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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Применить Всего найдено 14972. Отображено 100.

02-02-2012 дата публикации

Amphiphilic polysiloxane prepolymers and uses thereof

Номер: US20120029111A1

Автор: Arturo N. Medina, Dawn A. Smith, Frank Chang, Jinyu Huang, John Dallas Pruitt, Laura Ann Sanders, Robert Scott

Принадлежит: Individual

The present invention provides an amphiphilic polysiloxane prepolymer which comprises hydrophilic monomeric units derived from at least one hydrophilic vinylic monomer, polysiloxane crosslinking units derived from at least one polysiloxane crosslinker having at least two terminal ethylenically-unsaturated groups, dangling polysiloxane chains each of which is terminated with one ethylenically unsaturated group, and chain-transfer units derived from a chain transfer agent other than a RAFT agent. A prepolymer of the invention is suitable for making hydrogel contact lenses. The present invention is also related to hydrogel contact lenses made from an amphiphilic polysiloxane prepolymer of the invention and to processes for preparing an amphiphilic polysiloxane prepolymer of the invention and for making silicone hydrogel contact lenses.

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Номер записи: 1

09-02-2012 дата публикации

Method For The Production Of Copolymers

Номер: US20120035301A1

Автор: Christian Scholz, Mario Vierle

Принадлежит: CONSTRUCTION RESEARCH AND TECHNOLOGY GmbH

The invention relates to a process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus, comprising a polymerization reactor connected to a metering device, in each case acid monomer being initially taken in the metering device and polyether macromonomer and water in the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, free radical polymerization initiator being passed into the polymerization reactor before and/or during the metering of the acid monomer into the polymerization reactor so that an aqueous medium in which acid monomer and polyether macromonomer are reacted with formation of the copolymer by free radical polymerization forms in the polymerization reactor, the free radical polymerization initiator used being an H 2 O 2 — or alkali metal peroxodisulphate-containing redox initiator system, the temperature of the aqueous medium during the polymerization being adjusted to 5 to 43° C., the temperature of the aqueous medium being not more than 28° C. at the beginning of the polymerization, altogether 1 to 20 mol of acid monomer being metered into the polymerization reactor per mole of polyether macromonomer used, the weight ratio of polyether macromonomer used to water used being 5:1 to 1:5, at least 70% by weight of the water initially taken in the polymerization reactor being provided in the manner such that it is either added to the polymerization reactor at a temperature of not more than 19° C. or it is combined with the polyether macromonomer before it is added to the polymerization reactor and thus has a temperature of not more than 19° C.

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Номер записи: 2

22-03-2012 дата публикации

Ethylene copolymer with peg, cationic and anionic units, cosmetic composition including same and treatment method

Номер: US20120070399A1

Автор: Gwenaëlle JEGOU

Принадлежит: LOreal SA

The present invention relates to novel ethylenic copolymers comprising: a) from 25 to 95% by weight of monomer of formula (I), comprising PEG units; b) from 4 to 50% by weight of cationic monomer or one of its salts; c) from 1 to 35% by weight of anionic monomer and/or its salts. The invention also relates to cosmetic compositions, in particular hair compositions, comprising said copolymers and to a cosmetic treatment method employing them.

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Номер записи: 3

07-06-2012 дата публикации

Acrylate composition

Номер: US20120142867A1

Автор: Daichi Ogawa, Takeshi Iwasaki, Tomoaki Takebe, Yutaka Obata

Принадлежит: Idemitsu Kosan Co Ltd

The invention provides a composition containing (A) one or more (meth)acrylate compounds selected from among a (meth)acryl-modified silicone fluid, a long-chain alkyl(meth)acrylate, and a polyalkylene glycol(meth)acrylate having a number average molecular weight of 400 or more; (B) a (meth)acrylate compound having an alicyclic hydrocarbon group which has six or more carbon atoms and which is bonded to the compound via an ester bond; (C) (meth)acrylic acid or a (meth)acrylate compound having a polar group; and (D) a radical polymerization initiator. The composition is suitably employed as a raw material for, for example, an encapsulating material or a lens, exhibits transparency and heat resistance comparable to conventional levels, and provides a cured product exhibiting excellent adhesion to a base member surrounding the cured product.

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Номер записи: 4

14-06-2012 дата публикации

Photoreactive polymer and method for preparing the same

Номер: US20120149848A1

Автор: Dai-Seung Choi, Dong-Woo Yoo, Heon Kim, Hye-young Jung, Sung-Don Hong, Sung-Ho Chun

Принадлежит: LG Chem Ltd

The present invention relates to a photoreactive polymer that comprises a multi-cyclic compound in a main chain, and a polymerization method thereof. Since the photoreactive polymer according to the present invention comprises a multi-cyclic compound having a high glass transition temperature as a main chain, the thermal stability is excellent, and since the mobility of the main chain is relatively high as compared to that of an additional polymer, a photoreactive group can be freely moved in the main chain of the polymer. Accordingly, it is possible to overcome a slow photoreactive rate that is considered a disadvantage of a polymer material used to prepare an alignment film for known liquid crystal display devices.

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Номер записи: 5

26-07-2012 дата публикации

Reactive systems

Номер: US20120190787A1

Автор: Janin Tecklenburg, Klaus-Wilhelm Lienert, Majdi Al-Masri, Michael Berkei, Sabine Voedisch, Thomas Sawitowski

Принадлежит: Elantas GmbH

Reactive system comprising at least one component (I) composed of particles in very finely divided form present in a liquid phase of at least one further component (II) with which component (I) is capable of reacting following activation through energy supply, wherein component (I) is not soluble in component (II), process for preparation and use.

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Номер записи: 6

30-08-2012 дата публикации

Pressure sensitive adhesive comprising blend of synthetic rubber and functionalized synthetic rubber bonded to an acylic polymer

Номер: US20120216953A1

Автор: Babu N. Gaddam, Guy D. Joly, Jingjing Ma, Peiwang Zhu, Sanat Mohanty, Shujun Wang, Vivek Bharti

Принадлежит: 3M Innovative Properties Co

A pressure sensitive adhesive composition is described comprising unfunctionalized (e.g. polyisobutylene) synthetic rubber and an acrylic polymer having functionalized polyisobutylene polymer bonded to the acrylic polymer. In some embodiments, the functionalized polyisobutylene polymer has a first functional group hydrogen bonded with a second functional group present in the acrylic polymer backbone. In other embodiments, the functionalized polyisobutylene polymer is covalently bonded to the acrylic polymer backbone. Also described are adhesive articles, such as a tape, methods of adhesively bonding, and methods of making a pressure sensitive adhesive.

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Номер записи: 7

27-09-2012 дата публикации

Farnesene interpolymers

Номер: US20120244304A1

Автор: Derek James Mcphee

Принадлежит: Amyris Inc

Farnesene interpolymer comprises units derived from a farnesene (e.g., α-farnesene or β-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an α-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.

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Номер записи: 8

04-10-2012 дата публикации

Curable resin composition, surface protection method, temporary fixation method, and separation method

Номер: US20120246913A1

Автор: Kazuhiro Oshima, Tomoyuki Kanai

Принадлежит: Denki Kagaku Kogyo KK

Provided is a method for protecting the surface of a member to be processed, which comprises providing a protective film made of a photocurable resin composition for surface protection on the surface of the member to be processed, processing the member to be processed, and removing the protective film from the member to be processed, wherein the photocurable resin composition comprises (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton and (D) a photopolymerization initiator, which comprises from 1 to 50 parts by weight of (A), from 5 to 95 by mass of (B) and from 0.1 to 50 parts by mass of (C).

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Номер записи: 9

18-10-2012 дата публикации

Black curable composition for wafer - level lens, and wafer - level lens

Номер: US20120262793A1

Автор: Masaru Yoshikawa, Yoshiharu Yabuki, Yushi Kaneko

Принадлежит: Fujifilm Corp

A black curable composition for a wafer-level lens including (A) a metal-containing inorganic pigment, (B) a polymerization initiator, (C) a polymerizable compound, and (D) a cardo resin.

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Номер записи: 10

15-11-2012 дата публикации

Polybutadiene derivative composition

Номер: US20120289638A1

Автор: Hiroki Hashimoto, Yukikazu Nobuhara

Принадлежит: Nippon Soda Co Ltd

An object of the present invention is to provide a composition containing a stabilizer which does not turn yellow upon curing and which acts as a polymerization inhibitor during production and storage of a (meth)acrylic modified (hydrogenated) polybutadiene. The curable composition is characterized in that it contains 0.1-99.9999% by weight of component (A) which is a (meth)acrylic modified (hydrogenated) polybutadiene, and 0.0001-10% by weight of component (B) which is a compound represented by formula (IV).

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Номер записи: 11

22-11-2012 дата публикации

Photocurable resin composition and light-emitting element sealant

Номер: US20120296000A1

Автор: Kiyohiko Atami, Naoyuki Oomori, Toshihiko Kurata

Принадлежит: Bridgestone Corp

Provided are a photocurable resin composition which has a short time required for curing to make it possible to enhance the productivity and which can provide a light-emitting element sealant having an excellent heat resistance and an excellent optical transparency and a light-emitting element sealant prepared by using the above photocurable resin composition. To be specific, provided are a photocurable resin composition comprising 100 parts by mass of an end-modified hydrogenated styrene-butadiene rubber (A) and 0.1 to 13 parts by mass of an α-hydroxyalkylphenone base photopolymerization initiator and/or an acylphosphine oxide base photopolymerization initiator and a light-emitting element sealant prepared by using the above photocurable resin composition (B).

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Номер записи: 12

03-01-2013 дата публикации

Compositions comprising a reactive monomer and with a urea or urethane functional group

Номер: US20130004667A1

Автор: David K. Hood, Osama M. Musa

Принадлежит: ISP Investments LLC

Disclosed herein are compositions comprising a reactive monomer, and, in particular, coating and/or reactive coating compositions. More particularly, compositions containing monomers comprising a lactam moiety, a urethane or urea functional group, and a polymerizable moiety are disclosed.

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Номер записи: 13

17-01-2013 дата публикации

Contact lens

Номер: US20130015595A1

Автор: Robert Andrew Broad

Принадлежит: Sauflon CL Ltd

A contact lens formed of a composition comprising the reaction product of: A) at least 10 weight percent, based on the total composition weight excluding solvent, of at least one silicone-containing monomer of the formula I: where n is from 1 to 3, m is from 9 to 15, each a independently is C 1-4 alkyl, and each b independently is C 1-4 alkyl; B) at least 10 weight percent, based on the total composition weight excluding solvent, of 3-methacryloxypropyl tris(trimethylsiloxy)silane; C) N-vinyl pyrrolidone; and D) at least one other non-ionic hydrophilic monomer wherein the combined amount of A) and B) is at least 20 weight percent based on the total composition weight excluding solvent, and wherein the N-vinyl pyrrolidone (NVP) is present in such an amount that the reaction product comprises polyvinyl pyrrolidone (PVP) homopolymer.

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Номер записи: 14

28-03-2013 дата публикации

Novel thickening polymer for ionic oil phases free of monomers

Номер: US20130079420A1

Автор: Jean-Noel Ollagnier, Olivier Braun

Принадлежит: Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA

A copolymer that includes for 100 mol %: a) more than 70 mol % and up to 99.9 mol % of hydrophobic monomer units (A) from stearyl methacrylate; and b) 0.1 mol % to 30 mol % of monomer units (B) from at least one monomer of a compound of formula (I) where R1 is a linear or branched alkyl radical comprising 12 to 22 carbon atoms, R2 is a hydrogen atom or a methyl radical, and n is an integer greater than or equal to 0 and lower than or equal to 30, wherein it is understood that said compound of formula (I) is not stearyl methacrylate. The invention also relates to a method for preparing and using same as a modifier of the rheology of the oil phase of a topical cosmetic, dermopharmaceutical, or pharmaceutical composition.

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Номер записи: 15

06-06-2013 дата публикации

Liquid resin composition and semiconductor device

Номер: US20130143983A1

Автор: Kouji Makihara, Ryuichi Murayama

Принадлежит: Sumitomo Bakelite Co Ltd

According to the invention, a liquid resin composition which has favorable wet spreadability after mounting of a chip and exhibits excellent solder cracking resistance even in a high-temperature solder reflow process at about 260° C., i.e., even when being used in lead-free solder, and a semiconductor package using the liquid resin composition are provided. In the liquid resin composition of the invention, an acrylic copolymer having a radical polymerizable functional group contains alkyl(meth)acrylate as a constituent monomer having a linear or branched alkyl group having 6 to 9 carbon atoms in an amount of 10 wt % to 40 wt % of the entire constituent monomers.

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Номер записи: 16

04-07-2013 дата публикации

Ionic silicone hydrogels

Номер: US20130168617A1

Автор: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin

Принадлежит: Johnson and Johnson Vision Care Inc

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.

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Номер записи: 17

04-07-2013 дата публикации

Alkaline solubie resin and light sensible resin composition comprising same and use thereof

Номер: US20130171566A1

Автор: Chunmiao Zhou, Jianshe XUE, Jisheng ZHAO, Shi Shu, Xiaoxiong TIAN, Xuelan WANG

Принадлежит: BOE Technology Group Co Ltd

An embodiment of the invention discloses an alkaline soluble resin and a method for preparing the same. The chemical formula of this alkaline soluble resin is shown in Formula I: wherein a is an integer of 1 to 5, b is an integer of 1 to 5, c is an integer of 1 to 10, d is an integer of 1 to 10, m is an integer of 1 to 30, n is an integer of 1 to 10, R is hydrogen, alkyl, alkoxy or acrylate; the alkaline soluble resin has a weight-average molecular weight of 3,500-35,000. The invention also discloses a light sensible resin composition comprising the alkaline soluble resin, as well as a colored photoresist for color filters comprising the aforementioned light sensible resin composition and a display element comprising this colored photoresist.

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Номер записи: 18

18-07-2013 дата публикации

Monomer composition containing unsaturated polyalkylene glycol ether-based monomer, method for producing composition thereof, polymer obtained using composition thereof, and method for producing polymer thereof

Номер: US20130184420A1

Автор: Hiroshi Kawabata

Принадлежит: NIPPON SHOKUBAI CO LTD

To provide a monomer composition containing an unsaturated polyalkylene glycol ether-based monomer and having excellent stability. Provided is a monomer composition containing an unsaturated polyalkylene glycol ether-based monomer represented by the following chemical formula (1): YO(R 1 O) n R 2 (1) [in the formula, Y represents an alkenyl group having 2 to 7 carbon atoms; R 1 O represents one or two or more types of oxyalkylene groups having 2 to 18 carbon atoms; n represents an average addition mole number of oxyalkylene groups and is a number of 5 to 500; and R 2 represents a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms], an organic acid, and water, and having a pH of 4 to 13.

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Номер записи: 19

12-09-2013 дата публикации

Biomedical devices containing internal wetting agents

Номер: US20130237631A1

Автор: Azaam Alli, Douglas G. Vanderlaan, Frank F. Molock, JR., Gregory A. Hill, James D. Ford, Kevin P. Mccabe, Robert B. Steffen

Принадлежит: Johnson and Johnson Vision Care Inc

This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer.

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Номер записи: 20

12-09-2013 дата публикации

(meth)acrylate composition

Номер: US20130237660A1

Автор: Daichi Ogawa, Takeshi Iwasaki, Tomoaki Takebe, Yutaka Obata

Принадлежит: Idemitsu Kosan Co Ltd

Provided is a (meth)acrylate composition containing: (A) at least one (meth)acrylate compound selected from the group consisting of a (meth)acrylate-modified silicone oil, a (meth)acrylate having a long-chain aliphatic hydrocarbon group, and a polyalkylene glycol (meth)acrylate having number-average molecular weight of not less than 400; (B) a (meth)acrylate compound to which an alicyclic hydrocarbon group having 6 or more carbon atoms is ester-linked; (C) (meth)acrylic acid or a (meth)acrylate compound having a polar group; (D) a radical polymerization initiator; and (E) a white pigment.

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Номер записи: 21

03-10-2013 дата публикации

Transfer film and method for producing same, and laminate and method for producing same

Номер: US20130258479A1

Автор: Hideto Yamazawa, Hiroshi Okafuji, Osamu Kawai, Tetsuya Sawano

Принадлежит: Mitsubishi Rayon Co Ltd

Provided is a transfer film wherein: a low-refractive-index film having a refractive index (Nx) and a high-refractive-index film having a refractive index (Ny) are laminated in this order on one surface of a peeling film; the refractive indices satisfy Nx<Ny; and the high-refractive-index film contains an aminosilane. Also provided is a laminate wherein: a high-refractive-index film and a low-refractive-index film are laminated in this order on the surface of a substrate; and the high-refractive-index film contains an aminosilane. The transfer film is obtained by successively laminating and curing a composition for the low-refractive-index film and a composition for the high-refractive-index film on the peeling film. The laminate is produced by bonding the surface of the high-refractive-index film of the transfer film to the substrate, and then peeling away the peeling film.

