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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Применить Всего найдено 23883. Отображено 100.

16-02-2012 дата публикации

Aqueous coating systems based on physically drying urethane acrylates

Номер: US20120041145A1

Автор: Harald Blum, Jürgen Lippemeier, Miguel Fernandez, Stefan Sommer

Принадлежит: BAYER MATERIALSCIENCE AG

The invention relates to radiation curable coating systems on the basis of aqueous polyurethane dispersions, to a method for the production thereof, to the use of the coating systems as paints and/or adhesives, and to objects and substrates provided with said paints and/or adhesives.

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Номер записи: 1

22-03-2012 дата публикации

Reduced profile medical balloon element

Номер: US20120070599A1

Автор: Alan M. Zamore

Принадлежит: Individual

Medical dilatation balloons comprise a polymer that has the attribute of memory, and/or is crosslinked to impart memory. Such balloons exhibit a reduced tendency to overinflate at high inflation pressures. Furthermore, such balloons when shrunk radially by the application of heat while restraining axial shrinkage, exhibit customizable linear or non-linear compliance curves and lower crosslinking profile relative to the same balloon when unshrunk. Also disclosed is an expansive element within a tube whose outer diameter is equal to the outer diameter of the tube from which it was made. In addition, disclosed are (a) processes for preparing crosslinkable polymers, (b) joining crosslinked balloons to catheter systems, (c) forming shrunk balloon elements, and (d) forming an expansive element within a tube whose outer diameter is equal to the outer diameter of the tube from which it was made.

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Номер записи: 2

10-05-2012 дата публикации

Swellable biodegradable polymeric matrices and methods

Номер: US20120114589A1

Автор: Emily R. ROLFES-MEYERING, Pamela J. Reed, Stephen Chudzik

Принадлежит: Surmodics Inc

The invention provides biodegradable polymeric hydrogel matrices having excellent durability and swellability. The matrices are formed from a combination of poly-α(1→4)glucopyranose macromer and a biocompatible biostable hydrophilic macromer. The matrices can be used in association with a medical device or alone. In some methods the polymeric matrix is placed or formed at a target site in which the matrix swells and occludes the target area, and is able to be degraded at the target site after period of time.

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Номер записи: 3

17-05-2012 дата публикации

Unsaturated polyester resin

Номер: US20120121841A1

Автор: Johan Franz Gradus Antonius Jansen, Marian Henryk Szkudlarek, Silvana Rensina Antonnietta Di Silvestre, Stefanus Jacobus Duyvestijn

Принадлежит: DSM IP ASSETS BV

The present invention relates to an unsaturated polyester resin comprising itaconate esters as reactive unsaturations, wherein the acid value of the resin is in the range of from 25 to 125 and the molar ratio of hydroxyl end groups and carboxylic acid end groups is in the range of from 0.33 to 3. In one embodiment, the molar ratio of hydroxyl end groups and carboxylic acid end groups is in the range of from 0.33 to 0.9. In another embodiment, the molar ratio of hydroxyl end groups and carboxylic acid end groups is in the range of from 1.1 to 3.

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Номер записи: 4

24-05-2012 дата публикации

Photocurable resin composition

Номер: US20120125672A1

Автор: Masao Arima, Shoji Minegishi

Принадлежит: Taiyo Holdings Co Ltd

Provided is a photocurable resin composition, which has sensitivity equal to or greater than existing compositions, has alkali development properties, and which produces a cured product that does not become brittle with changes in temperature, and which also has excellent reliability in terms of water resistance, electrical insulating properties, PCT resistance, and the like. The photocurable resin composition comprises a carboxyl group-containing resin, a photopolymerization initiator, a vinyl group-containing elastomer, and a styryl group-containing compound.

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Номер записи: 5

14-06-2012 дата публикации

Coating Compositions and Articles Coated Therewith

Номер: US20120145721A1

Автор: Carl Cavallin, Jeffrey Niederst, Larry Brandenburger, Nhan Huynh, T. Howard Killilea

Принадлежит: Valspar Sourcing Inc

The present invention relates to a binder useful in coating end uses. The binder preferably includes an aqueous polymer dispersion and a vinyl polymer. The binder is useful in packaging coatings, including coatings for use on food or beverage cans, or a portion thereof.

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Номер записи: 6

19-07-2012 дата публикации

Process for preparing a polymer polyol

Номер: US20120184707A1

Автор: Andre Buijs, Nico Maria Venne, Paulus Jacobus Fennis, Willem Karzijn

Принадлежит: Shell Internationale Research Maatschappij BV

The invention relates to a process for preparing a polymer polyol, comprising mixing in a reactor vessel, a base polyol, one or more ethylenically unsaturated monomers, a polymerization initiator, optionally a macromer, and optionally a chain transfer agent, and polymerizing the mixture thus obtained at a temperature of 50 to 200° C., wherein after discharging the reactor vessel content, the interior surface of the reactor vessel walls and/or any internals present in the reactor vessel are blasted with round media.

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Номер записи: 7

26-07-2012 дата публикации

Polymeric compositions comprising polylactic acid oligomers and methods of making the same

Номер: US20120189860A1

Автор: Fengkui Li, John Ashbaugh

Принадлежит: Fina Technology Inc

Process of modifying polylactic acid and compositions formed therefrom are described herein. The process generally includes providing a first polylactic acid, wherein the first polylactic acid includes a carboxylic acid end group and unsaturating the first polylactic acid to form a second polylactic acid.

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Номер записи: 8

27-09-2012 дата публикации

Polyol Acrylates for Use in Energy Curable Inks

Номер: US20120245246A1

Автор: Michael E. O'Brien, Mingzhe Wang, Scott Yin

Принадлежит: Stepan Co

Polyol acrylates are disclosed that are the reaction products of a modified polyol and a (meth)acrylic acid or derivative thereof. The modified polyols used in preparing the polyol acrylates are the reaction product of a natural oil or fatty carboxylic acid or derivative thereof with a polyol selected from the group consisting of polyester polyols, polyether polyols, polyester ether polyols and polyalcohols such that the natural oil or fatty carboxylic acid or derivative thereof is incorporated into the backbone of the polyol. The polyol acrylates are used to prepare pigment dispersions that are useful in formulating energy curable ink compositions.

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Номер записи: 9

15-11-2012 дата публикации

Polyester (meth)acrylate resin composition, coated structure, and method for constructing the same

Номер: US20120289664A1

Автор: Takashi Matsumoto, Yuko Takikawa

Принадлежит: DIC Corp

The present invention provides a polyester (meth)acrylate resin composition that is excellent in terms of compatibility with dicyclopentenyloxyethyl (meth)acrylate (B) and that has a suitability for spraying that means the composition is suitable for use in a spraying method in the field of civil engineering and construction and the like, a coated structure produced by coating the same, and a method for constructing the same by using, as an acid component of the polyester structure of a polyester (meth)acrylate resin (A), an alicyclic dibasic acid (A1) and/or an aliphatic dibasic acid (A2) in an amount of 40% by mole or more.

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Номер записи: 10

20-12-2012 дата публикации

Resin suitable for construction purposes comprising norbornene functional groups and thiols

Номер: US20120322928A1

Автор: Guido Joseph Elisabeth Hensen, Johan Franz Gradus Antonius Jansen, Michael Alphonsus Cornelis Johannes Van Dijck

Принадлежит: DSM IP ASSETS BV

The present invention relates to a thermosetting resin composition suitable for construction purposes comprising (i) a thiol, (ii) a resin containing at least one norbornene group and having a molecular weight Mn of at least 500 Dalton, and (iii) a methacrylate containing compound whereby the resin composition comprises methacrylate containing compound in an amount of at least 5 wt % and at most 75 wt %, whereby 100 wt. % is the sum of methacrylate containing compound and resin containing at least one norbornene group. The present invention further relates to a two-component resin system consisting of component A and component B, wherein one of the components (A) comprises a resin containing at least one norbornene group and a methacrylate containing compound, whereby component (A) contains methacrylate containing compound in an amount of at least 5 wt % and at most 75 wt %, whereby 100 wt. % is the sum of methacrylate containing compound and resin containing at least one norbornene group; and the other component (B) comprises a thiol and a peroxide.

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Номер записи: 11

27-12-2012 дата публикации

Benzopinacol metalloester polymerization initiator

Номер: US20120329967A1

Автор: David L. Vines, Thomas James MURRAY

Принадлежит: Elantas PDG Inc

A polymerization initiator based on boroesters of benzopinacol for curing unsaturated polymers is disclosed. Methods of preparing the benzopinacol boroester initiator and using the initiator in polymerization reactions are additionally disclosed.

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Номер записи: 12

17-01-2013 дата публикации

Contact lens

Номер: US20130015595A1

Автор: Robert Andrew Broad

Принадлежит: Sauflon CL Ltd

A contact lens formed of a composition comprising the reaction product of: A) at least 10 weight percent, based on the total composition weight excluding solvent, of at least one silicone-containing monomer of the formula I: where n is from 1 to 3, m is from 9 to 15, each a independently is C 1-4 alkyl, and each b independently is C 1-4 alkyl; B) at least 10 weight percent, based on the total composition weight excluding solvent, of 3-methacryloxypropyl tris(trimethylsiloxy)silane; C) N-vinyl pyrrolidone; and D) at least one other non-ionic hydrophilic monomer wherein the combined amount of A) and B) is at least 20 weight percent based on the total composition weight excluding solvent, and wherein the N-vinyl pyrrolidone (NVP) is present in such an amount that the reaction product comprises polyvinyl pyrrolidone (PVP) homopolymer.

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Номер записи: 13

07-02-2013 дата публикации

Radical polymerizable resin, radical polymerizable resin composition, and cured product thereof

Номер: US20130035465A1

Автор: Kiyoharu Tsutsumi, Naoko Araki, Tomoaki Mahiko, Yoshinori Funaki

Принадлежит: Daicel Corp

Provided is a radically polymerizable resin which has a low viscosity, has excellent workability, and is rapidly cured upon application of heat and/or light to form a cured product having excellent flexibility and thermal stability. The radically polymerizable resin composition is obtained by cationic polymerization of an oxetane-ring-containing (meth)acrylic ester compound represented by following Formula (1) alone or in combination with another cationically polymerizable compound. In Formula (1), R 1 represents hydrogen atom or methyl group; R 2 represents hydrogen atom or an alkyl group; and “A” represents a linear or branched chain alkylene group having 4 to 20 carbon atoms.

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Номер записи: 14

18-04-2013 дата публикации

Thermochromic Resin Composite, Method For Adjusting Clouding Point Of Thermochromic Resin Composite, And Dimmer

Номер: US20130092888A1

Автор: Satoshi Honda, Takuya Yamamoto, Yasuyuki Tezuka

Принадлежит: Tokyo Institute of Technology NUC

Disclosed are a thermochromic resin composite and a dimmer allowing easy adjustment of a clouding point. The thermochromic resin composite is predominantly composed of an aqueous medium, an amphiphilic linear polymer changeable between a transparent state and an opaque state in the aqueous medium depending on temperature, and an amphiphilic endless polymer changeable between a transparent state and an opaque state in the aqueous medium depending on temperature, and the amphiphilic linear polymer and the amphiphilic endless polymer in the aqueous medium have one clouding point, the clouding point changing in accordance with a mixing ratio of the amphiphilic linear polymer to the amphiphilic endless polymer.

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Номер записи: 15

16-05-2013 дата публикации

Graft copolymers of polyfarnesenes with condensation polymers

Номер: US20130123379A1

Автор: Derek James Mcphee

Принадлежит: Amyris Inc

Provided herein are graft copolymers of polyfarnesenes with condensation polymers; and methods of making and using the graft copolymers disclosed herein. The graft copolymers are obtained from the reaction of a polycondensation polymer with a modified polyfarnesene obtained from reaction of a polyfarnesene with a modifier in the presence of a grafting initiator. In certain embodiments, the condensation polymers include polyesters, polycarbonates, polyamides, polyethers, phenol-formaldehyde resins, urea-formaldehyde resins, melamine-formaldehyde resins and combinations thereof. In some embodiments, the polyfarnesenes include farnesene homopolymers derived from a farnesene, and farnesene interpolymers derived from a farnesene and at least a vinyl monomer. In certain embodiments, the farnesene is prepared from a sugar by using a microorganism.

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Номер записи: 16

23-05-2013 дата публикации

Elevator rope

Номер: US20130130030A1

Автор: Atsushi Mitsui, Michio Murai

Принадлежит: Mitsubishi Electric Corp

An elevator rope of the present invention includes: a rope main body; and a covering resin layer that covers the periphery of the rope main body, the covering resin layer obtained by cross-linking a molded product of a composition comprising a thermoplastic polyurethane elastomer and a vinyl compound having two or more vinyl groups per molecule or a molded product of a thermoplastic polyurethane elastomer formed by using a polyol having a vinyl group for each molecule. In order to further stabilize the friction coefficient, inorganic fillers such as talc, a glass fiber and titanium oxide may be further mixed in the composition. The elevator rope of the present invention has a stable friction coefficient that does not depend on temperature or sliding velocity.

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Номер записи: 17

30-05-2013 дата публикации

RESIN COMPOSITION FOR FLEXOGRAPHIC PRINTING PLATE, FLEXOGRAPHIC PRINTING PLATE PRECURSOR AND PROCESS FOR PRODUCING SAME, AND FLEXOGRAPHIC PRINTING PLATE AND PROCESS FOR MAKING SAME

Номер: US20130133538A1

Автор: KANCHIKU Shigefumi, SUGASAKI Atsushi, USHIJIMA Kenta, WADA Kenji, Yoshida Kenta

Принадлежит: FUJIFILM Corporation

A resin composition for a flexographic printing plate that comprises comprising (Component A) a polyester resin having an ethylenically unsaturated bond in the interior and at a terminal. 1. A resin composition for a flexographic printing plate , comprising (Component A) a polyester resin having an ethylenically unsaturated bond in the interior and at a terminal.5. The resin composition for a flexographic printing plate according to claim 1 , wherein the resin composition further comprises (Component B) a polymerization initiator.6. The resin composition for a flexographic printing plate according to claim 1 , wherein the resin composition further comprises (Component C) an ethylenically unsaturated compound other than Component A.7. The resin composition for a flexographic printing plate according to claim 1 , wherein the resin composition is a resin composition for a laser-engraving type flexographic printing plate.8. A flexographic printing plate precursor comprising a relief-forming layer comprising the resin composition for a flexographic printing plate according to .9. A flexographic printing plate precursor claim 1 , comprising a crosslinked relief-forming layer formed by crosslinking by means of light and/or heat a relief-forming layer comprising the resin composition for a flexographic printing plate according to .10. A process for producing a flexographic printing plate precursor claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a layer formation step of forming a relief-forming layer comprising the resin composition for a flexographic printing plate according to ; and'}a crosslinking step of crosslinking the relief-forming layer by means of light and/or heat to thus obtain a flexographic printing plate precursor comprising a crosslinked relief-forming layer.11. The process for producing a flexographic printing plate precursor according to claim 10 , wherein the crosslinking step is a step of crosslinking the relief-forming layer by ...

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Номер записи: 18

04-07-2013 дата публикации

Ionic silicone hydrogels

Номер: US20130168617A1

Автор: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin

Принадлежит: Johnson and Johnson Vision Care Inc

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.

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Номер записи: 19

04-07-2013 дата публикации

Alkaline solubie resin and light sensible resin composition comprising same and use thereof

Номер: US20130171566A1

Автор: Chunmiao Zhou, Jianshe XUE, Jisheng ZHAO, Shi Shu, Xiaoxiong TIAN, Xuelan WANG

Принадлежит: BOE Technology Group Co Ltd

An embodiment of the invention discloses an alkaline soluble resin and a method for preparing the same. The chemical formula of this alkaline soluble resin is shown in Formula I: wherein a is an integer of 1 to 5, b is an integer of 1 to 5, c is an integer of 1 to 10, d is an integer of 1 to 10, m is an integer of 1 to 30, n is an integer of 1 to 10, R is hydrogen, alkyl, alkoxy or acrylate; the alkaline soluble resin has a weight-average molecular weight of 3,500-35,000. The invention also discloses a light sensible resin composition comprising the alkaline soluble resin, as well as a colored photoresist for color filters comprising the aforementioned light sensible resin composition and a display element comprising this colored photoresist.

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Номер записи: 20

25-07-2013 дата публикации

RESIN COMPOSITION FOR FLEXOGRAPHIC PRINTING PLATE, LASER-ENGRAVING TYPE FLEXOGRAPHIC PRINTING PLATE PRECURSOR AND PROCESS FOR PRODUCING SAME, AND FLEXOGRAPHIC PRINTING PLATE AND PROCESS FOR MAKING SAME

Номер: US20130186292A1

Автор: USHIJIMA Kenta

Принадлежит: FUJIFILM Corporation

Disclosed is a resin composition for a flexographic printing plate, comprising (Component A) a binder resin and (Component B) a compound represented by Formula (1) and/or Formula (2), Component B being contained at 1 to 50 parts by mass relative to 100 parts by mass of Component A, 2. The resin composition for a flexographic printing plate according to claim 1 , wherein Component A above comprises a urethane bond.3. The resin composition for a flexographic printing plate according to claim 2 , wherein Component A comprises an ethylenically unsaturated group claim 2 , a dialkoxysilyl group claim 2 , or a trialkoxysilyl group.4. The resin composition for a flexographic printing plate according to claim 1 , wherein Component A is a plastomer at 20° C.5. The resin composition for a flexographic printing plate according to claim 3 , wherein Component A is a plastomer at 20° C.6. The resin composition for a flexographic printing plate according to claim 1 , wherein Component A has a (meth)acryloyloxy group at both main chain termini.7. The resin composition for a flexographic printing plate according to claim 5 , wherein Component A has a (meth)acryloyloxy group at both main chain termini.8. The resin composition for a flexographic printing plate according to claim 1 , wherein it further comprises (Component C) a photothermal conversion agent.9. The resin composition for a flexographic printing plate according to claim 7 , wherein it further comprises (Component C) a photothermal conversion agent.10. The resin composition for a flexographic printing plate according to claim 8 , wherein Component C is carbon black.11. The resin composition for a flexographic printing plate according to claim 9 , wherein Component C is carbon black.12. The resin composition for a flexographic printing plate according to claim 1 , wherein it further comprises a polymerization initiator.13. The resin composition for a flexographic printing plate according to claim 11 , wherein it further ...

