ПОЛИСИЛИКАТНЫЕ МИКРОГЕЛИ

Изобретение относится к способам получения водных полисиликатных микрогелей. Способ получения включает смешивание водного раствора силиката щелочного металла с водной фазой материала на основе оксида кремния и дополнительного соединения. Дополнительное соединение представляет собой соль металла, отличную от соли алюминия, или органическую кислоту. Материал на основе диоксида кремния может содержать алюминий. Полученные полисиликатные микрогели используются в качестве флоккулянтов в бумажном производстве и для очистки воды. Технический результат изобретения - получение более экономически выгодным способом высококонцентрированных полисиликатных микрогелей и полисиликатных микрогелей с введенными алюминатами. 4 с. и 25 з.п.ф-лы, 7 табл.

АНТИПРИГАРНОЕ ПОКРЫТИЕ, СОДЕРЖАЩЕЕ ПО МЕНЬШЕЙ МЕРЕ ОДИН ФУНКЦИОНАЛЬНО-ДЕКОРАТИВНЫЙ СЛОЙ, И ИЗДЕЛИЕ, СНАБЖЕННОЕ ТАКИМ ПОКРЫТИЕМ

Настоящее изобретение относится к антипригарному покрытию, содержащему по меньшей мере один функционально-декоративный слой, содержащий пигментную композицию, демонстрирующую обратимое изменение оптических и/или колориметрических характеристик, когда покрытие подвергают воздействию изменения температуры между низкой температурой в диапазоне от 0°С до 40°С и высокой температурой в диапазоне от 80°С до 400°С. Также в соответствии с настоящим изобретением пигментная композиция содержит по меньшей мере одно соединение формулы YMFeQO, представленное в форме частиц, в котором М выбран из лантаноидов, щелочных металлов, щелочноземельных металлов и металлоидов со степенью окисления (СО) +3; Q выбран из группы, состоящей из лантаноидов, неметаллов со степенью окисления +4, металлов с СО +3 или +4, переходных металлов с СО +2 или +4, щелочноземельных металлов и щелочных металлов; при этом х составляет от 0 до 0,3 и y составляет от 0 до 3. 2 н. и 11 з.п. ф-лы, 3 ил., 12 табл.

Способ получения тетраметилортосиликата из кремнезёма

Изобретение относится к способу получения тетраметилортосиликата, осуществляемому в реакторе проточно-каскадного типа, синтезом из кремнеземсодержащего материала и метилового спирта, в котором растворен катализатор, при этом образующуюся в результате реакции воду удаляют из реакционной смеси с помощью картриджа с осушителем. Техническим результатом является получение предложенным способом тетраметилортосиликата из кремнезёмсодержащего материала и метанола с достижением повышенной концентрации продукта в реакционной смеси. Способ позволяет избежать образование олигомеров и последующего отложения аморфного SiOна стенках оборудования, предполагает исключение энергозатратной стадии восстановления кремнезёма до металлического кремния и обеспечивает экологическую чистоту производства вследствие отсутствия галогенов в производстве. 6 з.п. ф-лы, 4 ил., 7 пр.

СПОСОБ ПОЛУЧЕНИЯ СИЛИКАТА МЕТАЛЛА 4 ГРУППЫ И ЕГО ПРИМЕНЕНИЕ

СПОСОБ УЛУЧШЕНИЯ ЭЛЕКТРОСТАТИЧЕСКОЙ СЕПАРАЦИИ ПРИ ОБОГАЩЕНИИ РУД

... 1. Способ обогащения минерального субстрата посредством электростатической сепарации сухой смеси, содержащей проводящий компонент и непроводящий компонент, включающий стадии:перемешивания минерального субстрата и реагента для модификации электростатических свойств с образованием смеси, где, по меньшей мере, один из указанного проводящего компонента и указанного непроводящего компонента является электростатически модифицированным; иприложения электрического поля к смеси, чтобы таким образом по меньшей мере частично отделить электростатически модифицированный компонент от смеси;где реагент для модификации электростатических свойств содержит органическое соединение, выбранное из группы, состоящей из четвертичных аминов; имидазолиновых соединений; дитиокарбаматных соединений; пиридиновых соединений; пирролидиновых соединений; проводящих полимеров; полиэтилениминов; соединений формулы (IV):(IV) R-(CONH-O-X)где n в формуле (IV) равно 1-3; где R в формуле (IV) содержит от 1 до 50 атомов углерода ...

Способ получения силикатов цирнония и гафния

Positives aktives Material für sekundäre Batterie mit nichtwässrigen Elektrolyten

Kieselsäure-Metalloxidkompositteilchen und Verfahren zu deren Herstellung

Verfahren zur Herstellung eines hydrothermisch stabilen Thorium-, Plutonium- oder Uransilikat-Sols

Separierung von Silikaten, insbesondere Siliziumdioxid (SiO2) aus pflanzlichen Materialien mit Hilfe von Pilzen (Fungi)

Separierung von Silikaten, insbesondere Siliziumdioxid (SiO2) aus pflanzlichen Materialien mit Hilfe von Pilzen (Fungi). Zur Reduzierung des energetischen Aufwands und des Einsatzes von Chemikalien werden für den Erstaufschluss des pflanzlichen Materials verschiedene Formen von Pilzen und die von ihnen produzierten Enzyme genutzt. Für das neue Verfahren wird die Eigenschaft von Pilzen genutzt, dass nur sie (und Bakterien) in der Lage sind, Lignin aufspalten und verwerten zu können. Auch im Abbau von Zellulose, Hemizellulose und Keratin sind sie die wichtigsten Vertreter. Die pflanzliche Biomasse wird für das entwickelte Verfahren mit Wasser angefeuchtet. Der Feuchegrad ist dabei abhängig von der zum Einsatz kommenden Pilzart, die wiederum von der aufzuschließenden Pflanzenart bestimmt wird. Anschließend wird die feuchte pflanzliche Biomasse mit dem Pilzmyzel geimpft. In der folgenden Zeit entwickelt sich das Myzel, das eigentliche Lebewesen „Pilz”, löst durch die freigesetzten Enzyme die ...

Verfahren zur Herstellung eines magnetischen Europiumsilicats

A new process for the manufacture of lead silicate

Hydrated lead silicate suitable for a paint pigment is made by grinding a mixture of lead monoxide or hydroxide with silicic acid, preferably in a freshly precipitated gelatinous state, in water in the presence of an acid catalyst such as acetic, formic or nitric acid. The proportions are preferably such that the whole of the lead enters into combination and the final product may or may not contain a substantial amount of uncombined silica. The liquid is removed by centrifuging or filtering and the hydrated lead silicate dried, or if desired heated prior to use as a pigment, to about 250 DEG C. to remove some or all of the water of hydration. 0.5 per cent by weight of sulphuric acid, in addition to the acid catalyst may be added before, during or after grinding to prevent caking. Warming the mixture to 100 DEG C. after preliminary grinding accelerates the reaction.

Producing highly-stable hydrophobic silicates

A process for the preparation of a hydrophobic (alumino) silicate or refractory oxide comprises contacting a hydrophilic hydrous (alumino) silicate or refractory oxide with at least one hydrolysable organisilicon compound present in the vapour phase.

Novel crystalline metal oxide and process for production thereof

A crystalline metal oxide in the form of a solid solution comprising an oxide of a metal of Group II of the periodic table, titanium oxide and silicon dioxide as main components and having main peaks at about 26.7 DEG and about 20.9 DEG in its Cu-K alpha X-ray diffraction pattern (2 theta ) and a specific refractive index. The crystalline metal oxide is produced, for example, by dissolving a compound of a metal of Group II of the periodic table, a hydrolyzable organic silicon compound and a hydrolyzable titanium compound in an organic solvent, hydrolyzing said starting compounds in said solution or after said solution is added to a separately prepared solvent incapable of dissolving the reaction product, thereby to form a sol- or gel-like product, and thereafter calcining the sol- or gel-like product at a temperature and for a period of time sufficient to crystallize said product.

AMORPHOUS, SPHERICAL PARTICLES OF AN INORGANIC COMPOUND FOR USE IN DENTISTRY

Improvements in the manufacture and production of artificial plagioclase-compounds

... 282,402. Singer, F. Dec. 17, 1926, [Convention date]. Abrading-materials consisting of double silicates, similar in type to naturally-occurring plagioclase compounds, are produced by reacting the oxides, carbonates, sulphates, silicates or aluminates of divalent metals (such as magnesium, calcium, barium, strontium, zinc, and divalent iron), or mixtures thereof, with alumina and silica at temperatures below the fusion point of the mixture, and preferably at temperatures at least 50‹ C. below the fusion point, the value of the latter being taken as the softening point of the Seger-cone. The proportions of the mixture employed may be such as to correspond to the formula RO. Al2O3-2SiO2. Alumina is preferably introduced as oxide, hydroxide, silicate, double silicate free from alkali, or aluminate, and silica as quartz sand, alkaline-earth silicate, aluminium silicate, or double silicate free from alkali. In an example a mixture comprising 10-12 parts magnesium oxide, 33-43 parts alumina, and ...

METALLOSILICATES

Process for the preparation of inorganic compounds

Novel zirconium material and processes for its production and use in tanning

A dry silicated sodium zirconyl sulphate which does not gel on addition to water is prepared by reacting sodium zirconium silicate with sulphuric acid of at least 61 DEG B<\>e in a molar ratio of acid to silicate of from 1,5:1 to 2,5:1. The sodium zirconium silicate may be prepared by roasting finely-divided zircon with an approximately equimolar amount of sodium carbonate, for example, as soda ash. The silicated sodium zirconyl sulphate has a composition as follows:- .ZrO2.28%-31% (24%-30% in water-soluble ..form) .SiO2.13%-16% (1%-5% in water-soluble ..form) .SO3.34%-40% .Na2O.13%-16% .H2O.0,5%-4% The silicated sodium zirconyl sulphate may be employed for tanning (see Group VIII).

Process for preparation of lead compounds

Disclosed is a process for the preparation of lead compounds which comprises reacting lead monoxide according to the wet method with an inorganic acid or organic acid in the presence of hydroxylamine under such conditions that the initial pH value of the reaction system is not higher than 7. Lead monoxide according to the wet method has an excellent reactivity with an inorganic acid or organic acid, but it contains higher oxides such as lead dioxide and minium, which cause coloration in lead compound products. According to this process, this undesirable coloration can effectively prevented.

PROCESS FOR PREPARATION OF LEAD COMPOUNDS

A polymeric silicate material and a method of manufacturing the same

A polymeric silicate material having a substantially fibre- or flake-like microstructure is manufactured from a starting material comprising mainly natural or synthetic silicate mineral e.g., Olivine and/or Granate (garnet), having a hardness exceeding the value 6 on the Moh's hardness scale and which are compound(s) having the general formulae: 2(RIO)xSiO2 wherein RI may be the same or different and is Mg and/or Fe; and 3(RIIO)xR2IIIO3x3 SiO2 wherein RII may be the same or different and is Mg, Fe and/or Ca; and RIII is Al or Fe, by finely dividing said material to a specific surface area of at least 15,000 cm2/cm3, measured according to Blaine, and subsequently hydrothermally treating the resultant powderous starting material at a temperature of approximately 175 DEG -325 DEG C. and a pH of at least 9 in the presence of water or condensed steam.

Functional transition metal silicates (FTMS).

Process for enhancing electrostatic separation in the beneficiation of ores.

Functional transition metal silicates (FTMS).

Process for enhancing electrostatic separation in the beneficiation of ores

Process for enhancing electrostatic separation in the beneficiation of ores.

Functional transition metal silicates

Process for enhancing electrostatic separation in the beneficiation of ores

Process for enhancing electrostatic separation in the beneficiation of ores.

Process for enhancing electrostatic separation in the beneficiation of ores

Functional transition metal silicates (FTMS).

Process for enhancing electrostatic separation in the beneficiation of ores.

PROCEDURE FOR THE PRODUCTION OF SYNTHETIC SCAWTIT 6 CAO. 6 SIO2. CACO3. 2 H2O

POLYSILIKAT MIRKOGELE ONE

SILICAT SUBSTITUTING APATITES AND PROCEDURES FOR THEIR PRODUCTION

Procedure for the production of water-insoluble metal silicates

PROCEDURE FOR THE CLEANING OF ALKALI METAL SILICATE SOLUTIONS

Procedure for the production of a hohlhugelähnlich developed, predominantly or exclusive pigment consisting of SiO2

India rubber or india rubber mixture

PREPARATION OF SILICA

Zircon treatment

Production of improved microporous zirconium silicate

The present invention relates to novel microporous zirconium silicate compositions having a desired particle size distribution and methods of making those compositions. These compositions have an ideal particle size distribution for use ...

RECOVERING AND MANUFACTURING SILICIC ACID PRODUCTS

Method of producing synthetic silicates and use thereof in glass production

PREPARATION OF SYNTHETIC FRAIPONTITE

SILICIC ACID SYSTEM PIGMENT FROM ALKALI PULPING PROCESS BLACK LIQUOR

MIXED CRYSTALS, A METHOD FOR THEIR PRODUCTION, AND THE USE THEREOF

COMPOSITIONS COMPRISING INORGANIC METAL COMPOUNDS AND WATER-SOLUBLE ORGANIC SILICONE COMPOUNDS

SYNTHESIS PROCESS FOR REDOX MATERIALS COATED WITH SIZE-CONTROLLED CARBON

Procédé de synthèse de composés de formule C-Li¿x?M¿1-y?M'¿y?(XO¿4?)¿n?, où C- représente du C ponté au composé Li¿x?M¿1-y?M'¿y?(XO¿4?)¿n?, dans laquelle x, y et n sont des nombres tels que 0 <= x <= 2, 0 <= y <= 0,6, et 1 <= n <= 1,5, M est un métal de transition ou un mélange de métaux de transition de la première ligne du tableau périodique, M' est un élément de valence fixe choisi parmi Mg?2+¿, Ca?2+¿, Al?3+¿, Zn?2+¿ ou une combinaison de ces mêmes éléments et X est choisi parmi S, P et Si, par mise en équilibre dans les proportions requises d'un mélange de précurseurs, la synthèse se faisant par réaction et mise en équilibre du mélange dans les proportions requises des précurseurs, avec une atmosphère gazeuse, le procédé comportant au moins une étape de pyrolyse du composé source de carbone de manière à obtenir un composé dont la conductivité électronique, mesurée sur un échantillon de poudre compactée, à une pression de 3750 Kg.cm?-2¿, est supérieure à 10?-8¿ S.cm?-1¿. Les matériaux ...

ION CONDUCTIVE MIXED CRYSTAL

A mixed crystal of the general composition Na1+axZr2+2/3x-axSixp3-xO12-2/3x with 0.8 ? a ?0.9 and 1.8?x?2.3, has a particularly favorable favorable conductivity, particularly when a = 0.88 and x _ 2.2 ~ This makes its use desirable as the solid electrolyte in Na/S . The high density of the single phase monoclinic crystallized material, which reaches almost 3010 g/cm3, is the result of high temperature sintering, carried out in pure oxygen.

LAYERED COMPLEX METAL SILICATE COMPOSITION, THEIR PREPARATION AND USE IN HYDROCARBON CONVERSION TIONS

SOLUBLE AND COLLOIDAL SILICATES

PROCESS FOR MANUFACTURE OF COMPOSITE OXIDE

PROCESS FOR MANUFACTURE OF COMPOSITE OXIDE A novel process for the manufacture of a composite oxide is disclosed. The process comprises carrying out, in a non-aqueous medium, a condensation reaction between an organometallic compound having a structure such that the metallic element present in the compound is bonded to the organic moiety therein via an oxygen atom, and a protic acid which is capable of carrying out the condensation reaction with the organometallic compound, and is a hydroxide containing an element different from the metallic element contained in the organometallic compound. According to the above process, the composite oxide can be produced with a high level of purity but without segregation.

ION CONDUCTIVE MIXED CRYSTAL

PREPARATION OF SILICATE OR GLASS IN A FURNACE WITH BURNERS IMMERSED IN A REDUCING MEDIUM

... ²²²L'invention concerne un procédé de préparation de silicate d'un élément choisi ²parmi les alcalins, alcalino-terreux ou terre rare, comprenant une réaction ²entre de la silice et un sulfate dudit élément dans un réacteur équipé d'au ²moins un brûleur immergé dans une masse en fusion, ledit brûleur immergé étant ²alimenté par un gaz comprenant de l'oxygène, un excès de combustible réducteur ²étant introduit dans le réacteur par rapport à l'oxygène effectivement ²consommé. Le procédé permet le déroulement de la réaction de façon ²satisfaisante et à relativement basse température.² ...

THERMAL AND ENVIRONMENTAL BARRIER COATING COMPOSITIONS

A coated substrate is provided that comprises: a substrate; and a barrier coating comprising a compound having the formula: Ln2ABOs, where Ln comprises scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, or mixtures thereof; A comprises Si, Ti, Ge, Sn, Ce, Hf, Zr, or a combination thereof; and B comprises Mo, W, or a combination thereof. In one embodiment, B comprises Mo.

METHOD FOR PRODUCING LITHIUM-CONTAINING COMPLEX OXIDE

Disclosed is a method for producing a lithium-containing complex oxide represented by general formula (1) below, which comprises at least: a step for preparing a solution by dissolving starting materials, namely, a lithium source, an element M source, a phosphorus source and an element X source into a solvent, wherein the phosphorus source is added after dissolving at least the element M source; a step for gelatinizing the thus-obtained solution; and a step for firing the thus-obtained gel. The method is capable of providing a positive electrode active material for a lithium secondary battery, said positive electrode active material being excellent from the aspects of safety and cost and capable of extending the life of the battery. LixMyP1-zXzO4 (1) (In the formula, M represents at least one element that is selected from the group consisting of Fe, Ni, Mn, Zr, Sn, Al and Y; X represents at least one element that is selected from the group consisting of Si and Al; and x, y and z respectively ...

CATHODE ACTIVE MATERIAL CONTAINING LITHIUM, CATHODE CONTAINING LITHIUM, AND NONAQUEOUS SECONDARY BATTERY CONTINING LITHIUM

... ²A nonaqueous secondary battery of the present invention is ²a nonaqueous secondary battery, comprising: a cathode ²including: a cathode active material; a conductive material; ²and a binder, the cathode active material having a ²composition represented by General Formula (1) below,²LiFe1-x M x P1-y Si y O4 ... (1),²where: an average valence of Fe is +2 or more; M is an ²element having a valence of +2 or more and is at least one ²type of element selected from the group consisting of Zr, Sn, ²Y, and Al; the valence of M is different from the average ²valence of Fe; 0 < x .ltoreq. 0.5; and 0 < y < 1.0, the conductive ²material being a material selected from the group consisting ²of acetylene black, carbon, graphite, natural graphite, ²artificial graphite, and needle coke.² ...

METHOD OF PRODUCING SYNTHETIC SILICATES AND USE THEREOF IN GLASS PRODUCTION

A method is disclosed of producing a synthetic silicate. The method is advantageous in providing material useful in glass making. Such method involves the reaction of calcium oxides and magnesium oxides, water and sodium silicates. The glass formation is performed at a lower temperature than usual and performed with a lower amount of volatile gas release. Less cristobalite formation in the glass occurs. The synthetic silicate produced can be a cylindrical pellet.

Verfahren zur Herstellung von bleisilikathaltigen Massen.

Verfahren zur Herstellung von feinteilige Kieselsäure enthaltenden Stoffen.

Procédé de préparation d'une solution aqueuse de silicate d'ammonium.

Procédé de préparation d'une solution aqueuse de silicate d'ammonium

Silikatfaser

Verfahren zur Herstellung von dibasischen Bleisalzen anorganischer Säuren

Procédé de préparation de silicates synthétiques

Verfahren und Vorrichtung zur Verdichtung von pulverförmigen Stoffen

Catalyst for oxidn of olefines to unsatd aldehydes

Catalyst for the oxidation of C3-4, olefins to unsatd. aldehydes consisting of a mixture of silicon dioxide with the oxides of molybdenum oxide, bismuth oxide and, if desired, phosphorum oxide is prepared by converting a silicon-oxygen compound into the gas phase and introducing precursors for the oxides of molybdenum, bismuth and phosphorus into the gaseous silicon-oxygen compound. The precursors are atomised through a fine nozzle and introduced into the gaseous compound at above 1000 deg.C, preferably above 1400 deg.C. Silicon dioxide, silicon monoxide or a mixture of these oxides may be used as the silicon-oxygen compound. Preferably oxygen or air is supplied with the molybdenum, bismuth and phosphorus precursors.

