10-02-2022 дата публикации
Номер: US20220041544A1
An azobenzene derivative, a preparation method of the azobenzene derivative, an azophenyl light control reversible adhesive, and a method of using the azophenyl light control reversible adhesive are disclosed. The azobenzene derivative has a molecular structure as P1 or P2. In the abovementioned preparation method, the azobenzene derivative P1 or P2 is obtained from an esterification reaction of an azophenyl group, 3,4,5-tripentyloxybenzoic acid or 3,4,5-tri(dodecyloxy)benzoic acid, and 2,2′-dihydroxy-1,1′-binaphthol. The melting point of the azobenzene derivative P1 or P2 is modified commonly by alkyl chains and binaphthol to be slightly higher than room temperature. 2. A preparation method of an azobenzene derivative according to claim 1 , wherein an azobenzene derivative P1 or P2 is obtained from an esterification reaction of an azophenyl group claim 1 , 3 claim 1 ,4 claim 1 ,5-tripentyloxybenzoic acid or 3 claim 1 ,4 claim 1 ,5-tri(dodecyloxy)benzoic acid claim 1 , and 2 claim 1 ,2′-dihydroxy-1 claim 1 ,1′-binaphthol.3. The preparation method of the azobenzene derivative according to claim 2 , wherein a reaction medium for the esterification reaction of an azophenyl group claim 2 , 3 claim 2 ,4 claim 2 ,5-tripentyloxybenzoic acid or 3 claim 2 ,4 claim 2 ,5-tri(dodecyloxy)benzoic acid claim 2 , and 2 claim 2 ,2′-dihydroxy-1 claim 2 ,1′-binaphthol is water claim 2 , and adding the above three raw materials into water to react together claim 2 , so as to obtain the azobenzene derivative P1 or P2.4. The preparation method of the azobenzene derivative according to claim 2 , wherein a reaction time is 20-40 minutes.5. The preparation method of the azobenzene derivative according to claim 2 , wherein a reaction temperature is 20-30° C.6. The preparation method of the azobenzene derivative according to claim 2 , wherein an amount ratio of the azophenyl group to 3 claim 2 ,4 claim 2 ,5-tripentyloxybenzoic acid or 3 claim 2 ,4 claim 2 ,5-tri(dodecyloxy)benzoic acid to 2 ...
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