РЕГУЛИРУЮЩАЯ МОЛЕКУЛА

Изобретение относится к монозамещенной фосфиновой кислоте, способу ее получения и к применению указанной кислоты в качестве регулятора в свободно-радикальной полимеризации. Монозамещенная фосфиновая кислота формулы (I), где X представляет собой H, ион щелочного металла, ион щелочноземельного металла, ион двухвалентного или трехвалентного металла, ион аммония, органическую аммониевую группу или органический радикал с молекулярной массой ≤200 г/моль, в частности Naили K; где Rпредставляет собой H, алкильную группу, предпочтительно содержащую от 1 до 20 атомов C, алкиларильную группу, предпочтительно содержащую от 7 до 20 атомов C. Изобретение позволяет получить регуляторы, которые не приводят к образованию плохо растворимых солей, и, кроме того, полимеры, получаемые с их использованием, характеризуются однородной степенью полимеризации, имеющей узкое распределение по размерам. 6 н. и 9 з.п. ф-лы, 13 пр., 1 табл.

РЕГУЛИРУЮЩАЯ МОЛЕКУЛА

... 1. Монозамещенная фосфиновая кислота формулы (I)где X представляет собой Н, ион щелочного металла, ион щелочноземельного металла, ион двухвалентного или трехвалентного металла, ион аммония, органическую аммониевую группу или органический радикал с молекулярной массой ≤200 г/моль, в частности, Naили К;где Y представляет собой одну из формул (II)-(VI)где W представляет собой одну из формул (VII)-(X);где Rпредставляет собой Н, алкильную группу, предпочтительно содержащую от 1 до 20 атомов C, алкиларильную группу, предпочтительно содержащую от 7 до 20 атомов C, или формулу (XI)где заместитель А независимо представляет собой от C-C-алкиленовую группу, индекс q принимает значение от 2 до 300, в частности, от 2 до 50, особенно предпочтительно от 3 до 10, индекс n принимает значение от 2 до 4, предпочтительно значение 2, а индекс r принимает значение от 0 до 1,где R, Rи Rнезависимо представляют собой H, CH, COOH или CH-COOH,Rпредставляет собой -CH-CH- или -CH-CH(CH) иRпредставляет собой О или N ...

Regulator molecule

The invention relates to a mono-substituted phosphinic acid and to the use thereof as a regulator in radical polymerizations. Such regulators do not result in the formation of poorly soluble salts, and moreover the polymers produced by the regulator according to the invention are characterized by a uniform polymerization degree having a narrow size distribution. The invention further relates to a method for producing such mono-substituted phosphinic acids.

LIGANDS FOR USE IN CATALYTIC PROCESSES

PRODUCTION OF AN ISOMERIC MIXTURE OF SECONDARY PHOSPHINES, AND USE OF THE MIXTURE SO MADE

AN ADAMANTYL CATALYST SYSTEM

... ²²²A catalyst system capable of catalysing the carbonylation of an olefinally ²unsaturated compound is described. The 5 catalyst system is obtainable by ²combining: (a) a metal of Group VIB or Group VIII B or a compound thereof; and ²(b) a bidentate phosphine of general formula (I) Ad) s (CR4R5R6) T Q2-A- (K, ²D) Ar (E, Z) -B-Q1 (Ad) u (CR1R2R3) v. Ad represents an optionally substituted ²adamantyl radical bonded to the phosphorous atom via any one of its tertiary ²carbon atoms. A method of production of the catalyst is also illustrated.² ...

OPTICALLY ACTIVE PHOSPHINES, THEIR PREPARATION AND THEIR METAL COMPLEXES, AND USE IN ASYMMETRIC SYNTHESIS

Optically active phosphines of the general formula I or II XnPRm I II where the variables have the following meanings: X is an optically active terpene radical, R is an unsubstituted or substituted phenyl radical, Y is a bridge member having 1-10 C atoms in the formula I n is 1,2 or 3 and m is 0,1 or 2 with the proviso that n+m = 3 in the formula II n is 1 or 2 and m is 0 or 1 with the proviso that n+m = 2, their preparation and use are described.

Method for producing thermoplastic elastomers

Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use

In accordance with the present invention there is provided a cyclopentadienyl-type ligand represented by the formula ZA, wherein Z is a cyclopentadienyl-type group, wherein A is --YPR2, --YNR2, or --NR2, wherein Y is an alkylene group containing 1 to 24 carbon atoms, wherein each R is individually selected from alkyl groups containing 1 to 20 carbon atoms. Another aspect of the invention is to provide a metallocene represented by the formula ZAMX3, wherein Z and A are as described above, M is a Group IVB or VB transition metal, and X is a halide. Other aspects of the present invention include catalyst systems comprising the metallocenes and an organoaluminoxane, processes for preparing the above defined ligands, metallocenes and catalyst systems, and polymerization processes employing the catalyst systems.

СПОСОБ ПОЛУЧЕНИЯ НАСЫЩЕННЫХ И НЕНАСЫЩЕННЫХ ЭЛАСТОМЕРОВ

Эластомеры могут быть получены (со)полимеризацией мономеров из группы олефинов с 2-8 атомами углерода, диолефинов с 4-15 атомами углерода и других мономеров в твердой фазе, в растворе, а также в суспензии или в газовой фазе, при этом в качестве катализаторов используют металлоцены или π-комплексные соединения формул (I) или (XIII), в которых СрI и СрII представляют собой карбанионы с циклопентадиенилсодержащей структурой, πI и πII представляют собой заряженные или электрически нейтральные π-системы. Δ+D представляет собой атом донора и Δ-A атом акцептора, при этом D и А связаны обратимой координационной связью таким образом (так), что донорная группа принимает (частичный) положительный заряд, а акцепторная группа (частичный) отрицательный, М представляет собой переходный металл III, IV, V или VI побочной группы Периодической системы элементов, включая лантаниды и актиноиды, Х представляет собой эквивалент аниона и n, в зависимости от заряда М, равняется 0, 1, 2, 3 или 4. Техническая задача ...

Process for the carbonylation of ethylenically unsaturated compounds

PROCEDURE FOR THE PRODUCTION OF HIGH-MELTING POLYOLEFINS

PROCEDURE FOR THE PRODUCTION FROM CYCLOOLEFIN (CO) POLYMERS TO APPLICATION FOR OPTICAL DATA MEMORIES

A PHOSPHA-ADAMANTANE (S) CATALYTIC SYSTEM

Method for producing cycloolefin (co)polymers for use in optical data memories

TRIMERISATION AND OLIGOMERISATION OF OLEFINS USING A CHROMIUM BASED CATALYST

The invention provides a mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms, of which at least one heteroatom is nitrogen and at least two heteroatoms are not the same.The invention also provides a multidentate mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms. At least one heteroatom may be nitrogen and at least 2 heteroatoms may not be the same.

PRODUCTION METHOD OF OPTICALLY ACTIVE DIHYDROBENZOFURAN DERIVATIVE

Provided is a production method of an optically active dihydrobenzofuran derivative. A production method of an optically active form of a compound represented by the formula: wherein each symbol is as defined in the specification, or a salt thereof and the like.

OPTICALLY ACTIVE PHOSPHINES, THEIR PREPARATION AND THEIR METAL COMPLEXES, AND USE IN ASYMMETRIC SYNTHESIS

Optically active phosphines, their preparation and their metal complexes, and application in asymmetric synthesis Optically active phosphines of the general formula I or II where the variables have the following meanings: X is an optically active terpene radical, R is an unsubstituted or substituted phenyl radical, Y is a bridge member having 1-10 C atoms in the formula I n i s 1, 2 or 3 and m is 0,1 or 2 with the proviso that n+m = 3 in the formula II n is 1 or 2 and m is 0 or 1 with the proviso that n+m = 2, their preparation and use are described.

METHOD FOR PRODUCING THERMOPLASTIC ELASTOMERS

Thermoplastic elastomers can be produced by (co)polymerising monomers from the group of C2-C8-.alpha.-olefins, C4-C15-dioledins and other monomers in the solid phase, in solution, as slurry or in the gas phase where metallocen compounds or .pi.-complex compounds of formulas (I) or (XIII), are used as catalysts, in which CpI and CpII represent carbanions with a structure containing cyclopentadienyl, .pi. I and .pi. II represent charged or electrically neutral .pi.-systems, D represent a donator atom and A an acceptor atom, wherein D and A are linked by a reversible, coordinate bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge, M stands for a transition metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements including lanthanides and actinoides, X stands for an anion equivalent and n, depending on the charge of M, is 0, 1, 2, 3 or 4.

METHOD FOR PRODUCING HIGH MELTING-POINT POLYOLEFINS

High-melting polyolefins can be prepared in bulk, in solution, in suspension or in the gas phase, the catalysts employed being metallocene compounds or .pi. complex compounds of the formulae (see formulae Ia, Ib, XIII and XIIIb) in which CpI and CpII represent carbanions having a cyclopentadienyl-containing structure, .pi.I and .pi.II represent charged or electrically neutral .pi. systems, D represents a donor atom and A represents an acceptor atom, where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge, M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of the Elements (Mendeleev), including the lanthanides and the actinides, X denotes one anion equivalent and n denotes the number zero, one, two, three or four, depending on the charge of M.

.PI.-COMPLEX COMPOUNDS

... .pi.-complex compounds and in particular metallocene compounds of formula (Ia)(Ib), in which .pi.I and .pi.II represent .pi.-systems, D designates a donor atom and A designates an acceptor atom, D and A being linked by a reversible coordinative bond such that the donor group assumes a positive (partial) charge and the acceptor group assumes a negative (partial) charge, at least one of D and A being part of the associated .pi.-system in each case, M stands for a transition metal of the 3rd, 4th, 5th or 6th subgroup of the (Mendelian) periodic system of elements, X designates an anion equivalent and n designates the number zero, one, two, three of four depending on the charges of M and those of .pi.I and .pi.II, are novel and can be used as catalysts for the (co)polymerization of olefins, i-olefins, alkines and/or diolefins or for ring-opening polyaddition.

METHOD OF PRODUCING OPTICALLY ACTIVE DERIVATIVES OF DIHYDRO BENZOFURAN

PHOSPHINE LIGANDS, METAL COMPLEXES AND COMPOSITIONS THEREOF FOR CROSS-COUPLING REACTIONS

L'invention concerne de nouveaux procédés efficaces utilisés dans diverses réactions formant des liaisons, notamment les réactions de Suzuki et les aminations aryle. Les composés organiques (p. ex. les ligands), leurs complexes métalliques et les compositions contenant ces composés permettant d'obtenir des catalyseurs. L'invention concerne également les réactions de couplage croisé de Suzuki réalisées avec des aryl-chlorures non réactifs.

'pi'-COMPLEX COMPOUNDS

... 'pi'-complex compounds and in particular metallocene compounds of formula (Ia)(Ib), in which 'pi'I and 'pi'II represent 'pi'-systems, D designates a donor atom and A designates an acceptor atom, D and A being linked by a reversible coordinative bond such that the donor group assumes a positive (partial) charge and the acceptor group assumes a negative (partial) charge, at least one of D and A being part of the associated 'pi'-system in each case, M stands for a transition metal of the 3rd, 4th, 5th or 6th subgroup of the (Mendelian) periodic system of elements, X designates an anion equivalent and n designates the number zero, one, two, three of four depending on the charges of M and those of 'pi'I and 'pi'II, are novel and can be used as catalysts for the (co)polymerization of olefins, i-olefins, alkines and/or diolefins or for ring-opening polyaddition.

Process for preparing cyclopentadienyl-type ligands

In accordance with the present invention there is provided a cyclopentadienyl-type ligand represented by the formula ZA, wherein Z is a cyclopentadienyl-type group, wherein A is --YPR 2 , --YNR 2 , or --NR 2 , wherein Y is an alkylene group containing 1 to 24 carbon atoms, wherein each R is individually selected from alkyl groups containing 1 to 20 carbon atoms. Another aspect of the invention is to provide a metallocene represented by the formula ZAMX 3 , wherein Z and A are as described above, M is a Group IVB or VB transition metal, and X is a halide. Other aspects of the present invention include catalyst systems comprising the metallocenes and an organoaluminoxane, processes for preparing the above defined ligands, metallocenes and catalyst systems, and polymerization processes employing the catalyst systems.

Chiral diphosphorus compounds and their transition metal complexes

Chiral diphosphorus compounds (I) and their complexes with boranes are new. - Chiral diphosphorus compounds of formula (I) and their complexes with boranes are new. - asterisk 1- asterisk 3 = stereogenic C atom in R- or S- configuration; - R5 = alkyl, arylalkyl or aryl; either - R1-R4 = R5 or 4-16C heterocyclic group; or - R1+R2 and/or R3+R4 = alkylene; - R6 = R5 or alkoxy; and - n = 0-2. - Independent claims are also included for the following: - (1) phosphorus-containing cyclopentanol compounds of formula (IV); - (2) phosphorus containing cyclopentane derivatives of formula (V) and (VI); - (3) phosphorus containing cyclopentanol compounds of formula (VII) and their complexes with borane; - (4) sulfur-containing cyclopentanol compounds of formula (IX); - (5) the preparations of (I), (IV), (V), (VI), (VII) and (IX); - (6) cyclopentanol compounds of formula (II); - (7) transition metal complexes (C1) comprising (I); - (8) catalysts (C2) comprising (C1); and - (9) a method for preparing stereoisomerically ...

PI-COMPLEX COMPOUNDS

π-complex compounds and in particular metallocene compounds of formula (Ia)(Ib), in which πI and πII represent π-systems, D designates a donor atom and A designates an acceptor atom, D and A being linked by a reversible coordinative bond such that the donor group assumes a positive (partial) charge and the acceptor group assumes a negative (partial) charge, at least one of D and A being part of the associated π-system in each case, M stands for a transition metal of the 3rd, 4th, 5th or 6th subgroup of the (Mendelian) periodic system of elements, X designates an anion equivalent and n designates the number zero, one, two, three of four depending on the charges of M and those of πI and πII, are novel and can be used as catalysts for the (co)polymerization of olefins, i-olefins, alkines and/or diolefins or for ring-opening polyaddition.

СПОСОБ ПОЛУЧЕНИЯ ЦИКЛООЛЕФИНОВЫХ СО(ПОЛИМЕРОВ) ДЛЯ ТЕХНИЧЕСКИХ ПРИМЕНЕНИЙ

Изобретение относится к применению π-систем или металлоценов, в которых переходной металл связан в комплекс с двумя π-системами для получения циклоолефиновых со(полимеров). Циклоолефиновые (со)полимеры для технических применений, за исключением применения в устройствах оптической памяти, могут быть получены (со)полимеризацией мономеров из группы циклических олефинов, α-олефинов с двумя или более атомами углерода и сопряженных или несопряженных диолефинов (оптимально), при этом в качестве катализаторов используются металлоцены или π-комплексные соединения формул I или XIII по п.1, в которых СрI и СрII представляют собой карбанионы с циклопентадиенилсодержащей структурой, πI и πII представляют собой заряженные или электрически нейтральные π-системы, D представляет собой атом донора и А атом акцетора, при этом D и А связаны обратимой координационной связью так, что донорная группа принимает (частичный) положительный заряд, а акцепторная группа (частичный) отрицательный, М представляет собой ...