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Номер записи: 22

07-11-2013 дата публикации

Polymer

Номер: US20130295040A1

Автор: Adam Peter Jarvis, Adrian Carmichael, Andrew Gregory Steward, David M. Haddleton, François LECOLLEY, Giuseppe Mantovani, Lei Tao

Принадлежит: Warwick Effect Polymers Limited

The application provides a method of producing a comb polymer comprising the steps of: (a) Providing: (i) a plurality of monomers which are linear, branched or star-shaped, substituted or non-substituted, and have an olefinically unsaturated moiety, the olefinically unsaturated moiety being capable of undergoing addition polymerisation; (ii) an initiator compound; the initiator compound comprising a homolytically cleavable bond. (iii) a catalyst capable of catalysing the polymerisation of the monomer; and (b) Causing the catalyst to catalyse, in combination with the initiator, the polymerisation of a plurality of the monomers to produce the comb polymer. Catalysts and polymers obtainable by the process are also provided. Preferably, the comb polymer is capable of binding proteins and may be produced from monomers which are alkoxy polyethers, such as poly(alkyleneglycol) or polytetrahydrofuran.

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Номер записи: 23

14-11-2013 дата публикации

Active energy ray-curable resin composition, product having the uneven microstructure, and method for producing product having the uneven microstructure

Номер: US20130302564A1

Автор: Eiko Okamoto, Go Otani, Tsuyoshi Takihara, Yusuke Nakai

Принадлежит: Mitsubishi Rayon Co Ltd

The present invention provides an active energy ray-curable resin composition comprising at least a multifunctional monomer having three or more radical polymerizable functional groups in the molecule in which the cured product of the composition exhibits anti-reflective function because of an uneven microstructure formed on the surface of the cured product, and provides a product having the uneven microstructure having high decontaminating properties such as fingerprint removal properties and high scratch resistance.

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Номер записи: 24

14-11-2013 дата публикации

ARBORESCENT POLYMERS AND PROCESS FOR MAKING SAME

Номер: US20130303688A1

Автор: Kaszas Gabor, Kulbaba Kevin, Puskas Judit E.

Принадлежит:

The present invention relates to arborescent polymers and to a process for making same. In one embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with a polymer or copolymer having a low glass transition temperature (T), and to a process for making such arborescent polymers. In another embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with less than about 5 weight percent end blocks derived from a polymer or copolymer having a high glass transition temperature (T), and to a process for making such arborescent polymers. 1. An end-functionalized arborescent polymer comprising an arborescent elastomeric polymer having two or more branching points and a low glass transition temperature (T) having less than 5 wt. % end blocks derived from a polymer or copolymer having a high glass transition temperature (T).2. The end-functionalized arborescent polymer of claim 1 , wherein the end-functionalized arborescent polymer exhibits thermoplastic elastomeric properties.3. The end-functionalized arborescent polymer of claim 1 , wherein the arborescent elastomeric polymer comprises an arborescent polyisoolefin core.5. The end-functionalized arborescent polymer of claim 4 , wherein the inimer of Formula (I) comprises either an aryl or alkyl group joining A and B.6. The end-functionalized arborescent polymer of claim 4 , wherein the inimer of Formula (I) comprises a benzene ring joining A and B.8. The end-functionalized arborescent polymer of claim 4 , wherein the arborescent elastomeric polymer is formed from at least one inimer selected from the group consisting of 4-(2-hydroxyisopropyl)styrene claim 4 , 4-(2-methoxyisopropyl)styrene claim 4 , 4-(1-methoxyisopropyl)styrene claim 4 , 4-(2-chloroisopropyl)styrene claim 4 , 4-(2-acetoxyisopropyl)styrene claim 4 , 2 claim ...

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Номер записи: 25

21-11-2013 дата публикации

Hard coat coating composition for metal base material and molded product

Номер: US20130309510A1

Автор: Takashi Isogai

Принадлежит: Fujikura Kasei Co Ltd

A hard coat coating composition for a metal base material, includes a coated film forming component including a urethane(meth)acrylate (A) having a carboxyl group and having a solid fraction acid value being value of 0.5 to 2.0 mgKOH/g, a urethane(meth)acrylate (B) not having a carboxyl group, a thermoplastic resin (C) having a carboxyl group and having a solid fraction acid value of 1.0 to 30 mgKOH/g, and a silane coupling agent (D).

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Номер записи: 26

28-11-2013 дата публикации

Modifier for polyvinylidene fluoride, binder resin composition for battery, electrode for secondary battery and battery

Номер: US20130316234A1

Автор: Fumino Momose, Mitsufumi Nodono

Принадлежит: Mitsubishi Rayon Co Ltd

A modifier for polyvinylidene fluoride (PVDF), which improves the adhesion of PVDF to a metal, a binder resin composition for battery and a battery using the PVDF modifier are provided. The modifier for polyvinylidene fluoride herein is a modifier in which the peeling strength of a specific cured film to an aluminium foil is 20 g/cm or more, and the specific cured film is obtained from a mixture of 6 parts by mass of the modifier for polyvinylidene fluoride and 14 parts by mass of a polyvinylidene fluoride composition. The modifier preferably contains a macromonomer copolymer (X), obtained by polymerizing both a macromonomer (A) having unsaturated double bonds and a vinyl monomer (B) having polar groups. The macromonomer (A) is preferably a methacrylic acid ester-based macromonomer (A-1). The vinyl monomer (B) is preferably a methacrylate, and a fluoroalkyl methacrylate.

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Номер записи: 27

06-03-2014 дата публикации

Nanoimprint curable composition, nanoimprint-lithographic molded product, and method for forming pattern

Номер: US20140061970A1

Автор: Hisashi Tanimoto, Hitoshi Sekine, Naoto Yagi, Yasuhiro Takada

Принадлежит: DIC Corp

The present invention provides a nanoimprint curable composition to be used in “nanoimprint lithography” in which a nanoimprint mold is pressed to transfer a fine concave-convex pattern, the nanoimprint curable composition containing a composite resin which has a polysiloxane segment and a polymer segment other than the polysiloxane segment, the polysiloxane segment containing a silanol group and/or hydrolyzable silyl group and having a polymerizable double bond. In addition, the present invention provides a nanoimprint-lithographic molded product, resist film, resin mold, and method for forming a pattern, which each involves use of the nanoimprint composition.

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Номер записи: 28

02-01-2020 дата публикации

RESIN COMPOSITION, PREPREG, RESIN-COATED FILM, RESIN-COATED METAL FOIL, METAL-CLAD LAMINATE, AND WIRING BOARD

Номер: US20200001573A1

Автор: FUJIWARA Hiroaki, SAITO Hirosuke, Tsuda Kosuke

Принадлежит: Panasonic Intellectual Property Management Co., Ltd.

A resin composition which comprises: a modified polyphenylene ether having, at a terminal, a group represented by a formula (1) given below; a radical-polymerizable compound having, only at molecular terminals, two or more bonds or groups of at least one selected from the group consisting of a carbon-carbon unsaturated double bond and a maleimide group; a styrene-based thermoplastic elastomer in which repeating units having a carbon-carbon unsaturated double bond not belonging to an aromatic ring are contained in an amount less than 10 mol % with respect to all the repeating units; and an organic peroxide. In the formula (1), Rrepresents a hydrogen atom or an alkyl group. 2. The resin composition according to claim 1 , wherein claim 1 , in the styrene-based thermoplastic elastomer claim 1 , a ratio of the repeating units having a carbon-carbon unsaturated double bond contained in a molecular chain among the repeating units having a carbon-carbon unsaturated double bond not belonging to an aromatic ring is less than 3 mol % with respect to all the repeating units.3. The resin composition according to claim 2 , wherein the carbon-carbon unsaturated double bond contained in the molecular chain is a vinylene group.4. The resin composition according to claim 1 , wherein the radical-polymerizable compound is a radical-polymerizable compound having claim 1 , only at molecular terminals claim 1 , two or more groups of at least one selected from the group consisting of allyl group claim 1 , vinyl group claim 1 , acrylate group claim 1 , methacrylate group claim 1 , and maleimide group.5. The resin composition according to claim 1 , wherein the modified polyphenylene ether has a weight average molecular weight of 500 to 3000 and has claim 1 , at a molecular terminal claim 1 , an average of 1 to 5 groups represented by the formula (1) given above per one molecule.6. The resin composition according to claim 1 , wherein the styrene-based thermoplastic elastomer has a weight ...

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Номер записи: 29

03-01-2019 дата публикации

ANTIFOULING FILM

Номер: US20190001612A1

Автор: HAYASHI Hidekazu, NIINOH Atsushi

Принадлежит:

The antifouling film includes a polymer layer that includes on a surface thereof an uneven structure provided with multiple projections at a pitch not longer than a wavelength of visible light. The polymer layer has a proportion of the number of fluorine atoms relative to the sum of the numbers of carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms of 33 atom % or more on the surface of the uneven structure. The polymer layer has at least one local maximum of the proportion of the number of nitrogen atoms relative to the sum of the numbers of carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms in a region 5 to 90 nm deep from the surface of the uneven structure. The local maximum is 0.3 atom % or more greater than the average value in a region 90 to 120 nm deep from the surface of the uneven structure. 1. An antifouling film comprisinga polymer layer that includes on a surface thereof an uneven structure provided with multiple projections at a pitch not longer than a wavelength of visible light,the polymer layer being a cured product of a resin containing an antifouling agent and a curable resin and containing carbon atoms, nitrogen atoms, oxygen atoms, and fluorine atoms as constituent atoms,the antifouling agent containing fluorine atoms as constituent atoms,the curable resin containing nitrogen atoms as constituent atoms,fluorine atoms in the antifouling agent being distributed on the surface of the polymer layer,the polymer layer having a proportion of the number of the fluorine atoms relative to the sum of the numbers of the carbon atoms, the nitrogen atoms, the oxygen atoms, and the fluorine atoms measured by X-ray photoelectron spectroscopy of 33 atom % or more on the surface of the uneven structure,the polymer layer having at least one local maximum of the proportion of the number of the nitrogen atoms relative to the sum of the numbers of the carbon atoms, the nitrogen atoms, the oxygen atoms, and the fluorine atoms measured by X-ray ...

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Номер записи: 30

07-01-2016 дата публикации

Additive for hydraulically setting compounds

Номер: US20160002435A1

Автор: Alexander Kraus, Harald Grassl, Luc Nicoleau, Martin Winklbauer, Torben GÄDT

Принадлежит: CONSTRUCTION RESEARCH AND TECHNOLOGY GmbH

The present invention relates to an additive for hydraulically setting compositions, comprising a colloidally disperse preparation of at least one water-soluble salt of a polyvalent metal cation, at least one compound capable of releasing an anion which forms a sparingly soluble salt with the polyvalent metal cation, and at least one polymeric dispersant which comprises anionic and/or anionogenic groups and polyether side chains.

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Номер записи: 31

04-01-2018 дата публикации

Low-temperature-curable cross-section repair material, and cross-section repairing method using the same

Номер: US20180002562A1

Автор: Atsushi Umino, Kunihiro Kuroki

Принадлежит: Showa Denko KK

Provided is a low-temperature-curable cross-section repair material which can be cured in a short period of time, even in extremely low temperature environments of −25° C., and which exhibits excellent workability and strength development. Also provided is a cross-section repairing method using the same. The low-temperature-curable cross-section repair material is characterized by: comprising 100 parts by of a radical polymerizable resin composition (A), 0.1-10 parts by of a hydroxyl group-containing aromatic tertiary amine (C-1), 0.1-10 parts by of an organic peroxide (D), and 1.0-500 parts by of an inorganic filler (E); and the radical polymerizable resin composition (A) comprising at least one type of radical polymerizable resin (A-1) selected from the group consisting of vinyl ester resins, urethane (meth)acrylate resins and polyester (meth)acrylate resins, and a radical polymerizable unsaturated monomer (A-2) having at least two or more (meth)acryloyl groups per molecule thereof.

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Номер записи: 32

03-01-2019 дата публикации

ONE-PART CURABLE SOFT FEEL COATINGS

Номер: US20190002616A1

Автор: DRUJON Xavier, GUPTA Manjuli, KLANG Jeffrey, Spagnola Lisa M.

Принадлежит:

Disclosed herein arc one part, One-part, curable compositions that have a soft feel when applied as a coating/film and cured, may include a) at least one isocyanurate tri(meth)acrylate or derivative thereof; and at least one of components b)-e), wherein: b) is at least one urethane diacrylate; c) is at least one monofunctional or difunctional reactive diluent; d) is at least one solvent; and e) is additives. The one-part, curable compositions are advantageous with respect to softness and tailorability of softness as well as other properties such as mar resistance, abrasion resistance, stain resistance and chemical resistance. Due to their advantageous properties, embodiments of the one-part, curable compositions described herein are viable for a wide range of coating applications including automotives, aeronautics, cosmetics, small appliances, packaging and consumer electronics. Methods of making and using the one-part, curable are also described herein. 1. A one-part , curable composition comprising: b) at least one urethane diacrylate;', 'c) at least one monofunctional or difunctional reactive diluent, different from b)', 'd) at least one solvent; and', 'e) additives., 'a) at least one isocyanurate tri(meth)acrylate or derivative thereof and at least one of2. The one-part claim 1 , curable composition of claim 1 , wherein the composition comprises the b) at least one urethane diacrylate.3. The one-part claim 1 , curable composition of claim 1 , wherein the a) at least one isocyanurate tri(meth)acrylate or derivative thereof comprises tris(2-hydroxyethyl)isocyanurate triacrylate.4. The one-part claim 1 , curable composition of claim 1 , wherein the composition comprises the d) at least one solvent.5. The one-part claim 1 , curable composition of claim 1 , wherein the composition comprises the e) additives claim 1 , wherein the additives are selected from the group consisting of photo-initiators claim 1 , thermal free radical initiators claim 1 , accelerators claim ...

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Номер записи: 33

07-01-2021 дата публикации

RESIN COMPOSITION, PREPREG, RESIN-INCLUDING FILM, RESIN-INCLUDING METAL FOIL, METAL-CLAD LAMINATE, AND WIRING BOARD

Номер: US20210002480A1

Автор: FUJISAWA Hiroyuki, Nakamura Yoshihiko, SHINPO Takashi, TOSHIMITSU KENICHI, TUMURAYA Yuuji, YAMAUCHI AKIHIRO

Принадлежит: Panasonic Intellectual Property Management Co., Ltd.

A resin composition is used which contains a maleimide compound represented by the following Formula (1), a modified polyphenylene ether compound of which a terminal is modified with a substituent having a carbon-carbon unsaturated double bond, and a crosslinking agent containing an allyl compound. 2. The resin composition according to claim 1 , wherein the crosslinking agent further includes at least one of a polyfunctional acrylate compound having two or more acryloyl groups in a molecule and a polyfunctional methacrylate compound having two or more methacryloyl groups in a molecule.3. The resin composition according to claim 2 , wherein the polyfunctional methacrylate compound includes a dimethacrylate compound.4. The resin composition according to claim 1 , wherein the allyl compound includes at least one of triallyl isocyanurate and diallyl bisphenol.5. The resin composition according to claim 1 , wherein a content of the maleimide compound is 10 to 60 parts by mass with respect to 100 parts by mass of a total mass of the maleimide compound claim 1 , the modified polyphenylene ether compound claim 1 , and the crosslinking agent.6. The resin composition according to claim 1 , wherein a content of the modified polyphenylene ether compound is 10 to 75 parts by mass with respect to 100 parts by mass of a total mass of the maleimide compound claim 1 , the modified polyphenylene ether compound claim 1 , and the crosslinking agent.7. The resin composition according to claim 1 , further comprising an inorganic filler treated in advance with a silane coupling agent.8. A prepreg comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the resin composition according to or a semi-cured product of the resin composition; and'}a fibrous base material.9. A film with resin comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a resin layer containing the resin composition according to or a semi-cured product of the resin composition; and'}a support film.10. A ...

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Номер записи: 34

03-01-2019 дата публикации

Functionalized (poly)alkoxylated (per)fluoropolyether polymers

Номер: US20190002633A1

Автор: Giovanni Simeone, Pier Antonio Guarda, Silvia Rita Petricci

Принадлежит: Solvay Specialty Polymers Italy SpA

The present invention relates to novel derivatives of (poly)alkoxylated (per)fluoropolyethers, also referred to as PFPE-PAGs, comprising unsaturated end groups bearing acrylate, allylic or vinylic moieties.

