Pentamethylenediisocyanate, method for producing pentamethylenediisocyanate, polyisocyanate composition, polyurethane resin, and polyurea resin

A Pentamethylene diisocyanate is obtained by phosgenating pentamethylenediamine or its salt obtained by a biochemical method, and contains 5 to 400 ppm of a compound represented by the general formula (1) below and a compound represented by the general formula (2) below in total:

Rheology modifier

The present invention relates to a composition comprising a hydrophobically modified alkylene oxide polyurethane characterized by having a M w of from 50,000 to about 150,000 Daltons and a polydispersity of 2.5 to about 5.0. The present invention further relates to a multi-step process for the preparation of the hydrophobically modified polymer.

Method for producing light-coloured tdi-polyisocantes

The invention relates to polyisocyanates comprising urethane groups, based on toluylene diisocyanate, to a method for their production, and to their use as the polyisocyanate component in one- and two-component polyurethane coatings.

High-value polyurethane elastomers and production thereof

The present invention relates to high-value polyurethane (PUR) and polyurethaneurea elastomers, which can be processed in a particularly simple manner by use of low-viscosity prepolymers based on naphthalene 1,5-diisocyanate, and to a process for production thereof.

PHOTOCATALYST HAVING HIGH VISIBLE-LIGHT ACTIVITY

A photocatalyst according to the present invention has a structure in which the titanium dioxide doped with the transition metals is supported on the support such that a band gap thereof is low and a specific surface area thereof is high, thereby exhibiting an excellent photocatalytic activity even in a visible light region and providing an excellent effect of adsorbing an organic compound and removing the same even under a condition in which light is not emitted. 1. A photocatalyst comprising:titanium dioxide doped with vanadium (V); anda support on which the titanium dioxide is supported,wherein the support is a polymer matrix having a porous structure,wherein the a polymer matrix has a activating surface with an isocyanate group for chemical bond to titanium dioxide thought silane-based binder,{'sup': '2', 'wherein an average BET specific surface area of the photocatalyst is in a range of 120 to 480 m/g.'}2. The photocatalyst of claim 1 , wherein the photocatalyst has a band gap of 4 eV or less in a wavelength range of 400 to 700 nm.3. The photocatalyst of claim 1 , wherein the photocatalyst comprises 0.1 to 15 parts by weight of the titanium dioxide doped with the transition metal claim 1 , based on 100 parts by weight of the polymer matrix.4. The photocatalyst of claim 1 , wherein an average particle diameter of pores formed in the polymer matrix is in a range of 50 to 500 μm claim 1 , and{'sup': '3', 'an average volume of the pores is in a range of 0.01 to 0.03 cm/g.'}5. The photocatalyst of claim 1 , wherein the polymer matrix comprises one or more selected from the group consisting of a polyurethane resin claim 1 , a polyester resin claim 1 , and polyamide resin. This application is a Division of U.S. patent application Ser. No. 15/761,548 filed on Mar. 20, 2018, which is a National Phase of PCT Patent Application No. PCT/KR2015/012525 having International filing date of Nov. 20, 2015, which claims the benefit of priority of Korean Patent Application Nos. 10 ...

READILY ADHESIVE POLYESTER FILM AND METHOD FOR PRODUCING SAME

This invention provides a readily adhesive polyester film that has fewer flaws and in which no appearance defects occur due to tight winding during the storage of rolled products, and a method for efficiently producing the readily adhesive polyester film. More specifically, this invention provides a readily adhesive polyester film comprising a polyester film as a base film and a readily adhesive layer on at least one side of the base film, wherein the base film contains particles with an average particle diameter of 0.1-2 μm or more in an amount of 1 mass % or less based on the mass of the base film, and the readily adhesive layer is a cured product of a composition comprising a copolymerized polyester resin (A), a blocked isocyanate group-containing urethane resin (B), and a silicone surfactant (C). This invention also provides a method for producing a readily adhesive polyester film.

AQUEOUS COATING COMPOSITION FOR SIDE SEAM STRIP OR SIDE SEAM COATING ON THREE-PIECE CAN

An aqueous coating composition includes: i) an aqueous dispersion of a hydroxyl functional acrylic polymer; ii) a urethane component; iii) a hydroxyl reactive crosslinking agent different from component ii); and iv) an aqueous liquid carrier. The coating composition has a volatile organic (VOC) content of less than 420 g/L, and may be applied to a side seam strip or a side seam of a three-piece can. 2. The coating composition of claim 1 , wherein the urethane component comprises a water-dispersible polyurethane polymer.3. The coating composition of claim 1 , wherein the urethane component comprises a blocked isocyanate.4. The coating composition of claim 3 , wherein the blocked isocyanate is selected from the group consisting of a blocked aliphatic polyisocyanate and a blocked cycloaliphatic polyisocyanate claim 3 , preferably from the group consisting of blocked hexamethylene diisocyanate claim 3 , blocked isophorone diisocyanate claim 3 , blocked bis [4-isocyanatocyclohexyl]methane) claim 3 , blocked tetramethylene-m-xylidene diisocyanate claim 3 , blocked isopropenyldimethyl-benzylisocyanate and dimers or trimers thereof.5. The coating composition of claim 1 , wherein the urethane component contains an isocyanate content of at least 0.1 wt % claim 1 , based on the weight of isocyanate for forming the urethane component.6. The coating composition of claim 1 , wherein the component iii) comprises an aminoplast crosslinker.7. The coating composition of claim 6 , wherein the aminoplast crosslinker comprises a melamine-formaldehyde crosslinker claim 6 , a benzoguanamine-formaldehyde crosslinker claim 6 , a glycoluril-formaldehyde crosslinker or the combination thereof.8. The coating composition of claim 1 , wherein the hydroxyl-functional acrylic polymer comprises an emulsion polymerized latex polymer.9. The coating composition of claim 1 , wherein the hydroxyl-functional acrylic polymer comprises an organic-solution polymerized acrylic polymer10. The coating ...

ADHESIVE COMPOSITION AND HEAT-FUSIBLE MEMBER USING SAME

An adhesive composition having high room-temperature peel strength, high hot peel strength, and excellent adhesion, as well as excellent electrolyte resistance even when used for packaging materials for lithium ion batteries is provided, which contains an organic solvent, a polyolefin (A) that has an acidic group and/or an acid anhydride group and is soluble in the organic solvent, and an isocyanate compound, wherein the isocyanate compound comprises (B) a diisocyanate compound having a C4-7 hydrocarbon group and/or a derivative thereof, and (C) a diisocyanate compound having a C8-14 hydrocarbon group and/or a derivative thereof; and a heat-fusible member using the adhesive composition is also provided. 2. The adhesive composition according to claim 1 , wherein the diisocyanate compound having a hydrocarbon group with 4 to 7 carbon atoms is hexamethylene diisocyanate.3. The adhesive composition according to claim 1 , wherein the diisocyanate compound having a hydrocarbon group with 8 to 14 carbon atoms is a diisocyanate compound having at least one secondary isocyanate group.4. The adhesive composition according to claim 1 , herein the diisocyanate compound having a hydrocarbon group with 8 to 14 carbon atoms is isophorone diisocyanate.5. The adhesive composition according to claim 1 , wherein the derivative of the diisocyanate compound having a hydrocarbon group with 4 to 7 carbon atoms and/or the derivative of the diisocyanate compound having a hydrocarbon group with 8 to 14 carbon atoms comprise at least one bond selected from the group consisting of an isocyanurate bond claim 1 , a biuret bond claim 1 , a urethane bond and an allophanate bond.6. The adhesive composition according to claim 1 , wherein the component (A) is a polyolefin graft-modified with an acidic group-containing monomer and/or an acid anhydride group-containing monomer claim 1 , and an graft amount thereof is 0.10 to 30 wt %.7. The adhesive composition according to claim 1 , wherein the ...

Structural polyurethane adhesive

A two-component polyurethane adhesive is described having high strength and extensibility, wherein the mechanical properties are only slightly dependent on the temperature. The polyurethane adhesive can be suitable as a structural adhesive. The adhesive can include a triol, a diol, a polyamine, a polyisocyanate, and a polyurethane polymer having isocayanate groups in certain ratios.

Golf ball

To provide a golf ball that can prevent considerable decrease in carry distance of a driver shot when it rains and also can more reliably prevent adhesion of dirt, etc. to the surface of the golf ball. The golf ball of the present invention includes a core, a cover that is provided on an outer side of the core and is provided with dimples, and an outermost layer that is formed on an outer side of the cover and made of a material having a contact angle of 90° or more, a dynamic contact angle of 85° or less and an adhesive force of 130 μN or less. The material for forming the outermost layer includes a urethane coating material with a water repellent additive.

Cationic curing agent, method for producing same and cationically curable composition

A cationic curing agent includes porous particles and a compound represented by General Formula (1), where the compound is held in the porous particles.In the General Formula (1), R1 is an alkyl group having 1 to 18 carbon atoms or a phenyl group, where the alkyl group may be branched and the alkyl group and the phenyl group may each further have a substituent. R2 is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms where the alkyl group may be branched, a halogenoalkyl group, an alkoxy group, or a phenoxy group; where the alkyl group, the halogenoalkyl group, the alkoxy group, or the phenoxy group may further have a substituent. R1 and R2 may be identical to or different from each other.

Urethane Composition, Polyurethane Elastomer and Transmission Belt

An object is to provide a polyurethane elastomer excellent in strength and surface smoothness. To attain the object, a urethane composition including a certain prepolymer, a plasticizer and a crosslinking agent is provided.

Latent two-part polyurethane adhesives curable with infrared radiation

Disclosed are latent two-part polyurethane adhesives that rapidly develop adhesive strength when cured by application of infrared radiation containing a polyol component which includes; one or more polyols having a hydroxyl equivalent weight of 400 to 2000 and a nominal hydroxyl functionality of 2 to 4; one or more aliphatic diol chain extenders; and one or more latent room temperature organometallic catalysts; b) a polyisocyanate component containing one or more polyisocyanate compounds; and v) a carboxylic acid-blocked cyclic amidine compound and vi) a phenol-blocked cyclic amidine compound which each may be located in the polyol component or the isocyanate component. Further disclosed are methods of bonding structures together using the latent two-part polyurethane adhesives.

