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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 6240. Отображено 100.
17-01-2013 дата публикации

Contact lens

Номер: US20130015595A1
Автор: Robert Andrew Broad
Принадлежит: Sauflon CL Ltd

A contact lens formed of a composition comprising the reaction product of: A) at least 10 weight percent, based on the total composition weight excluding solvent, of at least one silicone-containing monomer of the formula I: where n is from 1 to 3, m is from 9 to 15, each a independently is C 1-4 alkyl, and each b independently is C 1-4 alkyl; B) at least 10 weight percent, based on the total composition weight excluding solvent, of 3-methacryloxypropyl tris(trimethylsiloxy)silane; C) N-vinyl pyrrolidone; and D) at least one other non-ionic hydrophilic monomer wherein the combined amount of A) and B) is at least 20 weight percent based on the total composition weight excluding solvent, and wherein the N-vinyl pyrrolidone (NVP) is present in such an amount that the reaction product comprises polyvinyl pyrrolidone (PVP) homopolymer.

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Номер записи: 1
07-02-2013 дата публикации

Radical polymerizable resin, radical polymerizable resin composition, and cured product thereof

Номер: US20130035465A1
Автор: Kiyoharu Tsutsumi, Naoko Araki, Tomoaki Mahiko, Yoshinori Funaki
Принадлежит: Daicel Corp

Provided is a radically polymerizable resin which has a low viscosity, has excellent workability, and is rapidly cured upon application of heat and/or light to form a cured product having excellent flexibility and thermal stability. The radically polymerizable resin composition is obtained by cationic polymerization of an oxetane-ring-containing (meth)acrylic ester compound represented by following Formula (1) alone or in combination with another cationically polymerizable compound. In Formula (1), R 1 represents hydrogen atom or methyl group; R 2 represents hydrogen atom or an alkyl group; and “A” represents a linear or branched chain alkylene group having 4 to 20 carbon atoms.

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Номер записи: 2
16-05-2013 дата публикации

Graft copolymers of polyfarnesenes with condensation polymers

Номер: US20130123379A1
Автор: Derek James Mcphee
Принадлежит: Amyris Inc

Provided herein are graft copolymers of polyfarnesenes with condensation polymers; and methods of making and using the graft copolymers disclosed herein. The graft copolymers are obtained from the reaction of a polycondensation polymer with a modified polyfarnesene obtained from reaction of a polyfarnesene with a modifier in the presence of a grafting initiator. In certain embodiments, the condensation polymers include polyesters, polycarbonates, polyamides, polyethers, phenol-formaldehyde resins, urea-formaldehyde resins, melamine-formaldehyde resins and combinations thereof. In some embodiments, the polyfarnesenes include farnesene homopolymers derived from a farnesene, and farnesene interpolymers derived from a farnesene and at least a vinyl monomer. In certain embodiments, the farnesene is prepared from a sugar by using a microorganism.

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Номер записи: 3
04-07-2013 дата публикации

Ionic silicone hydrogels

Номер: US20130168617A1
Автор: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin
Принадлежит: Johnson and Johnson Vision Care Inc

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.

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Номер записи: 4
04-07-2013 дата публикации

Alkaline solubie resin and light sensible resin composition comprising same and use thereof

Номер: US20130171566A1
Автор: Chunmiao Zhou, Jianshe XUE, Jisheng ZHAO, Shi Shu, Xiaoxiong TIAN, Xuelan WANG
Принадлежит: BOE Technology Group Co Ltd

An embodiment of the invention discloses an alkaline soluble resin and a method for preparing the same. The chemical formula of this alkaline soluble resin is shown in Formula I: wherein a is an integer of 1 to 5, b is an integer of 1 to 5, c is an integer of 1 to 10, d is an integer of 1 to 10, m is an integer of 1 to 30, n is an integer of 1 to 10, R is hydrogen, alkyl, alkoxy or acrylate; the alkaline soluble resin has a weight-average molecular weight of 3,500-35,000. The invention also discloses a light sensible resin composition comprising the alkaline soluble resin, as well as a colored photoresist for color filters comprising the aforementioned light sensible resin composition and a display element comprising this colored photoresist.

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Номер записи: 5
25-07-2013 дата публикации

RESIN COMPOSITION FOR FLEXOGRAPHIC PRINTING PLATE, LASER-ENGRAVING TYPE FLEXOGRAPHIC PRINTING PLATE PRECURSOR AND PROCESS FOR PRODUCING SAME, AND FLEXOGRAPHIC PRINTING PLATE AND PROCESS FOR MAKING SAME

Номер: US20130186292A1
Автор: USHIJIMA Kenta
Принадлежит: FUJIFILM Corporation

Disclosed is a resin composition for a flexographic printing plate, comprising (Component A) a binder resin and (Component B) a compound represented by Formula (1) and/or Formula (2), Component B being contained at 1 to 50 parts by mass relative to 100 parts by mass of Component A, 2. The resin composition for a flexographic printing plate according to claim 1 , wherein Component A above comprises a urethane bond.3. The resin composition for a flexographic printing plate according to claim 2 , wherein Component A comprises an ethylenically unsaturated group claim 2 , a dialkoxysilyl group claim 2 , or a trialkoxysilyl group.4. The resin composition for a flexographic printing plate according to claim 1 , wherein Component A is a plastomer at 20° C.5. The resin composition for a flexographic printing plate according to claim 3 , wherein Component A is a plastomer at 20° C.6. The resin composition for a flexographic printing plate according to claim 1 , wherein Component A has a (meth)acryloyloxy group at both main chain termini.7. The resin composition for a flexographic printing plate according to claim 5 , wherein Component A has a (meth)acryloyloxy group at both main chain termini.8. The resin composition for a flexographic printing plate according to claim 1 , wherein it further comprises (Component C) a photothermal conversion agent.9. The resin composition for a flexographic printing plate according to claim 7 , wherein it further comprises (Component C) a photothermal conversion agent.10. The resin composition for a flexographic printing plate according to claim 8 , wherein Component C is carbon black.11. The resin composition for a flexographic printing plate according to claim 9 , wherein Component C is carbon black.12. The resin composition for a flexographic printing plate according to claim 1 , wherein it further comprises a polymerization initiator.13. The resin composition for a flexographic printing plate according to claim 11 , wherein it further ...

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Номер записи: 6
12-09-2013 дата публикации

Biomedical devices containing internal wetting agents

Номер: US20130237631A1
Автор: Azaam Alli, Douglas G. Vanderlaan, Frank F. Molock, JR., Gregory A. Hill, James D. Ford, Kevin P. Mccabe, Robert B. Steffen
Принадлежит: Johnson and Johnson Vision Care Inc

This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer.

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Номер записи: 7
02-01-2020 дата публикации

Oxime ester photoinitiators

Номер: US20200004148A1
Автор: Hisatoshi Kura, Kazuhiko Kunimoto, Keita Tanaka, Ryuhei Yamagami, Yuichi Nishimae
Принадлежит: BASF SE

Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.

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Номер записи: 8
11-01-2018 дата публикации

SILICONE HYDROGELS COMPRISING HIGH LEVELS OF POLYAMIDES

Номер: US20180009922A1
Автор: Alli Azaam, Guzman Alexander
Принадлежит:

Described are silicone hydrogels with high levels of polyamides exhibiting an excellent balance of physical, mechanical, and biological properties. The silicone hydrogels are formed from a reactive monomer mixture comprising: a hydroxylalkyl (meth)acrylate monomer; hydroxyl-containing silicone components; and a polyamide, wherein the polyamide is present in an amount greater than 15 weight percent, based on the total weight of reactive components in the reactive monomer mixture. 1. A silicone hydrogel formed from a reactive monomer mixture comprising:a. at least one hydroxyalkyl (meth)acrylate monomer;b. at least one first mono-functional hydroxyl-substituted poly(disubstituted siloxane) having 4 to 8 siloxane repeating units;c. at least one second hydroxyl-substituted poly(disubstituted siloxane) selected from the group consisting of mono-functional hydroxyl-substituted poly(disubstituted siloxane) having 10 to 200, multifunctional hydroxyl-substituted poly(disubstituted siloxanes) having 10 to 200, and mixtures thereof;d. at least 15 wt % at least one polyamide, based on the total weight of reactive components in the reactive monomer mixture; ande. optional further constituents.2. The silicone hydrogel of claim 1 , wherein the polyamide is present in the reactive mixture in an amount between 15.1 weight percent and about 40 weight percent claim 1 , based on the total weight of all reactive components in the reactive monomer mixture.3. The silicone hydrogel of claim 1 , wherein the polyamide is selected from the group essentially consisting of cyclic polyamides claim 1 , acyclic polyamides claim 1 , and mixtures thereof.5. The silicone hydrogel of claim 4 , wherein the number of carbon atoms in Rand Rtaken together is 6 or less.6. The silicone hydrogel of claim 3 , wherein the cyclic polyamide is prepared from at least one of α-lactam claim 3 , β-lactam claim 3 , γ-lactam claim 3 , δ-lactam claim 3 , and ε-lactam.8. The silicone hydrogel of claim 7 , wherein f is 8 ...

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Номер записи: 9
08-01-2015 дата публикации

ORGANO-MODIFIED SILICONE POLYMERS AND HYDROGELS COMPRISING THE SAME

Номер: US20150011671A1
Автор: Bhat Shreedhar, Naik Sandeep Shashikant, Phukan Monjit, Saxena Anubhav
Принадлежит:

A hydrophilic silicone polymer composition suitable for use in producing hydrogel polymer films disclosed. In one aspect, a hydrophilic silicone monomer is of the Formula 1: 2. The polymer in the composition of claim 1 , wherein L is a hydrophilic residue chosen from a polyalkyleneoxide claim 1 , optionally a polyalkyleneoxide chosen from —CHCHO— claim 1 , —CHCH(CH)O— claim 1 , —CHCHCHO— claim 1 , and their analogues with up to 6 carbon atoms.4. The polymer in the composition of wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rin the unit G of group E are independently selected from a hydrocarbon radical chosen from methyl claim 1 , ethyl claim 1 , propyl claim 1 , iso-propyl claim 1 , butyl claim 1 , isobutyl claim 1 , phenyl claim 1 , naphthyl claim 1 , an aralkyl radical with 8 to 20 carbon atoms claim 1 , trifluoromethylpropyl claim 1 , and combinations of two or more thereof.6. The polymer in the composition of claim 1 , where Rand Rare hydrogen claim 1 , Ris chosen from hydrogen or a methyl radical claim 1 , and Ris a part of an ethylenically-unsaturated hydrophilic monomer or a hydrophobic monomer.7. The composition of claim 1 , wherein siloxane polymer has at least one terminal reactive group.8. The composition of where the siloxane polymer is (a) a homopolymer or (b) a copolymer.9. The composition of claim 8 , wherein the polymer is a copolymer further comprising a free-radical polymerizable organic monomer chosen from a vinylic monomer claim 8 , an acrylide monomer claim 8 , an acrylic monomer claim 8 , or a combination of two or more thereof.10. The copolymer of claim 8 , wherein the vinylic monomer is chosen from N-vinyl-pyrrolidone claim 8 , N-vinyl-caprolactam claim 8 , N-vinyl-acetamide claim 8 , N-vinyl-formamide and N-vinyl-isopropylamide claim 8 , vinyl benzene claim 8 , vinyl naphthalene claim 8 , vinyl pyridine claim 8 , vinyl alcohol claim 8 , vinyl containing silicones claim 8 , or a ...

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Номер записи: 10
08-01-2015 дата публикации

Silicone hydrogels having a structure formed via controlled reaction kinetics

Номер: US20150011672A1
Автор: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin
Принадлежит: Johnson and Johnson Vision Care Inc

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.

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Номер записи: 11
09-01-2020 дата публикации

OIL-REPELLENT COMPOSITION

Номер: US20200010691A1
Автор: MURATA Naoki
Принадлежит: SHOWA DENKO K.K.

An oil-repellent composition is provided containing an aqueous emulsion in which a copolymer (A) containing a constituent unit based on an ethylenically unsaturated carboxylic acid ester monomer (A1) and a constituent unit based on an ethylenically unsaturated carboxylic acid monomer (A2) is dispersed in an aqueous medium (B), and polyether-modified polydimethyl siloxane (C). 1. An oil-repellent composition , comprising:an aqueous emulsion in which a copolymer (A) containing, as an essential component, a constituent unit based on an ethylenically unsaturated carboxylic acid ester monomer A1) and a constituent unit based on an ethylenically unsaturated carboxylic acid monomer (A2) is dispersed in an aqueous medium (B); andpolyether-modified polydimethyl siloxane (C).2. The oil-repellent composition according to claim 1 ,wherein polyether described in the polyether-modified polydimethyl siloxane (C) is hydroxyl group-containing polyether-modified polydimethyl siloxane.3. The oil-repellent composition according to claim 1 ,wherein a content of the polyether-modified polydimethyl siloxane (C) is 0.1 to 20 parts by mass with respect to 100 parts by mass of the copolymer (A).4. The oil-repellent composition according to claim 1 ,wherein the constituent unit based on the ethylenically unsaturated carboxylic acid ester monomer A1) is contained at 80% to 99% by mass with respect to the entire constituent units of the copolymer (A).5. The oil-repellent composition according to claim 1 ,wherein the constituent unit based on the ethylenically unsaturated carboxylic acid monomer (A2) is contained at 0.1% to 20% by mass with respect to the entire constituent units of the copolymer (A).6. The oil-repellent composition according to claim 1 ,wherein the ethylenically unsaturated carboxylic acid ester monomer A1) is ester of alcohol having 1 to 8 carbon atoms and (meth)acrylic acid.7. The oil-repellent composition according to claim 1 ,wherein the ethylenically unsaturated carboxylic ...

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Номер записи: 12
14-01-2021 дата публикации

NEGATIVE-TYPE PHOTOSENSITIVE RESIN COMPOSITION, CURED FILM, ELEMENT AND DISPLAY APPARATUS THAT INCLUDE CURED FILM, PRODUCTION METHOD FOR THE SAME

Номер: US20210011381A1
Автор: KAMEMOTO Satoshi, Miyoshi Kazuto, Tanigaki Yugo
Принадлежит: Toray Industries, Inc.

To provide an alkaline developable negative-type photosensitive resin composition from which a cured film that has a high-resolution and low-taper pattern shape and that are excellent in heat resistance and light blocking property can be obtained. A negative-type photosensitive resin composition is characterized by containing an (A1) first resin, a (A2) second resin, a (C) photopolymerization initiator, and a (D) coloring agent, wherein the (A1) first resin is an (A1-1) polyimide and/or an (A1-2) polybenzo-oxazole, and wherein the (A2) second resin is one or more species selected from a (A2-1) polyimide precursor, a (A2-2) polybenzo-oxazole precursor, a (A2-3) polysiloxane, a (A2-4) cardo based resin, and an (A2-5) acrylic resin, and wherein a content ratio of the (A1) first resin in a total of 100 mass % of the (A1) first resin and the (A2) second resin is within the range of 25 to 90 mass %. 1. A cured film obtained by curing the negative-type photosensitive resin composition comprising an (A1) first resin , a (A2) second resin , a (C) photopolymerization initiator , and a (D) coloring agent ,wherein the (A1) first resin is an (A1-1) polyimide and/or an (A1-2) polybenzo-oxazole, andwherein the (A2) second resin is one or more species selected from a (A2-2) polybenzo-oxazole precursor, a (A2-3) polysiloxane, a (A2-4) cardo based resin, and an (A2-5) acrylic resin, andwherein a content ratio of the (A1) first resin in a total of 100 mass % of the (A1) first resin and the (A2) second resin is within a range of 25 to 90 mass %.2. The cured film according to claim 1 , wherein the (D) coloring agent contains a (D1) pigment and the (D1) pigment content ratio in the entire solid content of the negative photosensitive resin composition is within a range of 5 to 70 mass %.3. The cured film according to claim 1 , wherein the (D) coloring agent contains a (Da) black coloring agent and the (Da) black coloring agent contains a (D1a) black pigment.5. The cured film according to ...

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Номер записи: 13
19-01-2017 дата публикации

COMPOSITIONS FOR PROVIDING FRIZZ-FREE WAVY HAIRSTYLES USING LOW HEAT

Номер: US20170014330A1
Автор: Steigerwald Sean, WHITE Angie
Принадлежит:

Hairstyling compositions which provide the user with continuous wave fizz-free hairstyling using only low heat (such as that applied by a blow dryer) and a round hair brush as well as a natural feel to the hair is disclosed. The compositions incorporate a mixture of two and preferably three polymers, those polymers including an organopolysiloxane graft polymer, a graft polymer comprising polyacrylate (such as polyacrylate-32), and optionally a water-soluble silicone polymer (such as bis-PEG-8-dimethicone). The method of using these compositions to provide the desired hairstyles is also disclosed. 3. The hairstyling composition according to wherein the water-soluble silicone polymer is comprised of a linear inorganic backbone of silicon and oxygen.4. The hairstyling composition according to wherein the water-soluble silicone polymer has a dimethicone backbone.5. The hairstyling composition according to wherein the water-soluble silicone polymer has organic pendent groups said pendent groups containing multiple units of ethylene glycol in an amount so as to render the polymer water-soluble.6. The hairstyling composition according to wherein the water-soluble silicone polymer is a (PEG)dimethicone claim 5 , wherein x is from about 6 to about 20.7. The hairstyling composition according to wherein the water-soluble silicone polymer is bis-PEG-8-dimethicone.8. The hairstyling composition according to wherein the water-soluble silicone polymer is selected from dimethicone claim 2 , amino-functionalized PDMS claim 2 , and mixtures thereof.9. The hairstyling composition according to wherein the polyacrylate graft polymer has a Tof from about 85° C. to about 95° C.10. The hairstyling composition according to wherein the graft acrylate styling polymer is polyacrylate-32 (a copolymer of PEG/PPG-23/6-dimethicone claim 1 , sodium acryloyl dimethyltaurate claim 1 , citraconic anhydride claim 1 , and one or more monomers of acrylic acid claim 1 , methacrylic acid claim 1 , and ...

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Номер записи: 14
16-01-2020 дата публикации

GRAFT COPOLYMER, AND THERMOPLASTIC RESIN COMPOSITION USING SAME

Номер: US20200017686A1
Автор: Atsuta Hiroyuki, FUKAMACHI Yuusuke, IWANAGA Takashi, KAMATA Ichiro, Matsuyama Hironori, NAITO Yoshitaka
Принадлежит:

A graft copolymer (B-III) includes a rubbery polymer (A-III) that is a miniemulsion polymerization reaction product of an alkyl (meth)acrylate; and at least one monomer selected from aromatic vinyl compounds, (meth)acrylic acid esters, and vinyl cyanide compounds graft-polymerized onto the rubbery polymer (A-III). 1. A graft copolymer (B-III) comprising:a rubbery polymer (A-III) that is a miniemulsion polymerization reaction product of an alkyl (meth)acrylate; andat least one monomer selected from aromatic vinyl compounds, (meth)acrylic acid esters, and vinyl cyanide compounds graft-polymerized onto the rubbery polymer (A-III).2. A thermoplastic resin composition comprising the graft copolymer (B-III) according to .3. A molded article obtained by molding the thermoplastic resin composition according to . This is a divisional Application of Ser. No. 15/771,823 filed on Apr. 27, 2018, which claims priorities of Japanese Patent Applications No. 2015-212024 filed on Oct. 28, 2015, No. 2015-212025 filed on Oct. 28, 2015, No. 2015-212026 filed on Oct. 28, 2015, and No. 2015-212027 filed on Oct. 28, 2015, disclosure of which is incorporated herein.The present invention relates to first to fourth inventions below.The first invention relates to a graft polymer that has an excellent impact-resistance-imparting effect and that can provide a thermoplastic resin composition excellent in weather resistance and color developability, a production method thereof, a thermoplastic resin composition including the graft copolymer, and a molded article thereof.The second invention relates to crosslinked particles and graft crosslinked particles that, as modifiers of a thermoplastic resin, can improve the flowability, impact resistance, and abrasion resistance of the resin without impairing its color developability and mold shrinkage rate, a thermoplastic resin composition including the crosslinked particles and/or the graft crosslinked particles, and a molded article thereof.The third ...

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Номер записи: 15
17-04-2014 дата публикации

Method of forming an image having multiple phases

Номер: US20140106267A1
Автор: Audrey A. Sherman, John E. Potts, Kevin R. Schaffer, Marc D. Radcliffe, Mieczyslaw H. Mazurek, Raymond P. Johnston, Wendi J. Winkler
Принадлежит: 3M Innovative Properties Co

A method of forming an image having multiple phases is disclosed herein. The method includes forming exposed and unexposed areas, the exposed areas comprising a first polymer network exhibiting first and second phases that are chemically connected and have different refractive indices, the first phase being continuous, and the second phase comprising a plurality of structures dispersed within the first phase, and the unexposed areas comprising a second polymer network comprising third and fourth phases that are chemically connected and have different refractive indices, the third phase being continuous, and the fourth phase comprising a plurality of structures dispersed within the third phase. The first and second polymer networks are chemically connected, and morphology formed by the first and second phases is different than that formed by the third and fourth phases.