VERFAHREN ZUR HERSTELLUNG VON ELASTOMEREN

Process for producing biarylphosphine compound

PHOSPHINVERBINDUNG, INTERMEDIATE CONNECTION, PALLADIUM COMPLEX, AND THEIR USE

MANUFACTURING PROCESS OF LAKTAT ESTER OR ACID

METALLOCEN CONNECTIONS

PROCEDURE FOR THE PRODUCTION OF ELASTOMERS

PROCEDURE FOR THE PRODUCTION OF CYCLOOLEFIN (CO) POLYMERS FOR TECHNICAL APPLICATIONS

BIDENTATE ORGANOPHOSPHORLIGANDEN AND YOUR USE IN THE CATALYSIS

ADAMANTYLGRUPPEN ABSTENTIONS PHOSPHANE LIGANDS, THEIR PRODUCTION AND YOUR USE IN CATALYTIC REACTIONS

A PHOSPHA-ADAMANTANE (S) CATALYTIC SYSTEM

A catalyst system capable of catalysing the carbonylation of an olefinally unsaturated compound is described. The 5 catalyst system is obtainable by combining: (a) a metal of Group VIB or Group VIII B or a compound thereof; and (b) a bidentate phosphine of general formula (I) Ad) s (CR4R5R6) T Q2-A- (K, D) Ar (E, Z) -B-Q1 (Ad) u (CR1R2R3) v. Ad represents an optionally substituted adamantyl radical bonded to the phosphorous atom via any one of its tertiary carbon atoms. A method of production of the catalyst is also illustrated.

TERTIARY PHOSPHINES AND THEIR METHODS OF PREPARATION

TRIMERISATION AND OLIGOMERISATION OF OLEFINS USING A CHROMIUM BASED CATALYST

The invention provides a mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms, of which at least one heteroatom is nitrogen and at least two heteroatoms are not the same.The invention also provides a multidentate mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms. At least one heteroatom may be nitrogen and at least 2 heteroatoms may not be the same.

NOVEL CATALYSTS

The present invention provides novel compounds and ligands that are useful in transition metal catalyzed cross-coupling reactions. For example, the compounds and ligands of the present invention are useful in palladium or gold catalyzed cross-coupling reactions. The ligands are of formula (I) wherein each of R1 and R2 is independently selected from tert-butyl, cyclohexyl, 2-tolyl, or 1-adamantyl; each of R3 and R4 is independently selected from a C1-5 alkyl, or R3, R4, and the nitrogen atom to which they are attached form an optionally substituted 4 -10 membered heterocyclic ring; each of X1a and X1b, is independently selected from N or C-R5; each of X2a and X2b, is independently selected from N or C- R6; each R5 is independently selected from -H, -CH3, -OCH3, halogen, or -CF3; each R6 is independently selected from -H, -CH3, -OCH3, -N(CH3)2, halogen, or -CF3; or an R5 and an R6 located on adjacent carbon atoms together with the carbon atoms to which they are attached form an optionally ...

PHOSPHINE COMPOUND, INTERMEDIATE, PALLADIUM-COMPLEX, AND USE THEREOF

METHOD OF PRODUCTION OF OPTICALLY ACTIVE DERIVATIVE OF DIHIDROBENZOFURANO

Reivindicación 1: Un método de producción de una forma ópticamente activa de un compuesto representado por la fórmula (1) en donde R3 es un grupo hidroxi o un grupo alcoxi C1-6 opcionalmente sustituido, o una de sus sales, que comprende una etapa de producción de una forma ópticamente activa de un compuesto representado por la fórmula (2) en donde R1 es un grupo hidroxi o un grupo alcoxi C1-6 opcionalmente sustituido; y X es un átomo de halógeno, un grupo hidroxi o un grupo alcoxi C1-6 opcionalmente sustituido; o una de sus sales, al someter un compuesto representado por la fórmula (1) en donde cada símbolo es como se definió con anterioridad, o una de sus sales, a una reacción de hidrogenación asimétrica en presencia de un complejo de rutenio.Reivindicación 9: Una sal de una forma ópticamente activa de un compuesto representado por la fórmula (4) en donde X es un átomo de halógeno, un grupo hidroxi o un grupo alcoxi C1-6 opcionalmente sustituido, en donde una base orgánica de la sal es ...

molécula reguladora

Copper complex

The present invention provides a copper complex with superior brightness persistence than anyknown copper complex. The present invention provides a copper complex represented by composition formula (1): (Cu+)(L1)a(L2)b(L3)c(X1)d(L1 is a molecular containing 3 or 4 atoms selected from phosphorus atoms and nitrogen atoms of optionally substituted nitrogen atom-containing 5-member ring as neutral atoms capable of coordinating with the same Cu+, among the neutral atoms of L1 capable of coordinating with the same Cu+, two or more atoms are phosphorus atoms, and one or more of the atoms selected from the group consisting of the phosphorus atoms do not bond to sp3 carbon atom. L2 and L3 are molecules containing atoms or ions which are selected from phosphorus atoms, nitrogen atoms, oxygen atoms, sulfur atoms, arsenic atoms, oxygen anion and sulfur anion, which are capable of coordinating with Cu+, X1 is an anion, a is a number more than 0.5, b, c and d are numbers equal to or more than 0.) ...

NOVEL CATALYSTS

The present invention provides novel compounds and ligands that are useful in transition metal catalyzed cross-coupling reactions. For example, the compounds and ligands of the present invention are useful in palladium or gold catalyzed cross-coupling reactions.

METHOD FOR PRODUCING CYCLOOLEFIN (CO)POLYMERS FOR USE IN OPTICAL DATA MEMORIES

Cycloolefin copolymers for use in optical data memories can be produced by (co)polymerising monomers from the group of cyclic olefins, of α-olefins with 2 or more C atoms and optionally conjugated or unconjugated diolefins, wherein metallocene compounds or π-complex compounds of formula (I) or (XIII) are used as catalysts, in which CpI and CpII represent carbanions with a structure containing cyclopentadienyl, πI and πII represent charged or electrically neutral π-systems, D represents a donor atom and A an acceptor atom, wherein D and A are joined by a reversible, co-ordinative bond such that the donor group adopts a positive (partial) charge and the acceptor group a negative (partial) charge, M stands for a transition metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements (Mendeleev) including lanthanides and actinides, X stands for an anion equivalent and n, depending on the charge of M, stands for the figure nought, one, two, three or four.

Method for generating secondary phosphines

This invention provides a method for generating secondary phosphines from secondary phosphine oxides in the presence of a reducing agent, such as diisobutylaluminum hydride (DIBAL-H), triisobutyldialuminoxane, triisobutylaluminum, tetraisobutyldialuminoxane, or another reducing agent comprising: (i) an R1R2AlH moiety, wherein R1 and R2 are each an alkyl species or oxygen, and wherein at least one of R1 or R2 comprises at least 2 carbon atoms, or (ii) an R1R2R3Al moiety, wherein R1, R2, and R3 are not hydrogen, and wherein at least one of R1, R2, and R3 is an alkyl species comprising a β-hydrogen, not including triethylaluminum. Preferred reducing agents for the present invention include: diisobutylaluminum hydride, triisobutyldialiuminoxane, triisobutylaluminum, tetraisobutyldialuminoxane, and combinations thereof.

Tripodal cyclopentadiene derivatives and their use

Tripodal cyclopentadiene derivatives with good ligand properties and metal complexes Tripodal cyclopentadiene derivatives of formula (I) and (ii) tripodal metal complexes of formula LnM(Tp)m (II) are new; in which E = a (substituted) amine [-N(R)(R)], phosphine [-P(R)(R)], arsine [-As(R)(R)], stibine [-Sb(R)(R)], oxy [-OR], thio [-SR], seleno [-SeR] or telluro [-TeR] group or a labile group X; R, R1-6, T = H, 1-20C carbon-organyl or 1-30C silicon-organyl; or T = E-Y-; Y = a 1-20 C organyl group linking E to C1; Z = the cyclopentadienyl radical or a substituted cyclopentadienyl unit; M = a transition or main group metal; Tp = (I) or its conjugated anion; L = an anionic or neutral ligand; n = 0-7; and m = 1-8. Also claimed is a method for preparing functionalised tripodal cyclopentadiene derivatives (III), including chiral compounds.

Hydroformylation process

Hydroformylation process

A hydrof ormylation process for the production of alcohols comprising reacting, in a reactor system comprising one or more feed streams, a reaction environment and an output stream, a feedstock composition comprising a compound having at least one olefinic carbon-to-carbon bond with hydrogen and carbon monoxide in the presence of an organophosphine modified cobalt hydrof ormylation catalyst, wherein the hydrof ormylation process is carried out in the reaction environment which comprises at least two reaction zones, comprising a first reaction zone, a second reaction zone and, optionally, one or more later reaction zones, wherein the molar ratio of hydrogen to carbon monoxide entering the first reaction zone is in the range of from 0.5 to 1.65, and wherein water is added into the reactor system.

CARBONYLIERUNGSVERFAHREN FROM ETHYLENISCHUNGESÄTTIGTEN CONNECTIONS

A ADAMANTYL ABSTENTION CATALYST SYSTEM

PROCEDURE FOR THE PRODUCTION OF THERMOPLASTIC ELASTOMERS

Method for producing cycloolefin (co)polymers for technical applications

Cycloolefin copolymers for use for optical data memories, can be prepared by copolymerization of monomers from the group consisting of cyclic olefins, alpha-olefins having 2 or more C atoms and optionally conjugated or non-conjugated diolefins, the catalysts employed being metallocene compounds or pi complex compounds of the formulain whichCpI and CpII represent carbanions having a cyclopentadienyl-containing structure,piI and piII represent charged or electrically neutral pi systems,D represents a donor atom andA represents an acceptor atom,where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge,M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of elements (Mendeleev), including the lanthanides and the actinides,X denotes an anion equivalent andn denotes the number zero, one, two, three or four, depending on the charge of M.

METHOD FOR PRODUCING ELASTOMERS

Elastomers can be produced by (co)polymerising monomers from the group of C2C8-.alpha.-olefins, C4-C15-diolefins and other monomers in the solid phase, in solution, as a slurry or in gas phase where metallocene compounds or .pi.complex compounds of formulas (I) or (XIII) are used as catalysts, in which CpI and CpII represent carbanions with a structure containing cyclopentadienyl, .pi. I and .pi. II represent charged or electrically neutral .pi.-systems, D represents a donator atom and A an acceptor atom, wherein D and A are linked by a reversible, coordinate bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge, M stands for a transition metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements including lanthanides and actinoides, X stands for an anion equivalent and n, depending on the charge of M, is 0, 1, 2, 3 or 4.

METHOD FOR PRODUCING CYCLOOLEFIN (CO)POLYMERS FOR USE IN OPTICAL DATA MEMORIES

Cycloolefin copolymers for use in optical data memories can be produced by (co)polymerising monomers from the group of cyclic olefins, of .alpha.-olefins with 2 or more C atoms and optionally conjugated or unconjugated diolefins, wherein metallocene compounds or .pi.-complex compounds of formula (I) or (XIII) are used as catalysts, in which CpI and CpII represent carbanions with a structure containing cyclopentadienyl, .pi.I and .pi.II represent charged or electrically neutral .pi.-systems, D represents a donor atom and A an acceptor atom, wherein D and A are joined by a reversible, co-ordinative bond such that the donor group adopts a positive (partial) charge and the acceptor group a negative (partial) charge, M stands for a transition metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements (Mendeleev) including lanthanides and actinides, X stands for an anion equivalent and n, depending on the charge of M, stands for the figure nought, one, two, three or four.

P OR AS DERIVATIVE OF A CYCLOPENTADIENE

The invention relates to a process for the preparation of a P or As derivative of an at least bi-substituted cyclopentadiene. The invention is characterised in than an at least mono-substituted spiro-[2,4]-hepta-4,6-diene is reacted with an alkali metal phosphine or an alkali metal arsine. The invention also relates to a number of P or As derivatives of cyclopentadiene.

METHOD FOR PRODUCING ELASTOMERS

Elastomers can be produced by (co)polymerising monomers from the group of C2-C8-α-olefins, C4-C15-diolefins and other monomers in the solid phase, in solution, as a slurry or in gas phase where metallocene compounds or π-complex compounds of formulas (I) or (XIII) are used as catalysts, in which CpI and CpII represent carbanions with a structure containing cyclopentadienyl, π I and π II represent charged or electrically neutral π-systems, D represents a donator atom and A an acceptor atom, wherein D and A are linked by a reversible, coordinate bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge, M stands for a transition metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements including lanthanides and actinoides, X stands for an anion equivalent and n, depending on the charge of M, is 0, 1, 2, 3 or 4.

Trimerisation and oligomerisation of olefins using a chromium based catalyst

The invention provides a mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms, of which at least one heteroatom is nitrogen and at least two heteroatoms are not the same. The invention also provides a multidentate mixed heroatomic ligand for an oligomerization of olefins catalyst, which ligand includes at least three heteroatoms. At least one heteroatom may be nitrogen and at least 2 heteroatoms may not be the same.

-Komplex-Verbindungen

Process for producing biarylphosphines from biarylsulfonates

A process for producing a biarylphosphine compound. The process has a step of subjecting a biarylsulfonate compound to coupling reaction with a hydrogen-phosphine compound in the presence of a catalyst and an organic strong base to obtain a biarylphosphine compound. As the catalyst, preferably used is a nickel compound or a palladium compound. As the organic strong base, preferably a compound with the fragment (C)2N-(C=C)p-C=N-C wherein p=0,1 is used, preferably 1,8-diazabicyclo[5.4.0]undecene-7 (DBU).

LIGANDS FOR METALS AND IMPROVED METAL-CATALYZED PROCESSES BASED THEREON

Catalyst ligands useful for cross-coupling reactions

NOVEL VINYL PHOSPHINES AND PHOTO-INITIATORS OBTAINABLE THEREFROM

The present invention relates to a highly efficient process to prepare alkyl and vinyl phosphines which are useful as starting materials for novel bisacylphosphine oxides, bisacylphosphinic acids, salts, and derivatives thereof each bearing a vinyl functionality bound to the phosphorous atom as well as a versatile process for the preparation of the latter.