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Номер записи: 21

12-09-2013 дата публикации

Biomedical devices containing internal wetting agents

Номер: US20130237631A1

Автор: Azaam Alli, Douglas G. Vanderlaan, Frank F. Molock, JR., Gregory A. Hill, James D. Ford, Kevin P. Mccabe, Robert B. Steffen

Принадлежит: Johnson and Johnson Vision Care Inc

This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer.

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Номер записи: 22

09-01-2014 дата публикации

Hydrophobic nanostructured thin films

Номер: US20140011023A1

Автор: Alok Singh, Melik C. Demirel, Walter J. Dressick

Принадлежит: US Department of Navy

Provided herein are the polymers shown below. The value n is a positive integer. R 1 is an organic group, and each R 2 is H or a chemisorbed group, with at least one R 2 being a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured polyp-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties.

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Номер записи: 23

06-03-2014 дата публикации

Process for radically curing a composition

Номер: US20140066581A1

Автор: Iris Hilker, Johan Franz Gradus Antonius Jansen, Nanning Joerg Arfsten

Принадлежит: DSM IP ASSETS BV

The present invention relates to a process for radically curing a composition comprising a methacrylate containing compound (a1) and a monomer copolymerizable with said methacrylate containing compound in the presence of a 5 transition metal compound (c) and a peroxide, wherein the composition comprises a compound (b) according to formula (1) as monomer copolymerizable with said methacrylate containing compound whereby n=0-3; R 1 and R 2 each individually represent H, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 alkylaryl or C 7 -C 20 arylalkyl; X=O, S or NR 3 whereby R 3 =H, C 1 C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 alkylaryl, C 7 -C 20 arylalkyl, part of a polymer chain or attached to a polymer chain, and the composition comprises at least one transition metal compound (c) selected from the group consisting of Co, Cu, Mn and Fe compounds, and the curing is effected in the presence of a peroxide selected from the group consisting of hydroperoxides, perketals, peresters, percarbonates and mixtures thereof.

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Номер записи: 24

13-03-2014 дата публикации

UNSATURATED POLYESTER RESIN COMPOSITION

Номер: US20140073742A1

Автор: Arfsten Nanning Joerg, Hilker Iris, JANSEN Johan Franz Gradus Antonius

Принадлежит: DSM IP ASSETS B.V.

The present invention relates to unsaturated polyester resin compositions comprising (a) an unsaturated polyester, (b) a vinyl group containing organic compound as reactive diluent and (c) a tertiary aromatic amine, wherein the resin composition further comprises (d) a compound according to formula (1) as reactive diluent 3. Unsaturated polyester resin composition according to claim 1 , wherein the resin composition comprises styrene as vinyl group containing organic compound (b).4. Unsaturated polyester resin composition according to claim 1 , wherein the amount of unsaturated polyester (compound (a)) relative to the total amount of compounds (a) claim 1 , (b) and (d) is from 20 to 80 wt. % claim 1 , whereby the amount of compound (b) is the total amount of styrene claim 1 , styrene derivatives claim 1 , vinyl ethers claim 1 , vinyl amines and vinyl amides.5. Unsaturated polyester resin composition according to claim 1 , wherein the amount of compound (b) relative to the total amount of compounds (a) claim 1 , (b) and (d) is from 10 to 50 wt. % claim 1 , whereby the amount of compound (b) is the total amount of styrene claim 1 , styrene derivatives claim 1 , vinyl ethers claim 1 , vinyl amines and vinyl amides.6. Unsaturated polyester resin composition according to claim 1 , wherein the amount of compound (d) relative to the total amount of compounds (a) claim 1 , (b) and (d) is from 5 to 60 wt. %.7. Unsaturated polyester resin composition according to claim 1 , wherein the molar ratio of the amount of compound (b) to the amount of compound (d) is from 0.1 to 10.8. Unsaturated polyester resin composition according to claim 1 , wherein the amount of tertiary aromatic amine relative to the total amount of compounds (a) claim 1 , (b) and (d) is from 0.01 to 10 wt. %.9. Unsaturated polyester resin composition according to claim 1 , wherein the unsaturated polyester comprises fumarate building blocks.10. Unsaturated polyester resin composition according to claim 1 , ...

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Номер записи: 25

07-01-2016 дата публикации

RADICALLY POLYMERIZABLE POLYETHER, METHOD FOR PRODUCING SAID RADICALLY POLYMERIZABLE POLYETHER, POLYMERIZABLE COMPOSITION COMPRISING SAID RADICALLY POLYMERIZABLE POLYETHER AND RADICALLY POLYMERIZABLE VINYL MONOMER, AND COPOLYMER, MOLDED ARTICLE AND FILM EACH FORMED BY RADICAL POLYMERIZATION OF SAID POLYMERIZABLE COMPOSITION

Номер: US20160002399A1

Автор: KIKUCHI Saori, Niino Hiroshi

Принадлежит: MITSUBISHI RAYON CO., LTD.

Provided is (1) a radically polymerizable polyether which imparts excellent mechanical properties including excellent transparency, a high degree of elongation at break and high bending strength to a copolymer produced by the radical polymerization of a radically polymerizable monomer, and a method for producing the radically polymerizable polyether; (2) a polymerizable composition comprising the radically polymerizable polyether and a radically polymerizable vinyl monomer, which enables the formation of a copolymer having excellent mechanical properties; and (3) a copolymer, a molded article and a film, each of which comprises the copolymer. 1. A radically polymerizable polyether (A) which has a mass average molecular weight of from 20 ,000 to 100 ,000 and comprises a polyalkylene ether backbone having a (meth)acryloyl group as a pendant group and a polytetramethylene ether backbone.3. The radically polymerizable polyether (A) according to claim 2 , wherein m1 claim 2 , m2 claim 2 , and n in Formula (1) are in a relation of 0.0005 m1/(m1 +m2 +n) 0.20.4. The radically polymerizable polyether (A) according to claim 2 , wherein m1 claim 2 , m2 claim 2 , and n in Formula (1) are in a relation of 0.001≦m1/(m1+m2+n)≦0.10.5. A polymerizable composition (C) which comprises the radically polymerizable polyether (A) according to and a radically polymerizable vinyl monomer (B) as main components and is formed by blending the component (B) at from 99 to 1% by mass with respect to from 1 to 99% by mass of the component (A).6. The polymerizable composition (C) according to claim 5 , wherein the radically polymerizable vinyl monomer (B) is a (meth)acrylic monomer.7. A copolymer formed by radical polymerization of the polymerizable composition (C) according to .8. A molded article formed by radical polymerization of the polymerizable composition (C) according to after being shaped into a desired shape.9. A film formed by radical polymerization of the polymerizable composition (C) ...

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Номер записи: 26

04-01-2018 дата публикации

Lactam-functionalized polymer, compositions and applications thereof

Номер: US20180002480A1

Автор: Kelly A. BRUSH, Todd A. Brugel

Принадлежит: HERCULES LLC

A lactam-functionalized polymer is disclosed. The lactam-functionalized polymer includes lactam-functionalized polyacetal polyether, polyhemiaminal polyether or polyaminal polyether. The applications of the lactam-functionalized polymer are also disclosed.

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Номер записи: 27

04-01-2018 дата публикации

WATER DISPERSIBLE POLYAMIDE BUILDING BLOCKS

Номер: US20180002484A1

Автор: Erdodi Gabor, Pajerski Anthony D., Pourahmady Naser

Принадлежит:

Water dispersible polyamides having carboxylic acid groups are disclosed. These are made by reacting polycarboxyl is acids or anhydrides thereof with amine containing monomer or an amide terminated polyamide under reaction conditions such that a few of the carboxylic acid groups are residual and can promote dispersion in water. These polyamides after dispersion can be chain extended to higher molecular weight polymers or can be terminally functionalized with reactive groups such as isocyanate, epoxy, vinyl, acetoacetonate, or silanol groups. Composites and hybrids of these polyamides with vinyl polymers are also disclosed and claimed. 1. A water dispersible polyamide comprising a polyamide condensation reaction product of at least one polycarboxylic acid and/or anhydride thereof with at least one amine monomer with a primary or secondary amine group or an amine terminated polyamide , wherein said polyamide reaction product has a titratable acid content derived from said at least one polycarboxylic acid of from about 1 to about 100 mg KOH/gram of polyamide.2. A water dispersible polyamide according to claim 1 , wherein said titratable acid content is from about 10 to about 60 mgKOH/gram.3. A water dispersible polyamide according to claim 1 , wherein said water dispersible polyamide has a number average molecular weight from about 500 to about 50 claim 1 ,000 g/mole.4. A water dispersible polyamide according to claim 1 , wherein said water dispersible polyamide has a number average molecular weight from about 500 to about 30 claim 1 ,000 g/mole.5. A water dispersible polyamide according to claim 1 , wherein said at least one amine monomer is reacted with said polycarboxylic acid or anhydride thereof and said amine monomer comprises a polyamine with two or more primary or secondary amine groups.6. A water dispersible polyamide according to claim 1 , wherein said water dispersible polyamide is neutralized to a pH above 7 prior to dispersion or during dispersion in a ...

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Номер записи: 28

03-01-2019 дата публикации

ENVIRONMENTALLY-SENSITIVE MATERIAL AND METHOD FOR MANUFACTURING SAME

Номер: US20190002643A1

Автор: CHIEN HSIU-WEN

Принадлежит:

An environmentally-sensitive material includes a sensitive layer and a base. The sensitive layer includes a mixed portion and a sensitive portion seamlessly connected to the mixed portion. The mixed portion is made of a mixture of a first polymer gel and a second polymer gel. The sensitive portion is made of the second polymer gel. The second polymer gel is a reversible gel which is able to revert to an original size and state as a changed environmental factor reverts to a starting state. A method for manufacturing the material is also provided. 1. An environmentally-sensitive material , comprising:a sensitive layer, comprising a mixed portion and a sensitive portion, the mixed portion having a first side and a second side opposite to the first side, the entire sensitive portion being seamlessly connected to the second side of the mixed portion, the mixed portion being a mixture of a first polymer gel and a second polymer gel, the sensitive portion being the second polymer gel, the second polymer gel being a reversible gel; anda base adhered with the sensitive layer.2. The environmentally-sensitive material of claim 1 , wherein the first polymer gel is a non-sensitive gel.3. The environmentally-sensitive material of claim 2 , wherein the first polymer gel is a polyethyleneglycol based hydrogel.4. The environmentally-sensitive material of claim 3 , wherein the second polymer gel is a thermo-sensitive gel.5. The environmentally-sensitive material of claim 4 , wherein the second polymer gel is a poly N-isopropylacrylamide based hydrogel.6. The environmentally-sensitive material of claim 5 , wherein the second polymer gel is polymerized by a gel pre-polymer mixture claim 5 , comprising a mixture of N-isopropylacrylamide claim 5 , ethylene glycol dimethacrylate claim 5 , and an initiator; the second polymer gel has a critical solution temperature of about 37 degrees Celsius.7. The environmentally-sensitive material of claim 1 , wherein from the first side of the mixed ...

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Номер записи: 29

02-01-2020 дата публикации

Oxime ester photoinitiators

Номер: US20200004148A1

Автор: Hisatoshi Kura, Kazuhiko Kunimoto, Keita Tanaka, Ryuhei Yamagami, Yuichi Nishimae

Принадлежит: BASF SE

Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.

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Номер записи: 30

27-01-2022 дата публикации

Protective film for windshield of vehicle

Номер: US20220024194A1

Автор: Changsuk Lee, InHwan Oh, Subin Park

Принадлежит: Stek Co ltd

The present invention relates to a protective film for a windshield of a vehicle, which can be installed on a curved portion of the windshield of the vehicle without a thermoforming process, thereby improving the workability of a worker, and improving impact resistance to effectively protect the windshield of the vehicle.

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Номер записи: 31

14-01-2016 дата публикации

Composite Particles and a Process for Making the Same

Номер: US20160009844A1

Автор: Greenwood Bennett, Moeser Geoffrey D., Sharma Ravi, Zhang Qingling

Принадлежит:

The invention provides composite particles comprising core particles having organosilica particles disposed about the core particles. The invention also provides a process for making the composite particles. 1. Composite particles comprising core particles having organosilica particles disposed about the core particles.2. The composite particles of claim 1 , wherein the core particles comprise an organic material.34-. (canceled)5. The composite particles of claim 2 , wherein the organic material further comprises a polymerized ethylenically unsaturated monomer.6. (canceled)7. The composite particles of claim 1 , wherein the organosilica particles are derived via reaction of an organosilane compound.89-. (canceled)10. The composite particles of claim 1 , wherein the composite particles have a roundness R of from 1.1 to 2.0 claim 1 , wherein the roundness is determined by the formula: R=P/(4πS) wherein P is the perimeter of a cross-section of the particle and wherein S is the cross-sectional area of the particle.11. (canceled)12. A toner composition comprising toner particles mixed with the composite particles of .13. A structural adhesive comprising the composite particles of .14. A pressure-sensitive adhesive comprising the composite particles of .15. A coating composition comprising the composite particles of .16. A thermoset polymer comprising the composite particles of .17. A thermoplastic polymer comprising the composite particles of .18. A process for preparing composite particles comprising the steps of:(a) providing an aqueous dispersion comprising polymer or wax particles and a surface agent, the aqueous dispersion having a pH of 8 or more,{'sup': 1', '2', '1', '2, 'sub': 3', '1', '4', '2', '4', '2', '4, '(b) adding an aqueous mixture comprising an at least partially hydrolyzed organosilane compound to the aqueous dispersion to form a mixture, wherein the organosilane compound has a formula: RSiR, wherein Ris C-Calkyl, C-Calkenyl, or C-Calkynyl and wherein ...

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Номер записи: 32

27-01-2022 дата публикации

ADDITIVES FOR WINTERIZATION OF PARAFFIN INHIBITORS

Номер: US20220025245A1

Автор: Baron Holly, Felipe Mary Jane Legaspi, Mangadlao Joey Dacula, ZHANG LEI

Принадлежит: Baker Hughes Oilfield Operations LLC

A winterized paraffin inhibitor, which is capable of being used for preventing the deposition of paraffins in hydrocarbon streams and capable of withstanding freezing or crystallization at freezing or sub-freezing temperatures, may be formed by adding an oxyalkylated branched aliphatic compound having 12 or more carbons to a high molecular weight aliphatic polymer paraffin inhibitor, the oxyalkylated branched aliphatic compound having 12 or more carbons being produced by the oxyalkylation of the branched aliphatic compound having 12 or more carbon atoms in which the branched aliphatic compound having 12 or more carbon atoms is grafted with a polyether via a ring-opening reaction, wherein the polyether is a polymer of ethylene oxide, propylene oxide, butylene oxide, and combinations thereof. 1. A method for winterizing a paraffin inhibitor , the method comprising:introducing an oxyalkylated linear or branched aliphatic compound having 12 or more carbon atoms into a paraffin inhibitor composed of a high molecular weight aliphatic polymer in an amount effective to therebypreventing the freezing or crystallization of the paraffin inhibitor at temperatures ranging from about 0° C. to −40° C.2. The method of claim 1 , wherein the oxyalkylated linear or branched aliphatic compound is formed by the oxyalkylation of a linear or branched aliphatic compound having 12 or more carbon atoms.3. The method of claim 2 , wherein the linear or branched aliphatic compound having 12 or more carbon atoms is a branched aliphatic compound comprising branches containing functional groups having 2 to 28 carbon atoms.4. The method of claim 3 , wherein the branched aliphatic compound having 12 or more carbon atoms comprises branches containing functional groups selected from the group consisting of alkyl groups claim 3 , arylalkyl groups claim 3 , cycloalkyl groups claim 3 , and combinations thereof.5. The method of claim 2 , wherein the linear or branched aliphatic compound having 12 or more ...

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Номер записи: 33

14-01-2016 дата публикации

One component heat-curable powder coating composition

Номер: US20160009949A1

Автор: Jan Pieter Drijfhout, Johan F.G.A. Jansen

Принадлежит: DSM IP ASSETS BV

The invention relates to a one component heat-curable powder coating composition comprising a resin containing reactive unsaturations and wherein all said reactive unsaturations are carbon carbon double bonds connected directly to an electron withdrawing group, a thermal initiation system comprising a transition metal catalyst and a peroxide, wherein the peroxide is chosen from the group of peroxyesters, mono-peroxycarbonates and mixtures thereof and a co-crosslinker chosen from the group of vinylethers, vinylesters, vinylamides, itaconates, enamines and mixtures thereof.

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Номер записи: 34

14-01-2016 дата публикации

Heat-curable powder coating composition

Номер: US20160009950A1

Автор: Jan Pieter Drijfhout, Johan F.G.A. Jansen, Leendert Jan Molhoek

Принадлежит: DSM IP ASSETS BV

The invention relates to a heat curable powder coating composition suitable for being cured at a temperature from 60 to 130° C. comprising: a thermal initiation system and a resin system, wherein the reactivity of the thermal initiation system is such that the thermal initiation system provides a geltime between 2.5 and 1000 minutes at 60° C. in butane diol-dimethacrylate as measured according to DIN 16945 using 1 wt % of the thermal initiation system in 99 wt % of butane diol-dimethacrylate, wherein the amount of thermal initiation system is chosen such that when the powder coating composition is applied to a substrate and cured at a temperature of 130° C. for 20 minutes, the resulting coating resists at least 50 acetone double rubs, wherein the resin system comprises a resin and a co-crosslinker, wherein the resin contains reactive unsaturations and wherein said reactive unsaturations are carbon carbon double bonds connected directly to an electron withdrawing group, wherein the co-crosslinker is chosen from the group of acrylates, methacrylates, vinylesters, vinylethers, vinyl amides, alkyn ethers, alkyn esters, alkyn amides, alkyn amines, propargyl ethers, propargyl esters, itaconates, enamines and mixtures thereof, wherein the weight per unsaturation in the resin system is between 100 and 1000 g/mole as determined using 1 H NMR and wherein the powder coating composition is a one component system. The powder coating compositions of the invention balance the ability to be cured at a low temperature with the ability to be easily processed in an extruder without the formation of gel.

