SNAr substitutions on aromatic substrates, useful for effecting exchanges between fluorine and a higher halogen or pseudo-halogen

La présente invention a pour objet de nouveaux catalyseurs de substitution nucléophile aromatique. Ces catalyseurs sont des composés de formule génerale (I) où : - R1 , R2 , R3 , R4 , R5 , et R6 , identiques ou différents, sont choisis parmi les radicaux hydrocarbonés; - les Pn, avantageusement les mêmes, sont choisis parmi les éléments métalloïdes de la colonne V d'une période supérieure à celle de l'azote; - Z est un élément métalloïde de la colonne V, avantageusement distinct de Pn; de préférence un azote (N, P, As, Sb). Application à la synthèse organique.

METHOD FOR PRODUCING ENANTIOMER-ENRICHED LACTONES

The invention relates to a method for producing enantiomer-enriched lactones by carbonylating lactones into anhydrides in the presence of a catalyst system, containing: A) at least one carbonylation catalyst A comprised of neutral or anionic transition metal complexes of metals Re, Co, Ru, Rh, Ir, Fe, Ni, Mn, Mo, W or mixtures thereof, and; B) at least one chiral Lewis acid B comprised of compounds of metals Mg, Ca, Sc, Y, a rare-earth element, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Al, Ga, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl and Pb, the compounds in the reaction conditions of the carbonylation existing in a coordinatively undersaturated manner.

Process for producing acetic anhydride

A process for producing acetic anhydride which comprises reacting methyl acetate or dimethyl ether with carbon monoxide in the presence of a catalyst comprising (a) nickel or a nickel compound, (b) at least one halide selected from the group consisting of bromides, iodides and mixtures thereof and (c) at least one organic nitrogen group compound and together with a specific co-catalyst is disclosed. According to this invention acetic anhydride is produced by using highly active non-expensive catalyst and co-catalyst.

Process for producing ethanol using said novel catalyst system

A novel process for selectively producing ethanol which comprises introducing into a reaction zone (1) methanol, (2) hydrogen, (3) carbon monoxide, (4) a cobalt carbonyl, a hydrido cobalt carbonyl or a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, (5) a tertiary organo Group VA compound of the Periodic Table, (6) an iodine compound and (7) a ruthenium compound; and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to ethanol.

Preparation of sub-visual molecular aggregrates composed of antimony phosphate derivatives

The present invention relates to a process comprises mixing, at temperatures between about about 90° C. to 300° C., a first reactant solution comprising less than about 5×10-3 moles/l of at least one antimony compound and at least one first diol having having 2 to about 16 carbon atoms with a second reactant solution comprising less than about 30×10-3 moles/l of at least one phosphorus stabilizer compound and at least one second diol to form sub-visual molecular aggregates comprising antimony phosphate derivatives. Sub-visual molecular aggregates comprising antimony phosphate derivatives which are stable in suspension are also disclosed.

Method for preparing high-purity ionic liquids

A method for preparing a high-purity ionic liquid having a pH value of 7 and an elemental analysis deviation of less than 0.5 wt % between a calculated elemental analysis and a found elemental analysis for each of carbon, hydrogen and nitrogen, wherein the method comprises forming a monophasic or biphasic mixture of an ionic liquid and an inert liquid. When the monophasic mixture is formed, it is filtered to yield a filtrate from which the high-purity ionic liquid is recovered. When the biphasic mixtures is formed, it is separated into an aqueous phase and ionic liquid phase, whereby the ionic liquid phase is filtered to yield a filtrate from which the high-purity ionic liquid is recovered. Furthermore, the present purification procedure can be used for the clean-up of a contaminated ionic liquid by extracting it into a polar extractant to form an extract containing the ionic liquid. Water traces are removed from the extract. Then, the extract is filtered and the high-purity ionic liquid ...

Class of peroxy compounds based on tungsten and diphosphonic acids and process for obtaining them

Disclosed is a class of compounds based on tungsten and diphosphonic acids, which contain active oxygen atoms and cationic groups deriving from onium salts. Also disclosed is the method for preparing and using said class of compounds for olefin oxidation and diol and acid oxidation reactions.

IONIC LIQUIDS WITH A CATION COMPRISING A BASIC MOIETY

Use of ionic liquids as solvents in base-catalysed chemical reactions wherein the ionic liquid is composed of at least one species of cation and at least one species of anion, characterised in that a cation of the ionic liquid comprises a positively charge moiety and a basic moiety, and further wherein such ionic liquids may be used as promoters or catalysts for the chemical reactions.

СПОСОБ ФОТОАКТИВАЦИИ И ПРИМЕНЕНИЕ КАТАЛИЗАТОРА ПОСРЕДСТВОМ ОБРАЩЕННОЙ ДВУСТАДИЙНОЙ ПРОЦЕДУРЫ

FIELD: chemistry. SUBSTANCE: invention relates to a method of photoactivation of a photocatalyst by irradiating a composition containing the said catalyst. The method of using a photolatent catalyst (a) in which a composition containing said catalyst is irradiated before subsequent treatment is characterised by that, the photolatent catalyst is: (a1) a compound selected from a group consisting of a photolatent acid, an aromatic iodonium salt or oxime-based photolatent acid; (a2) a photolatent base compound. Also described is a substrate on which a coating made from the composition is deposited in accordance with the above described method. Also described is a method of using photolatent catalyst (a), in which a composition containing said catalyst is irradiated before subsequent treatment, characterised by that subsequent treatment is preparation of foam material and the composition contains polyol and isocyanate components and photolatent base (a2) as photolatent catalyst. EFFECT: provision for solidification of the system. 13 cl, 10 tbl, 16 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 381 835 (13) C2 (51) МПК B01J B01J B01J G03F C07D C07D 35/00 31/06 31/02 7/00 487/00 519/00 (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21), (22) Заявка: 2007106175/04, 11.07.2005 (24) Дата начала отсчета срока действия патента: 11.07.2005 (45) Опубликовано: 20.02.2010 Бюл. № 5 2 3 8 1 8 3 5 R U (85) Дата перевода заявки PCT на национальную фазу: 21.02.2007 C 2 C 2 (56) Список документов, цитированных в отчете о поиске: SU 238346 A1, 08.04.1970. GB 2357759 A, 04.07.2001. US 2002032248 A1, 14.03.2002. EP 0393407 A, 24.10.1990. US 2004053158 A1, 18.03.2004. US 6485886 B1, 26.11.2002. US 6261738 B1, 17.07.2001. WO 03072567 A, 04.09.2003. WO 03033500 A, 24.04.2003. (86) Заявка PCT: EP 2005/053299 (11.07.2005) (87) Публикация PCT: WO 2006/008251 (26.01.2006) ...