Verfahren zum Hydrophobieren von feinverteilten anorganischen Verbindungen

Verfahren zur Herstellung eines magnetischen Materials

Verfahren zur Herstellung von festen hochdispersen anorganischen, Siliciumdioxyd enthaltenden Mischungen

Procédé de préparation d'une composition contenant une source d'ions d'hypochlorite

Metal oxide particle prodn. - for use in nuclear fuel elements

Metal contng. materials are produced by (a) adding a polymeric organic substance to a soln. of a soluble metal salt, to give a viscous soln. contg. a complex of the metal ions and the polymer; (b) converting the viscous soln. to a chosen physical configuration; and (c) treating the configuration with a soln. which precipitates the metal as an insoluble compound. The process may be used for the prepn. of particles of oxides or carbides of Cl, Pt, or Th, for use as fissionale elements in nuclear reactors. In addn., the process can be used in powder metallurgy, and for the prodn. of metal cpds. in other than granular form.

Process for preparing synthetic scawtite 6CaO.6SiO2.CaCO3.2H2O

Solid-state ion conductor

Solid-state ion conductor, especially as a solid electrolyte in the Na/S battery having the following gross composition: AyB2- delta C3O12, in which A = lithium, sodium or potassium, B = zirconium or mixture zirconium/other metal having a valency of at least 2, C = silicon, mixture silicon/phosphorus or mixture silicon/other 3-, 4- or 5-valent element, O = oxygen and the indices delta and y satisfy the condition y + (2- delta )wB + 3 wC = 24 in which wB and wC represent mean valencies of the elements or mixtures of the elements B and C, respectively, and elements or mixtures of the elements A, B and C are chosen in such a way that 0< delta <2
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НОВЫЕ ФУНКЦИОНАЛЬНЫЕ СИЛИКАТЫ ПЕРЕХОДНЫХ МЕТАЛЛОВ (FTMS)

Настоящее изобретение предусматривает функциональный силикат переходного металла (FTMS), эффективный в качестве дезактиватора, дезинфектанта, детоксификанта, протектанта, микробицида или их сочетания, содержащий отношение переходного металла к окиси кремния в силикате переходного металла в заданных пределах, и структурную композицию для указанной эффективности, указанный FFMS способен к иммобилизации на соответствующих материалах или включению в смолы и/или покрытия вместе со смолами на соответствующих материалах.

ОДНОФАЗНОЕ ГИДРАВЛИЧЕСКОЕ ВЯЖУЩЕЕ ВЕЩЕСТВО, СПОСОБ ЕГО ПОЛУЧЕНИЯ И СТРОИТЕЛЬНЫЙ МАТЕРИАЛ НА ЕГО ОСНОВЕ

Изобретение относится к однофазному гидравлическому вяжущему веществу, которое отличается тем, что включает атомы кремния, кальция, кислорода и водорода в таком расположении, которое включает силикатные структурные звенья, имеющие среднюю степень сшивки более Q1'5, и силанольные группы, при этом атомы кальция не замещены или частично замещены атомами металла M[6]x+, шестикратно или более координированными с кислородом, и/или атомы кремния не замещаются или частично замещаются атомами металла M[4]y+, которые тетраэдрически координированы с атомами кислорода; а также молярное отношение имеет значение 0,2-2,0 и вяжущее вещество содержит 3,5-20 мас.% H2O, а также к смеси, включающей это вяжущее вещество. Кроме того, изобретение относится к способам получения указанного вяжущего вещества или смеси, включающей данное вяжущее вещество, путем реакционного измельчения исходного материала, состоящего из силикатных структурных звеньев со степенью сшивки Q0-Q2, и, возможно, других материалов с твердым ...

НЕОРГАНИЧЕСКИЕ ОКСИДЫ С МЕЗОПОРИСТОСТЬЮ ИЛИ СОЧЕТАНИЕМ МЕЗО- И МИКРОПОРИСТОСТИ И СПОСОБ ИХ ПОЛУЧЕНИЯ

... 1. Способ получения неорганического оксида, который содержит микро- и мезопоры, включающий выдержку при повышенной температуре смеси, содержащей воду, неорганический оксид и по меньшей мере одно соединение, которое связывается с неорганическим оксидом посредством водородных связей, причем эту выдержку осуществляют при температуре и в течение времени, обеспечивающих получение неорганического оксида, который содержит как микропоры, так и мезопоры. 2. Способ по п.1, в котором упомянутое соединение представляет собой триэтаноламин, сульфолан, тетраэтиленпентамин, диэтилгликольдибензонат или гликоль. 3. Способ по п.2, в котором упомянутое соединение представляет собой гликоль. 4. Способ по п.1, в котором смесь далее включает образующий микропоры агент. 5. Способ по п.4, в котором образующий микропоры агент представляет собой соль четвертичного аммония. 6. Способ по п.4, в котором неорганический оксид представляет собой аморфный силикат. 7. Способ по п.6, в котором нагревание включает выдержку ...

PROCESS FOR ENHANCING ELECTROSTATIC SEPARATION IN THE BENEFICIATION OF ORES

Anode active material, anode and nonaqueous secondary battery

An anode active material of the present invention is a anode active material having a composition represented by General Formula (1) below, LiFe1-xMxP1-ySiyO4 (1), where: an average valence of Fe is +2 or more; M is an element having a valence of +2 or more and is at least one type of element selected from the group consisting of Zr, Sn, Y, and Al; the valence of M is different from the average valence of Fe; 0 Подробнее

Porous silicon-containing carbon-based composite material, electrode composed of the same and battery

Disclosed is a porous silicon-containing carbon-based composite material obtained by carbonizing both (1) silicon metal or a silicon-containing compound and (2) an organic compound not containing silicon and having a softening point or melting point in an inert gas or in a vacuum at 300-1500 DEG C. This porous silicon-containing carbon-based composite material can be used as an electrode of a battery. By using this porous silicon-containing carbon-based composite material, a battery having high reversible capacity, stable charge/discharge cycle characteristics and small potential loss at the time when lithium is discharged can be produced by a simple production process.

Method of removing heavy metal from silicate source during silicate manufacturing

The present invention provides methods for the removal of lead from a metal silicate during the process of manufacturing of such a material are provided. With the reliance upon lower cost starting silicon dioxide starting materials that are known to exhibit elevated amounts of heavy metal therein for the purpose of producing metal silicates (such as sodium silicate, as one example), it has been realized that removal of significant amounts of such heavy metals is necessary to comply with certain regulatory requirements in order to provide a finished material that exhibits the same low level ofheavy metal contamination as compared with finished materials that are made from more expensive, purer starting silicon dioxides. Two general methods may be followed for such decontamination purposes. One entails the introduction of a calcium phosphate material, such as dicalcium phosphate, tricalcium phosphate, and/or hydroxyapatite, to a formed metal silicate solution but prior to filtering. The other ...

Protective film material and magnetic head comprising protective film made of material

Synthetic silicates and their preparation

Preparation of solutions of a mixed oxide containing tin and silicon.

METHOD FOR OBTAINING REFRACTORY METAL OXIDES SILICA-BASED SOL-GEL IN AN AQUEOUS MEDIUM.

PROCEDE D'OBTENTION DE SILICE ET SILICATES METALLIQUES A PARTIR DE SOLUTIONS DE SILICATES ALCALINS, PRODUITS OBTENUS ET APPLICATIONS, NOTAMMENT EN VERRERIE

LA PRESENTE INVENTION A TRAIT A UN PROCEDE DE FABRICATION DE SILICE ET DE SILICATES METALLIQUES PAR TRAITEMENT D'UNE SOLUTION AQUEUSE DE SILICATES ALCALINS PAR UN LIQUIDE ORGANIQUE POLAIRE MISCIBLE A L'EAU. IL SE CARACTERISE PAR LE FAIT QUE L'ON REALISE UNE SOLUTION ORGANIQUE, DU GROUPE DES OXYDES A LAQUELLE ON AJOUTE LA SOLUTION DE SILICATE(S) ALCALIN(S). LE PROCEDE S'APPLIQUANT EN PARTICULIER AUX PRODUITS POUR VERRERIE.

NEW CERAMICS USABLE AS a MATERIAL Of ANODE FOR COMBUSTIBLE BATTERY OF TYPE SOFC

New product aluminosilicate, its method of preparation and its applications

RELEASE COATING COMPRISING AT LEAST ONE LAYER OF DECORATION AND FUNCTIONAL ARTICLE PROVIDED WITH SUCH A COATING

Process of using conditioning of radioactive waste of the apatites silicated like matrix deconfinement

L'invention concerne un procédé de conditionnement de déchets radioactifs utilisant des apatites silicatées comme matrice de confinement. Ce procédé consiste à incorporer les déchets (1) dans une matrice de confinement (3) à base d'apatite silicatée. Lorsque les déchets sont des lanthanides et/ou des actinides, ils peuvent faire partie de la structure chimique de l'apatite qui répond par exemple à la formule: (CF DESSIN DANS BOPI) dans laquelle M est un métal alcalin, Ln est une terre rare, A est un actinide, X est O2 - , S2 - , 2F- , 2Cl- , 2Br- , 2I- ou 2OH- .

Preparation of mixed oxide solutions based on tin and silicon

La présente invention concerne un procédé pour préparer un oxyde d'étain et de silicium, sous forme d'un sol permettant d'obtenir des solutions aqueuses d'un pH voisin de la neutralité. Le procédé consiste en une méthode sol-gel, avec une étape de peptisation du gel en présence d'une base telle que l'ammoniaque. Application à l'obtention de couches antistatiques.

New crystalline complex of synthetic and proceeded zeolite for its preparation.

Process for the calcination of loads of silicic acid and silicates

Metal silicate made for use in the prodn. of vitreous prods. - esp. lead-potassium silicate employed in mfg. glass, enamels or pigments

PROCEEDED OF PREPARATION Of a GEOPOLYMERE POROSITY CONTROLEE, the GEOPOLYMERE THUS OBTAINED AND ITS VARIOUS APPLICATIONS HAS

La présente invention concerne un procédé de préparation d'un géopolymère à porosité contrôlée comprenant une étape de dissolution/polycondensation d'une source alumino-silicatée dans une solution d'activation pouvant éventuellement contenir des composants silicatés, caractérisé en ce qu'il comprend une étape consistant à sélectionner une valeur ou un élément pré-déterminé(e) pour au moins un paramètre choisi parmi la quantité totale d'eau, la quantité totale de silice, le cation de compensation et la distribution granulométrique des éventuels composants silicatés. La présente invention concerne un géopolymère susceptible d'être préparé par ledit procédé et présentant une mésoporosité ou une macroporosité monomodale et de distribution porale plus ou moins étendue ainsi que les différentes utilisations dudit géopolymère.

Vapor deposition of metal oxides, silicates and phosphates, and silicon dioxide

Metal silicates or phosphates are deposited on a heated substrate by the reaction of vapors of alkoxysilanols or alkylphosphates along with reactive metal amides, alkyls or alkoxides. For example, vapors of tris(tert-butoxy)silanol react with vapors of tetrakis(ethylmethylamido)hafnium to deposit hafnium silicate on surfaces heated to 300° C. The product film has a very uniform stoichiometry throughout the reactor. Similarly, vapors of diisopropylphosphate react with vapors of lithium bis(ethyldimethylsilyl)amide to deposit lithium phosphate films on substrates heated to 250° C. Supplying the vapors in alternating pulses produces these same compositions with a very uniform distribution of thickness and excellent step coverage.

REFRACTORY FILLER, SEALING MATERIAL USING SAME, AND MANUFACTURING METHOD FOR REFRACTORY FILLER

Provided is a manufacturing method for a refractory filler, comprising melting a raw material batch and cooling the resultant melt to precipitate willemite as a main crystal phase. 1. A manufacturing method for a refractory filler , comprising:melting a raw material batch; andcooling the melt to precipitate willemite as a main crystal phase.2. The manufacturing method for a refractory filler according to claim 1 , wherein the cooling of the melt comprises pouring the melt between forming rollers.3. The manufacturing method for a refractory filler according to claim 1 , wherein the cooling of the melt comprises pouring the melt into water.4. The manufacturing method for a refractory filler according to claim 1 , further comprising preparing the raw material batch so that the refractory filler comprises claim 1 , as a composition in terms of mol % claim 1 , 50 to 80% of ZnO claim 1 , 10 to 40% of SiO claim 1 , and 0 to 10% of AlO.5. The manufacturing method for a refractory filler according to claim 1 , wherein the raw material batch has an average particle diameter Dof less than 20 μm.6. The manufacturing method for a refractory filler according to claim 1 , wherein the raw material batch has a maximum particle diameter Dof less than 100 μm.7. The manufacturing method for a refractory filler according to claim 1 , wherein the willemite and gahnite are precipitated as the main crystal phase.8. The manufacturing method for a refractory filler according to claim 7 , wherein a ratio of the willemite to the gahnite falls within a range of 100:0 to 70:30 in terms of molar ratio.9. A refractory filler claim 1 , which is produced by the manufacturing method according to .10. A refractory filler having willemite precipitated therein as a main crystal claim 1 , which is produced by melting a raw material batch and cooling the resultant melt.11. A sealing material claim 1 , comprisingglass powder; anda refractory filler,{'claim-ref': {'@idref': 'CLM-00010', 'claim 10'}, ' ...

METHOD FOR PREPARING A COMPOSITION INCLUDING SYNTHETIC INORGANIC PARTICLES

A method for preparing a composition including synthetic mineral particles, in which: a hydrogel that is a precursor of the synthetic mineral particles is prepared, and the hydrogel is subjected to a hydrothermal treatment, characterized in that at least one step of the hydrothermal treatment is carried out with the addition of at least one carboxylate salt to the treatment medium, the carboxylate salt having the formula R—COOM′, where M′ denotes a metal selected from the group consisting of Na and K, and R is selected from H and the alkyl groups that include fewer than 10 carbon atoms. 118-. (canceled)19. A method for preparing a composition comprising synthetic mineral particles , in which:a hydrogel precursor of said synthetic mineral particles is prepared,said hydrogel precursor is subjected to a hydrothermal treatment,wherein at least one step of said hydrothermal treatment is carried out with the addition of at least one carboxylate salt to the treatment medium, said carboxylate salt having the formula R—COOM′ in which:M′ denotes a metal chosen from the group formed of Na and K, andR is chosen from H and alkyl groups having fewer than 10 carbon atoms.20. The method as claimed in claim 19 , wherein R is chosen from the group formed of H— claim 19 , CH— and CH—CH—CH—.21. The method as claimed in claim 19 , wherein said synthetic mineral particles are silicate mineral particles.22. The method as claimed in claim 19 , wherein said synthetic mineral particles are phyllosilicate mineral particles.24. The method as claimed in claim 19 , wherein said at least one carboxylate salt of the formula R—COOM′ is added to said treatment medium so that it has claim 19 , based on said hydrogel precursor of said synthetic mineral particles claim 19 , a molar ratio R—COOM′/hydrogel of from 0.4 to 100.25. The method as claimed in claim 21 , wherein said at least one carboxylate salt of the formula R—COOM′ is added to said treatment medium so that it has claim 21 , based on silicon ...

Li-CONTAINING SILICON OXIDE POWDER AND PRODUCTION METHOD THEREOF

There is produced a Li-containing silicon oxide powder containing a crystallized lithium silicate that is mostly water-insoluble LiSiOand containing little crystalline Si. This object is attained through the mixing of a lower silicon oxide powder represented by a compositional formula SiO(0.5 Подробнее

COMPOSITE OXIDE POWDER AND METHOD FOR PRODUCTION THEREOF

Composite oxide fine particles are produced by sol-gel method under conditions in which coarse particles and aggregated particles are unlikely to be generated, and the composite oxide fine particles are further wet-filtered using a filter to remove the coarse particles and the aggregated particles. Then, a salt is added to a dispersion of the composite oxide fine particles to produce weak aggregates of the composite oxide fine particles in the dispersion. A solid content is separated from the dispersion of the composite oxide fine particles containing the aggregates, and then dried. The solid content is easily made finer because no firm aggregates are generated during the drying. That is, composite oxide fine particles containing no coarse particles and aggregated particles are obtained. Use of a known cracking means can further reduce the amount of coarse particles. 17-. (canceled)8. A silica-based composite oxide powder comprising:a composite oxide of silicon and at least one metal selected from the group consisting of titanium and zirconium, the silica-based composite oxide powder having a volume-based cumulative 50% diameter measured by a laser diffraction scattering method in a range of 0.05 μm to 2.0 μm, and a coefficient of variation of 40% or less, whereinin a 5 mass % dispersion of the silica-based composite oxide powder obtained by ultrasonic irradiation (at an output of 40 W for 10 minutes), a content of particles having a particle diameter of 5 μm or more in a particle size distribution obtained by a Coulter counter method is 10 ppm or less on a number basis.9. The silica-based composite oxide powder of claim 8 , whereina content of particles having a particle diameter of 3 μm or more in the particle size distribution obtained by the Coulter counter method is 10 ppm or less on a number basis.10. A surface-treated silica-based composite oxide powder claim 8 , obtained by surface-treating the silica-based composite oxide powder of with a silylating agent ...

Method for Preparation of a Group 4 Metal Silicate and Use Thereof

The invention provides a method for the preparation of an amorphous silicate of at least one metal from the Group 4 of the Periodic Table of Elements with a total pore volume of at least 0.3 mL/g. The method of preparation involves the use of pore shaping conditions, which can be the use of a pore shaper and optionally an increased precipitation temperature, e.g. at least 60° C. The silicate of the invention is especially suitable in catalytic reactions such as esterifications, Michael additions, transesteritications, (ep)oxidations, hydroxylations, or in absorbance of small inorganic and organic molecules e.g. CO 2 or aromatic compounds.

METHOD FOR FABRICATING A TITANIUM-CONTAINING SILICON OXIDE MATERIAL WITH HIGH THERMAL STABILITY AND APPLICATIONS OF THE SAME

The present invention discloses a method for fabricating a titanium-containing silicon oxide material with high thermal stability and applications of the same, wherein a titanium source, a silicon source, an alkaline source, a template molecule and a peroxide are formulated into an aqueous solution; the aqueous solution reacts to generate a solid product; the solid product is separated from the aqueous solution with a solid-liquid separation process and dried; the solid product is calcined to obtain a titanium-containing silicon oxide material with high specific surface area. The titanium-containing silicon oxide material fabricated by the present invention has high thermal stability. Therefore, it still possesses superior catalytic activity after calcination. The titanium-containing silicon oxide material can be used to catalyze epoxidation of olefin and is very useful in epoxide production. 1. A method for fabricating a titanium-containing silicon oxide material with high thermal stability , comprising steps:mixing a titanium source, a silicon source, an alkaline source, a template molecule, a solvent and a peroxide to form an aqueous solution;after said aqueous solution have reacted, undertaking a solid-liquid separation process of said aqueous solution, and undertaking a drying process of a solid product separated from said aqueous solution; and {'br': None, 'i': x', 'x, 'sub': 2', '2, 'TiO(1−)SiO\u2003\u2003(I)'}, 'undertaking a calcination process of said solid product acquired in said solid-liquid separation process to obtain a titanium-containing silicon oxide material having Formula (I) in an anhydrous statewherein x ranges from 0.00001-0.5;wherein said titanium-containing silicon oxide material has an average pore size of 10 angstroms or more;wherein said titanium-containing silicon oxide material has a pore size of 90% or more of the total pore volume of 5 to 200 Å; and{'sup': '3', 'wherein said titanium-containing silicon oxide material has a specific ...

Process for Improving the Grade and Optical Quality of Zircons

A process for improving the grade and optical quality of zircon, comprising: baking a mixture of a zircon feed and concentrated sulphuric acid at a baking temperature in the range of from 200 up to 400° C., and for a time to form water leachable sulphates with impurities therein including at least iron and titanium; leaching the baked mixture to dissolve the leachable sulphates; and separating the zircon from the leachate containing the leached sulphates, which separated zircon is thereby of improved grade and optical quality.