LIGANDS FOR METALS AND IMPROVED METAL-CATALYZED PROCESSES BASED THEREON

... ²One aspect of the present invention relates to ligands for transition metals. ²A second ²²aspect of the present invention relates to the use of catalysts comprising ²these ligands ²²in transition metal-catalyzed carbon-heteroatom and carbon-carbon bond-forming ²²²reactions. The subject methods provide improvements in many features of the ²²transition metal-catalyzed reactions, including the range of suitable ²substrates, ²²reaction conditions, and efficiency. The invention relates to a ligand ²represented by ²²structure II:²(see formula II)² ...

Cirality diphosphaneterpene and transition metal complex thereof

Metallocene compounds

下式的金属茂化合物,其中CpⅠ和CpⅡ是具有含－环戊二烯基结构的负碳离子,D是给体原子,A是受体原子,其中D和A通过可逆的配位键以这样的方式连接:给体基团具有正(部分)电荷,受体基团具有负(部分)电荷,M表示元素(门捷列夫)周期表过渡族Ⅲ,Ⅳ,Ⅴ或Ⅵ的过渡金属,X是一阴离子等价物,n取决于M的电荷,是0,1,2,3或4,是新的,并可以在烯烃,异烯烃,炔烃和/或二烯烃的(共)聚合,或开环加聚中用作催化剂。一个典型的X－射线结构分析由式18a表示。

트리-(아다만틸)포스핀 및 이의 적용

... 하나의 양상에서, 3개의 아다만틸 모이어티(PAd3)를 포함하는 포스핀 화합물 및 연관된 합성 경로가 본원에 기재된다. 각각의 아다만틸 모이어티는 동일하거나 상이할 수 있다. 예를 들면, 인 원자에 부착된 각각의 아다만틸 모이어티(Ad)는 아다만탄, 디아만탄, 트리아만탄 및 이의 유도체로 이루어진 그룹으로부터 독립적으로 선택될 수 있다. PAd3 리간드를 포함하는 전이 금속 착물은 또한 촉매적 가교-커플링 반응을 포함하는 촉매적 합성을 위해 제공된다.

PROCESS FOR THE HYDROGENATION OF ARYL PHOSPHINES AND PRODUCTS OBTTAINED THEREFROM

A process for making a cycloalkyl phosphine comprising hydrogenating an aryl phosphine in the presence of an effective amount of an aryloxide of a metal selected from the group consisting of niobium and tantalum is disclosed. Cycloalkyl phosphine products of this process, useful as ligands in a complex of a transition metal which acts as a catalyst in the formation of stereoisomers, are also set forth. Furthermore, niobium or tantalum organometallic compounds, generated in this process, useful in the catalytic hydrogenation of aryl phosphines and arene-containing polymers, is also described.

Method for producing cycloolefin (co)polymers for technical applications

Cycloolefin copolymers for technical applications except for using in optical data storage devices can be produced by (co)polymerising monomers from the group of cyclic olefins, of α-olefins with 2 or more C atoms and conjugated or unconjugated diolefins (optional) where metallocene compounds or π-complex compounds of formula (I) or (XIII) are used as catalysts in which CpI and CpII represent carbanions with a structure containing cyclopentadienyl, πI and πII represent charged or electrically neutral π-systems, D represents a donator atom and A an acceptor atoms, wherein D and A are joined by a reversible coordinate bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge, M stands for a transition metal of the IIIrd, IVth, Vth or Vith subgroup of the periodic table of elements including lanthanides and actinoides, X stands for an anion equivalent and n, depending on the charge of M, is 0, 1, 2, 3 or 4.

Chiral diphosphinoditerpenes and their transition metals complexes

Chiral diphosphinoterpene compounds (I) are new. - Chiral diphosphinoterpene compounds of formula (I) are new. - asterisk 2, asterisk 3 = stereogenically marked carbon in R- or S- configuration where the substitutents are arranged in cis form related to the connecting carbon compound; and either - R1-R4 = alkyl, arylalkyl, aryl or 4-16C heterocyclic group; or - R1+R2 and/or R3+R4 = alkylene. - Independent claims are also included for: - (1) compounds comprising (I) and borane; - (2) preparation of (I); - (3) phosphinyl compounds of formulae (IVa, IVb, Va, Vb, VIa, VIb, VIIa, VIIb, IXa and IXb); - (4) transition metal complex comprising (I); - (5) catalysts comprising the transition metal complexes; and - (6) preparing stereoisomer enriched compounds in the presence of the catalysts.

PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUDS

A process for the carbonylation of ethylenically unsaturated compounds is described. The process comprises reacting an ethylenically unsaturated compound with carbon monoxide in the presence of a source of hydroxyl groups and a catalyst system. The catalyst system is obtained by combining: (a) metal of Group VIII or a compound thereof: and (b) a bidentate phosphine of general formula (I) The carbonylation reaction is carried out at a temperature of between -30·C to 49·C and under a CO partial pressure of less than 30 x105 N.m-2.

МЕТАЛЛОЦЕНОВЫЕ СОЕДИНЕНИЯ, СПОСОБЫ ИХ ПОЛУЧЕНИЯ

FIELD: metalloorganic compounds, chemical technology. SUBSTANCE: invention relates to metallocene compounds of the formula (I) where CpI and CpII represent carbanions of the cyclopentadienyl-containing structure; D represents donor atom and A + acceptor atom being D and A are linked by reverse coordinating linkage by so manner that donor group obtains positive (partial) charge and acceptor group + negative (partial) charge; M means transient metal from III, IV, V or VI subgroup of periodic Mendeleyev's system of elements; X means anionic equivalent and n means 0, 1, 2, 3 or 4 depending on M charge. Compounds (I) can be used as catalysts for (co)polymerization of olefins, isoolefins, alkynes and/or diolefins or for poly-addition with cycle opening. Typical X-ray analysis is presented by the formula (18a) с6госс ПЧ сэ (19) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ ВИ “” 2 201 935‘ (51) МПК” 13) С2 С 07Е 17/00, С 08 Е 10/02 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 99102241104, 02.07.1997 (24) Дата начала действия патента: 02.07.1997 (30) Приоритет: 05.07.1996 ОЕ 196 27 064.2 (43) Дата публикации заявки: 27.12.2000 (46) Дата публикации: 10.04.2003 (56) Ссылки: ЕР 0638593, 15.02.1995. ОЕ 4420456, 14.12.1995. (85) Дата перевода заявки РСТ на национальную фазу: 05.02.1999 (86) Заявка РСТ: ЕР 97/03463 (02.07.1997) (87) Публикация РСТ: У\У/О 98/01455 (15.01.1998) (98) Адрес для переписки: 103064, Москва, ул. Казакова, 16, НИИР-Канцелярия "Патентные поверенные Квашнин, Сапельников и партнеры", пат.пов. В.П. Квашнину, рег.№ 0004 (71) Заявитель: БАЙЕР АКЦИЕНГЕЗЕЛЬШАФТ (ОЕ) (72) Изобретатель: ОСТОЙА СТАРЦЕВСКИ Карл-Хайнц Александер (ОЕ), КЕЛЛИ Варрен Марк (0Е) (73) Патентообладатель: БАЙЕР АКЦИЕНГЕЗЕЛЬШАФТ (ОЕ) (74) Патентный поверенный: Квашнин Валерий Павлович (54) МЕТАЛЛОЦЕНОВЫЕ СОЕДИНЕНИЯ, СПОСОБЫ ИХ ПОЛУЧЕНИЯ (57) Изобретение относится к металлоценовым соединениям формулы (1), в которой СЫ и Ср! представляют собой карбанионы с ...

СПОСОБ ПОЛУЧЕНИЯ ЦИКЛООЛЕФИНОВЫХ (СО)ПОЛИМЕРОВ ДЛЯ ИСПОЛЬЗОВАНИЯ В УСТРОЙСТВАХ ОПТИЧЕСКОЙ ПАМЯТИ

FIELD: organic chemistry, antibiotics. SUBSTANCE: cycloolefin copolymers used in optical memory devices can be synthesized by (co)polymerization of monomers taken among group of cyclic olefins, α--olefins with two or more carbon atoms and optimally conjugated or non-conjugated diolefins. Metallocenes or π--complex compounds of formulas (I) or (XIII) by claim 1 given in the invention claim where CpI and CpII represent carbanions with cyclopentadienyl-containing structure are used as catalysts; πI and πII represent charged or electrically neutral π-systems; D represents donor atom and A represents acceptor atom being D and A are linked by reverse coordination linkage thus donor group accepts (partial) positive charge and acceptor group accepts (partial) negative charge; M represents transient metal of III, IV or VI by-side group of periodic law system elements including lanthanides and actinides; X represents anion equivalent and n means depending on M charge 0, 1, 2, 3 or 4. Cycloolefin (co)polymers exhibit many useful properties, for example, high transparency in initial moment of their using in the field of optical memory devices, high thermal stability, stability against aging, chemical stability, resistance to solvents, low hygroscopicity, resistance against scratching. EFFECT: improved preparing method, valuable properties. 11 cl, 60 ex о6с$0сс ПЧ сэ (19) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ ВИ ”’ 2 203 290” С2 (51) МПК” С 08Е 232/00, С 07Е 17/00, 19/00 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 9910224304, 02.07.1997 (24) Дата начала действия патента: 02.07.1997 (30) Приоритет: 05.07.1996 ОЕ 19627064.2 05.04.1997 ОЕ 19714058.0 (43) Дата публикации заявки: 20.01.2001 (46) Дата публикации: 27.04.2003 (56) Ссылки: 4$ 5567717 АЛ, 22.10.1996. Маковецкий К.Л. Координационная полимеризация циклоолефинов. Высокомолекулярные соединения, серия А, 1994, т.36, №10, с.1712-1730. ОЕ 4420456 АЛ, 14.12.1995. ЕР 638593 АЛ, 15.02. ...

Cyclopropenyl-yliden stabilisierte Phospheniumkationen

Es werden Phosphenium-Verbindungen mit der allgemeinen Formel I beanspruchtin der R1, R2, R3 und R4 gleich oder verschieden sind und für einen linearen oder verzweigten C1-C6-Alkylrest stehen, der gegebenenfalls substituiert sein kann, oder R1 und R2 und/oder R3 und R4 unter Bildung eines Ringes miteinander verbunden sind, R5 und R6 für eine gesättigte oder ungesättigte, verzweigte oder lineare Alkylgruppe, Alkenylgruppe, Arylgruppe, die geeignete Substituenten, auch Heteroatome aus Substituenten, haben kann, eine Heteroatom-enthaltene Kohlenwasserstoffgruppe, die geeignete Substituenten haben kann, und die Reste R5 und R6 einen Ring bilden können, der 4- bis 20-gliedrig, gesättigt oder ungesättigt, alicyclisch oder heteroalicyclisch sein kann und geeignete Substituenten aufweisen kann, X für ein Anion steht ein Verfahren zu ihrer Herstellung, sowie die Verwendung dieser Verbindungen in Metallkomplexen, die als Katalysatoren in der organischen Synthese eingesetzt werden können.

Production of novel phosphane ligands and use in catalytical reactions

A PHOSPHA-ADAMANTANE (S) CATALYTIC SYSTEM

Production method of optically active dihydrobenzofuran derivative

Provided is a production method of an optically active dihydrobenzofuran derivative. A production method of an optically active form of a compound represented by the formula: wherein each symbol is as defined in the specification, or a salt thereof and the like.

Method for producing elastomers

Cycloolefin copolymers for use for optical data memories, can be prepared by copolymerization of monomers from the group consisting of cyclic olefins, alpha-olefins having 2 or more C atoms and optionally conjugated or non-conjugated diolefins, the catalysts employed being metallocene compounds or pi complex compounds of the formulain whichCpI and CpII represent carbanions having a cyclopentadienyl-containing structure,piI and piII represent charged or electrically neutral pi systems,D represents a donor atom andA represents an acceptor atom,where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge,M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of elements (Mendeleev), including the lanthanides and the actinides,X denotes an anion equivalent andn denotes the number zero, one, two, three or four, depending on the charge of M.

PRODUCTION OF AN ISOMERIC MIXTURE OF SECONDARY PHOSPHINES, AND USE OF THE MIXTURE SO MADE

PRODUCTION OF AN ISOMEREC MIXTURE OF SECONDARY PHOSPHINES, AND USE OF THE MIXTURE SO MADE The invention relates to a process for making an isomeric mixture of secondary phosphines with the summation formula C20H27P. To this end, hydrogen phosphide is reacted with dicyclopentadiene in the presence of an agent yielding free radicals. More specifically, hydrogen phosphide and dicyclopentadiene are used in a molar ratio of 1 to at least 2 and the reaction is effected under a pressure of 5 to 90 bars. The mixture is used in the production of flotation aids and as an ingredient of catalytically active transition metal complexes.

BIDENTATE CHIRAL LIGANDS FOR USE IN CATALYTIC ASYMMETRIC ADDITION REACTIONS

Compounds of the formula (I), in the form of mixtures comprising predominantly one diastereomer or in the form of pure diastereomers, Z1-Q-P*R0R1 (I) in which Z1 is a C-bonded, secondary phosphine group -P(R)2; in which R is in each case independently hydrocarbon radicals or heterohydrocarbon radicals, or Z1 is the -P*R0R1 group; Q is a bivalent, achiral, aromatic base skeleton, a bivalent, achiral ferrocene base skeleton, an optionally substituted bivalent cycloalkane or heterocycloalkane skeleton, or a C1-C4-alkylene skeleton, and in which base skeletons a secondary phosphine group Z1 is bonded directly to a carbon atom, or, in the case of cyclic base skeletons, directly to a carbon atom or via a C1-C4-alkylene group, and in which base skeletons a P-chiral group -P*R0R1 is bonded directly to a carbon atom, or, in the case of cyclic base skeletons, directly to a carbon atom or via a C1-C4-alkylene group to a carbon atom such that the phosphorus atoms are linked via 1 to 7 atoms of a carbon ...

A phospha-adamantane (s) catalytic system

A PHOSPHA-ADAMANTANE (S) CATALYTIC SYSTEM

A catalyst system capable of catalysing the carbonylation of an olefinally unsaturated compound is described. The 5 catalyst system is obtainable by combining: (a) a metal of Group VIB or Group VIII B or a compound thereof; and (b) a bidentate phosphine of general formula (I) Ad)s (CR4R5R6)T Q2-A- (K, D) Ar (E, Z) -B-Q1 (Ad)u (CR1R2 R3)v. Ad represents an optionally substituted adamantyl radical bonded to the phosphorous atom via any one of its tertiary carbon atoms. A method of production of the catalyst is also illustrated. © KIPO & WIPO 2007 ...

