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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 18011. Отображено 100.
02-02-2012 дата публикации

Amphiphilic polysiloxane prepolymers and uses thereof

Номер: US20120029111A1
Автор: Arturo N. Medina, Dawn A. Smith, Frank Chang, Jinyu Huang, John Dallas Pruitt, Laura Ann Sanders, Robert Scott
Принадлежит: Individual

The present invention provides an amphiphilic polysiloxane prepolymer which comprises hydrophilic monomeric units derived from at least one hydrophilic vinylic monomer, polysiloxane crosslinking units derived from at least one polysiloxane crosslinker having at least two terminal ethylenically-unsaturated groups, dangling polysiloxane chains each of which is terminated with one ethylenically unsaturated group, and chain-transfer units derived from a chain transfer agent other than a RAFT agent. A prepolymer of the invention is suitable for making hydrogel contact lenses. The present invention is also related to hydrogel contact lenses made from an amphiphilic polysiloxane prepolymer of the invention and to processes for preparing an amphiphilic polysiloxane prepolymer of the invention and for making silicone hydrogel contact lenses.

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Номер записи: 1
09-02-2012 дата публикации

Method For The Production Of Copolymers

Номер: US20120035301A1
Автор: Christian Scholz, Mario Vierle
Принадлежит: CONSTRUCTION RESEARCH AND TECHNOLOGY GmbH

The invention relates to a process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus, comprising a polymerization reactor connected to a metering device, in each case acid monomer being initially taken in the metering device and polyether macromonomer and water in the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, free radical polymerization initiator being passed into the polymerization reactor before and/or during the metering of the acid monomer into the polymerization reactor so that an aqueous medium in which acid monomer and polyether macromonomer are reacted with formation of the copolymer by free radical polymerization forms in the polymerization reactor, the free radical polymerization initiator used being an H 2 O 2 — or alkali metal peroxodisulphate-containing redox initiator system, the temperature of the aqueous medium during the polymerization being adjusted to 5 to 43° C., the temperature of the aqueous medium being not more than 28° C. at the beginning of the polymerization, altogether 1 to 20 mol of acid monomer being metered into the polymerization reactor per mole of polyether macromonomer used, the weight ratio of polyether macromonomer used to water used being 5:1 to 1:5, at least 70% by weight of the water initially taken in the polymerization reactor being provided in the manner such that it is either added to the polymerization reactor at a temperature of not more than 19° C. or it is combined with the polyether macromonomer before it is added to the polymerization reactor and thus has a temperature of not more than 19° C.

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Номер записи: 2
22-03-2012 дата публикации

Ethylene copolymer with peg, cationic and anionic units, cosmetic composition including same and treatment method

Номер: US20120070399A1
Автор: Gwenaëlle JEGOU
Принадлежит: LOreal SA

The present invention relates to novel ethylenic copolymers comprising: a) from 25 to 95% by weight of monomer of formula (I), comprising PEG units; b) from 4 to 50% by weight of cationic monomer or one of its salts; c) from 1 to 35% by weight of anionic monomer and/or its salts. The invention also relates to cosmetic compositions, in particular hair compositions, comprising said copolymers and to a cosmetic treatment method employing them.

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Номер записи: 3
07-06-2012 дата публикации

Acrylate composition

Номер: US20120142867A1
Автор: Daichi Ogawa, Takeshi Iwasaki, Tomoaki Takebe, Yutaka Obata
Принадлежит: Idemitsu Kosan Co Ltd

The invention provides a composition containing (A) one or more (meth)acrylate compounds selected from among a (meth)acryl-modified silicone fluid, a long-chain alkyl(meth)acrylate, and a polyalkylene glycol(meth)acrylate having a number average molecular weight of 400 or more; (B) a (meth)acrylate compound having an alicyclic hydrocarbon group which has six or more carbon atoms and which is bonded to the compound via an ester bond; (C) (meth)acrylic acid or a (meth)acrylate compound having a polar group; and (D) a radical polymerization initiator. The composition is suitably employed as a raw material for, for example, an encapsulating material or a lens, exhibits transparency and heat resistance comparable to conventional levels, and provides a cured product exhibiting excellent adhesion to a base member surrounding the cured product.

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Номер записи: 4
14-06-2012 дата публикации

Photoreactive polymer and method for preparing the same

Номер: US20120149848A1
Автор: Dai-Seung Choi, Dong-Woo Yoo, Heon Kim, Hye-young Jung, Sung-Don Hong, Sung-Ho Chun
Принадлежит: LG Chem Ltd

The present invention relates to a photoreactive polymer that comprises a multi-cyclic compound in a main chain, and a polymerization method thereof. Since the photoreactive polymer according to the present invention comprises a multi-cyclic compound having a high glass transition temperature as a main chain, the thermal stability is excellent, and since the mobility of the main chain is relatively high as compared to that of an additional polymer, a photoreactive group can be freely moved in the main chain of the polymer. Accordingly, it is possible to overcome a slow photoreactive rate that is considered a disadvantage of a polymer material used to prepare an alignment film for known liquid crystal display devices.

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Номер записи: 5
26-07-2012 дата публикации

Reactive systems

Номер: US20120190787A1
Автор: Janin Tecklenburg, Klaus-Wilhelm Lienert, Majdi Al-Masri, Michael Berkei, Sabine Voedisch, Thomas Sawitowski
Принадлежит: Elantas GmbH

Reactive system comprising at least one component (I) composed of particles in very finely divided form present in a liquid phase of at least one further component (II) with which component (I) is capable of reacting following activation through energy supply, wherein component (I) is not soluble in component (II), process for preparation and use.

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Номер записи: 6
30-08-2012 дата публикации

Pressure sensitive adhesive comprising blend of synthetic rubber and functionalized synthetic rubber bonded to an acylic polymer

Номер: US20120216953A1
Автор: Babu N. Gaddam, Guy D. Joly, Jingjing Ma, Peiwang Zhu, Sanat Mohanty, Shujun Wang, Vivek Bharti
Принадлежит: 3M Innovative Properties Co

A pressure sensitive adhesive composition is described comprising unfunctionalized (e.g. polyisobutylene) synthetic rubber and an acrylic polymer having functionalized polyisobutylene polymer bonded to the acrylic polymer. In some embodiments, the functionalized polyisobutylene polymer has a first functional group hydrogen bonded with a second functional group present in the acrylic polymer backbone. In other embodiments, the functionalized polyisobutylene polymer is covalently bonded to the acrylic polymer backbone. Also described are adhesive articles, such as a tape, methods of adhesively bonding, and methods of making a pressure sensitive adhesive.

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Номер записи: 7
27-09-2012 дата публикации

Farnesene interpolymers

Номер: US20120244304A1
Автор: Derek James Mcphee
Принадлежит: Amyris Inc

Farnesene interpolymer comprises units derived from a farnesene (e.g., α-farnesene or β-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an α-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.

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Номер записи: 8
04-10-2012 дата публикации

Curable resin composition, surface protection method, temporary fixation method, and separation method

Номер: US20120246913A1
Автор: Kazuhiro Oshima, Tomoyuki Kanai
Принадлежит: Denki Kagaku Kogyo KK

Provided is a method for protecting the surface of a member to be processed, which comprises providing a protective film made of a photocurable resin composition for surface protection on the surface of the member to be processed, processing the member to be processed, and removing the protective film from the member to be processed, wherein the photocurable resin composition comprises (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton and (D) a photopolymerization initiator, which comprises from 1 to 50 parts by weight of (A), from 5 to 95 by mass of (B) and from 0.1 to 50 parts by mass of (C).

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Номер записи: 9
18-10-2012 дата публикации

Prepregs for manufacturing composite materials

Номер: US20120261060A1
Автор: Barrie Hayes, Daniel Thomas Jones
Принадлежит: Gurit UK Ltd

A prepreg comprising a fibrous material contacting a polymerisable resin, at least 50 wt % of the polymerisable resin comprising at least one polymerisable monomer having at least two carbon-carbon unsaturated functional groups, the monomer being polymerisable by reaction of the unsaturated functional groups to form a cured resin, wherein the resin has a heat of polymerization of less than 230 KJ/kg to provide a maximum increase in temperature of the prepreg of 60° C. during polymerisation under adiabatic conditions.

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Номер записи: 10
18-10-2012 дата публикации

Black curable composition for wafer - level lens, and wafer - level lens

Номер: US20120262793A1
Автор: Masaru Yoshikawa, Yoshiharu Yabuki, Yushi Kaneko
Принадлежит: Fujifilm Corp

A black curable composition for a wafer-level lens including (A) a metal-containing inorganic pigment, (B) a polymerization initiator, (C) a polymerizable compound, and (D) a cardo resin.

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Номер записи: 11
15-11-2012 дата публикации

Polybutadiene derivative composition

Номер: US20120289638A1
Автор: Hiroki Hashimoto, Yukikazu Nobuhara
Принадлежит: Nippon Soda Co Ltd

An object of the present invention is to provide a composition containing a stabilizer which does not turn yellow upon curing and which acts as a polymerization inhibitor during production and storage of a (meth)acrylic modified (hydrogenated) polybutadiene. The curable composition is characterized in that it contains 0.1-99.9999% by weight of component (A) which is a (meth)acrylic modified (hydrogenated) polybutadiene, and 0.0001-10% by weight of component (B) which is a compound represented by formula (IV).

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Номер записи: 12
22-11-2012 дата публикации

Photocurable resin composition and light-emitting element sealant

Номер: US20120296000A1
Автор: Kiyohiko Atami, Naoyuki Oomori, Toshihiko Kurata
Принадлежит: Bridgestone Corp

Provided are a photocurable resin composition which has a short time required for curing to make it possible to enhance the productivity and which can provide a light-emitting element sealant having an excellent heat resistance and an excellent optical transparency and a light-emitting element sealant prepared by using the above photocurable resin composition. To be specific, provided are a photocurable resin composition comprising 100 parts by mass of an end-modified hydrogenated styrene-butadiene rubber (A) and 0.1 to 13 parts by mass of an α-hydroxyalkylphenone base photopolymerization initiator and/or an acylphosphine oxide base photopolymerization initiator and a light-emitting element sealant prepared by using the above photocurable resin composition (B).

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Номер записи: 13
03-01-2013 дата публикации

Compositions comprising a reactive monomer and with a urea or urethane functional group

Номер: US20130004667A1
Автор: David K. Hood, Osama M. Musa
Принадлежит: ISP Investments LLC

Disclosed herein are compositions comprising a reactive monomer, and, in particular, coating and/or reactive coating compositions. More particularly, compositions containing monomers comprising a lactam moiety, a urethane or urea functional group, and a polymerizable moiety are disclosed.

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Номер записи: 14
17-01-2013 дата публикации

Contact lens

Номер: US20130015595A1
Автор: Robert Andrew Broad
Принадлежит: Sauflon CL Ltd

A contact lens formed of a composition comprising the reaction product of: A) at least 10 weight percent, based on the total composition weight excluding solvent, of at least one silicone-containing monomer of the formula I: where n is from 1 to 3, m is from 9 to 15, each a independently is C 1-4 alkyl, and each b independently is C 1-4 alkyl; B) at least 10 weight percent, based on the total composition weight excluding solvent, of 3-methacryloxypropyl tris(trimethylsiloxy)silane; C) N-vinyl pyrrolidone; and D) at least one other non-ionic hydrophilic monomer wherein the combined amount of A) and B) is at least 20 weight percent based on the total composition weight excluding solvent, and wherein the N-vinyl pyrrolidone (NVP) is present in such an amount that the reaction product comprises polyvinyl pyrrolidone (PVP) homopolymer.

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Номер записи: 15
28-03-2013 дата публикации

Novel thickening polymer for ionic oil phases free of monomers

Номер: US20130079420A1
Автор: Jean-Noel Ollagnier, Olivier Braun
Принадлежит: Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA

A copolymer that includes for 100 mol %: a) more than 70 mol % and up to 99.9 mol % of hydrophobic monomer units (A) from stearyl methacrylate; and b) 0.1 mol % to 30 mol % of monomer units (B) from at least one monomer of a compound of formula (I) where R1 is a linear or branched alkyl radical comprising 12 to 22 carbon atoms, R2 is a hydrogen atom or a methyl radical, and n is an integer greater than or equal to 0 and lower than or equal to 30, wherein it is understood that said compound of formula (I) is not stearyl methacrylate. The invention also relates to a method for preparing and using same as a modifier of the rheology of the oil phase of a topical cosmetic, dermopharmaceutical, or pharmaceutical composition.

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Номер записи: 16
18-04-2013 дата публикации

Multilayer adhesive sheet and method for manufacturing electronic component

Номер: US20130092318A1
Автор: Kazunori Shikano, Takeshi Saito
Принадлежит: Denki Kagaku Kogyo KK

Provided is a multilayer adhesive sheet which enables easy separation between an adhesive layer and a die attach film during the pick-up even in cases where an acrylate ester copolymer is used in the die attach film, thereby making the pick-up work of semiconductor chips after the dicing easy. The multilayer adhesive sheet comprises a base film, an adhesive layer that is disposed on one surface of the base film, and a die attach film that is disposed on an exposed surface of the adhesive layer. The adhesive that constitutes the adhesive layer contains: (A) a (meth)acrylate ester copolymer; (B) an ultraviolet polymerizable compound; (C) a multifunctional isocyanate curing agent; (D) a photopolymerization initiator; and (E) a silicone polymer.

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Номер записи: 17
06-06-2013 дата публикации

Liquid resin composition and semiconductor device

Номер: US20130143983A1
Автор: Kouji Makihara, Ryuichi Murayama
Принадлежит: Sumitomo Bakelite Co Ltd

According to the invention, a liquid resin composition which has favorable wet spreadability after mounting of a chip and exhibits excellent solder cracking resistance even in a high-temperature solder reflow process at about 260° C., i.e., even when being used in lead-free solder, and a semiconductor package using the liquid resin composition are provided. In the liquid resin composition of the invention, an acrylic copolymer having a radical polymerizable functional group contains alkyl(meth)acrylate as a constituent monomer having a linear or branched alkyl group having 6 to 9 carbon atoms in an amount of 10 wt % to 40 wt % of the entire constituent monomers.

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Номер записи: 18
04-07-2013 дата публикации

Ionic silicone hydrogels

Номер: US20130168617A1
Автор: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin
Принадлежит: Johnson and Johnson Vision Care Inc

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.

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Номер записи: 19
04-07-2013 дата публикации

Alkaline solubie resin and light sensible resin composition comprising same and use thereof

Номер: US20130171566A1
Автор: Chunmiao Zhou, Jianshe XUE, Jisheng ZHAO, Shi Shu, Xiaoxiong TIAN, Xuelan WANG
Принадлежит: BOE Technology Group Co Ltd

An embodiment of the invention discloses an alkaline soluble resin and a method for preparing the same. The chemical formula of this alkaline soluble resin is shown in Formula I: wherein a is an integer of 1 to 5, b is an integer of 1 to 5, c is an integer of 1 to 10, d is an integer of 1 to 10, m is an integer of 1 to 30, n is an integer of 1 to 10, R is hydrogen, alkyl, alkoxy or acrylate; the alkaline soluble resin has a weight-average molecular weight of 3,500-35,000. The invention also discloses a light sensible resin composition comprising the alkaline soluble resin, as well as a colored photoresist for color filters comprising the aforementioned light sensible resin composition and a display element comprising this colored photoresist.

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Номер записи: 20
18-07-2013 дата публикации

Monomer composition containing unsaturated polyalkylene glycol ether-based monomer, method for producing composition thereof, polymer obtained using composition thereof, and method for producing polymer thereof

Номер: US20130184420A1
Автор: Hiroshi Kawabata
Принадлежит: NIPPON SHOKUBAI CO LTD

To provide a monomer composition containing an unsaturated polyalkylene glycol ether-based monomer and having excellent stability. Provided is a monomer composition containing an unsaturated polyalkylene glycol ether-based monomer represented by the following chemical formula (1): YO(R 1 O) n R 2   (1) [in the formula, Y represents an alkenyl group having 2 to 7 carbon atoms; R 1 O represents one or two or more types of oxyalkylene groups having 2 to 18 carbon atoms; n represents an average addition mole number of oxyalkylene groups and is a number of 5 to 500; and R 2 represents a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms], an organic acid, and water, and having a pH of 4 to 13.

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Номер записи: 21
12-09-2013 дата публикации

Biomedical devices containing internal wetting agents

Номер: US20130237631A1
Автор: Azaam Alli, Douglas G. Vanderlaan, Frank F. Molock, JR., Gregory A. Hill, James D. Ford, Kevin P. Mccabe, Robert B. Steffen
Принадлежит: Johnson and Johnson Vision Care Inc

This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer.

