ВОДОРАСТВОРИМАЯ КОМПОЗИЦИЯ ДЛЯ ПОКРЫТИЯ, СОДЕРЖАЩАЯ СОЕДИНЕНИЯ С ТИОЛОВОЙ ФУНКЦИОНАЛЬНОЙ ГРУППОЙ

Изобретение относится к водорастворимой композиции для покрытия, содержащей а) полиол, b) полиизоцианатный сшиватель и с) соединение с тиоловой функциональной группой, в которой молярное отношение изоцианатных групп к тиоловым группам находится в диапазоне между 1:0,0001 и 1:0,4. Изобретение также относится к применению композиции для покрытия в качестве прозрачного или пигментированного наружного покрытия, основного покрытия, наполнителя, грунта или связующего вещества, в окраске и повторной окраске автомобилей и крупных транспортных средств и к набору для приготовления композиции для покрытия. Технический результат - получение композиции, обеспечивающей баланс высокой скорости затвердевания, длительной жизнеспособности и хорошего внешнего вида пленки для покрытия, приготовленной из нее. 6 н. и 11 з.п. ф-лы, 3 ил., 7 табл.

НЕВОДНАЯ ЖИДКАЯ КОМПОЗИЦИЯ ДЛЯ НАНЕСЕНИЯ ПОКРЫТИЯ

... 1. Неводная жидкая композиция для нанесения покрытия, содержащая:a) полиол,b) полиизоцианатный отвердитель,c) одно или несколько тиолсодержащих соединений,d) металлосодержащий катализатор отверждения для ускорения реакции присоединения изоцианатных групп и гидроксильных групп,e) основание, имеющее величину pKa по меньшей мере 7 и не взаимодействующее с изоцианатными группами со снижением основности, иf) одно или несколько содержащих кислотные группы соединений,где одно или несколько тиолсодержащих соединений содержится в количестве, обеспечивающем молярное отношение тиольных групп к атомам металла металлосодержащего катализатора отверждения, составляющее 1 или выше, и где основание содержится в молярном количестве, меньшем, чем молярное количество тиольных групп, и где молярное отношение кислотных групп и групп основания составляет 1:1 или выше.2. Композиция для нанесения покрытия по п. 1, где основание содержится в молярное количестве, равном или превышающем молярное количество атомов ...

КОМПОЗИЦИЯ ДЛЯ ПОКРЫТИЯ, ВКЛЮЧАЮЩАЯ СОЕДИНЕНИЕ, СОДЕРЖАЩЕЕ СПИРТО-ОРТОСИЛИКАТНУЮ ГРУППУ

... 1. Композиция для покрытия, включающая гетероциклическое соединение кремния и взаимодействующий с гидроксильными группами сшивающий агент, где гетероциклическим соединением кремния является соединение, содержащее, по меньшей мере, одну спиро-ортосиликатную группу, отличающаяся тем, что группы сшивающего агента, взаимодействующие с гидроксильными группами, выбраны из изоцианатных групп, тиоизоцианатных групп, эпоксигрупп, эписульфидных групп, ацетальных групп, групп карбоновых кислот, групп ангидридов карбоновых кислот, групп сложных эфиров карбоновых кислот, групп карбодиимидов, алкоксисилановых групп, акцепторных групп Михаэля, этерифицированных аминных групп и их смесей. 2. Композиция для покрытия по п.1, отличающаяся тем, что соединение, содержащее, по меньшей мере, одну спироортосиликатную группу, выбрано из соединений согласно следующим формулам Ia, Ib и Ic 3. Композиция для покрытия по п.1 или 2, отличающаяся тем, что сшивающим агентом, взаимодействующим с гидроксильными группами, ...

ОТВЕРЖДАЕМЫЕ ВЛАГОЙ ПОЛИЭФИРУРЕТАНЫ, СОДЕРЖАЩИЕ ОДНУ РЕАКЦИОННОСПОСОБНУЮ СИЛАНОВУЮ ГРУППУ, И ИХ ИСПОЛЬЗОВАНИЕ В КАЧЕСТВЕ ГЕРМЕТИКОВ, АДГЕЗИВОВ И ПОКРЫТИЙ

... 1. Отверждаемый влагой алкоксисилан-функциональный полиэфируретан, содержащий а) от 20 до 90 мас.%, рассчитанных от массы а) и b), полиэфируретана, содержащего две или более реакционноспособные силановые группы и один или более сегмент простого полиэфира, в котором сегменты простого полиэфира имеют среднечисловую молекулярную массу не менее 3000 и степень ненасыщенности менее 0,04 мэкв./г, при условии, что сумма среднечисловых молекулярных масс всех полиэфирных сегментов на молекулу составляет в среднем от 6000 до 20000, и в котором реакционноспособные силановые группы вводятся посредством реакции изоцианат-реакционной группы с соединением формулы где Х означает одинаковые или различные органические группы, инертные по отношению к изоцианатным группам при температуре ниже 100°С при условии, что по крайней мере две из этих групп являются алкоксильными или ацилоксильными группами, и Y означает линейную или разветвленную алкиленовую группу, содержащую от 1 до 8 атомов углерода, и b) от 10 ...

ОТВЕРЖДАЕМЫЕ ВЛАГОЙ ПОЛИЭФИРУРЕТАНЫ С РЕАКЦИОННОСПОСОБНЫМИ СИЛАНОВЫМИ ГРУППАМИ И ИХ ИСПОЛЬЗОВАНИЕ ВКАЧЕСТВЕ ГЕРМЕТИКОВ, АДГЕЗИВОВ И ПОКРЫТИЙ

... 1. Отверждаемый влагой алкоксисилан-функциональный полиэфируретан, включающий а) от 20 до 90 мас.%, рассчитанных от массы а) и b), полиэфируретана, содержащего две или более реакционноспособных силановых групп и один или более сегментов простого полиэфира, в котором сегменты простого полиэфира имеют среднечисловую молекулярную массу не менее 3000 и степень ненасыщенности менее 0,04 мэкв/г, при условии, что сумма среднечисловых молекулярных масс всех полиэфирных сегментов на молекулу составляет в среднем от 6000 до 20000, и в котором реакционноспособные силановые группы вводятся посредством реакции изоцианат-реакционной группы с соединением по формуле где Х означает одинаковые или различные органические группы, инертные по отношению к изоцианатным группам при температуре ниже 100°С при условии, что по крайней мере две из этих групп являются алкоксильными или ацилоксильными группами, и Y означает линейную или разветвленную алкиленовую группу, содержащую от 1 до 8 атомов углерода, и b) от ...

VERFAHREN ZUR HERSTELLUNG GEFAERBTER POLYURETHANSCHAUMSTOFFE

Harte Polyurethan- und Polyisocyanurat-Schaumstoffe

PHOTOAKTIVIERBARE BESCHICHTUNGSZUSAMMENSETZUNG

FEUCHTIGKEITSHÄRTBARE POLYETHERURETHANE MIT REAKTIVEN SILANGRUPPEN UND IHRE VERWENDUNG ALS DICHTSTOFFE, KLEBSTOFFE UND BESCHICHTUNGEN

CARRIER MEANS COATED WITH A HETERO-MACROCYCLIC COMPOUND

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

BESCHICHTUNGSMASSE UND VERFAHREN ZU DEREN AUSHAERTUNG

NOTCH-IMPACTTOUGH POLYHARNSTOFFURETHAN POLYSULFIDES

HUMIDITY-HARDENABLE POLYETHERURETHANE WITH REACTIVE GROUPS OF SILANES AND YOUR USE AS SEALING MATERIALS, ADHESIVES AND COATINGS

TWO-COMPONENT SYSTEMS FOR THE PRODUCTION OF FLEXIBLE COATINGS

ANTHRACHINON REAKTIVFARBSTOFFE AND THUS SHIFTING POLYMER MATERIALS

Procedure for the continuous production of colored polyurethan-foam materials

Procedure for the fixed connection of elastomerem material with metal surfaces

Procedure for the production of plastics foamed if necessary

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

THIOLFUNKTIONELLE CONNECTIONS ABSTENTION AQUEOUS ONE COATING COMPOSITION

Non-aqueous crosslinkable composition

The present invention relates to a crosslinkable composition comprising a polyol, a polyisocyanate crosslinker, a catalyst for catalysing the reaction between -OH groups of said polyol and -NCO groups of said crosslinker, a tertiary acid of formula RR'R"CCOOH (I), wherein each R, R' and R" group, independently, is an alkyl, alkenyl, aryl or aralkyi group containing at least one carbon atom, with the proviso that two or three of the R, R' and R" groups can be linked to form a ring structure and wherein the R, R' and/or R" groups can be substituted, and optionally, a complexing agent containing at least one -SH group, as well as its use for making coatings having improved application properties.

Polyurethanes cured with 4,4'-methylene-bis-(3-chloro-2,6-diethylaniline)

Coating composition based on thiol-nco curing

Improvements in colored polyurethane surface coatings

Two-component systems for producing flexible coatings

The invention relates to two-component coating systems for producing flexible coatings. Said coating systems comprise polyurethane prepolymers having allophanate structures, in addition to amino-functional polyaspartic acid esters as hardeners.

Polythiourethane polymerizable composition and method for producing optical resin by using same

Disclosed are a resin composition excellent in dyability and resin strength, a resin obtained by curing such a resin composition, and an optical component. Specifically disclosed is a polymerizable composition containing an isocyanate compound suitably used for transparent resin materials, at least one polythiol compound which may have one or more (poly)sulfide bond in a molecule, and at least one polyhydroxy compound having two or more hydroxy groups in a molecule and/or at least one (poly)hydroxy(poly)mercapto compound having one or more hydroxy groups and one or more thiol groups.

Process for producing plastic lens and plastic lens

POLYTHIOCARBAMATE LENSE MATERIAL

Sulfur-containing urethane-based resin composition, its resin, and optical element and lens comprising resin

Method of preparing an optical polymerizate

PROCESS FOR PREPARING POLYURETHANE RESINS COLORED WITH ANTHRAQUINONE COLORANTS AND PRODUCTS PRODUCED THEREBY

A process for coloring polyurethane resins made by a polyaddition reaction of a polyol and an isocyanate is provided, which comprises adding to the reaction mixture before or during the polyaddition reaction a reactive coloring agent suitable for incorporation in the resin with the formation of covalent bonds, said coloring agent having the formula: in which R1 and R2 are independently selected from an alkyl group having from 1 to about 12 carbon atoms, X is --CH2--, a and a' are integers from 1 to about 6, and Y and Y' are independently selected from polymeric units of hydroxy alkylenes or alkylene oxide monomers selected from ethylene oxide, propylene oxide, butylene oxide, cyclohexene oxide, or glycidol, b and b' are independently either 0 or 1, and Z and Z' are reactive groups independently selected from -OH, -NH2, or -SH.

PROCESS FOR COLORING THERMOSETTING RESINS

PROCESS FOR COLORING THERMOSETTING RESINS A process is provided for coloring thermosetting resins, made by polyaddition reaction of a nucleophile with an electrophile, with a polymeric liquid reactive coloring agent suitable for incorporation in the resin with the formation of covalent bonds, said coloring agent having the formula: R-(polymeric constituent-X)n wherein R is an organic dyestuff radicals the polymeric constituent is selected from polyalkylene oxides and copolymers of polyalkylene oxides in which the alkylene moiety of the polymeric constituent contains 2 or more carbon atoms and such polymeric constituent has a molecular weight of from about 44 to about 1500; and n is an integer of from 1 to about 6; and X is selected from -OH, -NH2 and -SH, said coloring agent being added in an amount sufficient to provide coloration of said thermosetting resin.

COPOLYMERIZABLE UV STABILIZERS

TWO-COMPONENT SYSTEMS FOR PRODUCING FLEXIBLE COATINGS

The invention relates to two-component coating systems for producing flexible coatings. Said coating systems comprise polyurethane prepolymers having allophanate structures, in addition to amino-functional polyaspartic acid esters as hardeners.

SILICATE ISOCYANATE

This invention relates to compositions comprising a potassium silicate and/or sodium silicate powder having a water content of substantially 0%w/w and an isocyanate,to processes for preparing and hardening these compositions, to a rock bolt filled with the composition and to a rock bolting capsule formed by a water impermeable membrane and containing the composition.

MODIFIED ALKOXYLATION PRODUCTS HAVING AT LEAST ONE NON-TERMINAL ALKOXYSILYL GROUP AND A PLURALITY OF URETHANE GROUPS, AND THEIR USE.

The invention relates to alkoxylation products, their preparation, compositions comprising the alkoxylation products of the invention, and the use thereof as or for producing adhesives and sealants.

POLYISOCYANATE TRIMERIZATION CATALYST COMPOSITION

A trimerization catalyst composition comprising a trimerization catalyst compound selected from one or more organic metal salt, preferably alkali or earth alkali metal salts, and one or more compounds selected from compounds which comprise a carboxamide group having the structure -CO-NH2 and/or from compounds which comprise a group having the structure -CO-NH-CO- is disclosed. Further a stable polyisocyanate composition comprising the catalyst composition and a process for making the polyisocyanate composition is disclosed. A curable polyisocyanate composition is obtained comprising the catalyst composition, a polyisocyanate composition, an epoxy resin and optionally a polyol/monool composition and a polyisocyanurate comprising material made by allowing the curable composition to react at elevated temperature and a process for making the polyisocyanurate comprising material.

CELLULAR POLYURETHANE ELASTOMERS

A cellular polyurethane elastomer is produced by reacting: (a) an isocyanate component comprising methylenebis(phenyl isocyanate)(MDI), tolylene diisocyanate (TDI), or both thereof, with (b) compounds with at least two isocyanate-reactive hydrogen atoms and (c)4,4'-methylenebis (3-chloro-2,6- dialkylaniline)or a mixture of 4,4'-methylenebis (3-chloro-2,6- dialkylaniline)with one or more aromatic, aliphatic or cycloaliphatic diamines as chain extending agents, possibly together with an additional polyol and (d) a blowing agent, in the presence of usual catalysts and other optional additives. These cellular polyurethane elastomers are useful to produce moulded bodies which are subjected to high dynamic and thermal stresses.

Verfahren zur Herstellung eines öllöslichen als Schmiermittelzusatz geeigneten Kopolymers

Procédé de polymérisation

Procédé pour accélérer une réaction chimique

Verfahren zur Herstellung gefärbter Polyurethankunststoffe

Verfahren zur Herstellung gefärbter Polyurethankunststoffe

Verfahren zur kontinuierlichen Herstellung gefärbter Polyurethan-Schaumstoffe

Procédé de liaison de substances élastomères aux métaux

Process for preparing coloured polyurethane foams

METHOD FOR STAINING OF THERMOSETTING RESINS.

Method for manufacturing polymerizable composition for optical material, and polymerizable composition for optical material

Fluorine and sulfur-containing compositions

PROCESS OF POLYURETHANE COLOURING OF SYNTHESIS

PROCESS FOR BONDING ELASTOMERIC MATERIALS TO METALS

FLAME RETARDANT INTEGRAL SKIN POLYURETHANE FOAM

Fluorine and sulfur-containing compositions

A METHOD FOR COLOURING THERMOHARDENING RESINS

새로운 티올화합물과 이를 포함하는 중합성 조성물

... 본 발명은, 새로운 티올화합물과 이를 포함하는 중합성 조성물에 관한 것이다. 본 발명에서는 티올화합물과 이를 포함하는 중합성 조성물이 제공된다. 본 발명의 티올화합물과 이를 포함하는 중합성 조성물은 품질과 경제성을 모두 만족하는 우레탄계 플라스틱 재료의 생산에 적합하며, 특히 무색 투명성과 고굴절 또는 중굴절이 요구되는 우레탄계 플라스틱 재료의 생산에 적합하다.

PROCESS FOR THE CONTINUOUS PREPARATION OF COLORED POLYURETHANE FOAMS IN

processo para produzir um produto de espuma de poliuretano, produto de espuma de poliuretano, pré-mistura de produto de espuma de poliuretano, e formulação de produto de espuma de poliuretano

catálise de formulações de resina de epóxido com catalisadores dificilmente solúveis

NOVEL DERIVATIVES OF DI - OR TRI-, CONSTRUCTION METHODS AND EMBODIMENTS

Optical material using thiourethane

Provided is a method for forming a resin with a high refractive index, which has excellent physical properties such as the transparency, color tone, thermal resistance and shock resistance. The invention provides a composition including a polythiol compound having a skeleton of dithioacetal, dithioketal, ortho-trithioformate ester or ortho-tetrathiocarbonate ester, and having two or more mercapto groups, and a compound having two or more iso(thio)cyanato group, wherein a mole ratio of the mercapto group to the iso(thio)cyanato group is larger than 1.0 and lower than 3.0. The composition is a polymer composition used in a resin with a high refractive index. The invention also discloses a method for forming the resin by hardening the composition, and the resin thus formed, and an optical element formed by the resin and a lens formed by the optical element.

LIGHT-ABSORBING POLYURETHANE COMPOSITIONS AND THERMOPLASTIC POLYMERS COLORED THEREWITH

Provided are novel light-absorbing polyurethane compositions and blends of said polyurethane compositions with other thermoplastic polymers. Also provided are shaped or formed articles comprised of the light-absorbing polyurethane compositions and light-absorbing thermoplastic polymer blends.

Sulfur-containing urethane-based resin and composition and process for producing the resin

A polythiol having four or more functional groups, a process for producing the polythiol comprising reacting thiourea with a specific compound, a sulfur-containing urethane-based resin prepared from the polythiol and a lens made of the resin. The resin has a high refractive index, and low dispersion of refractive index, is lightweight, colorless and transparent, has no optical distortion, and has excellent characteristics in weatherability, dye-affinity, heat resistance, impact resistance and machinability.

Overcoating of printed substrates

Phase change carrier compositions made from the combination of at least one urethane resin; at least one urethane/urea resin; at least one mono-amide; and at least one polyethylene wax are disclosed. The order of addition of the reactants to form the reactant product urethane resin and urethane/urea resin permits the tailoring or design engineering of desired properties.

Polymerizable composition, molded product, and use thereof

The polymerizable composition of the present invention includes at least one isocyanate compound (A) having a cyclic structure, selected from compounds represented by the following Formulae (1), (2), and (3), and aliphatic isocyanate compound (B) having 4 to 11 carbon atoms, and a thiol compound (C).

Polyisocyanate Trimerization Catalyst Composition

A trimerization catalyst composition comprising a trimerization catalyst compound selected from one or more organic metal salt, preferably alkali or earth alkali metal salts, and one or more compounds selected from compounds which comprise a carboxamide group having the structure CONH2 and/or from compounds which comprise a group having the structure CONHCO is disclosed. Further a stable polyisocyanate composition comprising the catalyst composition and a process for making the polyisocyanate composition is disclosed. A curable polyisocyanate composition is obtained comprising the catalyst composition, a polyisocyanate composition, an epoxy resin and optionally a polyol/monool composition and a polyisocyanurate comprising material made by allowing the curable composition to react at elevated temperature and a process for making the polyisocyanurate comprising material.

POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, OPTICAL MATERIAL, AND METHOD FOR PREPARING THE OPTICAL MATERIAL

The polymerizable composition for an optical material of the present invention comprises a phenylene diisocyanate, at least one polythiol compound selected from the group consisting of 4-mercaptomethyl-1,8-dimercapto-3,6-dithiaoctane, 4,8-, 4,7- or 5,7-dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane, 2,5-bis(mercaptomethyl)-1,4-dithiane, bis(mercaptoethyl)sulfide, 1,1,3,3-tetrakis(mercaptomethylthio)propane, 4,6-bis(mercaptomethylthio)-1,3-dithiane, 2-(2,2-bis(mercaptomethylthio)ethyl)-1,3-dithietane, 1,1,2,2-tetrakis(mercaptomethylthio)ethane 3-mercaptomethyl-1,5-dimercapto-2,4-dithiapentane and tris(mercaptomethylthio)methane.

Diols with different functions and polyurethane elastomers produced therefrom

Process for the preparation of pigments

МАТЕРИАЛ, ЧУВСТВИТЕЛЬНЫЙ К ДАВЛЕНИЮ

Изобретение относится к полимерному материалу, обладающему оптически детектируемым откликом на изменение нагрузки (давления), включающему полиуретановый эластомер, адаптированный для детектирования изменения нагрузки, содержащий алифатический диизоцианат, полиол с концевым гидроксилом и фотохимическую систему, включающую флуоресцентные молекулы для зондирования расстояния, модифицированные с превращением в удлиняющие цепь диолы, в котором мольное соотношение диолов и полиолов находится в диапазоне от приблизительно 10:1 до около 1:2, а фотохимическая система выбрана из группы, состоящей из системы эксиплекса и резонансного переноса энергии флуоресценции (FRET). Настоящее изобретение также относится к раствору, содержащему указанный выше полимерный материал, а также к полимерному материалу, обладающему детектируемым откликом на изменение давления, включающему эластомер, содержащий полиакрилатный или силиконовый эластомер и фотохимическую систему, включающую определенное количество флуоресцентных ...

КОМПОЗИЦИЯ ДЛЯ СОКРАЩЕНИЯ КОЛИЧЕСТВА АЛЬДЕГИДОВ, ВЫДЕЛЯЮЩИХСЯ ИЗ ПОЛИУРЕТАНОВЫХ ПЕН

Настоящее изобретение относится к отверждаемой полиуретановой композиции, имеющей пониженный уровень выделения альдегидов. Указанная композиция включает по меньшей мере один реакционноспособный по отношению к изоцианатам компонент, вспомогательный реагент, а также один или более аминных компонентов. Вспомогательный реагент выбран из группы (i) смеси циклической мочевины, замещенной по меньшей мере одной реакционноспособной по отношению к изоцианатам группой, и акцептора свободных радикалов, содержащего фосфит, и, необязательно, полимерной кислоты или (ii) только полимерной кислоты. Полимерная кислота представляет собой любое соединение, содержащее в своей структуре три или более одинаковых повторяющихся мономера на основе ненасыщенной карбоновой кислоты или ее ангидрида. Циклическая мочевина представляет собой соединение формулы (I)где заместители R, R, R, R, R, R, независимо друг от друга, выбирают из Н, ОН, ROH, Rпредставляет собой C1-C4-алкильную группу, и дополнительно при условии, ...