METAL COMPLEX AND SUPPORTED METAL COMPLEX HAVING DISILOXANE AS LIGAND, METHOD FOR PRODUCTION THEREFOF, AND SUPPORTED METAL CATALYST PREPARED BY USING THE SAME

A metal complex represented by the following Formula (1): 3. The supported metal complex according to claim 2 , wherein the inorganic oxide is silica or a composite oxide containing silicon.4. A method for producing the metal complex as defined in claim 1 , comprising reacting a metal complex LMX(wherein M represents palladium or platinum; L represents a ligand selected from carbon monoxide claim 1 , an olefin compound claim 1 , an amine compound claim 1 , a phosphine compound claim 1 , an N-heterocyclic carbene compound claim 1 , a nitrile compound and an isocyanide compound; n represents an integer of 0 to 2 showing the number of the ligand; and X represents halogen or a hydroxyl group) with a disiloxane compound HO—(R)(R)Si—O—(R)(R)Si—OH (each of Rto Rrepresents an organic group) in the presence of an alkaline metal hydride.6. A supported metal catalyst obtained by applying a heat treatment to the supported metal complex as defined in at a temperature of the range from 80 to 600° C. under an oxygen atmosphere.7. A catalyst for hydrogenation reaction of olefins claim 6 , comprising the supported metal catalyst as defined in .8. The catalyst for hydrogenation reaction according to claim 7 , wherein a central metal of the catalyst is platinum.9. A catalyst for hydrosilylation reaction of olefins claim 1 , comprising the metal complex compound as defined in .10. A catalyst for hydrosilylation reaction of olefins claim 2 , comprising the supported metal complex as defined in .11. The catalyst for hydrosilylation reaction according to claim 9 , wherein a central metal of the catalyst is platinum. 1. Technical FieldThe present invention relates to a metal complex having a skeletal structure in which a disiloxane group is coordinated as a chelate to a central metal. Further, the present invention relates to a supported metal complex obtained by fixing the metal complex on an inorganic oxide while retaining a skeletal structure thereof, and a method for producing the same ...

METHOD FOR PREPARING CERAMIC MATERIAL

Disclosed are a method for preparing a ceramic material including a compound of a formula of ABOand a ceramic material prepared by the method. The method includes: mixing a first oxide of AOand a second oxide of BOto obtain a mixture, ball-milling the mixture until a particle size of the mixture is not greater than 1 μm with a medium selected from a group consisting of ethanol, acetone, deionized water and a combination thereof, to obtain a powder, drying the powder at a temperature in a range of 60 to 80° C., and sintering the powder with a laser irradiation having a laser wavelength of 980 nm, an irradiation power ranging from 50 to 1500 W and an irradiation period of 3 s to 8 min to obtain the ceramic material. 1. A method for preparing a ceramic material comprising a compound of a formula of ABO , where A is at least one of Sc , Y , La , Nd , Eu , Gd , Dy , Er , Yb and Lu , B is at least one of Ti , Zr , Ce and Hf , 2≤x≤10 , 7≤y≤20 , and 0≤y/x≤3.5 , the method comprising:{'sub': m', 'n, 'mixing a first oxide of AOand a second oxide of BOto obtain a mixture,'}ball-milling the mixture until a particle size of the mixture is not greater than 1 μm with a medium selected from a group consisting of ethanol, acetone, deionized water and a combination thereof, to obtain a powder,drying the powder at a temperature in a range of 60 to 80° C., andsintering the powder with a laser irradiation having a laser wavelength of 980 nm, an irradiation power ranging from 50 to 1500 W, a spot diameter ranging from 10 to 15 mm and an irradiation period of 3 s to 8 min to obtain the ceramic material.2. The method according to claim 1 , wherein the ball-milling is performed at a ball-milling speed of 400 rpm for a period ranging from 8to 24 h.3. The method according to claim 1 , wherein after the powder is obtained claim 1 , the method further comprises a granulation process comprising:preparing an aqueous binder solution being of 1 to 10% of a binder by mass,dividing the aqueous binder ...

Process For Extracting Values from Lithium Slag

A process for extracting values from lithium slag comprising: (a) hydrothermally treating lithium slag with an aqueous solution of an alkaline compound at selected temperature and duration; (b) performing an ion exchange step on the alkaline treated lithium slag; and (c) recovering values selected from the group consisting of aluminium compounds, silicon compounds and compounds containing silicon and aluminium.

METHODS AND DEVICES FOR GROWING OXIDE CRYSTALS WITHOUT ANNEALING

The present disclosure discloses a method for growing a crystal without annealing. The method may include compensating a weight of a reactant, introducing a flowing gas, improving a volume ratio of oxygen during a cooling process, providing a heater in a temperature field, and optimizing parameters. According to the method, problems may be solved, for example, cracking and component deviation of the crystal during a crystal growth process, and without oxygen-free vacancy. The method for growing the crystal may have excellent repeatability and crystal performance consistency. 3. A crystal , a formula of the crystal being (AB)(PQ)O , whereinA consists of at least one of Gd, Lu, La, Yb, Sc, or Y,B consists of at least one of Ce, Na, K, Cu, Ag, Mg, Ca, Zn, Sr, Gd, B, Al, Ga, V, Cr, Mn, Fe, Co, Ni, Ti, Ge, Zr, Sn, Hf, La, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb, Y, Pm, or Lu,P consists of at least one of Al, Ga, In, or Sc, andQ consists of Al; andb=0˜1, q=0˜1.4. The crystal of claim 3 , whereinA consists of Gd, B consists of Ce, P consists of Ga, and{'sub': 1-b', 'b', '3', '1-4', 'q', '5', '12, 'the formula of the crystal is (GdCe)(GaAl)O.'}510-. (canceled)11. A method for growing a crystal claim 3 , comprising:weighting reactants based on a molar ratio of the reactants according to a reaction equation for generating the crystal after a first preprocessing operation is performed on the reactants, wherein the first preprocessing operation includes a roasting operation under 800° C.˜1400° C.; the second preprocessing operation includes at least one of an the reactants mixing operation or a pressing operation at room temperature; and', 'the assembly processing operation includes at least one of a coating operation, an acid soaking and cleaning operation, or an impurity cleaning operation;, 'placing the reactants, on which a second preprocessing operation has been performed, into a crystal growth device after an assembly preprocessing operation is performed on at least one ...

Titanium Stannate Silicate, Method of Preparation and Use Thereof

The present invention relates to an amorphous titanium stannate silicate with the general formula: MTiSiSnO, wherein M is proton, ammonium, a metal or a mixture of metals, wherein v is the valence of M being a positive integer, and wherein x, y, z and w are molar ratios: x is 1, y is from 0.01 to 99, z is from 0.01 to 99, and w is from 0.01 to 50. The described titanium stannate silicates are particularly useful in catalysis and adsorption. 2. The titanium stannate silicate according to claim 1 , wherein M is at least one of proton claim 1 , ammonium claim 1 , Na claim 1 , Li claim 1 , K claim 1 , Cs claim 1 , Ca claim 1 , Mg claim 1 , Sr claim 1 , Ba claim 1 , Fe(II) claim 1 , Fe(III) claim 1 , Sn(II) claim 1 , Ce claim 1 , La claim 1 , Nb claim 1 , Ni claim 1 , V claim 1 , W claim 1 , Mo claim 1 , Al claim 1 , Zn claim 1 , Cu claim 1 , Mn.3. The titanium stannate silicate according to claim 1 , wherein y is in the range of 0.1-10.4. The titanium stannate silicate according to claim 1 , wherein z is in the range of 0.03-5.5. The titanium stannate silicate according to claim 1 , wherein w is in the range 0.1-10.6. The titanium stannate silicate according to claim 1 , wherein said titanium stannate silicate has a pore volume of at least 0.3 mL/g claim 1 , determined by liquid nitrogen adsorption.7. The titanium stannate silicate according to claim 1 , wherein said titanium stannate silicate has an average pore diameter of at least 40 Å claim 1 , determined by liquid nitrogen adsorption.8. The titanium stannate silicate according to having a form of powder claim 1 , tablets claim 1 , granules or extrudate.9. A method for titanium stannate silicate preparation claim 1 , the method comprising:reacting a soluble silicate source, a soluble stannate source and a soluble titanium source in an aqueous medium to form titanium stannate silicate,percipitaing the titanium stannate silicate, andisolating the titanium stannate silicate.10. The method according to claim 9 , further ...

Method for Preparation of a Group 4 Metal Silicate and Use Thereof

The invention provides a method for the preparation of an amorphous silicate of at least one metal from the Group 4 of the Periodic Table of Elements with a total pore volume of at least 0.3 mL/g. The method of preparation involves the use of pore shaping conditions, which can be the use of a pore shaper and optionally an increased precipitation temperature, e.g. at least 60° C. The silicate of the invention is especially suitable in catalytic reactions such as esterifications, Michael additions, transesterifications, (ep)oxidations, hydroxylations, or in adsorbance of small inorganic and organic molecules e.g. COor aromatic compounds. 113-. (canceled)15. The method according to claim 14 , wherein the pore shaping conditions further consists of the use of a temperature of at least 60° C. during the precipitation in step (b).16. The method according to claim 14 , wherein the pore shaper is a soluble salt of M claim 14 , wherein M is selected from the group consisting of a proton claim 14 , ammonium claim 14 , a metal cation and combinations thereof.17. The method according to claim 16 , wherein M is selected from the group consisting of a proton claim 16 , ammonium claim 16 , Na claim 16 , Li claim 16 , K claim 16 , Cs claim 16 , Ca claim 16 , Mg claim 16 , Sr claim 16 , Ba claim 16 , Fe claim 16 , Sn claim 16 , Ce claim 16 , La claim 16 , Nb claim 16 , Ni claim 16 , V claim 16 , W claim 16 , Mo claim 16 , Al claim 16 , Ag claim 16 , Zn claim 16 , Cu claim 16 , Mn cations claim 16 , and combinations thereof.18. The method according to claim 14 , wherein said non-halide salt is selected from the group consisting of phosphate claim 14 , biphosphate claim 14 , phosphite claim 14 , biphosphite claim 14 , sulfate claim 14 , bisulfate claim 14 , sulfite claim 14 , bisulfite claim 14 , nitrate claim 14 , nitrite claim 14 , carbonate claim 14 , bicarbonate claim 14 , formate claim 14 , acetate and citrate.19. The method according to claim 14 , wherein T is selected from the ...

ENVIRONMENTAL BARRIER

A powder formed of fused particles. More than 95% by number of the feed particles exhibiting a circularity of greater than or equal to 0.85. The powder contains more than 88% of a silicate of one or more elements chosen from Zr, Hf, Y, Ce, Sc, In, La, Gd, Nd, Sm, Dy, Er, Yb, Eu, Pr, Ho and Ta, less than 10% of a dopant, as percentage by weight based on the oxides. The powder has a median particle size Dof less than 15 μm, a 90 percentile particle size, D, of less than 30 μm, and a size dispersion index (D-D)/Dof less than 2. The powder has a relative density of greater than 90%. The Dpercentiles of the powder are the particle sizes corresponding to the percentages, by number, of n %, on the cumulative distribution curve of the size of the particles of the powder. The particle sizes are classified in increasing order. 2. The powder as claimed in claim 1 , exhibiting:a percentage by number of particles having a size of less than or equal to 5 μm which is greater than 5%, and/or{'sub': '50', 'a median particle size Dof less than 10 μm, and/or'}{'sub': '90', 'a 90 percentile particle size Dof less than 25 μm, and/or'}{'sub': '99.5', 'a 99.5 percentile particle size Dof less than 40 μm, and/or'}{'sub': 90', '10', '10, 'a size dispersion index (D−D)/Dof less than 1.5.'}3. The powder as claimed in claim 1 , wherein the median particle size Dis less than 8 μm.4. The powder as claimed in claim 1 , said element being Y and/or Yb and/or Sc and/or Er.5. The powder as claimed in claim 1 , said dopant being chosen from the group consisting of the oxides of an element chosen from aluminum claim 1 , silicon claim 1 , alkali or alkaline earth metals; iron oxides; LiYO; mullite; barium and/or strontium aluminosilicate; and yttrium aluminum oxide composites.6. A method for manufacturing a powder as claimed in claim 1 , said method comprising the following steps:{'sub': '50', 'a) granulation of a particulate feedstock so as to obtain a powder formed of granules having a median size D′ ...

DEVICE AND METHOD OF PREPARING SIOX, AND SIOX ANODE MATERIAL

The present invention relates to a device and a method of preparing a SiOx, and a SiOx anode material, and more particularly, to a device and a method of preparing a SiOx, in which a SiOx is prepared by reacting liquid silicon and solid silicon dioxide in one or more crucibles, and a metal raw material is simultaneously supplied during SiOx preparing to continuously prepare a metal-SiOx in a single process, and a SiOx anode material. 1. A device for preparing a SiOx , comprising:one or more crucibles configured to provide a space in which a raw material is accommodated;a reaction unit inside which the crucible is located;a heater configured to heat the reaction unit; anda deposition unit configured to deposit a gas generated in the reaction unit,{'sup': '2', 'wherein the raw material is liquid silicon and solid silicon dioxide, and SiOx gas is generated by a liquid-solid reaction of the liquid silicon and the solid silicon dioxide, and a pore area of the solid silicon dioxide in a pore size range of 1.7 nm to 300 nm calculated through a Barrett-Joyner-Halenda (BJH) gas phase adsorption-desorption analysis is 200 m/g or more and an average pore size of the analyzed through desorption solid silicon dioxide after the BJH gas phase adsorption is 5 nm or less.'}2. The device of claim 1 , further comprising:a metal chamber in which a metal raw material is located,wherein the metal raw material is metal and/or a metal compound, and the metal raw material is phase-transited to metal gas by heating, and metal-SiOx gas is generated by reacting the metal gas and the SiOx gas.3. The device of claim 2 , wherein the metal includes one or more of silicon claim 2 , aluminum claim 2 , calcium claim 2 , potassium claim 2 , lithium claim 2 , magnesium claim 2 , zirconium claim 2 , nickel claim 2 , manganese claim 2 , zinc claim 2 , and sodium claim 2 , andthe metal compound is one or more selected from the group consisting of oxides, hydroxides, carbonates, and organometallic ...

SILICATE MIXTURE AND COMBUSTION ACCELERATOR USING THE SAME

Provided are a silicate mixture and a combustion accelerator for increasing combustion efficiency in a combustion engine. The silicate mixture is formed by mixing a first component including one or two or more materials selected from silicon compounds including silicon, glass, and quartz, and a second component including one or two or more materials selected from materials formed by sintering a silicate mineral at a temperature of 1300° C. or higher and 2000° C. or lower and ores emitting a terahertz wave. 1. (canceled)2. A silicate mixture formed by mixing a first component including one or two or more materials selected from silicon compounds including silicon , glass , and quartz , anda second component of one or two or more selected from materials formed by sintering a silicate mineral at a temperature of 1300° C. or higher and 2000° C. or lower and ores emitting a terahertz wave, whereinethe second component is blended at 10 to 90% by mass in the total mixture.3. A silicate mixture formed by mixing a first component emitting an electromagnetic wave with a frequency of less than 100 GHz , anda second component emitting a terahertz wave with a frequency of 100 GHz or more and 100 THz or less.4. The silicate mixture according to claim 2 , whereinthe first component and the second component are formed to have a particle size of 150 μm or less, andthe first component and the second component are dispersed in an organic or inorganic solvent or are kneaded with at least any one of metals, resins, and ceramics.5. The silicate mixture according to claim 2 , wherein the silicate mixture is further blended with carbon powder having a particle size of 150 μm or less.6. A combustion accelerator for improving combustion efficiency in a combustion engine claim 2 , wherein{'claim-ref': {'@idref': 'CLM-00002', 'claim 2'}, 'the silicate mixture according to is used as the combustion accelerator, and'}the first component emits an electromagnetic wave with a frequency of less than ...

RARE-EARTH SILICATE COMPOSITIONS AND THEIR PREPARATION

A new family of rare-earth silicate compositions and the synthetic methods used to prepare them. The materials have open-framework structures and are characterized by their ion-exchange properties. They are represented by the following empirical formula: 4. The rare-earth silicate material of where M is a mixture of rare-earth elements containing less than 50% of La claim 1 , Ce claim 1 , Pr claim 1 , Nd claim 1 , Pm claim 1 , Sm claim 1 , Eu claim 1 , Gd claim 1 , or Dy claim 1 , or mixtures thereof and has the diffraction pattern described in Table A.5. The rare-earth silicate material of where M is a mixture of rare-earth elements containing less than 50% of Ho claim 1 , Er claim 1 , Tm claim 1 , Yb claim 1 , Lu claim 1 , Y claim 1 , or Sc claim 1 , or mixtures thereof and has the diffraction pattern set forth in Table B.6. The rare-earth silicate material of where A is sodium and M′ is bismuth.7. The rare-earth silicate material of where x=0.8. The rare-earth silicate material of where A is an organoammonium or ammonium cation.9. The rare-earth silicate material of where A is a mixture of sodium and another alkali metal selected from lithium claim 1 , potassium claim 1 , rubidium claim 1 , or cesium.10. The rare-earth silicate material of where said rare earth element is in a polyhedral bonding geometry with a coordination number greater than 6.11. The rare-earth silicate material of where the M′ element is selected from a group comprising zinc (+2) claim 1 , iron (+3) claim 1 , zirconium (+4) claim 1 , titanium (+4) claim 1 , niobium (+5) claim 1 , antimony (+5) claim 1 , and mixtures thereof.12. The rare-earth silicate material of further characterized in that the A cation has been exchanged for a secondary cation A′ selected from the group consisting of alkali metal cations claim 1 , alkaline earth metal cations claim 1 , hydronium cations claim 1 , ammonium cations claim 1 , a transition metal cation with valence of +2 or +3 claim 1 , a rare-earth cation and ...

SILICON OXIDE MATERIAL, MAKING METHOD, NEGATIVE ELECTRODE, LITHIUM ION SECONDARY BATTERY, AND ELECTROCHEMICAL CAPACITOR

A silicon oxide material having a cobalt content of 2-200 ppm is provided. A negative electrode is formed using the silicon oxide material as active material. A nonaqueous electrolyte secondary battery constructed using the negative electrode exhibits improved cycle performance while maintaining the high battery capacity and low volume expansion of silicon oxide. 1. A silicon oxide material for nonaqueous electrolyte secondary battery negative electrodes , having a cobalt content of 2 to 200 ppm.2. The silicon oxide material of which is in the form of particles having an average particle size of 0.1 to 30 μm and a BET specific surface area of 0.5 to 30 m/g.3. A negative electrode for use in nonaqueous electrolyte secondary batteries claim 1 , made of a negative electrode material comprising the silicon oxide material of .4. A lithium ion secondary battery comprising the negative electrode of claim 3 , a positive electrode claim 3 , and a lithium ion-conductive nonaqueous electrolyte.5. An electrochemical capacitor comprising the negative electrode of claim 3 , a positive electrode claim 3 , and a conductive electrolyte.6. A method for preparing a silicon oxide material for nonaqueous electrolyte secondary battery negative electrodes claim 3 , comprising the steps of:heating a SiO gas-providing raw material at a temperature in the range of 1,100 to 1,600° C. under reduced pressure or in an inert gas to generate a SiO gas, said SiO gas-providing raw material having a cobalt content of 500 to 100,000 ppm, andcooling the SiO gas to a temperature in the range of 500 to 1,100° C. for precipitation.7. The method of claim 6 , wherein the SiO gas-providing raw material is a silicon oxide powder or a mixture of a silicon dioxide powder and a metal silicon powder. This non-provisional application claims priority under 35U.S.C. §119(a) on Patent Application No. 2012-269532 filed in Japan on Dec. 10, 2012, the entire contents of which are hereby incorporated by reference.This ...

Secondary battery positive-electrode active material and method for producing same

The present invention provides a positive electrode active substance for a secondary cell, the positive electrode active substance capable of suppressing adsorption of water effectively in order to obtain a high-performance lithium ion secondary cell or sodium ion secondary cell. The present invention also provides a method for producing the positive electrode active substance for a secondary cell. That is, the present invention is a positive electrode active substance for a secondary cell, in which one or two selected from the group consisting of a water-insoluble electrically conductive carbon material and carbon obtained by carbonizing a water-soluble carbon material, and 0.1 to 5 mass % of a metal fluoride are supported on a compound containing at least iron or manganese, the compound represented by formula (A) LiFe n Mn b M 1 c PO 4 , formula (B) Li 2 Fe d Mn e M 2 f SiO 4 , or formula (C) NaFe g Mn h Q i PO 4 .