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Номер записи: 35

11-01-2018 дата публикации

SILICONE HYDROGELS COMPRISING HIGH LEVELS OF POLYAMIDES

Номер: US20180009922A1

Автор: Alli Azaam, Guzman Alexander

Принадлежит:

Described are silicone hydrogels with high levels of polyamides exhibiting an excellent balance of physical, mechanical, and biological properties. The silicone hydrogels are formed from a reactive monomer mixture comprising: a hydroxylalkyl (meth)acrylate monomer; hydroxyl-containing silicone components; and a polyamide, wherein the polyamide is present in an amount greater than 15 weight percent, based on the total weight of reactive components in the reactive monomer mixture. 1. A silicone hydrogel formed from a reactive monomer mixture comprising:a. at least one hydroxyalkyl (meth)acrylate monomer;b. at least one first mono-functional hydroxyl-substituted poly(disubstituted siloxane) having 4 to 8 siloxane repeating units;c. at least one second hydroxyl-substituted poly(disubstituted siloxane) selected from the group consisting of mono-functional hydroxyl-substituted poly(disubstituted siloxane) having 10 to 200, multifunctional hydroxyl-substituted poly(disubstituted siloxanes) having 10 to 200, and mixtures thereof;d. at least 15 wt % at least one polyamide, based on the total weight of reactive components in the reactive monomer mixture; ande. optional further constituents.2. The silicone hydrogel of claim 1 , wherein the polyamide is present in the reactive mixture in an amount between 15.1 weight percent and about 40 weight percent claim 1 , based on the total weight of all reactive components in the reactive monomer mixture.3. The silicone hydrogel of claim 1 , wherein the polyamide is selected from the group essentially consisting of cyclic polyamides claim 1 , acyclic polyamides claim 1 , and mixtures thereof.5. The silicone hydrogel of claim 4 , wherein the number of carbon atoms in Rand Rtaken together is 6 or less.6. The silicone hydrogel of claim 3 , wherein the cyclic polyamide is prepared from at least one of α-lactam claim 3 , β-lactam claim 3 , γ-lactam claim 3 , δ-lactam claim 3 , and ε-lactam.8. The silicone hydrogel of claim 7 , wherein f is 8 ...

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Номер записи: 36

08-01-2015 дата публикации

ORGANO-MODIFIED SILICONE POLYMERS AND HYDROGELS COMPRISING THE SAME

Номер: US20150011671A1

Автор: Bhat Shreedhar, Naik Sandeep Shashikant, Phukan Monjit, Saxena Anubhav

Принадлежит:

A hydrophilic silicone polymer composition suitable for use in producing hydrogel polymer films disclosed. In one aspect, a hydrophilic silicone monomer is of the Formula 1: 2. The polymer in the composition of claim 1 , wherein L is a hydrophilic residue chosen from a polyalkyleneoxide claim 1 , optionally a polyalkyleneoxide chosen from —CHCHO— claim 1 , —CHCH(CH)O— claim 1 , —CHCHCHO— claim 1 , and their analogues with up to 6 carbon atoms.4. The polymer in the composition of wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rin the unit G of group E are independently selected from a hydrocarbon radical chosen from methyl claim 1 , ethyl claim 1 , propyl claim 1 , iso-propyl claim 1 , butyl claim 1 , isobutyl claim 1 , phenyl claim 1 , naphthyl claim 1 , an aralkyl radical with 8 to 20 carbon atoms claim 1 , trifluoromethylpropyl claim 1 , and combinations of two or more thereof.6. The polymer in the composition of claim 1 , where Rand Rare hydrogen claim 1 , Ris chosen from hydrogen or a methyl radical claim 1 , and Ris a part of an ethylenically-unsaturated hydrophilic monomer or a hydrophobic monomer.7. The composition of claim 1 , wherein siloxane polymer has at least one terminal reactive group.8. The composition of where the siloxane polymer is (a) a homopolymer or (b) a copolymer.9. The composition of claim 8 , wherein the polymer is a copolymer further comprising a free-radical polymerizable organic monomer chosen from a vinylic monomer claim 8 , an acrylide monomer claim 8 , an acrylic monomer claim 8 , or a combination of two or more thereof.10. The copolymer of claim 8 , wherein the vinylic monomer is chosen from N-vinyl-pyrrolidone claim 8 , N-vinyl-caprolactam claim 8 , N-vinyl-acetamide claim 8 , N-vinyl-formamide and N-vinyl-isopropylamide claim 8 , vinyl benzene claim 8 , vinyl naphthalene claim 8 , vinyl pyridine claim 8 , vinyl alcohol claim 8 , vinyl containing silicones claim 8 , or a ...

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Номер записи: 37

08-01-2015 дата публикации

Silicone hydrogels having a structure formed via controlled reaction kinetics

Номер: US20150011672A1

Автор: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin

Принадлежит: Johnson and Johnson Vision Care Inc

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.

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Номер записи: 38

14-01-2021 дата публикации

PREPARATION METHOD FOR POLYCARBOXYLATE WATER REDUCER HAVING REGULAR SEQUENCE STRUCTURE

Номер: US20210009741A1

Автор: RAN Qianping, SHU Xin, Yan Han, YANG Yong, ZHAI Shuying, ZHAO Hongxia, Zhou Dongliang

Принадлежит:

Disclosed is a preparation method of a polycarboxylate water reducer having a regular sequence structure. The preparation method of the present invention comprises: performing Michael addition on polyethylene glycol ether acrylate macromonomer A and amino-containing carboxylic acid B for 5-12 hours, then cooling to 0° C., dropwise adding acryloyl chloride slowly and evenly, and further reacting for 12 hours at room temperature to obtain carboxyl-containing polyether macromonomer C; mixing the carboxyl-containing polyether macromonomer C, a small molecular RAFT reagent, an initiator, and water adequately; and holding the polymerization mass concentration at 30%-60% and heating to 60-80° C. in the atmosphere of N2 to react for 2-5 hours to obtain the polycarboxylate water reducer having a regular sequence structure. 2. The method for preparing the polycarboxylate water reducer with a regular sequence structure according to claim 1 , wherein the small molecular RAFT reagent in step (2) is any of S claim 1 ,S′-bis(2-methyl-2-propionic acid) trithiocarbonate (BDMAT) claim 1 , and (4-cyano-4-[(ethylsulfanylthiocarbonyl) sulfanyl]pentane acid (CETPA).3. The method for preparing the polycarboxylate water reducer having a regular sequence structure according to claim 2 , wherein the initiator in step (2) is potassium persulfate claim 2 , ammonium persulfate claim 2 , azobisisobutylamidine hydrochloride (V-50) claim 2 , azobisisobutylimidazoline hydrochloride (VA-044) claim 2 , azobiscyanovaleric acid (V-501) claim 2 , and azodiisopropylimidazoline (VA-061).4. A polycarboxylate water reducer having a regular sequence structure prepared by the preparation method according to claim 1 , wherein the dosage of the polycarboxylate water reducer having a regular sequence structure is 0.1% to 0.5% of the total weight of a gelling material. The present invention relates to a polycarboxylate water reducer having a regular sequence structure and a preparation method thereof, belonging ...

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Номер записи: 39

14-01-2021 дата публикации

REACTIVE SILICON GROUP-CONTAINING POLYMER AND CURABLE COMPOSITION

Номер: US20210009742A1

Автор: Harumashi Tatsuro, Kubota Nodoka

Принадлежит: KANEKA CORPORATION

Provided are reactive silicon group-containing polymers and a curable composition containing said polymers. The curable composition provides a cured product having a low modulus, flexibility, excellent tensile strength, tensile elongation, and tear strength. The curable composition can also exhibit excellent rapid curing properties even when a low-activity catalyst has been added. In the reactive silicon group-containing polymer, a reactive silicon group, indicated by general formula (1): (—Si(R)(X)), is bonded to the molecular chain of the polymer and an atom adjacent to the reactive silicon group has an unsaturated bond. In general formula (1), each Rcan independently indicate a C1-20 hydrocarbon group, and the Rhydrocarbon groups can be substituted and a hetero-containing group can be used. X can be a hydroxyl group or a hydrolyzable group, and a is 1, 2, or 3. 1. A polymer comprising: {'br': None, 'sup': '1', 'sub': 3-a', 'a, '—Si(R)(X)\u2003\u2003(1)'}, 'a reactive silicon group represented by General Formula (1){'sup': 1', '1, 'wherein each Ris independently a hydrocarbon group having 1 to 20 carbon atoms, wherein the hydrocarbon group of Ris optionally substituted with a hetero-containing group as a substituent,'}wherein X is a hydroxyl group or a hydrolyzable group,wherein a is 1, 2, or 3, andwherein an atom adjacent to the reactive silicon group has an unsaturated bond.4. The polymer according to claim 1 , wherein the polymer has the reactive silicon group represented by General Formula (1) in an average number of more than 0.8 per end.5. The polymer according to claim 1 , wherein the reactive silicon group is a dimethoxymethylsilyl group.6. The polymer according to claim 1 , wherein the reactive silicon group is a trimethoxysilyl group and/or a (methoxymethyl)dimethoxysilyl group.7. The polymer according to claim 1 , wherein a main chain backbone of the polymer is a polyoxyalkylene-based polymer.8. A curable composition claim 1 , comprising: the (A) ...

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Номер записи: 40

09-01-2020 дата публикации

OIL-REPELLENT COMPOSITION

Номер: US20200010691A1

Автор: MURATA Naoki

Принадлежит: SHOWA DENKO K.K.

An oil-repellent composition is provided containing an aqueous emulsion in which a copolymer (A) containing a constituent unit based on an ethylenically unsaturated carboxylic acid ester monomer (A1) and a constituent unit based on an ethylenically unsaturated carboxylic acid monomer (A2) is dispersed in an aqueous medium (B), and polyether-modified polydimethyl siloxane (C). 1. An oil-repellent composition , comprising:an aqueous emulsion in which a copolymer (A) containing, as an essential component, a constituent unit based on an ethylenically unsaturated carboxylic acid ester monomer A1) and a constituent unit based on an ethylenically unsaturated carboxylic acid monomer (A2) is dispersed in an aqueous medium (B); andpolyether-modified polydimethyl siloxane (C).2. The oil-repellent composition according to claim 1 ,wherein polyether described in the polyether-modified polydimethyl siloxane (C) is hydroxyl group-containing polyether-modified polydimethyl siloxane.3. The oil-repellent composition according to claim 1 ,wherein a content of the polyether-modified polydimethyl siloxane (C) is 0.1 to 20 parts by mass with respect to 100 parts by mass of the copolymer (A).4. The oil-repellent composition according to claim 1 ,wherein the constituent unit based on the ethylenically unsaturated carboxylic acid ester monomer A1) is contained at 80% to 99% by mass with respect to the entire constituent units of the copolymer (A).5. The oil-repellent composition according to claim 1 ,wherein the constituent unit based on the ethylenically unsaturated carboxylic acid monomer (A2) is contained at 0.1% to 20% by mass with respect to the entire constituent units of the copolymer (A).6. The oil-repellent composition according to claim 1 ,wherein the ethylenically unsaturated carboxylic acid ester monomer A1) is ester of alcohol having 1 to 8 carbon atoms and (meth)acrylic acid.7. The oil-repellent composition according to claim 1 ,wherein the ethylenically unsaturated carboxylic ...

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Номер записи: 41

14-01-2021 дата публикации

NEGATIVE-TYPE PHOTOSENSITIVE RESIN COMPOSITION, CURED FILM, ELEMENT AND DISPLAY APPARATUS THAT INCLUDE CURED FILM, PRODUCTION METHOD FOR THE SAME

Номер: US20210011381A1

Автор: KAMEMOTO Satoshi, Miyoshi Kazuto, Tanigaki Yugo

Принадлежит: Toray Industries, Inc.

To provide an alkaline developable negative-type photosensitive resin composition from which a cured film that has a high-resolution and low-taper pattern shape and that are excellent in heat resistance and light blocking property can be obtained. A negative-type photosensitive resin composition is characterized by containing an (A1) first resin, a (A2) second resin, a (C) photopolymerization initiator, and a (D) coloring agent, wherein the (A1) first resin is an (A1-1) polyimide and/or an (A1-2) polybenzo-oxazole, and wherein the (A2) second resin is one or more species selected from a (A2-1) polyimide precursor, a (A2-2) polybenzo-oxazole precursor, a (A2-3) polysiloxane, a (A2-4) cardo based resin, and an (A2-5) acrylic resin, and wherein a content ratio of the (A1) first resin in a total of 100 mass % of the (A1) first resin and the (A2) second resin is within the range of 25 to 90 mass %. 1. A cured film obtained by curing the negative-type photosensitive resin composition comprising an (A1) first resin , a (A2) second resin , a (C) photopolymerization initiator , and a (D) coloring agent ,wherein the (A1) first resin is an (A1-1) polyimide and/or an (A1-2) polybenzo-oxazole, andwherein the (A2) second resin is one or more species selected from a (A2-2) polybenzo-oxazole precursor, a (A2-3) polysiloxane, a (A2-4) cardo based resin, and an (A2-5) acrylic resin, andwherein a content ratio of the (A1) first resin in a total of 100 mass % of the (A1) first resin and the (A2) second resin is within a range of 25 to 90 mass %.2. The cured film according to claim 1 , wherein the (D) coloring agent contains a (D1) pigment and the (D1) pigment content ratio in the entire solid content of the negative photosensitive resin composition is within a range of 5 to 70 mass %.3. The cured film according to claim 1 , wherein the (D) coloring agent contains a (Da) black coloring agent and the (Da) black coloring agent contains a (D1a) black pigment.5. The cured film according to ...

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Номер записи: 42

09-01-2020 дата публикации

Photosensitive resin composition, cured film, element equipped with cured film, organic el display device equipped with cured film, cured film production method, and organic el display device production method

Номер: US20200012191A1

Автор: Kazuto Miyoshi, Satoshi KAMEMOTO, Yugo Tanigaki

Принадлежит: TORAY INDUSTRIES INC

The present invention provides a photosensitive resin composition which has a light-blocking property, and at the same time, a high sensitivity, and has excellent half-tone characteristics. The present invention provides a photosensitive resin composition including an (A) alkali-soluble resin, a (B) radically polymerizable compound, a (C) photo initiator, and a (D) colorant, where the (A) alkali-soluble resin contains a polyimide, a polyimide precursor, a polybenzoxazole precursor, and/or a copolymer thereof, and the (B) radically polymerizable compound contains a (B-1) bifunctional or higher (meth)acrylic compound that has a glass transition temperature of 150° C. or higher as a homopolymer, and a (B-2) tetrafunctional or higher (meth)acrylic compound other than the (B-1).

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Номер записи: 43

19-01-2017 дата публикации

COMPOSITIONS FOR PROVIDING FRIZZ-FREE WAVY HAIRSTYLES USING LOW HEAT

Номер: US20170014330A1

Автор: Steigerwald Sean, WHITE Angie

Принадлежит:

Hairstyling compositions which provide the user with continuous wave fizz-free hairstyling using only low heat (such as that applied by a blow dryer) and a round hair brush as well as a natural feel to the hair is disclosed. The compositions incorporate a mixture of two and preferably three polymers, those polymers including an organopolysiloxane graft polymer, a graft polymer comprising polyacrylate (such as polyacrylate-32), and optionally a water-soluble silicone polymer (such as bis-PEG-8-dimethicone). The method of using these compositions to provide the desired hairstyles is also disclosed. 3. The hairstyling composition according to wherein the water-soluble silicone polymer is comprised of a linear inorganic backbone of silicon and oxygen.4. The hairstyling composition according to wherein the water-soluble silicone polymer has a dimethicone backbone.5. The hairstyling composition according to wherein the water-soluble silicone polymer has organic pendent groups said pendent groups containing multiple units of ethylene glycol in an amount so as to render the polymer water-soluble.6. The hairstyling composition according to wherein the water-soluble silicone polymer is a (PEG)dimethicone claim 5 , wherein x is from about 6 to about 20.7. The hairstyling composition according to wherein the water-soluble silicone polymer is bis-PEG-8-dimethicone.8. The hairstyling composition according to wherein the water-soluble silicone polymer is selected from dimethicone claim 2 , amino-functionalized PDMS claim 2 , and mixtures thereof.9. The hairstyling composition according to wherein the polyacrylate graft polymer has a Tof from about 85° C. to about 95° C.10. The hairstyling composition according to wherein the graft acrylate styling polymer is polyacrylate-32 (a copolymer of PEG/PPG-23/6-dimethicone claim 1 , sodium acryloyl dimethyltaurate claim 1 , citraconic anhydride claim 1 , and one or more monomers of acrylic acid claim 1 , methacrylic acid claim 1 , and ...

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Номер записи: 44

21-01-2016 дата публикации

POLYSILOXANE BASED BLOCK COPOLYMERS

Номер: US20160017080A1

Автор: CURTIN Scott, IYER Ananth, OUYANG Meng, Tian Yuan, Wang Anfeng

Принадлежит:

The invention is directed to polysiloxane based block copolymers that comprise siloxane units and units derived from diol compounds comprising at least one pendant oligomeric or polymeric group. The block copolymers according to the invention surprisingly allows any glassware used during its preparation to be washed cleaned with water. The block copolymer can be used in ophthalmic lenses, and may be useful in providing contact lens formulations which are water processable.