COATED PARTICLES, METHODS FOR THEIR MANUFACTURE AND FOR THEIR USE AS PROPPANTS

Disclosed are coated particles. The coated particles include substrate particles and a coating disposed over at least a portion of the substrate particles. The coating includes a condensation reaction product of a reaction mixture that includes a liquid isocyanate-functional component and an isocyanate-reactive composition. Also disclosed are methods for making such particles and methods for using such particles as proppants in hydraulic fracturing. 123-. (canceled)24. A method of making coated particles comprising:(1) mixing substrate particles having a particle size of no more than 3 mesh with a first reaction mixture comprising an isocyanate-reactive composition and a liquid isocyanate-functional component,(2) allowing a condensation reaction between the isocyanate-reactive composition and the liquid isocyanate-functional component to take place to form coated particles,(3) mixing the coated particles with a second reaction mixture comprising the isocyanate-reactive composition and the isocyanate-functional component; and(4) allowing a condensation reaction between the isocyanate-reactive composition and the isocyanate-functional component to take place to further coat the coated particles to form additionally coated particles.25. The method of claim 24 , further comprising drying the substrate particles by heating the substrate particles to a temperature of at least 50° C. prior to step (1) to produce dried substrate particles.26. The method of claim 25 , further adding an aminosilane to the dried substrate particles.27. The method of claim 24 , further comprising adding an aqueous dispersion of a crystalline or semicrystalline polyester/polyurethane to the additionally coated particles.28. The method of claim 27 , further comprising mixing the additionally coated particles with a solid particle anti-clumping agent.29. The method of claim 24 , wherein the total reaction mixture used is 0.1% to 10% by weight claim 24 , based on the total weight of substrate ...

FABRICATION AND APPLICATION OF SHAPE MEMORY POLYMER POSSESSING TRANSESTERIFICATION INDUCED PERMANENT RESHAPING PROPERTY

The present invention discloses the fabrication and application of a shape memory polymer possessing transesterification-induced permanent reshaping. The ester-containing crosslinked polymer is obtained by crosslinking ester bearing polymer precursors or by reaction of monomers which yield ester bonds. The transition temperature falls between 20-150° C. The reshaping temperature is tuned by catalyst amount and should be 20° C. above the transition temperature. The breakthrough of the present invention lies in integrating shape memory effect and plastic deformation into the same polymer and triggering the respective function at different occasions. The permanent shape of as synthesized polymer could be modified arbitrarily and cumulatively. Therefore, the hierarchical structure which could not otherwise be obtained due to the limit of mold fabrication process should expand the practical application of SMPs. 1. An application method of a shape memory polymer possessing transesterification-induced permanent reshaping property , the method comprising the steps of:a) (1) when the temperature reaches reshaping temperature, under the impact of an external force, the polymer with a certain original shape (shape I) is changed to an arbitrary desired new shape;b) (2) the temperature and external force remain stable to allow the transesterification reactions in the polymer system until dynamic equilibrium is reached;c) (3) the new shape is permanently fixed under cooling and now defined as the new original shape (shape II);d) (4) the processed polymer is further altered to a temporary shape (shape III) after being heated above the phase transformation temperature under an external force;e) (5) the temporary shape of step (4) shall be fixed after cooling below the phase transformation temperature;f) (6) the polymer obtained from step (5) is reheated to above its the phase transformation temperature so that the polymer will recover to the permanent shape (shape II) obtained in ...

Eyewear material, eyewear frame, and eyewear

The eyewear material is an eyewear material containing thermoplastic polyurethane. The eyewear material has a tan δ peak at both less than 0° C. and 0° C. or more and 70° C. or less observed in dynamic viscoelasticity measurement in tensile mode under the measurement conditions of a temperature increase speed of 5° C./min and a measurement frequency of 10 Hz.

A composition comprising solvent and heat resistant capsules

A composition includes a capsules having an improved solvent and heat resistance. The capsules are prepared via interfacial polymerization between a polyisocyanate including at least one substituted or unsubstituted arylene or heterearyl group and a compound including an active hydrogen. The capsules include a leuco dye and may be used in laser markable compositions.

Mdi based linings and membranes from prepolymers with very low free monomeric isocyanates

The invention relates to a holding means ( 1 ) for fastening a portable communication device to a vehicle component, in particular to a windscreen of a motor vehicle, the holding means ( 1 ) comprising a basic carrier ( 3 ) for carrying the portable communication device such that the portable communication device extends parallel to a front face ( 24 ) of the basic carrier ( 3 ). The basic carrier ( 3 ) comprises a pair of holding arms ( 11, 12 ) arranged on opposite sides of the front face ( 24 ) of the basic carrier ( 3 ) and extending perpendicular to the front face ( 24 ) and parallel to each other. The holding arms ( 11, 12 ) are arranged for accommodating the portable communication device between them, wherein the basic carrier ( 3 ) furthermore comprises an elastic coupling element ( 18 ) by means of which the holding arms ( 11, 12 ) are joined to each other.

NCO PREPOLYMERS OF LOW MONOMER CONTENT AND THEIR USE

The invention relates to a low-monomer NCO prepolymer composition of the type A-B-A, which is obtained by reacting CH-acidic compounds with diisocyanates, and methods for the production and use thereof. 2. The composition according to claim 1 , wherein(ii) the organofunctional C—H-acidic compound HBH of the formula III comprises an electron-withdrawing group on a carbon atom located alpha to the C—H-acidic carbon atom.3. The composition according to claim 1 , wherein(i) the diisocyanate compound of the formula II comprises isophorone diisocyanate (IPDI), hexamethylene diisocyanate (HDI), diisocyanatodicyclohexylmethane (H12MDI), 2-methylpentane diisocyanate (MPDI), 2,2,4-trimethylhexamethylene diisocyanate/2,4,4-trimethylhexamethylene diisocyanate (TMDI), norbornane diisocyanate (NBDI), diisocyanatomethylcyclohexane (HXDI), toluidine diisocyanate (TDI), methylenediphenyl diisocyanate (MDI), tetramethylxylylene diisocyanate (TMXDI), or a mixture thereof.4. The composition according to claim 1 , wherein (ii) the organofunctional C—H-acidic compound HBH of the formula III comprises a linear aliphatic claim 1 , (cyclo)aliphatic or branched aliphatic compound having 3 to 25 C atoms claim 1 , selected from β-dicarbonyl compounds claim 1 , diketones claim 1 , keto esters claim 1 , diesters claim 1 , nitrile esters claim 1 , dinitriles and cyclic diketones claim 1 , and derivatives thereof.5. The composition according to claim 1 , wherein (ii) the organofunctional C—H-acidic compound HBH of the formula III is 1 claim 1 ,3-cyclohexanedione claim 1 , dimedone claim 1 , a malonic diester claim 1 , an acetoacetic ester claim 1 , or a mixture thereof.6. The composition according to claim 1 , which comprises 0.1 wt % or more of said prepolymer.8. The process according to claim 7 , wherein the diisocyanate of the formula II comprises isophorone diisocyanate (IPDI) claim 7 , hexamethylene diisocyanate (HDI) claim 7 , diisocyanatodicyclohexylmethane (H12MDI) claim 7 , 2- ...

NON-REACTIVE FLUORO COMPOUND AND PHOTOPOLYMER COMPOSITION COMPRISING THE SAME

A photopolymerizable composition including: a polymer matrix or a precursor thereof containing a reaction product of an acrylate-based polyol and a compound containing at least one isocyanate group; a photoreactive monomer; and a non-reactive fluoro compound and a photoinitiator; a hologram recording medium produced from the composition; an optical element including the hologram recording medium; and a method of recording a hologram using the photopolymerizable composition. 1. A non-reactive fluoro compound represented by the following Chemical Formula 1 and 2:{'br': None, 'sup': 1', '3', '4', '5', '6', '2, 'sub': '1', 'R-A-(CRR—O—CRR)n—B—R\u2003\u2003[Chemical Formula 1]'}{'br': None, 'sup': 1', '3', '4', '5', '6', '3', '4', '5', '6', '2, 'sub': 2', '3, 'R—(CRR—O—CRR)n—X—(CRR—O—CRR)n—R\u2003\u2003[Chemical Formula 2]'}wherein, in Chemical Formula 1 and 2,{'sup': 1', '2, 'Rand Rare terminal blocking groups that are the same as or different from each other, and are each independently an alkyl ester group having 1 to 10 carbon atoms or an alkyl ether group having 1 to 10 carbon atoms, wherein the alkyl ester group and the alkyl ether group are substituted or unsubstituted with a halogen atom,'}A and B are a single bond or an alkylene group having 1 to 5 carbon atoms,{'sup': 3', '6', '3', '6, 'Rto Rare the same as or different from each other, and are each independently hydrogen, a halogen atom, or an alkyl group having 1 to 5 carbon atoms, and at least one of Rto Ris a fluorine atom,'}{'sub': 1', '3, 'each nto nis an integer of 1 to 5, and'}X is an alkylene group having 1 to 10 carbon atoms or an alkyl ether group having 1 to 10 carbon atoms.2. The non-reactive fluoro compound of claim 1 , wherein the non-reactive fluoro compound has a refractive index of less than 1.45.3. The non-reactive fluoro compound of claim 1 , wherein the non-reactive fluoro compound has a molecular weight of about 300 or more.4. The non-reactive fluoro compound of claim 1 , wherein more than ...

HYBRID POLYMERS

The present invention pertains to a polyurethane fluoropolymer [polymer (F)] obtainable by reacting: (i) at least one fluoropolymer [polymer (F)] comprising one or more recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: —R, Rand R, equal to or different from each other, are independently selected from a hydrogen atom and a C-Chydrocarbon group, —Ris a C-Chydrocarbon group comprising from 1 to 5 hydroxyl groups, x being an integer comprised between 1 and 5, and, optionally, comprising one or more functional groups selected from double bonds, epoxy, ester, ether and carboxylic acid groups, with (ii) at least one isocyanate compound comprising at least one isocyanate functional group [compound (I)], (iii) optionally in the presence of one or more chain extenders, said polyurethane fluoropolymer [polymer (F)] comprising at least one bridging group having formula (a) here below: wherein: —Ris a C-Chydrocarbon group comprising from 1 to 5 urethane moieties, x being an integer comprised between 1 and 5, and, optionally, comprising one or more functional groups selected from double bonds, epoxy, ester, ether and carboxylic acid groups. The invention also pertains to a process for the manufacture of said polymer (F) and to uses of said polymer (F). 2. The polyurethane fluoropolymer (F) according to claim 1 , comprising:{'sub': P', 'FC, 'from 0.01% to 99.99% by weight based on the weight of said polyurethane fluoropolymer (F), of at least one fluorinated block comprising a fluorocarbon chain (R), and'}{'sub': P', 'HC, 'from 99.99% to 0.01% by weight, based on the weight of said polyurethane fluoropolymer (F), of at least one hydrogenated block comprising a hydrocarbon chain (R), said blocks being linked to each other by one or more urethane moieties.'}3. The polyurethane fluoropolymer (F) according to claim 1 , wherein fluoropolymer (F) comprises from 0.01% to 10% by moles of recurring units derived from at ...