VERFAHREN ZUR ASYMMETRISCHEN HYDROFORMYLIERUNG

Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands

CATALYTIC EPOXIDATION PROCESS

... 1491635 Catalytic epoxidation processes PRODUITS CHIMIQUES UGINE KUHLMANN 10 Feb 1976 [11 Feb 1975] 05134/76 Heading C2C An epoxidation process comprises reacting an olefin of the formula R 1 R 2 C=CR 3 R 4 in which each of R 1 , R 2 , R 3 and R 4 , which may be the same or different, represents a hydrogen atom, a straight chain alkyl radical containing 1 to 30 carbon atoms, a branched alkyl radical or cycloalkyl radical containing 3 to 12 carbon atoms, or a hydrocarbon radical containing 6 to 12 carbon atoms and containing a benzene ring, or R 1 and R 2 together or R 3 and R 4 together represent a straight or branched alkylene radical with 3 to 11 carbon atoms, the radicals R 1 , R 2 , R 3 and R 4 optionally being unsaturated and/or substituted by functional atoms or groups which are stable in the reaction medium, with hydrogen peroxide at a pH of 6 to 9 in the presence of a catalytic system comprising, as a first constituent, at least one derivative of arsenic, antimony or bismuth, and ...

CATALYSTS FOR NUCLEOPHILIC SUBSTITUTION, SYNTHESIS THEREOF, COMPOSITION CONTAINING SAME AND USE THEREOF

OLIGOMERISATION OF OLEFINIC COMPOUNDS IN THE PRESENCE OF AN OLIGOMERISATION CATALYST, AND A CATALYST ACTIVATOR INCLUDING A HALOGENATED ORGANIC GROUP

According to the present invention there is provided a process for producing an oligomeric product by the oligomerssation of at least one olefi.pi.ic compound, by contacting the at least one olefinic compound with the combination of an otigomerisation catalyst and a catalyst activator. The catalyst activator is a compound which includes at least one halogenated organic group which is bound to one or more binding atoms selected from the group consisting of a group 5A atom and a group 6A atom, which one or more binding atoms are in turn bound to a central atom selected from the group consisting of a group 3A atom, and a group 3B to 7B transition metal atom. The oligomerisation catalyst includes the combination of i) a source of a transition metal; and ii) a ligating compound of the formula (R1)m X1 (Y) X2 (R2)n The invention also relates to a combination of an aligomerisation catalyst and a catalyst activator as set out above and to the use of such a combination in an oligomerisation process ...

Method for preparing bisphenol catalysts and bisphenols

HYDROGENIZING PROCESS SELECTIVE OF COMPOSE POLYINSATURES COMPOSE MONOINSATURES USING of THEM a HOMOGENEOUS CATALYST

ASYMMETRIC HYDROFORMYLATION

PROCESS FOR PREPARING AN OLEFIN DISPROPORTIONATION CATALYST

HYDROGENIZING PROCESS SELECTIVE OF COMPOSE POLYINSATURES COMPOSE MONOINSATURES USING of THEM a HOMOGENEOUS CATALYST

Une composition de catalyseur comprenant au moins un sel de métal de transition des groupes IB, IIB, VB, VIB, VIIB et VIII de la classification périodique, au moins un ligand et au moins un réducteur organométallique, éventuellement en présence d'un liquide ionique non-aqueux choisi dans le groupe formé par les sels liquides qui ont pour formule générale Q+ A- (dans laquelle Q+ représente un ammonium quaternaire et/ou un phosphonium quaternaire et A- représente tout anion susceptible de former un sel liquide en dessous de 90 °C) est utilisée pour l'hydrogénation sélective des composés dioléfiniques en composés monooléfiniques. A catalyst composition comprising at least one transition metal salt from groups IB, IIB, VB, VIB, VIIB and VIII of the periodic table, at least one ligand and at least one organometallic reducing agent, optionally in the presence of an ionic liquid non-aqueous chosen from the group formed by liquid salts which have the general formula Q + A- (in which Q + represents a quaternary ammonium and / or a quaternary phosphonium and A- represents any anion capable of forming a liquid salt below 90 ° C) is used for the selective hydrogenation of diolefin compounds to monoolefin compounds.

ASYMMETRIC HYDROFORMYLATION

COMPOSICAO DE MATERIA,PERCURSOR DE CATALISADOR E PROCESSO PARA A PREPARACAO DE COMPOSTOS DE CACHO BIMETALICO

IMPROVED POLYMER-SUPPORTED PHOTOSENSITIZERS

Improved polymer-immobilized photosensitizer are disclosed as well as methods of preparing and using them. The polymer-immobilized photosensitizers comprise a cross-linked polymer backbone, a plurality of cationic ammonium or phosphonium groups covalently bound to the polymer backbone and an immobilized photosensitizer. The average total number of carbon atoms in the ammonium or phosphonium group is at least four and preferably at least 12. The photosensitizer can be either covalently or ionically bound to the polymer. Polymer-supported photosensitizers of the invention are unexpectedly superior in catalyzing the photosensitized oxidation of compounds containing carbon-carbon double bonds.

Polymer-supported photosensitizers

Improved polymer-immobilized photosensitizer are disclosed as well as methods of preparing and using them. The polymer-immobilized photosensitizers comprise a cross-linked polymer backbone, a plurality of cationic ammonium or phosphonium groups covalently bound to the polymer backbone and an immobilized photosensitizer. The average total number of carbon atoms in the ammonium or phosphonium group is at least four and preferably at least 12. The photosensitizer can be either covalently or ionically bound to the polymer. Polymer-supported photosensitizers of the invention are unexpectedly superior in catalyzing the photosensitized oxidation of compounds containing carbon-carbon double bonds.

Verfahren zur Herstellung eines Katalysators fur die Disproportionierung von Olefinen

ALKYLENE GLYCOL ETHER ESTER OF ORGANIC CARBOXYLIC ACID

ETHANOL FROM METHANOL AND SYN-GAS

OLEFIN DISPROPORTIONATION

PROCESS Of EPOXYDATION

OLIGOMERISATION OF OLEFINIC COMPOUNDS IN THE PRESENCE OF AN OLIGOMERISATION CATALYST, AND A CATALYST ACTIVATOR INCLUDING A HALOGENATED ORGANIC GROUP

According to the present invention there is provided a process for producing an oligomeric product by the oligomerisation of at least one olefinic compound, by contacting the at least one olefinic compound with the combination of an oligomerisation catalyst and a catalyst activator. The catalyst activator is a compound which includes at least one halogenated organic group which is bound to one or more binding atoms selected from the group consisting of a group 5A atom and a group 6A atom, which one or more binding atoms are in turn bound to a central atom selected from the group consisting of a group 3A atom, and a group 3B to 7B transition metal atom. The oligomerisation catalyst includes the combination of i) a source of a transition metal; and ii) a ligating compound of the formula (R1)m X1 (Y) X2 (R2)n. The invention also relates to a combination of an oligomerisation catalyst and a catalyst activator as set out above and to the use of such a combination in an oligomerisation process. The preferred transition metal is Cr and the preferred ligating compounds are (R1)2 P (NR7) P (R2)2, [tris-N, N, N-(ethylhexyl)] 1, 3, 5-triaza cyclohexane and (decyl-S-Cu2Cu2)2NH. The preferred activator is [Ph3C][Al{OC(CF3)3}].

PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS, NOVEL CARBONYLATION LIGANDS AND CATALYST SYSTEMS INCORPORATING SUCH LIGANDS

A novel bidentate ligand of general formula (I) is described together with a process for the carbonylation of ethylenically unsaturated compounds. The group X1 may be defined as a univalent hydrocarbyl radical of up to 30 atoms containing at least one nitrogen atom having a pKb in dilute aqueous solution at 18° C. of between 4 and 14 wherein the said at least one nitrogen atom is separated from the Q2 atom by between 1 and 3 carbon atoms. The group X2 is defined as X1, X3 or X4 or represents a univalent radical of up to 30 atoms having at least one primary, secondary or aromatic ring carbon atom wherein each said univalent radical is joined via said at least one primary, secondary or aromatic ring carbon atom(s) respectively to the respective atom Q2. Q1 and Q2 each independently represent phosphorus, arsenic or antimony.

Process for the recovery of metals

A process for recovering Group VIII metals from process streams derived from carbonylation processes is provided. The process comprises contacting the process stream with an extracting stream comprising acetic acid in water and thereafter recovering the extracting stream. The process stream is preferably one which contains tar and is produced by diluting a side stream from a carbonylation reactor with methyl iodide. During the process the Group VIII metal is extracted into the extracting stream from the process stream.

ETHANOL SYNTHESIS BY HOMOLOGATION OF METHANOL

New catalytic compositions

Esters of formic acid are made by contacting an alcohol, an enol or a phenol with CO in the presence of a catalyst comprising, in a substantially anhydrous condition, an olefine oxide and at least one compound of general formula in which R1, R2 and R3 are the same or different hydrocarbon radicals and X is a group Vb element preferably N, P, or As. The same catalyst is used to prepare N-substituted formamides from primary or secondary aliphatic or aromatic amines and CO. Compounds which may be converted to formic esters are methanol, ethanol, n-butanol, sec-butanol, tert-butanol and 2-methoxy ethanol, and by similar treatment diphenylamine may be converted to N-formyldiphenylamine. Example 14 describes the preparation of the formate corresponding to 2-tert.-butylphenol.ALSO:A catalyst comprises an olefine oxide and at least one compound of general formula where R1, R2 and R3 are identical or different hydrocarbon radicals and X is a Group Vb element ...

Method for activating and immobilizing cationic transition metal catalysts using ionic fluids and compressed co2

METHANOL HOMOLOGATION USING IRON-COBALT CATALYST

ABSTRACT OF THE DISCLOSURE A homogeneous catalytic process for the homologa-tion of methanol to methyl acetate or methanol to ethanol, acetaldehyde or mixtures thereof. The process comprises reacting methanol with CO to yield methyl acetate or methanol with CO and H2 to yield ethanol, acetaldehyde or mixtures thereof in the presence of a catalytically effective amount of an iron-cobalt carbonyl cluster complex and an iodide promoter at temperatures of from about 100 to 250-C and pressures of about 5 to 100 MPa.

PROCESSES FOR MAKING POLYISOBUTYLENE COMPOSITIONS

Methods of making polyisobutylene and catalyst systems are described. Polyisobutylene compositions and catalyst system compositions are also described. In some embodiments, a method of making a catalyst system includes: providing a support material; calcining the support material; and forming a catalyst system by adding to the support material (a) a mixture comprising BF3, (b) a mixture comprising BF3 and a complexing agent, or (c) both. In some embodiments, a method of making a polymer composition includes providing a catalyst system comprising: (a) a support material; and (b) BF3; providing a feedstock comprising isobutylene; forming a reaction mixture comprising the feedstock and the catalyst system; contacting the isobutylene with the catalyst system; and obtaining a polymer composition.

PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS, NOVEL CARBONYLATION LIGANDS AND CATALYST SYSTEMS INCORPORATING SUCH LIGANDS

A novel bidentate ligand of general formula (I) is described together with a process for the carbonylation of ethylenically unsaturated compounds. The group X1 may be defined as a univalent hydrocarbyl radical of up to 30 atoms containing at least one nitrogen atom having a pKb in dilute aqueous solution at 18°C of between 4 and 14 wherein the said at least one nitrogen atom is separated from the Q2 atom by between 1 and 3 carbon atoms. The group X2 is defined as X1, X3 or X4 or represents a univalent radical of up to 30 atoms having at least one primary, secondary or aromatic ring carbon atom wherein each said univalent radical is joined via said at least one primary, secondary or aromatic ring carbon atom(s) respectively to the respective atom Q2. Q1 and Q2 each independently represent phosphorus, arsenic or antimony.

Precious-metal-free formaldehyde-eliminating supported catalyst and preparation method thereof

ASYMMETRIC HYDROFORMYLATION

New catalysts used to facilitate SN2 and more particularly SNAr substitutions on aromatic substrates, useful for effecting exchanges between fluorine and a higher halogen or pseudo-halogen

Catalyst of specific formula is used as a catalyst for nucleophilic substitution reactions preferably aromatic substitution reactions. Catalyst of formula (I) is used as a catalyst for nucleophilic substitution reactions preferably aromatic substitution reactions. R1, R2, R3, R4, R5 and R6 = hydrocarbyl radicals; Pn (preferably the same) = metalloid group V elements of a period higher than N; and Z = group V metalloid preferably distinct from Pn, and preferably N(N, P, As, Sb). Independent claims are also included for: (1) compositions including the catalysts (I); and (2) preparation of compounds (I).

플루오로중합체를 위한 경화 조성물

화학식, A n q- Q p m+ [여기서, m, n, p 및 q는 양의 정수이고, m * p = n * q이고, Q m+ 는 유기 오늄이고, A q- 는 음이온이며, 단 적어도 하나의 A q- 는 하기 화학식 I: [화학식 I] (여기서, 각각의 R은 독립적으로 H, 할로, 알킬, 아릴, 아르알킬 또는 사이클로알킬이고, 또한 할로겐화, 플루오르화, 또는 퍼플루오르화될 수 있으며, R과 R' 기 중 둘 이상은 함께 고리를 형성할 수 있으며, 각각의 R 기는 독립적으로 하나 이상의 헤테로원자(들)를 함유할 수 있으며, R'은 R과 동일할 수 있으며, 단 R'은 할로일 수 없음)로부터 선택됨]의 양이온과 음이온을 포함하며, 탄화수소 함유 알코올이 본질적으로 없는 촉매 조성물이 제공된다. 또한, 이러한 경화제를 포함하는 플루오로중합체 조성물, 플루오로중합체의 제조 방법, 및 경화성 또는 경화된 플루오로중합체 조성물을 포함하는 플루오로중합체 용품이 제공된다. Formula, and A n q- Q p m + [wherein, m, n, p and q are positive integers, m * p = n * q, and a Q m + is an organic onium, A q- is an anion, with the proviso that at least One A q- is selected from the group consisting of: (I) Wherein each R is independently H, halo, alkyl, aryl, aralkyl or cycloalkyl and may also be halogenated, fluorinated, or perfluorinated, and two or more of the R and R ' Each R group may independently contain one or more heteroatom (s), and R 'may be the same as R, with the proviso that R' is not halo) Wherein the catalyst composition is essentially free of hydrocarbon-containing alcohol. There is also provided a fluoropolymer composition comprising such a curing agent, a process for preparing a fluoropolymer, and a fluoropolymer article comprising a curable or cured fluoropolymer composition.

process for the photoactivation and use of a catalyst by a two stage procedure inverted

CURING COMPOSITIONS FOR FLUOROPOLYMERS

A catalyst composition comprising a cation and an anion of the formula Anq- Qpm+, wherein m, n, p, and q are positive integers, wherein m * p = n * q, wherein Qm+ is an organo onium, and Aq- is an anion, provided that at least one Aq- is selected from the formula (I) wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R' groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R' can be the same as R, with the proviso that R' cannot be halo, and wherein the catalyst composition is essentially free of hydrocarbon containing alcohol. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions ...