COMPOSITION CONTAINING SYNTHETIC MINERAL PARTICLES AND A PROCESS FOR PREPARING THE COMPOSITION

A composition comprising synthetic mineral particles, such as silicate or phyllosilicate mineral particles, is presented. The composition can be prepared by a process in which a hydrogel precursor of the synthetic mineral particles is produced by a coprecipitation reaction between at least one compound comprising silicon, such as sodium metasilicate, and at least one compound comprising at least one metal element, such as a dicarboxylate salt of the formula M(R—COO), wherein Ris H or an alkyl group having 1 to 4 carbon atoms. The coprecipitation reaction also takes place in the presence of at least one carboxylate salt of formula R—COOM′ wherein M′ is Na or K, and Ris H or an alkyl group having 1 to 4 carbon atoms. 1. A composition comprising synthetic mineral particles , wherein the composition has , in X-ray diffraction , the following characteristic diffraction lines:a plane (001) situated at a distance between 9.40 Å and 9.90 Å;a plane (002) situated at a distance between 4.60 Å and 4.80 Å;a plane (003) situated at a distance between 3.10 Å and 3.20 Å; anda plane (060) situated at a distance between 1.51 Å and 1.53 Å;the intensity of the diffraction line characteristic of the plane (002) being greater than the intensity of the signal corresponding to a plane (020) situated at a distance between 4.40 Å and 4.60 Å, andthe ratio between the intensity of the diffraction line characteristic of the plane (001) and the intensity of the diffraction line characteristic of the plane (003) being from 0.60 to 1.50.3. The composition according to claim 1 , wherein the composition has claim 1 , in near-infrared claim 1 , a vibration band situated between 5000 cmand 5500 cm claim 1 , corresponding to the presence of water bonded at lamina edges.4. The composition according to claim 2 , wherein said composition has claim 2 , in near-infrared claim 2 , a vibration band situated between 5000 cmand 5500 cm claim 2 , corresponding to the presence of water bonded at lamina edges.5. ...

Vapor Deposition of Metal Oxides, Silicates and Phosphates, and Silicon Dioxide

Metal silicates or phosphates are deposited on a heated substrate by the reaction of vapors of alkoxysilanols or alkylphosphates along with reactive metal amides, alkyls or alkoxides. For example, vapors of tris(tert-butoxy)silanol react with vapors of tetrakis(ethylmethylamido)hafnium to deposit hafnium silicate on surfaces heated to 300° C. The product film has a very uniform stoichiometry throughout the reactor. Similarly, vapors of diisopropylphosphate react with vapors of lithium bis(ethyldimethylsilyl)amide to deposit lithium phosphate films on substrates heated to 250° C. Supplying the vapors in alternating pulses produces these same compositions with a very uniform distribution of thickness and excellent step coverage. 1. A process for forming materials comprising silicon , oxygen and one or more metals or metalloids , comprising:reacting the vapor of one of an alkoxysilanol and an alkoxysilanediol together with a vapor of one or more of a metal compound and a metalloid compound.2. A process for forming materials comprising silicon , oxygen and one or more metals or metalloids , comprising:exposing a substrate alternately to the vapor of one or an alkoxysilanol and an alkoxysilanediol and the vapor of one or more of a metal compound or a metalloid compound to form a film on the substrate.3. The process of claim 1 , wherein compound is deposited as a film on a substrate.5. The process of claim 4 , wherein the groups Rcontain between one and four carbons and are the same or different.6. The process of claim 5 , wherein the groups Rare all methyl groups.8. The process of or claim 5 , wherein a metal or metalloid compound contains metal-nitrogen or metalloid-nitrogen bonds.9. The process of claim 8 , wherein a metal or metalloid compound is selected from Table 1.10. The process of or claim 8 , wherein a metal compound is selected from Table 2.11. The process of or claim 8 , wherein a metal or metalloid compound is selected from Table 3.12. A process for forming ...

SOLID ELECTROLYTE ASSEMBLY

A solid electrolyte assembly is obtained by joining a solid electrolyte layer having oxide ion conductivity and containing lanthanum and a first electrode layer made of an oxide that is represented by ABOand has a cubic perovskite structure to each other, where A represents an alkaline-earth metal element, B represents a transition metal element, and δ represents a fraction that occurs depending on the valences and amounts of A, B, and O. The oxide contains lanthanum at a part of the A site, and an atom ratio of lanthanum to all the elements occupying the A site is 0.01 or greater and 0.80 or less. 1. A solid electrolyte assembly comprising a solid electrolyte and a first electrode ,the solid electrolyte having oxide ion conductivity and containing lanthanum,{'sub': '3−δ', 'the first electrode being made of an oxide that has a cubic perovskite structure and that is represented by ABO, wherein A represents an alkaline-earth metal element, B represents a transition metal element, and δ represents a fraction that occurs depending on the valences and amounts of A, B, and O,'}the solid electrolyte and the first electrode being joined to each other, andthe oxide containing lanthanum occupying a part of A site, and an atom ratio of lanthanum to all the elements occupying the A site being 0.01 or greater and 0.80 or less.2. The solid electrolyte assembly according to claim 1 ,wherein, the A site of the oxide is occupied by lanthanum and one or more elements selected from the group consisting of barium and strontium.3. The solid electrolyte assembly according to claim 1 ,wherein iron occupies at least a part of B site of the oxide.4. The solid electrolyte assembly according to claim 3 ,wherein iron and copper occupy at least a part of the B site of the oxide.5. A solid electrolyte assembly comprising a solid electrolyte and a first electrode claim 3 , the solid electrolyte having oxide ion conductivity and containing lanthanum claim 3 ,{'sub': '3−δ', 'the first electrode ...

MICROPOROUS ZIRCONIUM SILICATE FOR THE TREATMENT OF HYPERKALEMIA

The present invention relates to novel microporous zirconium silicate compositions that are formulated to remove toxins, e.g. potassium ions, from the gastrointestinal tract at an elevated rate without causing undesirable side effects. The preferred formulations are designed avoid increase in pH of urine in patients and/or avoid potential entry of particles into the bloodstream of the patient. Also disclosed is a method for preparing high purity crystals of UZSi-9 exhibiting an enhanced level of potassium exchange capacity. These compositions are particularly useful in the therapeutic treatment of hyperkalemia. 146-. (canceled)47. A method for removing potassium from a patient in need thereof comprising administering a potassium-binding particle in an oral dosage form to the patient , the potassium binding particle comprising a microporous material , the particle having an average in vitro binding capacity of at least about 2.5 mmol per gram for binding potassium , and the patient being administered a dose from about 0.050 grams per day to about 33 grams per day.48. The method of claim 47 , wherein the dose is from about 0.5 grams per day to about 15 grams per day.49. The method of claim 47 , wherein the dose is from about 5 grams per day to about 20 grams per day.50. The method of claim 47 , wherein the dose is from about 5 grams per day to about 15 grams per day.51. The method of claim 47 , wherein the dose is from about 10 grams per day to about 20 grams per day.52. The method of claim 47 , wherein the dose is from about 10 grams per day to about 15 grams per day.53. The method of claim 47 , wherein the potassium-binding particle has an average in vitro binding capacity of at least about 3.5 mmol per gram.54. The method of claim 47 , wherein the microporous material having a capacity for binding potassium comprises a zirconium silicate.55. A method of treating hyperkalemia in a patient in need thereof comprising administering a potassium-binding particle in an ...

Synthesis of Nanostructured Zinc Silicate from Renewable Sources

A method of making Nanostructured Zinc Silicate from renewable sources comprising preparing powders of husks, preparing powders of ZnO, mixing the powders of husks and the powders of ZnO and forming a homogenous sample powder, pressing the homogenous sample and forming pellets, heating the pellets and forming nanostructured zinc silicate. The nanostructured zinc silicate from renewable sources product of the process of preparing powders of husks, preparing powders of ZnO, mixing the powders of husks and the powders of ZnO and forming a homogenous sample powder, pressing the homogenous sample and forming pellets, heating the pellets and forming nanostructured zinc silicate. 1. A method of making Nanostructured Zinc Silicate from renewable sources comprising:preparing powders of husks wherein the husks are selected from the group consisting of wheat husk, rice husk, and a combination of wheat husk and rice husk using ball milling with a SPEX 8000M including stainless steel milling media;preparing powders of ZnO using ball milling with a SPEX 8000M including stainless steel milling media;mixing the powders of husks and the powders of ZnO using ball milling with a SPEX 8000M including stainless steel milling media and thereby forming a homogenous sample powder;pressing the homogenous sample powder into disks having a diameter of 1 cm and thickness of 2-3 mm and forming pellets;heating the pellets at a temperature above 1400° C. and forming nanostructured zinc silicate pellets; andremoving excess carbon by processing the nanostructured zinc silicate pellets in air at a temperature of 650° C.2. The method of making Nanostructured Zinc Silicate from renewable sources of further comprising the steps ofwashing the husks in distilled water prior to the step of preparing powders of husks wherein the husks are selected from the group consisting of wheat husk, rice husk, and a combination of wheat husk and rice husk using ball milling with a SPEX 8000M including stainless steel ...

COMPOSITION INCLUDING SILICOTITANATE HAVING SITINAKITE STRUCTURE, AND PRODUCTION METHOD FOR SAME

The present invention provides a composition that includes a silicotitanate that has a sitinakite structure, the composition having higher cesium adsorptivity than conventional compositions. The present invention also provides a production method for the composition that includes a silicotitanate that has a sitinakite structure. The production method does not require the use of hazardous or deleterious materials, can generate a product using a compound that is easily acquired, and can use a general-purpose autoclave. Also provided is a silicotitanate composition that has higher strontium adsorptivity than the present invention. Provided is a silicotitanate composition that contains niobium and a silicotitanate that has a sitinakite structure, the composition having at least two or more diffraction peaks selected from the group consisting of 2θ=8.8°±0.5°, 2θ=10.0°±0.5°, and 2θ=29.6°±0.5°. 1. An adsorption method for at least any of cesium and strontium , comprising contacting a medium containing at least any of cesium and strontium with a silicotitanate composition ,wherein the composition comprises a silicotitanate having a sitinakite structure and niobium, and has at least two or more diffraction peaks at X-ray diffraction angles selected from the group consisting of 2θ=8.8±0.5°, 2θ=10.0±0.5°, and 2θ=29.6±0.5°.3. The adsorption method according to claim 1 , wherein the composition comprises a crystalline substance having at least two or more diffraction peaks at X-ray diffraction angles selected from the group consisting of 2θ=8.8±0.5° claim 1 , 2θ=10.0±0.5° and 2θ=29.6±0.5°.4. The adsorption method according to claim 2 , wherein the composition comprises a crystalline substance having at least two or more diffraction peaks at X-ray diffraction angles selected from the group consisting of 2θ=8.8±0.5° claim 2 , 2θ=10.0±0.5° and 2θ=29.6±0.5°.5. The adsorption method according to claim 3 , wherein the crystalline substance is a niobate.6. The adsorption method ...

COLLOIDAL COMPOSITIONS AND METHODS OF PREPARING SAME

Colloidal compositions and methods of preparing same are provided. The colloidal compositions include a silicate and a metal dispersed therein. The colloidal compositions can further include a stabilizer, such as a quaternary amine, to enhance the and dispersion of the metal loading within the silicate. The colloidal compositions can be made such that the metal is dispersed within the silicate in a controlled manner. 1. A method of producing a silica colloid , comprising:providing an alkaline solution having a stabilizing component,adding a silicic acid solution to the alkaline solution, andforming a colloid of silica particles, wherein the stabilizing component is dispersed throughout each silica particle.2. The method of claim 1 , wherein the alkaline solution comprises a cationic metal component.3. The method of claim 2 , wherein the metal component is dispersed within one or more of the silica particles.4. The method of claim 3 , wherein the stabilizing component and/or the metal component is dispersed in a homogenous manner.5. The method of claim 1 , wherein the stabilizer is a quaternary compound.6. The method of claim 5 , wherein the stabilizer is a quaternary amine.7. The method of claim 6 , wherein the quaternary amine is quaternary ammonium hydroxide.8. A method of preparing a metal-containing silica colloid claim 6 , comprising:reacting a silicic acid solution with a cationic metal component,forming a metal-silicate solution,adding the metal-silicate solution to an alkaline solution,forming a colloid of metal silicate particles.9. The method of claim 8 , further comprising forming a metal-silicate monomer by reacting the silicic acid solution with the metal component.10. The method of claim 9 , further comprising polymerizing the metal-silicate monomer.11. The method of claim 10 , further comprising forming a homogenous metal-silicate lattice microstructure throughout a solid phase of the colloid.12. The method of claim 8 , wherein the colloid is further ...

MULTILAYER ENVIRONMENTAL BARRIER COATINGS

A method of making a multilayer environmental barrier coating for a ceramic matrix composite is provided, comprising the steps of: plasma spray coating an oxide-based bond coat over top of the ceramic matrix composite and depositing a columnar top coat over the oxide-based bond coat. 1. An article comprising:a ceramic matrix composite;{'sub': 4', '2', '2', '3', '2', '2', '3', '4, 'an oxide-based bond coat over the ceramic matrix composite, wherein the oxide-based bond coat consists of HfSiO+SiO+AlO+Si, and wherein the Si is present in the oxide-based bond coat in an amount between about 10 wt. % and about 40 wt. %, the SiOis present in the oxide-based bond coat in an amount between about 10 wt. % and about 30 wt. %, the AlOis present in the oxide-based bond coat in an amount between about 0.1 wt. % and about 10 wt. %, and the balance of the oxide-based bond coat is HfSiO; and'}a top coat over the oxide-based bond coat.2. The article of claim 1 , wherein the top coat is selected from the group consisting of RESiOand RESiO(wherein RE is selected from the group consisting of at least one of lutetium claim 1 , ytterbium claim 1 , thulium claim 1 , erbium claim 1 , holmium claim 1 , dysprosium claim 1 , terbium claim 1 , gadolinium claim 1 , europium claim 1 , samarium claim 1 , promethium claim 1 , neodymium claim 1 , praseodymium claim 1 , cerium claim 1 , lanthanum claim 1 , yttrium claim 1 , and scandium) claim 1 , REO-stabilized ZrO(wherein RE is selected from the group consisting of at least one of lutetium claim 1 , ytterbium claim 1 , thulium claim 1 , erbium claim 1 , holmium claim 1 , dysprosium claim 1 , terbium claim 1 , gadolinium claim 1 , europium claim 1 , samarium claim 1 , promethium claim 1 , neodymium claim 1 , praseodymium claim 1 , cerium claim 1 , lanthanum claim 1 , yttrium claim 1 , and scandium) claim 1 , and REO-stabilized HfO(wherein RE is selected from the group consisting of at least one of lutetium claim 1 , ytterbium claim 1 , thulium ...

CATALYST AND METHOD FOR PRODUCING DIENE COMPOUND

A catalyst includes at least one element X selected from the group consisting of Groups 3 to 6 of the Periodic Table, and at least one element Z selected from the group consisting of Group 14 elements. At least one diffraction peak is observed in a low angle range of θ=6° or less in an X-ray diffraction profile observed using X-ray diffraction. The at least one diffraction peak has a ratio (I/H) of a peak intensity I to a half width at half maximum H of the diffraction peak of 5000 or more. 1. A catalyst comprising:at least one element X selected from the group consisting of Groups 3 to 6 of the Periodic Table; andat least one element Z selected from the group consisting of Group 14 elements, whereinat least one diffraction peak is observed in a low angle range of θ=6° or less in an X-ray diffraction profile observed using X-ray diffraction, andthe at least one diffraction peak has a ratio (I/H) of a peak intensity I to a half width at half maximum H of the diffraction peak of 5000 or more.2. The catalyst according to claim 1 , wherein a molar content (X/(X+Z)×100) of the element X with respect to the total amount (mole) of the element X and the element Z is 0.5 to 6 mol %.3. The catalyst according to claim 1 , wherein the element X is Hf and the element Z is Si.4. The catalyst according to claim 1 , wherein the catalyst is a diene compound synthesis catalyst for synthesizing a diene compound from a raw material including an alcohol.5. The catalyst according to claim 4 , wherein the raw material includes ethanol and/or acetaldehyde.6. The catalyst according to claim 1 , wherein a BET specific surface area is 700 to 1200 m/g and an average pore size is 2 to 20 nm.7. The catalyst according to claim 1 , wherein at least one diffraction peak having a half width at half maximum of 1° or more is observed in a high angle range of θ=10° to 40° in an X-ray diffraction profile observed using X-ray diffraction.8. A method for producing a diene compound claim 1 , comprising ...

METHODS AND DEVICES FOR GROWING OXIDE CRYSTALS IN OXYGEN ATMOSPHERE

The present disclosure discloses a method for growing a crystal in oxygen atmosphere. The method may include compensating a weight of a reactant, introducing a flowing gas, improving a volume ratio of oxygen during a cooling process, providing a heater in a temperature field, and optimizing parameters. According to the method, problems may be solved, for example, cracking and component deviation of the crystal during a crystal growth process, and without oxygen-free vacancy. The method for growing the crystal may have excellent repeatability and crystal performance consistency. 1. A method for growing a crystal , comprising:{'sub': 2', '2', '2, 'weighting reactants based on a molar ratio of the reactants according to a reaction equation for generating the crystal, the reactants at least including SiO, wherein a weight range of the SiOis 0.01%˜10% in excess of a theoretical weight value of the SiOcalculated according to the reaction equation;'}placing the reactants into a crystal growth device;introducing a flowing gas into the crystal growth device after sealing the crystal growth device; andoperating the crystal growth device to execute a crystal growth operation based on Czochralski technique.2. The method of claim 1 , wherein the crystal includes gadolinium aluminum gallium garnet (GAGG) claim 1 , yttrium aluminum garnet (YAG) claim 1 , lutetium orthosilicate (LSO) claim 1 , lutetium yttrium orthosilicate (LYSO) claim 1 , gadolinium yttrium oxy orthosilicate (GYSO) claim 1 , terbium gallium garnet (TGG) claim 1 , gadolinium gallium garnet (GGG) claim 1 , yttrium orthovanadate (YVO4) claim 1 , gadolinium orthosilicate (GSO) claim 1 , sapphire claim 1 , or a doped crystal thereof.3. The method of claim 1 , wherein:the crystal includes cerium-doped LSO; and {'br': None, 'i': −x', 'x', '+x/, 'sub': 2', '3', '2', '2', '2(1-x)', '2x', '5', '2, '(1)LuO+SiO+2CeO→LuCeSiO2O↑\u2003\u2003(1);'}, 'the reaction equation includeswhere x=[0.0001%˜6%];orthe crystal includes ...

Methods and devices for growing oxide crystals in oxygen atmosphere

The present disclosure discloses a method for growing a crystal in oxygen atmosphere. The method may include compensating a weight of a reactant, introducing a flowing gas, improving a volume ratio of oxygen during a cooling process, providing a heater in a temperature field, and optimizing parameters. According to the method, problems may be solved, for example, cracking and component deviation of the crystal during a crystal growth process, and without oxygen-free vacancy. The method for growing the crystal may have excellent repeatability and crystal performance consistency.

COMPOSITION INCLUDING SILICOTITANATE HAVING SITINAKITE STRUCTURE, AND PRODUCTION METHOD FOR SAME

The present invention provides a composition that includes a silicotitanate that has a sitinakite structure, the composition having higher cesium adsorptivity than conventional compositions. The present invention also provides a production method for the composition that includes a silicotitanate that has a sitinakite structure. The production method does not require the use of hazardous or deleterious materials, can generate a product using a compound that is easily acquired, and can use a general-purpose autoclave. Also provided is a silicotitanate composition that has higher strontium adsorptivity than the present invention. Provided is a silicotitanate composition that contains niobium and a silicotitanate that has a sitinakite structure, the composition having at least two or more diffraction peaks selected from the group consisting of 2θ=8.8°±0.5°, 2θ=10.0°±0.5°, and 2θ=29.6°±0.5°. 1. A silicotitanate composition comprising a silicotitanate having a sitinakite structure and niobium ,wherein the composition has at least two or more diffraction peaks at X-ray diffraction angles selected from the group consisting of 2θ=8.8±0.5°, 2θ=10.0±0.5°, and 2θ=29.6±0.5°.3. The silicotitanate composition according to claim 1 , wherein the composition comprises a crystalline substance having at least two or more diffraction peaks at X-ray diffraction angles selected from the group consisting of 2θ=8.8±0.5° claim 1 , 2θ=10.0±0.5° claim 1 , and 2θ=29.6±0.5°.4. The silicotitanate composition according to claim 3 , wherein the crystalline substance is a niobate.6. An adsorbent for at least cesium or strontium claim 1 , the adsorbent comprising the silicotitanate composition according to .7. An adsorption method for at least any of cesium and strontium claim 1 , comprising using the silicotitanate composition according to .8. A silicotitanate composition comprising a silicotitanate having a sitinakite structure and niobium claim 1 ,wherein the composition has at least diffraction ...

Gas turbine components and methods of assembling the same

A gas turbine component includes a substrate and a corrosion resistant layer coupled to the substrate. The corrosion resistant layer includes zirconium silicate and is configured to protect the substrate from exposure to a vanadium corrodent.