Production process of a lactate ester or acid

METHOD FOR PRODUCING THERMOPLASTIC ELASTOMERS

Thermoplastic elastomers can be produced by (co)polymerising monomers from the group of C2-C8-'alpha'-olefins, C4-C15-dioledins and other monomers in the solid phase, in solution, as slurry or in the gas phase where metallocen compounds or 'pi'-complex compounds of formulas (I) or (XIII), are used as catalysts, in which CpI and CpII represent carbanions with a structure containing cyclopentadienyl, 'pi' I and 'pi' II represent charged or electrically neutral 'pi'-systems, D represent a donator atom and A an acceptor atom, wherein D and A are linked by a reversible, coordinate bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge, M stands for a transition metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements including lanthanides and actinoides, X stands for an anion equivalent and n, depending on the charge of M, is 0, 1, 2, 3 or 4.

CARBONYLIERUNGSVERFAHREN VON ETHYLENISCH-UNGESÄTTIGTEN VERBINDUNGEN

ADAMANTYLGRUPPEN ENTHALTENDE PHOSPHANLIGANDEN, DEREN HERSTELLUNG UND IHRE VERWENDUNG IN KATALYTISCHEN REAKTIONEN

Cyclopentadiene compound substituted with branched alkyl groups

METHOD FOR PRODUCING HIGH MELTING-POINT POLYOLEFINS

High melting-point polyolefins can be produced as such, in solution, suspension or gas phase, metallocene compounds of formula (I) or .pi.-complex compounds of formulas (I) or (XIII) being used as catalysts. In said formulas: CpI and CpII represent carbanions with a structure containing cyclopentadienyl; .pi.I and .pi.II represent charged or electrically neutral .pi.-systems; D represent a donator atom and A an acceptor atom, D and A being linked by a reversible, co-ordinative bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge; M stands for a transitional metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements (Mendeleev's table) including lanthanides and actinoides; X stands for an anion equivalent; and n, depending on the charge of M, stands for the figure nought, one, two, three or four.

BIDENTATE SECONDARY PHOSPHINE OXIDE CHIRAL LIGANDS FOR USE IN ASYMMETRIC ADDITION REACTIONS

Compounds of the formula I, in the form of mixtures comprising predominantly one enantiomer or in the form of pure enantiomers, secondary phosphine-Q-P*(=O)HR1 (I) in which secondary phosphine is a C-bonded, secondary phosphine group -P(R) 2; in which R is in each case independently hydrocarbon radicals or heterohydrocarbon radicals; Q is a bivalent, achiral, aromatic base skeleton, a bivalent, achiral ferrocene base skeleton, an optionally substituted bivalent cycloalkane or heterocycloalkane skeleton, or a C 1-C 4-alkylene skeleton, and in which base skeletons a secondary phosphine group is bonded directly to a carbon atom, or, in the case of cyclic base skeletons, directly to a carbon atom or via a C1-C 4-alkylene group, and in which base skeletons a P-chiral group -P*(O)HR1 is bonded to a carbon atom such that the phosphorus atoms are linked via 1 to 7 atoms of a carbon chain optionally interrupted by heteroatoms from the group of O, S, N, Fe or Si; P* is a chiral phosphorus atom; and ...

Teritiary phosphines and preparation method thereof

叔膦通过膦(PH 3 或伯膦或仲膦)与只具有一个与羰基共轭的C＝C双键的α，β-不饱和羰基化合物反应制得。本发明的叔膦可具有相同的或不同的R基团。本发明的叔膦可用作金属催化剂的配体或用作制备鏻盐或膦内鎓盐的原材料。

METHOD FOR MANUFACTURING ELASTOMERS

PURPOSE: An appropriate catalyst with high activity, which residual weight of the catalyst is small in polymers, is provided to equal polymerization/copolymerization with arbitrary olefins, to equal diolefins, and to equal polymerization/copolymerization of the olefins, which supplies thermoplastic activity and an elastomeric product. CONSTITUTION: A method for manufacturing of thermoplastic elastomers are composed bulk(co)polymerizing gas phase, bulk phase, solution phase, or slurry phase of monomer from a group, formed with C2-C8-alpha-olefins, monocyclic and(or) polycyclic C4-C15-diolefins, 1 or 2 halidation C4-C15-dilolefins, vinyl ester, (math)acrylate and styrene, when having an organometallic catalyst which is activated by a co catalyst, using a metallocene compound as an organometallic catalyst between the metallocene compound of a formula (I) and a pi-complex of a formula (XIII). COPYRIGHT 2000 KIPO ...

SULFONATED ORGANOPHOSPHINE COMPOUNDS AND USE THEREOF IN HYDROFORMYLATION PROCESSES

A compound comprising a class of sulfonated triorganophosphine compounds of formula R1R2P-R3[-O-(CH2)n-(SO3M)]m, wherein the R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.

Methods for using phosphine ligands in compositions for suzuki cross-coupling reactions

The present invention discloses new efficient processes for various bond forming reactions, including Suzuki reactions. Organic compounds (e.g., ligands), their metal complexes and compositions using those compounds, provide useful catalysts. The invention also relates to performing Suzuki cross coupling reactions with unreactive aryl-chlorides.

Process for producing a biarylphosphine compound from a biarylsulfonate compound

Regulator molecule

The invention relates to a mono-substituted phosphinic acid and to the use thereof as a regulator in radical polymerizations. Such regulators do not result in the formation of poorly soluble salts, and moreover the polymers produced by the regulator according to the invention are characterized by a uniform polymerization degree having a narrow size distribution. The invention further relates to a method for producing such mono-substituted phosphinic acids.

TERTIARY PHOSPHINES AND THEIR METHODS OF PREPARATION

Tertiary phosphines are prepared by reacting a phosphine (PH3 or a primary or secondary phosphine) with a cyclic alpha, beta-unsaturated carbonyl compound having no more than one C=C double bond conjugated with a carbonyl group. The inventive tertiary phosphines can have R groups that are the same or different. The inventive tertiary phosphines may be used as ligands for metal catalysts or as starting materials for preparing phosphonium salts or ylids.

LIGANDS FOR METALS AND IMPROVED METAL-CATALYZED PROCESSES BASED THEREON

One aspect of the present invention relates to ligands for transition metals. A second aspect of the present invention relates to the use of catalysts comprising these ligands in transition metal-catalyzed carbon-heteroatom and carbon-carbon bond-forming reactions. The subject methods provide improvements in many features of the transition metal-catalyzed reactions, including the range of suitable substrates, reaction conditions, and efficiency.

SYNTHESIS OF CYCLOALKYLDIARYLPHOSPHINES

Phosphines having two aryl groups and one alkyl-substituted cycloalkyl group bonded to a phosphorus atom are formed by reacting an alkali metal diarylphosphide with a monoalkyl- or polyalkyl-substituted cycloalkyl mesylate or tosylate in which an alkyl group is in the 2-position, in a liquid reaction medium in which these reactants are soluble. This process avoids complications associated with prior known process technology for producing such phosphines. The phosphines are useful as ligands for making noble metal catalysts.

BIDENTATE CHIRAL LIGANDS FOR USE IN CATALYTIC ASYMMETRIC ADDITION REACTIONS

Compounds of the formula (I) in the form of a mixture of predominantly one diastereomer or in the form of pure diastereomers, 1. Compounds of the formula (I) in the form of a mixture of predominantly one diastereomer or in the form of pure diastereomers ,{'br': None, 'sub': 1', '0', '1, 'Z-Q-P*RR\u2003\u2003(I),'}wherein:{'sub': 1', '2, 'claim-text': {'sub': 1', '6', '1', '6', '1', '4', '2', '6', '5', '3', '1', '12', '3, 'wherein R is a hydrocarbon radical or O-atom(s)-containing heterohydrocarbon radical having 1 to 18 carbon atoms and optionally substituted by C-C-alkyl, trifluoromethyl, C-C-alkoxy, trifluoromethoxy, (C-C-alkyl)amino, (CH)Si, (C-C-alkyl)Si or halogen;'}, 'Zis a C-bonded, secondary phosphine group of the formula —P(R),'} [{'sub': 1', '0', '1, '(i) an optionally substituted achiral aromatic group, wherein the achiral aromatic group is bonded directly to Zthrough a carbon atom of the achiral aromatic group and bonded directly to P*RRthrough a carbon atom of the achiral aromatic group, and'}, {'sub': 1', '4, '(ii) an optionally substituted C-C-alkylene group;'}], 'Q is selected from the group consisting ofP* is a chiral phosphorus atom;{'sub': '0', 'Ris methyl; and'}{'sub': '1', 'Ris a C-bonded optically enriched or optically pure chiral, mono- or polycyclic, nonaromatic hydrocarbon ring.'}23-. (canceled)4. The compounds according to claim 1 , wherein the secondary phosphine Zis selected from the group consisting of: —P(C-C-alkyl) claim 1 , —P(C-C-cycloalkyl) claim 1 , —P(o-furyl) claim 1 , —P(CH) claim 1 , —P[2-(C-C-alkyl)CH] claim 1 , —P[3-(C-C-alkyl)CH] claim 1 , —P[4-(C-C-alkyl)CH] claim 1 , —P[2-(C-C-alkoxy)CH] claim 1 , —P[3-(C-C-alkoxy)CH] claim 1 , —P[4-(C-C-alkoxy)CH] claim 1 , —P[2-(trifluoromethyl)CH] claim 1 , —P[3-(trifluoromethyl)CH] claim 1 , —P[4-(trifluoromethyl)CH] claim 1 , —P[3 claim 1 ,5-bis(trifluoromethyl)CH] claim 1 , —P[3 claim 1 ,5-bis(C-C-alkyl)CH] claim 1 , —P[3 claim 1 ,5-bis(C-C-alkoxy)CH]and —P[3 claim 1 ,5-bis(C-C-alkyl ...

CYCLOPROPENYLIDENE-STABILIZED PHOSPHENIUM CATIONS

Phosphenium compounds with the general formula I: 2. The phosphenium compound as claimed in claim 1 , wherein R claim 1 , R claim 1 , Rand R claim 1 , each independently of one another claim 1 , are chosen from isopropyl and tert-butyl.3. The phosphenium compound as claimed in wherein Xis chosen from BF claim 1 , PF claim 1 , SbFand/or BPh.5. The process as claimed in claim 4 , wherein X represents chlorine.6. A metal complex comprising the phosphenium compound with the general formula I as claimed in as a ligand.8. The metal complex as claimed in claim 7 , wherein the ligands L are chosen from halogen claim 7 , CN claim 7 , CO claim 7 , alkenes claim 7 , cycloalkenes and/or alkynes.9. The metal complex as claimed in claim 7 , wherein MLrepresents AuCl claim 7 , AuCl claim 7 , PdCl(allyl) claim 7 , RhCl(cod) claim 7 , RhCl(CO) claim 7 , CuCl claim 7 , RhCland/or BH.10. A cycloisomerization reaction catalyzed by the metal complex as claimed in . The present invention relates to novel stabilized cyclopropenylylidene cations and their use as ligands in metal catalysts.Phosphenium cations of the general formula [RP:]are isolobal with singlet carbenes and can be stabilized, for example, by donation of electron density in their empty orbital. This stabilization can, for example, be achieved by incorporation of the phosphorus atom in a heterocyclic backbone A or by reaction with bases with the formation of the corresponding Lewis adduct B (scheme 1).In both cases, the presence of a free electron pair on the phosphorus atom suggests the use of these compounds as ligands, though their intrinsic positive charge results in them being weak a donors and strong Π acceptors. In particular, in the adducts of type B, the resonance structure of Bdominates in the basic structure, if D is a phosphine, so that transition metal complexes, which can be derived from these compounds, are rare. Even in cases in which D is an N-heterocyclic carbene (NHC), the coordination properties of the ...

PHOSPHOROUS COMPOUND AND TRANSITION METAL COMPLEX THEREOF

The present invention provides a phosphorous compound represented by general formula (1), and transition metal complexes containing such phosphorous compounds as ligands: 2. The phosphorous compound according to claim 1 , wherein Z is selected from the group consisting of an oxy group claim 1 , a thio group claim 1 , imino groups optionally having substitutent(s) claim 1 , methylene groups optionally having substitutent(s) claim 1 , and ethylene groups optionally having substitutent(s).3. The phosphorous compound according to which is an optically active substance.4. The phosphorous compound according to claim 1 , wherein Y is a lone electron pair.5. A transition metal complex comprising the phosphorous compound according to as a ligand.6. The transition metal complex according to claim 5 , comprising a transition metal selected from the group consisting of iron claim 5 , cobalt claim 5 , nickel claim 5 , copper claim 5 , ruthenium claim 5 , rhodium claim 5 , palladium claim 5 , silver claim 5 , osmium claim 5 , iridium claim 5 , platinum claim 5 , and gold. The present invention relates to a novel phosphorous compound and a transition metal complex containing the phosphorous compound as a ligand.Today, various transition metal complexes composed of transition metal species and ligands are used as catalysts of organic synthesis reactions. It is well known that not only transition metal species but also ligands of complexes play important roles as factors of exhibiting the performance or activity of such catalysts. For this reason, heretofore, numerous coordination compounds including phosphorous compounds have been developed as ligands. Furthermore, when an organic synthesis reaction is carried out using a complex catalyst, it is possible to construct optimum catalysts for a variety of substrates by appropriately combining transition metal species and ligands. Hence, the research and development are still actively conducted at present. It is needless to say that the ...

TRI-(ADAMANTYL)PHOSPHINES AND APPLICATIONS THEREOF

In one aspect, phosphine compounds comprising three adamantyl moieties (PAd) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAdligands are also provided for catalytic synthesis including catalytic cross-coupling reactions. 1. A method of synthesizing a tri-(adamantyl)phosphine compound , PAd , comprising:{'sub': 2', '2', 'N', '3, 'providing a reaction mixture including di-(adamantyl)phosphine (PAd) and a substituted adamantyl moiety and reacting the PAdand substituted adamantyl moiety via an S1 pathway to provide the PAd.'}2. The method of claim 1 , wherein adamantyl moieties (Ad) of the PAdare independently selected from the group consisting of adamantane claim 1 , diamantane claim 1 , triamantane and derivatives thereof.3. The method of claim 1 , wherein the substituted adamantyl moiety comprises a leaving group.4. The method of claim 3 , wherein the leaving group is selected from the group consisting of acetate claim 3 , triflate claim 3 , tosylate and hydroxyl.5. The method of claim 1 , wherein yield of the PAdis greater than 50 percent.6. The method of claim 1 , wherein yield of the PAdis greater than 60 percent.7. The method of claim 1 , wherein synthesizing the tri-(adamantyl)phosphine is performed at room temperature.8. A method of synthesizing a tri-(adamantyl)phosphine compound claim 1 , PAd claim 1 , comprising:{'sub': 2', 'N', '3, 'providing a reaction mixture including di-(adamantyl)phosphide and a substituted adamantyl moiety and reacting the PAdand substituted adamantyl moiety via an S1 pathway to provide the PAd.'}9. The method of claim 8 , wherein adamantyl moieties (Ad) of the di-(adamantyl)phosphide are independently selected from the group consisting of ...