Nickel-containing composition for catalysis and olefin dimerisation and oligomerisation process

The invention concerns a catalytic composition and a process for the dimerisation, codimerisation or oligomerisation of olefins, said composition comprising a mixture of at least one bivalent nickel complex which contains two tertiary phosphine molecules, at least one nickel complex which contains neither water nor phosphine, and at least one alkylaluminium halide. The mixture is particularly for use in ionic type non aqueous liquid compositions, such as those formed by quaternary ammonium halides and/or quaternary phosphonium halides with aluminium halides and/or alkylaluminium halides.

Processes for regenerating dispersions of ligand-stabilized, palladium and platinum (II) halide complexes used in carbonylation and hydroformylation catalysis

This invention concerns chlorinating processes for the regeneration of carbonylation and hydroformylation catalysts consisting of dispersions of ligand-stabilized palladium(II) and platinum(II) halide complexes in quaternary ammonium, phosphonium and arsonium salts of trihalostannate(II) and trihalogermanate(II).

Catalyst for sweetening a sour hydrocarbon fraction containing metal oxide solid solution and magnesium oxide

A catalyst and a process for using the catalyst have been developed. The catalyst is a metal chelate dispersed on a basic support which is a combination of a solid base and a secondary component. The solid base can be a solid solution of metal oxides and/or a layered double hydroxide (LDH) and the secondary component can be calcium oxide, magnesium oxide, calcium hydroxide and magnesium hydroxide. The process involves contacting a sour hydrocarbon fraction which contains mercaptans with the catalyst in the presence of an oxidizing agent and a polar compound. Examples of these polar compounds are water and alcohols, with methanol being especially preferred. The process is unique in that the solid solution or LDH are solid bases which eliminates the need for a liquid base. Optionally, an onium compound may be used as a catalyst promoter.

Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated -AR group

According to the present invention there is provided a process for producing an oligomeric product by the oligomerisation of at least one olefinic compound, by contacting the at least one olefinic compound with the combination of an oligomerisation catalyst and a catalyst activator. The catalyst activator is a compound which includes at least one halogenated organic group which is bound to one or more binding atoms selected from the group consisting of a group 5A atom and a group 6A atom, which one or more binding atoms are in turn bound to a central atom selected from the group consisting of a group 3A atom, and a group 3B to 7B transition metal atom. The oligomerisation catalyst includes the combination of i) a source of a transition metal; and ii) a ligating compound of the formula (R1)mX1(Y)X2(R2)n The invention also relates to a combination of an oligomerisation catalyst and a catalyst activator as set out above and to the use of such a combination in an oligomerisation process.

ETHANOL SYNTHESIS BY HOMOLOGATION OF METHANOL

ASYMMETRIC HYDROFORMYLATION

CURING COMPOSITIONS FOR FLUOROPOLYMERS

RECOVERY PROCESS

CATALYTIC HYDROFORMYLATION PROCESS

... 1326013 Oxo process; rhodium acetates JOHNSON MATTHEY & CO Ltd 6 July 1970 [14 July 1969] 16293/73 Divided out of 1326012 Heading C2C Aldehydes are produced by the hydroformylation of olefinically unsaturated compounds with H 2 and CO using as catalyst a composition prepared by adding a stabilizing donor ligand to a solution containing a strong acid and any of M 2 4+, M 2 (O 2 CR)n+ 4-n , M 2 (OCSR)n+ 4-n and M 2 (S 2 CR)n+ 4-n wherein n is 1, 2, 3 or 4, Ris alkyl or aryl and may be substituted and M is a transition metal. Stabilizing donor ligands are defined as organic isocyanides; other organic compounds, other than alcohols, having in the molecule an atom of an element of Groups VB or VIB in a valency state such that it possesses a lone pair of electrons ; or a stannous or germanium II halide. In the example heptaldehydes are produced by the hydroformylation of hex-1-one in a methanolic solution of Rh 2 (O 2 CCH 3 ) 2 , HBF 4 and P(C 6 H 5 ) 3 . [ ...

9-azanoradamantane n-oxyl compound and method for producing same, and organic oxidation catalyst and method for oxidizing alcohols using 9-azanoradamantane n-oxyl compound

An organocatalyst for oxidizing alcohols in which a primary alcohol is selectively oxidized in a polyol substrate having a plurality of alcohols under environmentally-friendly conditions. The organic oxidation catalyst has an oxygen atom bonded to a nitrogen atom of an azanoradamantane skeleton and at least one alkyl group at positions 1 and 5. The oxidation catalyst has higher activity than TEMPO, which is an existing oxidation catalyst, in the selective oxidation reaction of primary alcohols, and better selectivity than AZADO and 1-Me-AZADO. This DMN-AZADO can be applied to the selective oxidation reaction of primary alcohols that contributes to shortening the synthesizing process for pharmaceuticals, pharmaceutical raw materials, agricultural chemicals, cosmetics, organic materials, and other such high value-added organic compounds.

Composite Carrier for Immobilization of Proteins, Polypeptides or Oligopeptides, Preparation Methods and Application Thereof

Provided are a composite carrier for immobilization of a protein, polypeptide or oligopeptide, a preparation method and an application thereof. The composite carrier is a porous material which comprises: (1) a porous organic foam material containing open pores; and (2) a crosslinked product having aldehyde groups and immobilized on the surface of the walls of one or more pores of the porous organic foam material, wherein the aldehyde groups are able to react with the protein, polypeptide or oligopeptide, and the crosslinked product are formed by chitosan via a crosslinking reaction with a polyaldehyde compound. 1. A porous composite carrier for immobilization of a protein , polypeptide or oligopeptide , comprising:a) a porous organic foam material containing open pores; andb) a crosslinked product having aldehyde groups and immobilized on the surface of the walls of one or more pores of the porous organic foam material, wherein the aldehyde groups are able to react with the protein, polypeptide or oligopeptide, and the crosslinked product is formed by chitosan via a crosslinking reaction with polyaldehyde compounds.2. The composite carrier according to claim 1 , wherein the organic foam material is melamine foam.3. The composite carrier according to claim 1 , wherein the composite carrier is in a form of granules claim 1 , straps claim 1 , sheets claim 1 , blocks or columns.4. A method for preparation of the composite carrier according to claim 1 , wherein the method comprises the following steps:a) providing a porous organic foam material containing open pores;b) precipitating a chitosan onto a surface of walls of one or more pores of the porous organic foam material; andc) crosslinking the precipitated chitosan with a polyaldehyde compound to form the composite carrier.5. The method according to claim 4 , wherein in step b) claim 4 , the chitosan is precipitated onto the surface by reacting with an alkaline.6. The method according to claim 4 , wherein the ...