COATED PARTICLES, METHODS FOR THEIR MANUFACTURE AND FOR THEIR USE AS PROPPANTS

Disclosed are coated particles. The coated particles include substrate particles and a coating disposed over at least a portion of the substrate particles. The coating includes a condensation reaction product of a reaction mixture that includes a liquid isocyanate-functional component and an isocyanate-reactive composition. Also disclosed are methods for making such particles and methods for using such particles as proppants in hydraulic fracturing.

SUSTAINABLE ADDITIVE MANUFACTURING RESINS AND METHODS OF RECYCLING

Provided herein are methods of recycling additively manufactured objects (e.g., stereolithographically produced objects), the additively manufactured objects comprising linear polyurethane, branched polyurethane, linear polyurea, branched polyurea, a copolymer thereof, or a combination thereof. Compositions comprising the same and methods of use thereof are also provided. 1. A method of recycling additively manufactured objects , comprising: (i) linear polyurethane, branched polyurethane, linear polyurea, branched polyurea, a copolymer thereof, or a combination thereof,', '(ii) a polymerized reactive diluent, and', '(iii) optionally, at least one plasticizer;, '(a) providing recyclable material, the recyclable material comprised of additively manufactured objects or objects produced by flood curing scrap additive manufacturing resin, the objects optionally in fragmented and/or melt-processed form, the additively manufactured objects comprising a blend of(b) either: (i) melting said recyclable material, or (ii) dissolving said recyclable material in a solvent, to provide a liquid thermoplastic material; and(c) either: (i) forming a new object from said liquid thermoplastic material, or (ii) packaging said liquid thermoplastic material to produce a resin, thereby recycling said objects.2. The method of claim 1 , wherein the additively manufactured objects comprise a blend of:(i) linear polyurethane, linear polyurea, linear copolymer thereof, or a combination thereof, and(ii) a polymerized reactive diluent.3. The method of claim 2 , wherein the reactive diluent is monofunctional.4. The method of claim 1 , wherein said forming step is carried out by molding claim 1 , casting claim 1 , fused deposition modeling claim 1 , or binder jetting.5. The method of claim 1 , wherein said additively manufactured object comprises a support separated from a primary object following additive manufacturing thereof.6. The method of claim 1 , wherein said providing is carried out by ...

적외선으로 경화가능한 잠재적인 2성분 폴리우레탄 접착제

본원은 적외선 적용에 의해 경화되는 경우 접착제 강도를 신속하게 나타내는 잠재적인 2성분 폴리우레탄 접착제를 개시하되, 이는 a) 400 내지 2000의 하이드록실 당량 및 2 내지 3의 공칭 하이드록실 작용가를 갖는 1종 이상의 폴리올; 1종 이상의 지방족 디올 쇄 연장제; 1종 이상의 잠재적인 실온 유기금속 촉매; 및 3 초과의 작용가를 갖는 1종 이상의 다작용성 폴리올을 포함하는 폴리올 성분; b) 1종 이상의 폴리이소시아네이트 화합물을 함유하는 폴리이소시아네이트 성분; 및 상기 폴리올 성분 또는 이소시아네이트 성분에 위치될 수 있는, v) 카복실산-차단된 사이클릭 아미딘 혼합물, vi) 페놀-차단된 사이클릭 아미딘 화합물 또는 v) 1종 이상의 카르복실 산-차단된 사이클릭 아미딘 화합물 및 vi) 1종 이상의 페놀-차단된 사이클릭 아미딘 화합물 둘 다를 포함한다. 본원은 추가로 잠재적인 22성분 폴리우레탄 접착제를 함께 사용하여 구조물을 결합하는 방법을 개시한다.

一种自乳化型阴离子水性聚氨酯固化剂及其制备方法

本发明公开了一种自乳化型阴离子水性聚氨酯固化剂及制备方法，所述自乳化型阴离子水性聚氨酯固化剂包括以下按重量比计的原料：异氰酸酯类单体和/或其衍生物75‑85％，磺酸类衍生物2‑3％，醚酯类溶剂10‑15％，其他助剂2‑3％；本发明的自乳化型阴离子水性聚氨酯固化剂，各项指标都达到了国家标准，属于环保型聚氨酯；应用一般的预聚物生产设备即可生产，无需增加新设备，具有设备成本低、操作简单的特点，而且处理过程中不必使用大量的能源。

Coated particles, methods for their manufacture and for their use as proppants

Disclosed are coated particles. The coated particles include substrate particles and a coating disposed over at least a portion of the substrate particles. The coating includes a condensation reaction product of a reaction mixture that includes a liquid isocyanate-functional component and an isocyanate-reactive composition. Also disclosed are methods for making such particles and methods for using such particles as proppants in hydraulic fracturing.

Coated particles, methods for their manufacture and for their use as proppants

Disclosed are coated particles. The coated particles include substrate particles and a coating disposed over at least a portion of the substrate particles. The coating includes a condensation reaction product of a reaction mixture that includes a liquid isocyanate-functional component and an isocyanate-reactive composition. Also disclosed are methods for making such particles and methods for using such particles as proppants in hydraulic fracturing.

Coated particles, methods for their manufacture and for their use as proppants

Disclosed are coated particles. The coated particles include substrate particles and a coating disposed over at least a portion of the substrate particles. The coating includes a condensation reaction product of a reaction mixture that includes a liquid isocyanate-functional component and an isocyanate-reactive composition. Also disclosed are methods for making such particles and methods for using such particles as proppants in hydraulic fracturing.

Polyurethane-hot melt adhesive with low monomeric diisocyanate content and good crosslinking rate

本发明描述了湿固化热熔粘合剂，所述湿固化热熔粘合剂通过如下步骤获得：A)使作为组分a)的一种或多种多元醇与作为组分b)的一种或多种单体多异氰酸酯反应，其中异氰酸酯基团与羟基的化学计量比大于1，从而获得包含异氰酸酯官能的聚氨酯预聚物的反应产物，B)向反应产物中加入至少一种巯基硅烷并且使其反应，从而获得用巯基硅烷改性的反应产物，和C)在向反应产物或改性的反应产物中加入巯基硅烷之前、之中和/或之后加入具有低于1重量％的单体多异氰酸酯含量的异氰酸酯官能的聚氨酯预聚物作为组分d)，其中至少一种巯基硅烷以0.5至3.5重量％的量加入，并且作为组分d)的异氰酸酯官能的聚氨酯预聚物以10至50重量％的量加入，分别以组分a)至d)的总重量计。所述湿固化热熔粘合剂可以配制成残余单体含量低于1重量％的非R‑40类别的储存稳定和加工稳定的PUR‑HM，并且具有良好的交联密度和固化速度。所述热熔粘合剂特别适合于特别是汽车的车辆构造中、纺织工业或家具工业中或包装材料工业中的工业制造。

Storage-stable polyurethane encapsulation compounds for hollow fibers embedded in filter element preparation

本发明涉及用于包埋过滤元件的中空纤维的聚氨酯包封化合物。所述包封化合物可通过下述过程获得：使多元醇组分(A)和异氰酸酯组分(B)混合以得到反应混合物，并使该混合物反应以得到聚氨酯包封化合物，其中多元醇组分(A)包含(a1)至少一种基于脂肪酸的多元醇，(a2)至少一种具有至少一个叔氮原子和至少一个异氰酸酯反应性氢原子的胺化合物和(a3)至少一种用作聚氨酯催化剂的金属化合物，其中聚氨酯催化剂(a3)不含锡、铅和/或汞，并且异氰酸酯组分(B)包含至少一种具有至少两个异氰酸酯基团的芳族异氰酸酯。本发明还涉及一种使用所述聚氨酯包封化合物制备过滤元件的方法以及涉及所述聚氨酯包封化合物用于包埋中空纤维的用途。

Two-component adhesive compositions without solvents and methods for production thereof

FIELD: adhesive materials.SUBSTANCE: present invention discloses a two-component adhesive composition without solvents, which contains a polyol component and an isocyanate component. Polyol component contains a phosphate functional compound and at least one polyol selected from polyester, polyether and combinations thereof; and isocyanate component contains isocyanate prepolymer, which is a reaction product of at least one isocyanate monomer and at least one polyol selected from polyester, polyether and combinations thereof.EFFECT: invention enables to obtain an adhesive with good adhesion strength and thermal stiffness at room temperature, and also maintains at least 50 % of the initial adhesion strength after the boiling test in the package.10 cl, 6 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 739 841 C2 (51) МПК C09J 175/04 (2006.01) C09J 175/06 (2006.01) C09J 175/08 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C09J 175/04 (2019.08); C09J 175/06 (2019.08); C09J 175/08 (2019.08) (21)(22) Заявка: 2019110727, 19.09.2016 (24) Дата начала отсчета срока действия патента: Дата регистрации: 28.12.2020 (43) Дата публикации заявки: 12.10.2020 Бюл. № 29 (45) Опубликовано: 28.12.2020 Бюл. № 1 (73) Патентообладатель(и): ДАУ ГЛОУБЛ ТЕКНОЛОДЖИЗ ЛЛК (US), РОМ ЭНД ХААС КОМПАНИ (US) (56) Список документов, цитированных в отчете о поиске: WO 2015168670 A1, 05.11.2015. WO 9421453 A1, 29.09.1994. US 2013/0078460 A1, 28.03.2013. RU 2572890 C2, 20.01.2016. RU 2140954 C1, 10.11.1999. (85) Дата начала рассмотрения заявки PCT на национальной фазе: 10.04.2019 (86) Заявка PCT: 2 7 3 9 8 4 1 Приоритет(ы): (22) Дата подачи заявки: 19.09.2016 R U 19.09.2016 (72) Автор(ы): БАЙ, Чэньянь (CN), ЧЭНЬ, Май (US), МАРИН, Амира Аврил (US), ЦУПАНЧИК, Джозеф Джеймс (US), ГО, Иньчжун (US) 2 7 3 9 8 4 1 R U (87) Публикация заявки PCT: C 2 C 2 CN 2016/099304 (19.09.2016) WO 2018/049672 (22.03.2018) Адрес для переписки: 105082, Москва, ...