HYDROGENATION OF ESTERS WITH FE/TRIDENTATE LIGANDS COMPLEXES

The present invention relates to certain iron complexes that have utility in the field of catalytic hydrogenation and, more particularly, to certain iron complexes of tridentate ligands having one amino or imino coordinating groups and two phosphino coordinating groups. These iron complexes can be used in hydrogenation processes for the reduction of ketones, aldehydes, esters or lactones into the corresponding alcohol or diol, respectively. 2. A complex according to claim 1 , wherein L′ represents a CO moiety.3. A complex according to claim 1 , wherein the tridentate L3 ligand is a C-Cor a C-Ccompound.4. A complex according to claim 1 , wherein each Y represents claim 1 , simultaneously or independently claim 1 , a hydrogen or chlorine or bromine atom claim 1 , a methoxy claim 1 , ethoxy or isopropoxy radical claim 1 , or a BHgroup.5. A complex according to claim 1 , wherein each Z represents claim 1 , simultaneously or independently claim 1 , a chlorine or bromine atom claim 1 , a methoxy claim 1 , ethoxy or isopropoxy radical claim 1 , or a BHgroup. This application is a division of U.S. application Ser. No. 15/105,927 filed Jun. 27, 2016, which is a 371 filing of International patent application no. PCT/EP2014/077217 filed Dec. 10, 2014, which claims the benefit of European patent application no. 13198076.5 filed Dec. 18, 2013, the entire content of each of which is incorporated herein by reference thereto.The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of Fe complexes with tridentate ligands, in hydrogenation processes for the reduction of esters, lactones, ketones or aldehydes into the corresponding alcohol or diol, respectively.Reduction of an ester functional group to the corresponding alcohol is one of the fundamental reactions in organic chemistry, and is used in a large number of chemical processes.In general, two main types of processes are known to achieve such a transformation. Such types of ...

Metallocen-verbindungen

Metallocen-Verbindungen der Formel (I), in der CpI und CpII Carbanionen mit einer Cyclopentadienyl-haltigen Struktur darstellen, D ein Donoratom und A ein Akzeptoratom darstellen, wobei D und A durch eine reversible koordinative Bindung derart verknüpft sind, daß die Donorgruppe eine positive (Teil)Ladung und die Akzeptorgruppe eine negative (Teil)Ladung annehmen, M für ein Übergangsmetall der III., IV., V. oder VI. Nebengruppe des Periodensystems der Elemente (Mendelejew) steht, X ein Anionäquivalent bedeutet und n in Abhängigkeit von der Ladung von M die Zahl Null, Eins, Zwei, Drei oder Vier bedeutet, sind neu und können als Katalysatoren für die (Co)Polymerisation von Olefinen, i-Olefinen, Alkinen und/oder Diolefinen oder für die ringöffnende Polyaddition eingesetzt werden. Eine typische Röntgeustrukturanalyse wird durch Formel (18a) dargestellt.

Metallocen-Verbindungen, Verfahren zu deren Herstellung, sowie ihre Verwendung

Process for the carbonylation of ethylenically unsaturated compouds

A process for the carbonylation of ethylenically unsaturated compounds is described. The process comprises reacting an ethylenically unsaturated compound with carbon monoxide in the presence of a source of hydroxyl groups and a catalyst system. The catalyst system is obtained by combining: (a) metal of Group VIII or a compound thereof: and (b) a bidentate phosphine of general formula (I) The carbonylation reaction is carried out at a temperature of between -30°C to 49°C and under a CO partial pressure of less than 30 x105 N.m-2.

Catalyst systems and polymerization processes

In accordance with the present invention there is provided a cyclopentadienyl-type ligand represented by the formula ZA, wherein Z is a cyclopentadienyl-type group, wherein A is --YPR 2 , --YNR 2 , or --NR 2 , wherein Y is an alkylene group containing 1 to 24 carbon atoms, wherein each R is individually selected from alkyl groups containing 1 to 20 carbon atoms. Another aspect of the invention is to provide a metallocene represented by the formula ZAMX 3 , wherein Z and A are as described above, M is a Group IVB or VB transition metal, and X is a halide. Other aspects of the present invention include catalyst systems comprising the metallocenes and an organoaluminoxane, processes for preparing the above defined ligands, metallocenes and catalyst systems, and polymerization processes employing the catalyst systems.

Metallocene compounds

In accordance with the present invention there is provided a cyclopentadienyl-type ligand represented by the formula ZA, wherein Z is a cyclopentadienyl-type group, wherein A is --YPR 2 , --YNR 2 , or --NR 2 , wherein Y is an alkylene group containing 1 to 24 carbon atoms, wherein each R is individually selected from alkyl groups containing 1 to 20 carbon atoms. Another aspect of the invention is to provide a metallocene represented by the formula ZAMX 3 , wherein Z and A are as described above, M is a Group IVB or VB transition metal, and X is a halide. Other aspects of the present invention include catalyst systems comprising the metallocenes and an organoaluminoxane, processes for preparing the above defined ligands, metallocenes and catalyst systems, and polymerization processes employing the catalyst systems.

Process for preparing metallocene compounds

In accordance with the present invention there is provided a cyclopentadienyl-type ligand represented by the formula ZA, wherein Z is a cyclopentadienyl-type group, wherein A is --YPR 2 , --YNR 2 , or --NR 2 , wherein Y is an alkylene group containing 1 to 24 carbon atoms, wherein each R is individually selected from alkyl groups containing 1 to 20 carbon atoms. Another aspect of the invention is to provide a metallocene represented by the formula ZAMX 3 , wherein Z and A are as described above, M is a Group IVB or VB transition metal, and X is a halide. Other aspects of the present invention include catalyst systems comprising the metallocenes and an organoaluminoxane, processes for preparing the above defined ligands, metallocenes and catalyst systems, and polymerization processes employing the catalyst systems.

Process for preparing cyclopentadienyl-type ligands

In accordance with the present invention there is provided a cyclopentadienyl-type ligand represented by the formula ZA, wherein Z is a cyclopentadienyl-type group, wherein A is --YPR 2 , --YNR 2 , or --NR 2 , wherein Y is an alkylene group containing 1 to 24 carbon atoms, wherein each R is individually selected from alkyl groups containing 1 to 20 carbon atoms. Another aspect of the invention is to provide a metallocene represented by the formula ZAMX 3 , wherein Z and A are as described above, M is a Group IVB or VB transition metal, and X is a halide. Other aspects of the present invention include catalyst systems comprising the metallocenes and an organoaluminoxane, processes for preparing the above defined ligands, metallocenes and catalyst systems, and polymerization processes employing the catalyst systems.

Method for producing cycloolefin (co)polymers for technical applications

Cycloolefin copolymers for industrial applications, with the exception of the use for optical data memories, can be prepared by copolymerization of monomers from the group consisting of cyclic olefins, α-olefins having 2 or more C atoms and optionally conjugated or non-conjugated diolefins, the catalysts employed being metallocene compounds or π complex compounds of the formula ##STR1## in which CpI and CpII represent carbanions having a cyclopenadienyl-containing structure, πI and πII represent charged or electrically neutral π systems, D represents a donor atom and A represents an acceptor atom, where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge, M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of the elements (Mendeleev), including the lanthanides and the actinides, X denotes one anion equivalent and n denotes the number zero, one, two, three or four, depending on the charge of M.

Method for producing metallocene compounds formed by two carbanions

Metallocene compounds of the formulawhereCpI and CpII are carbanions having a cyclopentadienyl-containing structure,D is a donor atom andA is an acceptor atom,where D and A are linked by a reversible coordinative bond in such a way that the donor group takes on a positive (partial) charge and the acceptor group takes on a negative (partial) charge,M represents a transition metal of transition group III, IV, V or VI of the Periodic Table of the Elements (Mendeleev),X is one anion equivalent andn is, depending on the charge of M, zero, one, two, three or four,are new and can be used as catalysts for the (co)polymerization of olefins, i-olefins, alkines and/or diolefins or for ring-opening polyaddition.A typical X-ray structure analysis is represented by formula 18a.

Method for producing elastomers

Elastomers can be prepared by (co)polymerization of monomers consisting of the group of C 2 -C 8 -α-olefins, C 4 -C 15 -diolefins and other monomers in the bulk, solution, slurry or gas phase, the catalysts employed being metallocene compounds or the π complex compounds of the formula in which CpI and CpII represent carbanions having a cyclopentadienyl-containing structure, πI and πII represent charged or electrically neutral π systems, D represents a donor atom and A represents an acceptor atom, where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge, M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of the Elements (Mendeleev), including the lanthanides and the actinides, X denotes one anion equivalent and n denotes the number zero, one, two, three or four, depending on the charge of M.

高熔点聚烯烃的制备方法

高熔点聚烯烃可在体相、溶液相、悬浮液相或气相中制备，所采用的催化剂为下式的金属茂化合物或π配位化合物其中CpI和CpII代表具有含环戊二烯基的结构的负碳离子，πI和πII代表带电或电中性的π体系，D代表给体原子，和A代表受体原子，其中D和A通过可逆的配位键连接，使得给体基团带正电荷(或部分正电荷)，受体基团带负电荷(或部分负电荷)，M 代表(门捷列夫)元素周期表第III、IV、V或VI族的过渡金属，包括镧系元素和锕系元素，X 代表阴离子等价物，和n 代表0、1、2、3或4，其值取决于M的电荷数。

用于工业应用的环烯烃聚合物或共聚物的制备方法

除用于光学数据记忆外还可用于其它工业应用中的环烯烃共聚物可以通过由选自环烯烃、具有2个或多个碳原子的α-烯烃及任选地共轭或非共轭的二烯烃的单体进行共聚制备，所采用的催化剂是下式的金属茂化合物或π配位化合物其中CpI和CpII代表具有含环戊二烯基的结构的负碳离子，πI和πII代表带电荷的或电中性的π体系，D 代表给体原子，和A 代表受体原子，其中D和A通过可逆的配位键连接，使得给体带正电荷(或部分正电荷)，受体基团带负电荷(或部分负电荷)，M 代表(门捷列夫)元素周期表第III、IV、V或VI族的过渡金属，包括镧系元素和锕系元素，X 代表阴离子等价物，和n 代表0、1、2、3或4，其值取决于M的电荷数。

Method for producing thermoplastic elastomers

Thermoplastic elastomers can be prepared by (co)polymerization of monomers from the group consisting of C 2 -C 8 -α-olefins, C 4 -C 15 -diolefins and other monomers in the bulk, solution, slurry or gas phase, the catalysts employed being metallocene compounds or the π complex compounds of the formulae in which CpI and CpII represent carbanions having a cyclopentadienyl-containing structure, πI and πII represent charged or electrically neutral π systems, D represents a donor atom and A represents an acceptor atom, where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge, M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of the Elements (Mendeleev), including the lanthanides and actinides, X denotes one anion equivalent and n denotes the number zero, one, two, three or four, depending on the charge of M.

Method for producing cycloolefin (CO) polymers for use in optical data memories

Cycloolefin copolymers for use for optical data memories, can be prepared by copolymerization of monomers from the group consisting of cyclic olefins, α-olefins having 2 or more C atoms and optionally conjugated or non-conjugated diolefins, the catalysts employed being metallocene compounds or π complex compounds of the formula in which CpI and CpII represent carbanions having a cyclopentadienyl-containing structure, πI and πII represent charged or electrically neutral π systems, D represents a donor atom and A represents an acceptor atom, where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge, M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of elements (Mendeleev), including the lanthanides and the actinides, X denotes an anion equivalent and n denotes the number zero, one, two, three or four, depending on the charge of M.

感光性树脂组合物、感光性树脂膜、固化物的制造方法、层叠体及电子器件

本发明的感光性树脂组合物含有：(A)成分：具有光聚合性官能团及碳‑氮键的高分子量体；(B)成分：具有光聚合性官能团的低分子量体；(C)成分：光聚合引发剂；及(D)成分：三唑系化合物。

Trimerisation and oligomerisation of olefins using a chromium based catalyst

The invention provides a olefin oligomerisation catalyst system that includes: a multidentate mixed heteroatomic ligand, which ligand includes three donor heteroatoms of which one donor heteroatom is sulfur, one donor heteroatom is nitrogen and one donor heteroatom is a phosphorous atom and wherein the ligand is selected such that none of the donor heteroatoms are directly bonded to any of the other donor heteroatoms; and chromium; wherein the ligand is of the following type: R 1 A(R 2 BR 3 R 4 )(R 5 CR 6 ) wherein R 1 , R 3 , R 4 and R 6 may be hydrogen or independently be selected from the groups consisting of alkyl, aryl, aryloxy, halogen, nitro, alkoxycarbonyl, carbonyloxy, alkoxy, aminocarbonyl, carbonylamino, dialkylamino, or derivatives thereof, or aryl substituted with any of these substituents; R 2 and R 5 may be the same or different and are C 1 to C 15 hydrocarbyls; A is nitrogen; B is phosphorous; and C is sulfur. The invention also provides a process for the oligomerisation of olefins including the step of contacting the olefins with such a catalyst system.

Cyclopentadiene compound substituted with branched alkyl groups

Polysubstituted cyclopentadiene compound, in which at least one substituent is of the form -RDR' n , in which R is a bonding group, D is a hetero atom selected from group 15 or 16 of the Periodic System of the Elements, R' is a substituent and n is the number of R' groups bonded to D, and in that at least one further substituent is a branched alkyl group.

Met vertakte alkylgroepen gesubstitueerde cyclopentadieenverbinding.

hydrocarbon conversion catalyst system; and process for oligomerization of olefins.

Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use

In accordance with the present invention there is provided a cyclopentadienyl-type ligand represented by the formula ZA, wherein Z is a cyclopentadienyl-type group, wherein A is --YPR 2 , --YNR 2 , or --NR 2 , wherein Y is an alkylene group containing 1 to 24 carbon atoms, wherein each R is individually selected from alkyl groups containing 1 to 20 carbon atoms. Another aspect of the invention is to provide a metallocene represented by the formula ZAMX 3 , wherein Z and A are as described above, M is a Group IVB or VB transition metal, and X is a halide. Other aspects of the present invention include catalyst systems comprising the metallocenes and an organoaluminoxane, processes for preparing the above defined ligands, metallocenes and catalyst systems, and polymerization processes employing the catalyst systems.

Method for producing thermoplastic elastomers

Method for producing high melting-point polyolefins

High-melting polyolefins can be prepared in bulk, in solution, in suspension or in the gas phase, the catalysts employed being metallocene compounds or π complex compounds of the formula in which CpI and CpII represent carbanions having a cyclopentadienyl-containing structure, πI and πII represent charged or electrically neutral π systems, D represents a donor atom and A represents an acceptor atom, where D and A are linked by a reversible coordinate bond such that the donor groups assumes a positive (part) charge and the acceptor group assumes a negative (part) charge, M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of the Elements (Mendeleev), including the lanthanides and the actinides, X denotes one anion equivalent and n denotes the number zero, one, two, three or four, depending on the charge of M.