НЕВОДНАЯ СШИВАЕМАЯ КОМПОЗИЦИЯ

Изобретение относится к сшиваемым композициям для покрытий. Предложена сшиваемая композиция для покрытия, содержащая полиол, полиизоцианатный сшиватель, катализатор для катализирования прохождения реакции между группами -ОН упомянутого полиола и группами -NCO упомянутого сшивателя, третичную кислоту, описываемую формулой RR’R’’CCOOH (I), где каждая группа R, R’ и R’’ независимо представляет собой алкильную или алкенильную группу, содержащую по меньшей мере один атом углерода, при том условии, что две или три из групп R, R’ и R’’ могут быть связаны с образованием кольцевой структуры, и где группы R, R’ и/или R’’ могут быть замещенными, и необязательно комплексообразующую добавку, содержащую по меньшей мере одну группу -SH. Предложены также комплект и модуль связующего для получения сшиваемой композиции и способ получения покрытия. Предложенная композиция имеет улучшенное соотношение жизнеспособность/время высыхания, высокую раннюю твердость и продолжительную жизнестойкость. 4 н. и 14 з.п ...

СВЯЗУЮЩЕЕ ВЕЩЕСТВО НА ОСНОВЕ ПОЛИИЗОЦИАНАТОВ ДЛЯ ПРОДУКТОВ ИЗ МИНЕРАЛЬНОЙ ВАТЫ

... 1. Связующее вещество для связывания минеральных волокон, включающее в себя органический полиизоцианат и силикат щелочного металла. ! 2. Связующее вещество по п.1, в котором силикат щелочного металла является силикатом натрия, предпочтительно обладающим молярным соотношением SiO2:Na2O от 1,6:1 до 3,5:1. ! 3. Связующее вещество по п.1 или 2, в котором силикат щелочного металла применяется в форме водного раствора. ! 4. Связующее вещество по п.3, в котором содержание сухого остатка водного раствора составляет между 5 и 15 мас.%. ! 5. Связующее вещество по п.1, в котором полиизоцианат применяется в форме водного раствора. ! 6. Связующее вещество по п.1, в котором полиизоцианат является ароматическим жидким полиизоцианатом. ! 7. Связующее вещество по п.6, в котором полиизоцианат представляет собой дифенилметандиизоцианат или его производное. ! 8. Связующее вещество по п.1, в котором полиизоцианат является форполимером, имеющим среднюю функциональность от 2 до 2,9, предпочтительно 2,1 до 2,7 ...

КАТАЛИЗ СОСТАВОВ ЭПОКСИДНЫХ СМОЛ ТРУДНОРАСТВОРИМЫМИ КАТАЛИЗАТОРАМИ

... 1. Реакционноспособный состав, содержащий, в основном:A) по меньшей мере, одну эпоксидную смолу,B) по меньшей мере, один латентный отвердитель, который в некатализируемой реакции с компонентом А) имеет при дифференциальной сканирующей калориметрии (DSC) максимумом пика экзотермической реакции при температуре выше 150°С;C) по меньшей мере, один ускоритель, содержащий продукт реакции из:С1) по меньшей мере, одного NCO-содержащего компонента иС2) одного или нескольких N-, S- и/или Р-содержащих гетероциклов иС3) одного или нескольких полиаминов и/или полиолов,2. Реакционноспособный состав по п.1, отличающийся тем, что он содержит:D) прочие обычные инертные добавки.3. Реакционноспособный состав по п.1, отличающийся тем, что он содержит эпоксидные смолы А) из глицидиловых эфиров на основе бисфенолов А или F и/или на основе резорцина, и/или тетракисфенилолэтана, и/или фенол/крезол-формальдегидных новолаков.4. Реакционно-способный состав по п.1, отличающийся тем, что он содержит эпоксидные смолы ...

СТАБИЛЬНЫЕ ЖИДКИЕ МОДИФИЦИРОВАННЫЕ БИУРЕТНЫМИ И МОДИФИЦИРОВАННЫЕ БИУРЕТНЫМИ И АЛЛОФАНАТНЫМИ ГРУППАМИ ТОЛУОЛДИИЗОЦИАНАТЫ, ИХ ПРЕПОЛИМЕРЫ И СПОСОБЫ ИХ ПОЛУЧЕНИЯ

... 1. Стабильный жидкий модифицированный биуретными группами толуолдиизоцианат, включающий основанный на вторичном амине модифицированный биуретными группами толуолдиизоцианат, обладающий содержанием групп NCO, равным от 16 до 46 мас.%, включающий (a) содержащее вторичную моноаминную группу соединение, которое может быть алифатическим, ароматическим или арилалифатическим; и (b) толуолдиизоцианат, обладающий содержанием групп NCO, равным примерно 48,3%, и включающий (i) от 0 до 40 мас.% 2,6-толуолдиизоцианата и (ii) от 60 до 100 мас.% 2,4-толуолдиизоцианата, где выраженные в мас.% содержания компонентов (b) (i) и (b) (ii) в сумме составляют 100 мас.% (b). 2. Стабильный жидкий модифицированный толуолдиизоцианат по п.1, в котором содержание групп NCO составляет от 20 до 40 мас.%. 3. Стабильный жидкий модифицированный биуретными группами толуолдиизоцианат по п.1, в котором (а) указанное содержащее вторичную моноаминную группу соединение обладает молекулярной массой, равной от примерно 45 до примерно ...

Von Isocyanat abgeleitete Materialien zur Verwendung in Phasenaustausch-Tintenstrahltinten

Von Isocyanat abgeleitete Farbharze zur Verwendung in Phasenaustausch-Tintenstrahltinten

FEUCHTIGKEITSHÄRTBARE POLYETHERURETHANE MIT REAKTIVEN SILANGRUPPEN UND IHRE VERWENDUNG ALS DICHTSTOFFE, KLEBSTOFFE UND BESCHICHTUNGEN

Verfahren zur Herstellung von Pigmenten

WASSER- UND ÖL-ABWEISENDE EIGENSCHAFTEN VERLEIHENDE URETHANOLIGOMERE, UMFASSEND PERFLUORALKYLEINHEITEN

Process for preparing polymers, polymers, dispersions, inks and uses

A process for preparing a polymer comprising reacting at least the components i) to iii) in any order: i) a compound of the Formula (1): Formula (1) wherein: T1 and T2 independently are HO-, HS- or R1HN-; Q1 and Q2 independently are -NR2-; A1 and A2 independently are an optionally substituted divalent organic linking group; R1 when present is H or an optionally substituted alkyl, aryl or heterocyclyl group; R2 is H or an optionally substituted alkyl, aryl or heterocyclyl group; Z is an HO- group or a group of the Formula (2) or (3); Formula (2) wherein: L is -HN-, -O- or -S-; X is an optionally substituted organic group; Formula (3) wherein: each X independently is an optionally substituted organic group; in both Formulae (2) and (3) the asterisk (*) signifies the point of attachment to the triazine ring: ii) a diisocyanate; iii) an isocyanate reactive compound having at least one ionic group.

Self-cleaning coatings

The present invention provides two methods for synthesizing novel titania-polyurethane (nTiO 2 -PU) nanocomposites for self-cleaning coatings, one a polymer functionalization method (“grafting to”) and the other, a monomer functionalization method (“grafting from”). Here, 2,2 bis(hydroxymethyl) propionic acid (HMPA) was used as the coordination agent, which was reacted with n-TiO 2 (50:50 anatase/rutile) to form nTiO 2 -HMPA, then polymerized in the monomer functionalization method. In the polymer functionalization method, HMPA was reacted with a pre-polymer to form the PU, and then subsequently reacted with n-TiO 2 to form the polymer nanocomposite. The photocatalytic cleanability of the nanocomposites was investigated when exposed to ultraviolet radiation using additional unreacted HMPA or stearic acid as the model “dirt” compounds. Nanocomposites prepared using both strategies showed similar self-cleaning behavior, although the monomer technique gave less substrate degradation.

Method for formulating a reactive polyurethane emulsion

A method for production of a reactive polyurethane emulsion for use in impregnating and coating a textile fabric includes reacting polyols alone or in combination with at least one of diols and triols with a substoichiometric amount of diisocyanates so as to form medium-viscosity, OH-terminated prepolymers. The prepolymers are mixed with an external emulsifier. At least one of a diisocyanate, a triisocyanate and a polyisocyanate are added so as to bring about a crosslinking of the prepolymers.

Method for preparing an allophanate, allophanate, and low-viscosity composition containing the allophanate

A process for the preparation of an allophanate of one or more identical or different isocyanates, compositions obtained by the process, and uses of the compositions are disclosed. The process comprises reacting an isocyanate with at least one monoalcohol comprising an ether or polyether functional group in the presence of a bismuth-comprising catalyst and a metal compound as co-catalyst.

Process For The Iodination Of Aromatic Compounds

The present invention relates to a process for the preparation of iodinated anilines; in particular, it relates to a process including the direct iodination, with suitably activated iodine, of 3,5-disubstituted anilines to the corresponding 3,5-disubstituted-2,4,6-triiodoanilines, which are useful intermediates for the synthesis of x-ray contrast media, and to the preparation of the contrast media themselves.

Polyurethane materials comprising carbon nanotubes

The invention relates to semicrystalline polyurethane (PU) compositions which have been filled with carbon nanotubes (CNTs) and have improved electrical properties, and which are obtainable on the basis of water-based polyurethane-CNT mixtures. The invention further relates to a process for producing the polyurethane compositions, in which water-based polyurethane latices are mixed with carbon nanotubes dispersed in water. The invention further relates to films produced by pressurized injection moulding processes or processing of casting solutions.

Catalysis of epoxy resin formulations having sparingly soluble catalysts

The present invention relates to epoxy resin formulations having a specific sparingly soluble catalyst mixture for enhancing reactivity.

Film and uses thereof

Disclosed is a film composed of a resin having a thiourethane bond, wherein the molar ratio (S/N) of sulfur to nitrogen contained in the resin is equal to or more than 0.8 and less than 3. According to the present invention, the film is excellent in a balance among high refractive index, low birefringence and light transmittance, and further excellent in a balance of mechanical characteristics such as toughness, hardness and dimensional stability, so that effects of deformation and the like during processing are very small, and the film is further excellent in solvent resistance as well.

Method to form a polyurethane material

A method to form a urethane material, the method comprises blending and reacting at least one isocyanate, at least one isocyanate reactive compound and a metallized polyhedral oligomeric silsesquioxane to provide said urethane material, the metallized polyhedral oligomeric silsesquioxane is a dimeric structure with general formula wherein M represents a metal providing a 6-coordinated metal center, x and y being 1, R 1 O and R 2 O represent an alkoxide bridging the 6-coordinated metal centers, R 3 OH and R 4 OH represent an alcohol ligand and each of R 5 , to R 18 is selected from the group consisting of alkyl-, polyether- and polyester ligands.

Composition containing specific carbamate type compounds suitable for producing polyurethane foams

Compositions suitable for producing polyurethane foams which include at least an isocyanate component, a polyol component, a catalyst catalyzing formation of a urethane or isocyanurate bond, and at least one compound containing at least one structural element of formula (I)

Non-crystallizing bis-oxazolidines

Non-crystallizing oxazolidines as curing agents for polyisocyanates and polyurethanes. The curing agents are mixtures of at least one polyoxazolidine POU having at least two urethane groups and at least one polyoxazolidine POC having at least one carbonato group.

Formulation containing tin and/or zinc salts of ricinoleic acid, urea, polyethylene glycol and sugar alcohol and use of the formulation in the production of polyurethane systems

A formulation for the production of a polyurethane system, in particular a polyurethane foam, containing or consisting of tin and/or zinc ricinoleate(s), optionally tin carboxylate(s), a mixture containing or consisting of urea, sugar alcohol and polyethylene glycol, optionally organic solvent, one or more organic isocyanates having two or more isocyanate functions, one or more polyols having two or more groups which are reactive towards isocyanate, optionally further catalysts for the isocyanate-polyol and/or isocyanate-water reactions and/or isocyanate trimerization, water, optionally physical blowing agents, optionally flame retardants and optionally further additives, a process for the production of polyurethane systems, these polyurethane systems and their use.

SILICONE-CONTAINING POLYISOCYANURATE FOAM

Polyisocyanurate foams of closed cell structure and low density are obtained by reaction of an amino-functional hyperbranched organopolysiloxane polyol, polyisocyanate, trimerization catalyst, and blowing agent. 18.-. (canceled)10. The foamable composition of claim 9 , wherein p is equal to m+n.13. The foamable composition of claim 9 , wherein salts of carboxylic acids are used as component (G).14. The foamable composition of claim 9 , wherein trimerization catalyst (G) is used in amounts of 0.1 to 10.0% by weight claim 9 , based on the total weight of the foamable composition.15. The foamable composition of claim 9 , comprising(A) siloxanes of formula (I),(B) polyisocyanates,(C) optionally fillers,(D) optionally emulsifiers,(E) optionally physical blowing agents,(F) optionally catalysts to speed up foam formation,(G) trimerization catalysts,(H) optionally chemical blowing agents, and(I) optionally additives,wherein the compositions of the present invention comprise on average three or more isocyanate groups and also contain at least one blowing agent (E) and/or (H).16. A process for preparing silicone-containing polyisocyanurate foams claim 9 , comprising mixing and reacting a foamable composition of .17. A foam obtained by reaction of a foamable composition of and with at least one blowing agent. This application is the U.S. national phase of PCT Appln. No. PCT/EP2011/053974 filed Mar. 16, 2011 which claims priority to German application 10 2010 003 477.0 filed Mar. 30, 2010, the disclosures of which are incorporated in their entirety by reference herein.1. Field of the InventionThe invention relates to foamable compositions based on organosilicon compounds, to silicone-containing polyisocyanurate foams with low densities, and to processes for their preparation.2. Description of the Related ArtDespite the fact that in recent decades there has been no lack of intense research activities into improving the flame retardance properties of polymer foams, it has not yet ...

LOW VISCOSITY SILYL-TERMINATED POLYMERS

Embodiment of the invention provide for compositions having at least one crosslinkable silyl group in each molecule. The crosslinkable silane-terminated polymer may include a reaction product of at least a polyol having a nominal functionality of at least 2 and a isocyanate capped hydrosilylated polymer. The isocyanate capped hydrosilylated polymer may include a reaction product of at least one isocyanate and a hydrosilylated polymer. The hydrosilylated polymer may include a reaction product of a the reaction of at least a) a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule and having a number average molecular weight of between about 100 and about 5000 and b) a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule. 2. The crosslinkable silane-terminated polymer composition of claim 1 , wherein k and n are 0 claim 1 , at least one Rand at least one Rare H claim 1 , at least one Rand at least one Rare methyl groups claim 1 , one of Rand Ris a methyl group and one of Rand Ris a H claim 1 , x is a number between about 50 and about 90 claim 1 , and y is a number between about 10 and 18.3. The crosslinkable silane-terminated polymer composition of claim 1 , wherein k is 1 claim 1 , n is 0 or 1 claim 1 , at least one Rand at least one Rare H claim 1 , at least one Rand at least one Rare methyl groups claim 1 , one of Rand Ris a methyl group and one of Rand Ris a H claim 1 , x is a number between about 20 and about 50 claim 1 , and y is a number between about 10 and 18.4. A composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule claim 1 , wherein:the crosslinkable silane-terminated polymer comprises a reaction product of at least a polyol having a nominal functionality of at least 2 and a isocyanate capped hydrosilylated polymer;the isocyanate capped hydrosilylated polymer comprises a reaction product of at least ...

TIN FREE SILYL-TERMINATED POLYMERS

Embodiments of the invention provide for methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The method comprises providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymer, and optionally reacting the isocyanate reacted hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form a polyol reacted crosslinkable silane-terminated polymer. 1. A method of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule , the method comprising:providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule and having a number average molecular weight of between about 100 and about 10000;{'sup': '1', 'adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, wherein the hydrosilylation reaction has a hydrosilylation efficiency of at least about 70% as determined by H-NMR;'}reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate at an isocyanate index of between about 80 and about 250 and in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymers; ...

Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making The Same

The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.

MIXTURE COMPRISING SULFONATE GROUP-CONTAINING COMPOUND AND METHOD OF MANUFACTURING THE SAME, SOLUTION COMPOSITION, POLYURETHANE RESIN AND METHOD OF MANUFACTURING THE SAME, AND MAGNETIC RECORDING MEDIUM

An aspect of the present invention relates to a mixture of a sulfonate group-containing compound denoted by general formula (1) with a protonic acid: 2. The polyurethane resin according to claim 1 , which comprises a sulfonic acid (salt) group in a quantity of 1×10eq/g to 2×10eq/g.3. The polyurethane resin according to claim 1 , wherein the starting materials further comprises a diol comprising a (meth)acryloyloxy group.5. The method of manufacturing according to wherein the urethane-forming reaction is conducted in the presence of a catalyst.6. The method of manufacturing according to wherein the mixture or the solution composition is subjected to the urethane-forming reaction after adding the catalyst thereto. This is a Divisional application of U.S. Ser. No. 12/768,437 filed Apr. 27, 2010 which claims the benefit of priority under 35 USC 119 to Japanese Patent Application No. 2009-109683, filed on Apr. 28, 2009, the disclosures of which are expressly incorporated herein by reference in their entirety.1. Field of the InventionThe present invention relates to a mixture comprising a sulfonate group-containing compound and to a solution composition prepared from the mixture, and more particularly, to a mixture comprising a sulfonate group-containing compound with good storage stability in organic solvents and to a solution composition prepared from the mixture.The present invention further relates to polyurethane resin obtained using the above mixture or solution composition as a starting material, to a method of manufacturing the polyurethane resin, and to a magnetic recording medium comprising the above polyurethane resin as binder.2. Discussion of the BackgroundIn recent years, methods of transmitting information at high speed have developed markedly, making it possible to transmit images and data comprised of immense amounts of information. As data transmission technology has improved, there has been a demand to further increase the recording density of recording ...

SHAPE MEMORY POLYMERS

New shape memory polymer compositions, methods for synthesizing new shape memory polymers, and apparatus comprising an actuator and a shape memory polymer wherein the shape memory polymer comprises at least a portion of the actuator. A shape memory polymer comprising a polymer composition which physically forms a network structure wherein the polymer composition has shape-memory behavior and can be formed into a permanent primary shape, re-formed into a stable secondary shape, and controllably actuated to recover the permanent primary shape. Polymers have optimal aliphatic network structures due to minimization of dangling chains by using monomers that are symmetrical and that have matching amine and hydroxl groups providing polymers and polymer foams with clarity, tight (narrow temperature range) single transitions, and high shape recovery and recovery force that are especially useful for implanting in the human body. 1. An open cell shape memory polymer foam made from a cross-linked polyurethane polymer comprising the reaction product of a symmetric diisocyanate monomer or monomers and a symmetric hydroxyl containing monomer or monomers.2. The polymer foam of wherein the diisocyanate monomer or monomers are aliphatic.3. The polymer foam of wherein the monomer(s) are aliphatic and wherein the monomer(s) are chosen to provide matching hydroxyl and amine groups in order to minimize dangling chains in the finished polymer.4. The polymer of wherein the diisocyanate monomer(s) are selected from the group consisting of octamethylene diisocyanate claim 1 , hexamethylene diisocyanate (HDI) claim 1 , pentamethylene diisocyanate claim 1 , tetramethylene diisocyanate claim 1 , trimethylene diisocyanate claim 1 , ethylene diisocyanate claim 1 , methylene diisocyanate claim 1 , and dicyclohexylmethane-4 claim 1 ,4′-diisocyanate; and aromatic diisocyanates are selected from the group consisting of methylenedi-p-phenyl diisocyanate (MDI) and toluene diisocyanate (TDI) and the ...

PERFLUOROPOLYETHER URETHANE ADDITIVES HAVING (METH)ACRYL GROUPS AND HARD COATS

Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device. 1. A fluorocarbon- and urethane-(meth)acryl-containing composition comprising a perfluoropolyether urethane having a perfluoropolyether moiety and a multi-(meth)acryl terminal group and having the formula: ((A)QO(O)CHN)—R—(NHC(O)XQR);wherein{'sub': 'i', 'Ris the residue of a multi-isocyanate;'}X is O, S or NR, wherein R is H or an alkyl group having 1 to 4 carbon;{'sub': f', 'fc', 'x', 'd', '2d', 'fc, 'Ris a monovalent perfluoropolyether moiety comprising groups of the formula F(RO)CF—, wherein each Ris independently a fluorinated alkylene group having from 1 to 6 carbon atoms, each x is an integer greater than or equal to 2, and wherein d is an integer from 1 to 6;'}each Q is independently a connecting group having a valency of at least 2;{'sub': 2', '2', '2, 'A is a (meth)acryl functional group —XC(O)C(R)═CHwherein Ris an alkyl group of 1 to 4 carbon atoms or H or F;'}{'sub': 'i', 'm is at least 1; n is at least 1; p is 2 to 6; m+n is 2 to 10; wherein each group having subscripts m and n is attached to the Runit; wherein the perfluoropolyether urethane further comprises at least one unit selected from'}—(NHC(O)XQG),—(NCO),{'sub': f', 'y, 'R(Q)(XC(O)NH)—,'}{'sub': 'u', '—(NHC(O)XQD(QXC(O)NH)—,'}{'sub': 1', 'y, '-D(QXC(O)NH),'}{'sub': t', '1', 't, '—(NHC(O)OQ(A)QQ(A)OC(O)NH)—,'}{'sub': f2', 'u, '(NHC(O)XQ-R(QXC(O)NH)—,'}whereinG is selected from the group consisting of alkyl, aryl, alkaryl, aralkyl, fluoroalkyl, perfluoroalkyl;{'sub': 3', '3', '3, 'or a reactive group selected from (meth)acryl groups, vinyl groups, allyl groups and —Si(OR)groups, where Ris a lower alkyl of 1 to 4 carbon atoms;'}D is selected from the group consisting of alkylene, arylene, alkarylene, fluoroalkylene, perfluoroalkylene, and aralkylene; or said D group further containing heteroatoms selected from O, N, and S;{'sub': 1', '1, 'Dis ...