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Номер записи: 35

03-01-2019 дата публикации

ENVIRONMENTALLY-SENSITIVE MATERIAL AND METHOD FOR MANUFACTURING SAME

Номер: US20190002643A1

Автор: CHIEN HSIU-WEN

Принадлежит:

An environmentally-sensitive material includes a sensitive layer and a base. The sensitive layer includes a mixed portion and a sensitive portion seamlessly connected to the mixed portion. The mixed portion is made of a mixture of a first polymer gel and a second polymer gel. The sensitive portion is made of the second polymer gel. The second polymer gel is a reversible gel which is able to revert to an original size and state as a changed environmental factor reverts to a starting state. A method for manufacturing the material is also provided. 1. An environmentally-sensitive material , comprising:a sensitive layer, comprising a mixed portion and a sensitive portion, the mixed portion having a first side and a second side opposite to the first side, the entire sensitive portion being seamlessly connected to the second side of the mixed portion, the mixed portion being a mixture of a first polymer gel and a second polymer gel, the sensitive portion being the second polymer gel, the second polymer gel being a reversible gel; anda base adhered with the sensitive layer.2. The environmentally-sensitive material of claim 1 , wherein the first polymer gel is a non-sensitive gel.3. The environmentally-sensitive material of claim 2 , wherein the first polymer gel is a polyethyleneglycol based hydrogel.4. The environmentally-sensitive material of claim 3 , wherein the second polymer gel is a thermo-sensitive gel.5. The environmentally-sensitive material of claim 4 , wherein the second polymer gel is a poly N-isopropylacrylamide based hydrogel.6. The environmentally-sensitive material of claim 5 , wherein the second polymer gel is polymerized by a gel pre-polymer mixture claim 5 , comprising a mixture of N-isopropylacrylamide claim 5 , ethylene glycol dimethacrylate claim 5 , and an initiator; the second polymer gel has a critical solution temperature of about 37 degrees Celsius.7. The environmentally-sensitive material of claim 1 , wherein from the first side of the mixed ...

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Номер записи: 36

03-01-2019 дата публикации

AQUEOUS DISPERSIONS, COATING COMPOSITIONS FORMED WITH AQUEOUS DISPERSIONS, AND MULTI-LAYER COATINGS

Номер: US20190002709A1

Автор: Sadvary Richard J., Swarup Shanti, Xu Xiangling, Zhou Hongying

Принадлежит:

An aqueous dispersion includes an aqueous medium and self-crosslinkable core-shell particles dispersed in the aqueous medium. The core-shell particles include (1) a polymeric core at least partially encapsulated by (2) a polymeric shell having urethane linkages, keto and/or aldo functional groups, and hydrazide functional groups. Further, the polymeric core is covalently bonded to at least a portion of the polymeric shell. 1. An aqueous dispersion comprising an aqueous medium and self-crosslinkable core-shell particles dispersed in the aqueous medium , wherein the core-shell particles comprise (1) a polymeric core at least partially encapsulated by (2) a polymeric shell comprising urethane linkages , keto and/or aldo functional groups , and hydrazide functional groups , andwherein the polymeric core is covalently bonded to at least a portion of the polymeric shell.2. The aqueous dispersion of claim 1 , wherein the polymeric core of the self-crosslinkable core-shell particles comprises an addition polymer derived from ethylenically unsaturated monomers.3. The aqueous dispersion of claim 2 , wherein the ethylenically unsaturated monomers comprise a (meth)acrylate monomer claim 2 , a vinyl monomer claim 2 , or a combination thereof.4. The aqueous dispersion of claim 1 , wherein the polymeric shell of the self-crosslinkable core-shell particles further comprises at least one water dispersible group.5. The aqueous dispersion of claim 4 , wherein the at least one water dispersible group is selected from carboxylic acid functional groups claim 4 , salts thereof and/or polyoxyalkylene groups.6. The aqueous dispersion of claim 1 , wherein the self-crosslinkable core-shell particles are formed from a mixture of reactants comprising: (a) isocyanate-functional ethylenically unsaturated polyurethane prepolymers; (b) a Michael addition reaction product of ethylenically unsaturated monomers comprising a keto and/or aldo functional group claim 1 , and a compound comprising at least ...

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Номер записи: 37

14-01-2021 дата публикации

CORE-CORONA POLYMER PARTICLES

Номер: US20210007965A1

Автор: FUKUHARA Ryushi, SUGIYAMA Yuki

Принадлежит: SHISEIDO COMPANY, LTD.

Provided are a raw material for a cosmetic and an oil-in-water emulsion cosmetic comprising a core-corona polymer particle excellent in emulsion stability and feeling of use. Certain embodiments of the present invention provides a raw material for a cosmetic, comprising a core-corona polymer particle dispersion obtained by radical-polymerizing a polyethylene oxide macromonomer represented by formula (1) and one or two or more of hydrophobic monomers represented by formulas (2) and (3) under conditions (A) to (D). 2. An emulsifier comprising a core-corona polymer particle according to .3. A clouding agent comprising a core-corona polymer particle according to .4. The core-corona polymer particle according to claim 1 , wherein a particle size of the core-corona polymer particle is 50 to 600 nm.5. A cosmetic raw material comprising a core-corona polymer particle according to .6. A raw material for a cosmetic claim 1 , comprising a core-corona polymer particle according to and ethylene glycol dimethacrylate as a cross-linking agent.7. An oil-in-water emulsion cosmetic comprising a core-corona polymer particle according to .8. A water-in-oil emulsion cosmetic comprising a core-corona polymer particle according to . The present application claims the priority of Japanese Patent Application No. 2018-057271 filed on Mar. 23, 2018, which is incorporated herein.The present invention relates to a core-corona polymer particle. Particularly, the present invention relates to improvement in the emulsion stability and usability of a cosmetic containing the same.For stably dispersing a liquid in another liquid, emulsion cosmetics in the conventional sense require adding a surface-active substance (emulsifier). The emulsifier has an amphiphilic molecular structure and is constituted by polar (hydrophilic) and nonpolar (hydrophobic) moieties.In emulsion cosmetics for use in cosmetic products, etc., aqueous components and oil components are stably mixed by the emulsifying effect of an ...

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Номер записи: 38

14-01-2021 дата публикации

Curable composition for polymer electrolyte, and layered body

Номер: US20210008859A1

Автор: Kazumasa Inata

Принадлежит: TOAGOSEI CO LTD

Provided is a curable composition for a polymer electrolyte, including: a component (A): a radical polymerizable compound having a (meth)acryloyl group, a component (B): a compound having, in one molecule, an epoxy group and a skeleton of at least one selected from the group consisting of polybutadiene, polyisoprene, hydrogenated polybutadiene, and hydrogenated polyisoprene, and a component (C): a radical polymerization initiator, in which a content of each of the components (A) to (C) based on the entire composition is as follows, the component (A): from 30 to 98.9% by mass the component (B): from 1 to 40% by mass, and the component (C): from 0.1 to 15% by mass.

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Номер записи: 39

08-01-2015 дата публикации

Silicone hydrogels having a structure formed via controlled reaction kinetics

Номер: US20150011672A1

Автор: Azaam Alli, Douglas G. Vanderlaan, James D. Ford, Scott L. Joslin

Принадлежит: Johnson and Johnson Vision Care Inc

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.

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Номер записи: 40

14-01-2021 дата публикации

HYDROPHILIZED POLYDIORGANOSILOXANE VINYLIC CROSSLINKERS AND USES THEREOF

Номер: US20210009743A1

Автор: Chang Frank, HUANG JINYU, Jing Feng, Zhang Steve Yun

Принадлежит:

The invention provides a hydrophilized polydiorganosiloxane vinylic crosslinker which comprises (1) a polydiorganosiloxane polymer chain comprising dimethylsiloxane units and hydrophilized siloxane units each having one methyl substituent and one monovalent C-Corganic radical substituent having two to six hydroxyl groups, wherein the molar ratio of the hydrophilized siloxane units to the dimethylsiloxane units is from about 0.035 to about 0.15, and (2) two terminal (meth)acryloyl groups. The hydrophilized polydiorganosiloxane vinylic crosslinker has a number average molecular weight of from about 3000 Daltons to about 80,000 Daltons. The present invention is also related to a silicone hydrogel contact lens, which comprises repeating units derived from a hydrophilized polydiorganosiloxane vinylic crosslinker of the invention. 125-. (canceled)27. The silicone hydrogel contact lens of claim 26 , wherein in formula (1) Xis O.28. The silicone hydrogel contact lens of claim 27 , wherein in formula (1) ω1/υ1 is from about 0.040 to about 0.12.29. The silicone hydrogel contact lens of claim 28 , wherein in formula (2) q1 is zero or 1 claim 28 , n1 is an integer of 2 to 4 claim 28 , Ris hydrogen or methyl.31. The silicone hydrogel contact lens of claim 29 , wherein the crosslinked polymeric material comprises units of at least one hydrophilic vinylic monomer.32. The silicone hydrogel contact lens of claim 31 , wherein said at least one hydrophilic vinylic monomer is selected from the group consisting of N-vinylpyrrolidone claim 31 , N claim 31 ,N-dimethyl (meth)acrylamide claim 31 , (meth)acrylamide claim 31 , N-hydroxyethyl (meth)acrylamide claim 31 , N-hydroxypropyl (meth)acrylamide claim 31 , hydroxyethyl (meth)acrylate claim 31 , glycerol methacrylate (GMA) claim 31 , polyethylene glycol (meth)acrylate having a number average molecular weight of up to 1500 claim 31 , polyethylene glycol C-C-alkyl ether (meth)acrylate having a number average molecular weight of up to 1500 ...

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Номер записи: 41

14-01-2021 дата публикации

Thermoplastic acrylic resin and method for producing same, and resin composition

Номер: US20210009802A1

Автор: Sota OKUMURA, Takamasa Soejima, Yusuke Hirai

Принадлежит: Kaneka Corp

A thermoplastic acrylic resin is provided. The thermoplastic acrylic resin is a graft copolymer in which a stem polymer is an acrylic resin containing acrylonitrile and another ethylenically unsaturated monomer, and a branch polymer is a polymer composed of an ethylenically unsaturated monomer. The acrylonitrile is contained in an amount of 35 mass % or more and 84.5 mass % or less, the other ethylenically unsaturated monomer is contained in an amount of 15 mass % or more and 64.5 mass % or less, and the polymer composed of an ethylenically unsaturated monomer is contained in an amount of 0.5 mass % or more and 40 mass % or less. Thus, provided are a thermoplastic acrylic resin having improved melt-processability without compromising heat resistance, a method for producing the thermoplastic acrylic resin, a thermoplastic acrylic resin composition, a molded body, an acrylic fiber, and a method for producing the acrylic fiber.

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Номер записи: 42

09-01-2020 дата публикации

Multilayer Marking Film

Номер: US20200010722A1

Автор: Hye Jin Sim, Jang Soon Kim, Myung Hyun JO

Принадлежит: LG Chem Ltd

A multilayer marking film is disclosed herein. In some embodiments, a multilayer marking film includes, in sequential order, an adhesive layer, a colored base layer having a first color, and a colored coating layer having a second color, wherein information can be written by laser irradiation on the colored coating layer.

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Номер записи: 43

09-01-2020 дата публикации

VINYL-BASED COMB POLYMER

Номер: US20200010775A1

Автор: Ikari Yoshihiro

Принадлежит: KANEKA CORPORATION

A vinyl-based comb copolymer includes a polyisobutylene-based macromonomer unit and a vinyl-based monomer unit. A polyisobutylene-based macromonomer has at least 0.8 (meth)acryloyl groups represented by a specific formula at one end of a main chain per molecule, and is copolymerized with a vinyl-based monomer. A method for producing the vinyl-based comb copolymer includes copolymerizing the polyisobutylene-based macromonomer with the vinyl-based monomer. A viscosity index improver includes the comb copolymer. A lubricating oil composition includes the comb copolymer. 2. The vinyl-based comb copolymer according to claim 1 , wherein the vinyl-based comb copolymer contains 0.05 to 20 mol % of a polyisobutylene-based macromonomer unit.3. The vinyl-based comb copolymer according to claim 1 , wherein a molecular weight distribution (Mw/Mn) of the polyisobutylene-based macromonomer ranges from 1.0 to 1.8.4. The vinyl-based comb copolymer according to claim 1 , wherein a number-average molecular weight (Mn) of the polyisobutylene-based macromonomer ranges from 1 claim 1 ,000 to 200 claim 1 ,000 as a value obtained by size exclusion chromatography (SEC) measurement based on polystyrene standards.5. The vinyl-based comb copolymer according to claim 1 , wherein Rin the general formula (1) is at least one divalent hydrocarbon group selected from the group consisting of —CHCH— claim 1 , —CHCHCH— claim 1 , and —CHCHCHCH—.6. The vinyl-based comb copolymer according to claim 1 , wherein Rand Rin the general formula (1) are each hydrogen.7. The vinyl-based comb copolymer according to claim 1 , wherein Rin the general formula (1) is a methyl group.9. A method for producing the vinyl-based comb copolymer according to claim 1 , the method comprising copolymerizing the polyisobutylene-based macromonomer with the vinyl-based monomer.10. A viscosity index improver containing the comb copolymer according to .11. A lubricating oil composition containing the comb copolymer according to . One ...

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Номер записи: 44

19-01-2017 дата публикации

ACTIVE ENERGY RAY-CURABLE RESIN COMPOSITION AND AUTOMOBILE HEADLAMP LENS

Номер: US20170015774A1

Автор: MIYACHI Akira, Satou Hiroyuki

Принадлежит: MITSUBISHI RAYON CO., LTD.

Provided is an active energy ray-curable resin composition with which it is possible to form a cured film, having outstanding scratch resistance, hardness, and weather resistance, on the surface of a molded resin article for an automobile headlamp lens. The active energy ray-curable resin composition is used to form a cured film on the surface of a molded resin article for an automobile headlamp lens and comprises (A) 10-70% by mass of a mono- or poly-pentaerythritol poly(meth)acrylate compound having a specific structure, (B) 10-50% by mass of a urethane(meth)acrylate compound having at least two (meth)acryloyloxy groups, at least one amido group, and at least two urethane bonds, and (C) 20-80% by mass of a poly[(meth)acryloyloxyalkyl]isocyanurate compound having a specific structure. 2. The active energy ray-curable resin composition according to claim 1 , wherein the urethane (meth)acrylate mixture (B) is obtained by reacting materials (b1)-(b4) below:(b1): diisocyanate;(b2): a compound containing at least one amide group, which does not include the —NH—CO— structure in the urethane bond, and at least two hydroxyl groups;(b3): at least one type of diol selected from the group consisting of polyether diols, polycarbonate diols, and polyester diols other than material (b2); and(b4): a (meth)acrylic acid ester having at least one (meth)acryloyloxy group, and one hydroxyl group.3. The active energy ray-curable resin composition according to claim 2 , wherein material (b3) is a polyether diol other than material (b2).4. The active energy ray-curable resin composition according to claim 2 , wherein the molar equivalent ratio of materials (b1)-(b4) is [material (b1)]/[material (b2)+material (b3)]/[material (b4)]=10/4-6/4-6.5. The active energy ray-curable resin composition according to claim 2 , wherein the molar equivalent ratio of materials (b2) and (b3) is material (b2)/material (b3)=1-5/5-1.6. The active energy ray-curable resin composition according to claim 2 , ...

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Номер записи: 45

19-01-2017 дата публикации

Optically clear adhesives for durable plastic bonding

Номер: US20170015877A1

Автор: Albert I. Everaerts, Aya NAKADA, Hideyuki Hatanaka, Masaki Yoda, Shunsuke Suzuki, Toshihiro Suwa, Yasuhiro Kinoshita

Принадлежит: 3M Innovative Properties Co

The present invention is a copolymer of a monomer mixture including about 25 to about 80 parts by mass of an alkyl (meth)acrylate, approximately 15 to approximately 50 parts by mass of a hydroxyl group-containing monomer, and approximately 5 to approximately 25 parts by mass of a macromer having a glass transition temperature (Tg) of approximately 50° C. or higher. The copolymer contains substantially no acidic groups.

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Номер записи: 46

14-01-2021 дата публикации

METAL-CLAD LAMINATED BOARD, METAL MEMBER PROVIDED WITH RESIN, AND WIRING BOARD

Номер: US20210014967A1

Автор: Abe Tomoyuki, ARISAWA TATSUYA, GOTO Hirohisa

Принадлежит: Panasonic Intellectual Property Management Co., Ltd.