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Номер записи: 22
12-09-2013 дата публикации

(meth)acrylate composition

Номер: US20130237660A1
Автор: Daichi Ogawa, Takeshi Iwasaki, Tomoaki Takebe, Yutaka Obata
Принадлежит: Idemitsu Kosan Co Ltd

Provided is a (meth)acrylate composition containing: (A) at least one (meth)acrylate compound selected from the group consisting of a (meth)acrylate-modified silicone oil, a (meth)acrylate having a long-chain aliphatic hydrocarbon group, and a polyalkylene glycol (meth)acrylate having number-average molecular weight of not less than 400; (B) a (meth)acrylate compound to which an alicyclic hydrocarbon group having 6 or more carbon atoms is ester-linked; (C) (meth)acrylic acid or a (meth)acrylate compound having a polar group; (D) a radical polymerization initiator; and (E) a white pigment.

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Номер записи: 23
03-10-2013 дата публикации

Transfer film and method for producing same, and laminate and method for producing same

Номер: US20130258479A1
Автор: Hideto Yamazawa, Hiroshi Okafuji, Osamu Kawai, Tetsuya Sawano
Принадлежит: Mitsubishi Rayon Co Ltd

Provided is a transfer film wherein: a low-refractive-index film having a refractive index (Nx) and a high-refractive-index film having a refractive index (Ny) are laminated in this order on one surface of a peeling film; the refractive indices satisfy Nx<Ny; and the high-refractive-index film contains an aminosilane. Also provided is a laminate wherein: a high-refractive-index film and a low-refractive-index film are laminated in this order on the surface of a substrate; and the high-refractive-index film contains an aminosilane. The transfer film is obtained by successively laminating and curing a composition for the low-refractive-index film and a composition for the high-refractive-index film on the peeling film. The laminate is produced by bonding the surface of the high-refractive-index film of the transfer film to the substrate, and then peeling away the peeling film.

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Номер записи: 24
03-10-2013 дата публикации

Low Viscosity Synthetic Cement

Номер: US20130261220A1
Автор: Erin Murphy
Принадлежит: KRATON POLYMERS US LLC

The present invention relates to a synthetic cement that comprises a low viscosity monofunctional monomer, a dicyclopentadienyl moiety having a pendant free radical reactive species, 1,3-butyleneglycol dimethacrylate, unsaturated styrenic block copolymer, and a peroxide curing agent. Additionally it may include weighting agents depending on the circumstances of the well, as is well known to those skilled in the art. Other additional components such as oil based mud, suspending agents, Portland cement, acrylates and methacrylates, retardant curing additives, and clays may optionally be incorporated into the synthetic cement. The synthetic cement is activated by heat, for example, and can be crafted to set within a certain time frame, for example in 4 hours, so that it pumpable for as long as need be, and then be set to seal the well in the manner desired.

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Номер записи: 25
07-11-2013 дата публикации

Polymer

Номер: US20130295040A1
Автор: Adam Peter Jarvis, Adrian Carmichael, Andrew Gregory Steward, David M. Haddleton, François LECOLLEY, Giuseppe Mantovani, Lei Tao
Принадлежит: Warwick Effect Polymers Limited

The application provides a method of producing a comb polymer comprising the steps of: (a) Providing: (i) a plurality of monomers which are linear, branched or star-shaped, substituted or non-substituted, and have an olefinically unsaturated moiety, the olefinically unsaturated moiety being capable of undergoing addition polymerisation; (ii) an initiator compound; the initiator compound comprising a homolytically cleavable bond. (iii) a catalyst capable of catalysing the polymerisation of the monomer; and (b) Causing the catalyst to catalyse, in combination with the initiator, the polymerisation of a plurality of the monomers to produce the comb polymer. Catalysts and polymers obtainable by the process are also provided. Preferably, the comb polymer is capable of binding proteins and may be produced from monomers which are alkoxy polyethers, such as poly(alkyleneglycol) or polytetrahydrofuran.

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Номер записи: 26
14-11-2013 дата публикации

Active energy ray-curable resin composition, product having the uneven microstructure, and method for producing product having the uneven microstructure

Номер: US20130302564A1
Автор: Eiko Okamoto, Go Otani, Tsuyoshi Takihara, Yusuke Nakai
Принадлежит: Mitsubishi Rayon Co Ltd

The present invention provides an active energy ray-curable resin composition comprising at least a multifunctional monomer having three or more radical polymerizable functional groups in the molecule in which the cured product of the composition exhibits anti-reflective function because of an uneven microstructure formed on the surface of the cured product, and provides a product having the uneven microstructure having high decontaminating properties such as fingerprint removal properties and high scratch resistance.

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Номер записи: 27
14-11-2013 дата публикации

ARBORESCENT POLYMERS AND PROCESS FOR MAKING SAME

Номер: US20130303688A1
Автор: Kaszas Gabor, Kulbaba Kevin, Puskas Judit E.
Принадлежит:

The present invention relates to arborescent polymers and to a process for making same. In one embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with a polymer or copolymer having a low glass transition temperature (T), and to a process for making such arborescent polymers. In another embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with less than about 5 weight percent end blocks derived from a polymer or copolymer having a high glass transition temperature (T), and to a process for making such arborescent polymers. 1. An end-functionalized arborescent polymer comprising an arborescent elastomeric polymer having two or more branching points and a low glass transition temperature (T) having less than 5 wt. % end blocks derived from a polymer or copolymer having a high glass transition temperature (T).2. The end-functionalized arborescent polymer of claim 1 , wherein the end-functionalized arborescent polymer exhibits thermoplastic elastomeric properties.3. The end-functionalized arborescent polymer of claim 1 , wherein the arborescent elastomeric polymer comprises an arborescent polyisoolefin core.5. The end-functionalized arborescent polymer of claim 4 , wherein the inimer of Formula (I) comprises either an aryl or alkyl group joining A and B.6. The end-functionalized arborescent polymer of claim 4 , wherein the inimer of Formula (I) comprises a benzene ring joining A and B.8. The end-functionalized arborescent polymer of claim 4 , wherein the arborescent elastomeric polymer is formed from at least one inimer selected from the group consisting of 4-(2-hydroxyisopropyl)styrene claim 4 , 4-(2-methoxyisopropyl)styrene claim 4 , 4-(1-methoxyisopropyl)styrene claim 4 , 4-(2-chloroisopropyl)styrene claim 4 , 4-(2-acetoxyisopropyl)styrene claim 4 , 2 claim ...

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Номер записи: 28
21-11-2013 дата публикации

Hard coat coating composition for metal base material and molded product

Номер: US20130309510A1
Автор: Takashi Isogai
Принадлежит: Fujikura Kasei Co Ltd

A hard coat coating composition for a metal base material, includes a coated film forming component including a urethane(meth)acrylate (A) having a carboxyl group and having a solid fraction acid value being value of 0.5 to 2.0 mgKOH/g, a urethane(meth)acrylate (B) not having a carboxyl group, a thermoplastic resin (C) having a carboxyl group and having a solid fraction acid value of 1.0 to 30 mgKOH/g, and a silane coupling agent (D).

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Номер записи: 29
28-11-2013 дата публикации

Modifier for polyvinylidene fluoride, binder resin composition for battery, electrode for secondary battery and battery

Номер: US20130316234A1
Автор: Fumino Momose, Mitsufumi Nodono
Принадлежит: Mitsubishi Rayon Co Ltd

A modifier for polyvinylidene fluoride (PVDF), which improves the adhesion of PVDF to a metal, a binder resin composition for battery and a battery using the PVDF modifier are provided. The modifier for polyvinylidene fluoride herein is a modifier in which the peeling strength of a specific cured film to an aluminium foil is 20 g/cm or more, and the specific cured film is obtained from a mixture of 6 parts by mass of the modifier for polyvinylidene fluoride and 14 parts by mass of a polyvinylidene fluoride composition. The modifier preferably contains a macromonomer copolymer (X), obtained by polymerizing both a macromonomer (A) having unsaturated double bonds and a vinyl monomer (B) having polar groups. The macromonomer (A) is preferably a methacrylic acid ester-based macromonomer (A-1). The vinyl monomer (B) is preferably a methacrylate, and a fluoroalkyl methacrylate.

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Номер записи: 30
06-03-2014 дата публикации

Nanoimprint curable composition, nanoimprint-lithographic molded product, and method for forming pattern

Номер: US20140061970A1
Автор: Hisashi Tanimoto, Hitoshi Sekine, Naoto Yagi, Yasuhiro Takada
Принадлежит: DIC Corp

The present invention provides a nanoimprint curable composition to be used in “nanoimprint lithography” in which a nanoimprint mold is pressed to transfer a fine concave-convex pattern, the nanoimprint curable composition containing a composite resin which has a polysiloxane segment and a polymer segment other than the polysiloxane segment, the polysiloxane segment containing a silanol group and/or hydrolyzable silyl group and having a polymerizable double bond. In addition, the present invention provides a nanoimprint-lithographic molded product, resist film, resin mold, and method for forming a pattern, which each involves use of the nanoimprint composition.

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Номер записи: 31
02-01-2020 дата публикации

RESIN COMPOSITION, PREPREG, RESIN-COATED FILM, RESIN-COATED METAL FOIL, METAL-CLAD LAMINATE, AND WIRING BOARD

Номер: US20200001573A1
Автор: FUJIWARA Hiroaki, SAITO Hirosuke, Tsuda Kosuke
Принадлежит: Panasonic Intellectual Property Management Co., Ltd.

A resin composition which comprises: a modified polyphenylene ether having, at a terminal, a group represented by a formula (1) given below; a radical-polymerizable compound having, only at molecular terminals, two or more bonds or groups of at least one selected from the group consisting of a carbon-carbon unsaturated double bond and a maleimide group; a styrene-based thermoplastic elastomer in which repeating units having a carbon-carbon unsaturated double bond not belonging to an aromatic ring are contained in an amount less than 10 mol % with respect to all the repeating units; and an organic peroxide. In the formula (1), Rrepresents a hydrogen atom or an alkyl group. 2. The resin composition according to claim 1 , wherein claim 1 , in the styrene-based thermoplastic elastomer claim 1 , a ratio of the repeating units having a carbon-carbon unsaturated double bond contained in a molecular chain among the repeating units having a carbon-carbon unsaturated double bond not belonging to an aromatic ring is less than 3 mol % with respect to all the repeating units.3. The resin composition according to claim 2 , wherein the carbon-carbon unsaturated double bond contained in the molecular chain is a vinylene group.4. The resin composition according to claim 1 , wherein the radical-polymerizable compound is a radical-polymerizable compound having claim 1 , only at molecular terminals claim 1 , two or more groups of at least one selected from the group consisting of allyl group claim 1 , vinyl group claim 1 , acrylate group claim 1 , methacrylate group claim 1 , and maleimide group.5. The resin composition according to claim 1 , wherein the modified polyphenylene ether has a weight average molecular weight of 500 to 3000 and has claim 1 , at a molecular terminal claim 1 , an average of 1 to 5 groups represented by the formula (1) given above per one molecule.6. The resin composition according to claim 1 , wherein the styrene-based thermoplastic elastomer has a weight ...

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Номер записи: 32
03-01-2019 дата публикации

ANTIFOULING FILM

Номер: US20190001612A1
Автор: HAYASHI Hidekazu, NIINOH Atsushi
Принадлежит:

The antifouling film includes a polymer layer that includes on a surface thereof an uneven structure provided with multiple projections at a pitch not longer than a wavelength of visible light. The polymer layer has a proportion of the number of fluorine atoms relative to the sum of the numbers of carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms of 33 atom % or more on the surface of the uneven structure. The polymer layer has at least one local maximum of the proportion of the number of nitrogen atoms relative to the sum of the numbers of carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms in a region 5 to 90 nm deep from the surface of the uneven structure. The local maximum is 0.3 atom % or more greater than the average value in a region 90 to 120 nm deep from the surface of the uneven structure. 1. An antifouling film comprisinga polymer layer that includes on a surface thereof an uneven structure provided with multiple projections at a pitch not longer than a wavelength of visible light,the polymer layer being a cured product of a resin containing an antifouling agent and a curable resin and containing carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms as constituent atoms,the antifouling agent containing fluorine atoms as constituent atoms,the curable resin containing nitrogen atoms as constituent atoms,fluorine atoms in the antifouling agent being distributed on the surface of the polymer layer,the polymer layer having a proportion of the number of the fluorine atoms relative to the sum of the numbers of the carbon atoms, the nitrogen atoms, the oxygen atoms, and the fluorine atoms measured by X-ray photoelectron spectroscopy of 33 atom % or more on the surface of the uneven structure,the polymer layer having at least one local maximum of the proportion of the number of the nitrogen atoms relative to the sum of the numbers of the carbon atoms, the nitrogen atoms, the oxygen atoms, and the fluorine atoms measured by X-ray ...

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Номер записи: 33
07-01-2016 дата публикации

Additive for hydraulically setting compounds

Номер: US20160002435A1
Автор: Alexander Kraus, Harald Grassl, Luc Nicoleau, Martin Winklbauer, Torben GÄDT
Принадлежит: CONSTRUCTION RESEARCH AND TECHNOLOGY GmbH

The present invention relates to an additive for hydraulically setting compositions, comprising a colloidally disperse preparation of at least one water-soluble salt of a polyvalent metal cation, at least one compound capable of releasing an anion which forms a sparingly soluble salt with the polyvalent metal cation, and at least one polymeric dispersant which comprises anionic and/or anionogenic groups and polyether side chains.

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Номер записи: 34
04-01-2018 дата публикации

FREE RADICALLY POLYMERIZABLE SILOXANES AND SILOXANE POLYMERS

Номер: US20180002471A1
Автор: Craig Bradley A., HUMPAL PAUL E., Mazurek Mieczyslaw H., Sherman Audrey A.
Принадлежит:

Free radically polymerizable synthons for preparing siloxane polyoxamide copolymers are prepared by reacting amine-terminated siloxane polyoxamide compounds with an isocyanate-functional (meth)acrylate, an isocyanate-functional vinyl-substituted aromatic compound, or a vinyl azlactone. These free radically polymerizable synthons can be used to prepare polymer compositions by combining the free radically polymerizable synthons with an initiator and initiating polymerization. 1. A free radically polymerizable compound comprising the formula:{'br': None, 'sup': 3', '3', '1', '1', '1', '3', '3, 'sub': 2', '2', 'n', '2', 'p', 'r, 'X—[—RN—Z—NR]—{—(CO)(CO)—[NH—Y—Sir—(OSir)—OSir—Y—NH—(CO)(CO)—]—[—RN—Z—NR]—}—X'}{'sup': '1', 'wherein each Ris independently an alkyl, haloalkyl, aralkyl, aryl, or aryl substituted with an alkyl, alkoxy, or halo;'}each Y is independently a divalent alkylene, aralkylene, or a combination thereof;each Z is independently a divalent or higher-valent polydiorganosiloxane, alkylene, aralkylene, heteroalkylene, or branched alkylene group;{'sup': 3', '3, 'each Ris hydrogen or alkyl or Rtaken together with Z and with the nitrogen to which they are both attached forms a heterocyclic group;'}each X is independently a free radically polymerizable group;n is independently an integer of 0 to 1500;p is an integer of 1 or greater; andr is an integer of 1 or greater.2. The free radically polymerizable compound of claim 1 , wherein each Ris methyl.3. The free radically polymerizable compound of claim 1 , wherein Y is an alkylene having 1 to 4 carbon atoms.4. The free radically polymerizable compound of claim 1 , wherein Z is a —Y—Sir—(OSir)—OSir—Y— group wherein m is an integer of 0 to 1500.5. The free radically polymerizable compound of claim 1 , wherein Z is an alkylene claim 1 , aralkylene claim 1 , heteroalkylene claim 1 , or branched alkylene group comprising 2-20 carbon atoms.6. The free radically polymerizable compound of claim 1 , wherein each X group ...

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Номер записи: 35
04-01-2018 дата публикации

Low-temperature-curable cross-section repair material, and cross-section repairing method using the same

Номер: US20180002562A1
Автор: Atsushi Umino, Kunihiro Kuroki
Принадлежит: Showa Denko KK

Provided is a low-temperature-curable cross-section repair material which can be cured in a short period of time, even in extremely low temperature environments of −25° C., and which exhibits excellent workability and strength development. Also provided is a cross-section repairing method using the same. The low-temperature-curable cross-section repair material is characterized by: comprising 100 parts by of a radical polymerizable resin composition (A), 0.1-10 parts by of a hydroxyl group-containing aromatic tertiary amine (C-1), 0.1-10 parts by of an organic peroxide (D), and 1.0-500 parts by of an inorganic filler (E); and the radical polymerizable resin composition (A) comprising at least one type of radical polymerizable resin (A-1) selected from the group consisting of vinyl ester resins, urethane (meth)acrylate resins and polyester (meth)acrylate resins, and a radical polymerizable unsaturated monomer (A-2) having at least two or more (meth)acryloyl groups per molecule thereof.