CYCLOPENTENE RING-OPENING POLYMER AND METHOD OF PRODUCTION OF SAME

A cyclopentene ring-opening polymer which has hydroxy groups at the polymer chain terminal ends is produced, then the hydroxy groups of the cyclopentene ring-opening polymer and isocyanate groups of a compound containing alkoxysilyl groups and isocyanate groups in its molecule are made to react to thereby produce a cyclopentene ring-opening polymer which contains structures at the polymer chain terminal ends where the polymer chains and groups including alkoxysilyl groups are bonded through urethane bond groups and which has a weight average molecular weight of 100,000 to 1,000,000. 1. A cyclopentene ring-opening polymer which has structures at the polymer chain terminal ends where the polymer chains and groups including alkoxysilyl groups are bonded through urethane bond groups and which has a weight average molecular weight of 100 ,000 to 1 ,000 ,000.3. The cyclopentene ring-opening polymer as set forth in claim 1 , wherein the rate of introduction of the structures of polymer chains and groups including alkoxysilyl groups bonded through urethane bond groups to the polymer chain terminal ends claim 1 , expressed as a value of the percentage of (number of cyclopentene ring-opening polymer chain terminal ends to which said structures of polymer chains and groups including alkoxysilyl groups bonded through urethane bond groups are introduced/total number of cyclopentene ring-opening polymer chain terminal ends) claim 1 , is 20% or more.4. A method of production of the cyclopentene ring-opening polymer as set forth in claim 1 , comprising steps of producing a cyclopentene ring-opening polymer which has hydroxy groups at the polymer chain terminal ends claim 1 , then reacting the hydroxy groups of the cyclopentene ring-opening polymer and isocyanate groups of a compound which contains alkoxysilyl groups and isocyanate groups in its molecule.5. The method of production of a cyclopentene ring-opening polymer as set forth in claim 4 , wherein the cyclopentene ring-opening ...

BENZYLAMINE HYDROPHOBE

The present invention relates to a compound characterized by the following formula: 3. The compound of wherein Ris n-butyl or 2-ethylhexyl.7. The method of wherein Ris n-butyl or 2-ethylhexyl; m is 0; and p is 1. The present invention idea relates to an amine-based hydrophobe useful in preparing hydrophobically modified alkylene oxide urethane polymers, which are useful as rheology modifiers for coatings formulations.Rheology modifiers are typically designed to impart desirable rheological properties to coating formulations over a wide shear rate range. U.S. Pat. No. 7,741,402 discloses ethylene oxide urethane polymers modified with hydrophobes that contain organic bases such as secondary or tertiary amines (amine-modified HEURs), the presence of which provides for viscosity control through a pH trigger. When the pH of the HEUR composition is sufficiently low with respect to the pKof the incorporated base, the basic groups are protonated and the viscosity is relatively low; when the pH is sufficiently high, associative thickening occurs. Thus, incorporation of basic hydrophobes into the HEUR polymer allows relatively high concentration of polymer to be dissolved in water at low pH; once the solution is added to the high pH environment of paint coatings, the base is deprotonated and the associative thickening mechanism activated.Amine-modified HEURs can be sensitive to the pH of the paint formulation to which it is added. For example, the pH of the formulation, through time and heat aging, may decrease to a level below a critical pH conducive to associative thickening, thereby resulting in a poorer formulation; consequently, it would be desirable to discover a hydrophobe, more particularly an amine-based hydrophobe, that preserves the desired viscosity of the formulation in face of pH-lowering mechanisms.The present invention addresses a need by providing, in one aspect, a compound characterized by the following formula:where Ris C-C-alkyl, phenyl, naphthyl, C-C- ...

FUNCTIONALIZED AMINO ACIDS AND ABSORBABLE POLYMERS THEREFROM

The present invention relates to compounds of formula I and II, which are functionalized amino acids, and polymers formed from the same. 115-. (canceled)17. (canceled)18. (canceled)19. The polymer of claim 16 , wherein the polymer is formed from two functionalized amino acids.20. The polymer of claim 16 , wherein the polymer is further polymerized with a lactone monomer.21. The polymer of claim 20 , wherein the lactone monomer is selected from glycolide claim 20 , lactide claim 20 , ε-caprolactone claim 20 , trimethylene carbonate claim 20 , and p-dioxanone.22. The polymer according to claim 16 , wherein:y is selected from 2, 3, and 4;z is selected from 2, 3, and 4;m is selected from 2, 3, and 4; andn is selected from 2, 3, and 4.23. The polymer according to claim 16 , wherein: [{'sub': '2', '—CHCOO—;'}, {'sub': '3', '—CH(CH)COO—;'}, {'sub': 2', '2', '2, '—CHCHOCHCOO—; and,'}, {'sub': 2', '2', '2', '2', '2, '—CHCHCHCHCHCOO—;'}], 'X is selected from [{'sub': '2', '—COCHO—;'}, {'sub': '3', '—COCH(CH)O—;'}, {'sub': 2', '2', '2, '—COCHOCHCHO—;'}, {'sub': 2', '2', '2', '2', '2, '—COCHCHCHCHCHO—; and,'}], 'Y is selected froma, b, and c, are independently selected from 0-2, provided that a+b+c total from 2-4.24. The polymer according to claim 23 , wherein:{'sub': '1-4', 'R′ is selected from hydrogen, benzyl, and a straight-chained or branched Calkyl; and,'}a, b, and c, are independently selected from 0-2, provided that a+b+c total from 2-3.25. The polymer according to claim 24 , wherein:{'sub': '3', 'R′ is selected from hydrogen, benzyl, and CH; and,'}a, b, and c, are independently selected from 0-1, provided that a+b+c total from 2-3.26. The polymer according to claim 16 , wherein:{'sub': '2', 'X is —CHCOO—;'}{'sub': '2', 'Y is —COCHO—;'}{'sub': '1-4', 'R′ is selected from hydrogen, benzyl, and a straight-chained or branched Calkyl; and,'}a, b, and c, are independently selected from 0-2, provided that a+b+c total from 2-4.27. The polymer according to claim 26 , wherein:{' ...

Process for producing pigment dispersion composition

A method for producing a pigment dispersion composition having excellent image density, dispersibility, and storage stability, has high resolubility, and forms an ink film having excellent marker resistance and scratch resistance. The method includes bringing a pigment (I) having a surface acidic group and a basic compound (II) having two or more amino groups selected from a primary amino group and a secondary amino group in its molecule, into contact with each other in an aqueous medium to prepare a pigment having an unreacted surface amino group, bringing the pigment into contact with a polyisocyanate polyurethane resin (III) having two or more isocyanate end groups so that the pigment and the polyisocyanate polyurethane resin are bonded via a urea bond to prepare a dispersion of a polyurethane resin-bonded pigment (A), and heating the dispersion of the polyurethane resin-bonded pigment (A) at 40 to 100° C. for 1 to 30 days.

Pentamethylenediisocyanate, method for producing pentamethylenediisocyanate, polyisocyanate composition, polyurethane resin, and polyurea resin

A Pentamethylene diisocyanate is obtained by phosgenating pentamethylenediamine or its salt obtained by a biochemical method, and contains 5 to 400 ppm of a compound represented by the general formula (1) below and a compound represented by the general formula (2) below in total:

Airfoil leading edge coatings

A polyurethane or polyurea coating composition for use in protecting a leading edge substrate on an airfoil, such as aircraft wings, rotor blades and propeller blades, against liquid or solid particle erosion, the composition made from a polyisocyanate and curing agents, such as polyaspartic esters, aldimines and ketimines, polyamines and polyols or mixtures thereof with optional flatting agent for matte coatings.

OLIGOMERIC PHOSPHONATES AND COMPOSITIONS INCLUDING THE SAME

Disclosed are oligomeric phosphonates including oligophosphonates, random or block co-oligo(phosphonate ester)s and co-oligo(phosphonate carbonate)s produced using a condensation process terminated with hydroxyl, epoxy, vinyl, vinyl ester, isopropenyl, isocyanate groups, and the like. These materials can be used as a reactive additive to other polymers, oligomers or monomer mixtures to impart flame resistance without diminishing melt processability which is important in the fabrication of polymers for many applications. 1. A composition comprising oligomeric phosphonates having a total number of termini with reactive end groups of from about 80% to 100% , wherein the each reactive end group is independently selected from hydroxyl , epoxy , vinyl , vinyl ester , isopropenyl , isocyanate , and combinations thereof.2. The composition of claim 1 , wherein each reactive end-group is hydroxyl.3. The composition of claim 1 , wherein the oligomeric phosphonates comprise an oligophosphonate claim 1 , random co-oligo(phosphonate ester) claim 1 , block co-oligo(phosphonate ester) claim 1 , random co-oligo(phosphonate carbonate) claim 1 , or block co-oligo(phosphonate carbonate).4. The composition of claim 1 , wherein the oligomeric phosphonates comprise linear oligomeric phosphonates claim 1 , branched oligomeric phosphonates claim 1 , or a combination thereof.5. The composition of claim 1 , wherein the oligomeric phosphonates comprise a number averaged molecular weight of from about 500 g/mole to about 5000 g/mole.6. The composition of claim 1 , wherein the oligomeric phosphonates comprise units derived from bisphenol.8. The composition of claim 7 , wherein —O—Ar—O— is derived from resorcinol claim 7 , hydroquinone claim 7 , bisphenol A claim 7 , bisphenol F claim 7 , and 4 claim 7 ,4′-biphenol claim 7 , phenolphthalein claim 7 , 4 claim 7 ,4′-thiodiphenol claim 7 , 4 claim 7 ,4′-sulfonyldiphenol claim 7 , 1 claim 7 ,1-bis(4-hydroxyphenyl)-3 claim 7 ,3 claim 7 ,5-trimethyl- ...

PHOSPHOROUS-CONTAINING FLAME RETARDANTS FOR POLYURETHANE FOAMS

Embodiments of the invention include a phosphorus containing flame retardant which may be the reaction product of a reaction mixture where the reaction mixture includes at least one first polyol and at least one phosphorus containing compound having the general formula (1), (2) or combination thereof: 3. The phosphorus containing flame retardant of claim 1 , wherein R is at least one of propylene claim 1 , 2-methylpropylene claim 1 , neopentylene claim 1 , and 2-butyl-2-ethylpropylene.4. The phosphonate flame retardant of claim 1 , wherein X is selected from the group consisting of Cl claim 1 , Br claim 1 , and I claim 1 , and sulfonate.5. The phosphorus containing flame retardant of claim 1 , wherein the phosphorus containing compound is 2-Chloro-5 claim 1 ,5-dimethyl-1 claim 1 ,3 claim 1 ,2-dioxaphosphinane.6. The phosphorus containing flame retardant of claim 1 , wherein the at least one first polyol comprises at least one of polyoxalkylene polyol having an equivalent weight about 50-2500 and a combined nominal functionality of about 2-10.7. The phosphorus containing flame retardant of claim 6 , wherein the at least one polyoxalkylene polyol is initiated with glycerol claim 6 , sucrose claim 6 , sorbitol claim 6 , or a combination thereof claim 6 , and the polyoxalkylene comprises at least one of polyoxyethylene and polyoxypropylene.8. The phosphorus containing flame retardant of claim 1 , wherein the first polyol comprises a sorbitol initiated polyoxypropylene polyol with an equivalent weight of between about 100 and about 200.9. The phosphorus containing flame retardant of claim 1 , wherein the first polyol comprises a polyoxyethylene polyoxypropylene polyol initiated with a blend of glycerol and sucrose and having an equivalent weight of between about 1 claim 1 ,000 and about 2500 and a polyoxyethylene percentage of between about 15% and about 40% claim 1 , based on the weight of the polyoxyethylene polyoxypropylene polyol.10. The phosphorus containing flame ...

Biocompatible, Biodegradable Polyurethane Materials With Controlled Hydrophobic to Hydrophilic Ratio

The biocompatible, biodegradable materials in the solid and/or liquid form are based on segmented linear polyurethanes and/or segmented crosslinked polyurethanes based on A) one or more biocompatible polyols susceptible to hydrolytic and/or enzymatic degradation having a molecular weight of 100 to 20,000 dalton and a number of active hydroxyl groups per molecule (functionality) of at least two or higher; B) one or more diisocyanates and/or triisocyanates; and C) one or more low molecular weight chain extenders having a molecular weight of 18 to 1000 dalton and the functionality of at least two or higher.

SELF-CROSSLINKABLE POLYSILOXANE-MODIFIED POLYHYDROXY POLYURETHANE RESIN, PROCESS FOR PRODUCING SAID RESIN, RESIN MATERIAL COMPRISING SAID RESIN, AND ARTIFICIAL LEATHER PRODUCED UTILIZING SAID RESIN

A problem is to provide, in the field of polyhydroxy polyurethane resins the development of applications of which has not moved ahead by conventional technologies, a self-crosslinking polyhydroxy polyurethane resin, which enables to provide products, such as imitation leathers, excellent in abrasion resistance, chemical resistance, heat resistance and the like, and moreover, which is useful from the view point of a reduction in greenhouse gas, contains carbon dioxide incorporated and fixed therein, and is responsive to environmental conservation. Provided are a self-crosslinking, polysiloxane-modified, polyhydroxy polyurethane resin having masked isocyanate groups in a structure of a polysiloxane-modified, polyhydroxy polyurethane resin derived from a reaction of a -membered cyclic carbonate compound and an amine-modified polysiloxane compound and having polysiloxane segments therein; a production process of the self-crosslinking resin; a resin material containing the self-crosslinking resin; and an imitation leather composed of a base fabric and a resin composition composed of the self-crosslinking resin as its principal component and impregnated in or laminated on the base fabric. 1. A self-crosslinking , polysiloxane-modified , polyhydroxy polyurethane resin characterized by having masked isocyanate groups in a structure of a polysiloxane-modified , polyhydroxy polyurethane resin derived from a reaction of a 5-membered cyclic carbonate compound and an amine-modified polysiloxane compound and having polysiloxane segments therein.2. The self-crosslinking claim 1 , polysiloxane-modified claim 1 , polyhydroxy polyurethane resin according to claim 1 , wherein the 5-membered cyclic carbonate compound is a reaction product of an epoxy compound and carbon dioxide claim 1 , and contains claim 1 , in a structure thereof claim 1 , carbon dioxide in a range of 1 to 25 mass %.3. The self-crosslinking claim 1 , polysiloxane-modified claim 1 , polyhydroxy polyurethane resin ...

CARBOXYBETAINE-FUNCTIONALIZED DIOLS AND ZWITTERIONIC POLYURETHANE HYDROGELS DERIVED THEREFROM

A compound having the formula: XN(CH)(CHCHOH)[(CH)—COO—R] and a polymer having the repeat unit: X{—OCHCH—N(CH)[(CH)—CO—Y]—CHCHO—CO—NH—R—NH—CO—}. Ris an ester protecting group, Ris an organic group, X is a halide, and n is a positive integer. Each Y is OZor O—R, where Zis a cation from an aqueous base. A method of reacting N-methyldiethanolamine with an ω-halo-n-alkanoate ester to form the above compound. 1. A compound having the formula:{'sup': −', '+', '1, 'sub': 3', '2', '2', '2', '2', 'n, 'claim-text': wherein n is a positive integer;', {'sup': '−', 'wherein Xis a halide; and'}, {'sup': '1', 'wherein Ris an ester protecting group.'}], 'XN(CH)(CHCHOH)[(CH)—COO—R];'}2. The compound of claim 1 , wherein n is from 1 to 5.3. The compound of claim 1 , wherein n is 1 claim 1 , 3 claim 1 , 4 claim 1 , or 5.4. The compound of claim 1 , wherein n is greater than 2.5. The compound of claim 1 , wherein Xis Br.6. The compound of claim 1 , wherein Ris CHCH.7. A polymer comprising the repeat unit:{'sup': −', '+', '2, 'sub': 2', '2', '3', '2', 'n', '2', '2, 'claim-text': wherein n is a positive integer;', {'sup': '−', 'wherein Xis a halide;'}, {'sup': −', '+', '1, 'wherein each Y is independently selected from OZand O—R;'}, {'sup': '+', 'wherein Zis a cation from an aqueous base;'}, {'sup': '1', 'wherein Ris an ester protecting group; and'}, {'sup': '2', 'wherein Ris an organic group.'}], 'X{—OCHCH—N(CH)[(CH)—CO—Y]—CHCHO—CO—NH—R—NH—CO—};'}8. The polymer of claim 7 , wherein n is from 1 to 5.9. The polymer of claim 7 , wherein n is 1 claim 7 , 3 claim 7 , 4 claim 7 , or 5.10. The polymer of claim 7 , wherein n is greater than 2.11. The polymer of claim 7 , wherein Xis Br.12. The polymer of claim 7 , wherein Zis Na.13. The polymer of claim 7 , wherein Ris CHCH.14. The polymer of claim 7 , wherein OCN—R—NCO is an aliphatic polyisocyanate.15. The polymer of claim 7 , wherein OCN—R—NCO is hexamethylene diisocyanate or a biuret or trimer thereof.16. A hydrogel comprising the polymer ...

ALIPHATIC POLYCARBONATE POLYOLS CONTAINING SILYL GROUPS

In one aspect, the present invention pertains to novel silyl polyurethane (SPUR) compositions incorporating aliphatic polycarbonate polyols, as well as methods of making, formulating and using these novel materials. Also provided are films and higher polymers made from the novel SPUR compositions, as well as articles coated with, made from, or incorporating these compositions. 1. A siloxy-terminated prepolymer comprising a plurality of segments derived from one or more polyols , wherein at least a portion of the polyol segments comprise an epoxide-COcopolymer.26-. (canceled)18. The siloxy-terminated prepolymer of claim 16 , wherein comprises the carbon skeleton of a molecule selected from the group consisting of: a polyhydric alcohol claim 16 , a polyacid claim 16 , a hydroxyacid claim 16 , a phosphorous-containing functional group claim 16 , and a mixture of any two or more of these.19. The siloxy-terminated prepolymer of claim 18 , wherein comprises the carbon skeleton of a diol.21. (canceled)23. The siloxy-terminated prepolymer of claim 22 , wherein the polyol segments of formula c12 claim 22 , are derived from poly(propylene carbonate)polyol having an average molecular weight number of between about 500 g/mol and about 3 claim 22 ,000 g/mol.24. The siloxy-terminated prepolymer of claim 22 , wherein the polyol segments of formula c12 claim 22 , are derived from poly(propylene carbonate)polyol having a polydisperisty index less than about 1.25.25. The siloxy-terminated prepolymer of claim 22 , wherein the polyol segments of formula c12 claim 22 , are derived from poly(propylene carbonate)polyol having at least 95% carbonate linkages.26. The siloxy-terminated prepolymer of claim 22 , wherein the polyol segments of formula c12 claim 22 , are derived from poly(propylene carbonate)polyol having at least 98%—OH end groups.2729-. (canceled)31. The siloxy-terminated prepolymer of claim 30 , wherein the polyol segments of formula c13 claim 30 , are derived from poly( ...

FINE PARTICLE, HIGH CONCENTRATION, POLYISOCYANATE POLYADDITION/POLYURETHANE-UREA POLYOLS

Embodiments of the invention include a method of producing polymer polyol dispersions is. The method includes providing at least one reaction system, and the reaction system includes: a) at least one polyol, b) at least one seed population, c) at least one catalyst, d) at least one co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom, and e) at least one polyisocyanate. The at least one seed population includes less than about 5% by weight of the total weight of the at least one reaction system and includes seed particles having diameters of less than 5 μm. The at least one reaction mixture reacts to form at least one of a polyurea and polyurethane-urea particle population in the at least one polyol without the addition of any catalysts comprising tin. The polymer polyol dispersion has a solids content of at least 15% of the weight of the polymer polyol dispersion. 1. A method of producing a polymer polyol dispersion , the method comprising:providing at least one reaction system, the reaction system comprising:a) at least one polyol:b) at least one seed population:c) at least one catalyst;d) at least one of a co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom; ande) at least one polyisocyanate;wherein the at least one seed population comprises less than about 5% by weight of the at least one polyol and comprises suspended seed particles having maximum particle diameters of less than 5 μm;wherein to the at least one reaction mixture reacts to form at least one of a polyurea, polyurethane, and polyurethane-urea particle population in the at least one polyol without the addition of any catalysts comprising tin; andwherein the polymer polyol dispersion has a solids content of at least 15% of the weight of the polymer polyol dispersion.2. A polymer polyol dispersion comprising a reaction product of a reaction system , the ...

Implantable medical devices

A medical device includes a balloon catheter having an expandable member, e.g., an inflatable balloon, at its distal end and a stent or other endoprosthesis. The stent is, for example, an apertured tubular member formed of a polymer and is assembled about the balloon. The stent has an initial diameter for delivery into the body and can be expanded to a larger diameter by inflating the balloon.