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Номер записи: 45

18-01-2018 дата публикации

PHOTOINITIATORS THAT ARE POLYMERIC OR POLYMERIZABLE FOR USE IN UV CURABLE PRESSURE SENSITIVE ADHESIVES

Номер: US20180016363A1

Автор: Burdzy Sean M., Messana Andrew D., Silverberg Eric N., Sridhar Laxmisha, Stevens Bruce, Woods John G.

Принадлежит:

Disclosed are photoinitiators that are ultra violet (UV) reactive. The photoinitiators can be polymerized into polymeric backbones for use in UV curable hot melt pressure sensitive adhesives. The preferred polymeric backbones are acrylic-based polymers. The photoinitiators are very UVC sensitive and have excellent hot melt viscosity stability that is many fold higher than existing photoinitiators. The subject photoinitiators feature aryl ketones linked through an ether linkage to a variety of connector sequences that allow for polymerization of the photoinitiators. 5. (canceled)6. (canceled)8. (canceled)10. An ultra violet light curable polymer comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'an acrylic polymer that is a reaction product of a plurality of one or more acrylic monomers and one or more photoinitiators according to , wherein said acrylic polymer is crosslinkable through said photoinitiator groups upon exposure to ultra violet light.'}11. The ultra violet light curable polymer according to wherein the photoinitiator is present in an amount of from 0.1 to 10 mole percent based on the total number of moles of acrylate monomers used for polymerization to obtain the acrylic polymer.14. The ultra violet light curable polymer according to wherein the acrylic monomers are selected from the group consisting of: acrylic acid claim 10 , methacrylates claim 10 , methyl methacrylates claim 10 , ethyl acrylates claim 10 , 2-chloroethyl vinyl ethers claim 10 , 2 ethylhexyl acrylate claim 10 , acetoacetoxyethyl methacrylate (AAEM) claim 10 , hydroxyethyl methacrylate claim 10 , butyl acrylate claim 10 , butyl methacrylate claim 10 , trimethylolpropane triacrylate (TMPTA) claim 10 , and mixtures thereof.15. An ultra violet light curable polymer comprising:{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, 'an acrylic polymer that is a reaction product of a plurality of one or more acrylic monomers and one or more photoinitiators according to , wherein said ...

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Номер записи: 46

18-01-2018 дата публикации

Curable composition, curable ink, method for forming two-dimensional or three-dimensional images, apparatus for forming two-dimensional or three-dimensional images, cured product, structural body, and processed product

Номер: US20180016454A1

Автор: Masato Iio, Yuuki MATSUSHITA

Принадлежит: Ricoh Co Ltd

A curable composition is provided. The curable composition comprises diethylene glycol dimethacrylate and a resin, and the following conditions (1) to (3) are satisfied: (1) a mixed solution of 70 parts by mass of the diethylene glycol dimethacrylate and 30 parts by mass of the resin exhibits a viscosity 15 to 30 times that of the diethylene glycol dimethacrylate alone at 25° C.; (2) the mixed solution exhibits a spin-spin relaxation time of 240 ms or less measured by a CPMG method for pulse nuclear magnetic resonance analysis; and (3) the resin has a polystyrene or polyester structure.

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Номер записи: 47

21-01-2016 дата публикации

Photosensitive polyimide composition, base agent thereof, method of making the base agent, and solder-resistant polyimide thin film made from the composition

Номер: US20160018733A1

Автор: Hsiu-Ming Chang, Shih-Chang Lin, Tzu-Ching Hung

Принадлежит: Taiflex Scientific Co Ltd

A photosensitive polyimide composition; the composition comprises a base agent and a curing agent comprising a photoinitiator. By applying an aliphatic diamine monomer, which has a long carbon chain, and a grafting monomer, which has a main carbon chain having a double bond and an epoxy group at two ends respectively, to a method of making the base agent, a mixture of the base agent and the curing agent can be screen printed to form a photosensitive polyimide film on a copper foil. Also, the photosensitive polyimide film can be exposed under low exposure energy, and can be developed to a solder-resistant polyimide thin film by a weak alkaline developer after exposed. In addition, the solder-resistant polyimide thin film has low dielectric constant, low dielectric loss, good flame resistance, good solder resistance, and good pencil hardness. Accordingly, the photosensitive polyimide composition is applicable to high density flexible printed circuit boards.

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Номер записи: 48

16-01-2020 дата публикации

GRAFT COPOLYMER, AND THERMOPLASTIC RESIN COMPOSITION USING SAME

Номер: US20200017686A1

Автор: Atsuta Hiroyuki, FUKAMACHI Yuusuke, IWANAGA Takashi, KAMATA Ichiro, Matsuyama Hironori, NAITO Yoshitaka

Принадлежит:

A graft copolymer (B-III) includes a rubbery polymer (A-III) that is a miniemulsion polymerization reaction product of an alkyl (meth)acrylate; and at least one monomer selected from aromatic vinyl compounds, (meth)acrylic acid esters, and vinyl cyanide compounds graft-polymerized onto the rubbery polymer (A-III). 1. A graft copolymer (B-III) comprising:a rubbery polymer (A-III) that is a miniemulsion polymerization reaction product of an alkyl (meth)acrylate; andat least one monomer selected from aromatic vinyl compounds, (meth)acrylic acid esters, and vinyl cyanide compounds graft-polymerized onto the rubbery polymer (A-III).2. A thermoplastic resin composition comprising the graft copolymer (B-III) according to .3. A molded article obtained by molding the thermoplastic resin composition according to . This is a divisional Application of Ser. No. 15/771,823 filed on Apr. 27, 2018, which claims priorities of Japanese Patent Applications No. 2015-212024 filed on Oct. 28, 2015, No. 2015-212025 filed on Oct. 28, 2015, No. 2015-212026 filed on Oct. 28, 2015, and No. 2015-212027 filed on Oct. 28, 2015, disclosure of which is incorporated herein.The present invention relates to first to fourth inventions below.The first invention relates to a graft polymer that has an excellent impact-resistance-imparting effect and that can provide a thermoplastic resin composition excellent in weather resistance and color developability, a production method thereof, a thermoplastic resin composition including the graft copolymer, and a molded article thereof.The second invention relates to crosslinked particles and graft crosslinked particles that, as modifiers of a thermoplastic resin, can improve the flowability, impact resistance, and abrasion resistance of the resin without impairing its color developability and mold shrinkage rate, a thermoplastic resin composition including the crosslinked particles and/or the graft crosslinked particles, and a molded article thereof.The third ...

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Номер записи: 49

17-04-2014 дата публикации

Method of forming an image having multiple phases

Номер: US20140106267A1

Автор: Audrey A. Sherman, John E. Potts, Kevin R. Schaffer, Marc D. Radcliffe, Mieczyslaw H. Mazurek, Raymond P. Johnston, Wendi J. Winkler

Принадлежит: 3M Innovative Properties Co

A method of forming an image having multiple phases is disclosed herein. The method includes forming exposed and unexposed areas, the exposed areas comprising a first polymer network exhibiting first and second phases that are chemically connected and have different refractive indices, the first phase being continuous, and the second phase comprising a plurality of structures dispersed within the first phase, and the unexposed areas comprising a second polymer network comprising third and fourth phases that are chemically connected and have different refractive indices, the third phase being continuous, and the fourth phase comprising a plurality of structures dispersed within the third phase. The first and second polymer networks are chemically connected, and morphology formed by the first and second phases is different than that formed by the third and fourth phases.

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Номер записи: 50

25-01-2018 дата публикации

Curable resin composition, cured product, and laminate

Номер: US20180022849A1

Автор: Fumiaki Kakeya, Takahiro Matsumoto

Принадлежит: Mitsubishi Gas Chemical Co Inc

When achieving high hardness by forming a hardcoat layer including only organic matter, cure shrinkage increases, a film on which the hardcoat layer is formed curls, and in extreme cases, the hardcoat layer is prone to cracking; on the other hand, when attempting to suppress cure shrinkage, it is difficult for sufficient high hardness to be exhibited. Furthermore, organic/inorganic hybrid curable resin compositions use inorganic matter such as silica in order to increase hardness. However, this leads to the problem of the inherent properties of the resin, such as workability, being lost. The abovementioned problems have been solved by a curable resin composition containing: a urethane (meth)acrylate, which is a reactant comprising norbornene diisocyanate and a compound having one hydroxyl group and one or more (meth)acryloyl groups in a molecule; and a (meth)acrylate monomer, which is a reactant comprising a polyol having a condensed polycyclic structure, and (meth)acrylic acid.

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Номер записи: 51

22-01-2015 дата публикации

POLYURETHANE-GRAFTED HYDROGELS

Номер: US20150025161A1

Автор: Jaasma Michael J., Kourtis Lampros, McCrea Keith, Myung David, Ward Robert

Принадлежит:

An article comprising two chemically grafted polymer layers comprising a hydrogel layer and an end-functionalized polyurethane layer. The invention also includes methods of making and using the article. 1. A method of making a material that can be attached to bone , comprising the steps of:applying a solution comprising a polyurethane precursor comprising reactive endgroups, solvent, photoinitiator and crosslinker to a first polyurethane that is grafted to a hydrogel;polymerizing the polyurethane precursor; andtreating with heat and convection to remove the solvent to yield a second polyurethane coated on a polyurethane grafted hydrogel.2. The method of wherein the second polyurethane comprises polycarbonate urethane or polyether urethane.3. The method of wherein the reactive endgroups comprise one or more of acrylamide claim 1 , acrylate claim 1 , allyl ether claim 1 , methacrylate claim 1 , and vinyl.4. The method of wherein the solvent comprises one or more of dimethyacetamide claim 1 , dimethyl sulfoxide claim 1 , and tetrahydrofuran.5. The method of wherein the applying step further comprises a salt.6. A method of attaching an article to a bone claim 1 , the article comprising a porous polyurethane comprising a photoinitiator and a crosslinker claim 1 , the method comprising the steps of:placing the porous polyurethane in apposition to the bone; andpolymerizing the porous polyurethane to attach the article to the bone.7. The method of further comprising causing the porous polyurethane to contact and flow into bone.8. The method of wherein the article further comprises a second polyurethane attached to the porous polyurethane.9. The method of wherein the article further comprises a hydrogel.10. The method of wherein the polymerizing step comprises exposing the porous polyurethane to UV light claim 6 , heat claim 6 , or a chemical initiator. This application is a divisional of U.S. application Ser. No. 13/905,028, filed on May 29, 2013, entitled “Polyurethane- ...

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Номер записи: 52

10-02-2022 дата публикации

POLYCARBOXYLIC ACID WATER-REDUCING AGENT WITH HIGH ADAPTABILITY TO TEMPERATURE AND METHOD FOR PREPARING THE SAME

Номер: US20220041505A1

Автор: HUANG Zhen, LI Shentong, LIU Jiaping, RAN Qianping, SHU Xin, Yan Han, YANG Yong, ZHAO Hongxia

Принадлежит:

The present invention discloses a polycarboxylic acid water-reducing agent with high adaptability to temperature and a preparation method for preparing the same. The polycarboxylic acid water-reducing agent is prepared by introducing an unsaturated macromonomer D with a temperature-sensitive side chain which could be bonded to the backbone of the polycarboxylic acid through free radical polymerization. The polycarboxylic acid water-reducing agent prepared by the invention has an adsorption group density that can be automatically adjusted with the change of ambient temperature, and thereby shows similar dispersing capability and dispersion retention capability at different ambient temperatures, demonstrating high adaptability to different ambient temperatures. It can be used in a larger temperature range with a constant dosage, which is beneficial to further popularization and application of the polycarboxylic acid water-reducing agent in regions of different climates. 1. A polycarboxylic acid water-reducing agent with high adaptability to temperature , wherein an unsaturated macromonomer D having a temperature-sensitive side chain is introduced in the polycarboxylic acid water-reducing agent during a synthesis process of the polycarboxylic acid water-reducing agent , wherein the unsaturated macromonomer D contains an unsaturated double bond , through free radical polymerization of which the macromonomer D is bonded to a backbone of polycarboxylic acid , and the unsaturated macromonomer D further contains a temperature-sensitive side chain;the unsaturated macromonomer D is prepared by a method comprising: carrying out a step-by-step addition polymerization reaction of polyethylene glycol A with a lactone or lactam monomer B to obtain an intermediate product C, and then reacting the intermediate product C with maleic anhydride to obtain the unsaturated macromonomer D containing the double bond at a terminal end and the temperature-sensitive side chain; andthe ...

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Номер записи: 53

10-02-2022 дата публикации

EPOXY RESIN COMPOSITION, CURABLE RESIN COMPOSITION, CURED PRODUCT, AND ADHESIVE

Номер: US20220041856A1

Автор: KAMIMURA Iho, ODAKA Kazuyoshi, ONOMOTO Hiroshi, Otani Go

Принадлежит: MITSUBISHI CHEMICAL CORPORATION

These vinyl-based polymerizable group-containing silane compounds may be used alone, or two or more thereof may be used in combination. The content of the vinyl-based polymerizable group-containing silane compound is 1% by mass or more and 10% by mass or less, and preferably 1% by mass or more and 5% by mass or less, in 100% by mass of the organosiloxane mixture. When the amount of the vinyl-based polymerizable group-containing silane compound is the lower limit value or more, the peeling force and impact resistance of the obtained cured product tend to be high. When the amount of the vinyl-based polymerizable group-containing silane compound is the upper limit value or less, the peeling force and impact resistance of the obtained cured product tend to be high. 1. An epoxy resin composition , comprising:a rubber-containing polymer, andan epoxy resin, whereinthe rubber-containing polymer contains at least one rubbery polymer and at least one vinyl monomer part, andthe vinyl monomer part has a unit based on a monomer (a) described below, a unit based on a monomer (b) described below, and a unit based on a monomer (c) described below, whereinthe monomer (a) is a polyfunctional (meth)acrylate, the monomer (b) is at least one monomer selected from a group consisting of epoxy group-containing (meth)acrylates and aromatic vinyl monomers, and the monomer (c) is an alkyl (meth)acrylate.2. The epoxy resin composition according to claim 1 , whereinthe rubbery polymer is at least one selected from a group consisting of a diene rubber, a diene-acrylic composite rubber, an acrylic rubber, a silicone rubber, and an acrylic-silicone composite rubber.3. The epoxy resin composition according to claim 1 , whereina proportion of the unit based on the monomer (a) is 1% by mass or more and 45% by mass or less, and a proportion of the unit based on the monomer (b) is 1% by mass or more and 50% by mass or less, with respect to a total mass of the vinyl monomer part.4. A curable resin ...

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Номер записи: 54

23-01-2020 дата публикации

Surface-treated metal plate for polyolefin bonding, composite member, and method for manufacturing composite member

Номер: US20200023616A1

Автор: Takeshi Watase, Tatsuhiko IWA, Tetsuya Yamamoto, Yasuo Hirano

Принадлежит: Kobe Steel Ltd

A surface-treated metal sheet for adhesion to polyolefin includes a metal sheet, and a resin layer provided on at least one surface of the metal sheet. The resin layer contains an acid-modified polyolefin, the acid-modified polyolefin contains a first acid-modified polyolefin having an acid value of 5 mgKOH/g or less and a second acid-modified polyolefin having an acid value of 20 mgKOH/g or more and a melting point of higher than 90° C., and a difference between a melting point of the first acid-modified polyolefin and the melting point of the second acid-modified polyolefin is 0° C. or more and less than 40° C.

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Номер записи: 55

23-01-2020 дата публикации

COATING COMPOSITIONS EXHIBITING CORROSION RESISTANCE PROPERTIES AND RELATED COATED SUBSTRATES

Номер: US20200024461A1

Автор: Schneider John R., Walters David N.

Принадлежит:

Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating later is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed. 1. A method of coating a substrate comprising: applying a first coating composition to at least a portion of the substrate , wherein the coating composition comprises: epoxy functional material , organic solvent , and magnesium oxide particles; and wherein the substrate comprises a 2000 series aluminum alloy.2. The method of claim 1 , wherein the coating composition further comprises an amine functional material.3. The method of claim 1 , further comprising applying an additional coating onto the at least partially coated substrate.4. The method of claim 3 , wherein the additional coating comprises polyurethane.5. The method of claim 1 , wherein the first coating composition has a dry film thickness of 0.5 to 1.25 mils.6. The method of claim 1 , wherein the magnesium oxide particles have a surface area of at least 10 m/g.7. The method of claim 6 , wherein the magnesium oxide particles are platy.8. The method of claim 6 , wherein the magnesium oxide particles are spherical.9. The method of claim 6 , wherein the magnesium oxide particles are cubical.10. The method of claim 6 , wherein the magnesium oxide particles are acicular.11. The method of claim 1 , wherein the first coating composition is substantially chromate-free.12. The method of claim 3 , wherein both the first and second coating compositions are substantially chromate-free.13. The method of claim 1 , wherein the 2000 series aluminum alloy comprises an aluminum cladding.14. The method of claim 1 , comprising surface-treating the substrate prior to ...

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Номер записи: 56

28-01-2021 дата публикации

METHODS FOR PRODUCING HELMET INSERTS WITH MATERIALS HAVING MULTIPLE MECHANISMS OF HARDENING

Номер: US20210024775A1

Автор: Chen Kai, Desimone Joseph M., Goodrich James, JR. Robert K., Pinschmidt, Poelma Justin, Robeson Lloyd M., Rolland Jason P.