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Номер записи: 36
07-01-2021 дата публикации

COPOLYMER COMPATIBILIZERS AND USES THEREOF

Номер: US20210002406A1
Автор: ARRINGTON Kyle, Chen Junyi, Edgar Kevin, MATSON John
Принадлежит:

Described herein are block copolymers that can be used as compatibilizers. The block copolymers can be graft block or triblock copolymers. The block copolymers can include a polysaccharide or a polyester and a polyolefin. Also described herein are polymer blends that can include and be made using the block copolymers described herein. 1. An ABA triblock copolymer comprising:a polysaccharide, wherein the polysaccharide is the A block polymer; anda polyolefin, wherein the polyolefin is the B block polymer.2. The ABA triblock copolymer of claim 1 , wherein the B block polymer is a polybutadiene.3. The ABA triblock copolymer of claim 1 , wherein the polysaccharide is cellulose or a cellulose derivative.4. The ABA triblock copolymer of claim 3 , wherein the polysaccharide is cellulose triacetate.5. The ABA triblock copolymer of claim 3 , wherein the polysaccharide is methyl cellulose.6. The ABA triblock copolymer of claim 4 , wherein the B block polymer is a polybutadiene.7. A graft block copolymer having the structure A-g-B comprising:a polyolefin, wherein the polyolefin is the A-block polymer; anda polysaccharide, wherein the polysaccharide is the B block polymer.8. The graft block copolymer of claim 7 , wherein the polysaccharide is cellulose triacetate.9. The graft block copolymer of claim 7 , wherein the polyolefin is polybutadiene.10. A polymer blend comprising: wherein the ABA triblock copolymer comprises a polysaccharide, wherein the polysaccharide is the A block polymer and a polyolefin, wherein the polyolefin is the B block polymer, and', 'wherein the graft copolymer comprises a polyolefin, wherein the polyolefin is the A-block polymer and a polysaccharide, wherein the polysaccharide is the B block polymer., 'a compatibilizer, wherein the compatibilizer is an ABA triblock copolymer or a graft copolymer having the structure A-g-B,'}11. The polymer blend of claim 10 , wherein the compatibilizer is present at a wt. % ranging from about 0.5 wt. % to about 10 wt. %. ...

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Номер записи: 37
03-01-2019 дата публикации

ONE-PART CURABLE SOFT FEEL COATINGS

Номер: US20190002616A1
Автор: DRUJON Xavier, GUPTA Manjuli, KLANG Jeffrey, Spagnola Lisa M.
Принадлежит:

Disclosed herein arc one part, One-part, curable compositions that have a soft feel when applied as a coating/film and cured, may include a) at least one isocyanurate tri(meth)acrylate or derivative thereof; and at least one of components b)-e), wherein: b) is at least one urethane diacrylate; c) is at least one monofunctional or difunctional reactive diluent; d) is at least one solvent; and e) is additives. The one-part, curable compositions are advantageous with respect to softness and tailorability of softness as well as other properties such as mar resistance, abrasion resistance, stain resistance and chemical resistance. Due to their advantageous properties, embodiments of the one-part, curable compositions described herein are viable for a wide range of coating applications including automotives, aeronautics, cosmetics, small appliances, packaging and consumer electronics. Methods of making and using the one-part, curable are also described herein. 1. A one-part , curable composition comprising: b) at least one urethane diacrylate;', 'c) at least one monofunctional or difunctional reactive diluent, different from b)', 'd) at least one solvent; and', 'e) additives., 'a) at least one isocyanurate tri(meth)acrylate or derivative thereof and at least one of2. The one-part claim 1 , curable composition of claim 1 , wherein the composition comprises the b) at least one urethane diacrylate.3. The one-part claim 1 , curable composition of claim 1 , wherein the a) at least one isocyanurate tri(meth)acrylate or derivative thereof comprises tris(2-hydroxyethyl)isocyanurate triacrylate.4. The one-part claim 1 , curable composition of claim 1 , wherein the composition comprises the d) at least one solvent.5. The one-part claim 1 , curable composition of claim 1 , wherein the composition comprises the e) additives claim 1 , wherein the additives are selected from the group consisting of photo-initiators claim 1 , thermal free radical initiators claim 1 , accelerators claim ...

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Номер записи: 38
03-01-2019 дата публикации

RADICALLY CURABLE COMPOSITION AND CURED PRODUCT THEREOF

Номер: US20190002617A1
Автор: Kotani Jun
Принадлежит: KANEKA CORPORATION

A radically curable composition includes 100 parts by weight of a (meth)acrylic polymer (I) with an average of at least 0.8 radically-crosslinkable groups, 0.01 to 10 parts by weight of a radical polymerization initiator (II), and 10 to 100 parts by weight of a (meth)acrylate compound (III) having a rosin ester group. 1. A radically curable composition comprising:100 parts by weight of a (meth)acrylic polymer (I) with an average of at least 0.8 radically-crosslinkable groups;0.01 to 10 parts by weight of a radical polymerization initiator (II); and10 to 100 parts by weight of a (meth)acrylate compound (III) having a rosin ester group.2. The radically curable composition according to claim 1 , wherein the (meth)acrylic polymer (I) is a (meth)acrylic polymer having a radically-crosslinkable carbon-carbon double bond at a molecular terminal.3. The radically curable composition according to claim 1 , wherein the (meth)acrylic polymer (I) is a (meth)acrylic polymer having a (meth)acryloyl group at a molecular terminal.4. The radically curable composition according to claim 1 , wherein the (meth)acrylic polymer (I) has a molecular weight distribution of less than 1.8.5. The radically curable composition according to claim 1 , wherein the (meth)acrylic polymer (I) is obtained by polymerization or copolymerization of an acrylic acid alkyl ester monomer containing a saturated hydrocarbon group having 4 to 22 carbon atoms.6. The radically curable composition according to claim 1 , wherein the radical polymerization initiator (II) is a radical photoinitiator.7. The radically curable composition according to claim 1 , wherein the (meth)acrylate compound (III) is 1-acrylic acid-3-dehydroabietic acid-2-hydroxypropyl.8. A cured product obtained from the radically curable composition according to .9. A vibration damping material composed of the cured product according to .10. A pressure-sensitive adhesive composed of the cured product according to .11. An impact absorbing material ...

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Номер записи: 39
03-01-2019 дата публикации

POLYURETHANE (METH)ACRYLATE OLIGOMERS AND CURABLE COMPOSITIONS COMPRISING SAID OLIGOMERS

Номер: US20190002618A1
Автор: FAN Mingxin, OUYANG Liusheng, Shi Aibin, SHI ZHENG, YANG Qian T.
Принадлежит:

A polyurethane (meth)acrylate oligomer, having a tri-block symmetric structure BAB, comprises a polyether central block A linked by two urethane bonds to respectively two terminal hydrophobic blocs B based on hydrophobic polyester oligomers having a terminal (meth)acryloyloxy alkylene group. A curable composition (1k) comprises the oligomer and may be used for soft touch coatings in electronics, consumer goods and vehicle manufacture, as the resulting cured soft touch coating. 1. Polyurethane (meth)acrylate oligomer , wherein it has a tri-block symmetric structure B— A—B , comprising a polyether central block A linked by urethane bonds of two diisocyanate molecules , to respectively two terminal hydrophobic blocs B based on hydrophobic polyester oligomers generated from polylactones , having a terminal (meth)acryloyloxy alkylene group.2. Polyurethane oligomer according to claim 1 , wherein it has the following general formula (I):{'br': None, 'B—OCONH—R—NHCOO—A—OCONH—R—NHCOO—B \u2003\u2003(I)'}withA: the residue of a polyether diolOCONH—RNHCOO: urethane link or bond of a diisocyanate R—(NCO)2 with R being the residue of said diisocyanate, wherein R may have an aromatic, aliphatic or cycloaliphatic structure or R has a cycloaliphatic structure including hydrogenated aromatic structure,B: the residue of a hydrophobic polyester oligomer, bearing in terminal position a (meth)acryloyloxy alkylene group linked to said polyester oligomer chain, by an ester bond (—CO2—).3. Polyurethane oligomer according to claim 1 , wherein said alkylene in said (meth)acryloyloxy alkylene terminal group is a C2 to C8 alkylene.4. Polyurethane oligomer according to claim 1 , wherein said hydrophobic polyester oligomer residue comprises in its structural repeating unit claim 1 , at least 5 consecutive methylene groups and up to 12 methylene groups.5. Polyurethane oligomer according to claim 1 , wherein said polyester oligomer is a polycaprolactone oligomer bearing said terminal (meth) ...

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Номер записи: 40
07-01-2021 дата публикации

RESIN COMPOSITION, PREPREG, RESIN-INCLUDING FILM, RESIN-INCLUDING METAL FOIL, METAL-CLAD LAMINATE, AND WIRING BOARD

Номер: US20210002480A1
Автор: FUJISAWA Hiroyuki, Nakamura Yoshihiko, SHINPO Takashi, TOSHIMITSU KENICHI, TUMURAYA Yuuji, YAMAUCHI AKIHIRO
Принадлежит: Panasonic Intellectual Property Management Co., Ltd.

A resin composition is used which contains a maleimide compound represented by the following Formula (1), a modified polyphenylene ether compound of which a terminal is modified with a substituent having a carbon-carbon unsaturated double bond, and a crosslinking agent containing an allyl compound. 2. The resin composition according to claim 1 , wherein the crosslinking agent further includes at least one of a polyfunctional acrylate compound having two or more acryloyl groups in a molecule and a polyfunctional methacrylate compound having two or more methacryloyl groups in a molecule.3. The resin composition according to claim 2 , wherein the polyfunctional methacrylate compound includes a dimethacrylate compound.4. The resin composition according to claim 1 , wherein the allyl compound includes at least one of triallyl isocyanurate and diallyl bisphenol.5. The resin composition according to claim 1 , wherein a content of the maleimide compound is 10 to 60 parts by mass with respect to 100 parts by mass of a total mass of the maleimide compound claim 1 , the modified polyphenylene ether compound claim 1 , and the crosslinking agent.6. The resin composition according to claim 1 , wherein a content of the modified polyphenylene ether compound is 10 to 75 parts by mass with respect to 100 parts by mass of a total mass of the maleimide compound claim 1 , the modified polyphenylene ether compound claim 1 , and the crosslinking agent.7. The resin composition according to claim 1 , further comprising an inorganic filler treated in advance with a silane coupling agent.8. A prepreg comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the resin composition according to or a semi-cured product of the resin composition; and'}a fibrous base material.9. A film with resin comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a resin layer containing the resin composition according to or a semi-cured product of the resin composition; and'}a support film.10. A ...

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Номер записи: 41
03-01-2019 дата публикации

Functionalized (poly)alkoxylated (per)fluoropolyether polymers

Номер: US20190002633A1
Автор: Giovanni Simeone, Pier Antonio Guarda, Silvia Rita Petricci
Принадлежит: Solvay Specialty Polymers Italy SpA

The present invention relates to novel derivatives of (poly)alkoxylated (per)fluoropolyethers, also referred to as PFPE-PAGs, comprising unsaturated end groups bearing acrylate, allylic or vinylic moieties.

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Номер записи: 42
03-01-2019 дата публикации

ENVIRONMENTALLY-SENSITIVE MATERIAL AND METHOD FOR MANUFACTURING SAME

Номер: US20190002643A1
Автор: CHIEN HSIU-WEN
Принадлежит:

An environmentally-sensitive material includes a sensitive layer and a base. The sensitive layer includes a mixed portion and a sensitive portion seamlessly connected to the mixed portion. The mixed portion is made of a mixture of a first polymer gel and a second polymer gel. The sensitive portion is made of the second polymer gel. The second polymer gel is a reversible gel which is able to revert to an original size and state as a changed environmental factor reverts to a starting state. A method for manufacturing the material is also provided. 1. An environmentally-sensitive material , comprising:a sensitive layer, comprising a mixed portion and a sensitive portion, the mixed portion having a first side and a second side opposite to the first side, the entire sensitive portion being seamlessly connected to the second side of the mixed portion, the mixed portion being a mixture of a first polymer gel and a second polymer gel, the sensitive portion being the second polymer gel, the second polymer gel being a reversible gel; anda base adhered with the sensitive layer.2. The environmentally-sensitive material of claim 1 , wherein the first polymer gel is a non-sensitive gel.3. The environmentally-sensitive material of claim 2 , wherein the first polymer gel is a polyethyleneglycol based hydrogel.4. The environmentally-sensitive material of claim 3 , wherein the second polymer gel is a thermo-sensitive gel.5. The environmentally-sensitive material of claim 4 , wherein the second polymer gel is a poly N-isopropylacrylamide based hydrogel.6. The environmentally-sensitive material of claim 5 , wherein the second polymer gel is polymerized by a gel pre-polymer mixture claim 5 , comprising a mixture of N-isopropylacrylamide claim 5 , ethylene glycol dimethacrylate claim 5 , and an initiator; the second polymer gel has a critical solution temperature of about 37 degrees Celsius.7. The environmentally-sensitive material of claim 1 , wherein from the first side of the mixed ...

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Номер записи: 43
03-01-2019 дата публикации

AQUEOUS DISPERSIONS, COATING COMPOSITIONS FORMED WITH AQUEOUS DISPERSIONS, AND MULTI-LAYER COATINGS

Номер: US20190002709A1
Автор: Sadvary Richard J., Swarup Shanti, Xu Xiangling, Zhou Hongying
Принадлежит:

An aqueous dispersion includes an aqueous medium and self-crosslinkable core-shell particles dispersed in the aqueous medium. The core-shell particles include (1) a polymeric core at least partially encapsulated by (2) a polymeric shell having urethane linkages, keto and/or aldo functional groups, and hydrazide functional groups. Further, the polymeric core is covalently bonded to at least a portion of the polymeric shell. 1. An aqueous dispersion comprising an aqueous medium and self-crosslinkable core-shell particles dispersed in the aqueous medium , wherein the core-shell particles comprise (1) a polymeric core at least partially encapsulated by (2) a polymeric shell comprising urethane linkages , keto and/or aldo functional groups , and hydrazide functional groups , andwherein the polymeric core is covalently bonded to at least a portion of the polymeric shell.2. The aqueous dispersion of claim 1 , wherein the polymeric core of the self-crosslinkable core-shell particles comprises an addition polymer derived from ethylenically unsaturated monomers.3. The aqueous dispersion of claim 2 , wherein the ethylenically unsaturated monomers comprise a (meth)acrylate monomer claim 2 , a vinyl monomer claim 2 , or a combination thereof.4. The aqueous dispersion of claim 1 , wherein the polymeric shell of the self-crosslinkable core-shell particles further comprises at least one water dispersible group.5. The aqueous dispersion of claim 4 , wherein the at least one water dispersible group is selected from carboxylic acid functional groups claim 4 , salts thereof and/or polyoxyalkylene groups.6. The aqueous dispersion of claim 1 , wherein the self-crosslinkable core-shell particles are formed from a mixture of reactants comprising: (a) isocyanate-functional ethylenically unsaturated polyurethane prepolymers; (b) a Michael addition reaction product of ethylenically unsaturated monomers comprising a keto and/or aldo functional group claim 1 , and a compound comprising at least ...

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Номер записи: 44
14-01-2021 дата публикации

CORE-CORONA POLYMER PARTICLES

Номер: US20210007965A1
Автор: FUKUHARA Ryushi, SUGIYAMA Yuki
Принадлежит: SHISEIDO COMPANY, LTD.

Provided are a raw material for a cosmetic and an oil-in-water emulsion cosmetic comprising a core-corona polymer particle excellent in emulsion stability and feeling of use. Certain embodiments of the present invention provides a raw material for a cosmetic, comprising a core-corona polymer particle dispersion obtained by radical-polymerizing a polyethylene oxide macromonomer represented by formula (1) and one or two or more of hydrophobic monomers represented by formulas (2) and (3) under conditions (A) to (D). 2. An emulsifier comprising a core-corona polymer particle according to .3. A clouding agent comprising a core-corona polymer particle according to .4. The core-corona polymer particle according to claim 1 , wherein a particle size of the core-corona polymer particle is 50 to 600 nm.5. A cosmetic raw material comprising a core-corona polymer particle according to .6. A raw material for a cosmetic claim 1 , comprising a core-corona polymer particle according to and ethylene glycol dimethacrylate as a cross-linking agent.7. An oil-in-water emulsion cosmetic comprising a core-corona polymer particle according to .8. A water-in-oil emulsion cosmetic comprising a core-corona polymer particle according to . The present application claims the priority of Japanese Patent Application No. 2018-057271 filed on Mar. 23, 2018, which is incorporated herein.The present invention relates to a core-corona polymer particle. Particularly, the present invention relates to improvement in the emulsion stability and usability of a cosmetic containing the same.For stably dispersing a liquid in another liquid, emulsion cosmetics in the conventional sense require adding a surface-active substance (emulsifier). The emulsifier has an amphiphilic molecular structure and is constituted by polar (hydrophilic) and nonpolar (hydrophobic) moieties.In emulsion cosmetics for use in cosmetic products, etc., aqueous components and oil components are stably mixed by the emulsifying effect of an ...