High-functionality polyisocyanates having urethane groups

本发明涉及基于脂族和/或脂环族二异氰酸酯的包含氨基甲酸酯基的新型多异氰酸酯，及其用途。

High-value polyurethane elastomers and production thereof

本发明涉及高价值聚氨酯（PUR）弹性体和聚氨酯脲弹性体，其通过使用基于1,5-萘二异氰酸酯的低粘度预聚物而以特别简单的方式制备，并且涉及其制备方法。

A kind of low smell polyurethane white paint of low amounts curing agent proportioning

本发明公开了一种低量固化剂配比的低气味聚氨酯白漆，是由聚氨酯白漆主剂、固化剂、稀释剂按照施工重量份配比为1：0.25：0.5组成。所述主剂半成品为：蓖麻油改性醇酸树脂，椰子油改性醇酸树脂，醋酸仲丁酯，分散剂，钛白粉，膨润土，二甲苯。所述主剂成品为：主剂半成品浆，椰子油醇酸树脂，分散剂，消泡剂，流平剂，哑光粉，蜡粉，防沉浆，醋酸丁脂。本发明产品用于木器产品表面涂饰，涂装方式采用喷涂。产品具有低固化剂用量、高固含、硬度高、附着力强、耐黄变性强特点，且相比目前市场上所用白面漆具有更为低固化剂用量、低VOC、耐黄变性好、白度好、遮盖力强，丰满度好，流平及手感好，施工防雾滴性好等突出的特点。

Hydrophilic comb polyurethane

Comb water soluble hydrophilic polyurethanes containing polyoxyethylene side- chains and having molecular weight higher than 100,000 are useful as deflocculant and water retention agents in paper coating compositions.

The resting form bi-component polyurethane carbamate adhesive solidified with infra-red radiation

双组分聚氨基甲酸酯粘合剂包括多元醇组分和聚异氰酸酯组分。多元醇组分包括聚醚多元醇和脂肪族二醇增链剂，但不含伯胺和叔胺化合物。聚异氰酸酯组分包括一种或多种聚异氰酸酯化合物。粘合剂含有巯基乙酸二烷基锡催化剂与酸封端环脒催化剂的混合物。锡催化剂配制成多元醇组分，而环脒催化剂可以配制成多元醇或聚异氰酸酯组分。

Patent RU2019110727A3

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2019 110 727 A (51) МПК C09J 175/04 (2006.01) C09J 175/06 (2006.01) C09J 175/08 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2019110727, 19.09.2016 (71) Заявитель(и): ДАУ ГЛОУБЛ ТЕКНОЛОДЖИЗ ЛЛК (US), РОМ ЭНД ХААС КОМПАНИ (US) Приоритет(ы): (22) Дата подачи заявки: 19.09.2016 (43) Дата публикации заявки: 12.10.2020 Бюл. № 29 (86) Заявка PCT: CN 2016/099304 (19.09.2016) WO 2018/049672 (22.03.2018) (54) ДВУХКОМПОНЕНТНЫЕ АДГЕЗИВНЫЕ КОМПОЗИЦИИ БЕЗ РАСТВОРИТЕЛЕЙ И СПОСОБЫ ИХ ПОЛУЧЕНИЯ R U (57) Формула изобретения 1. Двухкомпонентная адгезивная композиция без растворителей, содержащая полиольный компонент, содержащий соединение с фосфатной функциональной группой и по меньшей мере один полиол, выбранный из сложного полиэфира, простого полиэфира и их комбинаций; и изоцианатный компонент, содержащий изоцианатный форполимер, который является продуктом реакции по меньшей мере одного изоцианатного мономера и по меньшей мере одного полиола, выбранного из сложного полиэфира, простого полиэфира и их комбинаций. 2. Композиция по п. 1, отличающаяся тем, что соединение с фосфатной функциональной группой имеет структуру I 3. Композиция по п. 2, отличающаяся тем, что соединение с фосфатной функциональной группой представляет собой полиол с фосфатной функциональной группой, содержащий две или более гидроксильные группы и одну или более структур I. Стр.: 1 A 2 0 1 9 1 1 0 7 2 7 A Адрес для переписки: 105082, Москва, Спартаковский пер., д. 2, стр. 1, секция 1, этаж 3, ЕВРОМАРКПАТ 2 0 1 9 1 1 0 7 2 7 (87) Публикация заявки PCT: R U (85) Дата начала рассмотрения заявки PCT на национальной фазе: 10.04.2019 (72) Автор(ы): БАЙ, Чэньянь (CN), ЧЭНЬ, Май (US), МАРИН, Амира Аврил (US), ЦУПАНЧИК, Джозеф Джеймс (US), ГО, Иньчжун (US) R U 4. Композиция по п. 3, отличающаяся тем, что полиол с фосфатной функциональной группой является продуктом реакции полиола и полифосфорной кислоты. 5. Композиция по п ...

Ionically hydrophilicized polyisocyanates having improved drying properties

本发明涉及多异氰酸酯混合物，其包含具有脂族和/或脂环族键合的异氰酸酯基团的多异氰酸酯组分A）和具有芳脂族和/或芳族键合的异氰酸酯基团的多异氰酸酯组分B），其特征在于多异氰酸酯组分A）包含至少0.85重量%的化学键合形式的磺酸根基团（以SO 3 计算；摩尔量=80 g/mol），并且多异氰酸酯组分B）的比例为组分A）和B）的总量的7至43重量%。本发明还涉及其用途以及包含该多异氰酸酯混合物的涂料组合物和涂布有这些涂料组合物的基底。

Two-component solvent-free adhesive composition and method for producing them

Two-component curable solventless adhesive for lamination and cured resin

二液固化型无溶剂系层压用粘接剂包含多异氰酸酯成分和多元醇成分，对于多异氰酸酯成分而言，含有五亚甲基二异氰酸酯的衍生物，五亚甲基二异氰酸酯的衍生物含有异氰脲酸酯基和脲基甲酸酯基，相对于异氰脲酸酯基和脲基甲酸酯基的总量100摩尔而言，异氰脲酸酯基的含有比例为60摩尔以上99摩尔以下。

The manufacture method of penta vulcabond, penta vulcabond, polyisocyantates composition, urethane resin and carbamide resin

本发明提供一种戊二异氰酸酯，所述戊二异氰酸酯通过将利用生物化学方法得到的戊二胺或其盐光气化而得到，所述戊二异氰酸酯中下述通式(1)表示的化合物及下述通式(2)表示的化合物的总含量为5～400ppm。

Ionically hydrophilicized polyisocyanates having improved drying properties

本发明涉及多异氰酸酯混合物，其包含具有脂族和/或脂环族键合的异氰酸酯基团的多异氰酸酯组分A）和具有芳脂族和/或芳族键合的异氰酸酯基团的多异氰酸酯组分B），其特征在于多异氰酸酯组分A）包含至少0.85重量%的化学键合形式的磺酸根基团（以SO 3 计算；摩尔量=80 g/mol），并且多异氰酸酯组分B）的比例为组分A）和B）的总量的7至43重量%。本发明还涉及其用途以及包含该多异氰酸酯混合物的涂料组合物和涂布有这些涂料组合物的基底。

Preparation method of polyurethane foam dressing and wound dressing patch

本发明公开了聚氨酯泡绵敷料的制备方法及伤口敷料贴片，涉及医疗领域，聚氨酯泡绵敷料的制备方法，包括如下步骤：步骤A：将摩尔比为1:3～1:8的疏水性多元醇与亲水性二异氰酸酯混合搅拌，反应得到含有3～6个异氰酸酯基团的预聚物；步骤B：将步骤A中得到的预聚物、亲水性聚醚多元醇、发泡剂、封端剂、强化剂和催化剂以摩尔比为1:(0.5‑2):(0.2‑0.8):(0.2‑0.8):(0.2‑0.8)混合搅拌，反应形成聚氨酯泡绵敷料。伤口敷料贴片，包括防水透气膜、聚氨酯泡绵敷料和黏着层，所述黏着层将防水透气膜黏着在聚氨酯泡绵敷料上。本发明有利于形成可供水气穿透的微小缝隙，能够将伤口和正常皮肤的水分进行充分调节，加快伤口愈合的速度。

LAYERS AND MEMBRANES BASED ON MDI FROM FORPOLIMERS CHARACTERIZED BY A VERY LOW LEVEL OF CONTENT OF FREE MONOMERIC ISOCIANATES

1. Двухкомпонентная система на основе полиуретана и/или полиуретан-полимочевинового гибрида для получения материала, подобного эластомеру и/или пластику, содержащая изо-компонент, характеризующийся низким уровнем содержания свободного мономера, и аминовый/полиольный компонент, где изо-компонент содержит форполимер на основе MDI, характеризующийся низким уровнем содержания свободного мономера MDI и имеющий концевые группы, блокированные изоцианатными группами от второго изоцианата относительно повышенного давления пара, где форполимер содержит менее, чем приблизительно 0,3% совокупного свободного мономера и характеризуется значением NCO% в диапазоне от приблизительно 0,1 до приблизительно 10%.2. Двухкомпонентная система на основе полиуретана и/или полиуретан-полимочевинового гибрида по п. 1, где упомянутым вторым изоцианатом относительно повышенного давления пара является толуолдиизоцианат.3. Двухкомпонентная система на основе полиуретана и/или полиуретан-полимочевинового гибрида по п. 1, где форполимер, по существу, не содержит свободного мономера MDI.4. Двухкомпонентная система на основе полиуретана и/или полиуретан-полимочевинового гибрида по п. 1, где форполимер характеризуется значением NCO% в диапазоне от приблизительно 0,5 до приблизительно 5%.5. Двухкомпонентная система на основе полиуретана и/или полиуретан-полимочевинового гибрида по п. 4, где форполимер характеризуется значением NCO% в диапазоне от приблизительно 1 до приблизительно 4%.6. Двухкомпонентная система на основе полиуретана и/или полиуретан-полимочевинового гибрида по п. 1, где аминовый/полиольный компонент содержит, по меньшей мере, один полиол РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C08G 18/10 (13) 2013 132 559 A (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2013132559/04, 19.12.2011 (71) Заявитель(и): АКЦО НОБЕЛЬ КОАТИНГС ИНТЕРНЭШНЛ Б.В. (NL) Приоритет(ы): (30) Конвенционный приоритет: 20.12.2010 US 61/424,934 (85) Дата начала ...