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Номер записи: 16
10-02-2022 дата публикации

EPOXY RESIN COMPOSITION, CURABLE RESIN COMPOSITION, CURED PRODUCT, AND ADHESIVE

Номер: US20220041856A1
Автор: KAMIMURA Iho, ODAKA Kazuyoshi, ONOMOTO Hiroshi, Otani Go
Принадлежит: MITSUBISHI CHEMICAL CORPORATION

These vinyl-based polymerizable group-containing silane compounds may be used alone, or two or more thereof may be used in combination. The content of the vinyl-based polymerizable group-containing silane compound is 1% by mass or more and 10% by mass or less, and preferably 1% by mass or more and 5% by mass or less, in 100% by mass of the organosiloxane mixture. When the amount of the vinyl-based polymerizable group-containing silane compound is the lower limit value or more, the peeling force and impact resistance of the obtained cured product tend to be high. When the amount of the vinyl-based polymerizable group-containing silane compound is the upper limit value or less, the peeling force and impact resistance of the obtained cured product tend to be high. 1. An epoxy resin composition , comprising:a rubber-containing polymer, andan epoxy resin, whereinthe rubber-containing polymer contains at least one rubbery polymer and at least one vinyl monomer part, andthe vinyl monomer part has a unit based on a monomer (a) described below, a unit based on a monomer (b) described below, and a unit based on a monomer (c) described below, whereinthe monomer (a) is a polyfunctional (meth)acrylate, the monomer (b) is at least one monomer selected from a group consisting of epoxy group-containing (meth)acrylates and aromatic vinyl monomers, and the monomer (c) is an alkyl (meth)acrylate.2. The epoxy resin composition according to claim 1 , whereinthe rubbery polymer is at least one selected from a group consisting of a diene rubber, a diene-acrylic composite rubber, an acrylic rubber, a silicone rubber, and an acrylic-silicone composite rubber.3. The epoxy resin composition according to claim 1 , whereina proportion of the unit based on the monomer (a) is 1% by mass or more and 45% by mass or less, and a proportion of the unit based on the monomer (b) is 1% by mass or more and 50% by mass or less, with respect to a total mass of the vinyl monomer part.4. A curable resin ...

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Номер записи: 17
23-01-2020 дата публикации

Radiation-Curable Resin Composition and Production Method Thereof

Номер: US20200026185A1
Автор: Mora Barrios Karla Daniela
Принадлежит:

A radiation-curable resin composition, suitable for use in 3D printing, and to the production method thereof, i.e. the method for producing three-dimensional objects using radiation by means of 3D printing of the laser, DLP or LCD type, with successive photopolymerisable layers. The radiation-curable resin composition comprises one or more epoxy-acrylic resins and polymethyl methacrylate, graphene, halloysite nanotubes and one or more photoinitiators. 1. Radiation curable resin composition suitable for use in 3D printing characterized in that it is comprised of:40% to 60% by weight of at least one liquid epoxy resin, in which the liquid epoxy resins have at least two groups capable of reacting by a ring opening mechanism to form a polymer lattice,0.1% to 40% by weight of at least one liquid poly(meth)acrylate, of a single functionality (meth)acrylate, wherein said liquid poly(meth)acrylate will be at most 50% by weight of the total content of (meth)acrylate,0.1% to 10% by weight of at least one cationic photoinitiator,0.1% to 10% by weight of at least one free-radical photoinitiator,5% to 15% by weight of at least one polyether provided with terminal OH groups.2% to 30% by weight of a compound that has at least one unsaturated group and at least one hydroxy group in its molecule,0% to 30% by weight of a hydroxylated compound that has no unsaturated group,0.1% to 5% graphene,0.1% to 20% by weight of halloysite nanotubes.2. Composition of radiation curable resin according to claim 1 , characterized as such because at least one liquid epoxy resin is difunctional.3. Radiation curable resin composition claim 1 , according to claim 1 , characterized in that at least one liquid epoxy resin has an epoxy functionality of at least 2.4. Radiation curable resin composition claim 1 , according to claim 1 , characterized in that it is comprised of at least one polyester provided with terminal OH groups.5. Radiation curable resin composition according to claim 1 , characterized in ...

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Номер записи: 18
24-04-2014 дата публикации

RESIN COMPOSITE MATERIAL AND METHOD FOR PRODUCING RESIN COMPOSITE MATERIAL

Номер: US20140113988A1
Автор: Inui Nobuhiko, Mukohata Daisuke
Принадлежит: Sekisui Chemical Co., Ltd.

To provide a resin composite material in which aggregation of silane compounds in the resin is suppressed and the linear expansion coefficient is lowered, and a method for producing the resin composite material. A resin composite material containing a resin and a silane compound having a structure of the formula (1), wherein a molecular chain of the resin and a molecular chain of the silane compound form an IPN structure or a semi-IPN structure, and a method for producing a resin composite material including a step of mixing a resin and a silane compound to obtain a resin composition and an IPN structure formation step of allowing a plurality of the silane compounds contained in the resin composition to be condensed with each other. Each of Rs in the formula (1) is independently selected from the group consisting of hydrogen, halogen and an arbitrary organic functional group and at least one thereof is a reactive organic functional group. x represents 1 or 1.5. n represents an integer of 100 or more and 10000 or less. 3. The resin composite material according to claim 1 , wherein each of Rs in the formula (1) is independently selected from the group consisting of hydrogen claim 1 , chlorine claim 1 , a silyl claim 1 , a siloxy claim 1 , an alkoxy claim 1 , a vinyl claim 1 , an aryl claim 1 , an alkyl claim 1 , an alkylamine claim 1 , an ether claim 1 , an ester claim 1 , an amine claim 1 , an amide claim 1 , a thiol claim 1 , a methacryl claim 1 , an acryl claim 1 , an epoxy claim 1 , a ureido claim 1 , a mercapto claim 1 , a sulfide and an isocyanate.4. The resin composite material according to claim 1 , wherein at least one of Rs in the formula (1) is a reactive organic functional group selected from the group consisting of a vinyl claim 1 , an alkylamine claim 1 , an amine claim 1 , a methacryl claim 1 , an acryl claim 1 , an epoxy claim 1 , a ureido claim 1 , a mercapto claim 1 , a sulfide and an isocyanate.5. The resin composite material according to claim 1 , ...

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Номер записи: 19
02-02-2017 дата публикации

PIGMENT DISPERSION LIQUID, DECORATIVE MATERIAL, TRANSFER MATERIAL FOR FORMING DECORATIVE MATERIAL, SUBSTRATE WITH DECORATIVE MATERIAL, TOUCH PANEL, INFORMATION DISPLAY DEVICE, AND GRAFT TYPE SILICONE POLYMER

Номер: US20170029648A1
Автор: ASADA Saori, KANEIWA Hideki
Принадлежит: FUJIFILM Corporation

A pigment dispersion liquid includes a pigment dispersant; and a pigment, in which the pigment dispersant is a graft type silicone polymer denoted by General Formula 1. In General Formula 1, Rto R, Rand Rrepresent a hydrogen atom, a hydroxy group, an aryl group, or an alkyl group having 1 to 3 carbon atoms; Rand Rrepresent an arylene group or an alkylene group having 1 to 3 carbon atoms; Y and Z represent a single bond or a divalent organic linking group; A represents a group having a pigment adsorption portion; B represents a group having a structure denoted by General Formula 2; 1 and n represent an integer of greater than or equal to 1; m represents an integer of greater than or equal to 0; and k represents an integer of greater than or equal to 1. 3. The pigment dispersion liquid according to claim 1 ,wherein in General Formula 1 described above, m represents an integer of greater than or equal to 1.4. The pigment dispersion liquid according to claim 2 ,wherein in General Formula 3 described above, m represents an integer of greater than or equal to 1.7. The pigment dispersion liquid according to claim 1 ,wherein the pigment is a white pigment or a black pigment.8. The pigment dispersion liquid according to claim 1 ,wherein the pigment is titanium dioxide or carbon black.9. The pigment dispersion liquid according to claim 1 ,wherein a content rate of the pigment with respect to the pigment dispersion liquid is 20 to 90 mass %.10. The pigment dispersion liquid according to claim 1 , further containing:a silicone resin.11. The pigment dispersion liquid according to claim 1 ,wherein the pigment dispersion liquid is used for forming a decorative material.12. A decorative material using the pigment dispersion liquid according to .13. The decorative material according to claim 12 ,wherein the decorative material is used for a touch panel, and is a white decorative material.14. A transfer material for forming a decorative material claim 12 , comprising:{'claim-ref': ...

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Номер записи: 20
11-02-2016 дата публикации

Impact strength modifier for chlorine-containing resin, chlorine-containing resin composition and molded body of chlorine-containing resin composition

Номер: US20160039963A1
Автор: Atsushi Kuwahara, Ayaka WAKITA, Toshihiro Kasai, Yuichiro Fujikawa
Принадлежит: Mitsubishi Rayon Co Ltd

Disclosed is an impact strength modifier (α) for a chlorine-containing resin, comprising a powder of a graft copolymer (A) obtained by graft polymerizing one or more kinds of vinyl monomers (b1) onto a polyorganosiloxane rubber (A1) or a composite rubber (A2) containing a polyorganosiloxane rubber and a polyalkyl(meth)acrylate rubber, wherein the specific surface area of the powder of the graft copolymer (A) measured by a nitrogen gas adsorption method is from 0.6 to 30 m 2 /g, and the pH of water used for extraction under conditions, in which (1) in an oven at 180° C., 5.0 g of the powder of the graft copolymer (A) is left to stand still and heated for 15 minutes, and (2) after the heating, the powder is dispersed in 100 ml of heated pure water and extracted for 1 hour at 70° C. while stirring, is from 4 to 11.

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Номер записи: 21
16-02-2017 дата публикации

IONIC SILICONE HYDROGELS

Номер: US20170044293A1
Автор: Alli Azaam, Ford James D., Joslin Scott L., Vanderlaan Douglas G.
Принадлежит:

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature. 1. A silicone hydrogel formed from a reaction mixture comprising about 37 to about 75 wt % of a mixture of slow-reacting hydrophilic monomers , each having a slow-reacting hydrophilic monomer kinetic half life; said mixture of slow reacting hydrophilic monomers comprising and least one slow-reacting ionic monomer;at least one silicone-containing component having a silicone-containing component kinetic half life, which may be optionally substituted with at least one hydroxyl containing group; andat least one hydroxyalkyl (meth)acrylate monomer,wherein ratio of each of said slow-reacting hydrophilic component half lives to said silicone-containing component half life is at least 2.2. The silicone hydrogel of wherein said slow-reacting ionic component is selected from the group consisting of anionic components claim 1 , cationic components claim 1 , zwitterionic components and mixtures thereof.3. The silicone hydrogel of wherein said slow-reacting ionic component comprise at least one anionic component selected from the group consisting of carboxylic acids claim 1 , sulfonic acids claim 1 , boronic acids claim 1 , phosphonic acids and their salts and mixtures thereof.4. The silicone hydrogel of wherein said slow-reacting ionic component comprises reactive functionality selected from the group consisting of ionic vinyl ethers claim 1 , ionic vinyl amines and ionic vinyl enamines.6. The silicone hydrogel of wherein said slow-reacting ionic component is ...

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Номер записи: 22
14-02-2019 дата публикации

Methods of Preparing Compositions for Containers and Other Articles and Methods of Using Same

Номер: US20190048126A1
Автор: "OBrien Robert M.", Deng Lan, Evans Richard H, Niederst Jeffrey, Prouvost Benoit, Romagnoli Kevin, Santure David J., Von Maier Mark S.
Принадлежит: SWIMC LLC

This invention provides a polymer, which is preferably a polyether polymer. The polymer may be uses in coating compositions. Containers and other articles comprising the polymer and methods of making such containers and other articles are also provided. The invention further provides compositions including the polymer (e.g., powder coatings), which have utility in a variety of coating end uses, including, for example, valve and pipe coatings. 112-. (canceled)14. The food or beverage packaging container of claim 13 , wherein the polyether polymer is completely free of bound polyhydric phenols claim 13 , or epoxides thereof claim 13 , having estrogenic activity greater than that of 4 claim 13 ,4′-(propane-2 claim 13 ,2-diyl)bis(2 claim 13 ,6-dibromophenol).15. The food or beverage packaging container of claim 13 , wherein the polyether polymer is completely free of bound polyhydric phenols claim 13 , or epoxides thereof claim 13 , having estrogenic activity greater than that of 2 claim 13 ,2-bis(4-hydroxyphenyl)propanoic acid.16. The food or beverage packaging container of claim 13 , wherein the coating composition is substantially free of mobile or bound bisphenol A claim 13 , bisphenol F claim 13 , bisphenol S claim 13 , polyhydric phenols having estrogenic activity greater than or equal to that of bisphenol S claim 13 , and epoxides thereof.18. The method of claim 17 , wherein the degree of polymerization is over 8.19. The method of claim 17 , wherein the degree of polymerization is over 12.20. The method of claim 17 , wherein the halohydrin is epichlorohydrin.22. The method of claim 17 , comprising the further step of reacting the polyether polymer with a hindered polyhydric phenol compound having an atom or group having an atomic weight of at least 15 Daltons in an ortho position relative to an oxygen atom on a phenol ring in the presence of a nitrogen-containing catalyst having at least one bridgehead Nitrogen atom.23. The method of claim 21 , wherein the ...

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Номер записи: 23
14-02-2019 дата публикации

Contact lens package and method for producing the same

Номер: US20190049751A1
Автор: Azusa OBATA, Masaki Baba, Susumu Ogawa
Принадлежит: Menicon Co Ltd

A contact lens package includes a silicone hydrogel contact lens, a packaging container composed of a polypropylene, and a packaging solution containing a nonionic surfactant, the nonionic surfactant including a linear alkyl moiety having 12 or more carbon atoms and an oxyethylene moiety, the average addition mole number of oxyethylene being 30 or more per mole of the nonionic surfactant.

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Номер записи: 24
04-03-2021 дата публикации

MULTIFUNCTIONAL NITROXIDE-MEDIATED POLYMERIZATION INITIATORS AND MULTI-ARMED POLYMERS AND HYDROGELS FORMED THEREFROM

Номер: US20210061957A1
Автор: Delaney, Dyndikova Tatyana, Grosso Paul V., JR. Joseph T., KUMMAILIL John, Rehder Carey
Принадлежит:

In some aspects, the present disclosure pertains to multi-arm polymers that comprise a core and a plurality of polymer segments having a first end that is covalently attached to the core and (a) a second end comprising a moiety that comprises a reactive end group, wherein the polymer segments comprise one or more hydrophilic aprotic NMP-polymerizable monomers, and wherein the reactive multi-arm polymer comprises nitroxide radicals or (b) a second end comprising a moiety that comprises an alkoxyamine group, wherein the core is a polyol residue, and wherein the polymer segments comprise one or more NMP-polymerizable monomers. In some aspects, the present disclosure pertains to a multifunctional alkoxyamine molecule comprising a core and a plurality of alkoxyamine groups covalently attached to the core, wherein the core is a polyol residue. 1. A multi-arm polymer comprising a core and a plurality of polymer segments having a first end that is covalently attached to the core and a second end comprising a moiety that comprises a reactive group , wherein the polymer segments comprise one or more hydrophilic aprotic NMP-polymerizable monomers , and wherein the multi-arm polymer comprises nitroxide radicals.2. The multi-arm polymer of claim 1 , wherein the core is selected from a polyol residue and a silsesquioxane core.3. The multi-arm polymer of claim 1 , wherein the reactive group is an electrophile or a nucleophile.4. The multi-arm polymer of claim 1 , wherein the moiety that comprises a reactive group further comprises a hydrolysable ester group.5. A system comprising (a) a first composition comprising a multi-arm polymer in accordance with and (b) a second composition comprising a multifunctional compound that comprises functional groups that are reactive with the reactive groups of the multi-arm polymer.6. The system of claim 5 , further comprising a delivery device.7. A crosslinked reaction product of (a) a multi-arm polymer in accordance with and (b) a ...

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Номер записи: 25
28-02-2019 дата публикации

AMPHIPHILIC BRANCHED POLYDIORGANOSILOXANE MACROMERS

Номер: US20190062485A1
Автор: Chang Frank, Holland Troy Vernon, HUANG JINYU
Принадлежит:

The invention provides a class of amphiphilic branched macromers and the uses thereof. An amphiphilic branched polydiorganosiloxane macromer of the invention is produced from an α,ω-dimethacryloyl-terminated polydiorganosiloxane vinylic crosslinker comprising one or more ATRP-containing siloxane units having one substituent having an ATRP initiator by ATRP polymerization of one or more hydrophilic vinylic monomers. It comprises at least two polydiorganosiloxane polymer chains each having at most two terminal methacryloxy groups, dangling hydrophilic polymer chains each having a polymerizable or non-polymerizable terminal group, and one or more hydrophilic polymer chains as linkages between two polydiorganosiloxane chains. The present invention is also related to a silicone hydrogel contact lens, which comprises units derived from a polydiorganosiloxane-containing amphiphilic branched macromer of the invention. 14-. (canceled)5. A silicone hydrogel contact lens , comprising a crosslinked polymeric material which comprises units of an amphiphilic branched polydiorganosiloxane macromer , wherein the amphiphilic branched polydiorganosiloxane macromer comprises:(1) at least first polydiorganosiloxane polymer chain having two terminal methacryloyl groups; and(2) at least one first hydrophilic chain;(3) at least one second hydrophilic polymer chain; and(4) at least one second polydiorganosiloxane polymer chain at least one end of which is covalently connected to the second hydrophilic polymer chain,wherein the first and second polydiorganosiloxane chains are derived from an α,ω-dimethacryloyl-terminated polydiorganosiloxane vinylic crosslinker comprising one or more ATRP-containing siloxane units having one substituent having an ATRP initiator,wherein the first hydrophilic chain is anchored covalently onto one single ATRP-containing siloxane unit of the first or second polydiorganosiloxane chain at one of the two ends of the first hydrophilic polymer chain and has one ...

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Номер записи: 26
27-02-2020 дата публикации

Polyorganosiloxane-containing-rubber latex and production method therefor, polyorganosiloxane-containing-rubber-grafted polymer, powder, resin composition, and molded object

Номер: US20200062946A1
Автор: Ayako Shimonaka, Hiroshi Niino, Shinji Matsuoka, Yuichiro Fujikawa
Принадлежит: Mitsubishi Chemical Corp

An object of the present invention is to provide an impact modifier that provides impact resistance to a molded object obtained by molding a resin composition such as polycarbonate at a high temperature, and exhibits more excellent heat stability (preservation of mechanical properties after a wet heat test, discoloration, and flame retardance), and a thermoplastic resin composition including the impact modifier. The polyorganosiloxane-containing-rubber latex, in which a total amount of sulfate ions and sulfonate ions included in 100 g of the solid content is 2.4 mmol or less, a powder thereof, and a resin composition including the powder and a resin. Further, a molded object thereof and a production method therefor are provided.

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Номер записи: 27
11-03-2021 дата публикации

ONE-POT PROCESS OF MAKING SILICONE-ACRYLIC HYBRID PRESSURE SENSITIVE ADHESIVE COMPOSITIONS

Номер: US20210070910A1
Автор: Liu Yuxia
Принадлежит:

The invention related to a one-pot process of making a single-phase silicone-acrylic hybrid adhesive composition comprising acrylic polymer and silicone polymer that are covalently bonded through a —Si—O—Si— linkage. The acrylic polymer contains at least one hydrolyzable silane (meth)acrylic monomer or siloxane (meth)acrylic macromer. These functional moieties provide reaction sites to form —Si—O—Si— bond by reacting hydrolyzable groups in the silicone polymer in the presence of a base or acid catalyst and water. The formed covalent bonds between the two incompatible systems of silicone polymer and acrylic polymer prevents phase separation and thereby a permanent, homogeneous single-phase system is formed. 1: A one-pot process of making a single-phase silicone-acrylic hybrid composition comprising the steps of:(a) making an acrylic polymer solution by a free radical polymerization in an organic solution;(b) adding (i) a silicone polymer and (ii) a catalyst to the acrylic polymer solution and reacting to form a silicone-acrylic hybrid solution;(c) neutralizing the silicone-acrylic hybrid solution with a neutralization reagent, wherein the ratio of the silicone polymer and the acrylic polymer is from 50:1 to 1:50,', 'wherein the silicon-acrylic hybrid composition comprises —Si—O—Si— covalent bond linkages between the silicone polymer and the acrylic polymer., '(d) filtering any solid precipitates from the silicone-acrylic hybrid solution to form a single-phase silicone acrylic hybrid composition in solution;'}2: A one-pot process of making a single-phase silicone-acrylic hybrid composition comprising the steps of: (i) a mixture of monomers, wherein at least one monomer comprises a hydrolyzable silane (meth)acrylic monomer and/or a siloxane (meth)acrylic macromer,', '(ii) a free radical initiator,', '(iii) an organic solvent,, '(a) making an acrylic polymer solution by polymerizingwherein the reaction temperature is from about 50 to about 150° C., and reaction time is ...