Принадлежит:

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component. 1. A method of forming a three-dimensional object , wherein said three-dimensional object is an insert for use between a helmet and a human body , comprising:(a) providing a carrier and an optically transparent member having a build surface, said carrier and said build surface defining a build region therebetween;(b) filling said build region with a polymerizable liquid, said polymerizable liquid comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component;(c) irradiating said build region with light through said optically transparent member to form a solid polymer scaffold from said first component and also advancing said carrier away from said build surface to form a three-dimensional intermediate having a shape of said insert, said three-dimensional intermediate containing said second solidifiable component carried in said scaffold in unsolidified and/or uncured form; and(d) subsequent to said irradiating step, heating, microwave irradiating, or both heating and microwave irradiating, second solidifiable component in said three-dimensional intermediate to form said insert.2. The method of claim 1 , wherein said second solidifiable component comprises a polymerizable liquid solubilized in or suspended in said first component.3. The method of claim 1 , wherein said second solidifiable component comprises:(i) a polymerizable solid suspended in said first component;(ii) a polymerizable solid solubilized in said first component; ...

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Номер записи: 57

28-01-2021 дата публикации

Textile Care Product Having An Optionally Cross-Linked Copolymer And Method For Finishing Textiles

Номер: US20210024853A1

Автор: Bluhm Nadine, Janssen Frank, Lohmeier Thomas, Richtering Walter, Schmiedel Peter, Wong John

Принадлежит:

The present invention relates to a textile care product containing a copolymer having N-isopropylacrylamide units, poly(ethylene glycol) methacrylate units and optionally at least one cross-linking agent. The copolymer is used as a soil-release active ingredient, reduces or prevents re-soiling and improves the removal of soiling. 1. A textile care product containing at least one copolymer comprising N-isopropylacrylamide units , poly(ethylene glycol) methacrylate units and optionally at least one cross-linking agent.2. The textile care product according to claim 1 , wherein the total mass of the copolymer comprising N-isopropylacrylamide units claim 1 , poly(ethylene glycol) methacrylate units and optionally at least one cross-linking agent is from 0.001% by mass to 10% by mass claim 1 , based on the total mass of the textile care product.3. The textile care product according to claim 2 , wherein the total mass of the copolymer comprising N-isopropylacrylamide units claim 2 , poly(ethylene glycol) methacrylate units and optionally at least one cross-linking agent is from 0.01% by mass to 5% by mass based on the total mass of the textile care product.4. The textile care product according to claim 1 , wherein the textile care product further contains at least one surfactant claim 1 , wherein the total mass of surfactant is from 1% by mass to 50% by mass based on the total mass of the textile care product.5. The textile care product according to claim 1 , wherein the textile care product is present as a powder claim 1 , liquid or gel claim 1 , or in the form of tablets or capsules.6. The textile care product according to claim 1 , wherein the textile care product is in the form of a detergent claim 1 , an auxiliary detergent claim 1 , a laundry care agent claim 1 , or a laundry aftertreatment agent.7. A method for finishing textiles using a soil-release protective layer claim 1 , comprising the method steps of:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a) ...

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Номер записи: 58

23-01-2020 дата публикации

Radiation-Curable Resin Composition and Production Method Thereof

Номер: US20200026185A1

Автор: Mora Barrios Karla Daniela

Принадлежит:

A radiation-curable resin composition, suitable for use in 3D printing, and to the production method thereof, i.e. the method for producing three-dimensional objects using radiation by means of 3D printing of the laser, DLP or LCD type, with successive photopolymerisable layers. The radiation-curable resin composition comprises one or more epoxy-acrylic resins and polymethyl methacrylate, graphene, halloysite nanotubes and one or more photoinitiators. 1. Radiation curable resin composition suitable for use in 3D printing characterized in that it is comprised of:40% to 60% by weight of at least one liquid epoxy resin, in which the liquid epoxy resins have at least two groups capable of reacting by a ring opening mechanism to form a polymer lattice,0.1% to 40% by weight of at least one liquid poly(meth)acrylate, of a single functionality (meth)acrylate, wherein said liquid poly(meth)acrylate will be at most 50% by weight of the total content of (meth)acrylate,0.1% to 10% by weight of at least one cationic photoinitiator,0.1% to 10% by weight of at least one free-radical photoinitiator,5% to 15% by weight of at least one polyether provided with terminal OH groups.2% to 30% by weight of a compound that has at least one unsaturated group and at least one hydroxy group in its molecule,0% to 30% by weight of a hydroxylated compound that has no unsaturated group,0.1% to 5% graphene,0.1% to 20% by weight of halloysite nanotubes.2. Composition of radiation curable resin according to claim 1 , characterized as such because at least one liquid epoxy resin is difunctional.3. Radiation curable resin composition claim 1 , according to claim 1 , characterized in that at least one liquid epoxy resin has an epoxy functionality of at least 2.4. Radiation curable resin composition claim 1 , according to claim 1 , characterized in that it is comprised of at least one polyester provided with terminal OH groups.5. Radiation curable resin composition according to claim 1 , characterized in ...

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Номер записи: 59

24-04-2014 дата публикации

RESIN COMPOSITE MATERIAL AND METHOD FOR PRODUCING RESIN COMPOSITE MATERIAL

Номер: US20140113988A1

Автор: Inui Nobuhiko, Mukohata Daisuke

Принадлежит: Sekisui Chemical Co., Ltd.

To provide a resin composite material in which aggregation of silane compounds in the resin is suppressed and the linear expansion coefficient is lowered, and a method for producing the resin composite material. A resin composite material containing a resin and a silane compound having a structure of the formula (1), wherein a molecular chain of the resin and a molecular chain of the silane compound form an IPN structure or a semi-IPN structure, and a method for producing a resin composite material including a step of mixing a resin and a silane compound to obtain a resin composition and an IPN structure formation step of allowing a plurality of the silane compounds contained in the resin composition to be condensed with each other. Each of Rs in the formula (1) is independently selected from the group consisting of hydrogen, halogen and an arbitrary organic functional group and at least one thereof is a reactive organic functional group. x represents 1 or 1.5. n represents an integer of 100 or more and 10000 or less. 3. The resin composite material according to claim 1 , wherein each of Rs in the formula (1) is independently selected from the group consisting of hydrogen claim 1 , chlorine claim 1 , a silyl claim 1 , a siloxy claim 1 , an alkoxy claim 1 , a vinyl claim 1 , an aryl claim 1 , an alkyl claim 1 , an alkylamine claim 1 , an ether claim 1 , an ester claim 1 , an amine claim 1 , an amide claim 1 , a thiol claim 1 , a methacryl claim 1 , an acryl claim 1 , an epoxy claim 1 , a ureido claim 1 , a mercapto claim 1 , a sulfide and an isocyanate.4. The resin composite material according to claim 1 , wherein at least one of Rs in the formula (1) is a reactive organic functional group selected from the group consisting of a vinyl claim 1 , an alkylamine claim 1 , an amine claim 1 , a methacryl claim 1 , an acryl claim 1 , an epoxy claim 1 , a ureido claim 1 , a mercapto claim 1 , a sulfide and an isocyanate.5. The resin composite material according to claim 1 , ...

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Номер записи: 60

02-02-2017 дата публикации

PIGMENT DISPERSION LIQUID, DECORATIVE MATERIAL, TRANSFER MATERIAL FOR FORMING DECORATIVE MATERIAL, SUBSTRATE WITH DECORATIVE MATERIAL, TOUCH PANEL, INFORMATION DISPLAY DEVICE, AND GRAFT TYPE SILICONE POLYMER

Номер: US20170029648A1

Автор: ASADA Saori, KANEIWA Hideki

Принадлежит: FUJIFILM Corporation

A pigment dispersion liquid includes a pigment dispersant; and a pigment, in which the pigment dispersant is a graft type silicone polymer denoted by General Formula 1. In General Formula 1, Rto R, Rand Rrepresent a hydrogen atom, a hydroxy group, an aryl group, or an alkyl group having 1 to 3 carbon atoms; Rand Rrepresent an arylene group or an alkylene group having 1 to 3 carbon atoms; Y and Z represent a single bond or a divalent organic linking group; A represents a group having a pigment adsorption portion; B represents a group having a structure denoted by General Formula 2; 1 and n represent an integer of greater than or equal to 1; m represents an integer of greater than or equal to 0; and k represents an integer of greater than or equal to 1. 3. The pigment dispersion liquid according to claim 1 ,wherein in General Formula 1 described above, m represents an integer of greater than or equal to 1.4. The pigment dispersion liquid according to claim 2 ,wherein in General Formula 3 described above, m represents an integer of greater than or equal to 1.7. The pigment dispersion liquid according to claim 1 ,wherein the pigment is a white pigment or a black pigment.8. The pigment dispersion liquid according to claim 1 ,wherein the pigment is titanium dioxide or carbon black.9. The pigment dispersion liquid according to claim 1 ,wherein a content rate of the pigment with respect to the pigment dispersion liquid is 20 to 90 mass %.10. The pigment dispersion liquid according to claim 1 , further containing:a silicone resin.11. The pigment dispersion liquid according to claim 1 ,wherein the pigment dispersion liquid is used for forming a decorative material.12. A decorative material using the pigment dispersion liquid according to .13. The decorative material according to claim 12 ,wherein the decorative material is used for a touch panel, and is a white decorative material.14. A transfer material for forming a decorative material claim 12 , comprising:{'claim-ref': ...

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Номер записи: 61

02-02-2017 дата публикации

Hydrophobic nanostructured thin films

Номер: US20170029658A1

Автор: Melik C. Demirel, Walter J. Dressick

Принадлежит: US Department of Navy

Provided herein are the polymers shown below. The value n is a positive integer. R 1 is an organic group, and each R 2 is H or a chemisorbed group, with at least one R 2 being a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured poly(p-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties.

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Номер записи: 62

02-02-2017 дата публикации

HYDROPHOBIC NANOSTRUCTURED THIN FILMS

Номер: US20170029659A1

Автор: Demirel Melik C., Dressick Walter J.

Принадлежит: The Government of the United States of America, as represented by the Secretary of the Navy

Provided herein are the polymers shown below. The value n is a positive integer. Ris an organic group, and each Ris H or a chemisorbed group, with at least one Rbeing a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured poly(p-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties. 1. A method comprising:converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers, the reactive vapor having a flux;depositing the reactive vapor under vacuum onto a substrate held fixed in a specific angle of orientation relative to the vapor flux to form nanostructured poly(p-xylylene) film;reacting the nanostructured poly(p-xylylene) film with an agent to form hydrogen atoms attached to the poly(p-xylylene) film that are reactive with a precursor of a chemisorbed group, if the deposited film does not contain the hydrogen atoms; andreacting the hydrogen atoms with the precursor of the chemisorbed group.2. The method of ;wherein the di-p-xylylene paracyclophane dimer is trifluoroacetyl-di-p-xylylene paracyclophane dimer;wherein the reducing agent is lithium aluminum hydride; and{'sub': '3', 'wherein reacting with lithium aluminum hydride produces —CHOH—CFgroups.'}3. The method of claim 2 , wherein the precursor is a fluoroalkyltrichlorosilane.4. The method of claim 3 , wherein the fluoroalkyltrichlorosilane is heptadecafluoro-1 claim 3 ,1 claim 3 ,2 claim 3 ...

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Номер записи: 63

04-02-2016 дата публикации

Acrylic Grafted Polyether Resins Based on Phenol Steric Acid and Coating Compositions Formed Therefrom

Номер: US20160032040A1

Автор: BANACH TIMOTHY EDWARD, Bode Daniel, CRAUN Gary Pierce, Howard Leigh Scott, Robideau Gary Joseph

Принадлежит:

Coating compositions can be prepared from an acrylic grafted polyether resin, wherein the smallest difunctional hydroxyl phenyl segment used to form the acrylic grafted polyether resin has a molecular weight greater than about 500, and wherein the smallest difunctional hydroxyl phenyl segment used to form the acrylic grafted polyether resin does not comprise two or more non-impaired hydroxyl groups attached to two or more different five-membered or six-membered carbon atom rings in a segment having a molecular weight less than about 500. The acrylic grafted polyether resin can be prepared by reacting a dihydroxyl compound and/or a diamine compound with a phenol stearic acid compound to produce a diphenol, reacting the diphenol with a diglycidyl ether compound to form a polyether resin, and mixing the polyether resin with an ethylenically unsaturated monomer component in the presence of an initiator to form the acrylic grafted polyether resin. 1. An acrylic grafted polyether resin , wherein the smallest difunctional hydroxyl phenyl segment used to form the acrylic grafted polyether resin has a molecular weight greater than about 500 , and wherein the smallest difunctional hydroxyl phenyl segment used to form the acrylic grafted polyether resin does not comprise two or more non-impaired hydroxyl groups attached to two or more different five-membered or six-membered carbon atom rings in a segment having a molecular weight less than about 500.2. The acrylic grafted polyether resin of claim 1 , wherein the acrylic grafted polyether resin is prepared by a method comprisinga) reacting a dihydroxyl compound and/or a diamine compound with a phenol stearic acid compound to produce a diphenol;b) reacting the diphenol with a diglycidyl ether compound to form a polyether resin; andc) mixing the polyether resin with an ethylenically unsaturated monomer component in the presence of an initiator to form the acrylic grafted polyether resin.3. The acrylic grafted polyether resin of ...

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Номер записи: 64

04-02-2016 дата публикации

Composition for light diffusion film, and light diffusion film

Номер: US20160033692A1

Автор: Baku Katagiri, Kentaro Kusama, Satoru Shoshi, Tomoo Orui

Принадлежит: Lintec Corp

A composition for light diffusion film in which the angle of aperture of diffused light in a light diffusion film obtainable therefrom can be expanded effectively, and a light diffusion film obtainable by the composition for light diffusion film are provided. Disclosed is composition for light diffusion film for obtaining a light diffusion film which has a predetermined internal structure within the film and in which plural regions having a relatively high refractive index are bent at an intermediate point along the film thickness direction, the composition for light diffusion film including a predetermined (meth)acrylic acid ester as component (A); a urethane(meth)acrylate as component (B); a photopolymerization initiator as component (C); and an ultraviolet absorber as component (D), wherein the content of the component (A) is adjusted to a value within a predetermined range relative to 100 parts by weight of the component (B), the content of the component (C) is adjusted to a value within a predetermined range relative to the total amount of the component (A) and the component (B), and the content of the component (D) is adjusted to a predetermined value relative to the total amount of the component (A) and the component (B).

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Номер записи: 65

05-02-2015 дата публикации

RESIN COMPOSITION

Номер: US20150034243A1

Автор: HAVEMAN DANIEL, JANSEN Johan Franz Gradus Antonius, Raimann Daniel

Принадлежит: DSM IP ASSETS B.V.

The present invention relates to a resin composition comprising (a) an unsaturated polyester resin and/or a methacrylate functional resin, wherein the resin composition further comprises an aromatic amine (b) according to formula (1) in which Pis an organic residue, R=H or a C-Calkyl, R=H or CH. 2. Resin composition according to claim 1 , characterized in that the molecular weight Mof the aromatic amine according to formula (1) is higher than 750 Dalton.3. Resin composition according to claim 1 , characterized in that the molecular weight Mof the aromatic amine according to formula (1) is lower than 10000 Dalton.4. Resin composition according to claim 1 , characterized in that R=CHand R=CH.5. Resin composition according to claim 1 , wherein Pis a residue of polymeric methylene diphenyl diisocyanate.6. Resin composition according to claim 1 , characterized in that the composition comprises a mixture of methacrylate functional resins which mixture has an average functionality higher than 1 claim 1 , preferably higher than 1.5 and more preferably higher than 1.7.7. Resin composition according to claim 1 , characterized in that the composition comprises a mixture of methacrylate functional resins which mixture has an average functionality lower than 4 claim 1 , more preferably lower than 3.8. Resin composition according to claim 6 , characterized in that the methacrylate functional resins further contain at least one urethane group.10. Resin composition according to claim 1 , characterized in that the resin composition further comprises a reactive diluent (c).11. Resin composition according to claim 1 , characterized in that the amount of the aromatic amine according to formula (1) (relative to the total amount of compounds (a) claim 1 , (b) and (c)) is from 1 up to and including 30 wt. % claim 1 , more preferably from 2 up to and including 20 wt. %.12. Two component resin system consisting of a first component A and a second component B claim 1 , characterized in that ...

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Номер записи: 66

31-01-2019 дата публикации

GRAPHENE OXIDE MODIFIED THERMOSET MONOMER AND SYNTHESIS THEREOF

Номер: US20190031808A1

Автор: ASUNCION Michael Z., Guha Probir Kumar, KRUG David J., Siwajek Michael J.

Принадлежит:

A monomer is provided for a thermoset molding compound. The monomer is also polymerized with conventional monomers to form thermoplastic polymers. Graphene oxide is used to chelate metal ions to form a graphene oxide chelate that is coupled to a monomer retaining an aliphatic unsaturation capable of free radical polymerization reaction. Inclusion of a metal ion chelated to the graphene oxide affords control over the conductivity of the resultant article. In some embodiments, the monomer is found polymerized into a resulting article proximal to the article surface. 1. A cross-linkable monomer having a free radical curable ethylenic unsaturation covalently bonded to graphene oxide , the graphene oxide bonded to a metal ion.2. The cross-linkable monomer of having the formula:{'br': None, 'sub': n', '2', 'n, 'X—(O-G-MY)CHOH or X—O-G-MY\u2003\u2003(I)'}{'sub': 2', '2', '2', '2', '2', '1', '10', '1', '10', '1', '10', '1', '10', '1', '10, 'where X is CH═CH—Ar—CH, CH═CH—Ar—CH(OH)CH, CH═CH—CHRCHor norbornene-C(O); Ar is phenyl, or a phenyl having a substituent; R is C-Calkyl, or hydroxyl; G is graphene oxide containing at least one carboxyl group and one hydroxyl group; M in each occurrence is independently a metal ion having a coordination number and selected from the group of silver, copper, iron, zinc, iron, or magnesium; n is an integer value of between 1 and 10, and Y is either a nullity or a chelating agent that in combination with the graphene oxide satisfies the coordination number of the metal ion, where the substituent is C-Calkyl, C-Calkyl hydroxyl, C-Calkyl sulfonyl, or C-Calkyl amine.'}{'claim-ref': {'@idref': 'CLM-00002', 'claim 2'}, 'The monomer of wherein M is only silver.'}3. The monomer of wherein Y is a nullity.4. The monomer of wherein Y is ethylenediaminetetraacetate.5. The monomer of where X is a mixture of CH═CH—Ar—CH and CH═CH—Ar—CH(OH)CH.6. The monomer of where X is norbornene-C(O).7. A molding composition formulation comprising:a thermoset cross- ...