Lining and membrane based on mdi from prepolymers, characterised by very low content of free monomeric isocyanates

FIELD: chemistry. SUBSTANCE: invention describes a two-component polyurethane and/or polyurethane polyurea hybrid based system for making a material, such as an elastomer and/or plastic, comprising an iso component having low content of free monomer and an amine/polyol component, wherein iso component comprises an MDI based pre-polymer with low content of free MDI monomer and capped with isocyanate groups of toluene diisocyanate, where pre-polymer contains less than about 0.3 % total free monomer and has an NCO% in range of about 0.1 to about 10 %. Also described is a coating composition containing two-component polyurethane system and use of said two-component system for producing material, such elastomer and/or plastic. EFFECT: technical result consists in producing a product with improved mechanical properties and chemical resistance. 13 cl, 5 ex, 2 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: (19) RU (11) (51) МПК C08G 18/10 C08G 18/32 C08G 18/40 C08G 18/48 C08G 18/76 C09D 175/08 C09D 175/04 (13) 2 591 699 C2 (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2013132559/04, 19.12.2011 (24) Дата начала отсчета срока действия патента: 19.12.2011 Приоритет(ы): (30) Конвенционный приоритет: (72) Автор(ы): УЛЬКЕМ Ильхан (US), ЭНДРЮС Эдриан Фергюсон (GB), ВИНТЕР Майкл (US) 20.12.2010 US 61/424,934 (43) Дата публикации заявки: 27.01.2015 Бюл. № 3 R U (73) Патентообладатель(и): АКЦО НОБЕЛЬ КОАТИНГС ИНТЕРНЭШНЛ Б.В. (NL) (45) Опубликовано: 20.07.2016 Бюл. № 20 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 22.07.2013 (86) Заявка PCT: 2 5 9 1 6 9 9 (56) Список документов, цитированных в отчете о поиске: DE 19931997 A1 27.01.2000. DE 102004057292 01.06.2006. US 2004/084138 A1 06.08.2004. RU 2279447 C2 10.07.2006. 2 5 9 1 6 9 9 R U (87) Публикация заявки PCT: WO 2012/087897 (28.06.2012) Адрес для переписки: 129090, Москва, ул. Б. Спасская, 25, строение 3, ...

Easily Adhesive Polyester Film and Manufacturing Method Thereof

본 발명을 흠집 결점이 적고, 또한 제품 롤 보관 시에서의 타이트 와인딩 등에 기인하는 외관 결점이 발생하지 않는 이접착성 폴리에스테르 필름 및 그의 효율적인 제조방법을 제공하는 것을 과제로 한다. 상기 과제의 해결 수단으로서, 본 발명은 폴리에스테르 필름을 기재 필름으로 하고, 상기 기재 필름의 적어도 편면 상에 이접착층을 갖는 이접착성 폴리에스테르 필름으로서, 상기 기재 필름이 평균 입자경 0.1 ㎛ 이상 2 ㎛ 이하의 입자를 기재 필름의 질량에 대해 1 질량% 이하 함유하고, 상기 이접착층이 공중합 폴리에스테르 수지(A), 블록 이소시아네이트기를 갖는 우레탄 수지(B), 및 실리콘계 계면활성제(C)를 함유하는 조성물이 경화되어 이루어지는 이접착성 폴리에스테르 필름, 및 인라인 코트법에 의한 이접착성 폴리에스테르 필름의 제조방법으로 이루어진다.

New organic polyisocyanates and their manufacture

The invention comprises allophanate polyisocyanates which are obtainable by reacting an excess of organic diisocyanate with a urethane isocyanate of formula R1(OOCNHRNCO)n where R1 is a monovalent or polyvalent organic radical, the residue of a mono or polyhydroxylic compound after reaction of the hydroxyl group with an isocyanate group, n is an integer from 1 to 6 and represents the functionality of the hydroxyl compound and R is a divalent organic radical, the excess of organic diisocyanate being an excess over that required for the reaction of one molecule of diisocyanat for each urethane group. Examples of monoe hydric alcoholds from which R1 may bedrived include methanol, ethanol, isopropanol and phenol.ALSO:Allophanate polyisocyanates are produced by reacting an excess of organic diisocyanate with a urethane isocyanate of formula R1(OOCNHRNCO)n, wherein R1 is a monovalent or polyvalent organic radical, the residue of a mono- or poly-hydroxylic compound after reaction of the hydroxyl group with an isocyanate group, n is an integer from 1 to 6 and represents the functionality of the hydroxyl compound and R is a divalent substituted or unsubstituted organic radical, the excess of organic diisocyanate being an excess over that required for the reaction of one molecule of diisocyanate for each urethane group. The divalent radical R may be alkyl, cycloalkyl, aryl or aralkyl and may be substituted e.g. by halogen, nitro or other radicals non-reactive to the isocyanate group. The radical R1 may preferably be derived from alcohols containing 2 to 6 hydroxyl groups, e.g. ethylene glycol, diethylene glycol, trimethylol propane, glycerol, butylene glycols and oxypropylation products of diethylene glycol, trimethylolpropane and sorbitol. Any organic diisocyanate may be used, preferred diisocyanates are: hexamethylene-, tolylylene-, methylcohexyl-, and xylylene diisocyanates in an excess of from 10 to 300% over that required for the reaction of one molecule of diisocyanate ...

Aqueous dispersion, production method for same, and image formation method

An aqueous dispersion that contains microcapsules and water. The microcapsules include a shell and a core. The shell has a three-dimensional cross-linked structure that includes: at least one type of linkage selected from urethane linkages and urea linkages; and, as hydrophilic groups, an anionic group and a nonionic group. The shell has a photopolymerization-initiating group and/or the core includes a photopolymerization initiator, and the shell has a polymerizable group and/or the core includes a polymerizable compound. A production for the aqueous dispersion. An image formation method that uses the aqueous dispersion.

Method for making polyisocyanate composition

Preparation of a (poly)isocyanate composition with reduced viscosity comprising dimeric isocyanate(s) with uretidine-dione unit from initial monomeric isocyanates. The initial reaction medium is heated, in the absence of a dimerization catalyst, to 50 deg C - 200 deg C for <= 24 hours. The preparation of a composition of polyfunctional isocyanates with reduced viscosity comprising isocyanate dimer(s), and / or trimer(s) with a uretidine-dione unit and other composition(s) with functional group derived from isocyanate group, from isocyanate monomers and another compound containing at least one group which can react with isocyanate comprises: (i) heating reaction mixture, in absence of dimerization catalyst, to at least 80 deg C, preferably at least 130 deg C, advantageously at least 170 deg C for advantageously less than 5 hours; (ii) reacting product from step (i) with compound containing at least one function different to isocyanate function, optionally in presence of a catalyst; (iii) eliminating isocyanate monomers from reaction product of step (ii); and (iv) isolating polyfunctional isocyanate composition.

POLYMERIZABLE PLASTICIZER, LIQUID POLYURETHANE RESIN COMPOSITION COMPRISING SAID PLASTICIZER AND USES THEREOF

Latent two-part polyurethane adhesives

Two-component polyurethane adhesives include a polyol component and a polyisocyanate component. The polyol component includes a polyether polyol and specific amount of an aliphatic diol chain extender. The polyisocyanate component includes an isocyanate prepolymer made by reacting an aromatic polyisocyanate with a polyether. The adhesive has an excellent combination of a prolonged open time followed by curing to form a strong adhesive bond. The adhesive is especially useful for bonding carbon fiber-reinforced plastics.

Hydrophilic comb polyurethane

Comb water soluble hydrophilic polyurethanes containing polyoxyethylene side-chains and having molecular weight higher than 100,000 are useful as deflocculant and water retention agents in paper coating compositions.

Compound having isocyanate functionality, preparation thereof and use thereof in a process for preparing a coating

平均异氰酸酯官能度大于2的本发明化合物由平均官能度大于2的(多)异氰酸酯与化合物X的反应产生，所述化合物X包含官能团B(H) n 或B’(H) n ’，其中n等于1或2，n’等于1、2或3，H是不稳定氢以及B表示O、S、N(N为伯或仲氮)、－C(＝O)－O、－C(＝O)－N、或基团O＝P(O) 2 ；O＝P(O)OR 1 ；O＝P(O) 3 ；O＝P(O) 2 OR 1 ；O＝P(O)－OR 1 ，R 1 表示烷基或芳烷基，以及B’表示－SiR 2 R 3 R 4 ，R 2 、R 3 和R 4 表示氧、带有与所述(多)异氰酸酯反应的官能团的烷基、或者芳烷基、芳基、－O－烷基或－O－芳烷基，另外X是脂环族、芳族或杂环化合物或者交联聚合物的粒子；以及条件是，当B表示仲氮以及当X是脂环族化合物时，则X是具有至少两个环的化合物；所述反应以化合物X/[化合物X+(多)异氰酸酯]重量比为至多50％下进行。本发明还涉及包含至少一种上述类型的化合物的固化剂型组合物。本发明的化合物或组合物可以用于油漆或清漆型的涂层的制备。

Polyisocyanate composition, polyurethane resin, two-part curable polyurethane composition, and coating material

多异氰酸酯组合物含有：苯二甲撑二异氰酸酯的改性体及五亚甲基二异氰酸酯的改性体，以及/或者，由苯二甲撑二异氰酸酯和五亚甲基二异氰酸酯形成的改性体。五亚甲基二异氰酸酯相对于苯二甲撑二异氰酸酯与五亚甲基二异氰酸酯的总量的比例为60摩尔％以上95摩尔％以下。

Process for fractionating a mixture of polyisocyanates

Method of fractionating a mixture of polyisocyanates in the liquid phase, optionally in the presence of a suitable solvent or mixture of two or more solvents, by means of a selectively permeable membrane into a permeate stream and a retentate stream of polyisocyanate compositions different to each other and different to the original mixture.