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Номер записи: 28
25-03-2021 дата публикации

Flexible and foldable abrasion resistant photopatternable siloxane hard coat

Номер: US20210087429A1
Автор: Gordon Graeme, Hadzic Admir, Hannu-Kuure Milja, Järvitalo Henna, Kãrkkãinen Ari, Kuvaja Rauna-Leena, Leivo Jarkko, Leppäjärvi Tiina
Принадлежит:

A layered structure comprising a substrate layer; and a layer of a siloxane polymer on the substrate layer, the layered structure being capable of being bent about a mandrel having a radius of curvature without breaking. The layer of the siloxane polymer has a thickness of 1 to 50 μm, in particular about 5 to 20 μm, and it is obtained by depositing on the substrate a composition comprising at least three different silane monomers, including at least one bi-silane; at least one of the silane monomers having an active group capable of achieving cross-linking to adjacent siloxane polymer; at least partially hydrolyzing the silane monomers to form siloxane polymer chains; and cross-linking the siloxane polymer chains so as to achieve a cross-linked siloxane polymer layer on the substrate. 2. The structure of claim 1 , wherein the layer of the siloxane polymer is deposited upon a laminar substrate layer having two opposite sides claim 1 , to form a coated substrate layer having a silicon coating on one or on both opposite sides thereof.3. The structure according to or claim 1 , wherein the layer of the siloxane polymer has a thickness of 1 to 50 μm claim 1 , in particular about 5 to 20 μm.4. The structure according to any of the preceding claims claim 1 , wherein the substrate has a thickness of about 10 to 250 μm claim 1 , in particular 20 to 150 μm for example 25 to 100 μm.5. The structure according to any of the preceding claims claim 1 , wherein the substrate is capable of being bent about a mandrel having a first minimum radius of curvature without breaking claim 1 , and the layered structure being capable of being bent about a mandrel having a second minimum radius of curvature without breaking claim 1 , said first minimum radius being smaller or equal to the second minimum radius of curvature.6. The structure according to any of the preceding claims claim 1 , wherein the substrate has thickness of about 10 to 250 μm claim 1 , in particular 20 to 150 μm for example ...

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Номер записи: 29
25-03-2021 дата публикации

Thiol-acrylate polymers, methods of synthesis thereof and use in additive manufacturing technologies

Номер: US20210088898A1
Автор: Amy Nguyen, Benjamin Lund, Caleb LUND, Crystal NIERMANN, Daniel ZAMORANO, Jesse HUFFSTETLER, Sushanta Das, Walter Voit, Yili WU
Принадлежит: Adaptive 3D Technologies LLC, University of Texas System

The present disclosure relates to thiol-acrylate photopolymerizable resin compositions. The resin compositions may be used for additive manufacturing. One embodiments of the invention includes a photopolymerizable resin for additive manufacturing in an oxygen environment, the resin comprising: a crosslinking component; at least one monomer and/or oligomer; and a chain transfer agent comprising at least one of a thiol, a secondary alcohol, and/or a tertiary amine, wherein the resin may be configured to react by exposure to light to form a cured material.

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Номер записи: 30
21-03-2019 дата публикации

Siloxane monomer, composition for preparation of silicone hydrogel lens containing same, and silicone hydrogel lens

Номер: US20190085000A1
Автор: Dong Hun Shin, Kyung Hee Oh, Sang Il Hyun, Soo Chang Lee
Принадлежит: Interojo Inc

The present invention relates to a siloxane monomer used in the production of a silicone hydrogel lens, a composition for the preparation of a lens containing the same, and a silicone hydrogel lens prepared from the same, wherein the silicone hydrogel lens according to the present invention has a feature of easy release from a component of a mold.

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Номер записи: 31
12-05-2022 дата публикации

DUAL CURE RESIN FOR THE PRODUCTION OF MOISTURE-RESISTANT ARTICLES BY ADDITIVE MANUFACTURING

Номер: US20220145019A1
Автор: Grover Ikpreet S., Menyo Matthew S.
Принадлежит:

Provided herein is a dual cure resin useful for the production of objects by stereolithography, said resin comprising a mixture of: (a) a light-polymerizable component; and (b) a heat-polymerizable component, said heat-polymerizable component comprising: (i) a dicyclopentadiene-containing polyepoxide resin; (ii) a cyanate ester resin; (iii) an epoxy-reactive toughening agent; and (iv) a core shell rubber toughener. 1. A dual cure resin useful for the production of objects by stereolithography , said resin comprising a mixture of:(a) a light-polymerizable component; and (i) a dicyclopentadiene-containing polyepoxide resin;', '(ii) a cyanate ester resin;', '(iii) an epoxy-reactive toughening agent; and', '(iv) a core shell rubber toughener., '(b) a heat-polymerizable component, said heat-polymerizable component comprising2. The dual cure resin of claim 1 , wherein said core shell rubber toughener comprises a polybutadiene core.3. The dual cure resin of claim 1 , wherein said cyanate ester resin comprises a bisphenol cyanate ester (e.g. claim 1 , bisphenol E or bisphenol A cyanate ester).5. The dual cure resin of claim 1 , wherein said light-polymerizable component comprises:(i) a light polymerizable monomer; and(ii) a photoinitiator.6. The dual cure resin of claim 5 , wherein the light polymerizable monomer comprises an acrylate or a methacrylate (e.g. a urethane acrylate or methacrylate).7. The dual cure resin of claim 1 , wherein said dual cure resin is homogeneous.8. The dual cure resin of claim 1 , wherein said dual cure resin is nonaqueous.9. A method of making a three-dimensional object claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(a) producing an intermediate three-dimensional object from a dual cure resin of by light polymerization of said resin in an additive manufacturing process;'}(b) optionally cleaning said intermediate object; and then(c) heating and/or microwave irradiating said intermediate three-dimensional object to produce ...

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Номер записи: 32
06-04-2017 дата публикации

Methods of Preparing Compositions for Containers and Other Articles and Methods of Using Same

Номер: US20170096521A1
Автор: "OBrien Robert M.", Deng Lan, Evans Richard H, Niederst Jeffrey, Prouvost Benoit, Romagnoli Kevin, Santure David J., Von Maier Mark S.
Принадлежит: Valspar Sourcing, Inc.

This invention provides a polymer, which is preferably a polyether polymer. The polymer may be uses in coating compositions. Containers and other articles comprising the polymer and methods of making such containers and other articles are also provided. The invention further provides compositions including the polymer (e.g., powder coatings), which have utility in a variety of coating end uses, including, for example, valve and pipe coatings. 3. The method of claim 2 , wherein the catalyst has a pka of at least 9.4. The method of claim 2 , wherein the catalyst comprises a polycyclic amidine base catalysts or an azabicycloalkane or mixtures thereof.5. The method of claim 4 , wherein the catalyst is selected from the group consisting of 1 claim 4 ,5 claim 4 ,7-Triazabicyclo(4.4.0)dec-5-ene; 7-Methyl-1 claim 4 ,5 claim 4 ,7-triazabicyclo(4.4.0)dec-5-ene; 1 claim 4 ,8-diazabicyclo[5.4.0]undec-7-ene; 1 claim 4 ,5-diazabicyclo[4.3.0]non-5-ene; 1-Azabicyclo[2.2.2]octane; and similar compounds.6. The method of claim 2 , wherein the catalyst is present in an amount of from 0.01 to 1% by weight claim 2 , based on the total polymer weight.7. The method of claim 2 , wherein the reaction is carried out at a temperature between 120 and 200° C. for less than 24 hours.8. The method of claim 2 , wherein the polyether polymer includes at least 45% by weight of phenylene groups and has a glass transition temperature of at least 60° C.9. The method of claim 2 , wherein the phenol compound comprises a phenol of Formula (III) claim 2 , and wherein t and n are each 1 and Ris an organic group having 8 or more carbon atoms.10. The method of claim 2 , wherein the phenol compound comprises a phenol of Formula (III) claim 2 , and wherein t and n are each 1 and each depicted hydroxyl group in Formula (III) is located at a para position relative to R.11. The method of claim 2 , wherein the phenol compound comprises a phenol of Formula (III) claim 2 , and wherein the phenol of Formula (III) has ...

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Номер записи: 33
14-04-2016 дата публикации

Silicone hydrogels having desirable water content and oxygen permeability

Номер: US20160103248A1
Автор: Azaam Alli, James D. Ford, Scott L. Joslin
Принадлежит: Johnson and Johnson Vision Care Inc

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.

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Номер записи: 34
26-04-2018 дата публикации

Amphiphilic branched polydiorganosiloxane macromers

Номер: US20180113237A1
Автор: Fei Cheng, Feng Jing, Frank Chang, Ying Zheng
Принадлежит: NOVARTIS AG

The invention provides a class of amphiphilic branched polydiorganosiloxane macromers and the uses thereof. Such a macromer comprises a polydiorganosiloxane polymer chain and two terminal groups free of any ethylenically unsaturated group, wherein the polydiorganosiloxane polymer chain comprises (1) at least 5 dimethylsiloxane units in a consecutive sequence, (2) at least two first siloxane units each having methyl as one of the two substituents of each first siloxane unit and one first first organic radical having one sole (meth)acryloyl group as the other substituent, (3) at least one second siloxane unit having methyl as one of the two substituents of the second siloxane unit and one second organic radical, which is free of any ethylenically unsaturated group and comprises one or more hydrophilic groups or polymer chains, as the other substituent.

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Номер записи: 35
27-04-2017 дата публикации

Silicone hydrogels having a structure formed via controlled reaction kinetics

Номер: US20170114174A1
Автор: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin
Принадлежит: Johnson and Johnson Vision Care Inc

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.

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Номер записи: 36
16-04-2020 дата публикации

WATER SWELLABLE CROSSLINKED ELASTOMER AND METHOD OF PREPARATION

Номер: US20200113812A1
Автор: Falk Benjamin, Kumar Mukesh, Pawar Amar
Принадлежит:

A water swellable cross-linked elastomer and method of preparation is provided. The elastomer can advantageously be included in skin treatment compositions. Swellable elastomers in accordance with the invention are particularly well suited for inclusion in skin tightening cosmetic products. The elastomers can be formulated to form a film. When applied to skin, an elastomer in accordance with preferred embodiments of the invention can adhere to the skin and shrink as it dries. This can provide a skin tightening, lifting and wrinkle smoothening effect upon drying. This effect can temporarily mask the appearance of wrinkles. 1. A cosmetically acceptable composition , comprising a water swellable cross linked polyacrylate elastomer containing at least one phosphate or phosphonate moiety , the elastomer formulated and adapted such that after the composition has been applied to a keratinous substrate in a water swelled condition , upon drying from the water swelled condition , the elastomer adheres to the substrate , shrinks and as it shrinks , provides tightening and smoothening of the substrate to which the composition had been applied.5. The cosmetically acceptable composition of claim 1 , wherein the elastomer includes about 0.01 wt %-40 wt % of the phosphate moiety.6. The cosmetically acceptable composition of claim 1 , wherein the elastomer includes about 2 wt %-15 wt % of the phosphate moiety.7. The water swellable elastomer of claim 1 , wherein the elastomer comprises moieties having the general formulae (I) claim 1 , (II) claim 1 , (III) or (IV).8. The cosmetically acceptable composition of claim 1 , wherein when undisturbed claim 1 , at least about 75 wt % of the elastomer film will remain as a film on the substrate claim 1 , without forming flakes claim 1 , after six hours.9. The cosmetically acceptable composition of claim 1 , wherein the tightening applied to the keratinous substrate urges a smoothening of the keratinous substrate.10. The cosmetically ...

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Номер записи: 37
04-05-2017 дата публикации

Method for Obtaining a Hybrid Latex and Use Thereof in Hydrophobic and Superhydrophobic Coatings

Номер: US20170121442A1
Автор: GALVAN-MIYOSHI Julian Masasue, Ming Weihua, PEZZOTTI-ROBLETO Fabio, ZHANG Quanyuan
Принадлежит:

The present invention relates to a siliconized hybrid latex that consists of a polysiloxane methacrylic copolymer of the formula (I), starting with at least one methacrylic monomer that is partially soluble in water, and at least one functionalised silicone-based macromonomer that is insoluble in water and highly hydrophobic, and to the use of said latex in a water-based formula, free of fluorinated compounds, generating highly hydrophobic or superhydrophobic surfaces with self- or easy-cleaning properties. 2. The hybrid silicone latex according to claim 1 , wherein the methacrylic monomer is selected from the group consisting of methylmethacrylate claim 1 , buthylmethacrylate claim 1 , methacrylic acid or mixtures thereof.3. The hybrid silicone latex according to claim 1 , wherein the functionalized silicone macromonomer is polydimethylsiloxane (PDMS).4. The hybrid silicone latex according to claim 1 , wherein the functionalized silicone macromonomer has a methacrylic functionality.5. The hybrid silicone latex according to claim 1 , wherein the functionalized silicone macromonomer has a molecular weight between 3 claim 1 ,000 and 15 claim 1 ,000 g/mol claim 1 , preferably between 5 claim 1 ,000 and 10 claim 1 ,000 g/mol .6. The hybrid silicone latex according to claim 1 , wherein the methacrylic monomer is present in an amount between 8 and 18% by weight of the total reaction mixture.7. The hybrid silicone latex according to claim 1 , wherein the functionalized silicone macromonomer and the methacrylic monomer are present in a weight ratio of 1:9 to 7:3.9. The method to obtain a hybrid silicone latex according to claim 8 , wherein the polymerization reaction is carried out via miniemulsion polymerization without the use of cosolvents claim 8 , stabilizing agents or hydrophobes.10. The method to obtain a hybrid silicone latex according to claim 8 , wherein the methacrylic monomer is selected from the group consisting of methylmethacrylate claim 8 , ...

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Номер записи: 38
25-08-2022 дата публикации

AQUEOUS DISPERSION OF POLYMERIC COMPOSITE MICROSPHERES

Номер: US20220267498A1
Автор: Eryazici Ibrahim, Grant Joseph, Katzenstein Joshua M., Liu Yihan, Nungesser Edwin A., Zimmerman Brett L.
Принадлежит:

The present invention relates to a composition comprising an aqueous dispersion of polymeric composite microspheres comprising an aqueous dispersion of polymeric composite microspheres that comprise a polysiloxane and a polymer, as defined herein, and a suspension polymerization process for making the composition. The composition is useful for making defect free coatings with a relatively low coefficient of friction. 3. The process of wherein each Ris methyl.5. The process of wherein the first stage monomers further comprise from 0.1 to 15 weight percent claim 4 , based on the weight of first stage monomers claim 4 , of a multiethylenically unsaturated nonionic monomer.6. The process of wherein the first composite microspheres are prepared by contacting under polymerization conditions an aqueous dispersion of a polysiloxane and a first monoethylenically unsaturated monomer.7. The process of wherein the dispersion of second composite microspheres is further reacted with a second stage monoethylenically unsaturated nonionic monomer claim 5 , in the presence of a water-soluble initiator/redox couple.8. The process of which further comprises the step of contacting the aqueous dispersion of composite microspheres with one or more components selected from the group consisting of binders claim 1 , thickeners claim 1 , pigments claim 1 , biocides claim 1 , solvents claim 1 , dispersants claim 1 , coalescents claim 1 , opaque polymers claim 1 , and extenders. The present invention relates to an aqueous dispersion of polymeric composite microspheres that comprise a polysiloxane and a polymer. The composite microspheres are useful for preparing formulations that form defective free coatings with a low coefficient of friction.Low-gloss (matte, low-sheen) surfaces can be made applying to a substrate an aqueous dispersion containing organic or inorganic matting agents as well as binders. Organic non-film-forming matting agents in the range of 1-30 μm are preferred in part because ...

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Номер записи: 39
25-08-2022 дата публикации

BIOMEDICAL DEVICES CONTAINING INTERNAL WETTING AGENTS

Номер: US20220268966A1
Автор: Alli Azaam, Ford James D., Hill Gregory A., JR. Frank F., McCabe Kevin P., Molock, Steffen Robert B., Vanderlaan Douglas G.
Принадлежит:

This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer. 1137-. (canceled)138. An ophthalmic device comprising at least one hydroxyl-functionalized silicone-containing monomer and an amount of high molecular weight hydrophilic polymer sufficient to provide said device , without a surface treatment , with tear film break up time after about one day of wear of at least about 7 seconds.139162-. (canceled) This patent application claims priority of a provisional application, U.S. Ser. No. 60/318,536 which was filed on Sep. 10, 2001.This invention relates to silicone hydrogels that contain internal wetting agents, as well as methods for their production and use.Contact lenses have been used commercially to improve vision since at least the 1950s. The first contact lenses were made of hard materials and as such were somewhat uncomfortable to users. Modern lenses have been developed that are made of softer materials, typically hydrogels and particularly silicone hydrogels. Silicone hydrogels are water-swollen polymer networks that have high oxygen permeability and surfaces that are more hydrophobic than hydrophilic. These lenses provide a good level of comfort to many lens wearers, but there are some users who experience discomfort and excessive ocular deposits leading to reduced visual acuity when using these lenses. This discomfort and deposits has been attributed to the hydrophobic character of the surfaces of lenses and the interaction of those surfaces with the protein, lipids and mucin and the hydrophilic surface of the eye.Others have tried to alleviate this problem by coating the surface of silicone hydrogel contact lenses with hydrophilic coatings, such as plasma coatings Uncoated lenses having low incidences of surface deposits are not disclosed.Incorporating internal hydrophilic agents (or wetting agents) into a macromer containing reaction mixture has ...

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Номер записи: 40
27-05-2021 дата публикации

AQUEOUS POLYMER DISPERSION AND PREPARATION METHOD THEREOF

Номер: US20210155721A1
Автор: Deng Rui, Wiese Harm, ZENG Zhong
Принадлежит:

The present invention relates to an aqueous polymer dispersion containing a multistage emulsion polymer particle. The multistage emulsion polymer particle contains a polysiloxane formed in the first stage; a transition layer formed in the second stage; and a polyacrylate formed in the third stage. The transition layer is made of silane coupling agents. The present invention also relates to a method of preparing the aqueous polymer dispersion and use of the aqueous polymer dispersion for preparing coatings. 1. An aqueous polymer dispersion , comprising a multistage emulsion polymer particle , said multistage emulsion polymer particle comprises:(1) a polysiloxane formed in the first stage;(2) a transition layer formed in the second stage; and(3) a polyacrylate formed in the third stage;wherein the transition layer is made of silane coupling agents.2. The aqueous polymer dispersion according to claim 1 , wherein the multistage emulsion polymer particle has a core/shell structure with the polysiloxane as core and the polyacrylate as shell.3. The aqueous polymer dispersion according to claim 2 , wherein the transition layer is positioned between the polysiloxane core and the polyacrylate shell.4. The aqueous polymer dispersion according to claim 1 , wherein the polysiloxane is prepared from siloxane monomer represented by formula (I) and optionally vinyl monomer:{'br': None, 'sup': 1', '2, 'sub': 'n', '[Si(RR)O],\u2003\u2003(I)'}{'sup': 1', '2, 'sub': 1', '20', '2', '20, 'wherein n=3, 4, 5, 6, or 7, Rand Rare independently —H, C-Calkyl, C-Calkenyl, or aryl.'}5. The aqueous polymer dispersion according to claim 4 , wherein the siloxane monomer is selected from the group consisting of hexamethyl cyclotrisiloxane claim 4 , octamethyl cyclotetrasiloxane claim 4 , decamethyl cyclopentasiloxane claim 4 , and any combination thereof.6. The aqueous polymer dispersion according to claim 1 , wherein the silane coupling agents are represented by formula (II):{'br': None, 'sup': 3', ...