PROCESS FOR PRODUCING POROUS MATERIALS BASED ON ISOCYANATE

The present invention relates to a process for producing porous materials, which comprises reaction of at least one polyfunctional isocyanate with at least one polyfunctional aromatic amine in the presence of at least one catalyst and a solvent. The invention further relates to the porous materials which can be obtained in this way and the use of the porous materials as insulation material, in particular for applications in the building sector and in vacuum insulation panels. 2. The process according to which comprises reacting from 35 to 93.8% by weight of component (a1) claim 1 , from 0.2 to 25% by weight of component (a2) claim 1 , from 0 to 10% by weight of water and from 6 to 30% by weight of component (a4) claim 1 , in each case based on the total weight of the components (a1) to (a4) claim 1 , where the % by weight of the components (a1) to (a4) add up to 100% by weight.3. The process according to claim 1 , wherein at least 5 and at the most 20% by weight of component (a2) are used claim 1 , based on the total weight of the components (a1) to (a4).4. The process according to which comprises reacting 52 to 92.5% by weight of component (a1) claim 1 , from 0.5 to 18% by weight of component (a2) claim 1 , from 0 to 6% by weight of water and from 7 to 24% by weight of component (a4) claim 1 , in each case based on the total weight of the components (a1) to (a4) claim 1 , where the % by weight of the components (a1) to (a4) add up to 100% by weight.5. The process according to claim 1 , wherein Q claim 1 , Q claim 1 , Q′ and Q′ are selected so that the aromatic amine (a2) having the general formula I comprises at least two primary amino groups which each have a linear or branched alkyl group which can bear further functional groups claim 1 , having from 1 to 12 carbon atoms claim 1 , in the a position relative to at least one primary amino group bound to the aromatic ring.6. The process according to claim 1 , wherein the amine component (a2) comprises at least one ...

DENSELY FUNCTIONALIZED POLYMERS DERIVED FROM BAYLIS-HILLMAN ADDUCTS

A method of preparing a polymer is provided comprising preparing a Baylis-Hillman adduct by reacting an activated alkene with a carbon electrophile; and polymerizing the Baylis-Hillman adduct. The Baylis-Hillman reaction provides an efficient platform for the synthesis of densely functionalized monomers, from which polymers with multiple functional groups can be readily synthesized. It has been discovered that that Baylis-Hillman adducts are versatile monomers for both controlled radical and step-growth polymerizations. 1. A method of preparing a polymer comprising:preparing a diol funtionalized Baylis-Hillman adduct by performing a Baylis-Hillman reaction on an activated alkene and a carbon electrophile, and polymerizing the diol functionalized Baylis-Hillman adduct through a step-growth polymerization.3. The method of claim 1 , where the step-growth polymerization prepares a polyurethane by reacting a diisocyanate and the Baylis-Hillman adduct.4. The method of claim 3 , where the diisocyante may be defined by the formula:{'br': None, 'sup': '8', 'O═C═N—R—N═C═O'}{'sup': '8', 'where Ris a hydrocarbon group.'}8. The method of claim 7 , where the polymer is modified post-polymerization by a thiol-ene reaction.9. The method of claim 8 , where the thiol-ene reaction is preformed with a thiol compound defined by the formula:{'br': None, 'sup': 2', '5, 'Z—R—SH'}{'sup': 5', '2, 'where Ris independently a bond or a hydrocarbon group, and Zis a hydrogen atom, aryl group, protected amine, protected carboxylic acid, alkoxy, silyloxy, hydroxyl, protected diol, amine, carboxylic acid, or diol'}10. The method of claim 1 , where diol functional Baylis-Hillman adduct is first modified prior to polymerization through the addition of a functional group through a thiol-ene reaction claim 1 , and the step-growth polymerization prepares polyester by reacting a dicarboxylic acid and the Baylis-Hillman adduct.14. The polymer of claim 13 , where each X is an ester group.15. The polymer of ...

Polyurethanes

A process for making a flame retardant polyurethane foam, the process comprising reacting a PO based polyol with foam-forming reactants to provide said polyurethane foam, wherein said polyol is prepared by ring-opening polymerization of alkylene oxide in the presence of a composite metal cyanide complex catalyst, and wherein said polyol is either free from EO moieties or comprises EO moieties in an amount of at most 1% w/w.

POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIALS, OPTICAL MATERIAL AND PLASTIC LENS OBTAINED FROM COMPOSITION

A polymerizable composition for optical materials of the present invention includes a polyisocyanate compound (A), a polyol compound (B) represented by the following General Formula (1) having a number average molecular weight of 100 or more, a di- or higher functional active hydrogen compound (C) (here, the compound (B) is excluded), and a photochromic compound (D). 2. The polymerizable composition for optical materials according to claim 1 ,wherein the polyisocyanate compound (A) is at least one kind selected from the group consisting of hexamethylene diisocyanate, pentamethylene diisocyanate, xylylene diisocyanate, isophorone diisocyanate, bis(isocyanatomethyl) cyclohexane, dicyclohexylmethane diisocyanate, 2,5-bis(isocyanatomethyl)bicyclo[2.2.1]-heptane, 2,6-bis(isocyanatomethyl)bicyclo-[2.2.1]-heptane, tolylene diisocyanate, phenylene diisocyanate, and diphenylmethane diisocyanate.4. The polymerizable composition for optical materials according to claim 3 ,wherein the polyol compound (B) is the compound represented by General Formula (I), (III), or (IV).5. The polymerizable composition for optical materials according to claim 3 ,wherein the compound represented by General Formula (I) is polyethylene glycol or polypropylene glycol.6. The polymerizable composition for optical materials according to claim 3 ,wherein the number average molecular weight of the compound represented by General Formula (I) is 200 to 4000.7. The polymerizable composition for optical materials according to claim 3 ,wherein the number average molecular weight of the compound represented by General Formula (I) is 300 to 3000.8. The polymerizable composition for optical materials according to claim 3 ,13. The polymerizable composition for optical materials according to claim 1 ,wherein the active hydrogen compound (C) is at least one kind selected from the group consisting of glycerin, pentaerythritol tetrakis(2-mercaptoacetate), pentaerythritol tetrakis(3-mercaptopropionate), 4- ...

Coating Composition Comprising a Polyisocyanate and a Polyol

The invention relates to a non-aqueous coating composition comprising 1. A non-aqueous coating composition comprisinga) a polyisocyanate,b) a polyol having an average functionality of more than 3 hydroxyl groups per molecule, and i) a metal based curing catalyst for the addition reaction of isocyanate groups and hydroxyl groups and', 'ii) a mercapto carboxylic acid,, 'c) the reaction product of'}wherein the coating composition does not contain a carboxylic acid wherein the carbonyl group of the carboxylic acid is in conjugation with a TT-electron system.2. The coating composition according to claim 1 , wherein the catalyst for the addition reaction of isocyanate groups and hydroxyl groups is based on a metal selected from the group consisting of tin claim 1 , bismuth claim 1 , zirconium claim 1 , and mixtures thereof.3. The coating composition according to claim 1 , wherein the catalyst for the addition reaction of isocyanate groups and hydroxyl groups is based on tin.4. The coating composition according to claim 1 , wherein the amount of metal based curing catalyst is in the range of 0.001 to 10 weight-% claim 1 , calculated on the non-volatile matter of the composition.5. The coating composition according to claim 1 , wherein the mercapto carboxylic acid is selected from the group consisting of 2-mercapto-carboxylic acids claim 1 , 3-mercapto-carboxylic acids claim 1 , and mixtures thereof.6. The coating composition according to claim 1 , wherein the amount of mercapto carboxylic acid is in the range of 0.1 to 18 weight-% claim 1 , calculated on the non-volatile matter of the composition.7. The coating composition according to claim 1 , wherein component b) comprises a polyester polyol and a polyacrylate polyol.8. The coating composition according to claim 1 , wherein the composition further comprises a volatile organic solvent.9. The coating composition according to claim 7 , wherein the amount of volatile organic solvent does not exceed 420 g/l of coating ...

URETHANE RESIN COMPOSITION

The present invention relates to a polyol composition for obtaining a polyurethane foam through a reaction with a polyisocyanate compound. The polyol composition comprises a polyol, a catalyst, a foam stabilizer, a foaming agent, and ammonium carboxylate, wherein the ammonium carboxylate has a quaternary ammonium cation as a cationic moiety, and a carboxylic acid anion represented by formula (1) as an anionic moiety. 2. The polyol composition according to claim 1 , wherein the amount of the ammonium carboxylate is 5 parts by mass to 20 parts by mass per 100 parts by mass of the polyol.3. The polyol composition according to claim 1 , wherein Ris CH.4. The polyol composition according to claim 1 , wherein the cationic moiety of the ammonium carboxylate is a tetramethyl ammonium cation.5. The polyol composition according to claim 1 , wherein the anionic moiety of the ammonium carboxylate is 2 claim 1 ,2-dimethylpropanoic acid anion.6. The polyol composition according to claim 1 , which comprises hydrofluoroolefin (HFO) as a foaming agent.7. A foamable polyurethane composition claim 1 , which is a mixture of the polyol composition according to and a polyisocyanate compound.8. The foamable polyurethane composition according to claim 7 , wherein the foamable polyurethane composition has an isocyanate index of 250 or more.9. A polyurethane foam obtained by curing the foamable polyurethane composition according to . The present invention relates to a polyol composition for obtaining a polyurethane foam through a reaction with a polyisocyanate compound, a foamable polyurethane premix composition, a foamable polyurethane composition, and a polyurethane foam.Urethane resin compositions, which have excellent insulation and adhesive properties, have been used as heat-insulating materials for buildings, such as housing complexes including condominium apartments, houses, school facilities, and commercial buildings.PTL 1: JP2000-230028APTL 2: JP2004-339269APTL 3: JP2000- ...

EROSION RESISTANT COATINGS

An erosion resistant article such as rotor blades for helicopters and wind turbines having the leading edge surface protected from damage from high speed impingement of rain or sand with a protective coating formed from specific polyurethane or polyurea coating having a defined set of minimum physical properties where the protective coating can be applied as a liquid coating and cured in place or as a preformed complementary shaped covering to protect the leading edge against erosion damage in service. 1. An erosion resistant article comprising an airfoil shaped substrate having a leading edge surface exposed in use to high speed impingement of liquid or solid particles , said leading edge surface covered with a protective coating comprising: a polyurethane or polyurea coating selected from the group consisting of an isocyanate-terminated prepolymer cured with a curing agent , a polyisocyanate cured with a curing agent , and a water dispersion of a pre-reacted polyurethane , said curing agent selected from a group consisting of an aldimine , a ketimine , a polyaspartic ester , a polyamine , one or more polyols and mixtures thereof having a tensile strength greater than 1000 psi (70 kg/cm) , an elongation at break greater than 350% , a tensile set of less than 150% , and a Shore A hardness of 44 A to 95 A as measured at 68° F. when tested without any filler.2. The erosion resistant article of wherein said polyurethane or polyurea coating is preformed into a cured form selected from the group consisting of boots claim 1 , films claim 1 , sheets claim 1 , and tapes.3. The erosion resistant article of further comprising an underlying layer of primer or an adhesive material bonding said preformed sheet to said airfoil shaped substrate.4. The erosion resistant article of wherein said polyurethane or polyurea coating is preformed into a cured sheet or tape.5. The erosion resistant article of wherein said cured form is a boot preformed to have the shape of the leading edge ...

ONE-PART CURABLE SOFT FEEL COATINGS

Disclosed herein arc one part, One-part, curable compositions that have a soft feel when applied as a coating/film and cured, may include a) at least one isocyanurate tri(meth)acrylate or derivative thereof; and at least one of components b)-e), wherein: b) is at least one urethane diacrylate; c) is at least one monofunctional or difunctional reactive diluent; d) is at least one solvent; and e) is additives. The one-part, curable compositions are advantageous with respect to softness and tailorability of softness as well as other properties such as mar resistance, abrasion resistance, stain resistance and chemical resistance. Due to their advantageous properties, embodiments of the one-part, curable compositions described herein are viable for a wide range of coating applications including automotives, aeronautics, cosmetics, small appliances, packaging and consumer electronics. Methods of making and using the one-part, curable are also described herein. 1. A one-part , curable composition comprising: b) at least one urethane diacrylate;', 'c) at least one monofunctional or difunctional reactive diluent, different from b)', 'd) at least one solvent; and', 'e) additives., 'a) at least one isocyanurate tri(meth)acrylate or derivative thereof and at least one of2. The one-part claim 1 , curable composition of claim 1 , wherein the composition comprises the b) at least one urethane diacrylate.3. The one-part claim 1 , curable composition of claim 1 , wherein the a) at least one isocyanurate tri(meth)acrylate or derivative thereof comprises tris(2-hydroxyethyl)isocyanurate triacrylate.4. The one-part claim 1 , curable composition of claim 1 , wherein the composition comprises the d) at least one solvent.5. The one-part claim 1 , curable composition of claim 1 , wherein the composition comprises the e) additives claim 1 , wherein the additives are selected from the group consisting of photo-initiators claim 1 , thermal free radical initiators claim 1 , accelerators claim ...

FREE-STANDING NON-FOULING POLYMERS, THEIR COMPOSITIONS, AND RELATED MONOMERS

Free-standing non-fouling polymers and polymeric compositions, monomers and macromonomers for making the polymers and polymeric compositions, objects made from the polymers and polymeric compositions, and methods for making and using the polymers and polymeric compositions. 119-. (canceled)2122-. (canceled)23. A polymer of having a fibrinogen binding level of less than 30 ng/cmin a fibrinogen binding assay (polymer surface is incubated at 37° C. for 90 minutes with a 1.0 mg/mL fibrinogen solution in 0.15 M phosphate buffered saline at pH 7.4).24. A polymer of having a tensile or compressive strength greater than 0.5 MPa.25. A polymer of having a fibrinogen binding level of less than 30 ng/cmin a fibrinogen binding assay (polymer surface is incubated at 37° C. for 90 minutes with a 1.0 mg/mL fibrinogen solution in 0.15 M phosphate buffered saline at pH 7.4) and a tensile or compressive strengths greater than 0.5 MPa.26. A polymer of claim 20 , wherein the polymer is crosslinked.27. A composite claim 20 , comprising a polymer of and a second polymer.28. The composite of claim 27 , wherein the second polymer is selected from the group consisting of polyesters claim 27 , polycarbonates claim 27 , polyurethanes claim 27 , polyureas claim 27 , polysulfides claim 27 , polysulfones claim 27 , polyimides claim 27 , polyepoxies claim 27 , aromatic polyesters claim 27 , cellulosics claim 27 , fluoropolymers claim 27 , polyacrylics claim 27 , polyamides claim 27 , polyanhydrides claim 27 , polyethers claim 27 , vinyl polymers claim 27 , phenolics claim 27 , elastomers claim 27 , and other addition polymers.29. The composite of further comprising a strength additive.30. The composite of further comprising a strength additive selected from the groups consisting of fiber claim 27 , clays claim 27 , nanotubes claim 27 , and other inorganic objects.31. A polymer of formed into an object by a method selected from the group consisting of injection molding claim 20 , blow molding claim ...

Polyurethane-based UV absorber

A polyurethane-based UV absorber, obtained by reacting a UV absorber having a reactive hydrogen with a polyisocyanate and a diol or polyol; wherein the weight average molecular weight of the polyurethane-based UV absorber is in a range of 10,000 to 200,000. 1. A polyurethane-based UV absorber , obtained by reacting a UV absorber having a reactive hydrogen with a polyisocyanate and a diol or polyol; wherein the weight average molecular weight of the polyurethane-based UV absorber is in a range of 10 ,000 to 200 ,000.2. The polyurethane-based UV absorber as claimed in claim 1 , wherein the reactive hydrogen as functional group comprised in the UV absorber is selected from the group consisting of: —OH claim 1 , —NH claim 1 , and —NH—.3. The polyurethane-based UV absorber as claimed in claim 1 , wherein the UV absorber is selected from the group consisting of benzotriazole UV absorber claim 1 , benzophenone UV absorber claim 1 , triazine UV absorber claim 1 , oxanilide UV absorber claim 1 , and cyanoacrylate UV absorber.4. The polyurethane-based UV absorber as claimed in claim 1 , wherein the polyisocyanate is selected from the group consisting of isophorone diisocyanate (IPDI) claim 1 , 4 claim 1 ,4′-dicyclohexylmethane diisocyanate (HMDI) claim 1 , hexamethylene diisocyanate (HDI) claim 1 , 1 claim 1 ,3-Bis(isocyanatomethyl)benzene (XDI) claim 1 , tetramethyl xylylene diisocyanate (TMXDI) claim 1 , 2 claim 1 ,2 claim 1 ,4-trimethylhexamethylene diisocyanate (HDI TRIMER) claim 1 , hexamethylene diisocyanate biuret (HDB) claim 1 , and a mixture thereof.5. The polyurethane-based UV absorber as claimed in claim 1 , wherein the diol or polyol is selected from the group consisting of anionic diol or polyol claim 1 , cationic diol or polyol claim 1 , nonionic diol or polyol claim 1 , and a mixture thereof.6. The polyurethane-based UV absorber as claimed in claim 5 , wherein the anionic diol or polyol is selected from the group consisting of 2 claim 5 ,2-Bis(hydroxymethyl) ...

Using occluding fluids to augment additive manufacturing processes

The present disclosure relates to the use of occluding fluids, such as a high-density fluid (a “z-fluid”) or a low-density fluid (an “a-fluid”), to displace resin within a vat during 3D printing. Further, an a-fluid may act as a protective boundary for a 3D printing resin wherein the a-fluid sits on top of the printing resin. Another embodiment of the disclosure provides a process of assessing which regions of a computer-aided design (CAD) model take advantage of a buoying force supplied by the occluding fluid, such that fewer support structures are needed for printing a final CAD model compared to printing the CAD model without the occluding fluid.

Semicarbazide composition, water-based coating composition, coating film, article, and method for producing semicarbazide composition

A semicarbazide composition contains a semicarbazide compound (A1) derived from a hydrazine and an isocyanate compound (a1) having an isocyanate group, and a semicarbazide compound (B1) derived from a hydrazine and an isocyanate compound (b1) having an isocyanate group and having a different structure from the isocyanate compound (a1), wherein the absolute value of the difference in the solubility parameters of the isocyanate compound (a1) and the isocyanate compound (b1) is at least 0.15 but not more than 2.10. A method for producing a semicarbazide composition includes, in sequence, a step 2-1 of reacting a hydrazine and an isocyanate compound (a2) having at least one cyclic structure within the molecule to obtain a semicarbazide compound (A2), and a step 2-2 of reacting a hydrazine and an isocyanate compound (b2) not having a cyclic structure within the molecule to obtain a semicarbazide compound (B2).

PRODUCTION OF RIGID POLYURETHANE FOAM

What are described are (a) a composition suitable for production of rigid polyurethane foam, comprising at least one isocyanate component, a polyol component, optionally a catalyst that catalyses the formation of a urethane or isocyanurate bond, optionally blowing agents, where the composition additionally comprises polyalkylsiloxane (PAS) containing no polyether modification, and polyether-modified siloxane, (b) a process for producing rigid polyurethane foam using polyalkylsiloxanes and polyether-modified siloxane, (c) the rigid polyurethane foam Thus obtainable and (d) the use thereof. 1. A composition for production of rigid polyurethane foam , the composition comprising at least one isocyanate component , a polyol component , optionally a catalyst that catalyses the formation of a urethane or isocyanurate bond , optionally blowing agents , where the composition additionally comprises polyalkylsiloxane containing no polyether modification , and polyether-modified siloxane.2. The composition according to claim 1 , wherein the polyalkylsiloxanes contain less than 20 silicon atoms.3. The composition according to claim 1 , wherein the polyalkylsiloxanes are used in combination with polyether-modified siloxanes in a mass ratio of from 1:5 to 1:200.4. The composition according to claim 1 , wherein the proportion by mass of the total amount of polyalkylsiloxanes and polyether-modified siloxanes claim 1 , based on 100 parts by mass of polyol component claim 1 , is from 0.1 to 10 pphp.6. The composition according to claim 5 , wherein{'br': None, 'c+d>0.5.'}7. The composition according to claim 5 , wherein{'br': None, 'd=0 and c>0.5.'}8. The composition according to claim 5 , wherein{'br': None, 'c+d<0.5.'}11. The process for producing rigid polyurethane foam by reacting one or more polyol components with one or more isocyanate components claim 1 , wherein the reaction is effected in the presence of polyalkylsiloxanes containing no polyether modification claim 1 , and ...