Coated particles, methods for their manufacture and for their use as proppants

Disclosed are coated particles. The coated particles include substrate particles and a coating disposed over at least a portion of the substrate particles. The coating includes a condensation reaction product of a reaction mixture that includes a liquid isocyanate-functional component and an isocyanate-reactive composition. Also disclosed are methods for making such particles and methods for using such particles as proppants in hydraulic fracturing.

Multilayer coatings and methods for production thereof

FIELD: chemistry. SUBSTANCE: present invention relates to a multilayer coating system, as well as a substrate coated with a multilayer coating, and a method of coating a substrate with a multilayer coating. Multilayer coating system comprises: (a) a first base coating layer, (b) a second base coating layer applied over at least a portion of the first base coating layer, and (c) a topcoat layer applied over at least a portion of the second base coat layer. First coating layer is formed from the first coating composition containing free polyisocyanate and polymer core-shell particles with hydroxyl functional groups. Polymer core and the polymer shell of the core-shell particles with hydroxyl functional groups each independently contain an additive polymer formed from ethylenically unsaturated monomers. Second coating layer is formed from the second coating composition containing polymer core-shell particles with carboxylic acid functional groups. Polymer core of core-shell particles with carboxyl acid functional groups contains an additive polymer formed from ethylenically unsaturated monomers, and the polymer shell of said particles contains urethane bonds and carboxylic acid functional groups. Topcoat layer is formed from a coating composition containing at least one free polyisocyanate having a weight average molecular weight of less than 600 g/mol, and at least one film-forming resin, wherein the amount of free polyisocyanate having a weight-average molecular weight of less than 600 g/mol is more than 5 wt. % based on the total weight of the solid polymer substances in the coating composition which forms the top coating layer. EFFECT: present invention provides for creation of multilayer coatings, which can be dehydrated and cured at relatively low temperatures with formation of coatings having different properties, thereby reducing costs and increasing efficiency of coating processes. 21 cl, 7 tbl, 26 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 768 458 C1 (51) ...

Eyewear material, eyewear frame, and eyewear

The eyewear material is an eyewear material containing thermoplastic polyurethane. The eyewear material has a tan δ peak at both less than 0° C. and 0° C. or more and 70° C. or less observed in dynamic viscoelasticity measurement in tensile mode under the measurement conditions of a temperature increase speed of 5° C./min and a measurement frequency of 10 Hz.

Laminated film

The present invention provides an environment-responsive laminated film including an inorganic thin film layer and a protective layer in this order on a substrate film layer using a polyester resin recycled from PET bottles. The laminated film has excellent barrier properties and adhesiveness even after a severe wet heat treatment and has less deterioration in appearance of the film even after retorting. The laminated film comprises a substrate film; an inorganic thin film layer on at least one surface of the substrate film; and a protective layer containing a urethane resin on the inorganic thin film layer, wherein (a) the substrate film contains 50% by weight or more of a polyester resin recycled from PET bottles; (b) standard deviation of a haze after retorting the laminated film at 130° C. for 30 minutes is 0.5% or less; and (c) an adhesion amount of the protective layer is 0.5 g/m2 or less.

TWO-COMPONENT ADHESIVE COMPOSITIONS WITHOUT SOLVENTS AND METHODS FOR THEIR PREPARATION

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2019 110 727 A (51) МПК C09J 175/04 (2006.01) C09J 175/06 (2006.01) C09J 175/08 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2019110727, 19.09.2016 (71) Заявитель(и): ДАУ ГЛОУБЛ ТЕКНОЛОДЖИЗ ЛЛК (US), РОМ ЭНД ХААС КОМПАНИ (US) Приоритет(ы): (22) Дата подачи заявки: 19.09.2016 (43) Дата публикации заявки: 12.10.2020 Бюл. № 29 (86) Заявка PCT: CN 2016/099304 (19.09.2016) WO 2018/049672 (22.03.2018) (54) ДВУХКОМПОНЕНТНЫЕ АДГЕЗИВНЫЕ КОМПОЗИЦИИ БЕЗ РАСТВОРИТЕЛЕЙ И СПОСОБЫ ИХ ПОЛУЧЕНИЯ R U (57) Формула изобретения 1. Двухкомпонентная адгезивная композиция без растворителей, содержащая полиольный компонент, содержащий соединение с фосфатной функциональной группой и по меньшей мере один полиол, выбранный из сложного полиэфира, простого полиэфира и их комбинаций; и изоцианатный компонент, содержащий изоцианатный форполимер, который является продуктом реакции по меньшей мере одного изоцианатного мономера и по меньшей мере одного полиола, выбранного из сложного полиэфира, простого полиэфира и их комбинаций. 2. Композиция по п. 1, отличающаяся тем, что соединение с фосфатной функциональной группой имеет структуру I 3. Композиция по п. 2, отличающаяся тем, что соединение с фосфатной функциональной группой представляет собой полиол с фосфатной функциональной группой, содержащий две или более гидроксильные группы и одну или более структур I. Стр.: 1 A 2 0 1 9 1 1 0 7 2 7 A Адрес для переписки: 105082, Москва, Спартаковский пер., д. 2, стр. 1, секция 1, этаж 3, ЕВРОМАРКПАТ 2 0 1 9 1 1 0 7 2 7 (87) Публикация заявки PCT: R U (85) Дата начала рассмотрения заявки PCT на национальной фазе: 10.04.2019 (72) Автор(ы): БАЙ, Чэньянь (CN), ЧЭНЬ, Май (US), МАРИН, Амира Аврил (US), ЦУПАНЧИК, Джозеф Джеймс (US), ГО, Иньчжун (US) R U 4. Композиция по п. 3, отличающаяся тем, что полиол с фосфатной функциональной группой является продуктом реакции полиола и полифосфорной кислоты. 5. Композиция по п ...

Hydrophilic comb polyurethane

本发明提供一种梳型水溶性亲水性聚氨酯，其包含聚氧乙烯侧链，且分子量高于100,000，可用作纸涂料组合物中的抗絮凝剂和保水剂。

infrared radiation curable two-part latent polyurethane adhesives

são divulgados adesivos de poliuretano latentes de duas partes que rapidamente desenvolvem resistência adesiva quando curados por aplicação de radiação infravermelha contendo um componente de poliol que inclui um ou mais polióis com um peso equivalente de hidroxil de 400 a 2000 e uma funcionalidade hidroxil nominal de 2 a 4; um ou mais extensores de cadeia de diol alifáticos; e um ou mais catalisadores organometálicos latentes de temperatura ambiente; b) um componente de poli-isocianato contendo um ou mais compostos de poli-isocianato; e v) um composto de amidina cíclica bloqueada com ácido carboxílico e vi) um composto de amidina cíclica bloqueada com fenol em que cada um pode estar localizado no componente de poliol ou no componente de isocianato. são divulgados ainda métodos de estruturas de ligação em conjunto usando o adesivos de poliuretano latentes de duas partes. Two-part latent polyurethane adhesives which rapidly develop adhesive strength when cured by infrared radiation containing a polyol component comprising one or more polyols having a hydroxyl equivalent weight of 400 to 2000 and a nominal hydroxyl functionality of 2 to 2 are disclosed. 4; one or more aliphatic diol chain extenders; and one or more room temperature latent organometallic catalysts; b) a polyisocyanate component containing one or more polyisocyanate compounds; and v) a carboxylic acid-blocked cyclic amidine compound; and vi) a phenol-blocked cyclic amidine compound wherein each may be located on the polyol component or the isocyanate component. Further disclosed are methods of bonding structures together using the two-part latent polyurethane adhesives.

Two-component solvent-less adhesive composition

本公開提供了一種2組分無溶劑的粘合劑組合物。2組分無溶劑的粘合劑組合物包含(A)異氰酸酯組分；和(B)多元醇組分的反應產物，多元醇組分包含(i)聚酯-聚碳酸酯多元醇和(ii)磷酸酯封端的多元醇。本公開還提供了一種形成2組分無溶劑的粘合劑組合物的方法。

Process for fractionating a mixture of polyisocyanates

Method of fractionating a mixture ofpolyisocyanates in the liquid phase, optionally in the presence of a suitable solvent or mixture of two or more solvents, by means of a selectively permeable membrane into a permeate stream and a retentate stream of polyisocyanate compositions different to each other and different to the original mixture.

Toluene diisocyanate residue-based compositions having reduced acid values

TDI residue-based urethane-filled isocyanate compositions are produced by reacting a TDI residue satisfying specified criteria with a monofunctional alcohol in amounts such that the equivalent ratio of isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. This reaction product is then dissolved in a diisocyanate or polyisocyanate before, during or after reaction of that product with an epoxide having an epoxide equivalent weight of from about 44 to about 400 at a temperature of up to 120~C. These TDI residue-based urethane-filled isocyanate compositions are particularly useful in the production of polyurethanes.

Method for the preparation of low-viscosity (poly)isocyanates.

Method for preparing (poly)isocyanate composition with reduced viscosity

본 발명은 출발 단량체 이소시아네이트로부터 우레티딘디온 단위를 갖는 1종 이상의 이합체 이소시아네이트를 포함하는 저점도 (폴리)이소시아네이트 조성물을 제조하기 위한 방법으로서, 출발 반응 매질을, 이합체화 촉매의 부재 하에서, 24시간 이하의 시간 동안, 50℃ 이상 그리고 200℃ 이하의 온도까지 가열하는 것을 특징으로 하는 방법에 관한 것이다. The present invention provides a process for the preparation of low viscosity (poly) isocyanate compositions comprising at least one dimeric isocyanate having uretidinedione units from the starting monomer isocyanate, wherein the starting reaction medium is used for 24 hours in the absence of a dimerization catalyst. And a temperature of at least 50 ° C and at most 200 ° C for the following times.

Two-component solvent-less adhesive composition

The present disclosure provides a two-component solvent-less adhesive composition. The two- component solvent-less adhesive composition contains the reaction product of (A) an isocyanate component and (B) a polyol component containing a polyester-amide polycarbonate polyol. The present disclosure also provides a method of forming a two-component solvent-less adhesive composition.