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Номер записи: 41
10-05-2018 дата публикации

Polyorganosiloxane-Containing Graft Copolymer, Thermoplastic Resin Composition, and Molded Product

Номер: US20180127579A1
Автор: Wakita Ayaka
Принадлежит: MITSUBISHI CHEMICAL CORPORATION

A resin composition having all of higher pigment colorability, low-temperature impact resistance, and flame retardance is provided. A graft copolymer is a polyorganosiloxane-containing graft copolymer formed by polymerizing one or more grafting vinyl monomers (b) in the presence of a rubber (A) containing polyorganosiloxane and a vinyl polymer, wherein the index of refraction of the rubber (A) is in the range of 1.47 to 1.56, and the volume-average particle size is in the range of 300 nm to 2000 nm. A resin composition contains the graft copolymer and a resin. 213-. (canceled)14. A thermoplastic resin composition claim 1 , comprising the polyorganosiloxane-containing graft copolymer according to and a thermoplastic resin.15. The thermoplastic resin composition according to claim 14 , wherein the polyorganosiloxane-containing graft copolymer is present in an amount of 0.5 mass % to 90 mass % based on 100 mass % of the thermoplastic resin composition.16. The thermoplastic resin composition according to claim 14 , wherein the thermoplastic resin is a polycarbonate resin.17. A molded product obtained by molding the thermoplastic resin composition according to . The invention relates to a polyorganosiloxane-containing graft copolymer capable of increasing low-temperature impact resistance of a thermoplastic resin composition obtained via addition in a thermoplastic resin and capable of achieving high pigment colorability and flame retardance of a molded product obtained from the thermoplastic resin composition. Moreover, the invention relates to a thermoplastic resin composition having high low-temperature impact resistance, pigment colorability, and flame retardance and a molded product thereof.The aromatic polycarbonate resin is used as an engineering plastic and is excellent in, for instance, transparency, impact resistance, thermal resistance, and dimensional stability, and the aromatic polycarbonate resin is extensively applied in industries as a material in, for ...

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Номер записи: 42
11-05-2017 дата публикации

SILICONE HYDROGELS FORMED FROM ZERO DILUENT REACTIVE MIXTURES

Номер: US20170129983A1
Автор: Alli Azaam, Ford James D., Joslin Scott L., Vanderlaan Douglas G.
Принадлежит:

The present invention relates to silicone hydrogels having a desirable balance of properties which can be formed without diluents. The silicone hydrogels are formed from reactive mixtures comprising at least one hydroxyl substituted, monofunctional polydialkylsiloxane monomer having between 2 and 120 dialkylsiloxane repeating units, at least one slow reacting hydrophilic monomer and at least one hydroxyl containing hydrophilic monomer. 1. A silicone hydrogel comprising about 8 to about 17 wt % silicon , an advancing dynamic contact angle of less than about 80° without surface modification formed from a reactive mixture comprisingat least one monofunctional polydialkylsiloxane monomer having between 7 and 120 dialkylsiloxane repeating units and which may be optionally substituted with at least one hydroxyl group;optionally one or more monofunctional, hydroxyl-containing siloxane monomer having less than 7 dialkylsiloxane repeating units, trialkyl siloxane groups or a combination thereof; with the proviso that if said monofunctional polydialkylsiloxane does not comprise at least one hydroxyl at least one monofunctional, hydroxyl-containing siloxane monomer is included;about 40-about 60 wt % of at least one slow reacting hydrophilic monomer;at least one hydroxyl containing hydrophilic monomer, wherein the molar ratio of hydroxyl containing components to the slow reacting hydrophilic monomer is between about 0.15 to about 0.4, wherein the reactive mixture is free of diluent.2. (canceled)3. The silicone hydrogel of comprising between about 8 to about 15 wt % silicon.4. The silicone hydrogel of wherein said monofunctional siloxane monomer comprises 7 to 60 dialkylsiloxane repeating units.5. The silicone hydrogel of wherein said monofunctional siloxane monomer comprises 7 to 30 dialkylsiloxane repeating units.6. The silicone hydrogel of wherein said monofunctional siloxane monomer comprises one or two hydroxyl groups.7. The silicone hydrogel of wherein said hydroxyl are ...

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Номер записи: 43
01-09-2022 дата публикации

VINYL ACETATE-SILICONE COPOLYMER RESIN AND METHOD FOR PRODUCING SAME

Номер: US20220275134A1
Автор: Uchida Koki, Watanabe Kentaro
Принадлежит: Nissin Chemical Industry Co., Ltd.

The present invention provides a vinyl acetate-silicone copolymer resin obtained by graft polymerization of vinyl acetate (B) onto an organopolysiloxane (A) represented by a specific general formula, wherein a weight ratio of the organopolysiloxane (A) to the vinyl acetate (B) is (A):(B)=10:90 to 95:5, a method for producing the same, and a vinyl acetate-silicone copolymer resin composition. The vinyl acetate-silicone copolymer resin of the present invention has slidability, substrate adhesiveness, and organic solvent solubility, and is suitably used for coating agents for various substrates, adhesive agents, exterior and interior paints for structures and building materials and the like, and cosmetics and the like. 2. The vinyl acetate-silicone copolymer resin according to claim 1 , wherein the vinyl acetate-silicone copolymer resin is an emulsion having a viscosity (25° C.) of 1 to 500 mPa s.3. The vinyl acetate-silicone copolymer resin according to claim 1 , wherein the organopolysiloxane as the component (A) has a weight average molecular weight (Mw) of 10 claim 1 ,000 to 1 claim 1 ,000 claim 1 ,000 as obtained by viscosity measurement.6. A vinyl acetate-silicone copolymer resin composition comprising the vinyl acetate-silicone copolymer resin according to claim 1 ,wherein the vinyl acetate-silicone copolymer resin composition is used as a product selected from the group consisting of a coating agent, a fiber treatment agent, an adhesive agent, a paint, and a cosmetic. This non-provisional application claims priority under 35 U.S.C. § 119(a) on Patent Application No. 2021-030514 filed in Japan on Feb. 26, 2021, the entire contents of which are hereby incorporated by reference.The present invention relates to a resin obtained by copolymerizing an organopolysiloxane with vinyl acetate and a method for producing the same, and more specifically, to a vinyl acetate-silicone copolymer resin having slidability, substrate adhesiveness, and organic solvent solubility and ...

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Номер записи: 44
19-05-2016 дата публикации

POLYORGANOSILOXANE-CONTAINING GRAFT COPOLYMER, THERMOPLASTIC RESIN COMPOSITION, AND MOLDED PRODUCT

Номер: US20160137836A1
Автор: Wakita Ayaka
Принадлежит: MITSUBISHI RAYON CO., LTD.

A resin composition having all of higher pigment colorability, low-temperature impact resistance, and flame retardance is provided. A graft copolymer is a polyorganosiloxane-containing graft copolymer formed by polymerizing one or more grafting vinyl monomers (b) in the presence of a rubber (A) containing polyorganosiloxane and a vinyl polymer, wherein the index of refraction of the rubber (A) is in the range of 1.47 to 1.56, and the volume-average particle size is in the range of 300 nm to 2000 nm. A resin composition contains the graft copolymer and a resin. 1. A polyorganosiloxane-containing graft copolymer , wherein ,{'sup': '2', '“test piece 1”, “test piece 2”, or “test piece 3” made according to the following “manufacturing conditions” are measured for Charpy impact strength [kJ/m], L*, and flame retardance under the following “measurement conditions” and have the following properties described in (1) to (3),'}{'sup': '2', '[(1) the Charpy impact strength at −30° C. is 20 kJ/mor more,'}(2) L* is 8 or less,(3) the flame retardance is V1 or V0;[manufacturing conditions of test piece 1 and test piece 2]:(a) the polyorganosiloxane-containing graft copolymer is 3 parts by mass,(b) an aromatic polycarbonate resin having a viscosity-average molecular weight of 24,000 (Iupilon S-2000F made by Mitsubishi Engineering-Plastics Corporation) is 97 parts by mass,(c) Irganox 1076 (made by BASF) is 0.1 parts by mass,(d) ADK STAB 2112 (made by ADEKA) is 0.1 parts by mass,(e) carbon black #960 (made by Mitsubishi Chemical Corporation) is 0.1 parts by mass,prepare the 5 materials (a) to (e), then perform mixing and extrusion under a condition of a screw rotation speed of 150 rpm via a devolatilizing extruder (PCM-30 made by IKEGAI Ltd.) heated to a roller temperature of 280° C. to obtain particles, and then mold the particles via a 100 t injection molding machine (SE-100DU made by Sumitomo Heavy Industries, Ltd.) under conditions of a barrel temperature of 280° C. and a mold ...

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Номер записи: 45
18-05-2017 дата публикации

Copolymerized high temperature bonding component

Номер: US20170137575A1
Автор: Jennifer Y. Sun, Sumanth Banda
Принадлежит: Applied Materials Inc

A bonding component includes a first amount of an organofluorine polymer and a second amount of an organosilicon polymer which are chemically bound to each other and form a copolymer.

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Номер записи: 46
10-06-2021 дата публикации

Two-part epoxy based composition

Номер: US20210171694A1
Автор: Che AiFu, Chen Chunfu, Li Bin, Wang Chao
Принадлежит:

This invention relates to a two-part epoxy based composition, comprising a first part comprising at least one epoxy resin; a second part comprising at least one epoxy resin curing agent, and at least one acrylamide compound containing a hydrogen atom bound to the nitrogen atom in the acrylamide structure. The two-part epoxy based composition according to the present invention exhibits excellent adhesion strength to low surface tension substrates, such as stainless steel and PVC. 2. The two-part epoxy based composition according to claim 1 , wherein the epoxy resin comprises at least two epoxy groups per molecule.3. The two-part epoxy based composition according to claim 1 , wherein the epoxy resin curing agent is selected from at least one of polyamide claim 1 , amine claim 1 , imidazole and the derivatives thereof.4. The two-part epoxy based composition according to claim 1 , wherein at least one of R claim 1 , Rand Rin the general formula (1) contains a tertiary amino group.6. The two-part epoxy based composition according to claim 5 , wherein Rand Rin the general formula (2) are preferably optionally substituted Cto Cunivalent organic groups.7. The two-part epoxy based composition according to claim 1 , wherein the amount of the acrylamide compound represented by the general formula (1) is from 30 to 90% claim 1 , and preferably from 50 to 70% by weight based on the total weight of the second part.9. The two-part epoxy based composition according to claim 1 , the weight ratio between the first part and the second part is from 20:1 to 1:1 claim 1 , preferably from 10:1 to 1.5:1 claim 1 , and more preferably from 2:1 to 1.5:1.10. A cured product of the two-part epoxy based composition according .11. An article bonded by the two-part epoxy based composition according to . This invention relates to a two-part epoxy based composition, comprising a first part comprising at least one epoxy resin; a second part comprising at least one epoxy resin curing agent, and at ...

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Номер записи: 47
16-05-2019 дата публикации

Furan-modified compound and oligomer

Номер: US20190144410A1
Автор: Feng-Po Tseng, Kuei-Yi CHUANG, Kuo-Chan Chiou
Принадлежит: Industrial Technology Research Institute ITRI

The invention provides a furan-modified compound or oligomer. The compound has a structure represented by Formula I: When formula I represents a compound, x is an integer of 1˜5; A including a group formed of ketone, amido, imide, imido, phenyl ether or enol ether group; G is a direct bond, —O—, —N—, —Ar—NH—(CH 2 ) b —, —Ar—O—(CH 2 ) b —, —Ar—O—(CH 2 ) a —NH—(CH 2 ) b —, —(CH 2 ) a —NH—(CH 2 ) b —, —(CH 2 ) a —O—(CH 2 ) b — or —(CH 2 ) a —CH(OH)—(CH 2 ) b —NH—; Ar is substituted or unsubstituted arylene group; a is an integer of 1 to 5; and b is an integer of 0 to 5.

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Номер записи: 48
07-05-2020 дата публикации

COPOLYMERIZED HIGH TEMPERATURE BONDING COMPONENT

Номер: US20200140620A1
Автор: Banda Sumanth, Sun Jennifer Y.
Принадлежит:

A method for preparing a bonding component comprises mixing a first solution comprising an organofluorine monomer unit with a second solution comprising an organosilicon monomer unit to form, in-situ, a copolymer solution comprising a copolymer of an organofluorine polymer and an organosilicon polymer based on the organofluorine monomer unit and the organosilicon monomer unit. The method further comprises depositing the copolymer solution onto a body to form a film of the copolymer, and curing the film of the copolymer. 1. A method for preparing a bonding component comprising:mixing a first solution comprising an organofluorine monomer unit with a second solution comprising an organosilicon monomer unit to form, in-situ, a copolymer solution comprising a copolymer of an organofluorine polymer and an organosilicon polymer based on the organofluorine monomer unit and the organosilicon monomer unit;depositing the copolymer solution onto a body to form a film of the copolymer; andcuring the film of the copolymer.2. The method of claim 1 , wherein depositing the copolymer solution onto the body comprises performing one of a spin casting claim 1 , drop casting claim 1 , spray coating claim 1 , dip coating or doctor blade technique.3. The method of claim 1 , wherein curing the film of the copolymer comprises using one of temperature claim 1 , UV light source claim 1 , high pressure claim 1 , plasma claim 1 , or a combination thereof.4. The method of claim 1 , wherein the bonding component binds dissimilar materials and is resistant to temperatures up to about 300° C.5. The method of claim 1 , wherein the organofluorine polymer is selected from the group consisting of a fluoropolymer claim 1 , a perfluoropolymer claim 1 , and combinations thereof.6. The method of claim 1 , wherein the organosilicon polymer comprises polydimethyl siloxane.7. The method of claim 1 , wherein the organofluorine polymer and the organosilicon polymer are chemically bound as a block copolymer in ...

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Номер записи: 49
31-05-2018 дата публикации

Bulk Polymerization of Silicone-Containing Copolymers

Номер: US20180148517A1
Автор: Ellis Mark F., Emslander Jeffrey O., Kumar Ramesh C., Mackey Sonja S., Peloquin Richard L., Sherman Audrey A.
Принадлежит:

Methods for preparing silicone-containing polymers by essentially adiabatic polymerization methods are disclosed. The polymerization system includes free radically polymerizable monomers. The monomers include ethylenically unsaturated silicone-containing monomers and/or mercapto-functional silicones as well as additional free radically polymerizable monomers. The silicone-containing polymers are useful as adhesives or release materials. 1. A method comprising: a mercapto-functional silicone;', 'at least one ethylenically unsaturated monomer;', 'a chain transfer agent; and', 'a thermal initiator;, 'providing a first reaction mixture comprisingdeoxygenating the first reaction mixture;heating the first reaction mixture to a temperature above the activation temperature of the thermal initiator;allowing the first reaction mixture to polymerize under essentially adiabatic conditions to yield an at least partially polymerized mixture;cooling the at least partially polymerized mixture;adding an additional thermal initiator to the partially polymerized mixture to form a second reaction mixture;deoxygenating the second reaction mixture;heating the second reaction mixture to a temperature above the activation temperature of the additional thermal initiator;allowing the second reaction mixture to polymerize under essentially adiabatic conditions to form a polymer.2. The method of claim 1 , wherein the mercapto-functional silicone has the structure:{'br': None, 'sup': 1', '2', '5', '6', '3', '4, 'sub': 3-x', 'x', 'y', '3-q', 'q, '(R)(HSR)Si—(OSiRR)—OSi(R)(RSH)'}{'sup': '1', 'wherein each Ris independently an alkyl, aryl, alkaryl, alkoxy, alkylamino, hydroxyl,'}hydrogen, or fluoroalkyl group;{'sup': '2', 'each Ris a divalent linking group;'}{'sup': '3', 'each Ris an alkyl, aryl, alkaryl, alkoxy, alkylamino, hydroxyl, hydrogen, or fluoroalkyl'}group;{'sup': '4', 'each Ris a divalent linking group;'}{'sup': '5', 'each Ris an alkyl, aryl, alkaryl, alkoxy, alkylamino, hydroxyl, ...

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Номер записи: 50
31-05-2018 дата публикации

Bulk Polymerization of Silicone-Containing Copolymers

Номер: US20180148518A1
Автор: Ellis Mark F., Emslander Jeffrey O., Kumar Ramesh C., Mackey Sonja S., Peloquin Richard L., Sherman Audrey A.
Принадлежит:

Methods for preparing silicone-containing polymers by essentially adiabatic polymerization methods are disclosed. The polymerization system includes free radically polymerizable monomers. The monomers include ethylenically unsaturated silicone-containing monomers and/or mercapto-functional silicones as well as additional free radically polymerizable monomers. The silicone-containing polymers are useful as adhesives or release materials. 1. A method comprising: an ethylenically unsaturated silicone-containing monomer;', 'at least one additional ethylenically unsaturated monomer;', 'a chain transfer agent; and', 'a thermal initiator;, 'providing a first reaction mixture comprisingdeoxygenating the first reaction mixture;heating the first reaction mixture to a temperature above the activation temperature of the thermal initiator;allowing the first reaction mixture to polymerize under essentially adiabatic conditions to yield an at least partially polymerized mixture;cooling the at least partially polymerized mixture;adding an additional thermal initiator, and a chain transfer agent to the partially polymerized mixture to form a second reaction mixture;deoxygenating the second reaction mixture;heating the second reaction mixture to a temperature above the activation temperature of the additional thermal initiator;allowing the second reaction mixture to polymerize under essentially adiabatic conditions to form a polymer.2. The method of claim 1 , wherein the ethylenically unsaturated silicone-containing monomer comprises a silicone macromer with the structure:{'br': None, 'sub': n', '3-m', 'm, 'sup': '7', 'W-(A)—Si(R)Q'}wherein W is a vinyl group;A is a divalent linking group;n is zero or 1;{'sup': '7', 'm is an integer of from 1 to 3; Ris hydrogen, alkyl, aryl, or alkoxy; and'}Q is a monovalent siloxane polymeric moiety having a number average molecular weight above about 500 and is essentially unreactive under copolymerization conditions.3. The method of claim 2 , ...

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Номер записи: 51
17-06-2021 дата публикации

POLYSILOXANE COMPOSITION

Номер: US20210179850A1
Автор: NIE Jian, Yang Lei
Принадлежит: Wacker Chemie AG

Viscosity peaking during initial formulation of condensation curing compositions employing silanol-functional organopolysiloxanes and alkoxysilanes is avoided by employing specific titanium compounds. A curing catalyst which may be a titanium compound or a tin compound may be added following disappearance of silanol functionality. 115.-. (canceled)17. The polysiloxane composition of claim 16 , wherein ingredient (a) is employed in an amount of from 10 wt % to 85 wt % and ingredient (c) from 0.01 wt % to 2 wt % claim 16 , based on the total weight of the starting materials of the polysiloxane composition.18. The polysiloxane composition of claim 16 , wherein ingredient (b) is employed in an amount of from 0.5 wt % to 5 wt % and ingredient (c) from 0.01 wt % to 2 wt % claim 16 , based on the total weight of the starting materials of the polysiloxane composition.19. The polysiloxane composition of claim 16 , wherein ingredient (a) contains at least one hydroxyl-terminated polyorganosiloxane having a kinematic viscosity at 25° C. ranging from 1 claim 16 ,000 to 100 claim 16 ,000 mm/s.20. The polysiloxane composition of claim 19 , wherein ingredient (a) is employed in an amount of from 50 wt % to 85 wt % claim 19 , based on the total weight of the starting materials of the polysiloxane composition.21. The polysiloxane composition of claim 16 , wherein ingredient (b) is a vinyl group-containing multifunctional alkoxysilane.22. The polysiloxane composition of claim 16 , wherein in the organotitanium compound of the formula I or II claim 16 , Ror Ris a saturated monovalent hydrocarbon group having from 2 to 4 carbon atoms.23. The polysiloxane composition of claim 16 , wherein in the organotitanium compound of the formula I or II claim 16 , Ror Ris a saturated divalent hydrocarbon group having from 3 to 5 carbon atoms.24. The polysiloxane composition of claim 16 , wherein ingredient (d) is an organotitanium catalyst (d1) or an organotin catalyst (d2).25. The polysiloxane ...

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Номер записи: 52
11-06-2015 дата публикации

Optical element and image display device

Номер: US20150160452A1
Автор: Satoshi Higuchi, Takashi Aridomi, Yuuichi Fukushige
Принадлежит: Fujifilm Corp

An optical element including a cell a cell, the cell including: a first substrate, at least a portion of at least one surface of the first substrate being electroconductive; a second substrate disposed so as to face the electroconductive surface of the first substrate; an electrically non-conductive oil and an electroconductive hydrophilic liquid that are provided between the electroconductive surface of the first substrate and the second substrate; and a hydrophobic insulating film that is provided at at least a portion of the electroconductive surface side of the first substrate, that contacts the oil, and that includes a crosslinked structure derived from a siloxane compound having an unsaturated double bond, the profile of an interface between the oil and the hydrophilic liquid changing according to a voltage applied across the hydrophilic liquid and the electroconductive surface of the first substrate.