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Номер записи: 45
12-01-2017 дата публикации

Method For Treating Clay And Clay-Bearing Aggregates and Compositions Therefor

Номер: US20170008800A1
Автор: Kuo Lawrence, Kwon O-il, Lee Ho, Tregger Nathan
Принадлежит:

The present invention provides compositions and methods involving the use of a carboxylate graft polymer having high molecular weight and low ratio of acid-to-polyoxyalkylene groups. Such clay-mitigation is particularly useful for treating clay and clay-bearing aggregates, particularly those aggregates used for construction purposes. The present invention minimizes the need to wash the aggregates, thus preserving fine aggregates (“fines”) content in construction materials, and thereby beneficiating the performance and/or properties of construction materials containing the clay-bearing aggregates. 118-. (canceled)2021-. (canceled)22. The method of wherein the carboxylate graft polymer composition further comprises at least one repeating unit of a polymerized (meth)acrylamide claim 19 , N-alkyl (meth)acrylamide claim 19 , N claim 19 ,N-dialkyl (meth)acrylamide claim 19 , 3-acrylamido-2-methylpropane sulfonic acid or its salts claim 19 , and styrene sulfonic acid or its salt claim 19 , or mixtures thereof.23. The method of wherein the plurality of clay-bearing aggregates comprises natural or manufactured sand claim 19 , crushed stone claim 19 , crushed gravel claim 19 , crushed rock claim 19 , crushed shale claim 19 , or mixtures thereof.24. The method of wherein said carboxylate graft polymer is mixed with the plurality of clay-containing aggregates in an amount of 0.1% to 100% by weight based on dry weight of clay contained in said plurality of aggregates.25. The method of wherein the carboxylate graft polymer is mixed with said plurality of clay-containing aggregates in an amount of 1% to 50% by weight based on dry weight of clay contained in said plurality of aggregates.26. The method of wherein said cementitious composition further comprises at least one chemical admixture selected from the group consisting of water-reducing agent claim 19 , set retarders claim 19 , set accelerators claim 19 , air entraining agents claim 19 , air detraining agents claim 19 , and ...

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Номер записи: 46
14-01-2021 дата публикации

Curable composition for polymer electrolyte, and layered body

Номер: US20210008859A1
Автор: Kazumasa Inata
Принадлежит: TOAGOSEI CO LTD

Provided is a curable composition for a polymer electrolyte, including: a component (A): a radical polymerizable compound having a (meth)acryloyl group, a component (B): a compound having, in one molecule, an epoxy group and a skeleton of at least one selected from the group consisting of polybutadiene, polyisoprene, hydrogenated polybutadiene, and hydrogenated polyisoprene, and a component (C): a radical polymerization initiator, in which a content of each of the components (A) to (C) based on the entire composition is as follows, the component (A): from 30 to 98.9% by mass the component (B): from 1 to 40% by mass, and the component (C): from 0.1 to 15% by mass.

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Номер записи: 47
08-01-2015 дата публикации

Silicone hydrogels having a structure formed via controlled reaction kinetics

Номер: US20150011672A1
Автор: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin
Принадлежит: Johnson and Johnson Vision Care Inc

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.

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Номер записи: 48
14-01-2021 дата публикации

HYDROPHILIZED POLYDIORGANOSILOXANE VINYLIC CROSSLINKERS AND USES THEREOF

Номер: US20210009743A1
Автор: Chang Frank, HUANG JINYU, Jing Feng, Zhang Steve Yun
Принадлежит:

The invention provides a hydrophilized polydiorganosiloxane vinylic crosslinker which comprises (1) a polydiorganosiloxane polymer chain comprising dimethylsiloxane units and hydrophilized siloxane units each having one methyl substituent and one monovalent C-Corganic radical substituent having two to six hydroxyl groups, wherein the molar ratio of the hydrophilized siloxane units to the dimethylsiloxane units is from about 0.035 to about 0.15, and (2) two terminal (meth)acryloyl groups. The hydrophilized polydiorganosiloxane vinylic crosslinker has a number average molecular weight of from about 3000 Daltons to about 80,000 Daltons. The present invention is also related to a silicone hydrogel contact lens, which comprises repeating units derived from a hydrophilized polydiorganosiloxane vinylic crosslinker of the invention. 125-. (canceled)27. The silicone hydrogel contact lens of claim 26 , wherein in formula (1) Xis O.28. The silicone hydrogel contact lens of claim 27 , wherein in formula (1) ω1/υ1 is from about 0.040 to about 0.12.29. The silicone hydrogel contact lens of claim 28 , wherein in formula (2) q1 is zero or 1 claim 28 , n1 is an integer of 2 to 4 claim 28 , Ris hydrogen or methyl.31. The silicone hydrogel contact lens of claim 29 , wherein the crosslinked polymeric material comprises units of at least one hydrophilic vinylic monomer.32. The silicone hydrogel contact lens of claim 31 , wherein said at least one hydrophilic vinylic monomer is selected from the group consisting of N-vinylpyrrolidone claim 31 , N claim 31 ,N-dimethyl (meth)acrylamide claim 31 , (meth)acrylamide claim 31 , N-hydroxyethyl (meth)acrylamide claim 31 , N-hydroxypropyl (meth)acrylamide claim 31 , hydroxyethyl (meth)acrylate claim 31 , glycerol methacrylate (GMA) claim 31 , polyethylene glycol (meth)acrylate having a number average molecular weight of up to 1500 claim 31 , polyethylene glycol C-C-alkyl ether (meth)acrylate having a number average molecular weight of up to 1500 ...

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Номер записи: 49
14-01-2021 дата публикации

Thermoplastic acrylic resin and method for producing same, and resin composition

Номер: US20210009802A1
Автор: Sota OKUMURA, Takamasa Soejima, Yusuke Hirai
Принадлежит: Kaneka Corp

A thermoplastic acrylic resin is provided. The thermoplastic acrylic resin is a graft copolymer in which a stem polymer is an acrylic resin containing acrylonitrile and another ethylenically unsaturated monomer, and a branch polymer is a polymer composed of an ethylenically unsaturated monomer. The acrylonitrile is contained in an amount of 35 mass % or more and 84.5 mass % or less, the other ethylenically unsaturated monomer is contained in an amount of 15 mass % or more and 64.5 mass % or less, and the polymer composed of an ethylenically unsaturated monomer is contained in an amount of 0.5 mass % or more and 40 mass % or less. Thus, provided are a thermoplastic acrylic resin having improved melt-processability without compromising heat resistance, a method for producing the thermoplastic acrylic resin, a thermoplastic acrylic resin composition, a molded body, an acrylic fiber, and a method for producing the acrylic fiber.

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Номер записи: 50
09-01-2020 дата публикации

Multilayer Marking Film

Номер: US20200010722A1
Автор: Hye Jin Sim, Jang Soon Kim, Myung Hyun JO
Принадлежит: LG Chem Ltd

A multilayer marking film is disclosed herein. In some embodiments, a multilayer marking film includes, in sequential order, an adhesive layer, a colored base layer having a first color, and a colored coating layer having a second color, wherein information can be written by laser irradiation on the colored coating layer.

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Номер записи: 51
09-01-2020 дата публикации

VINYL-BASED COMB POLYMER

Номер: US20200010775A1
Автор: Ikari Yoshihiro
Принадлежит: KANEKA CORPORATION

A vinyl-based comb copolymer includes a polyisobutylene-based macromonomer unit and a vinyl-based monomer unit. A polyisobutylene-based macromonomer has at least 0.8 (meth)acryloyl groups represented by a specific formula at one end of a main chain per molecule, and is copolymerized with a vinyl-based monomer. A method for producing the vinyl-based comb copolymer includes copolymerizing the polyisobutylene-based macromonomer with the vinyl-based monomer. A viscosity index improver includes the comb copolymer. A lubricating oil composition includes the comb copolymer. 2. The vinyl-based comb copolymer according to claim 1 , wherein the vinyl-based comb copolymer contains 0.05 to 20 mol % of a polyisobutylene-based macromonomer unit.3. The vinyl-based comb copolymer according to claim 1 , wherein a molecular weight distribution (Mw/Mn) of the polyisobutylene-based macromonomer ranges from 1.0 to 1.8.4. The vinyl-based comb copolymer according to claim 1 , wherein a number-average molecular weight (Mn) of the polyisobutylene-based macromonomer ranges from 1 claim 1 ,000 to 200 claim 1 ,000 as a value obtained by size exclusion chromatography (SEC) measurement based on polystyrene standards.5. The vinyl-based comb copolymer according to claim 1 , wherein Rin the general formula (1) is at least one divalent hydrocarbon group selected from the group consisting of —CHCH— claim 1 , —CHCHCH— claim 1 , and —CHCHCHCH—.6. The vinyl-based comb copolymer according to claim 1 , wherein Rand Rin the general formula (1) are each hydrogen.7. The vinyl-based comb copolymer according to claim 1 , wherein Rin the general formula (1) is a methyl group.9. A method for producing the vinyl-based comb copolymer according to claim 1 , the method comprising copolymerizing the polyisobutylene-based macromonomer with the vinyl-based monomer.10. A viscosity index improver containing the comb copolymer according to .11. A lubricating oil composition containing the comb copolymer according to . One ...

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Номер записи: 52
03-02-2022 дата публикации

Injectable Therapeutic Biocompatible Co-Polymers and Methods of Making and Using Same

Номер: US20220031908A1
Автор: Mendenhall Juana
Принадлежит:

Biocompatible copolymers and thermo-responsive hydrogels formed from the copolymers are disclosed. The biocompatible copolymers include monomers comprising polysaccharides or derivatives thereof, therapeutic agents or derivatives thereof and thermo-responsive monomers and are cross-linked with an acrylamide-containing crosslinker. The hydrogels are used as implant materials to treat or prevent joint damage or osteoarthritis in a subject. 1. A biocompatible copolymer , comprising:a first plurality of monomers each comprising a polysaccharide or derivative thereof;a second plurality of monomers each comprising a therapeutic agent or derivative thereof;a third plurality of monomers each comprising a thermo-responsive monomer; andan acrylamide-containing cross-linking agent.2. The biocompatible copolymer of claim 1 , wherein each of the monomers and the crosslinking agent comprise a vinyl functional group claim 1 , and wherein the vinyl functional groups form the backbone of the biocompatible co-polymer.3. The biocompatible copolymer of claim 1 , wherein the polysaccharide or derivative thereof comprises hyaluronic acid claim 1 , methacrylated hyaluronic acid claim 1 , or glycidyl methacrylated hyaluronic acid.4. The biocompatible copolymer of claim 1 , wherein the thermo-responsive monomer comprises n-vinylcaprolactam.5. The biocompatible copolymer of claim 1 , wherein the therapeutic agent or derivative thereof comprises an anti-osteoarthritic agent or derivative thereof.6. (canceled)7. The biocompatible copolymer of claim 1 , wherein the acrylamide-containing crosslinking agent is selected from the group consisting of bisacrylamide and poly(ethyleneoxide diacrylamide).8. The biocompatible copolymer of claim 1 , further comprising a surface adhesion protein.9. (canceled)10. A hydrogel implant material claim 1 , comprising the biocompatible copolymer of .11. The hydrogel implant material of claim 10 , wherein the composition is a liquid at temperatures below about 32° ...

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Номер записи: 53
03-02-2022 дата публикации

COMB POLYMERS AS BLOCKING ADDITIVES FOR SWELLING CLAYS

Номер: US20220033306A1
Автор: Frunz Lukas, JUILLAND Patrick, VELTEN Ulf, WEIDMANN Jürg
Принадлежит: SIKA TECHNOLOGY AG

A comb polymer, in particular for use as a clay-inerting agent, including: a) at least one poly(alkylene oxide) side chain-bearing monomer unit M1 without ionic groups, b) optionally at least one cationic monomer unit MC, c) optionally at least one anionic monomer unit MA, d) optionally, at least one non-ionic monomer unit M3, wherein the molar ratio of the cationic monomer units MC to the side chain-bearing monomer units M1 is equal to or less than 10, the molar ratio of the anionic monomer units MA to the side chain-bearing monomer units M1 is less than 1, preferably equal to or less than 0.5, and the molar ratio of the non-ionic monomer units M3 to the side chain-bearing monomer units M1 is less than 5. 6. A comb polymer according to claim 1 , wherein the comb polymer claim 1 , with respect to the total number of monomer units present in the comb polymer claim 1 , comprises:{'sup': '1', 'a) 95-100 mol-%, of the at least one poly(alkylene oxide) side chain-bearing monomer unit M,'}b) 0-1 mol-%, of the at least one cationic monomer unit MC,c) 0-1 mol-%, of the at least one anionic monomer unit MA,d) 0-1 mol-%, of the at least one non-ionic monomer unit M3.7. A comb polymer according to claim 1 , wherein the comb polymer claim 1 , with respect to the total number of monomer units present in the comb polymer claim 1 , comprises:{'sup': '1', 'a) 30-70 mol-%, of of the at least one poly(alkylene oxide) side chain-bearing monomer unit M, and b) 0-1 mol-%, of the at least one cationic monomer unit MC,'}c) 0-1 mol-%, of the at least one anionic monomer unit MA,d) 30-70%, of the at least one non-ionic monomer unit M3.8. A comb polymer according to claim 1 , wherein the comb polymer claim 1 , with respect to the total number of monomer units present in the comb polymer claim 1 , comprises:{'sup': '1', 'a) 10-99 mol-%, of the at least one poly(alkylene oxide) side chain-bearing monomer unit M, and'}b) 1-90 mol-%, of the at least one cationic monomer unit MC,c) 0-1 mol-%, of ...

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Номер записи: 54
19-01-2017 дата публикации

ACTIVE ENERGY RAY-CURABLE RESIN COMPOSITION AND AUTOMOBILE HEADLAMP LENS

Номер: US20170015774A1
Автор: MIYACHI Akira, Satou Hiroyuki
Принадлежит: MITSUBISHI RAYON CO., LTD.

Provided is an active energy ray-curable resin composition with which it is possible to form a cured film, having outstanding scratch resistance, hardness, and weather resistance, on the surface of a molded resin article for an automobile headlamp lens. The active energy ray-curable resin composition is used to form a cured film on the surface of a molded resin article for an automobile headlamp lens and comprises (A) 10-70% by mass of a mono- or poly-pentaerythritol poly(meth)acrylate compound having a specific structure, (B) 10-50% by mass of a urethane(meth)acrylate compound having at least two (meth)acryloyloxy groups, at least one amido group, and at least two urethane bonds, and (C) 20-80% by mass of a poly[(meth)acryloyloxyalkyl]isocyanurate compound having a specific structure. 2. The active energy ray-curable resin composition according to claim 1 , wherein the urethane (meth)acrylate mixture (B) is obtained by reacting materials (b1)-(b4) below:(b1): diisocyanate;(b2): a compound containing at least one amide group, which does not include the —NH—CO— structure in the urethane bond, and at least two hydroxyl groups;(b3): at least one type of diol selected from the group consisting of polyether diols, polycarbonate diols, and polyester diols other than material (b2); and(b4): a (meth)acrylic acid ester having at least one (meth)acryloyloxy group, and one hydroxyl group.3. The active energy ray-curable resin composition according to claim 2 , wherein material (b3) is a polyether diol other than material (b2).4. The active energy ray-curable resin composition according to claim 2 , wherein the molar equivalent ratio of materials (b1)-(b4) is [material (b1)]/[material (b2)+material (b3)]/[material (b4)]=10/4-6/4-6.5. The active energy ray-curable resin composition according to claim 2 , wherein the molar equivalent ratio of materials (b2) and (b3) is material (b2)/material (b3)=1-5/5-1.6. The active energy ray-curable resin composition according to claim 2 , ...

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Номер записи: 55
19-01-2017 дата публикации

Optically clear adhesives for durable plastic bonding

Номер: US20170015877A1
Автор: Albert I. Everaerts, Aya NAKADA, Hideyuki Hatanaka, Masaki Yoda, Shunsuke Suzuki, Toshihiro Suwa, Yasuhiro Kinoshita
Принадлежит: 3M Innovative Properties Co

The present invention is a copolymer of a monomer mixture including about 25 to about 80 parts by mass of an alkyl (meth)acrylate, approximately 15 to approximately 50 parts by mass of a hydroxyl group-containing monomer, and approximately 5 to approximately 25 parts by mass of a macromer having a glass transition temperature (Tg) of approximately 50° C. or higher. The copolymer contains substantially no acidic groups.

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Номер записи: 56
14-01-2021 дата публикации

METAL-CLAD LAMINATED BOARD, METAL MEMBER PROVIDED WITH RESIN, AND WIRING BOARD

Номер: US20210014967A1
Автор: Abe Tomoyuki, ARISAWA TATSUYA, GOTO Hirohisa
Принадлежит: Panasonic Intellectual Property Management Co., Ltd.