A metal-clad laminated board includes an insulating layer and a metal layer, in which the insulating layer includes a cured product of a resin composition containing a modified polyphenylene ether compound terminally modified with a substituent having an unsaturated double bond; and a crosslinkable curing agent having an unsaturated double bond in the molecule, and containing 40 to 250 parts by mass of silica particles with respect to 100 parts by mass in total of the modified polyphenylene ether compound and the crosslinkable curing agent, the resin composition contains 0.2 to 5 parts by mass of a first silane coupling agent having an unsaturated double bond in the molecule with respect to 100 parts by mass of the silica particles, and a contact surface of the metal layer in contact with the insulating layer is surface-treated with a second silane coupling agent having an amino group in the molecule. 1. A metal-clad laminated board comprising an insulating layer and a metal layer present in contact with at least one surface of the insulating layer ,whereinthe insulating layer includes a cured product of a resin composition containing a modified polyphenylene ether compound terminally modified with a substituent having a carbon-carbon unsaturated double bond; a crosslinkable curing agent having a carbon-carbon unsaturated double bond in a molecule; a first silane coupling agent having a carbon-carbon unsaturated double bond in a molecule; and at least one of silica particles and silica particles surface-treated with the first silane coupling agent,a total content of the silica particles and the silica particles surface-treated with the first silane coupling agent is 40 to 250 parts by mass with respect to 100 parts by mass in total of the modified polyphenylene ether compound and the crosslinkable curing agent,a total content of the first silane coupling agent contained in the resin composition and the first silane coupling agent contained in the silica particles ...

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Номер записи: 47

21-01-2016 дата публикации

Plasticizer Having Cationic Side Chains

Номер: US20160017082A1

Автор: AL SHEMARI Jabbar, FRIEDERICH Markus, Hampel Christina, Zimmermann Jörg

Принадлежит: SIKA TECHNOLOGY AG

Provided are cationic comb polymers, obtainable by polymerizing a monomer mixture, which contains at least one monomer having at least one cationic group covalently bonded to the monomer and which contains at least one monomer of the formula R—O-[AO]—R, wherein Ris an alkenyl group, Rrepresents H, an alkyl group having 1 to 20 C atoms, or an aryl group or alkylaryl group having 7 to 20 C atoms, A independently of one another represents a Cto Calkylene group, and n is a value from 2 to 300. Also provided are hydraulically setting cement compositions, shaped bodies, uses, and methods for producing comb polymers. Also provided are novel comb polymers with cationic side chains and structural subunits that comprise polyether components. Further provided are hydraulically setting cement compositions, shaped bodies, uses and methods for producing comb polymers.

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Номер записи: 48

18-01-2018 дата публикации

RADIATION CURABLE BINDER DISPERSION

Номер: US20180016453A1

Автор: Chen Tienteh, Huang Bin, Sarkisian George

Принадлежит:

An example of a radiation curable binder dispersion includes water and a radiation curable binder dispersed therein. The radiation curable polyurethane is formed from a polyisocyanate; an acrylate or methacrylate having at least two hydroxyl functional groups and having an acrylate functional group or a methacrylate functional group; another acrylate or methacrylate having one hydroxyl functional group or one amino functional group; and one of i) a homopolymer or copolymer of poly(ethylene glycol) having one or two hydroxyl functional groups or one or two amino functional groups at one end of its chain; or ii) a combination of i and a compound including a carboxylic functional group. 1. A radiation curable binder dispersion , comprising:water; and a polyisocyanate;', 'an acrylate or methacrylate, the acrylate or methacrylate having at least two hydroxyl functional groups and having an acrylate functional group or a methacrylate functional group;', 'an other acrylate or methacrylate, the other acrylate or methacrylate having one hydroxyl functional group or one amino functional group; and one of:', 'i) a homopolymer or copolymer of poly(ethylene glycol) having one or two hydroxyl functional groups or one or two amino functional groups at one end of its chain; or', 'ii) a combination of i and a compound including a carboxylic functional group., 'a radiation curable polyurethane dispersed in the water, the radiation curable polyurethane having been formed from2. The radiation curable binder dispersion as defined in wherein the homopolymer or copolymer of poly(ethylene glycol) has a number average molecular weight ranging from about 500 and about 5 claim 1 ,000 and a water solubility greater than 30% v/v.3. The radiation curable binder dispersion as defined in wherein the homopolymer or copolymer of poly(ethylene glycol) is:a poly(ethylene glycol) copolymer selected from the group consisting of a copolymer of poly(ethylene) and poly(ethylene glycol) with the one ...

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Номер записи: 49

17-01-2019 дата публикации

Associative polymers and related compositions, methods and systems

Номер: US20190016859A1

Автор: Julia A. Kornfield, Ming-Hsin Wei

Принадлежит: California Institute of Technology CalTech

Described herein are associative polymers capable of controlling a physical and/or chemical property of non-polar compositions and related compositions, methods and systems. Associative polymers herein described have a non-polar backbone and functional groups presented at ends of the non-polar backbone, with a number of the functional groups presented at the ends of the non-polar backbone formed by associative functional groups capable of undergoing an associative interaction with another associative functional group with an association constant (k) such that the strength of each associative interaction is less than the strength of a covalent bond between atoms and in particular less than the strength of a covalent bond between backbone atoms.

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Номер записи: 50

16-01-2020 дата публикации

BLUE LED CURE ON DEMAND COMPOSITIONS

Номер: US20200017623A1

Автор: Blackwell Charlie P., Dailey Ian, Griffin Michael E., Homnick Paul J., Keicher Dennis R., Klun Thomas P., Kropp Michael A., Lin Ying, Pokorny Richard J., Savu Patricia M., Schlechte Jay S., Smith Richard S., Ye Sheng, Yu Steven Y.

Принадлежит:

The disclosure relates to compositions, methods of applying such compositions, and methods for curing such compositions to a depth of cure of up to about 30 mm within about 0.5 second to about two minutes per light exposure area. 1. A method comprising: a urethane acrylate component;', 'an adhesion promoter comprising an acid-functional monomer; and', 'a photoinitiator having an extinction coefficient of from about 10 to about 2000 L/mol·cm at a wavelength from about 400 nm to about 500 nm in an amount of from about 0.1 wt. % to about 10 wt. %; and, 'applying a composition to a substrate, the composition comprising'}curing the composition using a light-emitting curing device emitting light at a wavelength of from about 260 to about 550 nm;wherein the composition cures to a depth of cure of up to about 30 mm within about 0.5 second to about two minutes per light exposure area.2. The method of claim 1 , wherein the composition further comprises at least one of about 3 to about 50 wt. % of adhesion promoter claim 1 , about 10 to about 80 wt. % of diluents claim 1 , about 0.3 to about 10 wt. % long alkyl chain (meth)acrylate claim 1 , about 0.3 to about 10 wt. % of fluorinated (meth)acrylate claim 1 , about 0.5 to about 10 wt. % of corrosion inhibitor claim 1 , about 1 to about 200 ppm of photobleaching agent claim 1 , about 1 to about 200 ppm of photosensitizer claim 1 , about 0.1 to about 30 wt. % of fillers claim 1 , about 0.5 to about 30 wt. % of monothiols claim 1 , polythiols claim 1 , or combination thereof claim 1 , and about 1 to about 40 wt. % of plasticizer.3. (canceled)4. (canceled)5. The method of claim 1 , wherein the composition comprises about 5 wt. % to about 85 wt. % urethane acrylate component.6. (canceled)7. (canceled)8. (canceled)9. The method of claim 1 , wherein the urethane acrylate component comprises an aliphatic urethane acrylate claim 1 , an aromatic urethane acrylate claim 1 , or a combination of an aliphatic urethane acrylate and an ...

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Номер записи: 51

21-01-2021 дата публикации

RESIN COMPOSITION, AND PREPREG, RESIN-COATED FILM, RESIN-COATED METAL FOIL, METAL-CLAD LAMINATE, AND WIRING BOARD EACH OBTAINED USING SAID RESIN COMPOSITION

Номер: US20210017317A1

Автор: Inoue Hiroharu, Umehara Hiroaki, Wang Yiqun

Принадлежит: Panasonic Intellectual Property Management Co., Ltd.

A resin composition is provided and includes (A) a modified polyphenylene ether compound terminal-modified with a substituent having a carbon-carbon unsaturated double bond, (B) a maleimide compound containing no phenylmaleimide group and having a hydrocarbon group having 10 or more carbon atoms in the molecule thereof, and (C) at least one selected from a maleimide compound containing a phenylmaleimide group and a maleimide compound having an aliphatic hydrocarbon group having 9 or less carbon atoms in the molecule thereof, in which the content ratio of the component (A) to the component (B) is (A):(B)=20:80 to 90:10 in mass ratio. 1. A resin composition , comprising:(A) a modified polyphenylene ether compound terminal-modified with a substituent having a carbon-carbon unsaturated double bond;(B) a maleimide compound containing no phenylmaleimide group and having a hydrocarbon group having 10 or more carbon atoms in a molecule thereof; and(C) at least one selected from a maleimide compound containing a phenylmaleimide group and a maleimide compound having an aliphatic hydrocarbon group having 9 or less carbon atoms in a molecule thereof,wherein a content ratio of the component (A) to the component (B) is (A):(B)=20:80 to 90:10 in mass ratio.3. The resin composition according to claim 1 , wherein the modified polyphenylene ether compound (A) has a weight average molecular weight (Mw) of 1000 to 5000.4. The resin composition according to claim 1 , wherein the maleimide compound (B) has a weight average molecular weight (Mw) of 500 to 4000.5. The resin composition according to claim 1 , wherein a content of the maleimide compound (C) is 5 to 50 parts by mass per 100 parts by mass of a resin component.6. A prepreg claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the resin composition according to or a semi-cured product of the resin composition; and'}a fibrous base material.7. A film with resin claim 1 , comprising:{'claim-ref': {'@idref': 'CLM- ...

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Номер записи: 52

03-02-2022 дата публикации

A buckling dielectric elastomer actuator

Номер: US20220037581A1

Автор: Gurunathan THANGAVEL, Pooi See Lee, Wei Ming Matthew TAN

Принадлежит: NANYANG TECHNOLOGICAL UNIVERSITY

Disclosed herein is a buckling actuator, comprising: a first electrode; a second electrode; and a film of a dielectric elastomeric material having a first surface and a second surface sandwiched between the first and second electrodes, wherein the material is formed by the random block copolymerisation of a polymeric material comprising silicon or nitrogen atoms that has two or more acrylate or vinyl end groups, and a polar polymeric material having two or more acrylate or vinyl end groups. Also disclosed herein is a method of forming said dielectric elastomeric material.

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Номер записи: 53

21-01-2021 дата публикации

METHOD FOR PRODUCING POLYIMIDE PRECURSOR, METHOD FOR PRODUCING PHOTOSENSITIVE RESIN COMPOSITION, METHOD FOR PRODUCING PATTERN CURED PRODUCT, METHOD FOR PRODUCING INTERLAYER INSULATING FILM, COVER COAT LAYER OR SURFACE PROTECTIVE FILM, AND METHOD FOR PRODUCING ELECTRONIC COMPONENT

Номер: US20210018837A1

Автор: ENOMOTO Tetsuya, Yoneda Satoshi

Принадлежит:

A method for producing a polyimide precursor having a structural unit represented by the following formula (1), 3. A method for producing a photosensitive resin composition comprising: producing a polyimide precursor by the method according to ; andmixing the polyimide precursor, (B) a polymerizable monomer, and (C) a photopolymerization initiator to obtain a photosensitive resin composition.4. A method for producing a pattern cured product comprising the following steps: producing a photosensitive resin composition by the method according to ;coating the photosensitive resin composition on a substrate and drying to form a photosensitive resin film;pattern-exposing the photosensitive resin film to obtain a resin film;developing the resin film after the pattern exposure using an organic solvent to obtain a pattern resin film; andheat-treating the pattern resin film.5. The method for producing a pattern cured product according to claim 4 , wherein a temperature of the heat treatment is 200° C. or less.6. A method for producing an interlayer insulating film claim 4 , a cover coat layer or a surface protective film claim 4 , which is produced using the pattern cured product produced by the method according to .7. A method for producing an electronic component claim 6 , which is produced using the interlayer insulating film claim 6 , the cover coat layer or the surface protective film produced by the method according to . The invention relates to a method for producing a polyimide precursor, a method for producing a photosensitive resin composition, a method for producing a pattern cured product, a method for producing an interlayer insulating film, a cover coat layer or a surface protective film, and a method for producing an electronic component.In recent years, the miniaturization of transistors which has supported the enhancement of the performance of computers has come to the limit of scaling law, and a laminated device structure in which semiconductor elements are ...

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Номер записи: 54

28-01-2016 дата публикации

Composite semifinished products and mouldings produced therefrom and directly produced mouldings based on hydroxy-functionalized (meth)acrylates and uretdiones which are crosslinked by means of radiation to give thermosets

Номер: US20160023384A1

Автор: Birte Olland, Emmanouil Spyrou, Friedrich Georg Schmidt, Guenter Schmitt, Holger Loesch, Michael Spittler, Sandra Reemers

Принадлежит: EVONIK DEGUSSA GmbH

The invention relates to a process for producing storage-stable polyurethane prepregs and to mouldings (composite components) produced therefrom. The prepregs and, respectively, components are produced by mixing (meth)acrylate monomers, (meth)acrylate polymers, hydroxy-functionalised (meth)acrylate monomers and/or hydroxy-functionalised (meth)acrylate polymers with uretdione materials. Photoinitiators can also optionally be added. This mixture or solution is applied by known processes to fibre material, e.g. carbon fibres, glass fibres or polymer fibres, and is polymerised with the aid of radiation or of plasma methods. Polymerisation, e.g. at room temperature or at up to 80° C., gives thermoplastics or thermoplastic prepregs, and these can subsequently also be subjected to forming processes. The hydroxy-functionalised (meth)acrylate constituents can then be crosslinked with the uretdiones already present within the system, by use of elevated temperature. It is thus possible to produce dimensionally stable thermosets or dimensionally stable crosslinked composite components.

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Номер записи: 55

26-01-2017 дата публикации

Adhesive sheet, manufacturing method thereof, and layered body

Номер: US20170021593A1

Автор: Hajime Kitano

Принадлежит: Bridgestone Corp

An adhesive sheet, the adhesive sheet having an adhesive composition layer, the adhesive composition layer being formed using a composition including: a polythiol compound; a (meth)acrylic compound having a plurality of at least one of an acryloyl group or a methacryloyl group; a radical generator; and a Michael addition catalyst, a ratio (Ac/SH) of a total molar number (Ac) of the at least one of an acryloyl group or a methacryloyl group contained in the (meth)acrylic compound to a total molar number (SH) of thiol groups contained in the polythiol compound being from 0.25 to 0.80.

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Номер записи: 56

25-01-2018 дата публикации

PHOTOCURABLE COMPOSITION

Номер: US20180022838A1

Автор: OTSUKI Naoya, TAKEO Yuko

Принадлежит:

An object of the present invention is to provide a photocurable composition from which a cured product having high concealing property is obtained by irradiation with an active energy ray such as ultraviolet ray, and which inhibits color fading of the cured product in a high temperature and high humidity (85 C and 85% RH) environment or a high temperature (100 C) environment. 1. A photocurable composition comprising the following components (A) to (D):component (A): a leuco dye;{'sub': a', '6-a', 'b', '6-b', 'c', '4-c, 'sup': −', '−', '−, 'component (B): a salt having an anion selected from the group consisting of [P(Rf)F], [Sb(Rf)F] and [B(Rf)F] (in the formulae, Rf represents a fluoroalkyl group having 1 to 20 carbon atoms, a and b each independently represent an integer of from 1 to 5, and c represents an integer of from 1 to 3);'}component (C): a radical polymerizable compound; andcomponent (D): a photoradical initiator.2. The photocurable composition according to claim 1 , wherein{'sub': a', '6-a, 'sup': '−', 'the component (B) is a salt having an anion represented by [P(Rf)F] (in the formula, Rf represents a fluoroalkyl group having 1 to 20 carbon atoms and a represents an integer of from 1 to 5).'}3. The photocurable composition according to claim 1 , whereinthe component (B) is a salt having a cation selected from the group consisting of an aryliodonium cation, an aryl sulfonium cation, and an aryldiazonium cation.4. The photocurable composition according to claim 1 , whereinthe component (B) is a salt having an aryl sulfonium cation.5. The photocurable composition according to claim 1 , wherein{'sub': a', '6-a', '3', '2', '3', '3', '3', '2', '2', '2', '4', '3', '2', '2', '3', '3', '3', '2', '2', '2', '2', '4', '3', '2', '2', '2', '3', '3, 'sup': −', '−', '−', '−', '−', '−, '[P(Rf)F] of the component (B) is an anion selected from the group consisting of [(CFCF)PF], [(CFCFCF)PF], [(CFCFCF)PF], [(CFCFCFCF)PF], and [(CFCFCFCF)PF].'}6. The photocurable ...