Fiber, fabric, non-woven fabric, film, sheet and apparel

【課題】各種用途において、要求物性を向上させることのできる１，４−ビス（イソシアナトメチル）シクロヘキサン、その１，４−ビス（イソシアナトメチル）シクロヘキサンを用いて得られるポリイソシアネート組成物およびポリウレタン樹脂、さらに、そのポリウレタン樹脂から得られる繊維、布帛、不織布、フィルム、シートおよび衣料を提供すること。【解決手段】１，４−ビス（イソシアナトメチル）シクロヘキサンは、シス体およびトランス体の総量に対してトランス体を７０モル％以上９５モル％以下の割合で含み、かつ、下記式（１）で示される化合物の含有割合が０．１ｐｐｍ以上３００ｐｐｍ以下である。【化１】【選択図】なし [PROBLEMS] To provide 1,4-bis (isocyanatomethyl) cyclohexane, polyisocyanate composition and polyurethane obtained by using the 1,4-bis (isocyanatomethyl) cyclohexane capable of improving required physical properties in various uses. To provide a resin, and further, a fiber, a fabric, a nonwoven fabric, a film, a sheet, and clothing obtained from the polyurethane resin. 1,4-bis (isocyanatomethyl) cyclohexane contains a trans isomer in a proportion of 70 mol% to 95 mol% with respect to the total amount of cis isomer and trans isomer, and has the following formula (1): The content ratio of the compound represented by is 0.1 ppm or more and 300 ppm or less. [Chemical 1] [Selected figure] None

The resting form bi-component polyurethane carbamate adhesive that can be solidified with infra-red radiation

公开潜伏型双组分聚氨基甲酸酯胶粘剂，在通过施加红外辐射来固化时快速产生胶粘强度，所述胶粘剂含有：多元醇组分，包括羟基当量为400到2000且标称羟基官能度为2到4的一种或多种多元醇、一种或多种脂族二醇扩链剂以及一种或多种潜伏型室温有机金属催化剂；b)聚异氰酸酯组分，含有一种或多种聚异氰酸酯化合物，且v)羧酸封端的环脒化合物以及vi)酚封端的环脒化合物各自能够定位于所述多元醇组分或所述异氰酸酯组分中。进一步公开使用所述潜伏型双组分聚氨基甲酸酯胶粘剂将结构粘合在一起的方法。

Potential two-component polyurethane adhesive that can be cured by infrared radiation

1,4-bis(isocyanatomethyl)cyclohexane, polyisocyanate composition, polyurethane resin, molded product, eyewear material, eyewear frame and lens

Polyisocyanate composition, polyurethane resin, two-liquid curing type polyurethane composition and coating material

폴리아이소사이아네이트 조성물이, 자일릴렌 다이아이소사이아네이트의 변성체, 및 펜타메틸렌 다이아이소사이아네이트의 변성체를 함유하거나, 및/또는, 자일릴렌 다이아이소사이아네이트 및 펜타메틸렌 다이아이소사이아네이트로 이루어지는 변성체를 함유한다. 자일릴렌 다이아이소사이아네이트와 펜타메틸렌 다이아이소사이아네이트의 총량에 대한 펜타메틸렌 다이아이소사이아네이트의 비율이 60몰% 이상 95몰% 이하이다. Wherein the polyisocyanate composition contains a modified product of xylylene diisocyanate and a modified product of pentamethylene diisocyanate and / or a mixture of xylylene diisocyanate and pentamethylene diisocyanate And a cyanate modified substance. The ratio of pentamethylene diisocyanate to the total amount of xylylene diisocyanate and pentamethylene diisocyanate is from 60 mol% to 95 mol%.

1,4-bis(isocyanatomethyl)cyclohexane, polyisocyanate composition, polyurethane resin, molded article, eyewear material, eyewear frame, and lens

本发明涉及1,4－双(异氰酸甲酯基)环己烷、多异氰酸酯组合物、眼镜材料、眼镜框以及镜片，该1,4－双(异氰酸甲酯基)环己烷，相对于顺式体和反式体的总量，以70摩尔％以上95摩尔％以下的比例含有反式体，并且下述式(1)表示的化合物的含有比例为0.1ppm以上300ppm以下。

Non-reactive fluorine-based compound and a photopolymerizable composition containing the same

Low-monomer nco prepolymers and use thereof

The invention relates to a low-monomer NCO prepolymer composition of the type A-B-A, which is obtained by reacting CH-acidic compounds with diisocyanates, and methods for the production and use thereof.

Latent two-part polyurethane adhesives curable with infrared radiation

USE OF POLYHYDROXYL PRODUCTS FOR THE PREPARATION OF POLYFUNCTIONAL POLYISOCYANATES

Adhesive composition and hot-melt adhesive member using same

[课题]本发明提供常温剥离强度和热剥离强度高且粘合性优异、而且即使在用于锂离子电池用包装材料时耐电解液性也优异的粘合剂组合物及使用其的热熔粘合性部件。[解决手段]本发明涉及一种粘合剂组合物及使用其的热熔粘合性部件，所述粘合剂组合物是含有有机溶剂、溶解在该有机溶剂中的具有酸性基团和/或酸酐基的聚烯烃(A)、以及异氰酸酯化合物的粘合剂组合物，其中，上述异氰酸酯化合物含有：具有碳数4～7的烃基的二异氰酸酯化合物和/或其衍生物(B)、以及具有碳数8～14的烃基的二异氰酸酯化合物和/或其衍生物(C)。

METHOD FOR FACTIONING A MIXTURE OF POLYISOCYANATES

1. Способ фракционирования смеси полиизоцианатов в жидкой фазе с помощью мембраны с избирательной проницаемостью на поток пермеата и поток ретентата полиизоцианатных составов, различающихся между собой и отличающихся от исходной смеси. ! 2. Способ по п,1, в котором впоследствии потоки пермеата и ретентата разделяют и извлекают. ! 3. Способ по п.1 или 2, в котором фракционирование проводят в присутствии подходящего растворителя или смеси двух или более растворителей. ! 4. Способ по п.3, в котором растворитель выбирают из ароматических углеводородов, галогенированных ароматических углеводородов, алкилированных ароматических углеводородов, других функционализированных ароматических углеводородов, алканов, циклических алканов, галогенированных алканов и алканов с другими функциональными группами, кетонов, амидов и сложных эфиров, N-метил-2-пирролидона, диметилсульфоксида, сульфолана и пиридина. ! 5. Способ по п.3, в котором растворитель извлекают, необязательно очищают и используют повторно. ! 6. Способ по п.1 или 2, в котором мембрану с избирательной проницаемостью выбирают из полимерных мембран, неорганических или керамических мембран или композиционных мембран, составленных более чем из одного материала. ! 7. Способ по п.6, в котором мембрана с избирательной проницаемостью представляет собой полимерную мембрану на основе полиимида или полидивинилфторида. ! 8. Способ по п.6, в котором мембрана с избирательной проницаемостью представляет собой керамическую мембрану, которая предпочтительно была подвергнута предварительной обработке. ! 9. Способ по п.1 или 2, в котором исходная смесь полиизоцианатов образуется в резу�

Two-component curing type solvent-based adhesive for laminate and resin cured product

Cationic curing agent, method for producing same and cationically curable composition

A cationic curing agent includes: porous particles; and a compound represented by General Formula (1) below, the compound being held in the porous particles.In the General Formula (1), R¹ is an alkyl group having 1 to 18 carbon atoms or a phenyl group, where the alkyl group may be branched and the alkyl group and the phenyl group may each further have a substituent,R² is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms where the alkyl group may be branched, a halogenoalkyl group, an alkoxy group, or a phenoxy group, where the alkyl group, the halogenoalkyl group, the alkoxy group, or the phenoxy group may further have a substituent, andR¹ and R² may be identical to or different from each other.

Adhesive composition and heat-sealable member using the same

(과제) 상온 박리 강도 및 열간 박리 강도가 높아 접착성이 우수하고, 또한 리튬이온 전지용 포장 재료에 사용한 경우에도 내전해액성이 우수한 접착제 조성물 및 그것을 사용한 열융착성 부재를 제공하는 것. (해결 수단) 유기 용제, 상기 유기 용제에 용해하는 산성기 및/또는 산무수물기를 갖는 폴리올레핀 (A) 및 이소시아네이트 화합물을 함유하는 접착제 조성물로서, 상기 이소시아네이트 화합물이 탄소수 4~7개의 탄화수소기를 갖는 디이소시아네이트 화합물 및/또는 그 유도체 (B), 및 탄소수 8~14개의 탄화수소기를 갖는 디이소시아네이트 화합물 및/또는 그 유도체 (C)를 포함하는 접착제 조성물 및 그것을 사용한 열융착성 부재에 관한다. (Problem) To provide an adhesive composition having high normal temperature peel strength and high hot peel strength, excellent adhesiveness, and excellent electrolyte resistance even when used for packaging materials for lithium ion batteries, and a heat-sealable member using the same. (Solution Means) An adhesive composition containing an organic solvent, a polyolefin (A) having an acidic group and/or an acid anhydride group soluble in the organic solvent, and an isocyanate compound, wherein the isocyanate compound is a diisocyanate having a hydrocarbon group having 4 to 7 carbon atoms. It relates to an adhesive composition comprising a compound and/or a derivative thereof (B), and a diisocyanate compound having a hydrocarbon group of 8 to 14 carbon atoms and/or a derivative thereof (C), and a heat-sealable member using the same.

Method of polyisocyanate mix fractionation

FIELD: process engineering. ^ SUBSTANCE: invention relates to method of polyisocyanate mix fractionation. polyisocyanate mix in liquid phase is subjected to fractionation with the help of membrane that features selective permeate and polyisocyanate-compound retentate flows permeability, said flows being different and differ from initial mix. ^ EFFECT: higher efficiency, lower costs. ^ 11 ex

Copolymers of hydrophobic and hydrophilic segments that reduce protein adsorption

The present disclosure relates to compositions A composition comprising a polymerization product of an anionic polysaccharide, a diisocyanate, and a linker, wherein the linker comprises i) an ether group, an ester group, or a combination thereof and, ii) a chain extender comprising a hydroxyl group, a thiol group, an amine group, or a combination thereof. The disclosure further relates to medical devices comprising the aforementioned compositions, and to methods of using the compositions and devices. More particularly, the compositions, devices and methods described herein are useful for preventing protein adhesions in vivo, particularly the Vroman effect.