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Номер записи: 53
07-06-2018 дата публикации

DIENE/DIENOPHILE COUPLES AND THERMOSETTING RESIN COMPOSITIONS HAVING REWORKABILITY

Номер: US20180155588A1
Автор: CHAMPAGNE Timothy M., Israel Jonathan B., Jordan Benny E., Klemarczyk Philip T., Sridhar Laxmisha M., Zhang XianMan
Принадлежит:

Thermosetting resin compositions are provided that are useful for mounting onto a circuit board semiconductor devices, such as chip size or chip scale packages (“CSPs”), ball grid arrays (“BGAs”), land grid arrays (“LGAs”) and the like (collectively, “subcomponents”), or semiconductor chips. Reaction products of the compositions are controllably reworkable when subjected to appropriate conditions. 124-. (canceled)26. The composition of claim 25 , wherein the curable resin component is a member selected from the group consisting of epoxy claim 25 , episulfide claim 25 , oxetane claim 25 , thioxetane claim 25 , oxazine claim 25 , maleimide claim 25 , itaconamide claim 25 , nadimide claim 25 , (meth)acrylate claim 25 , (meth)acrylamide claim 25 , and combinations thereof.27. The composition of claim 25 , wherein the two reactive groups are the same.28. The composition of claim 25 , wherein the two reactive groups are different.29. The composition of claim 25 , wherein the curative is selected from imidizoles claim 25 , dicyandimide claim 25 , carboxylic acids claim 25 , anhydride claim 25 , phenolic hardeners claim 25 , amines claim 25 , thiols claim 25 , alcohols claim 25 , and alkalines.30. The composition of claim 25 , wherein the diene/dienophile couple is selected from dicyclopentadiene claim 25 , cyclopentadiene-maleimide claim 25 , cyclopentadiene-maleate claim 25 , cyclopentadiene-fumarate claim 25 , cyclopentadiene-(meth)acrylate claim 25 , cyclopentadiene-crotonate claim 25 , cyclopentadiene-cinnamate claim 25 , cyclopentadiene-(meth)acrylamide claim 25 , and furan-maleimide.31. The composition of claim 25 , wherein the diene of the diene/dienophile couple is selected from acyclic 1 claim 25 ,3-diene claim 25 , cyclopentadiene claim 25 , cyclohexadiene claim 25 , furan claim 25 , fulvene claim 25 , pyrrole claim 25 , naphthalene and anthracene.32. The composition of claim 25 , wherein the dienophile of the diene/dienophile couple is selected from ...

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Номер записи: 54
22-09-2022 дата публикации

One component (1k) composition based on epoxy resin

Номер: US20220298283A1
Автор: Chunfu Chen
Принадлежит: Henkel AG and Co KGaA

The present invention is directed to an one-component (1K) composition comprising, based on the weight of the composition: from 40 to 98 wt. % of a) at least one epoxy resin; from 0.5 to 30 wt. % of b) at least one organoboron compound selected from tetrasubstituted borate salts of monovalent cations of tertiary amines; and, from 0.5 to 30 wt. % of c) at least one (meth)acrylamide monomer of Formula (VII): wherein: R a is H or Me; G is selected from —NH 2 , —NHR b and —N(R b )(R c ); R b and R c are independently selected from C 1 -C 18 alkyl, C 1 -C 18 hydroxyalkyl, C 1 -C 18 alkalkoxy, C 6 -C 18 aryl and —(CH 2 ) n —N(R d )(R e ); n is an integer of from 1 to 4; and, R d and R e are independently selected from H and C 1 -C 6 alkyl.

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Номер записи: 55
23-05-2019 дата публикации

REVERSIBLE CROSSLINKING REACTANT COMPOSITION

Номер: US20190153139A1
Автор: CHIOU Kuo-Chan, CHUANG Kuei-Yi, TSENG Feng-Po
Принадлежит: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

A reversible crosslinking reactant composition is provided. The composition includes at least one furan-group-containing oligomer having a structure represented by Formula (I) and a bismaleimide compound having a structure represented by 2. The reversible crosslinking reactant composition as claimed in claim 1 , wherein Ar is substituted or unsubstituted phenylene group claim 1 , biphenylene group claim 1 , naphthylene group claim 1 , thienylene group claim 1 , indolylene group claim 1 , phenanthrenylene claim 1 , indenylene group claim 1 , anthracenylene group claim 1 , or fluorenylene group.3. The reversible crosslinking reactant composition as claimed in claim 1 , wherein Ar is phenylene group claim 1 , biphenylene group claim 1 , naphthylene group claim 1 , thienylene group claim 1 , indolylene group claim 1 , phenanthrenylene claim 1 , indenylene group claim 1 , anthracenylene group claim 1 , or fluorenylene group with substitution groups of one to four C-Calkyl groups.7. The reversible crosslinking reactant composition as claimed in claim 6 , wherein Aris substituted or unsubstituted phenylene group claim 6 , biphenylene group claim 6 , naphthylene group claim 6 , thienylene group claim 6 , indolylene group claim 6 , phenanthrenylene claim 6 , indenylene group claim 6 , anthracenylene group claim 6 , or fluorenylene group.8. The reversible crosslinking reactant composition as claimed in claim 6 , wherein Aris phenylene group claim 6 , biphenylene group claim 6 , naphthylene group claim 6 , thienylene group claim 6 , indolylene group claim 6 , phenanthrenylene claim 6 , indenylene group claim 6 , anthracenylene group claim 6 , or fluorenylene group with substitution groups of one to four C-Calkyl groups.11. The reversible crosslinking reactant composition as claimed in claim 6 , wherein the at least one furan-group-containing oligomer having a structure represented by Formula (I) and the furan-group-containing compound having a structure represented by Formula ...

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Номер записи: 56
14-06-2018 дата публикации

ORGANOPOLYSILOXANE GRAFT POLYMER

Номер: US20180163002A1
Автор: Kobaru Shuichiro, MAEKAWA Tomoka, MIYAZAKI Chihiro
Принадлежит: KAO CORPORATION

The present invention relates to a organopolysiloxane graft polymer including an organopolysiloxane segment as a main chain thereof and an unsaturated monomer-derived polymer segment as a side chain thereof, in which the unsaturated monomer-derived polymer segment contains a repeating unit derived from N,N-dimethyl acrylamide in an amount of not less than 50% by mass and not more than 100% by mass, and a content of the organopolysiloxane segment in the organopolysiloxane graft polymer is not less than 10% by mass and not more than 70% by mass. 1. A method for treating hair , comprising applying an organopolysiloxane graft polymer onto the hair ,the organopolysiloxane graft polymer comprising an organopolysiloxane segment as a main chain thereof and an unsaturated monomer-derived polymer segment as a side chain thereof, in which the unsaturated monomer-derived polymer segment contains a repeating unit derived from N,N-dimethyl acrylamide in an amount of not less than 50% by mass and not more than 100% by mass, and a content of the organopolysiloxane segment in the organopolysiloxane graft polymer is not less than 10% by mass and not more than 70% by mass.2. The method for treating hair according to claim 1 , wherein the organopolysiloxane segment has a weight-average molecular weight of not less than 3 claim 1 ,000 and not more than 200 claim 1 ,000.3. The method for treating hair according to claim 1 , wherein among the organopolysiloxane segments claim 1 , the organopolysiloxane segment being present between the adjacent unsaturated monomer-derived polymer segments has a number-average molecular weight (MNg) of not less than 500 and not more than 10 claim 1 ,000.4. The method for treating hair according to claim 1 , wherein the unsaturated monomer-derived polymer segment further comprises a repeating unit derived from at least one unsaturated monomer selected from the group consisting of (meth)acrylamides except for N claim 1 ,N-dimethyl acrylamide claim 1 , and ( ...

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Номер записи: 57
01-07-2021 дата публикации

PHASE SEPARATED ARTICLES

Номер: US20210198536A1
Автор: DiZio James P., Hackbarth Kent C., Hao Encai, Liu Junkang J., TIAN ZHICHENG, Yang Zhaohui, ZHANG YING, ZHU DONG-WEI
Принадлежит:

Phase separated articles that include a matrix phase including an acrylate copolymer; and a silicone elastomer phase stably dispersed in the matrix phase. Methods of forming phase separated articles, and articles including phase separated articles are also included. 1: A phase separated article comprising:a matrix phase comprising an acrylate copolymer; anda silicone elastomer phase stably dispersed in the matrix phase.2: A pressure sensitive adhesive article , the article comprising:a matrix phase comprising an acrylate copolymer; anda silicone elastomer phase stably dispersed in the matrix phase.3: An optical article , the optical article comprising:a matrix phase comprising an acrylate copolymer; anda silicone elastomer phase stably dispersed in the matrix phase.4: A display device comprising:an organic light emitting diode; anda layer of phase separated article comprising:a matrix phase comprising an acrylate copolymer; anda silicone elastomer phase stably dispersed in the matrix phase.5: A display device comprising:an organic light emitting diode; anda phase separated pressure sensitive adhesive article comprising:a matrix phase comprising an acrylate copolymer; anda silicone elastomer phase stably dispersed in the matrix phase.6: A method of forming a phase separated article , the method comprising:preparing a solution polymer by radically copolymerizing a composition comprising functionalized silicone elastomer and acrylate monomers in at least one solvent;forming a film comprising the solution polymer composition; anddrying and curing the film to form the phase separated article.7: A method of controlling optical properties of a phase separated article , the method comprising:preparing a solution polymer by radically copolymerizing a composition comprising functionalized silicone elastomer and acrylate monomers in at least one solvent to form a coating composition.8: The article of claim 1 , wherein the silicone elastomers comprise siloxane polyoxamide ...

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Номер записи: 58
06-06-2019 дата публикации

POLYMERIZABLE COMPOSITION CONTAINING REACTIVE SILSESQUIOXANE COMPOUND CONTAINING PHENANTHRENE RING

Номер: US20190169345A1
Автор: KATO Taku, NAGASAWA Takehiro, SHUTO Keisuke
Принадлежит: NISSAN CHEMICAL CORPORATION

A polymerizable composition which can be cured into a cured product exhibiting a low Abbe's number and is suitable for producing a molded article having a further high transparency. A polymerizable composition including 100 parts by mass of a reactive silsesquioxane compound containing a phenathrene ring (a), and 10 to 500 parts by mass of a polymerizable compound having at least one polymerizable double bond (b), a cured product of the polymerizable composition, and a method for producing a molded article by using of the polymerizable composition. 1. A polymerizable composition comprising: 100 parts by mass of a reactive silsesquioxane compound (a) , which is a polycondensate of an alkoxy silicon compound A of formula [1] and an alkoxy silicon compound B of formula [2] , and 10 to 500 parts by mass of a polymerizable compound having at least one polymerizable double bond (b):{'br': None, 'sup': '1', 'sub': '3', 'X—Si(OR)\u2003\u2003[1]'}{'sub': '1-10', 'sup': '1', 'claim-text': {'br': None, 'sup': 1', '2, 'sub': '3', 'Ar—Si (OR)\u2003\u2003[2]'}, '(wherein X is a phenyl group having at least one substituent having a polymerizable double bond, naphthyl group having at least one substituent having a polymerizable double bond, biphenyl group having at least one substituent having a polymerizable double bond, or a Calkyl group having at least one (meth)acryloyl group, and Ris a methyl group or ethyl group);'}{'sup': 1', '2, 'sub': '1-6', '(wherein Aris a phenanthryl group optionally substituted with a Calkyl group, and Ris a methyl group or ethyl group).'}5. The polymerizable composition according to claim 1 , wherein a cured product obtained from the composition has an Abbe's number of 24 or less.6. A cured product of the polymerizable composition according to .7. A high-refractive-index resin lens material comprising the polymerizable composition according to .8. A resin lens produced from the polymerizable composition according to .9. A method for producing a molded ...

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Номер записи: 59
08-07-2021 дата публикации

POLYMERIZABLE COMPOSITION FOR THREE-DIMENSIONAL MODELING, PRODUCTION METHOD OF THREE-DIMENSIONAL MODEL USING SAME, AND THREE-DIMENSIONAL MODEL

Номер: US20210206898A1
Автор: Yonezaki Ayumi
Принадлежит: KONICA MINOLTA, INC.

The problem to be addressed by the invention is to provide a polymerizable composition for three-dimensional modeling used for producing three-dimensional models having high flexural modulus and impact strength, as well as high dimensional accuracy, and a production method for the composition. In order to solve the problem, the polymerizable composition for three-dimensional modeling contains an inorganic filler with an aspect ratio of 5 or greater, a dispersant, a photopolymerizable compound, and a thermally polymerizable compound. 1. A polymerizable composition for three-dimensional modeling comprising:an inorganic filler having an aspect ratio of 5 or more;a dispersant;a photocurable compound; anda thermopolymerizable compound.2. The polymerizable composition for three-dimensional modeling according to claim 1 , wherein:a content of the inorganic filler is 5 mass % or more and 60 mass % or less.3. The polymerizable composition for three-dimensional modeling according to claim 1 , wherein:the inorganic filler has a hydroxyl group on a surface.4. The polymerizable composition for three-dimensional modeling according to claim 1 , wherein:the thermopolymerizable compound has an epoxy group or an isocyanate group.5. The polymerizable composition for three-dimensional modeling according claim 1 , wherein:the inorganic filler is tubular.6. The polymerizable composition for three-dimensional modeling according to claim 5 , wherein:the inorganic filler has a structure in which a plurality of layers are concentrically stacked.7. A method for manufacturing a three-dimensional shaped object comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'photo-shaping for forming a primary cured product containing a cured product of the photocurable compound by selectively irradiating the polymerizable composition for three-dimensional modeling according to with active energy; and'}thermal curing of the primary cured product.8. The method for manufacturing a three-dimensional ...

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Номер записи: 60
30-06-2016 дата публикации

Polyorganosiloxane Latex, Graft Copolymer Using the Same, Thermoplastic Resin Composition, and Molded Body

Номер: US20160185965A1
Автор: Kasai Toshihiro, Kouno Hidemichi, Takeda Shigenari, Wakita Ayaka
Принадлежит:

A variety of molded bodies having high weatherability, impact resistance, designability, and the like, and a polyorganosiloxane latex and a graft copolymer used as the raw materials therefor are provided, where the polyorganosiloxane latex has a mass average particle diameter (Dw) of a polyorganosiloxane particle of 100 to 200 nm, and a ratio of the mass average particle diameter (Dw) to a number average particle diameter (Dn) (Dw/Dn) of 1.0 to 1.7. A polyorganosiloxane-containing vinyl-based copolymer (g) obtained by polymerizing one or more vinyl-based monomers in the presence of the latex. A graft copolymer (G) is obtained by graft polymerizing one or more vinyl-based monomers in the presence of the copolymer. A thermoplastic resin composition includes the graft copolymer (G) and a thermoplastic resin (Ha) except for the graft copolymer (G). A molded body is obtained by molding the resin composition. 120.-. (canceled)21. A method of preparing a polyorganosiloxane latex , where a polyorganosiloxane particle of the latex has a mass average particle diameter (Dw) of 100 to 200 nm , and where a ratio (Dw/Dn) of the mass average particle diameter (Dw) to a number average particle diameter (Dn) is 1.0 to 1.7 , the method comprising:dropping an emulsion (B) comprising an organosiloxane, an emulsifier, and water into a water-based medium (A) comprising water, an organic acid catalyst, and an inorganic acid catalyst; andpolymerizing the organosiloxane, wherein:a total amount of the organic acid catalyst and the emulsifier is 0.5 to 6 parts by mass based on 100 parts by mass of the organosiloxane,the water-based medium (A) is at a pH within the range of 0 to 1.2 when measured at 25° C., andthe dropping of the emulsion (B) is at a rate such that an amount of the organosiloxane fed is 0.5 parts by mass/min or less when a total amount of the organosiloxane to be used is 100 parts by mass.22. The method according to claim 21 , wherein a standard deviation of the mass average ...

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Номер записи: 61
04-06-2020 дата публикации

Adhesive composition

Номер: US20200172771A1
Автор: Hyun Sup Lee, Se Woo Yang, Seung Min Lee, So Young Kim, Yeon Soo Kim
Принадлежит: LG Chem Ltd

The present invention relates to an adhesive composition and an organic electronic device comprising the same, and provides an adhesive composition which can form a encapsulating structure capable of effectively blocking moisture or oxygen introduced from the outside into the organic electronic device, thereby securing the lifetime of the organic electronic device, and can improve processability by being easily applied in the process of forming the encapsulating structure of the organic electronic device, thereby preventing problems that air bubbles flow into the inside of the encapsulating structure or application nozzles are clogged, and an organic electronic device comprising the same.

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Номер записи: 62
15-07-2021 дата публикации

Process Of Processing A Radiation-Curable Thiolen Based Composition With Additive-Manufacturing Technology

Номер: US20210214504A1
Автор: Hoffmann Henning, Osswald Peter U., ZECH JOACHIM W.
Принадлежит:

The invention relates to a process of processing a radiation-curable composition with an additive-manufacturing technique comprising a radiation-curing step, the radiation-curable composition comprising mercapto-functional Component A comprising at least three mercapto moieties, crosslinker Component B with at least three vinyl or allyl moieties, photo-initiator(s) Component C for initiating a curing reaction between Component A and Component B, wherein the radiation-curable composition does not comprise urethane (meth)acrylate oligomers in an amount of more than 4 wt. % with respect to the whole composition. 3-dim articles which can be produced are typically transparent and have adequate mechanical properties. The radiation-curable composition is in particular useful for producing clear-tray aligners for dental and orthodontic purposes. 2. The process according claim 1 , the ratio of mercapto moieties to vinyl or allyl moieties being in the range of 1.5:1 to 1:1.5 with respect to mol.3. The process according to claim 1 , Component A and Component B being present in a ratio of 1.5:1 to 1:1.5 with respect to weight.4. The process according to claim 1 , the mercapto-functional component being characterized by the following features alone or in combination:{'sub': 'n', 'having a molecular weight Min the range of 200 to 20,000 g/mol;'}having a viscosity in the range of 1 to 1,000 Pa*s at 23° C.5. The process according to claim 1 , the crosslinker being characterized by the following features alone or in combination:having a molecular weight in the range of 100 to 5,000 g/mol;having a viscosity in the range of 0.1 to 10,000 Pa*s at 23° C.9. The process according to claim 1 , the radiation-curable composition being characterized by the following features alone or in combination:viscosity: less than 200 Pa*s at 23° C.;colour: light yellow or colourless;light transmission: greater than 90% for a path length of 1 mm using light having a wave length of 500 nm.10. The process ...

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Номер записи: 63
07-07-2016 дата публикации

GRAFT COPOLYMER CONTAINING POLYORGANOSILOXANE, RESIN COMPOSITION, MOLDED ARTICLE, SLIDABILITY-IMPROVING AGENT, AND SLIDING MEMBER

Номер: US20160194428A1
Автор: MATSUOKA Shinji, Otonari Hiroaki, Ueki Sohei
Принадлежит: MITSUBISHI RAYON CO., LTD.

The invention provides a thermoplastic resin composition, which does not substantially compromise color rendering and flame retardance of a thermoplastic resin and has high impact resistance, slidability, and chemical resistance in a wide scope of environmental conditions ranging from low temperature to high temperature. A graft copolymer (G) containing rubber is a graft copolymer containing rubber formed by performing graft polymerization of 1 or more vinyl monomers on a composite rubber containing a polyorganosiloxane (B1) and a polyalkyl (meth)acrylate (B2). The content of a component derived from a silane compound containing a vinyl-based polymerizable group in the polyorganosiloxane (B1) is 1 mass % to 10 mass %. The volume-average particle size of the graft copolymer containing rubber is 300 nm to 2000 nm. The content of the polyorganosiloxane (B1) in the graft copolymer containing rubber is 70 mass % to 98 mass %. An acetone soluble matter is 5.0 mass % or more and 30.0 mass % or less. 2. The graft copolymer containing rubber of claim 1 , wherein the rubber containing a polyorganosiloxane (B1) is a composite rubber containing a polyorganosiloxane (B1) and a polyalkyl (meth)acrylate (B2) claim 1 , and an acetone soluble matter in the graft copolymer containing rubber is 5.0 mass % or more to 30.0 mass % or less.3. The graft copolymer containing rubber of claim 1 , wherein a content of a component derived from a polyfunctional vinyl monomer in the graft copolymer containing rubber is greater that 0 mass % and less than 5 mass %4. The graft copolymer containing rubber of claim 1 , wherein the volume-average particle size is 400 nm to 1000 nm.5. The graft copolymer containing rubber of claim 2 , wherein a ratio “B1/B2” of the polyorganosiloxane (B1) and the polyalkyl (meth)acrylate (B2) is “74/26 to 99/1” mass %.6. A thermoplastic resin composition containing 0.1 parts by mass to 12 parts by mass of the graft copolymer containing rubber of claim 1 , 0.01 parts by ...