Nickel-containing composition for catalysis and olefin dimerisation and oligomerisation process

The invention concerns a catalytic composition and a process for the dimerization, codimerization or oligomerization of olefins, said composition comprising a mixture of at least one bivalent nickel complex which contains two tertiary phosphine molecules, at least one nickel compound or complex compound which contains neither water nor phosphine, and at least one alkylaluminum halide. The mixture is particularly for use in ionic type non aqueous liquid compositions, such as those formed by quaternary ammonium halides and/or quaternary phosphonium halides with aluminum halides and/or alkylaluminum halides.

Nickel-containing composition for catalysis and olefin dimerisation and oligomerisation process

The invention concerns a catalytic composition and a process for the dimerisation, codimerisation or oligomerisation of olefins, said composition comprising a mixture of at least one bivalent nickel complex which contains two tertiary phosphine molecules, at least one nickel complex which contains neither water nor phosphine, and at least one alkylaluminium halide. The mixture is particularly for use in ionic type non aqueous liquid compositions, such as those formed by quaternary ammonium halides and/or quaternary phosphonium halides with aluminium halides and/or alkylaluminium halides.

使用均相催化剂将多不饱和化合物选择性氢化为单不饱和化合物的方法

本发明涉及一种使用一种催化剂组合物将二烯烃化合物选择性氢化为单烯烃化合物的方法，其中使用的催化剂组合物含有至少一种选自元素周期表中第IB、IIB、VB、VIB、VIIB和VIII族的过渡金属的盐，至少一种配位体和至少一种有机金属还原剂，并且任选在选自通式Q + A － 的液体盐的非水离子性液体存在下(其中，Q + 代表季铵和/或季鏻，A － 代表可在低于90℃形成液体盐的任何阴离子)。

Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated organic group

According to the present invention there is provided a process for producing an oligomeric product by the oligomerisation of at least one olefiπic compound, by contacting the at least one olefinic compound with the combination of an oligomerisation catalyst and a catalyst activator. The catalyst activator is a compound which includes at least one halogenated organic group which is bound to one or more binding atoms selected from the group consisting of a group 5A atom and a group 6A atom, which one or more binding atoms are in turn bound to a central atom selected from the group consisting of a group 3A atom, and a group 3B to 7B transition metal atom. The oligomerisation catalyst includes the combination of i) a source of a transition metal; and ii) a ligating compound of the formula (R 1 )mX 1 (Y)X 2 (R 2 )n The invention also relates to a combination of an aligomerisation catalyst and a catalyst activator as set out above and to the use of such a combination in an oligomerisation process.

Processes for making polyisobutylene compositions

Methods of making polyisobutylene and catalyst systems are described. Polyisobutylene compositions and catalyst system compositions are also described. In some embodiments, a method of making a catalyst system includes: providing a support material; calcining the support material; and forming a catalyst system by adding to the support material (a) a mixture comprising BF 3 , (b) a mixture comprising BF 3 and a complexing agent, or (c) both. In some embodiments, a method of making a polymer composition includes providing a catalyst system comprising: (a) a support material selected from the group consisting of Al 2 O 3 , ZrO 2 , TiO 2 , SnO 2 , CeO 2 , SiO 2 , SiO 2 /Al 2 O 3 , and combinations thereof; and (b) BF 3 ; providing a feedstock comprising isobutylene; forming a reaction mixture comprising the feedstock and the catalyst system; contacting the isobutylene with the catalyst system; and obtaining a polymer composition.

Processes for making polyisobutylene compositions

Methods of making polyisobutylene and catalyst systems are described. Polyisobutylene compositions and catalyst system compositions are also described. In some embodiments, a method of making a catalyst system includes: providing a support material comprising one or more ion exchange resins; dehydrating the support material; and forming a catalyst system by adding to the support material (a) a mixture comprising BF 3 , (b) a mixture comprising BF 3 and a complexing agent, or (c) both. In some embodiments, a method of making a polymer composition includes providing a catalyst system comprising: (a) a support material comprising one or more ion exchange resins, and (b) BF 3 ; providing a feedstock comprising isobutylene; forming a reaction mixture comprising the feedstock and the catalyst system; contacting the isobutylene with the catalyst system; and obtaining a polymer composition.

Processes for making polyisobutylene compositions

Methods of making polyisobutylene and catalyst systems are described. Polyisobutylene compositions and catalyst system compositions are also described. In some embodiments, a method of making a catalyst system includes: providing a support material; calcining the support material; and forming a catalyst system by adding to the support material (a) a mixture comprising BF 3 , (b) a mixture comprising BF 3 and a complexing agent, or (c) both. In some embodiments, a method of making a polymer composition includes providing a catalyst system comprising: (a) a support material selected from the group consisting of Al 2 O 3 , ZrO 2 , TiO 2 , SnO 2 , CeO 2 , SiO 2 , SiO 2 /Al 2 O 3 , and combinations thereof; and (b) BF 3 ; providing a feedstock comprising isobutylene; forming a reaction mixture comprising the feedstock and the catalyst system; contacting the isobutylene with the catalyst system; and obtaining a polymer composition.

Process for the photoactivation and use of a catalyst by an inverted two-stage procedure

본 발명은, 광잠열 촉매(a)를 포함하는 조성물을 추가 처리하기 전에 방사선 조사하는 특정한 광잠열 촉매의 적용방법에 관한 것이다. The present invention relates to a method of applying a particular latent latent catalyst which is irradiated prior to further treatment of the composition comprising the latent latent catalyst (a). 광잠열 촉매, 방사선 조사, 폴리올, 이소시아네이트, UV 광, 열, 경화. Latent heat catalysts, radiation, polyols, isocyanates, UV light, heat, curing.

Process for the selective hydrogenation of polyunsaturated compounds to monounsaturated compounds using homogeneous catalysts

【課題】１，３−ブタジエンのブテンへの水素化に効果があり、それに続く１−ブテンまたは２−ブテンのブタンへの水素化に対する活性が低いような、水素化触媒を開発 【解決手段】 触媒組成物では、α−オレフィン系化合物から飽和化合物への水素化速度よりも、少なくとも３倍、一般には約５倍高い速度で、ジオレフィン系化合物からモノオレフィン系化合物へ水素化することが可能となる。この可溶性触媒は一般に、ＩＢ、ＩＩＢ、ＶＢ、ＶＩＢ、ＶＩＩＢおよびＶＩＩＩからなる群よりの遷移金属の少なくとも１種の塩と、少なくとも１種のリガンドと、少なくとも１種の有機金属還元剤とを含むものと、定義することができる。

Process for the selective hydrogenation of polyunsaturated compounds to monounsaturated compounds using homogeneous catalysts

Mesoporous polymer colloids

The invention provides a particulate material comprising porous polymeric microparticles having a mesoporous structure. A process for making the particles is also presented. The process comprises impregnating a porous microparticulate template material with a liquid comprising one or more monomers. The one or more monomers are then polymerized in and/or on the template material to form a polymer, and the template material is then removed to produce the particulate material.