A metal-clad laminated board includes an insulating layer and a metal layer, in which the insulating layer includes a cured product of a resin composition containing a modified polyphenylene ether compound terminally modified with a substituent having an unsaturated double bond; and a crosslinkable curing agent having an unsaturated double bond in the molecule, and containing 40 to 250 parts by mass of silica particles with respect to 100 parts by mass in total of the modified polyphenylene ether compound and the crosslinkable curing agent, the resin composition contains 0.2 to 5 parts by mass of a first silane coupling agent having an unsaturated double bond in the molecule with respect to 100 parts by mass of the silica particles, and a contact surface of the metal layer in contact with the insulating layer is surface-treated with a second silane coupling agent having an amino group in the molecule. 1. A metal-clad laminated board comprising an insulating layer and a metal layer present in contact with at least one surface of the insulating layer ,whereinthe insulating layer includes a cured product of a resin composition containing a modified polyphenylene ether compound terminally modified with a substituent having a carbon-carbon unsaturated double bond; a crosslinkable curing agent having a carbon-carbon unsaturated double bond in a molecule; a first silane coupling agent having a carbon-carbon unsaturated double bond in a molecule; and at least one of silica particles and silica particles surface-treated with the first silane coupling agent,a total content of the silica particles and the silica particles surface-treated with the first silane coupling agent is 40 to 250 parts by mass with respect to 100 parts by mass in total of the modified polyphenylene ether compound and the crosslinkable curing agent,a total content of the first silane coupling agent contained in the resin composition and the first silane coupling agent contained in the silica particles ...

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Номер записи: 57
21-01-2016 дата публикации

Plasticizer Having Cationic Side Chains

Номер: US20160017082A1
Автор: AL SHEMARI Jabbar, FRIEDERICH Markus, Hampel Christina, Zimmermann Jörg
Принадлежит: SIKA TECHNOLOGY AG

Provided are cationic comb polymers, obtainable by polymerizing a monomer mixture, which contains at least one monomer having at least one cationic group covalently bonded to the monomer and which contains at least one monomer of the formula R—O-[AO]—R, wherein Ris an alkenyl group, Rrepresents H, an alkyl group having 1 to 20 C atoms, or an aryl group or alkylaryl group having 7 to 20 C atoms, A independently of one another represents a Cto Calkylene group, and n is a value from 2 to 300. Also provided are hydraulically setting cement compositions, shaped bodies, uses, and methods for producing comb polymers. Also provided are novel comb polymers with cationic side chains and structural subunits that comprise polyether components. Further provided are hydraulically setting cement compositions, shaped bodies, uses and methods for producing comb polymers.

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Номер записи: 58
18-01-2018 дата публикации

RADIATION CURABLE BINDER DISPERSION

Номер: US20180016453A1
Автор: Chen Tienteh, Huang Bin, Sarkisian George
Принадлежит:

An example of a radiation curable binder dispersion includes water and a radiation curable binder dispersed therein. The radiation curable polyurethane is formed from a polyisocyanate; an acrylate or methacrylate having at least two hydroxyl functional groups and having an acrylate functional group or a methacrylate functional group; another acrylate or methacrylate having one hydroxyl functional group or one amino functional group; and one of i) a homopolymer or copolymer of poly(ethylene glycol) having one or two hydroxyl functional groups or one or two amino functional groups at one end of its chain; or ii) a combination of i and a compound including a carboxylic functional group. 1. A radiation curable binder dispersion , comprising:water; and a polyisocyanate;', 'an acrylate or methacrylate, the acrylate or methacrylate having at least two hydroxyl functional groups and having an acrylate functional group or a methacrylate functional group;', 'an other acrylate or methacrylate, the other acrylate or methacrylate having one hydroxyl functional group or one amino functional group; and one of:', 'i) a homopolymer or copolymer of poly(ethylene glycol) having one or two hydroxyl functional groups or one or two amino functional groups at one end of its chain; or', 'ii) a combination of i and a compound including a carboxylic functional group., 'a radiation curable polyurethane dispersed in the water, the radiation curable polyurethane having been formed from2. The radiation curable binder dispersion as defined in wherein the homopolymer or copolymer of poly(ethylene glycol) has a number average molecular weight ranging from about 500 and about 5 claim 1 ,000 and a water solubility greater than 30% v/v.3. The radiation curable binder dispersion as defined in wherein the homopolymer or copolymer of poly(ethylene glycol) is:a poly(ethylene glycol) copolymer selected from the group consisting of a copolymer of poly(ethylene) and poly(ethylene glycol) with the one ...

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Номер записи: 59
17-01-2019 дата публикации

Associative polymers and related compositions, methods and systems

Номер: US20190016859A1
Автор: Julia A. Kornfield, Ming-Hsin Wei
Принадлежит: California Institute of Technology CalTech

Described herein are associative polymers capable of controlling a physical and/or chemical property of non-polar compositions and related compositions, methods and systems. Associative polymers herein described have a non-polar backbone and functional groups presented at ends of the non-polar backbone, with a number of the functional groups presented at the ends of the non-polar backbone formed by associative functional groups capable of undergoing an associative interaction with another associative functional group with an association constant (k) such that the strength of each associative interaction is less than the strength of a covalent bond between atoms and in particular less than the strength of a covalent bond between backbone atoms.

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Номер записи: 60
16-01-2020 дата публикации

BLUE LED CURE ON DEMAND COMPOSITIONS

Номер: US20200017623A1
Автор: Blackwell Charlie P., Dailey Ian, Griffin Michael E., Homnick Paul J., Keicher Dennis R., Klun Thomas P., Kropp Michael A., Lin Ying, Pokorny Richard J., Savu Patricia M., Schlechte Jay S., Smith Richard S., Ye Sheng, Yu Steven Y.
Принадлежит:

The disclosure relates to compositions, methods of applying such compositions, and methods for curing such compositions to a depth of cure of up to about 30 mm within about 0.5 second to about two minutes per light exposure area. 1. A method comprising: a urethane acrylate component;', 'an adhesion promoter comprising an acid-functional monomer; and', 'a photoinitiator having an extinction coefficient of from about 10 to about 2000 L/mol·cm at a wavelength from about 400 nm to about 500 nm in an amount of from about 0.1 wt. % to about 10 wt. %; and, 'applying a composition to a substrate, the composition comprising'}curing the composition using a light-emitting curing device emitting light at a wavelength of from about 260 to about 550 nm;wherein the composition cures to a depth of cure of up to about 30 mm within about 0.5 second to about two minutes per light exposure area.2. The method of claim 1 , wherein the composition further comprises at least one of about 3 to about 50 wt. % of adhesion promoter claim 1 , about 10 to about 80 wt. % of diluents claim 1 , about 0.3 to about 10 wt. % long alkyl chain (meth)acrylate claim 1 , about 0.3 to about 10 wt. % of fluorinated (meth)acrylate claim 1 , about 0.5 to about 10 wt. % of corrosion inhibitor claim 1 , about 1 to about 200 ppm of photobleaching agent claim 1 , about 1 to about 200 ppm of photosensitizer claim 1 , about 0.1 to about 30 wt. % of fillers claim 1 , about 0.5 to about 30 wt. % of monothiols claim 1 , polythiols claim 1 , or combination thereof claim 1 , and about 1 to about 40 wt. % of plasticizer.3. (canceled)4. (canceled)5. The method of claim 1 , wherein the composition comprises about 5 wt. % to about 85 wt. % urethane acrylate component.6. (canceled)7. (canceled)8. (canceled)9. The method of claim 1 , wherein the urethane acrylate component comprises an aliphatic urethane acrylate claim 1 , an aromatic urethane acrylate claim 1 , or a combination of an aliphatic urethane acrylate and an ...

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Номер записи: 61
21-01-2021 дата публикации

RESIN COMPOSITION, AND PREPREG, RESIN-COATED FILM, RESIN-COATED METAL FOIL, METAL-CLAD LAMINATE, AND WIRING BOARD EACH OBTAINED USING SAID RESIN COMPOSITION

Номер: US20210017317A1
Автор: Inoue Hiroharu, Umehara Hiroaki, Wang Yiqun
Принадлежит: Panasonic Intellectual Property Management Co., Ltd.

A resin composition is provided and includes (A) a modified polyphenylene ether compound terminal-modified with a substituent having a carbon-carbon unsaturated double bond, (B) a maleimide compound containing no phenylmaleimide group and having a hydrocarbon group having 10 or more carbon atoms in the molecule thereof, and (C) at least one selected from a maleimide compound containing a phenylmaleimide group and a maleimide compound having an aliphatic hydrocarbon group having 9 or less carbon atoms in the molecule thereof, in which the content ratio of the component (A) to the component (B) is (A):(B)=20:80 to 90:10 in mass ratio. 1. A resin composition , comprising:(A) a modified polyphenylene ether compound terminal-modified with a substituent having a carbon-carbon unsaturated double bond;(B) a maleimide compound containing no phenylmaleimide group and having a hydrocarbon group having 10 or more carbon atoms in a molecule thereof; and(C) at least one selected from a maleimide compound containing a phenylmaleimide group and a maleimide compound having an aliphatic hydrocarbon group having 9 or less carbon atoms in a molecule thereof,wherein a content ratio of the component (A) to the component (B) is (A):(B)=20:80 to 90:10 in mass ratio.3. The resin composition according to claim 1 , wherein the modified polyphenylene ether compound (A) has a weight average molecular weight (Mw) of 1000 to 5000.4. The resin composition according to claim 1 , wherein the maleimide compound (B) has a weight average molecular weight (Mw) of 500 to 4000.5. The resin composition according to claim 1 , wherein a content of the maleimide compound (C) is 5 to 50 parts by mass per 100 parts by mass of a resin component.6. A prepreg claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the resin composition according to or a semi-cured product of the resin composition; and'}a fibrous base material.7. A film with resin claim 1 , comprising:{'claim-ref': {'@idref': 'CLM- ...

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Номер записи: 62
03-02-2022 дата публикации

A buckling dielectric elastomer actuator

Номер: US20220037581A1
Автор: Gurunathan THANGAVEL, Pooi See Lee, Wei Ming Matthew TAN
Принадлежит: NANYANG TECHNOLOGICAL UNIVERSITY

Disclosed herein is a buckling actuator, comprising: a first electrode; a second electrode; and a film of a dielectric elastomeric material having a first surface and a second surface sandwiched between the first and second electrodes, wherein the material is formed by the random block copolymerisation of a polymeric material comprising silicon or nitrogen atoms that has two or more acrylate or vinyl end groups, and a polar polymeric material having two or more acrylate or vinyl end groups. Also disclosed herein is a method of forming said dielectric elastomeric material.

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Номер записи: 63
21-01-2021 дата публикации

METHOD FOR PRODUCING POLYIMIDE PRECURSOR, METHOD FOR PRODUCING PHOTOSENSITIVE RESIN COMPOSITION, METHOD FOR PRODUCING PATTERN CURED PRODUCT, METHOD FOR PRODUCING INTERLAYER INSULATING FILM, COVER COAT LAYER OR SURFACE PROTECTIVE FILM, AND METHOD FOR PRODUCING ELECTRONIC COMPONENT

Номер: US20210018837A1
Автор: ENOMOTO Tetsuya, Yoneda Satoshi
Принадлежит:

A method for producing a polyimide precursor having a structural unit represented by the following formula (1), 3. A method for producing a photosensitive resin composition comprising: producing a polyimide precursor by the method according to ; andmixing the polyimide precursor, (B) a polymerizable monomer, and (C) a photopolymerization initiator to obtain a photosensitive resin composition.4. A method for producing a pattern cured product comprising the following steps: producing a photosensitive resin composition by the method according to ;coating the photosensitive resin composition on a substrate and drying to form a photosensitive resin film;pattern-exposing the photosensitive resin film to obtain a resin film;developing the resin film after the pattern exposure using an organic solvent to obtain a pattern resin film; andheat-treating the pattern resin film.5. The method for producing a pattern cured product according to claim 4 , wherein a temperature of the heat treatment is 200° C. or less.6. A method for producing an interlayer insulating film claim 4 , a cover coat layer or a surface protective film claim 4 , which is produced using the pattern cured product produced by the method according to .7. A method for producing an electronic component claim 6 , which is produced using the interlayer insulating film claim 6 , the cover coat layer or the surface protective film produced by the method according to . The invention relates to a method for producing a polyimide precursor, a method for producing a photosensitive resin composition, a method for producing a pattern cured product, a method for producing an interlayer insulating film, a cover coat layer or a surface protective film, and a method for producing an electronic component.In recent years, the miniaturization of transistors which has supported the enhancement of the performance of computers has come to the limit of scaling law, and a laminated device structure in which semiconductor elements are ...

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Номер записи: 64
28-01-2016 дата публикации

Composite semifinished products and mouldings produced therefrom and directly produced mouldings based on hydroxy-functionalized (meth)acrylates and uretdiones which are crosslinked by means of radiation to give thermosets

Номер: US20160023384A1
Автор: Birte Olland, Emmanouil Spyrou, Friedrich Georg Schmidt, Guenter Schmitt, Holger Loesch, Michael Spittler, Sandra Reemers
Принадлежит: EVONIK DEGUSSA GmbH

The invention relates to a process for producing storage-stable polyurethane prepregs and to mouldings (composite components) produced therefrom. The prepregs and, respectively, components are produced by mixing (meth)acrylate monomers, (meth)acrylate polymers, hydroxy-functionalised (meth)acrylate monomers and/or hydroxy-functionalised (meth)acrylate polymers with uretdione materials. Photoinitiators can also optionally be added. This mixture or solution is applied by known processes to fibre material, e.g. carbon fibres, glass fibres or polymer fibres, and is polymerised with the aid of radiation or of plasma methods. Polymerisation, e.g. at room temperature or at up to 80° C., gives thermoplastics or thermoplastic prepregs, and these can subsequently also be subjected to forming processes. The hydroxy-functionalised (meth)acrylate constituents can then be crosslinked with the uretdiones already present within the system, by use of elevated temperature. It is thus possible to produce dimensionally stable thermosets or dimensionally stable crosslinked composite components.

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Номер записи: 65
26-01-2017 дата публикации

Adhesive sheet, manufacturing method thereof, and layered body

Номер: US20170021593A1
Автор: Hajime Kitano
Принадлежит: Bridgestone Corp

An adhesive sheet, the adhesive sheet having an adhesive composition layer, the adhesive composition layer being formed using a composition including: a polythiol compound; a (meth)acrylic compound having a plurality of at least one of an acryloyl group or a methacryloyl group; a radical generator; and a Michael addition catalyst, a ratio (Ac/SH) of a total molar number (Ac) of the at least one of an acryloyl group or a methacryloyl group contained in the (meth)acrylic compound to a total molar number (SH) of thiol groups contained in the polythiol compound being from 0.25 to 0.80.

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Номер записи: 66
26-01-2017 дата публикации

CROSS-LINKABLE RUBBER COMPOSITION FOR SEAL MATERIAL USED AT OILFIELD OR GAS WELL AND SEAL MATERIAL

Номер: US20170022316A1
Автор: KATADA Arinobu
Принадлежит: ZEON CORPORATION

A cross-linkable rubber composition for a seal material which is used at an oilfield or gas well comprising a nitrile group-containing copolymer rubber which contains α,β-ethylenically unsaturated nitrile monomer units 10 to 60 wt % and has an iodine value of 120 or less, an α,β-ethylenically unsaturated carboxylic acid metal salt (B), and an organic peroxide cross-linking agent (C) is provided. According to the present invention, it is possible to provide a rubber composition which is excellent in shapeability, is high in durability against hydrogen sulfide and other corrosive gases, and is suitable for application as a seal material which is used at an oilfield or gas well. 1. A method of use of a cross-linkable rubber composition as a seal material which is used at an oilfield or gas well and is used in an environment with a ratio of hydrogen sulfide of 1 volume ppb to 50 vol % , whereinthe cross-linkable rubber composition comprises a nitrile group-containing copolymer rubber (A) which contains α,β-ethylenically unsaturated nitrile monomer units 10 to 60 wt % and has an iodine value of 120 or less, an α,β-ethylenically unsaturated carboxylic acid metal salt (B), and an organic peroxide cross-linking agent (C).2. The method of use of a cross-linkable rubber composition as a seal material which is used at an oilfield or gas well and is used in an environment with a ratio of hydrogen sulfide of 1 volume ppb to 50 vol % as set forth in claim 1 , wherein the α claim 1 ,β-ethylenically unsaturated carboxylic acid metal salt (B) is a zinc salt of an α claim 1 ,β-ethylenically unsaturated carboxylic acid.3. The method of use of a cross-linkable rubber composition as a seal material which is used at an oilfield or gas well and is used in an environment with a ratio of hydrogen sulfide of 1 volume ppb to 50 vol % as set forth in claim 2 , wherein the zinc salt of an α claim 2 ,β-ethylenically unsaturated carboxylic acid is zinc methacrylate.4. The method of use of a cross ...