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Номер записи: 67

31-01-2019 дата публикации

NON-AQUEOUS DISPERSIONS COMPRISING AN ACRYLIC POLYMER STABILIZER AND AN ALIPHATIC POLYESTER STABILIZED SEED POLYMER

Номер: US20190031905A1

Автор: Fenn David, Martin Roxalana, Sadvary Richard J., Simpson Dennis A., Wang Wei, Williams Richard

Принадлежит:

A non-aqueous dispersion comprising a continuous phase and a dispersed phase, wherein the dispersed phase comprises the dispersion polymerization reaction product prepared from a reaction mixture comprising an ethylenically unsaturated monomer, an acrylic polymer stabilizer, and an aliphatic polyester stabilized seed polymer, is disclosed. Related coatings and coated substrates are also disclosed. 1. A non-aqueous dispersion comprising a continuous phase and a dispersed phase , wherein the dispersed phase comprises a dispersion polymerization reaction product prepared from a reaction mixture comprising an ethylenically unsaturated monomer , an acrylic polymer stabilizer , and an aliphatic polyester stabilized seed polymer.2. The non-aqueous dispersion of claim 1 , wherein the polyester has a carbon to oxygen ratio of 4:1 to 20:1.3. The non-aqueous dispersion of claim 1 , wherein the polyester comprises poly-12-hydroxystearic acid.4. The non-aqueous dispersion of claim 1 , wherein the polyester has a weight average molecular weight of 10 claim 1 ,000 to 30 claim 1 ,000.5. The non-aqueous dispersion of claim 1 , wherein the continuous phase is substantially free of volatile organic compounds.6. The non-aqueous dispersion of claim 1 , wherein the continuous phase comprises a reactive diluent.7. A non-aqueous dispersion claim 1 , wherein the particles have an average particle size of 180 nm or less.8. The non-aqueous dispersion of claim 7 , wherein said NAD does not form seeds when subjected to the seed test.9. The non-aqueous dispersion of claim 7 , wherein the non-aqueous dispersion comprises a continuous phase and a dispersed phase claim 7 , wherein the dispersed phase comprises the dispersion polymerization reaction product prepared from a reaction mixture comprising an ethylenically unsaturated monomer claim 7 , an acrylic polymer stabilizer claim 7 , and an aliphatic polyester stabilized seed polymer.10. The non-aqueous dispersion of claim 9 , wherein the ...

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Номер записи: 68

31-01-2019 дата публикации

Methods of producing three-dimensional objects from materials having multiple mechanisms of hardening

Номер: US20190031911A1

Автор: James Goodrich, Jason P. Rolland, Joseph M. Desimone, Justin POELMA, Kai Chen, Lloyd M. Robeson, Robert PINSCHMIDT

Принадлежит: Carbon Inc

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

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Номер записи: 69

11-02-2016 дата публикации

Impact strength modifier for chlorine-containing resin, chlorine-containing resin composition and molded body of chlorine-containing resin composition

Номер: US20160039963A1

Автор: Atsushi Kuwahara, Ayaka WAKITA, Toshihiro Kasai, Yuichiro Fujikawa

Принадлежит: Mitsubishi Rayon Co Ltd

Disclosed is an impact strength modifier (α) for a chlorine-containing resin, comprising a powder of a graft copolymer (A) obtained by graft polymerizing one or more kinds of vinyl monomers (b1) onto a polyorganosiloxane rubber (A1) or a composite rubber (A2) containing a polyorganosiloxane rubber and a polyalkyl(meth)acrylate rubber, wherein the specific surface area of the powder of the graft copolymer (A) measured by a nitrogen gas adsorption method is from 0.6 to 30 m 2 /g, and the pH of water used for extraction under conditions, in which (1) in an oven at 180° C., 5.0 g of the powder of the graft copolymer (A) is left to stand still and heated for 15 minutes, and (2) after the heating, the powder is dispersed in 100 ml of heated pure water and extracted for 1 hour at 70° C. while stirring, is from 4 to 11.

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Номер записи: 70

09-02-2017 дата публикации

SURFACE MODIFICATION METHOD AND SURFACE-MODIFIED BODY

Номер: US20170037176A1

Автор: Minagawa Yasuhisa

Принадлежит: SUMITOMO RUBBER INDUSTRIES, LTD.

Methods are provided for surface-modifying a rubber vulcanizate or a thermoplastic resin. The methods allow these objects to have a chemically fixed surface layer that exhibits not only low adsorption or selective adsorption properties with respect to proteins and cells, but also excellent durability, instead of having a coating which has drawbacks such as reduction in properties due to separation or peeling of the coating. Included is a method for surface-modifying an object made of a rubber vulcanizate or a thermoplastic resin, the method including: a step 1 of forming polymerization initiation points on the surface of the object; and a step 2 of radically polymerizing a hydrophilic monomer starting from the polymerization initiation points by irradiation with UV light having a wavelength of 300 to 400 nm in the presence of an alkali metal salt to grow polymer chains on the surface of the object. 1. A method for surface-modifying an object made of a rubber vulcanizate or a thermoplastic resin , the method comprising:a step 1 of forming polymerization initiation points on a surface of the object; anda step 2 of radically polymerizing a hydrophilic monomer starting from the polymerization initiation points by irradiation with UV light having a wavelength of 300 to 400 nm in the presence of an alkali metal salt to grow polymer chains on the surface of the object.2. A method for surface-modifying an object made of a rubber vulcanizate or a thermoplastic resin , the method comprisinga step I of radically polymerizing a hydrophilic monomer by irradiation with UV light having a wavelength of 300 to 400 nm in the presence of a photopolymerization initiator and an alkali metal salt to grow polymer chains on a surface of the object.3. The method according to claim 1 ,wherein the step 1 comprises adsorbing a photopolymerization initiator to a surface of the object, optionally followed by irradiation with UV light having a wavelength of 300 to 400 nm, to form polymerization ...

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Номер записи: 71

09-02-2017 дата публикации

AMPHIPHILIC BLOCK COPOLYMER; COMPOSITION, MEMBRANE, AND SEPARATION MODULE THEREOF; AND METHODS OF MAKING SAME

Номер: US20170037177A1

Автор: Bajaj Pooja, Berzinis Albin Peter, Bikel Matias, Halbfinger Rachel Elizabeth

Принадлежит: Sabic Global Technologies B.V.

An amphiphilic block copolymer comprises a poly(phenylene ether) block or a poly(phenylene ether) copolymer block and a hydrophilic block or graft. A method of making the amphiphilic block copolymer comprises polymerization of a hydrophilic ethylenically unsaturated monomer in the presence of poly(phenylene ether) or a poly(phenylene ether) copolymer to make the amphiphilic block copolymer. A porous asymmetric membrane comprises a poly(phenylene ether) or poly(phenylene ether) copolymer, and the amphiphilic block copolymer comprising a poly(phenylene ether) block or a poly(phenylene ether) copolymer block, and a hydrophilic block or graft. The porous asymmetric membrane is made by phase-inversion of a dope solution of the poly(phenylene ether) or poly(phenylene ether) copolymer and the amphiphilic block copolymer in a coagulation bath. 1. An amphiphilic block copolymer , comprisinga hydrophobic block comprising, consisting essentially of, or consisting of a poly(phenylene ether) block or a poly(phenylene ether) copolymer block; anda hydrophilic block or graft.2. The amphiphilic block copolymer of claim 1 , comprising 20 to 50 weight percent of the hydrophobic block and 50 to 80 weight percent of the hydrophilic block or graft.5. The amphiphilic block copolymer of claim 1 , wherein the hydrophobic block of the amphiphilic copolymer comprises a poly(phenylene ether) copolymer comprising:80 to 20 mole percent repeat units derived from 2,6-dimethylphenol; and20 to 80 mole percent repeat units derived from the second monohydric phenol.6. The amphiphilic block copolymer of claim 5 , wherein the second monohydric phenol comprises 2-methyl-6-phenylphenol.7. The amphiphilic block copolymer of claim 1 , wherein the hydrophilic block or graft comprises a polymerized hydrophilic ethylenically unsaturated monomer.8. The amphiphilic block copolymer of claim 7 , wherein the hydrophilic ethylenically unsaturated monomer comprises methoxy-capped poly(ethylene oxide) methacrylate ...

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Номер записи: 72

11-02-2016 дата публикации

Graft copolymer, process for producing the graft copolymer, process for preparing a gel polymer electrolyte including the graft copolymer, and intermediate copolymer of the graft copolymer

Номер: US20160043434A1

Автор: Chih-Hao Tsao, Ching-An Wu, Chun-Han HSU, Chung-Yu Lu, Ping-Lin Kuo, Sheng-Shu Hou

Принадлежит: National Cheng Kung University NCKU

A graft copolymer comprising a backbone polymer and a branched-chain polymer, and represented by formula (I), where A, B, R a , R b , R c , R d , R e , R f , G 1 , G 2 , G 3 , G 4 , Y 1 , Y 2 , and k are as defined in the specification. A process for producing the grate copolymer, a process for preparing a gel polymer electrolyte including the graft copolymer, and an intermediate copolymer of the graft copolymer are also disclosed.

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Номер записи: 73

18-02-2016 дата публикации

POLYURETHANE-BASED POLYMER COMPOSITION

Номер: US20160046751A1

Автор: Braun Frank, PRISSOK Frank, Spies Patrick

Принадлежит: BASF SE

A polymer composition comprising at least one thermoplastic polyurethane (TPU) with a Vicat softening point (in accordance with ISO 306/A50) below 80° C. and from 5 to 95% by weight of at least one polymer obtainable via free-radical polymerization, based on the entirety of TPU and of the polymer obtainable via free-radical polymerization, where the polymer obtainable via free-radical polymerization has been bonded in the form of comb polymer, graft polymer, or copolymer to the TPU, is particularly suitable for injection-molding applications. 1. A polymer composition comprising a thermoplastic polyurethane (TPU) with a Vicat softening point , measured in accordance with ISO 306/A50 , below 80° C. and from 5 to 95% by weight of at least one polymer obtained via free-radical polymerization , based on the entirety of TPU and of the polymer obtained via free-radical polymerization , where the polymer obtained via free-radical polymerization has been bonded in a form of comb polymer , graft polymer , or copolymer to the TPU , and wherein the TPU comprises functional groups , which under typical conditions of a radical polymerization form a comb polymer , graft polymer or copolymer with free-radically polymerizable monomers of the polymer obtained via free-radical polymerization.2. The polymer composition according to claim 1 , where the polymer obtained via free-radical polymerization is a styrene polymer.3. The polymer composition according to claim 2 , where the styrene polymer is polystyrene.4. The polymer composition according to claim 1 , where the Vicat softening point of the TPU is in a range from 60 to 75° C.5. The polymer composition according to claim 1 , where a Shore hardness of the TPU is in a range from 50 to 100 claim 1 , measured in accordance with DIN 53505.6. The polymer composition according to claim 1 , where a glass transition temperature of the TPU is in a range from −20 to −60° C. claim 1 , measured in accordance with ISO 11357/-1/-2.7. The polymer ...

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Номер записи: 74

16-02-2017 дата публикации

IONIC SILICONE HYDROGELS

Номер: US20170044293A1

Автор: Alli Azaam, Ford James D., Joslin Scott L., Vanderlaan Douglas G.

Принадлежит:

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature. 1. A silicone hydrogel formed from a reaction mixture comprising about 37 to about 75 wt % of a mixture of slow-reacting hydrophilic monomers , each having a slow-reacting hydrophilic monomer kinetic half life; said mixture of slow reacting hydrophilic monomers comprising and least one slow-reacting ionic monomer;at least one silicone-containing component having a silicone-containing component kinetic half life, which may be optionally substituted with at least one hydroxyl containing group; andat least one hydroxyalkyl (meth)acrylate monomer,wherein ratio of each of said slow-reacting hydrophilic component half lives to said silicone-containing component half life is at least 2.2. The silicone hydrogel of wherein said slow-reacting ionic component is selected from the group consisting of anionic components claim 1 , cationic components claim 1 , zwitterionic components and mixtures thereof.3. The silicone hydrogel of wherein said slow-reacting ionic component comprise at least one anionic component selected from the group consisting of carboxylic acids claim 1 , sulfonic acids claim 1 , boronic acids claim 1 , phosphonic acids and their salts and mixtures thereof.4. The silicone hydrogel of wherein said slow-reacting ionic component comprises reactive functionality selected from the group consisting of ionic vinyl ethers claim 1 , ionic vinyl amines and ionic vinyl enamines.6. The silicone hydrogel of wherein said slow-reacting ionic component is ...

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Номер записи: 75

15-02-2018 дата публикации

LAYER MIGRATION CONTROL AGENT

Номер: US20180044551A1

Автор: OGAWA Kohei, OIWA Yasuhiro, UBUKATA Makoto

Принадлежит: KUSUMOTO CHEMICALS, LTD.

Provided is a novel layer migration control agent that is added to a paint composition when forming a multilayer coating film on a coating object by curing a prime coating film and a top coating film at the same time, the agent making it possible to control layer migration of the two coating films and obtain the multilayer coating film with satisfactory finish appearance. The layer migration control agent is a copolymer obtained by copolymerization of a monomer mixture including 5% by weight to 90% by weight of a polymerizable unsaturated monomer including an ether group and 10% by weight to 95% by weight of a polymerizable unsaturated monomer having a hydrophobic group having 1 to 22 carbon atoms, the copolymer having a weight average molecular weight of 1000 to 100,000. 3. The layer migration control agent according to claim 1 , wherein the polymerizable unsaturated monomer (B) having a hydrophobic group is a polymerizable unsaturated monomer of at least one kind selected from the group consisting of polymerizable unsaturated monomers having a linear portion claim 1 , a branched portion claim 1 , or a ring portion having 1 to 22 carbon atoms.4. The layer migration control agent according to claim 1 , wherein the polymerizable unsaturated monomer (C) is a polymerizable unsaturated monomer of at least one kind selected from the group consisting of a polymerizable unsaturated monomer having a hydroxyl group claim 1 , a polymerizable unsaturated monomer having an amide group claim 1 , a polymerizable unsaturated monomer having a glycol group claim 1 , a polymerizable unsaturated monomer having a glycidyl group claim 1 , a polymerizable unsaturated monomer having a carboxyl group claim 1 , a polyfunctional unsaturated monomer claim 1 , and a reactive silicone having a methacryloyloxy group.5. A paint composition comprising the layer migration control agent according to at 3% by weight to 15% by weight per weight of a resin solid component contained in the paint.6. An ...

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Номер записи: 76

03-03-2022 дата публикации

Hybrid foam formulations

Номер: US20220064361A1

Автор: Weijun Zhou, William A. Koonce, William J. Harris, Yonghui Zhang

Принадлежит: Dow Global Technologies LLC

Embodiments of the present disclosure are directed towards hybrid foam formulations that include: an isocyanate-reactive composition, and a high-functionality crosslinker; an azo type radical initiator; and an isocyanate.

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Номер записи: 77

03-03-2022 дата публикации

Profile control and oil displacement agent for oil reservoir and preparation method thereof

Номер: US20220064517A1

Автор: Gaoshen Su, Huan Yang, Wei Wang, Xiaorong Yu

Принадлежит: Yangtze University

The present disclosure relates to a profile control and oil displacement agent for an oil reservoir and a preparation method thereof. The profile control and oil displacement agent is prepared by uniformly dispersing polymer microspheres, an activator and a solvent. The polymer microspheres are micron-sized dry-powdered microspheres, which are prepared by stirring and polymerizing a first monomer, a second monomer, an initiator, a hydrophobic nano-powder and water in a specific proportion. The profile control and oil displacement agent of the present disclosure can reduce the oil-water interfacial tension, has good long-term stability, simple preparation and low cost, avoids solvent waste, and can be applied to the deep profile control and oil displacement system of oil fields.

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Номер записи: 78

14-02-2019 дата публикации

Methods of Preparing Compositions for Containers and Other Articles and Methods of Using Same

Номер: US20190048126A1

Автор: "OBrien Robert M.", Deng Lan, Evans Richard H, Niederst Jeffrey, Prouvost Benoit, Romagnoli Kevin, Santure David J., Von Maier Mark S.

Принадлежит: SWIMC LLC

This invention provides a polymer, which is preferably a polyether polymer. The polymer may be uses in coating compositions. Containers and other articles comprising the polymer and methods of making such containers and other articles are also provided. The invention further provides compositions including the polymer (e.g., powder coatings), which have utility in a variety of coating end uses, including, for example, valve and pipe coatings. 112-. (canceled)14. The food or beverage packaging container of claim 13 , wherein the polyether polymer is completely free of bound polyhydric phenols claim 13 , or epoxides thereof claim 13 , having estrogenic activity greater than that of 4 claim 13 ,4′-(propane-2 claim 13 ,2-diyl)bis(2 claim 13 ,6-dibromophenol).15. The food or beverage packaging container of claim 13 , wherein the polyether polymer is completely free of bound polyhydric phenols claim 13 , or epoxides thereof claim 13 , having estrogenic activity greater than that of 2 claim 13 ,2-bis(4-hydroxyphenyl)propanoic acid.16. The food or beverage packaging container of claim 13 , wherein the coating composition is substantially free of mobile or bound bisphenol A claim 13 , bisphenol F claim 13 , bisphenol S claim 13 , polyhydric phenols having estrogenic activity greater than or equal to that of bisphenol S claim 13 , and epoxides thereof.18. The method of claim 17 , wherein the degree of polymerization is over 8.19. The method of claim 17 , wherein the degree of polymerization is over 12.20. The method of claim 17 , wherein the halohydrin is epichlorohydrin.22. The method of claim 17 , comprising the further step of reacting the polyether polymer with a hindered polyhydric phenol compound having an atom or group having an atomic weight of at least 15 Daltons in an ortho position relative to an oxygen atom on a phenol ring in the presence of a nitrogen-containing catalyst having at least one bridgehead Nitrogen atom.23. The method of claim 21 , wherein the ...