Complexometric Precursors Formulation Methodology for Industrial Production of High Performance Fine and Ultrafine Powders and Nanopowders for Specialized Applications

A method of forming a powder M j X p wherein M j is a positive ion or several positive ions selected from alkali metal, alkaline earth metal or transition metal; and X p is a monoatomic or a polyatomic anion selected from Groups IIIA, IVA, VA, VIA or VIIA; called complexometric precursor formulation or CPF. The method includes the steps of: providing a first reactor vessel with a first gas diffuser and an first agitator; providing a second reactor vessel with a second gas diffuser and a second agitator; charging the first reactor vessel with a first solution comprising a first salt of M j ; introducing gas into the first solution through the first gas diffuser, charging the second reactor vessel with a second solution comprising a salt of M p ; adding the second solution to the first solution to form a complexcelle; drying the complexcelle, to obtain a dry powder; and calcining the dried powder of said M j X p .

Oriented Apatite-Type Oxide Ion Conductor and Method for Manufacturing Same

In order to provide a novel oriented apatite-type oxide ion conductor which can achieve an increase in area through suppression of crack generation and preferably can be manufactured more inexpensively by an uncomplicated process, an oriented apatite-type oxide ion conductor composed of a composite oxide represented by A[TM]OA in the formula is one kind or two or more kinds of elements selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Be, Mg, Ca, Sr, and Ba. T in the formula is an element including Si, Ge, or both of them. M in the formula is one kind or two or more kinds of elements selected from the group consisting of B, Ge, Zn, Sn, W, and Mo. 1. An oriented apatite-type oxide ion conductor comprising a composite oxide represented by A[TM]O , wherein A in the formula is one kind or two or more kinds of elements selected from the group consisting of La , Ce , Pr , Nd , Sm , Eu , Gd , Tb , Dy , Be , Mg , Ca , Sr , and Ba , T in the formula is an element including Si , Ge , or both of them , M in the formula is one kind or two or more kinds of elements selected from the group consisting of B , Ge , Zn , Sn , W , and Mo , whereinx in the formula is from −1 to 1,y in the formula is from 1 to 3,z in the formula is from −2 to 2, anda ratio (A/M) of the number of moles of A to the number of moles of M is from 3 to 10.2. The oriented apatite-type oxide ion conductor according to claim 1 , wherein the degree of orientation measured by the Lotgering method is 0.60 or more.3. A method for manufacturing an oriented apatite-type oxide ion conductor claim 1 , the method comprising a step claim 1 , referred to as the “vapor phase-solid phase diffusion step” of converting a precursor represented by ATO claim 1 , wherein A in the formula is one kind or two or more kinds of elements selected from the group consisting of La claim 1 , Ce claim 1 , Pr claim 1 , Nd claim 1 , Sm claim 1 , Eu claim 1 , Gd claim 1 , Tb claim 1 , Dy claim 1 , Be claim 1 , Mg claim 1 ...

ANISOTROPIC LAMELLAR INORGANIC FIBER AEROGEL MATERIALS AND PREPARATION METHOD THEREOF

The present disclosure provides an anisotropic lamellar inorganic fiber aerogel material and a preparation method thereof. The method includes: mixing a polymer solution, an inorganic precursor and a chloride to obtain a spinning precursor solution; blow spinning the spinning precursor solution to obtain a composite fiber aerogel; calcinating the composite fiber aerogel to obtain the anisotropic lamellar inorganic fiber aerogel material. Therefore, the method has advantages of simplicity, easy operation, low cost, high efficiency and easy industrialized production. The inorganic fiber aerogel materials prepared by the above method are composed of multi-layer stacked fibers and have an anisotropic lamellar structure, which can be cut into any desired shape, and stacked to any desired thickness. In addition, the inorganic fiber aerogel materials have good flexibility and compressibility, excellent fire resistance, good high and low temperature resistance and superior thermal insulation, which greatly expands their application field. 1. A method for preparing an anisotropic lamellar inorganic fiber aerogel material , comprising:mixing a polymer solution, an inorganic precursor and a chloride to obtain a spinning precursor solution;blow spinning the spinning precursor solution to obtain a composite fiber aerogel;calcinating the composite fiber aerogel to obtain the anisotropic lamellar inorganic fiber aerogel material.2. The method according to claim 1 , wherein the polymer solution comprises polymer material and a solvent claim 1 , wherein the mass ratio of the polymer material to the solvent is in a range of 2:100 to 30:100.3. The method according to claim 1 , wherein the spinning precursor solution further comprises a catalyst.4. The method according to claim 3 , wherein the spinning precursor solution comprises:2 to 30 parts by weight of the polymer material;100 parts by weight of the solvent;0.5 to 100 parts by weight of the inorganic precursor;0.001 to 1 part by ...

THERMAL AND ENVIRONMENTAL BARRIER COATING COMPOSITIONS AND METHODS OF DEPOSITION

A coated substrate is provided that comprises: a substrate; and a barrier coating comprising a compound having the formula: LnABO, where Ln comprises scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, or mixtures thereof; A comprises Si, Ti, Ge, Sn, Ce, Hf, Zr, or a combination thereof; and B comprises Mo, W, or a combination thereof. In one embodiment, B comprises Mo. 1. A coated substrate , comprising:a substrate; and {'br': None, 'i': 'n', 'sub': 2', '8, 'LABO'}, 'a barrier coating comprising a compound having the formulawhere Ln comprises scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, or mixtures thereof;A comprises Si, Ti, Ge, Sn, Ce, Hf, Zr, or a combination thereof; andB comprises Mo, W, or a combination thereof.2. The coated substrate as in claim 1 , wherein Ln is selected from the group consisting of scandium (Sc) claim 1 , yttrium (Y) claim 1 , lanthanum (La) claim 1 , cerium (Ce) claim 1 , praseodymium (Pr) claim 1 , neodymium (Nd) claim 1 , promethium (Pm) claim 1 , samarium (Sm) claim 1 , europium (Eu) claim 1 , gadolinium (Gd) claim 1 , terbium (Tb) claim 1 , dysprosium (Dy) claim 1 , holmium (Ho) claim 1 , erbium (Er) claim 1 , thulium (Tm) claim 1 , ytterbium (Yb) claim 1 , lutetium (Lu) claim 1 , and mixtures thereof.3. The coated substrate as in claim 1 , wherein Ln comprises yttrium.4. The coated substrate as in claim 1 , wherein B comprises Mo.5. The coated substrate as in claim 4 , wherein the compound has the formula:{'br': None, 'i': 'n', 'sub': 2', 'x', '1-x', '8, 'LAMoWO,'}where 0≤x≤about 0.5.6. The coated substrate as in claim 1 , wherein B comprises W or a combination of Mo and W.7. The coated substrate as in claim 6 , wherein the compound has the formula:{'br': None, 'i': 'n', 'sub': 2', 'x ...

SPRAYING PARTICLES AND MANUFACTURING METHOD THEREOF

Spraying particles including a rare earth silicate wherein the spraying particles are granulated particles and have a composition represented by the average compositional formula: (ASiO)(CeSiO)(EuSiO)or the average compositional formula: ASiOis manufactured from (A) rare earth oxide particles and/or rare earth silicate particles, and silicon oxide particle, (B) a water-soluble rare earth compound and silicon oxide particles, or rare earth silicate particles by granulating and firing. 3. The spraying particles of wherein the element A in the average compositional formula (1) is at least one rare earth element selected from the group consisting of Y claim 1 , Sm claim 1 , Gd claim 1 , Tb claim 1 , Dy claim 1 , Ho claim 1 , Er claim 1 , Tm claim 1 , Yb and Lu.4. The spraying particles of wherein the element A in the average compositional formula (1) is Yb alone claim 3 , or a combination of Yb claim 3 , and at least one rare earth element selected from the group consisting of Y claim 3 , Sm claim 3 , Gd claim 3 , Tb claim 3 , Dy claim 3 , Ho claim 3 , Er claim 3 , Tm and Lu.5. The spraying particles of having an angle of repose of up to 42°.6. The spraying particles of having a bulk density of at least 1.2 g/cm.7. The spraying particles of having a crushing strength of at least 2 MPa.8. A method for manufacturing spraying particles of comprising the steps of:mixing rare earth oxide particles and/or rare earth silicate particles, and silicon oxide particles,granulating the obtained mixture, andfiring the obtained granulated particles.9. A method for manufacturing spraying particles of comprising the steps of:to preparing an aqueous solution of a water-soluble rare earth compound, in which silicon oxide particles are dispersed,precipitating rare earth compound particles in the solution to form a mixture of the rare earth compound particles and the silicon oxide particles,granulating the obtained mixture, andfiring the obtained granulated particles.10. A method for ...

Guanidine-functionalized metal silicate particles and methods of making and using such particles

Guanidine-functionalized particles and methods of making and using such particles are provided, such as guanidine-functionalized metal silicate particles. A nonwoven article is also provided including a porous fibrous nonwoven matrix and guanidine-functionalized metal silicate particles enmeshed within the porous fibrous nonwoven matrix. The nonwoven article may be used, for instance, for removing microorganisms from an aqueous sample by contacting a fluid sample with the nonwoven article such that at least a portion of the microorganisms are removed from the fluid sample.

SUBSTRATE WITH WATER-AND-OIL REPELLENT LAYER, VAPOR DEPOSITION MATERIAL, AND METHOD FOR PRODUCING SUBSTRATE WITH WATER-AND-OIL REPELLENT LAYER

To provide a water/oil repellent layer-provided substrate having a water/oil repellent layer excellent in abrasion resistance, a deposition material and a method for producing a water/oil repellent layer-provided substrate. 1. A water/oil repellent layer-provided substrate comprising a substrate , an undercoat layer and a water/oil repellent layer in this order ,wherein the water/oil repellent layer comprises a condensate of a fluorinated compound having a reactive silyl group,the undercoat layer contains an oxide containing silicon and at least one element selected from the group consisting of titanium, zirconium and aluminum, andthe ratio of the total molar concentration of titanium, zirconium and aluminum in the undercoat layer to the molar concentration of silicon in the undercoat layer is from 0.03 to 0.7.2. The water/oil repellent layer-provided substrate according to claim 1 , wherein the oxide contains silicon claim 1 , and at least one element selected from the group consisting of titanium and zirconium.3. The water/oil repellent layer-provided substrate according to claim 1 , wherein the oxide contains silicon and titanium.4. The water/oil repellent layer-provided substrate according to claim 1 , wherein the oxide further contains an alkali metal element.5. The water/oil repellent layer-provided substrate according to claim 4 , wherein the ratio of the molar concentration of the alkali metal element to the molar concentration of silicon is at most 1.0.6. The water/oil repellent layer-provided substrate according to claim 1 , wherein the fluorinated compound is a fluorinated ether compound having a poly(oxyfluoroalkylene) chain and a reactive silyl group.7. A deposition material to be used for forming an undercoat layer of a water/oil repellent layer comprising a condensate of a fluorinated compound having a reactive silyl group claim 1 , wherein the deposition material contains an oxide of silicon and at least one element selected from the group consisting ...

Polycarbonate Diol Coating Composition For Caustic And UV Resistance

A curable glass coating composition including 5-70 wt % aliphatic polycarbonate diol, 5-60 wt % crosslinker, 1-20 wt % extender, 4-20 wt % fatty alcohol, and 2-30 wt % crystalline or amorphous powder filler material, and optionally 2-20 wt % aliphatic polyester polyol and 2-20 wt % cycloaliphatic epoxy. The coating composition can be applied to a glass substrate and cured to form a decorative cured polyurethane coating layer on the substrate that has improved caustic and UV resistance. 1. A curable glass coating composition including:5-70 wt % aliphatic polycarbonate diol,5-60 wt % crosslinker,1-20 wt % trimethylolpropane,4-20 wt % fatty alcohol2-30 wt % powder filler material.2. The composition according to claim 1 , including:10-60 wt % aliphatic polycarbonate diol,10-50 wt % the crosslinker,5-15 wt % trimethylolpropane,10-15 wt % fatty alcohol, and10-20 wt % powder filler material.3. The composition according to claim 2 , wherein the powder filler material is zinc silicate powder.4. The composition according to claim 1 , further including 2-20 wt % aliphatic polyester polyol.5. The composition according to claim 1 , further including 2-20 wt % cycloaliphatic epoxy.6. The composition according to claim 1 , further including a 2-20 wt % colorant.7. The composition according to claim 1 , further including 0.1 up to 5 wt % glass claim 1 , ceramic claim 1 , or polymer spherical particles from 100 nm to 20 um in average size.8. The composition according to claim 1 , wherein the composition is free of bisphenol A and free of heavy metals including lead claim 1 , cadmium claim 1 , chromium claim 1 , nickel claim 1 , vanadium claim 1 , antimony and bismuth.9. The composition according to claim 1 , wherein at 101.325 kPa the polycarbonate diol is solid at or below 25° C. and has a melt temperature above 25° C.10. The composition according to claim 1 , wherein the crosslinker comprises a blocked isocyanate and the composition can be cured by heating the composition.11. The ...

Method for producing crystalline silicotitanate

The invention provides an industrially advantageous method for producing a crystalline silicotitanate having high adsorption/removal capabilities for cesium and strontium in seawater. The method includes a first step of mixing a silicic acid source, a sodium compound, titanium tetrachloride, and water to prepare a mixed gel and a second step of hydrothermal reaction of the mixed gel prepared in the first step to produce crystalline silicotitanate of formula: Na 4 Ti 4 Si 3 O 16 .nH 2 O (wherein n represents 0 to 8). In the first step, the silicic acid source, sodium compound, and titanium tetrachloride are mixed in such a mixing ratio that the resulting mixed gel may have a Ti to Si molar ratio, Ti/Si, of 1.2 to 1.5 and an Na 2 O to SiO 2 molar ratio, Na 2 O/SiO 2 , of 0.7 to 2.5.

MICROPOROUS ZIRCONIUM SILICATE FOR THE TREATMENT OF HYPERKALEMIA

The present invention relates to novel microporous zirconium silicate compositions that are formulated to remove toxins, e.g. potassium ions, from the gastrointestinal tract at an elevated rate without causing undesirable side effects. The preferred formulations are designed avoid increase in pH of urine in patients and/or avoid potential entry of particles into the bloodstream of the patient. Also disclosed is a method for preparing high purity crystals of ZS-9 exhibiting an enhanced level of potassium exchange capacity. These compositions are particularly useful in the therapeutic treatment of hyperkalemia. 124-. (canceled)26. The composition of claim 25 , wherein less than 7% of the particles in the composition have a diameter less than 3 microns claim 25 , and the composition exhibits a sodium content below 12% by weight.27. The composition of claim 26 , wherein less than 4% of the particles in the composition have a diameter less than 3 microns.28. The composition of claim 26 , wherein less than 2% of the particles in the composition have a diameter less than 3 microns.29. The composition of claim 26 , wherein less than 1% of the particles in the composition have a diameter less than 3 microns.30. The composition of claim 26 , wherein less than 0.5% of the particles in the composition have a diameter less than 3 microns.31. The composition of claim 25 , wherein the protonated ZS-9 has a sodium content of below 12% by weight.32. The composition of claim 31 , wherein the protonated ZS-9 has a sodium content of below 6% by weight.33. The composition of claim 31 , wherein the protonated ZS-9 has a sodium content of below 3% by weight.34. The composition of claim 31 , wherein the protonated ZS-9 has a sodium content in a range of between 0.05 to 3% by weight.35. The composition of claim 25 , wherein the ZS-9 has a potassium exchange capacity of between 2.7 and 3.7 meq/g. This application is a continuation of U.S. patent application Ser. No. 14/496,978, filed Sep. 25 ...

METHODS AND SYSTEMS FOR PRODUCING ACTIVATED SILICATE BASED MATERIALS USING SUSTAINABLE ENERGY AND MATERIALS

Methods and systems for producing highly activated silicate materials are disclosed. A silicate source material is provided for reaction with a reforming agent in a reforming process. The reforming process is a hydrothermal process and/or a high temperature silicate reforming (HTSR) process. The reaction materials are brought to the suitable reaction temperature via a heat source in the presence of the suitable reaction medium. For the hydrothermal reaction process, the reaction medium and heat source can be exhausted steam that is the byproduct of another industrial process. For the HTSR process, the silicate source material and the heat source can be a molten slag byproduct from another industrial process. The activated silicate materials exhibit improved reactivity compared to non-activated silicate materials and thus are advantageously employed in elemental extraction processes to produce a value material product. By being integrated with the utilization of industrial waste heat, like molten slag heat utilization (MSHU), and the recycle of the reforming agents, the production of activated silicate based materials can base on sustainable energy and materials. 1. A method of producing activated silicate material comprising:providing a silicate source material;reforming the silicate source material to an activated silicate material with a reforming agent in a reforming reaction; andproviding the activated silicate material to an elemental extraction process.2. The method according to claim 1 , wherein the silicate source material is comprised of a calcium mineral claim 1 , a magnesium mineral claim 1 , slag claim 1 , mine tailing claim 1 , fly ash claim 1 , kiln dust claim 1 , or a combination thereof.3. The method according to claim 1 , wherein reforming the silicate source material further comprises applying heat from an industrial energy production source claim 1 , an industrial energy production process claim 1 , waste energy source claim 1 , molten iron slag ...

Zircon components

A zircon body for use in glass manufacturing is provided containing zircon grains and an intergranular phase present between the zircon grains The intergranular phase may contain silicon oxide. The body may be exposed to a halide to at least partially remove at least a majority of the silicon oxide contained in the intergranular phase from the outer portion or to at least partially remove the intergranular phase along an outer portion of the component.

Silicon (Si) Modified Li2MnO3-LiMO2 (M=Ni, Mn, Co) Cathode Material For Lithium-Ion Batteries

A lithium ion battery has a positive electrode or cathode having a silicon modified mixed metal oxide including a compound having empirical formula Li[Li y Mn a-x Si x M III b M II c ]O 2   (I) wherein y=0.01-0.33; x=0.001-0.15; a, b, and c are each greater than zero; M III is a trivalent metal or a combination of metals with an average valence of +3; M II is a divalent metal or a combination of metals with an average valence of +2; and y+4a+3b+2c is equal to 3 or about 3. Such a silicon modified mixed metal oxide may be exemplified by formula: Li [Li 0.2 Mn 0.49 Si 0.05 Ni 0.13 Co 0.13 ]O 2 .

PROCESS FOR THE PREPARATION OF A PARTICULATE DENTAL FILLER COMPOSITION

Process for the preparation of a particulate dental filler composition, comprising the following steps: (a) introducing a mixture containing (al) a silica precursor component, and (a2) a solution or dispersion of one or more compounds selected from compounds of aluminum, zinc, titanium, zirconium, tungsten, ytterbium, hafnium, bismuth, barium, strontium, silver, tantalum, lanthanum, tin, boron, and cerium, into a pulsed reactor; (b) converting the silica precursor component and the compounds into a particulate mixed oxide with a pulsed gas flow resulting from flameless combustion; (c) isolating the particulate mixed oxide from the pulsed reactor; (d) optionally subjecting the particulate mixed oxide to a heat treatment step; and (e) treating the optionally heat-treated particulate mixed oxide with a silane treatment agent for obtaining a particulate dental filler composition. 1. Process for the preparation of a particulate dental filler composition , comprising the following steps: (a1) a silica precursor component, and', '(a2) a solution or dispersion of one or more compounds selected from compounds of aluminum, zinc, titanium, zirconium, tungsten, ytterbium, hafnium, bismuth, barium, strontium, silver, tantalum, lanthanum, tin, boron, and cerium,', 'into a pulsed reactor;, '(a) introducing a mixture containing'}(b) converting the silica precursor component and the compounds into a particulate mixed oxide with a pulsed gas flow resulting from flameless combustion;(c) isolating the particulate mixed oxide from the pulsed reactor;(d) optionally subjecting the particulate mixed oxide to a heat treatment step; and(e) treating the optionally heat-treated particulate mixed oxide with a silane treatment agent for obtaining a particulate dental filler composition.2. The process according to claim 1 , wherein the pulsed reactor comprises a combustion chamber having an outlet orifice being in fluid-flow communication with a resonance tube having a significantly reduced flow ...

BOROSILICATE NANOPARTICLES AND METHOD FOR MAKING THE SAME

Borosilicate nanoparticles and method of making borosilicate nanoparticles. Advantages of the method include making the borosilicate nanoparticles at temperatures not greater than 200° C. The nanoparticles made are useful, for example, as fillers in coatings, adhesives, and composite articles.