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Номер записи: 67
25-01-2018 дата публикации

Modified liquid diene rubber and resin composition containing modified liquid diene rubber

Номер: US20180022835A1
Автор: Kei Hirata, Satoshi Motoda
Принадлежит: Kuraray Co Ltd

There are provided a modified liquid diene rubber that can be used for a curable resin composition and a resin composition containing the modified liquid diene rubber. The curable resin composition containing the modified liquid diene rubber has a much higher curing rate than that in the related art, and the resulting cured product has excellent mechanical properties, transparency, and heat resistance. Produced are a modified liquid diene rubber and a resin composition containing the modified liquid diene rubber. The modified liquid diene rubber includes a modifying group (p) partly containing a (meth)acryloyl group therein and a monomer unit (a1) derived from a conjugated diene compound. A carbon-carbon double bond derived from the conjugated diene compound has a hydrogenation rate of 30 to 95 mol %, and the modifying group (p) has a functional group equivalent weight of 700 to 20,000 g/eq.

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Номер записи: 68
25-01-2018 дата публикации

PHOTOCURABLE COMPOSITION

Номер: US20180022838A1
Автор: OTSUKI Naoya, TAKEO Yuko
Принадлежит:

An object of the present invention is to provide a photocurable composition from which a cured product having high concealing property is obtained by irradiation with an active energy ray such as ultraviolet ray, and which inhibits color fading of the cured product in a high temperature and high humidity (85 C and 85% RH) environment or a high temperature (100 C) environment. 1. A photocurable composition comprising the following components (A) to (D):component (A): a leuco dye;{'sub': a', '6-a', 'b', '6-b', 'c', '4-c, 'sup': −', '−', '−, 'component (B): a salt having an anion selected from the group consisting of [P(Rf)F], [Sb(Rf)F] and [B(Rf)F] (in the formulae, Rf represents a fluoroalkyl group having 1 to 20 carbon atoms, a and b each independently represent an integer of from 1 to 5, and c represents an integer of from 1 to 3);'}component (C): a radical polymerizable compound; andcomponent (D): a photoradical initiator.2. The photocurable composition according to claim 1 , wherein{'sub': a', '6-a, 'sup': '−', 'the component (B) is a salt having an anion represented by [P(Rf)F] (in the formula, Rf represents a fluoroalkyl group having 1 to 20 carbon atoms and a represents an integer of from 1 to 5).'}3. The photocurable composition according to claim 1 , whereinthe component (B) is a salt having a cation selected from the group consisting of an aryliodonium cation, an aryl sulfonium cation, and an aryldiazonium cation.4. The photocurable composition according to claim 1 , whereinthe component (B) is a salt having an aryl sulfonium cation.5. The photocurable composition according to claim 1 , wherein{'sub': a', '6-a', '3', '2', '3', '3', '3', '2', '2', '2', '4', '3', '2', '2', '3', '3', '3', '2', '2', '2', '2', '4', '3', '2', '2', '2', '3', '3, 'sup': −', '−', '−', '−', '−', '−, '[P(Rf)F] of the component (B) is an anion selected from the group consisting of [(CFCF)PF], [(CFCFCF)PF], [(CFCFCF)PF], [(CFCFCFCF)PF], and [(CFCFCFCF)PF].'}6. The photocurable ...

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Номер записи: 69
25-01-2018 дата публикации

FLUORINATED COMPOUND-CONTAINING COMPOSITION, METHOD FOR ITS PRODUCTION, COATING LIQUID, HARD COAT LAYER-FORMING COMPOSITION AND ARTICLE

Номер: US20180022850A1
Автор: HOSHINO Taiki, Takao Kiyotaka
Принадлежит: Asahi Glass Company, Limited

To provide a fluorinated compound-containing composition which is capable of imparting excellent antifouling properties to an object (such as a hard coat layer) and which is excellent in compatibility and has foaming suppressed. This composition comprises the following fluorinated compound (A), the following compound (B) and a solvent (S1), wherein the content of the following fluorinated compound (A) in the composition is from 5 to 30 mass % to the composition, and the content of the following compound (B) is from 0.1 to 2 mass % to the composition, 1. A composition characterized by comprising the following fluorinated compound (A) , the following compound (B) and a solvent (S1) , wherein the content of the following fluorinated compound (A) in the composition is from 5 to 30 mass % to the composition , and the content of the following compound (B) is from 0.1 to 2 mass % to the composition ,Fluorinated compound (A): a fluorinated compound which is a compound having a portion derived from a compound (a) having a poly(oxyperfluoroalkylene) chain and an active hydrogen-containing group, a portion derived from a compound (b) having a polymerizable carbon-carbon double bond and an active hydrogen-containing group, and a portion derived from a polyisocyanate (c), and which has no isocyanate group,Compound (B): a compound having a polymerizable carbon-carbon double bond and an active hydrogen-containing group.2. The composition according to claim 1 , wherein at least part of said compound (B) is said compound (b).3. The composition according to claim 1 , wherein each of said compound (b) and said compound (B) other than the compound (b) is a compound having one hydroxy group.4. The composition according to claim 1 , wherein said compound (a) is a compound having one hydroxy group.5. A method for producing a composition as defined in claim 1 , which comprises reacting said compound (a) claim 1 , said compound (b) and said polyisocyanate (c) in said solvent (S1) claim 1 , ...

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Номер записи: 70
25-01-2018 дата публикации

FLUORINATED COMPOUND, PHOTOCURABLE COMPOSITION, COATING LIQUID, HARD COAT LAYER-FORMING COMPOSITION AND ARTICLE

Номер: US20180022851A1
Автор: HOSHINO Taiki, Takao Kiyotaka
Принадлежит: Asahi Glass Company, Limited

To provide a fluorinated compound capable of imparting excellent antifouling properties (oily ink repellency and fingerprint-stain removability) and abrasion resistance of the antifouling properties to an object (such as a hard coat layer). It is a reaction product of a compound (a1) having a poly(oxyperfluoroalkylene) chain and one active hydrogen-containing group, a compound (a2) having a poly(oxyperfluoroalkylene) chain and two active hydrogen-containing groups, a compound (b) having a polymerizable carbon-carbon double bond and an active hydrogen-containing group, and a polyisocyanate (c), wherein the proportion of the portion derived from the compound (a1) to the total (100 mass %) of the portion derived from the compound (a1) and the portion derived from the compound (a2) is from 60 to 99.9 mass %. 2. The fluorinated compound according to claim 1 , wherein the number average molecular weight of the compound (a1) is from 1 claim 1 ,000 to 6 claim 1 ,000 claim 1 , and the number average molecular weight of the compound (a2) is from 1 claim 1 ,000 to 6 claim 1 ,000.4. The fluorinated compound according to claim 3 , wherein each of said (CFO)and said (CFO)is {(CFO)(CFCFO)} (wherein n11 is an integer of at least 1 claim 3 , n12 is an integer of at least 1 claim 3 , n11+n12 is an integer of from 2 to 200 claim 3 , and the bonding order of n11 pieces of CFO and n12 pieces of CFCFO is not limited).5. The fluorinated compound according to claim 3 , wherein D-R—O—CH— is R—O—CHFCF—O—CH— (wherein Ris a Cperfluoroalkyl group terminated with CF).6. The fluorinated compound according to claim 3 , wherein the compound (a1) is a compound obtained by converting Eor Ein the compound (a2) to D.7. A method for producing a fluorinated compound claim 3 , characterized by reactinga compound (a1) having a poly(oxyperfluoroalkylene) chain and one active hydrogen-containing group,a compound (a2) having a poly(oxyperfluoroalkylene) chain and two active hydrogen-containing groups, in such ...

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Номер записи: 71
23-01-2020 дата публикации

MODEL MATERIAL INK SET, SUPPORT MATERIAL COMPOSITION, INK SET, THREE-DIMENSIONAL SHAPED OBJECT, AND METHOD FOR MANUFACTURING THREE-DIMENSIONAL SHAPED OBJECT

Номер: US20200023572A1
Автор: HONGO Kenta, IZUMO Taeko, Kito Katsuyuki, Okawa Masakatsu
Принадлежит:

The present invention relates to a model material ink set for use in an optical molding method by an inkjet system, wherein the ink set comprises a color ink and a clear ink containing an ethylenically unsaturated monomer, as a model material ink, wherein the color ink contains, as the ethylenically unsaturated monomer, 30 to 75% of a (meth)acrylate and 10 to 50% of an ethylenically unsaturated monomer that is not a (meth)acrylate and that contains a nitrogen atom, based on a total amount of the color ink, the clear ink contains, as the ethylenically unsaturated monomer, 30 to 80% of a (meth)acrylate based on a total amount of the clear ink, provided that a content of the ethylenically unsaturated monomer that is not a (meth)acrylate and that contains a nitrogen atom is less than 10% based on the total amount of the clear ink. 1. A model material ink set for use in an optical molding method by an inkjet system , the ink set comprising a color ink and a clear ink as a model material ink ,whereinthe color ink and the clear ink each contain an ethylenically unsaturated monomer,the color ink contains, as the ethylenically unsaturated monomer, 30 to 75% by mass of a (meth)acrylate and 10 to 50% by mass of an ethylenically unsaturated monomer that is not a (meth)acrylate and that contains a nitrogen atom, based on a total amount of the color ink,the clear ink contains, as the ethylenically unsaturated monomer, 30 to 80% by mass of a (meth)acrylate based on a total amount of the clear ink, provided that a content of the ethylenically unsaturated monomer that is not a (meth)acrylate and that contains a nitrogen atom in the clear ink is less than 10% by mass based on the total amount of the clear ink.2. The model material ink set according to claim 1 , wherein the ethylenically unsaturated monomer that is not a (meth)acrylate and that contains a nitrogen atom is selected from the group consisting of (meth)acrylamides and N-vinyllactams.3. The model material ink set according ...

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Номер записи: 72
23-01-2020 дата публикации

COATING COMPOSITIONS EXHIBITING CORROSION RESISTANCE PROPERTIES AND RELATED COATED SUBSTRATES

Номер: US20200024461A1
Автор: Schneider John R., Walters David N.
Принадлежит:

Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating later is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed. 1. A method of coating a substrate comprising: applying a first coating composition to at least a portion of the substrate , wherein the coating composition comprises: epoxy functional material , organic solvent , and magnesium oxide particles; and wherein the substrate comprises a 2000 series aluminum alloy.2. The method of claim 1 , wherein the coating composition further comprises an amine functional material.3. The method of claim 1 , further comprising applying an additional coating onto the at least partially coated substrate.4. The method of claim 3 , wherein the additional coating comprises polyurethane.5. The method of claim 1 , wherein the first coating composition has a dry film thickness of 0.5 to 1.25 mils.6. The method of claim 1 , wherein the magnesium oxide particles have a surface area of at least 10 m/g.7. The method of claim 6 , wherein the magnesium oxide particles are platy.8. The method of claim 6 , wherein the magnesium oxide particles are spherical.9. The method of claim 6 , wherein the magnesium oxide particles are cubical.10. The method of claim 6 , wherein the magnesium oxide particles are acicular.11. The method of claim 1 , wherein the first coating composition is substantially chromate-free.12. The method of claim 3 , wherein both the first and second coating compositions are substantially chromate-free.13. The method of claim 1 , wherein the 2000 series aluminum alloy comprises an aluminum cladding.14. The method of claim 1 , comprising surface-treating the substrate prior to ...

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Номер записи: 73
28-01-2021 дата публикации

METHOD FOR PRODUCING WELL DEFINED COMB POLYMERS

Номер: US20210024415A1
Автор: FRIEDERICH Markus, Hampel Christina, WEIDMANN Jürg, Zimmermann Jörg
Принадлежит: SIKA TECHNOLOGY AG

A method for producing improved comb polymers having a block or gradient structure. The comb polymers are highly suitable for dispersing fine powder. 1. A process for preparing comb polymers having block or gradient structure , wherein at least one section A of the comb polymer is formed by polymerizing a monomer mixture M comprising a polyalkylene glycol (meth)acrylate , wherein the monomer mixture M includes less than 2% by weight of (meth)acrylic acid , based on the weight of the polyalkylene glycol (meth)acrylate present in the monomer mixture M.2. The process as claimed in claim 1 , wherein the monomer mixture M includes less than 1.8% by weight of (meth)acrylic acid claim 1 , based on the weight of the polyalkylene glycol (meth)acrylate present in the monomer mixture M.3. The process as claimed in claim 1 , wherein the polyalkylene glycol (meth)acrylate has been prepared by a process in which neither (meth)acrylic acid nor the anhydride of (meth)acrylic acid is used.4. The process as claimed in claim 1 , wherein the polyalkylene glycol (meth)acrylate is obtained by transesterifying an alkyl (meth)acrylate with a polyalkylene glycol capped at one end or by alkoxylating a hydroxyalkyl(meth)acrylate.5. The process as claimed in claim 4 , wherein at the start of the transesterification reaction claim 4 , the molar ratio of alkyl (meth)acrylate to polyalkylene glycol capped at one end is 1:1 to 50:1.6. The process as claimed claim 4 , wherein claim 4 , during and/or after the transesterification claim 4 , excess alkyl (meth)acrylate is partly or fully removed from the reaction mixture.7. The process as claimed in claim 1 , wherein the monomer mixture M comprises the reaction mixture which is obtained by transesterifying an alkyl (meth)acrylate with a polyalkylene glycol capped at one end and includes claim 1 , besides the polyalkylene glycol (meth)acrylate claim 1 , at least one compound selected from the group comprising alkyl (meth)acrylate claim 1 , polyalkylene ...

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Номер записи: 74
28-01-2021 дата публикации

Photocurable resin composition

Номер: US20210024682A1
Автор: Kenji Suzuki
Принадлежит: Kuraray Noritake Dental Inc

The present invention provides a photocurable resin composition that has good fabricability, and that exhibits superior flexibility, fracture resistance, and water resistance in the form of a cured product. The present invention relates to a photocurable resin composition comprising: a urethanized (meth)acrylic compound (A); a mono(meth)acrylic acid ester compound (B) containing no urethane bond; and a photopolymerization initiator (C), the urethanized (meth)acrylic compound (A) being a (meth)acrylate comprising, per molecule, at least one kind of structure selected from the group consisting of a polyester, a polycarbonate, a polyurethane, a polyether, a poly-conjugated diene, and a hydrogenated poly-conjugated diene; and a urethane bond, the mono(meth)acrylic acid ester compound (B) containing no urethane bond comprising at least one selected from the group consisting of a mono(meth)acrylic acid ester compound (b-I) represented by general formula (I), and a mono(meth)acrylic acid ester compound (b-II) represented by general formula (II).

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Номер записи: 75
28-01-2021 дата публикации

Resin composition, optical fiber and method for manufacturing optical fiber

Номер: US20210024772A1
Автор: Katsushi Hamakubo
Принадлежит: Sumitomo Electric Industries Ltd

A resin composition includes a base resin containing a urethane (meth)acrylate oligomer, a monomer, and a photopolymerization initiator, and surface-modified inorganic oxide particles having an alkyl group having 1 or more and 8 or less carbon atoms or a phenyl group, wherein the content of the surface-modified inorganic oxide particles is 1% by mass or more and 60% by mass or less based on the total amount of the resin composition and the amount of surface modification on the surface-modified inorganic oxide particles is 0.15 mg/m 2 or more.

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Номер записи: 76
28-01-2021 дата публикации

METHODS FOR PRODUCING HELMET INSERTS WITH MATERIALS HAVING MULTIPLE MECHANISMS OF HARDENING

Номер: US20210024775A1
Автор: Chen Kai, Desimone Joseph M., Goodrich James, JR. Robert K., Pinschmidt, Poelma Justin, Robeson Lloyd M., Rolland Jason P.
Принадлежит:

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component. 1. A method of forming a three-dimensional object , wherein said three-dimensional object is an insert for use between a helmet and a human body , comprising:(a) providing a carrier and an optically transparent member having a build surface, said carrier and said build surface defining a build region therebetween;(b) filling said build region with a polymerizable liquid, said polymerizable liquid comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component;(c) irradiating said build region with light through said optically transparent member to form a solid polymer scaffold from said first component and also advancing said carrier away from said build surface to form a three-dimensional intermediate having a shape of said insert, said three-dimensional intermediate containing said second solidifiable component carried in said scaffold in unsolidified and/or uncured form; and(d) subsequent to said irradiating step, heating, microwave irradiating, or both heating and microwave irradiating, second solidifiable component in said three-dimensional intermediate to form said insert.2. The method of claim 1 , wherein said second solidifiable component comprises a polymerizable liquid solubilized in or suspended in said first component.3. The method of claim 1 , wherein said second solidifiable component comprises:(i) a polymerizable solid suspended in said first component;(ii) a polymerizable solid solubilized in said first component; ...

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Номер записи: 77
28-01-2021 дата публикации

OPTICAL FIBER

Номер: US20210026065A1
Автор: Hamakubo Katsushi, HOMMA Yuya
Принадлежит: Sumitomo Electric Industries, Ltd.