MOISTURE-CURABLE SILYLATED POLYMER RESIN COMPOSITION WITH REDUCED MOISTURE SENSITIVITY

There is provided herein a silylated polyurethane composition, a process of preparing a silylated polyurethane polymer, and an adhesive, sealant or coating containing a silylated polyurethane made therewith. 4. The silylated polyurethane composition of where in formula (IIA) Rpossesses 1 to 4 carbon atoms claim 3 , each Ris the same or different group selected from the group consisting of methyl claim 3 , ethyl claim 3 , propyl or isopropyl group and a is 0.5. The silylated polyurethane composition of claim 1 , comprising the reaction product of:a polyol;an isocyanatosilane silylating agent; and,an yttrium-containing catalyst.6. The silylated polyurethane composition of claim 1 , comprising the reaction product of:a polyisocyanate;an active hydrogen-containing silane; and,an yttrium-containing catalyst.7. The silylated polyurethane composition of claim 1 , wherein the yttrium-containing catalyst is selected from the group consisting of an yttrium salt claim 1 , a hydrate of an yttrium salt claim 1 , an yttrium complex claim 1 , an yttrium alkoxide claim 1 , an organic yttrium compound claim 1 , an inorganic yttrium compound claim 1 , and combinations thereof.8. The silylated polyurethane composition of claim 1 , wherein the yttrium-containing catalyst is an yttrium salt selected from the group consisting of yttrium halide claim 1 , yttrium nitrate claim 1 , yttrium sulfate claim 1 , yttrium trifluoromethanesulfonate claim 1 , yttrium acetate claim 1 , yttrium trifluoroacetate claim 1 , yttrium malonate claim 1 , octylic acid (ethyl hexanoic acid) salt of yttrium claim 1 , yttrium naphthenate claim 1 , versatic acid salt of yttrium claim 1 , yttrium neodecanoate claim 1 , yttrium carbonate claim 1 , yttrium hydrogen carbonate claim 1 , and combinations thereof.9. The silylated polyurethane composition of claim 1 , wherein the yttrium-containing catalyst is an yttrium alkoxide selected from the group consisting of yttrium trimethoxide claim 1 , yttrium triethoxide ...

Shape-Memory-Self-Healing Polymers (SMSHPS)

A shape-memory self-healing polymeric network (SMSHP) is useful as a molded part, a coating, or as a matrix for a composite that can be repaired by heating to a controlled temperature. The SMSHP has thermally reversible repeating units where a thermally reversible adduct is situated between two common linking units formed during a polymerization process between thermally reversible monomers and cross-linking monomers. Optionally, other repeating units can be present from other monomers. Shape-memory results when the SMSHP is warmed to a temperature in excess of its glass transition temperature and self-healing then proceeds when a higher temperature is achieved where thermally reversible adducts dissociates to complementary groups that subsequently reform the adduct without distortion of the memorized shape. The thermally reversible adducts can be Diels-Alder (DA) adducts in a polyurethane, poly urea, or amine epoxy SMSHP network. 1. A shape-memory self-healing polymeric network (SMSHP) , comprising:thermally reversible repeating units comprising a Diels-Alder (DA) adduct between two linking units to other repeating units of the SMSHP, wherein the linking units are urethane units and/or urea units;optionally, one or more other repeating units lacking the DA adduct between two of the linking units; and{'sub': g', 'g, 'cross-linking repeating units lacking a thermally reversible unit; wherein the cross-linking units connect three or more chains by the linking units, wherein the majority of the chains comprise at least one of the thermally reversible units, wherein a glass transition temperature (T) of the SMSHP is below an onset temperature where the thermally reversible adduct cleaves to two complementary functionalities, and wherein at temperatures between the Tand the onset temperature form the thermally reversible adduct.'}2. The SMSHP of claim 1 , wherein the thermally reversible repeating unit is derived from the DA adduct of maleimide and furan.3. The SMSHP of ...

Self-healing elastomer and process for its preparation

The self-healing cross-linked polymer comprises units of formula (I), wherein: P is a polymeric chain, R 1 and R 1 ′ are independently selected from the group consisting of: —H, (C 1 -C 20 )alkyl, (C 5 -C 14 )aryl, —OR 4 , —(CO)R 5 , —O(CO)R 6 , —(SO)R 7 , —NH—CO—R 8 , —COOR 9 , —NR 10 R 11 , —NO 2 , and halogen; R 2 , R 2 ′, R 3 and R 3 ′ are independently selected from the group consisting of: —H, (C 1 -C 20 )alkyl and (C 5 -C 14 )aryl; R 4 to R 11 are the same or different, and are selected from the group consisting of: —H, (C 1 -C 20 )alkyl, and (C 5 -C 14 )aryl; m is from 3 to 4; n is from 1 to 2; provided that n+m is 5; the polymer having H-bonding interactions and being able to undergo catalyst free aromatic disulfide metathesis at room-temperature, and having a tensile strength value from 0.5 to 1.5 MPa and an elongation at break value higher than 200% at room-temperature.

Polyurethane Adhesive

The present invention relates to acrylic compositions capable of bonding directly with an isocyanate-containing composition, e.g. polyurethane, and methods for manufacturing the same. The acrylic compositions of the invention have multifunctional chain transfer agents and/or multifunctional crosslinkers with isocyanate-reactive groups.

Tin free silyl-terminated polymers

Embodiments of the invention provide for methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The method comprises providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymer, and optionally reacting the isocyanate reacted hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form a polyol reacted crosslinkable silane-terminated polymer.

POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, METHOD FOR MANUFACTURING POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, AND METHOD FOR MANUFACTURING OPTICAL ARTICLE

A polymerizable composition for an optical material includes a prepolymer which is a reaction product of a first amine compound (A1) having a weight-average molecular weight of less than 4,000, a first diol compound (B1) having a viscosity (25° C.) of equal to or less than 100 mPa·s, and a polyisocyanate compound (C); and a first polythiol compound (D1), in which the first amine compound (A1) is at least one selected from a polyetheramine and an aromatic amine, and the first polythiol compound (D1) includes a dithiol compound (d1) having two mercapto groups and a polythiol compound (d2) having equal to or more than three mercapto groups. 1. A polymerizable composition for an optical material , comprising:a prepolymer which is a reaction product ofa first amine compound (A1) having a weight-average molecular weight of less than 4,000,a first diol compound (B1) having a viscosity (25° C.) of equal to or less than 100 mPa·s, anda polyisocyanate compound (C);a first polythiol compound (D1); anda catalyst,wherein the first amine compound (A1) is at least one selected from a polyetheramine and an aromatic amine, andthe first polythiol compound (D1) includes a dithiol compound (d1) having two mercapto groups and a polythiol compound (d2) having equal to or more than three mercapto groups.3. The polymerizable composition for an optical material according to claim 2 ,wherein the polyetheramine has a weight-average molecular weight of more than 230.4. The polymerizable composition for an optical material according to claim 1 ,wherein the aromatic amine is at least one selected from the group consisting of 3,5-diethyltoluene-2,4-diamine and 3,5-diethyltoluene-2,6-diamine.5. The polymerizable composition for an optical material according to claim 1 , further comprising:a second diol compound (B2).6. The polymerizable composition for an optical material according to claim 1 , further comprising:a second amine compound (A2) having a weight-average molecular weight of equal to or ...

AQUEOUS POLYURETHANE-UREA DISPERSION

The present invention relates to an aqueous dispersion based on polyurethane-urea, a composition comprising the same, and a use of the same in a coating agent, a sealant and an adhesive. The aqueous polyurethane-urea dispersion comprises a polyurethane-urea dispersed therein having sulfonate and/or carboxylate groups and lateral carboxyl groups, wherein the amount of said sulfonate and or carboxylate groups is 1.5 to 15 mmol/100 g; said lateral carboxyl is introduced by an aminocarboxylic acid having an amino functionality of greater than 1; the amount of said lateral carboxyl is 1.5 to 9.5 mmol/100 g, based on the polyurethane-urea solid components. Compared with the prior art, the composition of the polyurethane-urea based aqueous dispersion and a carboxyl reactive cross-linking agent provided by the present invention has a good cross-linking property and an excellent heat-resistance, which is not prone to come unglued when being exposed to heat. 115-. (canceled)16. An aqueous polyurethane-urea dispersion , comprising a polyurethane-urea dispersed therein having sulfonate and/or carboxylate groups and lateral carboxyl groups , wherein an amount of said sulfonate and/or carboxylate groups is 1.5 to 15 mmol/100 g; said lateral carboxyl groups are introduced by an aminocarboxylic acid having an amino functionality of greater than 1; an amount of said lateral carboxyl groups is 1.5 to 9.5 mmol/100 g , based on the polyurethane-urea solid components.17. The aqueous polyurethane-urea dispersion according to claim 16 , wherein said polyurethane-urea is prepared by comprising following components:A) at least one polyol component having a number-average molecular weight of 400 to 5000 Daltons and a hydroxyl functionality of not less than 1.9;B) optionally at least one polyol component having a number-average molecular weight of 62 to 399 Daltons;C) at least one diisocyanate or polyisocyanate component;D) at least one aminocarboxylic acid having an amino functionality of ...

OPTICAL RESIN COMPOSITION, OPTICAL ELEMENT OBTAINED BY CURING OPTICAL RESIN COMPOSITION, AND PLASTIC LENS FOR EYEGLASSES

An optical resin composition from which an optical element having high heat resistance can be obtained, an optical element obtained by curing the optical resin composition, and a plastic lens for eyeglasses, where the optical resin composition contains a polyiso(thio)cyanate and a polythiol component, which contains a polythiol compound having a sulfide bond and/or a disulfide bond. 2. The optical resin composition according to claim 1 , wherein the polythiol component contains a compound having a refractive index of 1.62 or more.3. The optical resin composition according to claim 1 , wherein the polythiol compound has two or more sulfide bonds and/or disulfide bonds in total.4. The optical resin composition according to claim 1 , wherein the polythiol component contains a compound having three or more mercapto groups.5. The optical resin composition according to claim 1 , wherein the polythiol component contains at least one kind selected from the group consisting of 2 claim 1 ,3-bis(2-mercaptoethylthio) propane-1-thiol claim 1 , 5 claim 1 ,7-bis(mercaptomethyl)-3 claim 1 ,6 claim 1 ,9-trithiaundecane-1 claim 1 ,11-dithiol claim 1 , 4 claim 1 ,7-bis(mercaptomethyl)-3 claim 1 ,6 claim 1 ,9-trithiaundecane-1 claim 1 ,11-dithiol claim 1 , and 4 claim 1 ,8-bis(mercaptomethyl)-3 claim 1 ,6 claim 1 ,9-trithiaundecane-1 claim 1 ,11-dithiol.6. The optical resin composition according to claim 1 , further comprising at least one kind selected from the group consisting of a compound having three or more isocyanate groups claim 1 , a compound having three or more active hydrogen atoms claim 1 , and a compound having two or more episulfide groups.7. The optical resin composition according to claim 4 , wherein the polythiol component contains a compound having two mercapto groups.8. The optical resin composition according to claim 1 , wherein the amount of the compound represented by the formula (I-p) or formula (II-p) is 50% by mass or more in the polyiso(thio)cyanate component ...

POLYASPARTIC COATING COMPOSITION, COATING FILM, AND COATING ARTICLE

A polyaspartic coating composition contains: an aspartic acid ester compound; and a polyisocyanate composition containing a polyisocyanate obtained from at least one diisocyanate monomer selected from the group consisting of aliphatic diisocyanates and alicyclic diisocyanates, wherein the molar ratio x represented by equation (1) is 0.05 to 0.5, the molar ratio d represented by equation (4) is 0.02 to 0.5, and the molar ratio e represented by equation (5) is 0 to 0.05, 3. The polyaspartic coating composition according to claim 1 , wherein the molar ratio d in the polyisocyanate composition (B1) is 0.04 to 0.3 claim 1 , a molar ratio b of equation (2) is 0 to 0.4 claim 1 , and claim 1 , a molar ratio c of equation (3) is 0 to 0.3 claim 1 ,{'br': None, 'i': b=B/', 'A+B+C+D, 'the molar ratio () \u2003\u2003(2)'}{'br': None, 'i': c=C/', 'A+B+C+D, 'the molar ratio () \u2003\u2003(3)'}{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'in the equations, A, B, C and D are the same as defined in .'}5. The polyaspartic coating composition according to claim 4 , wherein the polyisocyanate composition (B2) further comprises a polyisocyanate (b2) obtained from at least one diisocyanate selected from the group consisting of aliphatic diisocyanates and alicyclic diisocyanates claim 4 , anda content of the polyisocyanate (b2), relative to a total mass of the polyisocyanate composition (B2), is more than 0% by mass and no more than 80% by mass.7. The polyaspartic coating composition according to claim 6 , wherein the polyisocyanate composition (B3) further comprises an isocyanurate group.8. The polyaspartic coating composition according to claim 1 , wherein a viscosity at 25° C. of the polyisocyanate composition is 10 mPa·s to 1000 mPa·s.9. The polyaspartic coating composition according to claim 1 , wherein an equivalent ratio of an amino group of the aspartic acid ester compound and isocyanate group of the polyisocyanate composition claim 1 , amino group: isocyanate group claim 1 , ...

ACCOMMODATING CAVITY LENS SHAPED WITH PHOTOCLEAVABLE INSERT

A lens comprises an internal cavity structure formed by dissolution of a soluble insert material. The internal soluble material may dissolve through a body of a lens such as a contact lens in order to form the cavity within the contact lens. The cavity within the lens can be shaped in many ways and corresponds to the shape of the dissolved material, such that many internal cavity shapes can be readily fabricated within the contact lens. The insert can be placed in a mold with a pre-polymer material, and the pre-polymer material cured with the insert placed in the mold to form the lens body. The polymerized polymer may comprise a low expansion polymer in order to inhibit expansion of the lens when hydrated. The polymer may comprise a hydrogel when hydrated. The soft contact lens material comprises a sufficient amount of cross-linking to provide structure to the lens and shape the cavity. 1. A soft contact lens for correcting vision of an eye , comprising:a hydrogel contact lens body comprising water and cross-linked polymer, wherein said contact lens body defines an internal cavity shaped with a photo-decomposable material and comprising a fluid.2. The soft contact lens of claim 1 , wherein said cross-linked polymer allows water to diffuse in and out of the contact lens body to the cavity from an external surface of the body claim 1 , and wherein said cavity is shaped to correct vision when in equilibrium with tear fluid of the eye.3. The soft contact lens of claim 1 , wherein said hydrogel contact lens body and said cavity are configured together to increase optical power by at least 2 D with an increase in internal pressure within a range from about 20 Pascals (Pa) to about 50 Pa and wherein the cavity comprises a volume containing the fluid within a range from about 0.5 mm3 to about 5 mm3 and wherein the hydrogel contact lens body comprises a modulus within a range from about 0.25 MPa to about 2 MPa and wherein a hydrogel material of the contact lens body ...

Electrode with enhanced cycle life and lithium secondary battery including the same

The present invention relates to an electrode for a secondary battery including an electrode current collector, an electrode active material combination layer formed on one or both sides of the electrode current collector, and a polyurethane-based coating layer formed on the electrode active material combination layer, and a lithium secondary battery including the same.

POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL AND OPTICAL MATERIAL

A polymerizable composition for an optical material of the present invention includes polyisocyanate (a) including aliphatic polyisocyanate (a1) and a modified aliphatic polyisocyanate (a2), an episulfide (b), and a polythiol (c). 1. A polymerizable composition for an optical material including:polyisocyanate (a) including aliphatic polyisocyanate (a1) and a modified aliphatic polyisocyanate (a2);an episulfide (b); anda polythiol (c).2. The polymerizable composition for an optical material according to claim 1 ,wherein the modified aliphatic polyisocyanate (a2) is an isocyanurate of the aliphatic polyisocyanate.3. The polymerizable composition for an optical material according to claim 1 ,wherein the aliphatic polyisocyanate (a1) and/or the aliphatic polyisocyanate in the modified aliphatic polyisocyanate (a2) are obtained from plant-derived materials.5. The polymerizable composition for an optical material according to claim 1 ,wherein the episulfide (b) includes an episulfide obtained from plant-derived materials.6. The polymerizable composition for an optical material according to claim 1 ,wherein the aliphatic polyisocyanate (a1) and/or the aliphatic polyisocyanate in the modified aliphatic polyisocyanate (a2) is at least one selected from 1,5-pentamethylene diisocyanate, 1,6-hexamethylene diisocyanate, 1,7-heptamethylene diisocyanate, lysine diisocyanate, lysine triisocyanate, dimer acid diisocyanate, octamethylene diisocyanate, and decamethylene diisocyanate.7. The polymerizable composition for an optical material according to claim 1 ,wherein the polythiol (c) is at least one selected from 4-mercaptomethyl-1,8-dimercapto-3,6-dithiaoctane, 4,8 or 4,7 or 5,7-dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane, pentaerythritol tetrakis mercaptoacetate, pentaerythritol tetrakis mercaptopropionate, 2,5-bis(mercaptomethyl)-1,4-dithiane, bis(mercaptoethyl)sulfide, 1,1,3,3-tetrakis(mercaptomethylthio)propane, 4,6-bis(mercaptomethylthio)-1,3-dithiane, 2-(2,2-bis( ...

PROCESS FOR PRODUCING EPISULFIDE COMPOUND FOR OPTICAL MATERIAL, EPISULFIDE-CONTAINING COMPOSITION, AND POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL INCLUDING THE SAME COMPOSITION

A process for producing an episulfide compound for an optical material of the present invention includes a step of chlorinating glycerin to obtain dichloropropanol; a step of epoxidizing the dichloropropanol to obtain epichlorohydrin; a step of reacting the epichlorohydrin with a sulfating agent to obtain a bis(chlorohydrin) (di)sulfide compound thought a thiol compound; a step of epoxidizing the bis(chlorohydrin) (di)sulfide compound under basic conditions to obtain an epoxy compound; and a step of reacting the epoxy compound with a sulfating agent to obtain an episulfide compound represented by following General Formula (1): 2. The process for producing an episulfide compound for an optical material according to claim 1 ,wherein the glycerin is obtained from plant-derived materials.5. A polymerizable composition for an optical material comprising:{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, 'the episulfide-containing composition according to .'}6. The polymerizable composition for an optical material according to claim 5 , further comprising:a polyisocyanate (a).7. The polymerizable composition for an optical material according to claim 6 ,wherein the polyisocyanate (a) is at least one selected from hexamethylene diisocyanate, isophorone diisocyanate, bis(isocyanatomethyl)cyclohexane, dicyclohexylmethane diisocyanate, 2,5-bis(isocyanatomethyl)bicyclo-[2.2.1]-heptane, 2,6-bis(isocyanatomethyl)bicyclo-[2.2.1]-heptane, m-xylylene diisocyanate, and 2,5-bis(isocyanatomethyl)-1,4-dithiane.8. The polymerizable composition for an optical material according to claim 5 , further comprising:a polythiol (b).9. The polymerizable composition for an optical material according to claim 8 ,wherein the polythiol (b) is at least one selected from 4-mercaptomethyl-1,8-dimercapto-3,6-dithiaoctane, 4,8 or 4,7 or 5,7-dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane, pentaerythritol tetrakis mercaptoacetate, pentaerythritol tetrakis mercaptopropionate, 2,5-bis(mercaptomethyl)- ...

METHOD FOR PRODUCING POLYTHIOL COMPOUND, POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, AND USES THEREOF

Provided is a method for producing a molded product comprising preparing a polymerizable composition for optical materials and curing the polymerizable composition for optical materials to produce the molded product. The preparation of the polymerizable composition comprises preparing a polythiol compound containing, as a main component, one kind or two or more kinds selected from a defined group of compounds, and preparing the polymerizable composition from the polythiol compound. The preparation of the polythiol compound comprises reacting 2-mercaptoethanol with a defined epihalohydrin compound to obtain a defined compound, reacting the defined compound with sodium sulfide to obtain a defined polyalcohol compound, reacting the polyalcohol compound with thiourea in the presence of hydrogen chloride to obtain an isothiuronium salt, adding aqueous ammonia to a reaction solution containing the isothiuronium salt thereby hydrolyzing the isothiuronium salt to obtain the polythiol compound and purifying the polythiol compound with hydrochloric acid.

COATING MATERIAL SYSTEM BASED ON Li/Bi CATALYSTS

Disclosed herein is a coating material system containing (A) at least one polyhydroxy group-containing compound, (B) at least one polyisocyanate-containing compound, and (C) at least one catalyst comprising lithium (Li) and bismuth (Bi) as metal components and where the molar ratio of lithium to bismuth is at least 7:1 [mol/mol], in which i) components (A), (B), and (C) are present separately from one another, or ii) are mixed wholly or at least partly with one another. Methods for producing and using the coating material system are also disclosed herein. 118-. (canceled).19. A coating material system , comprising:(A) at least one polyhydroxy group-containing compound,(B) at least one polyisocyanate-containing compound, and(C) at least one catalyst comprising lithium (Li) and bismuth (Bi) as metal components and where the molar ratio of lithium to bismuth is at least 7:1 [mol/mol],wherein:i) components (A), (B), and (C) are present separately from one another, orii) are mixed wholly or at least partly with one another.20. The coating material system of claim 19 , wherein the catalyst of component (C) hasi) a molar ratio of lithium to bismuth of 7.5:1 to 12:1 [mol/mol], orii) at least one further metal component.21. The coating material system of claim 19 , wherein:i) the polyhydroxy group-containing compound of component (A) is selected from the group consisting of the polyacrylate polyols, the polymethacrylate polyols, the polyester polyols, the polyurethane polyols or the polysiloxane polyols, orii) the polyisocyanate-containing compound of component (B) is selected from the group consisting of 1,6-hexamethylene diisocyanate, isophorone diisocyanate, 4,4′-methylene dicyclohexyl diisocyanate, the biuret dimers of the aforesaid diisocyanates, the iminooxadiazinediones of the aforesaid diisocyanates or the asymmetrical trimers of the aforesaid diisocyanatesin the coating material system.22. The coating material system of claim 19 , wherein the acid number of the ...