Method for producing high melting-point polyolefins

制备弹性体的方法

在本体、溶液、淤浆或气相中让选自C 2 -C 8 -α-烯烃，C 4 -C 15 -二烯烃和其它单体的单体进行(共)聚合反应来制备弹性体，所使用的催化剂是以下通式的金属茂化合物或π配位化合物：其中CpI和CpII表示具有含环戊二烯基结构的负碳离子，πI和πII表示带电荷的或电荷中性的π体系，D表示给体原子和A表示受体原子，其中D和A通过可逆配价键连接使得给体基团带正(部分)基团带负(部分)电荷，M表示元素(门捷列夫)周期表副族III，IV，V或VI的过渡金属，包括镧系元素和锕系元素，X指一阴离子当量物和n指0，1，2，3或4，依M的电荷而定。

Trimerisation and oligomerisation of olefins using a chromium based catalyst

The invention provides a mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms, of which at least one heteroatom is nitrogen and at least two heteroatoms are not the same. The invention also provides a multidentate mixed heroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms. At least one heteroatom may be nitrogen and at least 2 heteroatoms may not be the same.

Catalyst system for olefin oligomerization, and method for olefin oligomerization using the same

The present invention relates to a compound represented by Chemical Formula 1, a catalyst system for olefin oligomerization comprising the same, and a method of olefin oligomerization using the same.

Sulfonated organophosphine compounds and use thereof in hydroformylation processes

A compound comprising a sulfonated triorganophosphine of formula R1R2PR3[SO3M)]n, wherein R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups; wherein R3 represents a branched divalent or polyvalent, alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents, and further wherein R3 does not contain any aryl moieties; M represents a monovalent cation; and n is an integer representing a total number of sulfonated substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improving ligand and transition metal, e.g., rhodium, recovery and recycling, as compared with prior art ligands.

Sulfonated organophosphine compounds and use in hydroformylation processes

A compound comprising a sulfonated dihydrocarbyl(arylalkyl)phosphine of formula R 1 R 2 PR 3 —(SO 3 M) n , wherein the R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups, and R 3 is a divalent or polyvalent arylalkylene radical such that the alkyl moiety is bonded to the phosphorus atom and the aryl moiety is bonded to the alkyl and is also substituted with one or more sulfonate groups; M is a monovalent cation, and n ranges from 1 to 3. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improved ligand and transition metal, e.g., rhodium, recovery and recycling.

Sulfonated organophosphine compounds and use in hydroformylation processes

A compound comprising a sulfonated dihydrocarbyl(arylalkyl)phosphine of formula R 1 R 2 PR 3 —(SO 3 M) n , wherein the R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups, and R 3 is a divalent or polyvalent arylalkylene radical such that the alkyl moiety is bonded to the phosphorus atom and the aryl moiety is bonded to the alkyl and is also substituted with one or more sulfonate groups; M is a monovalent cation, and n ranges from 1 to 3. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improved ligand and transition metal, e.g., rhodium, recovery and recycling.

Sulfonated organophosphine compounds and use thereof in hydroformylation processes

A compound comprising a sulfonated triorganophosphine of formula R 1 R 2 PR 3 [SO 3 M)] n , wherein R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups; wherein R 3 represents a branched divalent or polyvalent, alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents, and further wherein R 3 does not contain any aryl moieties; M represents a monovalent cation; and n is an integer representing a total number of sulfonated substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improving ligand and transition metal, e.g., rhodium, recovery and recycling, as compared with prior art ligands.

Sulfonated organophosphine compounds and use thereof in hydroformylation processes

A compound comprising a class of sulfonated triorganophosphine compounds of formula R 1 R 2 P—R 3 [—O—(CH 2 ) n —(SO 3 M)] m , wherein the R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R 3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R 3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.

Sulfonated organophosphine compounds and use thereof in hydroformylation processes

A compound comprising a sulfonated triorganophosphine of formula R 1 R 2 PR 3 [SO 3 M)] n , wherein R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups; wherein R 3 represents a branched divalent or polyvalent, alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents, and further wherein R 3 does not contain any aryl moieties; M represents a monovalent cation; and n is an integer representing a total number of sulfonated substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improving ligand and transition metal, e.g., rhodium, recovery and recycling, as compared with prior art ligands.

Sulfonated organophosphine compounds and use thereof in hydroformylation processes

A compound comprising a class of sulfonated triorganophosphine compounds of formula R 1 R 2 P—R 3 [—O—(CH 2 ) n —(SO 3 M)] m , wherein the R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R 3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R 3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.

配体化合物、用于烯烃低聚反应的催化剂体系及使用其的烯烃低聚方法

本发明涉及由化学式1表示的化合物、包含所述化合物的用于烯烃低聚反应的催化剂体系、以及使用其的烯烃低聚方法。

Metallocene compounds

Metallocene compounds of the formula (See formulae (Ia & Ib) where CpI and CpII are carbanions having a cyclopentadienyl-containing structure, D is a donor atom and A is an acceptor atom, where D and A are linked by a reversible coordinative bond in such a way that the donor group takes on a positive (partial) charge and the acceptor group takes on a negative (partial) charge, M represents a transition metal of transition group III, IV, V or VI of the Periodic Table of the Elements (Mendeleev), X is one anion equivalent and n is, depending on the charge of M, zero, one, two, three or four, are new and can be used as catalysts for the (co)polymerization of olefins, i-olefins, alkines and/or diolefins or for ring-opening polyaddition. A typical X-ray structure analysis is represented by formula 18a. (See formula 18a)

Metallocen-verbindungen

Metallocene compounds

Metallocene compounds

Metallocene compounds of the formulawhereCpI and CpII are carbanions having a cyclopentadienyl-containing structure,D is a donor atom andA is an acceptor atom,where D and A are linked by a reversible coordinative bond in such a way that the donor group takes on a positive (partial) charge and the acceptor group takes on a negative (partial) charge,M represents a transition metal of transition group III, IV, V or VI of the Periodic Table of the Elements (Mendeleev),X is one anion equivalent andn is, depending on the charge of M, zero, one, two, three or four,are new and can be used as catalysts for the (co)polymerization of olefins, i-olefins, alkines and/or diolefins or for ring-opening polyaddition.A typical X-ray structure analysis is represented by formula 18a.

Metallocene compounds, process for their preparation, use of the compounds, reaction product of ionizing agents and rearrangement product of metallocene compound.

Metallocene compounds

金属茂化合物

下式的金属茂化合物其中CpI和CpII是具有含-环戊二烯基结构的负碳离子，D是给体原子，A是受体原子，其中D和A通过可逆的配位键以这样的方式连接：给体基团具有正(部分)电荷，受体基团具有负(部分)电荷，M表示元素(门捷列夫)周期表过渡族III，IV，V或VI的过渡金属，X是一阴离子等价物n取决于M的电荷，是0，1，2，3或4，是新的，并可以在烯烃，异烯烃，炔烃和/或二烯烃的(共)聚合，或开环加聚中用作催化剂。一个典型的X-射线结构分析由式 18a 表示。

METALOCENE COMPOUNDS.

COMPUESTOS DE METALOCENO DE FORMULA (I) EN LA CUAL CPL Y CPLL REPRESENTAN CARBANIONES CON UNA ESTRUCTURA QUE CONTIENE CICLOPENTADIENILO; D ES UN ATOMO DONADOR Y A ES UN ATOMO ACEPTOR, ESTANDO UNIDOS D Y A DE TAL MANERA MEDIANTE UN ENLACE COORDINADO REVERSIBLE, QUE EL GRUPO DONADOR ACEPTA UNA CARGA POSITIVA (PARCIAL) Y EL GRUPO ACEPTOR ACEPTA UNA CARGA NEGATIVA (PARCIAL), M ES UN METAL DE TRANSICION DE LOS GRUPOS SECUNDARIOS III., IV., V. O VI. DEL SISTEMA PERIODICO DE LOS ELEMENTOS (MENDELEJEW), X ES UN EQUIVALENTE ANIONICO Y N EN DEPENDENCIA CON LA CARGA DE M, ES EL NUMERO 0, 1, 2, 3 O 4; SON NUEVOS Y SE PUEDEN UTILIZAR COMO CATALIZADORES PARA LA (CO)POLIMERIZACION DE OLEFINAS, I OLEFINAS, ALQUINOS Y/O DIOLEFINAS O PARA LA POLIADICION CON APERTURA DEL CICLO. SE REPRESENTA UN ANALISIS ESTRUCTURAL TIPICO MEDIANTE RAYOS X EN LA FORMULA (18A). METALOCENE COMPOUNDS OF FORMULA (I) IN WHICH CPL AND CPLL REPRESENT CARBANIONS WITH A STRUCTURE CONTAINING CYCLOPENTADIENYL; D IS A DONOR ATOM AND IS AN ACCEPTING ATOM, BEING DYA UNDER SUCH WAY THROUGH A REVERSIBLE COORDINATED LINK, THAT THE DONATOR GROUP ACCEPTS A POSITIVE (PARTIAL) CHARGE AND THE ACCEPTING GROUP ACCEPTS A NEGATIVE (PARTIAL) CHARGE OF TRANSITION OF SECONDARY GROUPS III., IV., V. OR VI. OF THE PERIODIC SYSTEM OF THE ELEMENTS (MENDELEJEW), X IS AN ANIONIC EQUIVALENT AND N IN DEPENDENCE WITH THE LOAD OF M, IS THE NUMBER 0, 1, 2, 3 OR 4; THEY ARE NEW AND CAN BE USED AS CATALYSTS FOR THE (CO) POLYMERIZATION OF OLEFINS, I OLEFINS, ALKINES AND / OR DIOLEFINS OR FOR POLYADITION WITH OPENING OF THE CYCLE. A TYPICAL STRUCTURAL ANALYSIS IS REPRESENTED BY X-RAYS IN THE FORMULA (18A).

Method for the production of rubber clastomers

الملخص: يمكن تحضير المطاط elastomers عن طريق البلمره(المشتركة) للمركبات أحادية الأصل التي تشتمل على المركبات الأولفينية α-olefins الأولية C2-C8 والمركبات الأولفينية الثنائية C4-C15 diolefins والمركبات الأحادية الأخرى الموجودة بداخل الكتلة، المحلول، الرزع أو الوسط الغازي gas phase . المحفزات المستخدمة هي مركبات ميتالوسين metallocene او مركبات المعقد باي X ذو الصيغةالشحنة ( الجزء) السالب . M تمثل العنصر الفلزي الوسطي الذي يتم اختياره من المجاميع الفرعية III ، I V ، IV ، او VI من مجاميع الجدول الدوري للعناصر (مندليف Mendeleev) والتي تشتمل على اللانتينيدات lanthanides والأكتينيدات actinides ، X تشير إلي أحد المجاميعة الصاعدة بينما يشير N إلي عدد والذي يعتمد على شحنة M صفر ، واحد ، أثنين ، ثلاثة، أربعة.والتي فيهاCpI و CpII يمثلان مجاميع صاعدة كربونية carbanions والتي تحتوي على حلقي بنتادينيل Pi II ,cyclopentadienyl و pi I يمثلان نظام باي π المشحون او المتعادل كهربائيا. D تمثل ذرة ماغة بينهما A تمثل ذرة مستقبلة حيث يوجد رابطة تناسقية عكسية والتي فيها المجموعة الماغة تمثل الشحنة الموجبة بينما المجموعة المستقبلة تمثل Abstract: Rubber elastomers can be prepared by polymerization of monoclonal compounds comprising the primary α-olefins C2-C8, C4-C15 diolefins and other monocomponents present within the mass, solution, lactation or gas phase. The catalysts used are metallocene compounds or complex X-compounds of the negative charge. M represents the intermediate metal element chosen from the subtotals III, IV, IV, or VI of the totals of the periodic table of elements (Mendeleev), which include lanthanides and actinides actinides, X refers to one of the ascending group while N refers to a number which depends on A zero, one, two, three, and four M charge in which CpI and CpII represent carbon upward groups of carbanions containing pentadienyl cyclic Pi II, cyclopentadienyl and pi I represent the electrically charged or باي pi system. D represents a magma atom between them A represents a receiving atom where there is an inverse harmonic bond in which the magha group represents ...

Method for the production of metallocene compounds with carbanions

الملخص: مركبات metallocene بالصيغة :حيث CPI و CPH عبارة عن أيونات كاربان carbanions لها تركيب محتوي على cyclopentadienyl D عبارة عن ذرة مانحة . A عبارة عن ذرة مستقبلةحيث يتم إرتباط A , D بواسطة رابطة تناسقية coordinate bond قابلة للإنحلال بحيث تأخذ المجموعة المانحة شحنة موجبة جزئية وتأخذ المجموعة المستقبلة شحنة موجبة جزئية وتأخذ المجموعة المستقبلة شحنة سالبة جزئية .M عبارة عن معدن إنتقالي ينتمي إلى أحد المجموعات الانتقالية III ، أو IV أو V أو VI في الجدول الدوري للعناصر مندليف (Mendeleev) . X عبارة عن أنيون anion مرادف .n عبارة على الشحنة تكون صفر أو ١ أو ٢ أو ٣ أو ٤ ، وتلك المركبات جديدة ويمكن إستخدامها كعوامل حفز لعملية بلمرة (أو البلمرة المشاركة) olefins أو i-olefins أو alkines و/ أو diolefins أو لعمليات الإضافة العديدة بفتح الحلقات . ويتم تمثيل تركيب الأشعة السينية x-ray المثالي لتلك المركبات في الصيغة :17 Abstract: The metallocene compounds in the formula: where CPI and CPH are carbanions ions having a structure containing cyclopentadienyl D is a donor atom. A is a receptor atom, where A, D is bonded by a degradable coordinate bond so that the donor group takes a partial positive charge, the receiving group takes a partial positive charge and the receiving group takes a partial negative charge. M is a transitional metal belonging to one of the transition groups III, or IV, V or VI in the periodic table of Mendeleev elements. X is an anion synonymous with charge. N is zero, 1, 2, 3, or 4. These compounds are new and can be used as catalysts for polymerization (or co-polymerization) olefins, i-olefins, alkines and / or diolefins or additives. Numerous open loops. The ideal x-ray synthesis of these compounds is represented in the formula: 17

Metallocene compounds

Metallocene compounds of formula (I) in which: CpI and CpII represent carbanions with a structure containing cyclopentadienyl; D represent a donator atom and A an acceptor atom, D and A being linked by a reversible, co-ordinative bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge; M stands for a transitional metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements (Mendeleev's table) including lanthanides and actinoides; X stands for an anion equivalent; and n, depending on the charge of M, stands for the figure nought, one, two, three or four. These compounds are new and can be used as catalysts for the (co)polymerisation of olefins, i-olefins, alkines and/or diolefins or for ring-opening polyaddition. A typical x-ray structural analysis is represented by formula (18a).