An optical fiber comprises a glass fiber comprising a core and a cladding, a primary resin layer being in contact with the glass fiber and covering the glass fiber, and a secondary resin layer covering the primary resin layer, wherein the Young's modulus of the primary resin layer is 0.04 MPa or more and 1.0 MPa or less at 23° C.±2° C., the secondary resin layer consists of a cured product of a resin composition comprising a base resin containing a urethane (meth)acrylate oligomer, a monomer, and a photopolymerization initiator and hydrophobic inorganic oxide particles, and the content of the inorganic oxide particles is 1% by mass or more and 60% by mass or less based on the total amount of the resin composition. 1: An optical fiber comprising a glass fiber comprising a core and a cladding; a primary resin layer being in contact with the glass fiber and covering the glass fiber; and a secondary resin layer covering the primary resin layer ,wherein a Young's modulus of the primary resin layer is 0.04 MPa or more and 1.0 MPa or less at 23° C.±2° C., andwherein the secondary resin layer consists of a cured product of a resin composition comprising a base resin containing a urethane (meth)acrylate oligomer, a monomer, and a photopolymerization initiator; and hydrophobic inorganic oxide particles, and a content of the inorganic oxide particles is 1% by mass or more and 60% by mass or less based on a total amount of the resin composition.2: The optical fiber according to claim 1 , wherein the inorganic oxide particle is at least one selected from the group consisting of silicon dioxide claim 1 , zirconium dioxide claim 1 , aluminum oxide claim 1 , magnesium oxide claim 1 , titanium oxide claim 1 , tin oxide claim 1 , and zinc oxide.3: The optical fiber according to wherein the content of the inorganic oxide particles is 5% by mass or more and 60% by mass or less based on a total amount of the resin composition.4: The optical fiber according to claim 1 , wherein an ...

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Номер записи: 78
04-02-2016 дата публикации

Water-Absorbing (Meth) Acrylic Resin With Optical Effects, And Related Compositions

Номер: US20160030328A1
Автор: Emi Akabane, Fatemeh Mohammadi, Lisa Qu
Принадлежит: ELC Management LLC, Shin Etsu Chemical Co Ltd

A water-absorbing polymer obtained from (A) a phosphate-containing (meth)acrylic monomer and/or a salt thereof, (B) a monomer having one (meth)acrylic group within the molecule and/or a salt thereof other than component (A), and (C) an organopolysiloxane having a (meth)acrylic group at both ends and related compositions.

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Номер записи: 79
29-01-2015 дата публикации

Polymerizable composition, polymerization product, image display device, and method for producing same

Номер: US20150030836A1
Автор: Daigo Ito, Hiroto Kouka, Kazuhiko Ooga, Kazuhiro Sasaki, Kenichi Nakanishi, Yuta Takeuchi
Принадлежит: Showa Denko KK

In relation to a polymerizable composition for forming a transparent optical resin layer to be interposed between an image display section of an image display device and a light-transmissive protective section thereof, the present invention provides a polymerizable composition that does not give rise to display defects caused by the deformation of the image display section, enables high-luminance, high-contrast image displaying, has excellent heat resistance, and also has a low dielectric constant. This polymerizable composition comprises: (1) a urethane (meth)acrylate obtained by reacting a hydrogenated polyolefin polyol and a compound having an isocyanato group and a (meth)acryloyl group; (2) a (meth)acryloyl-group-containing compound having a hydrocarbon group with a carbon number of 6 or greater; and (3) a photopolymerization initiator.

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Номер записи: 80
02-02-2017 дата публикации

(meth)acrylic copolymer, adhesive composition containing same, and adhesive sheet

Номер: US20170029548A1
Автор: Eri Kawai, Hiroko Shinada, Junichi Nakamura
Принадлежит: Mitsubishi Rayon Co Ltd

A (meth)acrylic copolymer (A) having a mass average molecular weight of 50,000 to 1,000,000, in which the (meth)acrylic copolymer (A) is obtained by polymerizing a monomer mixture including a macromonomer (a) that has a number average molecular weight of 500 or more and less than 6000 and a vinyl monomer (b), and preferably includes 7 to 40% by mass of a repeat unit derived from the macromonomer (a), has sufficient coating workability, adhesive holding power and adhesive property as an adhesive composition.

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Номер записи: 81
02-02-2017 дата публикации

BIO-BASED POLYMER NANOPARTICLE AND COMPOSITE MATERIALS DERIVED THEREFROM

Номер: US20170029549A1
Автор: BLOEMBERGEN Steven, Lee Do Ik, MESNAGER Julien Francois Marie Antoine Philippe, NOEEI ANCHEH Vahid, SMEETS Niels Mathieu Barbara, VAN LEEUWEN Jan
Принадлежит:

Methods of producing a latex, and the resulting latexes, are described herein. Bio-based colloidal particles are used in a free radical polymerization process. The particles may provide one or more of a seed particle, stabilizing agent, Pickering emulsifier, surfactant or co-monomer. Optionally, the particles (or biopolymer molecules such as starch in the particles) are functionalized, for example to provide double bonds or free radicals, prior to or while conducting a free radical polymerization reaction including the particles and a second compound which is a monomer. In another option, the particles are used in the presence of a functionalizing agent (capable for example of providing double bonds or free radicals on a biopolymer) in a free radical polymerization reaction. Optionally, the resulting latex may include particles of a mixed morphology including a bio-based phase. Methods of functionalizing bio-based particles and, in some cases, resultant particles (intermediate reaction products) are also described. 1. A method of making a latex comprising the steps ,producing biopolymer nanoparticles; and,polymerizing a latex forming vinyl monomer in a free radical polymerization reaction in the presence of the biopolymer nanoparticles.2. The method of comprising co-polymerizing the biopolymer nanoparticles and the latex forming vinyl monomer.3. The method of further comprising reacting the biopolymer nanoparticles with a functionalizing agent before or during the polymerization reaction.4. The method of wherein the biopolymer nanoparticles are functionalized with double bonds or free radicals.5. The method of comprising reacting the biopolymer nanoparticles with another vinyl monomer before the polymerization reaction.6. The method of wherein the biopolymer nanoparticles are reacted with the vinyl monomer by way of reactive extrusion.7. The method of wherein the biopolymer nanoparticles are reacted with a grafting agent during the polymerization reaction.8. The ...

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Номер записи: 82
04-02-2016 дата публикации

COPOLYMERS MADE WITH ALLYL-TERMINATED POLYOLEFINS AND UNSATURATED ACIDIC REAGENTS, DISPERSANTS USING SAME, AND METHODS OF MAKING SAME

Номер: US20160032041A1
Автор: Harrison James J., Stokes Casey D.
Принадлежит:

Copolymers made with allyl-terminated polyolefins and unsaturated acidic reactants, dispersants using same, and methods of making same are provided. Under one aspect, a copolymer of an unsaturated acidic reactant and high molecular weight polyolefin, wherein the polyolefin comprises an allyl-terminated polymeric product, is provided. The allyl-terminated polymeric product is formed, e.g., by forming a quasi-living tert-halide terminated polyolefin under suitable quasi-living conditions, and contacting the tert-halide terminated polyolefin with an allylsilane compound and a Lewis acid. In some embodiments, the allylsilane compound includes allyltrimethylsilane. 1. A copolymer of an unsaturated acidic reactant and a high molecular weight polyolefin , wherein the polyolefin comprises an allyl-terminated polymeric product.2. The copolymer of claim 1 , wherein the allyl-terminated polymeric product is formed by:a) ionizing a polyolefin to form a carbocation terminated polyolefin;b) reacting the carbocation terminated polyolefin from step (a) with an allylsilane compound in the presence of a Lewis acid, andc) terminating step (b) to form the allyl-terminated polymeric product3. The copolymer of claim 1 , wherein the allyl-terminated polymeric product is an allyl-terminated quasi-living polymeric product.4. The copolymer of claim 3 , wherein the allyl-terminated quasi-living polymeric product is prepared by:(a) forming a quasi-living tert-halide terminated polyolefin under suitable quasi-living conditions in the presence of a Lewis acid, and(b) reacting the quasi-living tert-halide terminated polyolefin with an allylsilane compound, and(c) terminating step (b) to form the allyl-terminated quasi-living polymeric product.5. The copolymer of claim 2 , wherein the allylsilane compound comprises allyltrimethylsilane.6. The copolymer of claim 1 , wherein the copolymer is formed by contacting the polyolefin with the unsaturated acidic reactant in the presence of a free radical ...

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Номер записи: 83
01-02-2018 дата публикации

A COPOLYMER COMPRISING A LIGNIN OR LIGNIN DERIVATIVE AND A POLY(ALKYLENE OXIDE) ALKYL ETHER (METH)ACRYLATE, AND A HYDROGEL COMPRISING THE COPOLYMER

Номер: US20180030192A1
Автор: KAI Dan, LOH Xian Jun
Принадлежит:

A copolymer comprising an oxygenated polyaromatic alcohol and a poly (alkylene oxide) alkyl ether (meth)acrylate is disclosed, wherein the oxygenated polyaromatic alcohol is preferably lignin or lignin derivative. A hydrogel comprising the copolymer and a cyclic oligosaccharide such as α-cyclodextrin is also disclosed, which can be used in biomedical or personal care industries, for example as a carrier for an active agent. 125-. (canceled)26. A copolymer comprising an oxygenated polyaromatic alcohol and a poly (alkylene oxide) alkyl ether (meth)acrylate.27. The copolymer of claim 26 , wherein said copolymer has a molecular weight in the range of 5 claim 26 ,000 g/mol to 500 claim 26 ,000 g/mol.28. The copolymer of claim 26 , wherein said copolymer has a polydispersity of at least 1.29. The copolymer of claim 26 , wherein said copolymer has a melting temperature in the range of 32° C. to 36° C.30. The copolymer of claim 26 , wherein said copolymer has a degradation temperature in the range of 350° C. to 370° C.31. The copolymer of claim 26 , wherein said copolymer has 5 to 1 claim 26 ,000 molecules of poly (alkylene oxide) alkyl ether (meth)acrylate bound to each molecule of the oxygenated polyaromatic alcohol.32. The copolymer of claim 26 , wherein said oxygenated polyaromatic alcohol is a lignin or a lignin derivative claim 26 ,wherein said lignin is selected from the group consisting of lignin, steam explosion lignin, add hydrolysis lignin, lignosulfonate, soda lignin and organosolv lignin orwherein said lignin derivative is selected from the group consisting of lignin esters, lignin ethers, carboxy lignins, hydroxyalkylated lignin, acylated lignin and hydroxyalkoxy lignins oris further selected from the group consisting of lignin acetate, lignin propionate, lignin butyrate, lignin ethyl ether, lignin methyl ether, carboxymethyl lignin, (hydroxyethoxy) lignin, and (hydroxypropoxy) lignin.33. The copolymer of claim 26 , wherein said oxygenated polyaromatic alcohol ...

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Номер записи: 84
01-02-2018 дата публикации

URETHANE (METH)ACRYLATE RESIN, CURABLE RESIN COMPOSITION, CURED PRODUCT THEREOF, AND PLASTIC LENS

Номер: US20180030198A1
Автор: KOBAYASHI Nobuo, Odani Yasuko
Принадлежит:

A urethane (meth)acrylate resin wherein the viscosity of the resin is low, the formability into a sheet-formed product, in particular, an optical sheet provided with fine uneven shapes on the surface is excellent, and a high refractive index can be realized, a curable resin composition including the urethane (meth)acrylate resin as an indispensable component, a cured product thereof, and a plastic lens are provided. A urethane (meth)acrylate resin produced by reacting aromatic diisocyanate compound (a), bisphenol-ethylene oxide adduct diol (b) having at least three aromatic ring or alicyclic structures in the molecule, and hydroxy-containing (meth)acrylate compound (c), which are indispensable raw material components, a curable resin composition containing the urethane (meth)acrylate resin as a primary component, and a cured product thereof. 1. A urethane (meth)acrylate resin produced by reacting an aromatic diisocyanate compound (a) , a bisphenol-ethylene oxide adduct diol (b) having at least three aromatic ring or alicyclic structures in the molecule , and a hydroxy-containing (meth)acrylate compound (c) , which are indispensable raw material components.2. The urethane (meth)acrylate resin according to claim 1 , wherein the bisphenol-ethylene oxide adduct diol (b) having at least three aromatic ring or alicyclic structures in the molecule is an ethylene oxide adduct diol of at least one bisphenol selected from the group consisting of bisphenol AP claim 1 , bisphenol BP claim 1 , bisphenol M claim 1 , bisphenol P claim 1 , bisphenol PH claim 1 , bisphenol TMC claim 1 , and bisphenol Z.4. The urethane (meth)acrylate resin according to claim 3 , wherein the molar ratio [(a-1)/(a-2)] of the structural site (a-1) to the structural site (a-2) is 45/55 to 60/40.5. The urethane (meth)acrylate resin according to claim 1 , wherein the hydroxy-containing (meth)acrylate compound (c) is (meth)acrylic acid or a lactone adduct thereof.6. A curable resin composition comprising ...

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Номер записи: 85
04-02-2016 дата публикации

Composition for light diffusion film, and light diffusion film

Номер: US20160033692A1
Автор: Baku Katagiri, Kentaro Kusama, Satoru Shoshi, Tomoo Orui
Принадлежит: Lintec Corp

A composition for light diffusion film in which the angle of aperture of diffused light in a light diffusion film obtainable therefrom can be expanded effectively, and a light diffusion film obtainable by the composition for light diffusion film are provided. Disclosed is composition for light diffusion film for obtaining a light diffusion film which has a predetermined internal structure within the film and in which plural regions having a relatively high refractive index are bent at an intermediate point along the film thickness direction, the composition for light diffusion film including a predetermined (meth)acrylic acid ester as component (A); a urethane(meth)acrylate as component (B); a photopolymerization initiator as component (C); and an ultraviolet absorber as component (D), wherein the content of the component (A) is adjusted to a value within a predetermined range relative to 100 parts by weight of the component (B), the content of the component (C) is adjusted to a value within a predetermined range relative to the total amount of the component (A) and the component (B), and the content of the component (D) is adjusted to a predetermined value relative to the total amount of the component (A) and the component (B).

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Номер записи: 86
30-01-2020 дата публикации

Microspheres containing therapeutic agents and related methods of use

Номер: US20200030238A1
Автор: Philippe Reb
Принадлежит: Biosphere Medical Inc

Microspheres, compositions including the microspheres, and methods of using the microspheres are disclosed herein. The microspheres can be substantially spherical and can include a copolymer of a monomer (such as an acrylic monomer) and a cyclodextrin or a derivative thereof. The microspheres can also include a therapeutic agent, such as a platinum-based drug.

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Номер записи: 87
17-02-2022 дата публикации

Curable composition for optical materials, and optical material

Номер: US20220049037A1
Автор: Ayako Ohara, Junji Momoda, Junji Takenaka, Taichi HANASAKI
Принадлежит: Tokuyama Corp

The present invention relates to a curable composition for an optical material, containing (A) 100 parts by mass of a radical polymerizable monomer, (B) 0.005 to 0.5 parts by mass of a tetraazaporphyrin compound having a maximum absorption wavelength in a range of 560 nm or more and 620 nm or less, and (C) 0.1 to 10 parts by mass of an ultraviolet absorber having a maximum absorption wavelength in a range of 330 nm or more and 350 nm or less. According to the present invention, it is possible to provide a curable composition for an optical material, capable of being suitably used as a coating material that can easily provide an optical material having good antiglare properties and excellent weather resistance.

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Номер записи: 88
17-02-2022 дата публикации

RADICAL POLYMERIZABLE RESIN COMPOSITION AND STRUCTURE REPAIRING MATERIAL

Номер: US20220049039A1
Автор: NIIBAYASHI Ryota, UMINO Atsushi
Принадлежит: SHOWA DENKO K.K.

Provided are a radical-polymerizable resin composition and a structure repairing material which, when used for repairing concrete structures, enable construction working even in a low-temperature environment, achieve a high strength and a low shrinkage by curing, and prevent cracking. The radical-polymerizable resin composition contains a radical-polymerizable resin (A) containing at least one selected from the group consisting of a vinyl ester resin, an urethane (meth)acrylate resin, and a polyester (meth)acrylate resin, a radical-polymerizable monomer (B) containing an isobornyl group-having unsaturated compound (B1), and a hydroxy group-containing aromatic tertiary amine (C) represented by the general formula (I), and containing the radical-polymerizable resin (A) and the radical-polymerizable monomer (B) in a total amount of 75% by mass or more. The structure repairing material contains the radical-polymerizable resin composition, an organic peroxide, and a filler (Z). 2. The radical-polymerizable resin composition according to claim 1 , wherein the isobornyl group-having unsaturated compound (B1) contains an ethylenically-unsaturated bond.3. The radical-polymerizable resin composition according to claim 2 , wherein the isobornyl group-having unsaturated compound (B1) is an isobornyl (meth)acrylate.4. The radical-polymerizable resin composition according to claim 1 , wherein the content ratio of the isobornyl group-having unsaturated compound (B1) relative to the total amount of the radical-polymerizable resin (A) and the radical-polymerizable monomer (B) is 10% by mass or more and 65% by mass or less.5. The radical-polymerizable resin composition according to claim 1 , wherein the content ratio of the isobornyl group-having unsaturated compound (B1) in the radical-polymerizable monomer (B) is 30% by mass or more and 90% by mass or less.6. The radical-polymerizable resin composition according to claim 1 , wherein the other radical-polymerizable monomer (B2) than ...