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Номер записи: 79

25-02-2021 дата публикации

A compound, a reaction product of said compound and production methods thereof

Номер: US20210053953A1

Автор: Abdul Majeed Seayad, Jayasree Seayad, Satyasankar Jana

Принадлежит: Agency for Science Technology and Research Singapore

There is provided a compound represented by general formula (lb), wherein ring A is a carbocyclic or heterocyclic ring, a reaction product of the reaction between one or more said compounds and one or more amine containing compounds. Also provided is related production methods thereof.

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Номер записи: 80

25-02-2021 дата публикации

COATING COMPOSITIONS EXHIBITING CORROSION RESISTANCE PROPERTIES AND RELATED COATED SUBSTRATES

Номер: US20210054216A1

Автор: Schneider John R., Walters David N.

Принадлежит: PPG Industries Ohio, Inc.

Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating later is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed. 1. A coating composition comprising:(a) a thermosetting composition comprising a polyamine and an epoxy functional material; and{'sup': 2', '2, 'sub': (nm)', '(nm)', '(nm), '(b) magnesium oxide particles having a BET surface area of no more than 250 m/g and a calculated equivalent spherical diameter (D) of no more than 200 nanometers, wherein the calculated spherical diameter (D) is determined according to the equation: D=6000/[BET (m/g)*ρ(grams/cm)], wherein BET represents surface area as determined by nitrogen adsorption according to the ASTMD 3663-78 standard based on the Brunauer-Emmett-Teller method and p represents density,'}wherein the magnesium oxide particles act as a corrosion resisting material.2. The coating composition of claim 1 , wherein the polyamine comprises a polyamide resin.3. The coating composition of claim 1 , wherein the thermosetting composition is formulated as a two-component composition where the polyamine is in one component and the epoxy functional material is in a second component.4. The coating composition of claim 1 , wherein the thermosetting composition is capable of undergoing cure at ambient temperature.5. The coating composition of claim 1 , wherein the composition is a solvent borne composition further comprising an organic solvent.6. The coating composition of claim 1 , wherein the composition is formulated to be spray applied.7. The coating composition of claim 1 , wherein the magnesium oxide particles have a calculated equivalent spherical diameter (D) of from 100 to 200 ...

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Номер записи: 81

13-02-2020 дата публикации

AQUEOUS COATING COMPOSITION AND METHOD FOR FORMING MULTILAYERED COATING FILM

Номер: US20200048492A1

Автор: IMAI Takahiro

Принадлежит: KANSAI PAINT CO., LTD.

Provided are: an aqueous coating composition which is capable of giving coating films having excellent chipping resistance without lowering the finish; and a method for forming a multilayered coating film. The aqueous coating composition comprises an acrylic-modified polyester resin (A) comprising an acrylic moiety and a polyester moiety, a crosslinking agent (B), and an epoxy phosphoric acid ester compound (C), wherein the acrylic-modified polyester resin (A) contains a polyoxyalkylene-group-containing unsaturated monomer having a weight-average molecular weight of 400 or higher as a monomer component of the acrylic moiety and the polyester moiety is configured of components, 50 mass % or more of which is accounted for by a Cor higher compound, the content of the epoxy phosphoric acid ester compound (C) being 0.1-10 parts by mass per 100 parts by mass of the sum of the solid components of (A) and (B). 2. The aqueous coating composition according to claim 1 , wherein the compound of 6 or more carbon atoms among the components composing the polyester portion is a compound having an alkylene group of 4 or more carbon atoms.3. The aqueous coating composition according to claim 1 , wherein the ratio of the acrylic portion and the polyester portion of the acryl-modified polyester resin (A) is 5 to 40 mass % for the acrylic portion and 60 to 95 mass % for the polyester portion claim 1 , with respect to the acryl-modified polyester resin (A) (the total amount of the acrylic portion and the polyester portion).4. The aqueous coating composition according to claim 1 , wherein the epoxy phosphoric acid ester compound (C) is one having a hydroxyl group and a phosphoric acid residue in the molecule.5. An article having a coating film of an aqueous coating composition according to .7. The multilayer coating film-forming method according to claim 6 , wherein the clear coating material (Z) is one comprising a carboxyl group-containing resin and a polyepoxide claim 6 , or a hydroxyl ...

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Номер записи: 82

14-02-2019 дата публикации

Contact lens package and method for producing the same

Номер: US20190049751A1

Автор: Azusa OBATA, Masaki Baba, Susumu Ogawa

Принадлежит: Menicon Co Ltd

A contact lens package includes a silicone hydrogel contact lens, a packaging container composed of a polypropylene, and a packaging solution containing a nonionic surfactant, the nonionic surfactant including a linear alkyl moiety having 12 or more carbon atoms and an oxyethylene moiety, the average addition mole number of oxyethylene being 30 or more per mole of the nonionic surfactant.

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Номер записи: 83

22-02-2018 дата публикации

PROCESS FOR PRODUCING MODIFIED THERMOSETTING POLYPHENYLENE ETHER RESIN

Номер: US20180051116A1

Автор: Chang Hung-Yi, CHEN HAO-SHENG, Chou Chuan, HUANG Ying-Te, LAI Jui-Jung LIN, LIAO Te-Chao

Принадлежит:

A process for producing a modified polyphenylene ether resin having a purity of more than 99.4%, comprising steps of graft modification, water rinse, and extraction as well as phase splitting, is disclosed that step of separating out powder during purification is no needed, and the solvent for use in performing dissolving of or/and extraction of polyphenylene ether resin can be recycled for future use, so that the manufacturing process is simple and uses less solvent as compared to the prior art, and further helps to conserve resources and is environmentally friendly. 1. A process for producing modified thermosetting polyphenylene ether resin , without step of separating out polyphenylene ether resin into powder , comprising the following steps:a) dissolving a polyphenylene ether resin having a hydroxyl group in a good solvent selected from toluene solvent, xylene solvent, methyl isobutyl ketone (MIBK) solvent or butanone (MEK) solvent, heating to 65-85° C.; b1) based on the total weight of the polyphenylene ether resin, adding 0.5%-5 wt % of a phase transfer catalyst to the good solvent after the resin is completely dissolved;', 'b2) adding an aqueous solution containing alkali metal ion to allow the hydroxyl group of the polyphenylene ether resin to form terminal phenoxide;', 'b3) dropwise adding a graft monomer in the presence of the phase transfer catalyst to perform graft modification reaction at 50-120° C.; and', 'b4) setting the solution aside for reaction for 9-12 hours to obtain a modified thermosetting polyphenylene ether resin solution;, 'b) graft reaction for modificationc) performing water rinse to obtain a semi-finished product of a modified polyphenylene ether resin solution; d1) a congruent point corresponding to those weight fractions of the good solvent, the alcohol solvent, and the water is located within a two phase liquid-liquid region of the good solvent—the alcohol solvent—water ternary phase diagram measured at 25-75° C. and 1-3 atmosphere; ...

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Номер записи: 84

10-03-2022 дата публикации

WHITE PIGMENT DISPERSION AND TECHNOLOGY RELATED THERETO

Номер: US20220073776A1

Автор: INOUE Daisuke, MIZUHARA Tomohiro, SHODAI Hiroshi

Принадлежит:

Providing a white pigment dispersion that shows good storage stability because the white pigment contained therein is less likely to sediment, an ink composition comprising the white pigment dispersion, and a method of image formation using the ink composition. A white pigment dispersion comprising at least a specified white pigment, a polymeric dispersant, and an aqueous liquid as a solvent or dispersion medium, wherein; the specified white pigment is a titanium dioxide that has been surface-treated with at least alumina, the polymeric dispersant has a structure with a principal chain having a pigment adsorption group and a water-soluble molecular chain grafted to the principal chain, the overall weight-average molecular weight of the polymeric dispersant is in the range of 2000 to 50000, the weight-average molecular weight of the graft chain is in the range of 150 to 3000, and the difference between the lightness value L of the coating film from the pre-centrifugation white pigment dispersion and the lightness value L of the coating film from the post-centrifugation supernatant liquid is less than 25. 1. A white pigment dispersion comprising at least a specified white pigment , a polymeric dispersant , and an aqueous liquid as a solvent or dispersion medium , wherein:the specified white pigment is a titanium dioxide that has been surface-treated with at least alumina,the polymeric dispersant has a structure with a principal chain having a pigment adsorption group and a water-soluble molecular chain grafted to the principal chain,the overall weight-average molecular weight of the polymeric dispersant is in the range of 2000 to 50000,the weight-average molecular weight of the graft chain is in the range of 150 to 3000, andthe difference betweenthe lightness value L of the coating film from the pre-centrifugation white pigment dispersionandthe lightness value L of the coating film from the post-centrifugation supernatant liquidis less than 25.2. The white pigment ...

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Номер записи: 85

01-03-2018 дата публикации

PROCESSES FOR REDUCING THE FOULING OF SURFACES

Номер: US20180056245A1

Автор: BAUMANN Peter, Bohrer Erik, CEPRAGA Cristina, KELLERMEIER Matthias, Konradi Rupert, KUHN Jelan, Marty Laurent, SCHAUKSDAT Sarah-Jane, Staudt Claudia, Stengel Peter, Von Vacano Bernhard Ulrich, Wegmann Ludger

Принадлежит: BASF SE

Process for reducing the fouling of a surface O, wherein an aqueous solution S of at least one polymer P comprising styrene and at least one ester E of (meth)acrylic acid and polyethylene oxide in a molar ratio of 0.05:1 to 50:1 is applied to said surface O. 1. A process for reducing fouling of a surface O , the process comprising:applying an aqueous solution S comprising at least one polymer P comprising styrene and at least one ester E of (meth)acrylic acid and polyethylene oxide in a molar ratio of 0.05:1 to 50:1 to said surface O,wherein said aqueous solution S comprises at least 50% by weight of water.2. The process according to claim 1 , wherein said surface O is a membrane M.3. The process according to claim 1 , wherein said at least one ester E has an average molar mass Mn of 300 to 10000 g/mol.4. The process according to claim 1 , wherein said at least one ester E has an average molar mass Mn of 800 to 3000 g/mol.5. The process according to claim 1 , wherein said polymer P has an average molar mass Mn of 5000 to 100 claim 1 ,000 g/mol.6. The process according to claim 1 , wherein said polymer P is a statistical copolymer.7. The process according to claim 1 , wherein said aqueous solution S comprises 0.001 to 1% by weight of said at least one polymer P.8. The process according to claim 1 , wherein said at least one polymer P has been obtained in a solution polymerization.9. The process according to claim 8 , wherein said at least one polymer P has been obtained in a solution polymerization in a solvent comprising at least 50% by weight based on the solvent of at least one alcohol.10. The process according to claim 1 , wherein said at least one polymer P is applied to said surface O in intervals of 1 day to 24 months.11. The process according to claim 2 , wherein said membrane M is a RO claim 2 , FO claim 2 , NF claim 2 , UF or MF membrane.12. The process according to claim 1 , wherein said process is used in treating industrial or municipal waste water claim ...

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Номер записи: 86

20-02-2020 дата публикации

ROS-DEGRADEABLE HYDROGELS

Номер: US20200054755A1

Автор: Dollinger Bryan R., Duvall Craig L., Gupta Mukesh K, MARTIN John R.

Принадлежит:

The presently-disclosed subject matter includes a polymer (i.e., copolymer) comprising a thermally responsive block and a hydrophobic block. In some embodiments the copolymer is a terpolymer. Specific embodiments include a thermo-responsive, ROS degradable ABC triblock terpolymer comprising poly(propylenesulfide)-block-poly(N,N-dimethylacrylamide)-block-poly(N-isopropylacrylamide) (PPS-b-PDMA-b-PNIPAAM). 1. A polymer comprising:a thermally responsive block; anda hydrophobic block.2. The polymer of claim 1 , wherein the polymer comprises a copolymer.3. The polymer of claim 2 , wherein the copolymer is a terpolymer.4. The polymer of claim 3 , wherein the terpolymer comprises a reactive oxygen species (ROS) degradable ABC triblock.5. The polymer of claim 4 , wherein the terpolymer is thermo-responsive.6. The polymer of claim 4 , wherein the terpolymer comprises poly(propylenesulfide)-block-poly(N claim 4 ,N-dimethylacrylamide)-block-poly(N-isopropylacrylamide) (PPS-b-PDMA-b-PNIPAAM).7. The polymer of claim 6 , wherein the poly(propylenesulfide) block provides antioxidant functionality that reduces cytotoxic oxidative stress for at least one of a cell encapsulated in the polymer claim 6 , a cell delivered with the polymer claim 6 , and a local host environment.8. The polymer of claim 1 , wherein the polymer forms a reactive oxygen species-triggered active agent release.9. The polymer of claim 1 , wherein the polymer assembles into stable micelles in aqueous solution.10. The polymer of claim 9 , wherein the micelles include a hydrophobic PPS core.11. The polymer of claim 10 , further comprising an active agent loaded in the PPS core.12. The polymer of claim 11 , wherein the active agent comprises a hydrophobic small molecule drug.13. The polymer of claim 9 , wherein the polymer transitions to a hydrogel at about 37° C.14. A polymer comprising a thermo-responsive poly(propylenesulfide)-block-poly(N claim 9 ,N-dimethylacrylamide)-block-poly(N-isopropylacrylamide) (PPS-b- ...

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Номер записи: 87

04-03-2021 дата публикации

MULTIFUNCTIONAL NITROXIDE-MEDIATED POLYMERIZATION INITIATORS AND MULTI-ARMED POLYMERS AND HYDROGELS FORMED THEREFROM

Номер: US20210061957A1

Автор: Delaney, Dyndikova Tatyana, Grosso Paul V., JR. Joseph T., KUMMAILIL John, Rehder Carey

Принадлежит:

In some aspects, the present disclosure pertains to multi-arm polymers that comprise a core and a plurality of polymer segments having a first end that is covalently attached to the core and (a) a second end comprising a moiety that comprises a reactive end group, wherein the polymer segments comprise one or more hydrophilic aprotic NMP-polymerizable monomers, and wherein the reactive multi-arm polymer comprises nitroxide radicals or (b) a second end comprising a moiety that comprises an alkoxyamine group, wherein the core is a polyol residue, and wherein the polymer segments comprise one or more NMP-polymerizable monomers. In some aspects, the present disclosure pertains to a multifunctional alkoxyamine molecule comprising a core and a plurality of alkoxyamine groups covalently attached to the core, wherein the core is a polyol residue. 1. A multi-arm polymer comprising a core and a plurality of polymer segments having a first end that is covalently attached to the core and a second end comprising a moiety that comprises a reactive group , wherein the polymer segments comprise one or more hydrophilic aprotic NMP-polymerizable monomers , and wherein the multi-arm polymer comprises nitroxide radicals.2. The multi-arm polymer of claim 1 , wherein the core is selected from a polyol residue and a silsesquioxane core.3. The multi-arm polymer of claim 1 , wherein the reactive group is an electrophile or a nucleophile.4. The multi-arm polymer of claim 1 , wherein the moiety that comprises a reactive group further comprises a hydrolysable ester group.5. A system comprising (a) a first composition comprising a multi-arm polymer in accordance with and (b) a second composition comprising a multifunctional compound that comprises functional groups that are reactive with the reactive groups of the multi-arm polymer.6. The system of claim 5 , further comprising a delivery device.7. A crosslinked reaction product of (a) a multi-arm polymer in accordance with and (b) a ...

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Номер записи: 88

20-02-2020 дата публикации

NON-SILICON DEFOAMING AGENT

Номер: US20200056034A1

Автор: Cao Tian, Liu Yang, Zhang Zhen

Принадлежит: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD.

A non-silicon defoaming agent, includes an acrylate polymer, an organic solvent carrier, hydrophobic particles and defoaming auxiliaries; and the acrylate polymer is prepared from following raw material components: monomer-1, monomer-2, unsaturated terminated polyether, alkene, diluent and initiator. The present invention further includes a preparing method for the non-silicon defoaming agent and the application of the non-silicon defoaming agent to the defoaming and foam inhibiting in systems rich in anionic surfactants. The defoaming agent takes the acrylate polymer as the main active substance and has excellent defoaming and foam inhibiting performance. By dropwise adding monomers, the defoaming performance of the acrylate polymer is improved, by using unsaturated terminated polyether to modify, the hydrophilia of the acrylate polymer is improved, the instant defoaming capacity is further improved, and by the alkene with the carbon atoms of 6-22 to modify, the foam inhibiting performance of the defoaming agent is improved. 1. A non-silicon defoaming agent comprising an acrylate polymer , an organic solvent carrier , a plurality of hydrophobic particles and a plurality of defoaming auxiliaries; wherein a use level of the acrylate polymer is 15-70% of a total mass of the non-silicon defoaming agent , a use level of the organic solvent carrier is 10-70% of the total mass of the non-silicon defoaming agent , a use level of the plurality of hydrophobic particles is 0.1-15% of the total mass of the non-silicon defoaming agent , and a use level of the plurality of defoaming auxiliaries is 1-25% of the total mass of the non-silicon defoaming agent;the acrylate polymer is prepared from following raw material components: a first monomer, a second monomer, an unsaturated terminated polyether, an alkene, a diluent and an initiator; a total use level of the first monomer and the second monomer is 20-70% of a total mass of the raw material components, a use level of the ...