Double (isocyanatomethyl) hexamethylene of 1,4-, polyisocyantates composition, ocular lens material, spectacle-frame and eyeglass

本发明涉及1,4－双(异氰酸甲酯基)环己烷、多异氰酸酯组合物、眼镜材料、眼镜框以及镜片，该1,4－双(异氰酸甲酯基)环己烷，相对于顺式体和反式体的总量，以70摩尔％以上95摩尔％以下的比例含有反式体，并且下述式(1)表示的化合物的含有比例为0.1ppm以上300ppm以下。

Polyisocyanate composition, aqueous coating composition and coating base material

【課題】粘度変化が良好であり、水系コーティング組成物としたときのポットライフが良好であり、且つ、塗膜としたときの乾燥性、光沢、硬度、耐水性及び耐塩水噴霧性に優れるポリイソシアネート組成物を提供する。【解決手段】ポリイソシアネート組成物は、脂肪族ジイソシアネート及び脂環族ジイソシアネートからなる群より選択される１種以上のジイソシアネートから誘導されるポリイソシアネートを含み、ポリイソシアネートが有するイソシアネート基由来の結合基のうち、イソシアヌレート基のモル比率が最も多く、数平均分子量が２００以上４００未満であるポリイソシアネートの質量分率（Ａ）に対する、数平均分子量が４００以上７００以下であるポリイソシアネートの質量分率（Ｂ）の比が１～１５０であり、且つ、ポリイソシアネート組成物の総質量に対する数平均分子量が１０００以上であるポリイソシアネートの質量分率が５～２０質量％である。【選択図】なし

Polyurethane hot melt adhesive with a low monomer diisocyanate content and good curing speed

Pentamethylene diisocyanate, method for producing pentamethylene diisocyanate, polyisocyanate composition, polyurethane resin and polyurea resin

Un diisocianato de pentametileno obtenido sometiendo a fosgenación pentametilendiamina o su sal obtenida mediante un método bioquímico, en el que el diisocianato de pentametileno contiene de 5 a 400 ppm de un compuesto representado por la fórmula general (1) a continuación y un compuesto representado por la fórmula general (2) a continuación en total**Fórmula** A pentamethylene diisocyanate obtained by subjecting phosgenation pentamethylenediamine or its salt obtained by a biochemical method, wherein the pentamethylene diisocyanate contains 5 to 400 ppm of a compound represented by the general formula (1) below and a compound represented by the general formula (2) below in total ** Formula **

Storage stable polyurethane casting mass for embedding of hollow fibers in the production of filter elements

Polyurethane foam dressing and wound dressing products wherein the polyurethane foam dressing is formed by mixing the prepolymer with a hydrophilic polyether polyol, a foaming agent, a capping agent, a strengthening agent, and a catalyst

一種聚氨酯泡綿敷料，是由以下步驟所製得：(a) 提供一具有六個羥基的疏水性多元醇，該疏水性多元醇是由以下子步驟所製得：(a1) 使一分枝的三元醇與一第一二異氰酸酯反應，以得到一三異氰酸酯中間物，及(a2) 使該三異氰酸酯中間物與一疏水性聚醚三元醇反應。(b) 提供一親水性二異氰酸酯，該親水性二異氰酸酯是由一第二二異氰酸酯與一親水性聚醚二元醇反應而得。(c) 使該疏水性多元醇與該親水性二異氰酸酯反應，以得到一含有3~6個異氰酸酯基團的預聚物。(d) 混合該預聚物與一親水性聚醚多元醇、一發泡劑、一封端劑、一強化劑及一催化劑，以形成該聚氨酯泡綿敷料。

Multi-Layer Coatings and Methods of Preparing the Same

A multi-layer coating system includes: (a) a first basecoat layer formed from a first coating composition including a free polyisocyanate and hydroxyl functional polymeric core-shell particles; (b) a second basecoat layer applied over at least a portion of the first basecoat layer, the second basecoat layer formed from a second coating composition including carboxylic acid functional polymeric core-shell particles; and (c) a topcoat layer applied over at least a portion of the second basecoat layer, the topcoat layer formed from a coating composition including least one free polyisocyanate having a weight average molecular weight of less than 600 g/mol and at least one film-forming resin in which an amount of free polyisocyanate having a weight average molecular weight of less than 600 g/mol is greater than 5 weight %, based on the total resin solids of the coating composition that forms the topcoat layer.

1,4-bis (isocyanatomethyl) cyclohexane, polyisocyanate composition, polyurethane resin, and molded article

本發明之1,4-雙(異氰酸基甲基)環己烷相對於順式體及反式體之總量而以70莫耳%以上且95莫耳%以下之比例含有反式體，且下述式(1)所表示之化合物之含有比例為0.1ppm以上且300ppm以下。

Polyisocyantates composition, coating composition and coating process

一种多异氰酸酯组合物、涂料组合物以及涂装方法。[课题]目的在于提供与活性氢化合物的反应带来的固化性优异并且基底质地的隐藏性优异的多异氰酸酯组合物。[解决方法]一种多异氰酸酯组合物，其至少由脂肪族二异氰酸酯、二元醇、以及一元醇得到，异氰酸酯基平均数为3.8以上且10.0以下。

1,4-bis(isocyanatomethyl)cyclohexane, polyisocyanate composition, polyurethane resin, molded product, eyewear material, eyewear frame and lens

一种1,4－双(异氰酸甲酯基)环己烷，相对于顺式体和反式体的总量，以70摩尔％以上95摩尔％以下的比例含有反式体，并且下述式(1)表示的化合物的含有比例为0.1ppm以上300ppm以下。

Polyisocyanate resins

Polyisocyanatharzmischung, enthaltend A) wenigstens ein urethan- und/oder isocyanurathaltiges, Estergruppen-freies Polyisocyanat enthaltend aromatisch gebundene NCO-Gruppen mit einem NCO-Gehalt von 10-30 Gew.-%, bezogen auf das Polyisocyanat A), einer mittleren NCO-Funktionalität von größer gleich 2,1, insbesondere 2,1-6, bevorzugt 2,3-4, besonders bevorzugt 2,5-3,5 und einer mittleren Molmasse (Zahlenmittel) < 800 g/mol und B) wenigstens ein polyestermodifiziertes, isocyanuratgruppenhaltiges Polyisocyanat mit ausschließlich alphatisch gebundenen NCO-Gruppen und Isocyanuratgruppen mit einem NCO-Gehalt von 7-18 Gew.-%, bezogen auf das Polyisocyanat B), einem Isocyanuratgehalt (M = 126) von 8-20 Gew.-%, bezogen auf das Polyisocyanat B), einem Polyestergehalt (gerechnet als Polyesterdiol) von 30-50 Gew.-%, bezogen auf das Polyisocyanat B), wobei das zugrundeliegende Polyesterdiol eine mittlere Molmasse (Zahlenmittel) von 350-950 g/mol besitzt und aufgebaut ist aus a) Adipinsäure und/oder Capronsäure und b) Diolen mit einer Molmasse von 62-300 g/mol, vorzugsweise 1,6-Hexandiol, insbesondere auf Hexandiol gestartetem ε-Caprolactondiol.

Multilayer film

본 발명의 적층 필름은, 편광판과, 위상차 필름과, 제 1 점착제층을 적어도 이 순서대로 구비하고, 그 편광판은, 편광자와, 그 편광자의 위상차 필름을 구비하는 측에 배치된 제 1 보호층과, 그 편광자의 위상차 필름을 구비하는 측과는 반대측에 배치된 제 2 보호층을 포함하고, 그 위상차 필름은, 노르보르넨계 수지를 함유하는 연신 필름이고, 그 제 1 점착제층은, (메트)아크릴레이트계 (코)폴리머와, 과산화물을 주성분으로 하는 가교제를 적어도 배합한 조성물을 가교시켜 얻어질 수 있는 점착제를 포함한다. 본 발명의 적층 필름은, 액정 표시 장치의 표시 균일성을 개선할 수 있고, 나아가 액정 셀과의 접착성이 우수하며, 또한 경박리성이 우수하다. The laminated | multilayer film of this invention is equipped with a polarizing plate, a retardation film, and a 1st adhesive layer at least in this order, The polarizing plate is a 1st protective layer arrange | positioned at the side provided with a polarizer and the retardation film of this polarizer; And a 2nd protective layer arrange | positioned on the opposite side to the side provided with the retardation film of this polarizer, The retardation film is a stretched film containing a norbornene-type resin, The 1st adhesive layer is (meth) The adhesive which can be obtained by bridge | crosslinking the composition which mix | blended at least the acrylate-type (co) polymer and the crosslinking agent which has a peroxide as a main component is included. The laminated | multilayer film of this invention can improve the display uniformity of a liquid crystal display device, Furthermore, it is excellent in adhesiveness with a liquid crystal cell, and is excellent in hard peelability. 적층 필름, 편광판, 점착제층, 경박리성, 액정 표시 장치 Laminated film, polarizing plate, pressure-sensitive adhesive layer, light peelability, liquid crystal display device

Developing roller

A developing roller having a rubber elastomer layer on the outer periphery of a shaft core metal, having a coating layer formed from a binder (A) and silicone rubber particles (B) on the surface of the rubber elastomer, and having an electrostatic capacitance of 4 to 20 nF; wherein the binder (A) is formed from a diluting solvent solution of a terminal hydroxyl group-containing prepolymer (a) obtained by reaction of an isocyanate compound, an isocyanurate modified product thereof and a reactive silicone oil, and an isocyanate compound and/or an isocyanurate modified product thereof (b). This developing roller suppresses banding by suppressing electrostatic capacitance even if the nip width between the developing roll and the photoreceptor changes due to distortion of peripheral members in the development apparatus, and stick slip (vibration) of gears.

Potential two-component polyurethane adhesive that can be cured by infrared radiation

Latent two-part polyurethane adhesives cured with infrared radiation

Two-component polyurethane adhesives include a polyol component and a polyisocyanate component. The polyol component includes a polyether polyol and an aliphatic diol chain extender, but is devoid of primary and second amine compounds. The polyisocyanate component includes one or more polyisocyanate compounds. The adhesive contains a mixture of a dialkyltinthioglycolate catalyst and an acid-blocked cyclic amidine catalyst. The tin catalyst is formulated into the polyol component, whereas the cyclic amidine catalyst can be formulated into either the polyol or the polyisocyanate components.