RARE EARTH SILICATE COATINGS SOLVOTHERMALLY GROWN OVER HIGH TEMPERATURE CERAMIC COMPONENTS

Methods are provided for forming high temperature coating over ceramic components, such as ceramic turbomachine components. In various embodiments, the method includes the step or process of at least partially filling a reactor vessel with a reaction solution containing a solution-borne rare earth cation source. A silicon-containing surface region of a ceramic component is submerged in the reaction solution, and a solvothermal growth process is carried-out. During the solvothermal growth process, the reaction solution is subject to elevated temperature and pressure conditions within the reactor vessel in the presence of a silicate anion source, which reacts with the solution-borne rare earth cation source to grow a rare earth silicate layer over the silicon-containing surface region of the ceramic component. 1. A method for producing a high temperature coating over a ceramic component , the method comprising:at least partially filling a reactor vessel with a reaction solution containing a solution-borne rare earth cation source;submerging a silicon-containing surface region of a ceramic component in the reaction solution; andcarrying-out a solvothermal growth process during which the reaction solution is subject to elevated temperature and pressure conditions within the reactor vessel in the presence of a silicate anion source, which reacts with the solution-borne rare earth cation source to grow at least one rare earth silicate layer over the silicon-containing surface region of the ceramic component.2. The method of wherein the silicon-containing surface region comprises a native surface oxide; andwherein the method further comprises utilizing the native surface oxide as the silicate anion source during the solvothermal growth process.3. The method of further comprising:approximating an amount of native surface oxide present on the silicon-containing surface region; andselecting an amount of the solution-borne rare earth cation source within the reaction solution ...

Malleable Ceramics

The malleable ceramics taught in this application are formed from silica or silicon dioxide and transition metal compounds comprising titanium dioxide, iron (II) oxide, manganese (II) oxide, cobalt (II) oxide (MO) or salts thereof in a process of sintering or melting together in a suitable crucible within a specific mol ratio. The selected M/Si mol ratio comprises 1.6/1.0 to 1.9/1.0. 1. A process for formation of malleable ceramic materials comprising sintering or melting together transition metal compounds , comprising titanium dioxide , iron (II) oxide , manganese (II) oxide , cobalt (II) oxide (MO) or salts thereof , in combination with silicon dioxide or compounds thereof in a selected M/Si mol ratio comprising 1.6/1.0 to 1.9/1.0 in a suitable crucible.2. A process for formation of malleable ceramic materials comprising sintering or melting together transition metal compounds , comprising titanium dioxide , iron (II) oxide , manganese (II) oxide , cobalt (II) oxide (MO) or salts thereof , in combination with silicon dioxide or compounds thereof in a selected M/Si mol ratio comprising 1.6/1.0 to 1.9/1.0 in a suitable crucible in a temperature range comprising 1 ,100° C. to 1 ,800° C.3. A process for formation of malleable ceramic materials comprising sintering or melting together transition metal compounds comprising titanium dioxide , iron (II) oxide , manganese (II) oxide , cobalt (II) oxide (MO) or salts thereof , in combination with silicon dioxide or compounds thereof in a selected M/Si mol ratio comprising 1.6/1.0 to 1.9/1.0 in a suitable crucible in a temperature range comprising 1 ,100° C. to 1 ,800° C. , for which the cooled ceramic deforms under sharp impact from a hammer and does not fracture. This disclosure teaches a process for formation of malleable ceramics. These specialty materials may be used in construction, insulation, roofing and plumbing since they do not fracture, rot or corrode.Ceramic materials are inorganic, non-metallic solids prepared ...

Hydrogen Generation

The present invention provides a method for the generation of hydrogen, where the method comprises the step of reducing a mediator, such as a polyoxometallate, at a working electrode to yield a reduced mediator and generating oxygen at a counter electrode; and contacting the reduced mediator with a catalyst, such as a Pt, Rh, Pd, Mo or Ni containing catalyst, thereby to oxidise the reduced mediator to yield hydrogen. 1. A method for the generation of hydrogen , the method comprising the steps of:(i) reducing a mediator at a working electrode to yield a reduced mediator and generating oxygen at a counter electrode; and(ii) contacting the reduced mediator with a catalyst, thereby to oxidise the reduced mediator to yield hydrogen.2. The method of claim 1 , wherein step (i) includes oxidising water at the counter electrode to yield oxygen.3. The method of claim 1 , wherein the mediator is a metal oxide.4. The method of claim 3 , wherein the metal oxide is a polyoxometallate.5. The method of claim 4 , wherein the polyoxometallate is of formula {H[MOX]} where m is 0 claim 4 , 1 claim 4 , 2 claim 4 , 3 claim 4 , 4 claim 4 , 5 or 6 as appropriate claim 4 , M is a metal claim 4 , such as Mo claim 4 , W or V claim 4 , or mixtures thereof claim 4 , X is P or Si claim 4 , n is an integer claim 4 , and where n is not 0 claim 4 , one or more suitable counter ions may be provided.6. The method of claim 5 , wherein the polyoxometallate is of formula HMOX where m is 3 claim 5 , 4 claim 5 , 5 or 6 as appropriate claim 5 , M is a metal claim 5 , such as Mo claim 5 , W or V claim 5 , or mixtures thereof claim 5 , and X is P or Si.7. The method of claim 6 , wherein the polyoxometallate is of formula HWOSi or HWOSi.8. The method of claim 1 , wherein the catalyst is a heterogeneous catalyst.9. The method of claim 1 , wherein the catalyst is a metal catalyst claim 1 , such as a transition metal catalyst.10. The method of claim 9 , wherein the metal catalyst is or comprises a metal selected ...

Metal chalcogenide thin film electrode, method for the production thereof and use

The invention relates to a method for producing a metal chalcogenide thin film electrode, comprising the steps: 1. A method for producing a metal chalcogenide thin film electrode , comprising the steps:(a) contacting a metal or metal oxide with an elementary halogen in a non-aqueous solvent, producing a metal halide compound in the solution,(b) applying a negative electric voltage to an electrically conducting or semiconducting substrate which is in contact with the solution from step (a), and(c) during and/or after step (b), contacting the substrate with an elementary chalcogen, forming a metal chalcogenide layer on the substrate.2. The method according to claim 1 , wherein the metal is able to form a metal halide compound in which the metal is present in the oxidation state +2 or higher.3. The method according to claim 1 , wherein in step (b) the metal is deposited onto the substrate by reduction and because of the negative voltage the substrate is an electron transmitter during the reduction.4. The method according to claim 1 , wherein the metal comprises at least one transition metal.5. The method according to claim 1 , wherein the metal is a solid metal body.6. The method according to claim 1 , wherein the elementary chalcogen is elementary oxygen claim 1 , elementary sulphur or elementary selenium.7. The method according to claim 1 , wherein the substrate comprises an n-semiconductor material.8. The method according to claim 1 , wherein the elementary halogen is iodine (I) or bromine (Br).9. The method according to claim 1 , wherein the non-aqueous solvent is an organic solvent.10. The method according to claim 1 , wherein a proportion of water in the non-aqueous solvent is at most 0.2 wt. %.11. The method according to claim 1 , wherein contacting the substrate with the chalcogen is performed by the presence of the chalcogen in the solution or by contacting the substrate with a chalcogen-containing atmosphere.12. The method according to claim 1 , comprising ...

ELECTROSTATIC MODIFICATION REAGENT AND PROCESS FOR ENHANCING ELECTROSTATIC SEPARATION IN THE BENEFICIATION OF ORES

An electrostatic modification reagent and a process for beneficiating a mineral substrate by electrostatic separation as described herein. The electrostatic modification reagent may be used in an electric separation process for separating components from a mineral ore or sand. 2. The electrostatic modification reagent according to claim 1 , wherein the electrostatic modifier comprises a quaternary amine compound according to formula I:{'br': None, 'sub': 1', '2', '3, 'sup': +', '−, 'R(RRR)NX\u2003\u2003(I)'}wherein R comprises from 1 to 50 carbon atoms;{'sub': 1', '2', '3', '1', '10', '6', '10', '7', '10', '10', '18, 'wherein each of R, Rand Rare individually chosen from a member selected from the group consisting of H, C-Calkyl, C-Caryl, C-Caralkyl, and C-Cnaphthylalkyl; and'}wherein X is chosen from a member selected from the group consisting of halide, oxide, sulfide, nitride, hydride, peroxide, hydroxide, cyanide, perchlorate, chlorate, chlorite, hypochlorite, nitrate, nitrite, sulfate, sulfite, phosphate, carbonate, acetate, oxalate, tosylate, cyanate, thiocyanate, bicarbonate, permanganate, chromate, and dichromate.3. The electrostatic modification reagent according to claim 2 , wherein the quaternary amine compound has a number average molecular weight of 700 or less.6. The electrostatic modification reagent according to claim 1 , wherein the electrostatic modifier further comprises a dithiocarbamate compound.10. The electrostatic modification reagent according to claim 1 , wherein the electrostatic modifier further comprises a compound according to formula (IV) and is chosen from a C-Calkyl hydroxamate claim 1 , or salts thereof.11. The electrostatic modification reagent according to claim 10 , wherein the alkyl hydroxamate is selected from the group consisting of mono- claim 10 , di- claim 10 , or tri-hydroxamic acids claim 10 , sodium salts thereof claim 10 , potassium salts thereof claim 10 , and mixtures thereof.13. The electrostatic modification reagent ...

METHOD AND SYSTEM FOR NEUTRALIZING ASBESTOS

The invention relates to a system for neutralizing asbestos, said system comprising a mobile neutralization unit () comprising: 1. A system for asbestos neutralization , that comprises a mobile neutralization unit comprising:a module for sorting of asbestos waste,an asbestos grinder anda bath of hot acid to render the asbestos inert.2. A system according to claim 1 , wherein the module for sorting of asbestos waste comprises:a window equipped with glove boxes anda conveyor to transport the waste in front of the window.3. A system according to claim 1 , that comprises a means of atmospheric containment in the mobile neutralization unit.4. A system according to claim 1 , wherein the bath of hot acid of the mobile neutralization unit comprises sulfuric acid.5. A system according to claim 1 , wherein the hot acid is carried in the hot acid bath of the mobile neutralization unit at a temperature ranging from 70° C. to 100° C.6. (canceled)7. A system according to claim 1 , that comprises a vehicle trailer forming a support to the mobile neutralization unit.8. A system according to claim 1 , that comprises a boat forming a support to the mobile neutralization unit.9. (canceled)10. (canceled)11. (canceled)12. A system according to claim 1 , wherein the mobile neutralization unit comprises in addition:a tank for fresh water;a tank for used water;a decontamination chamber for the operator;a chamber for introduction of asbestos waste anda chamber evacuation of non-asbestos waste issued from the sorting process.13. A system according to claim 2 , wherein the module for sorting of asbestos waste comprises:a workbench,a conveyor anda metal detection unit.14. A system according to claim 1 , wherein the bath of hot acid is contained in a detachable insulated tank of the mobile neutralization unit.15. A system according to claim 14 , that comprises a supply vehicle comprising:a means for the dismounting of a tank from the mobile neutralization unit containing the used acid bath,a ...

POWDER FOR NEGATIVE ELECTRODE OF LITHIUM ION SECONDARY BATTERY, AND METHOD FOR PRODUCING SUCH POWDER

This invention provides a powder for a negative electrode of a lithium ion secondary battery, which is a powder that includes a silicon oxide powder containing Li. When a molar ratio between Li, Si and O is taken as y:1:x, the average composition of the powder overall satisfies the relation 0.5 Подробнее

DEODORANT, DEODORANT COMPOSITION, AND DEODORIZING PRODUCT

It is an object of the present invention to provide a deodorant or a deodorant composition which has excellent deodorizing performance with respect to sulfurous stench from methyl mercaptan and hydrogen sulfide and the like. It is another object of the present invention to provide a deodorant or a deodorant composition which maintains a deodorizing effect with respect to sulfurous stench and which makes it possible to suppress resin deterioration in the case of being kneaded into a resin, and a deodorizing product containing the same. A deodorant of the present invention contains amorphous copper silicate represented by the following formula [1]: 1. A deodorant comprising amorphous copper silicate represented by the following formula [1]:{'br': None, 'sub': 2', '2', '2, 'xNaO.yCuO.SiO.zHO \u2003\u2003[1]'}wherein, in formula [1], x is a positive number from 0.002 to 0.040, y is a positive number from 0.07 to 0.48, and z is a positive number from 0.02 to 0.30.2. The deodorant according to claim 1 , wherein the amorphous copper silicate has a bulk specific gravity of from 0.10 to 0.40 g/ml.3. A deodorant composition comprising the deodorant according to .4. A deodorizing product comprising the deodorant according to .5. A deodorizing product comprising the deodorant composition according to . The present invention relates to a deodorant, a deodorant composition, and a deodorizing product containing the same. Furthermore, in particular, the present invention relates to a deodorant having excellent deodorizing performance with respect to sulfurous stench and a deodorizing product containing the deodorant.In recent years, demands for a comfortable life have been rapidly increasing, and a deodorizing product capable of removing personal stench highly have attracted attention as one of them. Particularly, sulfurous stench which contains a compound containing a sulfur element such as methyl mercaptan or hydrogen sulfide as a main component is disliked because the sulfurous ...

Microporous zirconium silicate for the treatment of hyperkalemia

The present invention relates to novel microporous zirconium silicate compositions that are formulated to remove toxins, e.g. potassium ions, from the gastrointestinal tract at an elevated rate without causing undesirable side effects. The preferred formulations are designed avoid increase in pH of urine in patients and/or avoid potential entry of particles into the bloodstream of the patient. Also disclosed is a method for preparing high purity crystals of UZSi-9 exhibiting an enhanced level of potassium exchange capacity. These compositions are particularly useful in the therapeutic treatment of hyperkalemia.

POSITIVE-ELECTRODE ACTIVE MATERIAL FOR SECONDARY CELL, AND METHOD FOR MANUFACTURING SAME

The present invention provides a positive-electrode active material for a lithium-ion secondary cell or a sodium-ion secondary cell, which can effectively exhibit more excellent charge/discharge characteristics; and a method for manufacturing the positive-electrode active material. Namely, the present invention relates to a positive-electrode active material for a secondary cell comprising an oxide represented by formula (A): LiFeMnMPO, formula (B): LiFeMnMSiO, or formula (C): NaFeMnQPO; and carbon derived from a cellulose nanofiber supported thereon. 1. A positive-electrode active material for a secondary cell , comprising a compound particle represented by the following formula (B):{'br': None, 'sub': 2', 'a', 'b', 'c', '4, 'LiFeMnMSiO\u2003\u2003(B)'}wherein in formula (B), M represents Mg, Ca, Sr, Y, Zr, Mo, Ba, Pb, Bi, La, Ce, Nd or Gd; a, b and c represent numbers satisfying 0≤a≤1, 0≤b≤1 and 0≤c≤0.3, a and b are not simultaneously 0, and 2a+2b+(valence of M)×c=2 is satisfied; andcarbon,wherein the carbon is derived from a cellulose nanofiber and is supported on the compound particle,wherein an amount of the carbon derived from the cellulose nanofiber and supported on the compound particle is from 0.3 to 6 mass %, and{'sub': '50', 'the positive-electrode active material is a product obtained by pyrolyzing a granule S comprising the compound particle and the cellulose nanofiber and having a particle size (Dvalue) of 1 to 15 μm.'}2. The positive-electrode active material for a secondary cell according to claim 1 , wherein claim 1 , in a Raman spectrum claim 1 , an intensity ratio (G/D) of D band and G band is 0.5 to 1.8; or an intensity ratio (SiO/G) of the peak attributed to SiO and G band is 0.01 to 0.10 and no radial breathing mode (RBM) peak is present.34-. (canceled)5. The positive-electrode active material for a secondary cell according to claim 1 , wherein the granule S is a granulated material of a compound particle claim 1 , wherein the compound particle ...

BOROSILICATE NANOPARTICLES AND METHOD FOR MAKING THE SAME

Borosilicate nanoparticles and method of making borosilicate nanoparticles. Advantages of the method include making the borosilicate nanoparticles at temperatures not greater than 200 C. The nanoparticles made are useful, for example, as fillers in coatings, adhesives, and composite articles. 1. A plurality of borosilicate nanoparticles , wherein a majority of the boron of the borosilicate is tetragonally coordinated.2. A composite comprising the plurality of borosilicate nanoparticles of .3. The composite of that includes a thermoplastic polymer matrix.4. The composite of that includes a thermoset polymer matrix.5. The composite of in the form of a layer.7. The method of further comprising diluting the boroxine-silane adduct with at least one solvent prior to acidifying the boroxine-silane adduct.8. The method of claim 6 , wherein the solvent is at least one of a ketone claim 6 , ester claim 6 , alcohol claim 6 , or chlorocarbon.9. The method of claim 6 , wherein acidifying the boroxine-silane adduct is conducted with a carboxylic acid.10. The method of claim 6 , wherein the ratio of B to Si in the boroxine-silane adduct is in a range from 0.2 to 1.5.11. The method of claim 6 , wherein the heating is conducted at any temperature not greater than 200° C.12. The method of claim 6 , wherein the heating is conducted at any temperature not greater than 100° C.13. The method of claim 6 , wherein the heating is conducted at any temperature not greater than 50° C.14. The method of further comprising adding a surfactant of non-ionic claim 6 , cationic claim 6 , or anionic to the boroxine-silane adduct prior to providing the borosilicate network.15. The method of claim 6 , wherein the nanoparticles have particle sizes in a range in size from 5 nanometers to 1000 nanometers.16. The method of claim 6 , wherein a majority of the boron of the borosilicate is tetragonally coordinated. A common method of making borosilicate nanoparticles is involves firing a mixture of boron and ...

Thermal and Environmental Barrier Coating Compositions and Methods of Deposition

A coated substrate is provided that comprises: a substrate; and a barrier coating comprising a compound having the formula: LnABO, where Ln comprises scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, or mixtures thereof; A comprises Si, Ti, Ge, Sn, Ce, Hf, Zr, or a combination thereof; and B comprises Mo, W, or a combination thereof. In one embodiment, B comprises Mo. A gas turbine is also provided that comprises the coated substrate described above. 1. A coated component , comprising:a metal substrate; and {'br': None, 'sub': 2', '8, 'LnABO'}, 'a barrier coating comprising a compound having the formulawhere Ln comprises scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, or mixtures thereof;A comprises Si, Ti, Ge, Sn, Ce, Hf, Zr, or a combination thereof; andB comprises Mo, W, or a combination thereof.2. The coated substrate as in claim 1 , wherein Ln is selected from the group consisting of scandium (Sc) claim 1 , yttrium (Y) claim 1 , lanthanum (La) claim 1 , cerium (Ce) claim 1 , praseodymium (Pr) claim 1 , neodymium (Nd) claim 1 , promethium (Pm) claim 1 , samarium (Sm) claim 1 , europium (Eu) claim 1 , gadolinium (Gd) claim 1 , terbium (Tb) claim 1 , dysprosium (Dy) claim 1 , holmium (Ho) claim 1 , erbium (Er) claim 1 , thulium (Tm) claim 1 , ytterbium (Yb) claim 1 , lutetium (Lu) claim 1 , and mixtures thereof.3. The coated substrate as in claim 1 , wherein Ln comprises yttrium.4. The coated substrate as in claim 1 , wherein B comprises Mo.5. The coated substrate as in claim 4 , wherein the compound has the formula:{'br': None, 'sub': 2', 'x', '1-x', '8, 'LnAMoWO,'}where 0≤x≤about 0.5.6. The coated substrate as in claim 1 , wherein B comprises W or a combination of Mo and W.7. The coated substrate as in claim 6 , ...

MICROPOROUS ZIRCONIUM SILICATE FOR THE TREATMENT OF HYPERKALEMIA

The present invention relates to novel microporous zirconium silicate compositions that are formulated to remove toxins, e.g. potassium ions, from the gastrointestinal tract at an elevated rate without causing undesirable side effects. The preferred formulations are designed avoid increase in pH of urine in patients and/or avoid potential entry of particles into the bloodstream of the patient. Also disclosed is a method for preparing high purity crystals of UZSi-9 exhibiting an enhanced level of potassium exchange capacity. These compositions are particularly useful in the therapeutic treatment of hyperkalemia. 146-. (canceled)47. A cation exchange composition comprising a zirconium silicate wherein the composition exhibits an x-ray powder diffraction spectrum indicating at least the following d-spacing values:a first d-spacing within the range of 2.7-3.5 angstroms having a first intensity value,a second d-spacing within the range of 5.3-6.1 having a second intensity value, wherein the second intensity value is less than the first intensity value,a third d-spacing within the range of 1.6-2.4 angstroms having a third intensity value,a fourth d-spacing within the range of 2.0-2.8 angstroms having a fourth intensity value, anda fifth d-spacing within the range of 5.9-6.7 angstroms having a fifth intensity value, wherein the third, fourth, and fifth intensity values are each lower than the first and second intensity values, wherein the composition exhibits a median particle size of greater than 3 microns, and the composition exhibits a sodium content below 12% by weight.48. The composition of claim 47 , wherein less than 7% of the particles in the composition have a diameter less than 3 microns.49. The composition of claim 47 , wherein less than 4% of the particles in the composition have a diameter less than 3 microns.50. The composition of claim 47 , wherein less than 1% of the particles in the composition have a diameter less than 3 microns.51. The composition of ...