Novel composition containing nickel for catalysis and process for dimerization and oligomerization of olefins

Novel nickel-containing composition for catalysis and olefin dimerisation and oligomerisation process

本发明涉及催化组合物和烯烃的二聚、共二聚或 齐聚的方法，所述组合物由至少一种含两个叔膦分子 的二价镍复合物、至少一种既不含水也不含膦的镍复 合物、和至少一种烷基铝卤化物的混合物组成。这种 混合物特别是以溶于离子型非水液态组合物中的形 式得以使用，如那些通过季铵卤化物和/或季鏻卤化 物和卤化铝和/或烷基铝卤化合物形成的组合物。

Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated organic group

按照本发明，提供通过将至少一种烯属化合物与低聚催化剂和催化剂活化剂的组合物进行接触，使至少一种烯属化合物低聚来生产低聚产物的方法，所述催化剂活化剂是包括至少一个卤代有机基团的化合物，所述卤代有机基团键接一或多个选自5A族原子和6A族原子的联结原子，而所述一或多个联结原子再键接选自3A族和3B－7B族过渡金属原子的中心原子。所述低聚催化剂包括如下组分的组合物：i)过渡金属源；ii)式(R 1 ) m X 1 (Y)X 2 (R 2 ) n 的配位化合物。本发明还涉及上述催化剂和上述催化剂活化剂的组合物和该组合物在低聚方法中的应用。优选的过渡金属是Cr，优选的配位化合物是(R 1 ) 2 P(NR 7 )P(R 2 ) 2 、[三－N，N，N－(乙基己基)]1，3，5－三氮杂环己烷和(癸基－S－Cu 2 Cu 2 ) 2 NH。优选的活化剂是[Ph 3 C][Al{OC(CF 3 ) 3 }]。

Patent TWI367128B

Nickel containing catalytic composition and process for dimerization and oligomerization of olefins

PROCESS FOR THE PREPARATION OF ALKYLENE GLYCOL ETHERESTERS OF ORGANIC CARBONIC ACIDS.

Composition and a method of making and use of such composition

A composition and method of making such a composition that has application in the hydroprocessing of hydrocarbon feedstocks. The method comprises selecting an organic additive by the use of a correlation model for predicting catalytic activity as a function of a physical property that is associated with the organic additive and incorporating the organic additive into a support material to provide the additive impregnated composition.

Conversion of methanol to methyl acetate using iron-cobalt catalyst

A homogeneous catalytic process for the conversion of methanol to methyl acetate. The process comprises contacting CO with methanol in the presence of a catalytically effective amount of an iron-cobalt carbonyl complex of the formula M[FeCo 3 (CO) 12 ] or M[CoFe 3 (CO) 13 ] where M is hydrogen or a cation and an iodide promoter, heating the resultant mixture at temperatures of from 100° to 250° C. at pressures of from 5 to 100 MPa.

Process for the carbonylation of ehtylenically unisaturated compounds, novel carbonylation ligands and catalyst systsems incorporating such ligands

Methanol conversion with CO or CO+H2 using iron-cobalt catalyst

A homogeneous catalytic process for the homologation of methanol to methyl acetate or methanol to ethanol, acetaldehyde or mixtures thereof. The process comprises reacting methanol with CO to yield methyl acetate or methanol with CO and H 2 to yield ethanol, acetaldehyde or mixtures thereof in the presence of a catalytically effective amount of an iron-cobalt carbonyl cluster complex and an iodide promoter at temperatures of from about 100 to 250°C and pressures of about 5 to 100 MPa.

Electrode catalyst and method for producing same

An electrode catalyst which is characterized by being obtained by: forming a fired body by firing a metal phthalocyanine polymer that has a repeating structural unit wherein a structural unit represented by general formula (1a) and a structural unit represented by general formula (2a) are bonded with each other by an amide bond; and then treating the fired body with an acid. (In general formula (1a), L represents a divalent or trivalent metal ion of an element of the third to fifth rows of the long form periodic table.) (In general formula (2a), M represents a divalent or trivalent metal ion of an element of the third to fifth rows of the long form periodic table.)

Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated organic group

Method for producing enantiomer-enriched lactones

The invention relates to a method for producing enantiomer-enriched lactones by carbonylating lactones into anhydrides in the presence of a catalyst system, containing: A) at least one carbonylation catalyst A comprised of neutral or anionic transition metal complexes of metals Re, Co, Ru, Rh, Ir, Fe, Ni, Mn, Mo, W or mixtures thereof, and; B) at least one chiral Lewis acid B comprised of compounds of metals Mg, Ca, Sc, Y, a rare-earth element, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Al, Ga, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl and Pb, the compounds in the reaction conditions of the carbonylation existing in a coordinatively undersaturated manner.

Catalysts for nucleophilic substitution, synthesis thereof, composition containing same and use thereof

The invention concerns novel catalysts for aromatic nucleophilic substitution. Said catalysts are compounds of the general formula (I), wherein: R1, R2, R3, R4, R5, and R6, identical or different, are selected among hydrocarbon radicals; the Pn's, advantageously the same, are selected among metalloid elements of column V of a period higher than nitrogen; Z is a metalloid element of column V, advantageously distinct from Pn; preferably a nitrogen (N, P, As, Sb). The invention is applicable to organic synthesis.

Process for the carbonylation of ethylenically unsaturated compounds, new carbonylation ligands and catalyst systems incorporating said ligands

Ligando bidentado novedoso de la fórmula general (I)**Fórmula** donde: A y B representan cada uno independientemente a un grupo enlazador alquileno C0-C1; donde cuando uno de los grupos A o B es C0, entonces el otro grupo no puede ser C0 y debe ser un grupo C1; R representa a una estructura aromática de hidrocarbilo que tiene al menos un anillo aromático al cual están unidos Q1 y Q2 mediante el respectivo grupo enlazador, si está presente, en átomos adyacentes disponibles del al menos un anillo aromático; los grupos X3 y X4 independientemente representan radicales univalentes de hasta 30 átomos que tienen al menos un átomo de carbono terciario o X3 y X4 juntos forman un radical bivalente de hasta 40 átomos que tiene al menos dos átomos de carbono terciario donde cada uno de dicho radical univalente o bivalente se une mediante dicho al menos uno o dos átomos de carbono terciario respectivamente al átomo Q1 respectivo; el grupo X1 se puede definir como un radical hidrocarbilo univalente de hasta 30 átomos que contiene al menos un átomo de nitrógeno que tiene una pKb en disolución acuosa diluida a 18ºC entre 4 y 14 donde dicho al menos un átomo de nitrógeno está separado del átomo Q2 por entre 1 y 3 átomos de carbono; el grupo X2 se define como X1, X3 o X4 o representa un radical univalente de hasta 30 átomos que tiene al menos un átomo de carbono primario, secundario o de anillo aromático donde cada radical univalente se une mediante dicho al menos un átomo de carbono primario, secundario o de anillo aromático respectivamente al átomo Q2 respectivo; y Q1 y Q2 representan, cada uno independientemente, fósforo, arsénico o antimonio; donde el grupo X1 es aromático. Novel bidentate ligand of the general formula (I) ** Formula ** where: A and B each independently represent a C0-C1 alkylene linker group; where when one of the groups A or B is C0, then the other group cannot be C0 and must be a group C1; R represents an aromatic hydrocarbyl structure having at least one ...

