09-01-2020 дата публикации
Номер: US20200010337A1
A metal organic framework includes metal-containing secondary building units and perfluorinated linkers (e.g., pefluorinated arene linkers, perfluorinated heteroarene linkers, etc.). The metal may be copper, zinc, hafnium, zirconium, aluminum, gallium, or indium. A method for removing contaminants from wastewater may utilize the metal organic framework. The contaminants may include arenes. 1. A metal organic framework comprising:a secondary building unit comprising a metal; anda perfluorinated linker.2. The framework of claim 1 , wherein the metal is selected from the group consisting of copper claim 1 , zinc claim 1 , hafnium claim 1 , zirconium claim 1 , aluminum claim 1 , gallium claim 1 , and indium.3. The framework of claim 1 , wherein the metal is a group 13 metal.4. The framework of claim 3 , wherein the group 13 metal is selected from the group consisting of aluminum claim 3 , gallium claim 3 , and indium.5. The framework of claim 1 , wherein the perfluorinated linker is a perfluorinated arene linker.6. The framework of claim 1 , wherein the perfluorinated linker is a perfluorinated heteroarene linker.8. The framework of claim 1 , wherein the secondary building unit consists of a group 13 metal ion.9. The framework of claim 1 , wherein the secondary building units are clusters.10. The framework of claim 1 , wherein the metal is copper.11. The framework of claim 1 , wherein the metal is zinc.12. The framework of claim 1 , wherein the metal is hafnium.13. The framework of claim 1 , wherein the metal is zirconium.14. The framework of claim 1 , wherein the metal is aluminum.15. The framework of claim 1 , wherein the metal is gallium.16. The framework of claim 1 , wherein the metal is indium.18. The framework of claim 17 , wherein the metal is selected from the group consisting of copper claim 17 , zinc claim 17 , hafnium claim 17 , zirconium claim 17 , aluminum claim 17 , gallium claim 17 , and indium.19. The framework of claim 17 , wherein the secondary ...
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