Metallocene compounds

Metallocene compounds

Metallocene compounds of the formula (See formulae (Ia & Ib) where CpI and CpII are carbanions having a cyclopentadienyl-containing structure, D is a donor atom and A is an acceptor atom, where D and A are linked by a reversible coordinative bond in such a way that the donor group takes on a positive (partial) charge and the acceptor group takes on a negative (partial) charge, M represents a transition metal of transition group III, IV, V or VI of the Periodic Table of the Elements (Mendeleev), X is one anion equivalent and n is, depending on the charge of M, zero, one, two, three or four, are new and can be used as catalysts for the (co)polymerization of olefins, i-olefins, alkines and/or diolefins or for ring-opening polyaddition. A typical X-ray structure analysis is represented by formula 18a. (See formula 18a)

Metallocene compounds

Metallocene compounds of formula (I) in which: CpI and CpII represent carbanions with a structure containing cyclopentadienyl; D represent a donator atom and A an acceptor atom, D and A being linked by a reversible, co-ordinative bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge; M stands for a transitional metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements (Mendeleev's table) including lanthanides and actinoides; X stands for an anion equivalent; and n, depending on the charge of M, stands for the figure nought, one, two, three or four. These compounds are new and can be used as catalysts for the (co)polymerisation of olefins, i-olefins, alkines and/or diolefins or for ring-opening polyaddition. A typical x-ray structural analysis is represented by formula (18a).

Metallocenforbindelser

Ligand compound, catalyst system for olefin oligomerization, and method for olefin oligomerization using the same

본 발명은 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법에 관한 것이다. 상기 리간드 화합물은 특정한 신규 구조를 갖는 화합물로서, 보다 높은 촉매활성으로 에틸렌을 올리고머화할 수 있는 올레핀 올리고머화 촉매계의 제공을 가능케 한다. The present invention relates to a ligand compound, a catalyst system for olefin oligomerization, and an olefin oligomerization method using the same. The ligand compound is a compound having a specific new structure, which makes it possible to provide an olefin oligomerization catalyst system capable of oligomerizing ethylene with higher catalytic activity.

Ligand compound, catalyst system for olefin oligomerization, and olefin oligomerization method using the same

高熔点聚烯烃的制备方法

高熔点聚烯烃可在体相、溶液相、悬浮液相或气相中制备,所采用的催化剂为下式的金属茂化合物或π配位化合物其中CpⅠ和CpⅡ代表具有含环戊二烯基结构的负碳离子,πⅠ和πⅡ代表带电或电中性的π体系,D代表给体原子,和A代表受体原子,其中D和A通过可逆的配位键连接,使得给体基团带正电荷(或部分正电荷),受体基团带负电荷(或部分负电荷),M代表(门捷列夫)元素周期表第Ⅲ、Ⅳ、Ⅴ或Ⅵ族的过渡金属,包括镧系元素和锕系元素,X代表阴离子等价物,和n代表0、1、2、3或4,其值取决于M的电荷数。

Method for Producing High Melting-Point Polyolefins

본 발명의 고융점 폴리올레핀은 화학식 I 또는 화학식 XIII의 메탈로센 화합물 또는 π 착화합물을 촉매로 사용하는 벌크상, 용액상, 현탁액상 또는 기체상에서 제조될 수 있다. The high melting point polyolefins of the present invention can be prepared in bulk, solution, suspension or gas phase using the metallocene compound of formula I or formula XIII or? Complex as a catalyst. <화학식 I> <Formula I> <화학식 XIII> <Formula XIII> (상기 식 중, (In the above formula, CpI 및 CpII는 시클로펜타디에닐 함유 구조를 갖는 카바니온이고, CpI and CpII are carbanions having a cyclopentadienyl containing structure, πI 및 πII은 하전되거나 또는 전기적으로 중성인 π계이고, πI and πII are charged or electrically neutral π-based, D는 공여체 원자이고, D is a donor atom, A는 수용체 원자이고, A is a receptor atom, 여기서, D 및 A는 공여기가 (부분적) 양 전하를 띠고, 수용기가 (부분적) 음 전하를 띠도록 가역적 배위 결합에 의해 연결되어 있고, Where D and A are connected by reversible coordination bonds such that the donor has a (partially) positive charge and the receptor has a (partially) negative charge, M은 란탄족 및 악티늄족을 비롯하여, 원소 주기율표(멘델리브)의 III, IV, V 또는 VI 아족의 전이 금속이고, M is a transition metal of the III, IV, V or VI subgroups of the Periodic Table of the Elements (Mendellib), including the Lanthanides and Actinides, X는 1가 음이온 등가기이고, X is a monovalent anion equivalent, n은 M의 전하에 따라 0, 1, 2, 3 또는 4이다). n is 0, 1, 2, 3 or 4 depending on the charge of M).

Cyclopentadiene compound substituted with branched alkyl groups

Polysubstituted cyclopentadiene compound, in which at least one substituent is of the form -RDR'n', in which R is a bonding group, D is a hereto atom selected from group 15 or 16 of the Periodic System of the Elements, R' is a substituent and n is the number of R' groups bonded to D, and in that at least one further substituent is a branched alkyl group. Metal complexes in which at least one of these cyclopentadiene compounds is present as a ligand are useful as catalysts for the polymerisation of alpha-olefins.

Ligand compound, catalyst system for olefin oligomerization, and method for olefin oligomerization using same

The present invention relates to a compound represented by Chemical Formula 1, a catalyst system for olefin oligomerization comprising the same, and a method of olefin oligomerization using the same.

Method for producing thermoplastic elastomers

Thermoplastic elastomers can be prepared by (co)polymerization of monomers from the group consisting of C2-C8-.alpha.-olefins, C4-C15-diolefins and other monomers in the bulk, solution, slurry or gas phase, the catalysts employed being metallocene compounds or the .pi. complex compounds of the formulae (see figure I and II) in which CpI and CpII represent carbanions having a cyclopentadienyl-containing structure, .pi.I and .pi.II represent charged or electrically neutral .pi. systems, D represents a donor atom and A represents an acceptor atom, where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge, M ~represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of the Elements (Mendeleev), including the lanthanides and actinides, X ~denotes one anion equivalent and n ~denotes the number zero, one, two, three or four, depending on the charge of M.

A catalyst system

Tertiary phosphines and their methods of preparation

삼차 포스핀은 포스핀(PH 3 또는 1차 또는 2차 포스핀)을 카르보닐기와 공액 결합된 탄소-탄소 이중 결합을 하나 보다 많이는 갖지 않는 알파, 베타-불포화 카르보닐 화합물과 반응시켜 제조된다. 본 발명의 3차 포스핀은 동일 또는 다른 R 그룹을 가질 수 있다. 본 발명의 3차 포스핀은 금속 촉매에 대한 리간드로서 또는 포스포늄 염 또는 일리드의 제조에 대한 개시 물질로서 이용될 수 있다. Tertiary phosphines are prepared by reacting phosphines (PH 3 or primary or secondary phosphines) with alpha, beta-unsaturated carbonyl compounds having no more than one carbon-carbon double bond conjugated to a carbonyl group. Tertiary phosphines of the present invention may have the same or different R groups. The tertiary phosphines of the present invention can be used as ligands for metal catalysts or as starting materials for the preparation of phosphonium salts or illides. 삼차 포스핀, 융합 이중고리, 가교 이중고리, 리간드, 포스포늄 염, 일리드 Tertiary phosphines, fused bicycles, crosslinked bicycles, ligands, phosphonium salts, illides

Trimerization and oligomerization of olefins using a chromium-based catalyst

配体化合物、用于烯烃低聚反应的催化剂体系及使用该催化剂体系的烯烃低聚方法

本发明涉及一种配体化合物、用于烯烃低聚反应的催化剂体系以及使用该催化剂体系的烯烃低聚方法。该配体化合物是一种具有特殊的新的结构的化合物并且能够提供以更高的催化剂活性低聚乙烯的用于烯烃低聚反应的催化剂体系。

Trimerisation and oligomerisation of olefins using a chromium based catalyst

The invention provides a mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms, of which at least one heteroatom is nitrogen and at least two heteroatoms are not the same.The invention also provides a multidentate mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms. At least one heteroatom may be nitrogen and at least 2 heteroatoms may not be the same.

Method for producing elastomers

Elastomers can be prepared by (co)polymerization of monomers consisting of the group of C2 C8-.alpha.-olefins, C4-C15-diolefins and other monomers in the bulk, solution, slurry or gas phase, the catalysts employed being metallocene compounds or the .pi. complex compounds of the formulae (see figure I and II) in which CpI and CpII represent carbanions having a cyclopentadienyl-containing structure, .pi.I and .pi.II represent charged or electrically neutral .pi. systems, D represents a donor atom and A represents an acceptor atom, where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge, M ~represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of the Elements (Mendeleev), including the lanthanides and the actinides, X ~denotes one anion equivalent and n ~denotes the number zero, one, two, three or four, depending on the charge of M.

Method for producing cycloolefin (co)polymers for technical applications

Method for producing cycloolefin (co) polymer for use in optical data memory

(57)【要約】 光データメモリに使用するシクロオレフィンコポリマーを、環状オレフィン、２個以上のＣ原子を有するα-オレフィンおよび場合によっては共役結合した、またはしていないジオレフィンの群からのモノマーを（共）重合することにより製造することができ、ここで式（Ｉ）または（ＸIII）のメタロセン化合物またはπ錯体化合物を触媒として使用し、式中、ＣｐＩおよびＣｐIIは、シクロペンタジエニルを含有する構造を有するカルバニオンを表し、πＩおよびπIIは荷電した、または電気的に中性なπ系を表し、Ｄは供与体原子を表し、そしてＡは受容体原子を表し、ここでＤおよびＡは供与体基が正の（部分）電荷を帯び、そして受容体原子が負の（部分）電荷を帯びるように可逆的な配位的結合により連結され、Ｍは、ランタニド系およびアクチニド系を含む元素周期表（メンデレーフ）の第III、第IV、第Ｖまたは第VI亜族の遷移金属を表し、Ｘはアニオン等価体を表し、そしてｎはＭの荷電に依存して、０、１、２、３または４を表す。

PROCEDURE FOR OBTAINING THERMOPLASTIC ELASTOMERS.

SE PUEDEN SINTETIZAR ELASTOMEROS TERMOPLASTICOS MEDIANTE (CO)POLIMERIZACION DE MONOMEROS DEL GRUPO DE LAS AL OLEFINAS DE C 2 -C 8 , DE LAS DIOLEFINAS DE C 4 C 15 , ASI COMO DE OTROS MONOMEROS EN FASE SOLIDA, DISUELTA, PASTOSA O GASEOSA, UTILIZANDOSE COMO CATALIZADORES COMPUESTOS DE METALOCENO DE FORMULA (I) O COMPUESTOS DE COMPLEJO PI DE FORMULA (I) O (XIII), EN LA QUE CPL Y CPLL REPRESENTAN CARBANIONES CON UNA ESTRUCTURA QUE CONTIENE CICLOPENTADIENILO, PI I Y PI II REPRESENTAN SISTEMAS CARGADOS O ELECTRICAMENTE NEUTRALES DE PI , D ES UN ATOMO DONADOR Y A ES UN ATOMO ACEPTOR, ESTANDO UNIDOS D Y A MEDIANTE UN ENLACE COORDENADO REVERSIBLE DE TAL MANERA, QUE EL GRUPO DONADOR ACEPTA UNA CARGA (PARCIAL) POSITIVA Y EL GRUPO ACEPTOR ACEPTA UNA CARGA (PARCIAL) NEGATIVA, M ES UN METAL DE TRANSICION DE LOS GRUPOS SECUNDARIOS III., IV., V. O VI. DEL SISTEMA PERIODICO DE LOS ELEMENTOS (MENDELEJEW) INCLUYENDO LOS LANTANIDOS Y ACTINIDOS, X ES UN EQUIVALENTE ANIONICO Y N SEGUN LA CARGA DE M SIGNIFICA EL NUMERO CERO, UNO, DOS, TRES O CUATRO. THERMOPLASTIC ELASTOMERS CAN BE SYNTHESIZED THROUGH (CO) POLYMERIZATION OF MONOMERS OF THE C 2 -C 8 AL OLEPHINES GROUP, OF C 4 C 15 DIOLEFINES, AS WELL AS OTHER PHASE, SOLID PHASE, AND GASEOUS MONOMERS AS CATALYSTS COMPOUNDS OF METALOCHENE OF FORMULA (I) OR COMPOUNDS OF PI COMPLEX OF FORMULA (I) OR (XIII), IN WHICH CPL AND CPLL REPRESENT CARBANIONS WITH A STRUCTURE CONTAINING SEMI-CYLOPENTADYENYL, REPRESENT OTHER DE PI, D IS A DONOR ATOM AND IS AN ACCEPTING ATOM, BEING UNITED DYA THROUGH A REVERSIBLE COORDINATED LINK, SUCH THAT THE DONOR GROUP ACCEPTS A POSITIVE (PARTIAL) LOAD AND THE ACCEPTING GROUP ACCEPTS A NEGATIVE (PARTIAL) LOAD IT IS A TRANSITIONAL METAL FOR SECONDARY GROUPS III., IV., V. OR VI. OF THE PERIODIC SYSTEM OF THE ELEMENTS (MENDELEJEW) INCLUDING THE LANTANIDES AND ACTINIDES, X IS AN ANIONIC EQUIVALENT AND N ACCORDING TO THE LOAD OF M MEANS THE NUMBER ZERO, ONE, TWO, THREE OR FOUR.

Method for producing thermoplastic elastomers

Thermoplastic elastomers can be produced by (co)polymerising monomers from the group of C2-C8-α-olefins, C4-C15-dioledins and other monomers in the solid phase, in solution, as slurry or in the gas phase where metallocen compounds or π-complex compounds of formulas (I) or (XIII), are used as catalysts, in which CpI and CpII represent carbanions with a structure containing cyclopentadienyl, π I and π II represent charged or electrically neutral π-systems, D represent a donator atom and A an acceptor atom, wherein D and A are linked by a reversible, coordinate bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge, M stands for a transition metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements including lanthanides and actinoides, X stands for an anion equivalent and n, depending on the charge of M, is 0, 1, 2, 3 or 4.

PROCEDURE FOR OBTAINING CYCLOOLEFINE (CO) POLYMERS FOR TECHNICAL APPLICATIONS.