STORAGE STABLE MIXTURES

The present invention relates to improved formulations of propandiol mononitrate and derivatives thereof as well as to the production of such formulations. 2. The storage stable mixture according to claim 1 , wherein the compound according to formula (I) is propandiol mononitrate.3. The storage stable mixture according to claim 1 , wherein the at least one clay mineral is selected from the group consisting of Bentonite claim 1 , Sepiolite Kaolinite claim 1 , and Montmorillonite claim 1 , preferably from Bentonite and Sepiolite as well as mixtures thereof.4. The storage stable mixture according to claim 1 , wherein the weight-ratio of the mineral clay to the powderous formulation is selected in the range of 100:1 to 1:1 claim 1 , preferably in the range of 40:1 to 1:2 claim 1 , most preferably in the range of 30:1 to 1:1 or 20:1 to 1:1.5. The storage stable mixture according to claim 1 , wherein the powderous formulation consists essentially of(i) 2 to 20 wt-%, based on the total weight of the powderous formulation, of a compound of formula (I), and(iii) at least 25 wt-%, based on the total weight of the powderous formulation, of silica, and(iv) 10 wt-% to 45 wt-%, based on the total weight of the powderous formulation, of an edible oil, and(v) 0 to 10 wt-%, based on the total weight of the powderous formulation, of an additive.6. The storage stable mixture according to claim 5 , wherein the edible oil in the powderous formulation is selected from the group consisting of propyleneglycol claim 5 , canola oil claim 5 , corn oil claim 5 , rapeseed oil claim 5 , sunflower oil claim 5 , middle chain triglyceride (MCT) and glycerol as well as mixtures thereof.7. The storage stable mixture according to claim 5 , wherein the additive is a thickener selected from the group consisting of gums and/ or cellulose derivatives claim 5 , preferably from xanthan gum claim 5 , karaya gum and/or ethylcellulose.8. The storage stable mixture according to claim 5 , wherein the edible oil ...

Systems, Devices, and/or Methods for Reactive Nano Silicate

Certain exemplary embodiments can provide a reactive nano silicate, which can comprise a silica/acid composite comprising reactive functional groups activated by an intramolecular disturber. The reactive functional groups can comprise at least one of —SiH, —SiOH, silazane, durazane, polysilazane, and spiro silazane. The intramolecular disturber can comprise at least one of FeO, XeO, SnO, AlO, SiO, TiO, or a rare earth element oxide. 1. A reactive nano silicate , comprising: the reactive functional groups comprise at least one of —SiH, —SiOH, silazane, durazane, polysilazane, spiro silazane;', {'sub': 2', '3', '2', '2', '2', '3', '2', '2, 'the intramolecular disturber is an oxide that comprises at least one of FeO, XeO, SnO, AlO, SiO, TiO, or rare earth element oxide.'}], 'a silica/acid composite comprising reactive functional groups activated by an intramolecular disturber, wherein2. The reactive nano silicate of claim 1 , wherein:the reactive nano silicate exhibits intramolecular interaction caused by the reactive functional groups.3. The reactive nano silicate of claim 1 , wherein:the reactive nano silicate exhibits film forming properties.4. The reactive nano silicate of claim 1 , wherein:the reactive nano silicate exhibits water proofing properties.5. The reactive nano silicate of claim 1 , wherein:the reactive nano silicate exhibits flame retardant properties.6. The reactive nano silicate of claim 1 , wherein:the reactive nano silicate exhibits heat resistant properties.7. The reactive nano silicate of claim 1 , wherein:the reactive nano silicate exhibits UV blocking properties.8. The reactive nano silicate of claim 1 , wherein:the reactive nano silicate exhibits weather resistant properties.9. The reactive nano silicate of claim 1 , wherein:the reactive nano silicate is reactive with a polymer.10. The reactive nano silicate of claim 1 , wherein:the reactive nano silicate is reactive with a hydroxylated material.11. The reactive nano silicate of claim 1 , ...

Corrosion resistant coatings containing an amorphous phase

The disclosure relates to the forming mineralized coatings on metal surfaces and to methods of forming such coatings. The coating can include a wide range of compounds and normally at least a portion of the coating corresponds to an amorphous phase. The coating and method are particularly useful in providing a corrosion resistant coating or film upon a metallic surface. This aspect of the disclosure involves the formation of a corrosion resistant "mineralized" layer of tailored composition upon a metal substrate.

PREPARATION METHOD OF SILICON-BASED COMPOSITE NEGATIVE ELECTRODE MATERIAL FOR LITHIUM BATTERY

A preparation method of silicon-based composite negative electrode material for a lithium battery includes the following steps: forming steam from a raw material A containing Si and a reducing substance raw material B capable of reacting to generate a silicate under a vacuum heating condition, condensing and depositing in a deposition system after a reaction, and then carrying out carbon coating to obtain the silicon-based composite material. A certain amount of alloy is added into the raw material B, so that a proportion of a crystal region in the silicon-based composite material can be reduced, and the initial coulombic efficiency and the cycling stability of the negative electrode material are further improved. 1. A preparation method of a silicon-based composite negative electrode material for a lithium battery , comprising the following steps:{'sub': x', 'x, '(1) drying a raw material A capable of generating SiO(0 Подробнее

Silica-clay complexes

A clay composition comprising silica intercalated between the interlayers of the clay.

Silica-metal oxide co-gels

1356248 Silica-metal oxide cogels; metal silicate gels ZIRCONAL PROCESSES Ltd 21 Oct 1971 [5 Nov 1970] 52694/70 Headings C1A and C1J An acid hydrolysate of an organic silicate is prepared by hydrolysing the organic silicate with an acidic aqueous solution of a soluble salt (e.g. chloride) of the alkaline earth metals, zinc, aluminium, zirconium or chromium, no metallic compounds being precipitated during hydrolysis. The hydrolysate may be gelled by the action of an alkaline medium or by leaving to stand (Examples 3 and 6). The gel may be a silicametal oxide cogel or a metal silicate gel. The silicates may be C 1 -C 6 alkyl orthosilicates, polysilicates or ethyl silicate (a mixture of ethyl orthosilicate and ethyl polysilicate). The gelling may be carried out by the action of aqueous ammonia (Example 1), an aqueous suspension of alkaline earth metal oxide, e.g. MgO (Example 2) an aqueous solution of ammonium acetate (Examples 6, 7, 8 and 9) or the same solution containing NH 3 (Examples 4 and 5). The aqueous solvent may contain a water miscible monohydric alcohol and a strong non-oxidizing acid. In Example I MgCl 2 (10 g) was dissolved in N-hydrochloric acid (40 ml.) then ethyl alcohol (220 ml.) and ethyl silicate (160 ml.) were added. The mixture was gelled by aqueous ammonia. In Example IX hydrated magnesium acetate is used for preparing the mixed silica and magnesia gel. Examples II, III, IV, V, VI and VII illustrate the preparation of gels formed from silica and alumina, silica and zirconia, silica and calcium oxide, silica and chromium oxide, silica and zinc oxide using the respective metal chlorides (oxychloride in the case of zirconium). Refractory compositions, wherein the silica gel is used as a binder may be made from aluminium oxide or silicate, zirconium oxide, zircon, crystalline silicon oxide, silicon carbide, spinel, magnesite, or chrome magnesite. Examples I and VIII exemplify the preparation of sillimanite compositions, Examples VI an alumina ...

一种采用两步法合成Yb2Si2O7粉体的方法

一种采用两步法合成Yb 2 Si 2 O 7 粉体的方法，属于材料制备技术领域，包括以下步骤：1)取Yb(NO) 3 ·5H 2 O加水配成溶液A；取Na 2 SiO 3 ·9H 2 O溶于水中制得溶液B；按将NaOH溶于水中，制得溶液C；2)将溶液B、溶液C依次加入溶液A中，充分搅拌均匀，制得溶液D；3)将溶液D水热反应后冷却至室温，将反应液水洗、抽滤，制得粉体A；将粉体A烘干后，得到粉体B；4)将粉体B与Na 2 MoO 4 ·2H 2 O混匀后，于750～950℃下反应，制得粉体C；5)将粉体C加水溶解后，离心去除熔盐，然后经洗涤、干燥，制得Yb 2 Si 2 O 7 粉体。该方法操作简单，易控制，合成温度低，能够制备出粒径适宜的硅酸镱(Yb 2 Si 2 O 7 )粉体。

Metal complex and supported metal complex having disiloxane as ligand, method for production thereof, and supported metal catalyst prepared by using the same

하기 일반식(1)으로 나타내어지는 금속착체. (식 중, M은 팔라듐 또는 백금, L은 일산화탄소, 올레핀 화합물, 아민 화합물, 포스핀 화합물, N-복소환식 카르벤 화합물, 니트릴 화합물, 이소시아니드 화합물에서 선택되는 배위자, n은 배위자의 개수를 나타내는 0~2의 정수, R 1 ~R 4 는 유기기를 나타낸다.) 상기 금속착체는 그 골격 구조를 유지한 상태로 무기 산화물에 고정화되어 담지 금속착체로 할 수 있고, 이것에 의해 상기 담지 금속착체는 본래의 금속착체가 갖는 것과 동등한 촉매 활성을 유지할 수 있다. 또한, 이렇게 하여 얻어진 담지 금속착체를 소성함으로써, 종래의 담지 금속 촉매보다 촉매 활성이 대폭 향상된 담지 금속 촉매를 얻을 수 있다. A metal complex represented by the following general formula (1). (Wherein M is palladium or platinum, L is carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound, an isocyanide compound and n is the number of ligands And R 1 to R 4 represent an organic group. The metal complex may be immobilized on the inorganic oxide with keeping its skeletal structure to form a supported metal complex, whereby the supported metal complex can maintain the same catalytic activity as that of the original metal complex. Further, by calcining the thus obtained supported metal complex, it is possible to obtain a supported metal catalyst in which the catalytic activity is significantly improved as compared with the conventional supported metal catalyst.

超细硅酸锆粉末及其制备方法

本发明涉及一种超细硅酸锆粉末及其制备方法，制备方法包括如下步骤：一次研磨：选用φ10‑20mm的氧化铝球，湿法研磨将锆英砂研磨至D50为1.5‑3.0μm；二次研磨：选用φ4‑8mm的硅酸锆球和/或氧化锆球，将物料研磨至D50为0.9‑1.1μm；三次研磨：选用φ0.6‑1.5mm的硅酸锆球和/或氧化锆球，将物料研磨至D50为0.6‑0.8μm；干燥即得所述超细硅酸锆粉末。采用上述制备方法，通过三次分段研磨技术，可生产出D50为0.6～0.8的亚微米级超细硅酸锆乳浊剂，产品的氧化锆与氧化铪总含量(ZrHf)2≥65.5％，Fe 2 O 3 ≤0.05％，TiO 2 ≤0.13％，Al 2 O 3 ≤0.5％。

Method of obtaining geopolymer with controllable porosity, obtained geopolymer and different versions of its application

FIELD: chemistry. SUBSTANCE: invention relates to field of geopolymers. Objects of claimed invention are: method of geopolymer obtaining, geopolymer, obtained by said method, catalytic substrate or substrate for separation of chemical compounds, application of geopolymer in field of catalysis and filtering. Method of geopolymer obtaining contains the following successive stages, at which characteristic of general porosity of obtained geopolymer is specified; value for, at least, one parameter, selected from the group, including total quantity of water and granulometric composition of optional silicate components, which makes it possible to obtain claimed characteristic of general porosity, is determined; said preliminarily defined value is selected. Method also contains stage of dissolving/polycondensation of silica-alumina raw material in activating solution, which, if necessary, can contain silicate components. Geopolymer has monomodal mesoporosity with 50% pores, which have available diameter, determined by mercury porosimetry, spread for less than 5 nm (narrow distribution of pore size) or has monomodal macroporosity with 50% pores, which have available diameter, spread for less than 10 nm (narrow distribution of pore size) or for from 10 to 50 nm (wider distribution of pore size). EFFECT: method makes it possible to obtain geopolymers in form of monolithic materials, porosity of which can be regulated still at the stage of mixture composition preparation. 22 cl, 3 dwg, 4 tbl, 5 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 503 617 (13) C2 (51) МПК C01B 33/26 C04B 38/04 (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2010119693/04, 15.10.2008 (24) Дата начала отсчета срока действия патента: 15.10.2008 (72) Автор(ы): ФРИЗОН Фабьен (FR), ЖУССО ДЮБЬЕН Кристоф (FR) (43) Дата публикации заявки: 27.11.2011 Бюл. № 33 (56) Список документов, цитированных в отчете о поиске: Peter Duxson, John Provis, ...

一种陶瓷乳浊剂专用硅酸锆的制备方法

本发明涉及一种硅酸锆的制备方法，尤其涉及一种陶瓷乳浊剂专用硅酸锆的制备方法，属于陶瓷材料制备技术领域。本发明首先将玉米淀粉、谷朊粉和成面团，经发面后冷冻粉碎，再经炭化及活化后制得多孔活化炭化料，随后与正硅酸乙酯等超声混合，经反应后制得前驱体混合液A，接着将八水氧氯化锆与氟化锂等与水混合，制得前驱体混合液B，再将前驱体混合液A与B混合后于反应釜中高温搅拌反应，将产物过滤干燥后煅烧即可。本发明所得陶瓷乳浊剂专用硅酸锆纯度高，可达98.2%以上，粒度小，力度分布范围窄，粒径为400～500nm，折射率可达1.96～2.01。

Mixed gels composed of silicon dioxide and metal oxides and methods of making them

Vapor deposition of metal oxides, silicates and phosphates, and silicon dioxide

Metal silicates or phosphates are deposited on a heated substrate by the reaction of vapors of alkoxysilanols or alkylphosphates along with reactive metal amides, alkyls or alkoxides. For example, vapors of tris(tert-butoxy)silanol react with vapors of tetrakis(ethylmethylamido) hafnium to deposit hafnium silicate on surfaces heated to 300° C. The product film has a very uniform stoichiometry throughout the reactor. Similarly, vapors of diisopropylphosphate react with vapors of lithium bis(ethyldimethylsilyl)amide to deposit lithium phosphate films on substrates heated to 250° C. Supplying the vapors in alternating pulses produces these same compositions with a very uniform distribution of thickness and excellent step coverage.

包含金属的制剂

包含具有选自原子序数21‑31、39‑50、57‑82和89‑93的原子序数的金属的离子的硅酸盐水溶液及制备该溶液的方法。这种溶液可用于例如形成包含金属的涂层。

Pyrogenically Produced Silicon Dioxide Powder

200±25 m 2 /g의 BET 표면적을 갖는 일차 입자의 응집체 형태의 발열 제조된 이산화규소 분말로서, 응집체가 7000 내지 12000 nm 2 의 평균 표면적, 80 내지 100 nm의 평균 등가 원 직경(ECD), 및 850 내지 1050 nm의 평균 원주를 나타내는 발열 제조된 이산화규소 분말이 제공된다. An exothermic manufactured silicon dioxide powder in the form of an aggregate of primary particles having a BET surface area of 200 ± 25 m 2 / g, wherein the aggregate has an average surface area of 7000 to 12000 nm 2 , an average equivalent circle diameter (ECD) of 80 to 100 nm, And exothermicly produced silicon dioxide powders exhibiting an average circumference of 850-1050 nm. 그것은 사염화규소, 및 H 3 SiCl, H 2 SiCl 2 , HSiCl 3 , CH 3 SiCl 3 , (CH 3 ) 2 SiCl 2 , (CH 3 ) 3 SiCl 및(또는) (n-C 3 H 7 )SiCl 3 을 포함하는 제2 규소 성분이 일차 공기 및 연소 기체와 혼합되어, 반응실에 연소되어 들어가며, 이차 공기도 역시 반응실에 도입되고, 1570 내지 1630℃의 단열 화염 온도가 수득되도록 공급 원료가 선택되는 발열 방법에 의해 제조된다. It includes silicon tetrachloride, and H 3 SiCl, H 2 SiCl 2 , HSiCl 3 , CH 3 SiCl 3 , (CH 3 ) 2 SiCl 2 , (CH 3 ) 3 SiCl and / or (nC 3 H 7 ) SiCl 3 The exothermic method in which the second silicon component is mixed with the primary air and the combustion gas, combusted into the reaction chamber, the secondary air is also introduced into the reaction chamber, and the feedstock is selected so that an adiabatic flame temperature of 1570-1630 ° C is obtained. Is prepared by. 그것은 충전제로서 사용될 수 있다. It can be used as a filler. 이산화규소, 발열 제조, 응집체, 폴리에스테르, 실리콘 고무 Silicon Dioxide, Exothermic Manufacturing, Aggregates, Polyester, Silicone Rubber

Molded product for absorbing liquid

Vapor deposition of oxides, silicates, and phosphates

금속 규산염 또는 인산염들은, 알콕시 실라놀 또는 알킬 포스페이트의 증기와 반응성 있는 금속 아마이드,알킬 또는 알콕사이드와의 반응에 의해 가열된 기질상에 석출되어 진다. 예를 들면, 트리스(tert-부톡시)실라놀의 증기와 테트라키스 (에틸메틸아미도)하프늄의 증기가 반응하여 300℃로 가열된 표면위에서 하프늄규산염을 석출시킨다. 생성된 막은 반응기 전체를 통해 매우 균일한 화학양론을 갖는다. 이와 유사하게, 디이소프로필 포스페이트의 증기는 리튬비스(에틸메틸아미도)아마이드의 증기와 반응하여 250℃로 가열된 표면위에서 리튬인산염을 석출시킨다. 증기 펄스들을 교대로 공급함으로써, 매우 균일한 두께 분포와 탁월한 단계적 피막을 갖는 상기와 합성물이 생산된다. 증기 석출, CVD, ALD, 휘발성 화학 전구체, 금속 규산염, 금속 인산염, 하프늄,이트륨, 지르코늄, 란탄 Metal silicates or phosphates are precipitated on a heated substrate by reaction with metal amides, alkyls or alkoxides reactive with vapors of alkoxy silanol or alkyl phosphates. For example, steam and tetrakis of tris (tert-butoxy) silanol (Ethyl methyl amido) The vapor of hafnium reacts to precipitate hafnium silicate on the surface heated to 300 degreeC. The resulting membrane has a very uniform stoichiometry throughout the reactor. Similarly, the vapor of diisopropyl phosphate reacts with the vapor of lithium bis (ethylmethylamido) amide to precipitate lithium phosphate on a surface heated to 250 ° C. By alternately supplying steam pulses, the above and the composites are produced with a very uniform thickness distribution and an excellent stepwise coating. Vapor deposition, CVD, ALD, volatile chemical precursors, metal silicates, metal phosphates, hafnium, yttrium, zirconium, lanthanum

Spherical Silica Magnetic Particles and Manufacturing Method Thereof

본 발명은 구형 실리카 자성입자 및 이의 제조방법에 관한 것으로서, 보다 구체적으로는 비극성용매에 계면활성제, 가용성규산염 수용액, 및 자성입자를 첨가한 후, 초음파로 분산하여 에멀젼을 제조하는 단계, 상기 에멀젼에 지방산(Fatty Acid)을 첨가하여 실리카 자성입자를 제조하는 단계를 포함하며, 부가적으로 상기 실리카 자성입자 표면에 기능기를 도입하는 단계를 더 포함하는 구형 실리카 자성입자의 제조방법 및 이와 같이 제조된 구형 실리카 자성입자에 관한 것이다. The present invention relates to spherical silica magnetic particles and a method for preparing the same, and more specifically, to a surfactant, a soluble silicate aqueous solution, and magnetic particles are added to a nonpolar solvent, and then dispersed by ultrasonication to prepare an emulsion, in the emulsion. A method for producing spherical silica magnetic particles, comprising the step of preparing a silica magnetic particle by adding a fatty acid, and additionally including introducing a functional group on the surface of the silica magnetic particle, and the spherical silica prepared as described above. It relates to silica magnetic particles. 본 발명에 의해 제조된 구형 실리카 자성입자는 자성입자를 함유하고 부가적으로 표면에 기능기를 갖는 실리카 입자로서 입자의 크기 분포가 균일한 장점이 있으며, 바이오 물질 분리용 시약 및 바이오 물질 검출 시약으로 사용될 수 있다. The spherical silica magnetic particles prepared by the present invention have the advantage of uniform particle size distribution as silica particles containing magnetic particles and additionally having functional groups on the surface, and can be used as biomaterial separation reagents and biomaterial detection reagents. Can be. 자성입자, 실리카, 에멀젼, 기능기, 분리 Magnetic Particle, Silica, Emulsion, Functional Group, Separation

Magnesium fluoride doped hollow silica composites with low dielectric constant, process of the composites, forming solution containing the composites and low dielectric constant substrate manufactured by the solution

PURPOSE: Magnesium fluoride doped hollow silica composite, a method for preparing the same, a forming solution including the same, and a low dielectric constant substrate manufactured based on the forming solution are provided to prevent the penetration of organic solvent and resin into pores. CONSTITUTION: Magnesium fluoride doped hollow silica composite is represented by chemical formula 1. In chemical formula 1, a is the weight ratio of the magnesium fluoride which is doped to silica and is between 0.005 and 0.25. The average diameter of the hollow silica composite is between 10 and 500nm. The shell thickness of the hollow silica composite is between 5 and 100nm. A method for preparing the hollow silica composite includes the following: magnesium fluoride doped hollow silica composite sol is prepared; the composite sol is reacted with hydrotalcite sol to form inorganic particulates composed of the shells of magnesium fluoride doped silica and the cores of hydrotalcite; and the hydrotalcite is removed from the inorganic particulates.