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Номер записи: 57

25-01-2018 дата публикации

FLUORINATED COMPOUND-CONTAINING COMPOSITION, METHOD FOR ITS PRODUCTION, COATING LIQUID, HARD COAT LAYER-FORMING COMPOSITION AND ARTICLE

Номер: US20180022850A1

Автор: HOSHINO Taiki, Takao Kiyotaka

Принадлежит: Asahi Glass Company, Limited

To provide a fluorinated compound-containing composition which is capable of imparting excellent antifouling properties to an object (such as a hard coat layer) and which is excellent in compatibility and has foaming suppressed. This composition comprises the following fluorinated compound (A), the following compound (B) and a solvent (S1), wherein the content of the following fluorinated compound (A) in the composition is from 5 to 30 mass % to the composition, and the content of the following compound (B) is from 0.1 to 2 mass % to the composition, 1. A composition characterized by comprising the following fluorinated compound (A) , the following compound (B) and a solvent (S1) , wherein the content of the following fluorinated compound (A) in the composition is from 5 to 30 mass % to the composition , and the content of the following compound (B) is from 0.1 to 2 mass % to the composition ,Fluorinated compound (A): a fluorinated compound which is a compound having a portion derived from a compound (a) having a poly(oxyperfluoroalkylene) chain and an active hydrogen-containing group, a portion derived from a compound (b) having a polymerizable carbon-carbon double bond and an active hydrogen-containing group, and a portion derived from a polyisocyanate (c), and which has no isocyanate group,Compound (B): a compound having a polymerizable carbon-carbon double bond and an active hydrogen-containing group.2. The composition according to claim 1 , wherein at least part of said compound (B) is said compound (b).3. The composition according to claim 1 , wherein each of said compound (b) and said compound (B) other than the compound (b) is a compound having one hydroxy group.4. The composition according to claim 1 , wherein said compound (a) is a compound having one hydroxy group.5. A method for producing a composition as defined in claim 1 , which comprises reacting said compound (a) claim 1 , said compound (b) and said polyisocyanate (c) in said solvent (S1) claim 1 , ...

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Номер записи: 58

25-01-2018 дата публикации

FLUORINATED COMPOUND, PHOTOCURABLE COMPOSITION, COATING LIQUID, HARD COAT LAYER-FORMING COMPOSITION AND ARTICLE

Номер: US20180022851A1

Автор: HOSHINO Taiki, Takao Kiyotaka

Принадлежит: Asahi Glass Company, Limited

To provide a fluorinated compound capable of imparting excellent antifouling properties (oily ink repellency and fingerprint-stain removability) and abrasion resistance of the antifouling properties to an object (such as a hard coat layer). It is a reaction product of a compound (a1) having a poly(oxyperfluoroalkylene) chain and one active hydrogen-containing group, a compound (a2) having a poly(oxyperfluoroalkylene) chain and two active hydrogen-containing groups, a compound (b) having a polymerizable carbon-carbon double bond and an active hydrogen-containing group, and a polyisocyanate (c), wherein the proportion of the portion derived from the compound (a1) to the total (100 mass %) of the portion derived from the compound (a1) and the portion derived from the compound (a2) is from 60 to 99.9 mass %. 2. The fluorinated compound according to claim 1 , wherein the number average molecular weight of the compound (a1) is from 1 claim 1 ,000 to 6 claim 1 ,000 claim 1 , and the number average molecular weight of the compound (a2) is from 1 claim 1 ,000 to 6 claim 1 ,000.4. The fluorinated compound according to claim 3 , wherein each of said (CFO)and said (CFO)is {(CFO)(CFCFO)} (wherein n11 is an integer of at least 1 claim 3 , n12 is an integer of at least 1 claim 3 , n11+n12 is an integer of from 2 to 200 claim 3 , and the bonding order of n11 pieces of CFO and n12 pieces of CFCFO is not limited).5. The fluorinated compound according to claim 3 , wherein D-R—O—CH— is R—O—CHFCF—O—CH— (wherein Ris a Cperfluoroalkyl group terminated with CF).6. The fluorinated compound according to claim 3 , wherein the compound (a1) is a compound obtained by converting Eor Ein the compound (a2) to D.7. A method for producing a fluorinated compound claim 3 , characterized by reactinga compound (a1) having a poly(oxyperfluoroalkylene) chain and one active hydrogen-containing group,a compound (a2) having a poly(oxyperfluoroalkylene) chain and two active hydrogen-containing groups, in such ...

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Номер записи: 59

23-01-2020 дата публикации

MODEL MATERIAL INK SET, SUPPORT MATERIAL COMPOSITION, INK SET, THREE-DIMENSIONAL SHAPED OBJECT, AND METHOD FOR MANUFACTURING THREE-DIMENSIONAL SHAPED OBJECT

Номер: US20200023572A1

Автор: HONGO Kenta, IZUMO Taeko, Kito Katsuyuki, Okawa Masakatsu

Принадлежит:

The present invention relates to a model material ink set for use in an optical molding method by an inkjet system, wherein the ink set comprises a color ink and a clear ink containing an ethylenically unsaturated monomer, as a model material ink, wherein the color ink contains, as the ethylenically unsaturated monomer, 30 to 75% of a (meth)acrylate and 10 to 50% of an ethylenically unsaturated monomer that is not a (meth)acrylate and that contains a nitrogen atom, based on a total amount of the color ink, the clear ink contains, as the ethylenically unsaturated monomer, 30 to 80% of a (meth)acrylate based on a total amount of the clear ink, provided that a content of the ethylenically unsaturated monomer that is not a (meth)acrylate and that contains a nitrogen atom is less than 10% based on the total amount of the clear ink. 1. A model material ink set for use in an optical molding method by an inkjet system , the ink set comprising a color ink and a clear ink as a model material ink ,whereinthe color ink and the clear ink each contain an ethylenically unsaturated monomer,the color ink contains, as the ethylenically unsaturated monomer, 30 to 75% by mass of a (meth)acrylate and 10 to 50% by mass of an ethylenically unsaturated monomer that is not a (meth)acrylate and that contains a nitrogen atom, based on a total amount of the color ink,the clear ink contains, as the ethylenically unsaturated monomer, 30 to 80% by mass of a (meth)acrylate based on a total amount of the clear ink, provided that a content of the ethylenically unsaturated monomer that is not a (meth)acrylate and that contains a nitrogen atom in the clear ink is less than 10% by mass based on the total amount of the clear ink.2. The model material ink set according to claim 1 , wherein the ethylenically unsaturated monomer that is not a (meth)acrylate and that contains a nitrogen atom is selected from the group consisting of (meth)acrylamides and N-vinyllactams.3. The model material ink set according ...

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Номер записи: 60

23-01-2020 дата публикации

COATING COMPOSITIONS EXHIBITING CORROSION RESISTANCE PROPERTIES AND RELATED COATED SUBSTRATES

Номер: US20200024461A1

Автор: Schneider John R., Walters David N.

Принадлежит:

Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating later is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed. 1. A method of coating a substrate comprising: applying a first coating composition to at least a portion of the substrate , wherein the coating composition comprises: epoxy functional material , organic solvent , and magnesium oxide particles; and wherein the substrate comprises a 2000 series aluminum alloy.2. The method of claim 1 , wherein the coating composition further comprises an amine functional material.3. The method of claim 1 , further comprising applying an additional coating onto the at least partially coated substrate.4. The method of claim 3 , wherein the additional coating comprises polyurethane.5. The method of claim 1 , wherein the first coating composition has a dry film thickness of 0.5 to 1.25 mils.6. The method of claim 1 , wherein the magnesium oxide particles have a surface area of at least 10 m/g.7. The method of claim 6 , wherein the magnesium oxide particles are platy.8. The method of claim 6 , wherein the magnesium oxide particles are spherical.9. The method of claim 6 , wherein the magnesium oxide particles are cubical.10. The method of claim 6 , wherein the magnesium oxide particles are acicular.11. The method of claim 1 , wherein the first coating composition is substantially chromate-free.12. The method of claim 3 , wherein both the first and second coating compositions are substantially chromate-free.13. The method of claim 1 , wherein the 2000 series aluminum alloy comprises an aluminum cladding.14. The method of claim 1 , comprising surface-treating the substrate prior to ...

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Номер записи: 61

28-01-2021 дата публикации

METHOD FOR PRODUCING WELL DEFINED COMB POLYMERS

Номер: US20210024415A1

Автор: FRIEDERICH Markus, Hampel Christina, WEIDMANN Jürg, Zimmermann Jörg

Принадлежит: SIKA TECHNOLOGY AG

A method for producing improved comb polymers having a block or gradient structure. The comb polymers are highly suitable for dispersing fine powder. 1. A process for preparing comb polymers having block or gradient structure , wherein at least one section A of the comb polymer is formed by polymerizing a monomer mixture M comprising a polyalkylene glycol (meth)acrylate , wherein the monomer mixture M includes less than 2% by weight of (meth)acrylic acid , based on the weight of the polyalkylene glycol (meth)acrylate present in the monomer mixture M.2. The process as claimed in claim 1 , wherein the monomer mixture M includes less than 1.8% by weight of (meth)acrylic acid claim 1 , based on the weight of the polyalkylene glycol (meth)acrylate present in the monomer mixture M.3. The process as claimed in claim 1 , wherein the polyalkylene glycol (meth)acrylate has been prepared by a process in which neither (meth)acrylic acid nor the anhydride of (meth)acrylic acid is used.4. The process as claimed in claim 1 , wherein the polyalkylene glycol (meth)acrylate is obtained by transesterifying an alkyl (meth)acrylate with a polyalkylene glycol capped at one end or by alkoxylating a hydroxyalkyl(meth)acrylate.5. The process as claimed in claim 4 , wherein at the start of the transesterification reaction claim 4 , the molar ratio of alkyl (meth)acrylate to polyalkylene glycol capped at one end is 1:1 to 50:1.6. The process as claimed claim 4 , wherein claim 4 , during and/or after the transesterification claim 4 , excess alkyl (meth)acrylate is partly or fully removed from the reaction mixture.7. The process as claimed in claim 1 , wherein the monomer mixture M comprises the reaction mixture which is obtained by transesterifying an alkyl (meth)acrylate with a polyalkylene glycol capped at one end and includes claim 1 , besides the polyalkylene glycol (meth)acrylate claim 1 , at least one compound selected from the group comprising alkyl (meth)acrylate claim 1 , polyalkylene ...

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Номер записи: 62

28-01-2021 дата публикации

Photocurable resin composition

Номер: US20210024682A1

Автор: Kenji Suzuki

Принадлежит: Kuraray Noritake Dental Inc

The present invention provides a photocurable resin composition that has good fabricability, and that exhibits superior flexibility, fracture resistance, and water resistance in the form of a cured product. The present invention relates to a photocurable resin composition comprising: a urethanized (meth)acrylic compound (A); a mono(meth)acrylic acid ester compound (B) containing no urethane bond; and a photopolymerization initiator (C), the urethanized (meth)acrylic compound (A) being a (meth)acrylate comprising, per molecule, at least one kind of structure selected from the group consisting of a polyester, a polycarbonate, a polyurethane, a polyether, a poly-conjugated diene, and a hydrogenated poly-conjugated diene; and a urethane bond, the mono(meth)acrylic acid ester compound (B) containing no urethane bond comprising at least one selected from the group consisting of a mono(meth)acrylic acid ester compound (b-I) represented by general formula (I), and a mono(meth)acrylic acid ester compound (b-II) represented by general formula (II).

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Номер записи: 63

28-01-2021 дата публикации

Resin composition, optical fiber and method for manufacturing optical fiber

Номер: US20210024772A1

Автор: Katsushi Hamakubo

Принадлежит: Sumitomo Electric Industries Ltd

A resin composition includes a base resin containing a urethane (meth)acrylate oligomer, a monomer, and a photopolymerization initiator, and surface-modified inorganic oxide particles having an alkyl group having 1 or more and 8 or less carbon atoms or a phenyl group, wherein the content of the surface-modified inorganic oxide particles is 1% by mass or more and 60% by mass or less based on the total amount of the resin composition and the amount of surface modification on the surface-modified inorganic oxide particles is 0.15 mg/m 2 or more.

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Номер записи: 64

28-01-2021 дата публикации

METHODS FOR PRODUCING HELMET INSERTS WITH MATERIALS HAVING MULTIPLE MECHANISMS OF HARDENING

Номер: US20210024775A1

Автор: Chen Kai, Desimone Joseph M., Goodrich James, JR. Robert K., Pinschmidt, Poelma Justin, Robeson Lloyd M., Rolland Jason P.

Принадлежит:

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component. 1. A method of forming a three-dimensional object , wherein said three-dimensional object is an insert for use between a helmet and a human body , comprising:(a) providing a carrier and an optically transparent member having a build surface, said carrier and said build surface defining a build region therebetween;(b) filling said build region with a polymerizable liquid, said polymerizable liquid comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component;(c) irradiating said build region with light through said optically transparent member to form a solid polymer scaffold from said first component and also advancing said carrier away from said build surface to form a three-dimensional intermediate having a shape of said insert, said three-dimensional intermediate containing said second solidifiable component carried in said scaffold in unsolidified and/or uncured form; and(d) subsequent to said irradiating step, heating, microwave irradiating, or both heating and microwave irradiating, second solidifiable component in said three-dimensional intermediate to form said insert.2. The method of claim 1 , wherein said second solidifiable component comprises a polymerizable liquid solubilized in or suspended in said first component.3. The method of claim 1 , wherein said second solidifiable component comprises:(i) a polymerizable solid suspended in said first component;(ii) a polymerizable solid solubilized in said first component; ...

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Номер записи: 65

28-01-2021 дата публикации

OPTICAL FIBER

Номер: US20210026065A1

Автор: Hamakubo Katsushi, HOMMA Yuya

Принадлежит: Sumitomo Electric Industries, Ltd.

An optical fiber comprises a glass fiber comprising a core and a cladding, a primary resin layer being in contact with the glass fiber and covering the glass fiber, and a secondary resin layer covering the primary resin layer, wherein the Young's modulus of the primary resin layer is 0.04 MPa or more and 1.0 MPa or less at 23° C.±2° C., the secondary resin layer consists of a cured product of a resin composition comprising a base resin containing a urethane (meth)acrylate oligomer, a monomer, and a photopolymerization initiator and hydrophobic inorganic oxide particles, and the content of the inorganic oxide particles is 1% by mass or more and 60% by mass or less based on the total amount of the resin composition. 1: An optical fiber comprising a glass fiber comprising a core and a cladding; a primary resin layer being in contact with the glass fiber and covering the glass fiber; and a secondary resin layer covering the primary resin layer ,wherein a Young's modulus of the primary resin layer is 0.04 MPa or more and 1.0 MPa or less at 23° C.±2° C., andwherein the secondary resin layer consists of a cured product of a resin composition comprising a base resin containing a urethane (meth)acrylate oligomer, a monomer, and a photopolymerization initiator; and hydrophobic inorganic oxide particles, and a content of the inorganic oxide particles is 1% by mass or more and 60% by mass or less based on a total amount of the resin composition.2: The optical fiber according to claim 1 , wherein the inorganic oxide particle is at least one selected from the group consisting of silicon dioxide claim 1 , zirconium dioxide claim 1 , aluminum oxide claim 1 , magnesium oxide claim 1 , titanium oxide claim 1 , tin oxide claim 1 , and zinc oxide.3: The optical fiber according to wherein the content of the inorganic oxide particles is 5% by mass or more and 60% by mass or less based on a total amount of the resin composition.4: The optical fiber according to claim 1 , wherein an ...

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Номер записи: 66

04-02-2016 дата публикации

Water-Absorbing (Meth) Acrylic Resin With Optical Effects, And Related Compositions

Номер: US20160030328A1

Автор: Emi Akabane, Fatemeh Mohammadi, Lisa Qu

Принадлежит: ELC Management LLC, Shin Etsu Chemical Co Ltd

A water-absorbing polymer obtained from (A) a phosphate-containing (meth)acrylic monomer and/or a salt thereof, (B) a monomer having one (meth)acrylic group within the molecule and/or a salt thereof other than component (A), and (C) an organopolysiloxane having a (meth)acrylic group at both ends and related compositions.

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Номер записи: 67

29-01-2015 дата публикации

Polymerizable composition, polymerization product, image display device, and method for producing same

Номер: US20150030836A1

Автор: Daigo Ito, Hiroto Kouka, Kazuhiko Ooga, Kazuhiro Sasaki, Kenichi Nakanishi, Yuta Takeuchi

Принадлежит: Showa Denko KK

In relation to a polymerizable composition for forming a transparent optical resin layer to be interposed between an image display section of an image display device and a light-transmissive protective section thereof, the present invention provides a polymerizable composition that does not give rise to display defects caused by the deformation of the image display section, enables high-luminance, high-contrast image displaying, has excellent heat resistance, and also has a low dielectric constant. This polymerizable composition comprises: (1) a urethane (meth)acrylate obtained by reacting a hydrogenated polyolefin polyol and a compound having an isocyanato group and a (meth)acryloyl group; (2) a (meth)acryloyl-group-containing compound having a hydrocarbon group with a carbon number of 6 or greater; and (3) a photopolymerization initiator.