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Номер записи: 64
20-06-2019 дата публикации

BIOMEDICAL DEVICES CONTAINING INTERNAL WETTING AGENTS

Номер: US20190187332A1
Автор: Alli Azaam, Ford James D., Hill Gregory A., JR. Frank F., McCabe Kevin P., Molock, Steffen Robert B., Vanderlaan Douglas G.
Принадлежит:

This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer. 1. A biomedical device formed from a reaction mixture comprising a high molecular weight hydrophilic polymer; an effective amount of an hydroxyl-functionalized silicone-containing monomer; an ultra-violet absorbing compound; and a photochromic compound.2. The biomedical device of wherein the effective amount of said hydroxyl-functionalized silicone-containing monomer is about 5% to about 90%3. The biomedical device of wherein the device is a silicone hydrogel contact lens.4. The biomedical device of comprising about 1% to about 15% high molecular weight hydrophilic polymer.5. The biomedical device of wherein the effective amount of hydroxyl-functionalized silicone-containing monomer is about 10% to about 80%.7. The biomedical device of wherein said hydroxyl-functionalized silicone-containing monomer is selected from the group consisting of 2-propenoic acid claim 1 , 2-methyl-2-hydroxy-3-[3-[1 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetramethyl-1-[trimethylsilyl)oxy]disiloxanyl]propoxy]propyl ester claim 1 , (3-methacryloxy-2-hydroxypropyloxy)propyltris(trimethylsiloxy)silane claim 1 , (2-methacryloxy-3-hydroxypropyloxy)propylbis(trimethylsiloxy)methylsilane and mixtures thereof.8. The biomedical device of wherein the effective amount of said hydroxyl-functionalized silicone-containing monomer is about 20% to about 50%.9. The biomedical device of further comprising about 10% to about 40% additional silicone containing monomer claim 7 , about 10% to about 50% hydrophilic monomers claim 7 , and about 3% to about 15% high molecular weight hydrophilic polymer.10. The biomedical device of claim 9 , wherein the device is a soft contact lens.11. The biomedical device of claim 1 , wherein the hydroxyl-functionalized silicone-containing monomer has a monomer compatibility index of greater than about 0.5.12. The ...

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Номер записи: 65
14-07-2016 дата публикации

Two- and three-component siloxane and related compounds and compositions

Номер: US20160199266A1
Автор: John D. Blizzard, Joseph P. Rapp, Kirk Kimmerling
Принадлежит: Kimmerling Holding Group LLC, KIMMERLING HOLDINGS GROUP LLC

Compositions are disclosed that comprise at least one compound of formula IV: wherein the variable are as defined in the specification. The compositions are antimicrobial and optionally curable, and useful, inter alia, in dental, medical, and industrial applications for reinforcement and/or adhering two surfaces together.

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Номер записи: 66
13-07-2017 дата публикации

CONTACT LENS AND PROCESS FOR PRODUCING SAME

Номер: US20170198077A1
Автор: ITO Eri, YAMAMOTO Katsuhiro
Принадлежит: MENICON CO., LTD.

A contact lens is provided as hydrate of a copolymer of at least three components including (I) both terminal-polymerizable silicone oligomer exhibiting viscosity of at least 200 mPa·s at room temperature, (II) a hydrophilic monomer component having ethylenically unsaturated group, and (III) a hydrophobic monomer component having molecular weight of at most 700, wherein the lens exhibits an elastic-modulus ratio determined as ratio of a rupture elastic modulus to an initial elastic modulus in range of 0.8-1.2. The contact lens is transparent and by combination of high oxygen permeability and balance between softness and mechanical properties. The lens is produced through a process including steps of stirring material-liquid including at least three components of the above-mentioned (I), (II) and (III) under stirring power of 5-10000 W/m3 per unit volume of the material-liquid for at least 10 minutes, and injecting stirred material-liquid into a lens mold to polymerize material-liquid. 1. A contact lens , comprising: a hydrate of a copolymer of at least three components including (I) a both terminal-polymerizable silicone oligomer exhibiting a viscosity of at least 200 mPa·s at room temperature , (II) a hydrophilic monomer component having an ethylenically unsaturated group , and (III) a hydrophobic monomer component having a molecular weight of at most 700 , wherein the contact lens exhibits an elastic-modulus ratio determined as a ratio of a rupture elastic modulus to an initial elastic modulus in a range of 0.8-1.2.2. The contact lens according to claim 1 , exhibiting a rupture modulus of 0.1-0.5 N/mm claim 1 , and an initial modulus of 0.1-0.5 N/mm.3. The contact lens according to claim 1 , exhibiting a stress relaxation coefficient of 8 to 25% claim 1 , and an oxygen permeability coefficient Dk of at least 56×10(cm/sec)·(mLO/mL×mmHg).5. The contact lens according to claim 1 , wherein said hydrophilic monomer component (II) is a hydrophilic monomer selected from ...

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Номер записи: 67
19-07-2018 дата публикации

BIOMEDICAL DEVICES CONTAINING INTERNAL WETTING AGENTS

Номер: US20180203161A1
Автор: Alli Azaam, Ford James D., Hill Gregory A., JR. Frank F., McCabe Kevin P., Molock, Steffen Robert B., Vanderlaan Douglas G.
Принадлежит:

This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer. 115-. (canceled)16. The method of wherein said hydrophilic polymer is selected from the group consisting of poly-N-vinyl pyrrolidone claim 152 , poly-N-vinyl-2-piperidone claim 152 , poly-N-vinyl-2-caprolactam claim 152 , poly-N-vinyl-3-methyl-2-caprolactam claim 152 , poly-N-vinyl-3-methyl-2-piperidone claim 152 , poly-N-vinyl-4-methyl-2-piperidone claim 152 , poly-N-vinyl-4-methyl-2-caprolactam claim 152 , poly-N-vinyl-3-ethyl-2-pyrrolidone claim 152 , and poly-N-vinyl-4 claim 152 ,5-dimethyl-2-pyrrolidone claim 152 , polyvinylimidazole claim 152 , poly-N—N-dimethylacrylamide claim 152 , polyvinyl alcohol claim 152 , polyacrylic acid claim 152 , polyethylene oxide claim 152 , poly 2 ethyl oxazoline claim 152 , heparin polysaccharides claim 152 , polysaccharides claim 152 , mixtures and copolymers thereof.17. The method of wherein said hydrophilic polymer comprises poly-N-vinylpyrrolidone.18. The method of comprising about 1 to about 15 weight % high molecular weight hydrophilic polymer19. The method of comprising about 3 to about 15 weight % high molecular weight hydrophilic polymer.20. The method of comprising about 5 to about 12 weight % high molecular weight hydrophilic polymer.22. The method of wherein the effective amount of hydroxyl-functionalized silicone-containing monomer is about 20% to about 50%.23. The method of wherein said hydroxyl-functionalized silicone-containing monomer is selected from the group consisting of 2-propenoic acid claim 21 , 2-methyl-2-hydroxy-3-[3-[1 claim 21 ,3 claim 21 ,3 claim 21 ,3-tetramethyl-1-[trimethylsilyl)oxy]disiloxanyl]propoxy]propyl ester claim 21 , (3-methacryloxy-2-hydroxypropyloxy)propyltris(trimethylsiloxy)silane claim 21 , (2-methacryloxy-3-hydroxypropyloxy)propylbis(trimethylsiloxy)methylsilane and mixtures thereof.2428-. (canceled)29. The method of ...

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Номер записи: 68
06-08-2015 дата публикации

POLYMER PARTICLE DISPERSIONS WITH POLYOLS

Номер: US20150218299A1
Автор: Nunley Jeanette K., XIE RUI
Принадлежит:

A toughener composition comprising: a) a polyol component selected from the group consisting of a polyether polyol, a polyester polyol, a polycaprolactone polyol, a hydroxyl-terminated polybutadiene, and mixtures or copolymers thereof; and b) a core shell rubber comprising a rubber particle core and a shell layer wherein said core shell rubber has a particle size of from 0.01 μm to 0.5 μm is disclosed. The toughener can be used in epoxy resin compositions for composite applications. 1. A composition comprising:a) a polyol component comprising a polyol with an average molecular weight of from 2000 to 12000 and an average functionality of 1.5 to 6; andb) a core shell rubber comprising a rubber particle core and a shell layer wherein said core shell rubber has a particle size of from 0.01 μm to 0.5 μm.2. A composition in accordance with wherein said polyol component comprises a polyol having an ethylene oxide content of at least 5 weight percent.3. A composition in accordance with wherein said core shell rubber comprises a functional group selected from the group consisting of carboxyl groups claim 1 , hydroxyl groups claim 1 , carbon-carbon double bonds claim 1 , anhydride groups claim 1 , amino groups claim 1 , amide groups claim 1 , and combinations thereof.4. A composition in accordance with wherein said polyol component is a copolymer selected from the group consisting of ethylene oxide-proplylene oxide block copolymers claim 1 , ethylene oxide-butylene oxide block copolymers claim 1 , ethylene oxide end-capped proplylene polyols claim 1 , ethylene oxide end-capped butylenes oxide polyols claim 1 , and combinations thereof.5. A composition in accordance with wherein said polyol component comprises a polyol selected from the group consisting of a polyether polyol claim 1 , a polyester polyol claim 1 , a polycaprolactone polyol claim 1 , a hydroxyl-terminated polybutadiene claim 1 , and mixtures or copolymers thereof.6. A process for preparing the composition of ...

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Номер записи: 69
26-07-2018 дата публикации

DEFOAMING AGENT AND LUBRICATING OIL COMPOSITION

Номер: US20180208871A1
Автор: MATSUKI Shingo, TAKAGI Akira, TATSUMI Go
Принадлежит: JXTG NIPPON OIL & ENERGY CORPORATION

A defoaming agent including a polymer, the polymer including a repeating unit represented by the following general formula (1); and a repeating unit represented by the following general formula (3): 3. The defoaming agent according to claim 2 ,{'sup': '3', 'wherein Xis a repeating unit obtainable by polymerization of a third (meth)acryloyl group.'}4. The defoaming agent according to claim 1 ,{'sup': '2', 'wherein Xis a repeating unit obtainable by polymerization of a second (meth)acryloyl group; and'}{'sup': '1', 'Xis a repeating unit obtainable by polymerization of a first (meth)acryloyl group.'}5. The defoaming agent according to claim 1 ,wherein the polymer comprises the repeating unit represented by the general formula (1) in an amount of no less than 10 mass % on the basis of the total mass of all repeating units in the polymer.6. The defoaming agent according to claim 1 ,wherein the polymer has a weight average molecular weight of 10,000 to 1,000,000.7. A lubricating oil composition comprising:(A) a lubricant base oil; and{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(B) the defoaming agent as in , in an amount of 1 to 100 mass ppm in terms of silicon on the basis of the total mass of the composition.'}8. The lubricating oil composition according to claim 7 , which is a lubricating oil for an automobile engine claim 7 , an automobile transmission claim 7 , or an automobile transaxle unit. The present invention relates to defoaming agents, and lubricating oil compositions containing the defoaming agents.Lubricating oil is used in various kinds of machinery so as to improve lubricity between members. Increase of foaming of the lubricating oil may lead to insufficient lubrication, failure to control hydraulic pressure, deteriorated cooling efficiency, and so on. Thus, lubricating oil is required to suppress foaming.For example, automobile engines, transmissions, and axle units are demanding increasingly more from lubricating oil, accompanying their recent ...

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Номер записи: 70
04-07-2019 дата публикации

AQUEOUS COATING MATERIAL AND METHOD FOR MANUFACTURING THE SAME

Номер: US20190203060A1
Автор: CHEN WEI Su-Mei, CHIEN Shu-Yun, Su Yi-Che, WEI Yeu-Kuen
Принадлежит: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

An aqueous coating material is provided. The aqueous coating material includes an aqueous resin and a surfactant. The surfactant having a hydrophilic segment of poly(alkylene glycol), a hydrophobic segment of siloxane, and a terminal hydrophilic group. The aqueous resin and the surfactant may have a weight ratio of 100:1 to 100:25. 1. An aqueous coating material , comprising:an aqueous resin; anda surfactant, having a hydrophilic segment of poly(alkylene glycol), a hydrophobic segment of siloxane, and a terminal hydrophilic group.2. The aqueous coating material as claimed in claim 1 , wherein the aqueous resin and the surfactant have a weight ratio of 100:1 to 100:25.4. The aqueous coating material as claimed in claim 3 , wherein (a) hydrolyzed siloxane compound and (b1) amino crosslinker have a weight ratio of 100:10 to 100:200.6. The aqueous coating material as claimed in claim 5 , wherein (a) hydrolyzed siloxane compound and (b2) epoxy crosslinker have a weight ratio of 100:10 to 100:200.7. The aqueous coating material as claimed in claim 1 , wherein the aqueous resin comprises polyurethane resin claim 1 , carbonate resin claim 1 , acrylic resin claim 1 , or a combination thereof.8. A method for manufacturing an aqueous coating material claim 1 , comprising:reacting (a) hydrolyzed siloxane compound with (b1) amino crosslinker to form a surfactant, wherein the surfactant has a hydrophilic segment of poly(alkylene glycol), a hydrophobic segment of siloxane, and a terminal amino group; andmixing the surfactant with an aqueous resin to obtain an aqueous coating material.9. The method as claimed in claim 8 , wherein the aqueous resin and the surfactant have a weight ratio of 100:1 to 100:25.11. The method as claimed in claim 8 , wherein (a) hydrolyzed siloxane compound and (b1) amino crosslinker have a weight ratio of 100:10 to 100:200.12. The method as claimed in claim 8 , wherein the aqueous resin comprises polyurethane resin claim 8 , carbonate resin claim 8 , ...

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Номер записи: 71
04-08-2016 дата публикации

CURABLE RESIN AND PRODUCING PROCESS THEREFOR

Номер: US20160222154A1
Автор: OTSUKI Nobuaki, Yoshida Masatoshi
Принадлежит: NIPPON SHOKUBAI CO., LTD.

A curable resin obtained by reacting a polybasic anhydride with a reaction product of an epoxy resin with a phenol compound having an alcoholic hydroxyl group and an unsaturated monobasic acid, wherein an epoxy resin having a softening point of 93° C. or higher is used as the epoxy resin. 1. A curable resin obtained by reacting a polybasic anhydride with a reaction product of an epoxy resin with a phenol compound having an alcoholic hydroxyl group and an unsaturated monobasic acid , whereinan epoxy resin having a softening point of 93° C. or higher is used as the epoxy resin.2. The curable resin according to claim 1 , wherein a cresol novolac epoxy resin is used as the epoxy resin.3. The curable resin according to claim 1 , wherein 0.15 moles or more and 0.5 moles or less of the phenol compound is reacted with 1 chemical equivalent of an epoxy group of the epoxy resin.4. The curable resin according to claim 1 , wherein 0.5 moles or more and 0.85 moles or less of the unsaturated monobasic acid is reacted with 1 chemical equivalent of an epoxy group of the epoxy resin.5. The curable resin according to claim 1 , wherein 0.8 moles or more and 1.1 moles or less of the phenol compound and the unsaturated monobasic acid in total is reacted with 1 chemical equivalent of an epoxy group of the epoxy resin.6. The curable resin according to claim 1 , wherein 0.1 moles or more and 1.1 moles or less of the polybasic anhydride is reacted with 1 chemical equivalent of a hydroxyl group of the reaction product.7. The curable resin according to claim 1 , wherein the curable resin has double bond equivalent of 480 g/eq. or more and 620 g/eq. or less.8. A process for producing a curable resin comprising the steps of:reacting an epoxy resin having a softening point of 93° C. or higher with a phenol compound having an alcoholic hydroxyl group and an unsaturated monobasic acid to give a modified epoxy resin intermediate; andreacting a polybasic anhydride with a hydroxyl group of the ...

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Номер записи: 72
02-08-2018 дата публикации

SILICONE HYDROGELS COMPRISING N-VINYL AMIDES AND HYDROXYALKYL (METH)ACRYLATES OR (METH)ACRYLAMIDES

Номер: US20180217295A1
Автор: Alli Azaam, Ford James D., Joslin Scott L., Vanderlaan Douglas G.
Принадлежит:

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature. 1. (canceled)3. The contact lens of wherein each Ris independently selected from ethyl and methyl groups.4. The contact lens of wherein all Rare methyl.5. The contact lens of wherein Ris selected from the group consisting of C-Calkylene group which may be substituted with ether claim 2 , hydroxyl and combinations thereof.6. The contact lens of wherein Ris selected from the group consisting of Cor C-Calkylene groups which may be substituted with ether claim 2 , hydroxyl and combinations thereof.7. The contact lens of wherein Ris H or methyl.8. The contact lens of wherein Rand each Rare methyl.9. The contact lens of wherein at least one Ris 3 claim 2 ,3 claim 2 ,3-trifluoropropyl.10. The contact lens of wherein Ris methyl or 2-hydroxyethyl.11. (canceled)12. The contact lens of wherein the slow-reacting hydrophilic monomer is selected from the vinyl pyrrolidone of Formula II or IV or the N-vinyl amide monomer of Formula I claim 2 , having a total number of carbon atoms in Rand Rof 4 or less.13. The contact lens of wherein the slow-reacting hydrophilic monomer is selected from a vinyl pyrrolidone of Formula III or IV and Ris methyl claim 2 , Ris hydrogen claim 2 , Ris CH═CH claim 2 , Rand Rare H.14. The contact lens of wherein the slow-reacting hydrophilic monomer is selected from ethylene glycol vinyl ether (EGVE) claim 2 , di(ethylene glycol) vinyl ether (DEGVE) claim 2 , N-vinyl pyrrolidone (NVP) claim 2 , 1-methyl-3-methylene-2-pyrrolidone claim 2 , 1- ...

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Номер записи: 73
27-08-2015 дата публикации

Reactant of silicon resin polycondensate particles and polyvinyl chloride, method for manufacturing said reactant, vinyl chloride resin composition, and method for manufacturing vinyl chloride resin composition

Номер: US20150240019A1
Автор: Atsushi Kawano, Kohei Moritaka, Yoshihiro Kubo, Yuhki Gotoh
Принадлежит: Sekisui Chemical Co Ltd

Provided is a reaction product of silicone resin polycondensate particles and polyvinyl chloride wherein the reaction product can impart excellent impact resistance and chemical resistance. The reaction product of silicone resin polycondensate particles and polyvinyl chloride according to the present invention is obtained by causing reaction of a material containing silicone resin polycondensate particles and vinyl chloride monomer. The silicone resin polycondensate particles are obtained by causing reaction of a material mixture containing a first organosilicon compound having a structural unit represented by a formula (1) and serving as a siloxane, a second organosilicon compound represented by a formula (2), and a third organosilicon compound represented by a formula (3A) or formula (3B).

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Номер записи: 74
26-08-2021 дата публикации

POLYMER COMPOSITIONS CONTAINING GRAFTED POLYMERIC NETWORKS AND PROCESSES FOR THEIR PREPARATION AND USE

Номер: US20210261712A1
Автор: Aitken Brian, Arnold Stephen C., Duis Donnie, Joslin Scott, Lu Fang, Mahadevan Shivkumar, Martin Patricia, Scales Charles, Sinha Dola, Zhang Yong
Принадлежит:

Provided are polymer compositions made by a process comprising: (a) providing a first reactive composition containing: (i) a polymerization initiator that is capable, upon a first activation, of forming two or more free radical groups, at least one of which is further activatable by subsequent activation; (ii) one or more ethylenically unsaturated compounds; and (iii) a crosslinker; (b) subjecting the first reactive composition to a first activation step such that the first reactive composition polymerizes therein to form a crosslinked substrate network containing a covalently bound activatable free radical initiator, (c) combining the crosslinked substrate network with a second reactive composition containing one or more ethylenically unsaturated compounds; and (d) activating the covalently bound activatable free radical initiator of the crosslinked substrate network such that the second reactive composition polymerizes therein with the crosslinked substrate network to form a grafted polymeric network and a byproduct polymer. Also provided are precursors to the polymer compositions, processes for preparation of the polymer compositions, and methods of using the polymer compositions, for instance in medical devices. 1. A polymer composition formed by a process comprising:(a) providing a first reactive composition containing: (i) a polymerization initiator that is capable, upon a first activation, of forming two or more free radical groups, at least one of which is further activatable by subsequent activation; (ii) one or more ethylenically unsaturated compounds; and (iii) a crosslinker;(b) subjecting the first reactive composition to a first activation step such that the first reactive composition polymerizes therein to form a crosslinked substrate network containing a covalently bound activatable free radical initiator;(c) combining the crosslinked substrate network with a second reactive composition containing one or more ethylenically unsaturated compounds; and(d ...