Catalyst for sweetening a sour hydrocarbon fraction containing metal oxide solid solution and magnesium oxide

A catalyst and a process for using the catalyst have been developed. The catalyst is a metal chelate dispersed on a basic support which is a combination of a solid base and a secondary component. The solid base can be a solid solution of metal oxides and/or a layered double hydroxide (LDH) and the secondary component can be calcium oxide, magnesium oxide, calcium hydroxide and magnesium hydroxide. The process involves contacting a sour hydrocarbon fraction which contains mercaptans with the catalyst in the presence of an oxidizing agent and a polar compound. Examples of these polar compounds are water and alcohols, with methanol being especially preferred. The process is unique in that the solid solution or LDH are solid bases which eliminates the need for a liquid base. Optionally, an onium compound may be used as a catalyst promoter.

POLYMER-DRIVEN PHOTOSENSIBILIZERS

Patent TW287175B

Ethanol synthesis by homologation of methanol

Methanol can be converted into ethanol by reaction with carbon monoxide and hydrogen, at a temperature of at least 150°C and a pressure of at least 35 bars, in the presence of a catalyst comprising (a) a ruthenium compound, (b) a quaternary phosphonium or ammonium base or salt, and (c) cobalt (II) iodide, bromide or chloride. Optionally the reaction is carried out in the presence of an oxygenated hydrocarbon solvent (e.g. an ether, ester, ketone or alcohol). The simultaneous use of a ruthenium compound and a cobalt (II) halide results in ethanol formation in a higher yield and with greater selectivity than is achieved using either material in the absence of the other.

Process for the production of acetaldehyde by the reaction of methanol with synthesis gas

New Nickel-Containing Catalytic Compositions and Processes for Dimerization and Prepolymerization of Olefins

본 발명은 2개의 3차 포스핀 분자를 함유하는 하나 이상의 2가의 니켈착화합물, 물과 포스핀을 전혀 함유하지 않는 하나 이상의 니켈 착화합물, 및 하나 이상의 알킬알루미늄 할로겐화합물의 혼합물을 포함하는 촉매 조성물, 및 올레핀을 이합, 혼성 이합 또는 소중합시키는 방법에 관한 것으로서, 상기 혼합물은 특히 4차 암모늄 할로겐화물 및/또는 4차 포스포늄 할로겐화합물과 알루미늄 할로겐화물 및/또는 알킬아루미늄 할로겐화물에 의해 형성되는 것과 같은 이온 유형의 비수성 액체 조성물에 사용된다.

Method for selective hydrogenation of polyunsaturated compounds into monounsaturated compounds using a homogeneous catalyst

A process for the selective hydrogenation of diolefinic compounds to mono-olefinic compounds uses a catalyst composition comprising at least one salt of a transition metal from groups IB, IIB, VB, VIB, VIIB and VIII of the periodic table, at least one ligand and at least one organometallic reducing agent, optionally in the presence of a non-aqueous ionic liquid selected from the group formed by liquid salts with general formula Q + A − (in which Q + represents a quaternary ammonium and/or quaternary phosphonium and A − represents any anion which can form a liquid salt below 90° C.).

Composition and a method of making and use of such composition

A composition and method of making such a composition that has application in the hydroprocessing of hydrocarbon feedstocks. The method comprises selecting an organic additive by the use of a correlation model for predicting catalytic activity as a function of a physical property that is associated with the organic additive and incorporating the organic additive into a support material to provide the additive impregnated composition.

Antimony catalyst compositions

Novel active catalyst compositions comprising a compound or mixture of compounds represented by the formula SbFX m Y 4−m a complex of such a compound or mixture of such compounds being represented by the formula R·SbFX m Y 4−m or a combination of such compounds and complexes where in each formula, X is an anionic moiety, Y is an anion or anions resulting from the deprotonation of an active hydrogen-containing compound(s), m is 0 to 3 and R is one or more active hydrogen containing compound acting as molecules of solvation. The catalyst compositions are useful to promote alkoxylation reactions.

Process for the epoxidation of olefins

PROCESS FOR THE PRODUCTION OF ACETALDEHYDE THROUGH THE REACTION OF METHANOL WITH SYNTHESIS GAS

Improved polymer-supported photosensitizers

Improved polymer-immobilized photosensitizer are disclosed as well as methods of preparing and using them. The polymer-immobilized photosensitizers comprise a cross-linked polymer backbone, a plurality of cationic ammonium or phosphonium groups covalently bound to the polymer backbone and an immobilized photosensitizer. The average total number of carbon atoms in the ammonium or phosphonium group is at least four and preferably at least 12. The photosensitizer can be either covalently or ionically bound to the polymer. Polymer-supported photosensitizers of the invention are unexpectedly superior in catalyzing the photosensitized oxidation of compounds containing carbon-carbon double bonds.

Methanol homologation using iron-cobalt carbonyl cluster catalyst

A homogeneous catalytic process for the selective conversion of methanol to ethanol or acetaldehyde. The process comprises contacting CO and H 2 with a catalytically effective amount of an iron-cobalt carbonyl complex of the formula M[FeCo 3 (CO) 12 ] where M is hydrogen or a cation and an iodide promoter; heating the resulting mixture at temperatures of from 100° to 250° C. at pressures of from 5 to 100 MPa. By controlling the reaction parameters of H 2 :CO ratio, temperature and reaction time, acetaldehyde or ethanol can be selectively produced.

Homologation of methanol employing ironncobalt catalyst

Catalyst for sweetening a sour hydrocarbon fraction containing metal oxide solid solution and magnesium oxide

A catalyst and a process for using the catalyst have been developed. The catalyst is a metal chelate dispersed on a basic support which is a combination of a solid base and a secondary component. The solid base can be a solid solution of metal oxides and/or a layered double hydroxide (LDH) and the secondary component can be calcium oxide, magnesium oxide, calcium hydroxide and magnesium hydroxide. The process involves contacting a sour hydrocarbon fraction which contains mercaptans with the catalyst in the presence of an oxidizing agent and a polar compound. Examples of these polar compounds are water and alcohols, with methanol being especially preferred. The process is unique in that the solid solution or LDH are solid bases which eliminates the need for a liquid base. Optionally, an onium compound may be used as a catalyst promoter.