POLYURETHANE-BASED BINDER DISPERSION

A binder dispersion includes water and polyurethane. The polyurethane is formed from polyisocyanate; polyol having two hydroxyl (OH) groups at one chain end, no OH groups at an opposed chain end, and a number average molecular weight (M) ranging from ˜500-˜5,000; an alcohol, diol or amine having a M<500; and one of i) a carboxylic acid; ii) a sulfonate or sulfonic acid having one amino group; iii) i and ii; iv) i and a homopolymer or copolymer of poly(ethylene glycol) (PEG) having one or two OH or amino groups at one chain end; v) ii and a homopolymer or copolymer of PEG having one or two OH or amino groups at one chain end; or vi) i, ii, and a homopolymer or copolymer of PEG having one or two OH or amino groups at one chain end. 1. A polyurethane-based binder dispersion , comprising: a polyurethane dispersed in the water, the polyurethane having been formed from:', 'a polyisocyanate;', 'a polyol having a chain with two hydroxyl functional groups at one end of the chain and no hydroxyl groups at an opposed end of the chain, and having a number average molecular weight ranging from about 500 to about 5,000;', 'an alcohol or a diol or an amine having a number average molecular weight less than 500; and one of', 'i) a carboxylic acid;', 'ii) a sulfonate or sulfonic acid having one amino functional group;', 'iii) a combination of i and ii;', 'iv) a combination of i and a homopolymer or copolymer of poly(ethylene glycol) having one or two hydroxyl functional groups or one or two amino functional groups at one end of its chain;', 'v) a combination of ii and a homopolymer or copolymer of poly(ethylene glycol) having one or two hydroxyl functional groups or one or two amino functional groups at one end of its chain; or', 'vi) a combination of i, ii, and a homopolymer or copolymer of poly(ethylene glycol) having one or two hydroxyl functional groups or one or two amino functional groups at one end of its chain., 'water; and'}2. The polyurethane-based binder dispersion as ...

METHOD FOR PRODUCING POLYTHIOL COMPOUND FOR OPTICAL MATERIALS AND COMPOSITION COMPRISING SAME FOR OPTICAL MATERIALS

The present invention relates to a polythiol compound for a high quality optical material that exhibits excellent physical properties in terms of color, a composition for an optical material including the polythiol compound, a method for producing an optical material, and a method for preparing the polythiol compound. The method includes reacting an epichlorohydrin compound containing 0.5% by weight or less of impurities with 2-mercaptoethanol. The polythiol compound is prevented from being colored. The polythiol compound can be used to produce a urethane optical material that is prevented from being colored and has a low yellowness index and a good color. The polythiol compound can be used to produce various optical materials including urethane optical materials. The optical material can be used to manufacture an optical lens having a good color. The optical lens can be used as a spectacle lens, a polarizing lens, a camera lens, or the like. 1. A method for preparing a polythiol compound , comprising reacting an epichlorohydrin compound with 2-mercaptoethanol ,wherein the epichlorohydrin compound contains 0.5% by weight or less of impurities comprising acrolein, allyl chloride, 1,2-dichloropropane, 2,3-dichloropropene, 2-methyl-2-pentanol, 2-chloroallyl alcohol, cis-1,3-dichloropropene, trans-1,3-dichloropropene, 1,3-dichloroisopropanol, 1,2,3-trichloropropane and 2,3-dichloropropanol.2. A composition for an optical material comprising a polythiol compound prepared by the method according to .3. The composition according to claim 2 , further comprising a polyisocyanate compound.4. The composition according to claim 3 , wherein the polyisocyanate compound is selected from the group consisting of isophorone diisocyanate (IPDI) claim 3 , hexamethylene diisocyanate (HDI) claim 3 , dicyclohexyl methanediisocyanate (H12MDI) claim 3 , xylylene diisocyanate (XDI) claim 3 , 3 claim 3 ,8-bis(isocyanatomethyl)tricyclo[5 claim 3 ,2 claim 3 ,1 claim 3 ,02 claim 3 ,6]decane ...

Multifunctional sulfur-containing polymers, compositions thereof and methods of use

Disclosed are multifunctional sulfur-containing polymers that are the reaction products of a sulfur-containing diol, a polyol containing at least three hydroxyl groups per polyol molecule, and an aldehyde, a ketone, or a combination thereof. Sealant compositions comprising the multifunctional sulfur-containing polymers are also disclosed.

Method For Providing Surface Modifying Composition With Improved Byproduct Removal

A method forming a surface modifying composition with reduced need for organic solvent and evaporation thereof for removal of insoluble reaction byproducts from the composition. The purified composition can be used in the formation of articles having improved biocompatibility, such as medical articles (e.g., spun hollow fiber). 1. A method comprising:forming a first solution by phase transitioning at least a portion of a surface modifying composition to a liquid state, the surface modifying composition comprising:a) at least one polymer or oligomer, andb) an insoluble reaction byproduct of i) a fluorotelomer alcohol and ii) an isocyanate, wherein said insoluble reaction byproduct is substantially insoluble in said polymer or oligomer; andremoving from the first solution at least a portion of said insoluble reaction byproduct present in the first solution to obtain a second solution;wherein said polymer or oligomer comprises a polymer or oligomer backbone covalently attached to at least one surface active group.2. The method of claim 1 , wherein said first solution is formed by dissolving at least a portion of said surface modifying composition in at least one solvent.3. The method of claim 1 , wherein said first solution is formed by melting said polymer or oligomer of said surface modifying composition.4. The method of claim 1 , wherein the insoluble reaction byproduct is fluorotelomer alcohol end capped di-isocyanate.5. The method of claim 1 , wherein the fluorotelomer alcohol (FTOH) is 4:2 FTOH claim 1 , 5:2 FTOH claim 1 , 6:2 FTOH claim 1 , 7:2 FTOH claim 1 , 8:2 FTOH claim 1 , 9:2 FTOH claim 1 , 10:2 FTOH claim 1 , or a combination thereof.6. The method of claim 1 , wherein the fluorotelomer alcohol is 6:2 fluorotelomer alcohol.7. The method of claim 1 , wherein the isocyanate has two or more isocyanate functional groups.8. The method of claim 1 , wherein the isocyanate is di-isocyanate claim 1 , tri-isocyanate claim 1 , or a combination thereof.9. The method ...

POLYMERIZABLE COMPOSITION

A polymerizable composition comprising 1. A polymerizable composition comprising:a) at least one cyclic amide,b) 2.8 to 3.5% by weight of at least one blocked polyisocyanate, andc) 1.2 to 1.4% by weight of at least one catalyst for the polymerization of the cyclic amide,where the ratio by weight of components b) to c) is 2.0 to 2.9, and the % by weight data are always based on the entirety of components a) to c).3. The polymerizable composition as claimed in claim 1 , wherein the cyclic amide is laurolactam claim 1 , caprolactam claim 1 , or a mixture of these.4. The polymerizable composition as claimed in claim 1 , wherein component b) comprises at least HDI as blocked isocyanate.5. The polymerizable composition as claimed in claim 1 , wherein the at least one catalyst c) is selected from the group consisting of sodium caprotactamate claim 1 , potassium caprolactamate claim 1 , magnesium bromide caprolactamate claim 1 , magnesium chloride caprolactamate claim 1 , magnesium biscaprolactamate claim 1 , sodium hydride claim 1 , sodium claim 1 , sodium hydroxide claim 1 , sodium methanolate claim 1 , sodium ethanolate claim 1 , sodium propanolate claim 1 , sodium butanolate claim 1 , potassium hydride claim 1 , potassium hydroxide claim 1 , potassium methanolate claim 1 , potassium ethanolate claim 1 , potassium propanolate and potassium butanolate claim 1 , preferably from the group consisting of sodium hydride claim 1 , sodium and sodium caprolactamate claim 1 , particularly preferably sodium caprolactamate.6. A process for the production of the polymerizable composition as claimed in claim 1 , the process comprising contacting the cyclic amide with the at least one blocked polyisocyanate and the at least one catalyst.7. A process for the production of a fiber composite material claim 1 , the process comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'ia) contacting the polymer table composition as claimed in , with fibers to produce a fibered composition, ...

Use of polymerizable ultraviolet absorber in polyurethane and composition for preparing polyurethane comprising the same

A use of a polymerizable ultraviolet absorber is disclosed, which is applied to a polyurethane preparation. The polymerizable ultraviolet absorber is obtained by reacting an UV absorber having a reactive hydrogen group with a polyisocyanate having three —NCO groups. In addition, a composition for forming polyurethane comprising the aforementioned polymerizable ultraviolet absorber is also disclosed. 1. A use of a polymerizable ultraviolet absorber , which is applied to a process for preparing polyurethane , wherein the polymerizable ultraviolet absorber is obtained by reacting an UV absorber having a reactive hydrogen group with a polyisocyanate having three —NCO groups.2. The use of claim 1 , wherein a weight average molecular weight of the polymerizable ultraviolet absorber is less than 5 claim 1 ,000.3. The use of claim 1 , wherein the reactive hydrogen group as a functional group comprised in the UV absorber is selected from the group consisting of —OH claim 1 , —NHand —NH—.4. The use of claim 1 , wherein the UV absorber is selected from the group consisting of: a benzotriazole UV absorber claim 1 , a benzophenone UV absorber claim 1 , a triazine UV absorber claim 1 , an oxanilide UV absorber and a cyanoacrylate UV absorber.5. The use of claim 1 , wherein the polyisocyanate is selected from the group consisting of: hexamethylene diisocyanate trimer (HDI TRIMER) claim 1 , hexamethylene diisocyanate biuret (HDB) and a mixture thereof.6. The use of claim 1 , wherein the polymerizable ultraviolet absorber is obtained by reacting the UV absorber having the reactive hydrogen group with the polyisocyanate having the three —NCO groups and a diol or a polyol.7. The use of claim 6 , wherein the diol or the polyol is selected from the group consisting of an anionic diol claim 6 , an anionic polyol claim 6 , a cationic diol claim 6 , a cationic polyol claim 6 , a nonionic diol claim 6 , a nonionic polyol claim 6 , and a mixture thereof.8. The use of claim 7 , wherein the ...

METHOD FOR PRODUCING ORGANIC MERCAPTO COMPOUND OR INTERMEDIATE THEREOF, (POLY)THIOL COMPONENT, POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, MOLDED PRODUCT, OPTICAL MATERIAL, AND LENS

A method for producing an organic mercapto compound or an intermediate thereof according to the present invention has a reaction step of reacting an alcohol compound including a sulfur atom with a thioamide compound having a structure in which an organic group is bonded to at least one bonding hand of a thioamide group, under acidic conditions. 1. A method for producing an organic mercapto compound or an intermediate thereof , comprising:a reaction step of reacting an alcohol compound including a sulfur atom with a thioamide compound having a structure in which an organic group is bonded to at least one bonding hand of a thioamide group, under acidic conditions.2. The method for producing an organic mercapto compound or an intermediate thereof according to claim 1 ,{'sup': '2', 'wherein a topological polar surface area of the thioamide compound is 10.00 to 51.00 Å.'}4. The method for producing an organic mercapto compound or an intermediate thereof according to claim 3 ,{'sup': '1', 'wherein, in the compound represented by General Formula (2), Ris a monovalent aryl group having 6 to 10 carbon atoms, which optionally be substituted, a monovalent aliphatic group having 1 to 10 carbon atoms, which optionally be substituted, or a monovalent heteroaryl group having 3 to 10 carbon atoms, which optionally be substituted, and substituents of these groups optionally include a hetero atom, and'}{'sup': 2', '3', '2', '3, 'Rand Rare hydrogen atoms or Rand Rare bonded to each other to form a nitrogen-containing heterocyclic ring having 3 to 10 carbon atoms.'}5. The method for producing an organic mercapto compound or an intermediate thereof according to claim 1 , {'br': None, 'sup': '1', 'sub': 'n', 'Q\ue8a0OH\u2003\u2003(1)'}, 'wherein the alcohol compound is represented by General Formula (1),'}{'sup': '1', 'wherein in Formula (1), Qis an n-valent organic group including a sulfur atom and having 1 to 30 carbon atoms, and n is an integer of 1 to 10.'}7. The method for producing ...

CHEMICALLY MODIFIED SHAPE MEMORY POLYMER EMBOLIC FOAMS WITH INCREASED X-RAY VISUALIZATION

An embodiment includes a system comprising: an iodine containing thermoset open-cell shape memory polymer (SMP) foam that is x-ray visible; wherein (a) the SMP foam is configured to expand from a compressed secondary state to an expanded primary state in response to thermal stimulus, (b) the SMP foam is a poly(urethane-urea-amide). Other embodiments are described herein. 1. A system comprising:a thermoset shape memory polymer (SMP) foam that is covalently bonded to iodine;wherein (a) the SMP foam is configured to expand from a compressed secondary state to an expanded primary state in response to thermal stimulus, and (b) the SMP foam is a poly(urethane-urea-amide).2. The system of wherein the SMP foam is radiopaque.3. The system of wherein the iodine is included in a triiodobenzene monomer.4. The system of wherein the triiodobenzene monomer includes at least one of (a) 5-amino-2 claim 3 ,4 claim 3 ,6-triiodoisophthalic acid (ATIPA) claim 3 , (b) diatrizoic acid claim 3 , (c) iohexol claim 3 , (d) triiodophenol claim 3 , or (e) combinations thereof.5. The system of wherein the triiodobenzene monomer includes ATIPA.6. The system of wherein the ATIPA crosslinks polymer chains of the SMP foam.7. The system of wherein the SMP foam includes at least one of platinum claim 4 , tungsten claim 4 , tantalum claim 4 , or combinations thereof claim 4 , the at least one of platinum claim 4 , tungsten claim 4 , tantalum claim 4 , or combinations thereof being physically bound within the SMP foam.8. The system of wherein the at least one of platinum claim 7 , tungsten claim 7 , tantalum claim 7 , or combinations thereof is not chemically bound to the SMP foam.9. The system of comprising a backbone that traverses the SMP foam claim 4 , wherein the backbone includes at least one of a polymer filament claim 4 , a metal claim 4 , or combinations thereof.10. The system of wherein the backbone includes a polymer filament and no metal.11. A method comprising:providing a triiodobenzene ...

Polymerizable composition for optical materials and application of same

The polymerizable composition for optical materials of the present invention includes a polyester polyol (a), a compound (b) of which light absorption characteristics vary by sensing changes in environment; and a polymerization reactive compound (c).

Magnetic Flooring System Adhesive Composition

A liquid adhesive coating composition that cures into a solid form, used to non-permanently adhere interior floor or wall coverings to substrate floor or wall surfaces respectively, includes a polymer incorporating iron or other paramagnetic, superparamagnetic, ferromagnetic, or ferrimagnetic ingredients, that becomes permanently adhered to the substrate as it cures, and thereafter provides a low-tack adhesive surface that is also magnetically attractive, upon which magnetized floor or wall coverings including certain types of carpet, linoleum, vinyl, wallpaper, and other types of magnetically-backed coverings can be subsequently installed. The combined low-tack adhesive and magnetic adhesion qualities of the cured composition of the invention allow for the magnetically-backed floor or wall coverings to be sufficiently well adhered to the surface of the cured adhesive composition to remain in place during normal usage while retaining the ability for the coverings to be subsequently removed, repositioned or replaced without damaging the respective coverings, adhesive coating composition layer, or substrate. 1. A composition comprising:(a) an adhesive; and(b) magnetic and/or magnetizable particles mixed into the adhesive, the particles having a minimum diameter of greater than 100 nm.2. The composition as claimed in claim 1 , wherein the particles comprise between about 30% and about 80% by weight of the total composition.3. The composition as claimed in claim 2 , wherein the particles comprise about 67% by weight of the total composition.4. The composition as claimed in claim 1 , wherein the adhesive comprises an ambient temperature cured adhesive.5. The composition as claimed in claim 1 , wherein the adhesive comprises a moisture cured adhesive.6. The composition as claimed in claim 1 , wherein the adhesive comprises a polymer based adhesive.7. The composition as claimed in claim 1 , wherein the adhesive comprises a hot melt curing adhesive.8. The composition as ...

WATERPROOF ADHESIVE COMPOSITIONS

Waterproof urethane-based adhesive compositions are described herein. Silane is reacted with prepolymer urethane to at least partially end-cap the urethane. A reinforcing extender, a thixotropic agent, a magnetic agent, a first catalyst, and methylethylketoximino (MEKO) silane are also added to the composition to form the deactivated adhesive composition. Prior to coating a substrate with the adhesive, a second catalyst is added. The second catalyst speeds up the curing time and improves the shelf life of the moisture cure adhesive. The adhesive is cured to a final product that is waterproof, hydrolytically stable, and pH resistant. 1) A polymeric matrix adhesive composition , said composition comprising:a) a silane end-capped polymer component comprising a first silane and a urethane component, wherein the urethane component comprises a flexible binder urethane prepolymer, a slow-cure urethane, or both;b) a first catalyst;c) a second catalyst;d) a reinforcing extender;e) one or more thixotropic agents; and wherein the second catalyst is added to the composition immediately before coating a substrate,', 'wherein a cured product of the composition is waterproof, hydrolytically stable, and pH-resistant., 'f) an anti-skinning agent;'}2) The composition of wherein the composition further comprises a quenching agent claim 1 , a tackifier claim 1 , one or more moisture scavengers claim 1 , a magnetic agent claim 1 , and a pigment.3) The composition of wherein the silane end-capped polymer component comprises a slow-cure urethane having a functionality (Fn) of about 2.5 to 2.55 and an NCO content of about 15 to 23% claim 1 , or ii) a flexible binder urethane having a functionality (Fn) of about 2 and an NCO content of about 7 to 10%.4) The composition of claim 1 , comprising about 0-60 wt % of the silane end-capped polymer component claim 1 , about 0.05-0.08 wt % of the first catalyst claim 1 , about 1-2% of the second catalyst claim 1 , about 20-40 wt % of the reinforcing ...

COMPOSITIONS, METHOD OF BONDING, AND BONDED ASSEMBLY

A two-part curable composition comprises a Part A and a Part B. Part A composition includes uretdione-containing compound having an average uretdione ring functionality of at least 1.2. Part B composition includes polythiol having an average sulfhydryl group functionality of at least 2. At least one of the Part A composition and the Part B composition may further comprise accelerator for addition of the polythiol to the uretdione-containing compound. The accelerator comprises a nonacidic amine curative. The amine curative does not comprise a substituted or unsubstituted amidine group. Cured compositions, methods of making them and articles including them are also disclosed. A two-part composition without accelerator is disclosed wherein the uretdione-containing compound has at least one pendant —CHNRgroups, wherein each Rindependently represents an alkyl group having from 1 to 8 carbon atoms, or two Rgroups taken together form an alkylene group having from 2 to 8 carbon atoms. 122-. (canceled)23. A two-part curable composition comprising:a Part A composition comprising at least one uretdione-containing compound, the at least one uretdione-containing compound having an average uretdione ring functionality of at least 1.2, and wherein the at least one uretdione-containing compound has an average isocyanate functionality of less than 0.01;a Part B composition comprising at least one thiol-containing compound, the at least one thiol-containing compound having an average sulfhydryl group functionality of at least 2; and{'sup': 1', '2', '3, 'claim-text': [{'sup': '1', 'Rrepresents H or a monovalent organic group having from 1 to 18 carbon atoms;'}, {'sup': '2', 'Rrepresents H or a monovalent organic group having from 1 to 18 carbon atoms;'}, {'sup': '3', 'Rrepresents a monovalent organic group having from 2 to 18 carbon atoms; or'}, {'sup': 2', '3, 'Rand Rtaken together represent a divalent organic group having from 2 to 18 carbon atoms, or'}, {'sup': 1', '2', '3, 'R, R, ...

METHOD FOR PRODUCING POLYTHIOL COMPOUND, POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, AND USES THEREOF

Provided is a method for producing a molded product comprising a step for preparing a polymerizable composition for optical materials and a step for curing the polymerizable composition for optical materials to produce the molded product. The step for preparing the polymerizable composition for optical materials comprises a step for preparing a defined polythiol compound and a step for preparing the polymerizable composition for optical materials from the polythiol compound. The step for preparing the defined polythiol compound comprises reacting 2-mercaptoethanol with a defined epihalohydrin compound at a temperature of 10° C. to 50° C. to obtain a defined polyalcohol compound, reacting the polyalcohol compound with thiourea in the presence of hydrogen chloride to obtain an isothiuronium salt, hydrolyzing the isothiuronium salt to obtain the polythiol compound, adding hydrochloric acid at a defined concentration to a solution of the polythiol compound, and washing the solution to purify the polythiol compound. 3. The method for producing a molded product according to claim 1 ,wherein the polymerizable composition for optical materials further comprises a polyiso(thio)cyanate compound.4. The method for producing a molded product according to claim 2 ,wherein the polymerizable composition for optical materials further comprises a polyiso(thio)cyanate compound. The present invention relates to a method for producing a polythiol compound, a polymerizable composition for optical materials, and uses thereof.Plastic lenses are lightweight, not easily breakable and tintable as compared with inorganic lenses. Therefore, in recent years, plastic lenses have rapidly been in wide use in optical devices such as spectacle lenses and camera lenses.It has become necessary for resins for plastic lenses to have more enhanced performances, and there have been demands for an increase in the refractive index, an increase in the Abbe number, a decrease in specific gravity, an increase ...