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Номер записи: 75
24-08-2017 дата публикации

FILM-FORMING COMPOSITION AND COSMETIC

Номер: US20170240677A1
Автор: Akabane Emi
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

A film-forming composition containing a polymer obtained by polymerizing (A) 5 to 80 mass % of a silicone resin having an RSiOunit, an RR′SiOunit, and an SiOunit, where R may be the same or different and represents a monovalent hydrocarbon group having 1 to 6 carbon atoms, and R′ represents a —CHSH group, wherein a total amount of the RSiOunit, RR′SiOunit, and SiOunit is 80 mol % or more with respect to all structural units, and a mole ratio expressed by (sum of RSiOunit and RR′SiOunit)/(SiOunit) ranges from 0.5 to 1.5 and (B) 20 to 95 mass % of one or more radically polymerizable compounds, wherein component (B) includes (B-1) one or more radically polymerizable monomers having no SiO unit in a structure thereof. This composition is capable of forming a transparent film that is excellent in adhesiveness without exhibiting stickiness and secondary adhesion. 17-. (canceled)8. A film-forming composition comprising a polymer obtained by polymerizing:{'sub': 3', '1/2', '2', '12', '2', '3', '6', '3', '1/2', '2', '1/2', '2', '3', '1/2', '2', '1/2', '2, '(A) 5 to 80 mass % of a silicone resin having an RSiOunit, an RR′SiOunit, and an SiOunit, where R may be the same or different and represents a monovalent hydrocarbon group having 1 to 6 carbon atoms, and R′ represents a —CHSH group, in which a total amount of the RSiOunit, the RR′SiOunit, and the SiOunit is 80 mol % or more with respect to all structural units, and a mole ratio expressed by (sum of RSiOunit and RR′SiOunit)/(SiOunit) ranges from 0.5 to 1.5; and'} 'the component (B) includes (B-1) one or more radically polymerizable monomers having no SiO unit in a structure thereof.', '(B) 20 to 95 mass % of one or more radically polymerizable compounds, wherein'}9. The film-forming composition according to claim 8 , wherein the component (B-1) includes methyl (meth)acrylate.10. The film-forming composition according to claim 8 , wherein the component (B) further includes (B-2) a silicone macromonomer having a radically ...

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Номер записи: 76
10-09-2015 дата публикации

Polymer particle dispersions with epoxy hardeners

Номер: US20150252183A1
Автор: Krishnan KARUNAKARAN, Nikhil K. E. VERGHESE, Rui Xie
Принадлежит: Dow Global Technologies LLC

A process for producing a dispersion comprising: dispersing a) a core shell rubber into b) a hardener component selected from the group consisting of anhydrides, amines, phenol novolacs, and mixtures thereof in a dispersion zone under dispersion conditions wherein said dispersion zone does not contain a solvent and wherein said dispersion conditions comprise a dispersion temperature of 40° C. to 100° C., a Reynolds Number greater than 10, and a dispersion time of from 30 minutes to 80 minutes is disclosed.

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Номер записи: 77
24-08-2017 дата публикации

UV/VISIBLE-ABSORBING VINYLIC MONOMERS AND USES THEREOF

Номер: US20170242274A1
Автор: Chang Frank, DeSousa Ryan, Holland Troy Vernon, Jiang Xuwei, Laredo Walter R.
Принадлежит:

Described herein are UV-absorbing vinylic monomers and their uses in preparing UV-absorbing contact lenses capable of blocking ultra-violet (“UV”) radiation and violet radiation with wavelengths from 380 nm to 440 nm, thereby protecting eyes to some extent from damages caused by UV radiation and potentially from violet radiation. 2. The UV-absorbing vinylic monomer of claim 1 , wherein only one of Rand Rcontains a (meth)acryloylamido group.3. The UV-absorbing vinylic monomer of claim 1 , wherein only one of Rand Rcontains a (meth)acryloyloxy group.5. A contact lens comprising a crosslinked material which comprises monomeric units of a UV-absorbing vinylic monomer of .6. The contact lens of claim 5 , wherein in formula (I) only one of Rand Rcontains a (meth)acryloylamido group.7. The contact lens of claim 5 , wherein in formula (I) only one of Rand Rcontains a (meth)acryloyloxy group.8. The contact lens of claim 5 , wherein in formula (I) only one of Rand Rcontains a (meth)acryloyloxy group.10. The contact lens of claim 5 , wherein the contact lens is a hydrogel contact lens.11. The contact lens of claim 5 , wherein the contact lens is a silicone hydrogel contact lens.12. The contact lens of claim 5 , wherein the contact lens has: an UVB transmittance of about 10% or less between 280 and 315 nanometers; a UVA transmittance of about 30% or less between 315 and 380 nanometers; a Violet transmittance of about 60% or less between 380 nm and 440 nm; and a water content of from about 15% to about 80% by weight (at room temperature claim 5 , about 22° C. to 28° C.) when being fully hydrated.13. A method for producing UV-absorbing contact lenses claim 5 , comprising the steps of:{'claim-ref': [{'@idref': 'CLM-00001', 'claims 1'}, {'@idref': 'CLM-00004', '4'}], '(1) obtaining a lens formulation comprising (a) a UV-absorbing vinylic monomer of formula (I) of any one of to , (b) a free-radical initiator, and (c) at least one polymerizable component selected from the group ...

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Номер записи: 78
23-07-2020 дата публикации

SUBSTRATE FOR TEST USE, AND METHOD FOR PRODUCING SUBSTRATE FOR TEST USE

Номер: US20200231924A1
Автор: BARBA Bin Jeremiah Duenas, Ide Takashi, KINOSHITA Shinobu, OYAMA Tomoko, TAGUCHI Mitsumasa
Принадлежит:

Provided are a substrate for test use that is preferable for use in a test such as a culture test, and a method for manufacturing the substrate for test use. The substrate for test use, in which a solution retaining part for retaining water or an aqueous solution, is formed at a surface of a substrate of polydimethylsiloxane (PDMS). The solution retaining part is a concave part having a hydrophilic surface layer. The surface layer has a maximum thickness of 1 μm or larger. 1. A substrate for test use in which a solution retaining part for retaining water or an aqueous solution is formed at a surface of the substrate , whereinthe substrate is made of polydimethylsiloxane (PDMS),the solution retaining part is a concave part having a hydrophilic surface layer,the surface layer of the concave part has a water contact angle that is smaller than a water contact angle of a non-concave part in the surface of the substrate and a thickness of the thickest part of the hydrophilic surface layer of the concave part is 20 μm or larger.2. The substrate for test use according to claim 1 , wherein the concave part has a maximum depth of 0.5 μm or larger.3. The substrate for test use according to claim 1 , wherein the solution retaining part has wettability with a water contact angle of 90° or smaller.4. A method for manufacturing a substrate for test use claim 1 , in which a solution retaining part that retains water or a solution is formed claim 1 , the method comprising an electron beam irradiation process of irradiating a place which is of the substrate made of polydimethylsiloxane (PDMS) and at which the solution retaining part is to be formed with an electron beam at an acceleration voltage of the electron beam claim 1 , which is equal to or lower than 1 MV and a radiation dose claim 1 , of the electron beam claim 1 , which is equal to or larger than 2 MGy claim 1 , whereinin the electron beam irradiation process, by irradiating the electron beam, a concave part that retains ...

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Номер записи: 79
23-07-2020 дата публикации

BIOMEDICAL DEVICES CONTAINING INTERNAL WETTING AGENTS

Номер: US20200233118A1
Автор: Alli Azaam, Ford James D., Hill Gregory A., JR. Frank F., McCabe Kevin P., Molock, Steffen Robert B., Vanderlaan Douglas G.
Принадлежит:

This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer. 113-. (canceled)14. A silicone hydrogel formed from a reaction mixture comprising a high molecular weight hydrophilic polymer; an effective amount of an hydroxyl-functionalized silicone-containing monomer; an ultra-violet absorbing compound; and a photochromic compound.15. The silicone hydrogel of wherein said hydrophilic polymer is selected from the group consisting of polyamides claim 14 , polylactones claim 14 , polyimides claim 14 , polylactams claim 14 , functionalized polyamides claim 14 , functionalized polylactones claim 14 , functionalized polyimides claim 14 , functionalized polylactams claim 14 , and mixtures thereof.16. The silicone hydrogel of wherein said hydrophilic polymer is selected from the group consisting of poly-N-vinyl pyrrolidone claim 14 , poly-N-vinyl-2-piperidone claim 14 , poly-N-vinyl-2-caprolactam claim 14 , poly-N-vinyl-3-methyl-2-caprolactam claim 14 , poly-N-vinyl-3-methyl-2-piperidone claim 14 , poly-N-vinyl-4-methyl-2-piperidone claim 14 , poly-N-vinyl-4-methyl-2-caprolactam claim 14 , poly-N-vinyl-3-ethyl-2-pyrrolidone claim 14 , and poly-N-vinyl-4 claim 14 ,5-dimethyl-2-pyrrolidone claim 14 , polyvinylimidazole claim 14 , poly-N—N-dimethylacrylamide claim 14 , polyvinyl alcohol claim 14 , polyacrylic acid claim 14 , polyethylene oxide claim 14 , poly 2 ethyl oxazoline claim 14 , heparin polysaccharides claim 14 , polysaccharides claim 14 , mixtures and copolymers thereof.17. The silicone hydrogel of wherein said hydrophilic polymer comprises poly-N-vinylpyrrolidone.18. The silicone hydrogel of comprising about 1 to about 15 weight % high molecular weight hydrophilic polymer1920-. (canceled)22. (canceled)23. The silicone hydrogel of wherein said hydroxyl-functionalized silicone-containing monomer is selected from the group consisting of 2-propenoic acid claim 21 , 2- ...

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Номер записи: 80
01-09-2016 дата публикации

Negative photosensitive resin composition, cured resin film, partition walls and optical element

Номер: US20160252812A1
Автор: Keigo Matsuura, Kotaro Yamada
Принадлежит: Asahi Glass Co Ltd

A negative photosensitive resin composition comprising an alkali-soluble resin or alkali-soluble monomer which has a photo-curability, a photopolymerization initiator, and an ink repellent agent which has a fluorine atom content of from 1 to 45 mass % and which is a partially hydrolyzed condensate of a hydrolyzable silane compound mixture containing a hydrolyzable silane compound having a hydrolyzable group and an organic group having a polyfluoroalkyl group which has an etheric oxygen atom; a cured resin film and partition walls formed by using the negative photosensitive resin composition; and an optical element having the partition walls located between a plurality of dots and their adjacent dots on a substrate surface.

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Номер записи: 81
30-07-2020 дата публикации

PACKAGING SOLUTIONS

Номер: US20200239217A1
Автор: Barniak Vicki L., Coullard Lynn, Cubi Keyla M., Hunt Jennifer M., Mark Analuz, Nuñez Ivan M.
Принадлежит:

A packaging system for the storage of an ophthalmic device is disclosed. The packaging system comprises a sealed container containing one or more unused ophthalmic devices immersed in an aqueous packaging solution comprising one or more hydrophilic polymers or copolymers comprising hydrophilic units and endcapped with a hydrophobic end group and a hydrophilic end group, wherein the solution has an osmolality of at least about 200 mOsm/kg, a pH of about 6 to about 9 and is heat sterilized. 1. A packaging system for the storage of an ophthalmic device comprising a sealed container containing one or more unused ophthalmic devices immersed in an aqueous packaging solution comprising one or more hydrophilic polymers or copolymers comprising hydrophilic units and endcapped with a hydrophobic end group and a hydrophilic end group , wherein the solution has an osmolality of at least about 200 mOsm/kg , a pH of about 6 to about 9 and is heat sterilized.2. The packaging system of claim 1 , wherein the ophthalmic device is a contact lens.3. The packaging system of claim 1 , wherein the hydrophilic units are derived from at least one ethylenically unsaturated polymerizable hydrophilic monomer.4. The packaging system of claim 3 , wherein the at least one ethylenically unsaturated polymerizable hydrophilic monomer is selected from the group consisting of an acrylamide claim 3 , an acetamide claim 3 , a formamide claim 3 , a cyclic lactam claim 3 , a (meth)acrylated alcohol claim 3 , a (meth)acrylated poly(alkyleneoxy) claim 3 , an ethylenically unsaturated carboxylic acid claim 3 , a hydrophilic vinyl carbonate claim 3 , hydrophilic vinyl carbamate claim 3 , hydrophilic oxazolone monomer claim 3 , and mixtures thereof.5. The packaging system of claim 1 , wherein the one or more hydrophilic polymers or copolymers are endcapped with a hydrophilic group selected from the group consisting of an —OH and —CN.6. The packaging system of claim 1 , wherein the one or more hydrophilic ...

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Номер записи: 82
30-07-2020 дата публикации

COATING AGENT FOR LEATHER, AND LEATHER ON WHICH COATING BY COATING AGENT IS FORMED

Номер: US20200239972A1
Автор: Watanabe Kentaro
Принадлежит: Nissin Chemical Industry Co., Ltd.

The present invention provides a coating agent for leather, the coating agent containing: in terms of solid content ratio, (I) an aqueous urethane resin; (II) a matting agent; and (III) a silicone acryl graft copolymer resin emulsion in which the weight ratio of a polyorganosiloxane represented by a specified formula relative to acrylic ester units or methacrylic ester units is 50:50 to 90:10, and a leather on which a coating by the coating agent for leather is formed. This coating agent for leather has exceptional wear resistance and anti-fouling properties, and a leather on which a coating by the coating agent is formed can maintain a high-quality external appearance and high wear resistance. 2. The coating agent for leather according to claim 1 , wherein the amount of diphenylsiloxane in the polyorganosiloxane represented by the general formula (1) is 15% by weight or more and 85% by weight or less.3. The coating agent for leather according to claim 1 , whereinthe silicone acryl graft copolymer resin emulsion (III) is an emulsion graft copolymer of:(i) a polyorganosiloxane represented by the general formula (1);(ii) an acrylic ester monomer or a methacrylic ester monomer; and(iii) if necessary, a functional group-containing monomer copolymerizable with the component (ii).4. The coating agent for leather according to claim 1 , wherein the aqueous urethane resin is a polycarbonate-based urethane resin.5. The coating agent for leather according to claim 1 , wherein the matting agent is selected from silica claim 1 , silicone powder claim 1 , acrylic powder claim 1 , and urethane powder.6. The coating agent for leather according to claim 1 , wherein the silicone acryl graft copolymer resin emulsion has a solid content of 1 to 30% by weight and a viscosity of 500 mPa·s or less at 25° C.7. A leather on which a coating by the coating agent for leather according to is formed. The present invention relates to a coating agent for leather, having wear resistance and anti- ...

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Номер записи: 83
07-09-2017 дата публикации

Hydrophilized carbosiloxane vinylic monomers

Номер: US20170254927A1
Автор: Frank Chang, Jinyu Huang
Принадлежит: NOVARTIS AG

The invention provides a hydrophilized carbosiloxane vinylic monomer which comprises (1) a poly(carbosiloxane) segment, (2) one sole ethylenically unsaturated group, and (3) at least one terminal or pendant group which is a hydrophilic group or hydrophilic polymer chain. The present invention is also related to a polymer, an actinically-crosslinkable silicone-containing prepolymer, a silicone hydrogel polymeric material, or a silicone hydrogel contact lens, which comprises monomeric units derived from a hydrophilized carbosiloxane vinylic monomer of the invention.

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Номер записи: 84
06-09-2018 дата публикации

WIRE SHEATHING AND INSULATION COMPOSITIONS

Номер: US20180254125A1
Автор: Roberts David Geraint, Slevin Mike Edward
Принадлежит:

Halogen-free polymer composite materials, which are commonly for use in sheathing and insulation applications for wire and cable, are provided. The composite materials include a polymeric blend, which includes ethylene/α-olefin copolymer and polyolefin, a hydrated metal oxide flame-retardant, such as hydrated magnesium oxide, and an antimony compound. In some instances, the polymeric blend may include an olefin/unsaturated ester copolymer. 1. A halogen-free polymer composite comprising: about 30 to 75 wt % ethylene/α-olefin copolymer; and', 'about 25 to 60 wt % polyolefin;, '(A) 100 parts by weight polymer material, which comprises'}(B) about 50 to 175 parts by weight hydrated metal oxide flame-retardant; and(C) about 30 to 100 parts by weight antimony compound.2. The composite of claim 1 , wherein the hydrated metal oxide flame-retardant comprises magnesium hydroxide; and the antimony compound comprises antimony trioxide claim 1 , antimony pentoxide claim 1 , antimony tetroxide claim 1 , sodium antimonate claim 1 , and/or antimony tartrate.3. The composite of claim 2 , wherein the total of the hydrated metal oxide and antimony compound is about 50-70 wt % of the composition; and the polymer material comprises silane-grafted ethylene/α-olefin copolymer and/or silane-grafted polyethylene.4. The composite of claim 3 , wherein the polyolefin comprises linear low density polyethylene; and the ethylene/α-olefin copolymer comprises ethylene/α-octene plastomer.5. The composite of claim 3 , wherein the polyolefin comprises polyethylene; and the ethylene/α-olefin copolymer comprises ethylene/α-olefin plastomer and ethylene/α-olefin-polyethylene block copolymer.6. The composite of claim 3 , comprising: about 50 to 70 wt % ethylene/α-octene plastomer; and', 'about 30 to 50 wt % linear low density polyethylene;, '(A) 100 parts by weight of the polymer material, which comprises'}(B) about 70 to 150 parts by weight magnesium hydroxide; and(C) about 60 to 100 parts by weight ...

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Номер записи: 85
24-09-2015 дата публикации

Polyorganosiloxane-Containing Graft Copolymer, Resin Composition, and Molded Article

Номер: US20150267048A1
Автор: Ayaka WAKITA, Shinji Matsuoka, Sohei UEKI, Yuichiro Fujikaawa
Принадлежит: Mitsubishi Rayon Co Ltd

A graft copolymer capable of providing impact resistance, flame retardance, and color rendering properties to a thermoplastic resin is described. The graft copolymer contains a polyorganosiloxane, and is obtained by graft-polymerizing vinyl monomers including a (meth)acrylate ester (b 1 ) having an alkyl group or an aromatic group and an aromatic vinyl monomer (b 2 ) on a polyorganosiloxane-based rubber. The graft copolymer has a volume average particle diameter of 200-2000 nm, and contains 0.1-69 mass % of polyorganosiloxane. A thermoplastic resin composition is also described, containing a thermoplastic resin (A), the graft copolymer, a fluorine resin (C) and a flame retardant (D). A molded article is also described, which is obtained by molding the thermoplastic resin composition.

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Номер записи: 86
28-10-2021 дата публикации

ULTRAVIOLET CURABLE SILICONE COMPOSITION AND CURED PRODUCT THEREOF

Номер: US20210332175A1
Автор: KITAGAWA Taichi, MATSUDA Tsuyoshi, MATSUMOTO Nobuaki, OTAKE Kohei, OZAI Toshiyuki
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

Provided are a low-viscosity ultraviolet curable silicone composition capable of being used even in a surface exposure method and a lift-up method etc.; and a cured product superior in tensile strength and elongation at break. The ultraviolet curable silicone composition contains: 2. The ultraviolet curable silicone composition according to claim 1 , wherein Rin the general formula (1) represents an alkyl group having 1 to 10 carbon atoms.3. The ultraviolet curable silicone composition according to claim 1 , wherein the ultraviolet curable silicone composition has a viscosity of not higher than 10 claim 1 ,000 mPa·s at 25° C.4. A cured product of the ultraviolet curable silicone composition according to .5. (canceled)6. The ultraviolet curable silicone composition according to claim 2 , wherein the ultraviolet curable silicone composition has a viscosity of not higher than 10 claim 2 ,000 mPa·s at 25° C.7. A cured product of the ultraviolet curable silicone composition according to .8. A cured product of the ultraviolet curable silicone composition according to .9. A cured product of the ultraviolet curable silicone composition according to . The present invention relates to an ultraviolet curable silicone composition and a cured product thereof.In recent years, molding materials for use in 3D printers are being developed actively, and there exists various kinds of molding materials including metal to resin-based materials. While acrylate photocurable resin compositions and urethane acrylate photocurable resin compositions have been mainly employed in the field of resin, the cured products of these compositions are extremely hard and thus cannot be bended (Patent document 1).Flexible materials are now required more often depending on intended uses, and materials suitable for various molding methods have already been developed. For example, as a material intended for stereolithography (SLA), there has been developed a composition comprising an alkenyl group- ...