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Номер записи: 68

02-02-2017 дата публикации

(meth)acrylic copolymer, adhesive composition containing same, and adhesive sheet

Номер: US20170029548A1

Автор: Eri Kawai, Hiroko Shinada, Junichi Nakamura

Принадлежит: Mitsubishi Rayon Co Ltd

A (meth)acrylic copolymer (A) having a mass average molecular weight of 50,000 to 1,000,000, in which the (meth)acrylic copolymer (A) is obtained by polymerizing a monomer mixture including a macromonomer (a) that has a number average molecular weight of 500 or more and less than 6000 and a vinyl monomer (b), and preferably includes 7 to 40% by mass of a repeat unit derived from the macromonomer (a), has sufficient coating workability, adhesive holding power and adhesive property as an adhesive composition.

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Номер записи: 69

04-02-2016 дата публикации

COPOLYMERS MADE WITH ALLYL-TERMINATED POLYOLEFINS AND UNSATURATED ACIDIC REAGENTS, DISPERSANTS USING SAME, AND METHODS OF MAKING SAME

Номер: US20160032041A1

Автор: Harrison James J., Stokes Casey D.

Принадлежит:

Copolymers made with allyl-terminated polyolefins and unsaturated acidic reactants, dispersants using same, and methods of making same are provided. Under one aspect, a copolymer of an unsaturated acidic reactant and high molecular weight polyolefin, wherein the polyolefin comprises an allyl-terminated polymeric product, is provided. The allyl-terminated polymeric product is formed, e.g., by forming a quasi-living tert-halide terminated polyolefin under suitable quasi-living conditions, and contacting the tert-halide terminated polyolefin with an allylsilane compound and a Lewis acid. In some embodiments, the allylsilane compound includes allyltrimethylsilane. 1. A copolymer of an unsaturated acidic reactant and a high molecular weight polyolefin , wherein the polyolefin comprises an allyl-terminated polymeric product.2. The copolymer of claim 1 , wherein the allyl-terminated polymeric product is formed by:a) ionizing a polyolefin to form a carbocation terminated polyolefin;b) reacting the carbocation terminated polyolefin from step (a) with an allylsilane compound in the presence of a Lewis acid, andc) terminating step (b) to form the allyl-terminated polymeric product3. The copolymer of claim 1 , wherein the allyl-terminated polymeric product is an allyl-terminated quasi-living polymeric product.4. The copolymer of claim 3 , wherein the allyl-terminated quasi-living polymeric product is prepared by:(a) forming a quasi-living tert-halide terminated polyolefin under suitable quasi-living conditions in the presence of a Lewis acid, and(b) reacting the quasi-living tert-halide terminated polyolefin with an allylsilane compound, and(c) terminating step (b) to form the allyl-terminated quasi-living polymeric product.5. The copolymer of claim 2 , wherein the allylsilane compound comprises allyltrimethylsilane.6. The copolymer of claim 1 , wherein the copolymer is formed by contacting the polyolefin with the unsaturated acidic reactant in the presence of a free radical ...

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Номер записи: 70

01-02-2018 дата публикации

A COPOLYMER COMPRISING A LIGNIN OR LIGNIN DERIVATIVE AND A POLY(ALKYLENE OXIDE) ALKYL ETHER (METH)ACRYLATE, AND A HYDROGEL COMPRISING THE COPOLYMER

Номер: US20180030192A1

Автор: KAI Dan, LOH Xian Jun

Принадлежит:

A copolymer comprising an oxygenated polyaromatic alcohol and a poly (alkylene oxide) alkyl ether (meth)acrylate is disclosed, wherein the oxygenated polyaromatic alcohol is preferably lignin or lignin derivative. A hydrogel comprising the copolymer and a cyclic oligosaccharide such as α-cyclodextrin is also disclosed, which can be used in biomedical or personal care industries, for example as a carrier for an active agent. 125-. (canceled)26. A copolymer comprising an oxygenated polyaromatic alcohol and a poly (alkylene oxide) alkyl ether (meth)acrylate.27. The copolymer of claim 26 , wherein said copolymer has a molecular weight in the range of 5 claim 26 ,000 g/mol to 500 claim 26 ,000 g/mol.28. The copolymer of claim 26 , wherein said copolymer has a polydispersity of at least 1.29. The copolymer of claim 26 , wherein said copolymer has a melting temperature in the range of 32° C. to 36° C.30. The copolymer of claim 26 , wherein said copolymer has a degradation temperature in the range of 350° C. to 370° C.31. The copolymer of claim 26 , wherein said copolymer has 5 to 1 claim 26 ,000 molecules of poly (alkylene oxide) alkyl ether (meth)acrylate bound to each molecule of the oxygenated polyaromatic alcohol.32. The copolymer of claim 26 , wherein said oxygenated polyaromatic alcohol is a lignin or a lignin derivative claim 26 ,wherein said lignin is selected from the group consisting of lignin, steam explosion lignin, add hydrolysis lignin, lignosulfonate, soda lignin and organosolv lignin orwherein said lignin derivative is selected from the group consisting of lignin esters, lignin ethers, carboxy lignins, hydroxyalkylated lignin, acylated lignin and hydroxyalkoxy lignins oris further selected from the group consisting of lignin acetate, lignin propionate, lignin butyrate, lignin ethyl ether, lignin methyl ether, carboxymethyl lignin, (hydroxyethoxy) lignin, and (hydroxypropoxy) lignin.33. The copolymer of claim 26 , wherein said oxygenated polyaromatic alcohol ...

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Номер записи: 71

01-02-2018 дата публикации

URETHANE (METH)ACRYLATE RESIN, CURABLE RESIN COMPOSITION, CURED PRODUCT THEREOF, AND PLASTIC LENS

Номер: US20180030198A1

Автор: KOBAYASHI Nobuo, Odani Yasuko

Принадлежит:

A urethane (meth)acrylate resin wherein the viscosity of the resin is low, the formability into a sheet-formed product, in particular, an optical sheet provided with fine uneven shapes on the surface is excellent, and a high refractive index can be realized, a curable resin composition including the urethane (meth)acrylate resin as an indispensable component, a cured product thereof, and a plastic lens are provided. A urethane (meth)acrylate resin produced by reacting aromatic diisocyanate compound (a), bisphenol-ethylene oxide adduct diol (b) having at least three aromatic ring or alicyclic structures in the molecule, and hydroxy-containing (meth)acrylate compound (c), which are indispensable raw material components, a curable resin composition containing the urethane (meth)acrylate resin as a primary component, and a cured product thereof. 1. A urethane (meth)acrylate resin produced by reacting an aromatic diisocyanate compound (a) , a bisphenol-ethylene oxide adduct diol (b) having at least three aromatic ring or alicyclic structures in the molecule , and a hydroxy-containing (meth)acrylate compound (c) , which are indispensable raw material components.2. The urethane (meth)acrylate resin according to claim 1 , wherein the bisphenol-ethylene oxide adduct diol (b) having at least three aromatic ring or alicyclic structures in the molecule is an ethylene oxide adduct diol of at least one bisphenol selected from the group consisting of bisphenol AP claim 1 , bisphenol BP claim 1 , bisphenol M claim 1 , bisphenol P claim 1 , bisphenol PH claim 1 , bisphenol TMC claim 1 , and bisphenol Z.4. The urethane (meth)acrylate resin according to claim 3 , wherein the molar ratio [(a-1)/(a-2)] of the structural site (a-1) to the structural site (a-2) is 45/55 to 60/40.5. The urethane (meth)acrylate resin according to claim 1 , wherein the hydroxy-containing (meth)acrylate compound (c) is (meth)acrylic acid or a lactone adduct thereof.6. A curable resin composition comprising ...

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Номер записи: 72

17-02-2022 дата публикации

RADICAL POLYMERIZABLE RESIN COMPOSITION AND STRUCTURE REPAIRING MATERIAL

Номер: US20220049039A1

Автор: NIIBAYASHI Ryota, UMINO Atsushi

Принадлежит: SHOWA DENKO K.K.

Provided are a radical-polymerizable resin composition and a structure repairing material which, when used for repairing concrete structures, enable construction working even in a low-temperature environment, achieve a high strength and a low shrinkage by curing, and prevent cracking. The radical-polymerizable resin composition contains a radical-polymerizable resin (A) containing at least one selected from the group consisting of a vinyl ester resin, an urethane (meth)acrylate resin, and a polyester (meth)acrylate resin, a radical-polymerizable monomer (B) containing an isobornyl group-having unsaturated compound (B1), and a hydroxy group-containing aromatic tertiary amine (C) represented by the general formula (I), and containing the radical-polymerizable resin (A) and the radical-polymerizable monomer (B) in a total amount of 75% by mass or more. The structure repairing material contains the radical-polymerizable resin composition, an organic peroxide, and a filler (Z). 2. The radical-polymerizable resin composition according to claim 1 , wherein the isobornyl group-having unsaturated compound (B1) contains an ethylenically-unsaturated bond.3. The radical-polymerizable resin composition according to claim 2 , wherein the isobornyl group-having unsaturated compound (B1) is an isobornyl (meth)acrylate.4. The radical-polymerizable resin composition according to claim 1 , wherein the content ratio of the isobornyl group-having unsaturated compound (B1) relative to the total amount of the radical-polymerizable resin (A) and the radical-polymerizable monomer (B) is 10% by mass or more and 65% by mass or less.5. The radical-polymerizable resin composition according to claim 1 , wherein the content ratio of the isobornyl group-having unsaturated compound (B1) in the radical-polymerizable monomer (B) is 30% by mass or more and 90% by mass or less.6. The radical-polymerizable resin composition according to claim 1 , wherein the other radical-polymerizable monomer (B2) than ...

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Номер записи: 73

30-01-2020 дата публикации

Low-gloss cured product having excellent stain resistance, and manufacturing method therefor

Номер: US20200030845A1

Автор: Heon Jo KIM, Ji Yeon Seo, Min Kyung PARK, Tae Yi CHOI

Принадлежит: LG HAUSYS LTD

The present invention relates to a cured product having excellent stain resistance and low gloss, a method of manufacturing the same, and an interior material including the cured product. The cured product according to the present invention includes, along with an acrylic oligomer, an oligomer having a functional group containing silicon (Si) and an oligomer having a functional group containing fluorine (F), and thus, has excellent stain resistance and can implement a micro-folded structure on a surface thereof through extreme ultraviolet rays to be used during curing, thereby being capable of realizing low gloss without a matting agent.

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Номер записи: 74

31-01-2019 дата публикации

PHOTOSENSITIVE RESIN COMPOSITION, DRY FILM USING SAME, PRINTED WIRING BOARD, AND METHOD FOR MANUFACTURING PRINTED WIRING BOARD

Номер: US20190031790A1

Автор: DAIJIMA Yuta, KOMURO Nobuhito

Принадлежит:

Provided is a photosensitive resin composition: which has basic performance such as electrical insulation, soldering heat resistance, thermal shock resistance, solvent resistance, acid resistance, and alkali resistance required in a photosensitive resin composition used to produce a printed wiring board; which may form a resist shape having excellent linearity in the contours of the resist pattern because it is difficult to generate undercutting in which the bottom part is washed away or defects in the upper part of a resist; and which has excellent adhesion to a copper substrate and excellent fluidity. Also provided are a dry film prepared by using the photosensitive resin composition, a printed wiring board, and a method for producing the printed wiring board. The photosensitive resin composition contains (A) an acid-modified vinyl group-containing epoxy resin, (B) a photopolymerization initiator, (C) an ion scavenger having at least one selected from the group consisting of Zr, Bi, Mg, and Al, and (D) a photopolymerizable compound. 1. A photosensitive resin composition comprising:(A) an acid-modified vinyl group-containing epoxy resin;(B) a photopolymerization initiator; and(C) an ion scavenger having at least one selected from the group consisting of Zr, Bi, Mg, and Al; and(D) a photopolymerizable compound.2. The photosensitive resin composition according to claim 1 , wherein the component (A) contains (Al) at least one acid-modified vinyl group-containing epoxy resin obtained by using a bisphenol novolac type epoxy resin (a1) claim 1 , and (A2) at least one acid-modified vinyl group-containing epoxy resin obtained by using an epoxy resin (a2) different from the epoxy resin (a1).3. The photosensitive resin composition according to claim 2 , wherein the epoxy resin (a2) is at least one selected from the group consisting of a novolac type epoxy resin claim 2 , a bisphenol A type epoxy resin claim 2 , a bisphenol F type epoxy resin claim 2 , and a triphenol methane ...

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Номер записи: 75

31-01-2019 дата публикации

POLYMER PARTICLES

Номер: US20190031798A1

Автор: Cruise Gregory M., Harris Clayton, Keeley Edward Michael, Plotkin Steve, Yu Renee

Принадлежит:

Polymer particle embolics and methods of making same are described. The particle embolics can be used as embolization agents. 1. A polymer particle comprising:poly(ethylene glycol) diacrylamide, glycerol monomethacrylate, and amino ethyl methacrylate;wherein the polymer particle is spherical and has a diameter less than about 1,200 μm.2. The polymer particle of , wherein the polymer particle has a diameter between about 40 μm and about 1 ,200 μm. The polymer particle of , further comprising N ,N-methylenebisacrylamide.4. The polymer particle of claim 1 , wherein the N claim 1 ,N-methylenebisacrylamide is at a concentration of about 1% w/w.5. The polymer particle of claim 1 , wherein the poly(ethylene glycol) diacrylamide is at a concentration of about 28% w/w.6. The polymer particle of claim 1 , wherein the glycerol monomethacrylate is present at a concentration of about 68% w/w claim 1 ,7. The polymer particle of claim 1 , wherein the amino ethyl methacrylate at a concentration of about 3% w/w.8. The polymer particle of claim 1 , wherein the poly(ethylene glycol) diacrylamide is poly(ethylene glycol) diacrylamide 10 claim 1 ,000.9. The particle of claim 1 , further comprising a drug.10. A polymer particle comprising:poly(ethylene glycol) diacrylamide, 3-sulfopropyl acrylate, and amino propyl methacrylamide,wherein the polymer particle is spherical and has a diameter less than about 1,200 μm.11. The polymer particle of claim 10 , wherein the polymer particle has a diameter between about 40 pm and about 1 claim 10 ,200 μm.12. The polymer particle of claim 10 , wherein the poly(ethylene glycol) diacrylamide is at a concentration of about 40% w/w.13. The polymer particle of claim 10 , wherein the at least one monomer is 3-sulfopropyl acrylate at a concentration of about 59% w/w.14. The polymer particle of claim 10 , wherein the amino propyl methacrylamide is at a concentration of about 1% w/w.15. The polymer particle of claim 10 , wherein the poly(ethylene glycol) ...

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Номер записи: 76

31-01-2019 дата публикации

Methods of producing three-dimensional objects from materials having multiple mechanisms of hardening

Номер: US20190031911A1

Автор: James Goodrich, Jason P. Rolland, Joseph M. Desimone, Justin POELMA, Kai Chen, Lloyd M. Robeson, Robert PINSCHMIDT

Принадлежит: Carbon Inc

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

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Номер записи: 77

30-01-2020 дата публикации

ADMIXTURE AND INK COMPRISING THE ADMIXTURE

Номер: US20200032044A1

Автор: Akbulut Ozge, AKHLAGHI Omid, HODAEI Amin, SEZER Dilek

Принадлежит: Sabanci Universitesi

An admixture including at least one copolymer having a backbone. The backbone including at least one electrically charged monomer. The at least one copolymer is a grafted copolymer having mean molecular weight within a range between 600 g/mol and 3000 g/mol on side chains of the grafted copolymer. An additive manufacturing ink, Filament of the additive manufacturing ink, and inkjet printing ink including the admixture. 1. An ink for additive manufacturing , comprising an admixture , wherein the admixture comprises at least one copolymer with a backbone and the backbone comprises at least one electrically charged monomer; the at least one copolymer is a grafted copolymer having mean molecular weight within a range between 600 g/mol and 3000 g/mol on side chains of the grafted copolymer.2. The ink according to claim 1 , wherein the at least one copolymer is an alternating or random copolymer.3. The ink according to the claim 1 , wherein the at least one copolymer is a block copolymer.4. The ink according to claim 1 , wherein the backbone comprises acrylic acid or methacrylic acid.5. The ink according to claim 1 , wherein the the at least one copolymer comprises one or more monomers selected from the group consisting of 2-acrylamido-2-methylpropane sulfonic acid claim 1 , vinyl phosphonic acid claim 1 , N-[3(dimethylamino)propyl]methacrylamide claim 1 , 2-tert-butylamino)ethyl methacrylate claim 1 , and 2-vinyl pyridine claim 1 ,as modifying blocks.6. The ink according to claim 1 , wherein the ink comprises 60 wt. % to 80 wt. %_of inorganic solid content with respect to a total weight of an ink composition claim 1 , and has a volume fraction of the ink within a range of 35% (v/v) and 55% (v/v) with respect to a total volume of the ink composition.7. The ink according to claim 6 , wherein a ratio of the at least one copolymer is 2.5 wt % or less with respect to a total weight of the inorganic solid content.8. The ink according to claim 6 , wherein the ink is in a form ...