COPOLIMEROS DE CICLOOLEFINA SE PUEDEN SINTETIZAR Y QUE SE UTILIZAN PARA APLICACIONES TECNICAS CON EXCEPCION DE SU UTILIZACION PARA MEMORIAS OPTICAS DE DATOS, MEDIANTE LA COPOLIMERIZACION DE MONOMEROS DEL GRUPO DE LAS OLEFINAS CICLICAS, DE LAS AL - OLEFINAS CON 2 O MAS ATOMOS DE C Y OPCIONALMENTE DE LAS OLEFINAS CONJUGADAS O NO CONJUGADAS, UTILIZANDOSE COMO CATALIZADORES COMPUESTOS DE METALOCENO O COMPUESTOS DEL COMPLEJO PI DE FORMULA (I) O (XIII), EN LA QUE CPL Y CPLL REPRESENTAN CARBANIONES CON UNA ESTRUCTURA QUE CONTIENE CICLOPENTADIENILO, PI I Y PI II REPRESENTAN SISTEMAS CARGADOS O ELECTRICAMENTE NEUTRALES DE PI , D ES UN ATOMO DONADOR Y A ES UN ATOMO ACEPTOR, ESTANDO UNIDOS D Y A MEDIANTE UN ENLACE COCINADO REVERSIBLE DE TAL MANERA, QUE EL GRUPO DONADOR ACEPTA UNA CARGA (PARCIAL) POSITIVA Y EL GRUPO ACEPTOR ACEPTA UNA CARGA (PARCIAL) NEGATIVA, M ES UN METAL DE TRANSICION DE LOS GRUPOS SECUNDARIOS III., IV., V. O VI. DEL SISTEMA PERIODICO DE LOS ELEMENTOS (MENDELEJEV) INCLUYENDO LOS LANTANIDOS Y ACTINIDOS, X ES UN EQUIVALENTE ANIONICO Y N SEGUN LA CARGA DE M SIGNIFICA EL NUMERO CERO, UNO, DOS, TRES O CUATRO. CYCLLOOLEFINE COPOLYMERS CAN BE SYNTHESIZED AND ARE USED FOR TECHNICAL APPLICATIONS EXCEPT FOR THEIR USE FOR OPTICAL DATA MEMORIES, THROUGH THE COPOLYMERIZATION OF MONOMERES FROM THE OLEFINAS CYCLIC OLEFINES. CONJUGATED OR NON-CONJUGATED OLEFINS, USED AS CATALYSTS COMPOUNDS OF METALOCHENE OR COMPOUNDS OF THE PI COMPLEX OF FORMULA (I) OR (XIII), IN WHICH THE CPL AND CPLL REPRESENT CARBANIONS WITH PIANTANIUM STRUCTURES, OR ELECTRICALLY NEUTRAL OF PI, D IS A DONOR ATOM AND ALREADY IS AN ACCEPTOR ATOM, BEING UNITED BY A REVERSIBLE COOKED LINK IN SUCH A WAY, THAT THE DONOR GROUP ACCEPTS A (PARTIAL) POSITIVE LOAD AND THE ACCEPTING GROUP ACCEPTS A CHARGE NEGATIVE, M IS A TRANSITIONAL METAL FOR SECONDARY GROUPS III., IV., V. O VI. OF THE PERIODIC SYSTEM OF THE ELEMENTS (MENDELEJEV) INCLUDING THE LANTANIDES AND ACTINIDES, X IS AN ANIONIC EQUIVALENT AND N ACCORDING TO ...

PROCEDURE FOR OBTAINING ELASTOMERS.

SE PUEDEN FABRICAR ELASTOMEROS MEDIANTE (CO)POLIMERIZACION DE MONOMEROS DEL GRUPO DE LAS AL - OLEFINAS DE C 2 C SUB,8 , DE LAS DIOLEFINAS DE C 4 -C 15 , ASI COMO DE OTR OS MONOMEROS EN FASE SOLIDA, DISUELTA, PASTOSA O GASEOSA, UTILIZANDOSE COMO CATALIZADORES COMPUESTOS DE METALOCENO O COMPUESTOS CON COMPLEJO PI DE FORMULAS (I) Y (XIII), EN LA QUE CPL Y CPLL REPRESENTAN CARBANIONES CON UNA ESTRUCTURA QUE CONTIENE CICLOPENTADIENILO, PI I Y PI II REPRESENTAN SISTEMAS CARGADOS O ELECTRICAMENTE NEUTRALES DE PI , D ES UN ATOMO DONADOR Y A ES UN ATOMO ACEPTOR, ESTANDO UNIDOS D Y A MEDIANTE UN ENLACE COORDENADO REVERSIBLE DE TAL MANERA, QUE EL GRUPO DONADOR ACEPTA UNA CARGA (PARCIAL) POSITIVA Y EL GRUPO ACEPTOR ACEPTA UNA CARGA (PARCIAL) NEGATIVA, M ES UN METAL DE TRANSICION DE LOS GRUPOS SECUNDARIOS III., IV., V. O VI. DEL SISTEMA PERIODICO DE LOS ELEMENTOS (MENDELEJEV) INCLUYENDO LOS LANTANIDOS Y ACTINIDOS, X ES UN EQUIVALENTE ANIONICO Y N SEGUN LA CARGA DE M SIGNIFICA EL NUMERO CERO, UNO, DOS, TRES O CUATRO. ELASTOMERS MAY BE MANUFACTURED THROUGH (CO) POLYMERIZATION OF MONOMERS OF THE C 2 C SUB, 8, AL OLEFINS GROUP, OF C 4 -C 15 DIOLEFINES, AS WELL AS SOLID PHASE, DISPENSED OR GASEOUS, USING AS CATALYSTS COMPOUNDS OF METALLOCHENE OR COMPOUNDS WITH PI COMPLEX OF FORMULAS (I) AND (XIII), IN WHICH CPL AND CPLL REPRESENT CARBANIONS WITH A STRUCTURE CONTAINING CYCOPLOPENTADIENYL, PI I AND PI II REPRESENT SENT , D IS A DONOR ATOM AND IS AN ACCEPTING ATOM, BEING UNITED BY A REVERSIBLE COORDINATED LINK IN SUCH A WAY, THAT THE DONOR GROUP ACCEPTS A POSITIVE (PARTIAL) LOAD AND THE ACCEPTING GROUP ACCEPTS A NEGATIVE (PARTIAL) LOAD TRANSITIONAL METAL OF SECONDARY GROUPS III., IV., V. O VI. OF THE PERIODIC SYSTEM OF THE ELEMENTS (MENDELEJEV) INCLUDING THE LANTANIDES AND ACTINIDES, X IS AN ANIONIC EQUIVALENT AND N ACCORDING TO THE LOAD OF M MEANS THE NUMBER ZERO, ONE, TWO, THREE OR FOUR.

Method for producing high melting-point polyolefins

Cycloolefin copolymers for use for optical data memories, can be prepared by copolymerization of monomers from the group consisting of cyclic olefins, alpha-olefins having 2 or more C atoms and optionally conjugated or non-conjugated diolefins, the catalysts employed being metallocene compounds or pi complex compounds of the formulain whichCpI and CpII represent carbanions having a cyclopentadienyl-containing structure,piI and piII represent charged or electrically neutral pi systems,D represents a donor atom andA represents an acceptor atom,where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge,M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of elements (Mendeleev), including the lanthanides and the actinides,X denotes an anion equivalent andn denotes the number zero, one, two, three or four, depending on the charge of M.

Method for producing thermoplastic elastomers

Cycloolefin copolymers for use for optical data memories, can be prepared by copolymerization of monomers from the group consisting of cyclic olefins, alpha-olefins having 2 or more C atoms and optionally conjugated or non-conjugated diolefins, the catalysts employed being metallocene compounds or pi complex compounds of the formulain whichCpI and CpII represent carbanions having a cyclopentadienyl-containing structure,piI and piII represent charged or electrically neutral pi systems,D represents a donor atom andA represents an acceptor atom,where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge,M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of elements (Mendeleev), including the lanthanides and the actinides,X denotes an anion equivalent andn denotes the number zero, one, two, three or four, depending on the charge of M.

Method for producing cycloolefin (co)polymers for technical applications

Cycloolefin copolymers for technical applications except for using in optical data storage devices can be produced by (co)polymerising monomers from the group of cyclic olefins, of .alpha.-olefins with 2 or more C atoms and conjugated or unconjugated diolefins (optional) where metallocene compounds or .pi.-complex compounds of formula (I) or (XIII) are used as catalysts in which CpI and CpII represent carbanions with a structure containing cyclopentadienyl, .pi.I and .pi.II represent charged or electrically neutral .pi.-systems, D represents a donator atom and A an acceptor atoms, wherein D and A are joined by a reversible coordinate bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge, M stands for a transition metal of the IIIrd, IVth, Vth or Vith subgroup of the periodic table of elements including lanthanides and actinoides, X stands for an anion equivalent and n, depending on the charge of M, is 0, 1, 2, 3 or 4.

制备用于光学数据存储器的环烯烃(共)聚合物的方法

让选自环烯烃,具有两个或多个碳原子的α－烯烃和任选为共轭或非共轭二烯烃的单体进行共聚合反应来制备用于光学数据存储器的环烯烃共聚物,所使用的催化剂是以下通式的金属茂化合物或π配合物:其中CpⅠ和CpⅡ表示具有含环戊二烯基结构的负碳离子,πⅠ和πⅡ表示带电荷的或电中性的π体系,D表示给体原子和A表示受体原子,其中D和A通过可逆配价键连接,使得给体基团带正(部分)电荷,而受体基团带负(部分)电荷,M表示元素周期表副族Ⅲ,Ⅳ,Ⅴ或Ⅵ的过渡金属,包括镧系和锕系,X指阴离子当量物和n指数字0,1,2,3或4,依M的电荷而定。

Method for producing cycloolefin (co) polymer for industrial use

(57)【要約】 環状オレフィン類、Ｃ原子数が２以上のα−オレフィン類および共役もしくは非共役ジオレフィン類（任意）から成る群のモノマー類を（共）重合させることで、光学データ記憶装置における使用を除く工業用途用のシクロオレフィン共重合体を製造することができ、ここでは、式（Ｉ）または（ＸＩＩＩ）で表されるメタロセン化合物またはπ錯体化合物を触媒として用い、ここで、ＣｐＩおよびＣｐＩＩはシクロペンタジエニル含有構造を伴うカルボアニオン類を表し、πＩおよびπＩＩは帯電しているか或は電気的に中性のπ系を表し、Ｄは供与体の原子を表しそしてＡは受容体の原子を表し、ここで、ＤおよびＡは、供与体基が正（部分）電荷を取りかつ受容体基が負（部分）電荷を取るように可逆的配位結合で結合しており、Ｍはランタニド類およびアクチノイド類を包含する元素周期律表のＩＩＩ、ＩＶ、ＶまたはＶＩ亜族の遷移金属を表し、Ｘは１アニオン相当物を表しそしてｎはＭの電荷に応じて０、１、２、３または４である。

Method for producing elastomers

PROCEDURE FOR OBTAINING HIGH MELTING POINT POLYOLEFINES.

SE PUEDEN SINTETIZAR POLIOLEFINAS DE ELEVADO PUNTO DE FUSION EN FASE SOLIDA, EN SOLUCION, EN SUSPENSION O EN FASE GASEOSA, UTILIZANDOSE COMO CATALIZADORES COMPUESTOS DE METALOCENO DE FORMULA (I) O COMPUESTOS DE COMPLEJO PI DE FORMULA (I) O (XIII), EN LA QUE CPL Y CPLL REPRESENTAN CARBANIONES CON UNA ESTRUCTURA QUE CONTIENE CICLOPENTADIENILO, PI I Y PI II REPRE SENTAN SISTEMAS CARGADOS O ELECTRICAMENTE NEUTRALES DE PI , D ES UN ATOMO DONADOR Y A ES UN ATOMO ACEPTOR, ESTANDO UNIDOS D Y A MEDIANTE UN ENLACE COORDENADO REVERSIBLE DE TAL MANERA, QUE EL GRUPO DONADOR ACEPTA UNA CARGA (PARCIAL) POSITIVA Y EL GRUPO ACEPTOR ACEPTA UNA CARGA (PARCIAL) NEGATIVA, M ES UN MATERIAL DE TRANSICION DE LOS GRUPOS SECUNDARIOS III., IV., V. O VI. DEL SISTEMA PERIODICO DE LOS ELEMENTOS (MENDELEJEV) INCLUYENDO LOS LANTANIDOS Y ACTINIDOS, X ES UN EQUIVALENTE ANIONICO Y N SEGUN LA CARGA DE M SIGNIFICA EL NUMERO CERO, UNO, DOS, TRES O CUATRO. IT IS POSSIBLE TO SYNTHESIZE HIGH-FUSING POINT POLYOLEFINS IN SOLID PHASE, IN SOLUTION, IN SUSPENSION OR IN GASEOUS PHASE, USING AS CATALYSTS COMPOSED OF METALOCENE (I) OR COMPOUNDS OF FORMULI (I) COMPLEX (I) THE ONE THAT CPL AND CPLL REPRESENT CARBANIONS WITH A STRUCTURE CONTAINING CYCLOPENTADIENYL, PI I AND PI II REPRE FEATURE CHARGED OR ELECTRICALLY NEUTRAL PI SYSTEMS, D IS A GIVING ATTORNEY IN A MEDIAN REACH, , THAT THE DONOR GROUP ACCEPTS A POSITIVE (PARTIAL) LOAD AND THE ACCEPTING GROUP ACCEPTS A NEGATIVE (PARTIAL) LOAD, M IS A TRANSITIONAL MATERIAL OF THE SECONDARY GROUPS III., IV., V. OR VI. OF THE PERIODIC SYSTEM OF THE ELEMENTS (MENDELEJEV) INCLUDING THE LANTANIDES AND ACTINIDES, X IS AN ANIONIC EQUIVALENT AND N ACCORDING TO THE LOAD OF M MEANS THE NUMBER ZERO, ONE, TWO, THREE OR FOUR.

METHOD FOR PRODUCING HIGH-MELTING POLYOLEFINES

METHOD FOR PRODUCING CYCLOOLEFIN (CO) POLYMERS FOR USE WITH OPTICAL DATA STORAGE

Method for producing high melting-point polyolefins

High melting-point polyolefins can be produced as such, in solution, suspension or gas phase, metallocene compounds of formula (I) or π-complex compounds of formulas (I) or (XIII) being used as catalysts. In said formulas: CpI and CpII represent carbanions with a structure containing cyclopentadienyl; πI and πII represent charged or electrically neutral π-systems; D represent a donator atom and A an acceptor atom, D and A being linked by a reversible, co-ordinative bond such that the donator group adopts a positive (partial) charge and the acceptor group a negative (partial) charge; M stands for a transitional metal of the IIIrd, IVth, Vth or VIth subgroup of the periodic system of elements (Mendeleev's table) including lanthanides and actinoides; X stands for an anion equivalent; and n, depending on the charge of M, stands for the figure nought, one, two, three or four.