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Номер записи: 89
30-01-2020 дата публикации

Low-gloss cured product having excellent stain resistance, and manufacturing method therefor

Номер: US20200030845A1
Автор: Heon Jo KIM, Ji Yeon Seo, Min Kyung PARK, Tae Yi CHOI
Принадлежит: LG HAUSYS LTD

The present invention relates to a cured product having excellent stain resistance and low gloss, a method of manufacturing the same, and an interior material including the cured product. The cured product according to the present invention includes, along with an acrylic oligomer, an oligomer having a functional group containing silicon (Si) and an oligomer having a functional group containing fluorine (F), and thus, has excellent stain resistance and can implement a micro-folded structure on a surface thereof through extreme ultraviolet rays to be used during curing, thereby being capable of realizing low gloss without a matting agent.

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Номер записи: 90
31-01-2019 дата публикации

PHOTOSENSITIVE RESIN COMPOSITION, DRY FILM USING SAME, PRINTED WIRING BOARD, AND METHOD FOR MANUFACTURING PRINTED WIRING BOARD

Номер: US20190031790A1
Автор: DAIJIMA Yuta, KOMURO Nobuhito
Принадлежит:

Provided is a photosensitive resin composition: which has basic performance such as electrical insulation, soldering heat resistance, thermal shock resistance, solvent resistance, acid resistance, and alkali resistance required in a photosensitive resin composition used to produce a printed wiring board; which may form a resist shape having excellent linearity in the contours of the resist pattern because it is difficult to generate undercutting in which the bottom part is washed away or defects in the upper part of a resist; and which has excellent adhesion to a copper substrate and excellent fluidity. Also provided are a dry film prepared by using the photosensitive resin composition, a printed wiring board, and a method for producing the printed wiring board. The photosensitive resin composition contains (A) an acid-modified vinyl group-containing epoxy resin, (B) a photopolymerization initiator, (C) an ion scavenger having at least one selected from the group consisting of Zr, Bi, Mg, and Al, and (D) a photopolymerizable compound. 1. A photosensitive resin composition comprising:(A) an acid-modified vinyl group-containing epoxy resin;(B) a photopolymerization initiator; and(C) an ion scavenger having at least one selected from the group consisting of Zr, Bi, Mg, and Al; and(D) a photopolymerizable compound.2. The photosensitive resin composition according to claim 1 , wherein the component (A) contains (Al) at least one acid-modified vinyl group-containing epoxy resin obtained by using a bisphenol novolac type epoxy resin (a1) claim 1 , and (A2) at least one acid-modified vinyl group-containing epoxy resin obtained by using an epoxy resin (a2) different from the epoxy resin (a1).3. The photosensitive resin composition according to claim 2 , wherein the epoxy resin (a2) is at least one selected from the group consisting of a novolac type epoxy resin claim 2 , a bisphenol A type epoxy resin claim 2 , a bisphenol F type epoxy resin claim 2 , and a triphenol methane ...

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Номер записи: 91
31-01-2019 дата публикации

POLYMER PARTICLES

Номер: US20190031798A1
Автор: Cruise Gregory M., Harris Clayton, Keeley Edward Michael, Plotkin Steve, Yu Renee
Принадлежит:

Polymer particle embolics and methods of making same are described. The particle embolics can be used as embolization agents. 1. A polymer particle comprising:poly(ethylene glycol) diacrylamide, glycerol monomethacrylate, and amino ethyl methacrylate;wherein the polymer particle is spherical and has a diameter less than about 1,200 μm.2. The polymer particle of , wherein the polymer particle has a diameter between about 40 μm and about 1 ,200 μm. The polymer particle of , further comprising N ,N-methylenebisacrylamide.4. The polymer particle of claim 1 , wherein the N claim 1 ,N-methylenebisacrylamide is at a concentration of about 1% w/w.5. The polymer particle of claim 1 , wherein the poly(ethylene glycol) diacrylamide is at a concentration of about 28% w/w.6. The polymer particle of claim 1 , wherein the glycerol monomethacrylate is present at a concentration of about 68% w/w claim 1 ,7. The polymer particle of claim 1 , wherein the amino ethyl methacrylate at a concentration of about 3% w/w.8. The polymer particle of claim 1 , wherein the poly(ethylene glycol) diacrylamide is poly(ethylene glycol) diacrylamide 10 claim 1 ,000.9. The particle of claim 1 , further comprising a drug.10. A polymer particle comprising:poly(ethylene glycol) diacrylamide, 3-sulfopropyl acrylate, and amino propyl methacrylamide,wherein the polymer particle is spherical and has a diameter less than about 1,200 μm.11. The polymer particle of claim 10 , wherein the polymer particle has a diameter between about 40 pm and about 1 claim 10 ,200 μm.12. The polymer particle of claim 10 , wherein the poly(ethylene glycol) diacrylamide is at a concentration of about 40% w/w.13. The polymer particle of claim 10 , wherein the at least one monomer is 3-sulfopropyl acrylate at a concentration of about 59% w/w.14. The polymer particle of claim 10 , wherein the amino propyl methacrylamide is at a concentration of about 1% w/w.15. The polymer particle of claim 10 , wherein the poly(ethylene glycol) ...

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Номер записи: 92
31-01-2019 дата публикации

Methods of producing three-dimensional objects from materials having multiple mechanisms of hardening

Номер: US20190031911A1
Автор: James Goodrich, Jason P. Rolland, Joseph M. Desimone, Justin POELMA, Kai Chen, Lloyd M. Robeson, Robert PINSCHMIDT
Принадлежит: Carbon Inc

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

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Номер записи: 93
30-01-2020 дата публикации

ADMIXTURE AND INK COMPRISING THE ADMIXTURE

Номер: US20200032044A1
Автор: Akbulut Ozge, AKHLAGHI Omid, HODAEI Amin, SEZER Dilek
Принадлежит: Sabanci Universitesi

An admixture including at least one copolymer having a backbone. The backbone including at least one electrically charged monomer. The at least one copolymer is a grafted copolymer having mean molecular weight within a range between 600 g/mol and 3000 g/mol on side chains of the grafted copolymer. An additive manufacturing ink, Filament of the additive manufacturing ink, and inkjet printing ink including the admixture. 1. An ink for additive manufacturing , comprising an admixture , wherein the admixture comprises at least one copolymer with a backbone and the backbone comprises at least one electrically charged monomer; the at least one copolymer is a grafted copolymer having mean molecular weight within a range between 600 g/mol and 3000 g/mol on side chains of the grafted copolymer.2. The ink according to claim 1 , wherein the at least one copolymer is an alternating or random copolymer.3. The ink according to the claim 1 , wherein the at least one copolymer is a block copolymer.4. The ink according to claim 1 , wherein the backbone comprises acrylic acid or methacrylic acid.5. The ink according to claim 1 , wherein the the at least one copolymer comprises one or more monomers selected from the group consisting of 2-acrylamido-2-methylpropane sulfonic acid claim 1 , vinyl phosphonic acid claim 1 , N-[3(dimethylamino)propyl]methacrylamide claim 1 , 2-tert-butylamino)ethyl methacrylate claim 1 , and 2-vinyl pyridine claim 1 ,as modifying blocks.6. The ink according to claim 1 , wherein the ink comprises 60 wt. % to 80 wt. %_of inorganic solid content with respect to a total weight of an ink composition claim 1 , and has a volume fraction of the ink within a range of 35% (v/v) and 55% (v/v) with respect to a total volume of the ink composition.7. The ink according to claim 6 , wherein a ratio of the at least one copolymer is 2.5 wt % or less with respect to a total weight of the inorganic solid content.8. The ink according to claim 6 , wherein the ink is in a form ...

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Номер записи: 94
30-01-2020 дата публикации

FLOOR COATINGS COMPRISING A RESIN, A CURE SYSTEM AND DIAMOND PARTICLES AND METHODS OF MAKING THE SAME

Номер: US20200032102A1
Автор: BAKER Daniel P., SIGEL Gary A., Tian Dong
Принадлежит:

A curable coating for a substrate is disclosed that includes a curable resin containing at least one polyester urethane acrylate and monomers, a cure system and diamond particles. Methods of making the curable coatings and methods of making a coated flooring material are also included. 1. A curable coating for a substrate comprising: i. a polyester urethane acrylate; and', 'ii. an acrylate functional monomer;, 'a. a curable resin comprisingb. a cure system; andc. diamond particles.2. The coating of claim 1 , wherein the cure system is selected from a group consisting f photo-initiators claim 1 , thermal initiators claim 1 , curing resins claim 1 , and combinations thereof.3. The coating of claim 1 , wherein the photo-initiator is selected from a group consisting of benzophenone claim 1 , 1-hydroxycyclohexyl phenyl ketone claim 1 , benzoin claim 1 , benzoin methyl ether claim 1 , benzoin ethyl ether claim 1 , benzoin isopropyl ether claim 1 , benzyl diphenyl sulfide claim 1 , and any combination thereof.4. The coating of claim 1 , wherein the thermal initiator is selected from a group consisting of a peroxide compound claim 1 , an azo compound claim 1 , and a combination thereof.5. The coating of claim 1 , the coating has a Tg of about 15° C. to about 50° C. and double bond equivalent weight of about 0.0025 to about 0.0060.6. The coating of claim 1 , further comprising at least one additional abrasion resistant particle.7. The coating of claim 6 , wherein the at least one additional abrasion particle has a Mohs hardness value of at least 6.8. The coating of claim 1 , further comprising a matting agent.9. The coating of claim 1 , further comprising hydrophobic particles.10. The coating of claim 1 , wherein the coating contains about 0.5% to less than 5.5% by weight of diamond particles.11. The coating of claim 11 , wherein the coating contains about 1% to about 5% by weight of diamond particles.12. The coating of claim 12 , wherein the coating contains about 2% to ...

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Номер записи: 95
04-02-2021 дата публикации

SEMI-FINISHED PRODUCT ON THE BASIS OF A DUAL CROSSLINKING MECHANISM

Номер: US20210032392A1
Автор: Achten Dirk, Heinz Paul, Meisenheimer Richard
Принадлежит:

The present invention relates to semi-finished products which are obtained from a reaction mixture that contains ethylenic double bonds and isocyanate groups by radical polymerization of the ethylenic double bonds. The semi-finished product can be converted to an isocyanurate plastic having advantageous properties by carrying out polyaddition polymerization reactions of the isocyanate groups. 1. A process for producing a semifinished product , comprising: (i) an isocyanate component A;', '(ii) at least one trimerization catalyst C; and', '(iii) at least one component selected from the group consisting of components B, component D, and component E, wherein', 'component B has at least one ethylenic double bond but no isocyanate-reactive group;', 'component D has at least one isocyanate-reactive group and at least one ethylenic double bond in one molecule; and', 'component E has both at least one isocyanate group and at least one ethylenic double bond in one molecule; and, 'a) wetting a fiber with a reaction mixture having a molar ratio of isocyanate groups to isocyanate-reactive groups of at least 2:1, the reaction mixture comprising'}b) increasing a viscosity of the reaction mixture by at least 100% via free-radical polymerization of at least 50% of the ethylenic double bonds present in the reaction mixture.2. The process as claimed in claim 1 , wherein the fiber is present in the form of a woven fabric claim 1 , a non-crimp fabric claim 1 , or knitted fabric.3. The process as claimed in claim 1 , wherein the reaction mixture additionally comprises a component F which acts as an initiator for the free-radical polymerization of the ethylenic double bonds.4. The process as claimed in claim 3 , wherein the component F is activated by actinic radiation and/or the action of heat.5. The process as claimed in claim 1 , wherein a weight fraction of isocyanate groups in the reaction mixture is at least 1% and not more than 50%.6. The process as claimed in claim 1 , wherein a ...

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Номер записи: 96
04-02-2021 дата публикации

Microfluidic channel made of hydrophilic silicone resin

Номер: US20210032393A1
Автор: Mamoru Hagiwara
Принадлежит: Shin Etsu Chemical Co Ltd

A microfluidic channel made of a hydrophilic silicone resin includes a crosslinked material obtained by curing a composition containing a silicone macromer represented by the following general formula (1). Consequently, a microfluidic channel made from a resin having high oxygen permeability, where a surface after formation shows high hydrophilicity without a secondary treatment and the hydrophilicity is sustained for a long period of time.

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Номер записи: 97
04-02-2021 дата публикации

Resin composition, and prepreg, resin-coated film, resin-coated metal foil, metal-clad laminate, and wiring board each obtained using said resin composition

Номер: US20210032424A1
Автор: Hiroaki Umehara, Hiroharu Inoue, Rihoko WATANABE, Yiqun Wang
Принадлежит: Panasonic Intellectual Property Management Co Ltd

A resin composition is provided and contains (A) a thermosetting compound having a styrene structure or a (meth)acrylate structure, and (B) a maleimide compound represented by the following formula (1) (in the formula, p represents an integer of 1 to 10), in which the content ratio of the component (A) to the component (B) is (A):(B)=20:80 to 90:10 in mass ratio.

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Номер записи: 98
31-01-2019 дата публикации

ELECTROPHOTOGRAPHIC PHOTORECEPTOR, ELECTROPHOTOGRAPHIC PHOTORECEPTOR CARTRIDGE, IMAGE FORMING APPARATUS, AND DISPERSANT FOR FLUORORESIN

Номер: US20190033734A1
Автор: Yoshizawa Atsushi
Принадлежит: MITSUBISHI CHEMICAL CORPORATION

The invention relates to an electrophotographic photoreceptor which is excellent in abrasion resistance and electrical properties by using a fluororesin and a polymer containing a structure represented by a specific formula, and has a long life span, an electrophotographic photoreceptor cartridge and an image forming apparatus including the electrophotographic photoreceptor, and a dispersant which is excellent in dispersibility of a fluororesin particle, and the electrical properties, and the compatibility with a binder resin. 6. The electrophotographic photoreceptor according to claim 2 ,wherein in a polymer having the structure represented by the Formula (1) and the structure represented by the Formula (2), a content of the structure represented by the Formula (1) is 20% by mass to 70% by mass.7. The electrophotographic photoreceptor according to claim 2 ,wherein a weight average molecular weight of the polymer having the structure represented by Formula (1) and the structure represented by Formula (2) is 5,000 to 100,000.8. The electrophotographic photoreceptor according to claim 1 ,wherein a content of the polymer having the structure represented by Formula (1) is 0.5 parts by mass to 20 parts by mass with respect to 100 parts by mass of fluororesin.9. The electrophotographic photoreceptor according to claim 2 ,wherein the photosensitive layer further contains a binder resin in addition to the polymer having the structure represented by the Formula (1) and the structure represented by the Formula (2) and the fluororesin, and a content of the fluororesin is 1 parts by mass to 30 parts by mass with respect to 100 parts by mass of the binder resin.10. The electrophotographic photoreceptor according to claim 1 ,wherein an average primary particle diameter of the fluororesin is 0.1 μm to 1.0 μm.11. An electrophotographic photoreceptor cartridge comprising the electrophotographic photoreceptor according to .12. An image forming apparatus comprising the ...

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Номер записи: 99
08-02-2018 дата публикации

POLYMER COMPOSITIONS CONTAINING GRAFTED POLYMERIC NETWORKS AND PROCESSES FOR THEIR PREPARATION AND USE

Номер: US20180037690A1
Автор: Aitken Brian, Arnold Stephen C., Duis Donnie, Joslin Scott, Lu Fang, Mahadevan Shivkumar, Martin Patricia, Scales Charles, Sinha Dola, Zhang Yong
Принадлежит:

Provided are polymer compositions made by a process comprising: (a) providing a first reactive composition containing: (i) a polymerization initiator that is capable, upon a first activation, of forming two or more free radical groups, at least one of which is further activatable by subsequent activation; (ii) one or more ethylenically unsaturated compounds; and (iii) a crosslinker; (b) subjecting the first reactive composition to a first activation step such that the first reactive composition polymerizes therein to form a crosslinked substrate network containing a covalently bound activatable free radical initiator, (c) combining the crosslinked substrate network with a second reactive composition containing one or more ethylenically unsaturated compounds; and (d) activating the covalently bound activatable free radical initiator of the crosslinked substrate network such that the second reactive composition polymerizes therein with the crosslinked substrate network to form a grafted polymeric network and a byproduct polymer. Also provided are precursors to the polymer compositions, processes for preparation of the polymer compositions, and methods of using the polymer compositions, for instance in medical devices. 1. A polymer composition formed by a process comprising:(a) providing a first reactive composition containing: (i) a polymerization initiator that is capable, upon a first activation, of forming two or more free radical groups, at least one of which is further activatable by subsequent activation; (ii) one or more ethylenically unsaturated compounds; and (iii) a crosslinker;(b) subjecting the first reactive composition to a first activation step such that the first reactive composition polymerizes therein to form a crosslinked substrate network containing a covalently bound activatable free radical initiator;(c) combining the crosslinked substrate network with a second reactive composition containing one or more ethylenically unsaturated compounds; and(d ...

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Номер записи: 100