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Номер записи: 78

30-01-2020 дата публикации

FLOOR COATINGS COMPRISING A RESIN, A CURE SYSTEM AND DIAMOND PARTICLES AND METHODS OF MAKING THE SAME

Номер: US20200032102A1

Автор: BAKER Daniel P., SIGEL Gary A., Tian Dong

Принадлежит:

A curable coating for a substrate is disclosed that includes a curable resin containing at least one polyester urethane acrylate and monomers, a cure system and diamond particles. Methods of making the curable coatings and methods of making a coated flooring material are also included. 1. A curable coating for a substrate comprising: i. a polyester urethane acrylate; and', 'ii. an acrylate functional monomer;, 'a. a curable resin comprisingb. a cure system; andc. diamond particles.2. The coating of claim 1 , wherein the cure system is selected from a group consisting f photo-initiators claim 1 , thermal initiators claim 1 , curing resins claim 1 , and combinations thereof.3. The coating of claim 1 , wherein the photo-initiator is selected from a group consisting of benzophenone claim 1 , 1-hydroxycyclohexyl phenyl ketone claim 1 , benzoin claim 1 , benzoin methyl ether claim 1 , benzoin ethyl ether claim 1 , benzoin isopropyl ether claim 1 , benzyl diphenyl sulfide claim 1 , and any combination thereof.4. The coating of claim 1 , wherein the thermal initiator is selected from a group consisting of a peroxide compound claim 1 , an azo compound claim 1 , and a combination thereof.5. The coating of claim 1 , the coating has a Tg of about 15° C. to about 50° C. and double bond equivalent weight of about 0.0025 to about 0.0060.6. The coating of claim 1 , further comprising at least one additional abrasion resistant particle.7. The coating of claim 6 , wherein the at least one additional abrasion particle has a Mohs hardness value of at least 6.8. The coating of claim 1 , further comprising a matting agent.9. The coating of claim 1 , further comprising hydrophobic particles.10. The coating of claim 1 , wherein the coating contains about 0.5% to less than 5.5% by weight of diamond particles.11. The coating of claim 11 , wherein the coating contains about 1% to about 5% by weight of diamond particles.12. The coating of claim 12 , wherein the coating contains about 2% to ...

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Номер записи: 79

04-02-2021 дата публикации

SEMI-FINISHED PRODUCT ON THE BASIS OF A DUAL CROSSLINKING MECHANISM

Номер: US20210032392A1

Автор: Achten Dirk, Heinz Paul, Meisenheimer Richard

Принадлежит:

The present invention relates to semi-finished products which are obtained from a reaction mixture that contains ethylenic double bonds and isocyanate groups by radical polymerization of the ethylenic double bonds. The semi-finished product can be converted to an isocyanurate plastic having advantageous properties by carrying out polyaddition polymerization reactions of the isocyanate groups. 1. A process for producing a semifinished product , comprising: (i) an isocyanate component A;', '(ii) at least one trimerization catalyst C; and', '(iii) at least one component selected from the group consisting of components B, component D, and component E, wherein', 'component B has at least one ethylenic double bond but no isocyanate-reactive group;', 'component D has at least one isocyanate-reactive group and at least one ethylenic double bond in one molecule; and', 'component E has both at least one isocyanate group and at least one ethylenic double bond in one molecule; and, 'a) wetting a fiber with a reaction mixture having a molar ratio of isocyanate groups to isocyanate-reactive groups of at least 2:1, the reaction mixture comprising'}b) increasing a viscosity of the reaction mixture by at least 100% via free-radical polymerization of at least 50% of the ethylenic double bonds present in the reaction mixture.2. The process as claimed in claim 1 , wherein the fiber is present in the form of a woven fabric claim 1 , a non-crimp fabric claim 1 , or knitted fabric.3. The process as claimed in claim 1 , wherein the reaction mixture additionally comprises a component F which acts as an initiator for the free-radical polymerization of the ethylenic double bonds.4. The process as claimed in claim 3 , wherein the component F is activated by actinic radiation and/or the action of heat.5. The process as claimed in claim 1 , wherein a weight fraction of isocyanate groups in the reaction mixture is at least 1% and not more than 50%.6. The process as claimed in claim 1 , wherein a ...

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Номер записи: 80

04-02-2021 дата публикации

Microfluidic channel made of hydrophilic silicone resin

Номер: US20210032393A1

Автор: Mamoru Hagiwara

Принадлежит: Shin Etsu Chemical Co Ltd

A microfluidic channel made of a hydrophilic silicone resin includes a crosslinked material obtained by curing a composition containing a silicone macromer represented by the following general formula (1). Consequently, a microfluidic channel made from a resin having high oxygen permeability, where a surface after formation shows high hydrophilicity without a secondary treatment and the hydrophilicity is sustained for a long period of time.

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Номер записи: 81

04-02-2021 дата публикации

Resin composition, and prepreg, resin-coated film, resin-coated metal foil, metal-clad laminate, and wiring board each obtained using said resin composition

Номер: US20210032424A1

Автор: Hiroaki Umehara, Hiroharu Inoue, Rihoko WATANABE, Yiqun Wang

Принадлежит: Panasonic Intellectual Property Management Co Ltd

A resin composition is provided and contains (A) a thermosetting compound having a styrene structure or a (meth)acrylate structure, and (B) a maleimide compound represented by the following formula (1) (in the formula, p represents an integer of 1 to 10), in which the content ratio of the component (A) to the component (B) is (A):(B)=20:80 to 90:10 in mass ratio.

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Номер записи: 82

31-01-2019 дата публикации

ELECTROPHOTOGRAPHIC PHOTORECEPTOR, ELECTROPHOTOGRAPHIC PHOTORECEPTOR CARTRIDGE, IMAGE FORMING APPARATUS, AND DISPERSANT FOR FLUORORESIN

Номер: US20190033734A1

Автор: Yoshizawa Atsushi

Принадлежит: MITSUBISHI CHEMICAL CORPORATION

The invention relates to an electrophotographic photoreceptor which is excellent in abrasion resistance and electrical properties by using a fluororesin and a polymer containing a structure represented by a specific formula, and has a long life span, an electrophotographic photoreceptor cartridge and an image forming apparatus including the electrophotographic photoreceptor, and a dispersant which is excellent in dispersibility of a fluororesin particle, and the electrical properties, and the compatibility with a binder resin. 6. The electrophotographic photoreceptor according to claim 2 ,wherein in a polymer having the structure represented by the Formula (1) and the structure represented by the Formula (2), a content of the structure represented by the Formula (1) is 20% by mass to 70% by mass.7. The electrophotographic photoreceptor according to claim 2 ,wherein a weight average molecular weight of the polymer having the structure represented by Formula (1) and the structure represented by Formula (2) is 5,000 to 100,000.8. The electrophotographic photoreceptor according to claim 1 ,wherein a content of the polymer having the structure represented by Formula (1) is 0.5 parts by mass to 20 parts by mass with respect to 100 parts by mass of fluororesin.9. The electrophotographic photoreceptor according to claim 2 ,wherein the photosensitive layer further contains a binder resin in addition to the polymer having the structure represented by the Formula (1) and the structure represented by the Formula (2) and the fluororesin, and a content of the fluororesin is 1 parts by mass to 30 parts by mass with respect to 100 parts by mass of the binder resin.10. The electrophotographic photoreceptor according to claim 1 ,wherein an average primary particle diameter of the fluororesin is 0.1 μm to 1.0 μm.11. An electrophotographic photoreceptor cartridge comprising the electrophotographic photoreceptor according to .12. An image forming apparatus comprising the ...

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Номер записи: 83

08-02-2018 дата публикации

POLYMER COMPOSITIONS CONTAINING GRAFTED POLYMERIC NETWORKS AND PROCESSES FOR THEIR PREPARATION AND USE

Номер: US20180037690A1

Автор: Aitken Brian, Arnold Stephen C., Duis Donnie, Joslin Scott, Lu Fang, Mahadevan Shivkumar, Martin Patricia, Scales Charles, Sinha Dola, Zhang Yong

Принадлежит:

Provided are polymer compositions made by a process comprising: (a) providing a first reactive composition containing: (i) a polymerization initiator that is capable, upon a first activation, of forming two or more free radical groups, at least one of which is further activatable by subsequent activation; (ii) one or more ethylenically unsaturated compounds; and (iii) a crosslinker; (b) subjecting the first reactive composition to a first activation step such that the first reactive composition polymerizes therein to form a crosslinked substrate network containing a covalently bound activatable free radical initiator, (c) combining the crosslinked substrate network with a second reactive composition containing one or more ethylenically unsaturated compounds; and (d) activating the covalently bound activatable free radical initiator of the crosslinked substrate network such that the second reactive composition polymerizes therein with the crosslinked substrate network to form a grafted polymeric network and a byproduct polymer. Also provided are precursors to the polymer compositions, processes for preparation of the polymer compositions, and methods of using the polymer compositions, for instance in medical devices. 1. A polymer composition formed by a process comprising:(a) providing a first reactive composition containing: (i) a polymerization initiator that is capable, upon a first activation, of forming two or more free radical groups, at least one of which is further activatable by subsequent activation; (ii) one or more ethylenically unsaturated compounds; and (iii) a crosslinker;(b) subjecting the first reactive composition to a first activation step such that the first reactive composition polymerizes therein to form a crosslinked substrate network containing a covalently bound activatable free radical initiator;(c) combining the crosslinked substrate network with a second reactive composition containing one or more ethylenically unsaturated compounds; and(d ...

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Номер записи: 84

24-02-2022 дата публикации

SEPARATOR FOR ELECTROCHEMICAL ENERGY ACCUMULATORS AND CONVERTERS

Номер: US20220056186A1

Автор: Roth Michael, Smith Iain, Sutter Marco, Villing-Falusi Sandra, Waschinski Christian

Принадлежит:

A separator for at least one of electrochemical energy accumulators or converters includes: a porous substrate with a comb polymer, the comb polymer containing a polymer main chain along several lateral chains that are covalently bonded to the polymer main chain. At least one of the lateral chains has at least one Lewis-acid or Lewis-base functionality. 1: A separator for an electrochemical energy device , comprising:a porous substrate with a comb polymer,the comb polymer containing a polymer main chain along several lateral chains that are covalently bonded to the polymer main chain,wherein at least one of the lateral chains has at least one Lewis-acid or Lewis-base functionality.2: The separator of claim 1 , wherein an ion conductivity of the separator is decoupled from an air permeability of the separator.3: The separator of claim 1 , wherein the comb polymer has 10 to 3 claim 1 ,000 lateral chains.4: The separator of claim 1 ,wherein the polymer main chain has polymerized monomerselected from a group consisting of: acrylates, methacrylates, acrylic acids, methacrylic acids, acrylamides, methacrylamides, vinylamides, vinylpyridines, N-vinylimidazoles, N-vinyl-2-methylimidazoles, vinyl halides, styrenes, 2-methylstyrenes, 4-methylstyrenes, 2-(n-butyl)styrenes, 4-(n-butyl)styrenes, 4-(n-decyl)styrenes, N,N-diallylamines, N,N-diallyl-N-alkylamines, vinyl- and allyl-substituted nitrogen heterocycles, vinyl ethers, vinylsulfonic acids, allylsulfonic acids, vinylphosphonic acids, styrene sulfonic acids, acrylonitriles and methacrylnitriles, or mixtures thereof.5: The separator of claim 1 ,wherein the lateral chain has polymerized monomersselected from a group consisting of: acrylates, methacrylates, acrylamides, methacrylamides, vinylamides, vinylpyridines, N-vinylimidazoles, N-vinyl-2-methylimidazoles, vinyl halides, styrenes, 2-methylstyrenes, 4-methylstyrenes, 2-(n-butyl)styrenes, 4-(n-butyl)styrenes, 4-(n-decyl)styrenes, N,N-diallylamines, N,N-diallyl-N-alkylamines ...

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Номер записи: 85

06-02-2020 дата публикации

(METH)ACRYLIC RESIN AND METHOD FOR CONTROLLING STRAIN THEREOF

Номер: US20200040117A1

Автор: KITANOHARA Mitsuko, KOUDA Mitsuhiro, MIYAZAWA Yu, TOMIMORI Yuya

Принадлежит:

The purpose of the present invention is to provide a method for manufacturing a polymer having a desired strain. Provided is a method for manufacturing a polymer having a desired strain, said method comprising: a step for polymerizing one or more kinds of starting monomers by irradiating with ultraviolet rays having such an illuminance as to generate the desired strain; and, if required, a step for measuring the strain of the polymers thus formed and selecting a polymer having the desired strain. In one embodiment, provided is a method for determining the illuminance of ultraviolet rays for manufacturing a polymer having a desired strain. 1. A method of manufacturing a polymer with a desired strain , comprising:irradiating an ultraviolet ray with an illuminance that results in the desired strain onto, and polymerizing, one or more starting material monomers; andoptionally measuring a strain of generated polymers and selecting a polymer with the desired strain.2. The method of claim 1 , wherein the starting material monomer is a (meth)acryl monomer.3. The method of claim 1 , wherein the starting material monomer is a urethane (meth)acryl monomer.4. The method of claim 2 , wherein the illuminance is 10 mW/cmor less.5. The method of claim 3 , wherein the illuminance is 140 mW/cmor less.6. A method for determining an illuminance of an ultraviolet ray for manufacturing a polymer with a given strain claim 3 , comprising:1) providing a starting material monomer, which is a raw material of the polymer;2) irradiating an ultraviolet ray with a specific illuminance onto, and polymerizing, the starting material monomer to generate the polymer;3) measuring a strain of the generated polymer;4) optionally repeating steps 1) to 3); and5) calculating an illuminance resulting in the desired strain based on a measurement value obtained in 3) and 4).7. The method of claim 6 , comprising measuring a loss tangent (tan δ) of the polymer.8. The method of claim 7 , wherein an illuminance of ...

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Номер записи: 86

18-02-2021 дата публикации

ORAL CARE COMPOSITIONS COMPRISING PHOSPHONO-PHOSPHATE AND ANIONIC GROUP CONTAINING POLYMERS

Номер: US20210047475A1

Автор: Cron Scott Leroy, GLANDORF William Michael, JIN Yingkun, West Ryan Michael

Принадлежит:

Disclosed are oral care compositions of novel phosphono-phosphate and anionic group containing polymer compositions that have targeted uses with divalent cations and surfaces having divalent cations. These compounds can be used to deliver anionic character to surfaces such as calcium hydroxyapatite for use in oral care applications. 3. The oral care composition of wherein Ris H.5. The oral care composition of wherein said anionic group is selected from the group consisting of phosphate claim 1 , phosphonate claim 1 , sulfate claim 1 , sulfonate claim 1 , and carboxylate.6. The oral care composition of wherein Ris H.11. The oral care composition of wherein Ris —H.12. The oral care composition of wherein Ris another polymer chain with a head to head attachment.14. The oral care composition of wherein said composition further comprises from about 5% to about 70% claim 1 , by weight of the composition claim 1 , of water.15. The oral care composition of wherein said composition further comprises from about 0.1% to about 11% claim 1 , by weight of the composition claim 1 , of a metal ion salt.16. The oral care composition of wherein said metal ion salt is stannous fluoride. The present invention relates to novel phosphono-phosphate and anionic group containing polymers. The present invention further relates to using oral care compositions comprising the novel polymers.Chemical structures that interact with multivalent cations in solution and with surfaces containing multivalent cations are useful for manipulation of these systems. Polyphosphates and pyrophosphate, for example, have been used as builders in laundry and dish formulations to control calcium and in drilling muds to prevent precipitation. They have also been used in the oral care industry to help control tartar and reduce the thickness of the pellicle layer on teeth resulting in a slick tooth feel. Similarly, bisphosphonates, and hydroxy-bisphosphonates are active components in osteoporosis pharmaceuticals due ...

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Номер записи: 87

18-02-2016 дата публикации

Polymeric compositions and processes for molding articles

Номер: US20160046799A1

Автор: Norwin Van Riel, Pascal E.R.E.J. Lakeman

Принадлежит: Trinseo Europe GmbH

The present invention is directed to a polymeric article comprising a blend of (a) a first polymeric component; (b) a second polymeric component the second polymeric component including an α-olefin multilock interpolymer present in the amount of about 20 percent or less by weight of the second polymeric component; and (c) at least one reinforcement material; wherein the concentration of the second polymeric component is greater than about 20 wt. % based on the total concentration of the first polymeric component and the second polymeric component. The polymeric articles desirably have one or more of the following characteristics: a soft touch feel, a low gloss appearance, or a high surface durability.