WATER DISPERSION OF GEL PARTICLES, PRODUCING METHOD THEREOF, AND IMAGE FORMING METHOD

A water dispersion of gel particles, a method of producing the water dispersion, and an image forming method using the water dispersion. The gel particles have a three-dimensional crosslinked structure including a structural unit represented by Formula (1) and a urea bond, have a hydrophilic group and a polymerizable group, include photopolymerization initiators and are dispersed in water. In Formula (1), Rrepresents H or an alkyl group; Xrepresents hydrogen, halogen, a hydroxyl group, an alkyl group, a cyano group, a lactam group, a —C(═O)XRgroup, an —OC(═O)Rgroup, or an aryl group; Xrepresents oxygen or an —N(R)— group; Rand Rrepresent a hydrocarbon group that may contain a hetero atom or H; Rand Rmay be bonded to each other to form a ring, and Rrepresents a hydrocarbon group that may contain a hetero atom. 2. The water dispersion of gel particles according to claim 1 ,wherein, in Formula (1),{'sup': '1', 'Ris a hydrogen atom or an alkyl group having 1 to 6 carbon atoms,'}{'sup': 1', '2', '2', '3, 'Xis a hydrogen atom, a halogen atom, a hydroxyl group, an alkyl group having 1 to 6 carbon atoms, a cyano group, a lactam group, a —C(═O)XRgroup, an —OC(═O)Rgroup, or an aryl group,'}{'sup': 2', 'X2, 'Xis an oxygen atom or an —N(R)— group,'}{'sup': 'X2', 'Ris a hydrogen atom or an alkyl group having 1 to 6 carbon atoms,'}{'sup': '2', 'Ris a hydrogen atom, an alkyl group having 1 to 30 carbon atoms, an alkoxyalkyl group having 2 to 30 carbon atoms, a polyalkoxyalkyl group having 3 to 30 carbon atoms, an aryloxyalkyl group having 7 to 30 carbon atoms, an aminoalkyl group having 1 to 30 carbon atoms, a monoalkylaminoalkyl group having 2 to 30 carbon atoms, or a dialkylaminoalkyl group having 3 to 30 carbon atoms, and'}{'sup': '3', 'Ris an alkyl group having 1 to 6 carbon atoms.'}3. The water dispersion of gel particles according to claim 1 ,{'sup': 1', '2', '2, 'wherein Xin Formula (1) is a —C(═O)XRgroup.'}5. The water dispersion of gel particles according to claim 4 , ...

PROCESS FOR PRODUCING POROUS MATERIALS

The present invention relates to a process for preparing a porous material, at least comprising the steps of providing a mixture (I) comprising a composition (A) comprising components suitable to form an organic gel and a solvent (B), reacting the components in the composition (A) in the presence of the solvent (B) to form a gel, and drying of the gel obtained in step b), wherein the composition (A) comprises at least one compound (af) comprising phosphorous and at least one functional group which is reactive towards isocyanates. The invention further relates to the porous materials which can be obtained in this way and the use of the porous materials as thermal insulation material and in vacuum insulation panels, in particular in interior or exterior thermal insulation systems as well as in water tank or ice maker insulation systems. 1. A process for preparing a porous material , the process comprising:reacting a composition (A) comprising a compound (af) comprising phosphorous and a functional group which is reactive towards isocyanates, in the presence of a solvent (B), to form a gel; anddrying the gel;wherein compound (af) is present in an amount which results in a phosphorous content in the porous material in a range of from 1 to 5% by weight.2. The process of claim 1 , wherein the compound (af) comprises a functional group comprising phosphorous.3. The process of claim 2 , wherein the compound (af) comprises at least one functional group comprising the phosphorous selected from the group consisting of a phosphate claim 2 , a phosphonate claim 2 , a phosphinate claim 2 , a phosphite claim 2 , a phosphonite claim 2 , a phosphinite claim 2 , and a phosphine oxide.4. The process of claim 1 , wherein the composition (A) comprises at catalyst system (CS) comprising a catalyst component (C1) selected from the group consisting of an alkali metal of a saturated monocarboxylic acid claim 1 , an alkali metal salt of an unsaturated monocarboxylic acid claim 1 , an earth ...

FUNCTIONAL EYEGLASS LENS FOR BLOCKING ULTRAVIOLET AND BLUE LIGHT

The disclosure provides an eyeglass lens for blocking ultraviolet and blue light comprising a mixture of: a polymerization initiator which reacts with a monomer, which is a raw material of a plastic lens whose refractive index varies depending on physical properties, and which converts the monomer into a polymer; an ultraviolet absorber for absorbing ultraviolet from a plastic lens mixed with the monomer to then be converted into a polymer; and a transparent material for making the plastic lens, which was mixed with the monomer and converted into a polymer, transparent by minimizing a phenomenon in which the plastic lens appears yellow, wherein the ultraviolet absorber comprises a mixture of any one or more of UV-A, UV-B and UV-C which are benzotriazole-based ultraviolet absorbers having different molecular weights, and the transparent material is a mixture of a blue dye, showing blue color, and a red dye, showing red color. 14-. (canceled)5. A functional eyeglass lens for blocking ultraviolet and blue light comprising:a monomer comprising a raw material of a plastic lens whose refractive index varies depending on physical properties,a polymerization initiator that reacts with the monomer to covert it into a polymer,an ultraviolet absorber for absorbing ultraviolet radiation from a plastic lens, wherein the absorber is mixed with the monomer to be converted into a polymer and is composed of a mixture of one or more of a benzotriazole-based UV-A ultraviolet absorber having a molecular weight of 250-330 g/mol, a benzotriazole-based UV-B ultraviolet absorber having a molecular weight of 300-320 g/mol, and a benzotriazole-based UV-C ultraviolet absorber having a molecular weight of 430-450 g/mol, anda transparent material for making the plastic lens comprising a mixture of a blue dye and a red dye, wherein the transparent material is mixed with the monomer to be converted into a polymer, and wherein the transparent material minimizes a phenomenon in which the plastic ...

MAGNETIC FLOOR SURFACE

The present invention is directed to a method for providing a surface, in particular a floor surface, with a layer of a magnetic and/or magnetizable cover composition, the surface having at least one layer of cementitious material, wherein the method comprises the step of spreading the layer of the cover composition onto the surface, the cover composition comprising a polymeric binder and magnetic and/or magnetizable particles, characterized in that the layer of the cover composition has a water vapor transmission rate of at least 0.25 g hmaccording to ASTM D1653,and the surface and/ or the layer of cementitious material has a relative humidity of more than 75% according to ASTM F 2170-11. 1. A floor surface comprising at least one layer of cementitious material bearing a layer of a cover composition comprising a polymeric binder and magnetic and/or magnetizable particles , wherein the polymeric binder is prepared from a precursor composition comprising at least a polyisocyanate component and an amine-group containing component.2. The floor surface of claim 1 , wherein the polymeric binder further comprises a polyol component.3. The floor surface of claim 2 , wherein the polymeric binder further comprises one or more catalysts.4. The floor surface of claim 1 , wherein the polymeric binder further comprises a material selected from fillers claim 1 , extenders claim 1 , pigments or combinations thereof.5. The floor surface of claim 1 , wherein the polyisocyanate component has an average NCO-functionality of 1.5 to 4.6. The floor surface of claim 5 , wherein the polyisocyanate component comprises a polyisocyanate prepolymer derived from or blended with an uretdione claim 5 , a biuret or an isocyanurate of hexamethylene di-isocyanate (HDI) or any combination thereof.7. The floor surface of claim 6 , wherein the polyisocyanate prepolymer has an isocyanate content of 5-15% by weight.8. The floor surface of claim 5 , wherein the polyisocyanate component comprises a ...

COMPOSITIONS, METHOD OF BONDING, AND ASSEMBLY

A two-part curable composition comprises a Part A and a Part B. The Part A composition includes polyuretdione having an average uretdione ring functionality of at least 1.2. Part B composition includes polythiol having an average sulfhydryl group functionality of at least 1.2. At least one of the Part A composition and the Part B composition may further comprise accelerator for addition of the polythiol to the polyuretdione. The accelerator comprises a basic salt having the formula M+Zb−x y wherein M+ is a cation having a single positive charge a, wherein a is 1, 2, or 3; Zb− is an oxide anion having a negative charge b−, wherein b is 1 or 2; and x and y are positive integers, wherein x equals y times b. Cured compositions, methods of making them and articles including them are also disclosed. 126-. (canceled)27. A two-part curable composition comprising:a Part A composition comprising at least one polyuretdione, the at least one polyuretdione having an average uretdione ring functionality of at least 1.2, wherein the at least one polyuretdione has an average isocyanate functionality of less than 0.01;a Part B composition comprising at least one polythiol, the at least one polythiol having an average sulfhydryl group functionality of at least 1.2; and [{'br': None, 'sup': +', 'b−, 'sub': x', 'y, 'MZ'}, [{'sup': '+', 'M is a cation having a single positive charge;'}, {'sup': b−', '−, 'Z is an oxide anion having a negative charge b, wherein b is 1 or 2; and'}, 'x and y are positive integers, wherein x equals y times b., 'wherein'}], 'wherein at least one of the Part A composition and the Part B composition further comprises at least one accelerator for ring-opening addition of the at least one polythiol to the at least one polyuretdione, and wherein the at least one accelerator comprises a basic salt having the formula'}28. The two-part curable composition of claim 27 , wherein M is selected from lithium claim 27 , sodium claim 27 , potassium claim 27 , cesium claim ...

New systems for priming and adhesion of flooring

The invention relates to layer structures containing polyaspartic primers (AG) and curable compositions based on silane-modified polymers (KS), and to a method for adhesion of flooring onto pre-treated substructures.

COMPOSITION CONTAINING AROMATIC NITRILES FOR THE PRODUCTION OF TRANSPARENT POLYTHIOURETHANE BODIES

The invention relates to a composition for producing transparent polythiourethane bodies, containing or consisting of A) a polyisocyanate component that contains at least one polyisocyanate having an isocyanate group functionality of at least 2 per molecule, B) a thiol component that contains at least one polythiol having a thiol group functionality of at least 2 per molecule, and if appropriate, C) auxiliary and additional agents, the ratio of isocyanate groups to groups that are reactive to isocyanates being between 0.5:1 to 2.0:1, and said composition being characterised in that it also contains D) at least one aromatic nitrile. The invention also relates to a method for producing transparent polythiourethane bodies by reacting such a composition, to the polythiourethane bodies produced in this manner, to the use of aromatic nitriles for producing transparent polythiourethane bodies, and to a mixture of a polyisocyanate and an aromatic nitrile. 115.-. (canceled)16. A composition for producing transparent polythiourethane articles comprisingA) a polyisocyanate component containing at least one polyisocyanate having a functionality of isocyanate groups of at least 2 per molecule,B) a thiol component containing at least one polythiol having a functionality of thiol groups of at least 2 per moleculeand optionallyC) auxiliary and additive agents,wherein the ratio of isocyanate groups to isocyanate-reactive groups is 0.5:1 to 2.0:1,whereinthe composition further containsD) at least one aromatic nitrile.17. The composition as claimed in claim 16 , wherein the composition contains 0.0025 to 10 wt % based on the entire composition of aromatic nitrile.18. The composition as claimed in claim 16 , wherein the nitrile contains at least one further functional group claim 16 , in particular an isocyanate group.19. The composition as claimed in claim 16 , wherein the nitrile is selected from the group consisting of benzonitrile claim 16 , 3-(isocyanatomethyl)benzonitrile claim ...

Polymerizable composition for optical materials, optical material, and method of manufacturing optical material

The polymerizable composition for optical materials of the present invention includes: (A) a compound having a carbon-carbon double bond and at least one group selected from an isocyanate group and an isothiocyanate group in a molecule; and (B) a polythiol compound.

URETHANE ADHESIVE CORD TREATMENT FOR POWER TRANSMISSION BELT AND BELT

A belt with a tensile cord embedded in an elastomeric body, having an adhesive composition impregnating the cord and coating the fibers. The adhesive composition is the reaction product of a polyisocyanate and a polyol, or a polyurethane prepolymer derived therefrom, and a polyamine curative and optionally additional polyol, and with optionally added plasticizer. At least one of the polyisocyanate, the prepolymer, and the polyamine are blocked with a blocking agent. The belt body may be of cast polyurethane, vulcanized rubber, or thermoplastic elastomer. The cord may have an adhesive overcoat. 2. The belt of wherein said adhesive composition is further a reaction product of a second polyol claim 1 , or an oligomeric polyamine.3. The belt of wherein said adhesive composition further comprises a plasticizer.4. The belt of wherein said plasticizer is at least one selected from the group consisting of phthalates claim 3 , organo-phosphates claim 3 , dialkyl-ether di-alkylesters and polyalkylene-ether di-alkylesters.5. The belt of wherein said at least one of said polyurethane prepolymer claim 1 , said polyisocyanate claim 1 , and said curative is blocked curative complex 4 claim 1 ,4′-methylenebisdianiline-NaCl.6. The belt of wherein said polyurethane prepolymer is blocked with at least one said blocking agent selected from the group consisting of 3 claim 1 ,5-dimethylpyrazole (“DMP”) claim 1 , diethylmalonate (“DEM”) claim 1 , ε-caprolactam (“CAP”) claim 1 , and methyl ethyl ketoxime (“MEKO”).7. The belt of wherein said blocking agent is DMP.8. The belt of wherein said blocking agent is MEKO.9. The belt of wherein said tensile cord comprises carbon fiber.10. A method of preparing a belt comprising a reinforced elastomeric body claim 1 , said method comprising:providing a tensile cord impregnated with an adhesive composition comprising the reaction product of;a polyisocyanate and a first polyol or a polyurethane prepolymer comprising said polyisocyanate and said first ...

Recycling and reuse of sulfonated polymer material in additive manufacturing

A method of recycling and reusing a tap water-soluble sulfonated polymer material from a structural component made using an additive manufacturing process comprises dissolving the structural component in water to disperse the sulfonated polymer material into the water. The sulfonated polymer material is precipitated from the water and recovered; then dried and reformed into a form suitable for subsequent use as a consumable feedstock in a subsequent additive manufacturing process.

SPRAY FOAMS CONTAINING NON-HALOGENATED FIRE RETARDANTS

A spray foam formulation used to form a spray foam insulation layer in a wall structure is described. The formulation may include the reaction product of a polyisocyanate compound and a polyol compound; a fire retardant chosen from at least one of a non-halogenated fire retardant; and a reactive halogen-containing fire retardant, and a carbohydrate. The spray foam insulation layer has an insulative R value of 3.0 to 7.2 per inch, and a density of between about 0.3 to about 4.5 pcf. Further, spray foam insulation made from the spray foam formulation may have fire retardant characteristics that are equivalent to or better than a similar spray insulation foam insulation using non-reactive halogenated fire retardants such as tris(1-chloro-2-propyl)phosphate (TCPP). 1. A spray foam formulation used in an insulation layer in a wall structure , the spray foam formulation comprising:a reaction product of a polyisocyanate compound and a polyol compound;a fire retardant chosen from at least one of a non-halogenated fire retardant, and a reactive halogen-containing fire retardant; anda carbohydrate,wherein the insulation layer has an insulative R value of 3.0 to 7.2 per inch, and a density of between about 0.3 to about 4.5 pcf, andwherein the insulation layer exhibits an Appendix X and an ASTM E-84 performance equivalent with or better than a similar spray insulation layer having a non-reactive halogenated fire retardant tris(1-chloro-2-propyl)phosphate (TCPP).2. The spray foam formulation of claim 1 , wherein the insulation layer is an open cell insulation layer having a density between about 0.3-0.7 pcf.3. The spray foam formulation of claim 1 , wherein the insulation layer is a closed cell insulation layer having a density between about 2.0-4.0 pcf.4. The spray foam formulation of claim 1 , wherein the non-halogenated fire retardant comprises diethyl hydroxymethylphosphonate.5. The spray foam formulation of claim 1 , wherein the non-halogenated fire retardant comprises at ...

PROCESS FOR PRODUCING A PHOTOCHROMIC CURED BODY

A process for producing a photochromic cured body by curing a photochromic composition comprising (A) a polyiso(thio)cyanate compound having at least two isocyanate groups and/or isothiocyanate groups in one molecule, a poly(thi)ol compound having at least two hydroxyl groups and/or thiol groups in one molecule, (C) a mono(thi)ol compound having one hydroxy group or thiol group in one molecule, and a photochromic compound. 1. A process for producing a photochromic cured body by curing a photochromic composition comprising (A) a polyiso(thio)cyanate compound having at least two isocyanate groups and/or isothiocyanate groups in one molecule , (B) a poly(thi)ol compound having at least two hydroxyl groups and/or thiol groups in one molecule , (C) a mono(thi)ol compound having one hydroxy group or thiol group in one molecule , and (D) a photochromic compound.2. The process for producing a photochromic cured body according to claim 1 , wherein the photochromic composition comprises a mixture of a premixture of the component (A) and the component (D) and a premixture of the component (B) and the component (C) claim 1 , or a mixture of a premixture of the component (B) claim 1 , the component (C) and the component (D) claim 1 , and the component (A).3. The process for producing a photochromic cured body according to claim 1 , wherein the photochromic composition comprises 2 to 40 parts by mass of the component (C) based on 100 parts by mass of the total of the components (A) claim 1 , (B) and (C).4. The process for producing a photochromic cured body according to claim 1 , wherein the photochromic composition further comprises (E) a polyrotaxane having a composite molecular structure composed of an axial molecule and a plurality of cyclic molecules clathrating the axial molecule.5. The process for producing a photochromic cured body according to claim 4 , wherein the cyclic molecules of the polyrotaxane are cyclodextrin rings.6. The process for producing a photochromic ...

MEDICAL ADHESIVES FOR STOPPING HEAVY BLEEDING AND SEALING LEAKAGES

The present invention relates to a method that includes providing a formulation having an isocyanate-functional prepolymer and a curing component comprising an amino-functional aspartic ester of the general formula (I) 110.-. (canceled)12. The formulation according to claim 11 , wherein the curing component further comprises organic fillers which have a viscosity as measured to DIN 53019 at 23° C. in the range of from 10 to 6000 mPas.13. The formulation according to claim 12 , wherein the formulation further comprises reaction products of the isocyanate-functional prepolymer with the organic fillers.14. The formulation according to claim 11 , wherein the formulation further comprises reaction products of the isocyanate-functional prepolymer with the amino-functional aspartic ester.15. The formulation according to claim 14 , wherein the formulation further comprises reaction products of the isocyanate-functional prepolymer with organic fillers.16. The formulation according to claim 11 , wherein the curing component further comprises organic fillers which have a viscosity as measured to DIN 53019 at 23° C. in the range of from 10 to 6000 mPas and wherein the formulation further comprises reaction products of the isocyanate-functional prepolymer with the amino-functional aspartic ester and the organic fillers.17. The formulation according to claim 11 , wherein the polyol component has a number-average molecular weight of 4000 to 8500 g/mol.18. The formulation according to claim 11 , wherein the polyol component comprises a polyalkylene oxide polyether.19. The formulation according to claim 18 , wherein the polyalkylene oxide polyether contain from 60% to 90% of ethylene oxide-based units claim 18 , based on the total amount of alkylene oxide units.20. The formulation according to claim 12 , wherein the organic fillers comprise polyether polyols.21. The formulation according to claim 11 , wherein the formulation is cured for a period of time from 30 seconds to 10 ...

Curable composition of low density

A moisture-curing composition including a) at least one moisture-reactive polymer P with a proportion of 10% to 60% by weight, based on overall composition, b) at least one inorganic filler F with a proportion of at least 9% by weight, based on overall composition, c) between 3% and 25% by weight, based on overall composition, of at least one type of microscopic hollow beads H, wherein composition has density of less than 1.20 kg/l, and microscopic hollow beads H have compressive strength, measured to ASTM D3102-72, of at least 2.5 MPa, and microscopic hollow beads H have a volume-based particle size D90, measured by Coulter counter, of less than 100 μm.

RESIN COMPOSITION

The present invention relates to a resin composition comprising (a) an unsaturated polyester resin and/or a methacrylate functional resin, wherein the resin composition further comprises an aromatic amine (b) according to formula (1) in which Pis an organic residue, R=H or a C-Calkyl, R=H or CH. 2. Resin composition according to claim 1 , characterized in that the molecular weight Mof the aromatic amine according to formula (1) is higher than 750 Dalton.3. Resin composition according to claim 1 , characterized in that the molecular weight Mof the aromatic amine according to formula (1) is lower than 10000 Dalton.4. Resin composition according to claim 1 , characterized in that R=CHand R=CH.5. Resin composition according to claim 1 , wherein Pis a residue of polymeric methylene diphenyl diisocyanate.6. Resin composition according to claim 1 , characterized in that the composition comprises a mixture of methacrylate functional resins which mixture has an average functionality higher than 1 claim 1 , preferably higher than 1.5 and more preferably higher than 1.7.7. Resin composition according to claim 1 , characterized in that the composition comprises a mixture of methacrylate functional resins which mixture has an average functionality lower than 4 claim 1 , more preferably lower than 3.8. Resin composition according to claim 6 , characterized in that the methacrylate functional resins further contain at least one urethane group.10. Resin composition according to claim 1 , characterized in that the resin composition further comprises a reactive diluent (c).11. Resin composition according to claim 1 , characterized in that the amount of the aromatic amine according to formula (1) (relative to the total amount of compounds (a) claim 1 , (b) and (c)) is from 1 up to and including 30 wt. % claim 1 , more preferably from 2 up to and including 20 wt. %.12. Two component resin system consisting of a first component A and a second component B claim 1 , characterized in that ...