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Номер записи: 89

20-02-2020 дата публикации

Joint sealing compound and tool for the treatment thereof and set and illuminating means

Номер: US20200056078A1

Автор: Dinko Jurcevic

Принадлежит: KDS HOLDING GMBH

A joint sealing compound for the in-situ production of connection joints in wet areas. The joint sealing compound is based on acrylates. The joint sealing compound is either light-curable only with a light which is outside of the UV range, or the joint sealing compound is curable via a dual-curing process wherein the joint sealing compound is moisture-curing with a light which is outside of the UV range.

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Номер записи: 90

04-03-2021 дата публикации

CURABLE SEALANT COMPOSITIONS, SEAL CAP, AND METHODS OF MAKING AND USING THE SAME

Номер: US20210062858A1

Автор: Boyd Scott A., Cook Clinton J., DeMoss Susan E., Moser William H., Swan Michael D., Townsend Erik M., Zook Jonathan D.

Принадлежит:

Curable sealant compositions comprise the components: a) x weight percent of at least one polythiol; b) y weight percent of at least one unsaturated compound having at least two non-aromatic carbon-carbon double bonds, at least one carbon-carbon triple bond, or a combination thereof; c) from 0.01 to 8 weight percent of at least one organoborane-amine complex; d) from 0.05 to 10 weight percent of at least one organic peroxide; and e) from 0.01 to 10 weight percent of a photoinitiator system capable of generating free radicals upon exposure to actinic radiation. Each of x and y represents a positive real number. The sum x+y is in the range of 72 to 99. The weight percent ranges of the components a)-e) are based on the total weight of the components a)-e). A seal cap including the curable sealant composition and methods of making and using the curable sealant compositions are also disclosed. 1. A curable sealant composition comprising components:a) x weight percent of at least one polythiol;b) y weight percent of at least one unsaturated compound having at least two non-aromatic carbon-carbon double bonds, at least one carbon-carbon triple bond, or a combination thereof;c) from 0.01 to 8 weight percent of at least one organoborane-amine complex;d) from 0.05 to 10 weight percent of at least one organic peroxide; ande) from 0.01 to 10 weight percent of a photoinitiator system capable of generating free radicals upon exposure to actinic radiation, wherein x and y are positive real numbers, wherein x+y is in the range of 72 to 99, and wherein the weight percent ranges of the components a)-e) are based on the total weight of the components a)-e).2. The curable sealant composition of claim 1 , wherein the curable sealant composition comprises:a) from 70 to 98 weight percent of the at least one polythiol;b) from 2 to 20 weight percent of the at least one unsaturated compound;c) from 0.01 to 8 weight percent of the at least one organoborane-amine complex;d) from 0.05 to 10 ...

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Номер записи: 91

10-03-2022 дата публикации

All-solid-state battery and photocurable composition used in all-solid-state battery

Номер: US20220077528A1

Автор: Katsuaki Odagi, Kazuhito Kato, Kazumasa Inata, Keiichi Minami, Masato Ono, Yousuke KOIDE

Принадлежит: TOAGOSEI CO LTD, Toyota Motor Corp

A photocurable composition includes a compound having one (meth)acryloyl group in one molecule and not having a urethane bond and a photoradical polymerization initiator as essential components, and further includes a compound having one (meth)acryloyl group in one molecule and not having a urethane bond, a compound having a (meth)acryloyl group and a urethane bond, and a compound having another ethylenically unsaturated group as optional components, in which a viscosity of the photocurable composition at 25° C. is 1 Pa·s to 100 Pa·s. The photocurable composition is a material for forming a resin layer on at least a part of a side surface of a laminated electrode body in an all-solid-state battery.

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Номер записи: 92

28-02-2019 дата публикации

AMPHIPHILIC BRANCHED POLYDIORGANOSILOXANE MACROMERS

Номер: US20190062485A1

Автор: Chang Frank, Holland Troy Vernon, HUANG JINYU

Принадлежит:

The invention provides a class of amphiphilic branched macromers and the uses thereof. An amphiphilic branched polydiorganosiloxane macromer of the invention is produced from an α,ω-dimethacryloyl-terminated polydiorganosiloxane vinylic crosslinker comprising one or more ATRP-containing siloxane units having one substituent having an ATRP initiator by ATRP polymerization of one or more hydrophilic vinylic monomers. It comprises at least two polydiorganosiloxane polymer chains each having at most two terminal methacryloxy groups, dangling hydrophilic polymer chains each having a polymerizable or non-polymerizable terminal group, and one or more hydrophilic polymer chains as linkages between two polydiorganosiloxane chains. The present invention is also related to a silicone hydrogel contact lens, which comprises units derived from a polydiorganosiloxane-containing amphiphilic branched macromer of the invention. 14-. (canceled)5. A silicone hydrogel contact lens , comprising a crosslinked polymeric material which comprises units of an amphiphilic branched polydiorganosiloxane macromer , wherein the amphiphilic branched polydiorganosiloxane macromer comprises:(1) at least first polydiorganosiloxane polymer chain having two terminal methacryloyl groups; and(2) at least one first hydrophilic chain;(3) at least one second hydrophilic polymer chain; and(4) at least one second polydiorganosiloxane polymer chain at least one end of which is covalently connected to the second hydrophilic polymer chain,wherein the first and second polydiorganosiloxane chains are derived from an α,ω-dimethacryloyl-terminated polydiorganosiloxane vinylic crosslinker comprising one or more ATRP-containing siloxane units having one substituent having an ATRP initiator,wherein the first hydrophilic chain is anchored covalently onto one single ATRP-containing siloxane unit of the first or second polydiorganosiloxane chain at one of the two ends of the first hydrophilic polymer chain and has one ...

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Номер записи: 93

17-03-2022 дата публикации

COMPOSITION INCLUDING POLYESTER RESIN AND VINYL ESTER AND METHOD OF USING THE SAME

Номер: US20220081555A1

Автор: Norlander Andrew D., Pokorny Richard J., Schulz Mark F., Smith Felton L., XU Ruijian, Yang Yu

Принадлежит:

The composition includes at least one of a dicyclopentadiene-modified unsaturated polyester resin or an ethylene glycol fumarate unsaturated polyester resin; a vinyl ester represented by formula R—[C(O)—O—CH═CH]wherein R is alkyl, aryl, or a combination thereof, and n is 1 or 2; a tertiary amine; and inorganic filler. A method of repairing a damaged surface using the composition C is also described. 1. A composition comprising:at least one of a dicyclopentadiene-modified unsaturated polyester resin or an ethylene glycol fumarate unsaturated polyester resin;{'sub': ['2', 'n'], '#text': 'a vinyl ester represented by formula R—[C(O)—O—CH═CH]wherein R is alkyl, aryl, or a combination thereof, and n is 1 or 2;'}a tertiary amine; andinorganic filler.2. The composition of claim 1 , wherein the composition is substantially free of a vinyl aromatic compound comprising at least one vinyl substituent on an aromatic ring.3. The composition of claim 1 , wherein the vinyl ester is represented by formula R—C(O)—O—CH═CH claim 1 , wherein R is alkyl.4. The composition of claim 3 , wherein R has more than one carbon atom.5. The composition of claim 1 , further comprising a reactive diluent comprising at least one of acrylate groups claim 1 , methacrylate groups claim 1 , allyl ether groups claim 1 , or vinyl ether groups.6. The composition of claim 1 , further comprising one or more reactive compounds having at least one of a mercaptan or epoxy group.7. The composition of claim 1 , wherein the inorganic filler comprises at least one of ceramic beads claim 1 , polymer beads claim 1 , silica claim 1 , hollow ceramic elements claim 1 , hollow polymeric elements claim 1 , alumina claim 1 , zirconia claim 1 , mica claim 1 , dolomite claim 1 , wollastonite claim 1 , fibers claim 1 , talc claim 1 , calcium carbonate claim 1 , or clay.8. The composition of claim 1 , wherein the inorganic filler is non-fibrous.9. The composition of claim 1 , wherein the tertiary amine comprises at least one N ...

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Номер записи: 94

17-03-2022 дата публикации

COMPOSITION INCLUDING POLYESTER RESIN, ACRYLATE, AND VINYL ESTER AND METHOD OF USING THE SAME

Номер: US20220081556A1

Автор: Norlander Andrew D., Pokorny Richard J., Schulz Mark F., XU Ruijian, Yang Yu

Принадлежит:

The composition includes a polyester resin comprising at least one α,β-unsaturated ester group, an acrylate or methacrylate, a vinyl ester represented by formula R—[C(O)—O—CH—CH]n, wherein R is alkyl, aryl, or a combination thereof and n is 1 or 2, and a metal salt of a carboxylic acid. A method of repairing a damaged surface using the composition is also described. 1. A composition comprising:a polyester resin comprising at least one α,β-unsaturated ester group;an acrylate or methacrylate;{'sub': 2', 'n, 'a vinyl ester represented by formula R—[C(O)—O—CH═CH]wherein R is alkyl, aryl, or a combination thereof, and n is 1 or 2; and'}a metal salt of a carboxylic acid.2. The composition of claim 1 , wherein the composition is substantially free of a vinyl aromatic compound having at least one vinyl substituent on an aromatic ring.3. The composition of claim 1 , wherein the polyester resin comprises at least one of an unsaturated polyester resin having internal olefin groups claim 1 , a dicyclopentadiene-modified unsaturated polyester resin claim 1 , or an epoxy vinyl ester resin.4. The composition of claim 1 , wherein the acrylate or methacrylate is a multi-functional acrylate or methacrylate comprising at least one of a bis-acrylic acid or methacrylic acid ester of ethylene glycol claim 1 , 1 claim 1 ,4-butanediol or 1 claim 1 ,6-hexanediol; a tris-acrylic acid or methacrylic acid ester of glycerol claim 1 , trimethylolpropane or pentaerythritol; a tetrakis-acrylic acid or methacrylic acid ester of pentaerythritol; or an acrylate or methacrylate ester of an alkoxylation product of any of ethylene glycol claim 1 , 1 claim 1 ,4-butanediol claim 1 , 1 claim 1 ,6-hexanediol claim 1 , glycerol claim 1 , trimethylolpropane claim 1 , or pentaerythritol and at least one of propylene oxide or ethylene oxide.5. The composition of claim 1 , wherein the metal salt comprises at least one of an iron (II) carboxylate claim 1 , copper (II) carboxylate claim 1 , or cobalt (II) ...

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Номер записи: 95

27-02-2020 дата публикации

SURFACE-ACTIVE TWO-TAILED HYDROPHOBIC ASSOCIATED POLYMER AND PREPARATION METHOD THEREOF

Номер: US20200062881A1

Автор: Li Yongming, REN Qiang, ZHANG Liehui, Zhao Jinzhou

Принадлежит: SOUTHWEST PETROLEUM UNIVERSITY

The present invention provides a surface-active two-tailed hydrophobic associated polymer and a preparation method thereof. The surface-active two-tailed hydrophobic associated polymer is prepared using a micellar free radical copolymerization method including: adding a surfactant sodium lauryl sulfate and a hydrophobic monomer N-phenethyl-N-alkyl (methyl) acrylamide or N-benzyl-N-alkyl (methyl) acrylamide into an aqueous solution containing acrylamide, acrylic acid, 2-acrylamide-2-methylpropanesulfonic acid, and surface-active macromonomer polyoxyethylene lauryl ether (methyl) acrylate, wherein the surfactant is used to solubilize the hydrophobic monomer in the formed micelle; adjusting pH to 6-8 with sodium hydroxide, and copolymerizing the hydrophobic monomer and a water-soluble monomer by means of photoinitiation. The properties, such as viscosifying property, temperature resistance, salt resistance and hydrolysis resistance, of the hydrophobic associated polymer can be effectively improved. The preparation method is reliable in principle and simple in operation and has a wide market prospect. 2. The surface-active two-tailed hydrophobic associated polymer according to claim 1 , wherein the surface-active two-tailed hydrophobic associated polymer has a viscosity average molecular weight of 100 to 10 claim 1 ,000 claim 1 ,000.3. A preparation process of the surface-active two-tailed hydrophobic associated polymer according to claim 1 , sequentially comprising the following steps:(1) adding acrylamide, acrylic acid, 2-acrylamide-2-methylpropanesulfonic acid, and surface-active macromonomer polyoxyethylene lauryl ether (methyl) acrylate to distilled water to obtain a first solution, stirring uniformly, adjusting pH of the first solution to 6-8 with sodium hydroxide to obtain a second solution, adding a hydrophobic monomer N-phenethyl-N-alkyl (methyl) acrylamide or N-benzyl-N-alkyl (methyl) acrylamide and a surfactant sodium lauryl sulfate to the second solution to ...

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Номер записи: 96

27-02-2020 дата публикации

Polyorganosiloxane-containing-rubber latex and production method therefor, polyorganosiloxane-containing-rubber-grafted polymer, powder, resin composition, and molded object

Номер: US20200062946A1

Автор: Ayako Shimonaka, Hiroshi Niino, Shinji Matsuoka, Yuichiro Fujikawa

Принадлежит: Mitsubishi Chemical Corp

An object of the present invention is to provide an impact modifier that provides impact resistance to a molded object obtained by molding a resin composition such as polycarbonate at a high temperature, and exhibits more excellent heat stability (preservation of mechanical properties after a wet heat test, discoloration, and flame retardance), and a thermoplastic resin composition including the impact modifier. The polyorganosiloxane-containing-rubber latex, in which a total amount of sulfate ions and sulfonate ions included in 100 g of the solid content is 2.4 mmol or less, a powder thereof, and a resin composition including the powder and a resin. Further, a molded object thereof and a production method therefor are provided.

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Номер записи: 97

11-03-2021 дата публикации

THERMOSETTING RESIN COMPOSITION

Номер: US20210070909A1

Автор: INOUE Satoshi, NAGAI Yosuke

Принадлежит:

The present invention aims to provide a thermosetting resin composition that causes no environmental issues such as generation of VOCs and has curability (especially, curability at low temperature) as good as that in the case using a diallyl phthalate monomer as a crosslinking agent. The present invention reveals that the following thermosetting resin composition has excellent curability at low temperature. The thermosetting resin composition contains an unsaturated polyester resin; an alicyclic polyfunctional allyl ester represented by the following formula (1) [in the formula, n is an integer of 2 to 4 and Z is an n-valent alicyclic hydrocarbon group]; and an initiator having a one-minute half-life temperature in a range of 100° C. to 250° C. and a molecular weight of 100 to 400 and selected from the group consisting of peroxyketals, peroxyesters, dialkyl peroxides, and peroxy carbonates. 2. A cured product obtainable by thermally curing the thermosetting resin composition according to .3. A molded article obtainable by molding the thermosetting resin composition according to . The present invention relates to thermosetting resin compositions.Sealing resins are recently used for electronic components such as capacitors, coils, and resistors in order to improve reliability and productivity. Sealing resins are required to have various characteristics according to the shape and size of the target electronic component, such as physical characteristics including moisture resistance, low-stress properties, high thermal conductivity, and impact resistance. Examples of the resin satisfying these characteristics include thermosetting resins such as diallyl phthalate resins and unsaturated polyester resins.Known resin compositions such as unsaturated polyester resin compositions and vinyl ester resin compositions typically contain styrene as a crosslinking agent because of its excellent reactivity (see Patent Literature 1). Unfortunately, use of styrene may cause ...

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Номер записи: 98

11-03-2021 дата публикации

ONE-POT PROCESS OF MAKING SILICONE-ACRYLIC HYBRID PRESSURE SENSITIVE ADHESIVE COMPOSITIONS

Номер: US20210070910A1

Автор: Liu Yuxia

Принадлежит:

The invention related to a one-pot process of making a single-phase silicone-acrylic hybrid adhesive composition comprising acrylic polymer and silicone polymer that are covalently bonded through a —Si—O—Si— linkage. The acrylic polymer contains at least one hydrolyzable silane (meth)acrylic monomer or siloxane (meth)acrylic macromer. These functional moieties provide reaction sites to form —Si—O—Si— bond by reacting hydrolyzable groups in the silicone polymer in the presence of a base or acid catalyst and water. The formed covalent bonds between the two incompatible systems of silicone polymer and acrylic polymer prevents phase separation and thereby a permanent, homogeneous single-phase system is formed. 1: A one-pot process of making a single-phase silicone-acrylic hybrid composition comprising the steps of:(a) making an acrylic polymer solution by a free radical polymerization in an organic solution;(b) adding (i) a silicone polymer and (ii) a catalyst to the acrylic polymer solution and reacting to form a silicone-acrylic hybrid solution;(c) neutralizing the silicone-acrylic hybrid solution with a neutralization reagent, wherein the ratio of the silicone polymer and the acrylic polymer is from 50:1 to 1:50,', 'wherein the silicon-acrylic hybrid composition comprises —Si—O—Si— covalent bond linkages between the silicone polymer and the acrylic polymer., '(d) filtering any solid precipitates from the silicone-acrylic hybrid solution to form a single-phase silicone acrylic hybrid composition in solution;'}2: A one-pot process of making a single-phase silicone-acrylic hybrid composition comprising the steps of: (i) a mixture of monomers, wherein at least one monomer comprises a hydrolyzable silane (meth)acrylic monomer and/or a siloxane (meth)acrylic macromer,', '(ii) a free radical initiator,', '(iii) an organic solvent,, '(a) making an acrylic polymer solution by polymerizingwherein the reaction temperature is from about 50 to about 150° C., and reaction time is ...

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Номер записи: 99

16-03-2017 дата публикации

Solid Pharmaceutical Preparations Containing Copolymers Based On Polyethers Combined With Poorly Water-Soluble Polymers

Номер: US20170072059A1

Автор: Dejan Djuric, Karl Kolter, Stefan Fischer

Принадлежит: BASF SE

Dosage forms comprising preparations of slightly water-soluble active substances in a polymer matrix of polyether copolymers, the polyether copolymers being obtained by free radical polymerization of a mixture of from 30 to 80% by weight of N-vinyllactam, from 10 to 50% by weight of vinyl acetate and from 10 to 50% by weight of a polyether, and of at least one slightly water-soluble polymer in which the slightly water-soluble active substance is present in amorphous form in the polymer matrix.

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Номер записи: 100