一种锂电池正极材料Li2FeSiO4及其制备方法

本发明公开了一种锂电池正极材料Li 2 FeSiO 4 及其制备方法，涉及锂电池技术领域。本发明方法包括：按化学计量比将锂盐、铁盐及第三种原料混合得到第一混合物；第三种原料为正硅酸乙酯或二氧化硅；第一混合物在空气中并且温度为300℃‑500℃的条件下预烧2h‑10h后，粉碎过筛再混合得到第二混合物；第二混合物在真空、惰性气体或还原气体中并且温度为700℃‑1200℃的条件下烧结2h‑24h得到第一产物；第一产物在真空或惰性气体且温度为300℃‑600℃的条件下保温2h‑72h后的第二产物即为锂电池正极材料Li 2 FeSiO 4 。本发明方法制备的Li 2 FeSiO 4 的导电性和电池容量性能均较好。

Method for producing inorganic compounds

本发明涉及化合物(I)A a M m (YO 4 ) y Z z (I)，其中：A代表至少一种选自以下组中的元素：碱金属、碱土金属、掺杂剂元素和空隙；M代表(T 1-t T′ t )，T代表一种或多种过渡金属，而T′代表至少一种选自以下组中的元素：Mg、Ca、Al和稀土元素，0≤t＜1；Y代表至少一种选自以下组中的元素：S、Se、P、As、Si、Ge和Al；Z代表至少一种选自以下组中的元素：F、O和OH；a、m、y和z是0或更大的整数，使得式(I)的无机氧化物遵守电中性；a≥0；m＞0；y＞0；z≥0。所述化合物(I)是由构成元素的前体通过包括以下步骤的方法获得的：将所述前体分散在包含一种或多种由电荷平衡的阳离子和阴离子组成的离子液体的载体液体中，以获得所述前体在所述液体中的悬浮液；加热所述悬浮液到25至380℃的温度；及将所述离子液体和来自所述前体的反应的式(I)的无机氧化物分离。

Cesium or / and strontium adsorbent

セシウム及びストロンチウムの吸着性能を有し、特に、ストロンチウムを低濃度で含有する水等の媒体から、ストロンチウムを効率よく吸着できる吸着剤、及び該吸着剤の製造に好適な吸着剤の製造方法を提供すること。 本発明のセシウム又は／及びストロンチウム吸着剤は、一般式；Ａ ２ Ｔｉ ２ Ｏ ３ （ＳｉＯ ４ ）・ｎＨ ２ Ｏ（式中、ＡはＮａ及びＫから選ばれる１種又は２種のアルカリ元素を示す。ｎは０以上２以下の数を示す。）で表される結晶性シリコチタネートに第５族元素Ｍが含有されている第５族元素Ｍ含有結晶性シリコチタネートを含むストロンチウム吸着剤であって、２θ＝１１°以上１２°以下のメーンピークの半値幅が０．３２０°以下で、且つＣｕ−ＫαをＸ線源に用いて回折角（２θ）が５°以上８０°以下の範囲でＸ線回析測定したときに、２θ＝２９°以上３０°以下の範囲にピークが観察されない。 Provided is an adsorbent capable of adsorbing strontium efficiently from a medium such as water having cesium and strontium adsorption performance, and containing strontium in a low concentration, and a method for producing the adsorbent suitable for producing the adsorbent. To do. The cesium or / and strontium adsorbent of the present invention has a general formula; A 2 Ti 2 O 3 (SiO 4 ) · nH 2 O (wherein A represents one or two alkaline elements selected from Na and K). N is a strontium adsorbent containing a group 5 element M-containing crystalline silicotitanate in which a group 5 element M is contained in a crystalline silicotitanate represented by The half-width of the main peak of 2θ = 11 ° to 12 ° is 0.320 ° or less, and the diffraction angle (2θ) is in the range of 5 ° to 80 ° using Cu-Kα as an X-ray source. When X-ray diffraction measurement is performed, no peak is observed in the range of 2θ = 29 ° to 30 °.

Metal complex and supported metal complex having disiloxane as ligand, preparation method therefor, and supported metal catalyst prepared using same

以下通式(1)表示的金属络合物：[化学式1] (其中M表示钯或铂；L表示选自一氧化碳、烯烃化合物、胺化合物、膦化合物、N-杂环卡宾化合物、腈化合物和异腈化合物的配体；n表示显示所述配体数目的0至2的整数；以及R 1 至R 4 各自表示有机基团)。上述金属络合物可以固定在无机氧化物上且同时保持其骨架结构以获得负载型金属络合物，并且这可以允许所述负载型金属络合物保持与原始金属络合物相同的催化活性。此外，煅烧以上述方式获得的负载型金属络合物，可以获得负载型金属催化剂，其与常规的负载型金属催化剂相比在催化活性上有大幅提高。

Patent JPH0572326B2

Method for synthesizing the mesoporous silicate having a macropores and its application to adsorbent of vocs

본 발명은 매크로 크기의 기공을 갖는 메조/매크로포러스 실리케이트의 제조 방법과 이를 이용한 휘발성 유기화합물의 흡착제에 관한 것이다. 본 발명의 메조/매크로포러스 실리케이트는 매크로 기공의 벽 부분이 매우 규칙적으로 배열된 메조 기공 구조체로 이루어져 있다. 본 발명의 메조/매크로포러스 실리케이트는 메조 기공을 만들기 위한 액정 템플릿(liquid crystal template)과 매크로 기공을 만들기 위한 콜로리달 결정 템플릿(colloidal crystal template)이 결합된 이중 템플리팅(dual templating) 방법으로 합성하였다. 본 발명의 메조/매크로포러스 실리케이트는 메조 기공으로부터 오는 장점인 넓은 표면적에 의한 높은 흡착 능력뿐만 아니라 매크로 기공으로부터 오는 물질전달이 용이한 장점을 갖기 때문에 휘발성 유기화학물이 보다 빠르게 흡착점으로 도달하고 온도가 올라가면 탈착 후 흡착점으로부터 더 빠르게 빠져나와 쉽게 제거될 수 있다. 이러한 점에서 메조/매크로포러스 실리케이트는 휘발성 유기화합물 처리를 위한 흡착제로서 이용될 수 있다.

ACCOMMODATION

A kind of preparation method of zinc silicate hollow sub-microsphere

本发明公开了一种硅酸锌空心微米球的制备方法。该方法首先将硫脲溶液加入到醋酸锌溶液中，混合均匀，在温度为100～220℃条件下水热反应6～30h，制备出单分散硫化锌微米球；将单分散硫化锌微米球干燥，在搅拌下依次加入乙醇、氨水和正硅酸乙酯，搅拌后，制备出单分散硫化锌@二氧化硅核壳结构球，干燥后在800～1000℃中煅烧18‑48h，得到硅酸锌空心微米球。本发明通过简单水热法制备硫化锌微米球，再将硫化锌微米球进行二氧化硅包覆得到硫化锌@二氧化硅核壳结构球，最后煅烧得到硅酸锌空心微米球；制备方法新颖，反应过程不需表面活性剂，所得颗粒纯度高，尺寸可控、均匀，分散性好。

Vapor deposition of metal oxides, silicates and phosphates, and silicon dioxide

Metal silicates or phosphates are deposited on a heated substrate by the reaction of vapors of alkoxysilanols or alkylphosphates along with reactive metal amides, alkyls or alkoxides. For example, vapors of tris(tert-butoxy)silanol react with vapors of tetrakis(ethylmethylamido)hafnium to deposit hafnium silicate on surfaces heated to 300° C. The product film has a very uniform stoichiometry throughout the reactor. Similarly, vapors of diisopropylphosphate react with vapors of lithium bis(ethyldimethylsilyl)amide to deposit lithium phosphate films on substrates heated to 250° C. Supplying the vapors in alternating pulses produces these same compositions with a very uniform distribution of thickness and excellent step coverage.

Mixing reactive liquids and preparing coagulant aids

An apparatus and process for the preparation of colloidal dispersions of sodium metallo silicates, useful as coagulant aids, are disclosed. The dispersions are prepared by the controlled sequential mixing of separate streams of water, sodium silicate and a metal salt in a mixing block that has no moving parts. The apparatus and process are also useful in the mixing of other reactive solutions and fluids.

Zircon components

유리 제조에서 사용을 위한 지르콘 몸체가 제공되며, 지르콘 몸체는 지르콘 그레인과 그 지르콘 그레인들 사이에 존재하는 입계상을 함유한다. 입계상은 실리콘 산화물을 함유할 수 있다. 몸체는 외측부로부터 입계상에 함유된 실리콘 산화물의 적어도 대부분을 적어도 부분적으로 제거하기 위해 또는 부품으로부터 외측부를 따라 입계상을 적어도 부분적으로 제거하기 위해 할로겐화물에 노출될 수 있다. A zircon body for use in glass making is provided, the zircon body containing a zircon grain and an intergranular phase present between the zircon grains. The grain boundary phase may contain silicon oxide. The body may be exposed to the halide to at least partially remove at least a majority of the silicon oxide contained in the intergranular phase from the outer side or at least partially remove the intergranular phase along the lateral side from the component.

Lithium battery cathode material Li2FeSiO4And method for preparing the same

本发明公开了一种锂电池正极材料Li 2 FeSiO 4 及其制备方法，涉及锂电池技术领域。本发明方法包括：按化学计量比将锂盐、铁盐及第三种原料混合得到第一混合物；第三种原料为正硅酸乙酯或二氧化硅；第一混合物在空气中并且温度为300℃‑500℃的条件下预烧2h‑10h后，粉碎过筛再混合得到第二混合物；第二混合物在真空、惰性气体或还原气体中并且温度为700℃‑1200℃的条件下烧结2h‑24h得到第一产物；第一产物在真空或惰性气体且温度为300℃‑600℃的条件下保温2h‑72h后的第二产物即为锂电池正极材料Li 2 FeSiO 4 。本发明方法制备的Li 2 FeSiO 4 的导电性和电池容量性能均较好。

Adsorbent

【課題】海水においてもＣｓ及びＳｒの吸着除去特性に優れた吸着材、及び該吸着材に好適な結晶性シリコチタネートの製造方法を提供すること。【解決手段】本発明の吸着材は、Ｎａ4Ｔｉ4Ｓｉ3Ｏ16・ｎＨ2Ｏ、（ＮａxＫ(1-x)）4Ｔｉ4Ｓｉ3Ｏ16・ｎＨ2Ｏ及びＫ4Ｔｉ4Ｓｉ3Ｏ16・ｎＨ2Ｏ（これらの式中、ｘは０超１未満の数を示し、ｎは０〜８の数を示す。）で表される結晶性シリコチタネートから選ばれる少なくとも一種と、Ｎａ4Ｔｉ9Ｏ20・ｍＨ2Ｏ、（ＮａyＫ(1-y)）4Ｔｉ9Ｏ20・ｍＨ2Ｏ及びＫ4Ｔｉ9Ｏ20・ｍＨ2Ｏ（ｙは０超１未満の数を示し、ｍは０〜１０の数を示す。）で表されるチタン酸塩から選ばれる少なくとも一種とを含む。該吸着材は、ケイ酸源と、ナトリウム及び／又はカリウム化合物と、四塩化チタンと、水とを混合して混合ゲルを得、該混合ゲルを水熱反応させる結晶性シリコチタネートの製造方法により好適に製造される。【選択図】図２ To provide an adsorbent excellent in Cs and Sr adsorption removal characteristics even in seawater, and a method for producing crystalline silicotitanate suitable for the adsorbent. The adsorbents of the present invention are Na4Ti4Si3O16.nH2O, (NaxK (1-x)) 4Ti4Si3O16.nH2O and K4Ti4Si3O16.nH2O (wherein x is a number greater than 0 and less than 1, n is 0) And at least one selected from crystalline silicotitanates represented by: Na4Ti9O20 · mH2O, (NayK (1-y)) 4Ti9O20 · mH2O and K4Ti9O20 · mH2O (y is more than 0 and less than 1) And m represents a number of 0 to 10.) and at least one selected from titanates represented by: The adsorbent is obtained by mixing a silicic acid source, a sodium and / or potassium compound, titanium tetrachloride, and water to obtain a mixed gel, and hydrolyzing the mixed gel by a method for producing crystalline silicotitanate. It is preferably manufactured. [Selection] Figure 2

Mixed metallic oxides as scavengers for fluorinated ion exchange polymers

무기 관능기 -SO 3 H를 포함하는, Si의 산화물과 적어도 1종의 금속 M의 산화물의 혼합 산화물이다. 이렇게 혼합 산화물을 황산 관능기-함유 플루오르화 중합체에 첨가하면, 연료전지 적용분야에서 상기 중합체를 사용할 때 라디칼 분해에 대한 중합체의 안정성이 향상된다. It is a mixed oxide of an oxide of Si and an oxide of at least one metal M containing an inorganic functional group -SO 3 H. The addition of the mixed oxide to the sulfuric acid functional group-containing fluorinated polymer improves the stability of the polymer against radical decomposition when using the polymer in fuel cell applications.

Oxide Material, Method for Preparing Oxide Thin Film and Element Using Said Material

본 발명은 퍼로브스카이트 또는 층형 퍼로브스카이트 구조 산화물에 Si, Ge 및 Sn으로 이루어지는 군에서 선택되는 1종 이상의 IV족 원소를 함유하는 촉매 물질이 고용하여 형성된 산화물 재료에 관한 것이다. 본 발명에 따르면, 퍼로브스카이트 또는 층형 퍼로브스카이트 구조 산화물 재료를 저온에서 결정화할 수 있고, 이들 산화물 재료의 특성을 유지 또는 개선할 수 있다. The present invention relates to an oxide material formed by solid solution of a catalytic material containing at least one group IV element selected from the group consisting of Si, Ge, and Sn in a perovskite or layered perovskite structure oxide. According to the present invention, the perovskite or layered perovskite structure oxide materials can be crystallized at low temperatures, and the properties of these oxide materials can be maintained or improved.

Oriented apatite oxide ion conductor and method for producing same

为了提供一种新的取向性磷灰石型氧化物离子导体，该取向性磷灰石型氧化物离子导体可以抑制裂纹的产生而实现大面积化，优选通过不复杂的工艺低成本地进行制造，从而提出了一种由复合氧化物构成的取向性磷灰石型氧化物离子导体，该复合氧化物的特征在于，其由A 9.33+x [T 6‑y M y ]O 26.00+z (式中的A为选自由La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Be、Mg、Ca、Sr和Ba组成的组中的一种或两种以上的元素。式中的T为Si或Ge或包含其两者的元素。式中的M为选自由B、Ge、Zn、Sn、W和Mo组成的组中的一种或两种以上的元素。)表示，式中的x为‑1～1，式中的y为1～3，式中的z为‑2～2，A的摩尔数相对于M的摩尔数的比例(A/M)为3～10。

The method of obtaining magnesium-iron garnet

Metal complex having disiloxane as ligand and supported metal complex, method for producing the same, and supported metal catalyst prepared using the same

下記一般式（１）で表される金属錯体。（式中Ｍはパラジウムまたは白金、Ｌは一酸化炭素、オレフィン化合物、アミン化合物、ホスフィン化合物、Ｎ−複素環式カルベン化合物、ニトリル化合物、イソシアニド化合物から選ばれる配位子、ｎは配位子の個数を表す０から２の整数、Ｒ１〜Ｒ４は有機基を表す。）上記金属錯体は、その骨格構造を保持したまま無機酸化物へ固定化され、担持金属錯体とすることができ、これにより、当該担持金属錯体は、もとの金属錯体が有するのと同等の触媒活性を維持することができる。また、このようにして得られた担持金属錯体を焼成することにより、従来の担持金属触媒よりも触媒活性が大幅に向上した担持金属触媒を得ることができる。 A metal complex represented by the following general formula (1). (Wherein M is palladium or platinum, L is carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound, an isocyanide compound, and n is a ligand. An integer from 0 to 2 representing the number, and R1 to R4 represent an organic group.) The above metal complex can be immobilized on an inorganic oxide while retaining its skeleton structure to form a supported metal complex. The supported metal complex can maintain catalytic activity equivalent to that of the original metal complex. In addition, by calcining the supported metal complex thus obtained, it is possible to obtain a supported metal catalyst whose catalytic activity is significantly improved over the conventional supported metal catalyst.

Hollow-type metal oxide-silcate nanoparticle and preparation method thereof

본 발명은 유기 고분자의 미셀(micell) 또는 역미셀(reverse micell)로 이루어진 템플레이트 코어에 실란 화합물 및 금속 전구체를 반응시켜 금속 산화물실리케이트 쉘이 형성된 코어쉘 입자를 제조하는 단계; 및 상기 코어쉘 입자를 염기성 수용액 또는 산성 수용액과 반응시켜 쉘에 미세기공을 형성시키는 단계를 포함하는 중공형 금속 산화물-실리케이트 입자의 제조 방법에 관한 것이다. The present invention relates to a method for preparing a core shell particle, comprising the steps of: reacting a silane compound and a metal precursor to a template core composed of micell or reverse micell of an organic polymer to form a core shell particle having a metal oxide silicate shell; And And reacting the core shell particles with a basic aqueous solution or an acidic aqueous solution to form fine pores in the shell. The present invention also relates to a method for producing hollow metal oxide-silicate particles.

CONTAINING MIXED SILICON AND TITANIUM OXIDE DISPERSION FOR PRODUCTION OF TITANIUM-CONTAINING ZEOLITES

1. Дисперсия, содержащая пирогенный порошок смешанного оксида кремния и титана, с содержанием диоксида кремния от 75 до 99,99 мас.%, и содержанием диоксида титана от 0,01 до 25 мас.%, воду и основное четвертичное аммониевое соединение, отличающаяся тем, что средний совокупный диаметр частиц порошков смешанных оксидов кремния и титана в дисперсии составляет не более 200 нм. ! 2. Дисперсия по п.1, отличающаяся тем, что средний совокупный диаметр составляет менее 100 нм. ! 3. Дисперсия по п.1 или 2, отличающаяся тем, что удельная поверхность по БЭТ пирогенного порошка смешанного оксида кремния и титана составляет от 10 до 400 м2/г. ! 4. Дисперсия по п.1, отличающаяся тем, что содержание каждого из следующих элементов: Na, К, Fe, Co, Ni, Al, Ca и Zn в пирогенном порошке смешанного оксида кремния и титана составляет менее 50 ч./млн ! 5. Дисперсия по п.1, отличающаяся тем, что основное четвертичное аммониевое соединение представляет собой гидроксид тетраалкиламмония, выбранный из группы, включающей гидроксид тетраэтиламмония, гидроксид тетра-н-пропиламмония и/или гидроксид тетра-н-бутиламмония. ! 6. Дисперсия по п.1, отличающаяся тем, что отношение числа молей воды к числу молей смешанного оксида кремния и титана составляет от 10 до 20. ! 7. Дисперсия по п.1, отличающаяся тем, что ее рН составляет от 9 до 11. ! 8. Дисперсия по п.1, отличающаяся тем, что отношение числа молей аммониевого соединения к числу молей смешанного оксида кремния и титана составляет от 0,12 до менее чем 0,20. ! 9. Способ получения дисперсии пп.1-8, включающий следующие стадии: ! вода, рН которой в случае, если вводимый позже порошок смешанного оксида кремния и титана приводит к достижению величины рН в в РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2008 144 804 (13) A (51) МПК C01B 33/14 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21), (22) Заявка: 2008144804/15, 12.03.2007 (71) Заявитель(и): ЭВОНИК ДЕГУССА ГМБХ (DE) (30) Конвенционный ...