MOISTURE-CURABLE OMNIPHOBIC COATINGS

An omniphobic material and its method of making by: providing an alkoxysilane-terminated polyurea, and reacting by a moisture-curing reaction the polyurea and a fluorinated material having one or more alkoxy or hydroxyl groups. 1. A polymer made by a method comprising:providing an alkoxysilane-terminated polyurea; andreacting by a moisture-curing reaction the polyurea and a fluorinated material having one or more alkoxy or hydroxyl groups.2. The polymer of ;{'sup': 3', '2', '1, 'sub': 2', 'n', 'x', '3-x, 'wherein the alkoxysilane-terminated polyurea is a reaction product of an aliphatic polyisocyanate having at least 2 isocyanate groups and an amino-functional alkoxysilane of the formula NH(R)(CH)Si(R)(OR);'}wherein n is 1, 2, or 3;wherein x is 0, 1, or 2;{'sup': 1', '2, 'wherein each Rand Ris an alkyl group; and'}{'sup': '3', 'wherein Ris —H, aryl, alkyl, an ester-containing alkyl, or a fluorinated alkyl group.'}3. The polymer of ;{'sup': '4', 'sub': 3', '2', 'n', '3, 'wherein the fluorinated material is a fluoroalkyl alkoxysilane having the formula (RO)Si(CX)CX;'}wherein each X is —H or —F;wherein at least one X is —F; and{'sup': '4', 'wherein each Ris —H or an alkyl group.'}4. The polymer of claim 3 , wherein the fluoroalkyl alkoxysilane comprises a perfluoroalkyl group.5. The polymer of claim 3 , wherein the fluoroalkyl alkoxysilane is (3 claim 3 ,3 claim 3 ,3-trifluoropropyl)trimethoxy silane claim 3 , nonafluorohexyltrimethoxysilane claim 3 , (tridecafluoro-1 claim 3 ,1 claim 3 ,2 claim 3 ,2-tetrahydrooctyl)triethoxysilane claim 3 , (tridecafluoro-1 claim 3 ,1 claim 3 ,2 claim 3 ,2-tetrahydrooctyl)trimethoxysilane claim 3 , perfluorododecyl-1H claim 3 ,1H claim 3 ,2H claim 3 ,2H-triethoxysilane claim 3 , perfluorotetradecyl-1H claim 3 ,1H claim 3 ,2H claim 3 ,2H-triethoxysilane claim 3 , triethoxy(3 claim 3 ,3 claim 3 ,4 claim 3 ,4 claim 3 ,5 claim 3 ,5 claim 3 ,6 claim 3 ,6 claim 3 ,7 claim 3 ,7 claim 3 ,8 claim 3 ,8 claim 3 ,8-tridecafluoro-1-octyl)silane ...

CLEARCOAT COMPOSITIONS AND METHODS OF FORMING CLEARCOAT COMPOSITIONS

Clearcoat compositions and methods for forming a clearcoat compositions are provided. In one example, a clearcoat composition includes a binder portion A that includes a polyaspartic ester resin. An activator portion B includes a polyol-modified isocyanate that is a reaction product of a polyisocyanate component and a polyol component. The polyol component includes polycaprolactone polyol. 1. A clearcoat composition comprising:a binder portion A comprising a polyaspartic ester resin; andan activator portion B comprising a polyol-modified isocyanate that is a reaction product of a polyisocyanate component and a polyol component that comprises polycaprolactone polyol.2. The clearcoat composition of claim 1 , wherein the polycaprolactone polyol has a number average molecular weight (MN) of from about 200 to about 2000.3. The clearcoat composition of claim 1 , wherein the polycaprolactone polyol has a functionality of from 2 to 4.4. The clearcoat composition of claim 1 , wherein the polycaprolactone polyol has an equivalent weight of from about 80 to about 1000 g/mol.5. The clearcoat composition of claim 1 , wherein the polyol component further comprises at least one additional polyol and/or alcohol selected from polyester polyols claim 1 , polyether polyols claim 1 , polyacrylate polyols claim 1 , polycarbonate polyols claim 1 , polyurethane polyols claim 1 , polyacetal polyols claim 1 , polyester amide polyols claim 1 , polythioether polyols claim 1 , aliphatic dialcohols claim 1 , trialcohols claim 1 , tetra-functional alcohols claim 1 , and combinations thereof.6. The clearcoat composition of claim 5 , wherein the polyol component is a mixture of polyols comprising the polycaprolactone polyol and the at least one additional polyol and/or alcohol claim 5 , and wherein the mixture of polyols has a number average functionality of from about 1.5 to about 6.7. The clearcoat composition of claim 1 , wherein the polyisocyanate component comprises one or more ...

POLYOL OR POLYTHIOL COMPOUND, PREPARATION METHOD THEREFOR, TRANSPARENT POLYURETHANE-BASED RESIN PREPARED THEREFROM, AND OPTICAL BODY

The present invention relates to a novel polyol or polythiol having three or more functional groups, a preparation method there for, and an optical body manufactured therefrom. Especially, the present invention relates to a poly(thio)urethane-based resin and an optical body, such as lenses, manufactured using the resin, wherein the poly(thio)urethane-based resin is prepared by obtaining a novel polyol and then combining a polythiol, which is prepared from the obtained polyol, with a polyiso(thio)cyanate. 123-. (canceled)25. The polyol compound according to claim 24 , as represented by Formula (a) or (b) claim 24 , wherein Y is an oxygen atom; Ra is a methyl or ethyl group; and Rb is one substituent selected from the group consisting of the following substituents:{'sub': 2', '2', '2', '2', '2', '2', '2', '2, '—CHCH(OH)CHF, —CHCH(OH)CHCl, —CHCH(OH)CHBr, —CHCH(OH)CHI,'}{'sub': 2', '2', '2', '2', '2', '3, '—CHCH(OH)CHSCHCH(OH)CHSCHCH(OH)CH,'}{'sub': 2', '2', '2', '2', '3', '2, '—CHCH(OH)CHSCHCH(OH)CHSCH(CH)CHOH,'}{'sub': 2', '2', '2', '3, '—CHCH(OH)CHSCHCH(OH)CH,'}{'sub': 2', '2', '3', '2, '—CHCH(OH)CHSCH(CH)CHOH,'}{'sub': 2', '2', '2', '2', '3, '—CHCH(OH)CHSCHCH(OH)CHCH,'}{'sub': 2', '2', '2', '3', '2, '—CHCH(OH)CHSCH(CHCH)CHOH,'}{'sub': 2', '2', '2', '2', '2', '2', '3, '—CHCH(OH)CHSCHCH(OH)CHSCHCH(OH)CHCH, and'}{'sub': 2', '2', '2', '2', '2', '3', '2, '—CHCH(OH)CHSCHCH(OH)CHSCH(CHCH)CHOH.'}26. The polythiol compound according to claim 24 , as represented by Formula (a) or (b) claim 24 , wherein Y is a sulfur atom; Ra is a methyl or ethyl group; and Rb is one substituent selected from the group consisting of the following substituents:{'sub': 2', '2', '2', '2', '3', '2, '—CH(CHSH)CHSH, —CHCH(CHSH)SCH(CH)CHSH,'}{'sub': 2', '2', '2', '3', '2', '2', '3', '2, '—CHCH(CHSH)SCHCH(CH)SH, —CH(CHSH)CHSCH(CH)CHSH,'}{'sub': 2', '2', '2', '3, '—CH(CHSH)CHSCHCH(CH)SH,'}{'sub': 2', '2', '2', '3', '2, '—CHCH(CHSH)SCH(CHCH)CHSH,'}{'sub': 2', '2', '2', '2', '3, '—CHCH(CHSH)SCHCH(CHCH)SH ...

WATER DISPERSIBLE POLYMER FOR USE IN ADDITIVE MANUFACTURING

A water dispersible sulfo-polyamide is configured as a filament for use as an extrudable support material in the additive manufacture of a part comprising a non water dispersible polymer. The water dispersible sulfo-polyamide is a reaction product of a sulfo monomer, the water dispersible sulfo-polymer being dispersible in water resulting in separation of the water dispersible polymer from the part comprising the non water dispersible polymer. 1. A water dispersible sulfo-polyamide configured as a filament for use as an extrudable support material in the additive manufacture of a part comprising a non water dispersible polymer , wherein the water dispersible sulfo-polyamide is a reaction product of a sulfo monomer , the water dispersible sulfo-polymer being dispersible in water resulting in separation of the water dispersible polymer from the part comprising the non water dispersible polymer.2. The water dispersible sulfo-polymer of claim 1 , wherein the water dispersible sulfo-polymer has a heat deflection temperature within ±20° C. of the heat deflection temperature of the non water dispersible polymer.3. The water dispersible sulfo-polymer of claim 1 , wherein the water dispersible polymer has a glass transition temperature within ±20° C. of the glass transition temperature of the non water dispersible polymer.4. The water dispersible polymer of claim 1 , and further comprising the reaction product of a condensation reaction.5. The water dispersible polymer of claim 1 , and further comprising approximately 18 to 40% metal sulfoisophthalic monomer.6. The water dispersible polymer of claim 6 , and further comprising approximately 20 to 30% metal sulfoisophthalic monomer.7. The water dispersible polymer of claim 1 , wherein the metal sulfo monomer is a sodio sulfo monomer or a lithium sulfo monomer.8. The water dispersible polymer of claim 3 , wherein the water dispersible polymer is characterized by a glass transition temperature of at least approximately 40° C.9. ...

PRODUCTION OF POLYOLS USING DISTILLERS GRAINS AND PROTEINS AND LIGNIN EXTRACTED FROM DISTILLERS GRAINS

Processes for the production of polyols from sources such as dried distillers grains plus solubles (DDGS) make use of a two-stage reaction scheme. In the first stage, the proteinaceous starting material is reacted with an aminating agent, such as diethanolamine (DEOA), to generate amino-amides and amides. These products are then reacted with an alkoxylating agent, preferably a substituted or unsubstituted epoxide to yield polyols. These polyols may be further reacted with isocyanates to give low-cost rigid polyurethane foams. In alternate forms, lignin may be directly converted to polyols by reaction with an alkoxylating agent, optionally followed by reaction with an isocyanate to produce polyurethanes. 1. A process for the production of polyols comprising the steps of:reacting a proteinaceous component selected from the group consisting of distillers grains, polyamides, and mixtures thereof, with an amine under reaction conditions to generate amino-amides and amides; andreacting said amino-amides and amides with an alkoxylating agent to generate polyols.2. The process of claim 1 , said distillers grains being dried distillers grains with solubles.3. The process of claim 1 , said amine selected from the group consisting of primary amines claim 1 , secondary amines claim 1 , and mixtures thereof.5. The process of claim 4 , wherein R1 and R2 are selected from the group consisting of C2-C12 alkanols and alkenols.6. The process of claim 5 , each R1 and R2 being selected from the group consisting of C2-C4 alkanols.7. The process of claim 6 , each R1 and R2 being —CH2CH2OH.8. The process of claim 1 , said proteinaceous component comprising DDGS claim 1 , the ratio of said DDGS and said amine being from about 0.5-3.9. The process of claim 8 , said ratio being from about 1-1.2.10. The process of claim 1 , said proteinaceous component and said amine being reacted at a temperature of from about 150-250° C.11. The process of claim 10 , said temperature being from about 190-200 ...

SHEET-FORMING BODY, ADHESIVE SHEET, AND LAMINATE

The present invention provides a sheet-forming body containing a thiourethane bond-having compound and a thiol group-having compound, wherein, in an IR absorption spectrum thereof, the ratio of the peak intensity A of the absorption peak based on the carbonyl group in the thiourethane bond to the peak intensity B of the absorption peak based on the thiol group (A/B) is 20 or more and 250 or less. Using the sheet-forming body, rubber members, especially vulcanized rubber members can be strongly bonded, and the sheet-forming body and an adhesive sheet, which are excellent in handleability and workability, and a laminate produced by bonding rubber layers using the sheet-forming body are provided. 1. A sheet-forming body comprising a thiourethane bond-having compound and a thiol group-having compound , wherein:in an IR absorption spectrum thereof, the ratio of the peak intensity A of the absorption peak based on the carbonyl group in the thiourethane bond to the peak intensity B of the absorption peak based on the thiol group (A/B) is 20 or more and 250 or less.2. The sheet-forming body according to claim 1 , wherein at least a polythiol compound (A) and an isocyanate group-containing compound (B) are blended.3. The sheet-forming body according to claim 2 , wherein a radical generator (C) is further blended.4. The sheet-forming body according to claim 3 , wherein the radical generator (C) is a thermal radical generator containing a peroxide.5. The sheet-forming body according to claim 3 , wherein the content of the peroxide claim 3 , as measured through liquid chromatography mass spectrometry claim 3 , is 2% by mass or more.6. The sheet-forming body according to claim 2 , wherein the ratio of the total molar number of the isocyanate group contained in the isocyanate group-containing compound (B) to the total molar number of the thiol group contained in the polythiol compound (A) (isocyanate group/thiol group) is 0.2 or more and 0.78 or less.7. The sheet-forming body ...

Aqueous Peptide-Functionalized Polyurethane Dispersions

The present invention relates to aqueous peptide-functionalized polyurethane dispersions that can be used as adhesives, in particular for metal surfaces, such as steel surfaces. As hybrid materials, they provide for a versatile system that can be finely tuned and combine the advantageous properties of polyurethane and peptide materials. Also encompassed are processes for their production, compositions containing them and their use as coatings and adhesives. 1. A process for manufacturing a peptide-functionalized polyurethane dispersion (PUD) , comprising:(1) providing an NCO-terminated polyurethane prepolymer;(2) reacting said NCO-terminated polyurethane prepolymer with a compound comprising at least one NCO-reactive group and at least one maleimide group to obtain a maleimide-terminated polyurethane prepolymer;(3) dispersing said maleimide-terminated polyurethane prepolymer into a continuous aqueous phase; and(4) reacting the maleimide-terminated polyurethane prepolymer with one or more peptides, wherein said one or more peptides comprise amino acid side chains reactive with the maleimide group, thereby forming peptide-functionalized polyurethane particles.2. The process according to claim 1 , wherein the compound comprising at least one NCO-reactive group and at least one maleimide group is a compound comprising one hydroxyl and at least one maleimide group.3. The process according to claim 1 , wherein step (1) comprises forming an NCO-terminated polyurethane prepolymer from a reaction mixture comprising:{'sub': 'n', 'a) at least one polyol with a number average molecular weight Min the range of 400 g/mol to 10000 g/mol; and'}b) at least one aliphatic di- and/or triisocyanate, wherein the at least one aliphatic di- and/or triisocyanate is used in molar excess relative to the hydroxy groups of the at least one polyol of the reaction mixture to obtain the NCO-terminated polyurethane prepolymer.4. The process according to claim 3 , wherein the at least one polyol ...

ISO(THIO)CYANATE COMPOSITION, AND RESIN COMPOSITION INCLUDING SAME FOR OPTICAL MEMBER

An iso(thio)cyanate composition has excellent storage stability. The iso(thio)cyanate composition for an optical component includes an iso(thio)cyanate compound having two or more iso(thio)cyanate groups in a molecule, a phosphoric acid ester compound represented by general formula (1), and a phosphoric acid ester compound represented by general formula (2), a total amount of the phosphoric acid ester compounds being 1 ppm to 25,000 ppm, based on the mass of the iso(thio)cyanate compound. 2. The iso(thio)cyanate composition according to claim 1 , wherein a molar ratio of the phosphoric acid ester compound represented by general formula (1) and the phosphoric acid ester compound represented by general formula (2) is 30/70 to 70/30.4. The iso(thio)cyanate composition according to claim 1 , wherein the iso(thio)cyanate compound has an aromatic ring.5. The iso(thio)cyanate composition according to claim 4 , wherein the iso(thio)cyanate compound is at least one selected from the group consisting of phenylene diisocyanate claim 4 , methylphenylene diisocyanate claim 4 , bis(isocyanatomethyl)benzene claim 4 , mesitylene triisocyanate claim 4 , bis(isocyanatopropyl)benzene claim 4 , diphenylmethane diisocyanate claim 4 , diisocyanate naphthalene claim 4 , and (dimethylbiphenylylene) diisocyanate.6. The iso(thio)cyanate composition according to claim 1 , wherein the iso(thio)cyanate compound is at least one selected from the group consisting of bis(isocyanatomethyl)benzene claim 1 , bis(isocyanatomethyl)cyclohexane claim 1 , bis(4-isocyanatocyclohexyl)methane claim 1 , isophorone diisocyanate claim 1 , norbornanediylbis(methylene) diisocyanate claim 1 , and bis(isocyanatomethyl) dithiane.7. A resin composition for an optical component claim 1 , which is obtained by using the iso(thio)cyanate composition according to .8. The resin composition for an optical component according to claim 7 , which is obtained by further using an active hydrogen compound having two or more ...

ONE COMPONENT POLYURETHANE DISPERSION FOR VINYL WINDOWS AND OTHER SUBSTRATES

The present invention provides an aqueous polyurethane dispersion (PUD) comprising an amorphous polyester having a glass transition temperature (T) as determined by differential scanning calorimetry of less than −30° C.; wherein the aqueous polyurethane dispersion (PUD) has a glass transition temperature (T) as determined by differential scanning calorimetry (DSC) of 0° C. to 20° C. and a hard block content of greater than 50%. Coatings, adhesives, sealants, paints, primers and topcoats, made from the inventive aqueous polyurethane dispersion (PUD) pass detergent resistance testing according to the American Architectural Manufacturers Association's standard, AAMA 615-13, have a pencil hardness according to ASTM D3363 of at least 3H, and are particularly suited for use on low surface energy substrates such as vinyl and other surfaces including floors, windows, doors, window frames, door frames, window shutters, railing, gates, pillars, arbors, pergolas, trellises, gazebos, posts, fencing, pipes and fittings, wire and cable insulation, automobile components, credit cards, and siding. 1. A primer containing an aqueous polyurethane dispersion (PUD) comprising the reaction product of:(i) a polyisocyanate;(ii) a polymeric polyol having a number average molecular weight of 400 to 8,000 g/mol;(iii) a compound comprising at least one isocyanate-reactive group and an anionic group or potentially anionic group;(iv) an amorphous polyester having a glass transition temperature (Tg) as determined by differential scanning calorimetry (DSC) of less than −30° C.;(v) water;(vi) a mono functional polyalkylene ether;(vii) a polyol having a molecular weight of less than <400 g/mol, and(viii) a polyamine or amino alcohol having a molecular weight of 32 to 400 g/mol,{'sub': 'g', 'wherein the aqueous polyurethane dispersion (PUD) has a glass transition temperature (T) as determined by differential scanning calorimetry (DSC) of 0° C. to 20° C. and a hard block content of greater than 50%.'} ...

EPOXY RESIN COMPOSITION

Curable composition obtained by combining and mixing an epoxy resin composition comprising an epoxy resin, a monool and/or polyol and a compound comprising a carboxamide group, and a polyisocyanate composition comprising a polyisocyanate, a lithium halide and a urea compound, wherein the number of moles of lithium halide per isocyanate equivalent ranges of from 0.0001-0.04 and the number of urea+biuret equivalents per isocyanate equivalent of from 0.0001-0.4. The epoxy resin composition is claimed as well. 115-. (canceled)17. The method of claim 16 , wherein the urea compound is a compound obtained from a reaction of a diphenylmethane diisocyanate comprising at least 35% 4 claim 16 ,4′-diphenylmethan diisocyanate or a carbodiimide and/or a uretonimine variant of a diphenylmethane diisocyanate comprising at least 35% 4 claim 16 ,4′-diphenylmethan diisocyanate and an amine.18. The method of claim 17 , wherein the amine is a polyoxyalkylene monoamine comprising oxypropylene groups in an amount of at least 50% by weight claim 17 , based on the total weight of the monoamine.19. The method of claim 16 , wherein the lithium halide is premixed with the urea compound to form a mixture and the mixture is added to the polyisocyanate.20. The method of claim 16 , wherein the curable composition has a pot-life at ambient conditions of at least 5 hours up to 300 hours.21. The method of claim 16 , wherein the curable composition has a pot-life at ambient conditions of at least 40 hours up to 300 hours.22. A curable composition for making a polyisocyanurate material claim 16 , the curable composition comprising: a polyisocyanate composition comprising a polyisocyanate claim 16 , a urea compound having an average molecular weight of 500 to 15000 and comprising biuret groups and a lithium halide; and an epoxy resin composition comprising an epoxy resin claim 16 , at least one of a monool and a polyol and a carboxamide compound comprising a carboxamide group having a structure —CO— ...

Method for controlled release of antimicrobial compounds

wherein X is O or NH; R is an acrylic polymer, a saturated polyester, an alkyd resin, a polyether or a polycarbonate and R optionally has additional XC(O)NHCHR′R″ substituents; R′ is hydroxyl or NHC(O)XR; and R″ is an organic substituent group having from one to twenty carbon atoms and which optionally has additional CHR′NHC(O)XR substituents.

OXIDIC SILICON PARTICLE DISPERSION IN POLYOL

A graft macromer, comprising the reaction product of at least one macromer being at least one molecule which comprises in its structure one or more hydroxyl-terminated polyether and/or polyester chains, with at least one grafting compound which comprises in its structure at least one at least monoalkoxylated or at least monohalogenated silyl group and at least one alkyl, cycloalkyl or aryl containing group which is reactive towards the hydroxyl group of the macromer, is used for dispersing e.g. SiOin a polyol. 122-. (canceled)23. A dispersion , comprising a graft macromer comprising a reaction product of at least one macromer being at least one molecule which comprises in its structure one or more hydroxyl-terminated polyether and/or polyester chains , with at least one grafting compound which comprises in its structure at least one at least monoalkoxylated or at least monohalogenated silyl group and at least one alkyl , cycloalkyl or aryl comprising group which is reactive towards a hydroxyl group of the at least one macromer , reacted with oxidic silicon particles selected from the group consisting of silicon dioxide , silicates , silicic acid and mixtures thereof , in at least one polyol , which is different from the graft macromer , wherein the oxidic silicon particles have an arithmetic mean diameter (d) in a range of from 0.5 to 20 μm.24. The dispersion of claim 23 , wherein the oxidic silicon particles have an arithmetic mean diameter (d) in a range of from 1 to 10 μm.25. The dispersion of claim 23 , wherein the at least one polyol is selected from two- to eight-functional polyether polyols and/or polyester polyols having a molecular weight (M) of from 500 to 30000 g/mol.26. The dispersion of claim 23 , wherein the oxidic silicon particles are selected from silicon dioxide particles and aluminium silicate particles.27. The dispersion of claim 23 , wherein the at least one macromer is selected from two- to eight-functional polyether polyols and/or polyester ...