04-02-2021 дата публикации
Номер: US20210032378A1
Принадлежит:
Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices. 2. The method of claim 1 , wherein each Ris independently (C-C)alkylene.3. The method of claim 1 , wherein each Ris independently (C-C)alkylene.4. The method of claim 1 , wherein the cationic amine compound that is reacted with the precursor polymer is of Formula (VII){'br': None, 'sup': 5', '6', '5', '+', '5', '+, 'sub': 2', '2', 'v', '3, 'N(R)—R—{[N(R)]—R}—[N(R)]\u2003\u2003 (VII)'} [{'sup': '5', 'each Ris independently alkyl;'}, {'sup': '6', 'each Ris independently alkylene;'}, 'v is an integer in a range of 0 to 10; and', 'the cationic groups have corresponding anionic counter ions., 'wherein'}6. The cationic polymer of claim 5 , wherein each Ris independently (C-C)alkylene.7. The cationic polymer of claim 5 , wherein each Ris independently (C-C)alkylene.8. The cationic polymer of claim 5 , wherein:{'sup': '1', 'Ris independently aralkyl or substituted aralkyl;'}{'sup': '4', 'claim-text': [{'br': None, 'sup': 3', '+', '+', '+, 'sub': 3', '2', '2', 'm', '3', '2', '2', 'm', '0-8', '3', '3, 'R—N(CH)—(CH)—{[N(CH)]—(CH)}—[N(CH)],'}, {'br': None, 'sup': 3', '+', '+', '+, 'sub': 3', '2', '2', '6-8', '3', '2', '2', '6-8', 'v', '3', '3, '—R—N(CH)—(CH)—{[N(CH)]—(CH)}—[N(CH)]or'}, {'br': None, 'sup': 3', '+', '+', '+, 'sub': 3', '2', '2', '6-8', '3', '2', '2', '6-8', '3-8', '3', '3, '—R—N(CH)—(CH)—{[N(CH)]—(CH)}-[N(CH)];'}], 'each Ris independently a cationic group of the formula 'v is a variable in a range of 0 to 10; and', 'm is a variable in a range of 4 to 9;'}the cationic group has corresponding anionic counter ions.9. The cationic polymer of claim 8 , wherein the anionic counter ions are chloride claim 8 , bromide claim 8 , iodide claim 8 , bicarbonate claim 8 , carbonate claim 8 , hydroxide claim 8 , alkoxide claim 8 , acetate or sulfate.10. A membrane comprising the ...
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