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Номер записи: 88

06-02-2020 дата публикации

Anti-reflective film, polarizer comprising the same, and image display comprising the anti-reflective film and/or the polarizer comprising the same

Номер: US20200041695A1

Автор: Ching-Huang Chen, Gang-Lun Fan, Kuo-Hsuan Yu

Принадлежит: BenQ Materials Corp

The invention is to provide an anti-reflective film. The anti-reflective film comprises a substrate, a hard coating layer disposed on the substrate and a low refractive layer disposed on the hard coating layer. The low refractive layer comprises a (meth)acrylate resin, hollow silica nanoparticles, an initiator and a leveling agent. Wherein the leveling agent comprises a (meth)acrylic-modified organosilicone compound having a perfluoropolyether group. The reflectivity of the anti-reflective film of the present invention is in the range of 1.2% to 1.4%.

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Номер записи: 89

16-02-2017 дата публикации

Bio-based superabsorbents prepared via the macromonomer approach

Номер: US20170044294A1

Автор: Jinwen Zhang, Wenjia Song

Принадлежит: Washington State University WSU

A novel bio-based superabsorbent polymer material based on a proteinaceous natural polymer is introduced herein. There is further disclosed a method for the manufacture of such a bio-based crosslinked superabsorbent polymer material. The method includes, but not limited to, introducing polymerizable unsaturated groups onto the natural polymer or its derivative so as to yield a macromonomer. The macromonomer can be formed by covalently binding unsaturated carbon-carbon double bonds to a proteinaceous substrate through a reaction of a selected chemical compound and the amino group on the proteinaceous substrate. The macromonomer is then copolymerized with unsaturated co-monomer(s) to form a crosslinked superabsorbent material.

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Номер записи: 90

16-02-2017 дата публикации

Active energy beam-curable resin composition, resin molding, and method for producing resin molding

Номер: US20170044395A1

Автор: Hiroyuki Satou, Kazuyoshi Odaka, Riina Kanbara

Принадлежит: Mitsubishi Rayon Co Ltd

Provided are: a resin composition with which it is possible to form a cured film having excellent weather resistance and wear resistance; and a resin molding having said cured film. An active energy beam-curable resin composition containing a radical polymerizable compound and a photopolymerization initiator (d), wherein said radical polymerizable compound contains 57-90 mass % of (a) caprolactone-modified mono- or poly-penta erythritol poly (meth)acrylate represented by formula (1) and 10-43 mass % of (b) urethane (meth)acrylate synthesized from a polycarbonate polyol having a branched alkyl structure and an average molecular weight falling within the range of 500-1000, a diisocyanate having an alicyclic structure, and a mono (meth)acrylate containing a hydroxyl group. In formula (1), each X independently represents a caprolactone-modified (meth)acryloyl group, a (meth)acryloyloxy group, or a —OH group.

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Номер записи: 91

15-02-2018 дата публикации

NON-REACTIVE, HYDROPHILIC POLYMERS HAVING TERMINAL SILOXANES AND METHODS FOR MAKING AND USING THE SAME

Номер: US20180044518A1

Автор: Fadli Zohra, Healy Brent Matthew, Mahadevan Shivkumar, Scales Charles, Venkatasubban Kunisi

Принадлежит:

The present invention relates to compositions comprising at least one stable, near-monodisperse, non-reactive hydrophilic polymer comprising in said polymer's backbone, a hydrophilic segment having a degree of polymerization of about 10 to about 1000, and a linear silicone segment at at least one terminal end of said non-reactive hydrophilic polymer, wherein said silicone segment comprises between about 6 and about 200 siloxy units, and said non-reactive hydrophilic polymer is associated, via the linear silicone block with a silicone hydrogel. The non-reactive hydrophilic polymers may be incorporated into the formulation from which the silicone hydrogel is made or may be contacted with the silicone hydrogel post formation. 134-. (canceled)35. An ophthalmic solution comprising at least one stable , non-reactive hydrophilic polymer comprising in said polymer's backbone , a hydrophilic segment having a degree of polymerization of about 300 to about 10 ,000 , and a linear silicone segment at at least one terminal end of said non-reactive hydrophilic polymer , wherein said silicone segment comprises between about 6 and about 200 siloxy units , wherein said non-reactive hydrophilic polymer is present in a contact angle reducing amount and said ophthalmic solution is transparent.36. The ophthalmic solution of wherein said at least one stable claim 35 , non-reactive hydrophilic polymer comprises 6 to 60 siloxy repeat units.37. The ophthalmic solution of wherein said at least one stable claim 35 , non-reactive hydrophilic polymer further comprises 6 to 20 siloxy repeat units.38. The ophthalmic solution of wherein said at least one stable claim 35 , non-reactive hydrophilic polymer is present in an amount between about 0.005 and about 2%.39. The ophthalmic solution of wherein said at least one stable claim 35 , non-reactive hydrophilic polymer is present in an amount between about 0.01 and about 0.5 weight %.40. The ophthalmic solution of wherein said at least one stable ...

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Номер записи: 92

16-02-2017 дата публикации

AROMATIC GLYCOL ETHERS AS WRITING MONOMERS IN HOLOGRAPHIC PHOTOPOLYMER FORMULATIONS

Номер: US20170045816A1

Автор: Berneth Horst, Bruder Friedrich-Karl, Fäcke Thomas, Hagen Rainer, Hönel Dennis, Rölle Thomas, WALZE Günther, Weiser Marc-Stephan

Принадлежит:

The invention relates to a photopolymer formulation comprising specific aromatic glycol ethers as writing monomers, matrix polymers and a photoinitiator. The invention further provides an unexposed holographic medium obtainable using an inventive photopolymer formulation, and an exposed holographic medium obtainable by exposing a hologram into an inventive unexposed holographic medium. The invention likewise provides a visual display comprising an inventive exposed holographic medium, for the use of an inventive exposed holographic medium for production of chip cards, identification documents, 3D images, product protection labels, labels, banknotes or holographic optical elements, and specific aromatic glycol ethers. 118.-. (canceled)20. The photopolymer formulation according to claim 19 , wherein the aryl radical comprises 5 to 21 carbon atoms and/or heteroatoms in the aromatic system.21. The photopolymer formulation according to claim 19 , wherein the aryl radical is substituted by 1 to 5 identical or different substituents selected from the group consisting of n-alkyl claim 19 , branched alkyl claim 19 , alkyloxy claim 19 , phenyl claim 19 , benzyl claim 19 , phenylalkyl claim 19 , naphthyl claim 19 , methylthiyl claim 19 , ethylthiyl claim 19 , alkylthiyl claim 19 , alkylthioalkyl claim 19 , phenoxy claim 19 , phenylthiyl claim 19 , napthylthiyl claim 19 , fluorine claim 19 , chlorine claim 19 , bromine and iodine.22. The photopolymer formulation claim 19 , wherein the aryl radical is selected from the group consisting of phenyl claim 19 , methylphenyl claim 19 , ethylphenyl claim 19 , thiomethylphenyl claim 19 , methoxyphenyl claim 19 , biphenyl and naphthyl.23. The photopolymer formulation according to claim 19 , wherein R3 is a radical selected from the group consisting of —CH2— claim 19 , —CH2CH2— claim 19 , —CH(CH3)CH2— claim 19 , —CH2CH(CH3)— claim 19 , —CH2CH2CH2— claim 19 , —CH2CH2CH2CH2— claim 19 , —CH2CHOCH2CH2— claim 19 , —CH2CH2OCH2CH2OCH2CH2—.24. ...

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Номер записи: 93

15-02-2018 дата публикации

CURABLE LIQUID DEVELOPER

Номер: US20180046105A1

Автор: Aichi Yasuhiro, Ito Junji, Shirakawa Jun, TANABE Hiroshi

Принадлежит:

Provided is a curable liquid developer having sufficient fixability while being a curable liquid developer containing a polymer material. The curable liquid developer includes: a cationic polymerizable liquid monomer including a vinyl ether monomer; and toner particles insoluble in the cationic polymerizable liquid monomer, in which the curable liquid developer further includes a polymerizable polyolefin including a polyolefin in a main chain thereof, the polymerizable polyolefin having a vinyl ether group at at least one terminal of the polyolefin. 1. A curable liquid developer , comprising:a cationic polymerizable liquid monomer including a vinyl ether monomer; andtoner particles insoluble in the cationic polymerizable liquid monomer, whereinthe curable liquid developer further comprises a polymerizable polyolefin comprising a polyolefin in a main chain thereof, at least one terminal of the polyolefin having a vinyl ether group.2. A curable liquid developer according to claim 1 , wherein the polymerizable polyolefin has vinyl ether groups at a plurality of terminals of the polyolefin.3. A curable liquid developer according to claim 1 , wherein the polymerizable polyolefin has a weight-average molecular weight of 900 to 10 claim 1 ,000.4. A curable liquid developer according to claim 3 , wherein the polymerizable polyolefin has a weight-average molecular weight of 1 claim 3 ,000 to 10 claim 3 ,000.5. A curable liquid developer according to claim 1 , wherein the polymerizable polyolefin has a structure derived from one of 1 claim 1 ,2-polybutadiene and 1 claim 1 ,4-polyisoprene claim 1 , and has hydrogen added to a double bond moiety except the vinyl ether group.67-. (canceled)8. A curable liquid developer according to claim 2 , wherein the polymerizable polyolefin has a weight-average molecular weight of 900 to 10 claim 2 ,000.9. A curable liquid developer according to claim 2 , wherein the polymerizable polyolefin has a weight-average molecular weight of 1 claim 2 ...

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Номер записи: 94

03-03-2022 дата публикации

Limonene-based (meth)acrylates for use in 3d printing

Номер: US20220064350A1

Автор: Andre Fuchs, Anne Cathrin ASMACHER, Rolf Muelhaupt, Vitalij Schimpf

Принадлежит: Basf Schweiz Ag, BASF SE

The present invention relates to photocurable compositions, comprising a limonene-based (meth)acrylate (A) obtainable by reacting a) 1 equivalent of a compound of formula, especially (I) with 1 to 3 equivalents of a compound of formula (II) in the presence of a catalyst and an inhibitor at elevated temperature and its use in a photopolymerization 3D printing process. The limonene-based (meth)acrylate (A) significantly increases stiffness and glass transition temperatures of photo-cured acrylate compositions. While such effects are usually achieved with the use of aromatic or bisphenol A based compounds, the limonene-based (meth)acrylate (A) offers a sustainable alternative at much lower viscosity.

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Номер записи: 95

03-03-2022 дата публикации

Radiation Curable Polymers

Номер: US20220064364A1

Автор: Andrea GUTACKER, Claudia Meckel-Jonas, Johann Klein, Markus Bonigut, Ralf Dunekake, Sebastien Lanau

Принадлежит: Henkel AG and Co KGaA

The present invention relates to radiation or radiation/moisture dual curable polymers and methods for their manufacture. These polymers are useful for various applications in the fields of adhesives, coatings, and sealants. The radiation curable polymers comprise at least one terminal group of the general formula (I) -A 1 -C(═O)—CR 1 ═CH 2 (I), wherein A 1 is a divalent bonding group containing at least one heteroatom; and R 1 is selected from H and C 1 -C 4 alkyl, preferably H and methyl; wherein the polymer backbone is selected from the group consisting of polyoxyalkylenes, poly(meth)acrylates, polyesters, and combinations thereof. and optionally further comprise at least one terminal group of the general formula (II) -A 2 -SiXYZ (II), wherein X, Y, Z are, independently of one another, selected from the group consisting of a hydroxyl group and C 1 to C 8 alkyl, C 1 to C 8 alkoxy, and C 1 to C 8 acyloxy groups, wherein X, Y, Z are substituents directly bound with the Si atom or the two of the substituents X, Y, Z form a ring together with the Si atom to which they are bound, and at least one of the substituents X, Y, Z is selected from the group consisting of a hydroxyl group, C 1 to C 8 alkoxy and C 1 to C 8 acyloxy groups; and A 2 is a divalent bonding group containing at least one heteroatom.

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Номер записи: 96

14-02-2019 дата публикации

MACROMONOMER MIXTURE, TERMINAL-REACTIVE POLYMER MIXTURE, INTERMEDIATE FOR MACROMONOMER AND SILICONE HYDROGEL

Номер: US20190048117A1

Автор: Fujisawa Kazuhiko, Nakamura Masataka

Принадлежит:

To obtain a hydrophilic macromonomer mixture which is a highly polymerized hydrophilic macromonomer, has few components not bonded to the polymer chain after polymerization, and is less likely to leaching. Provided is a macromonomer mixture containing macromonomer A being a macromonomer having a group obtained by further introducing a polymerizable group into a reactive group derived from a polymerization initiator at an end thereof; and macromonomer B being a macromonomer having a group obtained by further introducing a polymerizable group into a reactive group derived from a chain transfer agent at an end thereof. 2. (canceled)3. The macromonomer mixture of claim 1 , wherein the reactive group derived from a polymerization initiator and the reactive group derived from a chain transfer agent are each independently at least one kind of functional group selected from the group consisting of a hydroxy group claim 1 , an amino group claim 1 , thiol claim 1 , ester and carboxylic anhydride.49-. (canceled)10. A production method of the macromonomer mixture of claim 1 , wherein after radical polymerization of a hydrophilic monomer using the polymerization initiator of formulas (j1) to (j4) claim 1 , and a chain transfer agent having at least one functional group selected from the group consisting of a hydroxy group claim 1 , an amino group and a carboxyl group in a molecule claim 1 , a compound having a radically polymerizable functional group is reacted with the resulting polymer mixture.11. (canceled)1317-. (canceled)18. A silicone hydrogel obtained by copolymerizing at least one kind of silicone monomer with at least one kind of monomer mixture containing the macromonomer mixture of .19. The macromonomer mixture of wherein the monomer of macromonomer A comprises N-vinylpyrrolidone claim 1 , N claim 1 ,N-dimethylacrylamide claim 1 , N-vinylacetamide claim 1 , or mixtures thereof. This application claims priority to JP2009-296803 filed on Dec. 28, 2009.The present ...

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Номер записи: 97

13-02-2020 дата публикации

WASH LIQUIDS FOR USE IN ADDITIVE MANUFACTURING WITH DUAL CURE RESIN

Номер: US20200047406A1

Автор: CONVERSE Courtney F., McCall William R., Rolland Jason P.

Принадлежит:

A method of forming a three-dimensional object, which method includes a cleaning or washing step, is carried out by: (a) providing a carrier and a fill level, and optionally an optically transparent member having a build surface defining the fill level, the carrier and the fill level having a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light, to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; (d) washing the three-dimensional intermediate; and (e) concurrently with or subsequent to the irradiating step, and/or the washing step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object. 1. A method of forming a three-dimensional object , comprising:(a) providing a carrier and a fill level, and optionally an optically transparent member having a build surface defining said fill level, said carrier and said fill level having a build region therebetween;(b) filling said build region with a polymerizable liquid, said polymerizable liquid comprising a mixture of (1) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component;(c) irradiating said build region with light (through said optically transparent member when present), to form a solid polymer scaffold from said first component and also advancing said carrier away from said build surface to form a three-dimensional ...

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Номер записи: 98

25-02-2021 дата публикации

Resin composition, optical fiber and method for manufacturing optical fiber

Номер: US20210053870A1

Автор: Katsushi Hamakubo

Принадлежит: Sumitomo Electric Industries Ltd

A resin composition includes a base resin containing a urethane (meth)acrylate oligomer, a monomer, and a photopolymerization initiator, and surface-modified inorganic oxide particles having an ultraviolet curable functional group, wherein the content of the surface-modified inorganic oxide particles is 1% by mass or more and 60% by mass or less based on the total amount of the resin composition and the amount of surface modification on the surface-modified inorganic oxide particles is 0.15 mg/m2 or more.

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Номер записи: 99

25-02-2021 дата публикации

Heat-curable resin composition, and adhesive agent, film, prepreg, laminate, circuit board and printed-wiring board using same

Номер: US20210054152A1

Автор: Atsushi Tsuura, Hiroyuki Iguchi, Naoyuki Kushihara, Yoshihiro Tsutsumi, Yuki Kudo

Принадлежит: Shin Etsu Chemical Co Ltd

Provided are a heat-curable resin composition capable of being turned into a cured product having a high glass-transition temperature, a low dielectric tangent and a superior adhesion to a metal foil; and an adhesive agent, film, prepreg, laminate, circuit board as well as printed-wiring board using such heat-curable resin composition. The heat-curable resin composition contains: (A) a polyphenylene ether resin having reactive double bonds at molecular chain ends; (B) a (meth)acrylic acid ester compound; (C) a cyclic imide compound containing, in one molecule, at least one dimer acid backbone, at least one linear alkylene group having not less than 6 carbon atoms, and at least two cyclic imide groups; and (D) a reaction initiator.

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Номер записи: 100