Method of manufacturing acetoaldehyde through reaction of methanol and synthetic gas

Electrode catalyst and method for producing same

本發明係一種電極觸媒，其特徵在於：藉由將具有由通式(1a)所示之結構單位與通式(2a)所示之結構單位以醯胺之形式鍵結而成之重複結構單位的金屬酞青聚合物進行燒成而製成燒成體後，利用酸進行處理而獲得。 □(通式(1a)中，L為屬於長週期型週期表之第3~第5週期之2價或3價之金屬離子) □(通式(2a)中，M為屬於長週期型週期表之第3~第5週期之2價或3價之金屬離子)

Method of manufacturing gasoline particulate filter

A method for the manufacture of a (GPF) gasoline particulate filter (also referred to as a catalyst-coated wall-flow filter substrate) for the treatment of an exhaust gas, the method comprising: forming a washcoat slurry; coating a wall-flow filter substrate with the washcoat slurry to form a washcoated substrate; and calcining the washcoated substrate to form a gasoline particulate filter. The washcoat slurry comprises a platinum group metal selected from Pt, Pd, Rh and mixtures thereof; an oxygen storage capacity (OSC) material; and a C2-C6 aliphatic amino acid. The aliphatic amino acid can have the formula HO2C-(CH2)n-NH2, wherein n is from 1-5; preferably n is 2, e.g. 3-amino-propionic acid. The amount of aliphatic amino acid in the slurry can be 1-50wt% relative to the slurry crucible solids. The slurry can comprise Pt and Rh or Pd and Rh, and the OSC material may comprise a mixed oxide of: cerium and zirconium; cerium, zirconium and aluminium; cerium, zirconium and neodymium; or cerium, zirconium and praseodymium. Preferably the OSC material is a cerium-zirconium mixed oxide nano sol with a mean particle size of less than 1µm. The slurry can further comprise an inorganic oxide support e.g. a gamma alumina.

Method for manufacturing gasoline particulate filter

A method for the manufacture of a gasoline particulate filter (GPF) for the treatment of an exhaust gas is disclosed. The method comprises (i) forming a washcoat slurry; (ii) coating a wall-flow filter substrate with the washcoat slurry to form a washcoated substrate; and (iii) calcining the washcoated substrate to form a gasoline particulate filter. The washcoat slurry comprises (a) a platinum group metal selected from the group consisting of Pt, Pd, Rh and mixtures thereof; (b) an oxygen storage capacity (OSC) material; and (c) a C2-C6 aliphatic amino acid.

Composizioni supportate a base di tungsteno o molibdeno,procedimento per il loro ottenimento e proprieta' come catalizzatori eterogenei di ossidazione

Processo per la produzione di acetaldeide mediante la reazione di metanolo con gas di sintesi.

Composizioni supportate a base di tungsteno o molibdeno, procedimento per il loro ottenimento e proprieta' come catalizzatori eterogenei di ossidazione

Method for manufacturing gasoline particulate filter

A method for the manufacture of a gasoline particulate filter (GPF) for the treatment of an exhaust gas is disclosed. The method comprises (i) forming a washcoat slurry; (ii) coating a wall-flow filter substrate with the washcoat slurry to form a washcoated substrate; and (iii) calcining the washcoated substrate to form a gasoline particulate filter. The washcoat slurry comprises (a) a platinum group metal selected from the group consisting of Pt, Pd, Rh and mixtures thereof; (b) an oxygen storage capacity (OSC) material; and (c) a C2-C6 aliphatic amino acid.

Method for manufacturing gasoline particulate filter

A method for the manufacture of a gasoline particulate filter (GPF) for the treatment of an exhaust gas is disclosed. The method comprises (i) forming a washcoat slurry; (ii) coating a wall-flow filter substrate with the washcoat slurry to form a washcoated substrate; and (iii) calcining the washcoated substrate to form a gasoline particulate filter. The washcoat slurry comprises (a) a platinum group metal selected from the group consisting of Pt, Pd, Rh and mixtures thereof; (b) an oxygen storage capacity (OSC) material; and (c) a C₂-C₆ aliphatic amino acid.

Method of manufacturing gasoline particulate filter

Trägerstützte Molybdän oder Wolfram Zusammensetzungen, Verfahren zur ihrer Herstellung und Verwendung als heterogene Oxydationskatalysatoren

碱性离子液体

离子液体作为在碱催化化学反应中的溶剂的应用，其中所述离子液体由至少一种阳离子和至少一种阴离子组成，其特征在于所述离子液体的阳离子包含带正电荷的部分和碱性部分，并且其中可以使用这些离子液体作为用于所述化学反应的促进剂或催化剂。

Verfahren zur rueckgewinnungvon edelmetal.

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Fremgangsmaate for gjenvinning av edelmetallkatalysatorer.

Platinum catalyzed isomerization of alkenyl succinic anhydrides

A process for preparing alkyl maleic anhydrides which comprises heating a lower alkenyl succinic anhydride in the presence of a catalytic amount of a platinum salt in combination with a weakly basic material under conditions effective to isomerize the alkenyl succinic anhydride.

Fremgangsmaate for gjenvinning av rhodiumkatalysator

Fremgangsmaate for gjenvinning av rhodiumkatalysator

Verfahren zur rueckgewinnungvon edelmetal.

Fremgangsmaate for gjenvinning av gruppe viii-edelmetallkatalysatorer

Organoclay triphase catalysts

In a method of carrying out organic conversions via heterogeneous phase transfer catalysis by contacting immiscible liquid phases containing respective substances capable of interacting, with a solid catalyst to promote the transfer of reactive species from one liquid phase to another, the improvement comprises employing as catalyst a cation exchanged form of a 2:1 layered silicate clay with layer charge densities in the range of above 0.4 to 2.0 containing an onium ion containing one or more alkyl hydrocarbon chains and maintaining the materials in emulsified form by having a sufficient chain length of an alkyl group relative to the charge density of the clay.

制备双酚催化剂和双酚的方法

本发明涉及在双酚生产中制备和使用催化剂的方法，特别是制备含有聚硫硫醇促进剂的催化剂的方法，以及在生产双酚A及其衍生物中使用这些催化剂的方法。聚硫基是含有氮或磷的带正电官能团的侧链，优选氮杂环。催化剂还包含固体酸载体组分，其中含有质子酸官能团，优选磺化聚合物树脂。

亲核取代用催化剂、它的合成、包含它的组合物以及它的用途

本发明涉及芳族亲核取代用新型催化剂。所述催化剂是通式(I)的化合物，其中：R 1 、R 2 、R 3 、R 4 、R 5 和R 6 相同或不同并且选自烃基；Pn有利地相同并且选自周期高于氮的第V族准金属元素；Z是第V族准金属元素，有利地不同于Pn；优选氮(N、P、As、Sb)。本发明可应用于有机合成。

不含贵金属的消除甲醛的负载型催化剂及制备方法

本发明公开了一种不含贵金属的消除甲醛的负载型催化剂，选用活性炭为载体材料，以化合物A和无机铵B为活性成分。其中，化合物A和无机铵B的负载量均为载体材料重量的1%~20%；且化合物A和无机铵B之间有一定的添加比例。制备方法：称取一定重量的活性炭，采用等量浸渍法，按照该活性炭的水容量量取去离子水；称取化合物A和无机铵B加入量好的去离子水中，搅拌至充分溶解后配置成浸渍液；将配置好的浸渍液均匀倒入活性炭载体上，并不断搅拌，待充分浸渍后，将混合料装入密封袋内，静置1~4h后于一定温度下烘干，烘干温度为40~160℃。在制备过程中不负载任何贵金属成分，与传统添加贵金属的催化剂相比，制备工艺简单，成本低廉。