07-01-2021 дата публикации
Номер: US20210002745A1
The disclosure relates to a method for preparing Ti(C,N)-based superhard metal composite materials, with Ti(C,N) powder and (W,Mo,Ta)(C,N) powder as main raw materials and Co powder as binding phase for preparation, thereby obtaining a material in which a microstructure is a double-core rim structure that has both a black core rim and a white core rim. The material has a complete and evenly distributed double-core rim structure. In the condition that the ensured hardness of the material is not reduced and even slightly increased, the toughness of the material is significantly improved, wherein the fracture toughness of the material is in the range of 11.3 to 12.5 MPa·m. 1. A preparation method of Ti(C ,N)-based superhard metal composite material , wherein Ti(C ,N) powder and (W , Mo , Ta)(C ,N) powder are adopted as main raw materials , the (W , Mo , Ta)(C ,N) powder is added into the Ti(C ,N) powder , and a Co powder is adopted as a binding phase , then molding and sintering are performed for preparation , thereby obtaining a double-core rim structure having a microstructure with black core rim and white core rim both; wherein mass fractions of the Ti (C , N) powder , the (W , Mo , Ta) (C , N) powder and the Co powder are 40-50% , 40-50% , 10-20% , respectively; the Ti (C , N) powder , the (W , Mo , Ta) (C , N) powder and the Co powder all have a fineness of 0.5 to 3 μm; specific steps are as follows:weigh the Ti(C,N) powder and the (W, Mo, Ta) (C, N) powder and mix them with the Co powder based on a proportion described above, and then add a paraffin wax, thereafter high-energy ball milling, drying, sieving, press-forming, sintering are performed; the sintering is carried out in sequence based on the following conditions: carried out in a solid phase at 1150° C., maintain the temperature for 60 to 80 minutes, sintering is carried out in a liquid phase at 1400° C. to 1450° C., maintain the temperature for 60 to 80 minutes, then fill in with nitrogen at 7 to 10 MPa, ...
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