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Номер записи: 87
11-11-2021 дата публикации

METHOD FOR PRODUCING SILICONE HYDROGEL CONTACT LENSES

Номер: US20210347929A1
Автор: Cheng Jing, Olson Lindsay, Zhang Steve Yun, ZHENG Yang
Принадлежит:

The invention provides a contact lens manufacturing method comprising a process for removing unprocessed molded silicone hydrogel contact lenses from mold halves in a relatively efficient and consistent manner. The method of the invention involves using a silicone fluid (or so-called silicone oil) as non-reactive diluent in SiHy lens formulation for making SiHy contact lenses. Resultant SiHy contact lenses cast-molded from such a SiHy lens formulation can have a significantly reduced adhesion force with the molding surfaces of a lens mold and consequently a higher efficiency and consistency in removing unprocessed molded SiHy contact lenses from mold halves can be achieved. This method of the invention can be easily implemented in a production environment for enhancing the production yield.

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Номер записи: 88
18-11-2021 дата публикации

Aqueous dispersion of polymeric composite microspheres

Номер: US20210355260A1
Автор: Brett L. Zimmerman, Edwin A. NUNGESSER, Ibrahim ERYAZICI, Joseph Grant, Joshua M. Katzenstein, Yihan Liu
Принадлежит: Dow Silicones Corp, Rohm and Haas Co

The present invention relates to a composition comprising an aqueous dispersion of polymeric composite microspheres comprising an aqueous dispersion of polymeric composite microspheres that comprise a polysiloxane and an organophosphate functionalized polymer, as defined herein, and a suspension polymerization process for making the composition. The composition is useful for making defect free coatings with a relatively low coefficient of friction.

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Номер записи: 89
20-08-2020 дата публикации

RESIN COMPONENT DISPOSED IN ROUTE OF BEAM EMITTED BY RADAR DEVICE, RADOME, AND RADAR DEVICE

Номер: US20200262958A1
Автор: Fujioka Shinsuke, Takahashi Yutaro
Принадлежит:

The present invention is a resin component disposed in a path of a beam emitted from a radar equipment, the resin component consisting of a thermoplastic resin composition containing at least one thermoplastic resin selected from a group consisting of a rubbery polymer-reinforced vinyl-based resin wherein a polymer part derived from a rubbery polymer and a vinyl-based resin part containing a structural unit derived from a vinyl-based monomer are chemically bonded, a polyolefin resin, and a polycarbonate resin, and having a dielectric constant of 2.9 or less, and a mold shrinkage rate of 1.2% or less as measured in accordance with JIS K 7152-4. This resin component can be used as a radome and may constitute part of a radar device. 1. A resin component , disposed in a path of a beam emitted from a radar equipment , the resin component comprising a thermoplastic resin composition comprising at least one thermoplastic resin selected from the group consisting of:a rubbery polymer-reinforced vinyl-based resin wherein a polymer part derived from a rubbery polymer and a vinyl-based resin part comprising a structural unit derived from a vinyl-based monomer are chemically bonded,a polyolefin resin, anda polycarbonate resin,wherein the resin component has a dielectric constant of 2.9 or less, andthe resin component has a mold shrinkage rate of 1.2% or less.2. The resin component according to claim 1 ,wherein the dielectric constant of the resin component is 2.8 or less.3. The resin component according to claim 1 ,wherein the dielectric constant of the resin component is 2.7 or less.4. The resin component according to claim 1 ,wherein the dielectric constant of the resin component is 2.6 or less.5. The resin component according to claim 1 ,wherein the dielectric constant of the resin component is 2.5 or less.6. The resin component according to claim 1 ,wherein the thermoplastic resin composition comprises the rubbery polymer-reinforced vinyl-based resin,the rubbery polymer is ...

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Номер записи: 90
05-09-2019 дата публикации

BLOCK COPOLYMER AND METHOD OF PRODUCING THE SAME, AND METHOD OF PRODUCING STRUCTURE CONTAINING PHASE-SEPARATED STRUCTURE

Номер: US20190270852A1
Автор: Dong Lei, Hayakawa Teruaki, Kawana Daisuke, Odashima Rin, Seshimo Takehiro, YAMAZAKI Akiyoshi
Принадлежит:

A block copolymer including a first block consisting of a polymer having a repeating structure of a structural unit (u1) containing no silicon atom, and a second block consisting of a polymer having a repeating structure of a structural unit (u2) containing a silicon atom, the second block containing a block (b21) consisting of a polymer having a repeating structure represented by general formula (u2-1), and a block (b22) consisting of a polymer having a repeating structure of a structural unit (u22) containing a silicon atom, and the block (b22) is positioned between the first block and the block (b21) (wherein Rrepresents an alkyl group, a halogenated alkyl group, a hydrogen atom, or an organic group having a polar group; and Rrepresents an organic group having a polar group). 7. The block copolymer according to claim 1 , which has a number average molecular weight of 5 claim 1 ,000 to 2 claim 1 ,000 claim 1 ,000.8. The block copolymer according to claim 1 , wherein the amount of the block (b22) based on the total amount (100 mol %) of the first block claim 1 , the block (b21) and the block (b22) is 1 to 50 mol %.10. A method of producing a structure containing a phase-separated structure claim 1 , the method comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a step (i) in which a layer containing the block copolymer according to is formed on a substrate, and'}a step (ii) in which the layer containing the block copolymer is phase-separated.12. The method according to claim 10 , which comprises claim 10 , prior to step (i) claim 10 , forming a guide pattern on the substrate. The present invention relates to a block copolymer and a method of producing the same, and a method of producing structure containing phase-separated structure. Priority is claimed on Japanese Patent Application No. 2018-039127, filed on Mar. 5, 2018, the content of which is incorporated herein by reference.Recently, as further miniaturization of large scale integrated circuits (LSI) ...

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Номер записи: 91
09-12-2021 дата публикации

SILICONE HYDROGELS COMPRISING N-ALKYL METHACRYLAMIDES AND CONTACT LENSES MADE THEREOF

Номер: US20210382203A1
Автор: Alli Azaam, Sinha Dola
Принадлежит:

The present invention relates to silicone hydrogels exhibiting desired combinations of physical and mechanical properties, formed from a reactive monomer mixture comprising at least one N-alkyl methacrylamide, and at least one silicone-containing component. These silicone hydrogels may also contain hydrophilic components, crosslinking agents and toughening monomers. These silicone hydrogels are useful in preparing biomedical devices, ophthalmic lenses, and contact lenses. 161-. (canceled)62. The process of any one of to wherein the peripheral region exhibits a lower modulus than the central region.63. The process of wherein the central region exhibits a modulus between about 10 claim 62 ,000 psi and about 200 claim 62 ,000 psi and the peripheral region exhibits a modulus between about 50 psi and about 300 psi.64. The process of wherein the first and second silicone hydrogels comprise water contents within about 5 weight percent of one another.65. The process of wherein the central region is encapsulated by the peripheral region. This application claims priority to U.S. Provisional Patent Application No. 62/358,967, filed Jul. 6, 2016, which is incorporated herein by reference in its entirety.The present invention relates to silicone hydrogels derived from reactive monomer mixtures comprising N-alkyl methacrylamides, and silicone-containing components, and displaying surprising combinations of physical and mechanical properties including modulus. These silicone hydrogels are suitable for use in a number of fields including medical devices, ophthalmic devices, and contact lenses.Soft contact lenses are based upon hydrogels. Many users find soft contact lenses comfortable enough to wear all day. There are two main classes of soft contact lens materials, conventional soft contact lenses which are formed from hydrogels containing no silicone, and silicone hydrogels. Conventional and silicone hydrogels have moduli ranging from about 20 psi to about 300 psi, which allows ...

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Номер записи: 92
27-08-2020 дата публикации

Molding material and method for producing resin molded body using same

Номер: US20200270386A1
Автор: Akihiro Oshima, Kazuyuki Satoh, Mitsuhiro Usugaya, Yoshikage Ohmukai, Yuko Shiotani
Принадлежит: Daikin Industries Ltd, Osaka University NUC

A molding material including a resin material that has a graft chain containing constituent units derived from a fluorine-containing compound and a non-fluorinated compound. The graft chain thereof may be formed, for example, using ionizing radiation.

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Номер записи: 93
27-08-2020 дата публикации

AQUEOUS DISPERSION OF POLYMERIC COMPOSITE MICROSPHERES

Номер: US20200270387A1
Автор: Eryazici Ibrahim, Grant Joseph, Katzenstein Joshua M., Liu Yihan, Nungesser Edwin A., Zimmerman Brett L.
Принадлежит:

The present invention relates to a composition comprising an aqueous dispersion of polymeric composite microspheres comprising an aqueous dispersion of polymeric composite microspheres that comprise a polysiloxane and a polymer, as defined herein, and a suspension polymerization process for making the composition. The composition is useful for making defect free coatings with a relatively low coefficient of friction. 3. The process of wherein each Ris methyl.5. The process of wherein the first stage monomers further comprise from 0.1 to 15 weight percent claim 4 , based on the weight of first stage monomers claim 4 , of a multiethylenically unsaturated nonionic monomer.6. The process of wherein the first composite microspheres are prepared by contacting under polymerization conditions an aqueous dispersion of a polysiloxane and a first monoethylenically unsaturated monomer.7. The process of wherein the dispersion of second composite microspheres is further reacted with a second stage monoethylenically unsaturated nonionic monomer claim 5 , in the presence of a water-soluble initiator/redox couple.8. The process of which further comprises the step of contacting the aqueous dispersion of composite microspheres with one or more components selected from the group consisting of binders claim 1 , thickeners claim 1 , pigments claim 1 , biocides claim 1 , solvents claim 1 , dispersants claim 1 , coalescents claim 1 , opaque polymers claim 1 , and extenders.11. The composition of where each Ris methyl; n is from 10 to 5000; and each Ris H. The present invention relates to an aqueous dispersion of polymeric composite microspheres that comprise a polysiloxane and a polymer. The composite microspheres are useful for preparing formulations that form defective free coatings with a low coefficient of friction.Low-gloss (matte, low-sheen) surfaces can be made applying to a substrate an aqueous dispersion containing organic or inorganic matting agents as well as binders. Organic ...

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Номер записи: 94
16-12-2021 дата публикации

IMIDAZOLIUM ZWITTERION POLYMERIZABLE COMPOUNDS AND OPHTHALMIC DEVICES INCORPORATING THEM

Номер: US20210388141A1
Автор: Mahadevan Shivkumar, Sinha Dola, Zhang Yong
Принадлежит:

Provided are imidazolium zwitterion polymerizable compounds and their applications in ophthalmic devices and packaging solutions. The zwitterionic polymerizable compounds are of formula I: 2. The compound of wherein Ris H or C-Calkyl.3. The compound of wherein Ris H.4. The compound of wherein Ris H.5. The compound of wherein Land Lare independently alkylene claim 1 , cycloalkylene claim 1 , heterocycloalkylene claim 1 , arylene claim 1 , heteroarylene claim 1 , oxaalkylene claim 1 , alkylene-amide-alkylene claim 1 , alkylene-amine-alkylene claim 1 , or combinations thereof.6. The compound of wherein Land Lare independently alkylene.7. The compound of wherein Pcomprises styryl claim 1 , vinyl carbonate claim 1 , vinyl ether claim 1 , vinyl carbamate claim 1 , N-vinyl lactam claim 1 , N-vinylamide claim 1 , (meth)acrylate claim 1 , or (meth)acrylamide.8. The compound of that is:3-(1-(3-methacrylamidopropyl)-1H-imidazol-3-ium-3-yl)propanoate;3-(1-(3-methacrylamidopropyl)-2-methyl-1H-imidazol-3-ium-3-yl)propanoate; or4-(1-(3-methacrylamidopropyl)-2-methyl-1H-imidazol-3-ium-3-yl)butanoate.9. An ophthalmic device comprising a polymer derived from a zwitterionic polymerizable compound according to .10. The ophthalmic device of wherein the polymer is contained in or is coated on the device.11. The ophthalmic device of wherein the polymer comprises a free radical reaction product of the compound and one or more monomers suitable for making the ophthalmic device.12. The ophthalmic device of wherein the monomer suitable for making the ophthalmic device is selected from a hydrophilic component claim 11 , a hydrophobic component claim 11 , a silicone-containing component claim 11 , and mixtures of two or more thereof.13. The ophthalmic device of that is an intraocular lens or a soft contact lens.14. The ophthalmic device of that is a hydrogel contact lens.15. A blister package including an ophthalmic device and a packaging solution claim 1 , wherein the packaging solution ...

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Номер записи: 95
24-09-2020 дата публикации

Conductive coating material and production method for shielded package using conductive coating material

Номер: US20200299523A1
Автор: Hiroaki Umeda, Kazuhiro Matsuda, Ken Yukawa
Принадлежит: Tatsuta Electric Wire and Cable Co Ltd

A conductive coating material is disclosed including at least (A) 100 parts by mass of a binder component including 5 to 30 parts by mass of solid epoxy resin that is solid at normal temperature and 20 to 90 parts by mass of liquid epoxy resin that is liquid at normal temperature, (B) 200 to 1800 parts by mass of silver-coated copper alloy particles in which the copper alloy particles are made of an alloy of copper, nickel, and zinc, the silver-coated copper alloy particles have a nickel content of 0.5% to 20% by mass, and the silver-coated copper alloy particles have a zinc content of 1% to 20% by mass with respect to 100 parts by mass of the binder component (A), and (C) 0.3 to 40 parts by mass of a curing agent with respect to 100 parts by mass of the binder component (A).

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Номер записи: 96
10-11-2016 дата публикации

AZETIDINIUM-CONTAINING COPOLYMERS AND USES THEREOF

Номер: US20160326395A1
Автор: Chang Frank, Chiang Chung-Yuan, Holland Troy Vernon, Kapoor Yash, Pruitt John Dallas, Qiu Yongxing, Scott Robert, Shankar Venkat
Принадлежит:

The invention is related to azetidinium-containing copolymers and vinylic monomers and their uses in formation of non-silicone hydrogel coatings on silicone hydrogel contact lenses. 1. (canceled)3. The azetidinium-containing copolymer of claim 2 , further comprising monomeric units derived from a hydrophobic vinylic monomer claim 2 , wherein the carboxyl-containing vinylic monomer is selected from the group consisting of acrylic acid claim 2 , a C-C-alkyl acrylic acid claim 2 , N claim 2 ,N-2-acrylamidoglycolic acid claim 2 , beta methyl-acrylic acid claim 2 , alpha-phenyl acrylic acid claim 2 , beta-acryloxy propionic acid claim 2 , sorbic acid claim 2 , angelic acid claim 2 , cinnamic acid claim 2 , 1-carboxy-4-phenyl butadiene-1 claim 2 ,3 claim 2 , itaconic acid claim 2 , citraconic acid claim 2 , mesaconic acid claim 2 , glutaconic acid claim 2 , aconitic acid claim 2 , maleic acid claim 2 , fumaric acid claim 2 , and combination thereof claim 2 ,{'sub': 2', '4', '1', '4', '1', '12', '2', '6', '2', '6', '1', '12', '2', '12, 'wherein the amino-containing vinylic monomer is selected from the group consisting of amino-C-Calkyl (meth)acrylate, allylamine, vinylamine, amino-C-Calkyl (meth)acrylamide, N-allyl C-Calkanamine, a coupling reaction product of an epoxy compound having one sole epoxy group with allylamine, vinylamine, amino-C-Calkyl (meth)acrylate, or amino-C-Calkyl (meth)acrylamide, a coupling reaction product of an C-Calkanamine or C-Caminoalkanol or with an epoxy-containing vinylic monomer, and combinations thereof,'}wherein the hydrophobic vinylic monomer is selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, isopropyl (meth)acrylate, butyl (meth)acrylate, sec-butyl (meth)acrylate, isobutyl (meth)acrylate, t-butyl (meth)acrylate, cyclohexylacrylate, 2-ethylhexylacrylate, vinyl acetate, vinyl propionate, vinyl butyrate, vinyl valerate, styrene, chloroprene, vinyl chloride, vinylidene chloride, ...

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Номер записи: 97
09-11-2017 дата публикации

SURFACE MODIFICATION METHOD

Номер: US20170320990A1
Автор: Hoshiba Takashi, Minagawa Yasuhisa, SHIBUYA Tomokazu, TANAKA Masaru
Принадлежит:

Provided are methods for surface-modifying a thermoplastic resin which produce surfaces that show not only low adsorption of proteins and cells but also selective adsorption or adhesion of specific cells such as cancer cells, and further have excellent durability. A method for surface-modifying an object made of a thermoplastic resin, the method including: step 1 of forming polymerization initiation points on the surface of the object; and step 2 of radically polymerizing at least a hydrophilic monomer starting from the polymerization initiation points by irradiation with UV light having a wavelength of 300 to 400 nm to form a graft layer having a thickness of 2 to 100 nm on the surface of the object. 1. A method for surface-modifying an object made of a thermoplastic resin , the method comprising:step 1 of forming polymerization initiation points on a surface of the object; andstep 2 of radically polymerizing at least a hydrophilic monomer starting from the polymerization initiation points by irradiation with UV light having a wavelength of 300 to 400 nm to form a graft layer having a thickness of 2 to 100 nm on the surface of the object.2. A method for surface-modifying an object made of a thermoplastic resin , the method comprisingstep I of radically polymerizing at least a hydrophilic monomer by irradiation with UV light having a wavelength of 300 to 400 nm in the presence of a photopolymerization initiator to form a graft layer having a thickness of 2 to 100 nm on a surface of the object.3. The method according to claim 1 ,wherein step 1 comprises adsorbing a photopolymerization initiator to the surface of the object, optionally followed by irradiation with UV light having a wavelength of 300 to 400 nm, to form polymerization initiation points from the photopolymerization initiator on the surface.4. The method according to claim 3 ,wherein the photopolymerization initiator is at least one of a benzophenone compound or a thioxanthone compound.5. The method ...

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Номер записи: 98
17-11-2016 дата публикации

Polyorganosiloxane-Containing Graft Copolymer, Resin Composition, and Molded Article

Номер: US20160333130A1
Автор: FUJIKAWA Yuichiro, MATSUOKA Shinji, Ueki Sohei, Wakita Ayaka
Принадлежит: MITSUBISHI RAYON CO., LTD.

A graft copolymer capable of providing impact resistance, flame retardance, and color rendering properties to a thermoplastic resin is described. The graft copolymer contains a polyorganosiloxane, and is obtained by graft-polymerizing vinyl monomers including a (meth)acrylate ester (b) having an alkyl group or an aromatic group and an aromatic vinyl monomer (b) on a polyorganosiloxane-based rubber. The graft copolymer has a volume average particle diameter of 200-2000 nm, and contains 0.1-69 mass % of polyorganosiloxane. A thermoplastic resin composition is also described, containing a thermoplastic resin (A), the graft copolymer, a fluorine resin (C) and a flame retardant (D). A molded article is also described, which is obtained by molding the thermoplastic resin composition. 110.-. (canceled)11. A powder comprising a polyorganosiloxane-containing graft copolymer (G2) obtained by graft polymerizing one or more vinyl monomers on a polyorganosiloxane-based rubber , wherein a particle diameter of the polyorganosiloxane-containing graft copolymer (G2) measured with absorptiometry is 300 nm to 2000 nm , an alkali metal content of the powder is 0 ppm to 20 ppm , and an alkaline earth metal content of the powder is 0 ppm to 150 ppm.12. The powder of claim 11 , wherein a sulfur content of the powder is 0 ppm to 200 ppm.13. The powder of claim 11 , wherein the polyorganosiloxane-based rubber is a composite rubber containing the polyorganosiloxane and a polyalkyl(meth)acrylate (PA).14. The powder of claim 11 , wherein the vinyl monomers form a monomer mixture containing an aromatic vinyl monomer.15. The powder of claim 11 , wherein an sp value of the graft part of the polyorganosiloxane-containing graft copolymer (G2) calculated with the Fedors method is 20.15 to 21.00.16. The powder of claim 11 , wherein the vinyl monomers form a monomer mixture containing a crosslinking monomer.1718.-. (canceled)21. A resin composition containing the powder and the resin of .22. The resin ...

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Номер записи: 99
17-11-2016 дата публикации

Photocurable composition and cured product

Номер: US20160333171A1
Автор: Ayumu Kiyomori, Yusuke Itoh
Принадлежит: Shin Etsu Chemical Co Ltd

A photocurable composition comprising (a) a cyano-containing silsesquioxane, (b) a cyano-containing ethylenically unsaturated monofunctional monomer, (c) an ethylenically unsaturated polyfunctional monomer, and (d) a photo-polymerization initiator has a long shelf life under light-shielded conditions. A cured product obtained by curing the photocurable composition is a polymeric material which is transparent and lightweight and has a high dielectric constant.

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Номер записи: 100